Download - ChemInform Abstract: Generation of Allylic Manganates from Trimethylmanganate and Allylic Stannanes and Their Reactions with Epoxides.

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Page 1: ChemInform Abstract: Generation of Allylic Manganates from Trimethylmanganate and Allylic Stannanes and Their Reactions with Epoxides.

1998 reactions of organo-metal compounds

reactions of organo-metal compoundsO 0350

15 - 057Generation of Allylic Manganates from Trimethylmanganate andAllylic Stannanes and Their Reactions with Epoxides. — Allylicmanganates, prepared in situ by transmetallation of allylstannanes withtrimethylmanganate, react with epoxides, epoxy alcohols, and alkyl halidesto give allylated products. — (TANG, J.; YORIMITSU, H.; KAKIYA, H.;INOUE, R.; SHINOKUBO, H.; OSHIMA, K.; Tetrahedron Lett. 38 (1997) 52,9019-9022; Dep. Mater. Chem., Fac. Sci., Kyoto Univ., Sakyo, Kyoto 606,Japan; EN)

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Page 2: ChemInform Abstract: Generation of Allylic Manganates from Trimethylmanganate and Allylic Stannanes and Their Reactions with Epoxides.

1998 reactions of organo-metal compounds

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