0-3670R Hydrosure Msds Eng AIP 30112010-2

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REVISION DATE 30/11/2010 SAFETY DATA SHEET Hydrosure 0-3670R 1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING PRODUCT NO. O3670R APPLICATION HYDROTEST CHEMICAL Champion Arabia, Co. Ltd. SUPPLIER P.O.Box 3254 Al-Khobar 31952 Saudi Arabia 0096638122100 0096638122040 2 HAZARDS IDENTIFICATION Causes burns. Contact with acids liberates toxic gas. CLASSIFICATION (1999/45) C;R34. R31. 3 COMPOSITION/INFORMATION ON INGREDIENTS EC No. Name Classification (67/548/EEC) CAS-No. Content % 270-325-2 Quaternary ammonium chloride Xn;R22. C;R34. N;R50. 68424-85-1 10-30% 233-469-7 AMMONIUM BISULPHITE Xi;R36/37/38. R31. 10192-30-0 10-30% 252-104-2 DIPROPYLENE GLYCOL MONOMETHYL ETHER (DPM) - 34590-94-8 1-10% 203-473-3 ETHANEDIOL Xn;R22 107-21-1 < 1% The Full Text for all R-Phrases is Displayed in Section 16 4 FIRST-AID MEASURES INHALATION Move the exposed person to fresh air at once. If respiratory problems, artificial respiration/oxygen. Get medical attention. INGESTION NEVER MAKE AN UNCONSCIOUS PERSON VOMIT OR DRINK FLUIDS! Immediately rinse mouth and drink plenty of water (200-300 ml). DO NOT induce vomiting. Get medical attention immediately. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Generates toxic gas in contact with acid. SKIN CONTACT Rinse the skin immediately with lots of water. Continue to rinse for at least 15 minutes. Remove contaminated clothes and rinse skin thoroughly with water. Get medical attention immediately. Chemical burns must be treated by a physician. EYE CONTACT Remove victim immediately from source of exposure. Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids. Continue to rinse for at least 15 minutes and get medical attention. To hospital or eye specialist. 5 FIRE-FIGHTING MEASURES EXTINGUISHING MEDIA Water spray. Carbon dioxide (CO2). Dry chemicals, sand, dolomite etc. SPECIAL FIRE FIGHTING PROCEDURES Avoid water in straight hose stream; will scatter and spread fire. Cool containers exposed to flames with water until well after the fire is out. Avoid breathing fire vapours. Keep run-off water out of sewers and water sources. Dike for water control. UNUSUAL FIRE & EXPLOSION HAZARDS May develop highly toxic or corrosive fumes if heated. SPECIFIC HAZARDS Fire or high temperatures create: Oxides of: Carbon. Nitrogen. Sulphur. 5 1 /

description

Hydrosure

Transcript of 0-3670R Hydrosure Msds Eng AIP 30112010-2

Page 1: 0-3670R Hydrosure Msds Eng AIP 30112010-2

REVISION DATE 30/11/2010

SAFETY DATA SHEET

Hydrosure 0-3670R

1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING

PRODUCT NO. O3670R

APPLICATION HYDROTEST CHEMICAL

Champion Arabia, Co. Ltd.SUPPLIER

P.O.Box 3254

Al-Khobar 31952

Saudi Arabia

0096638122100

0096638122040

2 HAZARDS IDENTIFICATION

Causes burns. Contact with acids liberates toxic gas.

CLASSIFICATION (1999/45) C;R34. R31.

3 COMPOSITION/INFORMATION ON INGREDIENTS

EC No.Name Classification (67/548/EEC)CAS-No. Content %

270-325-2Quaternary ammonium chloride Xn;R22. C;R34. N;R50.68424-85-1 10-30%

233-469-7AMMONIUM BISULPHITE Xi;R36/37/38. R31.10192-30-0 10-30%

252-104-2DIPROPYLENE GLYCOL MONOMETHYL ETHER

(DPM)

-34590-94-8 1-10%

203-473-3ETHANEDIOL Xn;R22107-21-1 < 1%

The Full Text for all R-Phrases is Displayed in Section 16

4 FIRST-AID MEASURES

INHALATION

Move the exposed person to fresh air at once. If respiratory problems, artificial respiration/oxygen. Get medical attention.

INGESTION

NEVER MAKE AN UNCONSCIOUS PERSON VOMIT OR DRINK FLUIDS! Immediately rinse mouth and drink plenty of water (200-300

ml). DO NOT induce vomiting. Get medical attention immediately. If vomiting occurs, keep head low so that stomach content doesn't get

into the lungs. Generates toxic gas in contact with acid.

SKIN CONTACT

Rinse the skin immediately with lots of water. Continue to rinse for at least 15 minutes. Remove contaminated clothes and rinse skin

thoroughly with water. Get medical attention immediately. Chemical burns must be treated by a physician.

EYE CONTACT

Remove victim immediately from source of exposure. Make sure to remove any contact lenses from the eyes before rinsing. Promptly

wash eyes with plenty of water while lifting the eye lids. Continue to rinse for at least 15 minutes and get medical attention. To hospital or

eye specialist.

5 FIRE-FIGHTING MEASURES

EXTINGUISHING MEDIA

Water spray. Carbon dioxide (CO2). Dry chemicals, sand, dolomite etc.

SPECIAL FIRE FIGHTING PROCEDURES

Avoid water in straight hose stream; will scatter and spread fire. Cool containers exposed to flames with water until well after the fire is out.

Avoid breathing fire vapours. Keep run-off water out of sewers and water sources. Dike for water control.

UNUSUAL FIRE & EXPLOSION HAZARDS

May develop highly toxic or corrosive fumes if heated.

SPECIFIC HAZARDS

Fire or high temperatures create: Oxides of: Carbon. Nitrogen. Sulphur.

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Hydrosure 0-3670R

PROTECTIVE MEASURES IN FIRE

Wear full protective clothing. Use air-supplied respirator during fire fighting.

6 ACCIDENTAL RELEASE MEASURES

PERSONAL PRECAUTIONS

Wear protective clothing as described in Section 8 of this safety data sheet. Avoid inhalation of vapours and contact with skin and eyes.

ENVIRONMENTAL PRECAUTIONS

Do not discharge into drains, water courses or onto the ground.

SPILL CLEAN UP METHODS

Stop leak if possible without risk. DO NOT touch spilled material! Absorb in vermiculite, dry sand or earth and place into containers.

Flush area with plenty of water. Do not let washing down water contaminate ponds or waterways. Containers with collected spillage must

be properly labelled with correct contents and hazard symbol.

7 HANDLING AND STORAGE

USAGE PRECAUTIONS

Avoid spilling, skin and eye contact. Ventilate well, avoid breathing vapours. Use approved respirator if air contamination is above

accepted level. Observe good chemical hygiene practices. Keep away from heat, sparks and open flame. Eye wash facilities and

emergency shower must be available when handling this product.

STORAGE PRECAUTIONS

Store in tightly closed original container in a dry, cool and well-ventilated place. Store separated from: Acids. Alkalis. Oxidising material.

8 EXPOSURE CONTROLS/PERSONAL PROTECTION

STD STEL - 15 MinTWA - 8 HrsName Notes

AMMONIUM BISULPHITE

50 ppm 308 mg/m3WELDIPROPYLENE GLYCOL MONOMETHYL ETHER

(DPM)

Sk

10 mg/m3WEL 104 mg/m3ETHANEDIOL Sk

WEL = Workplace Exposure Limit.

Sk = Can be absorbed through skin.

PROTECTIVE EQUIPMENT

PROCESS CONDITIONS

Provide eyewash, quick drench.

ENGINEERING MEASURES

Provide adequate general and local exhaust ventilation.

RESPIRATORY EQUIPMENT

In case of inadequate ventilation use suitable respirator.

HAND PROTECTION

Use protective gloves made of: Rubber, neoprene or PVC. The most suitable glove must be chosen in consultation with the gloves

supplier, who can inform about the breakthrough time of the glove material. Be aware that the liquid may penetrate the gloves. Frequent

change is advisable.

EYE PROTECTION

Use approved safety goggles or face shield.

OTHER PROTECTION

Wear appropriate clothing to prevent any possibility of skin contact.

HYGIENE MEASURES

DO NOT SMOKE IN WORK AREA! Wash at the end of each work shift and before eating, smoking and using the toilet. Wash promptly if

skin becomes wet or contaminated. Promptly remove any clothing that becomes contaminated. When using do not eat, drink or smoke.

9 PHYSICAL AND CHEMICAL PROPERTIES

APPEARANCE Liquid

COLOUR Light (or pale) Coloured

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REVISION DATE 30/11/2010

Hydrosure 0-3670RODOUR Pungent Sulphur.

SOLUBILITY Miscible with water

RELATIVE DENSITY 1.045 - 1.075 @ 20 °c

pH-VALUE, CONC. SOLUTION 4.0-6.0

REFRACTIVE INDEX 39-41

10 STABILITY AND REACTIVITY

STABILITY

Stable under normal temperature conditions.

CONDITIONS TO AVOID

Avoid heat, flames and other sources of ignition.

HAZARDOUS POLYMERISATION

Will not polymerise.

MATERIALS TO AVOID

Strong acids. Strong oxidising substances.

HAZARDOUS DECOMPOSITION PRODUCTS

Oxides of: Carbon. Nitrogen. Sulphur.

11 TOXICOLOGICAL INFORMATION

INHALATION

Gas or vapour may irritate respiratory system.

INGESTION

Causes burns. May cause chemical burns in mouth and throat. Generates toxic gas in contact with acid.

SKIN CONTACT

Causes burns.

EYE CONTACT

Causes burns. Risk of serious damage to eyes.

12 ECOLOGICAL INFORMATION

ECOTOXICITY

The product contains a substance which is very toxic to aquatic organisms.

MOBILITY

The product is soluble in water.

BIOACCUMULATION

No data available on bioaccumulation.

13 DISPOSAL CONSIDERATIONS

GENERAL INFORMATION

Empty containers should be taken for local recycling, recovery or waste disposal

DISPOSAL METHODS

Recover and reclaim or recycle, if practical. Dispose of waste and residues in accordance with local authority requirements.

WASTE CLASS

For this product, in accordance with the European Waste Catalogue (EWC), a catalogue number cannot be given because the customer

has to lay down the purpose first. The catalogue number has to be given according to the local waste removal processes.

14 TRANSPORT INFORMATION

PROPER SHIPPING NAME CORROSIVE LIQUID, ACIDIC, ORGANIC, n.o.s. (contains quaternary ammonium chloride)

3265UN NO. ROAD

8ADR CLASS NO.

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Hydrosure 0-3670RClass 8: Corrosive substances.ADR CLASS

IIIADR PACK GROUP

80 Corrosive or slightly

corrosive substance.

HAZARD NO. (ADR)

80HAZARD No. (ADR)

2XHAZCHEM CODE

3265UN NO. SEA

8IMDG CLASS

IIIIMDG PACK GR.

F-A S-BEMS

3265UN NO. AIR

8ICAO CLASS

IIIAIR PACK GR.

15 REGULATORY INFORMATION

LABELLING

Corrosive

CONTAINS Quaternary ammonium chloride

RISK PHRASES

R31 Contact with acids liberates toxic gas.

R34 Causes burns.

SAFETY PHRASES

S24/25 Avoid contact with skin and eyes.

S26 In case of contact with eyes, rinse immediately with plenty of water and seek

medical advice.

S36/37/39 Wear suitable protective clothing, gloves and eye/face protection.

S45 In case of accident or if you feel unwell, seek medical advice immediately

(show label where possible).

S60 This material and its container must be disposed of as hazardous waste.

UK REGULATORY REFERENCES

Approved Supply List.

STATUTORY INSTRUMENTS

The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716).

APPROVED CODE OF PRACTICE

Classification and Labelling of Substances and Preparations Dangerous for Supply.

GUIDANCE NOTES

Workplace Exposure Limits EH40. Approved guide to the classification and labelling of substances and preparations dangerous for supply.

16 OTHER INFORMATION

REVISION COMMENTS

NOTE: Lines within the margin indicate significant changes from the previous revision.

ISSUED BY

GC

REVISION DATE 30/11/2010

REV. NO./REPL. SDS

GENERATED

4

RISK PHRASES IN FULL

Causes burns.R34

Contact with acids liberates toxic gas.R31

Harmful if swallowed.R22

Irritating to eyes, respiratory system and skin.R36/37/38

Very toxic to aquatic organisms.R50

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Hydrosure 0-3670R

DISCLAIMER

The information provided in this SDS is correct to the best of our knowledge, information and belief at the date of its publication. The information given is

designed only as a guidance for safe handling, use, processing, storage, transportation, disposal, and release and is not to be considered a warranty or

quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any

other materials or in any process unless specified in the text.

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