BRUKER COMPANY CONFIDENTIAL 2014 1

S1 Titan

HH XRF for various applications

André SchmuckDirector Sales EMEAHandheld, Mobile Portable Products

Contents

• Bruker Instruments

• What Is XRF?

• How Does It Work?

• XRF for Metals

• XRF for Mining

• Models & Accessories

5/21/2014 2

Bruker

• Founded 1960 in Germany

• Headquarters in Billerica, MA

• Analytical Equipment

• $1.84 Billion revenue (2013)

• Bruker Elemental

• HHXRF in Kennewick, USA

• OES & CGA in Kalkar, Germany

5/21/2014 3

Technologies

5/21/2014 4

Mass Spectrometry and Separations Remote Sensing CS/ONH-Analysis IMS

GC Systems Imaging Spectrographs Magnetic Resonance MS

GC-MS Terahertz NMR FT-IR

FTMS OPUS - Software EPR ELISA

MALDI-MS X-ray Diffraction and Elemental Analysis MRI PCR

MALDI Biotyper X-ray Diffraction Time Domain (TD)-NMR ASAS

LC-MS Single Crystal X-ray Diffraction Power Electronics NAA

ICP-MS X-ray Micro-CT Surface Analysis Preclinical Imaging

Software X-ray Spectrometry Atomic Force Microscopy MR Imaging

Molecular Vibrational Spectroscopy Handheld XRF 3D Optical Microscopy Optical imaging

FT-IR X-ray Metrology Stylus Profilometry PET/ SPECT/ CT

FT-NIR EDS, EBSD and SEM Micro-CT Tribology and Mechanical Testing micro-CT

Raman Optical Emission Spectrometry Mobile Detection X-ray

What Is XRF?

• Analytical Method For Determining Elemental Content

• Qualitative And Quantitative

• Mg - U

• Fast – All Elements At Once

• Wide Range (PPM to 100%)

• Accurate & Precise

• Non Destructive

• Near Surface

5/21/2014 5

How Does It Work?

An X-ray of sufficient energy strikes an inner

shell electron of an atom in the sample, ejecting the electron

from its orbit.

Next-- an electron from an outer shell

moves to fill the vacancy in the inner

shell.

An X-ray photon is released and hits the analyzer’s detector.

This photon’s energy is unique to the element

it came from.

6

XRF Components

5/21/2014 7

8

Line Energy Graphite Glass Iron Lead

Cd KA1 23.17 keV 14.46 cm 8.20 mm 0.70 mm 77.30 m

Mo KA1 17.48 6.06 3.60 0.31 36.70

Cu KA1 8.05 5.51 mm 0.38 36.40 m 20.00

Ni KA1 7.48 4.39 0.31 29.80 16.60

Fe KA1 6.40 2.72 0.20 * 164.00 11.10

Cr KA1 5.41 1.62 0.12 104.00 7.23

S KA1 2.31 116..0 m 14.80 m 10.10 4.83

Mg KA1 1.25 20.00 7.08 1.92 1.13

F KA1 0.68 3.70 1.71 0.36 0.26

N KA1 0.39 0.83 1.11 0.08 0.07

C KA1 0.28 * 13.60 0.42 0.03 0.03

B KA1 0.18 4.19 0.13 0.01 0.01

0.01 m = 10 nm = 100 Å

atom radius: 0.5 - 3 Å

What is “Near Surface”?

(C) AS

Radiation Safety

9

Backscatter Shut-off

IR Sample Sensor

Warning Lights

Multilevel User Log-in User Supervisor

S1 TITAN for Metal Application

21.05.2014Innovation with Integrity

• Originated in the refinery industry

• Used to Ensure plant safety

• Over 75% of refinery failures are caused by installation of incorrect alloy

• Major refineries require 100% inspection and verification

Material TestingPositive Material Identification (PMI)

Material TestingPMI

Why is HHXRF used for PMI?

• Non-destructive testing

• Battery powered

• Speed & accuracy

• Ease of use

• Library size – over 400 alloys

• Customizeable user library

Material TestingPMI

Why is HHXRF used for PMI?

• Avoid material mixups

• Provide alloy verification to customers

• Can be used on almost any metals

• Easy data storage & transfer to a report

Scrap/Recycling

Why is HHXRF used forScrap/Recycling?

• Rapid, On-the-spot analysis of incoming materials

• Ease of use

• Weight/Field use

• Speed

• Faster = more $

Scrap/Recycling

Why is HHXRF used forScrap/Recycling?

• Accuracy (esp. valuable elements)

• Customizable user library

• Sort & Grade Incoming & OutgoingScrap for higher value

• Light Elemental Analysis – Al, Si, Mg

• Analysis of Tramp Elements

Alloy Analysis

21.05.2014Bruker Confidential

16

Alloy SMARTGrade

17

• Provides complete timing of the measurement

• All with Automatic Trigger

• No user judgment required

• Custom table can be created

ALLOYS SMARTGRADE™Press button get grade!

18

Pass/Fail Mode

19

Pass/Fail mode allows the quick investigation of samples with little or no background in alloy composition

S1 TITAN for Mining Application

May 21, 2014

XRF In Mining

5/21/2014 22

Applications in Mining

Exploration

Grade Control

Mineral Processing

Plant Maintenance

Mine Closure & Reclamation

5/21/2014 23

Exploration

• Field Based Analytical Solution

• Real-Time Spatially Registered Geochemistry

• Interactive & Immediate Feedback in the Field

• Dramatically Increase Sample Density (100’s Samples per Day)

• Compared to laboratory analysis, handheld XRF provides a huge time savings.

5/21/2014 24

Exploration

5/21/2014 25

Used for:

• Soil Sampling

• Percussion Drill Chip Screening

• Core Analysis

Grade Control

• More Samples, More Often = More Confidence!

• Significantly Reduce Decision Making Timeframes

• Blast Hole Sampling

• Open Pit - Ore Boundary Definition & Mapping

• Underground Face Sampling & Mapping

• Stockpile Checking & Monitoring

5/21/2014 26

Mineral Processing

• Investigation, Refinement & Problem Solving

• Use Real-Time Geochemistry in Your Flow-Sheet

• Simple Pre-Feasibility & Pre-Mining Data Acquisition (Met-Testing)

• Geometallurgy – Analysis of Elements not in the Standard Assay Package

5/21/2014 27

Plant Maintenance

• Preventative & Predictive Maintenance Tool

• Alloy & PMI Analysis

• Oil Analysis – Wear Metals: Ca, V, Cr, Fe, Ni, Cu, Zn, Pb & P

• Sulfur Level Determination in Diesel Fuels

5/21/2014 28

Mine Closure & Reclamation

• Real-Time In-Situ Soil & Filter Analysis

• Instant Delineation of contaminated soil boundaries

• Improved project management & cost savings

• Interactive Monitoring

5/21/2014 29

Handheld XRF ApplicationsIndustrial Minerals

• Limestone, Calcium carbonate (CaCO3) is one of the most versatile minerals found in the earth's crust. Physical properties and low processing cost makes it the most widely used filler material.

• Handheld XRF can be used to measure Calcium carbonate composition directly from rock or from quarry. This information can be used to effectively control mining and excavation process.

• Sand and Feldspar grade and Fe control

Limits of Detection

5/21/2014 31

Different sample cups

32

1530 cup with 1630 lid31mm/23mm/24mm

Lose powder/slurry/pastes preparation

CONFIGURATIONS

34BRUKER COMPANY CONFIDENTIAL 2014

The UNIQUE and MOST IMPORTANTNow standard on ALL units

35

TITAN Detector Shield

BRUKER COMPANY CONFIDENTIAL 2014

Camera functionality

36BRUKER COMPANY CONFIDENTIAL 2014

Make up to 5 pictures per object.Trigger pull makes the measurement.

37BRUKER COMPANY CONFIDENTIAL 2014

S1 Remote

38

Limits Editor

39

Report Generator

40

Spectrum ViewerOptions Dialog

41

Spectrum ViewerAtomic Table

42

Optional Accessories

• Test Stand

• Holster

• Bluetooth GPS Receiver

• Data Reporting Software

• Bluetooth Printer

• Tablet Computer

5/21/2014 43

21. Mai 2014 44© Copyright Bruker Corporation. All rights reserved