0-3670R Hydrosure Msds Eng AIP 30112010-2
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Transcript of 0-3670R Hydrosure Msds Eng AIP 30112010-2
REVISION DATE 30/11/2010
SAFETY DATA SHEET
Hydrosure 0-3670R
1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING
PRODUCT NO. O3670R
APPLICATION HYDROTEST CHEMICAL
Champion Arabia, Co. Ltd.SUPPLIER
P.O.Box 3254
Al-Khobar 31952
Saudi Arabia
0096638122100
0096638122040
2 HAZARDS IDENTIFICATION
Causes burns. Contact with acids liberates toxic gas.
CLASSIFICATION (1999/45) C;R34. R31.
3 COMPOSITION/INFORMATION ON INGREDIENTS
EC No.Name Classification (67/548/EEC)CAS-No. Content %
270-325-2Quaternary ammonium chloride Xn;R22. C;R34. N;R50.68424-85-1 10-30%
233-469-7AMMONIUM BISULPHITE Xi;R36/37/38. R31.10192-30-0 10-30%
252-104-2DIPROPYLENE GLYCOL MONOMETHYL ETHER
(DPM)
-34590-94-8 1-10%
203-473-3ETHANEDIOL Xn;R22107-21-1 < 1%
The Full Text for all R-Phrases is Displayed in Section 16
4 FIRST-AID MEASURES
INHALATION
Move the exposed person to fresh air at once. If respiratory problems, artificial respiration/oxygen. Get medical attention.
INGESTION
NEVER MAKE AN UNCONSCIOUS PERSON VOMIT OR DRINK FLUIDS! Immediately rinse mouth and drink plenty of water (200-300
ml). DO NOT induce vomiting. Get medical attention immediately. If vomiting occurs, keep head low so that stomach content doesn't get
into the lungs. Generates toxic gas in contact with acid.
SKIN CONTACT
Rinse the skin immediately with lots of water. Continue to rinse for at least 15 minutes. Remove contaminated clothes and rinse skin
thoroughly with water. Get medical attention immediately. Chemical burns must be treated by a physician.
EYE CONTACT
Remove victim immediately from source of exposure. Make sure to remove any contact lenses from the eyes before rinsing. Promptly
wash eyes with plenty of water while lifting the eye lids. Continue to rinse for at least 15 minutes and get medical attention. To hospital or
eye specialist.
5 FIRE-FIGHTING MEASURES
EXTINGUISHING MEDIA
Water spray. Carbon dioxide (CO2). Dry chemicals, sand, dolomite etc.
SPECIAL FIRE FIGHTING PROCEDURES
Avoid water in straight hose stream; will scatter and spread fire. Cool containers exposed to flames with water until well after the fire is out.
Avoid breathing fire vapours. Keep run-off water out of sewers and water sources. Dike for water control.
UNUSUAL FIRE & EXPLOSION HAZARDS
May develop highly toxic or corrosive fumes if heated.
SPECIFIC HAZARDS
Fire or high temperatures create: Oxides of: Carbon. Nitrogen. Sulphur.
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REVISION DATE 30/11/2010
Hydrosure 0-3670R
PROTECTIVE MEASURES IN FIRE
Wear full protective clothing. Use air-supplied respirator during fire fighting.
6 ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS
Wear protective clothing as described in Section 8 of this safety data sheet. Avoid inhalation of vapours and contact with skin and eyes.
ENVIRONMENTAL PRECAUTIONS
Do not discharge into drains, water courses or onto the ground.
SPILL CLEAN UP METHODS
Stop leak if possible without risk. DO NOT touch spilled material! Absorb in vermiculite, dry sand or earth and place into containers.
Flush area with plenty of water. Do not let washing down water contaminate ponds or waterways. Containers with collected spillage must
be properly labelled with correct contents and hazard symbol.
7 HANDLING AND STORAGE
USAGE PRECAUTIONS
Avoid spilling, skin and eye contact. Ventilate well, avoid breathing vapours. Use approved respirator if air contamination is above
accepted level. Observe good chemical hygiene practices. Keep away from heat, sparks and open flame. Eye wash facilities and
emergency shower must be available when handling this product.
STORAGE PRECAUTIONS
Store in tightly closed original container in a dry, cool and well-ventilated place. Store separated from: Acids. Alkalis. Oxidising material.
8 EXPOSURE CONTROLS/PERSONAL PROTECTION
STD STEL - 15 MinTWA - 8 HrsName Notes
AMMONIUM BISULPHITE
50 ppm 308 mg/m3WELDIPROPYLENE GLYCOL MONOMETHYL ETHER
(DPM)
Sk
10 mg/m3WEL 104 mg/m3ETHANEDIOL Sk
WEL = Workplace Exposure Limit.
Sk = Can be absorbed through skin.
PROTECTIVE EQUIPMENT
PROCESS CONDITIONS
Provide eyewash, quick drench.
ENGINEERING MEASURES
Provide adequate general and local exhaust ventilation.
RESPIRATORY EQUIPMENT
In case of inadequate ventilation use suitable respirator.
HAND PROTECTION
Use protective gloves made of: Rubber, neoprene or PVC. The most suitable glove must be chosen in consultation with the gloves
supplier, who can inform about the breakthrough time of the glove material. Be aware that the liquid may penetrate the gloves. Frequent
change is advisable.
EYE PROTECTION
Use approved safety goggles or face shield.
OTHER PROTECTION
Wear appropriate clothing to prevent any possibility of skin contact.
HYGIENE MEASURES
DO NOT SMOKE IN WORK AREA! Wash at the end of each work shift and before eating, smoking and using the toilet. Wash promptly if
skin becomes wet or contaminated. Promptly remove any clothing that becomes contaminated. When using do not eat, drink or smoke.
9 PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE Liquid
COLOUR Light (or pale) Coloured
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REVISION DATE 30/11/2010
Hydrosure 0-3670RODOUR Pungent Sulphur.
SOLUBILITY Miscible with water
RELATIVE DENSITY 1.045 - 1.075 @ 20 °c
pH-VALUE, CONC. SOLUTION 4.0-6.0
REFRACTIVE INDEX 39-41
10 STABILITY AND REACTIVITY
STABILITY
Stable under normal temperature conditions.
CONDITIONS TO AVOID
Avoid heat, flames and other sources of ignition.
HAZARDOUS POLYMERISATION
Will not polymerise.
MATERIALS TO AVOID
Strong acids. Strong oxidising substances.
HAZARDOUS DECOMPOSITION PRODUCTS
Oxides of: Carbon. Nitrogen. Sulphur.
11 TOXICOLOGICAL INFORMATION
INHALATION
Gas or vapour may irritate respiratory system.
INGESTION
Causes burns. May cause chemical burns in mouth and throat. Generates toxic gas in contact with acid.
SKIN CONTACT
Causes burns.
EYE CONTACT
Causes burns. Risk of serious damage to eyes.
12 ECOLOGICAL INFORMATION
ECOTOXICITY
The product contains a substance which is very toxic to aquatic organisms.
MOBILITY
The product is soluble in water.
BIOACCUMULATION
No data available on bioaccumulation.
13 DISPOSAL CONSIDERATIONS
GENERAL INFORMATION
Empty containers should be taken for local recycling, recovery or waste disposal
DISPOSAL METHODS
Recover and reclaim or recycle, if practical. Dispose of waste and residues in accordance with local authority requirements.
WASTE CLASS
For this product, in accordance with the European Waste Catalogue (EWC), a catalogue number cannot be given because the customer
has to lay down the purpose first. The catalogue number has to be given according to the local waste removal processes.
14 TRANSPORT INFORMATION
PROPER SHIPPING NAME CORROSIVE LIQUID, ACIDIC, ORGANIC, n.o.s. (contains quaternary ammonium chloride)
3265UN NO. ROAD
8ADR CLASS NO.
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REVISION DATE 30/11/2010
Hydrosure 0-3670RClass 8: Corrosive substances.ADR CLASS
IIIADR PACK GROUP
80 Corrosive or slightly
corrosive substance.
HAZARD NO. (ADR)
80HAZARD No. (ADR)
2XHAZCHEM CODE
3265UN NO. SEA
8IMDG CLASS
IIIIMDG PACK GR.
F-A S-BEMS
3265UN NO. AIR
8ICAO CLASS
IIIAIR PACK GR.
15 REGULATORY INFORMATION
LABELLING
Corrosive
CONTAINS Quaternary ammonium chloride
RISK PHRASES
R31 Contact with acids liberates toxic gas.
R34 Causes burns.
SAFETY PHRASES
S24/25 Avoid contact with skin and eyes.
S26 In case of contact with eyes, rinse immediately with plenty of water and seek
medical advice.
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection.
S45 In case of accident or if you feel unwell, seek medical advice immediately
(show label where possible).
S60 This material and its container must be disposed of as hazardous waste.
UK REGULATORY REFERENCES
Approved Supply List.
STATUTORY INSTRUMENTS
The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716).
APPROVED CODE OF PRACTICE
Classification and Labelling of Substances and Preparations Dangerous for Supply.
GUIDANCE NOTES
Workplace Exposure Limits EH40. Approved guide to the classification and labelling of substances and preparations dangerous for supply.
16 OTHER INFORMATION
REVISION COMMENTS
NOTE: Lines within the margin indicate significant changes from the previous revision.
ISSUED BY
GC
REVISION DATE 30/11/2010
REV. NO./REPL. SDS
GENERATED
4
RISK PHRASES IN FULL
Causes burns.R34
Contact with acids liberates toxic gas.R31
Harmful if swallowed.R22
Irritating to eyes, respiratory system and skin.R36/37/38
Very toxic to aquatic organisms.R50
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REVISION DATE 30/11/2010
Hydrosure 0-3670R
DISCLAIMER
The information provided in this SDS is correct to the best of our knowledge, information and belief at the date of its publication. The information given is
designed only as a guidance for safe handling, use, processing, storage, transportation, disposal, and release and is not to be considered a warranty or
quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any
other materials or in any process unless specified in the text.
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