MATERIAL SAFETY DATA SHEET - Spectrum Chemical SAFETY DATA SHEET 1. ... May affect electrolyte...

MATERIAL SAFETY DATA SHEET

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATIONProduct code: U1018Product Name: UREA, FCCChemical Name: CarbonyldimideSynonyms: Carbamide

CarbonyldiamineIsoureaUreaphilUreophilCarbonyldiamide

Recommended use: Manufacturing of resins, plastics; Condensed with Malonic ester to form Barbituricacid; cellulose softner; in ammoniated dentifrices; chemical intermediate; stabilizer inexplosives; in medicine (diuretic); separation of hydrocarbons; sulfamic acidproduction; in flameproofing agents; liquid and other fertilizer applications; livestocknutrient; monomer for urea-formaldehyde resins; insect (mosquito) repellent.

CAS #: 57-13-6RTECS # YR6250000Formula: NH2)2CO or CH4N2OCI#: Not availableSupplier: Spectrum Chemicals and Laboratory Products, Inc.

14422 South San Pedro St.Gardena, CA 90248(310) 516-8000

Order Online At: https://www.spectrumchemical.comEmergency Telephone Number: CHEMTREC: 1-800-424-9300Contact Person: Regina Wachenheim (East Coast)Contact Person: Martin LaBenz (West Coast)

2. HAZARDS IDENTIFICATION

Product code: U1018 Product name: UREA, FCC 1 / 11

Personal Protective EquipmentNFPA

See Section 8.

HMIS


Chronic Potential Health Effects:

Component Carcinogen Status:Urea57-13-6 (100)

No information available

Target Organs: No information available

Mutagenic Effects: May affect genetic materialMutagenic effects in mammalian somatic cellsExperiments with animal lymphocytes have shown mutagenic effectsExperiments with human lymphocytes have shown mutagenic effects

Teratogenic Effects: No information available

Aggravated Medical Conditions: No information available

See Section 11 for additional Toxicological Information

POTENTIAL ENVIRONMENTAL EFFECTS

Inhalation:May cause irritation of respiratory tract.

Ingestion:Causes digestive (gastrointestinal) tract irritation. May cause abdominal pain, nausea, vomiting, diarrhea. May affectrespiration. May cause central nervous system effects. May affect the cardiovascular system. It may affect the kidneys.May affect the blood. May affect electrolyte balance.

EMERGENCY OVERVIEWWARNING! IRRITANT

Irritating to eyesIrritating to skin

POTENTIAL HEALTH EFFECTS

Principal Routes of Exposure:Ingestion. Inhalation.

Acute Potential Health Effects:

OSHA Regulatory Status

Skin Contact:Causes skin irritation. Mild skin irritation.

Product code: U1018

This material is considered hazardous by the OSHA Hazard CommunicationStandard (29 CFR 1910.1200)

Product name: UREA, FCC 2 / 11

Eye Contact:Causes eye irritation. Mild eye irritation.

Appearance:Crystalline powder. Crystals.

Prills.

Color:White.

Odor:Almost odorless. It may

gradually develop a slight odor ofammonia, especially in the

presence of moisture.

Physical state:Solid.

No information available

3. COMPOSITION/INFORMATION ON INGREDIENTS

Components CAS-No. Weight %Urea 57-13-6 100

4. FIRST AID MEASURES

General Advice: Poison information centres in each State capital city can provide additionalassistance for scheduled poisons (13 1126).

Skin Contact: Wash off immediately with soap and plenty of water removing all contaminatedclothes and shoes. Get medical attention if irritation develops.

Eye Contact: Flush eye with water for 15 minutes. Get medical attention.

Inhalation: Move to fresh air. If not breathing, give artificial respiration. If breathing is difficult,give oxygen. Get medical attention.

Ingestion: Do not induce vomiting without medical advice. Never give anything by mouth to anunconscious person. Consult a physician if necessary.

Notes to Physician: Treat symptomatically

5. FIRE-FIGHTING MEASURES

Flammable Properties

Flashpoint (°C/°F): No information available.

Flash Point Tested according to:Not applicable

Lower Explosion Limit (%): No information availableUpper Explosion Limit (%): No information available

Autoignition Temperature (°C/°F): No information available

Suitable Extinguishing Media: Dry chemical. Carbon dioxide (CO2). Water spray mist orfoam.

Unsuitable Extinguishing Media: No information available.

Hazardous Combustion Products: Carbon monoxide; Carbon dioxide; Nitrogen oxides

Specific hazards: May be combustible at high temperatures

Special Protective Equipment for Firefighters: As in any fire, wear self-contained breathing apparatuspressure-demand, MSHA/NIOSH (approved or equivalent)and full protective gear

Specific Methods: No information available.

6. ACCIDENTAL RELEASE MEASURES

3 / 11Product code: U1018 Product name: UREA, FCC

Personal Precautions:Ensure adequate ventilation. Avoid contact with skin, eyes and clothing. Use personal protective equipment. Avoid dustformation. Remove all sources of ignition.

Environmental Precautions:No information available.

Methods for Cleaning Up:Sweep up and shovel into suitable containers for disposal. Clean contaminated surface thoroughly.

7. HANDLING AND STORAGE

Handling

Technical Measures/Precautions:Provide sufficient air exchange and/or exhaust in work rooms. Avoid dust formation. Keep away from incompatiblematerials.

Safe Handling Advice:Wear personal protective equipment. Avoid contact with skin, eyes and clothing. Avoid dust formation. Do notingest. Do not breathe vapours/dust. Keep away from heat and sources of ignition. Handle in accordance with goodindustrial hygiene and safety practice.

Storage

Technical Measures/Storage Conditions:Keep container tightly closed in a dry and well-ventilated place. Store at room temperature in the original container.Store away from incompatible materials.

Incompatible Materials:Oxidizing agents.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Engineering measures to reduce exposure: Ensure adequate ventilation. Use process enclosures, localexhaust ventilation, or other engineering controls to keepairborne levels below recommended exposure limits. If useroperations generate dust, fume or mist, use ventilation tokeep exposure to airborne contaminants below the exposurelimit.

Personal Protective Equipment

Eye protection: Goggles.

Skin and body protection: Long sleeved clothing. Chemical resistant apron. Gloves.

Respiratory protection: Wear respirator with dust filter..

Hygiene measures: Avoid contact with skin, eyes and clothing. Wash hands before breaks andimmediately after handling the product. When using, do not eat, drink or smoke.

National occupational exposure limits

United StatesComponents OSHA NIOSH ACGIH AIHA WHEEL

Urea - 57-13-6None None None 10 mg/m3 TWA

Canada


Components Alberta British Columbia Ontario QuebecUrea

57-13-6None None None None

Australia and MexicoComponents Australia Mexico

Urea57-13-6

None None

9. PHYSICAL AND CHEMICAL PROPERTIES

10. STABILITY AND REACTIVITY

Stability: Stable at normal conditions

Conditions to avoid: Heat. Avoid dust formation. Incompatible materials.

Incompatible Materials: Oxidizing agents.

Vapor pressure @ 20°C (kPa):No information available

Flash point (°C):No data available

Evaporation rate:No information available

Color:White.

Vapor density:2.07

VOC content (g/L):No information available

Lower Explosion Limit (%):No information available

Odor threshold (ppm):No information available

Partition coefficient(n-octanol/water):-2.1

Miscibility:No information available

Upper Explosion Limit (%):No information available

Solubility:Very soluble in waterSoluble in MethanolInsoluble in EtherInsoluble in ChloroformInsoluble in BenzeneSoluble in Acetic acidSoluble in concentrated hydrochloricacidSolubility: 1 gram dissolves in 1 mlwater, 10 ml of 95% Alcohol, 6 mlMethanol, 1 ml boiling 65% Alcohol, 2ml Glycerol


Autoignition Temperature (°C/°F):No information available

Odor:Almost odorless. It may graduallydevelop a slight odor of ammonia,especially in the presence of moisture.

Melting point/range(°C/°F):132-135 °C/269.6-275 °F

Boiling point/range(°C/°F):No information available

Appearance:Crystalline powder. Crystals. Prills.

pH:No information available

TasteSaline.

Specific gravity:1.323

Density (g/cm3):No information available

Molecular/Formula weight:60.06

Decomposition temperature(°C/°F):No information available


Bulk density:No information available

Hazardous decompositionproducts:

Carbon monoxide. Carbon dioxide. Nitrogen oxides (NOx).

Possibility of HazardousReactions:

Reacts violently with Gallum Perchlorate. Reacts with chlorine to form chloramines.It also reacts with the following: sodium hypochlorite, sodium nitrate, calciumhypochlorite, NaNO2, P2Cl5, nitrosyl perchlorate, strong oxidizing agents(permanganate, nitrate, dichromate, chloride)

Polymerization: Hazardous polymerisation does not occur

Corrosivity: No information available

Special Remarks on Corrosivity: No information available

11. TOXICOLOGICAL INFORMATIONAcute Toxicity

Component Information

Product Information

LC50/inhalation/rat No information availableLC50/Inhalation/mouse No information availableLD50/dermal/rabbit No information availableLD50/dermal/rat No information availableLD50/oral/mouse = 11000mg/kgLD50/oral/rat = 8471mg/kg

Local Effects

Skin irritation: Causes skin irritation. Mild skin irritation.

Eye irritation: Causes eye irritation. Mild eye irritation.

Inhalation: May cause irritation of respiratory tract.

Ingestion: Causes digestive (gastrointestinal) tract irritation. May cause abdominal pain,nausea, vomiting, diarrhea. May cause bloating. May cause dry mouth. May causesalivation. May cause regurgitation. May cause grinding of teeth. May affectrespiration (difficult or labored breathing resulting in shortness of breath). May affectrespiraton (apnea). May affect urinary system (kidneys). May cause mydriasis(dilated pupils). May affect electrolytes. May cause hypokalemia. May causehyponatremia. May affect cardiovascular system (hypotension, cardiac arrhythmias).May affect the cardiovascular system (change in heart rate). May cause headache.May cause fainting. May affect behavior/central nervous system (altered sleep time,change in motor activity, dizziness disorientation, ataxia, drowsiness, confusion,trembling, somnolence, aggressiveness, hyperreflexia, convulsions).

Sensitization: May cause sensitization by skin contact

LC50/inhalation/rat = No information available

LD50/oral/mouse = 11000 mg/kg

LC50/inhalation/mouse = No infomation available

LD50/oral/rat = 8471 mg/kg (RTECS)

Other LD50 or LC50information = No information available

LD50/dermal/rat = No information available

Urea - 57-13-6

Product code: U1018 Product name: UREA, FCC

LD50/dermal/rabbit = No information available

6 / 11

Chronic Toxicity

Chronic Toxicity Chronic exposure may affect the liver and kidneys. Chronic exposure may affect theblood (leukocytosis, thrombosis). Chronic exposure may affect the brain.

Carcinogenic effects: Tumorigenic agent by RTECS criteria. No other informaiton.

Components NTP IARC OSHA HCS -Carcinogens

ACGIH - Carcinogens Australia - ProhibitedCarcinogenicSubstances

Australia - NotifiableCarcinogenicSubstances

Urea Not listed Not listed Not listed Not listed Not listed Not listed


Reproductive Effects: No information available

Teratogenic Effects: No information available

Target Organs: No information available

12. ECOLOGICAL INFORMATION

ECOTOXICITY

Toxicity to terrestrial and aquatic plants and animals: Information given is based on data on the components andthe ecotoxicology of similar products

Ecotoxicity effects: Aquatic environment.

Aquatic toxicity:

Mobility: No information available

Persistence and degradability: No information available

Bioaccumulative potential: Potential for bioconcentration in aquatic organisms is low.

13. DISPOSAL CONSIDERATIONS

Waste from residues / unused products:Waste must be disposed of in accordance with Federal, State and Local regulation.

Contaminated packaging:Empty containers should be taken for local recycling, recovery or waste disposal

Components RCRA - F Series Wastes RCRA - K Series Wastes RCRA - P Series Wastes RCRA - U Series WastesUrea None None None None

14. TRANSPORT INFORMATION

Water Flea Data: 3910 mg/L EC50 Daphnia magna 48 h


Freshwater Fish Species Data:

7 / 11

16200 - 18300 mg/L LC50 Poecilia reticulata 96 h 1Urea - 57-13-6

DOTUN-No: Not regulatedProper Shipping Name: No information availableHazard Class: No information availablePacking Group: NoneSubsidiary Risk: Not applicableMarine Pollutant No data availableERG No: No information availableDOT RQ (lbs): No information available

TDG (Canada)UN-No: Not RegulatedProper Shipping Name: No information availableHazard Class: No information availablePacking Group: No information availableSubsidiary Risk: No information availableDescription: No information available

ADRUN-No: No information availableProper Shipping Name: No information availableHazard Class: No information availablePacking Group: No information availableSubsidiary Risk: No information availableClassification Code: No information availableDescription: No information availableCEFIC Tremcard No: No information available

IMO / IMDGUN-No: Not RegulatedProper Shipping Name: No information availableHazard Class: No information availablePacking Group: No information availableSubsidiary Risk: No information availableDescription: No information availableIMDG Page: No information availableMarine Pollutant No information availableMFAG: No information availableMaximum Quantity: No information available

RIDUN-No: No information availableProper Shipping Name: No information availableHazard Class: No information availablePacking Group: No information availableSubsidiary Risk: No information availableClassification Code: No information availableDescription: No information available

ICAOUN-No: No information availableProper Shipping Name: No information availableHazard Class: No information availablePacking Group: No information availableSubsidiary Risk: No information availableDescription: No information available

IATAUN-No: Not Regulated


Proper Shipping Name: No information availableHazard Class: No information availablePacking Group: No information availableSubsidiary Risk: No information availableDescription: No information available

15. REGULATORY INFORMATION

International Inventories

Components U.S. TSCA Philippines(PICCS)

KOREA KECL Japan ENCS CHINA Australia(AICS)

EINECS-No.

Urea Present Present Present KE-35144

Present (2)-1732

Present Present Present 200-315-5

U.S. Regulations

California Prop. 65: Safe Drinking Water and Toxic Enforcement Act of 1986.

Chemicals Known to the State of California to Cause Cancer:This product does not contain a chemical requiring a warning under California Prop. 65. (See table below)

Chemicals Known to the State of California to Cause Reproductive Toxicity:This product does not contain a chemical requiring a warning under California Prop. 65. (See table below)

Components Carcinogen Developmental Toxicity Male ReproductiveToxicity

Female ReproductiveToxicity:

Urea Not Listed Not Listed Not Listed Not Listed

CERCLA/SARA

Components CERCLA - HazardousSubstances and theirReportable Quantities

Section 302 ExtremelyHazardous

Substances and TPQs


Substances and RQs

Section 313 -Chemical Category

Section 313 - Reporting de minimis

Urea None None None None None

U.S. TSCA

Components TSCA Section 5(a)2 - Chemicals With SignificantNew Use Rules (SNURS)

TSCA 8(d) -Health and Safety Reporting

Urea Not Applicable Not Applicable

Canada

WHMIS hazard class:Non-controlled

Canada Controlled Products Regulation:This product has been classified according to the hazard criteria of the CPR (Controlled Products Regulation) and the MSDS containsall of the information required by the CPR.

Inventory

Urea

FDA - Food Additives Generally Recognized as Safe (GRAS): 21 CFR 184.1923

Urea


Minnesota - Hazardous Substance List: Present

9 / 11

Uncontrolled product according to WHMIS classification criteria

Components Canada (DSL) Canada (NDSL)Urea Present Not Listed

Components CEPA Schedule I - Toxic Substances CEPA - 2010 Greenhouse Gases Subject to ManditoryReporting

Urea Not listed Not listed

EU Classification

R-phrase(s)not determined

S -phrase(s)none

Components Classification Concentration Limits: Safety PhrasesUrea No information

The product is classified in accordance with Annex VI to Directive 67/548/EEC

Indication of danger:Not dangerous

16. OTHER INFORMATION

The MSDS format complies with ANSI Z400.1/Z129.1-2010 standards.

Preparation Date: 19-Feb-2014

Reason for revision: Not applicable

Prepared by: Sonia Owen

Literature reference: No information available

All chemicals may pose unknown hazards and should be used with caution. This Material Safety Data Sheet (MSDS)applies only to the material as packaged. If this product is combined with other materials, deteriorates, or becomescontaminated, it may pose hazards not mentioned in this MSDS. The physical properties reported in this MSDS areobtained from the literature and do not constitute product specifications. Information contained herein does not constitutea warranty, whether expressed or implied, as to the safety, merchantability or fitness of the goods for a particular purpose.Spectrum Chemicals & Laboratory Products, Inc. assumes no responsibility for results obtained or for incidental orconsequential damages, including lost profits, arising from the use of these data. No warranty against infringement of anypatent, copyright or trademark is made or implied. It shall be the user's responsibility to develop proper methods ofhandling and personal protection based on the actual conditions of use. While this MSDS is based on technical datajudged to be reliable, Spectrum assumes no responsibility for the completeness or accuracy of the information containedherein.

Product code: U1018

Urea


SAFETY DATA SHEET

1. IDENTIFICATION

Product identifierProduct code: U1018Product Name: UREA, FCC

Other means of identificationSynonyms: Carbamide

CarbonyldiamineIsoureaUreaphilUreophilCarbonyldiamide

CAS #: 57-13-6RTECS # YR6250000CI#: Not available

Recommended use of the chemical and restrictions on useRecommended use: Manufacturing of resins, plastics; Condensed with Malonic ester to form Barbituric

acid; cellulose softner; in ammoniated dentifrices; chemical intermediate; stabilizer inexplosives; in medicine (diuretic); separation of hydrocarbons; sulfamic acidproduction; in flameproofing agents; liquid and other fertilizer applications; livestocknutrient; monomer for urea-formaldehyde resins; insect (mosquito) repellent.

Uses advised against No information available

Supplier: Spectrum Chemicals and Laboratory Products, Inc.14422 South San Pedro St.Gardena, CA 90248(310) 516-8000

Order Online At: https://www.spectrumchemical.com

Emergency telephone number Chemtrec 1-800-424-9300Contact Person: Martin LaBenz (West Coast)Contact Person: Regina Wachenheim (East Coast)


Classification

This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)

Serious eye damage/eye irritation Category 2B

Label elements

Revision Date: 2/17/2014 Revision Number: G1


Preparation Date: 2/17/2014

1 / 11

Hazards not otherwise classified (HNOC)Not Applicable

Other hazardsCauses mild skin irritation

Precautionary Statements - PreventionWash face, hands and any exposed skin thoroughly after handling

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eyeirritation persists: Get medical advice/attention.If skin irritation occurs: Get medical advice/attention

3. COMPOSITION/INFORMATION ON INGREDIENTS

Components CAS-No. Weight % Trade SecretUrea

57-13-657-13-6 100 *

4. FIRST AID MEASURES

First aid measuresGeneral Advice: Poison information centres in each State capital city can provide additional

assistance for scheduled poisons (13 1126).

Skin Contact: Wash off immediately with soap and plenty of water removing all contaminated clothes andshoes. Get medical attention if irritation develops.

Eye Contact: Flush eye with water for 15 minutes. Get medical attention.

Inhalation: Move to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.Get medical attention.

Ingestion: Do not induce vomiting without medical advice. Never give anything by mouth to anunconscious person. Consult a physician if necessary.

Most important symptoms and effects, both acute and delayedSymptoms Mild skin irritation. Mild eye irritation. Ingestion may cause nausea, vomiting, and diarrhea.

Abdominal pain. May cause salivation. Hypotension. Cardiac arrhythmias. May affectrespiration. Central nervous system effects. May affect behavior/central nervous system(tremor, convulsions). Headache. Disorientation. Confusion. Fainting. May affect electrolytebalance.

Indication of any immediate medical attention and special treatment neededNotes to Physician: Treat symptomatically

Protection of first-aidersFirst-Aid Providers: Avoid exposure to blood or body fluids. Wear gloves and other necessary protective clothing. Dispose ofcontaminated clothing and equipment as bio-hazardous waste

Warning


Hazard statementsCauses eye irritation

2 / 11

5. FIRE-FIGHTING MEASURES

Extinguishing Media

Suitable Extinguishing Media: Dry chemical. Carbon dioxide (CO2). Water spray mist orfoam.

Unsuitable Extinguishing Media: No information available.

Specific hazards arising from the chemical

Hazardous Combustion Products: Carbon monoxide; Carbon dioxide; Nitrogen oxides

Specific hazards: May be combustible at high temperatures.

Special Protective Actions for Firefighters

Specific Methods: No information available.

Special Protective Equipment for Firefighters: As in any fire, wear self-contained breathing apparatuspressure-demand, MSHA/NIOSH (approved or equivalent)and full protective gear

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Personal Precautions: Ensure adequate ventilation. Avoid contact with skin, eyes and clothing. Use personalprotective equipment. Avoid dust formation. Remove all sources of ignition.

Environmental precautions No information available.

Methods and material for containment and cleaning up

Methods for containment Stop leak if you can do it without risk. Cover with plastic sheet to prevent spreading.

Methods for cleaning up Sweep up and shovel into suitable containers for disposal. Clean contaminatedsurface thoroughly.

7. HANDLING AND STORAGE

Precautions for safe handling

Technical Measures/Precautions:Provide sufficient air exchange and/or exhaust in work rooms. Avoid dust formation. Keep away from incompatiblematerials.

Safe Handling Advice:Wear personal protective equipment. Avoid contact with skin, eyes and clothing. Avoid dust formation. Do notingest. Do not breathe vapours/dust. Keep away from heat and sources of ignition. Handle in accordance with goodindustrial hygiene and safety practice.

Conditions for safe storage, including any incompatibilities

Technical Measures/Storage Conditions:Keep container tightly closed in a dry and well-ventilated place. Store at room temperature in the original container.Store away from incompatible materials.

Incompatible Materials:Oxidizing agents.

Product name: UREA, FCC 3 / 11Product code: U1018

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters

National occupational exposure limits

United StatesComponents OSHA NIOSH ACGIH AIHA WHEEL

Urea - 57-13-6None None None 10 mg/m3 TWA

CanadaComponents Alberta British Columbia Ontario Quebec

Urea - 57-13-6None None None None

Australia and MexicoComponents Australia Mexico

Urea57-13-6

None None

Appropriate engineering controls

Engineering measures to reduce exposure: Ensure adequate ventilation. Use process enclosures, localexhaust ventilation, or other engineering controls to keepairborne levels below recommended exposure limits. If useroperations generate dust, fume or mist, use ventilation tokeep exposure to airborne contaminants below the exposurelimit.

Individual protection measures, such as personal protective equipmentPersonal Protective Equipment

Eye protection: Goggles.

Skin and body protection: Long sleeved clothing. Chemical resistant apron. Gloves.

Respiratory protection: Wear respirator with dust filter..

Hygiene measures: Avoid contact with skin, eyes and clothing. Wash hands before breaks andimmediately after handling the product. When using, do not eat, drink or smoke.




10. STABILITY AND REACTIVITY

Reactivity

Chemical stabilityStability: Stable at normal conditions

Possibility of Hazardous Reactions: Hazardous polymerization does not occur

Conditions to avoid: Heat. Avoid dust formation. Incompatible materials.

Incompatible Materials: Oxidizing agents.

VOC content (g/L):No information available

Flashpoint (°C/°F):Not applicable

Odor threshold (ppm):No information available


Partition coefficient(n-octanol/water):-2.1

Viscosity:No information available

Flash Point Tested according to:Not applicable

Miscibility:No information available

Odor:Almost odorless. It may graduallydevelop a slight odor of ammonia,especially in the presence of moisture.

Solubility:Very soluble in waterSoluble in MethanolInsoluble in EtherInsoluble in ChloroformInsoluble in BenzeneSoluble in Acetic acidSoluble in concentrated hydrochloricacidSolubility: 1 gram dissolves in 1 mlwater, 10 ml of 95% Alcohol, 6 mlMethanol, 1 ml boiling 65% Alcohol, 2 mlGlycerol

Lower Explosion Limit (%):No information available

Upper Explosion Limit (%):No information available

Appearance:Crystalline powder. Crystals. Prills.

Autoignition Temperature (°C/°F):No information available

TasteSaline.

Reactive with oxidizing agentsReacts violently with Gallum Perchlorate. Reacts with chlorine to form chloramines.It also reacts with the following: sodium hypochlorite, sodium nitrate, calcium hypochlorite, NaNO2, P2Cl5, nitrosyl perchlorate, strongoxidizing agents (permanganate, nitrate, dichromate, chloride)

pH:No information available

Melting point/range(°C/°F):132-135 °C/269.6-275 °F

Formula:NH2)2CO or CH4N2O

Boiling point/range(°C/°F):No information available

Decomposition temperature(°C/°F):No information available

Specific gravity:1.323

Molecular/Formula weight:60.06

Density (g/cm3):No information available

Color:White.

Bulk density:No information available

Vapor pressure @ 20°C (kPa):No information available

Flash point (°C):Not applicable

Product code: U1018

Evaporation rate:No information available


Vapor density:2.07

Hazardous decomposition products: Carbon monoxide. Carbon dioxide. Nitrogen oxides (NOx).

Other Information

Corrosivity: No information available

Special Remarks on Corrosivity: No information available

11. TOXICOLOGICAL INFORMATION

Information on likely routes of exposure

Principal Routes of Exposure:Ingestion. Inhalation.

Acute Toxicity

Component Information

Product Information

LD50/oral/rat =VALUE- Acute Tox Oral = 8471mg/kg

LD50/oral/mouse =Value - Acute Tox Oral = 11000mg/kg

LD50/dermal/rabbitVALUE-Acute Tox Dermal = No information available

LD50/dermal/ratVALUE -Acute Tox Dermal = No information available

LC50/inhalation/ratVALUE-Vapor = No information availableVALUE-Gas = No information availableVALUE-Dust/Mist = No information available

LC50/Inhalation/mouseVALUE-Vapor = No information availableVALUE - Gas = No information availableVALUE - Dust/Mist = No information available

Symptoms

Skin Contact: Causes skin irritation. Mild skin irritation.

LC50/inhalation/mouse = No infomation available

LD50/oral/rat = 8471 mg/kg (RTECS)

Other LD50 or LC50information = No information available

LD50/dermal/rabbit = No information available

Urea - 57-13-6

LD50/dermal/rat = No information available


LC50/inhalation/rat = No information available

LD50/oral/mouse = 11000 mg/kg

Eye Contact: Causes eye irritation. Mild eye irritation.

Inhalation May cause irritation of respiratory tract.Ingestion Causes digestive (gastrointestinal) tract irritation. May cause abdominal pain,

nausea, vomiting, diarrhea. May cause bloating. May cause dry mouth. May causesalivation. May cause grinding of teeth. May affect respiration (difficult or laboredbreathing resulting in shortness of breath). May affect respiration (apna). May causemydriasis (dilated pupils). May affect urinary system (kidneys). May affectelectrolytes. May cause hypokalemia. May cause hyponatremia. May affectcardiovascular system (hypotension, cardiac arrhythmias). May affect thecardiovascular system (change in heart rate). May cause headache. May causefainting. May affect behavior/central nervous system (altered sleep time, change inmotor activity, dizziness disorientation, ataxia, drowsiness, confusion, trembling,somnolence, aggressiveness, hyperreflexia, convulsions).

Aspiration hazard No information available

Delayed and immediate effects as well as chronic effects from short and long-term exposure

Chronic Toxicity Chronic exposure may affect the liver and kidneys. Chronic exposure may affect theblood (leukocytosis, thrombosis). Chronic exposure may affect the brain.

Sensitization: May cause sensitization by skin contact


Carcinogenic effects: Tumorigenic agent by RTECS criteria. No other informaiton.

Components ACGIH -Carcinogens

IARC NTP OSHA HCS -Carcinogens

Australia - ProhibitedCarcinogenicSubstances

Australia - NotifiableCarcinogenicSubstances

Urea Not listed Not listed Not listed Not listed Not listed Not listed

Reproductive toxicity No data is available

Reproductive Effects: No information availableDevelopmental Effects: No information availableTeratogenic Effects: No information available

Specific Target Organ Toxicity

STOT - single exposure No information availableSTOT - repeated exposure No information availableTarget Organs: No information available

12. ECOLOGICAL INFORMATION

Ecotoxicity

Ecotoxicity effects: Aquatic environment.


Persistence and degradability: No information available

Bioaccumulative potential: Potential for bioconcentration in aquatic organisms is low.

Mobility: No information available

13. DISPOSAL CONSIDERATIONS

Disposal Methods

Waste from residues / unused products:Waste must be disposed of in accordance with Federal, State and Local regulation.

Contaminated packaging:Empty containers should be taken for local recycling, recovery or waste disposal

Components RCRA - F SeriesWastes

RCRA - K SeriesWastes

RCRA - PSeriesWastes

RCRA - U Series Wastes

Urea None None None None

14. TRANSPORT INFORMATION

DOTUN-No: Not regulatedProper Shipping Name: No information availableHazard Class: No information availableSubsidiary Risk: Not applicablePacking Group: NoneMarine Pollutant No data availableERG No: No information availableDOT RQ (lbs): No information available

TDG (Canada)UN-No: Not RegulatedProper Shipping Name: No information availableHazard Class: No information availableSubsidiary Risk: No information availablePacking Group: No information availableDescription: No information available

ADRUN-No: Not RegulatedProper Shipping Name: No information availableHazard Class: No information availablePacking Group: No information availableSubsidiary Risk: No information availableClassification Code: No information availableDescription: No information availableCEFIC Tremcard No: No information available

Freshwater Fish Species Data: 16200 - 18300 mg/L LC50 Poecilia reticulata 96 h 1

Product code: U1018

Urea - 57-13-6


Water Flea Data: 3910 mg/L EC50 Daphnia magna 48 h

14. TRANSPORT INFORMATIONIMO / IMDG

UN-No: Not RegulatedProper Shipping Name: No information availableHazard Class: No information availableSubsidiary Risk: No information availablePacking Group: No information availableDescription: No information availableIMDG Page: No information availableMarine Pollutant No information availableMFAG: No information availableMaximum Quantity: No information available

RIDUN-No: Not RegulatedProper Shipping Name: No information availableHazard Class: No information availableSubsidiary Risk: No information availablePacking Group: No information availableClassification Code: No information availableDescription: No information available

ICAOUN-No: Not RegulatedProper Shipping Name: No information availableHazard Class: No information availableSubsidiary Risk: No information availablePacking Group: No information availableDescription: No information available

IATAUN-No: Not RegulatedProper Shipping Name: No information availableHazard Class: No information availableSubsidiary Risk: No information availablePacking Group: No information availableDescription: No information available

15. REGULATORY INFORMATION

International Inventories

Components U.S. TSCA Philippines(PICCS)

KOREA KECL Japan ENCS CHINA Australia(AICS)

EINECS-No.

Urea Present Present Present KE-35144

Present (2)-1732

Present Present Present 200-315-5

U.S. Regulations

California Prop. 65: Safe Drinking Water and Toxic Enforcement Act of 1986.

Chemicals Known to the State of California to Cause Cancer:This product does not contain a chemical requiring a warning under California Prop. 65. (See table below)

Chemicals Known to the State of California to Cause Reproductive Toxicity:This product does not contain a chemical requiring a warning under California Prop. 65. (See table below)

FDA - Food Additives Generally Recognized as Safe (GRAS): 21 CFR 184.1923

Product code: U1018

Minnesota - Hazardous Substance List: Present


Urea

Components Carcinogen Developmental Toxicity Male ReproductiveToxicity

Female ReproductiveToxicity:

Urea Not Listed Not Listed Not Listed Not Listed

CERCLA/SARA

Components CERCLA - HazardousSubstances and theirReportable Quantities


Substances and TPQs


Substances and RQs

Section 313 -Chemical Category

Section 313 - Reporting de minimis

Urea None None None None None

U.S. TSCA

Components TSCA Section 5(a)2 - Chemicals With SignificantNew Use Rules (SNURS)

TSCA 8(d) -Health and Safety Reporting

Urea Not Applicable Not Applicable

Canada

WHMIS hazard class:Non-controlled

Canada Controlled Products Regulation:This product has been classified according to the hazard criteria of the CPR (Controlled Products Regulation) and the MSDS containsall of the information required by the CPR.

Inventory

Components Canada (DSL) Canada (NDSL)Urea Present Not Listed

Components CEPA Schedule I - Toxic Substances CEPA - 2010 Greenhouse Gases Subject to ManditoryReporting

Urea Not listed Not listed

EU Classification

R-phrase(s)not determined

S -phrase(s)none

Components Classification Concentration Limits: Safety PhrasesUrea No information

The product is classified in accordance with Annex VI to Directive 67/548/EEC

Indication of danger:Not dangerous

Urea


Uncontrolled product according to WHMIS classification criteria

16. OTHER INFORMATION

Preparation Date: 2/17/2014Revision Date: 2/17/2014Prepared by: Sonia Owen

Disclaimer: All chemicals may pose unknown hazards and should be used with caution. ThisSafety Data Sheet (SDS) applies only to the material as packaged. If this product iscombined with other materials, deteriorates, or becomes contaminated, it may posehazards not mentioned in this SDS. The physical properties reported in this SDS areobtained from the literature and do not constitute product specifications. Informationcontained herein does not constitute a warranty, whether expressed or implied, as tothe safety, merchantability or fitness of the goods for a particular purpose. SpectrumChemicals & Laboratory Products, Inc. assumes no responsibility for results obtainedor for incidental or consequential damages, including lost profits, arising from the useof these data. No warranty against infringement of any patent, copyright or trademarkis made or implied. It shall be the user's responsibility to develop proper methods ofhandling and personal protection based on the actual conditions of use. While thisSDS is based on technical data judged to be reliable, Spectrum assumes noresponsibility for the completeness or accuracy of the information contained herein.

End of Material Safety Data Sheet


See Section 8.

HMIS Personal Protective EquipmentNFPA

MATERIAL SAFETY DATA SHEET - Spectrum Chemical SAFETY DATA SHEET 1. ... May affect electrolyte...

Documents

Transcript of MATERIAL SAFETY DATA SHEET - Spectrum Chemical SAFETY DATA SHEET 1. ... May affect electrolyte...