WEATHERING*1 - WordPress.com · WEATHERING*1! Weathering*Categories:* Weathering* Types:*...
Transcript of WEATHERING*1 - WordPress.com · WEATHERING*1! Weathering*Categories:* Weathering* Types:*...
WEATHERING 1 Weathering Categories:
Weathering Types: Mechanical Chemical Biological
Description: Fragmentation of soild rocks into smaller fragments
Decay of soild rocks which crumble into smaller chemically altered fragments
Physical disintegration and chemical decomposition of soild rocks
Agent: Weather elements -‐ Temperature -‐ Frost/Ice -‐ Salt Crystals (ok not
really “weather” element D: )
-‐ Pressure release
Chemical reactions -‐ Rock minerals and
moisture -‐ Rainwater -‐ Seawater -‐ Organic Acids
Organic Agents e.g. plants, animals and man
Any change in the rocks?
Change in shape and size, NO chemical change
Chemical composition changed and structure changed
Products: Coarse & angular particles Fine particles (e.g. rust, minerals dissolved in solution)
Catalyst for? Chemical Weathering by increasing the rock surface i.e. increase in surface exposure when rock is broken up.
-‐
Dependent on whether it is biomechanical or biochemical
Climate/ Factors
Where it is most
effective:
Great diurnal range of temperature (e.g. deserts) And frost action (e.g. mountainous regions)
Hot and humid areas -‐ Heat speeds up chemical
reactions -‐ Most of the reactions
require water
Regions with continuous vegetation cover High rates of animal and human activity
Consists of: Insolation weathering (alternate insolation and radiation, temperature changes) -‐ Exfoliation -‐ Granular disintegration -‐ Block disintegration -‐ Wetting and drying Freeze Thaw Action Salt Crystal Growth Pressure Release
Oxidation Hydrolysis Solution Hydration Carbonation Spherodial Weathering Honeycomb Weathering
Biochemical -‐ Organic Reactions Biomechanical -‐ Burrowing -‐ Rock splitting -‐ Man’s activities
Mechanical Weathering: Insolation Weathering (Caused by the repeated heating and cooling (radiation) of rock over daily cycles, progressively breaking apart the grains of rock along joints as stress is developed)
Block Disintegration
-‐ The splitting of rocks along the joints is known as block disintegration. -‐ The blocks of rocks that are detached are of various shapes, depending on the
rock structure. -‐ In daytime, intense solar heating causes rocks to expand. -‐ At night, the temperature falls so rocks cool and contracts. -‐ Repeated expansion and contraction produces stress along joints. Joints are then
widened and deepened and finally break down the rocks block by block.
Process
Granular Disintegration
Differential Expansion -‐ Different coloured mineral grains expand at different rates. -‐ The darker minerals absorb more heat and expand more than the lighter minerals. -‐ This causes stresses between adjacent grains and the rock will disintegrate grain by
grain.
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-‐ Exfoliation -‐ Rocks expand when heated in the day and contract when they cool at night.
-‐ However, the rocks are not heated right through, and the outer parts expand and contract more
-‐ The repeated expansion of the outer parts form cracks that are parallel to the boulder surface, while repeated contraction forms cracks perpendicular to the boulder surface.
-‐ Eventually, the outer shell of the rocks peels and falls off in slabs.
Wetting and Drying
-‐ Alternate wetting and drying causes rocks to break up -‐ Physical weathering process where rocks are mechanically disintegrated by the
accumulation of successive layers of water molecules in between the mineral grains of a rock. Sometimes called slaking.
-‐ Increasing thickness of the water pulls the rock grains apart with great tensional stress.
Factors ALL TYPES Climate (Extremity of weather) Relief -‐ Landslides and slumping happens frequently on steep slopes, hence exposing
underlying rock -‐ Enables insolation weathering to work on the exposed underlying rocks
Block Disintegration
Well-‐jointed rocks
Granular Disintegration
Differential expansion needs rocks that are made up of different minerals that expand at different rates. Dark rocks (e.g. granite) weather faster physically as they heat up faster and experience a greater stress upon expansion as compared to light-‐coloured rocks. Rocks also need to be coarse-‐grained.
Exfoliation -‐
Rock Type
Wetting and Drying
-‐
Block Disintegration Granular Disintegration Exfoliation
Places with a large diurnal range of temperature, such as deserts. -‐ In the desert, day temperatures can rise to 35oC or higher because of the lack of
cloud cover to reduce incoming solar radiation/insolation. -‐ Night temperatures can go down to 10oC or lower because of the lack of cloud
cover to prevent outgoing terrestrial heat from escaping back to space.
Location
Wetting and Drying
Near Water or have water through precipitation. Temperatures should be high enough for a good rate of evaporation
Products Block Disintegration
Broken down into regular blocks
WEATHERING 3
Granular
Disintegration Coarse-‐grained rocks with homogenous structure break up into gravel or sand
Exfoliation Exfoliation domes with angular debris at base
Wetting and
Drying Rocks that are flaking off, or forms TAFONI (see salt crystal growth below)
Salt Crystal Growth (also known as haloclasty) Process -‐ Saline water seeps into cracks/ joints/ pore spaces/ cavities of rocks
-‐ Water evaporates, recrystallizing dissolved salt inside the rocks -‐ Salt crystals grow as more evaporation occurs -‐ When the rocks are heated up, the crystals will expand, putting pressure on the rock -‐ The rock would slowly disintegrate into fragments due to the stresses caused by the salt crystal
growth and the widening of joints.
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Factors Heat:
-‐ Affects the rate of cooling and heating of the salt crystals -‐> affects the size of the crystals Amount of solution: -‐ Affects the rate of evaporation and hence the rate of which salt crystals form Salinty of solution: -‐ A less diluted solution will have fewer salt crystals compared to a more concentrated solution Type of salts: -‐ The salts which have proved most effective in disintegrating rocks are sodium sulfate, magnesium
sulfate, and calcium chloride. -‐ Some of these salts can expand up to three times or even more.
Rock Type If calcium carbonate in present in the rock e.g. chalk/limestone, it is able to bind together other sediments from salt crystal growth to form beachrock and in warmer areas dunerock.
Location Climate
Arid Climate -‐ Strong heating causes strong evaporation and therefore salt crystallisation. Near the sea, near beaches -‐ Wind carries salt spray onto rocks, where it is absorbed into small pores and cracks within the rocks. -‐ There the water evaporates and the salt crystallises, creating pressure and often breaking down the
rock. At places where rock is decomposing -‐ Salt crystals of solutions formed by decomposition of rock
Products
Left, Azerbaiian, Salt weathering of sandstone. Right, Yehliu Taiwan, the surface pattern on this pedestal rock is honeycomb weathering, caused by salt crystallization. HONEYCOMB WEATHERING: -‐ Caused by salt crystal growth on sea walls
WEATHERING 5
-‐ Heterogenous rocks which contain soluble materials are subjected to differential weathering when pitted by sprays of sea water.
-‐ Pits or cavities on the cliff faces are exposed when the weathered materials are removed. -‐ A type of tafoni (below right), a weathering pattern assumed to be formed by salt weathering
o Tafoni: a class of cavernous rock weathering structures, which likely develop in large part by chemical and physical salt weathering processes.
o Small cave-‐like features found in granular rock such as sandstone, with rounded entrances and smooth concave walls.
o Occur in groups that can riddle a hillside, cliff, or other rock formation. They can found in all climate types, but are most abundant in intertidal areas and semi arid and arid deserts.
o Currently favored explanations controlling their formation include salt weathering, differential cementation, structural variation in permeability, and the length of the drying period between wettings.
Freeze Thaw Action/ Frost Shattering Process -‐ Water seeps into joints and cracks in rocks or boulders, and gets trapped in them.
-‐ When the temperature falls below freezing point, the water freezes and increases in volume by as much as 9%.
-‐ The expanding ice exerts pressure on the sides of the joints and cracks. -‐ When the temperature rises to above freezing point, the ice melts and contracts, and the pressure
is reduced. -‐ Repeated freeze and thaw action over long periods of time further increase the size of the joints
and cracks, and eventually break the boulder into smaller fragments.
Rock Type Well-‐jointed
-‐ For water to seep in Bare, exposed rocks are more vulnerable
Location Climatic conditions
6 WEATHERING Climate -‐ Have temperatures that always fluctuate above and below the freezing point to facilitate repeated
freezing and thawing actions (mountainous regions: Alps, Snowdonia) -‐ Rainfall to provide water to seep into the cracks
Products Talus slope: Accumulation of freshly broken rock materials that have fallen from the cliffs Scree: Freshly broken rock materials that are ANGULAR and have fallen from the cliffs, are DEBRIS, deposited at the base of the cliff due to gravity Regolith: Weathered Remains, may or may not be angular
Felsenmeer/Boulder field: In a felsenmeer (also known as a block/boulder field), freeze thaw weathering has broken up the top layer of the rock, covering the underlying rock formation with jagged, angular bolders. Felsenmeers are formed in situ, meaning that they are not transported during or after their creation, and form on extensive gentle slopes. Tors: Rock outcrop formed by weathering, usually found on or near the summit of a hill.
Pressure Release Process -‐ Pressure release of rock can cause physical weathering due to unloading. The majority of igneous
rocks were created deep under the Earth's surface at much higher pressures and temperatures. -‐ As erosion brings these rock formations to the surface, they become subjected to less and less
pressure as the overlying rocks are removed. -‐ This unloading of pressure causes the rocks to fracture horizontally with an increasing number of
fractures as the rock approaches the Earth's surface due to expansion. -‐ Spalling, the vertical development of fractures, occurs because of the bending stresses of unloaded
sheets across a three dimensional plane. -‐ Sheeting then occurs due to this unloading of pressure. (Removal of rock layer by layer)
Factors Need erosion to occur, in order for uplift of rock layers to surface to occur Rock Type Igneous Location Climate
-‐
Products Looks similar to exfoliation Chemical Weathering: Oxidation Process -‐ Oxygen comes into contact with other minerals, then forming a new compound which is known as
the oxide of that mineral. (oxygen can be dissolved in rainwater) -‐ This new compound is less resistant, has a weakened rock structure. -‐ A mineral that is commonly oxidized is iron, which is found in most rocks. When oxidized, the iron
changes into reddish-‐brown iron oxide which crumbles readily, weakening the rock structure. -‐ However, the iron oxides coat the whole rock giving it some protection from further oxidation. -‐ The problem that arises (which leads to more erosion) is that the iron oxide is very brittle and can
be broken off very easily, making the rock again susceptible to oxidization. -‐ When this process happens over a long period of time the strength of the rock will begin to erode
and it will eventually break apart. -‐ Rusting: Iron may have been blue or grey in color originally as this is characteristic of rocks with a
lack of oxygen. However, after it has come into contact with oxygen, it is oxidized and its rock structure is broken down, leading to it being discolored into a reddish brown.
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-‐ Commonly oxidized minerals are iron, aluminium, manganese, etc. Factors Amount of moisture
-‐ Water is needed as it helps to quicken the oxidation process. Temperature -‐ Aids in increasing the rate of oxidation. -‐ When temperature is increased, the molecules in the rock will move around faster and have more
collisions, creating greater opportunities for oxidation to occur. Rock composition -‐ Different compositions will subject the rock to different types of weathering and affect the rate and
extent of that weathering process. -‐ Certain minerals particularly iron and manganese weather primarily by oxidation. Jointing/Lines of weakness -‐ When there are many cracks and joints in the rocks, more rock surface is exposed to weathering
agents. -‐ The rocks that have cracks will be more susceptible to coming into contact with oxygen in the water. -‐ This further weakens the bonds between rocks and causes the rock structure to be broken down
more easily through oxidation. Rock Type Must contain the minerals that can be oxidized Location Climate
-‐ Hot and humid climate is more conducive for oxidation to occur.
Products Patina: Green layer covering Statue of Liberty Precipitation of Iron produces: -‐ Iron Stains on rock surfaces -‐ Iron dykes along joints -‐ Iron Caps: A layer of iron “skin” broken by running water
Carbonation Process -‐ A type of chemical weathering
-‐ Carbonation occurs on rocks which contains calcium carbonate such as limestone and chalk -‐ Atmospheric carbon dioxide dissolves in rainwater and water vapour in the surrounding air to form
weak carbonic acid. -‐ When rain falls on these rocks, the carbonic acid reacts with the calcium carbonate in the rocks to
form calcium bicarbonate (insoluble Calcium Carbonate+ Water + Carbon Dioxide —> soluble Calcium Bicarbonate)
-‐ Breaks down the rock which then can be dissolved by any form of aqueous solute (e.g. rainwater) in the surroundings
-‐ Rocks are dissolved in rainwater and are washed away Factors Mineral Composition of rocks (Calcium carbonate)
Temperature -‐ Decrease in temperature Colder water Can hold more carbon dioxide Greater acidity in
rainwater Speeds up process of carbonation Water -‐ Carbonation is maximized in wet environments.
Rock Type Limestone, rocks that contain calcium carbonate Location Climate
High amounts of precipitation
Products Karst landscape shaped by dissolution of layer(s) of soluble bedrock Some features of karst regions include sinkholes, caves, limestone pavements and springs Grykes: Grooves formed along joints of limestone pavements Clints: Flat platforms in between grykes
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Swallow holes (SINKHOLES!): Widened entrances to joints Dolines: Larger swallow holes
Hydration Process -‐ Swelling (Expansion) of rock minerals when they absorb water
-‐ Swelling causes stress in rocks, forcing grains apart -‐ Repeated wetting and drying of minerals led to flaking of rocks; granular disintegration -‐ Reversible change as mineral composition remains unchanged
Factors -‐ Water -‐ Temperature -‐ Mineral types
Rock Type -‐ Location Climate
High amounts of precipitation/near water Also need high amount of heat as evaporation is needed
Products -‐ Anhydrous calcium sulphate absorbs water to form hydrated calcium sulphate (gypsum) -‐ Flaking of rocks, granular disintegration -‐
Hydrolysis Process -‐ �Chemical weathering involving rainwater and some minerals in rocks (feldspar + ferromagnesian)
-‐ Acidic rainwater (carbonic acid in rainwater) react with feldspar and mica to form kaolin clay that crumbles easily and are washed away
-‐ The clay is soft and expands in volume; causing granular disintegration -‐ Iron in mica oxidised to form reddish-‐brown iron oxide -‐ More effective at the angular edges of the blocks of rocks. (See Spheroidal weathering)
Factors -‐ Temperature
WEATHERING 9
-‐ Moisture/Water Rock Type Must contain feldspar and mica (usually igneous rock)
Felsic rock such as granite Location Climate
Common in hot, wet regions
Products Granitic tors, deep weathering profile
Solution Process -‐ Soluble minerals e.g. salt and gypsum in rock are dissolved by standing water, causing the rock to
crumble Factors -‐ Amount of water
-‐ Type of rock minerals and their solubility Rock Type -‐ Contains the minerals that are water-‐soluble
Location Climate
-‐ Has to be near standing pools of water, maybe in caves where water collects, rock pools -‐ No particular climate, but must have some access to water though precipitation perhaps
Products -‐ Solution pans -‐ Solution pools
-‐ Spheroidal Weathering Process -‐ Rainwater percolating the joints of large rectangular blocks starts chemical weathering
(carbonation, hydrolysis, oxidation, all the above) along the joints and at the angular edges of the blocks. o Have higher surface area to volume ratio, hence these areas weather faster
-‐ The weathered materials break away from the core in concentric shells, revealing a rounded
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“corestone” Factors Amount of moisture
Temperature Rock Type -‐ Location Climate
Hot and humid e.g. tropical
Products -‐ Creates rounded boulders and domed monoliths -‐ Rectangular blocks are reduced to rounded boulders and eventually the entire corestone is reduced
to weathered materials -‐ Can form granitic tors and contribute to a deep weathering profile (Refer to Hydrolysis too!)
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Biological Weathering: Biochemical: Biochemical Process
Chelation: -‐ Chelation is a biological process where organisms produce organic substances (chelates), that
decomposes minerals and rocks by the removal of metallic cations. Carbonation/Other Acids: -‐ Organic acids are produced when leaves and other parts of plants fall to the ground and
decompose, hence breaking up the rocks. Organic acids can also be produced from the decomposition of animal waste and dead animals.
-‐ In addition, plants gives out carbon dioxide and when this is combined with water, a weak carbonic acid is formed. This acid is able to weaken rocks and cause them to disintegrate.
-‐ Organisms in the stagnant water gives out carbon dioxide which forms carbonic acid and reacts with the rock.
-‐ Plants such as mosses and lichens clinging to rock surface can cause the weathering of rocks through a chemical process. They produce organic acids that react with minerals in rocks and cause the rocks to decompose.
Algae and bacteria can break down the rocks, leeching them of their nutrients and causing them to weather.
Biomechanical Process
-‐ Simple breaking of soil/rock particles occurs when particles fracture because of animal burrowing or by the pressure from growing roots.
-‐ Roots of plants penetrate rocks by growing into the cracks and joints, and hence widen the cracks and joints.
WEATHERING 11
-‐ Many large soil organisms cause the movement of soil particles, thus introducing the materials to different weathering processes found at distinct locations in the soil profile.
Factors Climate:
-‐ Takes place faster in warm, moist climates with high temperature and high rainfall as chemical reactions take place faster in the presence of heat and moisture.
-‐ The warm and moist climate also leads to rapid plant growth and great rate of animal activities which accelerate biological weathering.
Plant and Animal Activity: -‐ As plants and animal activities aid biological weathering, hence the more the activities, the more
rapid the weathering process will get. -‐ The shade and roots from trees can also create an increase of water in soil, which lends itself to
physical and chemical weathering processes. Human Activities: -‐ Such as overgrazing, mining, burning, digging, ploughing, lumbering -‐ When vegetation is removed, biological weathering is reduced, also cause exposure of more
rock surface Rock Type -‐ Location Climate
-‐ Occurs mainly along coastal areas and tropical rainforests. -‐ Coastal areas are habitats for algae, limpets. -‐ There is more biotic activity and vegetation cover in tropical rainforests as well as a hot &
humid climate. Products No specific
e.g. Angkor Wat
12 WEATHERING Factors Affecting Rate of Weathering Processes: C3R3AM: Factor Description Climate -‐ One of the VERY IMPORTANT factors, can even be considered the most important factor for
LONG-‐TERM CONTROL OF WEATHERING PROCESSES -‐ Can be understood as two parts: Temperature and amount of precipitation (moisture/humidity) -‐ If asked to compare Temp. and Moisture/Precipitation: -‐ Temperature affects all the weathering processes
o Low temp. favourable for carbonation and freeze thaw o High temp favourable for insolation, oxidation, hydrolysis etc. o High temp favourable for biotic activity
-‐ Precipitation can speed up rate of chemical reactions (water acts as a solvent) o Except for insolation but can argue that it is the ABSENCE of precipitation that allows
this form of weathering to thrive. Composition of Rock
-‐ Key factor influencing the resistance of rock to weathering -‐ Constituent minerals and how they are cemented determine the rock’s resistance and what
chemical process will affect it more -‐ Igneous rocks are resistant, contain silica and feldspar (more resistant minerals) -‐ Sedimentary rocks less resistant due to soft cement -‐ Quartzite (a metamorphic rock type) is more resistant due to the hard silica cement!
Cover from Vegetation
-‐ Minor factor as a whole -‐ Vegetation speeds up biological weathering -‐ Protects underlying rocks from physical weathering -‐ Fungi, algae, lichens help to retain water in the ground
Rock Jointing -‐ Important influence on ALL TYPES OF WEATHERING -‐ Increases the surface areas exposed for attack, accelerates block disintegration -‐ Jointing pattern determines the character of the landforms produced.
o Granite = rectangular blocks when weathered leaves rounded corestone o Basalt = weathered into vertical polygonal columns
-‐ Allow for greater penetration of water and acidic solutions into rock, facilitate root penetration and animal burrowing
Rock Texture -‐ Coarse grained rocks are more susceptible to granular disintegration -‐ Rocks with coarse grains also weather more rapidly as once a weakened mineral is weathered,
the entire rock is weakened and breaks up more easily. Relief -‐ Landslides and slumps occur more frequently on steep slopes, and these expose the underlying
rock to weathering processes -‐ On gentle slopes, the weathered material protects the underlying rock from weathering
processes Activities of Man
-‐ Activities can cause the removal of vegetation cover hence leading to more exposed rock surface for weathering processes to take place, but at the same time can disrupt some biological weathering
-‐ Urbanization and industrialization lead to higher levels of carbon dioxide (so carbonation will be enhanced), and chemical weathering is more prevalent due to the acidic rainfall
Colour Code: Orange = MAJOR FACTOR Blue = MINOR Factor