CHEM 121 Chapter 8 Winter 2014 1. Mixtures Heterogeneous mixture: 2 Homogeneous mixture: Solution:...

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Transcript of CHEM 121 Chapter 8 Winter 2014 1. Mixtures Heterogeneous mixture: 2 Homogeneous mixture: Solution:...

CHEM 121

Chapter 8

Winter 2014

1

SolutionsSolution =

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Solute

Solvent

Types of Solutions• Colloids:

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• Suspensions:

Solubility

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Most ionic and polar substances __________________

Most nonpolar substances _______________________

___________ can be endothermic or exothermic

Solvation• Example: NaCl

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+ - + - + -+- +-+-

+ - + - + -+- +-+-

Solubility

Amount of solute that can dissolve in a given amount of solvent

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Solubility rules p. 247

Temperature and Solubility

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As T increases….

Pressure and Solubility

What dissolves?• Gases form solutions easily

• Solids and liquids:

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Dissolving RateDifferent from solubility

How to increase dissolving rate:

1.

2.

3.

• 11

Concentration

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Weight Percent =

Volume Percent =

Weight/Volume Percent =

3-minute Practice

The amount of alcohol in a bottle of wine is labeled 13.5% (v/v). How much alcohol is in the entire 750. mL bottle?

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ppm and ppb

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Parts per million =

=

Molarity

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Molarity (M) =

What is the molarity of the solution created when you dissolve 2.5 g of NaOH in 100. mL of solution?

3-minute Practice

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How many grams of NaOH would you have to dissolve in water to make 100. mL of a 1.0 M solution?

DilutionAdd more water:

Volume?

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Concentration?Amount of solute? Number of moles of solute?

3-minute Practice

Suppose you have a 1.0 M NaOH solution, but you want a 200. mL of a 0.25 M NaOH solution. How would you make this solution?

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Aqueous Reactants

You have 250 mL of 1.0 M NaOH. How many moles NaOH?

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)(SOH)(NaOH 42 aqaq )(OH )(SONa 242 laq

How much 0.2 M H2SO4 solution would you need to completely react the NaOH?

5-minute Practice

You have: 200. mL of 2.0 M H2SO4 and

500. mL of 1.5 M NaOH

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)(SOH)(NaOH 42 aqaq )(OH )(SONa 242 laq

How much water (g) can you make?

Hints: 1.Go to moles of each2.Determine which is limiting!

Electrolytes

Electrolyte:

• Strong electrolyte:

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Weak Electrolytes and Nonelectrolytes

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• Weak electrolytes: • •

• Nonelectrolytes: •

)(OHC OHC 112212OH

1122122 aq(s)

Colligative PropertiesProperties that change based on dissolved concentration

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Boiling point elevation:

Freezing point depression:

Osmotic pressure:

5-minute practice

You fill a pot with 320. g of NaCl and enough water to total 1.50 L of solution.

What is the boiling point of this solution?

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MembranesSemipermeable:

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OsmosisOsmosis:

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Osmotic Pressurepressure needed to prevent net flow of solvent through a semipermeable membrane

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constant

Dialysis:

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