ADVANCED CLEANING RODUCT FORMULATIONS
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ADVANCED
CLEANING
PRODUCT
FOR M U LATl ONS Volume 5
Ernest W. Flick
NOYES PUBLICATIONS WILLIAM ANDREW PUBLISHING, LLC
Nomich, New York, U.S.A.
Copyright 0 1999 by Ernest W. Flick No part of this book may be reproduced or utilized in any form or by any means, electronic or mechanical, including photocopying, recording or by any informa- tion storage and retrieval system, without permission in writing from the Publisher.
Library of Congress Catalog Card Number: 89-30274
Printed in the United States ISBN: 0-8155-1431-X
Published in the United States of America by Noyes Publications/William Andrew Publishing, LLC 13 Faton Avenue, Norwich, New York 13815
10 9 8 7 6 5 4 3 2
Library of Congress Cataloging-in-Publication Data (Revised for vol. 5)
Flick, Ernest W. Advanced cleaning product formulations
Includes bibliographical references and index. 1. Cleaning compounds. I. Title
TP990.F56 1989 668'1 89-30274 ISBN 0-8155-1186-8 (v. 1) ISBN 0-8155-1346-1 (v. 2) ISBN 0-8155-1382-1 (v. 3) ISBN 0-8155-1396-8 (v. 4) ISBN 0-8155-1431-X (v. 5)
To
the late Ernie and Jeanne
and
Allyn and Barbara
and
Chris and Rachel
V
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reface
ohme 5) presents more than 423 up-to-date advanced cleaning product formulations for household, industrial and automotive applications. It is the result of information received from numerous industrial companies and other organizations. The data represent selections made at no cost to, nor influence from, the makers or distributors of these materials. Only the most recent formulas have been included. All formulations are completely different than those contained in Volumes 1, 2, 3 and 4 published earlier.
~ ~ ~ ~ ~ a ~ ~ o ~ in the cleaning product industry has gradually been undergoing significant change during the past years. Raw materials costs have risen and manufacturers have been reluctant to pass along these increases. Environmental considerations have also played a part. By changing formulations to improve cost/performance characteristics, manufacturers have been able to control costs but still enhance performance. This book presents manufacturers' suggested formulations which might meet new performance criteria.
The formulations in this book are divided into the following sections and chapters, with the number of formulations indicated in ( ):
H. Household and Industrial Cleaners and Polishes 1. Bathroom Cleaners (9) 2. 3. Degreasers (9) 4. Dishwashing Detergents (34) 5. General Purpose Cleaners (31) 6. Glass CleanersPoiishes (12)
8. Laundry Products (55) 9. 10. Oven, Grill and Hot Plate Cleaners (9) 11. Polishes, Coatings and Finishes (6) 12. Rinse Aids (2) 13. Rug, Floor, Carpet, Upholstery Shampoos and Cleaners (33) 14. Miscellaneous (33)
Dairy, Food and General Industrial Cleaners (27)
ard Surface Cleaners (21)
Metal Cleaners and Polishes (72)
vii
viii Preface
11. Transportation Cleaners and Polishes 15. 16. 17. Whitewall Tire Cleaners (3) 18. Miscellaneous (12)
Auto Cleaners and Polishes (6) Car and Truck Wash Compounds (49)
Each formula is located in the chapter which is most applicable. The reader, seeking a formula for a specific end use, should check each chapter which could possibly apply. In addition to the above, there are two other sections which will be helpful to the reader.
111. A chemical trademark section where each tradenamed raw material included in the book is listed with a chemical description rand the supplier's name. The specifications which each raw material meets are included, if applicable.
IV. Main office addresses of the suppliers of trademarked raw materials.
Each formulation in the book lists the following information, as available, in the manufacturer's own words:
Description of end use and most outstanding properties.
The percent by weight or volume of each raw material included in the formula, rounded to a decimal figure.
Key properties of the formula, which are the features that the source considers to be more outstanding than other formulations of the same type.
The formula source, which is the company or organization that supplied the formula. The secondary source may be the originating company andlor the primary source's publication title, or both. A formula number is included, if applicable.
The table of contents is organized in such a way as to serve as a subject index.
My fullest appreciation is expressed to the companies and organizations who supplied the original starting formulations included in this book. I also thank the suppliers of the raw materials included in these formulations, who furnished information describing their trademarked raw materials.
Newburyport, Massachusetts July 1999
Ernest W. Flick
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NOTICE
To the best of our knowledge the information in this publication is accurate; however, the Publisher does not assume any responsibility or liability for the accuracy or completeness of, or consequences arising from, such information. This book is intended for informational purposes only. Mention of trade names or commercial products does not constitute endorsement or recommendation for use by the Publisher. Final determination of the suitability of any information or product for use contemplated by any user. We recommend that anyone intending to rely on any recommendation of materials QB
procedures mentioned in this publication should satisfy himself as to such suitability, and that he can meet all applicable safety and health standards.
X
ntents and Subject Index
SECTION I
CLEANERS AND POLISHES OUSEHOLD AND INDUSTRIAL
B OM CLEANERS: . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2 Toilet Bowl Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3
athroom Cleaner with Disinfectant . . . . . . . . . . . . . . . . . . . . . . . 4 Heavy Duty Acid Bathroom Cleaner . . . . . . . . . . . . . . . . . . . . . . . 4 Mildew Remover . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5 ~ o w ~ ~ ~ l d e w Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5 Tile Porcelain and Bathroom Cleaner. Acid . . . . . . . . . . . . . . . . . . 6 Tub and Tile Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6 Hypochlorite Tub and Tile Cleaner and Mildew Stain Remover . . . 6 Toilet Bowl Cleaner with Bleach . . . . . . . . . . . . . . . . . . . . . . . . . 7
2. . FOOD AND GENERAL INDUSTRIAL CLEANERS . . . . . 8
Oxalic Acid Gel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9 ust Removal Jelly . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9
Acid Industrial and Household Cleaners
Cleaners for Industrial Application Desinfecting Cleaner. Acid . . . . . . . . . . . . . . . . . . . . . . . . . . 10 Dipping Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10 Spray Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10
sphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11 uced Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . 11
Zero phosphate. powder . . . . . . . . . . . . . . . . . . . . . . . . . . . . 12 Baking Pan Cleaner
phosphate. powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 12 Heavy Duty Cleaners
BBll Purpose-Food Process Plant . . . . . . . . . . . . . . . . . . . . . . 13 Hard Surface Spray Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13
Destainer
xi
xii Contents and Subject Index
High Foaming Alkaline Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . 14 Heavy Duty Alkaline Degreaser . . . . . . . . . . . . . . . . . . . . . . . . . 44 Steam Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 14
Cleaner, Strongly Alkaline . . . . . . . . . . . . . . . . . . . . . . . . . . 15 Cleaner. Weakly Alkaline . . . . . . . . . . . . . . . . . . . . . . . . . . . 15 Cleaner. Strongly Alkaline (Phosphate-Free) Cleaner. Weakly Alkaline (Phosphate-Free) . . . . . . . . . . . . . . 45
(Liquid) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 16
(Liquid) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 16
(Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 17 (Zero Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . 17
Economy Presoak . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 18 Premium Presoak . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 18 Enzyme Prespotter for Oily/Smutty Soils . . . . . . . . . . . . . . . . IS
(Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 19
(Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 19
Industrial and High Pressure Cleaners
. . . . . . . . . . . . . 15
Metal Cleaner
Food Industry Cleaner
Milk Can Cleaner
Powdered Enzyme Presoaks
Sanitizing Cleaner
Sanitizing Agent
3 . DEGREASERS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 20 Aqueous Degreaser . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 21
d-Limonene Microemulsion . . . . . . . . . . . . . . . . . . . . . . . . . 21 Water Based Degreaser . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 21
Degreaser Concentrate (Liquid) . . . . . . . . . . . . . . . . . . . . . . . . . 22 Metal De-Oiling Liquid Concentrate (Liquid) . . . . . . . . . . . . . . . 22 Solvent Degreaser . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 23 Solvent Based Degreaser . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 24 Engine Cleaner and Degreaser . . . . . . . . . . . . . . . . . . . . . . . . . . 24
Aqueous Degreaser
4 . DISHWASHING DETERGENTS . . . . . . . . . . . . . . . . . . . . . . . . . 25
(Zero Phosphate. Chlorine Free. Powder) . . . . . . . . . . . . . . . . 26
(Phosphate. Chlorine Free. Powder) . . . . . . . . . . . . . . . . . . . . 26
(Phosphate. Solid Block . . . . . . . . . . . . . . . . . . . . . . . . . . . . 27
Automatic Dishwash Detergent-Consumer
Automatic Dishwash Detergent-Consumer
Automatic Dishwash Detergent-Industrial & Institutional
Automatic Dishwashing Detergent-Industrial & Institutional (Liquid~7
Contents and Subject Index xiii
Automatic Dishwash Detergent-Industrial & Institutional (Zero.Phosphate. Chlorine Free. Powder) . . . . . . . . . . . . . . . . 28
Automatic Dishwash Detergent-Industrial & Institutional (Phosphate. Chlorine Free. Powder) . . . . . . . . . . . . . . . . . . . . 28
Automatic Dishwashing Gel with Chlorine Bleach . . . . . . . . . . . . 29 Clear. Colorless Manual Dish Wash . . . . . . . . . . . . . . . . . . . . . . 30 Powder Stainless Silverware Pre-Soak . . . . . . . . . . . . . . . . . . . . 30 Low Alkaline Warewashing Block . . . . . . . . . . . . . . . . . . . . . . . 30 Dish Washing Agents . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 31
sh w/Amine Oxide/LABS/SLES . . . . . . . . . . . . . . . . . . . 33 Dish Wash w l h i n e Oxide/LABS/ALES . . . . . . . . . . . . . . . . . . 33 Hand Dishwashing Liquid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 33 Foam Booster: E-14-5 in Hand Dishwashing Liquids
Economy Formulation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 34 Standard Formulation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 34 90% Premium Formulation . . . . . . . . . . . . . . . . . . . . . . . . . . 34 Rernium Formulation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 34
Hand Dish Detergent Formulations Clear Dishwash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 35
Pearlescent Dishwash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 35 Hand Dishwashing Liquid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 36 Rand Dishwashing Paste . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 37 Light Duty Liquid. Premium Hand Dishwash . . . . . . . . . . . . . . . 38 Light Duty Liquid Low Cost Hand Dishwash . . . . . . . . . . . . . . . 38 Liquid Automatic Dishwasher Detergent . . . . . . . . . . . . . . . . . . . 39 Manual Dishwashing Gel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 40 Manual Dishwashing Liquid . . . . . . . . . . . . . . . . . . . . . . . . . . . . 41 Now-Chlorinated Machine Dishwashing Compound. Liquid . . . . . 42 Chlorinated Machine Dishwashing Compound. Powder . . . . . . . . 42 Non-Chlorinated Machine Dishwashing Compound. Powder . . . . 42 Premium Hand Dishwashing Detergent . . . . . . . . . . . . . . . . . . . . 43 Dish Washing Agents for Manual Use . . . . . . . . . . . . . . . . . . . . 43
5 . GEN LEANERS . . . . . . . . . . . . . . . . . . . . . . . 44 Abrasive Cleaner with Bleach . . . . . . . . . . . . . . . . . . . . . . . . . . 45
rasive Cleaner Without Bleach . . . . . . . . . . . . . . . . . . . . . . . . 46 Purpose Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 47
All Purpose Cleaner - No Rinse . . . . . . . . . . . . . . . . . . . . . . . . . 48 AB1-Purpose Disinfectant Cleaner . . . . . . . . . . . . . . . . . . . . . . . . 49 All Purpose Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 49 &alp Purpose Cleaner w/Amide/€’hosphate Ester . . . . . . . . . . . . . . 50 A1 Purpose Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 50
xiv Contents and Subject Index
All Purpose Cleaner Concentrate (Phosphate. Liquid. Foam . . . . . . . . . . . . . . . . . . . . . . . . . . . 51
All Purpose Concentrate
Calcium Carbonate Abrasive Cleaner Without Bleach . . . . . . . . . 52 Citric Acid Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 53
(Phosphate. Liquid) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5%
General Purpose Cleaner
General Purpose Cleaner (Consumer Low Alkaline. Non-Phosphate Powder) . . . . . . . . 54
(Consumer High Alkaline. Non-Phosphated Powder) . . . . . . . 54 General Purpose Spray & Wipe Cleaner . . . . . . . . . . . . . . . . . . . 55 General Purpose Spray & Wipe . . . . . . . . . . . . . . . . . . . . . . . . . 56 All Purpose Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 56 Hypochlorite Vertical Surface Cleaner . . . . . . . . . . . . . . . . . . . . 57 Pump Spray All Purpose Cleaner . . . . . . . . . . . . . . . . . . . . . . . . 57 Liquid Cleanser with Bleach . . . . . . . . . . . . . . . . . . . . . . . . . . . 58 All Purpose Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 58 Pine Oil Cleaner Concentrate . . . . . . . . . . . . . . . . . . . . . . . . . . . 59 Disinfecting Cleaner. Alkaline . . . . . . . . . . . . . . . . . . . . . . . . . . 59 Sodium Bicarbonate Abrasive Cleaner Without Bleach . . . . . . . . 60
6 . GLASS CLEANERS/POLISHES . . . . . . . . . . . . . . . . . . . . . . . . . . 61 Anti.Fogging. Anti-Static Glass Cleaner . . . . . . . . . . . . . . . . . . 62 Glass Cleaner. Ready to Use . . . . . . . . . . . . . . . . . . . . . . . . . . . 62 Glass Cleaner Concentrate (Non-Ammoniated) . . . . . . . . . . . . . . 63 Glass Cleaner Concentrate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 63 Ammoniated Glass Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . 63 Glass and Window Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . 64 Household Window Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . 65 Premium Household Window Cleaner . . . . . . . . . . . . . . . . . . . . . 65 Glass Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 65 Windows/Glass
Glass Cleaner (Concentrate) . . . . . . . . . . . . . . . . . . . . . . . . . 66 Windshield Washer Concentrate . . . . . . . . . . . . . . . . . . . . . . . . . 66 Windshield Washer Concentrate (Low VOC) . . . . . . . . . . . . . . . . 66
7 . HARD SURFACE CLEANERS . . . . . . . . . . . . . . . . . . . . . . . . . . . 67 Alkaline Hard Surface Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . 58 Hard Surface Cleaner Concentrate (All Purpose Type) . . . . . . . . . 68 Concentrated Hard Surface Cleaner . . . . . . . . . . . . . . . . . . . . . . 69 Hard Surface Cleaner-Spray . . . . . . . . . . . . . . . . . . . . . . . . . . . 69 Pine Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 69 Hard Surface Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 70
Contents and Subject Index xv
Bard Surface Cleaner w/Amphoteric . . . . . . . . . . . . . . . . . . . . . . 71 Hard Surface Cleaner Concentrate w/d’Limonene . . . . . . . . . . . . . 71 Bard Surface Cleaner Concentrate (Phosphate. Liquid) . . . . . . . . . 72 Hard Surface Spray Cleaner (Phosphate. Liquid) . . . . . . . . . . . . . 72 Hard Surface Cleaner Concentrate wmipentene . . . . . . . . . . . . . . 73 Alkaline Hard Surface Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . 73 Liquid Abrasive Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 74 Tile and Sanitary Cleaners . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 74 Liquid Hard Surface Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . 74 Hard Surface Cleaner-All Purpose . . . . . . . . . . . . . . . . . . . . . . . 75
old and Mildew Remover . . . . . . . . . . . . . . . . . . . . . . . . . . . . 76
PRODUCTS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 77 gent for Fine Fabrics-1 . . . . . . . . . . . . . . . . . . . . . . . . . . . 78
Detergent for Fine Fabrics-2 . . . . . . . . . . . . . . . . . . . . . . . . . . . 78 Heavy Duty Laundry . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 79 1 h 1 Liquid Laundry Detergent with Enzyme & Optical . . . . . . . 80
Powder for Automatic Dishwashing Machines . . . . . . . . . . . . . . . 80 . . . . . . . . . . . . . . . . . . . . 81
Industrial Laundry Detergents
Surfactant Rich Detergent for Nursing Homes . . . . . . . . . . . . . . . 80
dustrial Heavy Duty Laundry Liquid
High Caustic Formulation . . . . . . . . . . . . . . . . . . . . . . . . . . . 82
Laundry Detergent-Consumer (Liquid) . . . . . . . . . . . . . . . . . . . . 83
Mixed Builder Formulation . . . . . . . . . . . . . . . . . . . . . . . . . . 82 Washing Paste with Bleaching Agent . . . . . . . . . . . . . . . . . . . . . 82
Laundry Detergent-Consumer
Laundry Detergent-Consumer
Laundry Detergent-Consumer
bundry Break-Industrial & Institutional
Laundry Break-Industrial & Institutional
Laundry Detergent-Industrial & Institutional
Laundry Break-Industrial & Institutional
Laundry Detergent-Industrial & Institutional
Laundry Detergent-Industrial & Institutional
(Zeolite Built. Zero Phosphate. Liquid) . . . . . . . . . . . . . . . . . 83
(Zero Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . 84
phosphate. Powder) ............................... 84
(Liquid. Phosphate) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 85
(Liquid) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 85
(NTAJZeolite. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 86
(Zero Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . 86
(Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 87
(Sodium Carbonate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . 87
mi Contents and Subject Index
Laundry Break-Industrial & Institutional
Laundry Break-Industrial & Institutional
Laundry Detergent-Industrial & Institutional
Laundry Detergent-Industrial & Institutional
Laundry Detergent-Industrial & Institutional
Laundry Detergant-Industrial & Institutional
Laundry Detergent-Industrial and Institutional
Laundry Detergent-Industrial and Institutional
Laundry Detergent-Industrial & Institutional
Laundry Detergent-Industrial & Institutional
Laundry Builder-Industrial & Institutional
Laundry Detergent-Industrial & Institutional . . . . . . . . . . . . . . . . . 93
Laundry Prespotter Sprayable Gel . . . . . . . . . . . . . . . . . . . . . . . . 94 Laundry Prespotter Sprayable Liquid . . . . . . . . . . . . . . . . . . . . . 95 Light Duty Liquid Detergent . . . . . . . . . . . . . . . . . . . . . . . . . . . 96
Calsoft LAS-99 Based . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 98 Dry Cleaner: Pre Spot-Water Soluble . . . . . . . . . . . . . . . . . . . . . 99 Wool Wash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 99 Two Part Industrial Laundry Detergents
Break Formulations Highly Alkaline Break . . . . . . . . . . . . . 5100 Mixed Builder Break . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 100 Detergent Additive . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 100
Ultra Liquid Laundry Detergent . . . . . . . . . . . . . . . . . . . . . . . . 101 Fine Fabric Wash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1641
phosphate. Powder. High Alkalinity)
(Zero Phosphate Powder. High Alkalinity . . . . . . . . . . . . . . . . 88
. . . . . . . . . . . . . . . . . . 88
(Reduced Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . 89
(NTA, Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 89
(Sodium Carbonate with Flow Aid. Powder) . . . . . . . . . . . . . . 90
(Phosphate. Solid Block) . . . . . . . . . . . . . . . . . . . . . . . . . . . . 964
(Zero Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . 91
(Zero Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . 911
(Phosphate Built. Liquid) . . . . . . . . . . . . . . . . . . . . . . . . . . . 92
(Liquid) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 92
(Liquid) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 93
(Zeolite Built. Zero Phosphate. Liquid)
9 . METAL CLEANERS AND POLISHES . . . . . . . . . . . . . . . . . . . 802 Acid Metal Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . p03
Dipping Cleaner for Silver . . . . . . . . . . . . . . . . . . . . . . . . . . . . 103 Aluminum CleanerBrightener . . . . . . . . . . . . . . . . . . . . . . . . . 104 Powdered Metal Cleaning Concentrate . . . . . . . . . . . . . . . . . . . 104 Aluminum Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1104
Contents and Subject Index xvii
Aluminum Cleaner Concentrate F-498 . . . . . . . . . . . . . . . . . . . 105 Aluminum Wash F-499 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 105
ffing Compound Remover . . . . . . . . . . . . . . . . . . . . . . . . . . 106 t Alkaline Paint Stripper Concentrate . . . . . . . . . . . . . . . . . . 106
Metal De-Oiling Liquid Concentrate (Liquid) . . . . . . . . . . . . . . 106 Cutting Oil . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 107 Semi-synthetic Cutting Oil . . . . . . . . . . . . . . . . . . . . . . . . . . . 109 Cutting Oil Concentrate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 109 General Purpose Machine Cleaner . . . . . . . . . . . . . . . . . . . . . . 110 Aircraft Cleaner Type IV . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 110 General Purpose Synthetic Fluid (A) . . . . . . . . . . . . . . . . . . . . . 111 General Purpose Synthetic Fluid (€3) . . . . . . . . . . . . . . . . . . . . . 111 Copper Machining Fluid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 111 General Purpose Synthetic Fluid (C) . . . . . . . . . . . . . . . . . . . . . 112 General Purpose Synthetic Fluid @) . . . . . . . . . . . . . . . . . . . . . 112 Metal Cleaner
(Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 113 Aluminum Cleaner
phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 113
phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 114 (Zero Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . 115
Non-Phosphorous Aluminum Cleaner . . . . . . . . . . . . . . . . . . . . 116 Alkaline Aluminum Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . 116 Semi Synthetic . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 117 Silver and Metal Polish . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 119 Soluble Oil . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 120 Soluble Oil Machining Fluid . . . . . . . . . . . . . . . . . . . . . . . . . . 122 Synthetic Machining Fluid . . . . . . . . . . . . . . . . . . . . . . . . . . . . 122 Synthetic . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 123 Synthetic DrawindStamping Fluid . . . . . . . . . . . . . . . . . . . . . . 124 Oil Based DrawindStamping Fluid . . . . . . . . . . . . . . . . . . . . . . 124 Spray Metal Cleaning Concentrate . . . . . . . . . . . . . . . . . . . . . . 124 Synthetic Formula . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 125 Synthetic Formulation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 130 Universal Scouring Paste . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 133 Aluminum Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 133 Water Soluble Stamping Fluid . . . . . . . . . . . . . . . . . . . . . . . . . 134
-40 Type Lubricant Concentrate . . . . . . . . . . . . . . . . . . . . 134 Penetrating Oil . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 134 Burnishing Compound . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 134
eta1 Cleaner
xviii Contents and Subject Index
10 . OVEN. GRILL AND HOT PLATE CLEANERS . . . . . . . . . . . 135 Caustic Oven Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 136 Non-Caustic Oven Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . B36 High Caustic Oven Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . 137 Oven Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 138 Aerosol Oven Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 138 Oven Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 139 Heavy Duty Oven Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . 139 Oven Cleaner w/Amphoteric . . . . . . . . . . . . . . . . . . . . . . . . . . 140 Oven Cleaner wphosphate . . . . . . . . . . . . . . . . . . . . . . . . . . . . 140
11 . POLISHES. COATINGS AND FINISHES . . . . . . . . . . . . . . . . 141 Furniture Polish . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 142 LeatherPlastic Polish . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 143 Marble Polish . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 144 Rust Removing Polish . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 144 Scratched Wood Polish . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 145 High Gloss. Detergent Resistant Polish . . . . . . . . . . . . . . . . . . . 145
12 . RINSE AIDS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.46 Rinse Aid. Acid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 147 Rinse Aid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 147
13 . RUG. FLOOR, CARPET. UPHOLSTERY SHAMPOOS AND CLEANERS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . n48
Carpet Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 149 Low Foam Carpet Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . 149 Steam Rug Cleaner-A . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 149 Steam Rug Cleaner-B . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 149 Carpet Cleaners for the Spray-Extraction Process . . . . . . . . . . . 150 Carpet Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 150
(Phosphate. Liquid) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1151 Rug Steam Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 151 Carpet Shampoo. High Foam . . . . . . . . . . . . . . . . . . . . . . . . . . 152 Carpet Spot Remover . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1152 Carpet & Upholstery Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . 153 Vinyl Dressing (B) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 153 Carpet & Upholstery Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . 154 Liquid Steam Carpet Cleaner For Hard Water Systems . . . . . . . 154 Floor Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 155 Liquid Floor Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 155 Heavy-Duty Floor Scrubber . . . . . . . . . . . . . . . . . . . . . . . . . . . 155 Household Carpet Freshenedhtistat . . . . . . . . . . . . . . . . . . . . 156
Contents and Subject Index xix
Pump Spray Carpet Antistat . . . . . . . . . . . . . . . . . . . . . . . . . . . Liquid Leather. Vinyl. and Plastic Cleaner and Restorer . . . . . . . Liquid Leather. Vinyl. and Plastic Cleaner . . . . . . . . . . . . . . . . 157 Low Cost Extraction Carpet Cleaner . . . . . . . . . . . . . . . . . . . . .
156 157
158 Premium. Medium Duty Steam Extraction Carpet Cleaner . . . . . 158
uty Steam Extraction Carpet Cleaner . . . . . . . . . . . . . . 158 aming Carpet Extractor Detergent . . . . . . . . . . . . . . . . . 159
No Rinse Floor Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 160 Heavy Duty Floor Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . 160 No-Rinse Floor Cleaner Degreaser ...................... 160 Wax Stripper (A) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 161
ax Stripper (B) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 161 Concentrated Wax Stripper . . . . . . . . . . . . . . . . . . . . . . . . . . . 161
m Cleaner (Liquid) . . . . . . . . . . . . . . . . . . . . . . . . . . 159
CEELANEQUS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 162 acteriostatic Concentrate w/Pine Oil . . . . . . . . . . . . . . . . . . . . 163
General Disinfectant Solution . . . . . . . . . . . . . . . . . . . . . . . . . . 163 Hospital Disinfectant . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 163 Cutting Oil Concentrate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 164 Cutting Oil . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 164 Concrete Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 164 White Wall Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 164 d ' lhonene Waterless Hand Cleaner . . . . . . . . . . . . . . . . . . . . . 165 Paste Nand Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 165 Dipentene Microemulsion Formulations
-alkaline Formulations . . . . . . . . . . . . . . . . . . . . . . . . . 166 line Formulations . . . . . . . . . . . . . . . . . . . . . . . . . . . . 167
Emsol D-110 Formulations . . . . . . . . . . . . . . . . . . . . . . . . 168 Isopar M Formulations . . . . . . . . . . . . . . . . . . . . . . . . . . . . 169
h w Viscosity Silicone Emulsion Using Pemulen Resins . . . . . . 170 Luminizing Pet conditioner . . . . . . . . . . . . . . . . . . . . . . . . . . . 171 Pea Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 171
iao-Emulsions with d-Limonene . . . . . . . . . . . . . . . . . . . . . 172 Micro-Emulsions with Pine Oil . . . . . . . . . . . . . . . . . . . . . . . . 173 Plastic Bottle Wash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 174 Bottle Wash Formulations
w Foam . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 174 oderate Foam . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 174
Concentrated Formula . . . . . . . . . . . . . . . . . . . . . . . . . . . . 175 176
Hydrocarbon Solvent Microemulsions
Terpene Microemulsions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 175
Wax Emulsion Using Pemulen Resins . . . . . . . . . . . . . . . . . . . .
xx Contents and Subject Index
SECTION 11 TRANSPORATION CLEANERSl
AND POLISHES
15 . AUTO CLEANERS AND POLISHES . . . . . . . . . . . . . . . . . . . . 11’9’8 Chrome Polish . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 179 Liquid Car Polish . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 180 Liquid Spray Cleaner for Aluminum Trucks . . . . . . . . . . . . . . . 181 Aluminum Cleanermrightener . . . . . . . . . . . . . . . . . . . . . . . . . 181 Non-Phosphorous Aluminum Cleaner . . . . . . . . . . . . . . . . . . . . 1181 Mild Abrasive Automobile Polish . . . . . . . . . . . . . . . . . . . . . . . 182
16 . CAR AND TRUCK WASH COMPOUN S . . . . . . . . . . . . . . . . %83
Automobile Car Wash Concentrate . . . . . . . . . . . . . . . . . . . . . . 184 Car Shampoo Concentrate . . . . . . . . . . . . . . . . . . . . . . . . . . . . 184
Car Wash (Calsoft LAS-99-Based) . . . . . . . . . . . . . . . . . . . . . 185 Car Wash (Calsuds A-Based) . . . . . . . . . . . . . . . . . . . . . . . . . 185 Car Wash (Calsoft T-60-Based) . . . . . . . . . . . . . . . . . . . . . . . 185
Paste Car Wash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 186 Car Wash w/Amphoteric . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 187 Windshield Washer Concentrate . . . . . . . . . . . . . . . . . . . . . . . . 187 Windshield Washer Formulation . . . . . . . . . . . . . . . . . . . . . . . . 187 Car Wash Concentrate w/Alcohol Ethoxylate . . . . . . . . . . . . . . 133 Car and Truck Wash Formula . . . . . . . . . . . . . . . . . . . . . . . . . 189 Car Wash powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 189 Car Wash (Calsuds A-Based) . . . . . . . . . . . . . . . . . . . . . . . . . 189
Car Shampoo with Water-Repellent Effect . . . . . . . . . . . . . 190 Rinse-off Agent (Water Repellent) . . . . . . . . . . . . . . . . . . . 190
Windshield-Cleaner (Summer) . . . . . . . . . . . . . . . . . . . . . . 190 Windshield-Cleaner (Winter) . . . . . . . . . . . . . . . . . . . . . . . 19B Insect Remover . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 191 Wheel Cleaner, Alkaline . . . . . . . . . . . . . . . . . . . . . . . . . . . 191 Tar Remover . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 191
Car Wax . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 192 Auto Wipe & Shine Polish . . . . . . . . . . . . . . . . . . . . . . . . . . . . 192 Concentrated Traffic Film Removers . . . . . . . . . . . . . . . . . . . . 193 Foamy Brush Car Wash, Liquid . . . . . . . . . . . . . . . . . . . . . . . . 194 Low Cost Car Wash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 194 General Purpose Car Wash . . . . . . . . . . . . . . . . . . . . . . . . . . . 195 Liquid Car Wash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 195
CarWash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 186
Car Wash and Care
Rinse-off Agent (Water-Repellent) Without Hydrocarbons . ~ 190
Contents and Subject Index xxi
Boat Wash & Car Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . 195 Heavy Duty Truck Wash. Liquid . . . . . . . . . . . . . . . . . . . . . . . 196 Heavy Duty Truck Wash. Powder . . . . . . . . . . . . . . . . . . . . . . . 196 Premium Car Wash Concentrate . . . . . . . . . . . . . . . . . . . . . . . . 197 Car Wash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 197 Auto Shampoo Concentrate . . . . . . . . . . . . . . . . . . . . . . . . . . . 197 Touchless Vehicle Wash Detergent
(Zero Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . 198 Vehicle Wash Detergent (Low pH)
(Zero Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . 198 Tmck/Bus Wash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 199 Economy Tnuck/Bus Wash . . . . . . . . . . . . . . . . . . . . . . . . . . . . 199 Car Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 199 Car Wash and Wax Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . .
(Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 200 (Liquid. low foam) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 200
(Zero Phosphate. Liquid) . . . . . . . . . . . . . . . . . . . . . . . . . . 201
(Zero Phosphate. Liquid) . . . . . . . . . . . . . . . . . . . . . . . . . . 201
199 Vehicle Wash Detergent
Vehicle Wash Detergent (Low pH)
Touchless Vehicle Wash Booster/Additive
ITEWALL TIRE CLEANERS . . . . . . . . . . . . . . . . . . . . . . 202
(Zero Phosphate Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . 203 phosphate Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 203 (Liquid) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 203
Mitewall Tire Cleaner
n SCEEUNEOUS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 204
(Reduced Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . 205 (Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 205
Auto Care: Hnterior/Exterior Rubber & Vinyl Protectant
Concrete CIeanerDegreaser . . . . . . . . . . . . . . . . . . . . . . . . . . . 208 Garage Floor Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 208 Acid Rust Remover . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 208 ConcreteDriveway Cleaners
For Other Stains . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 209 Heavy Duty Concrete Cleaner (Phosphate Free) Formula 1C . . . 209 Vinyl Dressing . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 210
ressing (A) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 210
Aircraft Cleaner
. . . . . . . 206 Boat Polish . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 207
xxii Contents and Subject Index
SECTION III: TRADEMARKED RAW MATE s . . . . . . . . . . . 2nn
SECTION IV: SUPPLIERS' ADDRESSES . . . . . . . . a . . . . . . ~ . . . ~ 229
ection I Household and Industrial
Cleaners and Polishes
1
1. Bathroom Cleaner
a
Bathroom Cleaners 3
A c i d i c Toilet Bowl Cleaner
Carbopol r e s i n s a r e used t o t h i c k e n t h i s a c i d i c t o i l e t bowl c leaner f o r m u l a t i o n . I n a d d i t i o n , t h e use o f t h e r e s i n p rov ides v e r t i c a l c l i n g t o inc rease t h e con tac t t i m e o f t h e de tergent on t h e s o i l e d su r face and enhance consumer convenience.
I n s r e d i e n t : DI Water Carbopol 674 ( 1 ) C i t r i c Ac id (50%) A l k y l benzene s u l f o n i c a c i d Sodi um dodecyl d i pheny lox i de
Brookf i e l d v i scos i t y (RVT Product pH: 1 .O-2.0 Product C l a r i t y : C lear
( 1 ) BFGoodrich
5 43.00
2 . 0 0 50.00
97%) ( 2 ) 2.00 d i s u l f ona te (45%) ( 3 ) 3.00
20 rpm): 4,000 cps
i2j Stepan Co.: B i o s o f t 5-100 ( 3 ) Dow Chemical Co.: Dowfax 2A1
Procedure: 1 . Mix t h e D I water and c i t r i c a c i d s o l u t i o n toge the r . 2. Using moderate a g i t a t i o n (800 rpm) prov ided by a L i g h t n i n '
M ixer o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e f o r general m ix ing and b lend ing opera t ions , d i spe rse o r screen t h e Carbopol r e s i n i n t o t h e w a t e r / c i t r i c a c i d sol- u t i o n . Mix t h e s l u r r y f o r approx imate ly 30 minutes. The produc t w i l l become i n c r e a s i n g l y t h i c k e r w i t h t i m e - hea t ing t o 40-50C w i l l hasten t h e process.
s u r f a c t a n t .
room temperature.
3 . Add t h e s u l f o n i c a c i d and t h e d ipheny lox ide d i s u l f o n a t e
4 . Add c o l o r and f ragrance, as des i red . Cool t h e produc t t o
To ta l Ac t i ves : C i t r i c a c i d : 25.00 A l k y l benzene s u l f o n i c ac id : 1.94 Dodecyl d ipheny lox ide d i s u l f o n a t e : 1.35
SOURCE: BFGoodrich S p e c i a l t y Chemicals: DET-351
4 Advanced Cleaning Product Formulatioris
Bathroom Cleaner with Disinfectant
Inqredi ents: A: Veegum T, Magnesium Aluminum Silicate
Rhodopol 23, Xanthan Gum Deionized Water
B: Diatomaceous Earth (Super Floss) Tetrasodium EDTA (Hampene 100) Sodium o-Phenylphenate (Dowicide A) Sodi um A1 kyl benzene Sul fonate (Cal soft L-40) Butyl Cellosolve
Wt .%* 1 .oo 0.35 86.65
5.00 2.75 0.25 3.00 1 .oo
Procedure: 1 . Dry blend the Veegum T and Rhodopol 23 and add them to the
water while stirring with an homogenizer at 5000 rpm. Continue mixing for 30 minutes.
each for 5 minutes. * A s received basis
2. Slowly add the Part 8 ingredients in the order shown, mixing
SOURCE: R.T. Vanderbilt Co., Inc.: Formulation No. 363
Heavy Duty Acid Bathroom Cleaner
Inqredi ents: Hydroxyacetic acid Sulfamic acid Ammonyx LO Water, D.I.
Wt% 5.0 5.0 10.0 80.0
Mixing Procedure:
homogeneous.
Properties:
Add ingredients to water in the order given and mix until
Appearance: Clear liquid pH, as is: 1.0 Solids, %: 1 4 . 0 Density, lbs/gal: 8.7
Use Instructions:
or polished aluminum. Use gloves. Do not mix with bleach.
Storage Stability:
Use as is o r dilute as needed. Do not use on natural marble
Formulation is freeze/thaw stable through 3 cycles. Formulation is stable for 3 weeks @ 50C.
SOURCE: Stepan Co.: Formulation No. 200
Bathroom Cleaners 5
M i 1 dew Remover
I n g r e d i e n t s : Van Gel 0 D e i o n i z e d Water Sodium Hydrox ide , 50% S o l u t i o n Sodium H y p o c h l o r i t e , 10% S o l u t i o n (Hypure N ) Vanseal NALS-30
Wt%* 3 .00
85 .55 0 . 4 5
10 .00 1 . o o
P rocedure : 4 . S l o w l y s p r i n k l e t h e Van Gel 0 i n t o w a t e r a t room t e m p e r a t u r e
w h i l e m i x i n g w i t h a homogenizer o r d i s p e n s e r o p e r a t i n g a t 5000 rpm. C o n t i n u e m i x i n g f o r 40 m i n u t e s .
Slow t h e m i x e r t o 1000 rpm o r l e s s .
u n i f o r m .
2 . Add sodium h y d r o x i d e and m ix u n t i l u n i f o r m l y d i s s o l v e d .
3 . Add t h e Vanseal NALS-30. A v o i d a i r en t rapmen t . M ix u n t i l
F o r m u l a t i o n No. 458
Bowl /Mi 1 dew C1 eaner
I n g r e d i e n t s : A : Veegum T , Magnesium Aluminum S i l i c a t e
Te t rasod ium Pyrophosphate (TSPP) Water
8 : Sodium H y p o c h l o r i t e , 5 .25% Sodium M e t a s i l i c a t e , Anhydrous
5 . 0 0 0 . 2 5
50 .75
34.00 10 .00
P rocedure : 1 . D ry b l e n d t h e Veegum T and TSPP. S l o w l y add t h e w a t e r w h i l e
2 . Add P a r t B i n g r e d i e n t s s l o w l y i n t h e o r d e r shown, m i x i n g
F o r m u l a t i o n No. 424
a g i t a t i n g a t maximum a v a i l a b l e s h e a r . C o n t i n u e u n t i l smooth.
a f t e r each a d d i t i o n u n t i l smooth and u n i f o r m .
*As r e c e i v e d b a s i s
SOURCE: R.T. V a n d e r b i l t Co. , I n c . : Suggested F o r m u l a t i o n s
6 Advanced Cleaning Product Formulations
T i l e , P o r c e l a i n and Bathroom C leaner , A c i d
I n g r e d i e n t s : Water , D . I . 75 .5 Xanthan Gum 0 . 5 P e t r o BAF Powder 2 . 0 Phosphor i c Ac id , 75% 1 2 . 0 H y d r o x y a c e t i c A c i d , 70% 1 0 . 0 Perfume, Dye q .s . B l e n d i n g Procedure:
t o m ix u n t i l m a t e r i a l t h i c k e n s . Add r e m a i n i n g i n g r e d i e n t s i n o r d e r l i s t e d . I f p rob lems deve lop a d d i n g Xanthan Gum t o w a t e r , p remix t h e Xanthan Gum i n some i s o p r o p a n o l b e f o r e a d d i n g t o w a t e r .
Add Xanthan Gum s l o w l y t o w a t e r w i t h h i g h speed m i x i n g . A l l o w
Formula 529
Tub and T i l e C leaner
I n g r e d i e n t : Water , D . I . 6 7 . 4 Phosphor i c A c i d , 86% 17.6 H y d r o c h l o r i c A c i d , 37% 1 3 . 5 Rewote r i c AM TEG 0 . 5 V a r o n i c T202 SR 1 . o B l e n d i n g P rocedure :
each a d d i t i o n . T y p i c a l P r o p e r t i es:
V i s c o s i t y , cps : 293 S o l i d s : 16.3% pH: 1 . 7
Add i n g r e d i e n t s i n o r d e r shown and d i s s o l v e c o m p l e t e l y between
Formula 530
H y p o c h l o r i t e Tub and T i l e C leaner and M i l * S t a i n R e m o z
I n g r e d i e n t s : Water, D . I . 4 4 . 9 Sodium H y d r o x i d e (30%) 1 . o Varox 365 1 . 5 Sodi urn H y p o c h l o r i t e (5 .7%) 5 2 . 6 B l e n d i n g P rocedure :
each add i t i on. T y p i c a l P r o p e r t i e s :
V i s c o s i t y , c p s : 4 S o l i d s : 3.8% pH: 13 .5
Formula 531
SOURCE: W i t c o C o r p . : Suggested F o r m u l a t i o n s
Add i n g r e d i e n t s i n o r d e r shown and d i s s o l v e c o m p l e t e l y between
Bathroom Cleaners 7
T o i l e t Bowl C leaner w i t h B l e a c h
Carbopol r e s i n s a r e used t o t h i c k e n t h i s t o i l e t bowl w i t h c h l o r i n e b l e a c h f o r m u l a t i o n . I n a d d i t i o n , t h e use o f t h e r e s i n p r o v i d e s v e r t i c a l c l i n g t o i n c r e a s e d e t e r g e n t on t h e s o i l e d s u r f a c e and
t h e c o n t a c t t i m e o f t h e enhance consumer convenience.
I nq r e d i-w D I Water Carbopol 676 ( 1 ) P o t a s s i um h y d r o x i d e (45%) 2 . l r Potass ium s i l i c a t e (39%) ( 2 ) Potass ium c a r b o n a t e Sodium h y p o c h l o r i t e (12.50%) Amine Oxide (30%) ( 3 )
B r o o k f i e l d v i s c o s i t y (RVT-20rpm) : 2,500 cps P roduc t pH: 12-13 P roduc t c l a r i t y : Opaque
( 1 ) BFGoodri ch ( 2 ) PQ Corp. ( 3 ) Lonza, I n c . : B a r l o x 12
P rocedure :
W t % 60.75
1 . 2 5 5 . 0 0 5 . 0 0 5 . 0 0 8 . 0 0
10 .00
1 .
2 .
3 .
4 . 5 .
U s i n g moderate a g i t a t i o n (800 rpm) p r o v i d e d by a L i g h t n i n ' M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t i o n s , d i s p e r s e o r sc reen t h e Carbopol r e s i n i n t o t h e D I w a t e r . M ix t h e s l u r r y f o r a p p r o x i m a t e l y 15 m inu tes o r u n t i l t h e s l u r r y i s homogeneous. W i t h c o n s t a n t a g i t a t i o n , add t h e p o t a s s i u m h y d r o x i d e and t h e po tass ium s i l i c a t e . M ix u n t i l homogeneous. C o n t i n u e a g i t a t i o n and add t h e po tass ium c a r b o n a t e f o l l o w e d by t h e b l e a c h . Add t h e amine o x i d e s u r f a c t a n t and m ix u n t i l homogeneous. Add c o l o r and f r a g r a n c e , as d e s i r e d .
T o t a l A c t i v e s : S i l i c a t e ( a s S i 0 2 ) : 1 . 3 2 Carbonate (as Na2C03): 3 .84 A v a i l a b l e C h l o r i n e : 1 . O O Amine Ox ide : 3 . 0 0
SOURCE: BFGoodrich S p e c i a l t y Chemicals : DET-350
2. Dairy, Food and General Industrial Cleaner
8
Daiq , Food and General Industrial Cleaners 9
A c i d I n d u s t r i a l and Household Cleaners O x a l i c Ac id Gel
I n q r e d i e n t s : W t .%* Water 53.70 Van Gel B 2.50 Rhodopol 2 3 0.80 Oxa l i c Ac id D ihydra te , 12.59n Aqueous S o l u t i o n 40 .00 Po lysorbate 40 (Tween 40) 3 . 0 0
Procedure: 1 . Dry b lend t h e Van Gel €3 and Rhodopol 2 3 and add them t o t h e
water w h i l e m ix ing w i t h a p r o p e l l e r s t i r r e r a t 1800 rpm. Cont inue mix ing f o r 60 minutes.
s low ly add the o x a l i c a c i d s o l u t i o n .
and mix u n t i l un i fo rm.
2 . Reduce t h e s t i r r e r speed t o produce a s l i g h t vo r tex and
3 . When a l l t h e a c i d has been added, add the Po lysorbate 40
Formula t ion No. 466
Rust Removal J e l IY
I n s r e d i en ts : Water Van Gel B Rhodopol 2 3 Phosphoric Aci d, 50% Aqueous Sol u t i on Octoxynol-9
WtD/ou 5 3 . 2 0
3 . 0 0 0 . 8 0
40 00 3 00
Procedure: 1 . Dry b lend the Van Gel 0 and Rhodopol 2 3 and add them t o
water w h i l e mix ing w i t h a p r o p e l l e r s t i r r e r a t 1800 rpm. Cont inue mix ing f o r 60 minutes.
s low ly add t h e Phosphoric Ac id s o l u t i o n .
and mix u n t i l un i fo rm.
*As rece ived bas i s
2 . Reduce t h e s t i r r e r speed t o produce a s l i g h t vo r tex and
3 . A f t e r a l l t he a c i d has been added, add t h e Octoxynol-9
Formula t ion No. 467
SOURCE: R . T . Vanderb i l t Co., I n c . : Suggested Formulat ions
he
10 Advanced Cleaning Product Formulations
C l e a n e r s f o r I n d u s t r i a l A p p l i c a t i o n
D e s i n f e c t i n q C leaner , A c i d
I n s ed i en t s : w a t e r Phosphor i c a c i d (85Oh) S u l p h u r i c a c i d (98%) P r o p e t a l 241 Dodigen 226
Formula CT 06-06-01
D i ppi n q C1 eaner
I n r e d i e-n-t-sL itatger T e t r a p o t a s s i u m py rophospha te C a u s t i c soda D i p r o p y l e n e g l y c o l monomethyl e t h e r S u l f e t a l 4069 Zusol a t 1008/85
Formula CT 07-03-01
Spray C 1 eaner
I n s r e d i e n t s : Water Cublen D50 T r i e t h a n o l ami ne S u l f e t a l 4105 P r o p e t a l 241 Z u s o l a t l005/85 P h o s f e t a l 201 B u t y l g l y c o l C i t r u s t e r p e n e I n h i b i t o r 4000
Formula CT 07-06-01
I n g r e d i e n t s w a t e r Sul f e t a l 4105 P r o p e t a l 99 Z u s o l a t 1005/85 B u t y l g l y c o l Orange t e r p e n e
Formula CT 07-06-03
wts/, 4 8 . 0 2 4 . 0
5 . 0 3 . 0
2 0 . 0
Wt% 7 5 . 5 1 0 . 0
1 . 5 5 . 0 5 . 0 3 . 0
Q 5 8 . 0
3 . 0 3 . 0 4 . 0 2 . 0 0 . 5 2 . 0 5 . 0 0 . 5
2 2 . 0
8 6 . 0 6 . 0 3 . 0 0 . 5 4 . 0 0 . 5
SOURCE: Zschimmer & Schwarz GmbH 8, Co. : Genera l F o r m u l a t i o n s
Dairy, Food and General Industrial Cleaners I1
D e s t a i n e r (Phosphate, Powder)
S o i l - O r g a n i c s t a i n s : f ood , mold and g rass Surface-Cement, wood, p a i n t , p o l y m e r i c A p p l i c a t i o n Method-Brush Manu fac tu re -Dry b l e n d / A g g l o m e r a t i o n
Compos i t to^ *STPP Metso Beads 2048 Sodium S u l f a t e PQ Epsom S a l t * *Oc ty lphenoxy P o l y e t h o x y e t h a n o l , 9- Sodium P e r b o r a t e , Monohydrate
Use D i l u t i o n : 2 .3 -4 .5% bw (3-6 oz/ga
* FMC ** Rhone Poulenc I g e p a l CA-630
0 Moles EO
i o n )
D e s t a i n e r (Reduced Phosphate, Powder)
S o i l - O r g a n i c s t a i n s : f ood , mold and g r a s s Surface-Cement, wood, p a i n t , p o l y m e r i c A p p l i c a t i o n Methods-Brush Manu fac tu re -Dry b l e n d / A g g l o m e r a t i o n
Composi t i on: *STPP Metso Beads 2048 Sodi um S u l f a t e PQ Epsom S a l t **Octy lphenoxy P o l y e t h o x y e t h a n o l , 9-10 Moles EO V a l f o r 100 Z e o l i t e A Sodium P e r b o r a t e , Monohydrate
Use L e v e l : 3-6 o z / g a l l o n
* FMC ** Rhone-Poulenc I g e p a l CA-630
SOURCE: PQ Corp.: D e t e r g e n t F o r m u l a t i o n Guide
Wt% 25.0 2 5 . 0
8 . 0 2 .0 2 . 0 38.0
&% 10 .0 2 5 . 0
8 .0 2 . 0 2 . 0
1 5 . 0 3 8 . 0
12 Advanced Cleaning Product Formulations
Eaa Cleaner L x o phosphatS?,.powder)
Soi 1 - P r o t e i n Sur face-Egg and egg h a n d l i n g equipment A p p l i c a t i o n Method-High p r e s s u r e s p r a y (700-1400 p s i ) Manu fac tu re -Dry b l e n d
Composi t i on : Sodium Carbonate Metso Beads 2048 Sodium S u l f a t e V a l f o r 100 Z e o l i t e A *Sodi urn D i c h l o r o i socyanura te 2H20 **Sodi um A1 k y l a r y l S u l f o n a t e Powder (90%)
Use D i l u t i o n : 0 . 7 5 - 1 . 5 % bw ( 1 - 2 o z / g a l l o n )
* O l i n Chemical * * W i t c o
Bgki-ng Pan C l e a n e r (Phosphate,- Powder)
S o i l - A n i m a l f a t and grease, v e g e t a b l e o i l Sur face-A1 umi num and s t e e l A p p l i c a t i o n Method-Irnmersion/brush Manu fac tu re -Dry b l e n d / A g g l o m e r a t i o n
C O ~ ~ S l t 1 on : *Sodium Carbonate *STPP **Nonylphenoxy P o l y e t h o x y e t h a n o l , 9-10 Moles €0 Metso Pentabead 2 0
Use D i l u t i o n . 1 .5% bw ( 2 o z / g a l l o n )
* FMC ** Rhone-Poulenc I g e p a l CO-630
SOURCE: PQ C o r p . . D e t e r g e n t F o r m u l a t i o n Guide
W t % 3 0 . 0 20 .0 1 2 . 0 3 0 . 0
3 . 0 5 . 0
W t % 3 5 . 0 1 2 . 0 3 . 0
5 0 . 0
Dairy, Food and General Industrial Cleaners 13
Heavv D u t v C l e a n e r s A l l Purpose-Food Process P l a n t
I n g r e d i e n t s : Water EDTA ( E t h y l e n e d i a m i n e t e t r a c e t i c A c i d ) TKPP ( T e t r a Potass ium Pyrophosphate) P i l o t SXS-40 KOH, 45% Calamide C
Weight% 74.00
2.00 4 .00 5 .00
10.00 5 . 0 0
Comments abou t t h i s f o r m u l a : 1 . Add i n g r e d i e n t s i n o r d e r l i s t e d . 2 . Water and EDTA g i v e a m i l k y w h i t e s o l u t i o n . 3 . Upon a d d i n g t h e o t h e r i n g r e d i e n t s t h e s o l u t i o n i s c l e a r . 4. EDTA can be s u b s t i t u t e d w i t h Na4EDTA t o make a c l e a r f i n a l
5 . T h i s i s a heavy d u t y c l e a n e r f o r f o o d p r o c e s s i n g p l a n t s . 6 . Use l e v e l . 2-4 o z p e r g a l l o n .
s o l u t i o n .
F o r m u l a t i o n HDC-004-01
Hard S u r f a c e Spray C leaner
- I n q r e d i e n t s : Water TKPP ( T e t r a Potass ium Pyrophosphate) E t h y l e n e G l y c o l Monobuty l E t h e r Calsuds 81 NH40H, 28%
Weight% 89.00
1 .oo 3 . 0 0 4 .00 3 . 0 0
Comments abou t t h i s f o r m u l a : 1 . I n g r e d i e n t Water and TKPP when mixed a r e c l e a r . 2 . Hazy s o l u t i o n when E t h y l e n e G l y c o l Monobuty l E t h e r i s added. 3 . W i t h t h e a d d i t i o n o f Calsuds 81 t h e s o l u t i o n t u r n s c l e a r and
4 . When iUH40H i s added, t h e pH i n c r e a s e s t o 12 . has a pH o f 9.
F o r m u l a t i o n HDC-002-01
SOURCE: P i 1 o t Chemical Co. : Suggested Formul a t i ons
14 Advanced Cleaning Product Formulations
H i qh Foaming A1 k a l i ne Cleaner
Monater ic EH c o n t r i b u t e s t o detergency and e f f e c t i v e l y con- t r o l s bo th t h e k r a f f t and c loud p o i n t i n t h i s h igh foaming fo rmu la t i on .
Water 76.0 I n n r e d i e n t s : Wt9/o
Sodium Hydroxide (50%) 10 .0 Sodium M e t a s i l i c a t e (Pentahydrate) 2 . 0 Dodecyl benzenesul f o n i c a c i d 2 . 0 Monater ic EH 8 . 0 Nonoxynol -1 0 2 . 0 Procedure:
Recommened Use D i l u t i o n : 1 : 2 0 w i t h water Formula t ion F-768
Add i n g r e d i e n t s i n t h e order l i s t e d w i t h a g i t a t i o n . Package.
Heavy Duty A l k a l i n e Degreaser
Monater ic EH a i d s i n the removal o f o i l y s o i l s w i thou t emul- s i f i c a t i o n . I t e a s i l y d i sp laces o i l y s o i l s f rom hard sur faces and keeps them from redepos i t i ng . I n g r e d i e n t s : Wt% Water 65.0 Sodi u m Hydroxi de (50%) 2 0 . 0 Sodium M e t a s i l i c a t e (Pentahydrate) 3 . 0 Monater ic EH 1 0 . 0 Nonoxynol -1 0 2 . 0 Procedure:
Recommended Use D i l u t i o n : 1 :20 w i t h water . Formula t ion F-769
Add i n g r e d i e n t s i n t h e order l i s t e d w i t h a g i t a t i o n . Package.
Steam C1 eaner
Mona NF-20 c o n t r i b u t e s the non-foaming and detergency proper - t i e s i n t h i s fo rmu la t i on .
Water 65.00 Potassi um Hydroxide 3 . 0 0
I n a r e d i en ts : WtO/o
Sodium M e t a s i l i c a t e (Anhydrous) 1 0 . 0 0 Te t rapotass i um Pyrophosphate 10 .00 Mona NF-20 1 2 . 0 0 Procedure:
Add i n g r e d i e n t s i n t h e order l i s t e d w i t h a g i t a t i o n . T y p i c a l P r o p e r t i e s :
Cloud P o i n t : 75C K r a f f t P o i n t : t O C
Recommended Use D i l u t i o n : 4-6 oz . /ga l . Formula t ion F-762
SOURCE: Mona I n d u s t r i e s , I n c . : Suggested Formulat ions
Dairy, Food and General Industrial Cleaners 15
I n q r e d i e n t s : Water Cublen D 50 T e t r a p o t a s s i u m py rophospha te C a u s t i c soda Sodi um metas i 1 i c a t e S u l f e t a l 4105 Z u s o l a t 1008/85 P h o s f e t a l 201 B u t y l g l y c o l
Formula CT 06-13-01
I n d u s t r i a l and Hiqh Pressure Cleaners - C1 eaner. Strong1 y A1 Kal i ne
yw% 76.5
1 . o 4 .0 0 . 6 4 . 9 4 . 0 2 .0 2 . 0 5 . 0
C1 eaner, Weakly A1 k a l i ne I n g r e d i e n t s : Water Cublen D 50 T e t r a p o t a s s i u m py rophospha te T r i e t h a n o l ami ne S u l f e t a l 4105 Z u s o l a t 1008/85 P h o s f e t a l 201 B u t y l g l y c o l
Formula CT 06-13-02
Cleaner, Stronqly A1 ka l i n e (Phosphate-Free) I n g r e d i e c Water Cublen D50 Sodi um metas i 1 i c a t e C a u s t i c soda S u l f e t a l 4105 Z u s o l a t 1008/85 P h o s f e t a l 201 B u t y l g l y c o l
Formula CT 06-13-03
@1 eaner, Weak1 y A1 k a l i ne ( Phosphate-Free1 I n g r e d i e n t s : Water Cublen D 50 T r i sod i um c i t r a t e S u l f e t a l 4105 Zusol a t 1008/85 P h o s f e t a l 201 B u t y l g l y c o l T r i e t h a n o l ami ne
Formula CT 06-13-04
Wt% 8 0 . 4
1 . o 2 . 0 3 . 6 4 .0 2 .0 2 . 0 5 . 0
Wt% 8 0 . 5
1 . o 4 .9 0 . 6 4 .0 2 .0 2 . 0 5 .0
Wt% 80 .4
1 . o 2 . 0 4 . 0 2 .0 2 . 0 5 . 0 3 . 6
SOURCE: Zschimmer & Schwarz GmbH & Co. : Genera l F o r m u l a t i o n s
16 Advanced Cleaning Product Formulations
M e t a l C l e a n e r (m S o i l - P e t r o l e u m and animal o i l and g rease S u r f a c e - M e t a l : S t e e l Appl i c a t i on Method-Immersi on Manu fac tu re -M ix t a n k w i t h p r o p e l l e r s t i r r e r
Composi ti on : Water S t a r Sodi um S i 1 i c a t e Sodium H y d r o x i d e (50%) *Phosphate E s t e r * * L i q u i d N o n i o n i c S u r f a c t a n t (C9-C11; 6 Moles EO)
Use D i l u t i o n : 2%-5% b v
* Rhone-Poulenc Rhodafac RE-610 ** Rhone-Poulenc Rhodasur f 91-6
w.t% 65 .6 1 5 . 6 6 . 3 5 . 0 7 . 5
Food Indus try C l e a n e r (W
Soi l -Heavy f o o d grease, o i l and p r o t e i n Sur face -Meta l , ce ramic , p o l y m e r i c , g l a s s A p p l i c a t i o n Method-Wipe, mop o r b r u s h Manu fac tu re -M ix t a n k w i t h p r o o e l l e r s t i r r e r
Compos i t i on : Wt% Water 74 .0 TKPP (60%) 3 .0 N C l e a r Sodium S i l i c a t e 7 . 0
*Phosphate E s t e r 2 .5 * * E t h y l e n e G l y c o l n - B u t y l E t h e r 5 . 0 * * * L i q u i d N o n i o n i c S u r f a c t a n t (C12-Cl3; 6 . 5 Moles € 0 ) 5 . 0
Use D i l u t i o n : 6-12% bw (8-16 o z / g a l l o n )
* Rhone-Poulenc Rhodafac RE-600 ** Dow Chemical , Union Carb ide *** Rhone-Poulenc Rhodasur f LA-7
SOURCE: PQ C o r p . : D e t e r g e n t F o r m u l a t i o n Guide
Sodi um H y d r o x i d e (50%) 3 . 5
Dairy, Food and General Industrial Cleaners 17
M i l k Can C l e a n e r (Phosphat_e, Powder)
Sol 1 -Fa t and p r o t e i n Sur face -Meta l A p p l i c a t i o n Method-Wipe o r b r u s h Manu fac tu re -Dry b l e n d / A g g l o m e r a t i o n
Compo_sit ion’ *STPP Metso Beads 2048 *Sod1 u m Carbonate +*Sod1 um D i c h l o r o i socyanura te , 2H20 ***Sodium A1 k y l a r y l S u l f o n a t e Powder, (90%)
Use D i l u t i o n 0 . 7 5 - 1 5% bw (1-2 o z / g a l l o n )
* FMC ** O l i n Chemical * ** w 1 t c o
M i l k Can CLea-ner (Zeco Phosphate, Powder)
S o l 1 - F a t and p r o t e i n S u r f ace-Meta l A p p l i c a t i o n Method-Wipe o r b r u s h Manu fac tu re -Dry b l e n d
Composi t i on : Val f o r 100 Z e o l i t e A Metso Pentabead 20 Sodium Carbonate *Sodium D i c h l o r o i s o c y a n u r a t e , 2H20 **Sod1 um A1 k y l a r y l Sul f o n a t e Powder, (90%)
Use Leve l : 1 - 2 o z / g a l l o n
* O l i n Chemical ** Stepan, W i t co
SOURCE: PQ C o r p . : D e t e r g e n t F o r m u l a t i o n Guide
WX/, 3 0 . 0 3 0 . 0 35.0 3.0 2.0
W t % 20.0 40.0 3 5 . 0
3 . 0 2 . 0
18 Advanced Cleaning Product Formulations
Powdered Enzyme Presoaks Economy Presoak
Component: Soda Ash Sodium Metasilicate Pentahydrate Sodium Dodecylbenzenesulfonate Powder Burcosperse AP Powder Burcotase EP-60
Premi um Presoak
Component: Soda Ash STPP Neodol 25.7 Sodium Metasi 1 icate Pentahydrate Sodium Dodecylbenzenesulfonate Powder Burcosperse AP Powder Burcotase EP-60
Wt% 8 0 . 0 1 0 . 0
5 . 0 3 . 0 2 . 0
5
35. n 4 0 . 0
5 . 0 1 0 . 0
5 . 0 3 . 0 2 . 0
The recommended use concentration o f these products i s 1 - 4 g/1 in the presoak bath. For optimum results, the presoak temperature should be 130-15OF.
Enzyme Prespotter f o r Oilv/Smuttv Soils
Component: Water Propyl ene G1 ycol Dodecyl benzenesul foni c Acid
Burco TME Nonionic Surfactant* Burcotase LL-100
TEA-85
wtD/, 4 9 . 0 1 0 . 0 1 0 . 0 2 0 . 0
5 . 0 5 . 0 1 . o
*An HLB of 9 . 5 - 1 0 . 0 i s preferred. Alcohol ethoxylates are preferred.
Add components in the order listed. Blend until uniform between each addition. Cool before adding the enzyme.
SOURCE: Burlington Chemical Go., Inc. : Suggested Formulations
Dairy, Food and General Industrial Cleaners 19
S a n i t i z i n s C leaner (Phosphate, Powder)
S o i l - H o s p i t a l s o i l : sebum, b lood , u r i n e , e t c . Su r face -Meta l , ce ramic , p o l y m e r i c A p p l i c a t i o n Method-Wipe o r b r u s h Manu fac tu re -Dry B lend
Composi t 1 1 0 ~
Metso Beads 2048 *Sodium Carbonate *STPP **Sodi urn D i c h l o r o i socyanura te , 2H20 ***Sod; um A1 k y l a r y l Sul f o n a t e Powder (99%)
Use D i l u t i o n : 0 .75-1.5% bw (1-2 o z / g a l l o n )
* FMC ** 01 i n Chemical *** w i t c o
Wt% 2 0 . 0 35 .0 30.0 10 .0
5 .0
Sani t i z i na Aaen t (Phosphate, Powder)_
S o i l - H o s p i t a l s o i l : sebum, b lood , u r i n e , e t c . Su r face -Meta l , ce ramic , p o l y m e r i c A p p l i c a t i o n Method-Wipe, b r u s h Manu fac tu re -Dry b l e n d / A g g l o m e r a t i o n
Composi t i on : Wt% *STPP 30 .0 *Sodi um Carbonate 2 5 . 0 * * L i q u i d N o n i o n i c S u r f a c t a n t (C12-Cl6; 12 Moles EO) 1 0 . 0 Metso Pentabead 20 30 .0 Qua te rna ry Germ ic ide 5 .0
Use D i l u t i o n : 0 .75-1.5% bw (1-2 o z / g a l l o n )
* FMC ** Rhone-Poulenc Rhodasur f LA-12
SOURCE: PQ C o r p . : D e t e r g e n t F o r m u l a r y Guide
3. Degreaser
20
Degreasers 21
Aqueous Desreaser
I n g r e d i e n t s : Water NaOH, 50% Cal s o f t LAS-99 P i l o t SXS-40 Cal o x y l a t e N-9 TKPP ( T e t r a Po tass ium Pyrophosphate) Sodium Metas i 1 i c a t e E t h y l e n e G l y c o l Monobuty l E t h e r
Comments abou t t h i s f o r m u l a : D i s s o l v e t h e s a l t s i n t h e wa te r f i r s t . F o r m u l a t i o n DEG-001-01
Aqueous Deqreaser d -L i monene M i croemul s i o n
I n g r e d i e n t s : d - L i monene Calsuds CD-6 Cal i mu1 se PRS D i e t h y l e n e G l y c o l n - B u t y l E t h e r Water
Wei qh t% 60.80
2 . 0 0 9.40 8 . 7 0 4 .60 4 .70 6.60 3.20
Weight% 9.90 9 . 8 0 2 . 4 4 4 .93
73.00
Comments abou t t h i s f o r m u l a : 1 . A d d i t i o n a l Calsuds CD-6 may be needed t o c l a r i f y t h e sample. 2 . Add t h e w a t e r s l o w l y .
F o r m u l a t i o n DEG-002-01
Water Based Deareaser
I n g r e d i e n t s : Water NaOH, 50% Cal s o f t LAS-99 P i lot SXS-40 Na4EDTA Cal o x y l a t e N-9 E t h y l e n e G l y c o l Monobuty l E the r Sodi urn Me tas i 1 i c a t e
Weight% 68.50
2 . 0 0 7 .00 7 .50 2 .00 5 .00 3 . 0 0 5 .00
Comments abou t t h i s f o r m u l a : 1 . There i s a phosphate v e r s i o n where 3 .5% sodium t r i p h o s p h a t e
2 . Use w a t e r t o b a l a n c e i n g r e d i e n t s . i s s u b s t i t u t e d f o r t h e sodium m e t a s i l i c a t e and Na4EDTA.
F o r m u l a t i o n DEG-006-01
SOURCE: P i l o t Chemical Co. : Suggested F o r m u l a t i o n s
22 Advanced Cleaning Product Formulatiorrs
m r e a s e r C o n c e n t r a t e ( L i qui d)
S o i l - G r e a s e , o i l Su r face -Pa i n t , p o l y m e r i c , me ta l A p p l i c a t i o n Method-Spray o r w ipe Manu fac tu re -M ix t a n k w i t h p r o p e l l e r s t i r r e r
Composi t i on : Water Metso Beads 2048 *Sodi urn Pol y a c r y l a t e (40%) **Phosphate E s t e r * * * L i q u i d N o n i o n i c S u r f a c t a n t (C9-C l l ; 6 Moles EO) * * * * L i q u i d N o n i o n i c S u r f a c t a n t ( C 9 - C l l ; 2 . 5 Moles EO)
Use D i l u t i o n : Normal Duty-1.5% bw ( 2 o z / g a l l o n ) Heavy Du ty -3 .0% bw ( 4 o z / g a l l o n )
* Rhone-Poulenc C o l l o i d 226/35 P o l y a c r y l a t e (40%) ** Rhone-Poulenc Rhodafac R E - 6 1 0 *** Rhone-Poulenc Rhodasur f 91-6 **** Rhone-Poulenc Rhodasur f A-24
M e t a l D e - O i l i n g L i q u i d C o n c e n t r a t e ( L i quid )
Soi 1-Petro leum-based o i 1 S u r f a c e - M e t a l : S t e e l , copper , aluminum, e t c . Appl i c a t i o n Method-Spray and /o r immersi on Manu fac tu re : M i x t a n k w i t h p r o p e l l e r s t i r r e r
Composi t i on : Water S t a r s o Sodi urn S i 1 i c a t e EDTA, Te t rasod ium (37%) Sodium Xy lene S u l f o n a t e (40%) * L i q u i d N o n i o n i c S u r f a c t a n t (C9-C11; * * L i q u i d N o n i o n i c S u r f a c t a n t (C9-C11
Use D i l u t i o n : 2%-4% bv
* Rhone-Poulenc Rhodasur f 91-6 ** Rhone-Poulenc Rhodasur f A-24
SOURCE: PQ Corp. : D e t e r g e n t Fo rmu la t
6 Moles EO) 2 .5 Moles EO)
on Guide
wt"/o
6 7 . 0 8 . 0 5 . 0
10 .0 5 . 0 5.0
W B 4 2 . 0 1 2 . 0 1 6 . 0 2 0 . 0
3 .0 7.0
aegreasers 23
Solvent Denreaser
Carbopol r e s i n s a re used t o emu ls i f y and s t a b i l i z e t h i s d-limonene o i l based emulsion. I n a d d i t i o n , t h e use o f t h e r e s i n p rov ides v e r t i c a l c l i n g t o inc rease t h e con tac t t ime o f t h e de tergent on t h e s o i l e d su r face and enhance consumer convenience.
I n q r e d i en t : D I Water Carbopol ETD 2623 ( 1 ) d-Limonene (2 ) Propylene g l y c o l methyl e the r (3 ) Alkylbenzene s u l f o n i c a c i d ( 4 ) C12-13 l i n e a r a l coho l , 6.5 moles EO ( 5 ) Isopropanol Sodium hydrox ide (50%)
9 81.18
0.32 10.00 2.00 2.00 1.50 2.50 0.50
Brookf i e l d v i scosi t y (RVT-20 rpm) : 750 cps Product pH: 9.5-10 Product C1 a r i t y : Opaque
( 1 ) BFGoodrich ( 2 ) Arylessence, I n c . : H-7892 d-limonene ( 3 ) Dow Chemical : Dowanol PM ( 4 ) Stepan C o . : B i o s o f t S-100 ( 5 ) S h e l l Chemical: Neodol 23-6.5
Procedure: 1 . Using moderate a g i t a t i o n (800 rpm) p rov ided by a L i g h t n i n '
Mixer o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e f o r general m ix ing and b lend ing opera t ions , d i spe rse o r screen t h e Carbopol r e s i n i n t o t h e D I water. Mix t h e s l u r r y f o r approximately 15 minutes o r u n t i l t h e s l u r r y i s homogen- eous.
2 . Add t h e d-limonene w i t h good a g i t a t i o n and mix u n t i l homogene-
3 . Reduce a g i t a t i o n and add t h e g l y c o l e the r , s u l f o n i c ac id , and
4 . Add t h e isopropanol . 5 . Add t h e sodium hydrox ide u n t i l t h e t a r g e t pH range i s
6. Add c o l o r , as des i red .
T o t a l Actives:
ous.
a l coho l e thoxy l a t e .
reached.
d-l imonene: 10.0 Propylene g l y c o l methyl e t h e r : 2.0 Sodium a1 kylbenzene su l fona te : 2 .2 Psopropanol : 1 .5 C12-13 l i n e a r a l coho l , 6 .5 moles EO: 2 .5
SOURCE: BFGoodrich S p e c i a l t y Chemicals: DET-330
24 Advanced Cleaning Product Formulations
S o l v e n t Based Deqreaser
I n s r e d i e n t s : Kerosene A r i s t o n a t e M P i n e O i l T a l l O i l F a t t y A c i d C a l o x y l a t e N-9 Hexyl ene G1 y c o l
Comments about t h i s f o r m u l a : 1 . Use a low odor g rade o f t a l l o i l f a t t y a c i d . 2 . Add i n g r e d i e n t s i n t h e o r d e r i n d i c a t e d . 3. A r i s t o n a t e L can be s u b s t i t u t e d f o r A r i s t o n a t e M~
F o r m u l a t i o n DEG-004-01
S o l v e n t Based Degreaser
I n g r e d i e n t s : A r i s t o n a t e M T r i t o n X-45 T r i t o n N-101 Kerosene
Comments about t h i s f o r m u l a : 1 . Kerosene can be s u b s t i t u t e d w i t h Aromat ic Naphtha. 2 . A r i s t o n a t e M can be s u b s t i t u t e d w i t h A r i s t o n a t e L.
F o r m u l a t i o n DEG-003-01
Enqine C leaner and Deqreaser
I n g r e d i e n t s : Water M I PA Cal i mu1 se PRS Dowanol DPM Na4EDTA
Comments about t h i s f o r m u l a : C l e a r , p a l e y e l l o w produc t F o r m u l a t i o n DEG-005-01
SOURCE: P i 1 o t Chemi c a l Co. : Suggested Formul a t i ons
Wei ghP% 72.85
3.00 10.00 10 .06
3 . 0 2 1 . 0 6
We i g h t % 5 . 1 0 5 . 0 0 2 .99
86.93
Weight% 58.94 20.33
5 . 0 8 45 .24
0.41
lshwashing Detergents
25
26 Advanced Cleaning Product Formulations
A u t o m a t i c Dishwash Deteraent-Consumer (Ze ro Phosohate. C h l o r i n e Free. Powder1
S o i l - F o o d grease, o i l and p r o t e i n Sur face -Meta l , g l a s s , p l a s t i c and ce ramic A p p l i c a t i o n Method-Dishwasher ( s p r a y ) Manu fac tu re -Dry B lend /Agg lomera t i on
Composi t i on : Sodi urn C i t r a t e D i h y d r a t e * B r i t e s i l H20 Hydrous P o l y s i l i c a t e Sodi urn Carbonate * * L i q u i d N o n i o n i c S u r f a c t a n t ( 3 moles EO) ***Acusol 445ND Sodi um Pol y a c r y l a t e (92% sol i d s ) ****Sodium P e r b o r a t e Monohydrate V a l f o r 100 Z e o l i t e A Sodium S u l f a t e
1 0 . 0 2 0 . 0 2 3 . 0
3 . 0 4 . 0
1 0 . 0 15.0 15 .0
* 2 . 0 w e i g h t r a t i o powder w i t h 17.5% wa te r ** Rhone-Poulenc A n t a r o x BL-330 *** Rohm & Haas; o r use a c o m b i n a t i o n o f Acusol 445ND and Acusol
**** O r use Sodium D i c h l o r o i s o c y a n u r a t e b l e a c h ( c o n t a i n s c h l o r - 479ND ( 2 w t . % each)
i n e ) a t 2 w t % . Balance w i t h s u l f a t e .
Au tomat i c Dishwash Detersent-Consumer (Phosphate, C h l o r i n e Free, Powder)
Soi 1-Food grease, o i 1 and p r o t e i n Sur face -Meta l , g l a s s , p l a s t i c and ce ramic A p p l i c a t i o n Method-Dishwasher ( s p r a y ) Manu fac tu re -Dry b l e n d / A g g l o m e r a t i o n
Composi t i on : RU L i q u i d Sodium S i l i c a t e *Sodium Carbonate * * L i q u i d N o n i o n i c S u r f a c t a n t ( 3 moles EO) ***Acusol 445ND Sodi um Pol y a c r y l a t e (92% so l i ds) ****Sodium P e r b o r a t e Monohydrate *STPP Sodi u m S u l f a t e
15 .0 2 3 . 0
3 . 0 4 . 0
1 0 . 0 30 .0 1 5 . 0
* FMC ** Rhone-Poulenc A n t a r o x BL-330 *** Rohm & Haas; O r use a c o m b i n a t i o n o f Acusol 445ND and
**** O r use Sodi u m D i c h l o r o i s o c y a n u r a t e b l e a c h ( c o n t a i n s c h l o r - Acusol 479ND ( 2 w t . % each)
i n e ) a t 2 w t %. Ba lance w i t h s u l f a t e .
SOURCE: PO Corp. : D e t e r g e n t F o r m u l a t i o n Guide
Dishwashing Detergents 27
A u t o m a t i c Dishwash D e t e r c i e n t - I n d u s t r i a l & I n s t i t u t i o n a l (Phosphate, S o l i d Block)
S o i l - F o o d grease, o i l and p r o t e i n Sur face -Meta l , g l a s s , p l a s t i c and ce ramic A p p l i c a t i o n Method-Dishwasher ( s p r a y ) M a n u f a c t u r e - S o l i d b l o c k
Composi t i on : Metso Beads 2048 NaOH (50% S o l u t i o n ) *STPP *Sodi um Carbonate * * L i q u i d N o n i o n i c S u r f a c t a n t (7-9 Moles EO; C12-15)
* FMC ** Rhone-Poulenc Rhodasur f LA-7 o r LA-9 o r
S h e l l Chemical Neodol 25-7
Wt% 2 5 . 0 2 5 . 0 3 5 . 0 12.0 3.0
A u t o m a t i c D i shwashi ng D e t e r g e n t - I n d u s t r i a1 & I n s t i t u t i o n a l ( L i q u i d )
S o i l - F o o d grease, o i l and p r o t e i n S u r f a c e - M e t a l , ce ramic and g l a s s A p p l i c a t i o n Method-Dishwasher ( s p r a y ) Manu fac tu re -M ix t a n k w i t h p r o p e l l e r s t i r r e r
Compos i t i on : Water * A c r y s o l ASE 108 ( A c r y l i c Polymer) * * T r i t o n DF-16 ( N o n i o n i c S u r f a c t a n t ) P o t a s s i um H y d r o x i d e (45%)
N C l e a r Sodium S i l i c a t e TKPP (60%)
Wt% 50.9
6 . 9 3 . 0 1 . 2
25.0 13 .0
Use D i l u t i o n : 0 .15-0.30% bw ( 0 . 2 - 0 . 4 o z / g a l l o n )
* Rohm & Haas; o r Rhone-Poulenc C o l l o i d 226/35 P o l y a c r y l a t e ( 4 0 % ) ** Rohm & Haas; o r Rhone-Poulenc A n t a r o x EL-330
SOURCE: PQ C o r p . : D e t e r g e n t F o r m u l a t i o n Guide
28 Advarrced Clearring Product Formulatiorls
A u t o m a t i c Dishwash D e t e r g e n t T I n d u s t r i a l - &- I n s t i ~ ! . ! t i g n ~ j (Zero-Phosphate, C h l o r i n e Free, Powde_rj
S o i l - F o o d grease, oil and p r o t e i n S u r f a c e - M e t a l , g l a s s , p l a s t i c and ce ramic A p p l i c a t i o n Method-Dishwasher ( s p r a y ) Manuf a c t u r e - D r y B1 end /Agg lomera t i on
Composi t i on : Metso Pentabead 20 Sod1 um Carbonate * L i q u i d N o n i o n i c S u r f a c t a n t (7 -9 Moles € 0 ; C12-15) **Acusol 445ND Sodium P o l y a c r y l a t e (92% s o l i d s ) ***Sodium P e r b o r a t e Monohydrate B leach Val f o r 100 Z e o l i t e A Sodium S u l f a t e
W t % 3 0 . 0 2 6 . 0 3.0 4 . 0
1 0 . 0 1 5 . 0 1 2 . 0
* Rhone-Poulenc Rhodasur f LA-7 o r LA-9 o r
* * Rohm & Haas; O r use a comb ina t ion o f Acusol 445ND and Acusol
*** O r use sodium d i c h l o r o i s o c y a n u r a t e b l e a c h ( c o n t a i n s c h l o r i n e )
S h e l l Chemical Neodol 25-7
479ND ( 2 w t % e a c h ) .
a t 2 w t % . Balance w i t h s u l f a t e .
A u t o m . a t i c P ~ h w a ~ h _ D e t e ~ e _ n ~ . ~ I ~ d - u Stri-a 1. _&-Ins t_ii-tluti_ o?e_a_8 L Phospha te_ ,Ch l_or ine _Free- Pow_s1ec)
S o i l - F o o d grease, o i l and p r o t e i n Sur face -Meta l , g l a s s , p l a s t i c and ce ramic A p p l i c a t i o n Method-Dishwasher ( s p r a y ) Manu fac tu re -Dry B lend /Agg lomera t i on
C o m p o s i t i o n : Wt% G t s o Pentabead 20 3 0 . 0 *STPP 25 .0 *Sodi um Carbonate 2 8 . 0 * * L i q u i d N o n i o n i c S u r f a c t a n t (7 -9 Moles EO; C12-15) 3 . 0 ***Acusol 445ND Sodi um Pol y a c r y l a t e (92% sol i d s ) 4 . 0 ****Sodium P e r b o r a t e Monohydrate B leach 1 0 . 0
* FMC ** Rhone-Poulenc Rhodasur f LA-7 o r LA-9 o r
*** Rohm & Haas; O r use a c o m b i n a t i o n o f Acusol 445ND and
**** O r use sodium d i c h l o r o i s o c y a n u r a t e b l e a c h ( c o n t a i n s
S h e l l Chemical Neodol 2 5 - 7
Acusol 479ND ( 2 w t % each)
c h l o r i n e ) a t 2 w t % . Balance w i t h s u l f a t e .
SOURCE: PP Corp . : D e t e r g e n t F o r m u l a t i o n Guide
Dishwashing Detergents 29
A u t o m a t i c D i shwashi ng Gel w i tJ1_..Chlori n e B1 each
Carbopol r e s i n s a r e used t o t h i c k e n t h e p r o d u c t t o reduce s p l a s h i n g , p r o v i d e cup r e t e n t i o n i n t h e d i shwasher , and c r e a t e a s t a b l e suspens ion o f i n s o l u b l e s ( i . e . phosphate b u i l d e r s ) i n t h i s AOL f o r m u l a t i o n c o n t a i n i n g c h l o r i n e b l e a c h .
I n q r e d i e n t : 01 wa te r Carbopol 672 ( 1 ) P o t a s s i um h y d r o x i d e (45%) 2 . l r p o t a s s i u m s i l i c a t e (39%) ( 2 ) P o t a s s i urn c a r b o n a t e ( 3 ) Sodium t r i p o l y p h o s p h a t e ( 4 ) Sodi um h y p o c h l o r i t e ( 1 2 . 5 C 0 h ) Sodium n -decy l d i p h e n y l o x i d e d i s u l f o n a t e ( 4 5 % ) ( 5 )
W t % 4 4 . 7 5
1 . 2 5 5 . 0 0
15 .00 5 . 0 0
2 0 . 0 0 8 . 0 0 1 . o o
B r o o k f i e l d v i s c o s i t y (RVT-20 rpm): 15,000 cps P roduc t p H : 12-13 P roduc t c l a r i t y : Opaque
( 1 BFGoodri ch ( 2 The PO Corp. ( 3 Armand ( 4 FMC Corp. ( 5 ) O o w Chemica l : Dowfax 382
Procedure : 1 . Use a L i g h t n i n ' M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an
impe l 1 e r s u i t a b 1 e f o r g e n e r a l m i x i ng and b l e n d i n g o p e r a t i o n s . Screen t h e Carbopol r e s i n i n t . 0 t h e v o r t e x o f t h e r a p i d l y a g i t a t i n g w a t e r (800 r p m ) . A l l o w t o m i x u n t i l homogeneous and f r e e o f po lymer lumps.
u n t i l homogeneous. The p r o d u c t w i l l become v e r y t h i c k a t t h i s p o i n - t .
3 . Add t h e po tass ium c a r b o n a t e and phosphate. M ix u n t i l t h e r e a r e no more phosphate p a r t i c l e s . H e a t i n g t o 50-60C w i l l speed t h i s p r o c e s s .
4 . Add t h e b l e a c h and t h e n t h e s u r f a c t a n t . M i x u n t i l homogeneous. A d j u s t t h e pH t o 12-13 u s i n g KOH. 00 n o t u s e a c i d t o reduce t h e pH, e s p e c i a l l y a f t e r t h e a d d i t i o n o f t h e b l e a c h .
be low 30C t o a v o i d e x c e s s i v e b l e a c h decompos i t i on .
2 . Add i n t h e po tass ium h y d r o x i d e and p o t a s s i u m s i l i c a t e . M i x
5 . Add c o l o r and f r a g r a n c e , as d e s i r e d . Cool t h e p r o d u c t t o
T o t a l A c t i v e s : Phosphorous c o n t e n t : 5 . 0 S i l i c a t e ( a s S i 0 2 ) : 3 . 9 Carbonate ( a s Na2CO3): 3 . 8 Ava i 1 a b 1 e c ti 1 o r i ne : 1 . o
SOURCE: BFGoodrich S p e c i a l t y Chemica ls : DET-100
30 Advanced Cleaning Product Formulations
Clear, Co lo r less Manual -D ish Wash
I n s r e d i e n t s : Water, D . I. W i t c o l a t e ES-3 Rewoteric AM 8-14 Ethanol Sodium Ch lo r ide
Wt% 57 .5 34 .2 5.0 3.0 3 . 3
B lend ing Procedure:
between each a d d i t i o n .
Comment:
Blend i n g r e d i e n t s i n t h e order l i s t e d . D isso lve comple te ly
Rewoteric AM 8-14: Grease c u t t e r and foam booster . Formula 132
Powder S t a i n l e s s S i l ve rware Pre-Soak
I n q r e d i en ts : Sodium Carbonate (Soda Ash) Pet ro BAF Powder DeSonic 11N T r i sodi um Phosphate, Anhydrous Caust ic Soda Beads
61 endi ng Procedure:
Use D i 1 u t u i on : 1 oz/gal
Blend i n g r e d i e n t s i n t h e order l i s t e d
Formula 127
Low A1 k a l i ne Warewashi nq Block
I n q r e d i en ts : Water, D . I . R .U . S i l i c a t e DeSoni c LFD-97 Sodium Carbonate (Soda Ash) Sodium Tr ipolyphosphate Code 185
B lend ing Procedure:
produced, pour i n t o molds and a l l o w t o harden. Blend i n g r e d i e n t s i n the order l i s t e d . When s l u r r y i s
Formula 129
SOURCE: Witco Corp . : Suggested Formulat ions
Wt% 6 7 . 0
5 . 0 11 . o 2 . 0
2 5 . 0
W B 1 6 . 0 29.0
2 . 0 2 3 . 0 3 0 . 0
Dishwashing Detergents 31
Dish Washi nq Agents clear, liquid, 25% WAS
alkanesulphonate:ethersulphate=4:l
I n g r e d i e m A : Hostapur SAS 60
Genapol Z R O l i q u i d
B: Water P r e s e r v a t i v e DY e Perfume
T e s t s : v i s c o s i t y (rnPas) : 75 C loud p o i n t : <-5C
I n q r e d i e n t s : A : Hos tapur SAS 60
Genapol ZRO l i q u i d
B: Water P r e s e r v a t i ve DY e Perfume Genagen LAB
T e s t s : V i s c o s i t y (mPas): 100 Cloud p o i n t : <-5C
I n q r e d i e n t s : A : Hostapur SAS 60
Genapol ZRO l i q u i d
B: Water P r e s e r v a t i v e DY e Perfume Genagen LAB
T e s t s : V i s c o s i t y (mPas): 2 3 0 Cloud p o i n t : <-5c
M a n u f a c t u r i n g : One a f t e r a n o t h e r , t h e components o f B a r e added t o A
3 3 . 3 0 1 7 . 9 0
48.50 0 . 1 0
0 . 2 0 q . s .
Wto/, 3 3 . 3 0 1 7 . 9 0
47 .50 0 . 1 0
0 . 2 0 1 . o o
q . s .
3 3 . 3 0 17.90
44.50 0 . 1 0
0 . 2 0 4 .00
9 , s .
SOURCE: Hoechst A k t i e n g e s e l l s c h a f t : Suggested F o r m u l a t i o n s
32 Advanced Cleaning Product Formulations
D i s h Washi nq Agen ts C l e a r , liquid, 30% WAS
a1 kanesulphonate:ethersulphate=4: 1
I n s r e d i e n t s : A : Hos tapur SAS 60
Genapol Z R O l i q u i d
€3: Water P r e s e r v a t i v e DY e Perfume Genagen LAB
T e s t s : V i s c o s i t y (mPas) : 380 C loud p o i n t : <-5C
I n q r e d i e n t s : A: Hos tapur SAS 60
Genapol Z R O l i q u i d
0: Water P r e s e r v a t i v e DY e Perfume Hoe S 3924
T e s t s : V i s c o s i t y (mPas) : 420 C loud p o i n t : <-5C
I n g r e d i e n t s : A: Hos tapur SAS 60
Genapol Z R O l i q u i d
El: Water P r e s e r v a t i ve DY e Perfume Hoe S 3924
T e s t s : V i s c o s i t y (mPas) : 61 0 C loud p o i n t : <-5C
W B 40 .00 21 . 4 0
37 .30 0 . 1 0
0 . 2 0 1 . o o
q . s .
wtsl, 40 .00 2 1 . 4 0
37.30 0 . 1 0
0 . 2 0 1 .oo
q . s .
wt./, 40 .00 21 .40
34.30 0 . 1 0
0 . 2 0 4 . 0 0
q . s .
M a n u f a c t u r i n g :
SOURCE: Hoechst A k t i e n g e s e l l s c h a f t : Suggested F o r m u l a t i o n s
One a f t e r a n o t h e r , t h e components o f 8 a r e added t o A .
Dishwashing Detergents 33
l n g r e d i e n t s : Water, D . I . W i t c o n a t e 1240 Varox 1770 W i t c o l a t e SE-5
D i s h Wash w/Am&e Oxide/LABS/SLES
Wtl 6 6 . 3 10.3
5 . 3 18.1
81 end i ng P rocedure :
between each a d d i t i o n . Add e t h a n o l as needed t o l o w e r v i s c o s i t y .
T y p i c a l P r o p e r t i e s : V i s c o s i t y , c p s : 620 S o l i d s : 16.8% pH: 9.12 Formula 117
Add i n g r e d i e n t s i n o r d e r shown and d i s s o l v e c o m p l e t e l y
D i sh Wash w/Ami ne Oxi de/LABS/ALES
I n g r e d i e n t s 1 Water, D.I. W i t c o n a t e 1240 Varox 1770 W i t c o l a t e LES-6OA E thano l
70 .0 13.8
3 . 1 8 . 2 5 . 0
B1 end? ng Procedure:
each a d d i t i o n . A c i d i f y w i t h C i t r i c A c i d t o pH=6.5.
T y p i c a l P r o p e r t i e s : V i s c o s i t y , cps : 4 S o l i d s : 10.1% pH: 6 . 6 8 Formula 118
Add i n g r e d i e n t s i n o r d e r shown and d i s s o l v e c o m p l e t e l y between
_ _ Hand Di shwashi ng L i sui d
I n g r e d i e n t s : Water W i t c o n a t e AOS W i t cami de 128T W i t c o l a t e LES-6OC
K% 6 0 . 0 26 .0
4 . 0 1 0 . 0
B l e n d j n g I n s t r u c t i o n s :
add i t i ons . Add a l l i n g r e d i e n t s i n t h e o r d e r l i s t e d , m i x i n g w e l l between
Formula 106
SOURCE: W i t c o C o r p . : Suggested F o r m u l a t i o n s
34 Advanced Cleaning Product Formulations
Foam Boos te r : Ez-4-5 i n Hand D i shwashi na L i q u i d s
L i q u i d d i s h f o r m u l a t o r s a r e c h a l l e n g e d t o p roduce l o w c o s t q u a l i t y p r o d u c t s . Hand d i s h d e t e r g e n t s a r e expec ted t o foam i n t h e p resence o f f o o d s o i l s , c u t grease and c l e a n . I n a d d i t i o n , a e s t h e t i c s , s k i n m i l d n e s s , and env i ronmen ta l impac t a r e a l s o ma jo r p r o d u c t c o n s i d e r a t i o n s . The f o l l o w i n g d a t a i l l u s t r a t e d how E-14-5 can be used t o f o r m u l a t e c o s t e f f e c t i v e p r o d u c t s s u i t a b l e f o r t h e v a r i o u s l i q u i d d i s h soap market segments. O p t i m i z e d l i q u i d d i s h d e t e r g e n t s c o n t a i n i n g E-14-5 p r o v i d e t h e optimum i n c o s t pe r fo rmance when compared t o a l l o t h e r t y p e s o f foam b o o s t e r s . A l t h o u g h i t p e r f o r m s w e l l a l o n e , E-14-5 s y n e r g i s t i c a l l y enhances t h e pe r fo rmance o f most t r a d i t i o n a l foam b o o s t e r s as i l l u s t r a t e d below w i t h Coco d i e t h a n o l a m i d e .
Economy Eormul a t i on
I n g r e d i e n t s : D e i o n i z e d w a t e r Dodecylbenzene s u l f o n a t e , sodium s a l t , (60% s o l i d s ) L a u r y l a l c o h o l e t h e r s u l f a t e - 4 EO, (60% s o l i d s ) E t h y l a l c o h o l Tomah E-14-5 Coco d i e t h a n o l ami de
S tandard F o r m u l a t i o n
I n g r e d i e m D e i o n i z e d w a t e r Dodecylbenzene s u l f o n a t e , sodium s a l t , (60% s o l i d s ) L a u r y l a l c o h o l e t h e r s u l f a t e - 4 E 0 , (60% s o l i d s ) E t h y l a l c o h o l Tomah E-14-5 Coco d i e t h a n o l ami de
90% Premi u m Formul a t i on
I n q r e d i e n t s : D e i o n i z e d w a t e r Dodecylbenzene s u l f o n a t e , sodium s a l t , (60% s o l i d s )
e t h e r s u l f a t e - 4 EO, (60% s o l i d s ) L a u r y i a l c o h o E t h y l a l c o h o l Tomah E-14-5 Coco d i e thano ami de
_ _ _ _ ~ - ~ Premi urn F o r m u l a t i o n
I n q r e d i en& D e i o n i z e d wa te r Dodecyl benzene s u l f o n a t e , sod i um s a l t , (60% s o l i d s ) L a u r y l a l c o h o l e t h e r s u l f a t e - 4 E 0 , (6O0h s o l i d s ) E t h y l a l c o h o l Tomah E-14-5 Coco d i e t h a n o l ami de SOURCE: Tomah Produc ts , I n c . : Suggested F o r m u l a t i o n s
Wt.% 59.7 2 5 . 9 ( 15)
8 . 4 ( 5 ) 0 3 3
wt> 52.9 31 . 0 ( 1 8 ) 1 0 . l ( 6 )
1 . 5 3 3
Wt.% 3 8 . 6 3 8 . 8 ( 2 2 . 5 ) 1 2 . 6 ( 7 . 5 )
4 3
Wt.% 2 8 . 3 46.6( 27 ) 15 .1 ( 9 )
4 3 3
Dishwashing Detergents 35
Hand D i s h D e t e r a e n t F o r m u l a t i o n s C l e a r D i shwash
IngredienPs 1 Water SXS (4O%j C12 A i f a O i e f i n s u i f o n a t e (28.75% s o i i d s j L a u r y l e t h e r s u l f a t e - 3 E 0 (27 .5% s o l i d s ) Tomah AO-728 S p e c i a l NaCl*
M i x i ng I n s t r u c t i o n s : Add t h e i n g r e d i e n t s i n t h i s o r d e r . M ix u n t i l homogeneous a f t e r each a d d i t i o n
\N t % 1 2 . 3 0 8 . 0 0
52.50 18 .20 6 . 0 0 3 . 0 0
SpG 2 0 / 2 0 C : 1 .05 pH: 6 V i s c o s i t y : 505 cps ( B r o o k f i e i d LVT 30 rpm s p i n d l e number 2)
NOTES: *Add more Nacl t o i n c r e a s e v i s c o s i t y .
P e a r i escen t U i shwash __
i n g r e d i e n t s : Water Dodecyibenzene s u i f o n a t e (60% s o l i d s ) Caury i e t h e r s u l f a t e - 4 E 0 (60% s o i i d s j O p a c i f i e r La tex (4OWja P e a r l i z i n g Agent ( 4 7 % j * * Tomah A0-728 S p e c i a i Tomah Amphoter ic L
M i x i n g I n s t r u c t i o n s : Add t h e i n g r e d i e n t s i n t h i s o r d e r . M ix u n t i i homogeneous a f t e r each a d d i t i o n .
WLL7O 5 4 . 4 0 25.00
8 . 30 0 . 0 4 2 . 3 0 4 . 0 0 6 . 0 0
SpG 2 0 / 2 0 C : 1 . 03
V i s c o s i t y : 1363 cps ( B r o o k f i e l d LVT, 12 rpm, s p i n d l e number PH: 6 . 5
NOTES: * L y t r o n 295 Mortor! i n t e r n a t i o n a l * * Euper ian PK-771, Henkei
SOURCE: Tomah P r o d u c t s , f n c . : Suggested F o r m u l a t i o n s
36 Advanced Cleaning Product Formulations
Hand Dishwashing L i q u i d
Carbopol r e s i n s can be used t o b u i l d r h e o l o g y i n p l a c e o f u s i n g h i g h e r s u r f a c t a n t l e v e l s . T h i s w i l l improve t h e s k i n f e e l and m i l d n e s s . A d d i t i o n a l l y , because o f t h e i r h i g h y i e l d v a l u e , t h e use o f Carbopol r e s i n s w i l l i n c r e a s e foam s t a b i l i t y .
I n q r e d i e n t : D I Water Carbopol ETD 2623 ( 1 ) 5800 MW p o l y a c r y l i c a c i d ( 2 ) A lpha s u l f o methy l e s t e r (37%) ( 3 ) TEA (99%) Sodium l a u r y l e t h e r s u l f a t e (28%) ( 4 ) Coconut d i e t h a n o l ami de ( 5 )
B r o o k f i e l d v i s c o s i t y (RVT-20 rpm): 400-600 cps Produc t pH: 6.0-7.0 Produc t c l a r i t y : C l e a r
( 1 ) BFGoodrich ( 2 ) BFGoodrich: Good-Rite K-7058 ( 3 ) Stepan Co.: A lphas tep ML-40 ( 4 ) Henkel C o r p . : Standapol ES-3 ( 5 ) Stepan Co. : N i n o l 11-CM
Q 38.11
0 .70 4 . 0 0
27.03 5 . 5 0
17 .86 2 .00
1 .
2 .
3 .
4 . 5 .
Procedure: Use a L i g h t n i n ' M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e f o r genera l m i x i n g and b l e n d i n g o p e r a t i o n s Preheat t h e water t o 40-5OC. Screen t h e Carbopol r e s i n i n t o t h e v o r t e x o f t h e r a p i d l y a g i t a t i n g water (800 rpm). A l l o w t o mix f o r a t l e a s t 15 minu tes o r u n t i l homogeneous and f r e e o f po lymer lumps. Add i n t h e low m o l e c u l a r we igh t p o l y a c r y l a t e w i t h c o n s t a n t m i x i n g . Add i n t h e ASME s u r f a c t a n t w i t h a low l e v e l o f a g i t a t i o n t o a v o i d excess ive foam g e n e r a t i o n . Add i n t h e TEA, l a u r y l e t h e r s u l f a t e , and coconut DEA. A d j u s t t h e pH u s i n g TEA t o reach t h e t a r g e t range. Add c o l o r and per fume, as d e s i r e d . Cool b a t c h t o room tempera ture .
T o t a l A c t i v e s : A lpha s u l f o methy l e s t e r : 10.00 Sodium l a u r y l e t h e r s u l f a t e : 5 . 0 0 Coconut d i e t h a n o l a m i d e : 2 . 0 0 5800 MW p o l y a c r y l i c a c i d : 2 . 0 0
SOURCE: BFGoodrich S p e c i a l t y Chemicals : DET-I10
Dishwashing Detergents 37
Hand Dishwashina Paste
Carbopol r e s i n s a r e used t o t h i c k e n and suspend i n s o l u b l e s i n t h i s hand dishwashing pas te . A d d i t i o n a l l y , because o f t h e i r h i g h y i e l d value, t h e use o f Carbopol r e s i n s w i l l i nc rease t h e foam s t a b i 1 i t y .
I n a r e d i en t : D I water Carbopol 672 ( 1 ) Alkylbenzene s u l f o n i c a c i d (9796) ( 2 ) Sodi um hydrox ide (50%) 2 .4 r sodium s i l i c a t e (52%) (3 ) Sodium t r i po l yphospha te ( 4 ) Sodium carbonate Sodium o l e f i n s u l f o n a t e (40%) (5)
Wt% 41.50
1 .oo 17.00
5.00 7.50
15.00 5 . 0 0 8.00
B rook f i e l d v i scosi t y (RVT-20 rpm) : 75,000 cps Product pH: 10-11 Product c l a r i t y : Opaque
( 1 ) BFGoodri ch ( 2 ) Stepan Co.: B i o s o f t S-100 (3 ) The PO Corp. ( 4 ) FMC Corp. ( 5 ) Stepan Go.: E io te rge AS-40
Procedure: 1 . Use a L i g h t n i n ’ M ixer o r s i m i l a r v a r i a b l e speed u n i t and
i m p e l l e r s u i t a b l e f o r general m ix ing and b lend ing opera t Screen t h e Carbopol r e s i n i n t o t h e v o r t e x o f t h e r a p i d l y a g i t a t i n g water (800 r p m ) . A l low t o mix u n t i l homogeneou and f r e e o f polymer lumps.
2. Add t h e s u l f o n i c a c i d w i t h cont inuous a a i t a t i o n .
an ons.
3 . Add t h e sodium hydrox ide and sodium s i l i c a t e w i t h cont inuous ag i t a t i on. M i x u n t i 1 homogeneous.
4 . Slowly, add t h e phosphate. Mix u n t i l homogeneous and f r e e o f phosphate p a r t i c l e s . Heat ing t h e produc t t o 50-60C w i l l speed up t h i s process.
homogeneous. 5 . Add t h e sodium carbonate and o l e f i n su l fona te . Mix u n t i l
6 . A d d c o l o r and fragrance, as des i red .
T o t a l A c t i ves : Phosphorous con ten t : 3.7 S i l i c a t e (as S i02) : 2.7 Carbonate (as Na2C03): 5 .0 Sodium o l e f i n su l fona te : 3.2 Sodium alkylbenzene su l fona te : 17 .6
SOURCE: BFGoodrich Spec ia l t y Chemicals: DET-111
1
38 Advanced Cleaning Product Formulations
L i g h t Du ty L i q u i d , Premium Hand Dishwash
I n g r e d i e n t s : Water , D . I . W i t c o l a t e SE-5 W i t c o n a t e 1260 S l u r r y W i t cami de 128T P e t r o LBA L i q u i d Sodium S u l f a t e E thano l Formal i n Perfume, Dye
Wt% 30 .2 21 .7 3 6 . 7
5 . 0 1 . 9 2 .6 1 . 8 0 . 1 9 , s .
81 e n d i n g P rocedure :
u s i n g C i t r i c A c i d .
T y p i c a l P r o p e r t i e s :
B lend i n g r e d i e n t s i n t h e o r d e r l i s t e d . A d j u s t pH t o 6 . 5 - 7 . 0
V i s c o s i t y , cps : 230 Appearance: C1 ea r L i q u i d Formula 113
L i g h t D u t y L i q u i d Low Cos t Hand Dishwash
I n g r e d i e n t s : . Water, D . I. W i t c o l a t e SE-5 W i t c o n a t e 1260 S l u r r y W i t cami de 128T P e t r o LBA L i q u i d Sodium C h l o r i d e Formal i n Perfume, Dye
81 . 5 5.5 9 .2 1 . 2 0 . 5 2 .0 0 . 1 q . s .
B l e n d i n g P rocedure :
u s i n g C i t r i c A c i d .
T y p i c a l P r o p e r t i e s :
B l e n d i n g r e d i e n t s i n t h e o r d e r l i s t e d . A d j u s t pH=6 .5 -7 .0
V i s c o s i t y , c p s : 170 Appearance: C l e a r L i q u i d Formula 116
SOURCE: W i t c o Corp . : Suggested F o r m u l a t i o n s
Dishwashing Detergents 39
Liquid A u t o m a t i c Dishwasher D e t e r q e n t
T h i s f o r m u l a t i o n f e a t u r e s Van Gel ES, magnesium aluminum s i l i c a t e , as a suspending agen t and r h e o l o g y m o d i f i e r . The sodium h y p o c h l o r i t e f u n c t i o n s as a d i s i n f e c t a n t , c l e a n i n g agen t and b l e a c h . Sodium m e t a s i l i c a t e a d j u s t s t h e f o r m u l a pH. The phosphate b l e n d p r o v i d e s de te rgency and t h e s u r f a c t a n t s c o n t r i b u t e e x c e l l e n t r i n s a b i l i t y .
I n q r e d i e n t s : A : Van Gel ES
D e i o n i z e d Water
Wt% 4 .00
53.00
B : T e t r a p o t a s s i u m Pyrophosphate, t e c h n i c a l powder 10.00 Sodi um T r i po l yphospha te , t e c h n i c a l powder 20.00
C : Sodium M e t a a s i l i c a t e . Anhydrous Sodium H y p o c h l o r i t e , 12.5% s o l n .
D : Sodium X y l e n e s u l f o n a t e Deceth-4-Phosphate
2.00 8 .00
2.25 0 .75
P rocedure : P rehea t t h e w a t e r t o 55 t o 60C. H y d r a t e t h e Van Gel ES
s l o w l y by a d d i n g i t t o t h e a v a i l a b l e w a t e r u s i n g a h i g h speed d i s p e r s e r . P reb lend B i n g r e d i e n t s , A d d B t o A s l o w l y w i t h m i x i n g . M i x u n t i l u n i f o r m . Add C i n g r e d i e n t s i n t h e o r d e r l i s t e d , m i x i n g u n t i l d i s s o l v e d . C o n t i n u e m i x i n g w h i l e c o o l i n g r a p i d l y t o 25C. F i n a l l y , combine D i n g r e d i e n t s and add w h i l e m i x i n g s l o w l y u n t i l smooth and u n i f o r m ( a v o i d i n c o r p o r a t i o n o f a i r ) .
C o n s i s t e n c y and pH:
LVT, S p i n d l e 4 a t 60 rpm measured a t room t e m p e r a t u r e a f t e r 30 days ag ing ; pH a p p r o x i m a t e l y 12 .5 .
Suggested Packaging: Squeeze b o t t l e o r pump.
SOURCE: R.T. V a n d e r b i l t Co., I n c . : F o r m u l a t i o n No. 438
Pumpable l i q u i d , V i s c o s i t y 1300-1800 cps , B r o o k f i e l d Model
40 Advanced Cleaning Product Formulations
Manual D i shwashi nq Gel
F u n c t i o n s & B e n e f i t s : Carbopol EX-473: * v i s c o s i t y m o d i f i e r f o r h i g h s u r f a c t a n t systems, independent
* p r o v i d e s h i g h c l a r i t y a c r o s s s u r f a c t a n t l e v e l * i m p a r t s y i e l d v a l u e f o r suspens ion o f , f o r i n s t a n c e , encap-
* a b i l i t y t o p o s t - t h i c k e n t r a d i t i o n a l s a l t - t h i c k e n e d systems *easy- to-use, o d o r l e s s , l i q u i d f o r m
o f s u r f a c t a n t t y p e
s u l a t e d a c t i v e s
i n i r e d l e n t : DI w a t e r Carbopol EX-473 ( 3 0 % ) * Sodium c i t r a t e Sodium h y d r o x i d e (18%) Ammonium l a u r y l s u l f a t e (30%)** Sodium l a u r y l e t h e r s u l f a t e (30%)***
W t % 37.50 10 .00
0 . 5 0 2 . 0 0
2 5 . 0 0 2 5 . 0 0
* V i s c o s i t y modi f i e r : BFGoodrich * * A n i o n i c s u r f a c t a n t : Standapol A : Stepan Chemical
* * * A n i o n i c s u r f a c t a n t : Standapol ES-3: Stepan Chemical
P h y s i c a l P r o p e r t i es : B r o o k f i e l d RVT v i s c o s i t y - 2 0 rpm: 8 ,000 C P P roduc t pH: 6 . 5 - 7 . 0 P roduc t c l a r i t y : c l e a r
P rocedure : 1 . Us ing s l o w a g i t a t i o n ( 2 0 0 rpm) p r o v i d e d by a L i g h - t n i n ' m i x e r
o r s i m i l a r v a r i a b l e speed u n - i t and an i m p e l l e r s u i t a b l e f o r g e n e r a l m i x i n g and b l e n d i ng o p e r a t i o n s , add t h e Carbopol EX-473 r e s i n i n t o t h e D I w a t e r . M ix u n t i l u n i f o r m and homogeneous.
2 . Add t h e sodium c i t r a t e . M ix u n t i l t h e sodium c i t r a t e i s c o m p l e t e l y d i s s o l v e d .
3 . A d j u s t t h e pH w i t h sodium h y d r o x i d e t o d e s i r e d pH. 4. Add t h e l a u r y l s u l f a t e and l a u r y l e t h e r s u l f a t e s u r f a c t a n t s
w i t h s l o w m i x i n g t o a v o i d e x c e s s i v e foam g e n e r a t i o n . 5 . Check pH, r e a d j u s t w i t h a d d i t i o n a l sodium h y d r o x i d e i f
necessa ry . 6 . Add f r a g r a n c e and c o l o r , as d e s i r e d .
SOURCE: BFGoodrich S p e c i a l t y Chemicals : DET-130
Dishwashing Detergents 41
__ Manual D i shwashi nq L iqu id
F u n c t i o n s B B e n e f i t s : Carbopol E X - 4 7 3 : * v i s c o s i t y m o d i f i e r f o r h i g h s u r f a c t a n t systems, independent
* p r o v i d e s h i g h c l a r i t y a c r o s s s u r f a c t a n t l e v e l * i m p a r t s y i e l d v a l u e f o r suspens ion o f , f o r i n s t a n c e , encap-
* a b i l i t y t o p o s t - t h i c k e n t r a d i t i o n a l s a l t - t h i c k e n e d systems *easy- to-use, o d o r l e s s , l i q u i d f o r m
o f s u r f a c t a n t t y p e
s u l a t e d a c t i v e s
I n g r e d i en t . D I w a t e r Carbopol EX-473 ( 3 0 % ) Ammonium l a u r y l s u l f a t e (30%)* Sodium l a u r y l e t h e r s u l f a t e ( 3 0 % ) * + Sodium c i t r a t e Sodium h y d r o x i d e (18%)
y t% 4 3 . 0 0
5 . 5 0 2 5 . 0 0 2 5 . 0 0
0 . 5 0 I . oo
* A n i o n i c s u r f a c t a n t : Star idapol A : Stepari Chemical * * A n i o n i c s u r f a c t a n t : Standapol ES-3: Stepan Chemical
P h y s i c a l P r o p e r t i e s : B r o o k f i e l d RVT v i s c o s i t y - 2 0 rpm: 500 CP Produc t p H : 6 .5 -7 .0 P roduc t c l a r i t y : C l e a r
P rocedure : 1 . U s i n g s l o w a g i t a t i o n ( 2 0 0 r p m ) p r o v i d e d by a L i g h t n i n ' M i x e r
o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t i o n s , add t h e Carbopol EX-473 r e s i n i n t o t h e D I w a t e r . M i x u n t i l u n i f o r m and homogeneous.
2 . Add t h e l a u r y l s u l f a t e and l a u r y l e t h e r s u l f a t e s u r f a c t a n t s w i t h s l o w m i x i n g t o a v o i d e x c e s s i v e foam g e n e r a t i o n .
3 . Add t h e sodium c i t r a t e , M ix u n t i l t h e sodium c i t i - a t e i s c o m p l e t e l y d i s s o l v e d .
4 . A d j u s t t h e pH w i t h sodium h y d r o x i d e . 5 . Add f r a g r a n c e and c o l o r , as d e s i r e d .
SOURCE: BFGoodrich S p e c i a l t y Chemicals : DET-120
42 Advanced Cleaning Product Formulations
Non-Ch lo r ina ted Machine D ishwash inq Compound, L i q u i d
I n Q r e d i e n t s : Water , D . I . Sodi um T r i p o l yphosphate Versene 220, Powder Sodi um G1 ucona te Sodium M e t a s i l i c a t e , Pen tahyd ra te C a u s t i c Soda 50% P e t r o ULF L i q u i d
\Mt% 7 9 . 5
2 . 0 1 . o 1 . o 7 . 0 8.5 1 . o
81 end i ng Procedure :
add i t i ons . Add a l l components i n t h e o r d e r shown, m i x i n g w e l l between
Formula 109
C h l o r i n a t e d Machine D i shwashi n q Compound, Powder
I n g r e d i e n t s : Sodi um Carbonate (Soda Ash) , L i g h t D e n s i t y Sodi um T r i p o l yphosphate (STPP) , L i g h t D e n s i t y DeSoni c LFD-97 Sodium M e t a s i l i c a t e , Anhydrous C a u s t i c Soda Beads CDB C l e a r o n
3 0 . 0 2 5 . 0
1 . o 30 .0 10 .0
4 . 0
B l e n d i n g P rocedure : B l e n d i n g r e d i e n t s i n t h e o r d e r l i s t e d , m i x i n g t h o r o u g h l y w i t h
each a d d i t i o n . Formula 111
Non-Ch lo r i n a t e d Machine D i shwashi ng Compound. Powder
I n q r e d i e n t s : Sodi um Carbonate (Soda Ash) , L i g h t D e n s i t y Sodium T r i p o l y p h o s p h a t e (STPP), L i g h t D e n s i t y DeSoni c LFD-97 Sodium Metas i l i c a t e , Anhydrous C a u s t i c Soda Beads
Wt% 33.0 2 5 . 0
2 . 0 3 0 . 0 1 0 . 0
B l e n d i n g P rocedure :
w i t h each a d d i t i o n . B lend i n g r e d i e n t s i n t h e o r d e r l i s t e d , m i x i n g t h o r o u g h l y
Formula 112
SOURCE: W i t c o C o r p . : Suggested F o r m u l a t i o n s
Dishwashing Detergents 43
Premi um Hand D i shwashi ng D e t e r q e n t
I n q r e d i e n t s : Water , D . I . A1 pha-Step MC-48 S t e o l CS-330 N i n o l 30-LL o r N i n o l 40-CO Sodium C h l o r i d e
Wt% 6 .9
56.0 30.0
5 . 6 1 . 5
P r o p e r t i es : Appearance: C l e a r y e l l o w l i q u i d pH, as i s : 6 .5 -7 .5 V i s c o s i t y @ 25 deg. C , cps: 220 S o l i d s , %: 39-40 D e n s i t y , l b s / g a l : 8 . 8 Freeze/ thaw, 3 c y c l e s : Pass C o l d s t o r a g e @ 4 deg. C . , 2 weeks: Pass F l a s h p o i n t , deg. F: >200
M i x i n g P rocedure : CHarge w a t e r . Add MC-48 and CS-330 and m i x . Add 30-LL o r 40-CO
and mix u n t i l homogeneous. S l o w l y add sodium c h l o r i d e t o t h i c k e n . M ix u n t i l c l e a r . A d j u s t p H w i t h s u l f u r i c a c i d o r sodium h y d r o x i d e as necessa ry .
Comment :
o leochemica l r e s o u r c e s and a r e b i o d e g r a d a b l e .
SOURCE: Stepan C o . : F o r m u l a t i o n No. 173
The s u r f a c t a n t s used i n t h i s f o r m u l a t i o n a r e d e r i v e d f r o m
D i s h Washina Aqents f o r Manual Use
I n q r e d i e n t s : Water Lumorol 4154 Z e t e s o l NL Zusol a t 1008/85 Sodium c h l o r i d e F o r m u l a t i o n CT 02-01-04
m e d i en t s : Water Z e t e s o l 2056 Amphotensid B 4 Zusol a t 1008/85 P u r t o n CFD F o r m u l a t i o n CT-02-01-05
7 9 . 0 12.0 6 . 0 1 . o
app rox . 2 . 0
Wt% 76.5 20.0
2 . 0 1 . o 0 .5
SOURCE: Zschimmer & Schwarz GmbH & C o . : Suggested F o r m u l a t i o n s
5. General Purpose
44
General Purpose Cleaners 45
Abrasive Cleaner w i t h Bleach
Carbopol r e s i n s a r e used t o achieve a s t a b l e suspension o f t h e ca l c ium carbonate abras ive o a r t i c l e s i n t h e presence o f c h l o r i n e b leach
l n q r e d i e n t : DI[ Water Carbopol 674 o r 691* Good-Rite K-7058 (50%)** Sodi um hydrox ide (50%) 2 . 4 ~ sodium s i l i c a t e (52%) Sodium h y p o c h l o r i t e (14%) Calc i urn carbonate*** Sodium n-decyl d ipheny lox ide d i s u l f o n a t e (45%
*Suspension a i d : BFGoodrich * *An t i - redepos i t i on : BFGoodrich
+*+Abrasive: White #8 (Georgia Marble) ****Anionic s u r f a c t a n t : Dowfax 382 (Dow Chemi
Physi ea9 Proper t i es : B r o o k f i e l d RVT v i s c o s i t y - 20 rpm: 3,960 cp
Product c l a r i t y : Opaque Product pH: 12-13
Wt% 53.76 0.80 2.00 2.80 2.50 7.14
30.00 **** 1 .oo
~ ~ ~ ~ ~ d ~ r ~ ~ 1 . Using moderate a g i t a t i o n (800 rpm) prov ided by a L i g h t n i n '
M ixer o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t - ab le for general m ix ing and b lend ing opera t ions , d isperse o r screen t h e Carbopol r e s i n i n t o t h e D I water . Mix t h e s l u r r y f o r approx imate ly 15 minutes o r u n t i l t h e s l u r r y i s homogen- eous
2 . Add t h e low molecular weight p o l y a c r y l a t e polymer fo l l owed by t h e sodium hydrox ide and sodium s i l i c a t e . Mix u n t i l homogeneous.
(The produc t w i l l drop i n v i s c o s i t y a t t h i s p o i n t . )
cons tan t a g i t a t i o n . Mix u n t i l homogeneous.
3 . Reduce a g i t a t i o n speed and add t h e sodium h y p o c h l o r i t e bleach.
4. Add t h e ca lc ium carbonate and f i n a l l y t h e s u r f a c t a n t w i t h
5 . Add f ragrance, as des i red .
FGoedrich S p e c i a l t y Chemicals: DET-343
46 Advanced Cleaning Product Formulations
Abras ive Cleaner Wi thout B1 each
Carbopol r e s i n s a re used i n t h i s f o r m u l a t i o n t o achieve a s t a b l e suspension o f t h e h igh l oad ing o f ca lc ium carbonate abras ives . I n s r e d i e n t : D I Water Ethanol Carbopol 674 ( 1 ) Sodium hydrox ide (50%) Sodium b icarbonate Calcium carbonate ( 2 ) C12-15 1 i near a1 coho1 , Coconut d i ethanol ami de
3 moles EO ( 3 ) (4 )
Wt% 62.10
2 . 0 0 0.60 1 .00 1 . 2 0
30.00 2.50 0.60
Brookf i e l d v i scosi t y (RVT-20 rpm) : 4,500 cps Product pH: 8-10 Product c l a r i t y : Opaque
( 1 ) BFGoodr i ch ( 2 ) Georgia Marble Co.: Georgia Marble White #8 (3 ) S h e l l Chemical: Neodol 25-3 ( 4 ) Stepan Co.: N ino l 11-CM
1 .
2 .
3 .
4 .
5 .
Procedure: Add t h e ethanol t o t h e water - h o l d i n g back 10 p a r t s o f water f o r s t e p #3. Using moderate a g i t a t i o n (800 rpm) prov ided by a L i g h t n i n ’ Mixer or s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e f o r general m ix ing and b lend ing opera t ions , d i spe rse o r screen t h e Carbopol r e s i n i n t o t h e D I water/ethanol m ix tu re . M i x t h e s l u r r y for approximately 15 minutes o r u n t i l t h e s l u r r y i s homogeneous. Prepare a n e u t r a l i z i n g s o l u t i o n o f t h e 10 p a r t s o f water w i t h t h e sodium hydrox ide and sodium b icarbonate . Add t h i s t o t h e m ix tu re formed above and mix u n t i l homogeneous. Add t h e ca l c ium carbonate, a lcoho l e thoxy la te and coconut QEA. Mix u n t i l homogeneous. Add fragrance, as des i red .
To ta l Ac t i ves : Ca lc i um carbonate: 30.0 C12-15 l i n e a r a l coho l , 3 moles EO: 2 .5 Coconut DEA: 0 .6
SOURCE: BFGoodrich S p e c i a l t y Chemicals: DET-340
General Purpose Cleaners 47
A l l Purpose C l e a n e r
I n g r e d i e n t s : Urea Na4EOTA Water 2990 Ammonia C a l s o f t L-40 C a l o x y l a t e N-9
Comments abou t t h i s f o r m u l a : Add i n g r e d i e n t s i n o r d e r l i s t e d . F o r m u l a t i o n APC-001-01
A l l Purpose C l e a n e r
I n g r e d i e n t s : Na4EDTA Water, Perfume Dowanol DPnB C a l s o f t L-40
Wei q h t % 2.00 2.00
88 .00 1 . o o 5 .00 2 . 0 0
Wei q h t % 4 .00
84 .00 4.00 8 . 0 0
Comments abou t t h i s f o r m u l a : Compare t o M r . C lean , a t rademark o f P r o c t o r & Gamble. F o r m u l a t i o n APC-002-01
A l l Purpose C leaner
I n q r e d i e n t s : d - L i monene Calamide C Calamide CWT Cal i mu1 se PRS Water
Comments abou t t h i s f o r m u l a : 1 . Add i n g r e d i e n t s f i r s t and m i x . 2 . Add w a t e r s l o w l y . 3 . M ix u n t i l homogeneous.
F o r m u l a t i o n APC-005-01
A l l Purpose C l e a n e r
I n q r e d i e n t s : Water Calamide CWT
Comments abou t t h i s f o r m u l a : Formula t h i c k e n s e f f e c t i v e l y . F o r m u l a t i on APC-003-01
SOURCE: P i l o t Chemical Co. : Suggested F o r m u l a t i o n s
Wei qh t% 40.00
4 .00 4 . 0 0
1 0 . 0 0 42.00
Weight% 85.00 15 .00
48 Advanced Cleaning Product Formulations
A l l Purpose C leaner
I n q r e d i e n t s : Na4EDTA Water Calamide C Calamide CWT P i l o t SXS-40 Laurami ne Oxide
Comments about t h i s f o r m u l a : Add i n g r e d i e n t s i n o r d e r l i s t e d . F o r m u l a t i o n APC-006-01
A l l Purpose C leaner
I n q r e d i e n t s : Na4EDTA Water 50% NaOH Cal s o f t LAS-99 P i l o t SXS-40 Calamide C Calamide CWT
Comments about t h i s f o r m u l a : Add i n g r e d i e n t s i n o r d e r l i s t e d . F o r m u l a t i o n APC-007-01
A l l Purpose C leaner - No Rinse
I n q r e d i e n t s : Water C a l f a x 1OL-45 Na4 EDTA E t h y l e n e G l y c o l Monobutyl E t h e r Calamide CWT
Comments about t h i s f o r m u l a : Spray as i s , t h e n wipe w i t h a paper t o w e l . F o r m u l a t i o n APC-008-01
SOURCE: P i l o t Chemical Co.: Suggested F o r m u l a t i o n s
Wei q h t % 5.00
77 .50 2 . 5 0 2.50 2 . 5 0
1 0 . 0 0
Wei q h t % 5.00
76.10 0 .80 2 . 8 0 5 . 3 0 5 . 0 0 5 . 0 0
Weight% 89.00
3 .00 3 . 0 0 3 . 0 0 2 . 0 0
General Purpose Cleaners 49
A1 1 -Purpose C1 eaner
Composi t i on : Ke lzan xanthan gum A1 i p a l CD-128 Gafamide CDD 518 B u t y l C e l l o s o l ve Sodi urn Metas i 1 i c a t e T r i s o d i urn Phosphate Water , Perfume
0.3 1 . 7 0 . 5 3 . 5 1 . 7 1 . o
91 .3
P rocedure : P repare wa te r s o l u t i o n o f Ke lzan xan than gum by add ing t h e
powder s l o w l y t o t h e s i d e o f t h e v o r t e x w i t h c o n s t a n t a g i t a t i o n . Add o t h e r i n g r e d i e n t s as i n d i c a t e d . Fo r a e r o s o l use, cha rge w i t h a p p r o x i m a t e l y 85 p e r c e n t c o n c e n t r a t i o n and 15 p e r c e n t Genetron 1 2 .
- A l l - P u r p o s e D i s i n f e c t a n t C leaner
Composi ti= Ke lzan xan than gum Makon 10 Sodium T r i p o l y p h o s p h a t e Versene 100 Hyarnine 1OX Water
Q 0.5
1 0 . 0 3 . 0 3 . 0 1 . o
82 .5
P rocedure : P repare w a t e r s o l u t i o n o f Ke lzan xan than gum by add ing t h e
powder s l o w l y t o t h e s i d e o f t h e v o r t e x w i t h c o n s t a n t a g i t a t i o n . Add o t h e r i n g r e d i e n t s as i n d i c a t e d . F o r a e r o s o l use, charge w i t h a p p r o x i m a t e l y 85 p e r c e n t c o n c e n t r a t i o n and 15 p e r c e n t Genetron 1 2 .
SOURCE: Monsanto Per formance M a t e r i a l s : Ke lzan Suggested F o r m u l a t i o n s
A l l Purpose C leaner
l n q r e d i en& Rhodaterge SMC STPP Water
SOURCE: Rhone-Poulenc S u r f a c t a n t s & S p e c i a l t i e s : Suggested F o r m u l a t i o n s
Wt% 1 0 2
88
50 Advanced Cleaning Product Formulations
A l l Purpose C leaner w/Amide/Phosphate E s t e r
I n n r e d i e n t s : Water , D.I. T e t r a p o t a s s i u m Pyrophosphate Varami de A-1 0 Emphos 5AP
Wt% 8 3 . 0
5 . 0 1 0 . 0
2 . 0
81 end i ng P rocedure :
each a d d i t i o n . T y p i c a l P r o p e r t i e s :
V i s c o s i t y , cps : 145 S o l i d s : 17 .0% pH: 8 . 8
Add i n g r e d i e n t s i n o r d e r shown and d i s s o l v e c o m p l e t e l y between
Formula 514
A l l Purpose C leaner
I n g r e d i e n t s : Water W i t c o n a t e 1260 S1 u r r y Wi tcamide 6445
B l e n d i n g P rocedure : B1 end i n g r e d i e n t s i n t h e o r d e r 1 i s t e d .
T y p i c a l P r o p e r t i e s : V i s c o s i t y , c p s : 670 Sol i d s : 33 .0% pH, as i s : 9 . 2
Formula 520
A1 1 Purpose C l e a n e r
I n g r e d i e n t s : Water Sodi um T r i p o l yphosphate C a u s t i c Soda, 50% W i t c o 12988 W i t cami de 6445 Perfume, Dye
B l e n d i n g P rocedure :
Typ i c a l P r o p e r t i es : B lend i n g r e d i e n t s i n o r d e r l i s t e d .
Speci f i c G r a v i t y : 1 . 0 2 0 6 W t . / G a l . l b s . : 8 . 5 pH, as i s : 9 .12 V i s c o s i t y , cps : 107 C o l o r : Be ige
Use D i l u t i o n : 1 -2 o z . / G a l . Formula 535 SOURCE: W i t c o Corp. : Suggested F o r m u l a t i o n s
wto/, 5 6 . 0 3 8 . 5
5 . 5
W S 9 0 . 0
2 . 0 0 . 5 2 . 0 5 . 0 q . s .
General Purpose Cleaners 51
A l l Purpose C leaner C o n c e n t r e (Phosphate, - L i q u i d , Foam)
Soi 1 -Grease and o i 1 S u r f a c e - P a i n t , p o l y m e r i c , me ta l A p p l i c a t i o n Method-Spray Manu fac tu re -M ix t a n k w i t h p r o p e l l e r s t i r r e r
Composi t ion: Water Metso Beads 2048
*Phosphate E s t e r * * D i p r o p y l e n e G l y c o l Monomethyl E t h e r * * *Oc ty lphenoxy P o l y e t h o x y e t h a n o l , 9-10 Moles EO ****Octy lphenoxy P o l y e t h o x y e t h a n o l , 5 Moles EO
Use D i l u t i o n : Normal Duty-1.5% bw ( 2 o z / g a l l o n )
TKPP (60%)
Heavy Duty-2.5% b w ( 3 . 3 o z / g a l 1 on) Tough Duty-as s u p p l i e d
* Rhone-Poulenc Rhodafac RE-610 **( Dow, A rc0 Chemical *** Rhone-Poulenc I g e p a l CA-630 **** Rhone-Poulenc I g e p a l CA-520
A l l Purpose C o n c e n t r a t e (Phosphate, L i q u i d 1
Soi 1-Grease and o i 1 S u r f a c e - P a i n t , p o l y m e r i c , me ta l A p p l i c a t i o n Method-Wipe o r b r u s h Manufacture-Mix t a n k w i t h p r o p e l l e r s t i r r e r
Composi t i on : Water Metso Beads 2048 TKPP Sodium Xy lene S u l f o n a t e , 40% * E t h y l e n e G l y c o l n - B u t y l E t h e r P i n e O i l * * L i q u i d N o n i o n i c S u r f a c t a n t (C12-Cl3, 6 . 5 Moles EO) * * * L i q u i d N o n i o n i c S u r f a c t a n t (C12-Cl5, 3 Moles EO)
Use D i 1 u t i on: 1 .5-3.0% bw (2 -4 o z / g a l l on )
* Dow Chemical , Union C a r b i d e *l Rhone-Poul enc Rhodasur f LA-7 * S * Rhone-Poulenc Rhodasur f A-24
SOURCE: PQ C o r p . : D e t e r g e n t F o r m u l a t i o n Guide
Wt% 78 .1
2 .4 3 . 0 3 . 0 6 . 0 5 . 0 2 . 5
wto/, 78.75
1 . o o 3.00 3 . 5 0 6 . 0 0 0 . 2 5 5 . 0 0 2 .50
52 Advanced Cleaning Product Formulations
Calcium Carbonate Abras ive Cleaner Wi thout Bleach
Carbopol r e s i n s a r e used i n t h i s f o r m u l a t i o n t o achieve a s t a b l e suspension o f t h e h igh l oad ing o f ca lc ium carbonate abras ives . I n q r e d i en t : D I Water Carbopol ETD 2623 ( 1 ) Sodium hydrox ide (50%) C12-I5 l i n e a r a l coho l , 3 moles EO (2 ) Sodium a l k y l benzene su l fona te ( 3 ) Calcium carbonate ( 4 )
62.10 0 . 2 5 0 .20 1 .50 0.50
30.00
Phys ica l Proper t i es : B r o o k f i e l d V i s c o s i t y (RVT-20 rpm): 7,500 cp Product pH: 8-10 Product C l a r i t y : Opaque
Raw M a t e r i a l Supp l i e rs : ( 1 ) BFGoodrich ( 2 ) S h e l l Chemical Co.: Neodol 25-3 (3 ) Stepan Co. : Nacconol SQG ( 4 ) Georgia Marble C o . : Georgia Marble White #8
Procedure: 1 . Using moderate a g i t a t i o n (800 rpm) prov ided by a L i g h t n i n '
M ixer o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t - ab le f o r general m i x i ng and b l endi ng opera t ions , d i sperse o r screen t h e Carbopol r e s i n i n t o t h e D I water. Mix t h e s l u r r y f o r approximately 15 minutes or u n t i l t h e s l u r r y i s homogeneous.
w i l l become ve ry t h i c k a t t h i s p o i n t .
ac tan ts . Mix u n t i l homogeneous.
2. Add t h e sodium hydrox ide t o reach t a r g e t pli. The produc t
3 . Add t h e a l coho l e thoxy la te and alkylbenzene s u l f o n a t e surf-
4 . Add t h e ca lc ium carbonate. Mix u n t i l homogeneous. 5. Add fragrance, as des i red .
To ta l Ac t i ves : Calcium carbonate: 30.00 C12-15 l i n e a r a l coho l , 3 moles EO: 1.50 Sodium a1 kylbenzene su l fona te : 0 . 5 0
SOURCE: BFGoodrich Spec ia l t y Chemicals: BET-341
General Purpose Cleaners 53
C i t r i c A c i d Cleaner
Functiane 8 B e n e f i t s : Carbopol ETD 2623: *Provides low p H t h i c k e n i n g v i a hydrogen bonding w i t h s u r f -
* Impar ts y i e l d va lue f o r suspension o f abras ive p a r t i c l e s *Provides v e r t i c a l c l i n g f o r inc reased su r face con tac t t i m e *Shear t h i n n i n g rheology f o r easy d ispens ing through t r i g g e r
*Easy-to-disperse r e s i n f o r improved and eas ie r f u l l - s c a l e
ac tan t
sprayer o r nozz le
p rocess ing
Inqiredi en t : Wt% DI Water 78.40 Carbopo? ETD 2623 Resin* C12-15 l i n e a r a l coho l , 3 moles EO** C12-13 l i n e a r a l coho l , 6 .5 moles EO*** Alkylbenzene s u l f o n i c acid**** C i t r i c A c i d (50%)
0.10 5.00 2.50 2.00
12.00
*V i scos i t y modi f i e r : BFGoodr i ch s W o n i o n i c s u r f a c t a n t : Neodol 25-3: She1 1 Chemical
>N**Nonionic s u r f a c t a n t : Neodol 23-6.5: She l l Chemical * * r *An ion ic s u r f a c t a n t : B i o s o f t 5-100: Stepan
P h y s i c a l P r o p e r t i ee: Storage Temperature
B r o o k f i e l d RVT v i scos i t y -20 rpm: I n i t i a l : 50cP 50cP
Age-Up V i s c o s i t y : Week 2 : 170cP 400cP Week 4: 250cP 600cP Week 6: 350cP 400cP
Product pH: 1 . 4 Product c l a r i t y : T rans lucent
-. 25C 5oc
Procedurw: 4 . Using J marine b lade p r o p e l l e r and r a p i d a g i t a t i o n (800 rpm)
prov ided by a L i g h t n i n ' M ixer o r s i m i l a r v a r i a b l e speed u n i t , s p r i n k l e t h e Carbopol ETD 2623 r e s i n i n t o t h e v o r t e x . A l l ow t o hyd ra te f o r 15-20 minutes or u n t i l no lumps a r e present . Warming t h e de ion ized water t o 30C w i l l decrease t h e h y d r a t i o n t i m e and improve t h e d i s p e r s i b i l i t y o f t h e Carbopol powder.
needed) t o ensure homogeneity. A d d w i t h moderate m ix ing (300 rpm). A l low t o mix u n t i l un i fo rm and smooth.
a l l o w t o mix u n t i l un i fo rm and smooth.
u n t i l smooth and un i fo rm.
2 . M i x t h e Neodol 25-3 and Neodol 23-6.5 ( o r warm s l i g h t l y i f
3. Add t h e B i o s o f t S-100 w i t h moderate (300 rpm) mix ing and
4. S ~ O W ~ Y add t h e C i t r i c Ac id w i t h s low m ix ing (200 r p m ) . M i x
5 . Add f ragrance and c o l o r , as des i red .
SOURCE: BFGoodr ick S p e c i a l t y ChemicaJs: DET-352
54 Advanced Cleaning Product Formulations
Genera l Purpose C1 eaner (Consumer Low Alkaline, Non-Phasphate Powder)
S o i l - F o o d ( f a t and p r o t e i n ) , p e t r o l e u m o i l and grease, c l a y
Sur face -Hard s u r f a c e , i . e . , m e t a l , p l a s t i c , ce ramic , c o n c r e t e ,
Appl i c a t i on Method-Wi pe o r Brush Manu fac tu re -Dry b l e n d / A g g l o m e r a t i o n
and p a r t i c u l a t e s o i l
and a s p h a l t
Composi t i on : Wt% Sodi um Carbonate ( 1 i g h t d e n s i t y ) 3 0 . 0 * B r i t e s i 1 C20 Hydrous P o l y s i 1 i c a t e 1 0 . 0 * * L i q u i d N o n i o n i c S u r f a c t a n t (C12-Cl5; 9 Moles EO) 15.0 V a l f o r 100 Z e o l i t e A 30 .0 ***Acusol 445ND Sodium P o l y a c r y l a t e (92% S o l i d s ) 0 . 5 Sodi um S u l f a t e 1 4 . 5
Use L e v e l : 1-4 o z / g a l l o n
* 2.0 w e i g h t r a t i o s i l i c a t e powder, 82.5% s o l i d s ** Rhone-Poulenc Rhodasur f LA-9 *** Rohm & Haas
Genera l Purpose C l e a n e r (Consumer H i g h A1 k a l i ne, Non-Phosphated Powder1
Soi -Food ( f a t and p r o t e i n ) , p e t r o l e u m o i l and grease, c l a y
Sur ace-Hard s u r f a c e , i . e . , m e t a l , p l a s t i c , ce ramic , c o n c r e t e ,
App i c a t i o n Method-Wipe o r b r u s h Manu fac tu re -Dry b l e n d / A g g l o m e r a t i o n
and p a r t i c u l a t e s o i l
and a s p h a l t
Composi t i o n 1 Wt% Sodium S u l f a t e 1 4 . 5 Sodi um Carbonate ( 1 i g h t d e n s i t y ) 3 0 . 0 * L i q u i d N o n i o n i c S u r f a c t a n t ( C 1 2 - C l 5 ; 9 Moles EO) 1 5 . 0 V a l f o r 100 Z e o l i t e A 3 0 . 0 Metso Beads 2048 1 0 . 0 **Acusol 445ND Sodium P o l y a c r y l a t e (92% S o l i d s ) 0 . 5
Use L e v e l : 1-4 o z / g a l l o n
* Rhone-Poulenc Rhodasur f LA-9 ** Rohm & Haas
SOURCE: PQ Corp. : D e t e r g e n t F o r m u l a t i o n Guide
General Purpose Cleaners 55
Genera l Purpose Spray & Wipe C l e a n e r
Carbopol r e s i n s a r e used t o i n c r e a s e t h e y i e l d v a l u e r e s u l t i n g i n v e r t i c a l c l i n g when sprayed on a v e r t i c a l s u r f a c e . T h i s " n o - d r i p " a c t i o n w i l l i n c r e a s e t h e c o n t a c t t i m e o f t h e d e t e r g e n t on t h e s o i l e d s u r f a c e as w e l l as enhance consumer conven ience .
I n g r e d i e n t : D I Water Carbopol ETD 2 6 9 1 ( 1 ) EDTA ( t e t r a sodium s a l t ) Sodium m e t a s i l i c a t e , anhydrous P r o p y l ene g l y c o l me thy l e t h e r ( 2 ) C12-15 l i n e a r a l c o h o l , 7 moles EO ( 3 )
wto/, 9 0 . 7 0
0 . 2 0 2 . 0 0 2 . 3 0 3 . 0 0 1 . 5 0
B r o o k f i e l d v i s c o s i t y (RVT-20 rpm) : 120 cps P roduc t p H : 12-13 P roduc t C l a r i t y : C l e a r t o hazy
( 1 ) BFGoodri ch ( 2 ) Dow Chemical : Dowanol DPM ( 3 ) S h e l l Chemical : Neodol 25-7
P rocedure : 1 . U s i n g moderate a g i t a t i o n (800 rpm) p r o v i d e d by a L i g h t n i n '
M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t i o n s , d i s p e r s e o r sc reen t h e Carbopol r e s i n i n t o t h e D I w a t e r . M i x t h e s l u r r y f o r a p p r o x i m a t e l y 15 m inu tes or u n t i l t h e s l u r r y i s homogen- eous.
2 . Under s l i g h t a g i t a t i o n , add t h e EDTA and M e t a s i l i c a t e . 3 . C o n t i n u e a g i t a t i o n and add t h e g l y c o l e t h e r and a l c o h o l
4 . Add c o l o r and f r a g r a n c e , as d e s i r e d .
T o t a l A c t i v e s :
e t hoxy 1 a t e .
P ropy lene g l y c o l me thy l e t h e r : 3 . 0 C12-I5 l i n e a r a l c o h o l , 7 moles EO: 1 . 5
SOURCE: BFGoodrich S p e c i a l t y Chemicals : DET-310
56 Advanced Cleaning Product Formulations
Genera l Purpose Spray & Wipe
I n g r e d i e n t s : Water, D.I. Sodi um C i t r a t e A1 pha-Step MC-48 S tepano l WA-Extra N i n o l 11-CM
Wt% 79.0
2 . 0 1 0 . 0
7 . 0 2 . 0
M i x i n g Procedure:
m ix u n t i 1 homogeneous.
Typ i c a l P r o p e r t i es :
Charge w a t e r and s u r f a c t a n t s and m i x . Add sodium c i t r a t e and
Appearance: C l e a r c o l o r l e s s l i q u i d pH, as i s : 9 .4 V i s c o s i t y I3 25 deg. C : Very t h i n S o l i d s , %: 1 0 . 0 D e n s i t y , l b s / g a l : 8 .54 Co ld s t o r a g e @ 4 deg. C, 1 day: pass Freeze/ thaw, 3 c y c l e s : pass
Per formance: Gardner S t r a i g h t L i n e W a s h a b i l i t y T e s t :
Commercial P r o d u c t - 66% s o i l removed f r o m t i l e s Above f o r m u l a t i o n - 82%' s o i l removed f r o m t i l e s Above f o r m u l a t i o n p e r f o r m s b e t t e r t h a n commerc ia l p r o d u c t .
Use I n s t r u c t i o n s : Use as i s
Comment :
o leochemica l r e s o u r c e s and a r e b i o d e g r a d a b l e .
SOURCE: Stepan Co. : Suggested F o r m u l a t i o n No. 575
The s u r f a c t a n t s used i n t h i s f o r m u l a t i o n a r e d e r i v e d f r o m
A1 1 -Purpose C1 eaner
I n g r e d i e n t s : Water Z e t e s o l 2056 Z u s o l a t 1008/85
8 2 . 0 14 .0 4 . 0
SOURCE: Zschimmer & Schwarz GmbH & Co. : F o r m u l a t i o n CT 02-04-02
General Purpose Cleaners 57
H y p o c h l o r i t e V e r t i c a l S u r f a c e C l e a n e r
Monatrope 1250 i s a h y p o c h l o r i t e s t a b l e s u r f a c t a n t t h a t c o n t r i b u t e s t o w e t t i n g and foaming c h a r a c t e r i s t i c s .
I n q r e d i e n t s : Monatrope 1250 Sodium C14-17 A l k y l Sec S u l f o n a t e (60%) Laurami ne Oxide (30%) Potass ium H y d r o x i d e (45%) Sodi um T r i p o l y p h o s p h t e Sodium H y p o c h l o r i t e 5.25%)
Wt% 2 . 0 2 .0
1 0 . 0 15.0
5 . 0 6 6 . 0
P rocedure : Add i n g r e d i e n t s w
T y p i c a l P r o p e r t i e s : Appearance: C l e a r p H : 13
t h a g i t a t i o n .
y e l l o w l i q u i d
Recommended Use D i l u t i o n : 1:lO w i t h w a t e r Formul a t i on F-783
Pump Sprav A l l Purpose C l e a n e r
A f a s t a c t i o n sp ray and w ipe f o r m u l a t i o n . S u r f a c e s w i l l d r y s t r e a k - f r e e .
I n q r e d i e n t s : Water Monaterge 779 (DEA-Laureth S u l f a t e ) P ropy lene G l y c o l B u t y l E t h e r
Wt% 94 .0
3 . 0 3 . 0
P rocedure : Add i n g r e d i e n t s i n t h e o r d e r l i s t e d w i t h a g i t a t i o n . Package.
T y p i c a l P r o p e r t i e s : Appearance: C l e a r l i q u i d
Recommended Use D i 1 u t i o n : As i s
SOURCE: Mona I n d u s t r i e s , I n c . : Suggested F o r m u l a t i o n s
58 Advanced Cleaning Product Formulations
L i q u i d C1 eanser w i t R B1 each
I n t h i s f o r m u l a Van Gel B i s used t o suspend t h e a b r a s i v e and t o a d j u s t t h e v i s c o s i t y . The sodium carbonate b u f f e r h e l p s m a i n t a i n a pH o f about 11, necessary f o r t h e s t a b i l i t y o f t h e h y p o c h l o r i t e . T h i s l i q u i d c l e a n s e r o f f e r s t h e advantage o f m i l d - ness i n use and g r e a t e r ease and e f f e c t i v e n e s s on v e r t i c a l s u r f a c e s as compared t o powders.
I n g r e d i e n t s : A : Van Gel B
Water
6 : Diatomaceous E a r t h Sodium c a r b o n a t e Sodium h y p o c h l o r i t e , 5 .25% s o l n . Sodium L a u r y l S u l f a t e , 29% s o l n .
2 . 2 5 6 2 . 2 5
'10.00 4.50
2 0 . 0 0 1 . o o
Procedure:
a v a i l a b l e shear . Cont inue m i x i n g u n t i l smooth. Add remain ing i n g r e d i e n t s i n o r d e r , m i x i n g w e l l a f t e r each a d d i t i o n .
Cons is tency : Medium v i s c o s i t y l i q u i d .
Suggested Packaging: P l a s t i c squeeze b o t t l e .
SOURCE: R.T. V a n d e r b i l t Co. , I n c . : F o r m u l a t i o n N o . 391
S l o w l y add Van Gel B t o t h e water w h i l e a g i t a t i n g a t maximum
I n g r e d i e n t s : A: Hostapur SAS 60
Genapol ZRO 1 i q u i d Genapol UD-080
B : Water Perfume P r e s e r v a t i v e Dye
A l l Purpose C leaner C l e a r , l i q u i d
W t %
0 . 0 - 4 . 0 1 . 0 - 3 . 0
10.0-15.0
ad 1 0 0 . 0 0 . 2 0 . 1 q . s .
M a n u f a c t u r i n g : Add one a f t e r a n o t h e r , t h e components o f B t o A .
Modern s t a n d a r d f o r m u l a t i o n s a r e based on a lkansu lphonates and non i o n i c s . E t h e r s u l p h a t e s a r e used i n r a r e cases. Phosphates, sodium carbonate and ammonia a r e n o t common any 1 onger . The above g u i d e f o r m u l a t i o n c o v e r s t h e common european p r o d u c t s .
SOURCE: Hoechst A k t i e n g e s e l l s c h a f t : Suggested F o r m u l a t i o n
I n g r e d i e n t s : P i n e o i l N i n o l 11-CM Makon 12 Ammonyx LO B i o - S o f t S-1 00 I s o p r o p a n o l Water, D . I .
General Purpose Cleaners 59
P i n e O i l Cleaner C o n c e n t r a t e
g 20 .0
9 . 0 5 . 0 0 . 5 2 .0
1 0 . 0 5 3 . 5
M i x i ng Procedure :
w a t e r s l o w l y w h i l e under a g i t a t i o n . M i x u n t i l c l e a r . P r o p e r t i e s :
Combine p i n e o i l , s u r f a c t a n t s and IPA . M i x u n t i l c l e a r . Add
Appearance: C l e a r y e l l o w l i q u i d Odor: P i n e V i s c o s i t y @ 25C, cps: 50 pH (as i s ) : 8 . 1 D e n s i t y 1 b s / g a l : 8 . 0 6 Freeze/Thaw ( 3 c y c l e s ) : Pass 50 C oven ( 1 week): Pass
Use I n s t r u c t i o n s : D i l u t e 1-2 o z s i n t o one g a l l o n Per formance:
Gardner S t r a i g h t L i n e W a s h a b i l i t y T e s t : Above f o r m u l a t i o n : 73.0% s o i l removed f r o m t i l e s Commercial f o r m u l a t i o n : 55.5% s o i l removed f r o m t i l e s
SOURCE: Stepan Co.: F o r m u l a t i o n No. 208
D i s i n f e c t i n g Cleaner , A l k a l i n e
I n g r e d i e n t s : Water C i t r i c a c i d Z u s o l a t 1008/85 Lumorol 4192 T r i l o n A l i q u i d Lonzabac-1230 I n g r e d i e n t s : Water Disodium t e t r a b o r a t e decahydra te Sodi um b i c a r b o n a t e Burdac-114 Zusol a t '1008/85 I n g r e d i e n t s : Water T r i l o n A l i q u i d C i t r i c a c i d Su l f e t a l 4069 Zusol a t 1008/85 Lonrabac-1230
Wt% 57.5
2 . 0 3 .5 5 . 0 7 . 0
25 .0 Wt%
6 9 . 0 0 . 5 1 . 0
20 .0 9 . 5 g
57 .5 7 .0 2 . 0 5 . 0 3 .5
2 5 . 0
SOURCE: Zschimmer & Schwarz GmbH & Co.: F o r m u l a t i o n s CT 06-09-01, CT 06-09-02, CT 06-09-03
60 Advanced Cleaning Product Formulatiorrs
Sodi urn B i c a r b o n a t e A b r a s i v e C leaner W i t h o u t B leach
Carbopol r e s i n s a r e used i n t h i s f o r m u l a t i o n t o a c h i e v e a s t a b l e suspens ion o f t h e h i g h l o a d i n g o r sodium b i c a r b o n a t e a b r a s i v e s .
- I n g r e d i e n t : D I Water Carbopol ETD 2691 ( 1 ) A l k y l benzene s u l f o n i c a c i d ( 2 ) C12-13 l i n e a r a l c o h o l , 6 . 5 moles € 0 ( 3 ) Sodium h y d r o x i d e (50%) Sodium b i c a r b o n a t e ( 4 ) :
Grade 1 : Grade 5 :
wtsl, 44.25
0 . 5 0 0 . 7 5 2 .50 2 . 0 0
2 0 . 0 0 3 0 . 0 0
P h y s i c a l P r o p e r t i e s : B r o o k f i e l d V i s c o s i t y (RVT-20 rprn): 6 ,000 c p P roduc t p H : 8 . 5 0 P roduc t C l a r i t y : Opaque
Raw M a t e r i a l S u p p l i e r s : ( 1 ) BFGoodrich ( 2 ) Stepan Co.: B i o s o f t 5-100 ( 3 ) S h e l l Chemical Co.: Neodol 23-6.5 ( 4 ) Church & Dwight
Procedure: 1 . U s i n g moderate a g i t a t i o n ( 8 0 0 r p m ) p r o v i d e d by a L i g h t n i n '
M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t i o n s , d i s p e r s e or sc reen t h e Carbopol r e s i n i n t o t h e D I w a t e r . M i x t h e s l u r r y f o r a p p r o x i m a t e l y 15 m i n u t e s o r u n t i l t h e s l u r r y i s homogen- eous.
e t h o x y l a t e . M i x u n t i l homogeneous.
t o 8 . 5 0 p r i o r t o t h e n e x t s t e p .
M ix u n t i l smooth, homogeneous, and f r e e o f b i c a r b o n a t e lumps. Re-check pH and a d j u s t , i f necessa ry .
2 . Add t h e a l k y l b e n z e n e s u l f o n i c a c i d f o l l o w e d by t h e a l c o h o l
3 . Add t h e sodium h y d r o x i d e . M i x u n t i l homogeneous. A d j u s t pH
4 . W i t h m in ima l a g i t a t i o n , s l o w l y add t h e sodium b i c a r b o n a t e .
5 . Add c o l o r and f r a g r a n c e , as d e s i r e d .
T o t a l A c t i ves : Sodi um b i c a r b o n a t e : 5 0 . 0 0 C12-13 l i n e a r a l c o h o l , 6 . 5 moles EO: 2 . 5 0 Sodium a1 k y l benzene s u l f o n a t e : 0 . 9 0
SOURCE: BFGoodrich S p e c i a l t y Chemicals : DET-342
leaners/Polishes
61
62 Advanced Cleaning Product Formulations
A n t i -Foggi ng , A n t i -Stat i c G lass C l eaner
I n g r e d i e n t s : Water I s o p r o p y l A l c o h o l Adogen 66 Varox 365 Emcol 4500
MIBo/o 9 0 . 0
9 . 0 0 . I 0 . 5 0 . 4
B l e n d i n g I n s t r u c t i o n s :
I f p r o d u c t i s hazy, a d d i t i o n a l I s o p r o p y l A l c o h o l can be used t o c l a r i f y t h e s o l u t i o n . G e n t l y h e a t i n g can be used t o f a c i l i t a t e m i x i n g o f t h e Emcol 4500.
Use I n s t r u c t i o n s :
w ipe o n t o t h e g l a s s . A l l o w t o d r y .
P roduc t I n f o r m a t i o n : P r o d u c t : B e n e f i t : Varox 365 W e t t i n g agen t , deg reaser and d e t e r g e n t Adogen 66 A n t i - s t a t i c agen t Emcol 4500 W e t t i n g agen t , c o u p l e r and d e t e r g e n t
Combine i n g r e d i e n t s i n t h e o r d e r shown and mix t h o r o u g h l y .
App ly f i n i s h e d p r o d u c t t o a t o w e l l e t e (Kimwipe, e t c . ) and
T h i s f o r m u l a t i o n p r e s e n t s a t h i n b a r r i e r between t h e w a t e r vapor ( f o g , steam, e t c . ) and t h e g l a s s wh ich w i l l p r e v e n t f ogg ing . The a b i l i t y t o l o w e r t h e s u r f a c e t e n s i o n o f t h e w a t e r p r e v e n t s t h e c l i n g i n g o f i n d i v i d u a l w a t e r d r o p l e t s t o t h e g l a s s ; t h e r e f o r e l i g h t i s n o t s c a t t e r e d as much as i t i s when p a s s i n g t h r o u g h i n d i v i d u a l d r o p l e t s .
Formula 708
G lass C leaner , Ready t o Use
I n g r e d i e n t s : Water, D . I . P e t r o BAF L i q u i d I s o p r o p a n o l E t h y l e n e G l y c o l Monobuty l E t h e r Dye
B l e n d i ng P rocedure : B l e n d i n g r e d i e n t s i n t h e o r d e r 1 i s t e d . Formula 705
SOURCE: W i t c o Corp. : Suggested F o r m u l a t i o n s
84 .9 0 . 1
1 0 . 0 5 .0 q . s .
Glass CleanerslPolishes 63
Glass C l e a n e r C o n c e n t r a t e (Non-Ammoniated)
I n g r e d i e n t s : Water , D . I. I s o p r o p a n o l , 99% P e t r o LBA Powder Monoethanol ami ne Perfume, Dye
K% 7 . 5
82 .0 1 . o 0 . 5 q. s
B l e n d i n g Procedure: B l e n d i n g r e d i e n t s i n t h e o r d e r l i s t e d .
T h i s c o n c e n t r a t e s h o u l d be mixed w i t h n i n e p a r t s of w a t e r t o one p a r t c l e a n e r t o be ready t o use . T h i s p r o d u c t r e q u i r e s a r e d l a b e l .
Formula 702
G l a s s C leaner C o n c e n t r a t e
I n q r e d i e n t s : Water, D . I . P e t r o BAF L i q u i d DeSonic 5 N Ammonia, 29% Dye
B l e n d i n g Procedure: B l e n d i n g r e d i e n t s i n t h e o r d e r l i s t e d .
Use D i l u t i o n : 1 p a r t c o n c e n t r a t e t o 50 p a r t s w a t e r . Formula 703
Amrnoniated G lass C leaner
m r e d i e n t s : Water W i t c o l a t e 231 0 B u t y l C e l l o s o l ve Aqua Ammonia, 26 Be '
B l e n d i n g Procedure: B lend i n g r e d i e n t s i n t h e o r d e r l i s t e d . Formula 704
SOURCE: W i t c o C o r p . : Suggested F o r m u l a t i o n s
Wt% 7 7 . 0 20 .0
1 . o 2 .0 q . s .
Wt% 9 4 . 0
3 . 0 2 . 0 2.0
64 Advanced Cleaning Product Formulations
Glass and Window Cleaner
Carbopol r e s i n s a r e used t o inc rease t h e y i e l d va lue r e s u l t i n g i n v e r t i c a l c l i n g when sprayed on a v e r t i c a l sur face . T h j s "no-dr ip " a c t i o n w i l l i nc rease t h e con tac t t i m e o f t h e de tergent on t h e s o i l e d su r face as w e l l as enhance consumer convenience.
I n a r e d i e n t : D I Water Carbopol ETD 2623 Isopropanol Ammonium hydrox ide Alkylbenzene s u l f o n i c a c i d (97%) (2 ) Propylene g l y c o l methyl e the r (3)
wel 92 * 45
(4.10 5.00 0.20 0 .25 2.00
Phys ica l P roper t i es : Brookf i e l d V i scosi t y (RVT-20 rpm) : 200 cp Product pH: 9.5-10.0 Product C l a r i t y : Clear
Raw Mate r i a1 Suppl i e r s : ( 1 ) BFGoodrich ( 2 ) Stepan Chemical: B i o s o f t 5-100 (3 ) Dow Chemical: Dowanol PM
Procedure: 1 . Using moderate a g i t a t i o n (800 rpm) prov ided by a L i g h t n i n '
M ixer o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e f o r general m ix ing and b lend ing opera t ions , d i spe rse o r screen t h e Carbopol r e s i n i n t o t h e D I water . Mix t h e s l u r r y f o r approx imate ly 15 minutes o r u n t i l t h e s l u r r y i s homogen- eous.
2 . Add t h e isopropano l . 3 . Add t h e ammonium hydrox ide . M i x u n t i l homogeneous. 4 . Add t h e s u l f o n i c a c i d and g l y c o l e the r w i t h minimal a g i t a t i o n
5 . Add a d d i t i o n a l ammonium hydroxide, i f necessary, t o reach the
6 . Add c o l o r and fragrance, as des i red .
To ta l Ac t i ves :
t o a v o i d excessive foaming.
t a r g e t pH range.
Ammonium alkylbenzene su l fona te : 0 . 3 0 Propylene g l y c o l methyl e the r : 2 .00 Isopropano l : 5.00
SOURCE: BFGoodrich S p e c i a l t y Chemicals: DET-300
Glass CleanerslPolishes 65
Household Window C leaner
I n q r e d i e n t s : Water . D . I . I s o p r o p a n o l Varox 365 Me thy lene B l u e
Wt% 89 .3 1 0 . 0
0 .7 q . s .
B l e n d i n g P rocedure :
each a d d i t i o n .
T y p i c a l P r o p e r t i es : V i s c o s i t y , c p s : 4 S o l i d s : 0 . 2 % pH: 7 . 4
Add i n g r e d i e n t s i n o r d e r shown and d i s s o l v e c o m p l e t e l y between
Formula 706
Bremi u m Household W i ndow C1 eaner
I n g r e d i e n t s : Water , D . I . I s o p r o p a n o l Varox 1770 Methy lene B l u e
Q 89.4 1 0 . 0
0 . 6 q. s
81 end i ng Procedure :
each add i t i on.
T y p i c a l P r o p e r t i e s : V i s c o s i t y , c p s : 4 So l i d s : 0.23% pH: 6 . 2
Add i n g r e d i e n t s i n o r d e r shown and d i s s o l v e c o m p l e t e l y between
Formula 707
GI ass @1 eaner
I n g r e d i e n t s : Water . D . I . I s o p r o p a n o l Dowanol EB R e w o t e r i c AM V
Wt% q . s . 6.0 4 . 0 0 .85
81 endi ng Procedure :
ween each a d d i t i o n . Formula 709
SQURCE: W i t c o Gorp . : Suggested F o r m u l a t i o n s
B l e n d i n g r e d i e n t s i n t h e o r d e r shown, m i x i n g t h o r o u g h l y b e t -
66 Advanced Cleaning Product Formulations
W i n d o w s / G l ass
Gl-ass Cl gangr CConcentrate)
I n g r e d i e n t s : Water E t h y l e n e G l y c o l Monobuty l E the r I s o p r o p y l A l c o h o l Ammonia, 29.4% Cal foam SLS-30
Comments abou t t h i s f o r m u l a : Add i n g r e d i e n t s i n o r d e r l i s t e d F o r m u l a t i o n WIN-001-01
W i n-dzhield Washer C c n c e n t r a t e
Ingredients : Water I s o p r o p y l A l c o h o l Calsuds 81
Comments abou t t h i s f o r m u l a : Use 4 0 2 . o f t h e c o n c e n t r a t e p e r g a l l o n . F o r m u l a t i o n WIN-002-01
W i ndshjeld-pWashec Concen tya te (Low VOC)
I ng r e d i-en t s : Water P r o p y l ene G1 y c o l Calsuds 81
Comments abou t t h i s f o r m u l a Use l e v e l : 2-4 o z p e r g a l l o n . F o r m u l a t i o n WIN-003-01
SOURCE: P i l o t Chemical Co . : Suggested F o r m u l a t i o n s
We i s h t YO 10 .04 21.34 53 .30
2 . 3 5 5 . 0 0
Weigh_% 47.66 47.30
5 .10
We i gh ts/, 62.20 33.80
4.02
ard Surface Cleaners
67
68 Advanced Cleaning Product Formulations
A l k a l i n e Hard S u r f a c e C leaner
I n g r e d i e n t s : Water, D . I . Sodi um Metas i 1 i c a t e Varami de A-83 W i t c o n a t e 30DS W i t c o n a t e SXS L i q u i d
3 4 . 0 8 . 0
1 2 . 0 40.0
8 . 0
81 end ing Procedure:
each a d d i t i on.
T y p i c a l P r o p e r t i e s : V i s c o s i t y , c p s : 205 Sol i ds : 34 .4% pH: 12.5
Formula 516
Add i n g r e d i e n t s i n o r d e r shown and d i s s o l v e c o m p l e t e l y between
Hard S u r f a c e CleaEer C o n c e n t r a t e ( A l l Purpose Type)
I n g r e d i e n t s : Water, D . I . T e t r a s p o t a s s i u m Pyrophosphate, Anhydrous W i t cami de 1 PET Emphos 5AP W i t c o 1298SA
\Ne% 8 2 . 0 1 0 . 0
1 . o 4 .0 3 . 0
B l e n d i n g P rocedure :
a d d i t i o n .
T y p i c a l P r o p e r t i e s :
B l e n d i n g r e d i e n t s i n o r d e r l i s t e d , m i x i n g w e l l a f t e r each
S p e c i f i c G r a v i t y : 1 .085 Wt . /Ga l . l b s : 9 . 0 4 pH, as i s : 7 .57 V i s c o s i t y , cps : 94 3 Freeze/Thaw c y c l e s : Passed 1 Week @ 52C: Passed 4 Weeks Room Temp: Passed S o l i d s : 17.8% Appearance: C 1 e a r L i q u i d
Use D i l u t i o n : 1-3 o z . / g a l . Formula 540
SOURCE: W i t c o Corp . : Suggested F o r m u l a t i o n s
Hand Surface Cleaners 69
C o n c e n t r a t e d Hard S u r f a c e C l e a n e r
I n g r e d i e n t s : Deodor i zed Kerosene Calamide CWT Cal o x y l a t e N-9 E t h y l e n e G l y c o l Monobuty l E t h e r Water N a4 E DTA Comments abou t t h i s f o r m u l a :
Add i n g r e d i e n t s i n o r d e r l i s t e d . Use 1-2 o z p e r g a l l o n . F o r m u l a t i o n HSC-009-01
Wei qh t% 2 5 . 0 0 16 .30
9 .00 9 . 0 0
41 .30 0.40
Hard S u r f a c e Cleaner-Spray
I n q r e d i e n t s : Wei qh t% Water 86.50 Ammonia, 29% 3 . 0 0 Na4EDTA 0 . 5 0 E t h y l e n e G l y c o l Monobuty l E t h e r 5 . 0 0 Calsuds 81 5.00 Comments abou t t h i s f o r m u l a : 1 . A f t e r a d d i t i o n o f E t h y l e n e G l y c o l Monobuty l E t h e r , t h e
2 . It becomes c l e a r w i t h t h e a d d i t i o n o f Calsuds 81 . m i x t u r e i s c l o u d y .
F o r m u l a t i o n HSC-008-01
P i n e Cleaner
I n q r e d i e n t s : P i n e O i l I PA Calamide CWT Cal o x y l a t e N-9 Cal s o f t LAS-99 Water Comments abou t t h i s f o r m u l a :
Add i n g r e d i e n t s i n o r d e r l i s t e d . Use a t 1-2 o z p e r g a l l o n . F o r m u l a t i o n HSC-004-01
- P i n e C leaner
I n g r e d i e n t s : P i n e O i l Calsuds CD-6 C a l o x y l a t e N-9 I P A Water Comments abou t t h i s f o r m u l a :
Add i n g r e d i e n t s i n o r d e r l i s t e d . F o r m u l a t i o n HSC-007-01
~~~~~~~ P i l o t Chemical Co. : Suggested F o r m u l a t i o n s
Weight% 20.00 10.00
9.00 5 .00 2 . 0 0
54.00
Weight% 15 .00 10.00
8 .00 1 0 . 0 0 57.00
70 Advanced Cleatiing Product Formulations
Hard S u r f a c e Cleanerc
I n g r e d i e n t s : Water Sodi um Metas i 1 i c a t e Na4EDTA Dowanol PnB P i l o t SXS-40 C a l o x y l a t e N-9 P i n e 01 1 Comments about t h i s f o r m u l a :
Add i n g r e d i e n t s i n o r d e r l i s t e d F o r m u l a t i o n HSC-001-01
Hard-Surface-C1 @anex
I n g r e d i e n t s : Water Sodi um Metas i 1 i c a t e Na4EDTA P i l o t SXS-40 Cal i mu1 se PRS Dowanol PnB Cal o x y l a t e N - 9 Comments sbou t t h i s f o r m u l a :
Add i n g r e d i e n t s i n o r d e r l i s t e d . F o r m u l a t i o n HSC-002-01
Hard S u r f a c e Cle&ne_r
I n g r e d i s n t s : Water Sodi um Metas i 1 i c a t e Na4EDTA P i l o t SXS-40 Calamide CWT Comments abou t t h i s f o r m u l a :
Add i n g r e d i e n t s i n o r d e r l i s t e d . Use 1 - 4 o z p e r g a l l o n . F o r m u l a t i o n HSC-005-01
Hardsu.!-33Cs~_ec1 eane r Irns r e d i en t-s 1 Water Sodi um C i t r a t e Soda Ash Ammonia, 29% P i l o t SXS-40 Calamide CWT Comments abou t t h i s f o r m u l a :
Add i n g r e d i e n t s i n o r d e r l i s t e d . Use 2-4 oz p e r g a l l o n . F o r m u l a t i o n HSC-006-01
SOURCE: P i l o t Chemical Co. : Suggested F o r m u l a t i o n s
w e i g h t % 7 5 . 2 5
2 . 0 0 2 . 0 0 6 . 0 0 9 . 0 0 5 . 5 0 0 . 2 5
Wi q h t 9 6 7 4 . 5 0
2 . 0 0 2 . 0 0 7 . 0 0 3 . 0 0 5 . 0 0 6 . 5 0
Weisht_"L. 79.30
5 . 2 0 2 . 5 0 5 . 0 0 8 . 0 0
We i_ph t % 58.50 1 5 . 0 0
5 . 0 0 3 . 5 0 8 . 0 0
1 O . D O
Hand Sqface Cleaners 71
Hard S u r f a c e C leaner w/Amphoter ic
I n q r e d i e n t s : Water, D . I . Sodi um Carbonate Rewote r i c AM KSF-40 Dowanol DPM Versene 100 W i t c o n a t e SXS (40%)
Wt% 75 .0
4 .0 10.0
5.0 2 .0 4.0
B l e n d i n g P rocedure :
each a d d i t i o n .
Typ i c a l P r o p e r t i es :
Add i n g r e d i e n t s i n o r d e r shown and d i s s o l v e c o m p l e t e l y between
V i s c o s i t y , cps : 4 S o l i d s : 10.2% pH: 1 0 . 8
Formula 507
Hard S u r f a c e C leaner C o n c e n t r a t e w/d'Limonene
I n g r e d i e n t s : Phase I: I s o p r o p a n o l O l e i c A c i d .Varoni c K205 d ' L i monene
Phase 11: Water , D . I . Potass ium H y d r o x i d e (87%)
10.0 8.8 5 . 0
12.0
62 .2 2 . 0
B1 end i ng Procedure :
I 1 i n g r e d i e n t s and m ix t h o r o u g h l y . W h i l e m i x i n g , add Phase I t o Phase 11.
T y p i c a l P r o p e r t i es : V i s c o s i t y , c p s : 75 S o l i d s : 13.8% pH: 1 0 . 2
Formula 508
SOURCE: W i t c o Corp . : Suggested F o r m u l a t i o n s
Combine Phase I i n g r e d i e n t s and m ix t h o r o u g h l y . Combine Phase
72 Advanced Cleaning Product Formulations
Hard S u r f a c e C leaner C o n c e n t r a t e IPhospha te . L i q u i d )
S o i l - F o o d grease, o i l and p r o t e i n , p e t r o l e u m g rease and o i l Su r face -Meta l , ce ramic , p o l y m e r i c , g l a s s A p p l i c a t i o n Method-Wipe, mop o r s p r a y ( d i l u t e d ) Manufacture-Mi x t a n k w i t h p r o p e l 1 e r s t i r r e r
ComDosi t ion A : Water 71.4 TSP 1 . 6 S t a r s o Sodium S i l i c a t e 14.0 Sodium H y d r o x i d e (50%) 4 . 0 *Phosphate E s t e r 5 . 0 * * L i q u i d N o n i o n i c S u r f a c t a n t (C9-C l l ; 6 Moles EO) 2 .8 * * * L i q u i d N o n i o n i c S u r f a c t a n t (C9-C11; 2 . 5 Moles EO) 1 .2
Compos i t i on B : Water TSP S t a r s o Sodi um S i 1 i c a t e Sodium H y d r o x i d e (50%) *Phosphate E s t e r * * L i q u i d N o n i o n i c S u r f a c t a n t (C9-Cl1; 6 Moles EO) * * * L i q u i d N o n i o n i c S u r f a c t a n t ( C 9 - C l l ; 2 .5 Moles EO)
Use D i l u t i o n : 3-6% bw (4-8 o z / g a l l o n )
* Rhone-Poulenc Rhodafac RE-600 ** Rhone-Poulenc Rhodasur f 91-6 *** Rhone-Poulenc Rhodasur f A-24
Wt% 6 5 . 4
1 . 6 18.0
5 . 0 6 . 0 2 . 8 1 . 2
Hard S u r f a c e Spray C leaner LPhosphate, L iqu id )
S o i l - F o o d grease, o i l and p r o t e i n , p e t r o l e u m g rease and o i l Sur face -Meta l , ce ramic , p o l y m e r i c , g l a s s A p p l i c a t i o n Method-Spray and wipe Manu fac tu re -M ix t a n k w i t h p r o p e l l e r s t i r r e r
W t % Composi t i on : ~- Water 90 .00 TKPP 2.00 N C l e a r Sodium S i l i c a t e 1 . 8 8 Sodium H y d r o x i d e (50%) 0 .12 * D i p r o p y l ene G1 y c o l Monomethyl E t h e r 5 . 0 0 **Octy lphenoxy P o l y e t h o x y e t h a n o l , 12-13 Moles EO 1 .00
Use: As i s , sp ray
* Dow Chemical * * Rhone-Poulenc I g e p a l CA-720
SOURCE: PQ C o r p . : D e t e r g e n t F o r m u l a t i o n Guide
Hand Surface Cleaners 73
Hard Sur face Cleaner Concentrate w/Dipentene
I nnredi en t s : Phase I: Isopropanol O l e i c Ac id Varonic K205 D i pentene
Phase 11: Water, D . I . Potassium Hydroxide (87%)
Wt%
10.0 8 . 8 5 .0
12.0
62.2 2 . 0
B lend ing Procedure:
I 1 i n g r e d i e n t s and mix thorough ly . Whi le mix ing , add Phase I t o Phase XI ~
T yp i ca l P r o p e r t i e s : V i s c o s i t y , cps: 50 Solids: 13.8% pH: 10.1
Formula 509
Combine Phase I i n g r e d i e n t s and mix thorough ly . Combine Phase
A1 k a l i ne Hard Sur face Cleaner
I n q r e d i en ts : Water, D . I . Sodi um Metasi 1 i c a t e Varami de A-83 \ M i t cona te 3 0 D S W i t cona te SXS L i q u i d
Wt% 62.7
3 . 0 5.0 6 . 8 2 .5
B lend ing Procedure:
each a d d i t i o n .
Typ ica l P r o p e r t i e s : V i s c o s i t y , cps: 32 S o l i d s : 1 1 .O% pH: 12.0
Formula 515
SOURCE: Witco Corp.: Suggested Formulat ions
Add i n g r e d i e n t s i n o rder shown and d i s s o l v e comple te ly between
74 Advanced Cleaning Product Formulations
L i q u i d A b r a s i v e C1 eanser
I n q r e d i e n t s : Water, t a p Ca lc ium ca rbona te , 100 mesh Sodium t a l l o w soap, f l a k e s A lpha -S tep MC-48 N i n o l 11-CM Sodi um C h l o r i d e
Wt% 48.5 42.5
2 . 0 2 . 5 2 .0 2 .5
M i x i ng P rocedure :
Add soap and m ix u n t i l d i s p e r s e d . Add MC-48 and 11-CM and m ix u n t i l homogeneous. Add sodium c h l o r i d e t o t h i c k e n .
P r o p e r t i es :
Charge warm w a t e r and add c a l c i u m c a r b o n a t e w h i l e m i x i n g .
Appearance: Opaque, o f f - w h i t e creamy l i q u i d pH, as i s : 9 . 3 V i s c o s i t y @ 25 deg C . : t h i x o t r o p i c
s p i n d l e #3, 6 rpm, B r o o k f i e l d : 4520 cps s p i n d l e #3, 12 rpm, B r o o k f i e l d : 3840 cps s p i n d l e #3, 30 rpm, B r o o k f i e l d : 3060 cps
S o l i d s , % : 50 D e n s i t y , l b s / g a l : 11.69 S t o r a g e a t ambient temp, 1 week: N o s e p a r a t i o n
Use I n s t r u c t i o n s : Use as i s
Per formance:
t i l e s s i m i 1 a r t o commerci a1 p r o d u c t s .
SOURCE: Stepan Co. : F o r m u l a t i o n No. 314
Cleans grease p e n c i l , s c u f f marks and l i p s t i c k f r o m v i n y l
T i l e and Sani t a r v C l e a n e r s
I n q r e d i e n t s : Zusol a t 1008/85 Water Xanthan Gum C i t r i c a c i d
I n q r e d i e n t s : Amphotensid B 4 Water C i t r i c a c i d
Wt% 5 . 0
7 9 . 6 0 . 4
1 5 . 0
Wt% 3 0 . 0 6 0 . 0 1 0 . 0
SOURCE: Zschimmer & Schwarz GmbH & Co.: Suggested F o r m u l a t i o n s CT 02-10-03 and CT 02-10-04
Hand Sutface Cleaners 75
L i q u i d Hard S u r f a c e C leaner
I n g r e d i e n t s : Wt%* A : Van Gel ES, Magnesium Aluminum S i l i c a t e 4.00
Rhodopol 23, Xanthan Gum 0 .50 D e i o n i z e d Water 68.50
0 : Cocamide DEA (Monamid 150-ADD) A1 k o x y l a t e d F a t t y A l c o h o l (P1 u r a f a c C-17) T e t r a p o t a s s i um Pyrophosphate Potass ium Phosphate T r i b a s i c D e i o n i z e d Water
0 .50 2 .50 1 .25 0 . 7 5
21 .oo
C: Ammonium Hydrox ide , 28% 1 . o o
Procedure: 1 . D ry b l e n d t h e Van Gel ES and Rhodopol 23 and s l o w l y add them
t o t h e w a t e r w h i l e s t i r r i n g w i t h an homogenizer a t 5000 r p m . C o n t i n u e m i x i n g f o r 40 m i n u t e s .
2. Combine t h e P a r t B i n g r e d i e n t s w i t h s l o w s t i r r i n g . 3 . Move t h e b a t c h t o a p r o p e l l e r m i x e r and a d j u s t t h e speed t o
4. Add P a r t I3 t o P a r t A, mix f o r 5 m i n u t e s and t h e n add P a r t C
F o r m u l a t i o n No. 303
produce a s l i g h t v o r t e x .
and m i x f o r 5 m i n u t e s .
Hard S u r f a c e C l e a n e r - A l l Purpose
I n g r e d i e n t s : A : Veegum, Magnesi um A1 umi num S i 1 i c a t e
Rhodopol 23, Xanthan Gum D e i o n i z e d Water
W t .%* 1 .20 0 .40
48.40
B : Ca lc ium Carbonate 40.00
C : C12-CI3 L i n e a r P r imary A l c o h o l E t h o x y l a t e (Neodol 23-6.5)
Cocamide DEA ( N i n o l 40-CO) P r e s e r v a t i v e , Dye, F rag rance
9.00 1 .oo q . s .
Procedure : 1 . Dry b l e n d t h e Veegum and Rhodopol 23 and s l o w l y add t h e b l e n d
t o t h e w a t e r w h i l e s t i r r i n g w i t h an homogenizer a t 5000 rpm. C o n t i n u e m i x i n g f o r 20 m i n u t e s .
2 . Add P a r t B and m ix f o r 10 m inu tes . 3 . Move t h e b a t c h t o a p r o p e l l e r m i x e r and a d j u s t t h e speed t o
4. Add t h e P a r t C i n g r e d i e n t s i n t h e o r d e r shown, m i x i n g f o r 5
F o r m u l a t i o n f r o m S h e l l Chemical Co.
p roduce a s l i g h t v o r t e x .
m i n u t e s a f t e r each a d d i t i o n .
AS r e c e i v e d b a s i s
SOURCE: R.T. V a n d e r b i l t Co., I n c . : Van Gel and Veegum i n Hard S u r f a c e C leaners and Pol i s h e s : Suggested F o r m u l a t i o n s
76 Advanced Cleaning Product Formulations
Mold and Mildew Remover
Carbopol r e s i n s a r e used t o reduce sp lash ing and t o p r o v i d e v e r t i c a l c l i n g when sprayed on a v e r t i c a l su r face . Th is "no-dr ip " a c t i o n w i l l i nc rease t h e con tac t t i m e o f t h e de te r - gent on t h e s o i l e d su r face and enhance consumer convenience.
I n p r e d i e n t : D I water Carbopol 672 ( 1 ) Sodium hydrox ide (50%) Sodium m e t a s i l i c a t e , pentahydrate Pr imary alkane s u l f o n a t e (40%) ( 2 ) Sodium h y p o c h l o r i t e (15.00%)
\Rlt% 84.50
1 . 0 0 2 . 0 0 0 . 5 0 5 . 0 0 7.00
Brookf i e l d v i scosi t y (RVT-PO rpm) : 120 cps Product pH: 12-13 Product c l a r i t y : Opaque
( 1 ) BFGoodrich ( 2 ) Stepan Co.: Bio-Terge PAS-8S
Procedure : 1 . Using moderate a g i t a t i o n (800 rpm) p rov ided by a L i g h t n i n '
Mixer or s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e f o r general m i x i ng and b l endi ng opera t i ons , d i sperse o r screen t h e Carbopol r e s i n i n t o t h e D I water. Mix t h e s l u r r y f o r approx imate ly 15 minutes o r u n t i l t h e s l u r r y i s homogen- eous.
m e t a s i l i c a t e . 2. Under moderate a g i t a t i o n , add t h e sodium hydrox ide and t h e
3. Add t h e alkane su l fona te . 4. Under low a g i t a t i o n , add t h e sodium h y p o c h l o r i t e b leach. 5 . Add c o l o r and f ragrance, as des i red .
To ta l Ac t i ves : Pr imary alkane su l fona te : 2.0 A v a i l a b l e c h l o r i n e : 1 . 0
SOURCE: BFGoodrich S p e c i a l t y Chemicals: DET-320
Laundry Products
77
78 Advanced Cleaning Product Formulations
D e t e r g e n t f o r F i n e F a b r i c s - 1 Powder
I n p r e d i e n t s : Genapol OA-080 DDBS-Na* Thermphos NW T a l l o w soap, Powder Sodi um d i s i 1 i c a t e Sokalan CP 5 Sokalan HP 22 A q u a m o l l i n BC Powder Perfume Sodi um s u l p h a t e
Q 3.0 15.0 25.0
1 .O-3.0 3.0 1 . o 1 . o 0.5 q.s.
ad 1 0 0 . 0
M a n u f a c t u r i n g :
b e employed i n f o r m o f a sp ray d r i e d powder. DDBS-Na p a s t e i s n o t s u i t a b l e .
To be p r e p a r e d by s p r a y mix p rocess . T h e r e f o r e DDBS-Na must
*DDBS=Dodecyl Benzene Su lphona te
D e t e r g e n t f o r F i n e F a b r i c s - 2 Powder
I n q r e d i e n t s : Genapol OA-080 DDBS-Na* Z e o l i t h A ( W e s s a l i t h T a l l o w soap, Powder Sodi um d i s i 1 i c a t e Soka lan CP 5 Sokalan HP 22 Aquamoll i n BC Powder Perfume Sodium s u l p h a t e
Wt% 3.0 15.0
20.0-25.0 1.0- 3.0
3.0 2.0- 3.0
1 . o 0.5 q . s .
ad 100.0
M a n u f a c t u r i n g :
be employed i n f o r m o f a s p r a y d r i e d powder. DDBS-Na p a s t e i s n o t s u i t a b l e .
To be p r e p a r e d by s p r a y mix p r o c e s s . T h e r e f o r e DDBS-Na must
*DDBS=Dodecyl Benzene Sul f o n a t e
SOURCE: Hoechst A k t i e n g e s e l l s c h a f t : Suggested F o r m u l a t i o n s
Laundry Products 79
Heavy Duty Laundry
I n g r e d i e n t s : Wei q h t % Water 28.90 Sodi um Hydrox ide , 50% 6.60 Calamide C 7.00 Pi l o t SXS-40 12.50 Cal s o f t LAS-99 40 .00 Cal o x y l a t e N-9 5 . 0 0 Comments about t h i s f o r m u l a : Add C a l o x y l a t e N-9 a f t e r 50% o f LAS-99 has been n e u t r a l i z e d .
F o r m u l a t i o n HDL-001-01
Heavy Duty Laundry
I n q r e d i e n t s : Water P i l o t SXS-40 Calamide CWT Sodium S i l i c a t e ( S o l i d ) C a l s o f t L-60 EDTA (Ethylenediaminetetraacetic A c i d ) Comments about t h i s f o r m u l a :
Add i n g r e d i e n t s i n o r d e r l i s t e d . F o r m u l a t i o n HDL-006-01
Heavv Duty Laundry
I nqred i e n t s : Water C a l f a x DB-45 C a l o x y l a t e N-9 P r o p y l ene G1 y c o l TKPP ( T e t r a P o t a s s i um Pyrophosphate) Comments about t h i s f o r m u l a :
Add i n g r e d i e n t s i n o r d e r l i s t e d . F o r m u l a t i o n HDL-007-01
Wei oh t% 42.50 22.50
4.00 3 .01
18.00 2 . 5 0
Weight% 78.50
7 .00 7 .00 2 . 5 0 5 .00
Heavv Duty Laundry
I n q r e d i e n t s : Wei q h t % Water 42.00 TKPP ( T e t r a Potass ium Pyrophosphate) 15.00 Sodium S i l i c a t e ( S o l i d ) 10 .00 C a l s o f t L-60 18.00 P i l o t SXS-40 10.00 Calamide CWT 5 . 0 0 Comments about t h i s f o r m u l a :
May need t o be heated t o s o l u b i l i z e t h e s u r f a c t a n t . F o r m u l a t i o n HDL-008-01
SOURCE: P i 1 o t Chemical Co. : Suggested Formul a t i ons
80 Advanced Cleaning Product Formulations
I & I L i q u i d Laundrv D e t e r g e n t w i t h Enzyme & O p t i c a l
Components: Water T r i e t h a n o l ami ne 85% D i e t h y l ene G1 y c o l B u r c o l 117 B u r c o l LAF-6 Burcowi t e BBH-PO Burco tase SL-160
% by Weisht 50 .00
3 . 2 5 20.00 1 0 . 0 0 10 .00
1 . 2 5 0.50
Burco LAF-6 i s used t o c o n t r o l foam as w e l l as t o p r o v i d e w e t t i n g and d e t e r g e n c y .
P rocedure : Charge 1 /2 o f w a t e r I3 120F. Add 1 ,2 ,3 , & 4 and b l e n d . Add
r e m a i n i n g w a t e r . Cool t o 1OOF. Add 5 and 6 . B lend u n t i l u n i f o r m .
1% pH: 9 . 5 % s o l i d s : 26 Lbs /ga l : 8 . 6 6
S u r f a c t a n t R i c h D e t e r g e n t f o r N u r s i n o Homes
I n g r e d i e n t s : Water TKPP Sodium M e t a s i l i c a t e Pen tahyd ra te B u r c o t e r g e DG-40 Burco NPS-876 SXS-40%
% bv Weiqht 30
5 5
40 10 10
6-8 ounces p e r 100 pounds o f l a u n d r y . Heavy s o i l s may r e q u i r e s l i g h t l y h i g h e r l e v e l s .
SOURCE: B u r l i n g t o n Chemical Co.: Suggested F o r m u l a t i o n s
Powder f o r A u t o m a t i c D ishwash inn Machines
I n g r e d i e n t s : A Genapol 2908 B Sodium metas i 1 i c a t e x 5H20 C Sodium c a r b o n a t e
Sodi um d i c h l o r o i socyanura te Thermphos NW
YO by Weiqht 1 . o o
52.00 10 .00
2 . 0 0 35.00
M a n u f a c t u r i n g : I Spray A on B . I 1 One a f t e r a n o t h e r , t h e components o f C a r e added t o 1 A p p l i c a t i o n : 1-29 d e t e r g e n t / L d i shwash ing l i q u o r
SOURCE: Hoechst A k t i e n g e s e l l s c h a f t : Suggested F o r m u l a t i o n
Laundry Products 81
IndustriaT Heavy Duty Laundry L i q u i d
Carbopol ETD 2691 is t o p rov ide product phase s t a b i l i z a t i o n i n t h i s h igh a l k a l i n i t y i n d u s t r i a l s t reng th c leaner .
I nsred i en t : D I water Carbopol ETD 2691 ( 1 ) 612-15 l i n e a r a lcoho l , 7 moles EO ( 2 ) Sodium alkylbenzene su l fona te (60%) ( 3 ) Potassium hydrox ide (45%) Sodium m e t a s i l i c a t e , anhydrous Tetrapotassium pyrophosphate
Wt% 49.00
0.50 18.00 5.50 2 .00 5.00
20.00
Phys ica l Pi-opert i es: B r o o k f i e l d V i s c o s i t y (RVT-20 rpm): 900 Product pH: 14 Product C l a r i t y : Opaque
Raw M a t e r i a l Supp l i e rs : (1 ) BFGoodrich ( 2 ) S h e l l Chemical Co.: Neodol 25-7 ( 3 ) Stepan Co.: B i o s o f t D-62
PP.0cedure: I . Use a b i g h t n i n ' Mixer o r s i m i l a r v a r i a b l e speed u n i t and an
i m p e l l e r s u i t a b l e f o r general m ix ing and b lend ing opera t ions . Screen t h e Carbopol r e s i n i n t o t h e vo r tex o f t h e r a p i d l y a g i t a t i n g water (800 rpm). Al low t o mix u n t i l homogeneous and f r e e o f polymer lumps.
benzene su l fona te s u r f a c t a n t s .
s i l i c a t e .
entrapment.
2 . Wi th s low mixing, add i n t h e a lcoho l e thoxy la te and a l k y l -
3 . Continue a g i t a t i n g and add t h e potassium hydroxide and meta-
4. Add i n t h e pyrophosphate w i t h minimal a g i t a t i o n t o avo id a i r
5. Add dyes and fragrance, as des i red .
Total Wcti ves : Sodi um a1 k y l benzene sul fona te : 3 .30 C12-15 l i n e a r a l coho l , 7 moles EO: 18.00 Tetrapotassium pyrophosphate: 20.00
SOURCE: BFGoodrich Spec ia l t y Chemicals: DET-201
82 Advanced Cleaning Product Formulatioris
I n d u s t r i a l Laundry Deteraents High Caust ic Formula-
Components: Burco NPS-816 Burcosperse LP B u r c o l i t e BSGH-255 Dequest 2000 50% NaOH
% bv Weiaht 15 .0 10 .0 5 .0 5 . 0
65.0
Procedure:
a g i t a t i o n . Keep temperature below 160F du r ing t h e e n t i r e a g i t a t i o n .
Blend a l l components except 50% NaOH. S lowly add NaOH w i t h
Mixed B u i l d e r Formula t ion
Components: Water 45% KOH Burcosperse LP TKPP Burco NPS-816 S ta r Grade Sodium S i l i c a t e
% by Weight 3 1 . 5 2 3 . 5 1 0 . 0 1 0 . 0 1 5 . 0 1 0 . 0
Procedure: D isso lve KOH i n water . S lowly add Burcosperse LP w h i l e
a g i t a t i n g . Keep temperature below 160F. Add TKPP and s t i r u n t i l d i sso l ved . Add Burco NPS-816, then S t a r Grade Sodium S i l i c a t e and b lend u n t i l un i fo rm.
Use l e v e l s a re 6-12 ounces per 100 pounds, depending on s o i l load ing , temperature, e t c .
SOURCE: B u r l i n g t o n Chemical Co., I n c . : Suggested Formula t ions
Washi np Paste w i t h 81 eachi n g A g e n t
I n g r e d i e n t s : Water Sodium t r i po l yphospha te Sodium d i t h i o n i t Xanthan Gum Whi t e - s p i r i t Lumorol 4154 Zusol a t 1005/85
% by Weiaht 39 .0
3 . 0 12.0 2 . 0
1 0 . 0 30 .0
5 . 0
SOURCE: Zschimmer & Schwarz GmbH & Co.: Formula t ion CT 07-06-01
Laundry Products 83
Laundry Deteraent-Consumer ( L i q u i d )
S o i l - B o d y o i l and p e r s p i r a t i o n , body waste. make-up, f o o d s o i l S u r f a c e - C o t t o n and c o t t o n / p o l y e s t e r A p p l i c a t i o n Method-Household washing machine Manu fac tu re -M ix t a n k w i t h p r o p e l l e r s t i r r e r
Compos i t i on : Water F l u o r e s c e n t B r i g h t e n e r C a r b o x y m e t h y l c e l l u l o s e (CMC) * A c r y s o l A S E - I 08 **Nonylphenoxy P o l y e t h o x y e t h a n o l Potass ium H y d r o x i d e (45%) ***Sodium C i t r a t e (and /o r C i t r i c K a s i l #6 Potass ium S i l i c a t e EDTA Enzymes ( P r o t e a s e )
Wt% 37 .6
0 . 2 0 . 5 6 .0
, 9-10 Moles €0 10.0 2 .2
A c i d ) 25 .0 1 2 . 5
5 . 0 1 . o
x( Rohm & Haas; o r Rhone-Poulenc C o l l o i d 225/35 P o l y a c r y l a t e
* * Rhone-Poul enc I g e p a l CO-630 *** A d j u s t p H w i t h c i t r i c a c i d t o m a i n t a i n pH f o r e f f e c t i v e
(40%)
enzyme pe r fo rmance ( i . e . 8 . 5 - 9 . 5 pH).
Laundry Detergent-Consumer I Z e o l i t e B u i l t , Z e r o Phosphate, L i q u i d )
S o i l - B o d y o i l and p e r s p i r a t i o n , body waste, food s o i l , make-up S u r f a c e - C o t t o n and c o t t o n - p o l y e s t e r A p p l i c a t i o n Method-Household washing machine Manu fac tu re -M ix t a n k w i t h p r o p e l l e r s t i r r e r
Compos i t i on : Water Carbopol 674 D L i q u i d Sodium S i l i c a t e *Acusol 445ND Sodium P o l y a c r y l a t e Sodium Carbonate V a l f o r 100 Z e o l i t e A * * L i q u i d N o n i o n i c S u r f a c t a n t (C12-
Wt% 5 2 . 6
0 . 5 8 . 1
(92% s o l i d s ) 0 .9 9 . 1
24.5 .13, EO 6 . 5 Mo les ) 4 . 3
t: Rohm & Haas ** S h e l l Chemical Neodol 23-6.5
SOURCE: PQ C o r p . : D e t e r g e n t F o r m u l a r y Guide
84 Advanced Cleaning Product Formulations
Laundry Detergent-Consumer (Zero Phosphate, Powder)
S o i l - A c i d i c food f a t , o i l grease, blood, sebum and body waste Surface-Cotton and co t ton -po lyes te r A p p l i c a t i o n Method-Household Washing Machine Manufacture-Dry Blend/Agglomeration
Composit ion: Sodi um Carbonate B r i t e s i l H20 Hydrous P o l y s i l i c a t e *Acusol 445ND Sodium Po lyac ry la te (92% s o l i d s ) * *L inear A1 k y l benzene Sul f ona te (LAS) * * * L i q u i d Nonionic Sur fac tan t (7-9 moles EO; C12-15) V a l f o r 100 Z e o l i t e A Sodi um S u l f a t e O p t i c a l B r igh tener , Perfume
Use Level : 1000 ppm detergent d e l i v e r e d t o wash ( 1 gram d e t e r g e n t / l i t e r o f water )
* Rohm & Haas
Wt9/o 30.0 10.0
2 . 0 1 0 . 0
5 . 0 3 0 . 0 1 2 . 5 0.5
** Stepan Nacconol 9OG (90% a c t i v e ; powder) *** Rhone-Poulenc Rhodasurf LA-7 o r LA-9 o r S h e l l Chemical Neodol 25-7
Laundry Detergent-Consumer (Phosphate, Powder)
S o i l - A c i d i c food f a t and p r o t e i n , body p e r s p i r a t i o n , grass and
Sur face-Po lyes ter , co t ton /po lyes te r , c o t t o n A p p l i c a t i o n Method-Household washing machine Manufacture-Dry blend/agglomerat ion
d i r t
Composi t i on : B r i t e s i l H20 Hydrous P o l y s i l i c a t e *STPP *Sodium Carbonate Sodi um S u l f a t e * *L inear A1 k y l benzene Sul f ona te (LAS) * * *L iqu id Nonionic Sur fac tan t (7-9 Moles EO; C12-15) O p t i c a l B r igh tener , Perfume
Q 1 0 . 0 30 .0 30.0 14.5 1 0 . 0 5.0 0.5
Use Leve l : 1000 ppm detergent d e l i v e r e d t o wash ( 1 g r a m / l i t e r o f water )
* FMC ** Stepan Nacconol 90G (90% a c t i v e ; powder) *** Rhone-Poulenc Rhodasurf LA-7 o r LA-9 o r S h e l l Chemical Co. Neodol 25-7
SOURCE: PQ Corp.: Detergent Formula t ion Guide
Laundry Products 85
Laundry B r e a k - I n d u s t r i a l & I n s t i t u t i o n a l ( L i q u i d , Phosphate1
S o i l - A c i d i c f o o d f a t , o i l and grease; b l o o d , sebum and body
S u r f a c e - C o t t o n and c o t t o n / p o l y e s t e r A p p l i c a t i o n M e t h o d - I n d u s t r i a l washing machine Manu fac tu re -M ix t a n k w i t h p r o p e l l e r s t i r r e r
was te
Compos i t i on A : Water TKPP P o t a s s i urn H y d r o x i d e (45%) S t a r Sodium S i l i c a t e Sodium H y d r o x i d e (50%)
Compos i t i on B: Water TKPP Po tass ium H y d r o x i d e (45%) S t a r Sodi um S i 1 i c a t e Sodium H y d r o x i d e (50%)
3 4 . 1 1 0 . 0 30 .4 1 8 . 0
7 .5
wts/, 25 .6 10 .0 30.4 24.0 10 .0
Use D i l u t i o n : L i g h t S o i l : 0.25% by w e i g h t o r 1 l b p e r 100 l b s 1 aundry
Medium t o Heavy S o i l : 0.25%-0.50% by w e i g h t o r 1-2
No te : Use b u i l d e r s o l u t i o n i n c o n j u n c t i o n w i t h l a u n d r y d e t e r g e n t l b s p e r 100 l b s l a u n d r y
( u n b u i l t ) a t 2-4 p a r t s o f b u i l d e r t o 1 p a r t d e t e r g e n t .
Laundry B r e a k - I n d u s t r i a l & I n s t i t u t i o n a l ( L i q u i d )
S o i l - P e t r o l e u m o i l and grease, g r a p h i t e and c o l o r e d p igment S u r f a c e - P o l y e s t e r and c o t t o n / p o l y e s t e r A p p l i c a t i o n M e t h o d - I n d u s t r i a l washing machine Manu fac tu re -M ix t a n k w i t h p r o p e l l e r s t i r r e r
Compos i t i on : Water N C l e a r Sodium S i l i c a t e Sodium H y d r o x i d e (50%)
% 0-20
70-90 10-20
Use D i l u t i o n : L i g h t S o i l : 0.25% by w e i g h t o r 1 l b p e r 100 l b s
Medium/Heavy S o i l : 0.25%-0.50% by w e i g h t o r 1-2 1 aundry
l b s p e r 100 l b s l a u n d r y No tes : B l e n d t h i s b u i l d e r s o l u t i o n t o 1 . 7 - 2 . 0 r a t i o S i02 /Na20 b w
f o r b e s t s t a b i l i t y and i n d u s t r i a l de te rgency . D o r BJ-120 sodium s i l i c a t e s can a l s o be used as b u i l d e r s o l u t i o n s w i t h o u t b l e n d i n g . Use b u i l d e r s o l u t i o n i n c o n j u n c t i o n w i t h l a u n d r y d e t e r g e n t ( u n b u i l t ) a t 2-4 p a r t s bw o f b u i l d e r t o 1 p a r t d e t e r g e n t .
SOURCE: PQ C o r p . : D e t e r g e n t F o r m u l a t i o n Guide
86 Advanced Cleaning Product Formulatiom
Laundry D e t e r s e n t - I n d u s t r i a l & I n s t i t u t i o n a l (NTA/Zeol i t e , P o w d e d
S o i l - A c i d i c f o o d f a t , o i l and grease; b l o o d , sebum and body
S u r f a c e - C o t t o n and c o t t o n / p o l y e s t e r A p p l i c a t i o n M e t h o d - I n d u s t r i a l washing machine Manu fac tu re -Dry b l e n d / A g g l o m e r a t i o n
was te
Composi t i on : Metso Beads 2048 25 .0 Sodi um Carbonate 3 8 . 0 NTA 1 5 . 0 * L i q u i d N o n i o n i c S u r f a c t a n t (7-9 moles EO; C12-15) 12.0 V a l f o r 100 Z e o l i t e A 10 .0
Use L e v e l : L i g h t Soi l -O.25% by w e i g h t o r 1 l b p e r 100 l b s 1 aundry
Medium S o i l - 0 . 5 0 % b y w e i g h t o r 2 l b s p e r 100 l b s
Heavy S o i l - 0 . 7 5 % by w e i g h t o r 3 l b s p e r 100 l b s 1 aundry
1 aundry
No te : Use B r i t e s i l H20 i n p l a c e o f Metso Beads 2048, p a r t i a l l y or f u l l y , i f l o w e r a l k a l i n i t y i s d e s i r e d and more suspending/ e m u l s i f y i n g power i s needed. B r i t e s i l H20 w i l l a l s o i n - c r e a s e t h e s u r f a c t a n t adsorbency o f d e t e r g e n t b l e n d .
* Rhone-Poulenc Rhodasur f LA-7 o r LA-9 o r S h e l l Chemical Neodol 25-7
Laundry B r e a k - I n d u s t r i a1 & I n s t i t u t i o n a l ( Z e r o Phosphate, Powder)
S o i l - P e t r o l e u m o i l and grease, g r a p h i t e and c o l o r e d p igment S u r f a c e - P o l y e s t e r and c o t t o n / p o l y e s t e r A p p l i c a t i o n M e t h o d - I n d u s t r i a l washing machine Manufacture-Use as r e c e i v e d
Composi t i on : Metso Beads 2048
Wt46 100.0
Use D i l u t i o n : L i g h t Soi l -O.25% by w e i g h t o r 1 l b p e r 100 l b s 1 aundry
Medium S o i l - 0 . 5 0 % by w e i g h t o r 2 l b s p e r 100 l b s 1 aundry-
Heavy So i l -O .75% by w e i g h t o r 3 l b s p e r 100 I b s 1 aundry
Note: Use i n c o n j u n c t i o n w i t h l a u n d r y d e t e r g e n t ( u n b u i l t ) a t 2-4 p a r t s b w o f b u i l d e r w i t h 1 p a r t d e t e r g e n t .
SOURCE: PQ Corp. : Detergent Formula t ion Guide
Laundqi Products 87
Laundry D e t e r g e n t - I n d u s t r i a l 8 I n s t i t u t i o n a l (Phosphate, Powder)
S o i l - A c i d i c f o o d f a t , o i l and grease; b lood, sebum and body
Sur face-Cot ton and c o t t o n / p o l y e s t e r A p p l i c a t i o n M e t h o d - I n d u s t r i a l washing machine Manufacture-Dry b lend/Agg lomera t ion
waste
Compos i t ion : WtO/o Metso Beads 2048 25.0 *Sodium Carbonate 35.0 *STPP 30.0
Use Leve l : L i g h t Soi 1-0.25% by we igh t or 1 l b p e r 100 l b s l a u n d r y * * L i q u i d N o n i o n i c S u r f a c t a n t (7-9 moles EO; C12-15) 1 0 . 0
Medium So i l -O.50% by we igh t o r 2 l b s p e r 100 l b s
Heavy Soi l -O.75% b y w e i g h t o r 3 l b s p e r 100 l b s 1 aundry
1 aundry Note: Use B r i t e s i l H20 i n p l a c e o f Metso Beads 2048, p a r t i a l l y
o r f u l l y , i f lower a l k a l i n i t y i s d e s i r e d and more suspend- i n g / e m u l s i f y i n g power i s needed. B r i t e s i l H20 w i l l a l s o i n c r e a s e t h e s u r f a c t a n t adosrbency o f d e t e r g e n t b l e n d .
x< FMC ** Rhone-Poulenc Rhodasur f LA-7 o r LA-9 o r
S h e l l Chemical Neodol 25-7
Laundry D e t e r g e n t - I n d u s t r i a l 8 I n s t i t u t i o n a l (Sodium Carbonate, Powder)
S o i l - A c i d i c f o o d f a t , o i l and grease; b l o o d , sebum and body
Sur face-Cot ton and c o t t o n / p o l y e s t e r A p p l i c a t i o n M e t h o d - I n d u s t r i a l washing machine Manufacture-Dry b lend/Agg lomera t ion
waste
Composi t i on : Q Metso Beads 2048 25.0 Sodium Carbonate 55.0 Sodi um S u l f a t e 10.0 * L i q u i d N o n i o n i c S u r f a c t a n t (7-9 moles EO; C12-15) 1 0 . 0 Use Leve l : L i g h t Soi 1-0.25% by we igh t o r 1 l b p e r 100 l b s l a u n d r y
Medium S o i l - 0 . 5 0 % by we igh t o r 2 l b s p e r 100 l b s
Heavy Soi l -O.75% by w e i g h t o r 3 l b s p e r 100 l b s 1 aundry
1 aundry Note: Use B r i t e s i l H20 i n p l a c e o f Metso Beads 2048, p a r t i a l l y o r
f u l l y , i f lower a l k a l i n i t y i s d e s i r e d and more suspending/ e m u l s i f y i n g power i s needed. B r i t e s i l H20 w i l l a l s o i n - c rease t h e s u r f a c t a n t adsorbency o f d e t e r g e n t b l e n d .
'k Rhone-Poulenc Rhodasurf LA-7 o r LA-9 o r S h e l l Chemical Neodol 25-7
SQURCE: PQ G o r p . : Detergent F o r m u l a t i o n Guide
88 Advanced Cleaning Product Formulations
Laundry B reak - Indus t r i a l & I n s t i t u t i o n a l (Phosphate. Powder, High A l k a l i n i t y )
S o i l - A c i d i c food f a t , o i l and grease; blood, sebum and body
Surface-Cotton and co t ton /po lyes te r A p p l i c a t i o n Method- Indus t r ia l washing machine Manufacture-Dry b l end/Agglomeration
waste
Composit ion A : Metso Beads 2048
Wt% 6 0 . 0
Sodium Hydroxide Beads 40 .0 Composit ion 8: Wt% Metso Beads 2048 30 .0 *STPP 2 0 . 0 *Sodium Carbonate 2 8 . 0 Carboxymethy lce l lu lose 2 .0 Sodium Hydroxide Beads 2 0 . 0 Use D i l u t i o n : L i g h t So i l -0 .25% by weight o r 1 l b per 100 l b s
1 aundry Medium So i l -0 .50% by weight o r 2 l b s per 100 I b s 1 aundry Heavy So i l -0 .75% by weight o r 3 l b s pe r 1 0 0 lbs 1 aundry
Note: Use these a l k a l i b u i l d e r s i n con junc t i on w i t h laundry de tergent ( u n b u i l t ) a t 2-4 p a r t s bw o f b u i l d e r w i t h 1 p a r t de tergent
* FMC
Laundrv B reak - Indus t r i a1 8, I n s t i t u t i o n a l (Zero Phosphate Powder, H i ah A1 k a l i n i t v )
S o i l - A c i d i c food f a t , o i l and grease; blood, sebum and body
Surface-Cotton and co t ton /po lyes te r A p p l i c a t i o n Method- Indus t r ia l washing machine Manufacture-Dry blend/Agglomerat ion
waste
Composi t i on A : Wt% Metso Beads 2048 6 0 . 0 Sodium Hydroxide Beads 4 0 . 0 Composit ion 8: W S Metso Beads 2048 3 0 . 0 Sodi um Carbonate 28.0 Carboxymethylcel l u l o s e 2.0 Sodium Hydroxide Beads 2 0 . 0 V a l f o r 100 Z e o l i t e A 20.0 Use Leve l : L i g h t So i l -0 .25% by weight o r 1 l b per 100 l b s laundry
Medium So i l -0 .50% by weight o r 2 l b s per 100 I b s 1 aundry
Heavy Soi l -O.75% by weight o r 3 l b s per 1 aundry
Note: Use these a l k a l i b u i l d e r s i n con junc t i on w i t h e rgent ( u n b u i l t ) a t 2-4 p a r t s bw o f b u i l d e r w de tergent
SOURCE: PQ C o r p . : Detergent Formula t ion Guide
00 l b s
laundry de t - t h 1 p a r t
Laundry Products 89
Laundry D e t e r g e n t - I n d u s t r i a l 8 I n s t i t u t i o n a l (Reduced Phosphate, Powder)
S o i l - A c i d i c f o o d f a t , o i l and grease; b l o o d , sebum and body
S u r f a c e - C o t t o n and c o t t o n / p o l y e s t e r A p p l i c a t i o n M e t h o d - I n d u s t r i a l washing machine Manu fac tu re -Dry b l e n d / A g g l o m e r a t i o n
was te
Compos i t i on : Wt% Metso Beads 2048 25.0 *Sodium Carbonate 35 .0 *STPP 2 0 . 0 % * L i q u i d N o n i o n i c S u r f a c t a n t (7 -9 moles EO; C12-15) 10.0 V a l f o r 100 Z e o l i t e A 10 .0 Use L e v e l : L i g h t S o i l - 0 . 2 5 % by w e i g h t o r 1 l b p e r 100 l b s l a u n d r y
Medium S o i l - 0 . 5 0 % by w e i g h t o r 2 l b s p e r 100 l b s
Heavy So i l -O .75% by w e i g h t o r 3 l b s p e r 100 l b s 1 aundry
1 aundry No te : Use B r i t e s i l H20 i n p l a c e o f Metso Beads 2048, p a r t i a l l y
o r f u l l y , i f l o w e r a l k a l i n i t y i s d e s i r e d and more suspend- i ng /emu ls i f y i ng power i s needed. B r i t e s i 1 H20 w i 11 a1 so i n c r e a s e t h e s u r f a c t a n t adsorbency o f d e t e r g e n t b l e n d .
96 FMC dc* Rhone-Poulenc Rhodasur f LA-7 o r LA-9 o r
S h e l l Chemical Neodol 25-7
Laundry D e t e r g e n t - I n d u s t r i a l & I n s t i t u t i o n a l (NTA, Powder)
S o i l - A c i d i c f o o d f a t , o i l and grease; b l o o d , sebum and body
S u r f a c e - C o t t o n and c o t t o n / p o l y e s t e r A p p l i c a t i o n M e t h o d - I n d u s t r i a1 washi ng machine Manu fac tu re -Dry b l e n d / A g g l o m e r a t i o n
waste
Composi ti on : Wt% Metso Beads 2048 25.0 Sodium Carbonate 40.0 NTA 25.0
Use L e v e l : L i g h t S o i l - 0 . 2 5 % by w e i g h t o r 1 l b p e r 100 l b s l a u n d r y * L i q u i d N o n i o n i c S u r f a c t a n t (7-9 moles EO; C12-15) 1 0 . 0
Medium S o i l - 0 . 5 0 % by w e i g h t o r 2 l b s p e r 100 l b s
Heavy S o i l - 0 . 7 5 % by w e i g h t o r 3 l b s p e r 100 l b s 1 aundry
1 aundry No te : Use B r i t e s i l H20 i n p l a c e o f Metso Beads 2048, p a r t i a l l y o r
f u l l y , i f l o w e r a l k a l i n i t y i s d e s i r e d and more suspending/ e m u l s i f y i n g power i s needed. B r i t e s i l H20 w i l l also i n - c r e a s e t h e s u r f a c t a n t adsorbency o f d e t e r g e n t b l e n d .
*Rhone-Poulenc Rhodasur f LA-7 o r LA-9 o r S h e l l Chemical Neodol 25-7
SOURCE: PQ C s r p . : D e t e r g e n t F o r m u l a t i o n Guide
90 Advanced Cleaning Product Formulations
Laundry De te rqen t - Indus t r i a l B I n s t i t u t i o n a l (Sodium Carbonate w i t h Flow A i d . Powder)
S o i l - A c i d i c food f a t , o i l and grease; blood, sebum and body
Surface-Cotton and co t ton /po lyes te r Appl i c a t i on Method-I ndust r i a1 wash i ng mach i ne Manufacture-Dry blend/agglomerat ion
waste
Composi t i on : Wt% Metso Beads 2048 20.0 Sodium Carbonate 55.0 Sodi um S u l f a t e 10 .0 * L i q u i d Non ion ic Sur fac tan t (7-9 moles EO; C 1 2 - 1 5 ) 1 0 . 0 V a l f o r 100 Z e o l i t e A 5 . 0
Use Leve l : L i g h t S o i l : 0.25% by weight o r 1 l b per 100 l b s 1 aundry
Medium S o i l : 0 .50% by weight o r 2 l b s per 100 l b s
Heavy S o i l : 0.75% by weight o r 3 l b s per 100 l b s 1 aundry
1 aundry
Note: Use B r i t e s i l H20 i n p lace o f Metso Beads 2048, p a r t i a l l y o r f u l l y , i f lower a l k a l i n i t y i s des i red and more sus- pend ing /emuls i fy ing power i s needed. B r i t e s i l H20 w i l l a l s o inc rease t h e s u r f a c t a n t adsorbency o f de tergent b lend.
* Rhone-Poulenc Rhodasurf LA-7 o r LA-9 or She l l Chemical Neodol 25-7
Laundry De te rgan t - Indus t r i a l & I n s t i t u t i o n a l IPhosphate, S o l i d Block)
S o i l - A c i d i c food f a t , o i l and grease; blood, sebum and body
Surface-Cotton and co t ton /po lyes te r A p p l i c a t i o n Method-Industr i a1 washing machine Manufacture-Sol i d b lock
waste
Composi t i on : Metso Beads 2048 NaOH (50% S o l u t i o n ) *STPP *Sodium Carbonate * *L iqu id Nonionic Sur fac tan t (7-9 Moles EO; C12-15)
* FMC ** Rhone-Poulenc Rhodasurf LA-7 o r LA-9 o r
S h e l l Chemical Neodol 25-7
SOURCE: PQ Corp.: Detergent Formula t ion Guide
Wt% 2 5 . 0 2 5 . 0 3 5 . 0 12.0 3.0
Laundry Products 91
Laundry D e t e r g e n t - I n d u s t r i a l and I n s t i t u t i o n a l (Zero Phosphate, Powder)
S o i l - A c i d i c f o o d f a t , o i l grease, b l o o d , sebum and body waste S u r f a c e - C o t t o n and c o t t o n p o l y e s t e r A p p l i c a t i o n M e t h o d - I n d u s t r i a l washing machine Manu fac tu re -Dry B lend /Agg lomera t i on
Compos i t i on : Wt% Sodi um Carbonate 35 .0 * L i q u i d N o n i o n i c S u r f a c t a n t (7 -9 moles €0; C12-15) 15.0 V a l f o r 100 Z e o l i t e A 2 5 . 0 Metso Beads 2048 25.0 Use L e v e l : L i g h t S o i l - 0 . 2 5 % by w e i g h t o r 1 l b p e r 100 l b s l a u n d r y
Medium So i l -O .50% by w e i g h t o r 2 l b s p e r 100 l b s
Heavy S o i l - 0 . 7 5 % by w e i g h t o r 3 l b s p e r 100 l b s 1 aundry
1 aundry No te : Use B r i t e s i l H20 i n p l a c e o f Metso Beads 2048, p a r t i a l l y o r
f u l l y , i f l o w e r a1 k a l i n i t y i s d e s i r e d and more suspending/ e m u l s i f y i n g powder i s needed. B r i t e s i l H20 w i l l a l s o i n - c r e a s e t h e s u r f a c t a n t adsorbency o f d e t e r g e n t b l e n d .
*Rhone-Poulenc Rhodasur f LA-7 o r LA-9 o r S h e l l Chemical Neodol 25-7
Laundry D e t e r g e n t - I n d u s t r i a l and I n s t i t u t i o n a l ( Z e r o Phosphate, Powder)
S o i l - P e t r o l e u m o i l and grease, g r a p h i t e and c o l o r e d p igment S u r f a c e - P o l y e s t e r and c o t t o n / p o l y e s t e r A p p l i c a t i o n M e t h o d - I n d u s t r i a l washing machine Manufacture-Dry B1 end/Aggl omera t i on
Composi t i on : Wt% Sodium Carbonate 4 4 . 5 * L i q u i d N o n i o n i c S u r f a c t a n t (7-9 moles EO; C12-15) 18.0 V a l f o r 100 Z e o l i t e A 3 0 . 0 **Acusol 445ND Sodium P o l y a c r y l a t e (92% s o l i d s ) 2 . 5 Metso Beads 2048 5 . 0 Use L e v e l : L i g h t S o i 1-0.25% by w e i g h t o r 1 l b p e r 100 l b s l a u n d r y
Medium So i l -O .50% b y w e i g h t o r 2 l b s p e r 100 l b s
Heavy S o i l - 0 . 7 5 % b y w e i g h t o r 3 l b s p e r 100 l b s 1 aundry
1 aundry No te : Use B r i t e s i l H20 i n p l a c e o f Metso Beads 2048, p a r t i a l l y o r
f u l l y , i f lower a l k a l i n i t y i s d e s i r e d and more suspending/ e m u l s i f y i n g power i s needed. B r i t e s i l H20 w i l l a l s o i n - c r e a s e t h e s u r f a c t a n t adsorbency o f d e t e r g e n t b l e n d .
Rhone-Poulenc Rhodasur f LA-7 o r LA-9 o r S h e l l Chemical Neodol 25-7
** Rohm & Haas
SOURCE: PQ Corp. : De te rgen t F o r m u l a t i o n Guide
92 Advanced Cleaning Product Formulations
Laundry D e t e r q e n t - I n d u s t r i a l & I n s t i t u t i o n a l [Phosphate Bu i 1 t , L i q u i d )
S o i l - B o d y o i l and p e r s p i r a t i o n , body waste, make-up, f o o d s o i l Su r face -Co t ton and c o t t o n / p o l y e s t e r A p p l i c a t i o n M e t h o d - I n d u s t r i a l washing machine Manu fac tu re -M ix t a n k w i t h p r o p e l l e r s t i r r e r
Compos i t i on A : Water TKPP Potass ium H y d r o x i d e (45%) S t a r s o Sodium S i l i c a t e Sodi um H v d r o x i d e ( 5 0 % )
Wt% 5 4 . 5
4 . 6 1 3 . 7 1 5 . 0
4 . 2 , . *PhosphaGe E s t e r 5 . 0 * * L i q u i d N o n i o n i c S u r f a c t a n t (C12-C15, 7-9 Moles € 0 ) 3 . 0
Compos i t i on B: Wt% Water 5 9 . 1 Potass ium H y d r o x i d e (45%) 13 .7 S t a r s o Sodi um S i 1 i c a t e 1 5 . 0 Sodium H y d r o x i d e (50%) 4 . 2 *Phosphate E s t e r 5 . 0 * * L i q u i d N o n i o n i c S u r f a c t a n t (C12-C15, 9 Moles EO) 3 . 0 Use D i l u t i o n : 0 .25%-0.50% by w e i g h t or 1-2 l b s p e r 100 l b s
* Rhone-Poulenc Rhodafac RE-610 ** Rhone-Poulenc Rhodasur f LA-7 o r LA-9
1 aundry
Laundry D e t e r g e n t - I n d u s t r i a l & I n s t i t u t i o n a l ( L i quid)
Soi 1-Body o i 1 and p e r s p i r a t i o n , body waste, make-up, f o o d s o i 1 S u r f a c e - C o t t o n and c o t t o n / p o l y e s t e r A p p l i c a t i o n M e t h o d - I n d u s t r i a l washing machine Manu fac tu re -M ix t a n k w i t h p r o p e l l e r s t i r r e r
Compos i t i on : Water
wts/, 2 8 . 7
F1 u o r e s c e n t B r i g h t e n e r 0 . 1
**Nonylphenoxy P o l y e t h o x y e t h a n o l , 9-1 0 Moles EO 10 .0 P o t a s s i um H y d r o x i d e (45%) 2 . 2
C a r b o x y m e t h y l c e l l u l o s e (CMC) 0 . 5 * A c r y s o l ASE-108 ( A c r y l i c Polymer) 6 . 0
TKPP (60%) 40 .0 Kasi 1 #6 P o t a s s i um S i 1 i c a t e 1 2 . 5 Use D i l u t i i o n : 0.25%-0.50% by w e i g h t or 1-2 l b s p e r 100 I b s
* Rohm & Haas; or Rhone-Poulenc C o l l o i d 226/35 P o l y a c r y l a t e (40%) **Rhone-Poulenc I g e p a l CO-630
SOURCE: PQ Corp . : D e t e r g e n t Fo rmu la ry Guide
1 aundry
Laundry Products 93
Laundry B u i l d e r - I n d u s t r i a l & I n s t i t u t i o n a l ( L i q u i d )
S o i l - A c i d i c food, f a t , o i l and grease; b lood, sebum and body
S u r f a c e - P o l y e s t e r and c o t t o n / p o l y e s t e r A p p l i c a t i o n M e t h o d - I n d u s t r i a l washing machine Manufacture-Mix t a n k w i t h p r o p e l l e r s t i r r e r
waste
Composi t ion A : Potass ium Hydrox ide (45%) iU C l e a r o r E Sodium S i l i c a t e
Compos i t ion B: Water Potass ium Hydrox ide ( S o l i d ) N C l e a r or E Sodium S i l i c a t e
Compos i t ion C : Water Potass ium Hydrox ide ( S o l i d ) N C l e a r o r E Sodium S i l i c a t e Sodium Hydrox ide ( S o l i d )
Wt% 35-45 55-65
Wt% 1 1 . 0 37 .0 52.0
Wt% 6 . 0
28.0 52 .0 1 4 . 0
Use D i l u t i o n : L i g h t S o i l : 0.25% by we igh t o r 1 l b p e r 100 l b s 1 aundry
Medium t o Heavy S o i l : 0.25%-0.50% by we igh t o r 1-2 l b s p e r 100 l b s l a u n d r y
Note: Use b u i l d e r s o l u t i o n i n c o n j u n c t i o n w i t h l a u n d r y d e t e r g e n t ( u n b u i l t ) a t 2-4 p a r t s bw o f b u i l d e r t o 1 p a r t d e t e r g e n t
Laundry D e t e r g e n t - I n d u s t r i a l & I n s t i t u t i o n a l ( Z e o l i t e B u i l t , Zero Phosphate, L i q u i d )
So i l -Body o i l and p e r s p i r a t i o n , body waste, f o o d s o i l , make-up Sur face-Cot ton and. c o t t o n - p o l y e s t e r - A p p l i c a t i o n M e t h o d - I n d u s t r i a l washing Manufacture-Mix t a n k w i t h p r o p e l l e r s t
Compos i t ion : Water Carbopol 674 Metso Beads 2048 *Acusol 445N Sodi um P o l y a c r y Sodium Carbonate V a l f o r 100 Z e o l i t e A * * L i q u i d N o n i o n i c S u r f a c t a n t
8 Rohm 8: Haas
a t e (45% s o l
a c h i ne r r e r
d s )
WtO/o 57.06
0 .5 2 . 7 1 . 0 4 9 . 1
24.5 (C12-13; EO 6 . 5 Moles) 4 . 3
* * S h e l l Chemical Neodol 23-6.5
SOURCE: PQ Corp. : Detergent F o r m u l a t i o n Guide
94 Advanced Cleaning Product Formulations
Laundry Presoot te r Sprayable Gel
Carbopol ETD 2623 i s used i n t h i s fo rmu la t i on t o cos t e f f e c - t i v e l y t h i c k e n t h e su r fac tan t system i n t o a ge l form - which can be app l i ed t o t h e f a b r i c by brush o r sprayed on due to Carbopal 's shear t h i n n i n g na ture .
I na red i en t : D I water Carbopol ETD 2623 ( 1 ) C12-15 l i n e a r a l coho l , 3 moles €0 (2 ) C12-13 l i n e a r a lcoho l , 6 . 5 males €0 (3 ) EDTA ( t e t r a sodium s a l t ) Sodium hydrox ide (18%)
B r o o k f i e l d v i s c o s i t y (RVT-20 rpm): 8,300 cps Product pH: 7.0-8.0 Product c l a r i t y : Opaque
(1) BFGoodrich (2 ) She l l Chemical Co.: Neodol 25-3 (3) She l l Chemical C o . : Neodol 23-6.5
83.75 0.20
10.00 5.00 0.50 0.55
1.
2.
3. 4 . 5.
Procedure: Using moderate a g i t a t i o n (800 rpm) prov ided by a L i g h t n i n ' Mixer o r s i m i l a r v a r i a b l e speed u n i t and an impe l l e r s u i t a b l e f o r general m i x i ng and b lend ing opera t ions , d isperse o r screen t h e Carbopol r e s i n i n t o t h e D I water. Mix t h e s l u r r y f o r approximately 15 minutes o r u n t i l t h e s l u r r y i s homogen- eous. Add i n bo th o f t h e a lcoho l e thoxy la te su r fac tan ts . Mix u n t i l homogeneous. Add i n t h e EDTA. Add i n t h e sodium hydroxide u n t i l t h e pH i s a t t a i n e d . Add c o l o r and fragrance, as des i red .
To ta l Ac t i ves : C12-15 l i n e a r a l coho l , 3 moles EO ( 2 ) : 10.0 C12-13 l i n e a r a lcoho l , 6.5 moles EO (3 ) : 5.0
SOURCE: BFGoodrich Spec ia l t y Chemicals: DET-224
Laundry Products 95
Laundry Presootter Sorayable Liquid
Carbopol ETD 2623 i s used i n t h i s f o r m u l a t i o n t o s l i g h t l y t h i c k e n t h e s u r f a c t a n t system and enable the produc t t o s tay i n con tac t w i t h t h e s o i l longer by reduc ing seepage through t h e f a b r i c .
I n s r e d i en t : D I water Carbopol ETO 2623 ( 1 ) C12-15 l i n e a r a l coho l , 3 moles €0 ( 2 ) C12-13 l i n e a r a l c o h o l , 6 . 5 moles €0 ( 3 ) EOTA ( t e t r a sodium s a l t ) Sodi um hydrox ide (18%)
Wt% 84.30
0.05 10.00
5 . 0 0 0 .50 0 . 1 5
B rook f i e l d v i s c o s i t y (RVT-20 rpm) : 250 cps Product pH: 7.0-8.0 Product c l a r i t y : Opaque
( 1 ) BFGoodri ch ( 2 ) S h e l l Chemical Co.: Neodol 25-3 ( 3 ) She l l Chemical Co.: Neodol 23-6.5
Procedure: I . Using moderate a g i t a t i o n (800 rpm) prov ided by a L i g h t n i n '
Mixer o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e f o r general m ix ing and b lend ing opera t i ons , d i spe rse o r screen t h e Carbopol r e s i n i n t o t h e D I water. Mix t h e s l u r r y f o r approx imate ly 15 minutes o r u n t i l t h e s l u r r y i s homogen-
2 . Add i n bo th o f t h e a lcoho l e thoxy la te s u r f a c t a n t s . Mix u n t i l homogeneous.
3 . Add i n t h e EDTA. 4 . Add i n t h e sodium hydrox ide u n t i l t h e pH i s a t t a i n e d . 5 . Add c o l o r s o l u t i o n and fragrance, as des i red .
T o t a l Ac t i ves :
eous.
C12-15 l i n e a r a l coho l , 3 moles EO: 1 0 . 0 C12-13 l i n e a r a l coho l , 6 . 5 moles EO: 5 .0
SOURCE: BFGoodrich S p e c i a l t y Chemicals: DET-220
96 Advanced Cleaning Product Formulations
L i g h t Du ty L i q u i d D e t e r g e n t
I n g r e d i e n t s : Water P i l o t SXS-40 C a l s o f t L-60 Calamide C Cal foam EA-603 Cal s o f t LAS-99 C i t r i c A c i d Sodium C i t r a t e Comments about t h i s f o r m u l a : 1 . pH=7.1 2 . Add C i t r i c A c i d i f pH i s h i g h o r Sodium C i t r a t e if 3 . V i s c o s i t y s h o u l d be 300 cPs.
F o r m u l a t i o n LDL-001-01
w e j - g h s 4 8 . 4 5
7 .50 30.00
5 . 0 0 8 . 3 0 0 . 6 0 0 . 1 0 0 . 0 5
pH i s l o w .
L i s h t Duty L i q u i d D e t e r g e n t
I n g r e d i e n t s : Water C a l s o f t L-60 P1 l o t s x s - 4 0 Calamide C Cal foam EA-603 Cal s o f t LAS-99 Opaci f i e r Sod1 um C i t r a t e Comments abou t t h i s f o r m u l a : 1 . Add e i t h e r C i t r i c A c i d or
2 . S o l i d s 45%. 3 . S u b s t i t u t i n g C a l s o f t L-40
p r o d u c t s o l i d s t o 42%. F o r m u l a t i o n LDL-002-01
7.0-7.2.
Weight% 22.31 39 .70 2 2 . 1 0
7 . 0 6 7 .35 0 . 5 6 0 . 8 8 0 . 0 4
C a l s o f t LAS-99 t o a d j u s t pH t o
f o r C a l s o f t L-60 w i l l l o w e r
I n g r e d i e n t s : Water Calsuds A Cal foam ES-303 Perfume Kathon CG Opaci f i e r Comments abou t t h i s f o r m u l a : 1 . I f o p a c i f i e r i s t o be added, w i t h h o l d 5% o f t h e w a t e r 2 . Add t h e o p a c i f i e r t o t h e w a t e r p r i o r t o a d d i n g t o t h e
d e t e r g e n t . F o r m u l a t i o n LDL-004-01
L i g h t D u t y L i q u i d D e t e r g e n t
Weight% 1 8 . 8 0 70 .00 1 0 . 0 0
0 . 1 0 0 . 1 0 1 . o o
SOURCE: P i l o t Chemical Co . : Suggested F o r m u l a t i o n s
Laundry Products 97
L i g h t -Duty L i q u i d D e t e r g e n t
I n g r e d i e n t s : Water Calsuds CD-6 P i l o t SXS-40 Cal foam EA-603 Cal s o f t LAS-99
Weight% 50.20 2 5 . 0 0
6 . 8 0 1 0 . 0 0
6 . 0 0
Comments abou t t h i s f o r m u l a : 1 . I n g r e d i e n t s s h o u l d be added i n t h e o r d e r l i s t e d t o a i d i n
2. Sodium C i t r a t e / C i t r i c A c i d s h o u l d be added f o r pH ad jus tmen t
3 . S a l t (Sodium o r Ammonium C h l o r i d e ) w i l l r a i s e t h e v i s c o s i t y .
b l e n d i n g .
t o 7 + .
F o r m u l a t i o n LDL-006-01
L i g h t Du ty L i q u i d D e t e r g e n t
I n g r e d i e n t s : Water P i l o t SXS-40 C a l s o f t T-60 Cal foam ES-303 Calamide C P r e s e r v a t i ve Sodi um C h l o r i d e
Comments about t h i s f o r m u l a : V i s c o s i t y 2 7 5 cPs. Sol i d ~ = 3 2 - 3 3 % pH=6.2 F o r m u l a t i o n LOI-007-01
L i g h t Du ty L i q u i d D e t e r g e n t
I n g r e d i e n t s : Water P i l o t s x s - 4 0 L i nea r A1 coho1 E t h o x y l a t e NaOH, 50% D i e t h a n o l am1 ne Cal s o f t LAS-99
Comments abou t t h i s f o r m u l a : So l 1 ds=30% Good f o r g reasy a p p l i c a t i o n s . F o r m u l a t i o n IDL-006-01
SOURCE: P i l o t Chemical Co : Suggested F o r m u l a t i o n s
Weight% 36.90
5 . 0 0 4 0 . 0 0 15 .00
2 . 0 0 0 . 1 0 1 . 0 0
Weight% 65.16
6 .29 2.52 2 .81 0 . 4 3
19 .77
98 Advanced Cleaning Product Formulations
L i g h t Du ty L i q u i d D e t e r g e n t
I n g r e d i ent -s l Water Ammonium C h l o r i d e P i l o t sxs-40 C a l s o f t L-60 Cal foam ES-303 Calamide C C i t r i c A c i d P r e s e r v a t i ve
Weight% 13 .90
2 . 4 0 19.60 4 4 . 1 0 1 5 . 8 0 4 . 0 0 0 . 1 0 0 . 1 0
Comments about t h i s f o r m u l a : 1 . “As i s ” pH=8.0. 2 . Add C i t r i c A c i d i n p l a c e o f Sodium C i t r a t e t o l o w e r pH.
F o r m u l a t i o n LDL-009-01
Ligh-t- Du ty L i q u i d D e t e r q e n t Ca l s o f t LAS-99 Based
I n g r e d i e n t s : Water NaOH, 50% Cal s o f t LAS-99 P i l o t SXS-40 Cal foam ES-303 Cal o x y l a t e N-9 C i t r i c A c i d Opaci f i e r P r e s e r v a t i v e
Comments abou t t h i s f o r m u l a : A d d i n g r e d i e n t s i n o r d e r 1 i s t e d . F o r m u l a t i o n LDL-011-01
L i g h t D u t y L i q u i d D e t e r g e n t Cal s o f t LAS-99 Based
I n g r e d i e n t s : Water NaOH, 50% Cal s o f t LAS-99 Calamide C P i l o t SXS-40 Cal foam ES-303 C a l o x y l a t e N-9 C i t r i c A c i d Opaci f i e r
Comments abou t t h i s f o r m u l a : A d d i n g r e d i e n t s i n o r d e r l i s t e d . F o r m u l a t i o n LDL-012-01
SOURCE: P i l o t Chemical Co. : Suggested F o r m u l a t i o n s
Weight% 43.60
5 . 8 0 21 .70 1 6 . 7 0
3 . 0 0 8 . 0 0 0 . 1 0 1 . o o 0 . 1 0
Weight% 5 2 . 4 0
4 . 4 0 16 .30
5 . 0 0 1 2 . 5 0
2 . 2 0 6 .00 0 . 1 0 1 . o o
Laundry Products 99
a h t Du ty L i q u i d D e t e r g e n t __ C a l s o f t LAS-99 Based
I n a r e d i e n t s ; Water Cal s o f t LAS-99 NaOH, 50% A l c o h o l E t h o x y l a t e Calamide C P i l o t SXS-40 Perfume P r e s e r v a t i ve Comments abou t t h i s f o r m u l a :
Add i n g r e d i e n t s i n o r d e r l i s t e d . Formul a t i on LDL-014-01
Weight% 54.60 16.30
4 .35 10.00 2 . 0 5
12.50 0 . 1 0 0 . 1 0
L i g h t D u t L L C q u i d D e t e r E n t D r y Cleaner : Pre-Spot-Water S o l u b l e
I n g r e d i e n t s : Weight% Water 75 .70 Calamide C 2 .00 C a l o x y l a t e N-9 1 1 . 0 0 C a l i mu1 se PRS 1 1 . o o C i t r i c A c i d 0 . 2 0 Perfume & C o l o r 0 . 1 0 Comments abou t t h i s f o r m u l a : 1 . Add i n g r e d i e n t s i n o r d e r 1 i s t e d . V i s c o s i t y i n c r e a s e s as
2 . A c l e a r p r o d u c t i s o b t a i n e d when a l l i n g r e d i e n t s a r e mixed
3 . D e t e r g e n t f r a g r a n c e R-1264 can be used i n t h i s f o r m u l a . 4 . Use l e v e l : d i l u t e 8 : l w i t h w a t e r .
C a l o x y l a t e N-9 i s added.
t o g e t h e r .
F o r m u l a t i o n LDY-001-01
Li-ght D u t y Li.qu2d D e t e r g e n t Wool _Wash
I c g r e d i ents-: C a l s o f t T-60 Cal ami de CW-100 Cal foam ES-303 C i t r i c A c i d Comments abou t t h i s f o r m u l a :
The room t e m p e r a t u r e v i s c o s i t y i s abou t 520 cPs. F o r m u l a t i o n LDY-002-01
-- L i g h t D u t E L i q u j d D e t e r g e n t Wool Wash
I ng r e d i g n t s : Calsuds A Water Comments abou t t h i s f o r m u l a :
The room t e m p e r a t u r e v i s c o s i t y i s abou t 25 cPs. F o r m u l a t i o n LDY-004-01
SOURCE: P i l o t Chemical Co. : Stiggested F o r m u l a t i o n s
Wei g h t % 14 .15
5 . 4 8 39 .64
0 . 1 3
We1 g h t % 50 .06 49.93
100 Advanced Cleaning Product Formulations
Two Part Industri a1 Laundry Deteraents Break Formulations
Hi q h l v A1 kal i ne Break
Components: Water Burcosperse LP Burcolite BSGH-255 Dequest 2000 50% NaOH
Mixed Builder Break
Components: Water 45% KOH Burcosperse LP TKPP Sodi um Si 1 i cate (Star Grade)
% by Weight 5 10 5 5 75
% by Weight 4 0 . 0 27.5 10 .0 10.0 12.5
Procedure:
between each addition. Keep temperature below 160F during bl endi ng.
Add components in the order listed. Blend until homogeneous
Detergent Additive
Components: Water Burco NPS-816 Neodol 25-7 Dodecylbenzenesulfonic Acid TEA-85
% by Weight 60.00 10.00 12.50 11.65 5.85
Procedure:
between each addition.
Use Level:
Add components in the order listed. Blend until homogeneous
Break: 4-12 ounces/100 pounds Detergent: 2-4 ounces/100 pounds
SOURCE: Burlington Chemical Co., Inc.: Suggested Formulations
Laundry Products 101
U l t r a L i q u i d Laundrv D e t e r q e n t I n g r e d i e n t s : Wt% Alpha-Step MC-48 2 9 . 0 Sodi urn 01 e a t e 5 .0 A l c o h o l , E t h o x y l a t e , 7 19.0 Borax 1 . 3 3A A l c o h o l 0 . 5 P r o p y l ene G1 y c o l 5 .0 PVP K-15 0 . 8 Water , f r a g r a n c e & dye Q.S. t o 100.0 M i x i n g P rocedure :
Combine Alpha-Step MC-48, p r o p y l e n e g l y c o l , a l c o h o l e t h o x y - l a t e and w a t e r w h i l e m i x i n g u n t i l s o l u t i o n i s homogeneous. Heat t o a p p r o x i m a t e l y 50 deg. C, add sodium o l e a t e and m ix u n t i l s o l u t i o n and i s a g a i n homogeneous. A l l o w m i x t u r e t o c o o l t o room t e m p e r a t u r e and add t h e r e m a i n i n g i n g r e d i e n t s w i t h m i x i n g . A d j u s t p H w i t h c a u s t i c soda o r c i t r i c a c i d i f necessa ry . T y p i c a l F o r m u l a t i o n P r o p e r t i e s :
F o r m u l a t i o n D e s c r i p t i o n : SME/Soap pfl : 8-10 V i s c o s i t y : 200-350 cps D e n s i t y : 8 . 6 Appearance: C l e a r , l i g h t y e l l o w 1 Use I n s t r u c t i o n s : Use 1/3 cup p e r
Comment:
Based HDL
q u i d normal s i z e washload
Alpha-Step MC-48 i s an e x c e l l e n t oap s o l u b i l i z e r t h a t can make h i g h soap l e v e l s p o s s i b l e i n f i n i s h e d p r o d u c t s . F o r m u l a t i o n No. 658
F i n e F a b r i c Wash I n g r e d i e n t s : Wt% Water , D . I . 43.4 Alpha-Step MC-48 46.0 N i n o l 30-LL 4 .6 Sodi um c h l o r i de 6 .0 M i x i n g P rocedure :
homogeneous. Add sodium c h l o r i d e t o t h i c k e n . A d j u s t pH w i t h s u l f u r i c a c i d o r sodium h y d r o x i d e as necessa ry . P r o p e r t i e s :
Charge w a t e r and MC-48 and m i x . Add 30-LL and m ix u n t i l
Appearance: C l e a r y e l l o w l i q u i d pH, as i s : 7 . 5 V i s c o s i t y @ 25 deg. C, cps: 220 S o l i d s , %: 29.0 Freeze/ thaw, 3 c y c l e s : pass C o l d s t o r a g e @ 4 deg. C, 1 week: pass H igh temp. s t o r a g e @ 50 deg. C, 1 week: pass D e n s i t y , l b s / g a l : 0 . 6
Use s m a l l amount f o r hand washing o r 1 / 4 cup f o r machine Use I n s t r u c t i o n s :
washing. Comment :
o l e o c h e m i c a l r e s o u r c e s and a r e b i o d e g r a d a b l e . F o r m u l a t i o n No. 358 SOURCE: Stepan C o . : Suggested F o r m u l a t i o n s
The s u r f a c t a n t s used i n t h i s f o r m u l a t i o n a r e d e r i v e d f r o m
9. Metal Cleaners and Polish
Metal Cleaners and Polishes 103
A c i d M e t a l C leaner*
The combina t ion o f Veegum and Rhodopol 23 suspends t h a abra- s i v e and p r o v i d e s a s t a b l e , f r e e f l o w i n g c l e a n e r w i t h good v e r t i c a l s u r f a c e c l i n g . Veegum i s p r o t e c t e d a g a i n s t f l o c c u l a t i o n i n t h i s pH 1 c o m p o s i t i o n t h r o u g h base exchange w i t h t h e i m i d - a z o l i n e . Te t rasod ium EDTA f a c i l i t a t e s t h i s exchange. Veegum and Rhodopol p r o v i d e s y n e r g i s t i c t h i c k e n i ng w i t h b e t t e r v i s c o s i t y s t a b i l i t y and i n h i b i t i o n o f s y n e r e s i s t h a n i s p o s s i b l e w i t h e i t h e r t h i c k e n e r a l o n e . Diatomaceous E a r t h p r o v i d e s good c l e a n s - i n g and p o l i s h i n g .
I n q r e d i e n t s : A : Veegum
Rhodopol 23 Water
y& 0.8 0 . 4
72.1
6: Tet rasod ium EDTA 0 .9 1 - H y d r o x y e t h y l - 2 - c a p r y l i m i d a z o l i i ne Phosphor ic a c i d Diatomaceous E a r t h
Procedure: B lend Veegum and Rhodopol
a g i t a t i ng a t maximum ava i 1 ab smooth. Add B i n g r e d i e n t s i n a d d i t i o n u n t i l smooth and un
Cons is tency : Whi te , p o u r a b l e
0 . 8 1 5 . 0 10 .0
S l o w l y add them t o t h e water w h i l e e shear . Cont inue m i x i n g u n t i l o r d e r , m i x i n g w e l l a f t e r each f o r m ( a v o i d i n c o r p o r a t i o n o f a i r ) . l i q u i d .
Suggested Packaging: P l a s t i c squeeze b o t t l e w i t h p r e c a u t i o n a r y l a b e l i n g f o r a c i d .
*U.S. P a t e n t No. 4,302,253
SOURCE: R.T. V a n d e r b i l t Co., I n c . : F o r m u l a t i o n No. 392
D i ppi ns C1 eaner f o r S i 1 v e r
I n g r e d i e n t s : Zusol a t 1008/85 2 .5 Th iourea 8 . 0 H y d r o c h l o r i c a c i d 3 .0 Water 8 6 . 5
SOURCE: Zschimmer & Schwarz GmbH & Co. : F o r m u l a t i o n CT 02-15-02
104 Advanced Cleaning Product Formulations
A1 umi num C1 eaner /Br i ghtener
T r a d i t i o n a l l y , a n i o n i c s u r f a c t a n t s have o f f e r e d b e t t e r d e t - ergency then non ion ics , bu t were no t compat ib le i n a c i d systems. Th is f o r m u l a t i o n uses Avanel S-70, an a n i o n i c molecule which performs even a t very low pH's and a i d s i n t h e removal o f sur face o i l s and depos i ts . U n l i k e non ion ics , Avanel 5-70 w i l l d i s s o l v e r e a d i l y i n t o the fo rmu la t i on w i thou t fo rming gel p a r t i c l e s thus e l i m i n a t i n g t h e need f o r excessive a g i t a t i o n . T h i s f o r m u l a t i o n can be used f o r over- the-road aluminum t r a i l e r s , w i r e wheels on automobiles o r i n t h e p repara t i on o f aluminum f o r anod iz ing and c l eani ng.
I n q r e d i e n t s : Dei on i zed Water Phosphoric Ac id ( 8 5 % ) C i t r i c Ac id ( 5 0 % ) N i t r i c Ac id (70%) Avanel S-70
Wt% 8 3 . 0
6 . 0 8 . 0 1 . o 2 . 0
Procedure: Charge t h e water t o a mix ing vesse l . Under slow a g i t a t i o n and
w i t h due care, add t h e ac ids t o t h e water. Add t h e Avanel S-70 and m i x 10 minutes. NOTE: I f a d d i t i o n a l b r i g h t e n i n g i s requ i red , t h e n i t r i c a c i d concen t ra t i on may be increased t o 1.5%.
Formula t ion CM-101
Powdered Metal Cleaning Concentrate
I n a r e d i en ts : Sodi um Hydroxide Sodium Carbonate STPP Avanel 5-70
Procedure: Add i n g r e d i e n t s as l i s t e d .
A1 u m i num C1 eaner
I n g r e d i e n t s : Deionized Water Avanel S-70 Tetrapotassium Pyrophosphate Sodium M e t a s i l i c a t e Pentahydrate C a r b i t o l Solvent
Wt% 5 8 . 5 13.5 2 0 . 0
8 . 0
8 5 . 0 6 . 0 5 . 0 1 . o 3.0
Procedure:
e r a t e a g i t a t i o n . NOTE: Other Avanel p roduc ts cou ld be used i n t h i s f o r m u l a t i o n t o achieve d i f f e r e n t s u r f a c t a n t c h a r a c t e r i s t i c s .
SOURCE: PPG I n d u s t r i e s , I n c . : Suggested Formulat ions
Charge vessel w i t h i n g r e d i e n t s i n the order l i s t e d us ing mod-
Metal Cleaners and Polishes 105
A1 umi num Cleaner Concentrate F-498
Water Sodium M e t a s i l i c a t e (Anhydrous) Te t ra Potassium Pyrophosphate (Powder) Mona NF-10
U h W e i g h t 75 10
5 10
Procedure:
i n water w i t h mix ing , then add Mona NF-10.
Typ ica l P roper t i es : Appearance : Clear 1 i q u i d Cloud P o i n t : 8 8 C
Recommended Use D i l u t i o n : 1 t o 4 oz/gal
D isso lve sodium m e t a s i l i c a t e and t e t r a potassium pyrophosphate
Aluminum Wash F-499
Water Sodium M e t a s i l i c a t e (Anhydrous) Te t ra Sodium Pyrophosphate (Powder) B u t y l Carbi t o 1 Mona N F - I 0
% By Weiaht 88
2 3 2 5
Procedure:
i n water, then add Bu ty l C a r b i t o l and Mona NF-10.
Typ ica l P roper t i es :
D isso lve sodium m e t a s i l i c a t e and t e t r a sodium pyrophosphate
Appearance: Clear 1 i qu id pH: 1 2 . 8
Recommended Use D i l u t i o n : 1 : l O w i t h water
SOURCE: Mona I n d u s t r i e s , I n c . : Suggested Formulat ions
106 Advanced Cleaning Product Formulations
B u f f i nq Compound Remover
Component: Water TEA B u r c o t r o p e 1250 Burcosperse LP Borax Burco TME Burco LAF-6
% 42.5 20 .0 1 2 . 5 1 2 . 5
5 .0 5 . 0 5 . 0
Add components i n o r d e r l i s t e d . B l e n d u n t i l homogeneous between each a d d i t i o n .
H o t A1 k a l i n e P a i n t S t r i p p e r C o n c e n t r a t e
Comp o n e n t s : 45% KOH K a s i l #1 Burco HCS-50 NF
a 67 3 2
1
Add components i n t h e o r d e r l i s t e d . B l e n d u n t i l homogeneous between each a d d i t i o n .
SOURCE: B u r l i n g t o n Chemical Co., I n c . : Suggested F o r m u l a t i o n s
M e t a l De-Oi 1 i ng L iqu id C o n c e n t r a t e ( L i q u i d )
S o i l - Petro leum-based o i l S u r f a c e - M e t a l : S t e e l , copper , aluminum, e t c . A p p l i c a t i o n Method - Spray and/or immers ion Manu fac tu re - Mix t a n k w i t h p r o p e l l e r s t i r r e r
Composi t i on : Water S t a r s o EDTA, Te t rasod ium (37%) Sodi um X y l ene Sul f o n a t e (40%) C9-C11 L i n e a r A l c o h o l , 6 Moles EO C9-C11 L i n e a r A l c o h o l , 2.5 Moles EO
Use D i l u t i o n : 2%-4% bv
SOURCE: The PQ Corp . : Suggested F o r m u l a t i o n
wtu/, 4 2 . 0 1 2 . 0 16.0 20.0
3 . 0 7 . 0
Metal Cleaners and Polishes 107
C u t t i n g O i l
Monalube 215 p r o v i d e s e x c e l l e n t l u b r i c i t y , and ex t reme p r e s s - u r e p r o p e r t i e s . T h i s f o r m u l a t i o n i s used i n mach in ing , s tamp ing and d r a w i n g f e r r o u s and n o n f e r r o u s m e t a l s . I n n r e d i e n t s : Wt% 100 P a l e O i l 9 5 . 0 Monalube 215 5 . 0 P rocedure :
Combine i n g r e d i e n t s w i t h a g i t a t i o n w h i l e warming t o 50C. T y p i c a l P r o p e r t i e s :
Appearance: C1 e a r Amber L i q u i d V i s c o s i ty/4OC: 24 CS
Fa1 ex ( D i r e c t S c a l e ) : 2000 Lbs. /56 I n . -Lbs . Draw Bead E f f i c i e n c y : 95 Draw Bead E f f i c i e n c y Re fe rence O i l : 115
Per formance Data:
Formul a t i on F-791
C u t t i n g O i 1
I n q r e d i e n t s : 100 P a l e O i l 90 .0 Monalube 205 5 . 0 Monalube 215 5 . 0 P rocedure :
Combine i n g r e d i e n t s w i t h a g i t a t i o n w h i l e warming t o 50C. T y p i c a l P r o p e r t i e s :
Appearance: C l e a r Amber L i q u i d V i s c o s i t y (40C): 25 CS Fa1 ex : 2250 Lbs . /60 I n . -Lbs .
Appl i c a t i ons: Fo r machi n i ng s tamp ing and d raw i ng . F o r m u l a t i o n F-792
C u t t i n g O i l
I n q r e d i e n t s : 100 P a l e O i l
Wt% 8 5 . 0
Monalube 205 5 . 0 Monalube 215 5 . 0 Monalube 225 5 . 0 Procedure:
Combine i n g r e d i e n t s w i t h a g i t a t i o n w h i l e warming t o 50C. T y p i c a l P r o p e r t i e s :
Appearance: C1 e a r Amber L i q u i d V i s c o s i ty /40C: 30 CS
Per formance Data: F a l e x ( D i r e c t S c a l e ) : 2750 Lbs . /70 I n . . - L b s . Draw Bead E f f i c i e n c y : 90 Draw Bead E f f i c i e n c y Re fe rence O i l : 115
Appl i c a t i ons: Heavy d r a w i n g and s tamp ing F o r m u l a t i o n F-793 SOURCE: Mona I n d u s t r i e s , I n c . : Suggested F o r m u l a t i o n s
108 Advanced Cleaning Product Formulations
Cut t i ng O i l
I n g r e d i e n t s : 100 P a l e O i l Monalube 215 Monalube 225
&% 9 0 . 0
5 . 0 5 .0
Procedure: Combine i n g r e d i e n t s w i t h a g i t a t i o n w h i l e warming t o 50C.
Typ i c a l P r o p e r t i es : Appearance: C l e a r Amber L i q u i d V i s c o s i t y 40C: 27 CS
F a l e x ( D i r e c t S c a l e ) : 2500 Lbs./6O I n . - L b s . Draw Bead E f f i c i e n c y : 90 Draw Bead E f f i c i e n c y Reference O i l : 115
Performance Data:
Formul a t i on F-794
C u t t i n a O i l
I n s r e d i e n t s : 100 Pa le O i l Monalube 225
WtO/o 95 .0
5 .0
Procedure:
T y p i c a l P r o p e r t i e s :
Performance Data:
Combine i n g r e d i e n t s w i t h a g i t a t i o n w h i l e warming t o 50C.
Appearance: C1 ear Amber L i q u i d V i s c o s i t y 40C: 24 CS
F a l e x ( D i r e c t S c a l e ) : 2750 Lbs./6O I n . - L b s . Draw Bead E f f i c i e n c y : 90 Draw Bead E f f i c i e n c y Reference O i l : 115
Formul a t i on F-795
C u t t i n g O i 1
I n q r e d i e n t s : 100 P a l e O i l Monalube 215 Monalube 325
Wt% 9 0 . 0
5 .0 5 .0
Procedure:
T y p i c a l P r o p e r t i e s :
Per formance Data:
F o r m u l a t i o n F-796
SOURCE: Mona I n d u s t r i e s , I n c . : Suggested F o r m u l a t i o n s
Combine i n g r e d i e n t s w i t h a g i t a t i o n w h i l e warming t o 50C.
Appearance: C l e a r Dark Brown L i q u i d V i s c o s i t y 40C: 22 CS
F a l e x ( D i r e c t S c a l e ) : 2250 Lbs. /55 I n . - L b s .
Metal Cleaners and Polishes 109
I n g r e d i e n t s : A r i s t o n a t e M-LF O l e i c A c i d TEA P r o p y l ene G l y c o l Water
C u t t i n g O i l s
S e m i - S y n t h e t i c - C u t t i n g O i 1
Wei qh t% 1 7 . 7 7
2 . 9 8 2 . 7 5
15 .04 61.48
Comments abou t t h i s f o r m u l a : 1 . M i x a l l of t h e i n g r e d i e n t s , excep t t h e P ropy lene G l y c o l . 2 . Add t h e w a t e r SLOWLY. 3 . Add t h e P ropy lene G l y c o l l a s t .
F o r m u l a t i o n SOF-001-01
C u t t i n g O i 1 C o n c e n t r a t e
I n g r e d i e n t s : A r i s t o n a t e M D r e s i n a t e 91 I g e p a l CO-430
O l e i c A c i d , Emersol 213 O l e i c A c i d D i e t h y l e n e G l y c o l Water
KOH, 45%
Wei g h t % 60 .60 2 0 . 2 0
0 . 1 0 1 . 2 5 8 . 2 5 7 . 1 0 2 . 5 0
Comments abou t t h i s f o r m u l a : 1 . S o l u b l e O i l - D i l u t e 1 : 3 w i t h 100 SUS n a p h t h e n i c o i l . 2 . Emuls ion - D i l u t e 4 : 7 6 w i t h 160 ppm h a r d w a t e r .
F o r m u l a t i o n SOL-001-01
C u t t i n g O i 1 C o n c e n t m e
I ny, ,ed i e n t s : A r i s t o n a t e M Neodol 25-3 TEA, 85% O l e i c A c i d D i e t h y l ene G1 y c o l Water
Weight% 5 1 . 8 0 2 1 . 6 0
4 . 5 0 8 . 5 0 8 . 6 0 5 . 0 0
Comments abou t t h i s f o r m u l a : 1 . S o l u b l e O i l - D i l u t e 1 : 3 w i t h 100 SUS n a p h t h e n i c o i l . 2 . Emu ls ion - D i l u t e 4 :76 w i t h 160 ppm h a r d w a t e r .
F o r m u l a t i o n SOL-002-01
SOURCE: P i l o t Chemical Co. : Suggested F o r m u l a t i o n s
I 1 0 Advanced Cleaning Product Formulations
Genera l Purpose Machine C leaner
T h i s i s an e x c e l l e n t a l l - p u r p o s e c l e a n e r f o r c l e a n i n g a l l t y p e s o f f e r r o u s p a r t s and machine s u r f a c e s . Monacor 4000 i s i n c o r p o r a t e d f o r added c o r r o s i o n p r o t e c t i o n .
I n g r e d i e n t s : Water T r i e thanolami ne Monacor 4000 Monami ne CF-1 OOM M o n a t e r i c CyNa-50 Tet rasod ium EDTA (40%) T r i a d i n e 10 ( P r e s e r v a t i v e ) Procedure:
between each a d d i t i o n a t moderate speed. T y p i c a l P r o p e r t i e s :
M i x t h e i n g r e d i e n t s i n o r d e r a t ambient
Appearance: C l e a r amber l i q u i d S p e c i f i c G r a v i t y : 1 .06 pH Concent ra te : 10.2 pH o f a 1:10 s o l u t i o n : 9 . 8
Recommended Use D i l u t i o n : 1 :10 w i t h water Cast I r o n B l o c k : Pass C o r r o s i o n T e s t : 1 :10 D i l u t i o n F o r m u l a t i o n F-770
69.00 4 . 0 0 3 .50 6 .00 6 . 0 0
10.00 I .50
tempera ture . M i x we1 1
A i r c r a f t Cleaner Type I V
The f o l l o w i n g f o r m u l a t i o n uses Monamulse 653-838 as an emul- s i f i e r i n a m i l i t a r y s p e c i f i c a t i o n (MIL-C-855706) f o r m u l a t i o n .
I n a r e d i e n t : P a r t A: Monamulse 653-0313 Monami ne 1-76 Aromat ic 150 I s o p a r M (Odor less M i n e r a l S p i r i t s ) D i e t h y l e n e G l y c o l B u t y l E t h e r Decanol
vvts/,
7 . 0 2 . 7 7 . 5 7 .5 3 . 5 1 . 6
P a r t B:
Water 55.1 P l u r o n i c F98 1 .8 Hycar 1422 1 0 . 6 Procedure:
Add P a r t B t o P a r t A. A g i t a t e u n t i l u n i f o r m . T y p i c a l P r o p e r t i e s :
F o r m u l a t i o n F-784
SOURCE: Mona I n d u s t r i e s , I n c . : Suggested F o r m u l a t i o n s
T r i s o d i u m Phosphate (Dodecahydrate) 2 . 7
Add i n g r e d i e n t s o f P a r t A & P a r t 8 s e p a r a t e l y w i t h a g i t a t i o n .
Appearance: C1 ear L i q u i d
Metal Cleaners and Polishes 111
General Purpose Syn the t i c F l u i d ( A )
I n g r e d i e n t s : Mas l i p 501 Bas= Maphos 8135 Mazon R I 4 A Tr ie thano lamine, 85% B i o c i de Water
Wt96 5.0 8 . 0 8.0 12.0 0.5
Balance
Procedure: 4 . Add i n g r e d i e n t s as l i s t e d . 2. Th is f l u i d i s f o r f e r r o u s meta ls . The concent ra te should be
f u r t h e r d i l u t e d from 1:lO (heavy d u t y ) t o 1:40 ( l i g h t d u t y ) w i t h water t o form a ready-to-use f l u i d . For increased and s t a i n p r o t e c t i o n , inc rease t h e amount o f Mazon R I 4 A . For inc reased l u b r i c i t y inc rease t h e amount o f l u b r i c a n t o r extreme pressure a d d i t i v e .
General Purpose Syn the t i c F l u i d (BZ
I n g r e d i e n t s : Mas l i p 500 Mazon R I 8 B Propyl ene G1 yco l T o l y t r i a z o l e (Cl imax) T r i ethanolami ne, 85% 8 i o c i de Water
Wt% 38.0 12.0 2.5 2.5 10.0 0.5
Balance
Procedure: 1 . Add i n g r e d i e n t s as l i s t e d . 2 . T h i s f l u i d i s f o r f e r r o u s meta ls . The concent ra te should be
f u r t h e r d i l u t e d from 1:lO (heavy d u t y ) t o 1:40 ( l i g h t du ty ) w i t h water t o form a ready-to-use f l u i d . For increased r u s t and s t a i n p r o t e c t i o n , inc rease t h e amount o f Mazon R I 8 B . For increased l u b r i c i t y inc rease t h e amount o f l u b r i c a n t o r extreme pressure a d d i t i v e .
Copper Machinina F l u i d I n g r e d i e n t s : Macol 5100 Mazon R I 6 Maphos 8135 Potassi um Hydroxide B i o c i de Water
Procedure: Add i n g r e d i e n t s as l i s t e d .
SOURCE: PPG I n d u s t r i e s , I n c . : Suggested Formulat ions
Wt% 15.0 8.0 7.0 6.0 0.5
Balance
112 Advanced Cleaning Product Formulations
Genera l Purpose S y n t h e t i c F l u i d (C )
I n g r e d i e n t s : M a s l i p 501 A Mazon R I 8 B Maphos 58 T r i e t h a n o l ami ne, 85% B i o c i de Water
Mle9/0 3 0 . 0 12.0
6 . 0 7.0 0 . 5
5al ance
Procedure: 1. Add i n g r e d i e n t s as l i s t e d . 2 . T h i s f l u i d i s f o r f e r r o u s m e t a l s . The c o n c e n t r a t e s h o u l d b e
f u r t h e r d i l u t e d f r o m 1:lO (heavy d u t y ) t o 1 : 4 0 ( l i g h t d u t y ) w i t h w a t e r t o f o r m a ready - to -use f l u i d . F o r i n c r e a s e d r u s t and s t a i n p r o t e c t i o n , i n c r e a s e t h e amount o f Mazon R I 8 8. F o r i n c r e a s e d l u b r i c i t y i n c r e a s e t h e amount of l u b r i c a n t o r ext reme p r e s s u r e a d d i t i v e .
Genera l Purpose S y n t h e t i c F l u i d (D)
I n s r e d i e n t s : M a s l i p 501 Base Mazon R I 8 A Maphos 8135 T r i e t h a n o l ami n e , 85% B i o c i de Water
Wt% 12 .0 2 5 . 0
5 . 0 1 2 . 0
0 . 5 5 a l ance
Procedure: 1 . Add i n g r e d i e n t s as l i s t e d . 2 . T h i s f l u i d i s f o r f e r r o u s m e t a l s . The c o n c e n t r a t e s h o u l d be
f u r t h e r d i l u t e d f r o m 1:lO (heavy d u t y ) t o 1 : 4 0 ( l i g h t d u t y ) w i t h w a t e r t o f o r m a ready - to -use f l u i d . F o r i n c r e a s e d r u s t and s t a i n p r o t e c t i o n , i n c r e a s e t h e amount o f Mazon R I 8 A . For i n c r e a s e d l u b r i c i t y i n c r e a s e t h e amount o f l u b r i c a n t o r ext reme p r e s s u r e a d d i t i v e .
SOURCE: PPG I n d u s t r i e s , I n c . : Suggested F o r m u l a t i o n s
Metal Cleaners and Polishes 113
M e t a l C leaner (Phosphate, Powder)
Soi 1 -Drawing l u b r i c a n t , an imal f a t and grease S u r f a c e - S t e e l A p p l i c a t i o n Method-Spray Manufacture-Dry b lend/Agglomerat
Composi t i on : *STPP *Sodi um Carbonate * * A l k o x y l a t e d l i n e a r a l c o h o l non ion
( 1 ow foam) Metso Beads 2048 Sodi um Hydrox ide Beads
on
10.0 25.0
5 . 0 30 .0 30.0
c s u r f a c t a n t
Use: Heavy d u t y low- foaming meta l c l e a n e r wh ich i s good f o r a
Use D i l u t i o n : 0.8-1.5% bw (1-2 o z / g a l l o n ) spray c l e a n i n g p r o c e s s .
FMC ** O l i n P o l y t e r g e n t S-305LF o r
Rhone-Poulenc I g e p a l CO-530
A1 umi num C1 eaner (Phosphate, Powder)
Soi 1 - L i g h t d rawing o i 1 Surface-Aluminum A p p l i c a t i o n Method-Spray washer Manufacture-Dry b l end/Aggl omera t i on
Composi t i on : Metso Beads 2048 *STPP *Sodi um B i c a r b o n a t e **Sodium P o l y a c r y l a t e ***Octy lphenoxy P o l y e t h o x y e t h a n o l , 9-10 Moles EO
Use D i l u t i o n : 1.5-3.036 bw (2-4 o z / g a l )
* FMC ** Rohm 8, Haas Acusol 445ND (92% s o l i d s ) *** Rhone-Poul enc I g e p a l CA-630
SOURCE: PQ C o r p . : Detergent F o r m u l a t i o n Guide
Wt% 45.0 30.0 20 .0
3 .0 2 . 0
114 Advanced Cleaning Product Formulations
M e t a l C1 eaner (Phosphate. Powder2
S o i l - O i l , d r a w i n g l u b r i c a n t , an imal f a t Sur face-Stee l A p p l i c a t i o n Method-Immersion ManufacturekDry b lend/Agg lomera t ion
Composi t i o m *Sodium Carbonate *STPP **Octy lphenoxy P o l y e t h o x y e t h a n o l ( 6 Moles € 0 ) Metso Beads 2048 Sodi um Hydrox ide Beads
Use D i l u t i o n : 2 .3-4.5% bw (3-6 o z / g a l l o n )
* FMC ** Rhone-Poulenc I g e p a l CA-630
and grease
2 0 . 0
Meta l C1 eaner (Phosphate, Powder)
S o i l - O i l , d rawing l u b r i c a n t , animal f a t and grease S u r f a c e - S t e e l A p p l i c a t i o n Method-Immersion/electrolytic c l e a n i n g Manufacture-Dry b lend/Agg lornera t ion
Com o s i t i o n :
TSP Metso Beads 2048 Sodium Carbonate *Octy lphenoxy P o l y e t h o x y e t h a n o l (12-13 Moles EO) Sodium H y d r o x i d e Beads
Use D i l u t i o n : 2 . 3 - 4 . 5 % bw (3-6 o z / g a l )
* Rhone-Poulenc I g e p a l CA-720
SOURCE: PO C o r p . : Detergent F o r m u l a t i o n Guide
TSPF
8 . 0 2 . 0
3 0 . 0 40 .0
Wt% 1 5 . 0
5 . 0 3 5 . 0 28.0
2 . 0 1 5 . 0
Metal Cleaners and Polishes 115
M e t a l C leaner I Phosphate, Powder 1
So i 1 -0i 1, f a t , p r o t e i n S u r f a c e - S t a i n l e s s s t e e l A p p l i c a t i o n Method-Cleaning i n p l a c e Manu fac tu re -Dry b l e n d / A g g l o m e r a t i o n
Composi t i o n A : *STPP *Sodium Carbonate * * L i q u i d N o n i o n i c S u r f a c t a n t (C12-Cl3; 3 Moles EO) Metso Beads 2048 Sodi um H y d r o x i d e Beads
- Compos i t i on 0 : *STPP *Sodium Carbonate * * L i q u i d N o n i o n i c S u r f a c t a n t (C12-Cl3; 3 Moles EO) Metso Pentabead 20
Use D i l u t i o n : 1 .5-3.0% bw (2 -4 o z / g a l l o n )
* FMC ** Rhone-Poluenc Rhodasur f A-24
M e t a l C1 eaner ( Z e r o Phosphate, Powder)
Soi 1-Oi 1 , d r a w i n g l u b r i c a n t , animal f a t and g rease S u r f a c e - S t e e l A p p l i c a t i o n Method-Immersion Manu fac tu re -Dry b lend /Agg lo rne ra t i on
Composi t i on: V a l f o r 100 Z e o l i t e A Sodium Carbonate *Oc ty lphenoxy P o l y e t h o x y e t h a n o l (9-10 Moles EO) Metso Pentabead 20 Acusol 445ND Sodi um P o l y a c r y l a t e
Use L e v e l : 3-6 o z / g a l l o n
g Rhone-Poulenc I g e p a l CA-630
SOURCE: PB C o r p . : D e t e r g e n t F o r m u l a t i o n Guide
40.0 12.0
3 . 0 2 5 . 0 20.0
WtO/o 40 .0 12 .0
3 . 0 45.0
WtO/o 15.0 38.0
2 .0 43.0
2 . 0
116 Advanced Cleaning Product Formulations
Non-Phosphorous Aluminum Cleaner
Th is i s a t o t a l l y o rgan ic , phosphate-free aluminum c leaner t h a t p rov ides excel 1 en t c l eani ng and b r i gh ten i ng o f a1 umi num. The Avanel S-70 p rov ides f o r removal o f o rgan ic su r face depos i t s and, by su r face tens ion reduc t i on , b e t t e r con tac t between the aluminum sur face and t h e organ ic ac ids . I n a d d i t i o n t o i n d u s t r i a l a p p l i c a t i o n s l i k e c lean ing over- the-road aluminum t r a i l e r s and aluminum p r i o r t o anodiz ing, t h i s c leaner may also be used i n household a p p l i c a t i o n s such as c lean ing aluminum f l a s h i n g , windows and door f i x t u r e s . Depending on the app l i ca - t i o n , t h i s p roduc t may be used i n a Dressure wash, pump spray o r d i p tank .
I n q r e d i e n t s : C i t r i c Acid, 50% Gluconic Acid, 50% Avanel S-70 Deionized Water, Dye
w.e-l 12.0 8 . 0 3.0
Balance
Procedure: Charge t h e water, c i t r i c ac id , g lucon c a c i d and Avanel S-70
Mix w e l l . If dye i s t o be added, p a r t o f t he water should be he out; and t h e dye added t o t h i s water w i t good a g i t a t i o n . The d i sso l ved dye can then be added t o t h e ba tch . NOTE: Ce r ta in dyes may n o t be s t a b l e under these c o n d i t i o n s . Consequently, s h e l f s t a b i l i t y t e s t s should be performed.
Formula t ion CM-102
d
A1 k a l i ne A1 u m i num C1 eaner
I n a r e d i e n t s : Dei on i zed Water Avanel S-70 Tetrapotassium Pyrophosphate Sodium M e t a s i l i c a t e Pentahydrate Macol 48
pH (as i s ) : 11.5-12.5 Appearance: C lear , water -wh i te l i q u i d S p e c i f i c G r a v i t y : 1 .05
8 7 . 0 4 .0 5.0 1 . o 3 . 0
Procedure: Charge t h e water and d i s s o l v e t h e b u i l d e r s a l t s under a g i t -
a t i o n . When d i sso l ved , charge t h e remaining i n g r e d i e n t s . Cont inue m ix ing f o r a t l e a s t 15 minutes. NOTE: Th i s a l k a l i n e aluminum c leaner has shown excel l e n t c l eani ng p r o p e r t i e s w i thou t chemical a t t a c k o f t h e meta l . Th i s f o r m u l a t i o n may be c u t -!:I w i t h water t o p repare a m i l d hard-sur face c leaner .
SOURCE: PPG I n d u s t r i e s , I n c . : Suggested Formulat ions
Formula t ion CM-1034
Metal Cleaners and Polishes 11 7
Semi S y n t h e t i c
T h i s f o r m u l a t i o n i s p a r t i c u l a r l y u s e f u l f o r heavy mach in ing and l i g h t d r a w i n g f o r f e r r o u s and s t a i n l e s s s t e e l .
I n g r e d i e n t s : 100 P a l e O i l Monalube 320 Monalube 610 Monalube 205 Monalube 215 T r i e t h a n o l ami ne (99%) Monacor BE Water
P rocedure : Combi ne i n g r e d i e n t s w i t h a g i t a t i o n .
T y p i c a l P r o p e r t i e s :
Per formance Data (5% i n W a t e r ) : Appearance: C l e a r Amber L i q u i d
Fa1 ex ( D i r e c t S c a l e ) : 2500 Lbs. /50 I n . -Lbs. Cast I r o n B l o c k C o r r o s i o n T e s t : Pass Appearance: C l e a r pH: 9 . 6
F o r m u l a t i o n F-797
Semi S y n t h e t i c
I n Q r e d i e n t s : 100 P a l e O i 1 Monalube 320 Monalube 610 Monalube 220 T r i e t h a n o l a m i n e (99%) Monacor BE Water
wt9j0 9 . 0 9 . 0 13.6 0.8 0.8 3.2 5.0
58.6
wt9j0 9 . 0 9 . 0 13.6 1.6 3.2 5.0 58.6
Procedure:
c o n c e n t r a t e t o 95% w a t e r fo rms m i c r o e m u l s i o n . F o r m u l a t i o n can be used f o r g r i n d i n g and l i g h t mach in ing .
T y p i ca9 P r o p e r t i es : Appearance : C1 e a r Amber L i q u i d
Per formance Data ( 5 % i n Wate r ) : Appearance: C l e a r L i q u i d p H : 9.5 S u r f a c e Tens ion (dynes/cm): 32 Cast I r o n B l o c k C o r r o s i o n T e s t : Pass F a l e x ( D i r e c t S c a l e ) : 2500 Lbs./45 I n . - L b s .
M i x i t e m s 1,2, and 3 u n t i l c l e a r . Add i t e m s 4,5, and 6 . 5% o f
Formul a t i on F-800
SOURCE: Mona I n d u s t r i e s , I n c . : Suggested F o r m u l a t i o n s
I18 Advanced Cleaning Product Forniulations
Semi S y n t h e t i c
I n a r e d i e n t s : 100 P a l e O i l Monalube 225 TEA Monalube 610 Water
T y p i c a l P r o p e r t i e s :
Per formance Data ( 5 % i n w a t e r ) : Appearance: C1 e a r L i q u i d pH: 9 .0 Cast I r o n B l o c k C o r r o s i o n T e s t : Pass Fa1 ex ( D i r e c t Sca l e ) : 2750 Lbs. /55 I n . -Lbs .
Appearance: C 1 e a r Amber L i q u i d
For mach in ing l i g h t s tamp ing and d r a w i n g . F o r m u l a t i o n F-799
Semi S y n t h e t i c
I n q r e d i e n t s : 100 P a l e O i l Monalube 320 Monalube 610 Monalube 205 T r i e t h a n o l a m i n e (99%) Monacor BE Water
y& 1 0 . 0
5 .5 7.5
25.0 47 .5
Wt% 9 . 0 9 . 0
13 .6 1 . 6 3 .2 5 . 0
5 8 . 6
P rocedure :
5% o f c o n c e n t r a t e added t o w a t e r fo rms m i c r o e m u l s i o n . Suggested f o r g r i n d i n g and mach in ing f o r b o t h f e r r o u s and n o n f e r r o u s m e t a l s .
T y p i c a l P r o p e r t i e s :
M i x i t e m s 1 , 2, and 3 u n t i l c l e a r . Add i t e m s 4 and 5 t h e n 6 .
Appearance: C l e a r Amber L i q u i d
Per formance Data ( 5 % i n Wate r ) : Appearance: C l e a r L i q u i d p H : 9 .5 S u r f a c e Tens ion : 2 7 . 0 Cast I r o n B l o c k C o r r o s i o n T e s t : Pass Fa1 ex ( D i r e c t S c a l e ) : 2500 Lbs. /57 I n . -Lbs .
F o r m u l a t i o n F-801
SOURCE: Mona I n d u s t r i e s , I n c . : Suggested F o r m u l a t i o n s
Metal Cleaners and Polishes 119
Silver and Metal Polish
I n a d d i t i o n t o th i cken ing , Carbopol r e s i n s impar t y i e l d va lue a l l o w i n g p a r t i c l e s , such as abrasives, t o become permanently suspended ~ The r e s i n a1 so prevents "creami ng" o r phase separ- a t i o n by suspending and separa t ing t h e o i l d r o p l e t s .
I n s r e d i e n t : SF96 S i l i c o n e F l u i d (350) ( 1 ) Dow Corninp 20 Release Coat ing (2 ) Stoddard Solvent (3) P r i f a c 2922 Laur i c Ac id D I Water Morphol i ne Carbopol EZ-2 ( 4 ) Ammoni um hydroxide bgopg l i e Kao l i Clay (5)
ysp c a f Proper€+ es. B r o o k f i e l d V i s c o s i t y (RVT-20 rpm):
Wt% 1 .oo 2 . 0 0
20.00 2.00
43.48 0.86 0.35 0.31 14.00
10,000 cps Product pH: 8.50 Product C l a r i t y : Paste
Raw Ma te r ia l Supp l ie rs : ( 1 ) General E l e c t r i c ( 2 ) Dow Corning Corp. ( 3 ) Exxon Corp. ( 4 ) BFGoodrich (5) Kaopo l i te , I n c .
Procedure: 4 . Add t h e s i l i c o n e f l u i d , re lease coat ing , so lvent , and l a u r i c
a c i d P o a vesse l . Mix us ing a h igh shear mixer. 2 . Continue t o mix, and add t h e water (43.48 p a r t s ) and t h e
morphol i ne. 3 . Disperse t h e Carbopol i n t o t h e water (16.00 p a r t s ) by s imply
"dumping" i t i n . The polymer w i l l wet ou t i n a few minutes. Add t h e d i spe rs ion t o t h e above m ix tu re w i t h good a g i t a t i o n .
4. Add t h e ammonium hydroxide t o reach t h e t a r g e t pH. 5. Add t h e c l a y and mix u n t i l uni form.
T o t a l Act i ves : S i l i c o n e f l u i d : 1 .oo Stoddard so l ven t : 20.00 Re1 ease c o a t i ng : 2.00 Abras i vet 14.00
FGoodrich Spec ia l t y Chemicals: DET-563
120 Advanced Cleaning Product Formulations
So lub le O i 1
I n g r e d i e n t s : 100 Pale O i l Monalube 605 P a r o i l 160
WtO/o 8 0 . 0 20 .0 2 0 . 0
Procedure: Combine a l l i n g r e d i e n t s w i t h a g i t a t i o n w h i l e warming t o 50C.
Typi c a l P roper t i es : Appearance: C lear Dark Brown
Performance Data (5% i n water ) : Appearance: M i 1 ky L i q u i d pH: 8 . 5 Falex ( D i r e c t Sca le ) : 2750 Lbs./60 In . -Lbs .
Above f o r m u l a t i o n f o r heavy du ty machining and drawing f o r use on s t a i n l e s s s t e e l and fe r rous meta ls . Formula t ion F-803
Soluble O i 1
I n g r e d i e n t s : 100 Pale O i l Monalube 605
Wt% 85.0 1 5 . 0
Procedure: Combine above i n g r e d i e n t s w i t h a g i t a t i o n w h i l e warming t o 5 0 C .
Typ ica l P roper t i es : Appearance: Clear L i g h t Brown L i q u i d
Performance Data (5% i n wa te r ) : Appearance: M i 1 ky Emulsion pH: 8 . 8 Cast I r o n B lock Cor ros ion Tes t : Pass Falex ( D i r e c t Sca le ) : 1750 Lbs./47 In . -Lbs .
Appl i c a t i on:
Formul a t i on F-804
SOURCE: Mona I n d u s t r i e s , I n c . : Suggested Formula t ions
For g r i n d i n g and very l i g h t machining.
Metal Cleaners and Polishes 121
S o l u b l e Qi 1
I n a r e d i e n t s : 100 P a l e O i l
Wt% 78.0
Monalube 605 Wonalube 215 T EA
1 5 . 0 5 . 0 2 . 0
P rocedure :
u t i o n i s s l i g h t l y hazy, a d j u s t w i t h t a l l o i l f a t t y a c i d . M i x above i n g r e d i e n t s w i t h a g i t a t i o n . Warm t o 12OF. I f s o l -
T y p i c a l P r o p e r t i e s : Appearance: M i l k y Emuls ion
Per formance Data (5% i n Wate r ) : Appearance: M i 1 ky Emu1 s i o n pH: 8 . 0 Cas t I r o n B l o c k C o r r o s i o n T e s t : Pass Fa1 ex ( D i r e c t S c a l e ) : 2500 Lbs . /55 I n . -Lbs .
The above f o r m u l a t i o n i s suggested f o r g r i n d i n g and l i g h t mach in ing . F o r m u l a t i o n F-805
S o l u b l e O i 1
I n g r e d i e n t s : 100 P a l e O i l Monalube 605 Monalube 215
Procedure : Combine i n g r e d i e n t s w i t h a g i
T y p i c a l P r o p e r t i e s : Appearance: C l e a r Amber L i q u
Per formance Data (5% i n W a t e r ) : Aooearance: M i 1 kv Emuls ion
Wt% 8 5 . 0 1 0 . 0
5 . 0
a t i o n w h i l e warming t o 50C.
d
. . pH: 8 . 0 F a l e x ( D i r e c t S c a l e ) : 1250 L b s . / 4 5 I n . - L b s .
The above f o r m u l a t i o n i s suggested f o r g r i n d i n g and l i g h t mach in ing . F o r m u l a t i o n F-806
SOURCE: Mona I n d u s t r i e s , I n c . : Suggested F o r m u l a t i o n s
122 Advanced Cleaning Product Formulations
S o l u b l e O i l M a c h i n i n g F l u i d
Monalube 225 p r o v i d e s l u b r i c i t y , and EP p r o p e r t i e s i n t h i s mach in ing f l u i d . T h i s f o r m u l a t i o n was des igned f o r mach in ing ca rbon s t e e l , b r a s s , b ronze copper and s t a i n l e s s s t e e l .
I n g r e d i e n t s : Naph then ic O i l (lOOSUS/lOO) Monalube 225 Monalube 605 T r i e t h a n o l a r n i n e (99%)
Procedure : Add i n t h e o r d e r l i s t e d w i t h a g i t a t i o n .
F a l e x EP T e s t : D i r e c t Load S c a l e : 2750 l b s Torque: 47 i n c h pounds
Use D i l u t i o n s : G r i n d i n g : I -2% i n w a t e r L i g h t M a c h i n i n g : 3-5% i n wa te r Moderate Mach in ing : 5-7% i n wa te r Heavy M a c h i n i n g : 8-10% i n wa te r
Formula F-764
Wt% 72 .0
5 . 0 20.0
3 . 0
S y n t h e t i c M a c h i n i n q F l u i d
T h i s f o r m u l a t i o n i s i d e a l f o r mach in ing ca rbon s t e e l , b r a s s , bronze, copper , aluminum and s t a i n l e s s s t e e l .
I n g r e d i e n t s : Monalube 225 T r i e t h a n o l a m i n e (99%) Water
Procedure: Add i n t h e o r d e r l i s t e d w i t h a g i t a t i o n .
F a l e x EP T e s t P rocedure : C o n c e n t r a t i o n : 20% Aqueous s o l u t i o n D i r e c t Load S c a l e 3000 l b s . Torque 60 i n c h pounds
Formul a t i on F-766
SOURCE: Mona I n d u s t r i e s , I n c . : Suggested F o r m u l a t i o n s
wto/, 1 5 . 0 3 0 . 0 5 5 . 0
Metal Cleaners and Polishes 123
S v n t h e t i c
I n g r e d i e n t s : Monalube 210 T r i e t h a n o l a m i n e (99%) Water A n t i foam
Procedure : Combine i n g r e d i e n t s w i t h a g i t a t i o n .
T y p i c a l P r o p e r t i e s : Appearance: C l e a r Amber L i q u i d
Per formance Data ( 5 % i n W a t e r ) : Appearance: C l e a r L i q u i d pH: 8 . 5 S u r f a c e Tens ion : 42 Cast I r o n B l o c k C o r r o s i o n T e s t : Pass F a l e x ( D i r e c t S c a l e ) : 2500 Lbs . /56 I n . - L b s .
Wt% 16.6 33.3 50.0 0.1
The f o r m u l a t i o n i s des igned f o r f e r r o u s and n o n f e r r o u s m e t a l s p r i m a r i l y f o r g r i n d i n g . Formul a t i on F-819
S y n t h e t i c
I n q r e d i e n t s : Monalube 210 Monalube 315 T r i e t h a n o l a m i n e (99%) Water
Procedure.: Combine i n g r e d i e n t s w i t h a g i t a t i o n .
T y p i c a l P r o p e r t i e s :
Per formance Data (5% i n W a t e r ) : Appearance: C l e a r L i q u i d p H : 8 . 0 Cast I r o n B l o c k C o r r o s i o n T e s t : Pass F a l e x ( D i r e c t S c a l e ) : 2500 Lbs . /56 I n . - L b s .
Appearance: C l e a r Amber L i q u i d
K% 1 2 . 5 1 2 . 5 2 5 . 0 5 0 . 0
F o r m u l a t i o n i s des igned f o r b o t h f e r r o u s and n o n f e r r o u s systems p r i m a r i l y f o r g r i n d i n g . F o r m u l a t i o n F-820
SOURCE: Mona I n d u s t r i e s , I n c . : Suggested F o r m u l a t i o n s
124 Advanced Cleaning Product Formulations
S y n t h e t i c Drawing/Stampinp F l u i d
T h i s f o r m u l a t i o n i s i d e a l f o r s tamp ing h o t o r c o l d r o l l e d s t e e l .
I n g r e d i e n t s : Monalube 225 T r i e t h a n o l a m i n e (99%) Monalube 315 Water
P rocedure : Add i n t h e o r d e r l i s t e d w i t h a g i t a t i o n .
F a l e x EP T e s t P rocedure : C o n c e n t r a t i o n : 20% Aqueous s o l u t i o n D i r e c t Load S c a l e 3000 l b s . Torque 55 i n c h pounds
F o r m u l a t i o n F-765
1 5 . 0 30.0 20.0 35 .0
O i 1 Based Drawi ng/Stampi ng F1 ui d
Monalube 225 p r o v i d e s l u b r i c i t y , EP and c o n t r i b u t e s t o t h e c o r r o s i o n p r o t e c t i o n p r o p e r t i e s i n t h i s heavy -du ty s tamping/ d raw i ng f 1 u i d.
I n g r e d i e n t s : P a r a f f i n i c O i l (300SUS/lOO) Monalube 225
Procedure: B lend Monalube 225 i n t o t h e o i l
F a l e x EP T e s t : D i r e c t Load S c a l e : 3000 l b s Torque 57 i n c h pounds
F o r m u l a t i o n F-763
Spray M e t a l C1 ean i ng C o n c e n t r a t e
I n g r e d i e n t s : Water Sodi um Metas i 1 i c a t e Sodium Carbonate Sodi um H y d r o x i d e Monatrope 1250 A l k y l P o l y a l k y l e n e E t h e r
Procedure:
i n g r e d i e n t i s d i s s o l v e d b e f o r e n e x t a d d i t i o n . F o r m u l a t i o n F-751
SOURCE: Mona I n d u s t r i e s , I n c . : Suggested F o r m u l a t i o n s
Add i n o r d e r l i s t e d w i t h a g i t a t i o n , making s u r e each
Wt% 9 0 . 0 1 0 . 0
75.00 3 . 0 0 4 . 0 0 5 .00
11 .00 2.00
I n q r e d i e n t s : Monalube 205 Monalube 210 T r i e t h a n o l a m i n e (99%) Water
Metal Cleaners and Polishes 125
S y n t h e t i c Formula
W y t 5 . 0
10.0 30 .0 55.0
P rocedure : Combine i n g r e d i e n t s w i t h a g i t a t i o n .
T y p i c a l P r o p e r t i e s : Appearance: C1 e a r Amber L i q u i d
Per formance Data (5% i n Wate r ) : Appearance: C l e a r L i q u i d p H : 8.7 S u r f a c e Tens ion : 27 Cast I r o n B l o c k C o r r o s i o n T e s t : Pass F a l e x ( D i r e c t S c a l e ) : 2500 Lbs . /47 I n . - L b s .
T h i s f o r m u l a t i o n i s des igned f o r b o t h f e r r o u s and n o n f e r r o u s systems f o r a r e a s o f mach in ing and g r i n d i n g a t 10% f o r m i l d s tampi ng. F o r m u l a t i o n F-813
S y n t h e t i c Formula
I n q r e d i e n t s : Monalube 205 Monalube 210 Monalube 315 T r i e t h a n o l ami ne (99%) Water
wt% 5 . 0
10.0 10.0 30 .0 45 .0
P rocedure : Combine i n g r e d i e n t s w i t h a g i t a t i o n .
T y p i c a l P r o p e r t i e s : Appearance: C1 e a r Amber L i q u i d
Per formance Data ( 5 % i n Wate r ) : Appearance: C1 e a r L i q u i d pH: 8 .0 S u r f a c e Tens ion : 32 Cast I r o n B l o c k C o r r o s i o n T e s t : Pass F a l e x ( D i r e c t S c a l e ) : 2750 Lbs. /57 I n . - L b s .
T h i s f o r m u l a t i o n i s des igned f o r b o t h f e r r o u s and n o n f e r r o u s systems f o r a reas o f mach in ing and g r i n d i n g a t 10% f o r m i l d s tampi ng. F o r m u l a t i o n F-814
SOURCE: Mona I n d u s t r i e s , I n c , : Suggested F o r m u l a t i o n s
126 Advanced Cleaning Product Formulations
Syn the t i c Formula
I n q r e d i e n t s : Monalube 2 0 5 Monalube 220 Tr ie thano lamine (99%) Monalube 315 Water
w%% 4.5 9 . 0
2 7 . 0 2 0 . 0 39.5
Procedure: Mix i tems 1, 2 , 3, and 4 . Add water and mix u n t i l homogeneous.
Typ ica l P roper t i es :
Performance Data (5% i n Water) :
Appearance: C lear Amber L i q u i d
Appearance: Trans lucent S o l u t i o n pH: 9 .0 Surface Tension: 32 Cast I r o n B lock Corrosion Tes t : Pass Falex ( D i r e c t Sca le ) : 2500 Lbs./47 In . -Lbs .
Formula t ion F-815
Syn the t i c Formula
Clear product designed f o r f e r r o u s g r i n d i n g .
I n g r e d i e n t s : Monalube 210 Mona1 ube 110 Water
Procedure: Combine i ngredi en ts w i t h a g i t a t i o n .
Typ ica l P r o p e r t i e s : Appearance: C1 ear Sol u t i on
Performance Data (5% i n Water) : Appearance: C1 ear L i qu id pH: 7 . 5 Falex ( D i r e c t Sca le ) : 2500 Lbs./45 In . -Lbs .
15.0 40.0 4 5 . 0
Note: No TEA needed. Excess DEA i n Monalube 110 n e u t r a l i z e s PE. Formula t ion F-816
SOURCE: Mona I n d u s t r i e s , I n c . : Suggested Formulat ions
Metal Cleaners and Polishes 127
S y n t h e t i c Formula
P roduc t d e s i gned f o r g r i n d i ng and 1 i g h t mach in ing
I n g r e d i e n t s : Monalube 210 T r i e t h a n o l a m i n e (99%) Monalube 315 Water
P rocedure : Combine i n g r e d i e n t s w i t h a g i t a t i o n .
T y p i c a l P r o p e r t i e s : Appearance: C l e a r Amber L i q u i d
Per formance Data (5% i n W a t e r ) : Appearance: C1 e a r L i q u i d pH: 8 . 0 Cast I r o n B l o c k C o r r o s i o n T e s t : Pass F a l e x ( D i r e c t S c a l e ) : 2500 Lbs . /45 I n . - L b s .
F o r m u l a t i o n F-817
S y n t h e t i c Formula
I n a r e d i e n t s : Monalube 215 T r i e t h a n o l ami ne (99%) A n t i foam Water
P rocedure : Combine i n g r e d i e n t s w i t h a g i t a t i o n .
T y p i c a l P r o p e r t i e s : Appearance: C l e a r Amber L i q u i d
Per formance Data (5% i n W a t e r ) : Appearance: C l e a r L i q u i d pH: 8 . 5 S u r f a c e Tens ion : 42 F a l e x ( D i r e c t S c a l e ) : 2500
Produc t des igned f o r machi n A l s o some v e r y l i g h t s tamp ing . F o r m u l a t i o n F-818
SOURCE: Mona I n d u s t r i e s , I n c . :
Wt% 15 .0 30.0 10 .0 45.0
Wt% 16.6 3 3 . 3
0 . 1 50.0
b s . / 4 4 I n . - L b s .
ng f e r r o u s and n o n f e r r o u s m e t a l .
Suggested F o r m u l a t i o n s
128 Advanced Cleaning Product Formulations
Syn the t i c Formula
I n g r e d i e n t s : Monalube 210 Monoethanol ami ne Water
Procedure: Combine i n g r e d i e n t s w i t h a g i t a t i o n .
Typ ica l P roper t i es :
Performance Data (5% i n Water): Appearance: C lear L i q u i d pH: 1 1 Cast I r o n B lock Cor ros ion Test: Pass Fa1 ex (Di r e c t Scal e) : 2250 Lbs. /58 In. -Lbs.
Appearance: C lear Amber L i q u i d
Formulated f o r g r i n d i n g a p p l i c a t i o n s . Ferrous metals on l y . Formula t ion F-821
Syn the t i c Formula
Ing red ien ts : Monalube 205 Tr ie thano lamine (99%) A n t i foam Water
Procedure: Combi ne i ngredi en ts w i t h a g i t a t i o n .
Typ ica l P r o p e r t i es :
Performance Data (5% i n Water): Appearance: C1 ear L i q u i d pH: 8 . 3 Sur face Tension (dynes/cm): 24 Cast I r o n B lock Corrosion Test: Pass Fa1 ex (D i r e c t Scale) : 2500 Lbs . / 5 5 In. -Lbs .
Appearance: Clear Amber L i q u i d
Q 1 6 . 6 3 3 . 3 50.4
1 6 . 6 3 3 . 3
0 . 1 50.0
Th is i s t h e most un i ve rsa l formula s ince i t can be used on all meta l l u rgy a t 1% t o 2%. I t a l s o can be used f o r g r i n d i n g a t 5% t o 8% f o r machining and a t 8% t o 15% f o r r e a l heavy machining. Formula t ion F-822
SOURCE: Mona I n d u s t r i e s , I n c . : Suggested Formula t ions
Metal Cleaners and Polishes 129
Svnthet i c Formul a
I n a r e d i e n t s : Monalube 205 Monalube 110 Water
P rocedure : Combine i n g r e d i e n t s w i t h a g i t a t i o n .
T y p i c a l P r o p e r t i e s : Appearance: C l e a r S o l u t i o n
Per formance Data (5% i n Wate r ) : Appearance: C1 e a r L i q u i d ptl: 8 . 0 S u r f a c e Tens ion : 28 Cast I r o n B l o c k C o r r o s i o n F a l e x ( D i r e c t S c a l e ) : 2250
Fo r use i n mach in ing and 1 n o n f e r r o u s m e t a l s . NOTE: Excess DEA i n Monalube
phosphate e s t e r . F o r m u l a t i o n F-823
Wt% 10 .0 30.0 6 0 . 0
e s t : Pass Lbs./5O I n . - L b s .
g h t s tamp ing f o r f e r r o u s and
10 i s enough t o n e u t r a l i z e t h e
* t h e t i c Formula
I n g r e d i e n t s : Monalube 205 Monoethanol ami ne Water
P rocedure : Combine i n g r e d i e n t s w i t h a g i t a t i o n .
T y p i c a l P r o p e r t i e s :
Per formance Data (5% i n W a t e r ) : Appearance: C l e a r L i q u i d p H : 10 Cast I r o n B l o c k : Pass Fa1 ex ( D i r e c t Sca l e ) : 2000 Lbs. /50 I n . -Lbs.
Appearance: C l e a r Amber L i q u i d
Fo r f e r r o u s systems f o r mach in ing and g r i n d i n g . Formul a t i on F-824
SOURCE: Mona I n d u s t r i e s , I n c . : Suggested F o r m u l a t i o n s
25.0 25 .0 5 0 . 0
130 Advanced Cleaning Product Formulations
S y n t h e t i c F o r m u l a t i o n
I n q r e d i e n t s : Monalube 210 Monalube 225 TEA Water
P rocedure : Combine i n g r e d i e n t s w i t h a g i t a t i o n .
T y p i c a l P r o p e r t i es :
Per formance Data (5% i n Wate r ) : Appearance: C1 e a r L i q u i d pH: 8 . 5 S u r f a c e Tens ion (dynes/cm): 42 Cast I r o n B l o c k C o r r o s i o n T e s t : Pass F a l e x ( D i r e c t S c a l e ) : 2500 Lbs . /46 I n
F o r mach in ing , f o r m i n g , and s tamp ing a l l Forrnul a t i on F-807
Appearance: C l e a r Amber L i q u i d
S y n t h e t i c F o r m u l a t
I n q r e d i e n t s : Monalube 225 Monalube 310 T r i e t h a n o l ami ne (99%) Water
P rocedure :
M i x u n t i l c l e a r , t h e n add w a t e r .
T y p i c a l P r o p e r t i es :
Per formance Data (5% i n Wate r ) : Appearance: C l e a r L i q u i d pH: 8 . 6 S u r f a c e Tens ion : 41 Cast I r o n B l o c k C o r r o s i o n T e s t : Pass F a l e x ( D i r e c t S c a l e ) : 2750 Lbs./55 I n .
M ix Monalube 225 w i t h t r i e t h a n o l a m i n e
Appearance: C l e a r C o n c e n t r a t e
10.0 10.0 40 ~ 0 4 0 . 0
-Lbs.
m e t a l s
15.0 2 5 . 0 30.0 30.0
and add Monalube 315.
-Lbs
Fo r heavy d u t y s tamp ing o f f e r r o u s m e t a l s a t 10 t o 20% i n w a t e r . F o r m u l a t i o n F-808
SOURCE: Mona I n d u s t r i e s , I n c . : Suggested F o r m u l a t i o n s
I n g r e d i en t s : Monalube 205 Monalube 210 Monalube 220 T r i e t h a n o l a m i n e (99%) Water
Metal Cleaners and Polishes 131
S v n t h e t i c F o r m u l a t i o n
5 . 0 10.0 10.0 50.0 2 5 . 0
Procedure : M i x i t e m s 1, 2, 3 , and 4 . Then add w a t e r .
T y p i c a l P r o p e r t i e s : Appearance: C l e a r L i q u i d
Per formance Data (5% i n W a t e r ) : Appearance: C l e a r L i q u i d p H : 9 . 0 S u r f a c e Tens ion : 32 Cast I r o n B l o c k C o r r o s i o n T e s t : Pass F a l e x ( D i r e c t S c a l e ) : 2750 Lbs . /57 I n . - L b s
Fo r s tamping, d r a w i n g and b r o a c i n g 10 t o 20% i n w a t e r . Formul a t i on F-809
S y n t h e t i c F o r m u l a t i o n
I n q r e d i e n t s : Monalube 205 Monalube 225 T r i e t h a n o l a m i n e (99%) Water
P rocedure : M ix i t e m s 1 , 2, 3, and 4 , t h e n add w a t e r and m i x .
T y p i c a l P r o p e r t i e s :
Per formance Data (5% i n W a t e r ) : Appearance: C l e a r L i q u i d pH: 8 . 7 S u r f a c e Tens ion : 35 Cast I r o n B l o c k C o r r o s i o n T e s t : Pass F a l e x ( D i r e c t S c a l e ) : 2250 L b s . / 5 1 I n . - L b s .
Appearance: C1 e a r Amber L i q u i d
A p p l i c a t i o n :
and s tamp ing . F o r m u l a t i o n F-810
SOURCE: Mona I n d u s t r i e s , I n c . : Suggested Formu
F o r f e r r o u s and n o n f e r r o u s systems f o r mach
wtsl, 5 . 0
10 .0 30 .0 5 5 . 0
n i ng, f o r m i n g ,
a t i ons
132 Advanced Cleaning Product Formulations
S y n t h e t i c F o r m u l a t i o n
I n q r e d i e n t s : Monalube 215 Monalube 220 T r i e t h a n o l a m i n e (99%) Water
P rocedure : Combine i n g r e d i e n t s w i t h a g i t a t i o n .
T y p i c a l P r o p e r t i e s :
Per formance Data (5% i n Wate r ) : Appearance: C l e a r L i q u i d pH: 9 . 0 S u r f a c e Tens ion : 42 Cast I r o n B l o c k C o r r o s i o n T e s t : Pass Fa1 ex ( D i r e c t S c a l e ) : 2500 Lbs. /47 I n . -Lbs
Appearance: C l e a r Amber L i q u i d
Wt% 9 . 0 9 . 0
36 .0 4 6 . 0
Use i n mach in ing and s tamp ing f o r b o t h f e r r o u s and n o n f e r r o u s m e t a l l u r g y . F o r m u l a t i o n F-811
S y n t h e t i c F o r m u l a t i o n
I n q r e d i e n t s : Monalube 205 Monalube 220 T r i e t h a n o l a m i n e (99%) Water
P rocedure : Combine i n g r e d i e n t s w i t h a g i t a t i o n .
Typ i c a l P r o p e r t i es : Appearance: C1 e a r Amber L i q u i d
Per formance Data (5% i n W a t e r ) : Appearance: C l e a r L i q u i d pH: 0.7 S u r f a c e Tens ion : 35 Cast I r o n B l o c k C o r r o s i o n T e s t : Pass F a l e x ( D i r e c t S c a l e ) : 2500 Lbs . /35 I n . - L b s .
Fo r mach in ing , f o r m i n g , and s tamp ing f o r a1 1 me ta l 1 u r g y F o r m u l a t i o n F-812
SOURCE: Mona I n d u s t r i e s , I n c . : Suggested F o r m u l a t i o n s
5 . 0 1 0 . 0 3 0 . 0 5 5 . 0
Metal Cleaners and Polishes 133
Uni ve rsa1 S c o u r i na Pas te
I n q r e d i e n t s : WtO/o A : T y l o s e CBR 10000 5 .00
5: Water (50C) 51 .80
C : Hos tapur SAS 60 Genapol ZRO 1 i q u i d Genapol U D - 0 3 0 Komperlan KD NaCl
21.80 10.70
2 . 0 0 0 .70 0.00
0: P r e s e r v a t i v e , Perfume q . s .
Manufacku r i ng: I. A, wh ich i s added by c o n t i n u i n g s t i r r i n g , s h o u l d s w e l l ,
u n t i l a homogeneous g e l f r e e o f lumps has been o b t a i n e d I I . Add one a f t e r a n o t h e r , t h e components o f C t o I. 1 1 1 . F i n a l l y D i s added.
T e s t s : V i s c o s i t y (B rook
SOURCE: Hoeckst A k t
i e l d RVT, sp. 6, 10 min -1, 25C): 49b00 mPas
e n g e s e l l s c h a f t : Suggested F o r m u l a t i o n
A1 u m i n u m C 1 eaner
Comoosi t i on: Ke lzan xan than gum B u t y l C e l l o s o l v e T e r g i t o l NP Phosphor i c A c i d (85%) C i t r i c A c i d Sodi um D ich romate Water
Wt% 1 .o 4 . 0 3 . 0 3 . 0 4 . 0
t r a c e 85 .0
Procedure: D i s s o l v e Ke lzan xanthan gum i n w a t e r . Add t h e c i t r i c and
p h o s p h o r i c a c i d s f o l l o w e d by 5 u t y l C e l l o s o l v e and T e r g i t o l NP. To use, sp read e v e n l y on t h e s u r f a c e t o be c l e a n e d and a l l o w s u f f i c i e n t t i m e f o r t h e c l e a n i n g a c t i o n t o be accompl ished.
SOURCE: Monsanto Performance M a t e r i a l s : Ke lzan Suggested F o r m u l a t i o n
134 Advanced Cleaning Product Formulations
Water Sol u b l e Stampi ng F1 u i d
I n g r e d i e n t s : \nit% Mas l i p 501 Base 3 0 . 0 Mazon R I 8 B 1 2 . 0 D i ethanol ami ne 8 .8 Propyl ene G1 yco l 1 . 2 Tr iethanolamine, 85% 1 0 . 0 Water Balance Procedure:
Add i n g r e d i e n t s as l i s t e d . I f more l u b r i c i t y i s requ i red , add Macol 5100. I f more co r ros ion i n h i b i t o r i s requ i red , add more Mazon R I 8 8. Use 1O:l d i l u t i o n r a t e f o r heavy du ty a p p l i c a t i o n .
WD-40 Type Lubr i can t Concentrate
I nq red i en t s : S-Maz 80 Mazawet 77 H i t e c E-515 ( E t h y l ) Pa lmet ic Ac id S h e l l f l e x 213 She l l Sol 135 Procedure: Add i n g r e d i e n t s as l i s t e d .
I n a r e d i en ts : S-Maz 80 Mazon R I 6 Masi l SF-10 Nekal WT-27 Gafac RE-40 Indopol H-100 Odor1 ess M i nera Procedure:
Pene t ra t i ng O i l
S p i r i t s
W 3 . 7 1 . Q 5 . 2 0 . 7
1 0 . 5 70 .9
Wt% 2- 6 7-1 2 0- 1 0- 1 0- 1 0 - 6
11 ance
Add i n g r e d i e n t s as l i s t e d . NOTE: A p o r t i o n o f t h e mineral s p i r i t s may be de le ted and s u b s t i t u t e d w i t h a naphthenic o i l (5-1 5%).
Burn i sh ins Compound
I n g r e d i e n t s : Mazamide 65 Mafo 1 3 MOD 1 Mazon R I 4 A T r i sodi um Phosphate EDTA Water Procedure: Add i n g r e d i e n t s as l i s t e d .
SOURCE: PPG I n d u s t r i e s , I n c . : Suggested Formulat ions
Wt% 1 0 . 0
7 . 0 5 . 0 7 . 0 1 . o
7 0 . 0
10. Oven, Grill and Hot Plate Cleaners
136 Advanced Cleaning Product Formulations
C a u s t i c Oven C l e a n e r
I n a r e d i e n t s : A: Van Gel C, 4 .8% Aqueous D i s p e r s i o n
Dei o n i zed Water
Wt%* 62.50 45.75
B: Sodium Hydrox ide , 50% S o l u t i o n 5.00
C : B u t y l C a r b i t o l Aminomethyl Propanol (AMP-95) Sodium Cocoamphoacetate ( M o n a t e r i c CM-36s)
'10.00 1 . 5 0 0 .25
D . Sodium Hydrox ide , 50% S o l u t i o n 5 . 0 0
Procedure: 1 . Make t h e 4.8% Van Gel C d i s p e r s i o n by s l o w l y add ing 4 . 8 p a r t s
by w e i g h t o f Van Gel C i n t o 95 .2 p a r t s by w e i g h t o f w a t e r o f a t room t e m p e r a t u r e , w h i l e m i x i n g w i t h a homogenizer a t 5000 rpm. C o n t i n u e m i x i n g f o r 60 m inu tes . Add t h e r e m a i n i n g P a r t A w a t e r t o t h e i n d i c a t e d amount o f d i s p e r s i o n and m ix u n t i l u n i f o r m .
t o a c h i e v e good m i x i n g o f e n t i r e b a t c h .
u n t i l u n i f o r m . A v o i d ent rapment o f a i r and g e n e r a t i o n o f foam.
2 . S l o w l y add P a r t B and a d j u s t homogenizer speed as r e q u i r e d
3 . Add t h e P a r t C i n g r e d i e n t s i n t h e o r d e r l i s t e d , m i x i n g each
4. S l o w l y add P a r t D and m ix u n t i l u n i f o r m . F o r m u l a t i o n No. 461
Non-Caust ic Oven C leaner
I n q r e d i e n t s : A : Water
Van Gel C, Magnesium Aluminum S i l i c a t e Rhodopol 50MD, Xanthan Gum
Wt%* 55 .00
0 . 7 5 0 . 2 5
6 : D i e t h a n o l ami ne 5 . 0 0 T r i e t h a n o l a m i n e 5 . 0 0 T r i p r o p y l enegl y c o l Me thy l E t h e r (Dowanol TPM) 5 .00 Po tass ium Carbonate, 25% Aqueous S o l u t i o n 28 .00 Vanseal NACS-30, Sodium L a u r o y l S a r c o s i n a t e 1 . o o
P rocedure : 1 . D ry b l e n d t h e Van Gel C and Rhodopol 50MD and add t h e m i x t u r e
t o t h e w a t e r w h i l e s t i r r i n g w i t h a homogenizer o p e r a t i n g a t 5000 r p m . C o n t i n u e m i x i n g f o r 30 m i n u t e s .
each f o r 5 m i n u t e s . Package.
*As r e c e i v e d b a s i s
2 . S l o w l y add t h e r e m a i n i n g i n g r e d i e n t s i n t h e o r d e r shown. M i x
F o r m u l a t i o n No. 468
SOURCE: R.T. V a n d e r b i l t Co., I n c . : Suggested F o r m u l a t i o n s
Oven, Grill and Hot Plate Cleaners 137
H i g h Caust ic Oven Cleaner
Carbopol r e s i n s a r e used t o t h i c k e n t h i s h i g h c a u s t i c form- u l a t i o n . I n a d d i t i o n , t h e use o f t h e r e s i n p rov ides v e r t i c a l c l i n g t o inc rease t h e con tac t t ime o f t h e de tergent on t h e s o i l e d su r face and enhance consumer convenience.
I n a r e d i e n t : D I Water Carbopol 674 ( 1 ) Potassium hydrox ide (45%) Propylene g l y c o l methyl e the r ( 2 ) C8-16 a l k y l po l yg l ycos ide (50%) (3 )
Wei Qht Percent 71.03 69.78 0.75 2.00
22.22 22.22 3 .00 3 .00 3.00 3.00
Brookf i e l d v i s c o s i t y (RVT-20 rpm) : 250 5,000 CPS CPS
Product p H : 13-14 13-14 Product c l a r i t y : C lear C lear
( 1 ) 8FGoodrich ( 2 ) Dow Chemical : Dowanol PM ( 3 ) Henkel Corp.: Glucopon 425CS
Procedure: 1 . Using moderate a g i t a t i o n (800 rpm) prov ided by a L i g h t n i n '
M ixer or s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e f o r general m ix ing and b lend ing opera t ions , d i spe rse o r screen t h e Carbopol r e s i n i n t o t h e DI water . Mix t h e s l u r r y f o r approx imate ly 15 minutes o r u n t i l t h e s l u r r y i s homogen- eous.
2 . Add t h e potassium hydrox ide w i t h cont inuous m ix ing . 3 . Add t h e g l y c o l e t h e r . 4 . Add t h e APG s u r f a c t a n t . Mix u n t i l homogeneous. 5. Add f ragrance, as des i red .
To ta l Ac t i ves : Potassium hydrox ide : 10.00 Propylene g l y c o l methyl e t h e r : 3.00 C8-16 a l k y l po l yg l ycos ide : 1.50
FGoodrich S p e c i a l t y Chemicals: OET-360
138 Advanced Cleaning Product Formulations
Oven C leaner
I n g r e d i e n t s : A : Veegum T, Magnesium Aluminum S i l i c a t e
Rhodopol 23, Xanthan Gum D e i o n i z e d Water
B : Sodium Hydrox ide , 50% Deceth-4 Phosphate (Rhodafac RA-600)
VVt%* 0 . 4 0 1 . 2 0
80 .40
8 . 0 0 1 0 . 0 0
Procedure: 1 . Weigh t h e w a t e r , h e a t i t t o 85-9OC and m ix w i t h an homogenizer
2 . D ry b l e n d t h e Veegum T and Rhodopol 23 and s l o w l y add them t o
3 . Move t h e b a t c h t o a p r o p e l l e r m i x e r and a d j u s t t h e speed t o
4 . Add t h e P a r t B i n g r e d i e n t s i n t h e o r d e r shown, m i x i n g f o r 5
a t 5000 rpm.
t h e w a t e r . C o n t i n u e m i x i n g f o r 20 m i n u t e s .
p roduce a s m a l l v o r t e x . Cool t o 55C.
m i n u t e s a f t e r each a d d i t i o n . NOTE: I t i s p a r t i c u l a r l y i m p o r t a n t t h a t t h e Sodium H y d r o x i d e s o l u t i o n be added v e r y s l o w l y w i t h good m i x i n g o f t h e e n t i r e b a t c h .
F o r m u l a t i o n f r o m Rhone-Poulenc S u r f a c t a n t s & S p e c i a l t i e s
A e r o s o l Oven C1 eaner
I n g r e d i e n t s : A : Veegum T, Magnesium Aluminum S i l i c a t e
Dei o n i zed Water
W t . %* 1 .50
74.25
8 : n-Methy l P y r r o l i d o n e (M-Py ro l ) 20.00
Nonoxynol ( I g e p a l CO-630) 1 . o o D isod ium Cocoamphodipropionate ( M i r a n o l C2M-SF Conc.) 3.25
P rocedure : 1 . Weigh w a t e r and p l a c e on homogenizer . 2 . D i s p e r s e t h e Veegum T i n t h e w a t e r u s i n g a homogenizer a t
5000 r p m . Con t inue m i x i n g for 20 m inu tes , w h i l e h e a t i n g t o 70C.
3 . Combine t h e i n g r e d i e n t s o f P a r t 8, h e a t t o 70C. 4 . Move t h e b a t c h t o a p r o p e l l e r m i x e r and a d j u s t t h e speed
5 . Add P a r t B t o P a r t A and c o o l w h i l e m i x i n g t o 30C. 6 . Package i n a e r o s o l can u s i n g Propane/Butane p r o p e l l a n t . F o r m u l a t i o n f r o m I n t e r n a t i o n a l S p e c i a l t y P r o d u c t s .
t o p r o v i d e a s l i g h t v o r t e x .
*As r e c e i v e d b a s i s
SOURCE: R.T. V a n d e r b i l t Co . , I n c . : Suggested F o r m u l a t i o n s
Oven, Grill and Hot Plate Cleaners 139
Oven C leaner
Compos i t i on : K e l z a n xan than gum T r i sod i um Phosphate Sodi urn me tas i 1 i c a t e Sul f o n a t e OA5 B r i j 96 S i 1 i cone 200 F l u i d 3 5 0 c s Hexane Water
0 . 1 3 . 2 1 . l 2 . 1 3 . 2 4 . 0 4 . 2
8 2 . 1
Procedure : P repare wa te r s o l u t i o n o f Ke lzan xan than gum as b e f o r e and
add n e x t t h r e e i n g r e d i e n t s . M ix t h e B r i j 96, S i l i c o n e and hexane s e p a r a t e l y . Then add w a t e r s o l u t i o n t o t h e s i l i c o n e / h e x a n e m ix w i t h c o n s t a n t a g i t a t i o n . Fo r a e r o s o l use cha rge w i t h 90% conc- e n t r a t e and 10% Genetron 1 2 .
Heavy D u t y Oven C leaner
Compos i t i on : Ke lzan xan than g u m A n t a r o n FC-34 Sodi um h y d r o x i d e Water
Wt% 0.3 2 . 0
1 0 . 0 8 7 . 0
Procedure :
S e p a r a t e l y , p r e p a r e t h e 40% sodium h y d o x i d e s o l u t i o n and s l o w l y add t o m i x . Fo r a e r o s o l use cha rge w i t h 80% m i x t u r e and 20% o f 1 : l mix o f Genetron 1 2 and 114.
SOURCE: Monsanto Per formance M a t e r i a l s : T e c h n i c a l B u l l e t i n 1-20:
P repare w a t e r s o l u t i o n o f Kelzan xanthan gum t h e n add A n t a r o n .
K e l zan Formul a t i ons
140 Advanced Cleaning Product Formulatioris
Oven C1 eaner w/Amphoter ic
I n g r e d i e n t s : Water, D.I . Sodi urn C i t r a t e Sodi um Metas i 1 i c a t e Sodium Hydrox ide , 40% Monoethanol ami ne Dowanol PM R e w o t e r i c AM HC W i t c o 1298SA DeSonic 9 N
B l e n d i n g P rocedure :
each add i t i on.
T y p i c a l P r o p e r t i e s :
Add i n g r e d i e n t s i n o r d e r shown and d i s s o l v e c o m p l e t e l y
V i s c o s i t y , cps: 96 pH: 1 3 . 9
Formula 1114
- Oven C leaner w/Phosphate
I n g r e d i e n t s : Phase I : Water , D . I . Carbopol 940 Phase 11: Water, D.I. Potass ium Hydrox ide , 87% T e t r a p o t a s s i u m Pyrophosphate Phase 111: Rewote r i c AM HC
\Mt96 71 . 6
2 . 1 4 . 2 6.5 4 . 2 3 . 1 3 . 1 3 . 1 2 . 1
between
71 . 4 1 . 3
1 5 . 4 2 .4 3 . 6
5 . 9
B l e n d i n g P rocedure :
Combine Phase I1 i n g r e d i e n t s i n s e p a r a t e vesse l and m ix t h o r - o u g h l y . W h i l e m i x i n g , pou r Phase I1 i n t o Phase I . M i x t h o r o u g h l y t h e n add Phase 11. Formula 1115
SOURCE: W i t c o C o r p . : Suggested F o r m u l a t i o n s
Combine Phase I i n g r e d i e n t s and m ix u n t i l homogeneous.
dishes, Coatings and Finishes
141
142 Advanced Cleaning Product Formulations
F u r n i t u r e Pol i sh
I n a d d i t i o n t o th i cken ing , Carbopol r e s i n s impar t y i e l d va lue a l l o w i n g p a r t i c l e s , such as abras ives , t o become permanently suspended. The r e s i n a1 so prevents "creaming" o r phase separ- a t i o n by suspending and separa t ing t h e o i l d r o p l e t s .
I n q r e d i e n t : Pa r t A: D I Water Carbopol EZ-2 ( 1 ) TEA
Par t B: Cardis 36 Wax (2 ) Hoechst Wax S ( 3 ) O l e i c Ac id Morphol i ne D I Water
Pa r t C : SM2133 S i l i c o n e Emulsion ( 4 ) SM2135 S i l i c o n e Emulsion ( 4 )
Phys ica l P roper t i es : B r o o k f i e l d V i s c o s i t y (RVT-20 rpm): 9,500 cps Product pH: 7 .00 Product C l a r i t y : P o l i s h
Raw M a t e r i a l Supp l i e rs : ( 1 ) BF Goodrich (2 ) P e t r o l i t e S p e c i a l t y Polymers ( 3 ) Hoechst Celanese ( 4 ) General E l e c t r i c
wp9b
91.10 0 . 2 0 0 .20
0.25 0.25 0 . 0 8 0.10 1 .82
4 . 0 0 2 . 0 0
Procedure: 1. Disperse t h e Carbopol i n t o t h e water by s imp ly "dumping" i t
2. Add t h e TEA. Mix u n t i l homogeneous. 3. Prepare P a r t B. Add t h e Card is Wax, Hoechst Wax S, and o l e i c
a c i d t o a vesse l . Wi th m i l d s t i r r i n g , b r i n g t h e temperature up t o 96-IOOC. When melted, add t h e morphol ine u n t i l t h e m i x t u r e i s homogeneous. Add t h e water a t 95C. Continue s t i r r i n g u n t i l t h e temperature reaches 45C. Cool t o room temperature.
i n . The polymer w i l l wet ou t i n a few minutes.
4. Add Par t B. 5. Add i n t h e s i l i c o n e emulsions w i t h m i l d m ix ing .
T o t a l Ac t i ves : T o t a l Wax : 0 .50 T o t a l S i l i c o n e : 6.00
SOURCE: BFGoodrich S p e c i a l t y Chemicals: DET-530
Polishes, Coatings and Finishes 143
Lea the r /P las t i c P o l i s h
I n a d d i t i o n t o th i cken ing , Carbopol r e s i n s impar t y i e l d va lue a l l o w i n g p a r t i c l e s , such as abrasives, t o become permanently suspended. The r e s i n a1 so prevents "creami ng" o r phase separ- a t i o n by suspending and separa t i ng t h e o i l d r o p l e t s .
I n q r e d i e n t : DI Water Renex 20 ( 1 ) Morphol i ne SF96 S i l i c o n e F l u i d (350) ( 2 ) O l e i c Ac id Minera l S p i r i t s 01 Water Carbopol EZ-2 (3 )
Wt% 5 0 . 0 0
2 . 0 0 1 .oo 5.00 2.00
20.00 19.60 0 .40
Phys ica l P roper t i es : B r o o k f i e l d V i s c o s i t y (RVT-20 rpm): 3,200 cps Product pH: 8 .5 Product C l a r i t y : Opaque
Raw M a t e r i a l Supp l i e rs : ( 1 ) I C I Su r fac tan ts ( 2 ) General E l e c t r i c ( 3 ) BFGoodrich
Procedure: 1 . Disso lve t h e Renex 20 and morphol ine i n t h e water w i t h m i l d
2 . D i sso l ve t h e s i l i c o n e f l u i d and t h e o l e i c a c i d i n t h e minera l
3 . I n a separate vessel , d i spe rse 0.40 p a r t s o f Carbopol i n t o
a g i t a t i o n .
s p i r i t s . Add t o t h e above m ix tu re w i t h good a g i t a t i o n .
49.60 p a r t s o f water by s imp ly "dumping" t h e polymer i n t o t h e water . I n j u s t a few minutes, t h e polymer w i l l completely wet o u t . Add t h i s d i spe rs ion t o t h e above m ix tu re .
4 . Mix u n t i l homogeneous.
Total A c t i wes: S i l i c o n e F l u i d : 5.00 Minera l S p i r i t s : 20.00
SOURCE: BFGoodrich S p e c i a l t y Chemicals: DET-540
144 Advanced Cleaning Product Formulations
Marble Pol i sh
I n a d d i t i o n t o th i cken ing , Carbopol r e s i n s impar t y i e l d va lue a l l o w i n g p a r t i c l e s , such as abras ives , t o become permanently suspended. The r e s i n a1 so prevents "creami ng" o r phase separ- a t i o n by suspending and separa t i ng t h e o i l d r o p l e t s . I n g r e d i e n t : we% D I Water 74.80 Carbopol EZ-2 ( 1 ) 0.20 Minera l S p i r i t s 15.00 Igepa l 630 (2 ) 3.70 Diatomaceous e a r t h (3 ) 8.00 T r i ethanol ami ne 0.30 Phys ica l P roper t i es :
Brookf i e l d V i scos i t y (RVT-20 rpm) : 1 I , 700 cp Product pH: 7 .50 Product C l a r i t y : Opaque
Raw M a t e r i a l Supp l i e rs : ( 1 ) BFGoodrich (2 ) Rhone-Poul enc (3 ) Kaopo l i t e
Procedure: 1. Disperse t h e Carbopol i n t h e water by s imp ly "dumping" i t
i n . The polymer w i l l wet ou t i n a few minutes. Add t h e s u r f - ac tan t w h i l e m ix ing under moderate a g i t a t i o n .
homogeneous. 2. Add t h e minera l s p i r i t s . Mix u n t i l t h e emulsion becomes
3. Add t h e TEA. Mix u n t i l smooth. 4 . Add t h e diatomaceous ea r th . Mix u n t i l homogeneous. DET-552
Rust Removing P o l i s h
Carbopol r e s i n s a r e used i n t h i s fo rmula t o t h i c k e n t h e g luc - o n i c a c i d t o enable improved a p p l i c a t i o n e f f i c a c y . The polymer w i l l a l s o impar t v e r t i c a l c l i n g t o enable a p p l i c a t i o n s on v e r t - i c a l o r angled sur faces . I n q r e d i en t : Wt% D I Water 44.64 Carbopol €2-2 ( 1 ) 1 - 7 9 Sodium hydrox ide (50%) 35.71 Gluconic a c i d s o l u t i o n (50%) ( 2 ) 17.86 Phys ica l P roper t i es :
B r o o k f i e l d V i s c o s i t y (RVT-20 r p m ) : 3,000 cp Product pH: 13.90 Product C l a r i t y : T rans lucent
Procedure: 1. Disperse t h e Carbopol i n t o t h e water. 2. A d d t h e sodium hydrox ide w i t h a g i t a t i o n . Th icken ing will occur
3. Add t h e g lucon ic a c i d s o l u t i o n . Mix u n t i l homogeneous.
SOURCE: BFGoodrich S p e c i a l t y Chemicals: Suggested Formulations
i mmedi a t e l y . DET-560
Polishes, Coatings and Finishes 145
S c r a t c h e d Wood P o l i s h
I n g r e d i e n t s : A : Veegum T, Magnesium Aluminum S i l i c a t e
Dei o n i zed Water
B: S t e a r i c A c i d Carnauba Wax Beeswax, Ye1 1 ow
C : T r i e t h a n o l ami ne, 99% M i n e r a l Spi r i t s
Wt% 1 . 5 0
31 .25
4 .50 1 6 . 5 0 16 .50
2 .75 27 .00
D: P r e s e r v a t i v e , Dye, F rag rance q . s
Procedure : 1 . Weigh t h e w a t e r and m ix w i t h a p r o p e l l e r m i x e r a t 1800 rpm. 2 . S l o w l y add t h e Veegum T and m ix f o r 20 m i n u t e s w h i l e
3. Combine t h e P a r t B i n g r e d i e n t s and h e a t t o 9OC. 4 . Add t h e P a r t C i n g r e d i e n t s t o t h e P a r t B m i x t u r e i n t h e
5 . Add P a r t B+C t o P a r t A and m i x f o r 10 m i n u t e s . 6 . Cool t h e b a t c h t o 35C, add P a r t D, and m ix u n t i l u n i f o r m .
h e a t i n g t o 9OC.
o r d e r shown, m i x i n g each f o r 10 m i n u t e s .
*As r e c e i v e d b a s i s
SOURCE: R . T . V a n d e r b i l t Co., I n c . : F o r m u l a t i o n No. 2 1 0
H i qh Gloss, D e t e r q e n t Resi s t a n t Pol i sh
A wax - f ree p o l i s h , wh ich p r o v i d e s a h i g h - g l o s s , d e t e r g e n t r e s i s t a n t f i n i s h on non-porous s u b s t r a t e s . S imp le a p p l i c a t i o n , w i t h o u t hard r u b b i n g o r b u f f i n g , r e s u l t s i n b o t h d e p t h o f g l o s s and d e t e r g e n t r e s i s t a n c e f o r ex tended p r o t e c t i o n .
I n g r e d i e n t s : ( 1 ) GP-121 S i l i c o n e P o l i s h A d d i t i v e ( 2 ) GP-RA-159 S i l i c o n e P o l i s h A d d i t i v e ( 3 ) S toddard S o l v e n t ( 4 ) M i n e r a l S p i r i t s ( O d o r l e s s ) ( 5 ) GP-227 S i l i c o n e S u r f a c t a n t S o l u t i o n ( 6 ) K a o p o l i t e SF ( 7 ) S o f t Water ( 8 ) B a c t e r i c i d e
Wt% 9 . 0 1 . 5 3 . 5 3 . 5 9 . 0 3 . 4
70.0 0 . 1
Combine i n o r d e r shown w i t h h i g h shear m i x i n g u n t i l t h i c k e n i n g o c c u r s . M i x u n t i l homogeneous and package.
F o r m u l a t i o n P r o p e r t i e s : C o n t a i n s no wax Non-smeari ng H igh g l o s s Cost e f f i c i e n t D e t e r g e n t r e s i s t a n t Co ld b l e n d (On ly m i x i n g r e q u i r e d ) Easi 1 y app l i ed R e s i s t a n t t o wash-o f f
SQURCE: Genesee Polymers C o r p . : Formula 20-12
12. Rinse Aids
146
Rinse Aids 147
R i nse A i d , A c i d
I n q r e d i e n t s : Water, D . I . P e t r o 22 Powder DeSoni c LFD-97 H y d r o x y a c e t i c A c i d , 70%
B l e n d i n g P rocedure : 51 end i n g r e d i e n t s i n t h e o r d e r 1 i s t e d .
T y p i c a l P r o p e r t i e s : S p e c i f i c G r a v i t y : 1 .105 Wt/Gal, l b s : 9 . 2 1 V i s c o s i t y , cps: 85 Cloud P o i n t , C : 59 S o l i d s , %: 40
Formula 131
R i nse A i d
I n g r e d i e n t s : Water , D . I . P e t r o 22 Powder DeSoni c LFD-97
T y p i c a l P r o p e r t i e s : S p e c i f i c G r a v i t y : 1 .029 Wt/Gal. l b s : 8 .58 pH, as i s : 6 . 4 V i s c o s i t y , cps : 80 Cloud P o i n t , C : 68 S o l i d s : 40%
Formula 130
SOURCE; W i t c o Corp. : Suggested Formul a t i ons
Wt9/o 5 0 . 0
5.0 3 5 . 0 1 0 . 0
Wt% 60 .0
5 .0 3 5 . 0
13. Rug, Floor, Carpet, Upholstery Shampoos an
148
I nq r e d i e n t s : Water T r i s o d i urn Phosphate T e t r a p o t a s s i u m Pyrophosphate P l u r a f a c D-25 A1 i p a l CO-436 Mazawet 77 EDTA ( T e t r a s o d i u m S a l t ) T i n o p a l 5 BM
Procedure : Add i n g r e d i e n t s as l i s t e d .
Rug, Floor, Carpet, Upholstery Shampoos and Cleaners 149
C a r p e t C1 eaner
Low Foam Carpe t Shampoo
I n g r e d i e n t s : Macol 2LF E t h y l e n e G l y c o l M e t h y l E the r Sodi urn T r i po l yphospha te Sodi urn X y l ene Su l f o n a t e Mazu DF 210 SX Water ( s o f t )
P rocedure : Add i n g r e d i e n t s as l i s t e d .
Steam Rua Cleaner-A
I n g r e d i e n t s : Macol OP 10 SP Sodium S i l i c a t e Sodi urn X y l ene Su l f o n a t e Water
P rocedure : Add i n g r e d i e n t s as l i s t e d .
S t e a m Rug Cleaner -8
I n q r e d i e n t s : Macol OP 10 SP Sodi um S i 1 i c a t e Sodium Xy lene S u l f o n a t e Water
Procedure: Add i n g r e d i e n t s as l i s t e d
SOURCE: PPG I n d u s t r i e s , I n c . : Suggested F o r m u l a t i o n s
wt% 56.0 15 .0 10 .0
7 . 0 10 .0
1.25 0 . 5 0 .25
Wt% 6.0
10 .0 1 . o 1 . o 0 .5
81 .5
wa 5.0
10 .0 5 . 0
8 0 . 0
Wt% 3 .0
1 0 . 0 3 .0
8 4 . 0
150 Advanced Cleaning Product Formulations
C a r p e t C l e a n e r s f o r t h e S p r a y - E x t r a c t i o n P rocess
I n q r e d i e n t s : Cublen 0 50 T e t r a p o t a s s i u m py rophospha te P r o p e t a l 241 P r o p e t a l 281 S u l f e t a l 4105 I s o p r o p a n o l Water
Formula CT 02-08-01
I n g r e d i e n t s : Water Soap S u l f e t a l 4105 P r o p e t a l 99 Cont raspum 300 U b a t o l TR 1138 I s o p r o p a n o l
Formula C T 02-08-02
W S 1 . o 5 . 0 2 .0 3 . 0 4 . 0 4 . 0
81 . o
Wt% 7 5 . 0
1 . o 5 . 0 5 . 0 1 . o 3 . 0
1 0 . 0
SOURCE: Zschimmer & Schwarz GmbH & C o . : Genera l F o r m u l a t i o n s
C a r p e t Shampoo L iqu id , t r a n s p a r e n t
I n g r e d i e n t s : A : Hostapur 0s l i q u i d
Med ia lan KA conc.
B: Water , P r e s e r v a t i v e
wtu/, 25 .00
3 . 0 0
Manu f a c t u r i ng : One a f t e r a n o t h e r , t h e components o f A a r e added t o 8 .
SOURCE: Hoechst A k t i e n g e s e l l s c h a f t : Suggested F o r m u l a t i o n
72.00
Rug, Floor, Carpet, Upholstery Shampoos and Cleaners 151
C a r p e t Shampoo I Phosphate, L i quid)
S o i l - F o o d ( f a t and p r o t e i n ) , p e t r o l e u m o i l and grease, c l a y
S u r f a c e - P o l y e s t e r and n y l o n A p p l i c a t i o n Method-Rug sc rubber Manu fac tu re -M ix t a n k w i t h p r o p e l l e r s t i r r e r
and p a r t i c u l a t e
Composi t i on : Water *TSP *STPP Kasi 1 #6 P o t a s s i um S i 1 i c a t e **Phosphate E s t e r ***Sodi um A1 k y l naphtha1 ene Su l f o n a t e ****Octy lphenoxy P o l y e t h o x y e t h a n o l , 7-8 Moles EO
Use D i l u t i o n : 0 .8 -1 .5% bw (1 -2 o z / g a l l o n )
* FMC ** Rhone-Poulenc Rhodafac RE-610 *** DeSoto **** Rhone-Poulenc I g e p a l CA-620
RUQ Steam C leaner
Soi 1 -Food ( f a t and p r o t e i n ) , p e t r o l e u m
S u r f a c e - P o l y e s t e r and n y l o n A p p l i c a t i o n Method-Rug s c r u b b e r Manu fac tu re -M ix t a n k w i t h p r o p e l l e r s t
and p a r t i c u l a t e
Composi t i on : Water Wetso Beads 2048 Sodi um X y l ene Sul f o n a t e , 40% * M i r a n o l JEM C o n c e n t r a t e (34%)
Wt% 6 2 . 5
2 .0 5 . 0
2 0 . 0 3 . 0 3 . 5 4 .0
o i l and grease, c l a y
r r e r
84 .0 5 . 0 6 .0 5 . 0
Use D i l u t i o n : 4 .7-9.4% b w (6-12 o z / g a l l o n )
*Rhone-Poul enc; o r She1 1 Chemical Neodol 25-1 2
SOURCE: PQ C o r p . : D e t e r g e n t F o r m u l a t i o n Guide
152 Advanced Cleaning Product Formulations
C a r p e t Shampoo, H i s h Foam
I n Q r e d i e n t s : Water P e t r o BAF L i q u i d W i t c o l a t e WAC-LA
WtS/o 78.3
5 . 0 16.7
B1 end i ng P rocedure : B1 end i n g r e d i e n t s i n t h e o r d e r 1 i s t e d .
P e t r o BAF, i n c o m b i n a t i o n w i t h sodium l a u r y l s u l f a t e , reduces t h e l o w t e m p e r a t u r e c l o u d p o i n t , g i v i n g e x c e l l e n t f r e e z e / t h a w p r o p e r t i e s . The P e t r o BAF c o m b i n a t i o n d r i e s l e s s t a c k y t h a n sodium l a u r y l s u l f a t e a l o n e .
Formula 908
Carpe t Shampoo, H i g h Foam
I n q r e d i e n t s : Water P e t r o BAF L i q u i d W i t c o l a t e WAC-LA
B l e n d i n g P rocedure : B 2nd i n g r e d i e n t s i n t h e o r d e r
Use L e v e l : 1 t o 2 ounces p e r g a l l o n .
i s
Wt% 7 1 . 1
6 . 7 2 2 . 2
I
Comments : P e t r o BAF, i n c o m b i n a t i o n w i t h sodium l a u r y l s u l f a t e , reduces
t h e low t e m p e r a t u r e c l o u d p o i n t , g i v i n g e x c e l l e n t f r e e z e / t h a w p r o p e r t i e s . The P e t r o BAF c o m b i n a t i o n d r i e s l e s s t a c k y t h a n sodium l a u r y l s u l f a t e a l o n e .
Formula 910
Carpe t Spo t Remover
I n q r e d i e n t s : Water, 13.1. W i t c o l a t e WAC-LA P e t r o BA L i q u i d G l y c o l E t h e r DPM G l y c o l E t h e r PM FC-129 (1% S o l i d s )
B l e n d i n g Procedure: B l e n d i n g r e d i e n t s i n t h e o r d e r l i s t e d .
T y p i c a l P r o p e r t i e s : S p e c i f i c G r a v i t y : 0 .999 Wt./Gal. l b s . : 8 .33 pH: 10 .35
Use D i l u t i o n : Use as i s
SOURCE: W i t c o C o r p . : Suggested F o r m u l a t i o n s Formula 945
Wt% 9 0 . 3
3.3 0 . 5 3 .5 2 . 3 0 . 1
Rug, Floor, Carpet, Upholstery Shampoos and Cleaners 153
Carpet 8 Upho ls te ry Cleaner Th is oeneral Duroose s t a i n remover f o r m u l a t i o n i s o a r t i c u l a r l v
e f f e c t i v e i n removing o i l s t a i n s . I n g r e d i e n t : Wt% Deionized Water ( h o t ) 37.0 SMA-2625 Resin 2.4 Aqua Ammonia 0.7 W i t c o l a t e WACLA 18.0 Witconate 60T L i q u i d 4 . 0 Avanel 5-70 4 . 0 Dei on i zed Water 34 .0 Dye, Fragrance, e t c . (2.5.
pH (as i s ) : 8.0-9.0 Appearance: C lear l i q u i d S p e c i f i c G r a v i t y : 1.016
Procedure: 1. Charge t h e ho t water t o a m ix ing vessel and s t a r t a g i t a t i o n .
S lowly s i f t i n t h e SMA-2625 Resin t o avo id c lumping. Add t h e Aqua Ammonia, app ly coo l i ng , and mix w e l l u n t i l t h e r e s i n i s d i sso l ved .
2 . Reduce a g i t a t i o n and add t h e remaining i n g r e d i e n t s . Stop a g i t a t i o n t o pe rm i t deaera t i on o f t h e produc t p r i o r t o f i l l i n g o f f .
3 . If t h i s p roduc t i s t o be co lo red , a p o r t i o n o f t h e f i n a l water should be reserved f o r d i s s o l v i n g t h e dye. A f t e r t h e dye is thorough ly mixed, t h e dye s o l u t i o n may be added NOTE: Use "as i s " on ca rpe t ing . D i l u t e 1O: l and 5 : l w i t h water f o r upho ls te ry .
V i n y l Dress ing ( 8 ) I n g r e d i e n t : Wt% Par t A : Mas i l EM 250 C 18 .0 Mas i l EM 10,000 C 10 .0 Dei on i zed Water 30.0 Par t B: Macol OP-10 SP 2.0 G1 y c e r i ne 1 . o Deioni r e d Water 38 .0 Sodium Benzoate 1 . o Procedure: 1. To a m ix ing vesse l , charge t h e Mas i l EM 250 C and Mas i l
EM 10,000 C. S t a r t g e n t l e a g i t a t i o n . Slowly add t h e water so as no t t o break t h e emulsion.
g l y c e r i n e t o t h e water. Mix w i t h g e n t l e a g i t a t i o n u n t i l a l l components a re d isso lved, and t h e s o l u t i o n i s f r e e o f " f i s h eyes". Charge t h e sodium benzoate and mix u n t i l d i sso l ved .
3. Under g e n t l e a g i t a t i o n , add Par t 0 t o Par t A. Cont inue m ix ing g e n t l y t o avo id a i r entrapment. NOTE: Th i s formula i s designed to be used "as i s " . I f des i red , UV absorbers and o the r compon- en ts may be added t o t h e fo rmu la t i on .
2. I n a separate m ix ing vesse l , charge t h e Macol OP-10 SP and
SOURCE: PPG I n d u s t r i e s , I n c . : Suggested Formula t ions
154 Advanced Cleaning Product Formulations
Carpe t & U p h o l s t e r y C l e a n e r
I n g r e d i e n t s : Dei o n i zed Water ( H o t ) SMA-2625 Res in Aqua Ammonia Sodi um L a u r y l S u l f a t e R i chami de 5725 Avanel 5-70 Dei o n i zed Water Dye, Fragrance, E t c .
p H ( a s i s ) : 8 . 0 - 9 . 0 Appearance: C l e a r l i q u i d S p e c i f i c G r a v i t y : 1 .016
Wt% 37.0
2 . 3 7 0 . 6 7
1 8 . 0 4 . 0 4 . 0
33 .96 As d e s i r e d
Procedure:
S l o w l y s i f t i n t h e SMA-2625 r e s i n t o a v o i d c l u m p i n g . Add t h e Aqua Ammonia, a p p l y c o o l i n g and mix w e l l u n t i l t h e r e s i n i s d i s s o l v e d . Reduce a g i t a t i o n and add t h e r e m a i n i n g i n g r e d i e n t s . I f t h e p r o d u c t i s t o be c o l o r e d , a p o r t i o n o f t h e f i n a l w a t e r s h o u l d be r e s e r v e d f o r d i s s o l v i n g t h e dye. A f t e r t h e dye i s t h o r o u g h l y mixed, t h e dye s o l u t i o n may be added t o t h e p r o d u c t . S top a g i t a t i o n t o p e r m i t d e a e r a t i o n o f t h e p r o d u c t p r i o r t o f i l l i n g o f f .
Notes :
i s p a r t i c u l a r l y e f f e c t i v e a t removing o i l s t a i n s . Use a s - i s on c a r p e t i n g . D i l u t e 1O: l and 5 : l w i t h w a t e r f o r u p h o l s t e r y . N o t e : The dye s h o u l d b e t h o r o u g l y screened t o a v o i d f a b r i c s t a i n i n g .
Charge t h e h o t w a t e r t o t h e m i x i n g v e s s e l and s t a r t a g i t a t i o n .
T h i s i s a g e n e r a l pu rpose o i l y s t a i n remover. T h i s f o r m u l a t i o n
F o r m u l a t i o n CP-101
L i q u i d Steam Carpe t C1 eaner F o r Hard Water Systems
I n g r e d i e n t s : Sodium Metas i 1 i c a t e A T e t r a p o t a s s i u m Pyrophosphate Emphos PS-331 Macol NP 11 D e i o n i z e d Water
P rocedure : Add i n g r e d i e n t s as l i s t e d .
SOURCE: PPG I n d u s t r i e s , I n c . : Suggested F o r m u l a t i o n s
Wt% 7 . 5
12.5 4 . 0 1 . o
7 6 . 0
Rug, Floor, Carpet, Upholstery Shampoos and Cleaners 155
F1 oor C leaner
I n g r e d i e n t s : M a z a m i de 1281 Sodi urn T r i p o l y p h o s p h a t e Tet rapotass ium Pyrophosphate Water
Procedure: Add i n g r e d i e n t s as l i s t e d .
L i q u i d F l o o r C leaner
I n g r e d i e n t s : Macol NP 9 . 5 Sodi urn T r i p o l yphosphate T r i sod i urn Phosphate Sodi urn Metas i 1 i c a t e Pentahydra te Maphos 60A Water
Procedure: A d d i n g r e d i e n t s as l i s t e d . NOTE: T h i s f o r m u l a t i o n i s s t a b l e t o 120F.
F l o o r Scrubber
I n g r e d i e n t s : Sodi urn Metas i 1 i c a t e Tet rasod ium Pyrophosphate Emphos PS-331 De ion ized Water Mazami de 1281 Sodium Hydrox ide , 50%
Procedure :
SOURCE: PPG I n d u s t r i e s , I n c . : Suggested F o r m u l a t i o n s
Add i n g r e d i e n t s as l i s t e d .
wtsl, 8.0 2.0 2 .0
8 8 . 0
Q 7 . 0 8 . 0 2 . 0 2 . 0 3 . 0
78 .0
2 . 0 18.0 1 5 . 0 53.95
6 . 0 5 .05
156 Advanced Cleaning Product Formulations
Household C a r p e t F r e s h e n e r / A n t i s t a t
I n Q r e d i e n t s : P a r t A : P u f f e d Borax (10 l b s / c u f t ) F rag rance Sodi um B i c a r b o n a t e L a r o s t a t 519
P a r t 6: Sodi um B i c a r b o n a t e
Wt%
1 . 8 0 . 2
1 5 . 0 3 . 0
8 0 . 0
P rocedure :
f i r s t p o r t i o n o f sodium b i c a r b o n a t e . S t a r t m i x i n g and s l o w l y add t h e f r a g r a n c e . A f t e r a l l o f t h e f r a g r a n c e has been added, c o n t i n u e m i x i n g f o r 5 m inu tes t o comp le te a b s o r p t i o n . Add t h e L a r o s t a t 519 and t h e r e m a i n i n g sodium b i c a r b o n a t e . M i x f o r 15 m i n u t e s more.
Notes : T h i s i s a powdered c o m b i n a t i o n consumer f r e s h e n e r / a n t i s t a t .
The p r o d u c t i s des igned t o be shaken o n t o t h e c a r p e t , l i g h t l y rubbed i n t o t h e c a r p e t and t h e n t h e excess removed by vacuuming.
I n a r i b b o n m i x e r o r V-b lender , cha rge t h e p u f f e d bo rax and
F o r m u l a t i o n SP-I01
Pump Spray Carpe t A n t i s t a t
I n g r e d i e n t s : P a r t A : Water I s o p r o p y l A l c o h o l L a r o s t a t 264 A
Appearance: C l e a r , w a t e r - w h i t e t o p a l e - y e l l o w l i q u i d S p e c i f i c G r a v i t y : 0.98
94.3 5 . 0 0 . 7
P rocedure :
p y l a l c o h o l and L a r o s t a t 88. M i x u n t i l c l e a r .
Notes : T h i s i s a non -ae roso l , pump sp ray c a r p e t a n t i s t a t f o r t h e
removal o f n u i s a n c e s t a t i c . T o remove s t a t i c f r o m c a r p e t i n g and o t h e r s u r f a c e s , s p r a y l i g h t l y w i t h t h i s f o r m u l a t i o n . I t i s n o t necessa ry t o s a t u r a t e t h e s u r f a c e . I f a d d i t i o n a l p r o t e c t i o n i s needed, i t i s p r e f e r a b l e t o have r e p e a t a p p l i c a t i o n s r a t h e r t h a n one, t o i n s u r e even t r e a t m e n t .
T o a m i x i n g v e s s e l , cha rge t h e w a t e r , f o l l o w e d by t h e i s o p r o -
F o r m u l a t i o n SP-102
SOURCE: PPG I n d u s t r i e s , I n c . : Suggested F o r m u l a t i o n s
Rug, Floor, Carpet, Upholstery Shampoos and Cleaners 157
h i qlai d L e a t h e r . V i nv l , and P l a s t i c C leaner and R e s t o r e r
I n q r e d i e n t s : DeSonic 9N Dowanol PM G l y c o l E t h e r I s o p r o p y l A l c o h o l Amy1 A c e t a t e Water
Wt% 1 0 . 0
5 . 0 2 . 5 1 . o
81 . 5
B l e n d i n g I n s t r u c t i o n s : Combine i n g r e d i e n t s i n t h e o r d e r shown and mix t h o r o u g h l y .
Use I n s t r u c t i o n s : App ly f i n i s h e d p r o d u c t t o a t o w e l o r t o w e l l e t e (Kimwipe, e t c . )
and w i p e o n t o t h e s u r f a c e t o be c leaned , t h e n r i n s e . A l t e r n a t i v e - l y , sp ray o n t o t h e s u r f a c e t o be c leaned , a l l o w t o s e t a few m i n u t e s , t h e n r i n s e or hose o f f .
P roduc t I n f o r m a t i o n : P r o d u c t : B e n e f i t : DeSonic 9N D e t e r g e n t and degreaser Dowanol PM G l y c o l E t h e r S o l v e n t and c o u p l i n g agen t Amyl A c e t a t e S o l v e n t I s o p r o p y l A l c o h o l Sol v e n t
Formula 1000
L i q u i d Leather, V i n y l , and P l a s t i c C leaner
I n Q r e d i e n t s : W i t c o n o l NP-100 Dowanol PM G l y c o l E t h e r I s o p r o p y l A l c o h o l Amy1 A c e t a t e Water
Wt% 1 0 . 0
5 . 0 2 . 5 1 . o
8 1 . 5
B l e n d i n g I n s t r u c t i o n s : Combine i n g r e d i e n t s i n t h e o r d e r shown and mix t h o r o u g h l y .
Use I n s t r u c t i o n s : App ly f i n i s h e d p r o d u c t t o a t o w e l o r t o w e l l e t e (Kimwipe, e t c . )
and w ipe o n t o t h e s u r f a c e t o be c leaned , t h e n r i n s e . A l t e r n a t i v e - l y , sp ray o n t o t h e s u r f a c e t o be c leaned , a l l o w t o s e t a few m inu tes , t h e n r i n s e o r hose o f f .
P roduc t I n f o r m a t i o n : B e n e f i t : W i t c o n o l N P - 1 0 0 D e t e r g e n t and degreaser Dowanol PM G l y c o l E t h e r S o l v e n t and c o u p l i n g agen t Amyl A c e t a t e So l v e n t I s o p r o p y l A1 coho1 Sol v e n t
Formula 1001
SOURCE: W i t c o C o r p . : Suggested F o r m u l a t i o n s
158 Advanced Cleaning Product Formulations
Low Cost E x t r a c t i o n C a r p e t C leaner
I n g r e d i e n t s : Water, D . I . P e t r o 22 Powder EDTA Powder Perfume
81 end ing P rocedure : B1 end i n g r e d i e n t s i n t h e o r d e r 1 i steci.
Use D i l u t i o n : 1-2 o z / g a l of w a t e r Formula 901
91 . o 5 . 0 4 . 0 q. s .
Premium, Medium Du ty Steam E x t r a c t i o n C a r p e t C leaner
I n q r e d i e n t s : Sodi um T r i p o l y p h o s p h a t e , L i g h t D e n s i t y Sodi urn Metas i 1 i c a t e , Pen tahyd ra te P e t r o 22 Powder O p t i c a l B r i g h t e n e r
B l e n d i n g P rocedure : B l e n d i n g r e d i e n t s i n t h e o r d e r l i s t e d .
Use D i l u t i o n : 1-2 o z / g a l Formula 904
Heavy Du ty Steam E x t r a c t i o n C a r p e t C leaner
I n q r e d i e n t s : Sodium Carbonate (Soda Ash) T r i s o d i u m Phosphate, C r y s t a l Sodium M e t a s i l i c a t e , Pen tahyd ra te Sodium S u l f a t e ( S a l t Cake) P e t r o 22 Powder
B l e n d i n g Procedure: B l e n d i n g r e d i e n t s i n t h e o r d e r l i s t e d
Use D i l u t i o n : 1-2 o z / g a l Formula 905
SOURCE: W i t c o Corp . : Suggested F o r m u l a t i o n s
6 5 . 0 29.5
5 . 0 0 .5
W t % 1 0 . 0 10 .0 20 .0 56.0
4 . 0
Rug, Floor, Carpet, Upholstery Shampoos and Cleaners 159
Low Foaming C a r p e t E x t r a c t o r D e t e r g e n t
Component: Sodi um B i c a r b o n a t e STPP Burco LAF-6 Burco SZS Burcosperse AP Powder B u r c o t a s e SP-60 ( i f d e s i r e d ) F rag rance
Wt% t o 100% t o t a l
47 .0 2 . 5 0 .25 2 . 5 1 . o
as d e s i r e d
Procedure:
u n t i l absorbed. Add Burco SZS, t h e n Sodium B i c a r b o n a t e and b l e n d u n t i l u n i f o r m . Add Burcosperse A P Powder (and i f d e s i r e d ) Bu rco tase SP-60. B l e n d u n t i 1 u n i f o r m .
Use C o n c e n t r a t i o n :
Spray LAF-6 (and i f d e s i r e d ) f r a g r a n c e o n t o STPP and b l e n d
2-3 ounces p e r g a l l o n i n e x t r a c t o r .
SOURCE: B u r l i n g t o n Chemical Co. , I n c . : Suggested F o r m u l a t i o n s
RUQ Steam C l e a n e r ( L i q u i d )
S o i l - Food ( f a t and p r o t e i n ) , p e t r o l e u m o i l and grease, c l a y and p a r t i c u l a t e
S u r f a c e - P o l y e s t e r and n y l o n A p p l i c a t i o n Method - Rug sc rubber Manu fac tu re - M i x t a n k w i t h p r o p e l l e r s t i r r e r
Compos i t i on : Water Metso Beads 2048 Sodium Xy lene S u l f o n a t e , 40% C12-Cl5 L i n e a r A l c o h o l , 12 Moles EO
Use D i 1 u t i on : 4 .7-9.4% bw (6 -1 2 o z / g a l 1 o n )
SOURCE: The PQ C o r p . : Suggested F o r m u l a t i o n
Wt% 7 9 . 6
7 . 0 6 . 7 3 .9
160 Advanced Cleaning Product Formulations
No Rinse F loor Cleaner
I npred i ent s : Water, D.I. Sodi um Carbonate Rewoteric AM 8-14 Versene 100 Butyl Cel losolve
\Mt% 79.0 4.0 10.0 2.0 5 . 0
Blending Procedure:
each addi t i on. Formula 932
Add ingredients i n order shown and d isso lve completely between
Heavy D u t y F loor Cleaner
Ingredients : Water, D.I. Varami de A-1 2 T r i sodi um Phosphate Sodium Tripolyphosphate
Wt% 78.0 7.0 10.0 5.0
81 end$ ng Procedure:
each add i t i on .
Typical Propert i es : Sol ids: 22.0%
Formula 933
Add ingredients i n order shown and d isso lve completely between
No-Rinse Floor Cleaner Deareaser
Ingredients : Deionized water Sodium carbonate Rewoteric AM V Versene 100 Buty l Cel losolve
WtO/o 79.0 4.0 10.0 2.0 5.0
Blending Procedure:
each add i t i on .
Typical Proper t ies: Sol ids: 8.1% pH: 10.9 V iscos i t y : 4 cps
Formula 951
SOURCE: Witco Corp. : Suggested Formulations
Add ingredients i n order shown and d isso lve completely between
Rug, Floor, Carpet, Upholstery Shampoos and Cleaners 161
Wax S t r i p p e r ( A )
I n q r e d i e n t s : O l e i c Ac id Monoethanol ami ne Avanel S-74 Potassium Hydroxide, 45% Sodi um Hydroxide, 50% Versene 100 Dowanol TBA Water
Procedure: Add i n g r e d i e n t s as l i s t e d .
Wax S t r i p p e r (B)
I n a r e d i e n t s : O l e i c Ac id Monoethanolamine Avanel S-74 Potassium Hydroxide, 45% Sodi um Hydroxide, 50% Versene 100 Ethylene G1 yco l Monobutyl Ether Water
Procedure: Add i n g r e d i e n t s as l i s t e d .
Concentrated Wax S t r i p p e r
I n a r e d i e n t s : Sodium Hydroxide, 50% Macol NP 9 . 5 EDTA, 40% Mazox LDA Barquat MB-50 Monoethanolami ne Water
Wt% 7.0 2.0 2.0 1 . o 1 . o 1 . o 5 . 0
81 . o
7 .0 2.0 2.0 1 . o 1 . o 1 . o
81 . o 5.0
WtO/o 6 . 5 1 . o 0.5 1 . o 1 . o 8.5 81 .5
Procedure:
Mac01 NP 10 .5 can be s u b s t i t u t e d f o r t h e Macol NP 9 . 5 . Mafo CB-40 can be s u b s t i t u t e d f o r t h e Mazox LDA.
SOURCE: PPG I n d u s t r i e s , I n c . : Suggested Formulat ions
Add i n g r e d i e n t s as l i s t e d . To use, d i l u t e 1:lO t o 1:30.
14. Miscellaneous
1 fi7
Miscellaneous 163
B a c t e r i o s t a t i c C o n c e n t r a t e w/Pine 021 I n q r e d i e n t s : Wt% Phase I : I s o p r o p a n o l 1 0 . 0 O l e i c A c i d 8 . 8 Varox 1770 5 . 0 P i n e O i 1 12 .0 Phase 11: Water, D . I . 62 .2 P o t a s s i um H y d r o x i d e (87%) 2 .0 81 end i ng Procedure :
Combine Phase I i n g r e d i e n t s and m ix t h o r o u g h l y . Combine Phase I T i n g r e d i e n t s and m ix t h o r o u g h l y . W h i l e m i x i n g , add Phase I t o Phase 11. T y p i c a l P r o p e r t i es :
V i s c o s i t y , c p s : 5 S o l i d s : 10.6% pH: 9 . 3
Formula 302
_ ~ ~ _ _ _ _ _ _ _ _ ~ ~ Genera l D i s i n f e c t a n t S o l u t i o n I n g r e d i e n t s : Water . D . I .
wtsl, 68 .0
Varquat 50 MC 10 .0 G1 y o x a l (40%) 5 . 0 R e w o t e r i c AM DML-35 1 7 . 0 B l e n d i n g P rocedure :
each add1 t i on, T y p i c a l P r o p e r t i e s :
V l s c o s l t y , c p s : 4 Sol 1 ds: 13.0% pH: 7 . 1
Add i n g r e d i e n t s 1 n o r d e r shown and d i s s o l v e c o m p l e t e l y between
Formula 303
H o s p i t a l D i s i n f e c t a n t -~ I n g r e d i e n t s : Wt% Water , D . I . 84 .2 V a r i q u a t 50 MC 9 . 6 Varox 365 4 . 0 Versene 100 1 . 5 Sod1 urn H y d r o x i d e (30%) 0 . 7 B l e n d i n g P rocedure :
each a d d i t i o n . T y p i c a l P r o p e r t i e s :
V i s c o s i t y , c p s : 4 S o l i d s : 6 .7% pH: 12.2
Formula 304
SOURCE: W i t c o C o r p , : Suggestecl F o r m u l a t i o n s
Add i n g r e d i e n t s i n o r d e r shown and d i s s o l v e c o m p l e t e l y between
I64 Advanced Cleaning Product Formulations
C u t t i n g O i l C o n c e n t r a t e
I n g r e d i e n t s : Wei s h t % A r i s t o n a t e M 36 .00 I g e p a l CO-430 20 .00 TEA, 85% 8 . 0 0 O l e i c A c i d 8 .00 100 SUS Naph then ic O i l 2 8 . 0 0 Comments abou t t h i s f o r m u l a : 1 . S o l u b l e O i l - D i l u t e 1 : 3 w i t h 100 SUS n a p h t h e n i c o i l . 2 . Emuls ion - D i l u t e 4:76 w i t h 160 ppm h a r d w a t e r .
F o r m u l a t i o n SOL-003-01
C u t t i n g O i 1
I n g r e d i e n t s : A r i s t o n a t e M TEA, 85% T a l l O i l A c i d , A c t i n o l FA-1 Calamide SM 100 SUS Naph then ic O i l Water Comments abou t t h i s f o r m u l a :
Emuls ion - D i l u t e 4:76 w i t h 160 ppm h a r d w a t e r . F o r m u l a t i o n SOL-004-01
Wei q h t % 10.50
0.90 1 . 2 0 1 .65
8 5 . 0 0 0 . 7 5
C o n c r e t e C1 eaner
I n g r e d i e n t s : Weight% C a l s o f t F-90 5 .00 Sodi um S i 1 i c a t e 30.00 Sodium Carbonate 30.00 Sodi um H y d r o x i d e 25 .00 Sodi um T r i phosphate 10.00 Comments abou t t h i s f o r m u l a :
G r i n d m i x t u r e t o g e t h e r t o y i e l d a s l i g h t l y t a c k y w h i t e powder. F o r m u l a t i o n CON-001-01
W h i t e W a l l C l e a n e r
I n s r e d i e n t s : Wei s h t % Water 60.20 C a l s o f t L-40 29 .30 P i l o t SXS-40 2 . 2 0 Na4 EDTA 1.30 Cal o x y l a t e N-9 7 .00 Comments abou t t h i s f o r m u l a :
V i s c o s i t y o f t h e p r o d u c t i s abou t 160 cPs a t room t e m p e r a t u r e . F o r m u l a t i o n TIR-001-01
SOURCE: P i l o t Chemical Co. : Suggested F o r m u l a t i o n s
Miscellaneous 165
d L i monene Water1 ess Hand C1 eaner
I n g r e d i e n t s : Phase I : Water, D . I . T r i s o d i u m Phosphate Sodium C i t r a t e G l y c e r i n
Phase 11: d - L i monene DeSonic 9N V a r o n i c T202
Wt%
81 . O 1 .o 2 . 0 2 . 0
7 . 0 5.0 2 . 0
B l e n d i n g Procedure: I n v e s s e l fit1 combine Phase I i n g r e d i e n t s and mix t h o r o u g h l y .
Heat t o 140F. Combine Phase I1 i n g r e d i e n t s i n s e p a r a t e v e s s e l and m ix t h o r o u g h l y . Heat t o 140F. W h i l e m i x i n g r a p i d l y , add Phase 11 Po Phase I. Cool q u i c k l y t o s t a b i l i z e emu ls ion .
T y p i c a l P r o p e r t i e s : Appearance, Room Temp.: Heavy Cream S o l i d s : 12.0% pH: 10 .4
Formula 1120
Pas te Hand C leaner
I n g r e d i e n t s : Water, D . I . Varami de MA-1 Rewote r i c AM 8-15 W i t c o l a t e S E - 5
WtS/o 70 .0 10 .0 10.0 10 .0
81 e n d i n g Procedure:
each a d d i t i on.
T y p i c a l P r o p e r t i e s : V i s c o s i t y , cps : 6360 S o l i d s : 19.5% pH: 8 . 7
Formula 1121
SOURCE: W i t c o C o r p . : Suggested F o r m u l a t i o n s
Add i n g r e d i e n t s i n o r d e r shown and d i s s o l v e c o m p l e t e l y between
166 Advanced Cleaning Product Formulations
Dipen tene M i c r o e m u l s i o n F o r m u l a t i o n s
D ipen tene i s d e s c r i b e d as a p r o d u c t o f f r a c t i o n a t i o n o f p i n e o i l s c o n t a i n i n g r e l a t e d monocyc l i c t e r p e n e hyd roca rbons , predomi- n a n t l y d i p e n t e n e . ( S t r u c t u r a l l y , d i p e n t e n e i s t h e same as l i m - onene. D-l imonene i s one o f t h e 2 o p t i c a l i somers o f d i p e n t e n e . ) O the r components o f commercial d i p e n t e n e i n c l u d e ca rene and a l p h a - and b e t a - p i n e n e .
N o n - a l k a l i n e F o r m u l a t i o n s
I n g r e d i e n t s : D i pen tene 122 Tomah E-14-5 Tomah E-14-2 Tomah A l k a l i S u r f a c t a n t Water
CPL, c : 1 1 CPH, C : 30 E m u l s i f i e r / D i p e n t e n e R a t i o : 1 .60
I n g r e d i e n t s : D i pen tene 122 Tomah E-14-5 Tomah E-14-2 Tomah A l k a Water
CPL, c : CPH, C : Emu1 s i f
i S u r f a c t a n t
11 50 e r / D i p e n t e n e R a t i o : 1 . 1 0
I n a r e d i e n t s : D i pen tene 122 Tomah E-14-5 Tomah E-14-2 Tomah A l k a l i S u r f a c t a n t Water
CPL, c : 19 CPH, C : 41 E m u l s i f i e r / D i p e n t e n e R a t i o : 0.90
&% 5 .00 6 . 4 0 0 .80 0 . 8 0
87 ~ 00
VVt.% 10 .00
8 . 8 0 1 . 1 0 1 . 1 0
79.00
Wt.% 20 .00 1 4 . 4 0
1 . 8 0 1 . 8 0
62.00
Add and m ix t h e f i r s t f o u r i n g r e d i e n t s ( d i p e n t e n e and emuls- i f i e r s ) . D i s s o l v e t h e sodium m e t a s i l i c a t e ( i f used) i n t h e w a t e r and add i t t o t h e e m u l s i f i e r s and d i p e n t e n e w i t h m i x i n g .
t e m p e r a t u r e c l o u d p o i n t " .
SOURCE: Tomah Produc ts , I n c . : B u l l e t i n : Terpene M i c r o e m u l s i o n s
CPL i s " l o w t e m p e r a t u r e c l o u d p o i n t " w h i l e CPH i s " h i g h
Miscellaneous 167
D i pen tene M i c roemul s i on Formul a t i ons (Con t i nued)
D i pen tene i s d e s c r i b e d as a p r o d u c t o f f r a c t i o n a t i o n o f p i ne o i l s c o n t a i n i n g r e l a t e d monocyc l i c t e r p e n e hyd roca rbons , predom- i n a n t l y d i p e n t e n e . ( S t r u c t u r a l l y , d i p e n t e n e i s t h e same as l i m o n - ene. D-l imonene i s one o f t h e 2 o p t i c a l i somers o f d i p e n t e n e . ) O the r components o f commercial d i p e n t e n e i n c l u d e ca rene and a l p h a - and b e t a - p i n e n e .
A l k a l i n e F o r m u l a t i o n s
I n g r e d i e n t s : D i pen tene 122 E-14-5 E-14-2 A1 k a l i S u r f a c t a n t Water Sodium M e t a s i l i c a t e Pen tahyd ra te
CPL, C : 15 CPH, C : 44 E m u l s i f i e r / D i p e n t e n e R a t i o : 2 .00
I n g r e d i e n t s : D i pen tene 122 E-14-5 E-14-2 A1 k a l i S u r f a c t a n t Water Sodium M e t a s i l i c a t e Pen tahyd ra te
CPL, c : 20 CPH, C : 46 E m u l s i f i e r / D i p e n t e n e R a t i o : 1 . 5 0
I n g r e d i e n t s : D i pentene 122 E- 14-5 E-14-2 A1 k a l i S u r f a c t a n t Water Sodium M e t a s i l i c a t e Pen tahyd ra te
Wt.96 5.00 8 . 0 0 0.50 1 . 50
83 .30 1 . 7 0
Wt.% 1 0 . 0 0 12 .00
0 . 7 5 2 . 2 5
73.50 1 . 5 0
Wt.% 20 .00 17 .60
1 . 1 0 3 . 3 0
56.80 1.20
CPL, C : 18 CPH, C : 43 E m u l s i f i e r / D i p e n t e n e R a t i o : 1 .I0 Add and mix t h e f i r s t f o u r i n g r e d i e n t s ( d i p e n t e n e and e m u l s i -
f i e r s ) . D i s s o l v e t h e sodium m e t a s i l i c a t e ( i f used) i n t h e w a t e r and add i t t o t h e e m u l s i f i e r s and d i p e n t e n e w i t h m i x i n g .
t e m p e r a t u r e c l o u d p o i n t " .
SOURCE: Tomah P r o d u c t s , I n c . : B u l l e t i n : Terpene M i c r o e m u l s i o n s
CPL i s " l ow t e m p e r a t u r e c l o u d p o i n t " w h i l e CPH i s " h i g h
168 Advanced Cleaning Product Formulatioris
Hydrocarbon S o l v e n t M i croemul s i ons
Developed i n o r d e r t o o f f e r rep lacemen ts f o r expens ive d- l imonene and p i n e o i l i n m i c r o e m u l s i o n c l e a n e r s . They a l l have f l a s h p o i n t s above I O O C and l o w VOC c o n t e n t .
Formula A: I n g r e d i e n t s :
Tomah E-14-2 Tomah E-14-5 Tomah A l k a l i S o f t Water
Exxso l D-110
Formula 8 : I n a r e d i e n t s :
Tomah E-14-2 Tomah E-14-5 Tomah A l k a l i S o f t Water
Exxso l D-110
Formula C : I n q r e d i e n t s :
Tomah E-14-2 Tomah E-14-5 Tomah A l k a l i S o f t Water
Exxsol D-110
Exxso l D - I 1 0 F o r m u l a t i o n s
S u r f a c t a n t
S u r f a c t a n t
S u r f a c t a n t
\Nt.% 20 .0 11.9
5 . 4 4 . 3
5 8 . 4
Wt.% 30.0 17.9 8 . 1 6 . 5
3 7 . 5
Wt.% 4 0 . 0 2 3 . 9 1 0 . 8
8 . 7 1 6 . 6
Add each component i n t h e o r d e r g i v e n and m ix u n t i l homogen- eous b e f o r e add ing t h e n e x t component. Add t h e w a t e r i n p o r t i o n s w i t h m i x i n g .
These m i c r o e m u l s i o n s s h o u l d be c l e a r and s t a b l e i n t h e temp- e r a t u r e range f r o m 20-37C. O u t s i d e t h a t range t h e y may c l o u d or separa te , b u t w i l l r e g a i n c l a r i t y upon r e t u r n i n g t o room temp- e r a t u r e . I f i t i s necessary t o r a i s e t h e c l o u d p o i n t t empera tu re , a s m a l l amount o f a d d i t i o n a l Tomah A l k a l i S u r f a c t a n t s h o u l d be added.
SOURCE: Tomah Produc ts , I n c . : Suggested F o r m u l a t i o n s
Miscellaneous 169
Hydrocarbon S o l v e n t M i c r o e m u l s i o n s ( C o n t i n u e d l
Developed i n o r d e r t o o f f e r rep lacemen ts f o r expens ive d- l imonene and p i n e o i l i n m i c r o e m u l s i o n c l e a n e r s . They a l l have f l a s h p o i n t s above 1OOC and l o w VOC c o n t e n t .
Isopar M F o r m u l a t i o n s
I s o p a r M can be s u b s t i t u t e d d i r e c t l y f o r t h e Exxso l D-110 i n t h e above f o r m u l a t i o n s . I n a d d i t i o n , two f o r m u l a t i o n s w i t h l ower s o l v e n t c o n t e n t have been deve loped .
Unbui 1 t : Component: S o f t Water Sodium Metas Tomah E-14-2 Tomah E-14-5 Tomah A1 k a l i I s o p a r Wi
l i c a t e Pen tahyd ra te
S u r f a c t a n t
L i g h t l y b u i 1 t : Component: S o f t Water Sodium M e t a s i l i c a t e P e n t a h y d r a t e Tomah E-14-2 Tomah E-14-5 Tomah A l k a l i S u r f a c t a n t I s o p a r M
Wt.% 83 .0
0 . 0 4 . 7 4 .7 1 . 6 6 . 0
Wt.% 7 9 . 0
1 . o 5 . 6 5 . 6 1 . a 7 . 0
S t a r t by d i s s o l v i n g t h e sodium m e t a s i l i c a t e ( i f used) i n t h e w a t e r . Then add t h e E-14-2, E-14-5, and A l k a l i S u r f a c t a n t . M ix u n t i l homogeneous. F i n a l l y add t h e I s o p a r M i n p o r t i o n s w i t h m i x i n g . The m i x t u r e w i l l c l o u d , t h e n s h o u l d c l e a r as t h e l a s t o f t h e I s o p a r M i s added. These m i c r o e m u l s i o n s w i l l be c l e a r and s t a b l e i n t h e t e m p e r a t u r e range f r o m 20-5OC. The c l o u d p o i n t can be r a i s e d f u r t h e r by add ing a sma l l amount o f a d d i t i o n a l A l k a l i S u r f a c t a n t .
SOURCE: Tomah Produc ts , I n c . : Suggested F o r m u l a t i o n s
I70 Advanced Cleaning Product Formulations
Lo!. . V i_s_cosi_tv_s_jlicon ..Emu 1- si- o~n-UsinxPemulen s resins
S i l i c o n e o i l can b e e m u l s i f i e d and s t a b i l i z e d v i a t h e use o f Pemulen r e s i n s . The r e s i n s s t a b i l i z e emu ls ions v i a e l e c t r o s t a t i c s t a b i l i z a t i o n . T h i s r e l i e v e s t h e c o n s t r a i n t o f s e e k i n g an approp- r i a t e s u r f a c t a n t e m u l s i f i e r .
I n y c e d i e n t l D I Water Pemulen 1622 ( 1 ) Makon 10 ( 2 ) Dow 200 S i l i c o n e F l u i d ( 3 ) T r i e t h a n o l a m i n e
W t"/. 8 3 . 8 0
0 . 2 0 0 . 7 0
1 5 . 0 0 0 . 3 0
P h y s i c a l P r o p e r t i e s : B r o o k f i e l d V i s c o s i t y (RVT-20 rpm) : 1,000 cp P roduc t p H : 7 . 3 P roduc t C l a r i t y : Opaque
Raw M a t e r i a1 Suppl i e r s : ( 1 ) BFGoodrich ( 2 ) Stepan C o . ( 3 ) Dow C o r n i n g
P rocedure : 1 . Use a L i g h t n i n ' M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an
i m p e l l e r s u i t a b l e f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t i o n s Screen t h e Pemuleri r e s i n int.o t h e v o r t e x o f t h e r a p i d l y a g i t a t i n g w a t e r (800 r p m ) . A l l o w t o mix u n t i l homogeneous and f r e e o f po l ymer lumps.
2 . Add t h e Makon 10 and mix u n t i l homogeneous. 3 . Add t h e s i l i c o n e o i l w i t h v i g o r o u s a g i t a t i o n . M ix u n t i l
4 . Add t h e T E A . M i x u n t i l smoot.h.
T o t a l A c t i v e s :
u n i f o r m .
S i l i c o n e O i l : 1 5 . 0 0 %
SOURCE: BFGoodrich S p e c i a l t y Chemicals : DET-510
Miscellaneous 171
Lumi n i z i n g P e t C o n d i t i o n e r
P h o s p h o l i p i d EFA adds s h i n e and a s i l k y t e x t u r e t o t h e a n i m a l ' s c o a t o r mane. The Monaquat TG p r o v i d e s body b u i l d i n g c o n d i t i o n i n g and d e t a n g l i n g w h i l e l e a v i n g a s o f t smooth f e e l . Monaquat I S I E S i s an e f f e c t i v e l o n g l a s t i n g a n t i s t a t t h a t c o n t r o l s d i r t a t t r a c t i o n .
I n a r e d i e n t s : Wt% Water 85.2 H y d r o x y e t h y l C e l l u l o s e 0 . 8 S t e a r i c a c i d 2.0 S t e a r y l a l c o h o l 2 . 0 Monaquat TG 7 . 0 Monaquat I S I E S ( I s o s t e a r y l E thy lm idon ium E t h o s u l f a t e ) 0 . 5 P h o s p h o l i p i d EFA ( L i n o l e a m i d o p r o p y l PG-Dimonium C h l o r i d e
Phosphate) 2 . 0 Sodium C h l o r i d e 0 .5
P rocedure :
l o s e and t u r n h e a t on. A t 50-60C add s t e a r i c a c i d , s t e a r y l a l c o h o l , Monaquat TG, Monaquat ISIES, P h o s p h o l i p i d EFA, and sodium c h l o r i d e . Heat and mix t o 70-75C ( a smooth creme). Cool t o 40C. A d j u s t pH t o 4 .5 -5 .0 . A d d c o l o r , f r a g r a n c e and p r e s e r v - a t i ve . Package.
T y p i c a l P r o p e r t i e s :
Change w a t e r w i t h a g i t a t i o n , s p r i n k l e i n h y d r o x y e t h y l c e l l u -
Appearance: Opaque v i s c o u s l o t i o n Recommended Use D i l u t i o n : As i s
F o r m u l a t i o n F-777
Pe t Shampoo
A h i g h foaming, m i l d d e t e r g e n t wh ich w i l l l e a v e you r p e t f r e s h and c l e a n .
I n g r e d i e n t s : Water Monaterge 779 d -L i monene
Wt% 70.0 25 .0
5 .0
P rocedure :
pH t o 7 . 0 . Add c o l o r and p r e s e r v a t i v e . Package.
T y p i c a l P r o p e r t i e s :
Add i n g r e d i e n t s i n t h e o r d e r l i s t e d w i t h a g i t a t i o n . A d j u s t
Appearance: C l e a r y e l l o w l i q u i d
Recommended Use D i l u t i o n : 1 :50 w i t h w a t e r F o r m u l a t i o n F-774
SOURCE: Mona I n d u s t r i e s , I n c . : Suggested F o r m u l a t i o n s
172 Advanced Cleaning Product Formulations
M i cro-Emu1 s i ons with d-Li monene
The f o l l o w i n g c o n c e n t r a t e s a r e c l e a r , m ic ro-emuls ions o f imonene and w a t e r . These f o r m u l a s a r e g e n e r a l l y used by u t i n g i n water a r e v e r y e f f e c t i v e f o r removing many o i l y
. .I r e s i n o u s s o i l s . The f o r m u l a themselves a r e c l e a r and e x h i b i t a bloom e f f e c t upon d i l u t i o n .
Formula I
I n q r e d i e n t s : d - L i monene Monamul se dL-1273 Water
I n q r e d i e n t s : d -L i monene Monamulse dL-1273 Isopropano l Water
I n g r e d i e n t s : d -L i monene Monamul se dL-1273 Water
Formula I1
Formula I11
Wt% 10 .0 18 .0 62.0
Wt% 35.0 28.0
5 . 0 32.0
Wt% 6 5 . 0 23 .0 12 .0
Procedure:
Add o t h e r i n g r e d i e n t s except w a t e r . M i x u n t i l homogeneous. Add water s l o w l y w i t h s t i r r i n g .
Recommended Use D i l u t i o n : 1 :10 w i t h water
SOURCE: Mona I n d u s t r i e s , I n c . : F o r m u l a t i o n F-786
I n a l l cases, mix s u r f a c t a n t w i t h d-Limonene u n t i l d i s s o l v e d .
Miscellaneous 173
M i cro-Emu1 s i ons w i t h P i ne O i 1
The fol 1 owi ng f o r m u l a s a r e c l ear m i c roemul s i ons o f p i ne o i 1 and w a t e r . They r e p r e s e n t t h e range o f p i n e o i l and w a t e r concen- t r a t i o n s commonly used. The f o r m u l a s themse lves a r e c l e a r and e x h i b i t a bloom e f f e c t upon d i l u t i o n .
Formula 1
I n a r e d i e n t s : P i n e O i l Monamulse TRP Water Appearance: C l e a r D i l u t i o n (1% i n t a p w a t e r ) : Blooms
Formula 2
I n g r e d i e n t s : P i n e O i l Monamul se TRP I s o p r o p a n o l Water Appearance: C1 e a r D i l u t i o n (1% i n t a p w a t e r ) : Blooms
Formula 3
I n g r e d i e n t s : P i n e O i l Monamul se TRP I s o p r o p a n o l Water Appearance: C1 e a r D i l u t i o n (1% i n t a p w a t e r ) : Blooms
Formula 4
I n q r e d i e n t s : P i n e O i l Monamul se TRP Water Appearance: C l e a r D i l u t i o n (1% i n t a p w a t e r ) : C l e a r
&y& 35.0 2 0 . 0 45 .0
WtO/o 2 0 . 0 2 0 . 0 5.0
5 5 . 0
Wt% 9 . 0
10 .0 1 0 . 0 71 .O
WtO/o 2 . 0 5 . 0 93.0
Procedure : B l e n d i n g r e d i e n t s i n t h e o r d e r l i s t e d w i t h a g i t a t i o n . Package Recommended Use D i l u t i o n : 1:lO w i t h w a t e r
Formula F-785
SOURCE: Mona I n d u s t r i e s , I n c . : Suggested F o r m u l a t i o n s
174 Advanced Cleaning Product Formulations
P l a s t i c B o t t l e Wash S t a b l e i n h a r d w a t e r
I n q r e d i e n t s : Water
K a s i l # I STPP Burco HCS-5ONF
KOH-45%
% S o l i d s : 31.0
Wt% 2 6 . 5 1 9 . 5 39.0
8 . 0 7 . 0
Add components i n o r d e r l i s t e d . B l e n d between a d d i t i o n s .
To f o r m u l a t e a l o w e r a c t i v i t y p r o d u c t , keep t h e r a t i o of t h e components t h e same, so t h a t t h e b a l a n c e o f t h e f o r m u l a t i o n i s n o t d e s t r o y e d . End use c o n c e n t r a t i o n s w i l l depend o n degree o f s o i l t o be removed. Norma l l y , a 2% end use c o n c e n t r a t i o n i s s u f f i c i e n t f o r b o t t l e c l e a n i n g .
A s l i g h t s i l i c a t e p r e c i p i t a t e may o c c u r upon l o n g s t a n d i n g .
B o t t l e Wash F o r m u l a t i o n s Low Foam
I n q r e d i e n t s : 50% NaOH Burco BSGH-270 Burco HCS-50NF
Add BSGH-270 and HCS-50 NF t o 50% NaOH.
Moderate Foam
I n q r e d i e n t s : 50% NaOH Burco BSGH-270 Burco NPS-225 Water
y& To 100% T o t a l
2 .5-5.0% 0.5-2.5%
W O
To 100% T o t a l 2 .5 -5 .0% 0.5-2.5% 3.0-7.5%
I t i s recommended t h a t t h e BSGH-270 and NPS-225 b e d i s s o l v e d i n an equa l amount o f wa te r and t h e c a u s t i c added t o t h a t p r e m i x . To defoam t h i s f o r m u l a t i o n use a 3/1 r a t i o o f NPS-225/Burco LAF-I 25.
SOURCE: B u r l i n g t o n Chemical Co., I n c . : Suggested F o r m u l a t i o n s
Miscellaneous 175
Teroene M i croemul s i ons
The f o r m u l a t i o n s g i v e n h e r e w i l l p roduce c l e a r s t a b l e m i c r o -
G l i d s o l 180 ( f r o m SCM G l i d c o Organ ics C o r p . ) , a p i n e o i l emu ls ions c o n t a i n i n g f r o m 15% t o 40% d - l imonene .
d e r i v a t i v e can be s u b s t i t u t e d f o r d- l imonene i n t h e f o r m u l a t i o n s t o g i v e a f l a s h p o i n t above 140F. N o t e t h a t o t h e r p i n e o i l s may n o t work i n t h e s e f o r m u l a t i o n s . Formula A : D-Limonene 40 .0 Tomah E-14-5 2 2 . 4 Tomah E-14-2 2 . 8 Tomah A l k a l i S u r f a c t a n t 2.8 Water 3 2 . 0
% t o t a l s u r f a c t a n t : 28.0% Emul s i f i e r /Te rpene r a t i 0: 0 .700
Formula 5: Wt.9/o D-Li monene 30 .0 Tomah E-14-5 19 .2 Tomah E-14-2 2 . 4 Tomah A l k a l i S u r f a c t a n t 2 . 4 Water 4 6 . 0
% t o t a l s u r f a c t a n t : 24.0% Emul s i f i er /Te rpene r a t i 0: 0 .800
Formula C : Wt.% D-Li monene 2 0 . 0 Tomah E-14-5 1 2 . 8 Tomah E-14-2 1 . 6 Tomah A l k a l i S u r f a c t a n t 1 . 6 Water 64 .0
% t o t a l s u r f a c t a n t : 16.0% E m u l s i f i e r / T e r p e n e r a t i o : 0 .800
Formula D : Wt.o/a D-Li monene 15 .0 Tomah E-14-5 1 2 . 0 Tomah E-14-2 1 . 5 Tomah A l k a l i S u r f a c t a n t 1 . 5 Water 7 0 . 0
% t o t a l s u r f a c t a n t : 15 .0% E m u l s i f i e r / T e r p e n e r a t i o : 1 . 0 0 0 Add each component i n t h e o r d e r g i v e n and m i x u n t i l homogen-
eous b e f o r e a d d i n g t h e n e x t component. Add t h e w a t e r i n p o r t i o n s w i t h m i x i n g .
1-2% d - l imonene a t use l e v e l i s u s u a l l y s u f f i c i e n t . Heavy g rease would r e q u i r e a h i g h e r c o n c e n t r a t i o n o f d - l imonene .
C o n c e n t r a t e d Formula Formula: D-Limonene 70 .0 Tomah E-14-5 1 4 . 0 Monamid 705 4 . 0 T a l l O i l F a t t y A c i d 1 . 6 Monoethanolamine 0 .4 Water 1 0 . 0 SOURCE: Tomah Produc ts , I n c . : B u l l e t i n : Terpene M i c r o e m u l s i o n s
A t y p i c a l use l e v e l would b e a t 10/1 t o 40/1 w i t h w a t e r . About
176 Advanced Cleaning Product Formulatioris
Wax Emulsion Using Pemulen Resins
Th is wax emulsion can be c rea ted and s t a b i l i z e d v i a t h e use o f Pemulen r e s i n s . The r e s i n s s t a b i i z e emulsions v i a e l e c t r o s t a t - i c s t a b i l i z a t i o n . T h i s r e l i e v e s t h e c o n s t r a i n t o f s e l e c t i n g an approp r ia te s u r f a c t a n t e m u l s i f i e r .
I n g r e d i e n t : Bareco C-36 Wax (1) Hoechst Wax E ( 2 ) Pemulen 1622 (3 ) 01 Water Morphol i ne
vytsb 12.00
8 . 0 0 0.30 79 ~ 50
0 . 2 0
Phys ica l P roper t i es :
Raw M a t e r i a l Supp l i e rs :
Product C l a r i t y : Opaque
(1 ) P e t r o l i t e Corp. ( 2 ) American Hoechst Corp. ( 3 ) BFGoodrich
Procedure: 1. Me l t t h e waxes together i n a vesse l , approx imate ly a t 9 0 C . 2 . Use a L i g h t n i n ' M ixer o r s i m i l a r v a r i a b l e speed u n i t and an
i m p e l l e r s u i t a b l e f o r general m ix ing and b lend ing opera t ions Screen t h e Pemulen r e s i n i n t o t h e vo r tex o f t h e r a p i d l y a g i t a t i n g water (800 rpm). A l low t o mix u n t i l homogeneous and f r e e o f polymer lumps.
3. Heat t h e Pemulen d i spe rs ion t o 9OC. Add t h e Pemulen d i spe r - s i o n t o t h e mel ted wax w i t h v igorous a g i t a t i o n .
4 . Add t h e morphol ine and cool q u i c k l y .
T o t a l Ac t i ves : T o t a l Wax: 20.00%
SOURCE: BFGoodrich Spec ia l t y Chemicals: DET-501
Section I I sportation Cleaners
and Polishes
177
15. Auto Cleaners and Polis
1 78
Auto Cleaners and Polishes 179
Chrome P o l i s h
I n a d d i t i o n t o th i cken ing , Carbopol r e s i n s impar t y i e l d va lue a l l o w i n g p a r t i c l e s , such as abrasives, t o become permanently suspended. The r e s i n a l s o prevents "creaming" o r phase separ- a t i o n by suspending and separa t ing t h e o i l d r o p l e t s .
I n g r e d i e n t : D I Water Morphol i ne Pumice Snow F loss SFSB S i l i c o n e F l u i d (350) ( 1 ) Yarmor 302 P ine O i l ( 2 ) O l e i c Ac id Minera l S p i r i t s TEA l a u r y l s u l f a t e ( 3 ) Cocamide DEA (4 ) D I Water Carbopol EZ-2 (5 )
39.25 1.39
14.00 9 . 2 5 1.85 0.46 1.85
24.50 2.30 0.50 4.46 0.19
Phys ica l P roper t i es : B r o o k f i e l d V i s c o s i t y (RVT-20 rpm): 10,800 cp Product pH: 9 .0 Product C l a r i t y : Opaque
Raw M a t e r i a l Supp l i e rs : ( 1 ) General E l e c t r i c (2 ) Hercules ( 3 ) Rhone-Poul enc ( 4 ) Henkel: Standamid PO ( 5 ) BFGoodri ch
Procedure: 1 . D isso lve t h e morphol ine i n t h e water . 2 . Wi th r a p i d a g i t a t i o n , add t h e pumice and Snow F loss . 3 . D i sso l ve t h e s i l i c o n e o i l , p i n e o i l , and o l e i c a c i d i n t h e
minera l s p i r i t s . S lowly add i n t o t h e above m ix tu re w i t h r a p i d a g i t a t i o n .
4 . Add i n t h e TEA l a u r y l s u l f a t e and Standamid PD. Blend t h o r - oughl y .
5. I n a separate vessel , d i spe rse 0.19 p a r t s o f Carbopol i n t o 4.48 p a r t s o f water by s imp ly "dumping" t h e polymer i n t o t h e water. I n j u s t a few minutes, t h e polymer w i l l comple te ly wet o u t . Add t h i s d i spe rs ion t o t h e above m ix tu re . Blend thorough1 y .
T o t a l Asti ves : S i l i c o n e F l u i d : 1 .85 T o t a l Su r fac tan t : 4.65 Minera l S p i r i t s : 24.50 T o t a l Abrasives: 23.25
FGoodrich Spec ia l t y Chemicals: DET-551
I80 Advanced Cleaning Product Formulations
L i q u i d Car Polish
I n a d d i t i o n t o th i cken ing , Carbopol r e s i n s impar t y i e l d value a l l o w i n g p a r t i c l e s , such as abrasives, t o become permanently suspended. The r e s i n a l s o prevents "creaming" o r phase separ- a t i o n by suspending and separa t ing t h e o i l d r o p l e t s .
I n s r e d i e n t : D I Water T r i ethanol ami ne Wax Emulsion ( 1 ) Morphol i ne SF90 S i l i c o n e F l u i d (350) (2 ) O l e i c Ac id Kerosene Minera l S p i r i t s D I Water Carbopol EZ-2 (3 ) Isopropanol Minera l S p i r i t s SF1706 React ive Amine Polymer ( 4 ) SF1705 React ive Amine Polymer ( 4 ) Kaopo l i t e k a o l i n c l a y ( 5 )
Wt96 37.80
8.20 2.50 2.00 1 * 50 2.50
10.00 8.00 49.70 0.30 0 . 4 0 5 .00 1.50 2.10 8.50
Physical P roper t i es : B r o o k f i e l d V i s c o s i t y (RVT-20 rpm): 3,200 cps Product pH: 8-9 Product C l a r i t y : Opaque
Raw M a t e r i a l Supp l ie rs : (1 ) see EiFGoodrich L i t e r a t u r e DET-501 ( 2 ) General E l e c t r i c (3) BFGoodrich ( 4 ) General E l e c t r i c ( 5 ) Kaopo l i te , I n c .
Procedure: 1. Mix together t h e water, TEA, wax emulsion, and t h e morpholine 2 . I n a separate vessel , mix t h e s i l i c o n e f l u i d , o l e i c ac id ,
kerosene and t h e mineral s p i r i t s t oge the r . Add t h i s t o t h e above m ix tu re w i t h v igorous a g i t a t i o n .
3. I n a separate vessel, d isperse 0.30 p a r t s o f Carbopol i n t o 19.70 p a r t s o f water by s imp ly "dumping" i t i n . The polymer w i l l wet ou t i n a few minutes. Add t h i s d i spe rs ion t o t h e above m ix tu re . Mix u n t i l homogeneous.
4 . I n a separate vessel , mix t h e isopropanol , m inera l s p i r i t s , and t h e two r e a c t i v e amine polymers toge the r . Add t o t h e above m ix tu re . Mix u n t i l homogeneous.
5. Slowly add i n t h e c l a y . Mix u n t i l homogeneous. To ta l Ac t i ves :
To ta l Wax : 0.50 S i l i c o n e F l u i d : 1.50
React i ve Ami ne Polymer : 3.60 Abrasive: 8.50
Minera l S p i r i t s : 11 .oo
SOURCE: BFGoodrich Spec ia l t y Chemicals: DET-BOO
Auto Cleaners and Polishes 181
Liquid Spray Cleaner f o r A luminum Trucks
Bngredi en ts : Water Phosphoric Acid, 75% C i t r i c Ac id Macol 48 Ammoni um B i f 1 u o r i de Avanel S-30
- W t % 5 0 . 0 20.0 1 0 . 0 4 . 0 3.0 3.0
~ r ~ c ~ d U r ~ ~
w i t h f i v e p a r t s water t o use. Add i n g r e d i e n t s i n order as l i s t e d . D i l u t e one p a r t c leaner
A1 umi num Cleaner/Br i nhtener
Pnaredi en t : Phosphoric Acid, 85% C i t r i c Acid, 50% N i t r i c Acid, 70% Avanel S-70 Water
Wt% 6.0 8.0 1 .o 2.0
83.0
Procedure:
and w i t h due care, add t h e ac ids t o t h e water. Add t h e Avanel S-70 and mix f o r 10 minutes. Note: I f a d d i t i o n a l b r i g h t e n i n g i s requ i red , t h e n i t r i c a c i d may be increased t o 1.5%.
Charge t h e water t o t h e mix ing vesse l . Under slow a g i t a t i o n
Formulat ion CM-101
Non-Phosphorous A l u m i n u m Cleaner
Ina red i en t : C i t r i c Acid, 50% Gluconic Acid, 50% Avanel 5-70 Water, Dye
Wt% 12.0 8.0 3.0
77.0
PPOC@dUr&?: Charae t h e water, c i t r i c ac id , g lucon ic a c i d and Avanel S-70
t o t h e Gix ing vessei . M i x w e l l . I f - d y e i s t o be added, p a r t of t h e water should be h e l d ou t . Add t h e dye t o t h e water w i t h good a g i t a t i o n and then add t h e water t o t h e batch.
Formu 1 a t i on CM- 102
UWCE: PPG I n d u s t r i e s , I n c . : Suggested Formulat ions
182 Advanced Cleaning Product Formulations
M i l d Abrasive Automobile Polish
I n q r e d i e n t : Par t A : Masi 1 SF 1,000 O l e i c Ac id Carnauba Wax #1 Yel low Isopar M Mazami de SS-1 0
Pa r t B: I sopar M Mas i l 123
Par t C : I sopar M Morphol i ne
Par t D: Water Kaopo l i t e SF
pH (as i s ) : 7 . 5 - 8 . 5 Appearance: Cream-Colored Paste
Wt%
4 . 0 2 . 0 6 . 0
14 .5 0 . 7 5
1 2 . 0 2.0
2 . 5 1 . 1
45.15 1 0 . 0
Procedure: 1 . Charge t h e components i n Pa r t A t o a steam-heated mix ing
vessel equipped w i t h a g i t a t i o n . S t a r t a g i t a t i o n and heat t o 9QC.
When Par t A reaches 9OC and a l l t h e wax has melted, add Par t B t o t h e vessel f o l l owed by Par t C . Apply c o o l i n g .
3 . I n a separate vessel , prepare Par t D by adding t h e Kaopoldte SF t o t h e water under a g i t a t i o n . Add Par t D t o Pa r t A and con t inue c o o l i n g . NOTE: The f i n i s h e d produc t i s a pas te . A s t i f f e r pas te can be prepared by i nc reas ing t h e o l e i c a c i d charge.
2 . I n separate vesse ls , charge Par t B and Par t C components.
SOURCE: PPG I n d u s t r i e s , I n c . : Formula t ion S A - 1 0 1
0 r and Truck Wash Compounds
183
184 Advanced Cleaning Product Formulations
Car Shampoo Concentrate
Th is fo rmu la t i on produces copious amounts o f foam w h i l e c lean ing automot ive f i n i s h e s . I t i s m i l d t o bo th t h e user and t h e automot ive f i n i s h .
I n g r e d i e n t : Pa r t A : Dei on i zed Water Sodi um C i t r a t e
Wt%
30 .0 0 . 5
Par t 8: Mafo CSB-50 5.0 Witconate 60 T L i q u i d 7 .5 Macol TD-12 4 . 0 T r i ethanol ami ne, 85% 1 . o Deionized Water 52.0
pH (as i s ) : 8 . 0 - 9 . 0 Appearance: Clear, l i g h t - y e l l o w l i q u i d S p e c i f i c G r a v i t y : 1.00
Procedure: 1 . Charge t h e f i r s t p o r t i o n o f water t o a m ix ing vessel and
d i s s o l v e t h e sodium c i t r a t e i n i t . 2 . Add t h e remaining i n g r e d i e n t s i n t h e order l i s t e d . Stop
a g i t a t i o n and pe rm i t t h e produc t t o deaerate p r i o r t o f i l l i n g o f f . NOTE: Use concen t ra t i on i s 1-2 ounces per g a l l o n o f warm water.
Automat ic Car Wash Concentrate
I n a r e d i e n t s : Dei on i zed Water Maphos 60-A Potassi um Hydroxide Tetrapotassium Pyrophosphate Sodium M e t a s i l i c a t e , Anhydrous Macol LF 120 Mazamide 00 Sodium Xylene Su l fonate , 40% Macol 48 Deionized Water
pH (as i s ) : 12.5-13.5 Appearance: C lear , l i g h t - y e l l o w l i q u i d S p e c i f i c G r a v i t y : 1 .06
Procedure: Charge t h e f i r s t p o r t i o n o f water t o t h e m ix ing vessel and
s t a r t a g i t a t i o n . Add t h e i n g r e d i e n t s i n the order l i s t e d and mix u n t i l c l e a r . NOTE: Th is i s a h i g h l y a l k a l i n e c leaner designed t o be used i n commercial au tomat ic car washes a t a d i l u t i o n r a t e o f 1-2 ounces per g a l l o n . Do no t use d i r e c t l y on automot ive f i n i s h e s
Formula t ion CA-102
w.t% 50.0
6 . 0 3.0 2 .0 2 . 0 2 . 0 2 . 0 3 .0 3 . 0
27.0
SOURCE: PPG I n d u s t r i e s , I n c . : Suggested Formulat ions
1
Car and Truck Wash Compounds 185
I n g r e d i e n t s : Water NaOH, 50% D i e t h a n o l ami ne Cal s o f t LAS-99 Calamide C P i l o t SXS-40 Cal foam EA-603
Car Wash ( C a l s o f t LAS-gg-Basedl Weight%
72.50 2.40 0 .50
10 .10 3 .70 7.00 2.80
Ammonium C h l o r i d e Comments abou t t h i s f o r m u l a :
Add i n g r e d i e n t s i n o r d e r l i s t e d . F o r m u l a t i o n CWC-008-01
Car Wash ( C a l s o f t LAS-99-Based) I n g r e d i e n t s : Water NaOH, 50% Cal s o f t LAS-99 Calamide C P i l o t SXS-40 Cal foam EA-603 Cal o x y l a t e N-9 Comments abou t t h i s f o r m u l a :
Add i n g r e d i e n t s i n o r d e r 1 i s t e d F o r m u l a t i o n CWC-007-01
Car Wash (Ca lsuds A-Based) I n g r e d i e n t s : Water Calsuds A Cal foam EA-603 Calsuds CD-6 Ammonium C h l o r i d e Comments abou t t h i s f o r m u l a :
Add i n g r e d i e n t s i n o r d e r l i s t e d . F o r m u l a t i o n CWC-006-01
Car Wash ( C a l s o f t T-60-Based) I n g r e d i e n t s : Water C a l s o f t T-60 Pi l o t sxs-40 Cal o x y l a t e N-9 Comments abou t t h i s f o r m u l a :
Add i n g r e d i e n t s i n o r d e r l i s t e d . F o r m u l a t i o n CWC-005-01
SOURCE: P i l o t Chemical C o . : Suggested F o r m u l a t i o n s
1 . o o
Wei q h t % 59.80
4 . 3 5 16.30
2 . 0 5 12 .50
3 .00 2 .00
Wei a h t % 64.20 28.00
2 . 8 0 4 .00 1 . o o
Weight% 70.00 20.00
5 . 0 0 5 . 0 0
186 Advanced Cleaning Product Formulatioris
Car Wash
Readi l y removes a wide v a r i e t y o f r o a d s o i 1 s .
I n g r e d i e n t s : Water 70 .0 Monaterge ALX-100s (Cocamide DEA (and) DEA Dodecyl -
benzenesu l fonate (and) D ie thano lamine) 3 0 . 0
Procedure:
t o 7 . 0 . Add c o l o r , f r a g r a n c e and p r e s e r v a t i v e . Package. Add i n g r e d i e n t s i n t h e o r d e r l i s t e d w i t h a g i t a t i o n . A d j u s t pH
Typ i c a l P r o p e r t i e s : Appearance: C l e a r y e l l o w l i q u i d Recommnded Use D i l u t i o n : 1 :20 w i t h water
F o r m u l a t i o n F-772
Paste Car Wax
T h i s e a s i l y a p p l i e d au tomobi le p a s t e wax f o r m u l a w i l l p r o v i d e improved c l e a n i n g , depth o f g l o s s , l a s t i n g beauty and s h i n e t o new and o l d e r a u t o m o b i l e f i n i s h e s . Monas i l PCA w i l l p r o v i d e s h i n e and d e t e r g e n t r e s i s t a n c e t o any p a s t e wax f o r m u l a .
I n g r e d i e n t s : P a r t I: Monas i l PCA Dimeth icone (12,500 c s t ) Carnauba Wax #1 Y e l l o w T a l l O i l F a t t y A c i d I s o p a r K Kaopol i t e 11 52
P a r t 11: Water TEA (99%)
Procedure: Prepare each phase s e p a r a t e l y , h e a t t o 70C.
s l o w l y t o P a r t I w i t h good a g i t a t i o n . S t i r coo package. F o r m u l a t i o n F-826
SOURCE: Mona I n d u s t r i e s , I n c . : Suggested Formu
We96
4 . 5 2 .0 6 . 0 3 . 0
24 .0 1 0 . 0
5 0 . 0 0 . 5
Add P a r t II t o 40-50C and
a t i o n s
Car and Truck Wash Compounds 187
Car Wash w/Amphoter ic
I n g r e d i e n t s : Water, D . I . Sodi um T r i po l yphospha te R e w o t e r i c AM 8-14 Varon i c DM-55 Sodi um Hydrox ide , 30% W i t c o 1298SA
wt% 5 5 . 0
4 . 0 10.0 2 . 0 9 . 0
20 .0
B1 end i ng P rocedure :
each a d d i t i o n .
T y p i c a l P r o p e r t i e s : V i s c o s i t y , c p s : 290 S o l i d s : 29.5% pH: 8 . 9
Add i n g r e d i e n t s i n o r d e r shown and d i s s o l v e compl e t e l y between
Formula 630
I n g r e d i e n t s : Water, D . I . I s o p r o p a n o l P e t r o BAF Powder DeSophos 5AP EDTA, 38%
W i n d s h i e l d Washer C o n c e n t r a t e
Wt% 5 6 . 0 30.0
1 . o 0 .5 2 . 5
B l e n d i n g Procedure: B l e n d i n g r e d i e n t s i n t h e o r d e r l i s t e d .
Use "as i s " i n w i n t e r ; d i l u t e up t o 2 9 : l f o r summer use.
Formula 666
W i n d s h i e l d Washer F o r m u l a t i o n
I n q r e d i e n t s : W i t c o n a t e 1240 I s o p r o p a n o l Water
51 end i ng P rocedure :
Formula 867
SOURCE: W i t c o C o r p . : Suggested F o r m u l a t i o n s
D i s s o l ve W i t c o n a t e 1240 i n wa te r , t h e n add i sopropanol
Wt% 1 . o
39.0 6 0 . 0
188 Advanced Cleaning Product Formulations
Car Wash C o n c e n t r a t e w /A lcoho l E t h o x y l a t e
I n q r e d i e n t s : Water , D . I . W i t c o l a t e SE-5 W i t c o n a t e 1260 S l u r r y P e t r o LBA L i q u i d DeSonic 81-6 W i t cami de 128T
B l e n d i n g Procedure: B l e n d i n g r e d i e n t s i n t h e o r d e r l i s t e d
T y p i c a l P r o p e r t i e s : V i s c o s i t y , cps : 210 A c t i v e s , %: 23 .7
Formula 61 1
Car Wash C o n c e n t r a t e w /A lcoho l E t h o x y l a t e
I n g r e d i e n t s : Water, D . I . W i t c o l a t e SE-5 W i t c o n a t e 1260 S l u r r y P e t r o LBA L i q u i d DeSonic 81-6 W i t cami de 128T
B l e n d i n g P rocedure : B l e n d i n g r e d i e n t s i n t h e o r d e r l i s t e d .
Typ i c a l P r o p e r t i es : V i s c o s i t y , c p s : 335 A c t i v e s , %: 37.5
Formula 611
Car Wash C o n c e n t r a t e w /A lcoho l E t h o x y l a t e
I n a r e d i e n t s : Water, D . I . W i t c o l a t e SE-5 W i t c o n a t e 1260 S l u r r y P e t r o LBA L i q u i d DeSonic 81-6 W i t cami de 128T
B l e n d i n g P rocedure : B1 end i n g r e d i e n t s i n t h e o r d e r 1 i s t e d .
T y p i c a l P r o p e r t i e s : V i s c o s i t y , cps : 315 A c t i v e s , %: 43.0
Formula 611
SOURCE: W i t c o Corp . : Suggested F o r m u l a t i o n s
64 .9 8 . 3
1 6 . 7 1 . 3 5 . 0 3 . 8
W S 4 3 . 3 13 .9 2 7 . 8
5 . 0 7 .0 3 . 0
3 6 . 0 15.0 30 .0
6 . 0 8 . 0 5 . 0
I n g r e d i e n t s : C a l f a x DB-45 C a l s o f t L-40 T r i s o d i um Phosphate Water
Car and Truck Wash Compounds 189
C a r and T r u c k Wash Formula
Wei q h t % 19 .83 24.95 10.02 45.18
Comments abou t t h i s f o r m u l a : Add i n g r e d i e n t s i n o r d e r l i s t e d . F o r m u l a t i o n CWC-001-01
Car and T r u c k Wash Formula
I n g r e d i e n t s : C a l f a x DB-45 C a l s o f t L-40 D i s o d i um Phosphate Water
Comments abou t t h i s f o r m u l a : 1 . T h i s i s l o w e r p H f o r m u l a t h e n CWC-001-01. 2 . H e a t i n g i s necessa ry t o homogenize.
F o r m u l a t i o n CWC-002-01
Car Wash [Powder)
I n g r e d i e n t s : Sodi um T r i po l yphospha te C a l s o f t F-90 Cal o x y l a t e N-9
Comments abou t t h i s f o r m u l a : Add i n g r e d i e n t s i n o r d e r l i s t e d . F o r m u l a t i o n CWC-003-01
C a r Wash (Calsuds A-Based)
I n q r e d i e n t s : Calsuds A Cal foam EA-603 C a l o x y l a t e N-9 Water
Comments abou t t h i s f o r m u l a : Add i n g r e d i e n t s i n o r d e r l i s t e d . F o r m u l a t i o n CWC-004-01
SOURCE: B1 i o t Chemi c a l Co. : Suggested F o r m u l a t i o n s
Wei qh t% 20 .00 25.17 10.04 44.76
Wei q h t % 85.00
5.00 10.00
Wei g h t % 50.00
3.00 2.00
45.00
190 Advanced Cleaning Product Formulations
Car Wash and Care
Car Shampoo with Water-Repellent Effect
Ingredients: Autopur WK 4332 Amphotensid 0 4 Water
Formula CT 04-03-02
Rinse-off ARent (Water-Repellent)
Ingredients: Autopoon GK 4004 Mulsifan RT 1 Produkt 2058 Pine oil Butyl di glycol Water
Formula CT 04-05-07
Wt% 4 5 . 0
5 . 0 5 0 . 0
wtu/, 1 7 . 0 6 . 0 6 . 0 3 . 0 8 . 0
6 0 . 0
Rinse-off Aqent (Water-Repellent) Without Hydrocarbons
Ingredients: Autopoon GK 4008 Mulsifan RT 1 Produkt 2058 Butyl di glycol Water
Formula CT 04-05-03
Windshield-Cleaner (Summer)
Inqredi ents: Water Ethanol Zusol at 1005/85 Zusolat 1008/85
Formula CT 04-06-01
Innredi ents: Water Zetesol NL Zusol at 1008/85 Isopropanol
Formula CT 04-06-04
Wt% 17 .0
6 . 0 6 . 0 8 . 0
63 .0
Wt% 6 7 . 9 2 0 . 0
5 . 2 6 .9
Wt% 2 3 . 7 6 4 . 0
1 . 3 11 . o
SOURCE: Zschimmer & Schwarz GmbH & Co.: Suggested Formulations
Car and Truck Wash Compounds 191
Car Wash and Care
Windsh ie ld -C leaner ( W i n t e r )
I n g r e d i e n t s : Water I s o p r o p a n o l Z e t e s o l 2056
Formula CT 04-06-07
I n s e c t Remover
I n q r e d i e n t s : S u l f e t a l 4105 Z u s o l a t 1008/85 P h o s f e t a l 201 T r i l o n A l i q u i d Monoethanol ami ne B u t y l d i g l y c o l Water
Formula CT 04-07-01
Wheel C1 eaner . A1 k a l i n e
I n g r e d i e n t s : Water T e t r a p o t a s s i u m py rophospha te Lumorol 4192 Zusol a t 1005/85 B u t y l d i g l y c o l Orange t e r p e n e
Formula CT 04-11-04
T a r Remover
I n q r e d i e n t s : M u l s i f a n K 326 S p e z i a l Whi t e - s p i r i t n -bu tano l O l e i c a c i d Water
Formula CT 04-13-02
Wtl 29.5 70.0
0 . 5
Wt% 4 .0 2 .0 2 . 0 4 . 0 4 . 0 5 . 0
79 .0
Wt% 77.5
3 . 0 1 0 . 0
4.0 5 . 0 0 . 5
Wt% 1 5 . 0 6 0 . 0
7 . 0 3 . 0
15.0
SOURCE: Zschimmer & Schwarz GmbH & Co. : Genera l F o r m u l a t i o n s
192 Advanced Cleaning Product Formulations
Car Wax
I n g r e d i e n t : Pa r t A : Morphol i ne Water
Pa r t B: Wax S O l e i c Ac id Minera l Spi r i t s Kerosene
Par t C : Mas i l EM 250 C Mas i l EM 10,000 C Snow F loss Kaopol i t e SF Carbopol 941 ( 1 % i n water )
Wt%
0 .8 44.2
8.0 1 . o
18.0 9.0
10.0 3.0 3.0 3.0
As needed
Procedure: 1 . Add t h e morphol ine t o the water w i t h h igh speed mix ing . 2 . I n Pa r t B, add the o l e i c ac id , m inera l s p i r i t s , kerosene,
and Wax S w i t h h igh speed m ix ing . Add Par t B t o Pa r t A w i t h h i g h shear m ix ing .
3. Add t h e Mas i l EM 250 C and Mas i l EM 10,000 C from Par t C t o t h e concent ra te w i t h slow mix ing . Add t h e Snow F l o s s and Kaopo l i t e SF. Thicken w i t h t h e Carbopol 941 s o l u t i o n .
Auto Wipe B Shine P o l i s h
I n g r e d i e n t ; Pa r t A : Mas i l SF 100
O l e i c Ac id Minera l O i 1 , 70 SUS
Par t 0 : Morphol i ne Carbopol 934 Tr ie thano lamine Water
A-C 617A 3 . 5 2 . 0 1 . 5 5.6
1.4 0.2 0 .2
8 5 . 6
Procedure: 1 . Add t h e i n g r e d i e n t s i n Pa r t A as l i s t e d and heat t o 9OC. 2 . For Pa r t B, heat t h e water t o 85C. Disperse t h e Carbopol 934
i n t h e water. When comple te ly d i sso l ved , add t h e t r i e t h a n o l - amine. Then, add t h e morphol ine.
3. Add P a r t A t o P a r t 0 and b lend .
SOURCE: PPG I n d u s t r i e s , I n c . : Suggested Formulat ions
Car and Truck Wash Compounds 193
Concentrated T r a f f i c F i lm Removers
Two f o r m u l a t i o n s were developed w h i c h c o n t a i n 50% t o t a l w a t e r , i n c l u d i n g t h e w a t e r i n t h e sodium m e t a s i l i c a t e p e n t a h y d r a t e . One c o n t a i n s n o n i o n i c , t h e o t h e r has no n o n i o n i c b u t has more AO-14-2 and A l k a l i S u r f a c t a n t , t h e c o m b i n a t i o n o f w h i c h s h o u l d do as w e l l as t h e n o n i o n i c f o r h a r d s u r f a c e c l e a n i n g .
M ix i n t h e o r d e r g i v e n : Formula 1 : Component: Water Versene 100 Sodium M e t a s i l i c a t e P e n t a h y d r a t e Tomah A l k a l i S u r f a c t a n t Tomah AO-14-2 Tomah Q-17-2
% anhydrous b u i l d e r : 19.00 S u r f a c t a n t / b u i l d e r r a t i o : 1 .68
M i x i n t h e o r d e r g i v e n : Formula 2 : Component: Water Versene 100 Sodium M e t a s i l i c a t e Pen tahyd ra te Tomah A l k a l i S u r f a c t a n t Tomah AO-14-2 Tomah Q-17-5 Noni o n i c NP-9.5
Wt% 22.00 38.00
8.00 16.00 8.00 8.00
Wt.% 36.20 19 .70 4 .10
1 0 . 0 0 10.00 10 .00 10.00
% anhydrous b u i l d e r : 9 .82% S u r f a c t a n t / b u i l d e r r a t i o : 4 .07
Note t h a t sodium m e t a s i l i c a t e p e n t a h y d r a t e i s a c t u a l l y about 57% sodium m e t a s i l i c a t e on an anhydrous b a s i s . Versene 100 i s abou t 38% t e t r a s o d i u m EDTA on an anhydrous b a s i s . Thus t h e s e f o r m u l a t i o n s a r e about 50% t o t a l w a t e r when c a l c u l a t e d on an anhydrous b u i l d e r b a s i s . The s u r f a c t a n t s were c o n s i d e r e d on an a s - i s b a s i s , and n o t c o r r e c t e d f o r t h e w a t e r c o n t e n t . Anhydrous sodium m e t a s i l i c a t e and anhydrous t e t r a s o d i u m EDTA a r e r e a d i l y a v a i l a b l e ; anhydrous ampho te r i cs and amine o x i d e s a r e n o t .
These f o r m u l a t i o n s were made up and found t o be f reeze - thaw s t a b 1 e.
Formula 1 was d i l u t e d 1/20 w i t h w a t e r t o 2.5% a c t i v e s , and t e s t e d by s p r a y i n g on a d i r t y c a r . It was compared w i t h Formula- t i o n T-107 T r a f f i c F i l m Remover a l s o a t 2.5% a c t i v e s . No s i g - n i f i c a n t d i f f e r e n c e s were seen, so t h e absence o f n o n i o n i c d i d n o t a d v e r s e l y a f f e c t t h e pe r fo rmance o f t h e c o n c e n t r a t e d f o r m u l a t i on. SOURCE: Tomah Products, I n c . : Suggested F o r m u l a t i o n s
194 Advanced Cleaning Product Formulatioris
Foamy Brush Car Wash, L i q u i d
I n q r e d i e n t s : Water, D . I . * C a u s t i c Soda, 50% W i t c o 1298SA W i t c o l a t e SE-5 P e t r o BAF L i q u i d W i t cami de 128T Formal i n Sodi um C h l o r i d e
Wtg 79.75
1.40 5 . 0 0 7 . 0 0 3 . 0 0 3.00 0 . 1 0 0.75
B l e n d i n g P rocedure :
used t o a d j u s t v i s c o s i t y o f t h e p r o d u c t .
T y p i c a l P r o p e r t i es :
B l e n d i n g r e d i e n t s i n t h e o r d e r l i s t e d . Sodium C h l o r i d e i s
S p e c i f i c G r a v i t y : 1 .015 Wt . /Ga l . l b s . : 8 . 4 6 pH, as i s : 9 . 8 V i s c o s i t y , cps : 410
D i l u t i o n R a t i o a t Wand=l : 4 0 * I f u n s o f t e n e d t a p w a t e r i s used, add 0 .25% l i q u i d EDTA, 40%
t o c o u n t e r a c t ha rdness . Formula 621
Low Cost Car=
I n g r e d i e n t s : Water . D . I . P e t r o LBA Powder W i t c o l a t e SE-5 W i t cami de 128T Formal i n Sodi um C h l o r i d e Perfume, Dye
Wt% 8 9 . 9
1 . o 6 . 0 3 . 0 0 . 1 4 . s . 4 . s .
B l e n d i n g P rocedure :
pH=7.5-8.0. The Sodium C h l o r i d e i s used t o a d j u s t t h e v i s c o s i t y o f t h e f i n a l p r o d u c t .
B lend t h e i n g r e d i e n t s i n t h e o r d e r l i s t e d . A d j u s t t h e
Formula 609
SOURCE: W i t c o Corp.: Suggested F o r m u l a t i o n s
Car and Truck Wash Compounds 195
Genera l Purpose C a r Wash
T h i s i s a cop ious - foaming , a l l - p u r p o s e c a r wash f o r m u l a t e d t o be s a f e on c a r f i n i s h e s , y e t e f f e c t i v e i n t h e removal o f r o a d g r i m e and o t h e r s o i l s .
I n s r e d i e n t : D e i o n i z e d Water Mazon 98 Macol TD-3 W i t c o l a t e WACLA Mazamide 80 Macol 48 T r i e t h a n o l a m i n e , D e i o n i z e d Water
85%
w b 5 0 . 0
9 . 5 1 . 5 2 . 5 3 . 0 1 . o 1 . 5
31 . O
pH ( a s i s ) : 8 . 5 - 9 . 5 Appearance: C l e a r , l i g h t - y e l l o w l i q u i d S p e c i f i c G r a v i t y : 1 . 0 2
P rocedure :
s t a r t s l o w a g i t a t i o n ( e x c e s s i v e a g i t a t i o n w i l l p roduce a foaming p r o b l e m ) . Add t h e r e m a i n i n g i n g r e d i e n t s i n t h e o r d e r l i s t e d and mix u n t i l c l e a r . NOTE: Use c o n c e n t r a t i o n i s 1-2 ounces p e r g a l l o n o f warm w a t e r .
Charge t h e f i r s t p o r t i o n o f wa te r t o a m i x i n g v e s s e l and
F o r m u l a t i o n CA-103
L i q u i d Car Wash
I n g r e d i e n t : Water W i t c o n a t e 60 T L i q u i d Macol OP-10 SP Mazamide 80 Hexyl C a r b i t o 1 Methanol
P rocedure : Add i n g r e d i e n t s i n o r d e r as l i s t e d .
~ Boa t ~~ Wash ~~~~ & CarPCleaner
I n g r e d i e n t : Water Mazamide 80 Macol NP 9 .5 W i t c o n a t e 60 T L i q u i d
P rocedure : Add i n g r e d i e n t s i n o r d e r as l i s t e d .
SOURCE: PPG I n d u s t r i e s , I n c . : Suggested F o r m u l a t i o n s
N t S 3 4 . 0 30 .0 10.0
6 . 0 1 0 . 0 1 0 . 0
v v t % 3 9 . 0 11 . o
5 . 0 45.0
196 Advanced Cleaning Product Formulatiom
Heavy Duty T r u c k Wash, L i q u i d
I n q r e d i e n t s : Water , D . I . T r i s o d i um Phosphate, C r y s t a l C a u s t i c Soda Beads W i t c o 1298 S o f t A c i d P e t r o BAF L i q u i d Sodium S i l i c a t e 40 Be' ( S t a r ) W i t c o l a t e SE-5 E t h y l e n e G l y c o l Monobuty l E t h e r (EB) Emcol 6744
B l e n d i n g P rocedure : B lend i n g r e d i e n t s i n o r d e r 1 i s t e d .
T y p i c a l P r o p e r t i e s : S p e c i f i c G r a v i t y : 1 .042 Wt . /Ga l . l b s . : 8 . 6 9 pH, as i s : 1 2 . 7
D i l u t i o n Ra te : D i l u t e 1 : 4 0 a t Wand Formula 603
Heavy Duty T r u c k Wash, Powder
I n q r e d i e n t s : Sodi um Carbonate (Soda Ash) , L i g h t D e n s i t y Sodium T r i p o l y p h o s p h a t e , L i g h t D e n s i t y DeSophos 5AP DeSonic 9N Sodium M e t a s i l i c a t e , Anhydrous Sodium S u l f a t e ( S a l t Cake) C a u s t i c Soda Beads Dye*
70.0 2 . 0 2 .0
1 0 . 0 3 . 0 3 . 0 3 . 0 3 .0 4 . 0
wtd/, 47.25 55.00
2 . 9 0 7 . 5 0 5 .00
1 0 . 0 0 2.30 0 .05
B1 end i ng P rocedure : Premix Soda Ash and T r i p o l y t o g e t h e r and s l o w l y add DeSophos
5AP w h i l e m i x i n g . M i x u n t i l p r o d u c t i s u n i f o r m i n appearance. Add DeSonic 9N w h i l e m i x i n g . M ix u n t i l t h e p r o d u c t l o o k s d r y ( 4 - 5 m i n u t e s ) . Add M e t a s i l i c a t e , S a l t Cake and t h e n C a u s t i c Soda beads.
* I f dye i s used, m ix w i t h t h e DeSonic 9N. Formula 604
SOURCE: W i t c o Corp . : Suggested F o r m u l a t i o n s
Car and Truck Wash Compounds 197
Premium Car Wash C o n c e n t r a t e
I n g r e d i e n t s : Water , D . I . E thano l Varox 1770 W i t c o n a t e AOS L i q u i d W i t c o l a t e SE-5
Wt% 11 .7
5 .9 17.6 4 6 . 8 17.6
B l endi ng Procedure:
d i s s o l v e completel ’y between each a d d i t i o n . Add W i t c o l a t e SE-5 l a s t i n s m a l l a l i q u o t s a l l o w i n g complete d i s s o l u t i o n between a d d i t i o n s .
T y p i c a l P r o p e r t i es : V i s c o s i t y , c p s : 160 Sol i d s : 35.4% p H : 8 . 4
Add a l l i n g r e d i e n t s except W i t c o l a t e SE-5, i n o r d e r shown and
Formula 629
I n g r e d i e n t s : Water T e t r a p o t a s s i um W i t cami de 6445
Car Wash
Pyrophosphate, 60%
51ending Procedure: B lend i n g r e d i e n t s i n o r d e r l i s t e d .
Typ i c a l P r o p e r t i es : V i s c o s i t y , cps: 2100 S o l i d s : 6 .8% pH, as i s : 9 .3
Formula 615
A u t o Shampoo Concent ra te
P ngred i e n t s : Water, D . I . Rewoter ic AM KSF-40 W i t c o l a t e SE-5
Wt% 91.67
3.33 5 .00
Wt% 80.0 15 .0
5 . 0
B l e n d i n g Procedure:
each a d d i t i o n .
T y p i c a l P r o p e r t i e s : V i s c o s i t y , cps : 4 . 0 S o l i d s : 9 .0% ptl : 9 . 5
Add i n g r e d i e n t s i n o r d e r shown and d i s s o l ve c o m p l e t e l y between
Formula 628 SOURCE: W i t c o Corp. : Suggested F o r m u l a t i o n s
198 Advanced Cleaning Product Formulations
Touch less V e h i c l e Wash D e t e r a e n t l Z e r o Phosphate, Powder)
So i l -Grease , o i l , s a l t , w a t e r d e p o s i t s , c l a y , p a r t i c u l a t e s ,
S u r f a c e - P a i n t e d me ta l s u r f a c e , P o l y m e r i c A p p l i c a t i o n Method-High p r e s s u r e s p r a y (700-1400 p s i ) Manu fac tu re -Dry B1 end/Aggl o m e r a t i on
r o a d f i l m
Compos i t i on : \nrt36
*Sodium P o l y a c r y l a t e (92% s o l i d s ) 1 . 0 - 3 . 0
Sodium Carbonate 25-30 Metso Beads 2048 20-25
S u r f a c t a n t 5-1 0 T u r b o b r i t e A1 umi n o s i 1 i c a t e 25-35 F i 1 l e r s Ba lance
D i l u t i o n : 1 .0-2.0% by w e i g h t ( 0 . 1 - 0 . 2 p o u n d s / g a l l o n ) Add 0 . 1 - 0 . 2 pounds o f d e t e r g e n t p e r g a l l o n o f w a t e r o u t p u t t o
t h e sp ray n o z z l e . M ix powder d e t e r g e n t i n t a n k and me te r i n t o c a r wash system. M i l d a b r a s i v e c l e a n i n g and p o l i s h i n g e f f e c t o f T u r b o b r i t e i s e x t r e m e l y e f f e c t i v e i n h i g h p r e s s u r e s p r a y wash systems f o r removing o i l and w a t e r d e p o s i t s , p a r t i c u l a t e s o i l s , and haze f r o m body p a r t s and w i n d s h i e l d s .
suspended. Cons tan t a g i t a t i o n i n t a n k i s necessa ry t o keep T u r b o b r i t e
V e h i c l e Wash D e t e r g e n t (Low pH) ( Z e r o Phosphate. Powder)
So i l -Grease , o i l , s a l t , w a t e r d e p o s i t s , c l a y , p a r t i c u l a t e s ,
S u r f a c e - P a i n t e d me ta l s u r f a c e , P o l y m e r i c A p p l i c a t i o n Method-High p r e s s u r e s p r a y (700-1400 p s i ) Manu fac tu re -Dry b l e n d / A g g l o m e r a t i o n
r o a d f i l m .
Composi t i on : Wt% Sodium Carbonate 27.9 B r i t e s i 1 H20 Hydrous Sodi um P o l y s i 1 i c a t e 21 . o *Acusol 445ND Sodi um Pol y a c r y l a t e (92% s o l i ds) 3 . 0 * * L i q u i d N o n i o n i c S u r f a c t a n t 1 2 . 0 V a l f o r 100 Z e o l i t e A 3 6 . 1
Add 0 .125 pounds o f d e t e r g e n t p e r g a l l o n o f w a t e r o u t p u t t o * D i l u t i o n : 1 .5% by w e i g h t (0 .125 p o u n d s / g a l l o n )
t h e s p r a y n o z z l e . D i s s o l v e powder d e t e r g e n t i n t a n k and me te r i n t o c a r wash system. M i l d a b r a s i v e c l e a n i n g and p o l i s h i n g e f f e c t o f V a l f o r 100 i s e x t r e m e l y e f f e c t i v e i n h i g h p r e s s u r e s p r a y wash systems f o r removing o i l and w a t e r d e p o s i t s , p a r t - i c u l a t e s o i l s , and haze f r o m body p a r t s and w i n d s h i e l d s .
Cons tan t a g i t a t i o n i n t a n k i s necessa ry t o keep V a l f o r 100 suspended i n s o l u t i o n . * Rohm & Haas ** Low Foam: Rhone-Poulenc A n t a r o x BL-330 ( 3 moles EO)
H i g h Foam: S h e l l Chemical Neodol 23-6.5 o r Neodol 25-7
SOURCE: PQ Corp . : D e t e r g e n t F o r m u l a t i o n Guide
Car and Truck Wash Compounds 199
Truck/Bus Wash
Components: Burco TME Burcosolv TM Neodol 91-6 TEA 85% Burcene 100 Water
% by Weight 7 5
20 5 2
8a l ance
D i l u t e 50:l t o 1OO:l depending on degree o f s o i l t o be removed
Economy Truck/Bus Wash
Components: Water Burco TME Meodol 1.5 C i t r i c Ac id L i q u i d 50% KOH. 45% Ammonyx LO TEA 85%
% by Weight 76
D i l u t e 20:l t o 50:l depending on degree o f s o i l t o be removed.
SOURCE: B u r l i n g t o n Chemical Co., I n c . : Suggested Formulat ions
Car Shampoo
I ngred i en t s : Zetesol 2056 Lumo WW 75 Zusolat 1008/85 Purton CFD Water
Formula D 1 1 / 1 0
I n g r e d i e n t s : Zusol a t 1008/85 Wachsemul s i on 1864 Isopropanol Water, p r e s e r v a t i v e
Formula D 12/2
% by Wei ah t 15.0 1 0 . 0 3.0 1 . o
7 5 . 0
Car Wash and Wax Shampoo
% by Weiqht 10 .0 1 0 . 0
2 . 0 q . s . t o make 100 .0
SOURCE: Zschimmer & Schwarz GmbH & Co.: Suggested Formulat ions
200 Advanced Cleaniris Product Formulations
V e h i c l e Wash D e t e r g e n t e h o s p h a t e . Powder1
So i l -Grease, o i l , s a l t , water d e p o s i t s , c l a y , p a r t i c u l a t e s ,
S u r f a c e - P a i n t e d meta l s u r f a c e , Po lymer ic A p p l i c a t i o n Method-High p r e s s u r e spray Manufacture-Dry b lend/Agg lomera t ion
r o a d f i l m
Composi t ion A : We9/0 Metso Beads 2048 20 .0 *STPP 4 0 . 0 *TSP 5 . 0 *Sodi um Carbonate 2 0 . 0 **Sodium A 1 k y l a r y l Sul f o n a t e Powder (90%) 5 . 0 * * * L i q u i d N o n i o n i c S u r f a c t a n t (C9-10; 6 Moles EO) 1 0 . 0 Composi t ion 8 : Wt% Metso Pentabead 20 30.0
0 0 0 0 0 0
*STPP 44. *Sodi um Carbonate 1 0 . CMC 1 **Sodium A l k y l a r y l S u l f o n a t e Powder (90%) 5 ****Octy lphenoxy P o l y e t h o x y e t h a n o l , 7-8 Moles EO 5 *****Octy lphenoxy Po lye thoxyethano l , 5 Moles EO 5
Use D i l u t i o n : 1 .5% by w e i g h t (0 .125 pounds/ga l lon) D i s s o l v e i n s t o c k t a n k and meter i n t o wash system. Compos
6 can be u t i l i z e d i n h i g h p r e s s u r e spray carwash systems and s u p p l i e s adequate s o i l remova l . * FMC ** W i t c o *** Rhone-Poulenc Rhodasurf 91-6 **** Rhone-Poulenc I g e p a l CA-620 ***** Rhone-Poulenc I g e p a l CA-520
P i on
V e h i c l e Wash D e t e r g e n t ( L i q u i d , low foam)
So i l -Grease, o i l , s a l t , water d e p o s i t s , c l a y , p a r t i c u l a t e s ,
Sur face-Pa in ted meta l s u r f a c e , Po lymer ic A p p l i c a t i o n Method: H igh p r e s s u r e spray (700-1400 p s i ) Manufacture-Mix t a n k w i t h p r o p e l l e r s t i r r e r
r o a d f i l m
Composi t i on : Wt% Water 79.0 Metso Beads 2048 2 . 0 *Sodium P o l y a c r y l a t e (40%) 5 . 0 **Sodium Xylene S u l f o n a t e (40%) 8 . 0 * * * L i q u i d N o n i o n i c S u r f a c t a n t (C9-C11; 6 Moles EO) 3.0 * * * * L i q u i d N o n i o n i c S u r f a c t a n t (C9-Cl l ; 2 . 5 Moles € 0 ) 3.0
* Rhone-Poulenc C o l l o i d 226/35 (40%) ** Stepan, W i t c o *** Rhone-Poulenc Rhodasur f 91-6 **** Rhone-Poulenc Rhodasurf A-24 SOURCE: PQ Corp . : Detergent F o r m u l a t i o n Guide
Use D i l u t i o n : 10% bw (13 o z / g a l l o n )
Car and Truck Wash Compounds 201
Veh ic le Wash Detergent (Low PH) (Zero Phosphate, L i q u i d )
Soi l-Grease, o i l , s a l t , water depos i ts , c lay , p a r t i c u l a t e s ,
Surface-Painted metal sur face , Polymeric Appl i c a t i on Method-Hi gh pressure spray (700-1400 p s i ) Manufacture-Mix tank w i t h p r o p e l l e r spray
road f i l m
Composi t i on : Wt% Water 51.66 Carbopol 674 0 . 5 D L i q u i d Sodium S i l i c a t e 8 .1 *Acusol 445N Sodi um Po lyac ry l a t e (45% s o l i d s ) 1.84 Sodium Carbonate 9 . 1 Turbobr i t e A1 umi nosi 1 i ca te 24.5 * * L i q u i d Nonionic Sur fac tan t 4.3
D i l u t e l i q u i d de tergent w i t h water ( 1 g a l l o n de tergent : 64 g a l l o n s water ) and d e l i v e r t o h igh pressure spray wash system.
M i l d abras ive c lean ing and p o l i s h i n g e f f e c t o f Tu rbobr i t e i s extremely e f f e c t i v e i n removing o i l , p a r t i c u l a t e s o i l s , water depos i t s , and haze from body p a r t s and w indsh ie ld . * Rohm & Haas ** Low Foam: Rhone-Poulenc Antarox BL-240
High Foam: She l l Chemical Neodol 23-6.5 o r Neodol 25-7
Touchless Veh ic le Wash Boos te r /Add i t i ve LZero Phosphate, L i q u i d )
Soi l-Grease, o i l , s a l t , water depos i ts , c l a y , p a r t i c u l a t e s ,
Surface-Painted metal sur face , Polymeric A p p l i c a t i o n Method-High pressure spray (700-1400 p s i ) Manufacture-Mix tank w i t h p r o p e l l e r s t i r r e r
road f i l m
Composit ion: Wt%
S1 u r r y ) 100.0 T u r b o b r i t e L (25 w t . % a c t i v e Tu rbobr i t e A l u m i n o s i l i c a t e
D i l u t e l i q u i d Tu rbobr i t e L a t h igh pressure pump w i t h water ( 1 g a l l o n de tergent : 128 g a l l o n s water) and d e l i v e r t o h igh pressure spray wash system.
i s extremely e f f e c t i v e i n removing o i l , p a r t i c u l a t e s o i l s ( c lays , carbon b lack , brake d u s t ) , water depos i ts , and haze from body p a r t s and w indsh ie ld .
T u r b o b r i t e L can be used as an a d d i t i v e o r boos ter f o r con- ven t iona l touch less , h i g h pressure carwash o r f lee twash d e t e r - gents.
O r make a de tergent by b lend ing Tu rbobr i t e L w i t h 1-2% low- foaming non ion ic s u r f a c t a n t t o make f o r best c lean ing r e s u l t s . D i l u t e T u r b o b r i t e L / su r fac tan t b lend a t h igh pressure pump w i t h water (128: 1 ) .
i ng produc ts .
SOURCE: PQ Corp. : Detergent Formula t ion Guide
M i l d abras ive c lean ing and p o l i s h i n g e f f e c t o f Tu rbobr i t e
T u r b o b r i t e L a l s o works i n waxes, po l i shes , and o the r d e t a i l -
17. Whitewall Tire Cleaners
202
Whi tena 1 1 Ti.r&C!ean.ey 1 z e r o .P.b-s phate -?.w&cl
Soil-Clay, p a r t i c u l a t e , o i l , grease S u r f a c e - W h i t e w a l 1 t i r e s Application Method-High pressure spray/brush/wipe Manufact tire - Dry b 1 end/Agg 1 omerat i On
Nt% c_q.m3os i t i . on l *Acusol 4 4 5 N D Sodium Polyacrylate ( 9 2 % Solids) 2 . 0 * * L i q u i d N o n i o n i c S u r f a c t a n t (C9-Cll; 6 M o l e s E D ) 8 . 0 Sodium Alkylaryl S u l f o n a t e 1 0 . 0 M e t s o Beads 2048 3 5 . 0
35.0 Valfor 100 Zeolite A
S o d i u m Carbonate 12.0 * Rohm & Haas ** Rhone-Pou 1 enc Rhodasurf 91 -6
wi j. t. ew an -T i. r,e C L Y C ~ e 1: 1 Pbes?batePowde.!’l
Soil-Clay, p a r t i c u l a t e , o i l , g r e a s e Surface-Whi tewal1 t i r e s Application Methods-High p r e s s u r e s p r a y / b r u s h / w i p e M a n u f a c t u r e - D r y b l e n d
Cs-mmeo s. i. t j P.V :. *STPP * * t i q u i d N o n i n n i c S u r f a c t a n t (C9-Cll; 6 nroles € 0 ) GTSP Sodium Alkylaryl Sulfonate Met50 Beads 2048 * FMC * a Rhone-Poulenc Rhodasurf 91 -6
WRitewal..1..Ti re,&!ea_n_er (.Lictuj.d).
Soil-Clay, particulate, o i l , p r e a s e Surface-Whi tewall tires A p p l i c a t i o n Method-High pressur’e spray/brush/wipe Manufacture-Mi x t a n k w i t h propeller s t i r r e r
Comq.~S !.f.bn: Water Potassium H y d r o x i d e 145%) N Clear o r S t a r Sodium Silicate Sodi uni A 1 k y l a r y l Sulfonate (60%) * L i q u i d Nonionic S u r f a c t a n t (CS-Cll; 6 moles E O ) *Rhone-Poul e m R h o d a s u r f 91 -6
S O U R C E : FQ Corp. : D e t e r g e n t F o r m u l a t i o n Guide
Y!t.% 4 5 . 0
5 . 0 1 0 . 0 1 0 . 0 30.0
flL?b 7 0 . 0 1 6 . 0 1 0 . 0
2 . 0 2 . 0
18. Miscellaneous
204
Miscellaneous 205
A i r c r a f t Cleaner (Reduced Phosphate. Powder)
Soi 1 -Par t i cu la tes , carbon b lack , pe t ro leum o i 1 and grease Surface-Aluminum, metal A p p l i c a t i o n Method-High pressure spray (700-1400 p s i ) Manufacture-Dry blend/Agglomerat i on
Composi t i on : Metso Pentabead 20 V a l f o r 100 Z e o l i t e A Ammoni u m B i f 1 uor i de TSPP *Sodi um A1 k y l naphtha1 ene Sul f ona te **Sodium A l k y l a r y l Su l fona te Powder (90%)
Use D i l u t i o n : 1.5-6.096 bw (2-8 oz /ga l l on )
* Rhone-Poulenc Suprag i l N K ** Witco
Note: Constant a g i t a t i o n i s requ i red i n s tock tank t o keep V a l f o r 100 suspended i n s o l u t i o n . May use 0.25% w t Carbopol 647 (BFGoodrich) as a suspending agent.
Wt% 3 0 . 0 30 .0 8.0
20.0 8.0 4 . 0
A i r c r a f t 61 eaner (Phosphate, Powder)
S o i l - P a r t i c u l a t e s , carbon b lack , pe t ro leum o i l and grease Surface-Metal A p p l i c a t i o n Method-High pressure spray (700-1400 p s i ) Manufacture-Dry b l end/Aggl omerati on
Composi t i on : Metso Pentabead 20 *STPP Ammonium B i f l u o r i d e *TSPP **Sodium A1 kylnaphthalene Su l fonate ***Sodi um A1 k y l a r y l Sul fonate Powder (90%)
Use D i l u t i o n : 1.5-6.0% bw (2-8 oz /ga l l on )
* FMC ** DeSoto, I n c . *%Xc Witco
OURCE: PQ Corp . : Detergent Formula t ion Guide
Wt% 3 0 . 0 3 0 . 0 8.0
20.0 8 . 0 4 .0
206 Advanced Cleaning Product Formulations
Auto Care: I n t e r i o r / E x t e r i o r Rubber B V i n y l P ro tec tan t
Funct i ons 8 Benef i t s : Pemul an 1622 :
*Primary e m u l s i f i e r f o r s i l i c o n e o i l *NO s u r f a c t a n t s and no so l ven ts r e q u i r e d equals zero VOC * Impar ts y i e l d va lue f o r v e r t i c a l c l i n g *Exce l l en t w e t t i n g f o r "spray and no-wipe" a p p l i c a t i o n s *Improved d u r a b i l i t y and water-res stance
Good-Rite K-752: *Reduction i n emu1 s i on v i s c o s i t y w
I n q r e d i en t : D I water Pemulen 1622* 1000 cSt s i l i c o n e o i l * *
T r ie thano lamine (99%) Good-Rite K-752 (63%)****
DC Q2-5211***
* E m u l s i f i e r : BFGoodrich
t h o u t l o s s i n s t a b i l i t y
Wtl 78.55 0.20
20.00 0.50 0.25 0.50
* *Pro tec tan t : DC 200 F l u i d : Dow Corning ***Super-wett ing agent: DC (12-5211: Dow Corning
* * * *V iscos i t y reduc t i on : BFGoodrich
Phys ica l P roper t i es : B r o o k f i e l d RVT v i s c o s i t y - 2 0 rpm: 150 CP Product pH: 5.5-6.0 Product C l a r i t y : Opaque
Procedure: 1 . Using moderate a g i t a t i o n (800 rpm) prov ided by a L i g h t n i n '
M ixer o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e f o r general m ix ing and b lend ing opera t ions , d i spe rse o r screen t h e Pemulen r e s i n i n t o t h e D I water. Mix t h e s l u r r y f o r app- rox ima te l y 15 minutes o r u n t i l t h e s l u r r y i s homogeneous.
2. Add t h e s i l i c o n e f l u i d w i t h good a g i t a t i o n . 3. Add t h e DC Q2-5211 super -wet t ing agent w i t h moderate a g i t a t i o n 4. Add t h e t r i e thano lamine w i t h moderate a g i t a t i o n . 5 . Reduce a g i t a t i o n and add t h e Good-Rite K-752 polymer. The
v i s c o s i t y w i l l d rop from about 3,000 CP t o <200 CP w i t h t h i s a d d i t i o n .
6. Adjus t t h e pH w i t h a d d i t i o n a l t r i e thano lamine , i f necessary. 7 . Add f rag rance and c o l o r , as des i red .
SOURCE: BFGoodrich S p e c i a l t y Chemicals: DET-512
Miscellaneous 207
Boat Polish
I n a d d i t i o n t o th icken ing , Carbopol r e s i n s impar t y i e l d va lue a l l o w i n g p a r t i c l e s , such as abrasives, t o become permanently suspended. The r e s i n a l s o prevents "creaming" o r phase separ- a t i o n by suspending and separa t ing t h e o i l d r o p l e t s .
I nq red i en t : #I Water Carbopol EZ-2 ( 1 ) Morphol i ne SF96 S i l i c o n e F l u i d (350) ( 2 ) V i s c a s i l F l u i d (10,000) ( 2 ) O l e i c Ac id Minera l S p i r i t s Hoechst Wax E (3) Mineral Spi r i t s SF1 706 React i ve Ami ne Polymer Kaopo l i t e k a o l i n c l a y ( 4 )
Wt% 37.80
0.20 2.50 2.00 1.50 2 .50
10.00 6.00 5.00 1.50 8 . 5 0
Physical P roper t i es : Brookf i e l d V i scosi t y (RVT-20 rpm) : 7,200 cps Product pH: 9.00 Product C l a r i t y : Opaque
Raw M a t e r i a l Supp l ie rs : (1 ) BFGoodrich (2 ) General E l e c t r i c ( 3 ) Hoechst Celanese ( 4 ) Kaopo l i te , I n c .
Procedure: 4 . Disperse t h e Carbopol i n t o t h e water by s imp ly "dumping" i t
2. Add t h e morpholine, mix w i t h good a g i t a t i o n . Heat t o 60-65C. 3 . I n a separate vessel , combine t h e s i l i c o n e f l u i d , V i s c a s i l ,
o l e i c ac id , and t h e wax i n t h e minera l s p i r i t s . Heat t o 90-95C u n t i l t h e wax me l t s and t h e m ix tu re appears homogeneous. Add to t h e above m ix tu re w i t h good mix ing .
r e a c t i v e amine polymer. Add t o t h e above m ix tu re w i t h h igh shear mix ing .
i n . The polymer w i l l wet ou t i n a few minutes.
4 . When homogeneous, coo l t o 60-65C. 5. I n a separate vessel , combine t h e minera l s p i t i t s and t h e
6. S lowly add i n t h e c l a y . Mix u n t i l homogeneous.
To ta l Ac t i ves : To ta l Wax : 1.50 To ta l S i l i c o n e F l u i d : 4.50 React i ve Ami ne Polymer : 2.00 Minera l S p i r i t s : 13.00 Abrasive: 12.00
$ ~ ~ ~ ~ ~ : BFGoodrich Spec ia l t y Chemicals: DET-520
208 Advanced Cleaning Product Formulations
Concrete Cleaner/Deqreaser
I n g r e d i en ts : Water, D . I . Sodium Tr ipo lyphosphate T r i sodi um Phosphate Varami de A-83 Varonic DM55
WtB 81 . O
2.0 1 . o 6 . 0
1 0 . 0
B lend ing Procedure:
each addi t i on.
Typ ica l P r o p e r t i es : V i s c o s i t y , cps: 0 S o l i d s : 19.0%
Formula 937
Add i n g r e d i e n t s i n order shown and d i s s o l v e completely between
Garage F loo r C1 eaner
I n s r e d i en ts : Water T r i sodi um Phosphate Emphos PS-236 Witconate 45 L i q u i d
Wt% 8 2 . 0
8 . 0 4 . 0 6 . 0
Blend ing Procedure:
b lend ing between a d d i t i o n s . Formula 941
Blend i n g r e d i e n t s i n the order l i s t e d . A l low f o r complete
Ac id Rust Remover
I n q r e d i en ts : Water, D . I . Phosphoric Ac id , 86% C i t r i c Ac id Varox 365
\Me% 81 . O 15 .0
3 . 0 1 . o
B lend ing Procedure:
each a d d i t i o n .
T y p i c a l Proper t i es :
Add i n g r e d i e n t s i n o rder shown and d i s s o l v e completely between
V i s c o s i t y , cps: 4 S o l i d s : 16.2% pH: 1.3
Formula 1116
SOURCE: Witco Corp.: Suggested Formulat ions
Miscellaneous 209
Concrete/Dr iveway C l e a n e r s
F o r l e a f and o t h e r t a n n i n s t a i n s - use as i s . Wet s p o t . S p r i n k l e FB Sodium Perca rbona te o n t o s p o t . Scrub i n and r i n s e w i t h hose when s p o t i s removed.
For O t h e r S t a i n s
Component: Soda Ash (Dense) B r i t e s i 1 H-24 TSP Anhydrous Burcosperse AP Powder Dry S u r f a c t a n t * FB-Sodi um Perca rbona te
Wt% 25 15 20
5 5
30
Wet s p o t . S p r i n k l e c l e a n e r o n t o a r e a . Scrub i n and a l l o w t o
*Sodium L a u r y l S u l f a t e , Sodium Dodecylbenzene S u l f o n a t e o r s t a n d . R i n s e w i t h hose.
Sodium Cocoyl T a u r a t e s can be used.
SOURCE: B u r l i n g t o n Chemical Co . : Suggested F o r m u l a t i o n
Neavv Duty C o n c r e t e C l e a n e r (Phosphate F ree )
Water, D . I . EDTA, 38% Sodium Metas i l i c a t e , P e n t a h y d r a t e Sodium Carbonate (Soda Ash) W i t cami de S-780 W i t c o n o l NP-120 B u t y l Cel l o s o l v e M i n e r a l S p i r i t s KOH, 45% W i t c o n a t e SXS L i q u i d P i n e O i l
Formula 1C
Wt% 75.0
0 . 5 2 . 0 1 .5 6 .5 1 . 5 3 . 0 4 .0 2 . 5 1 . 5 2 . 0
B l e n d i n g P rocedure :
a d d i t i o n .
T y p i c a l P r o p e r t i e s :
B lend i n g r e d i e n t s i n o r d e r l i s t e d , m i x i n g w e l l a f t e r each
S p e c i f i c G r a v i t y : 1 .022 Wt . /Ga l . I b s . : 8 . 5 2 pH, as i s : 13.18 3 Freeze/Thaw C y c l e s : Passed 1 Week @ 52C: Passed 4 Weeks Room Temp: Passed S o l i d s : 13.5%
Use D i l u t i o n : As s t r o n g as needed, depending on t y p e o f s o i l .
SOURCE: W i t c o C o r p . : Formula 949
210 Advanced Cleaning Product Formulations
__ Vinyl Dressing
I ng r e d i & P a r t A : M a s i l EM 250 C Dei o n i zed Water
P a r t 8 : Macol NP 9 . 5 G1 y c e r i ne D e i o n i z e d Water Sodium Benzoate
~- W t %
3 0 . 0 3 0 . 0
1 . 5 1 . 5
3 6 . 9 0 . 1
Procedure: 1 . To a m i x i n g v e s s e l , cha rge t h e M a s i l EM 250 C and s t a r t
g e n t l e a g i t a t i o n . S l o w l y add t h e w a t e r so as n o t t o b reak t h e emu1 s i on.
g l y c e r i n e t o t h e w a t e r . M i x w i t h g e n t l e a g i t a t i o n u n t i l a l l components a r e d i s s o l v e d , and t h e s o l u t i o n i s f r e e o f " f i s h eyes " . Charge t h e sodium benzoate and m i x u n t i l d i s s o l v e d .
m i x i n g g e n t l y t o a v o i d a i r en t rapmen t . NOTE: T h i s f o r m u l a i s des igned t o be used "as i s " as a d r e s s i n g f o r r u b b e r and v i n y l p r o d u c t s . I f d e s i r e d , UV abso rbe rs and o t h e r components may be added t o t h e f o r m u l a t i o n . F o r m u l a t i o n SV-101
2 . I n a s e p a r a t e m i x i n g v e s s e l , cha rge t h e Macol NP 9 .5 and
3 . Under g e n t l e a g i t a t i o n , cha rge P a r t B t o P a r t A . C o n t i n u e
I n q r e d i e n t : M a s i l EM 10,000 C M a s i l EM 250 C Macol NP 9 . 5 G l y c e r i n e Barquat MB-50 Water
&% 10 .0 18 .0
2 . 0 1 . 5 0 . 1
6 8 . 4
Procedure: Add t h e s i l i c o n e emu ls ion t o a b l e n d e r . S l o w l y add a p o r t i o n
o f t h e w a t e r and a g i t a t e . Add t h e Macol NP 9 . 5 and g l y c e r i n e . M ix f o r 10 m i n u t e s . Add t h e ba lance o f t h e w a t e r and mix f o r 15 m i n u t e s .
SOURCE: PPG I n d u s t r i e s , I n c . : Suggested F o r m u l a t i o n s
Section Ill demarked Raw Materials
211
21 2 Advanced Cleaning Product Formulations
RAW MATERIAL CHEMICAL DESCRIPTION A-C 617A P o l y e t h y l e n e
A c i d Th ickener C a t i o n i c s u r f a c t a n t
A c r y s o l AS€-108 P o l y a c r y l a t e (40%)
A c t i n o l FA-I T a l l o i l f a t t y a c i d
Acusol 445ND Sodium p o l y a c r y l a t e (92% s o l i d s )
Acusol 479ND Sodium p o l y a c r y l a t e
Adogen 66 A n t i - s t a t i c agent
A1 i p a l CO-128 A n i o n i c s u r f a c t a n t
A1 i p a l CO-436 A n i o n i c s u r f a c t a n t
A l k y l a r y l S u l f o n i c A c i d (98%)
Alpha-Step MC-48 Alpha s u l f o methy l e s t e r
A 1 pha-Step ML-40 Alpha s u l f o methy l e s t e r (37%)
Ammonyx LO Amine o x i d e
AMP-95 A m i nomethyl p ropano l
Amphotensid 84 Amphoter ic s u r f a c t a n t
Amphoteri c SC Amphoter ic (35% a c t i v e )
Amphoter ic TC Hydro t rope
Antaron FC-34 Amphoter ic s u r f a c t a n t
c s u r f a c t a n t
c s u r f a c t a n t
Antarox BL-240 L i q u i d non ion
Antarox BL-330 L i q u i d non ion
Antarox LF-330 S u r f a c t a n t
Aquamoll i n BC Powder
A r i s t o n a t e M
A r i s t o n a t e M-LF
Aromat ic 150
Pet ro leum s u l f o n a t e (61%)
Pet ro leum s u l f o n a t e
Sol v e n t
SOURCE A l l i e d
Tomah
Rohm&
A r i zon
Rohm&
RohmB
W i t c o
Rho ne -
Rhone-
W i t c o
Stepan
Stepan
Stepan
Angus
Zschim
Tomah
Tomah
Rhone-
Rhone-
Rhone-
Rhone-
P i l o t
P i l o t
Exxon
Trademarked Raw Materials 213
RAW MATERIAL Autopoon GK4004
Autopoon GK4008
Autopur WK4332
Avanel S-30
Avanel S-70
Avanel S-74
B i o te rge
B i o te rge
83-120 b
B r i j 96
B r i t e s i 1
B r i t e s i I
B r i t e s i 1
5;mr lOX 12
Barquat NIB-50
BiQSOft D-62
B i o s o f t s-100
AS-40
PAS-8S
CHEMICAL DESCRIPTION SOURCE Blend o f s u r f a c t a n t s Zschim
Blend o f s u r f a c t a n t s Zschim
Blend o f s u r f a c t a n t s Zschim
An ion ic s u r f a c t a n t PPGMaz
Sodium l i n e a r a l k y l po l ye the r PPGMaz
An ion ic s u r f a c t a n t PPGMaz
q u i d Sodi um S i 1 i ca te
Sur fac tan t
c20 Hydrous sodium p o l y s
H20 Hydrous sodium po lys
H24 Hydrous sodium p o l y s
Burcene I00
Burco BSGH-270
Burco WCS-SONF
Amine ox ide (30%) Lonza
Quaternary ammonium compound Lonza
Sodium a l k y l benzene sul fonate(60%) Stepan
Alkylbenzene s u l f o n i c ac id , l i n e a r Stepan
Sodium o l e f i n s u l f o n a t e (40%) Stepan
Pr imary alkane s u l f o n a t e (40%) Stepan
PO
ICI
1 i c a t e PQ
1 i c a t e PQ
1 i c a t e PQ
Bur l i n
P r o p r i e t a r y t e x t i l e a u x i l i a r y Bur l i n
P r o p r i e t a r y t e x t i l e a u x i l i a r y Bur l i n
NPS-225 P r o p r i e t a r y t e x t i l e a u x i l i a r y B u r l i n
NPS-816 P r o p r i e t a r y t e x t i l e a u x i l i a r y Bur l i n
SZS P r o p r i e t a r y t e x t i l e a u x i l i a r y Bur l i n
LAF-6 P r o p r i e t a r y t e x t i l e a u x i l i a r y Bur l i n
21 4 Advanced Cleaning Product Formulations
RAW MATERIAL B u r c o l 117
B u r c o l i t e BSGH-255
B u r c o s o l v TM
Burcosperse AP Powder
Burcosperse LP
Burcosperse SP-60
Burco tase LL-100
Burco tase EP-60
Burco tase SL-160
B u r c o t e r g e DG-40
Burco TME
B u r c o t r o p e 1250
B u r c o w h i t e BBH-20
Burdac-114
B u t y l C a r b i t o 1
B u t y l C e l l o s o l v e
Calamide C
Calamide CW-100
Calamide CWT
Calamide SM
C a l f a x DB-45
Cal f a x 1 OL-45
Cal foam EA-603
CHEMICAL DESCRIPTION P r o p r i e t a r y t e x t i l e a u x i l i a r y
Water s o l u b l e s o l v e n t m i x t u r e
Sodi um p o l y a c r y l a t e
Sodium p o l y a c r y l a t e s o l u t i o n
Sodium p o l y a c r y l a t e
P r o p r i e t a r y d e t e r g e n t enzyme
P r o p r i e t a r y d e t e r g e n t enzyme
P r o p r i e t a r y d e t e r g e n t enzyme
D e t e r g e n t c o n c e n t r a t e
P r o p r i e t a r y t e x t i l e a u x i l i a r y
SOURCE B u r l i n
B u r l i n
B u r l i n
B u r l i n
B u r l i n
B u r l i n
B u r l i n
B u r l i n
B u r l i n
B u r l i n
B u r l i n
B u r l i n
B u r l i n
I n d u s t r i a1 s o l v e n t UnCarb
E t h y l e n e g l y c o l monobuty l e t h e r UnCarb
Coconut d e r i ved ami de P i l o t
Coconut d i e t h a n o l a m i d e 100% P i l o t
Super ami de P i l o t
Non-DEA 1 i q u i d ami de P i l o t
Sodium a l k y l (b ranched) d i p h e n y l Mona o x i d e d i s u l f o n a t e 45%
Sodi um a1 k y l ( 1 i n e a r ) d i pheny l Mona o x i d e d i s u l f o n a t e 45%
L i q u i d d e t e r g e n t P i l o t
Trademarked Raw Materials 215
RAW MATERIAL Cal foam ES-303
Cal foam SLS-30
Gal i mu1 se PRS
Ca loxy la te M - 9
C a l s o f t F-90
C a l s o f t L-40
C a l s o f t L-60
Cal s o f t LAS-99
C a l s o f t T-60
Calsuds A
Calsuds CD-6
Calsuds 81
Carbi t o 1
Carbopol
Carbopol
Carbopo 1
Ca rbopo l
Ca rbopo 1
Carbopol
Carbopol
Carbopol
Ca rbopol
So lvent
672
674
676
69 1
934
940
941
ETD 2623
ETD 2691
CHEMICAL DESCRIPTION SOURCE Sodium l a u r y l e the r s u l f a t e (30%) P i l o t
Sodium l a u r y l s u l f a t e 30% P i l o t
Emu1 s i f i e r P i l o t
Nonyl phenol e t h o x y l a t e ( 9 Mole EO) P i l o t
P i l o t
P i l o t
P i l o t
L inear a1 k y l a t e s u l fonate
Sodi um 1 i near a1 k y l benzene s u l f ona te 1 i q u i d 40%
Sodi um 1 i near a1 k y l benzene s u l f o n a t e pas te 60%
L inear a1 k y l benzene s u l f on a c i d 99%
TEA l i n e a r a l k y l benzene su 60%
C P i l o t
f ona te P i l o t
Conc. b lend o f a n i o n i c de tergents P i l o t and amides
M o d i f i e d coconut diethanolamidelOO% P i l o t
Conc. b lend o f a n i o n i c de tergents P i l o t and amides
I n d u s t r i a l so l ven t UnCarb
Th icken ing agent BFGood
Thickening agent BFGood
Thickening agent BFGood
Suspension a i d BFGood
Thickening agent BFGood
Thickening agent BFGood
Thickening agent BFGood
Resin v i scosi t y m o d i f i e r BFGood
Resin v i s c o s i t y m o d i f i e r BFGood
216 Advanced Cleaning Product Formulations
RAW MATERIALS Carbopol EX-473 (30%)
Carbopol EZ-2
Card is 36 Wax
CDB Clearon
C o l l o i d 225/35
Col 1 o i d 226/35
Contraspum 300
Cublen D50
CHEMICAL DESCRIPTION V i scosi t y modi f i e r
V i scosi t y modi f i e r
Oxidized m i c r o c r y s t a l l i n e wax
Ch lor ina ted i socyanurate
Po lyac ry la te (40%)
Po lyac ry la te (40%)
G lyco l e ther defoamer
DC (22-5211
Decanol
Dequest 2000
DeSonic LFD-97
DeSonic 5N
DeSonic 9N
DeSonic 11N
DeSonic 81-6
DeSophos 5AP
Diatomaceous Ear th
D L i q u i d Sodium S i l i c a t e
Dipropylene Glyco l Monoethyl Ether Solvent
Super-wett ing agent
Organophosphorous product
Nonionic s u r f a c t a n t
Nonioni c s u r f a c t a n t
Detergent/degreaser
Nonionic s u r f a c t a n t
Nonionic s u r f a c t a n t
Phosphate es te r
Dodigen 226
Dowanol DPM Glyco l e ther
Dowanol DPnB Glyco l e ther
SOURCE: BF600d
BFGood
P e t r o l
01 i n
RAOPa@
Rhone
Zschi e
DowCor
I\iiCN7san
DeSoto
DeSoto
DeSoto
DeSoto
DeSoto
DeSoto
Kaopol
PQCorp
Dow or Arc0
D o w
Bow
Trademarked Raw Materials 21 7
RAW MATERIAL CHEMICAL DESCRIPTION Dowanol EB E t h y l e n e g l y c o l n - b u t y l e t h e r
Dowanol PM Propy lene g l y c o l methy
Dowanol PnB G l y c o l e t h e r
Dowanol TBA G l y c o l e t h e r
Dowanol TPM T r i p r o p y l e n e g l y c o l me
Dow C o r n i n g 20 Release C o a t i n g
e t h e r
Dowfax 382 Sodi um n -decy l d i pheny lox d i s u l f o n a t e (45%)
Dow ic ide A Sodium o-Phenylphenate
Dow 200 S i l i c o n e F l u i d (1000 c S t )
e t h e r
de
Dowfax 2A1 Sodi um dodecy l d i p h e n y l o x i de d i s u l f o n a t e (45%)
Dowfax 382 A n i o n i c s u r f a c t a n t
D r e s i n a t e 91 Ros in soap
E L i q u i d Sodium
Emcol 4500
Emcol 6744
Emersol 213
Emphos PS-236
Emphos PS-331
Emphos 5AP
E m u l s i f i e r Four
S i l i c a t e
W e t t i n g agent
S u r f a c e - a c t i v e agen t
O l e i c a c i d
Phosphate e s t e r s u r f a c t a n t
Phosphate e s t e r s u r f a c t a n t
Phosphate e s t e r s u r f a c t a n t
HF D i a1 k y l q u a t e r n a r y (75% a c t i v e )
SOURCE Dow
Dow
Dow
Dow
Dow
DowCor
Dow
Dow
DowCor
Dow
Dow
H e r c u l
PQ
W i t c o
W i t c o
Henkel
W i t c o
W i t c o
W i t c o
Tomah
Emul s i f i e r 827 M ixed d i a l k y l q u a t e r n a r y (75% a c t ) Tomah
Emul s i o n C340 Tomah
Epsom S a l t PQ
218 Advanced Cleaning Product Formulations
RAW MATERIAL CHEMICAL DESCRIPTION SOURCE Ethylene G lyco l n-Butyl Ether Solvent Dow or Union @arb
Euperlan PK-771 Pear l i z i ng agent (47%) Henkel
Foam Booster 14 Def oamer Tornah
Gafac RE-40 An ion ic s u r f a c t a n t
Gafamide CDD 518 Ethanolamide
Genagen LAB C12C14 a l k y l d i m e t h y l b e t a i n e
Genapol OA-80 Alcohol e thoxy la te
Genapol UD-030 C11 0x0 ethoxy a t e ( 3 moles EO)
Genapol UD-080 A lcoho l ethoxy a t e
Genapol ZRO l i q u i d A l k y l t r i g l y c o l e the r s u l f a t e so ln
Genapol 2908 A lcoho l e t h o x y l a t e
Georgia Marble White #8 ca lc ium carbonate
Gluconic Ac id S o l u t i o n (50%)
G1 ucopon 425CS C8-16 a l k y l po l yg l ycos ide (50%)
G lyco l E ther DPM
G lyco l E ther PM
Good-Ri t e K-752 V i s c o s i t y reducer
Good-Rite K-7058 5800 MW p o l y a c r y l i c a c i d
GP-RA-159 S i 1 i cone Pol i sh A d d i t i v e
GP-121 S i l i c o n e P o l i s h A d d i t i v e
GP-227 S i l i c o n e Sur fac tan t S o l u t i o n
Rhone
Rhone
Hoechs
Hoechs
H Q ~ C ~ S
Hoechs
Hoechs
Hoechs
GaMarb
Ashlan
Henkel
BFGood
BFGood
Genes
Genes
Genes
Trademarked Raw Materials 219
RAW MATERIAL H-7892 d-Limonene
Hampene 100
Hexyl C a r b i t o 1
H i t e c E-515
Hoe S3924
Hoechst Wax E
Hoechst Wax S
Hostapur 0s L i q u i d
Hostapur SAS6O
Hyamine 1 O X
Hypure N
Igepa l CA-520
Igepa l CA-620
Pgepal CA-630
Igepa l CA-720
Igepa l CO-430
Igepa l CO-530
Igepa l 60-630
Pndopol H-100
I n h i b i t o r 4000
Isopar K
I sopar M
CHEMICAL DESCRIPTION
Tet rasod i um EDTA
I ndust r i a1 s o l vent
Wax
Wax
Secondary a lkane s u l f o n a t e
Quaternary ammonium compound
Secondary h y p o c h l o r i t e , 10% s o l n
SOURCE A r y l es
Grace
UnCarb
E t h y l
Hoechs
Hoechs
Hoechs
Hoechs
Hoechs
Lonza
Octylphenoxy po lye thoxyethano l .5 EO Rhone-
Octylphenoxy po lye thoxyethano l ,8 EO Rhone-
Octylphenoxy polyethoxyethano1,g EO Rhone-
Octylphenoxy po lye thoxyethano l , Rhone- 12-13 moles EO
Nonionic e thoxy la te s u r f a c t a n t Rhone-
A1 koxy l a ted 1 i near a1 coho1 Rhone- non ion i c s u r f a c t a n t (low foam)
Nonylphenoxy po lye thoxyethano l , Rhone- 9-10 moles €0
Viscous polybutene Amoco
A1 kanolami ne b o r a t e
I s o p a r a f f i n so l ven t
Zschim
Exxon
I s o p a r a f f i n so l ven t Exxon
220 Advanced Cleaning Product Formulations
RAW MATERIAL CHEMICAL DESCRIPTION Kaopol i t e K a o l i n c l a y
K a o p o l i t e SF Anhydrous a lum i num s i 1 i c a t e
Kaopol i t e 11 52 Anhydrous aluminum s i 1 i c a t e
K a s i l #1 P o t a s s i um s i 1 i c a t e
K a s i l #6 P o t a s s i um s i 1 i c a t e
Kathon CG F u n g i c i d e ( b i o c i d e )
Kel zan Xan
Kerr-McGee M i n e r a l Seal O i
Komperlan KD
L a r o s t a t 88 Ant
han gum
s t a t
L a r o s t a t 264A A n t i s t a t
L a r o s t a t 519 A n t i s t a t
Laundry A d d i t i v e LA-5
Lonzabac-1230
Lumo WW 75
Lumorol 4154 S u r f a c t a n t b l e n d
Lumorol 4192 S u r f a c t a n t b l e n d
L y t r o n 295 O p a c i f i e r . P o l y s t y r e n e emu ls ion
Macol NP 9 . 5 & NP-11 & P o l y o x y e t h y l e n e f a t t y e t h e r OPlOSP & TD-3 & TD-12 & 2LF & 48 & 5100
Mafo CSB Amphoter ic s u r f a c t a n t
Mafo 13 MOD 1 Amphoter ic s u r f a c t a n t
SOURCE Kaopol
Kaopol
Kaopol
PQ
PQ
Rohrn&
Kel co
K e r r -
PPGMaz
PPGMaz
PPGMaz
Tomah
Lonza
Zschim
Zschirn
Zschim
Mor ton
PPGMaz
PPGMaz
PPGMaz
Trademarked Raw Materials 221
RAW MATERIAL CHEMICAL DESCRIPTION Makon 10 A l k y l phenol e the r
Makon 12 A lky? pheno7 e the r
Maphos 58 Phosphate e s t e r
Maphos 60A Phosphate es te r
Maphos 8135 Phosphate es te r
Mas i l EM250C & S i l i c o n e f l u i d s EM10,OOOC & SF-10 & SF-100 & SF-1,000 & 123
Mas l i p 500 & 501A & Syn the t i c l u b r i c a n t a d d i t i v e s 501 Base
Mazamide SS-10 & 65 & Spec ia l t y alkanolamides 80 & 1281
Mazawet 77 Sur fac tan t
Mazon R I 4A & R I 6 & Spec ia l t y p r o p r i e t a r i e s RI 8A & R I 88 & 98
Mazox LDA F a t t y amine ox ide
Mazu DF 210 SX Def oamer
Medialan KA Conc.
Metso Beads 2048 Anhydrous sodium m e t a s i l i c a t e
Metso Pentabead 20 Sodium m e t a s i l i c a t e pentahydrate
M i rano l CPM-SF Conc. D i sodi um cocoamphodi p rop i onate
Mi rano l JEM Conc.(34%) Sodium mixed C8-amphocarboxylate
Monacor BE Corrosion i n h i b i t o r
Monacor 4000 Corrosion i nh i b i t o r
Monalube 110 & 205 & Syn the t i c l u b r i c a n t s 210 & 215 & 220 & 225 & 310 & 315 & 320 & 325 Ik 605 & 610
Monamid 150-ADD Cocamide DEA
SOURCE Stepan
Stepan
PPGMaz
PPGMaz
PPGMaz
PPGMaz
PPGMaz
PPGMaz
PPGMaz
PPGMaz
PPGMaz
PPGMaz
PQ
PQ
Rhone-
Rhone-
Mona
Mona
Mona
Mona
222 Advanced Cleaning Product Formulations
RAW MATERIAL Monamine CF-100M &
1-76
Monamulse dL-1273
Mona NF-10 & NF-20
Monamulse TRP & 653-83D
Monaquat I S I E S
Monayuat TG
M o n a s i l PCA
Monaterge ALX-100s
Monaterge 779
Mona te r i c CM-36s
M o n a t e r i c CyNa-50
M o n a t e r i c EH
Monat rope 1250
M-Pyro l
M u l s i f a n K326 S p e z i a l
M u l s i f a n RTI
Nacconol 9 0 G
CHEMICAL DESCRIPTION SOURCE 2 : 1 f a t t y a1 kanolamides Mona
P r o p r i e t a r y emu1 s i f i e r / s o l u b i 1 i z e r s Mona
S u r f a c t a n t s
L i q u i d e m u l s i f i e r and s o l u b i l i z e r
I s o s t e a r y l e t h y l d i m o n i urn e t h o - s u l f a t e
Qua te rna ry p h o s p h o l i p i d compound
Cocami de DEA & DEA-Dodecyl benzene- s u l f o n a t e & d i e t h a n o l a m i n e
DEA-Laureth s u l f a t e
Sodium cocoamphoacetate
1 -Hydroxye thy l ene -2 -cap ry l i m i d - a z o l i fie ( 5 0 % a c t i ve)
M i I d ampho te r i c d e t e r g e n t / e m u l - s i f i e r
n - M e t h y l - 2 - p y r r o l i d o n e
E m u l s i f i e r f o r s o l v e n t s
F a t t y a c i d e t h o x y l a t e . E m u l s i f i e r .
L i n e a r a l k y l b e n z e n e s u l f o n a t e ( L A S )
N C l e a r Sodium S i l i c a t e Sodium m e t a s i l i c a t e
Nekal WT-27 A n i o n i c w e t t i n g agent
Mona
Mona
Mona
Mona
Mona
Mona
Mona
Mona
Mona
Mona
Mona
I S P
Zschim
Zschim
Stepan
PQ
Rhone-
Neodol 1 . 5 E t h o x y l a t e . L i n e a r p r i m a r y a l c o h o l S h e l l
Trademarked Raw Materials 223
RAW MATERIAL Neodol 23-6.5
Neodol 25-3
Neodol 25-7
Neodol 25-12
Neodol 91-6
N ino l 11-CWI
N ino l 30-LL
N ino l 40-CO
CHEMICAL DESCRIPTION C12-13 l i n e a r a l coho l .6 .5 moles EO
Cf2-15 l i n e a r a l coho l .3 moles EO
C12-15 l i n e a r a l coho l .7 moles EO
L inear p r imary a l coho l
L inear p r imary a l c o h o l . E thoxy la te
Coconut diethanolamide, mod i f i ed
A1 ky lo lamide
Cocamide DEA
P a r o i l 160 Chlor
Pemulen 1622 Resin
Pe t ro BW L i q u d & BAF Anion L i q u i d & BAF Powder & LBA L i q u i d & LBA Powder & ULF L i q u i d & 22 Powder
na ted p a r a f f i n
c s u r f a c t a n t / d
SOURCE Shel 1
Shel 1
Shel 1
Shel 1
Shel 1
Stepan
Stepan
Stepan
spersant
Dover
BFGood
DeSoto
Phosfe ta l 201
Phosphol i p i d EFA
P i l o t SXS-40
Plu ra fac C-17
P lu ra fac 0-25
Po ly te rgen t S-305LF
PQ Epsom S a l t
P r i f a c 2922
Produkt 2058
Propeta l 99
Phosphoric a c i d e s t e r Zschi m
L i ndeamidopropyl PE-Dimoni um Mona c h l o r i d e phosphate
Sodi um xy lene s u l f ona te 40% P i l o t
A1 koxy l a ted f a t t y a1 coho1 BAS F
L inear a l coho l e thoxy la te . MW:930 BASF
A lkoxy la ted l i n e a r a l coho l non ion i c O l i n s u r f a c t a n t ( l ow foam)
PQ
Laur i c a c i d Uni che
F a t t y a l coho l f a t t y a c i d e s t e r Zschi m
A1 k y l p o l y a l ky lene g l y c o l e the r Zschi m
224 Advanced Cleaning Product Formulations
RAW MATERIAL Propetal 241
Propetal 281
Purton CFD
PVP K-15
Renex 20
Rewoteric AM 8-14
Rewoteric AM B-15 & AM DML 35 & AM HC & AM KSF 40 & AM TEG & AMV
Rhodafac RA-600
Rhodafac RE-600
Rhodafac RE-61 0
Rhodasurf A-24
Rhodasurf LA-7
Rhodasurf LA-9
Rhodasurf LA-12
Rhodasurf 91 -6
Rhodaterge SMC
Rhodopol 23
Rhodopol 50MD
R i chami de 5725
CHEMICAL DESCRIPTION A1 k y l p o l y a l ky lene g l y c o l e the r
A1 k y l p o l y a l ky lene g l y c o l e ther
F a t t y a c i d alkanolamide
Po lyv iny lpy r ro l i done polymer
Sur fac tan t
Grease c u t t e r & foam booster
Su r fac tan ts
L inear a lcoho l e thoxy la te
Phosphate es te r
Phosphate es te r
L i q u i d non ion ic su r fac tan t . 2.5 moles EO
L i q u i d non ion ic s u r f a c t a n t . 7-9 moles EO
L i q u i d non ion ic s u r f a c t a n t . 9 moles EO
L i q u i d non ion ic s u r f a c t a n t . 12 moles EO
L i q u i d non ion ic s u r f a c t a n t . 6 moles EO
Cleaner concent ra te
Xanthan gum
Xanthan gum
RU L i q u i d Sodium S i l i c a t e co r ros ion i n h i b i t o r
SOURCE Zschirn
Eschirn
Zschi m
Rhone-
ICI
Wi t c o
w i eco
RhOne-
RhOn@-
Rhone-
Rhone-
Rhone-
Rhone-
Rhone-
Rhone-
Rhone-
Rhone-
Richar
PO
Trademarked Raw Materials 225
RAW MATERIAL CHEMICAL DESCRIPTION SOURCE SF96 S i l i c o n e F l u i d Polydimethyl s i l i c o n e f l u i d GE
S F I 705 React i ve S i 1 i cone Polymer GE
SF I 706 React ive S i 1 i cone Polymer GE
S h e l l f e x 213 Rubber process o i l Shel 1
She l l Sol 135 Solvent
SM2133 S i 1 i cone Emu1 s i on
SM2135 S i l i c o n e Emulsion
SMA-2625 Resin Cop01 ymer r e s i n
S-Mar 80 Sorb i tan f a t t y e s t e r
Snow F loss Minera l f i 1 l e r
Sodium A l k y l a r y l Su l fonate Powder (99%)
Sodium Alkylnaphthalene Su l fonate
Sodium Bicarbonate (Grades 1 & 5 )
Sodium Carbonate
Shel 1
GE
GE
Arco
PPGMaz
J M
W i t c o
DeSoto
Church
FMC
Sodium Dich lo ro isocyanura te , 2H20 O l i n
Sodi um T r i pol yphosphate
Sodium Xylene Su l fonate (40%)
Sokalan CP5 B HP22
Standamid PD Cocamide DEA
FMC
Stepan, W i t c o
Hen ke l
Standapol A An ion ic s u r f a c t a n t . Ammonium Stepan l a u r y l s u l f a t e (30%)
Standapol ES-3 An ion ic s u r f a c t a n t . Sodium l a u r y l Stepan e the r s u l f a t e (30%)
S t a r Sodium s i 1 i c a t e 4QBe' PQ
S t a r s o L i q u i d sodium s i l i c a t e PO
Steal CS-330 Alcohol e ther s u l f a t e Stepan
226 Advanced Cleaning Product Formulations
RAW MATERIAL Stepanol WA-Extra
Stoddard So lvent
STPP
S u l f e t a l 4069
S u l f e t a l 4105
Sul f ona te OA5
Super F loss
Suprag i l NK
Su r fon i c N-150
CHEMICAL DESCRIPTION Hydrotrope
F a t t y a l coho l s u l f a t e . An ion ic s u r f a c t a n t
F a t t y a l coho l s u l f a t e . An ion i c s u r f a c t a n t
Wet t ing agent
Diatomaceous e a r t h
Sodium a lky lnaphtha lene s u l f o n a t e
Surface a c t i v e agent
TEA Laury l S u l f a t e
T e r g i t o l NP
Thermphos
Thermphos NW
T inopa l 5BM
Nonoxynol
F luorescent wh i ten ing agent
Tomah A l k a l i Su r fac tan t Amphoteric (35% a c t i v e )
Tomah Amphoteric L M i I d s u r f a c t a n t
Tomah AO-14-2 Ether amine ox ide (50% a c t i v e
Tomah A0-728 Special Amine ox ide-h igh foaming (50%
Tomah Q-14-2 Quaternary
Tomah Q-17-2 Quaternary
T r i l o n A L i q u i d
T r i t o n DF-16 & N-101 Non ion ic s u r f a c t a n t s & x-45
ac t 1
SOURCE Stepan
Exxon
FMC
Zschim
Zschim
Tennes
JM
Rhone-
Texaco
Rhone-
UnCarb
Hoechs
Hoechs
C i ba-
Toma h
Tomah
Tomah
Tomah
Toma h
Tomah
Zschim
Rohm
Trademarked Raw Materials 227
R A W MATERIAL Tur bobr i t e
Tu rbobr i t e L
Tween 40
Ty lose CBR 10000
Ubatol TR1138
CHEMICAL DESCRIPTION A l u m i n o s i l i c a t e
A l u m i n o s i l i c a t e s l u r r y
Po lysorbate 40
V a l f o r 100 Z e o l i t e A b u i l d e r
Van Gel B & C & ES & 0 Magnesium aluminum s i l i c a t e s
Vanseal NACS-30 Sodi um 1 auroy l sarcos i na te
Vanseal NALS-30
Varami de A-1 0 & A-1 2 Detergent a1 kanolami des & A-83 & MA-1
Varonic DM-55 & K205 Nonionic w e t t i n g agents 8 T202 & T202SR
Varox 365 8 1770 Wet t ing agents
Varquat 50MC S p e c i a l t y quaternary, germic ide
Veegum & Veegum T Magnesi um a1 umi num s i 1 i ca tes
Versene 100 & 220 Che la t i ng agents
V i scas i a F l u i d ( 1 0 , O O O ) S i 1 i cone
Wachsemulsion 1864
Witcamide S-780 & 128T Alkanolamide s u r f a c t a n t s & 6445
Witco 12986
Witco 1298SA S o f t a c i d
W i t c o l a t e ES-3 & S u l f a t e d s u r f a c t a n t s LES-6OA & LES-6OC & SE-5 & WAC-LA & 2310
SOURCE PO
PQ
I C I
PQ
RTVan
RTVan
RTVan
W i t c o
w i t C O
W i t c o
w i t c o
RTVan
Dow
GE
Zschim
W i t c o
W i t c o
W i t c o
w i t c o
228 Advanced Cleaning Product Formulations
RAW MATERIAL CHEMICAL DESCRIPTION Witconate AOS & SXS Sur fac tan ts
& 30DS & 45 L i q u i d & 60T L i q u i d & 1240 & 1260 S l u r r y
W i t cono l NP-100 Detergents & degreasers & NP-120
Wessa l i th P Z e o l i t h P
SOUWGE \ M i ~ C O
w i tco
Ya rmor 3 02 Pine o i l Hercul
Zetesol 2056 F a t t y a l coho l e the r s u l f a t e Zschim
Zetesol NL F a t t y a l coho l e t h e r s u l f a t e Pschi I
Zusol a t 1005/85 A1 k y l po l ye thy lene g l y c o l e the r Zschim
Zusol a t 1008/85 A l k y l po l ye thy lene g l y c o l e the r Zschi rn
2 . l r Potassium s i l i c a t e (39%)
2 . 4 r Sodium s i l i c a t e (52%)
PQ
BQ
Section IV
pliers' Addresses
230 Advanced Cleaning Product Formulations
A1 1 i ed-Si gnal , I n c . P.O. Box 2332R Morr istown, NJ 07962
Amoco Chemical Co. 200 E. Randolph D r . Chicago, I L 60601
(201)-455-2000/(800)-526-0717
(312)-856-3200/(800)-621-8888
Angus Chemical Co. 2211 Sanders Rd. Northbrook, I L 60062
Arco Chemical Co. 3801 West Chester P ike Newtown Square, PA 19073
(708)-498-6700/(800)-323-6209
(215)-359-2000
A r i zona Chemical Co. 1001 E . Business Hwy 98 Panama C i t y , FL 32401 (904)-785-6700/(800)-526-5294
Ash1 and Chemical Co. P . O . Box 2219 Columbus, OH 43216
BASF Corp. 100 Cherry H i l l Rd. Parsippany, N J 07054
(614)-889-3333/(800)-848-7485
(201)-316-3000/(800)-526-1072
B u r l i n g t o n Chemical Co. I n c . P .O. Box 1 1 1 615 Huffman M i l l Rd. Bu r l i ng ton , NC 27215 (919)-584-0111/(800)-672-5888
C i ba-Gei gy Corp. 7 S k y l i n e D r i v e Hawthorne, NY 10532 (914)-374-4700/(800)-431-1900
DeSoto I n c . 1700 S. M t . Prospect Rd. Des P la ines , I L 60018 (312)-391-9000
Dover Chemical Corp W15 & Davis P.O. Box 40 Dover, OH 44622 (800) -321 -8805
Dow Chemical USA Midland, M I 48674 (800)-258-CHEM
Dow Corning Corp. Box 0994 Midland, M I 48686 (51 7)-496-4000
Ethy l Corp. 451 F l o r i d a Baton Rouge, LA 70801 (504)-388-7556/(800)-535-3030
Exxon Chemical Americas 13501 Katy Frwy Houston, TX 77079 (713)-870-6000/(800)-231-6f333
FMC Corp. 2000 Market S t . Ph i l ade lph ia , PA 19103 (215)-299-6000/(800)-526-3649
GE S i l i c o n e s 260 Hudson R ive r Rd. Waterford, NY 12188 (518)-237-3330/(800)-255-8886
Genesee Polymers Corp. Fenton Rd./P.O. Box 7047 F l i n t , M I 48507 (313)-238-4966
Georgia Marble C o . 1201 Roberts B l vd . Kennesaw, GA 30144 (404)-421-6500
B.F. Goodrich G o . 991 1 Brecksv i 1 1 e Rd , B r e c k s v i l l e , OH 44141 (216)-447-5000/(800)-331-1~44
Suppliers' Addresses 231
W.R. Grace 8 Co. 55 Hayden Ave. Lexington, MA 02173 (61 7 ) -861 -6600
Henkel Corp. 5325 S . N i n t h Ave. LaGrange, I L 60525 (708)-530-7300/(800)-543-7370
blercul es I n c . Hercules P1 aza Wilmington, DE 19894 (800)-247-4372
Woechst Celanese Corp. 801 Water S t . Portsmouth, VA 23704 (804)-393-3100/(800)-368-2822
I C I S p e c i a l t i e s Concord P ike & New Murphy Rd. W i 1 m i ngton , DE 19897 (302)-886-3000/(800)-822-8215
Johns-Manvi 11 e Ken Cary l Ranch Denver, CO 80217
Kaopo l i te , I n c . 2444 M o r r i s Ave. Union, W J 07083 (9081-789-0609
Kel co D i v i s i on Merck & Co., I n c . 8355 Aero D r i v e San Diego, CA 92123 (61 9)-292-4900
Kerr-McGee Chemical Corp. Kerr-McGee C t r . P.O. 80x 25861 Oklahoma C i t y , OK 73125 (405)-270-1313/(800)-654-3911
Lonfa I n c . 1717 Rta 208 F a i r Lawn, NJ 07410 (201)-794-2400/(800)-777-1875
Mona I n d u s t r i e s I n c . 76 E . 24 S t . P . O . Box 425 Paterson, N3 07544 (201)-345-8220/(800)-553-6662
Monsanto Chemical Co. 800 N. Lindbergh B lvd . S t . Lou is , MO 63167 (314)-694-1000/(800)-325-43
Morton I n t e r n a t i o n a l 100 N. R i v e r s i d e Plaza Chicago, I L 60606 (312)-807-2000/(800)-367-33
O l i n Corp. 120 Long Ridge Rd. P . O . Box 1355 Stamford, CT 06904 (203)-356-2000/(800)-243-9171
P e t r o l i t e Corp. 6910 E. 14 S t . Tulsa, OK 74112 (918)-836-1601
P i l o t Chemical Co. 11756 Burke S t . Santa Fe Spr ings, CA 90670 (310)-723-0036
PPG/Mazer One PPG Place P i t t sbu rgh , PA 15272 (412)-434-3131/(800)-243-6774
PQ Corp. P . O . Box 840 Va l l ey Forge, PA 19482 (215)-293-7200
Quest I n t e r n a t i o n a l Fragrances 400 I n t e r n a t i o n a l D r i v e Mount O l i v e , NJ 07828 (201 )-691-7100
232 Advanced Cleaning Product Formulatioris
Rhone-Poul enc Prospect P l a i n s Rd. Cranbury, N J 08512 (609)-860-4000/(800)-626-2613
Richardson Co. 2400 East Devon Ave. Des P la ines , I L 60018
Rohm & Haas Co. Independence Ma l l West Ph i l ade lph ia , PA 19105 (215)-592-3000
She l l Chemical Co. P .O. Box 2463 Houston, TX 77252 (713)-241-6161
Stepan Co. 22 W . Frontage Rd. N o r t h f i e l d , IL 60093 (708)-446-7500/(800)-745-7837
Tennessee Chemical Co. 3400 Peachtree Rd NE A t lan ta , GA 30326 (404)-239-6700/(800)-241-1912
Texaco Chemical Co. 3040 Post Oak 8 l v d . Houston, TX 77056 (713)-961-3711
3M 3M Center S t . Paul, MN 55144 (612)-733-5454
Tomah Products, I n c . 1012 Te r ra D r i v e M i 1 ton , W I 53563
Uni chema Chemicals I n c . 4650 S. Racine Ave. Chicago, IL 60609
(608)-868-68l l / (800)-441-0708
(312)-376-9000/(800)-833-2884
Union Carbide Corp. 39 Old Ridgebury Rd. Danbury, CT 06817 (203)-794-2000
R . T . Vanderb i l t Co., I n c . P.O. Box 5150 30 W i n f i e l d S t . Norwalk, CT 06856
Witco Corp. 520 Madison Ave. New York, NY 10022
(203)-853-1400/(800)-243-6084
(212)-605-3941/(800)-634-4010
Zschimmer & Schwarz Max-Schwarz-Strabe 3-5 D-56112 Lahnstei n/RH D 26 21/120
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