Nineteenth International
Symposium on
Capillary Chromatographyand Electrophoresis
Wintergreen Conference Center
Wintergreen, Virginia, USA
May 18-22, 1997
UB/TIB Hannover 89
119 803 348
TABLE OF CONTENTS
LECTURES
M.J.E. Golay Award Lecture
M.J.E. Golay Award1
Fast Gas Chromatography: A Comparison of DifferentApproaches.Carel A. Cramers 2
Plenary Award Lecture
Applications of High-speed and Two-dimensional Gas Chromatography.
JohnB.Phillips 4
Microfabricated Separation SystemsFluidic Manipulations and Separations Using Microchips. J. Michael Ramsey 6
Integration ofBiochemical and Cellular Reactions with Separations On-chip.
P. JedHarrison. PerE. Andersson, Paul C.H. Li, Nghia Chiem,
Thompson Tang, R. Smith, R. Szarka, and T. Tran 8
Technologies for Nanochemistry and Nanoseparations. Johan Roeraade 10
Exhaustive Electromigration Injection from Small Volumes. Kazimierz Surowiec
and Purnendu K. Dasgupta 12
Electrophoresis in Flatland. Robert Austin. OlgicaBakajin, JeffChou,
Shirley Chan, and Thomas Duke14
Continuous On-lineSeparations with Electrophoresis in Narrow Channels:
From Small Neurochemicals to DNA Separations. Andrew G. Ewing.
Peter Gavin, Paula Beyer Hietpas, and Katherine Bullard 16
Microfabricated Integrated DNA Analysis Systems. Adam T. Woolley.
Peter C. Simpson, Stephen J. Williams, and Richard A. Mathies 18
Micro-capillary Electrophoresis Devices Fabricated Using Polymeric Substrates
and X-ray Lithography: A Logical Choice for High Resolution DNA
Separations. Steven A. Soper. SeanFord, Bill Kar, JackDavies, Mike Klopf,
Gina Calderon, andVolker Saile 20
MicrofabricatedDevices for Biological Analysis. Stephen C. Jacobson and
J. Michael Ramsey22
Enhanced Fluidity SeparationsHigh Pressure Gas Chromatography on Packed Capillary Columns.
Keith P. Bartle. Mark M. Robson, Peter Myers, and Anthony A, Clifford 24
Packed Column SFC: Advantages Over LC. Heinz Engelhardt 26
Packed Microcolumns for Novel Analytical Applications. Karin E. Markides.
Pernilla Koivisto, Susanne Wallenborg, Per Sjoberg, Benita Hyllbrant,Ulrika Petersson, F. Javier Seflorans, Bengt Langstrom, Leif Nyholm, and
Morgan Stefansson28
Advantages of Packed Capillary Columns in LC/SFC. Tyge Greibrokk.
Elsa Lundanes, Paal Molander, Iris Hunnes, andRoger Trones 30
I
New Applications of Enhanced-fluidity Chromatography. Susan V. Olesik.
Dong Wen, and Hao Yun 32
Solvating Gas Chromatography Using Packed Capillary Columns. Yufeng Shen
and Milton L. Lee 34
Analytical Extraction and Chromatography with Subcritical (Hot/Liquid) Water.
Steven B. Hawthorne. Yu Yang, Carol B. Grabanski, Arnaud Lagadec,
Kimberly J. Hageman, Maya Belghazi, and David J. Miller 36
Superheated Water as a Mobile Phase in Reversed Phase High Performance
Liquid Chromatography. Roger M. Smith. Robert J. Burgess, and
Orapin Chienthavorn 38
Addressing the Analytical Sample Preparation Needs in Industry.
Douglas E. Raynie 40
Capillary Liquid ChromatographyUltra-high Pressure Liquid Chromatography. John E. MacNair and
James W. Jorgenson 42
Gradient Elution Microchip Liquid Chromatography. Joerg P. Kutter.
Norio Matsubara, John W. Halliwell, Stephen C. Jacobson, and
J. Michael Ramsey 44
Evaporative Light Scattering Detection for Microcolumn LiquidChromatography. James N. Alexander IV 46
Multidimensional Microcolumn Liquid Chromatography for Complex Sample
Analysis. Johannes P.C. Vissers. Mario Ursem, Remco E.J. van Soest,
and Jean Pierre Chervet 48
Capillary HPLC/NMR Coupling 2D NMR Spectroscopy in the Nanoliter Scale
Structure Determination of Vitamin A Acetate Dimers. Gotz Schlotterbeck.
Li- Hong Tseng, Ulrich Braumann, and Klaus Albert 50
On-line NMR Detection for Capillary Separations. Jonathan V. Sweedler.
Dean L. Olson, Michael Lacey, and Andrew G. Webb 52
Advanced Sol-gel Column Technology for Condensed-phase Microseparations.Abdul Malik. James D. Hayes, Dongxin Wang, Sau L. Chong,
Gregory S. Corbett, and Jeff W. Cramer 54
Influence of the Length of the Nebulizer Drift Tube in a Laser Light-scatteringDetector and in the /t-LC-ICP-MS Coupling. Roger Trones. Anders Tangen,
Yngve Kristiansen, Walter Lund, and Tyge Greibrokk 56
Applications of Micro Packed Columns in Chiral Capillary Liquid Chromatography.Fernando M. Lancas. Andrea L. Rezemini, and Fernando A. Daher 58
Capillary ElectrochromatographyRecent Developments and Directions in Capillary Electrochromatography.
Csaba Horvath. Gargi Choudhary and Xian Huang 60
Sol-Gel Stationary Phases and Non-aqueous Mobile Phases for Electrochromatography:Will Any of This Work? JohnG. Dorsey. Ashley Lister, Paul B. Wright,Steven C. Wendelken, and Thomas L. Chester 62
II
Capillary Electrochromatography Versus High Temperature Capillary Liquid
Chromatography. Djordjevic M. Nebojsa, Fabrice Houdiere, Guido Lerch,andPatrickFowler 64
Capillary Electrochromatography in Open Tubes and Packed Columns.
Luis A. Colon. Yong Guo, Adam M. Fermier, Kimberly J. Reynolds,and Shirley Rodriguez 66
Practical Experiences and Applications of Capillary Electrochromatography (CEC)in the Pharmaceutical Industry. MelvinR, Euerby. Christopher M. Johnson,
Keith D. Bartle, Maria Cikalo, Peter Myers, and Stephanie C.P. Roulin 68
Varieties of Stationary Phases in Capillary Electrochromatography. Chuzo Fujimpto,Masahito Sakurai, and Yutaka Fujise 70
Electrochromatographyin Packed and Open Tubular Capillaries at Ambient
Pressure. Johan C. Kraak. S. Heemstra, R. Swart, andH. Poppe 72
Development and Evaluation of Capillary Electrochromatography for Analysis of
Pharmaceutical Samples. Kent M.Payne. Charles W. Demarest, Kurt R. Sedo,
Lai Y. Rwok, Thomas T, Catalano, Peter D.A. Angus, and John F. Stobaugh 74
Capillary Electrochromatography: Optimization of Instrumental Parameters.
Hans Rebscher, Andreas Banholczer, andUtePyell 76
CEC and CEC-ES-MS in Natural Product Research. Pat Sandra. Anna Dermaux,
andEric Van Hove 78
Novel Stationary Phases and Packing Materials for Capillary Electrokinetic
Chromatography. Vincent T. Remcho. Zhixin Jessica Tan, and
Michael Cipoletti 80
CEC with Predetermined Selectivity Created byMolecular Imprinting.StaffanNilsson. Leif Schweitz, and Lars I. Andersson 82
Capillary Electrochromatography (CEC) - Methodology and Applications.Monika M. Dittmann and Gerard P. Rozing 84
Capillary Electrochromatography: Advances in High-speed, High-efficiency and
High-selectivity Separations. Chao Yan. RajeevDadoo, Richard N. Zare,
Deon S. Anex, andDavidJ. Rakestraw 86
Capillary Electrochromatography: Evaluation of Some Column Fabrication
Techniques andApplication to PharmaceuticalAnalysis. Peter D.A. Angus,John F. Stobaugh. Charles W. Demarest, KentM. Payne, KurtR. Sedo,
Lai Y. Kwok, and Thomas Catalano 88
Chiral CapillaryElectrochromatography Using Capillaries Packed with
Chiralcel OD. Sally J. Grieb, Andrew Maxwell, and Joe P. Foley 90
Separation ofSynthetic Polymers by Electrically Driven Size Exclusion
Chromatography. Edward Venema. Johan C. Kraak, Hans Poppe,
and Rob Tijssen 92
Electrochromatography in Wide-bore Capillary Tubes. MarkM.Robson.
Peter Myers, andKeithD. Bartle 94
Liquid Phase Separations/Mass SpectrometryHigh Performance Capillary Electrophoresis/Mass Spectrometry: New
Developments and Applications. Steven A. Hofstadler. Richard D. Smith
and Joanne C. Severs 96
Generating Electrospray from Planar Glass Chips. Roswitha S. Ramsey and
J. Michael Ramsey 98
Micromachined Device for High Throughput Handling and Mass Spectrometric
Analysis of Biological Samples. Frantisek Foret, Qifeng Xue,
Yuri DunayevsMy, and Barry L. Karger 100
New Electroseparation Strategies Using Mass Spectrometric Detection.
Martin Mazereeuw and Jan Van der Greef 102
Recent Developments in SFC/Electrospray-MS for the Analysis of Pharmaceuticals
and Other Small Molecules. Timothy R. Baker. Thomas H. Eichhold,
J. David Pinkston, and Rosemary T. Hentschel 104
Microcolumn Separations Coupled with Mass Spectrometry for Optimizing
Protein-ligand and Enzyme-substrate Interactions. Daniel B. Kassel.
Ann Edison, Alison Meekhof, Kevin Blackburn, and W.Blaine Knight 106
Capillary Column HPLC Electrospray Mass Spectrometry of Combinatorial
Libraries. Kenneth C. Lewis. William L. Fitch, and Derek Maclean 108
Incorporation of a RAM Cell in a Microcolumn for On-column Detection of
Radiolabeled Molecules for LC-RAM-ESI-MS. Gary A. Schultz and
James N. Alexander IV 110
Capillary Electrophoresis/ElectrosprayIonization/Time-of-flight Mass
Spectrometry. Iulia M. Lazar and Milton L. Lee 112
Sequencing Biologically Derived Peptides at the Attomole Level: A Comparisonof the Utility of HPLC and CE Chromatographic Methods. Robert E. Settlage.Paul S. Russo, Jeffrey Shabanowitz, and Donald F. Hunt 114
High Resolution Capillary Isoelectric Focusing-Electrospray Ionization Mass
Spectrometry for Protein Characterization. Cheng S. Lee. Qing Tang,
Liyu Yang, andKamel A. Harrata 116
Basic Investigation and Application of MEKC-MS Using Atmospheric Pressure
Chemical Ionization. Koji Otsuka, Masaki Yokoi, Pirn Muijselaar, Hiroto Ozaki,
and Shigeru Terabe 118
Advances in the Understanding and Application of Capillary Electrophoresis
Inductively Coupled Plasma Mass Spectrometry. JohnW. Olesik.
Jeffrey A. Kinzer, and Eric J. Grunwald 120
Electrospray Nebulisation Interface for Micro-high Performance Liquid
Chromatography-inductively Coupled Plasma-mass Spectrometry of
OrganometallicCompounds. Mark W. Raynor. Maria Balcerzak,
Warren G. Pretorius, andLes Ebdon 122
Detection for Microcolumn Separations: The TOF-MS Advantage. Edgar D. Lee.
Alan L. Rockwood, Jacqueline P. Fabbi, Joseph C.H. Sin, Jeff Jones,
Chad Ogden, Hal Tolley, and Harold G. Lee 124
Gradient CapillaryHPLC in the Nanoliter Scale with Electrospray-MS and LD7/CCDDetection. Beate Behnke. Staffan Nilsson, Jonas Johansson, Christoph Kempter,J6rg W. Metzger, and Ernst Bayer 126
CE/Raman Spectroscopy: A Harmonious Marriage. Michael P. Morris.
Patrick A. Walker, III, Jeremey M. Shaver, and Hong- Min Li 128
Development of an Integrated Capillary Electrophoresis-Fiberoptic Sensor.
Michael J. Sepaniak. David L. Stokes, Jason E. Dickens, Victoria Tropina,and Tuan Vo-Dinh 130
Fast GC and GC-MS
Fast GC-MS with Supersonic Molecular Beams. Aviv Amirav and Shai Dagan 132
Realization of True Multi-channel Detection by High-speed GC/Time-of-flight MS.
John F. Holland and Ben D. Gardner 134
Environmental Air Monitoring with a Roving GC/MS System. William H. McClennen
and Henk Meuzelaar 136
Comprehensive Two-dimensional Gas Chromatography: Instrumentation Issues
Relevant to Portability. Edward B. Ledford. Jr.. Richard B. Gaines, and
John B. Phillips 138
Interfacing Fast Gas Chromatographic Techniques with Time-of-flight Mass
Spectrometry: Sharing the Burden of Component Resolution.
Ritchard C, Parry. Nancy Brichford, Viatcheslav B. Artaev, and Joel Mitchell 140
Analytical Advances in Biological Monitoring: Endocrin-disrupting and Other
Environmental Toxicants. Donald G. Patterson. Jr.. JohnR. Barr,
James Grainger, Vaughn Green, Chester Lapeza, Jr., Vincent Maggio,Sarath Sirimanne, C. Smith, Wayman Turner, and Adrian Woolfitt 142
Screening Environmental Samples for Oxygenates and Aromatics Using ComprehensiveTwo-dimensional Gas Chromatography. Richard B. Gaines. James D. Stuart,and Edward B. Ledford, Jr 144
Methods and Models for Selectivity Tuning in High-speed GC. Richard Sacks.
Heather Smith, and Mark Nowak 146
High-speed, Short Column Capillary Gas Chromatography with Chemometrics.
Robert E. Synovec. Carsten A. Bruckner, and Bryan J. Prazen 148
Fast Gas Chromatography Coupled with Mass Spectrometric Detection.
Jens Dalluge. Isabel Catalina, Ren6 Vreuls, Udo Brinkman, .and Eva Pocurull 150
New Approaches to Cryogenic and Related Solute Manipulation for Enhanced
Performance in Capillary Gas Chromatography. Philip J. Marriott and
Russell M. Kinghorn 152
Reducing Gas Chromatography Analysis Times with the New High Temperature
Multi-cap Column. William S. Cooke. Joseph W. Walsh, and Robert T. Wiedemer..
154
CE and MEKC
Capillary Electrophoresis of Charged Polysaccharides at High Resolution.
Milos V. Novotny. Jan Sudor, Mingfang Hong, and Morgan Stefansson 156
An "Immunosensor" Based on Capillary Electrophoresis. Robert T. Kennedyand Li Tao 158
On-line Coupling of Microanalysis Sampling to Capillary Electrophoresis.
Craig E. Lunte. Barry Hogan, Simon Y. Zhou, and Susan M. Lunte 160
On-line Injection in Capillary Electrophoresis. Christine E. Evans 162
Towards Classification of Pseudo-stationary Phases in MEKC. Morteza G. Khaledi.
MarkD. Trone, Michael S. Leonard, Jefferson G. Bumgarner, and
Armel A. Agbodjan 164
High Performance Capillary Electophoresis-Laser Induced Fluorescence of Glycoside
Toxins. Ziad EI Rassi and Arron Karcher 166
Dispersion in Micellar Electrokinetic Chromatography: Revisiting a Somewhat
Neglected Problem Child. Lixin Yu, Troy Seals, and Joe M. Davis 168
On-line ITP-CZE: Preconcentration and Clean-up Aspects. Dusan Kaniansky.Jozef Marak, Marian Masar, Jan Lastinec, Jetse C. Reijenga, and
Francis I. Onuska 170
Isotachophoresis: Trials, Tribulations and Trends in Environmental Analysis.Francis I. Onuska. Dusan Kaniansky, Milton L. Lee, and Kenneth D. Onuska 172
Single-Isomer Charged Cyclodextrins for Enantiomer Separations by CE.
J. Bryan Vincent, Hong Cai, Thanh V. Nguyen, Dawn M. Kirby,Alex D. Sokolowski, Billy A. Williams, and Gyula Vigh 174
Studies of Interconverting Systems by Dynamic Capillary Electrophoresis.Wilfried A. Konig. Detlev H. Hochmuth, Christian Wolf, and Gerald Weseloh 176
Use of a Dual Linear Photodiode Array for Enhanced UV Detection of Peptidesand Proteins in CZE and 2D micro-LC-CZE. Thomas F. Hooker and
James W. Jorgenson 178
Analytical Extraction/Concentration
On-line Membrane Extraction Microtrap Gas Chromatography (OLMEM-GC)for Continuous Extraction/Analysis of Organics from Air and Water.
Somenath Mitra. Xuemei Guo, and Naihong Zhu 180
Analytical Extraction, A Determinant of Throughput and Precision. Barry Kaye.David A. Stopher, and Richard F. Venn 182
Theory and Practice of Membrane Extraction with a Sorbent Interface.
Tadeusz Gorecki. Janusz Pawliszyn, M. Yang, Y. Luo, and M. Adams 184
Solvent Extraction into a Single Microliter Drop. Frederick F. Cantwell and
Michael Jeannot 186
New Developments in On-line Solid-phase Extraction-Gas Chromatography:
Newly Designed SPE-to-GC Transfer System and Sensor Controlled
Parameter Optimization. Rene" J.J. Vreuls. Thomas Hankemeier, and
Udo A.Th. Brinkman 188
Trace Level Analysis of Contaminants in Water and Air Using Sorptive Enrichment
in Packed Dimethyl-silicone Traps. Hans-Gerd Janssen. Erik Baltussen,Pat Sandra, and Carel A. Cramers 190
Large Volume Injection and On-line Transfer in Capillary GC. Konrad Grob 192
Use of On-column Large Volume Injection for the Analysis of Semi-volatiles in Water.
Mark Schneider, Marisa Bonilla. and Harold M. McNair 194
Automated Solid-phase Microextraction. Ralf Eisert and Janusz Pawliszyn 196
SPME/Micro-LC for Drug Analysis in Human Fluids. Kiyokatsu Jinno. Masahiro
Taniguchi, Makiko Hayashida, and Yokichi Ohno 198
State-of-the-art in Accelerated Solvent Extraction (ASE). Bruce E. Richter,John L. Ezzell, Richard E. Carlson, and Eric S. Francis 200
Supercritical Fluid Extraction of Wood Pulp with Analysis by Capillary Gas
Chromatography-Mass Spectrometry. Lori H. McDaniel.
Mehdi Ashraf-Khorassani, and Larry T. Taylor 202
VT
POSTERS
Gas Chromatography (Hydrocarbons and Fossil Fuels)1 Standardization and Automatization of Simulated Distillation Methods for
Routine Analysis. J .P. Durand. A. Bre, J.J. Beboulene, A. Ducrozet, and
S. Carbonneaux 204
2 Simulated Distillation of Petroleum Products by Capillary Gas Chromatography:Influence of Analytical Parameters. A. Bre. J.P. Durand, S. Carbonneaux,
D. Gabriel, J.J. Beboulene, and A. Ducrozet 206
3 Two Minute GC Simulated Distillation Analysis of Gasoline Range Material UsingShort 100-/tm Diameter Capillary Columns. Vince Giarrocco 208
4 Tar Bases from Resins of Brazilian Coal Tar. P.J. Sanchez Filho and E.B. Caramao 210
5 GC/MS (SIM Mode) Applied to the Quantification of Alkyl Phenols in Coal Tar.
I. Nascimento F°, M.G.R. Vale, and E.B. Caramao 212
6 Comparison of Solvents Used for Extraction of PAHs and Organic Matter from
Flue Gas. Marianna Czaplicka and Krystyna Kubica 214
7 Comparison of GC/FID and HPLC Methods for Determination of PAHs in Coal
Derived Materials. Krystyna Kubica, Marianna Czaplicka. Krystyna Tyrpien,and Teresa Kordas 216
8 High Resolution Capillary Gas Chromatography Using Three Different StationaryPhases to Identify and Quantify Polycyclic Aromatic Sulfur Heterocycles(PASH) in Oil Samples. Stephanie G. Moessner and Stephen A. Wise 218
9 Reliable PIONA Analysis of Complex Hydrocarbon Mixtures Using Capillary GC
and PID/FDD Response Ratios. Olga V. Napalkova, Paul P. Vulikh,
Igor A. Revelsky. Yuri S. Yashin, Igor N. Glazkov, Boris I. Zirko, and
Igor V. Galakhov 220
Gas Chromatography (Unique Applications)10 Analysis of Fire Debris for Water Soluble Accelerants. Q. Ren and Wolfgang Bertsch ....
222
11 On-line Reaction Gas Chromatography on the Nanoscale. Wolfgang Bertsch and
T. Moore 224
12 On-line Derivatization of Short Chain Fatty Acids in Headspace GC. Yuwen Wang,Maha Khaled, and Harold M. McNair 226
13 Identification and Quantitation of Thermal Decomposition Products of a Novolac
Resin by Pyrolysis-Gas Chromatography-Mass Spectrometry. C.A. Lytle,
Wolfgang Bertsch. S. Liu, S. Zhang, and M. McKinley 228
14 Organic Residues Analysis by CGC-MS in Floor Samples from the Hall of the
Eagle Warriors, Temple Mayor, Mexico. Araceli Pena. Luz Lazos,
Santiago Capella, Luis Barba, and Carmen Labastida 230
15 Chromatographic Behaviour of Underivatized Lidocaine and Metabolites in CGC.
Mohamed Abdel-Rehim. Margareta Bielenstein, and Torbjorn Arvidsson 232
16 Design and Optimization of a Benchtop GC Analyzer for Measuring Oxygenated
Compounds in Propylene and 1,3-Butadiene. Jim Luong. Lyndon Sieben,
and Jaap de Zeeuw 234
17 The Virtual Chromatogram®. Del E. Moore 236
VII
18 The Measurement of Dissolved and Total Water Content in Advanced Turbine
Engine Fuels Using a Gas-Liquid Chromatographic OTC Technique.
Wayne A. Rubey. Richard C. Striebich, and Steven D. Anderson 238
Gas Chromatography (Environmental)19 Development of Analytical Tools for the Determination of Airborne and Waterborne
Marine Engine Exhaust Contaminants. Todd Vanyo, Darning Li,Richard Morrison, and Vincent T. Remcho 240
20 Analysis of Organics in Complex Wastewaters. Laell Racovalis. Malcolm D. Hobday,Albert W. Hoveling, and Steven Hodges 242
21 Analysis of Sulfur Compounds by Solid Adsorbent Tenax GR Preconcentration
and Gas Chromatography with Flameless Sulfur Chemiluminescence
Detection. Wen-Fa Sye and Mei-Fang Cheng 244
22 Screening of Water Samples for PCBs at the ppt-ppq Level Using Direct LargeWater Sample GC/MS Analysis. Alexander I. Revelsky, Yuri S. Yashin,
Igor A. Revelsky. and Boris I. Zirko 246
23 FTIR Investigation of Organic Discharge in Polluted Water: IV. Monitoring of
Some Oil Fuel. Adrian Jeley. Claudia Barbu, Marian F. Ciobanu, L. Frunza 248
24 Limited Congener-number PCB Standard for Quantitation with Gas
Chromatography and Ion Trap Mass Spectrometry. Jack W. Cochran 250
25 Pesticide Analysis with the PFPD and a Novel Extract-free Direct SampleIntroduction Device. Aviv Amirav and Hongwu Jing 252
Gas Chromatography (Column Technology)26 Testing Column Performance. Roy J.M.N. Dresen, Huub J.W. Henderickx, and
Sjoerd van der Wal 254
27 Comparison of Capillary Column Selectivity for the Analysis of Essential Oils.
Leonard M. Sidisky. Kathleen H. Kiefer, and Greg A. Baney 256
28 Optimizing PCB Separations Using Gas Chromatography/Mass Spectrometry with
Unique, Low-bleed Stationary Phase Columns. Jack W. Cochran and
Shawn L. Reese 258
29 New In-situ Prepared Adsorbent for PLOT Columns with an Operational
Temperature Range from Subambient to 490°C. Jaap de Zeeuw and
J. Buyten 260
30 Effect of Various Binary Gas Mixtures as Mobile Phases on Theoretical Plate
Number in Capillary Gas Chromatography. Daniel L. Vassilaros.
Frank K. Schweighardt, Karen Yang, Michael T. Combs, and Larry T. Taylor 262
31 Analysis of Volatile Components in Alcoholic Beverages Using a Highly Selective Polar
Stationary Phase Which Is Water Resistent. Jaap de Zeeuw and N. Vonk 264
32 New Low-bleed 100% Styrene-divinylbenzene Porous Polymer with a Temperature
Stability up to 290°C. P. Heynsdijk and Jaap de Zeeuw 26633 Sol-gel Technology for Coating and Deactivation of GC Columns with High
Thermal Stability. Dongxin Wang and Abdul Malik 268
VTTT
34 Comparison ofArylene-containing Polysiloxane Polymers with Their CorrespondingPure Polysiloxane Capillary GC Stationary Phases. Dennis R.Gere and
Alan D. Broske 270
35 BPX70-Using ECL Numbers to Unravel Fatty Acid Methyl Esters. Mark Cumbers and
T. Norris 272
36 Unique Selectivity of Carborane Modified Phases for the Analysis ofPesticides.
Mark Cumbers and Russell Kinghorn 274
37 Applications on a New, Thermally Stable, High Cyanopropyl Capillary GC Column.Robert T. Wiedemer. Joseph W. Walsh, andDennis H. Mowrer 276
38 Use of a PoraPLOT Q-HT (TM) PLOT Column for the Analysis ofVolatile and
Active Organic Compounds. Jim Luong. Lyndon Sieben, Terry Dahoy,and Jaap de Zeeuw 278
39 Chromatographic Properties of Novel Inorganic Stationary Phases. Darin Sanchez,James LansbarMs, Beth McCulloch, and Wayne Rathbun 280
40 Cyclodextrin Doped Cyanosilicone Capillary Columns. Leonard M. Sidisky.AlokKumar, and Greg Baney 282
41 New Column for Amine Analysis in Capillary Gas Chromatography. N. Lammers,J. Buijten, Jaap de Zeeuw. and F. Biermans 284
42 New Silica-based Adsorbentfor Analyzing Volatile Compounds. C. Duvekot,
Jaap de Zeeuw. B. Schmidt, R. Schmidt, M. Mohnke, andR. deNijs 28643 New Porous Polymer Q Type PLOT Columns: Low Bleed, ExcellentImmobilization
and Inertness. Zhengb.ua Ji and Steve Hurt 288
Gas Chromatography (Detection)44 Gas Chromatographic Characterization of a Pear Aroma with Parallel Sniffing/Fn),
Sniffing/PID and MS Detection. Rizzolo Anna. Cocucci Maurizia,Tagliabue Silvia,andPolesello Stefano 290
45 Use of F-685 nm Atomic Emission Spectroscopy with GC for the Analysis of
Fluorine-containing Derivatives of Carbonyls and Carboxylic Acids in
Environmental Samples. Christof C.E. Simons. Paul J. Clarkson.
MalcolmR. Clench, andMichael Cooke 292
46 Influence ofthe Optical Configuration upon the Chromatographic Signals Generated
by a Microwave Induced Plasma Detector. Larisse Montero, Fabio Augusto.Ana Claudia Lemes, and Antonio Luiz Pires Valente 294
47 Trace Analysis of Sulphur Compounds in Natural Gas Using Large Volume Inj ection,Selective Enrichment and Sensitive SCD-Detection. Mark van Lieshout
Pham Tuan Hai, Hans-Gerd Janssen, and Carel A. Cramers 296
48 Screening for More Than 400 Pesticides by GC/AED: Reaping the Benefits of
Retention Time Locking. Philip L. Wylie, Bruce D. Quimby, and
DonaldD.Nixon 298
49 Enhanced Sensitivity and Selectivity of a Gas Chromatography-Microwave Induced
Helium Plasma Atomic Emission Detection System (GC-MIP) at the 685.6 nm
Fluorine Emission Line. Fabio Augusto and Antonio Luis Pires Valente 300
50 Fragmentation ofthe Trimethyl Silyl Derivatives of Substituted Aromatic Acids in
the Ion Trap Detector: Quantitation Study. Ibolya Molnar-Perl and
Kornelia Hovath 302
51 GC Dedicated Plasma Mass Spectrometric Detection. Cato Brede. Elsa Lundanes,
Tyge Greibrokk, and Stig Pedersen-Bjergaard 304
52 Design and Performance of a New ECD for the HP 6890 Series GC. Matthew S. Klee.
Imogene Chang, and Mahmoud Abdel-Rahman 306
53 Characterization of Products from Chemical Degradation and Pyrolysis of Humic
Organic Material Using GC/MS and GC/AED. Juergen Poerschmann and
Frank-Dieter Kopinke 308
54 Chemical Characterization and Quantitative Determination of DNA Damage, Induced
by Free Radicals, in Human Tumor Tissue by Gas Chromatography-MassSpectrometry. Gunther Guetens. Karel Van Cauwenberghe,Ernst Arthur de Bruijn, and Alex A.M. Eggermont 310
55 New Approach to the P- and N-containing Pesticides Reliable Identification -
Multiditection with NPD, PID and FID. Paul P. Vulikh, Elena V. Gitelmakher,
Igor A. Revelsky. Yuri S. Yashin, Boris I. Zirko, and Igor V. Galakhov 312
56 Gas Analysis by Gas Chromatography and Atomic Emission Detection.
J. Andreas Lippert. Paul B. Farnsworth, Milton L. Lee, Mingin Wu,Cole L. Woolley, and Edgar D. Lee 314
57 Determination of Organometallic Compounds in Hydrocarbon Matrices by HighResolution Gas Chromatography/Atomic Emission Detection. Jim Luong.Jonathan Mason, Terry Dahoy, Aaron Eidt, and Jaap de Zeeuw 316
58 Application of a Multicapillary Column to the Estimation of Electron Capture
Response: Is the ECD Concentration Dependent or Mass-flow Dependent?Masahiro Takeuchi, Kazuko Mizuishi, and Toshiyuki Hobo 318
59 Determination of Sameridine in Blood Plasma and Tissues by Gas Chromatographywith Nitrogen-sensitive Detection. Par Neidenstrorrt, Torbjorn Arvidsson, andCarina Norsten-H66g 320
60 Determination of Part Per Billion Levels of Light Chlorinated Hydrocarbons in
Complex Hydrocarbon Matrices by Gas Chromatography/ElectrolyticConductivity Detection. Jim Luong. D. Thibodeau, Aaron Eidt, and
Jaap de Zeeuw 322
Gas Chromatography (Natural Products)61 Investigating the Changes in Terpene Concentrations in Some of the Poplar Clones
Which are Most Often Used in Afforestation Practice Through the CGC-MSMethod. Krassimir P. Naydenov. Z.A. Rafii, and R. Dodd 324
62 Monoterpene Composition on in vitro Cultivated Plantlets of Aleppo Pine
(JPinus halepensis Mill). Marco Michelozzi, M. Lambardi, R. Tognetti,and C. Boggi 326
63 HRGC-MS Analysis of Terpenoids from Maytenus Aquifolium Martius and
Maytenus Ilicifolia Martius (Espinheira Santa). Fernando M. Lancas.
P.J.M. Cordeiro, and J.H.Y. Vilegas 32864 Simultaneous Analysis of the Main Constituents of Honeys by GC/MS as Their
TMS(Oxime)Ether/Ester Derivatives. Korn61ia Horv&th and
Ibolva Molnar-Perl 330
X
65 GC-MS Analysis of 21 Fragrance Substances in Deodorants. Suresh C. Rastogi.J.D. Johansen, P. Frosch, T. Menne, M. Bruze, J,P. Leppoitevin,K.E. Andersen, and I. White 332
66 GC Enantioseparation of Food Additives. Yuri P. Belov and Alok Kumar 334
67 Stereochemical Studies ofPlant Volatiles by Enantioselective Capillary Gas
Chromatography. Martin Pietsch. Nils Bulow, Christiane Fricke,Stefan Jung, Stephanie Melching, Angela Rieck, Yucel Saritas, and
Kolja Wihstutz 336
68 Differentiation of Twelve Pine Species from Central Portugal by Monoterpene
Composition Analysis Using HS-SPME and HRGC. Eduardo P. Mateus.
Q. H. Zhang, M.H. Farrall, andM. Rosa Paiva 338
69 Determination of Nonpolar/Neutral Composition of a Wood Pine Medium
Density Fiber Factory Effluent by High Resolution Gas Chromatography-
Mass Spectrometry and FT-BR. Spectrometry. Eduardo P. Mateus.
F. Santana, and I. Domingos 340
70 Occurrence of Trans Unsaturated Fatty Acids in Heteropappus hispidus and Some
Other Compositae Seed Oils. N. Tsevegsuren. K. Aitzetmuller, L. Bruhl, and
Gisela Werner 342
71 Capillary GLC Study of y-Linolenic Acidin Youngia tenuicaulis (Compositae) Seed
Oil. Nanzad Tsevegsuren. Kurt Aitzetmuller, and Klaus Vosmann 344
Gas Chromatography (Retention Measurement/Mobile Phase Manipulation)72 Effect ofAtmospheric Pressure on Capillary Column Gas Chromatographic
Retention Times. JohnV.Hinshaw. P.E. Schallis, andN.R. Green 346
73 Retention Time Locking: A New Tool for Method Development in Gas
Chromatography. Bruce D. Quimby and Matthew S. Klee 348
74 Influence of Carrier Gas Nature and Pressure on the Retention of Organic
Compounds in Capillary GLC. Victor G. Berezkin. Alexander A. Korolev,
and Irina V. Malyukova 350
75 Report on ASTM E-19 Task Force Group Re-examining Retention Indices and
Capillary Column Polarity Protocols. Dennis R. Gere. Alan D. Broske,
Linda Green, andRobert Trengove 352
76 Retention Time Locking in Capillary Chromatography: The Next Giant Step in
Practical Chromatography. Leonid Blumberg andMatthewS.Klee 354
Gas Chromatography (High Speed)77 Fast GC: 100 Jim R) Capillary Columns Maximizing the Use ofHigh Linear
Velocity and Fast Temperature Programming. Dermis R. Gere.
Alan D. Broske, and Linda Green 356
78 Advantages of Computer Assisted Data Acquisition for High Speed Packed
Capillary Chromatography. Christopher R. Bowerbank. Yufeng Shen,
andMiltonL. Lee 358
79 Strategies Toward Increasing Sample Throughput Using GC/Time-of-flight/MS.
BenD. Gardner and John F. Holland 360
80 Rapid Analysis of Air Particulates by Pyrolysis-Gas Chromatography/Ion Mobility
Spectrometry. WilliamH. McClennen. Sidney N. Thornton,
Jacek P. Dworzanski, HenkL.C. Meuzelaar, and Neil S. Arnold 362
81 Fast Analyses in the Food Sciences by GC/TOFMS. Ritchard Parry. Nancy Brichford,
Viatcheslav B. Artaev, Joel Mitchell, Randy Beaudry, and Jun Song 364
82 Parallel-column Gas Chromatography Coupled with Mass Spectrometry and
Chemometrics. Robert E. Synovec. Bryan J. Prazen, and Bruce R. Kowalski 366
Gas Chromatography (On-line Preconcentration Techniques)83 On-column Gas Chromatographic Sample Storage System for the Monitoring of
Multi-component Time-dependent Profiles. Jean-Marie P. Dimandja. and
JohnB. Phillips 368
84 Development of a Novel Microtrap System. Yoshiyuki Takei and Mitsuhiro Kurano 370
85 On-lineVOC Monitoring of the Raw Water Intake to a Maj or Water Treatment
Works by Purge and Trap-HRGC-MS. Helen Eggleston, Ivan Jepson, and
Ian A. Fowlis 372
86 Determination of Terpenes in Water Samples by Headspace Gas
Chromatography and Membrane Inlet Mass Spectrometry. Marja Ojala.Raimo Ketola, Timo Mansikka, Tapio Kotiaho, and Risto Kostiainen 374
87 On-site Monitoring System for Volatile Hazardous Air Pollutants Using CapillaryColumn GC/MS. Tsuneaki Maeda. Kouji Ichioka, Kaoru Funaki,Satoshi Arakawa, YukaYasuki, and Aki Sakai 376
88 Analysis of VOCs in Air Using a Portable Micro Gas Chromatograph in
Conjunctionwith Preconcentration Techniques. Hai Pham Tuan.
Hans-Gerd Janssen, Carel A. Cramers, Pbillippe Mussche, Jurgen Lips,Nigel Wilson, and Alan Handley 378
89 Two Stage Trapping for Continuous On-line GC Monitoring with a Microtrap.Chaohua Feng and Somenath Mitra 380
90 On-line Solid-Phase Extraction-Gas Chromatography-Ion Trap Detection (MS and
MS/MS) for Determination and Identification of Pollutants at the ng/1 Level.
Rene J.J. Vreuls. Arjan J,H. Louter, Krishna Verma, and Udo A.Th. Brinkman 382
91 Automated On-line Coupled SPE-Capillary GC: Applications to Ground Water
Pollution Control. Adriano Trisciani, Fausto Munari, Pier Albino Colombo, and
Sorin Trestianu 384
92 Large Sample Volume Capillary GC and GC/MS for Trace Analysis: Flexible,Modular Automated Multi-injector System Suitable for Cold On-column
and PTV Injection Techniques. Paolo Magni, Fausto Munari. and
Sorin Trestianu 386
93 In-vial Extraction and Large Volume Sample Injection: A Powerful Alternative to
Conventional Sample Preparation Procedures for Ground Water Pollution
Control. Paolo Magni, Fausto Munari. and Sorin Trestianu 388
94 Practical Approaches to Large Volume Injection. Philip L, Wylie and
DonaldD.Nixon 390
YTT
95 Comparison of Different Types of Drinking Waters Using Direct Large
Sample Volume GC Analysis, Maxim G. Lazutin. Michail A. Kucherenko,
Igor A. Revelsky. Yuri S. Yashin, Boris I. Zirko, and IgorN. Glazkov 392
96 Fully Automated Field Analysis ofAtmospheric Hydrocarbons Using Peltier
Cooled PTV-GC. Alastair C. Lewis andKeith D. Bartle 394
Supercritical Fluid Chromatography97 Supercritical Fluid Chromatography/Fourier Transform Infrared Spectroscopy
of Commercial Conjugated Linoleic Acid. Elizabeth M. Calvey.Martin P. Yurawecz, and Magdi M. Mossoba 396
98 Progress in the Development of an Open-tubular SFC/MS Method for the
Determination ofEthoxylated Alcohols in Environmental Samples.
J.DavidPinkston and Claudia A. Smith 398
99 Automated Systems Based on Supercritical Fluids. Andrei Medvedovici, Pat Sandra.
andFrankDavid 400
100 Chiral Separations by Supercritical Fluid Chromatography. Pat Sandra.
Andrei Medvedovici, Laura Toribio, and Frank David 402
101 Advantages of Small Particles in SFC. Christopli Siffrin and Heinz Engelhardt 404
102 HPLC with Subcritical (Hot/Liquid) Water and FID Detection. David J. Miller
and StevenB. Hawthorne 406
103 Performance of Packed Capillary Column Chromatography Under Conditions
of Large Pressure Gradients and Phase Transformations. Yufeng Shen
andMiltonL. Lee 408
104 Comparison of Packed Capillary Solvating Gas Chromatography with SupercriticalFluid Chromatography. Naijun Wu. Yufeng Shen, and Milton L. Lee 410
105 Oxidative and Reductive Amperometric Detection of Phenols and Nitroaromatic
Compounds in Packed CapiUary Column SFC. Susanne R. Wallenborg.
KarinE. Markides, andLeifNyholm 412
106 Reversed-phase Liquid Chromatography with Flame Ionization Detection Using
Water as the Eluent. Robert J. Burgess and Roger M. Smith 414
107 Applicabilities ofLong Packed Capillary Columns in Chromatography.Iris Hunnes, Paal Molander, Cathrine Thomsen, Lai M.T. Nguyen,
Inge Bruheim, Lise Marken, Line Roed, Cato Brede, Roger Trones,
ElsaLundanes, and Tyge Greibrokk 416
Capillary Liquid Chromatography108 Optimization of the Use of Cyclodextrins in the Enantiomeric Separation of
Terpenes in Citrus by (i-LC and CE. Fernando M. Lancas. C.A. Diagone,
and C.A. Ogawa 418
109 Modification of Polytetrafluoroethylene (Teflon®) Particles for Chromatographic
Applications. Luis A. Colon. Rafael Alicea-Maldonado, and Joseph A. Gardella, Jr 420
110 Different Gradient Modes in Micro and Capillary HPLC. Fabrice Houdiere,
Patrick Fowler, and Djordjevic M. Nebojsa 422
111 Advantages of MicroLC Coupled to Mass Spectrometry. Pernilla Koivisto.
Benita Hyllbrant, Lena Nyholm, Per Sjoberg, and Karin E. Markides 424
112 Pump Technology for Ultra High Pressure Capillary Liquid Chromatography.
John E. MacNair and James W. Jorgenson 426
113 Fused Silica Capillary Columns Protected by a Flexible Housing. Bijan Modrek 428
114 Photo-alternative Stationary Phases for Semi-micro HPLC and Capillary LC.
Hideo Matsuoka, Tatsuro Nakaeama. and Toshiyuki Hobo 430
115 Pressure-induced Perturbations in Solute Complexation in Capillary Separations.Christine E. Evans and Moria C. Ringo 432
116 Microdialysis/SFE/SFC/FJD of Antioxidants and Related Compounds in Water.
F. Javier Setiorans. Ulrika Petersson, and Karin E. Markides 434
117 Comparison of Reversed-phase HPLC Separation Using Carbon Dioxide and
Fluoroform for Enhanced-fluidity Liquid Mobile Phases.
Huimin Yuan and Susan V. Olesik 436
118 Reversed-phase Microcolumn LC as an Effective Preconcentration Techniquefor MALDI/MS and NMR Studies ofDerivatized Oligosaccharides.P. ChenandM.V.Novotny 438
119 A Compact, Portable Capillary Ion Chromatograph: C. Brad Boring and
Purnendu K. Dasgupta 440
120 High Throughput, High Resolution Microcolumn LC/MS Separations for
Assessing Purity and Biological Activity of Combinatorial Libraries.
Daniel B. Kassel. Lu Zeng, Lyle Burton, and Kai Yung 442
121 Performance Testing of an Eluent-Jet Interface for the Coupling ofMicroflow
Liquid Chromatography with Electron Impact and Chemical Ionization
Mass Spectrometry. Rene J.J. Vreuls. Reijer J. Dijkstra, Ben L.M. van Baar,Charles E. Kientz, and Udo A.Th. Brinkman 444
122 Microelectrochemical Detector for Use at Low Linear Velocities in CapillaryColumn Systems. Susanne R. Wallenborg. Karin E. Markides, and
LeifNyholm 446
123 Controlling Extra-column Dispersion in Microbore and Capillary HPLC.
RichardLudwig andRichardHenry 448
124 Characteristics of High Temperature Micro Liquid Chromatography.Paal Molander. Roger Trones, and Tyge Greibrokk 450
Capillary Electrochromatography125 Analysis of Environmental Toxicants in Human Serum by Cloud-point Extraction
and Capillary Electrochromatography. Sarath R. Sirimarme. Li Ma, John Barr,and Donald G. Patterson, Jr 452
126 Enantiomeric Resolution of Dansyl Amino Acids by Capillary ElectrochromatographyUsing Molecularly Imprinted Polymers as Recognition Agents. Jin-Ming Lin,
Yunhua Gao, Tatsuro Nakagama, Katsumi Uchiyama, and Toshiyuki Hobo 454
127 Use of Step-gradient Capillary Electrochromatography (CEC) with CommerciallyAvailable Capillary Electrophoresis (CE) Instrumentation. Melvin R. Euerby.Declan Gilligan, Christopher M. Johnson, and Keith D. Bartle 456
128 Rapid Analysis Capillary Electrochromatography (CEC) Using the "Short-end
Injection" Capillary Electrophoresis (CE) Approach. Melvin R. Euerby.Christopher M. Johnson, Keith D. Bartle, Maria Cikalo, and Peter Myers 458
129 Capillary Electrochromatographic Performance of a New Mixed Mode (C18/SCX)
Stationary Phase. Melvin R. Euerby. Christopher M. Johnson, Helen Lomax,and Paul Ross 460
130 Evaluation ofthe Fundamental Properties of Capillaries Coated with Different
Ion-exchangers. Maria G. Cikalo. Keith D. Bartle, and Peter Myers 462
131 New Developments in Capillary Gel Electrochromatography for the Analysis of
Small Molecules. Chuzo Fujimoto. Masahito Sakurai, and Yutaka Fujise 464
132 Molecular Imprinted Stationary Phases for Capillary Electrokinetic
Chromatography. Zhixin Jessica Tan, Michael Cipoletti, andVincent T. Remcho 466
133 Transfer ofHPLC Methods and Applications to Capillary Electrochromatography
(CEC). Gordon Ross, Monika M. Dittmann. and GerardP. Rozing 468
134 Characterization of Stationary Phases for CEC. Frank T. Hafher. M. Scherer, and
H. Engelhardt 470
135 Design and Evaluation of a NewCEC System. Baomin Xin. Samuel E. Tolley,andMiltonL.Lee 472
136 Macroporous Polyacrylamide/Polyethylene Glycol Matrices as Stationary Phases
for Capillary Electrochromatography. Anders Palm andMilos V. Novotny 474
Capillary Electrophoresis (Detection)137 Photodiode Array for Multi-point (Spatial) UV Absorption Detection in Capillary
Electrophoresis. Karen A. Burton, Thomas F. Hooker, ChristopherT. Culbertson, and James W. Jorgenson 476
138 Analysis of Chlorinated Phenoxyalkyl Acid Herbicides in Water Using Capillary
Electrophoresis/Negative Electrospray/Mass Spectrometry. Xinbei Song and
William L. Budde 478
139 Acquisition System Requirements for Micro Separations Time-of-flight Mass
Spectrometry. AlanL. Rockwood, Edgar P. Lee. Jacqueline P. Fabbi,
Joseph C.H. Sin, Larry Davis, Metin Gunsay, Logan Harris, Chad Ogden,Hal Tolley, and Harold G. Lee 480
140 CE-TOFMS for the Analysis of Paraquat and DiquatHerbicides. IuliaM.Lazar
andMiltonL. Lee 482
Capillary Electrophoresis (Biomacromolecules)141 Diastereomeric and Enantiomeric Separation ofPeptides Containing Aspartic
or Glutamic Acid by Capillary Electrophoresis: Application to StabilityStudies. Gerhard K.E. Scriba. Sigrid Zimmermann, and Samir Sabah 484
142 High-speed High-resolution Separation of DNA Fragments by Capillary
Electrophoresis in Cellulose Derivative Polymer Solutions. LineRoed,
Elsa Lundanes, and Tyge Greibrokk 486
143 DNA Analysis by Electrophoresis Microchip Device. Larry C. Waters, JuliaKhandurina.
N. Kroutchinina, R.S. Foote, Stephen C. Jacobson, and J. Michael Ramsey 488
144 Capillary Electrophoresis of Plasmids and Linear Nucleic Acids in Dilute PolymerSolutions. Richard W. Hammond, Jeffrey J. Schwinefus, Shau-Chun Wang, and
Michael D. Morris 490
145 High Resolution Separation of DNA Restriction Fragments Using Capillary
Electrophoresis with Near-infrared Laser-induced Fluorescence Detection.
S.Kar. S.M. Ford, C.V. Owens, Y.Y. Davidson, and S.A. Soper 492146 Sensitive Analysis of [D-PEN^JEnkephalin in Rat Serum with Capillary
Electrophoresis and Laser-induced Fluorescence Detection. Cuiping Chen.
Dorothea Jeffery, James W. Jorgenson, M. Arthur Moseley, and
GaryM. Pollack 494
147 DNA Base-pair Mismatch Detection Using Mismatch Repair Enzyme Cleavageand Capillary Electrophoresis. Barbara A. Siles. David L. Tung,G. Bruce Collier, Christopher LP. Lovelace, and Martin L. Smith 496
148 In-line Coupling of the Enzymatic Degradation of Oligonucleotides with Capillaryolymer Sieving Electrophoresis. Jan Saevels, Ann Van Schepdael,
Eugene Roets, and Jos Hoogmartens 498
149 Electrochromatographic Contributions in Capillary Electrophoresis of Biomolecules.Xiaowen Shao. Yufeng Shen, Kim O'Neill, and Milton L. Lee 500
150 Analysis ofthe Protein Matrix ofHubridoma Cell Culture by SDS-GEL CapillaryElectrophoresis. VadimE. Klyushnichenko, Holger Heine, Manfred Biselli, and
Maria-Regina Kula 502
151 Separation ofHyaluronate Oligomers through End-label Free Solution Electrophoresis.Mingfang Hong and Milos V. Novotny 504
Capillary Electrophoresis (Unique Applications)152 Separation and Analysis ofBacterial Cells and Cell Constituents by Capillary
Electrophoresis. Roy MA. Lautamo and David T. Mao 506
153 A Method of Analysis ofRecombinant Acidic Fibroblast Growth Factor (aFGF)by Capillary Electrophoresis. Thomas P. Roddy. Thomas E. Molnar,Robert E. McKean, and Joe P. Foley 508
154 Capillary Electrophoresis Applied to PhysicochemicalMeasurements in Pharmaceutical
Analysis. Jinping Liu. Charlene La, Kevin J. Volk, Sadia Abid, andMike S. Lee 510
155 Ultra High Voltage Capillary Zone Electrophoresis. Katariina M. Hutterer and
James W. Jorgenson 512156 Capillary Electrophoretic Techniques for Drug Analysis in Human Fluids.
Kiyokatsu Jinno. Yinghong Han, Hirokazu Sawada, Makiko Hayashida,and Yokichi Ohno 514
157 Capillary Electrophoretic Performance of Sol-gel Columns with SupercriticalDrying. James D. Hayes and Abdul Malik 516
158 Nonaqueous Capillary Electrophoresis. Morteza G. Khaledi. Joseph L. Miller,Fang Wang, Wei Zhou, and Vicki B. Ward 518
159 pH-Mediated Stacking of High Ionic Strength Samples for Capillary Electrophoresis.Sangyroul Park, Yeping Zhao, and Craig E. Lunte 520
160 Capillary Electrophoresis of Chiral Pyrethroid Insecticides. Ziad El Rassj and
Arron Karcher 522
161 Determination of Melphalan and its Hydrolysis Products in Perfusion Samplesof Cancer Patients by CE. Gert de Boeck, Karel van Cauwenberghe,Alexander A.M. Eggermont, Ernst A. de Bruijn, and Allan T. van Oosterom 524
162 Determination of Nitrophenols by Isotachophoresis and Capillary Zone
Electrophoresis. Francis I. Onuska. Dusan Kaniansky, and Jozef Marak 526
163 Determination of a Glutathione Adduct of Atrazine by SPE and CapillaryElectrophoresis. Massimo Rossi, Luana Dragani, Vinicio Sperandio,Rita Frassanito, and Domenico Rotilio 528
164 Dynamic Channel Electrophoresis. Jonathan V. Sweedler and Yi-Ming Liu 530
165 Migration Markers for Capillary Isotachophoretic Separation of Ribonucleotides.
Shujun Chen and Milton L. Lee 532
166 Determination of Morphine in Human Hair Using Isotachophoresis and CapillaryZone Electrophoresis. Kenneth D. Onuska and Milton L. Lee 534
167 Polypropylene Hollow Fibers Modified by PMMA for Capillary Electrophoresis.Shize Qi and Milton L. Lee 536
168 Plastic Microfluidic Devices Prepared by Imprinting Techniques. Laurie E. Locascio.
Larisa Martynova, Michael Gaitan, William A. MacCrehan, Gary W. Kramer,and Richard G. Christensen 538
169 Discrimination of Foam Concretes from Gas Concretes by Capillary Electrophoresis.Heili Siren and Jari Pukkila 540
Capillary Electrophoresis and Chromatography (Fundamental/Modeling)170 Calculation of Predicted Migration Rates in Capillary Electrophoresis from
Molecular Structure. Roger M. Smith. Andrew G. McKillop, Ray C. Rowe,
and Stephen A.C. Wren 542
171 Estimation of the Variance in Electrophoretic Mobility by Measuring the Peak
Width and Asymmetry on Time Domain Electropherograms.Brian S. Weekley. Joe P. Foley, and Greg Mclntire 544
172 Computer Simulation of Capillary Zone Electrophoresis and Micellar Electrokinetic
Chromatography. Arthur B. Coddington and Joe P. Foley 546
173 Mathematical Modeling and Optimization of Electroinjection Analysis and
Electrophoretically Mediated Microanalysis. Victor P. Andreev.
E.V. Lebedeva, and N.S. Pliss 548
174 Explanation for Success of New Statistical Models of Overlap with Poorly Resolved
Separations. Joe M. Davis 550
175 Modeling Concealment in Microcolumn Separations. H. Dennis Tolley,Steven J. Butala. and Milton L. Lee 552
Micellar Electrokinetic Capillary Chromatography and Chiral CE
176 Micellar Electrokinetic Chromatography (MEKC) of S-Triazine Herbicides.
Fernando M. Lancas and M.A. Ruggiero 554
177 Evaluation of Methacrylate Copolymers as Pseudo-stationary Phases for
Electrokinetic Chromatography. Christopher P. Palmer 556
178 Influence of the Inorganic Counterion on the Chiral Micellar Electrokinetic
Separation of Basic Drugs Using the Surfactant N-Dodecoxycarbonyvaline.Alicia G. Peterson and Joe P. Foley 558
179 Comparison of the Retention Behavior of Beta-blockers and Octanol-water
Partition Coefficient Estimation Using Immobilized Artificial Membrane
Chromatography and Lysophospholipid Micellar Eletrokinetic
Chromatography. John A. Masucci. Gary W. Caldwell, and Joe P. Foley 560180 Micellar Capillary Electrophoresis (MCE) Use for Determination of Biocides
in Paper Food Packaging Materials. Shirley Abrantes, Mark Philo,Andrew P. Damant. and Laurence Castle 562
181 Chiral CE with Crown Ethers. Katleen Verleysen and Pat Sandra 564182 On-line Micellar Electrokinetic Chromatography-Electrospray Ionization Mass
Spectrometry for Protein Characterization. Cheng S. Lee and Liyu Yang 566183 Urate and Ascorbate Levels in Premature Infants' Lung Lavage. Qirtglin Tang. Hai
Wang, Thomas T.-S. Huang, William L. Stone, Des Bharti, and Milton L. Lee....
568184 Evaluation of Micelle Modifiers for use in Micellar Electrokinetic Capillary
Chromatography. Kent P. Demon. William E. Wall and Joel T. Smith 570185 Enantiomeric Separations of Isoflavonoids from Legumes Using Capillary
Electrophoresis. Darin J. Allen. Joel T. Smith, William E. Wall, Kent D. Densonand Nancy Paiva 572
186 Investigation of Electrokinetic Chromatography Using Thermodynamically-stableVesicles and Mixed Micelles Formed from Oppositely Charged Surfactants.Mei Hong and Joe P. Foley 574
Micromachining in Microcolumn Separations187 Microfabricated Devices for Enzyme Assays. Andrew G. Hadd. Stephen C. Jacobson and
J. Michael Ramsey 576188 Confocal Single Molecule Detection on Microchips. Julius C. Fister III, Stephen C.
Jacobson, and J, Michael Ramsey 578189 Microfabricated, Recycling Electrochemical Detector for Capillary Separations.
Sunday A. Brooks and Robert T. Kennedy 580
Multidimensional
190 Comprehensive LC/LC/MS of E. coli Lysates to Separate, Identify, and Characterize
a Protein of Pharmaceutical Interest for Further Characterization. Suzanne M.Ramirez. Gregory J. Opiteck, James W. Jorgenson, M. Arthur Moseley III, andRobert J. Anderegg 582
191 Microbore LC/LC/MS for Peptide Mapping and Sequencing. Gregory J. Opiteck.Suzanne M. Ramirez, James W. Jorgenson, M. Arthur Moseley III, and Robert J.
Anderegg 584192 Development of a Novel 2D Microcolumn RPLC-CZE-LIF Assay for [D-
PEN2,5]enkephalin in Rat Serum. Dorothea J. Jeffery and James W. Jorgenson ....
586193 Multidimensional GC-ECD System for the Analysis of CB Marker Congeners.
Russell Kinghorn. Tim Anastasopoulos, Phillip Marriott, and Mark Cumbers 588
XVTTT
194 LC Optimization in the On-line Coupling of LC to GC-ECD. G. Rene van der Hoff.
Ronald Hoogerbrugge, Robert A, Baumann, and Piet van Zoonen 590
195 On-line Clean-up of Soil Samples Prior to GC Analysis. G. Rene van der Hoff.
Peter Kaim, Robert A. Baumann, and Piet van Zoonen 592
196 RPLC-GC with the Vaporizer/Precolumn Solvent Split/Gas Discharge Interface; On¬
line LC-GC-MS Analysis of Phthalates in Water. Tuulia Hyotylainen, Konrad
Grob, Maurus Biedermann, and Marja-Liisa Riekkola 594
197 Statistical Theory of Overlap for Chromatographic Heartcutting. Matthew Peters and
Joe M. Davis 596
198 Multidimensional Capillary GC-GC System for the Analysis of Real Complex Samples.LuigiMondello, Maurizio Catalfamo, Paola Dugo, and
Giovanni Dugo 598
199 Characterization of Petroleum-based Fuels Using Comprehensive Two-dimensional Gas
Chromatography. Richard B. Gaines. Wayne R. Gronlund, and
Glenn S. Frysinger 600
200 Making Quantitative Measurements with Comprehensive Two-dimensional Gas
Chromatography. John B. Phillips and Yang Pan 602
Solid Phase Extraction
201 GC Analysis of Low Volatile Compounds Traces in Water and Air Using Sorbents
with Low Specific Area and Thermodesorption. Irina V. Nesterova, Igor A.
Revelsky. Yuri S. Yashin, Boris I. Zirko, and Maxim G. Lazutin 604
202 Use of Styrene-Divinyl Benzene Copolymer Based Solid Phase Extraction Cartridgesfor General Purpose Air Sampling. Paul J. Clarkson. Malcolm R. Clench, and
Michael Cooke 606
203 Selectivity of Functionalized Silica Solid Phase Extraction Cartridges in Air Sampling.Paul J. Clarkson. Malcolm R. Clench, and Michael Cooke 608
204 Enhanced Recovery of Chlorophenols from Surface Waters Using Polymer Based
Extraction Cartridges. Ricarda Schilling, Paul J. Clarkson. and
Michael Cooke 610
205 GC/MS Determination of Xenobiotics in Fruit Brandy. Zdenek Weidenhoffer and Ivana
Rouckova 612
206 Trace Analysis of Antineoplastic Drugs in Urine of Hospital Pharmacy Technicians
with HRGC/MS. Karlheinz Hauff. Inge Sautter, Gertrud Koethe-Schmolin, and
Angelika Pethran 614
207 Application of On-line SAMOS-HPLC Systems for the Determination of Organic
Compounds in River Water. Ian A. Fowlis. Ivan Jepson, and
Rene J. J. Vreuls 616
208 Separation and Analysis of Produced Formation Water Components. Courtney P.
Milner. Robert D. Trengove, and Iva Stejskal 618
209 Improvement of an SPE Procedure for Analysis of Chlorophenols in Pulp Bleaching
Effluent. Tania Mara. Pissolatto. Patricia Schossler, and
Elina Bastos Caramao 620
Solid Phase Microextraction
210 Application of Solid-phase Microextraction for the Analysis of Pesticides. Ralf Eisert,
Janusz Pawliszyn, and Karsten Levsen 622
211 Automation of On-line SPME Coupled to HPLC. Ralf Eisert and Janusz Pawliszyn 624
212 Advances in Automated Solid Phase Microextraction (SPME). John R. Berg 626
213 Field Portable Fast GC System with Solid Phase Microextraction Interface. Tadeusz
Gorecki. Perry Martos, and Janusz Pawliszyn 628
214 Sample Volume in Solid Phase Microextraction (SPME). Tadeusz Gorecki and Janusz
Pawliszyn 630
215 Strategies for the Analysis of Selected Polar Compounds in Water by SPME. Tadeusz
Gorecki. Perry Martos, and Janusz Pawliszyn 632
216 Determination of Tetraethyllead, Inorganic Lead and Ionic Organolead Compounds in
Water by Solid Phase Microextraction/Gas Chromatography. Tadeusz Gorecki.
Haodan Yuan, and Janusz Pawliszyn 634
217 Solid Phase Microextraction (SPME): Use of SPME for the Determination of Residual
Solvents in Pharmaceutical Drug Substances. Pam Cafiero. Ann-Marie Smith,and Stephen Scypinski 636
218 Determination of Tributyltin and Triphenyltin Compounds in Sediment as Halides bySPME and GC/NICI-MS. Kazuko Mizuishi. Masahiro Takeuchi, and ToshiyukiHobo 638
219 Analysis of Anabolic Steroids from Human Urine and Serum by SPME with On-fiber
Derivatization and GC/MS. Nicholas H. Snow and Pius Okeyo 640
220 Determination of Muscat-type Aroma Additives for Wines Using SPME Head-spaceSampling and CGC Analysis. Gyorgy Vas, A. Lialios, J. Harangi,A. Dobo, and K. V6key 642
221 Determination and Comparison of Volatile Aroma Compounds and Organic Acid
Composition of Various Grape Berries from Eger (Hungary) Using SPME-CGC Technique and HPLC-DAD Analysis. Gyorgy Vas. P. Kozma,J. Harangi, A. Dob6, and K. Vekey 644
222 Solid Phase Microextraction of Flavor Components in Wines. Paola Dugo,Luigi Mondello, and Giovanni Dugo 646
223 Sol-gel Technology for Thermally Stable Coatings in Solid-phase Microextraction.
Sau L. Chong. Brian Wilhite, and Abdul Malik 648
Supercritical and Enhanced Liquid Extraction
224 Optimization of the Experimental Parameters for the Supercritical C02 Extraction ofDicofol Residues from Fish Samples. Fernando M. Lancas. M.S. Galhiane, S.R.
Rissato, and M.A. Barbirato 650225 Determination of PCBs in Water on ppt-ppq Level Using Direct SFE and Whole
Extract Analysis by GC/ECD. Igor N. Glazkov, Igor A. Revelsky. Yuri S.
Yashin, Igor P. Efimov, Boris I. Zirko, and Yuri A. Zolotov 652226 Extraction of Polymer Additives from Polymers by Accelerated Solvent Extraction.
David E. Knowles and Jody Clark 654227 Determination of Fat in Foods Using Accelerated Solvent Extraction (ASE).
Eric S. Francis. David E. Knowles, and Bruce E. Richter 656
YX
228 Understanding the Basis of Analytical Extractions Through the Use of ConceptMapping. Douglas E. Raynie and Richard P. Gregory, IV 658
229 Evaluation of Fluazinan Residue from Fruit Crops by HRGC-ECD. Fernando M.
Lancas. M.A. Barbirato, M.S. Galhiane, and S.R. Rissato 660
230 Comparison of Liquid Extraction and Supercritical Fluid Extraction for the Analysisof Gestagens in Samples of Bovine Fat. Alida A.M. Stolker. Paulus W. Zoontjes,Leendert A. van Ginkel, and Robert J. Maxwell 662
231 Comparison of SFE, Soxhlet and Sonification Methods for the Extraction of OrganicMaterial in Mineral Coal. Maria G.R. Vale. Luiza P. Luz, Ayrton F. Martins,ElinaB. Caramao. Claudio Dariva, and Jose V. de Oliveira 664
232 Subcritical Water Extraction of Organic Pollutants. Yu Yang, Arnaud Lagadec, Maya
Belghazi, David J. Miller, and Steven B. Hawthorne 666
233 Coupled Subcritical Water Extraction/SPME Determination of Organic Pollutants
from Environmental Solids. Kimberly J. Hageman, Carol B. Grabanski, David J.
Miller, and Steven B. Hawthorne 668
234 Extraction of Polar Pollutants Using Enhanced-fluidity Liquids. Susan V. Olesik.
Huimin Yuan, Tricia S. Reighard, and Michael Shows 670
235 Evaluation of Pressurized Fluid Extraction for Use in the Certification of
Environmental Matrix Reference Materials. Michele M. Schantz and Stephen A.
Wise 672
236 Extraction of Polychlorinated Dibenzo-p-Dioxins and Polychlorinated Dibenzo-furans
from Environmental Samples Using Accelerated Solvent Extraction (ASE).
Bruce E. Richter. J.L. Ezzell, D.E. Knowles, F. Hoefler, A.K.R. Mattulat, M.
Scheutwinkel, D.S. Waddell, T. Gobran, and V. Khurana 674
237 On-line SFE-bioassay with MECC of Uterotonically-active Fractions from Medicinal
Plants. Vikash Sewram, Mark W. Raynor. Deshandra M. Raidoo, and Dulcie.A.
Mulholland 676
Novel Extraction/Concentration Techniques238 Membrane Extraction with a Sorbent Interface (MESI): An Efficient and Fast Method
of Clean-up of the Hollow Silicone Membrane. Eduardo Carasek da Rocha,
Fabio Augusto. and Antonio Luis Pires Valente 678
239 Solvent Double-extraction for Sample Clean-up and Preconcentration in a Microliter
Drop System. Minimi Ma and Frederick F. Cantwell 680
240 Synthesis and Use of Molecular Imprints as an Extraction Technique. Richard F. Venn,
Robin Goody, and Barry Kaye 682
241 In-vial Extraction Combined with Large-volume On-column Injection-GC-MS for the
Determination of Anilines in Aqueous Samples at the Low ng/L Level. Ren£
J.J. Vreuls. Edwin Romijn, Thomas Hankemeier, and Udo A.Th. Brinkman 684
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