Post on 11-Apr-2018
MATERIAL SAFETY DATA SHEET
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATIONProduct code: U1018Product Name: UREA, FCCChemical Name: CarbonyldimideSynonyms: Carbamide
CarbonyldiamineIsoureaUreaphilUreophilCarbonyldiamide
Recommended use: Manufacturing of resins, plastics; Condensed with Malonic ester to form Barbituricacid; cellulose softner; in ammoniated dentifrices; chemical intermediate; stabilizer inexplosives; in medicine (diuretic); separation of hydrocarbons; sulfamic acidproduction; in flameproofing agents; liquid and other fertilizer applications; livestocknutrient; monomer for urea-formaldehyde resins; insect (mosquito) repellent.
CAS #: 57-13-6RTECS # YR6250000Formula: NH2)2CO or CH4N2OCI#: Not availableSupplier: Spectrum Chemicals and Laboratory Products, Inc.
14422 South San Pedro St.Gardena, CA 90248(310) 516-8000
Order Online At: https://www.spectrumchemical.comEmergency Telephone Number: CHEMTREC: 1-800-424-9300Contact Person: Regina Wachenheim (East Coast)Contact Person: Martin LaBenz (West Coast)
2. HAZARDS IDENTIFICATION
Product code: U1018 Product name: UREA, FCC 1 / 11
Personal Protective EquipmentNFPA
See Section 8.
HMIS
2. HAZARDS IDENTIFICATION
Chronic Potential Health Effects:
Component Carcinogen Status:Urea57-13-6 (100)
No information available
Target Organs: No information available
Mutagenic Effects: May affect genetic materialMutagenic effects in mammalian somatic cellsExperiments with animal lymphocytes have shown mutagenic effectsExperiments with human lymphocytes have shown mutagenic effects
Teratogenic Effects: No information available
Aggravated Medical Conditions: No information available
See Section 11 for additional Toxicological Information
POTENTIAL ENVIRONMENTAL EFFECTS
Inhalation:May cause irritation of respiratory tract.
Ingestion:Causes digestive (gastrointestinal) tract irritation. May cause abdominal pain, nausea, vomiting, diarrhea. May affectrespiration. May cause central nervous system effects. May affect the cardiovascular system. It may affect the kidneys.May affect the blood. May affect electrolyte balance.
EMERGENCY OVERVIEWWARNING! IRRITANT
Irritating to eyesIrritating to skin
POTENTIAL HEALTH EFFECTS
Principal Routes of Exposure:Ingestion. Inhalation.
Acute Potential Health Effects:
OSHA Regulatory Status
Skin Contact:Causes skin irritation. Mild skin irritation.
Product code: U1018
This material is considered hazardous by the OSHA Hazard CommunicationStandard (29 CFR 1910.1200)
Product name: UREA, FCC 2 / 11
Eye Contact:Causes eye irritation. Mild eye irritation.
Appearance:Crystalline powder. Crystals.
Prills.
Color:White.
Odor:Almost odorless. It may
gradually develop a slight odor ofammonia, especially in the
presence of moisture.
Physical state:Solid.
No information available
3. COMPOSITION/INFORMATION ON INGREDIENTS
Components CAS-No. Weight %Urea 57-13-6 100
4. FIRST AID MEASURES
General Advice: Poison information centres in each State capital city can provide additionalassistance for scheduled poisons (13 1126).
Skin Contact: Wash off immediately with soap and plenty of water removing all contaminatedclothes and shoes. Get medical attention if irritation develops.
Eye Contact: Flush eye with water for 15 minutes. Get medical attention.
Inhalation: Move to fresh air. If not breathing, give artificial respiration. If breathing is difficult,give oxygen. Get medical attention.
Ingestion: Do not induce vomiting without medical advice. Never give anything by mouth to anunconscious person. Consult a physician if necessary.
Notes to Physician: Treat symptomatically
5. FIRE-FIGHTING MEASURES
Flammable Properties
Flashpoint (°C/°F): No information available.
Flash Point Tested according to:Not applicable
Lower Explosion Limit (%): No information availableUpper Explosion Limit (%): No information available
Autoignition Temperature (°C/°F): No information available
Suitable Extinguishing Media: Dry chemical. Carbon dioxide (CO2). Water spray mist orfoam.
Unsuitable Extinguishing Media: No information available.
Hazardous Combustion Products: Carbon monoxide; Carbon dioxide; Nitrogen oxides
Specific hazards: May be combustible at high temperatures
Special Protective Equipment for Firefighters: As in any fire, wear self-contained breathing apparatuspressure-demand, MSHA/NIOSH (approved or equivalent)and full protective gear
Specific Methods: No information available.
6. ACCIDENTAL RELEASE MEASURES
3 / 11Product code: U1018 Product name: UREA, FCC
Personal Precautions:Ensure adequate ventilation. Avoid contact with skin, eyes and clothing. Use personal protective equipment. Avoid dustformation. Remove all sources of ignition.
Environmental Precautions:No information available.
Methods for Cleaning Up:Sweep up and shovel into suitable containers for disposal. Clean contaminated surface thoroughly.
7. HANDLING AND STORAGE
Handling
Technical Measures/Precautions:Provide sufficient air exchange and/or exhaust in work rooms. Avoid dust formation. Keep away from incompatiblematerials.
Safe Handling Advice:Wear personal protective equipment. Avoid contact with skin, eyes and clothing. Avoid dust formation. Do notingest. Do not breathe vapours/dust. Keep away from heat and sources of ignition. Handle in accordance with goodindustrial hygiene and safety practice.
Storage
Technical Measures/Storage Conditions:Keep container tightly closed in a dry and well-ventilated place. Store at room temperature in the original container.Store away from incompatible materials.
Incompatible Materials:Oxidizing agents.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Engineering measures to reduce exposure: Ensure adequate ventilation. Use process enclosures, localexhaust ventilation, or other engineering controls to keepairborne levels below recommended exposure limits. If useroperations generate dust, fume or mist, use ventilation tokeep exposure to airborne contaminants below the exposurelimit.
Personal Protective Equipment
Eye protection: Goggles.
Skin and body protection: Long sleeved clothing. Chemical resistant apron. Gloves.
Respiratory protection: Wear respirator with dust filter..
Hygiene measures: Avoid contact with skin, eyes and clothing. Wash hands before breaks andimmediately after handling the product. When using, do not eat, drink or smoke.
National occupational exposure limits
United StatesComponents OSHA NIOSH ACGIH AIHA WHEEL
Urea - 57-13-6None None None 10 mg/m3 TWA
Canada
4 / 11Product code: U1018 Product name: UREA, FCC
Components Alberta British Columbia Ontario QuebecUrea
57-13-6None None None None
Australia and MexicoComponents Australia Mexico
Urea57-13-6
None None
9. PHYSICAL AND CHEMICAL PROPERTIES
10. STABILITY AND REACTIVITY
Stability: Stable at normal conditions
Conditions to avoid: Heat. Avoid dust formation. Incompatible materials.
Incompatible Materials: Oxidizing agents.
Vapor pressure @ 20°C (kPa):No information available
Flash point (°C):No data available
Evaporation rate:No information available
Color:White.
Vapor density:2.07
VOC content (g/L):No information available
Lower Explosion Limit (%):No information available
Odor threshold (ppm):No information available
Partition coefficient(n-octanol/water):-2.1
Miscibility:No information available
Upper Explosion Limit (%):No information available
Solubility:Very soluble in waterSoluble in MethanolInsoluble in EtherInsoluble in ChloroformInsoluble in BenzeneSoluble in Acetic acidSoluble in concentrated hydrochloricacidSolubility: 1 gram dissolves in 1 mlwater, 10 ml of 95% Alcohol, 6 mlMethanol, 1 ml boiling 65% Alcohol, 2ml Glycerol
Physical state:Solid.
Autoignition Temperature (°C/°F):No information available
Odor:Almost odorless. It may graduallydevelop a slight odor of ammonia,especially in the presence of moisture.
Melting point/range(°C/°F):132-135 °C/269.6-275 °F
Boiling point/range(°C/°F):No information available
Appearance:Crystalline powder. Crystals. Prills.
pH:No information available
TasteSaline.
Specific gravity:1.323
Density (g/cm3):No information available
Molecular/Formula weight:60.06
Decomposition temperature(°C/°F):No information available
Product code: U1018 Product name: UREA, FCC 5 / 11
Bulk density:No information available
Hazardous decompositionproducts:
Carbon monoxide. Carbon dioxide. Nitrogen oxides (NOx).
Possibility of HazardousReactions:
Reacts violently with Gallum Perchlorate. Reacts with chlorine to form chloramines.It also reacts with the following: sodium hypochlorite, sodium nitrate, calciumhypochlorite, NaNO2, P2Cl5, nitrosyl perchlorate, strong oxidizing agents(permanganate, nitrate, dichromate, chloride)
Polymerization: Hazardous polymerisation does not occur
Corrosivity: No information available
Special Remarks on Corrosivity: No information available
11. TOXICOLOGICAL INFORMATIONAcute Toxicity
Component Information
Product Information
LC50/inhalation/rat No information availableLC50/Inhalation/mouse No information availableLD50/dermal/rabbit No information availableLD50/dermal/rat No information availableLD50/oral/mouse = 11000mg/kgLD50/oral/rat = 8471mg/kg
Local Effects
Skin irritation: Causes skin irritation. Mild skin irritation.
Eye irritation: Causes eye irritation. Mild eye irritation.
Inhalation: May cause irritation of respiratory tract.
Ingestion: Causes digestive (gastrointestinal) tract irritation. May cause abdominal pain,nausea, vomiting, diarrhea. May cause bloating. May cause dry mouth. May causesalivation. May cause regurgitation. May cause grinding of teeth. May affectrespiration (difficult or labored breathing resulting in shortness of breath). May affectrespiraton (apnea). May affect urinary system (kidneys). May cause mydriasis(dilated pupils). May affect electrolytes. May cause hypokalemia. May causehyponatremia. May affect cardiovascular system (hypotension, cardiac arrhythmias).May affect the cardiovascular system (change in heart rate). May cause headache.May cause fainting. May affect behavior/central nervous system (altered sleep time,change in motor activity, dizziness disorientation, ataxia, drowsiness, confusion,trembling, somnolence, aggressiveness, hyperreflexia, convulsions).
Sensitization: May cause sensitization by skin contact
LC50/inhalation/rat = No information available
LD50/oral/mouse = 11000 mg/kg
LC50/inhalation/mouse = No infomation available
LD50/oral/rat = 8471 mg/kg (RTECS)
Other LD50 or LC50information = No information available
LD50/dermal/rat = No information available
Urea - 57-13-6
Product code: U1018 Product name: UREA, FCC
LD50/dermal/rabbit = No information available
6 / 11
Chronic Toxicity
Chronic Toxicity Chronic exposure may affect the liver and kidneys. Chronic exposure may affect theblood (leukocytosis, thrombosis). Chronic exposure may affect the brain.
Carcinogenic effects: Tumorigenic agent by RTECS criteria. No other informaiton.
Components NTP IARC OSHA HCS -Carcinogens
ACGIH - Carcinogens Australia - ProhibitedCarcinogenicSubstances
Australia - NotifiableCarcinogenicSubstances
Urea Not listed Not listed Not listed Not listed Not listed Not listed
Mutagenic Effects: May affect genetic materialMutagenic effects in mammalian somatic cellsExperiments with animal lymphocytes have shown mutagenic effectsExperiments with human lymphocytes have shown mutagenic effects
Reproductive Effects: No information available
Teratogenic Effects: No information available
Target Organs: No information available
12. ECOLOGICAL INFORMATION
ECOTOXICITY
Toxicity to terrestrial and aquatic plants and animals: Information given is based on data on the components andthe ecotoxicology of similar products
Ecotoxicity effects: Aquatic environment.
Aquatic toxicity:
Mobility: No information available
Persistence and degradability: No information available
Bioaccumulative potential: Potential for bioconcentration in aquatic organisms is low.
13. DISPOSAL CONSIDERATIONS
Waste from residues / unused products:Waste must be disposed of in accordance with Federal, State and Local regulation.
Contaminated packaging:Empty containers should be taken for local recycling, recovery or waste disposal
Components RCRA - F Series Wastes RCRA - K Series Wastes RCRA - P Series Wastes RCRA - U Series WastesUrea None None None None
14. TRANSPORT INFORMATION
Water Flea Data: 3910 mg/L EC50 Daphnia magna 48 h
Product code: U1018 Product name: UREA, FCC
Freshwater Fish Species Data:
7 / 11
16200 - 18300 mg/L LC50 Poecilia reticulata 96 h 1Urea - 57-13-6
DOTUN-No: Not regulatedProper Shipping Name: No information availableHazard Class: No information availablePacking Group: NoneSubsidiary Risk: Not applicableMarine Pollutant No data availableERG No: No information availableDOT RQ (lbs): No information available
TDG (Canada)UN-No: Not RegulatedProper Shipping Name: No information availableHazard Class: No information availablePacking Group: No information availableSubsidiary Risk: No information availableDescription: No information available
ADRUN-No: No information availableProper Shipping Name: No information availableHazard Class: No information availablePacking Group: No information availableSubsidiary Risk: No information availableClassification Code: No information availableDescription: No information availableCEFIC Tremcard No: No information available
IMO / IMDGUN-No: Not RegulatedProper Shipping Name: No information availableHazard Class: No information availablePacking Group: No information availableSubsidiary Risk: No information availableDescription: No information availableIMDG Page: No information availableMarine Pollutant No information availableMFAG: No information availableMaximum Quantity: No information available
RIDUN-No: No information availableProper Shipping Name: No information availableHazard Class: No information availablePacking Group: No information availableSubsidiary Risk: No information availableClassification Code: No information availableDescription: No information available
ICAOUN-No: No information availableProper Shipping Name: No information availableHazard Class: No information availablePacking Group: No information availableSubsidiary Risk: No information availableDescription: No information available
IATAUN-No: Not Regulated
8 / 11Product code: U1018 Product name: UREA, FCC
Proper Shipping Name: No information availableHazard Class: No information availablePacking Group: No information availableSubsidiary Risk: No information availableDescription: No information available
15. REGULATORY INFORMATION
International Inventories
Components U.S. TSCA Philippines(PICCS)
KOREA KECL Japan ENCS CHINA Australia(AICS)
EINECS-No.
Urea Present Present Present KE-35144
Present (2)-1732
Present Present Present 200-315-5
U.S. Regulations
California Prop. 65: Safe Drinking Water and Toxic Enforcement Act of 1986.
Chemicals Known to the State of California to Cause Cancer:This product does not contain a chemical requiring a warning under California Prop. 65. (See table below)
Chemicals Known to the State of California to Cause Reproductive Toxicity:This product does not contain a chemical requiring a warning under California Prop. 65. (See table below)
Components Carcinogen Developmental Toxicity Male ReproductiveToxicity
Female ReproductiveToxicity:
Urea Not Listed Not Listed Not Listed Not Listed
CERCLA/SARA
Components CERCLA - HazardousSubstances and theirReportable Quantities
Section 302 ExtremelyHazardous
Substances and TPQs
Section 302 ExtremelyHazardous
Substances and RQs
Section 313 -Chemical Category
Section 313 - Reporting de minimis
Urea None None None None None
U.S. TSCA
Components TSCA Section 5(a)2 - Chemicals With SignificantNew Use Rules (SNURS)
TSCA 8(d) -Health and Safety Reporting
Urea Not Applicable Not Applicable
Canada
WHMIS hazard class:Non-controlled
Canada Controlled Products Regulation:This product has been classified according to the hazard criteria of the CPR (Controlled Products Regulation) and the MSDS containsall of the information required by the CPR.
Inventory
Urea
FDA - Food Additives Generally Recognized as Safe (GRAS): 21 CFR 184.1923
Urea
Product code: U1018 Product name: UREA, FCC
Minnesota - Hazardous Substance List: Present
9 / 11
Uncontrolled product according to WHMIS classification criteria
Components Canada (DSL) Canada (NDSL)Urea Present Not Listed
Components CEPA Schedule I - Toxic Substances CEPA - 2010 Greenhouse Gases Subject to ManditoryReporting
Urea Not listed Not listed
EU Classification
R-phrase(s)not determined
S -phrase(s)none
Components Classification Concentration Limits: Safety PhrasesUrea No information
The product is classified in accordance with Annex VI to Directive 67/548/EEC
Indication of danger:Not dangerous
16. OTHER INFORMATION
The MSDS format complies with ANSI Z400.1/Z129.1-2010 standards.
Preparation Date: 19-Feb-2014
Reason for revision: Not applicable
Prepared by: Sonia Owen
Literature reference: No information available
All chemicals may pose unknown hazards and should be used with caution. This Material Safety Data Sheet (MSDS)applies only to the material as packaged. If this product is combined with other materials, deteriorates, or becomescontaminated, it may pose hazards not mentioned in this MSDS. The physical properties reported in this MSDS areobtained from the literature and do not constitute product specifications. Information contained herein does not constitutea warranty, whether expressed or implied, as to the safety, merchantability or fitness of the goods for a particular purpose.Spectrum Chemicals & Laboratory Products, Inc. assumes no responsibility for results obtained or for incidental orconsequential damages, including lost profits, arising from the use of these data. No warranty against infringement of anypatent, copyright or trademark is made or implied. It shall be the user's responsibility to develop proper methods ofhandling and personal protection based on the actual conditions of use. While this MSDS is based on technical datajudged to be reliable, Spectrum assumes no responsibility for the completeness or accuracy of the information containedherein.
Product code: U1018
Urea
Product name: UREA, FCC 10 / 11
SAFETY DATA SHEET
1. IDENTIFICATION
Product identifierProduct code: U1018Product Name: UREA, FCC
Other means of identificationSynonyms: Carbamide
CarbonyldiamineIsoureaUreaphilUreophilCarbonyldiamide
CAS #: 57-13-6RTECS # YR6250000CI#: Not available
Recommended use of the chemical and restrictions on useRecommended use: Manufacturing of resins, plastics; Condensed with Malonic ester to form Barbituric
acid; cellulose softner; in ammoniated dentifrices; chemical intermediate; stabilizer inexplosives; in medicine (diuretic); separation of hydrocarbons; sulfamic acidproduction; in flameproofing agents; liquid and other fertilizer applications; livestocknutrient; monomer for urea-formaldehyde resins; insect (mosquito) repellent.
Uses advised against No information available
Supplier: Spectrum Chemicals and Laboratory Products, Inc.14422 South San Pedro St.Gardena, CA 90248(310) 516-8000
Order Online At: https://www.spectrumchemical.com
Emergency telephone number Chemtrec 1-800-424-9300Contact Person: Martin LaBenz (West Coast)Contact Person: Regina Wachenheim (East Coast)
2. HAZARDS IDENTIFICATION
Classification
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Serious eye damage/eye irritation Category 2B
Label elements
Revision Date: 2/17/2014 Revision Number: G1
Product code: U1018 Product name: UREA, FCC
Preparation Date: 2/17/2014
1 / 11
Hazards not otherwise classified (HNOC)Not Applicable
Other hazardsCauses mild skin irritation
Precautionary Statements - PreventionWash face, hands and any exposed skin thoroughly after handling
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eyeirritation persists: Get medical advice/attention.If skin irritation occurs: Get medical advice/attention
3. COMPOSITION/INFORMATION ON INGREDIENTS
Components CAS-No. Weight % Trade SecretUrea
57-13-657-13-6 100 *
4. FIRST AID MEASURES
First aid measuresGeneral Advice: Poison information centres in each State capital city can provide additional
assistance for scheduled poisons (13 1126).
Skin Contact: Wash off immediately with soap and plenty of water removing all contaminated clothes andshoes. Get medical attention if irritation develops.
Eye Contact: Flush eye with water for 15 minutes. Get medical attention.
Inhalation: Move to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.Get medical attention.
Ingestion: Do not induce vomiting without medical advice. Never give anything by mouth to anunconscious person. Consult a physician if necessary.
Most important symptoms and effects, both acute and delayedSymptoms Mild skin irritation. Mild eye irritation. Ingestion may cause nausea, vomiting, and diarrhea.
Abdominal pain. May cause salivation. Hypotension. Cardiac arrhythmias. May affectrespiration. Central nervous system effects. May affect behavior/central nervous system(tremor, convulsions). Headache. Disorientation. Confusion. Fainting. May affect electrolytebalance.
Indication of any immediate medical attention and special treatment neededNotes to Physician: Treat symptomatically
Protection of first-aidersFirst-Aid Providers: Avoid exposure to blood or body fluids. Wear gloves and other necessary protective clothing. Dispose ofcontaminated clothing and equipment as bio-hazardous waste
Warning
Product code: U1018 Product name: UREA, FCC
Hazard statementsCauses eye irritation
2 / 11
5. FIRE-FIGHTING MEASURES
Extinguishing Media
Suitable Extinguishing Media: Dry chemical. Carbon dioxide (CO2). Water spray mist orfoam.
Unsuitable Extinguishing Media: No information available.
Specific hazards arising from the chemical
Hazardous Combustion Products: Carbon monoxide; Carbon dioxide; Nitrogen oxides
Specific hazards: May be combustible at high temperatures.
Special Protective Actions for Firefighters
Specific Methods: No information available.
Special Protective Equipment for Firefighters: As in any fire, wear self-contained breathing apparatuspressure-demand, MSHA/NIOSH (approved or equivalent)and full protective gear
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Personal Precautions: Ensure adequate ventilation. Avoid contact with skin, eyes and clothing. Use personalprotective equipment. Avoid dust formation. Remove all sources of ignition.
Environmental precautions No information available.
Methods and material for containment and cleaning up
Methods for containment Stop leak if you can do it without risk. Cover with plastic sheet to prevent spreading.
Methods for cleaning up Sweep up and shovel into suitable containers for disposal. Clean contaminatedsurface thoroughly.
7. HANDLING AND STORAGE
Precautions for safe handling
Technical Measures/Precautions:Provide sufficient air exchange and/or exhaust in work rooms. Avoid dust formation. Keep away from incompatiblematerials.
Safe Handling Advice:Wear personal protective equipment. Avoid contact with skin, eyes and clothing. Avoid dust formation. Do notingest. Do not breathe vapours/dust. Keep away from heat and sources of ignition. Handle in accordance with goodindustrial hygiene and safety practice.
Conditions for safe storage, including any incompatibilities
Technical Measures/Storage Conditions:Keep container tightly closed in a dry and well-ventilated place. Store at room temperature in the original container.Store away from incompatible materials.
Incompatible Materials:Oxidizing agents.
Product name: UREA, FCC 3 / 11Product code: U1018
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
National occupational exposure limits
United StatesComponents OSHA NIOSH ACGIH AIHA WHEEL
Urea - 57-13-6None None None 10 mg/m3 TWA
CanadaComponents Alberta British Columbia Ontario Quebec
Urea - 57-13-6None None None None
Australia and MexicoComponents Australia Mexico
Urea57-13-6
None None
Appropriate engineering controls
Engineering measures to reduce exposure: Ensure adequate ventilation. Use process enclosures, localexhaust ventilation, or other engineering controls to keepairborne levels below recommended exposure limits. If useroperations generate dust, fume or mist, use ventilation tokeep exposure to airborne contaminants below the exposurelimit.
Individual protection measures, such as personal protective equipmentPersonal Protective Equipment
Eye protection: Goggles.
Skin and body protection: Long sleeved clothing. Chemical resistant apron. Gloves.
Respiratory protection: Wear respirator with dust filter..
Hygiene measures: Avoid contact with skin, eyes and clothing. Wash hands before breaks andimmediately after handling the product. When using, do not eat, drink or smoke.
9. PHYSICAL AND CHEMICAL PROPERTIES
Product name: UREA, FCC 4 / 11Product code: U1018
9. PHYSICAL AND CHEMICAL PROPERTIES
10. STABILITY AND REACTIVITY
Reactivity
Chemical stabilityStability: Stable at normal conditions
Possibility of Hazardous Reactions: Hazardous polymerization does not occur
Conditions to avoid: Heat. Avoid dust formation. Incompatible materials.
Incompatible Materials: Oxidizing agents.
VOC content (g/L):No information available
Flashpoint (°C/°F):Not applicable
Odor threshold (ppm):No information available
Physical state:Solid.
Partition coefficient(n-octanol/water):-2.1
Viscosity:No information available
Flash Point Tested according to:Not applicable
Miscibility:No information available
Odor:Almost odorless. It may graduallydevelop a slight odor of ammonia,especially in the presence of moisture.
Solubility:Very soluble in waterSoluble in MethanolInsoluble in EtherInsoluble in ChloroformInsoluble in BenzeneSoluble in Acetic acidSoluble in concentrated hydrochloricacidSolubility: 1 gram dissolves in 1 mlwater, 10 ml of 95% Alcohol, 6 mlMethanol, 1 ml boiling 65% Alcohol, 2 mlGlycerol
Lower Explosion Limit (%):No information available
Upper Explosion Limit (%):No information available
Appearance:Crystalline powder. Crystals. Prills.
Autoignition Temperature (°C/°F):No information available
TasteSaline.
Reactive with oxidizing agentsReacts violently with Gallum Perchlorate. Reacts with chlorine to form chloramines.It also reacts with the following: sodium hypochlorite, sodium nitrate, calcium hypochlorite, NaNO2, P2Cl5, nitrosyl perchlorate, strongoxidizing agents (permanganate, nitrate, dichromate, chloride)
pH:No information available
Melting point/range(°C/°F):132-135 °C/269.6-275 °F
Formula:NH2)2CO or CH4N2O
Boiling point/range(°C/°F):No information available
Decomposition temperature(°C/°F):No information available
Specific gravity:1.323
Molecular/Formula weight:60.06
Density (g/cm3):No information available
Color:White.
Bulk density:No information available
Vapor pressure @ 20°C (kPa):No information available
Flash point (°C):Not applicable
Product code: U1018
Evaporation rate:No information available
Product name: UREA, FCC 5 / 11
Vapor density:2.07
Hazardous decomposition products: Carbon monoxide. Carbon dioxide. Nitrogen oxides (NOx).
Other Information
Corrosivity: No information available
Special Remarks on Corrosivity: No information available
11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure
Principal Routes of Exposure:Ingestion. Inhalation.
Acute Toxicity
Component Information
Product Information
LD50/oral/rat =VALUE- Acute Tox Oral = 8471mg/kg
LD50/oral/mouse =Value - Acute Tox Oral = 11000mg/kg
LD50/dermal/rabbitVALUE-Acute Tox Dermal = No information available
LD50/dermal/ratVALUE -Acute Tox Dermal = No information available
LC50/inhalation/ratVALUE-Vapor = No information availableVALUE-Gas = No information availableVALUE-Dust/Mist = No information available
LC50/Inhalation/mouseVALUE-Vapor = No information availableVALUE - Gas = No information availableVALUE - Dust/Mist = No information available
Symptoms
Skin Contact: Causes skin irritation. Mild skin irritation.
LC50/inhalation/mouse = No infomation available
LD50/oral/rat = 8471 mg/kg (RTECS)
Other LD50 or LC50information = No information available
LD50/dermal/rabbit = No information available
Urea - 57-13-6
LD50/dermal/rat = No information available
Product code: U1018 Product name: UREA, FCC 6 / 11
LC50/inhalation/rat = No information available
LD50/oral/mouse = 11000 mg/kg
Eye Contact: Causes eye irritation. Mild eye irritation.
Inhalation May cause irritation of respiratory tract.Ingestion Causes digestive (gastrointestinal) tract irritation. May cause abdominal pain,
nausea, vomiting, diarrhea. May cause bloating. May cause dry mouth. May causesalivation. May cause grinding of teeth. May affect respiration (difficult or laboredbreathing resulting in shortness of breath). May affect respiration (apna). May causemydriasis (dilated pupils). May affect urinary system (kidneys). May affectelectrolytes. May cause hypokalemia. May cause hyponatremia. May affectcardiovascular system (hypotension, cardiac arrhythmias). May affect thecardiovascular system (change in heart rate). May cause headache. May causefainting. May affect behavior/central nervous system (altered sleep time, change inmotor activity, dizziness disorientation, ataxia, drowsiness, confusion, trembling,somnolence, aggressiveness, hyperreflexia, convulsions).
Aspiration hazard No information available
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Chronic Toxicity Chronic exposure may affect the liver and kidneys. Chronic exposure may affect theblood (leukocytosis, thrombosis). Chronic exposure may affect the brain.
Sensitization: May cause sensitization by skin contact
Mutagenic Effects: May affect genetic materialMutagenic effects in mammalian somatic cellsExperiments with animal lymphocytes have shown mutagenic effectsExperiments with human lymphocytes have shown mutagenic effects
Carcinogenic effects: Tumorigenic agent by RTECS criteria. No other informaiton.
Components ACGIH -Carcinogens
IARC NTP OSHA HCS -Carcinogens
Australia - ProhibitedCarcinogenicSubstances
Australia - NotifiableCarcinogenicSubstances
Urea Not listed Not listed Not listed Not listed Not listed Not listed
Reproductive toxicity No data is available
Reproductive Effects: No information availableDevelopmental Effects: No information availableTeratogenic Effects: No information available
Specific Target Organ Toxicity
STOT - single exposure No information availableSTOT - repeated exposure No information availableTarget Organs: No information available
12. ECOLOGICAL INFORMATION
Ecotoxicity
Ecotoxicity effects: Aquatic environment.
Product name: UREA, FCC 7 / 11Product code: U1018
Persistence and degradability: No information available
Bioaccumulative potential: Potential for bioconcentration in aquatic organisms is low.
Mobility: No information available
13. DISPOSAL CONSIDERATIONS
Disposal Methods
Waste from residues / unused products:Waste must be disposed of in accordance with Federal, State and Local regulation.
Contaminated packaging:Empty containers should be taken for local recycling, recovery or waste disposal
Components RCRA - F SeriesWastes
RCRA - K SeriesWastes
RCRA - PSeriesWastes
RCRA - U Series Wastes
Urea None None None None
14. TRANSPORT INFORMATION
DOTUN-No: Not regulatedProper Shipping Name: No information availableHazard Class: No information availableSubsidiary Risk: Not applicablePacking Group: NoneMarine Pollutant No data availableERG No: No information availableDOT RQ (lbs): No information available
TDG (Canada)UN-No: Not RegulatedProper Shipping Name: No information availableHazard Class: No information availableSubsidiary Risk: No information availablePacking Group: No information availableDescription: No information available
ADRUN-No: Not RegulatedProper Shipping Name: No information availableHazard Class: No information availablePacking Group: No information availableSubsidiary Risk: No information availableClassification Code: No information availableDescription: No information availableCEFIC Tremcard No: No information available
Freshwater Fish Species Data: 16200 - 18300 mg/L LC50 Poecilia reticulata 96 h 1
Product code: U1018
Urea - 57-13-6
Product name: UREA, FCC 8 / 11
Water Flea Data: 3910 mg/L EC50 Daphnia magna 48 h
14. TRANSPORT INFORMATIONIMO / IMDG
UN-No: Not RegulatedProper Shipping Name: No information availableHazard Class: No information availableSubsidiary Risk: No information availablePacking Group: No information availableDescription: No information availableIMDG Page: No information availableMarine Pollutant No information availableMFAG: No information availableMaximum Quantity: No information available
RIDUN-No: Not RegulatedProper Shipping Name: No information availableHazard Class: No information availableSubsidiary Risk: No information availablePacking Group: No information availableClassification Code: No information availableDescription: No information available
ICAOUN-No: Not RegulatedProper Shipping Name: No information availableHazard Class: No information availableSubsidiary Risk: No information availablePacking Group: No information availableDescription: No information available
IATAUN-No: Not RegulatedProper Shipping Name: No information availableHazard Class: No information availableSubsidiary Risk: No information availablePacking Group: No information availableDescription: No information available
15. REGULATORY INFORMATION
International Inventories
Components U.S. TSCA Philippines(PICCS)
KOREA KECL Japan ENCS CHINA Australia(AICS)
EINECS-No.
Urea Present Present Present KE-35144
Present (2)-1732
Present Present Present 200-315-5
U.S. Regulations
California Prop. 65: Safe Drinking Water and Toxic Enforcement Act of 1986.
Chemicals Known to the State of California to Cause Cancer:This product does not contain a chemical requiring a warning under California Prop. 65. (See table below)
Chemicals Known to the State of California to Cause Reproductive Toxicity:This product does not contain a chemical requiring a warning under California Prop. 65. (See table below)
FDA - Food Additives Generally Recognized as Safe (GRAS): 21 CFR 184.1923
Product code: U1018
Minnesota - Hazardous Substance List: Present
Product name: UREA, FCC 9 / 11
Urea
Components Carcinogen Developmental Toxicity Male ReproductiveToxicity
Female ReproductiveToxicity:
Urea Not Listed Not Listed Not Listed Not Listed
CERCLA/SARA
Components CERCLA - HazardousSubstances and theirReportable Quantities
Section 302 ExtremelyHazardous
Substances and TPQs
Section 302 ExtremelyHazardous
Substances and RQs
Section 313 -Chemical Category
Section 313 - Reporting de minimis
Urea None None None None None
U.S. TSCA
Components TSCA Section 5(a)2 - Chemicals With SignificantNew Use Rules (SNURS)
TSCA 8(d) -Health and Safety Reporting
Urea Not Applicable Not Applicable
Canada
WHMIS hazard class:Non-controlled
Canada Controlled Products Regulation:This product has been classified according to the hazard criteria of the CPR (Controlled Products Regulation) and the MSDS containsall of the information required by the CPR.
Inventory
Components Canada (DSL) Canada (NDSL)Urea Present Not Listed
Components CEPA Schedule I - Toxic Substances CEPA - 2010 Greenhouse Gases Subject to ManditoryReporting
Urea Not listed Not listed
EU Classification
R-phrase(s)not determined
S -phrase(s)none
Components Classification Concentration Limits: Safety PhrasesUrea No information
The product is classified in accordance with Annex VI to Directive 67/548/EEC
Indication of danger:Not dangerous
Urea
Product code: U1018 Product name: UREA, FCC 10 / 11
Uncontrolled product according to WHMIS classification criteria
16. OTHER INFORMATION
Preparation Date: 2/17/2014Revision Date: 2/17/2014Prepared by: Sonia Owen
Disclaimer: All chemicals may pose unknown hazards and should be used with caution. ThisSafety Data Sheet (SDS) applies only to the material as packaged. If this product iscombined with other materials, deteriorates, or becomes contaminated, it may posehazards not mentioned in this SDS. The physical properties reported in this SDS areobtained from the literature and do not constitute product specifications. Informationcontained herein does not constitute a warranty, whether expressed or implied, as tothe safety, merchantability or fitness of the goods for a particular purpose. SpectrumChemicals & Laboratory Products, Inc. assumes no responsibility for results obtainedor for incidental or consequential damages, including lost profits, arising from the useof these data. No warranty against infringement of any patent, copyright or trademarkis made or implied. It shall be the user's responsibility to develop proper methods ofhandling and personal protection based on the actual conditions of use. While thisSDS is based on technical data judged to be reliable, Spectrum assumes noresponsibility for the completeness or accuracy of the information contained herein.
End of Material Safety Data Sheet
Product code: U1018 Product name: UREA, FCC 11 / 11
See Section 8.
HMIS Personal Protective EquipmentNFPA