Welcome to the World of Chemistry

Welcome to the Welcome to the World of World of ChemistryChemistry

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Types of Observations and Types of Observations and MeasurementsMeasurements

• We makeWe make QUALITATIVEQUALITATIVE observations of reactions — observations of reactions — changes in color and physical changes in color and physical state.state.

• We also makeWe also make QUANTITATIVE QUANTITATIVE MEASUREMENTSMEASUREMENTS, which involve , which involve numbersnumbers..

–UseUse SI unitsSI units — based on the — based on the metric systemmetric system

SI measurementSI measurement• Le Système international Le Système international

d'unitésd'unités • The only countries that have not The only countries that have not

officiallyofficially adopted SI are Liberia adopted SI are Liberia (in western Africa) and Myanmar (in western Africa) and Myanmar (a.k.a. Burma, in SE Asia), but (a.k.a. Burma, in SE Asia), but now these are reportedly using now these are reportedly using metric regularlymetric regularly

• Metrication is a process that Metrication is a process that does not happen all at once, but does not happen all at once, but is rather a process that happens is rather a process that happens over time. over time.

• Among countries with non-Among countries with non-metric usage, the U.S. is the metric usage, the U.S. is the only only country significantly holding outcountry significantly holding out.. The U.S. officially adopted SI in The U.S. officially adopted SI in 1866.1866.

Information from U.S. Metric Association

Standards of MeasurementStandards of Measurement

When we measure, we use a measuring tool to When we measure, we use a measuring tool to compare some dimension of an object to a standard.compare some dimension of an object to a standard.

For example, at one time the For example, at one time the standard for length was the standard for length was the king’s foot. What are some king’s foot. What are some

problems with this standard?problems with this standard?

Stating a MeasurementStating a Measurement

In every measurement there is aIn every measurement there is a

Number Number followed by a followed by a

Unit Unit from a measuring devicefrom a measuring device

The number should also be as precise as the measurement!The number should also be as precise as the measurement!

UNITS OF UNITS OF MEASUREMENTMEASUREMENT

Use Use SI unitsSI units — based on the metric — based on the metric systemsystem

Length Length

MassMass

VolumeVolume

TimeTime

TemperatureTemperature

Meter, mMeter, m

Kilogram, kgKilogram, kg

Seconds, sSeconds, s

Celsius degrees, ˚CCelsius degrees, ˚Ckelvins, Kkelvins, K

Liter, LLiter, L

Mass vs. WeightMass vs. Weight

• Mass: Amount Mass: Amount of Matter (grams, of Matter (grams, measured with a measured with a BALANCE)BALANCE)

• Weight: Force Weight: Force exerted by the exerted by the mass, only mass, only present with present with gravity (pounds, gravity (pounds, measured with a measured with a SCALE)SCALE)

Can you hear Can you hear me now?me now?

Some Tools for Some Tools for MeasurementMeasurement

Which tool(s) Which tool(s) would you use to would you use to measure:measure:

A.A. temperature temperature

B.B. volume volume

C.C. time time

D.D. weight weight

Learning Check

Match Match L) lengthL) length M) mass M) mass V) volume V) volume

____ A. A bag of tomatoes is 4.6 kg.____ A. A bag of tomatoes is 4.6 kg.

____ B. A person is 2.0 m tall.____ B. A person is 2.0 m tall.

____ C. A medication contains 0.50 g Aspirin.____ C. A medication contains 0.50 g Aspirin.

____ D. A bottle contains 1.5 L of water.____ D. A bottle contains 1.5 L of water.

M

L

M

V

Learning CheckLearning Check

What are some U.S. units that are used to What are some U.S. units that are used to measure each of the following?measure each of the following?

A. length A. length

B. volume B. volume

C. weightC. weight

D. temperatureD. temperature

Metric PrefixesMetric Prefixes• Kilo-Kilo- means 1000 of that unit means 1000 of that unit

– 1 kilometer (km) = 1000 meters (m)1 kilometer (km) = 1000 meters (m)

• Centi-Centi- means 1/100 of that unit means 1/100 of that unit

– 1 meter (m) = 100 centimeters (cm)1 meter (m) = 100 centimeters (cm)

– 1 dollar = 100 cents1 dollar = 100 cents

• Milli-Milli- means 1/1000 of that unit means 1/1000 of that unit

– 1 Liter (L) = 1000 milliliters (mL)1 Liter (L) = 1000 milliliters (mL)

Metric PrefixesMetric Prefixes

1. 1000 m = 1 1. 1000 m = 1 ______ a) mm b) km c) dma) mm b) km c) dm

2. 0.001 g = 1 2. 0.001 g = 1 ___ ___ a) mg b) kg c) dga) mg b) kg c) dg

3. 0.1 L = 1 3. 0.1 L = 1 ______ a) mL b) cL c) dLa) mL b) cL c) dL

4. 0.01 m = 1 ___ 4. 0.01 m = 1 ___ a) mm b) cm c) dma) mm b) cm c) dm

Learning Check

Units of Units of LengthLength

• ? kilometer (km) = 500 meters (m)? kilometer (km) = 500 meters (m)

• 2.5 meter (m) = ? centimeters (cm)2.5 meter (m) = ? centimeters (cm)

• 1 centimeter (cm) = ? millimeter (mm)1 centimeter (cm) = ? millimeter (mm)

• 1 nanometer (nm) = 1.0 x 101 nanometer (nm) = 1.0 x 10-9-9 meter meter

O—H distance =O—H distance =9.4 x 109.4 x 10-11 -11 mm9.4 x 109.4 x 10-9 -9 cmcm0.094 nm0.094 nm

O—H distance =O—H distance =9.4 x 109.4 x 10-11 -11 mm9.4 x 109.4 x 10-9 -9 cmcm0.094 nm0.094 nm

Learning Check

Select the unit you would use to measure Select the unit you would use to measure

1. Your height1. Your height

a) millimeters a) millimeters b) metersb) meters c) kilometers c) kilometers

2. Your mass2. Your mass

a) milligramsa) milligrams b) gramsb) grams c) kilograms c) kilograms

3. The distance between two cities3. The distance between two cities

a) millimetersa) millimeters b) metersb) meters c) kilometers c) kilometers

4. The width of an artery4. The width of an arterya) millimetersa) millimeters b) metersb) meters c) kilometers c) kilometers

Temperature ScalesTemperature Scales• FahrenheitFahrenheit

• CelsiusCelsius

• KelvinKelvin

Anders Celsius1701-1744

Lord Kelvin(William Thomson)1824-1907

Temperature ScalesTemperature Scales

Notice that 1 kelvin = 1 degree Celsius1 kelvin = 1 degree Celsius

Boiling point Boiling point of waterof water

Freezing point Freezing point of waterof water

CelsiusCelsius

100 ˚C100 ˚C

0 ˚C0 ˚C

100˚C100˚C

KelvinKelvin

373 K373 K

273 K273 K

100 K100 K

FahrenheitFahrenheit

32 ˚F32 ˚F

212 ˚F212 ˚F

180˚F180˚F

Calculations Calculations Using Using TemperatureTemperature

• Generally require temp’s in Generally require temp’s in kelvinskelvins

• T (K) = t (˚C) + 273.15T (K) = t (˚C) + 273.15

• Body temp = 37 ˚C + 273 = 310 KBody temp = 37 ˚C + 273 = 310 K

• Liquid nitrogen = -196 ˚C + 273 = 77 KLiquid nitrogen = -196 ˚C + 273 = 77 K

• Generally require temp’s in Generally require temp’s in kelvinskelvins

• T (K) = t (˚C) + 273.15T (K) = t (˚C) + 273.15

• Body temp = 37 ˚C + 273 = 310 KBody temp = 37 ˚C + 273 = 310 K

• Liquid nitrogen = -196 ˚C + 273 = 77 KLiquid nitrogen = -196 ˚C + 273 = 77 K

Fahrenheit Formula – Fahrenheit Formula –

180°F180°F = = 9°F 9°F == 1.8°F 1.8°F 100°C 100°C 5°C 5°C 1°C1°C

Zero point: 0°C = 32°FZero point: 0°C = 32°F

°F = 9/5 °C + 32°F = 9/5 °C + 32

Celsius Formula – Celsius Formula –

Rearrange to find T°CRearrange to find T°C

°F °F = = 9/5 °C + 329/5 °C + 32

°F - 32 = °F - 32 = 9/5 °C ( +32 - 32)9/5 °C ( +32 - 32)

°F - 32°F - 32 = = 9/5 °C9/5 °C

9/5 9/5 9/5 9/5

(°F - 32) * 5/9 = (°F - 32) * 5/9 = °C°C

Temperature Conversions – Temperature Conversions –

A person with hypothermia has a body A person with hypothermia has a body temperature of 29.1°C. What is the body temperature of 29.1°C. What is the body temperature in °F? temperature in °F?

°F °F = = 9/5 (29.1°C) + 329/5 (29.1°C) + 32

= = 52.4 + 3252.4 + 32

= = 84.4°F84.4°F

Learning Check – Learning Check –

The normal temperature of a chickadee is The normal temperature of a chickadee is 105.8°F. What is that temperature in °C?105.8°F. What is that temperature in °C?

1) 73.8 °C 1) 73.8 °C

2) 58.8 °C2) 58.8 °C

3) 41.0 °C3) 41.0 °C

Learning Check –

Pizza is baked at 455°F. What is that in °C?

1) 437 °C1) 437 °C

2) 235°C2) 235°C

3) 221°C3) 221°C

Three Three targets with targets with three arrows three arrows each to each to shoot.shoot.

Can you hit the bull's-eye?Can you hit the bull's-eye?

Both accurate and precise

Precise but not accurate

Neither accurate nor precise

How do How do they they compare?compare?

Can you define accuracy and precision?Can you define accuracy and precision?

Significant FiguresSignificant Figures

The numbers reported in a The numbers reported in a measurement are limited by the measurement are limited by the measuring toolmeasuring tool

Significant figures in a Significant figures in a measurement include the known measurement include the known digits plus one estimated digitdigits plus one estimated digit

Counting Significant FiguresCounting Significant Figures

RULE 1. All non-zero digits in a measured number RULE 1. All non-zero digits in a measured number are significant. Only a zero could indicate that are significant. Only a zero could indicate that rounding occurred.rounding occurred.

Number of Significant Figures

38.15 cm38.15 cm 44

5.6 ft5.6 ft 22

65.6 lb65.6 lb ______

122.55 m122.55 m ___

Leading ZerosLeading Zeros

RULE 2. Leading zeros in decimal numbers are RULE 2. Leading zeros in decimal numbers are

NOTNOT significant. significant.


0.008 mm0.008 mm 11

0.0156 oz0.0156 oz 33

0.0042 lb0.0042 lb ________

0.000262 mL 0.000262 mL ____

Sandwiched ZerosSandwiched Zeros

RULE 3. Zeros between nonzero numbers are significant. RULE 3. Zeros between nonzero numbers are significant.

(They can not be rounded unless they are on an end of a (They can not be rounded unless they are on an end of a

number.)number.)


50.8 mm50.8 mm 33

2001 min2001 min 44

0.702 lb0.702 lb ________

0.00405 m0.00405 m ____

Trailing ZerosTrailing Zeros

RULE 4. Trailing zeros in numbers without RULE 4. Trailing zeros in numbers without

decimals are NOT significant. They are only decimals are NOT significant. They are only

serving as place holders.serving as place holders.


25,000 in. 25,000 in. 22

200. yr200. yr 33

48,600 gal48,600 gal ________

25,005,000 g 25,005,000 g ________


A. Which answers contain 3 significant figures?A. Which answers contain 3 significant figures?

1) 0.47601) 0.4760 2) 0.00476 2) 0.00476 3) 4760 3) 4760

B. All the zeros are significant inB. All the zeros are significant in

1) 0.00307 1) 0.00307 2) 25.300 2) 25.300 3) 2.050 x 10 3) 2.050 x 1033

C. 534,675 rounded to 3 significant figures isC. 534,675 rounded to 3 significant figures is

1) 535 1) 535 2) 535,000 2) 535,000 3) 5.35 x 10 3) 5.35 x 1055


In which set(s) do both numbers In which set(s) do both numbers contain the contain the samesame number of number of significant figures?significant figures?

1) 22.0 and 22.00 1) 22.0 and 22.00

2) 400.0 and 40 2) 400.0 and 40

3) 0.000015 and 150,0003) 0.000015 and 150,000

State the number of significant figures in each of the State the number of significant figures in each of the following:following:

A. 0.030 mA. 0.030 m 1 1 2 2 3 3

B. 4.050 LB. 4.050 L 2 2 3 3 4 4

C. 0.0008 gC. 0.0008 g 1 1 2 2 4 4

D. 3.00 mD. 3.00 m 1 1 2 2 3 3

E. 2,080,000 beesE. 2,080,000 bees 3 3 5 5 7 7


Significant Numbers in CalculationsSignificant Numbers in Calculations

A calculated answer cannot be more precise than A calculated answer cannot be more precise than the measuring tool. the measuring tool.

A calculated answer must match the least precise A calculated answer must match the least precise measurement.measurement.

Significant figures are needed for final answers Significant figures are needed for final answers fromfrom

1) adding or subtracting1) adding or subtracting

2) multiplying or dividing2) multiplying or dividing

Adding and SubtractingAdding and Subtracting

The answer has the same number of decimal The answer has the same number of decimal places as the measurement with the fewest places as the measurement with the fewest decimal places.decimal places.

25.25.22 one decimal placeone decimal place

+ 1.+ 1.3434 two decimal placestwo decimal places

26.5426.54

answer 26.5answer 26.5 one decimal placeone decimal place


In each calculation, round the answer to the In each calculation, round the answer to the correct number of significant figures.correct number of significant figures.

A. 235.05 + 19.6 + 2.1 = A. 235.05 + 19.6 + 2.1 =

1) 256.751) 256.75 2) 256.8 2) 256.8 3) 2573) 257

B. 58.925 - 18.2B. 58.925 - 18.2 ==

1) 40.7251) 40.725 2) 40.73 2) 40.73 3) 40.73) 40.7

Multiplying and Dividing

Round (or add zeros) to the calculated Round (or add zeros) to the calculated answer until you have the same number answer until you have the same number of significant figures as the measurement of significant figures as the measurement with the fewest significant figures.with the fewest significant figures.


A. 2.19 X 4.2 =A. 2.19 X 4.2 = 1) 91) 9 2) 9.2 2) 9.2 3) 9.1983) 9.198

B. 4.311 ÷ 0.07 =B. 4.311 ÷ 0.07 = 1)1) 61.5861.58 2) 62 2) 62 3) 603) 60

C. C. 2.54 X 0.00282.54 X 0.0028 = =

0.0105 X 0.060 0.0105 X 0.060

1) 11.31) 11.3 2) 112) 11 3) 0.041 3) 0.041

Reading a MeterstickReading a Meterstick

. l. l22. . . . I . . . . I. . . . I . . . . I33 . . . .I . . . . I . . . .I . . . . I44. . cm. . cm

First digit (known)First digit (known) = 2 = 2 2.?? cm2.?? cm

Second digit (known)Second digit (known) = 0.7 = 0.7 2.7? cm2.7? cm

Third digit (estimated) between 0.05- 0.07Third digit (estimated) between 0.05- 0.07

Length reportedLength reported == 2.75 cm 2.75 cm

oror 2.74 cm 2.74 cm

oror 2.76 cm2.76 cm

Known + Estimated DigitsKnown + Estimated Digits

In 2.76 cm…In 2.76 cm…

• Known digitsKnown digits 2 andand 7 are 100% certainare 100% certain

• The third digit 6 is estimated (uncertain)The third digit 6 is estimated (uncertain)

• In the reported length, all three digits In the reported length, all three digits (2.76 cm) are significant including the (2.76 cm) are significant including the estimated oneestimated one


. l8. . . . I . . . . I9. . . .I . . . . I10. . cm

What is the length of the line?What is the length of the line?

1) 9.6 cm 1) 9.6 cm

2) 9.62 cm 2) 9.62 cm

3) 9.63 cm3) 9.63 cm

How does your answer compare with your How does your answer compare with your

neighbor’s answer? Why or why not?neighbor’s answer? Why or why not?

Zero as a Measured NumberZero as a Measured Number

. l3. . . . I . . . . I4 . . . . I . . . . I5. . cm

What is the length of the line?What is the length of the line?

First digitFirst digit 5.?? cm5.?? cm

Second digitSecond digit 55.0? cm.0? cm

Last (estimated) digit isLast (estimated) digit is 5.05.00 cm0 cm

Always estimate ONE place past the smallest mark!Always estimate ONE place past the smallest mark!

DENSITYDENSITY - an important - an important and useful physical propertyand useful physical property

Density mass (g)volume (cm3)


Mercury

13.6 g/cm13.6 g/cm33 21.5 g/cm21.5 g/cm33

Aluminum

2.7 g/cm2.7 g/cm33

Platinum

ProblemProblem A piece of copper has a A piece of copper has a mass of 57.54 g. It is 9.36 cm long, mass of 57.54 g. It is 9.36 cm long, 7.23 cm wide, and 0.95 mm thick. 7.23 cm wide, and 0.95 mm thick. Calculate density (g/cmCalculate density (g/cm33).).



Volume DisplacementVolume Displacement

A solid displaces a matching volume of A solid displaces a matching volume of water when the solid is placed in water.water when the solid is placed in water.

33 mL33 mL25 mL 25 mL


What is the density (g/cmWhat is the density (g/cm33) of 48 g of a metal if ) of 48 g of a metal if the metal raises the level of water in a graduated the metal raises the level of water in a graduated cylinder from 25 mL to 33 mL? cylinder from 25 mL to 33 mL?

1) 0.2 g/ cm1) 0.2 g/ cm33 2) 6 g/m 2) 6 g/m33 3) 252 g/cm3) 252 g/cm33

33 mL33 mL

25 mL25 mL


Which diagram represents the liquid layers in the Which diagram represents the liquid layers in the cylinder?cylinder?

(K) Karo syrup (1.4 g/mL), (V) vegetable oil (0.91 (K) Karo syrup (1.4 g/mL), (V) vegetable oil (0.91 g/mL,) (W) water (1.0 g/mL)g/mL,) (W) water (1.0 g/mL)

1)1) 2) 2) 3) 3)

K

K

W

W

W

V

V

V

K

Scientific MethodScientific Method

1.1. State the problem clearly.State the problem clearly.2.2. Gather information.Gather information.3.3. Form a _______________.Form a _______________.4.4. Test the hypothesis.Test the hypothesis.5.5. Evaluate the data to form a conclusion.Evaluate the data to form a conclusion.

If the conclusion is valid, then it becomes a If the conclusion is valid, then it becomes a theorytheory. If the theory is found to be true over . If the theory is found to be true over along period of time (usually 20+ years) with along period of time (usually 20+ years) with no counter examples, it may be considered a no counter examples, it may be considered a lawlaw..

6. Share the results.6. Share the results.

Welcome to the World of Chemistry

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