voCo’S ADvANCED NANo tECHNology SEtS gRANDio … · grandio® syringe kit 5-4gm syringes (A1, A2,...

6
THE AWARD WINNING UNIVERSAL NANO HYBRID COMPOSITE WITH OUTSTANDING PERFORMANCE AND SUPERIOR HANDLING VOCO’S ADVANCED NANO TECHNOLOGY SETS A NEW BENCH MARK FOR COMPOSITES SUPERIOR HANDLING www.dentaladviso r. com Editors’ Choice + + + + +

Transcript of voCo’S ADvANCED NANo tECHNology SEtS gRANDio … · grandio® syringe kit 5-4gm syringes (A1, A2,...

Page 1: voCo’S ADvANCED NANo tECHNology SEtS gRANDio … · grandio® syringe kit 5-4gm syringes (A1, A2, A3, A3.5, b2),shade guide REF 1800 ... * Prices subject to change. ** at time of

VOCO America, Inc. · 555 Pleasantville Rd Suite 120 NB · Briarcliff Manor, NY 10510 · www.vocoamerica.com · [email protected]

Call 1-888-658-2584

SURFACE HARDNESS

90

80

70

60

50

40

30

20

10

0

Vi

cker

s ha

rdne

ss [

HV]

Source: Dr. S. Schultz, University of Regensburg, 2003. Data on file.

Gra

ndio

®

Com

pogl

ass®

Dyr

act®

AP

Dyr

act®

Xtr

a

Ena

mel

® H

FO

Est

het

Filt

ek™

Sup

rem

e

Z 2

50

Hel

io®M

ol.

InTe

nS®

Mir

is™

Poi

nt 4

Qui

xx®

Sin

fony

®

TPH

Spe

ctru

Tetr

ic®

Cer

am

4 -po iNt tRANSvERSE StRENgtH

140

120

100

80

60

40

20

0

[MP

a]

Source: U. Lohbauer, University of Erlangen, 2003. Data on file.

Gra

ndio

®

Sol

itai

re®2

Tetr

ic® C

eram

InTe

nS®

Defi

nite

®

Hel

iom

olar

® H

B

Dyr

act®

A

P

tHERmAl ExpANS ioN CoEFF iC iENt

60

50

40

30

20

10

0Ther

mal

exp

ansi

on c

oeffi

cien

t [

10

-6/K

]

Source: Dr. H. Wolter, ISC Würzburg, 2003.

Gra

ndio

®

Filt

ek™

Sup

rem

e

Gra

ndio

® F

low

Venu

s™

Pre

mis

e

TPH

3

Est

het

Cer

am X

Evo

Cer

am

Hel

io M

olar

®

Est

het

X® fl

ow

Tetr

ic®

Fl

ow

Venu

s™ F

low

SHR iNkAgE

30

25

20

15

10

5

0

lin.

shr

inka

ge [

µm]

Source: Prof. I. Krejci, University of Geneva, 2003. Data on file.

Gra

ndio

®

InTe

nS®

Tetr

ic® H

B

Defi

nite

®

Pro

digy

™ C

ond.

grandio® is significantly more fracture-

resistant than conventional composites.

VOCO is not the holder of the mentioned trademarks.

Extremely high surface hardness due to the use of

nano-fillers and high filler degree (87% by weight).

VOCO is not the holder of the mentioned trademarks.

Due to its high filler degree, grandio® exhibits

more tooth-like thermal expansion behavior for

long-term marginal integrity and reduced hot-cold

sensitivity.

VOCO is not the holder of the mentioned trademarks.

grandio® exhibits much lower levels of shrinkage

than conventional composites.

VOCO is not the holder of the mentioned trademarks.

CRA Salt Lake City, UT

REALITY Houston, TX

LSUHSC School of Dentistry, New Orleans, LA

The Dental Advisor Ann Arbor, MI

With compliments of your representative:

VC 8

4 0

01

80

0 U

S 0

61

0

tECHNiCAl DAtA :

gRANDio

tHE AwARD w iNN iNg UN ivERSAl NANo HybR iD CompoS itE w itH

oUtStAND iNg pERFoRmANCE AND SUpER ioR HANDl iNg

voCo’S ADvANCED NANo tECHNology SEtS A NEw bENCH mARk FoR CompoSitES

SUpERioRHANDliNg

www.dentaladviso r. com

Editors’ Choice+ + + + +

Filler content 87% by weight

71.4% by vol. DiN 13922

Shrinkage 1.57% by vol. University of manchester, gb

Surface hardness (micro vickers-hardness) 285 mHv University of Rostock, germany

wear rate 14 µm 3 body wear (ACtA 200,000)

Depth of cure 3mm/20 sec. iSo 4049

Radiopacity 250% Al iSo 4049

iNtRo kitS

grandio® syringe kit 5-4gm syringes (A1, A2, A3, A3.5, b2),shade guide REF 1800

grandio® Caps kit 50-0.25gm Caps (A1, A2, A3, A3.5, b2), shade guide REF 1830

REFillS: grandio® – 4gm syringe / grandio® Caps – 20-0.25gm Caps each

shade syringes capsshade syringes capsshade syringes

incisal

opaque A2

opaque A3.5

bl (bleach)

REF 1820

REF 1821

REF 1822

REF 1823

REF 1850

REF 1851

REF 1852

REF 1853

b2

b3

C2

C3

D2

D3

REF 1815

REF 1816

REF 1817

REF 1818

REF 1825

REF 1819

REF 1845

REF 1846

REF 1847

REF 1848

REF 1855

REF 1849

A1

A2

A3

A3.5

A4

b1

REF 1810

REF 1811

REF 1812

REF 1813

REF 1814

REF 1824

REF 1840

REF 1841

REF 1842

REF 1843

REF 1844

REF 1854

caps

Easygloss – one-step-polishing brush

6 diamond impregnated polishing brushes REF 2050

* Prices subject to change. ** at time of product launch

grandio

tHE AwARD wiNNiNg UNivERSAl NANo HybRiD CompoSitE witH oUtStANDiNg pERFoRmANCE AND SUpERioR HANDliNg

Page 2: voCo’S ADvANCED NANo tECHNology SEtS gRANDio … · grandio® syringe kit 5-4gm syringes (A1, A2, A3, A3.5, b2),shade guide REF 1800 ... * Prices subject to change. ** at time of

VOCO America, Inc. · 555 Pleasantville Rd Suite 120 NB · Briarcliff Manor, NY 10510 · www.vocoamerica.com · [email protected]

Call 1-888-658-2584

SURFACE HARDNESS

90

80

70

60

50

40

30

20

10

0

Vi

cker

s ha

rdne

ss [

HV]

Source: Dr. S. Schultz, University of Regensburg, 2003. Data on file.

Gra

ndio

®

Com

pogl

ass®

Dyr

act®

AP

Dyr

act®

Xtr

a

Ena

mel

® H

FO

Est

het

Filt

ek™

Sup

rem

e

Z 2

50

Hel

io®M

ol.

InTe

nS®

Mir

is™

Poi

nt 4

Qui

xx®

Sin

fony

®

TPH

Spe

ctru

Tetr

ic®

Cer

am

4 -po iNt tRANSvERSE StRENgtH

140

120

100

80

60

40

20

0

[MP

a]

Source: U. Lohbauer, University of Erlangen, 2003. Data on file.

Gra

ndio

®

Sol

itai

re®2

Tetr

ic® C

eram

InTe

nS®

Defi

nite

®

Hel

iom

olar

® H

B

Dyr

act®

A

P

tHERmAl ExpANS ioN CoEFF iC iENt

60

50

40

30

20

10

0Ther

mal

exp

ansi

on c

oeffi

cien

t [

10

-6/K

]

Source: Dr. H. Wolter, ISC Würzburg, 2003.

Gra

ndio

®

Filt

ek™

Sup

rem

e

Gra

ndio

® F

low

Venu

s™

Pre

mis

e

TPH

3

Est

het

Cer

am X

Evo

Cer

am

Hel

io M

olar

®

Est

het

X® fl

ow

Tetr

ic®

Fl

ow

Venu

s™ F

low

SHR iNkAgE

30

25

20

15

10

5

0

lin.

shr

inka

ge [

µm]

Source: Prof. I. Krejci, University of Geneva, 2003. Data on file.

Gra

ndio

®

InTe

nS®

Tetr

ic® H

B

Defi

nite

®

Pro

digy

™ C

ond.

grandio® is significantly more fracture-

resistant than conventional composites.

VOCO is not the holder of the mentioned trademarks.

Extremely high surface hardness due to the use of

nano-fillers and high filler degree (87% by weight).

VOCO is not the holder of the mentioned trademarks.

Due to its high filler degree, grandio® exhibits

more tooth-like thermal expansion behavior for

long-term marginal integrity and reduced hot-cold

sensitivity.

VOCO is not the holder of the mentioned trademarks.

grandio® exhibits much lower levels of shrinkage

than conventional composites.

VOCO is not the holder of the mentioned trademarks.

CRA Salt Lake City, UT

REALITY Houston, TX

LSUHSC School of Dentistry, New Orleans, LA

The Dental Advisor Ann Arbor, MI

With compliments of your representative:

VC 8

4 0

01

80

0 U

S 0

61

0

tECHNiCAl DAtA :

gRANDio

tHE AwARD w iNN iNg UN ivERSAl NANo HybR iD CompoS itE w itH

oUtStAND iNg pERFoRmANCE AND SUpER ioR HANDl iNg

voCo’S ADvANCED NANo tECHNology SEtS A NEw bENCH mARk FoR CompoSitES

SUpERioRHANDliNg

www.dentaladviso r. com

Editors’ Choice+ + + + +

Filler content 87% by weight

71.4% by vol. DiN 13922

Shrinkage 1.57% by vol. University of manchester, gb

Surface hardness (micro vickers-hardness) 285 mHv University of Rostock, germany

wear rate 14 µm 3 body wear (ACtA 200,000)

Depth of cure 3mm/20 sec. iSo 4049

Radiopacity 250% Al iSo 4049

iNtRo kitS

grandio® syringe kit 5-4gm syringes (A1, A2, A3, A3.5, b2),shade guide REF 1800

grandio® Caps kit 50-0.25gm Caps (A1, A2, A3, A3.5, b2), shade guide REF 1830

REFillS: grandio® – 4gm syringe / grandio® Caps – 20-0.25gm Caps each

shade syringes capsshade syringes capsshade syringes

incisal

opaque A2

opaque A3.5

bl (bleach)

REF 1820

REF 1821

REF 1822

REF 1823

REF 1850

REF 1851

REF 1852

REF 1853

b2

b3

C2

C3

D2

D3

REF 1815

REF 1816

REF 1817

REF 1818

REF 1825

REF 1819

REF 1845

REF 1846

REF 1847

REF 1848

REF 1855

REF 1849

A1

A2

A3

A3.5

A4

b1

REF 1810

REF 1811

REF 1812

REF 1813

REF 1814

REF 1824

REF 1840

REF 1841

REF 1842

REF 1843

REF 1844

REF 1854

caps

Easygloss – one-step-polishing brush

6 diamond impregnated polishing brushes REF 2050

* Prices subject to change. ** at time of product launch

grandio

tHE AwARD wiNNiNg UNivERSAl NANo HybRiD CompoSitE witH oUtStANDiNg pERFoRmANCE AND SUpERioR HANDliNg

Page 3: voCo’S ADvANCED NANo tECHNology SEtS gRANDio … · grandio® syringe kit 5-4gm syringes (A1, A2, A3, A3.5, b2),shade guide REF 1800 ... * Prices subject to change. ** at time of

87% Filled

VOCO’s advanced Nano technology sets a new benchmark for composites

SURFACE HARDNESS

VOC

O i

s no

t th

e ho

lder

of

the

men

tion

ed t

rade

mar

ks.

300

250

200

150

100

50

0

Mik

ro V

icke

rs h

ardn

ess

[MH

V]

Source: Prof. Dr. D. Behrend, University of Rostock, 2003. Data on file.

Gra

ndio

®

Filt

ek™

Sup

rem

e

Sur

efil™

Tetr

ic®

Cer

am

Dyr

act®

AP

Defi

nite

®

tHREE boDy wEAR RES iStANCE

VOC

O i

s no

t th

e ho

lder

of

the

men

tion

ed t

rade

mar

ks.

80

70

60

50

40

30

20

10

0

[Wea

r] –

µm

Source: Dabanoglu, A., Kunzelmann, K.H., Hickel, R., Kory, F., Universities of Istanbul, Munich, Three Body Wear Resistance of Resin Composites, DGZ/EFCD-meeting, Munich 2003.

Gra

ndio

®

Filt

ek™

Sup

rem

e

Cle

arfil

™ A

P-X

Sur

efil™

Est

het

Poi

nt 4

Cha

rism

a® F

Mir

is™

Venu

Tetr

ic® C

eram

InTe

nS®

Dyr

act®

AP

Hel

iom

olar

®

Hel

iom

olar

® H

B

polymER izAt ioN SHR iNkAgE

VOC

O i

s no

t th

e ho

lder

of

the

men

tion

ed t

rade

mar

ks.

3.0

2.5

2.0

1.5

1.0

0.5

0

[Vol

.%]

Source: Prof. D. Watts, University of Manchester, 2002. Data on file.

Gra

ndio

®

Sur

efil™

Defi

nite

®

Est

het

Filt

ek™

Sup

rem

e

Sol

itai

re® 2

Poi

nt 4

F illER CoNtENt

VOC

O i

s no

t th

e ho

lder

of

the

men

tion

ed t

rade

mar

ks.

100

90

80

70

60

50

40

30

20

10

0

Filler

con

tent

[w

/w %

]

According to manufacturers data.

Gra

ndio

®

InTe

nS®

Poi

nt 4

Venu

s™

Filt

ek™

Sup

r. (

D)

Filt

ek S

upr.

(I)

Ena

mel

™ H

FO

Est

het

Small nano fillers make a big difference!

Grandio’s Nano Technology leads to enormous clinical benefits

Conventional filler technology creates its particles by

grinding down large pieces of glass ceramic into fine

powders. The lower limit of particles obtainable by

grinding is approx. 0.5 µm or 500 nm. In a conventional

composite, the space between these particles is filled

with resin. Thus, a typical universal restorative has a

filler degree of around 77% w/w. Since polymerization

shrinkage only occurs in the resin matrix, a higher

filler degree would reduce shrinkage. Yet, higher filler

degrees make the materials more difficult to handle

and may lead to enclosures of air bubbles when

applying them in the depth of a cavity.

A material that promises a smooth consistency for

easy handling, adaptation and modeling, plus low

shrinkage values, seems to have been a very elusive

item.

Recently, restoratives using nano technology have

been introduced. The nano particles used in grandio

are silicon dioxide filler particles grown from a liquid

in a sol-gel process to a size of 20 to 60 nm. The

surfaces of these particles are then functionalized

to provide cross-linking capabilities. These nano

particles have the following amazing properties:

• they are not visible to the human eye

• they behave rather like liquids

• they can cross-link after surface modification

• they offer incredibly large surfaces

Currently, nano technology is used in different approa-

ches: e.g. one manufacturer uses nano particles

and nano clusters to produce a restorative aimed at

anterior restorations; an other approach is to combine

nano particles with traditional glass ceramic filler

particles to obtain a high-performance universal

restorative. Here, the traditional fillers form a hard

net work and the nano particles fill the spaces bet-

ween them. This maximizes the packing density and

leaves less resin within the filler/resin matrix. VOCO

has chosen the latter approach for its universal

nano-hybrid composite grandio.

The ratio of resin to fillers determines the physical

properties of the restorative. grandio combines nano

scaled particles with conventional sized glass ceramic

fillers of a select size range. The result: an extremely

high filler loading of 87% by weight, (71.4% by vol)

with an extremely low resin content. This successful

combination leads to grandio’s outstanding physical

properties. grandio out performs the strength of a

hybrid and sets a new standard in surface hardness,

wear and fracture resistance.

Single Shade Simplicity via enhanced translucency

A nano particle is so small that it cannot be seen with

the naked eye. In fact, it is so small that a nano

particle can pass through a beam of visible light

without causing it to diffract. This perfect translu-

cency affords excellent esthetic properties for the

clinician. grandio has a very high degree of trans-

lucency, allowing the clinician to achieve natural,

vital esthetics using only ONE shade! The Shade

Simplicity concept results in fewer shades to store

for the clinician without any esthetic compromise

for the patients.

VOCO has chosen a “Single Shade Simplicity” ap-

proach when it comes to the available shade range.

In general, most clinicians actually solve all their

esthetic cases with 6 to 8 shades grandio offers a

practical choice of 16 shades in either syringes or

Caps. The shade range offers 14 translucent inclu-

ding bleach, incisial shade and 2 opaque shades.

High polish and color retention

Due to small nano fillers, grandio has the high gloss

polishability of a micro filled composite, but without

the physical compromises. grandio’s 30-50% less

resin content compared to micro hybrids gives the

material long term polish and color retention.

Resin is used for all composite manufacturing. Re-

sin is also the primary cause for such concerns as:

polymerization shrinkage, extrinsic staining and free

radicals/ residual monomers. grandio reduces these

problems to a nominal level. The 87% filler content

of grandio results in a nominal resin content of 13%.

This is 30–50% less resin than most micro-hybrids.

grandio has only 1.57% shrinkage, less staining and

a much higher level of biocompatibility.

When hearing about Grandio’s filler degree of 87% w/w,

almost every general practitioner expects to find an

extremely hard material of amalgam-like consistency.

Due to the liquid-like behavior of the nano particles,

however, Grandio is smoother than most conventional

micro-hybrids without slumping. Grandio will not stick

to instruments, thereby avoiding a “pull-back effect.”

Even extruding caps/compules do not require the force

one might expect. Modelling and shaping are easy with

any composite instrument. Polishing and grinding re -

veals the extreme hardness of the material to the dentist

and is best done with diamond-based burs and polishers.

The short light-curing time of 20 seconds with a

standard halogen curing unit saves time. grandio is

also suitable for LED lights. Moreover, grandio is

compatible with all conventional bonding agents.

Standard micro hybrid

unfilled resin

grandio® – filled with

Nano fillers

grandio®

Nano fillers

Standard micro hybrid

micro hybrid fillers

1nm

1nm to a Soccer ball a Soccer ball is to the Earth

=: :

as

the size of a nano particle:

one of the results of the Dental Advisors Editors’ evaluation is: 100% of the evaluators would recommend grandio!

initial situation After preparation Finished grandio® restoration

Source: Dr. Jürgen Manhart, University of Munich, 2003

grandio

NANo tECHNology

grandio

ExCEllENt NAtURAl EStHEtiCS

grandio

87% FillED FoR oUtStANDiNg wEAR AND FRACtURE RESiStANCE

grandio

tERRiFiC HANDliNg pRopERtiES

grandio

30–50% lESS RESiN CoNtENt FoR lESS SHRiNkAgE AND HigHER bioCompAtibility

Page 4: voCo’S ADvANCED NANo tECHNology SEtS gRANDio … · grandio® syringe kit 5-4gm syringes (A1, A2, A3, A3.5, b2),shade guide REF 1800 ... * Prices subject to change. ** at time of

87% Filled

VOCO’s advanced Nano technology sets a new benchmark for composites

SURFACE HARDNESS

VOC

O i

s no

t th

e ho

lder

of

the

men

tion

ed t

rade

mar

ks.

300

250

200

150

100

50

0

Mik

ro V

icke

rs h

ardn

ess

[MH

V]

Source: Prof. Dr. D. Behrend, University of Rostock, 2003. Data on file.

Gra

ndio

®

Filt

ek™

Sup

rem

e

Sur

efil™

Tetr

ic®

Cer

am

Dyr

act®

AP

Defi

nite

®

tHREE boDy wEAR RES iStANCE

VOC

O i

s no

t th

e ho

lder

of

the

men

tion

ed t

rade

mar

ks.

80

70

60

50

40

30

20

10

0

[Wea

r] –

µm

Source: Dabanoglu, A., Kunzelmann, K.H., Hickel, R., Kory, F., Universities of Istanbul, Munich, Three Body Wear Resistance of Resin Composites, DGZ/EFCD-meeting, Munich 2003.

Gra

ndio

®

Filt

ek™

Sup

rem

e

Cle

arfil

™ A

P-X

Sur

efil™

Est

het

Poi

nt 4

Cha

rism

a® F

Mir

is™

Venu

Tetr

ic® C

eram

InTe

nS®

Dyr

act®

AP

Hel

iom

olar

®

Hel

iom

olar

® H

B

polymER izAt ioN SHR iNkAgE

VOC

O i

s no

t th

e ho

lder

of

the

men

tion

ed t

rade

mar

ks.

3.0

2.5

2.0

1.5

1.0

0.5

0

[Vol

.%]

Source: Prof. D. Watts, University of Manchester, 2002. Data on file.

Gra

ndio

®

Sur

efil™

Defi

nite

®

Est

het

Filt

ek™

Sup

rem

e

Sol

itai

re® 2

Poi

nt 4

F illER CoNtENt

VOC

O i

s no

t th

e ho

lder

of

the

men

tion

ed t

rade

mar

ks.

100

90

80

70

60

50

40

30

20

10

0

Filler

con

tent

[w

/w %

]

According to manufacturers data.

Gra

ndio

®

InTe

nS®

Poi

nt 4

Venu

s™

Filt

ek™

Sup

r. (

D)

Filt

ek S

upr.

(I)

Ena

mel

™ H

FO

Est

het

Small nano fillers make a big difference!

Grandio’s Nano Technology leads to enormous clinical benefits

Conventional filler technology creates its particles by

grinding down large pieces of glass ceramic into fine

powders. The lower limit of particles obtainable by

grinding is approx. 0.5 µm or 500 nm. In a conventional

composite, the space between these particles is filled

with resin. Thus, a typical universal restorative has a

filler degree of around 77% w/w. Since polymerization

shrinkage only occurs in the resin matrix, a higher

filler degree would reduce shrinkage. Yet, higher filler

degrees make the materials more difficult to handle

and may lead to enclosures of air bubbles when

applying them in the depth of a cavity.

A material that promises a smooth consistency for

easy handling, adaptation and modeling, plus low

shrinkage values, seems to have been a very elusive

item.

Recently, restoratives using nano technology have

been introduced. The nano particles used in grandio

are silicon dioxide filler particles grown from a liquid

in a sol-gel process to a size of 20 to 60 nm. The

surfaces of these particles are then functionalized

to provide cross-linking capabilities. These nano

particles have the following amazing properties:

• they are not visible to the human eye

• they behave rather like liquids

• they can cross-link after surface modification

• they offer incredibly large surfaces

Currently, nano technology is used in different approa-

ches: e.g. one manufacturer uses nano particles

and nano clusters to produce a restorative aimed at

anterior restorations; an other approach is to combine

nano particles with traditional glass ceramic filler

particles to obtain a high-performance universal

restorative. Here, the traditional fillers form a hard

net work and the nano particles fill the spaces bet-

ween them. This maximizes the packing density and

leaves less resin within the filler/resin matrix. VOCO

has chosen the latter approach for its universal

nano-hybrid composite grandio.

The ratio of resin to fillers determines the physical

properties of the restorative. grandio combines nano

scaled particles with conventional sized glass ceramic

fillers of a select size range. The result: an extremely

high filler loading of 87% by weight, (71.4% by vol)

with an extremely low resin content. This successful

combination leads to grandio’s outstanding physical

properties. grandio out performs the strength of a

hybrid and sets a new standard in surface hardness,

wear and fracture resistance.

Single Shade Simplicity via enhanced translucency

A nano particle is so small that it cannot be seen with

the naked eye. In fact, it is so small that a nano

particle can pass through a beam of visible light

without causing it to diffract. This perfect translu-

cency affords excellent esthetic properties for the

clinician. grandio has a very high degree of trans-

lucency, allowing the clinician to achieve natural,

vital esthetics using only ONE shade! The Shade

Simplicity concept results in fewer shades to store

for the clinician without any esthetic compromise

for the patients.

VOCO has chosen a “Single Shade Simplicity” ap-

proach when it comes to the available shade range.

In general, most clinicians actually solve all their

esthetic cases with 6 to 8 shades grandio offers a

practical choice of 16 shades in either syringes or

Caps. The shade range offers 14 translucent inclu-

ding bleach, incisial shade and 2 opaque shades.

High polish and color retention

Due to small nano fillers, grandio has the high gloss

polishability of a micro filled composite, but without

the physical compromises. grandio’s 30-50% less

resin content compared to micro hybrids gives the

material long term polish and color retention.

Resin is used for all composite manufacturing. Re-

sin is also the primary cause for such concerns as:

polymerization shrinkage, extrinsic staining and free

radicals/ residual monomers. grandio reduces these

problems to a nominal level. The 87% filler content

of grandio results in a nominal resin content of 13%.

This is 30–50% less resin than most micro-hybrids.

grandio has only 1.57% shrinkage, less staining and

a much higher level of biocompatibility.

When hearing about Grandio’s filler degree of 87% w/w,

almost every general practitioner expects to find an

extremely hard material of amalgam-like consistency.

Due to the liquid-like behavior of the nano particles,

however, Grandio is smoother than most conventional

micro-hybrids without slumping. Grandio will not stick

to instruments, thereby avoiding a “pull-back effect.”

Even extruding caps/compules do not require the force

one might expect. Modelling and shaping are easy with

any composite instrument. Polishing and grinding re -

veals the extreme hardness of the material to the dentist

and is best done with diamond-based burs and polishers.

The short light-curing time of 20 seconds with a

standard halogen curing unit saves time. grandio is

also suitable for LED lights. Moreover, grandio is

compatible with all conventional bonding agents.

Standard micro hybrid

unfilled resin

grandio® – filled with

Nano fillers

grandio®

Nano fillers

Standard micro hybrid

micro hybrid fillers

1nm

1nm to a Soccer ball a Soccer ball is to the Earth

=: :

as

the size of a nano particle:

one of the results of the Dental Advisors Editors’ evaluation is: 100% of the evaluators would recommend grandio!

initial situation After preparation Finished grandio® restoration

Source: Dr. Jürgen Manhart, University of Munich, 2003

grandio

NANo tECHNology

grandio

ExCEllENt NAtURAl EStHEtiCS

grandio

87% FillED FoR oUtStANDiNg wEAR AND FRACtURE RESiStANCE

grandio

tERRiFiC HANDliNg pRopERtiES

grandio

30–50% lESS RESiN CoNtENt FoR lESS SHRiNkAgE AND HigHER bioCompAtibility

Page 5: voCo’S ADvANCED NANo tECHNology SEtS gRANDio … · grandio® syringe kit 5-4gm syringes (A1, A2, A3, A3.5, b2),shade guide REF 1800 ... * Prices subject to change. ** at time of

87% Filled

VOCO’s advanced Nano technology sets a new benchmark for composites

SURFACE HARDNESS

VOC

O i

s no

t th

e ho

lder

of

the

men

tion

ed t

rade

mar

ks.

300

250

200

150

100

50

0

Mik

ro V

icke

rs h

ardn

ess

[MH

V]

Source: Prof. Dr. D. Behrend, University of Rostock, 2003. Data on file.

Gra

ndio

®

Filt

ek™

Sup

rem

e

Sur

efil™

Tetr

ic®

Cer

am

Dyr

act®

AP

Defi

nite

®

tHREE boDy wEAR RES iStANCE

VOC

O i

s no

t th

e ho

lder

of

the

men

tion

ed t

rade

mar

ks.

80

70

60

50

40

30

20

10

0

[Wea

r] –

µm

Source: Dabanoglu, A., Kunzelmann, K.H., Hickel, R., Kory, F., Universities of Istanbul, Munich, Three Body Wear Resistance of Resin Composites, DGZ/EFCD-meeting, Munich 2003.

Gra

ndio

®

Filt

ek™

Sup

rem

e

Cle

arfil

™ A

P-X

Sur

efil™

Est

het

Poi

nt 4

Cha

rism

a® F

Mir

is™

Venu

Tetr

ic® C

eram

InTe

nS®

Dyr

act®

AP

Hel

iom

olar

®

Hel

iom

olar

® H

B

polymER izAt ioN SHR iNkAgE

VOC

O i

s no

t th

e ho

lder

of

the

men

tion

ed t

rade

mar

ks.

3.0

2.5

2.0

1.5

1.0

0.5

0

[Vol

.%]

Source: Prof. D. Watts, University of Manchester, 2002. Data on file.

Gra

ndio

®

Sur

efil™

Defi

nite

®

Est

het

Filt

ek™

Sup

rem

e

Sol

itai

re® 2

Poi

nt 4

F illER CoNtENt

VOC

O i

s no

t th

e ho

lder

of

the

men

tion

ed t

rade

mar

ks.

100

90

80

70

60

50

40

30

20

10

0

Filler

con

tent

[w

/w %

]

According to manufacturers data.

Gra

ndio

®

InTe

nS®

Poi

nt 4

Venu

s™

Filt

ek™

Sup

r. (

D)

Filt

ek S

upr.

(I)

Ena

mel

™ H

FO

Est

het

Small nano fillers make a big difference!

Grandio’s Nano Technology leads to enormous clinical benefits

Conventional filler technology creates its particles by

grinding down large pieces of glass ceramic into fine

powders. The lower limit of particles obtainable by

grinding is approx. 0.5 µm or 500 nm. In a conventional

composite, the space between these particles is filled

with resin. Thus, a typical universal restorative has a

filler degree of around 77% w/w. Since polymerization

shrinkage only occurs in the resin matrix, a higher

filler degree would reduce shrinkage. Yet, higher filler

degrees make the materials more difficult to handle

and may lead to enclosures of air bubbles when

applying them in the depth of a cavity.

A material that promises a smooth consistency for

easy handling, adaptation and modeling, plus low

shrinkage values, seems to have been a very elusive

item.

Recently, restoratives using nano technology have

been introduced. The nano particles used in grandio

are silicon dioxide filler particles grown from a liquid

in a sol-gel process to a size of 20 to 60 nm. The

surfaces of these particles are then functionalized

to provide cross-linking capabilities. These nano

particles have the following amazing properties:

• they are not visible to the human eye

• they behave rather like liquids

• they can cross-link after surface modification

• they offer incredibly large surfaces

Currently, nano technology is used in different approa-

ches: e.g. one manufacturer uses nano particles

and nano clusters to produce a restorative aimed at

anterior restorations; an other approach is to combine

nano particles with traditional glass ceramic filler

particles to obtain a high-performance universal

restorative. Here, the traditional fillers form a hard

net work and the nano particles fill the spaces bet-

ween them. This maximizes the packing density and

leaves less resin within the filler/resin matrix. VOCO

has chosen the latter approach for its universal

nano-hybrid composite grandio.

The ratio of resin to fillers determines the physical

properties of the restorative. grandio combines nano

scaled particles with conventional sized glass ceramic

fillers of a select size range. The result: an extremely

high filler loading of 87% by weight, (71.4% by vol)

with an extremely low resin content. This successful

combination leads to grandio’s outstanding physical

properties. grandio out performs the strength of a

hybrid and sets a new standard in surface hardness,

wear and fracture resistance.

Single Shade Simplicity via enhanced translucency

A nano particle is so small that it cannot be seen with

the naked eye. In fact, it is so small that a nano

particle can pass through a beam of visible light

without causing it to diffract. This perfect translu-

cency affords excellent esthetic properties for the

clinician. grandio has a very high degree of trans-

lucency, allowing the clinician to achieve natural,

vital esthetics using only ONE shade! The Shade

Simplicity concept results in fewer shades to store

for the clinician without any esthetic compromise

for the patients.

VOCO has chosen a “Single Shade Simplicity” ap-

proach when it comes to the available shade range.

In general, most clinicians actually solve all their

esthetic cases with 6 to 8 shades grandio offers a

practical choice of 16 shades in either syringes or

Caps. The shade range offers 14 translucent inclu-

ding bleach, incisial shade and 2 opaque shades.

High polish and color retention

Due to small nano fillers, grandio has the high gloss

polishability of a micro filled composite, but without

the physical compromises. grandio’s 30-50% less

resin content compared to micro hybrids gives the

material long term polish and color retention.

Resin is used for all composite manufacturing. Re-

sin is also the primary cause for such concerns as:

polymerization shrinkage, extrinsic staining and free

radicals/ residual monomers. grandio reduces these

problems to a nominal level. The 87% filler content

of grandio results in a nominal resin content of 13%.

This is 30–50% less resin than most micro-hybrids.

grandio has only 1.57% shrinkage, less staining and

a much higher level of biocompatibility.

When hearing about Grandio’s filler degree of 87% w/w,

almost every general practitioner expects to find an

extremely hard material of amalgam-like consistency.

Due to the liquid-like behavior of the nano particles,

however, Grandio is smoother than most conventional

micro-hybrids without slumping. Grandio will not stick

to instruments, thereby avoiding a “pull-back effect.”

Even extruding caps/compules do not require the force

one might expect. Modelling and shaping are easy with

any composite instrument. Polishing and grinding re -

veals the extreme hardness of the material to the dentist

and is best done with diamond-based burs and polishers.

The short light-curing time of 20 seconds with a

standard halogen curing unit saves time. grandio is

also suitable for LED lights. Moreover, grandio is

compatible with all conventional bonding agents.

Standard micro hybrid

unfilled resin

grandio® – filled with

Nano fillers

grandio®

Nano fillers

Standard micro hybrid

micro hybrid fillers

1nm

1nm to a Soccer ball a Soccer ball is to the Earth

=: :

as

the size of a nano particle:

one of the results of the Dental Advisors Editors’ evaluation is: 100% of the evaluators would recommend grandio!

initial situation After preparation Finished grandio® restoration

Source: Dr. Jürgen Manhart, University of Munich, 2003

grandio

NANo tECHNology

grandio

ExCEllENt NAtURAl EStHEtiCS

grandio

87% FillED FoR oUtStANDiNg wEAR AND FRACtURE RESiStANCE

grandio

tERRiFiC HANDliNg pRopERtiES

grandio

30–50% lESS RESiN CoNtENt FoR lESS SHRiNkAgE AND HigHER bioCompAtibility

Page 6: voCo’S ADvANCED NANo tECHNology SEtS gRANDio … · grandio® syringe kit 5-4gm syringes (A1, A2, A3, A3.5, b2),shade guide REF 1800 ... * Prices subject to change. ** at time of

VOCO America, Inc. · 555 Pleasantville Rd Suite 120 NB · Briarcliff Manor, NY 10510 · www.vocoamerica.com · [email protected]

Call 1-888-658-2584

SURFACE HARDNESS

90

80

70

60

50

40

30

20

10

0

Vi

cker

s ha

rdne

ss [

HV]

Source: Dr. S. Schultz, University of Regensburg, 2003. Data on file.

Gra

ndio

®

Com

pogl

ass®

Dyr

act®

AP

Dyr

act®

Xtr

a

Ena

mel

® H

FO

Est

het

Filt

ek™

Sup

rem

e

Z 2

50

Hel

io®M

ol.

InTe

nS®

Mir

is™

Poi

nt 4

Qui

xx®

Sin

fony

®

TPH

Spe

ctru

Tetr

ic®

Cer

am

4 -po iNt tRANSvERSE StRENgtH

140

120

100

80

60

40

20

0

[MP

a]

Source: U. Lohbauer, University of Erlangen, 2003. Data on file.

Gra

ndio

®

Sol

itai

re®2

Tetr

ic® C

eram

InTe

nS®

Defi

nite

®

Hel

iom

olar

® H

B

Dyr

act®

A

P

tHERmAl ExpANS ioN CoEFF iC iENt

60

50

40

30

20

10

0Ther

mal

exp

ansi

on c

oeffi

cien

t [

10

-6/K

]

Source: Dr. H. Wolter, ISC Würzburg, 2003.

Gra

ndio

®

Filt

ek™

Sup

rem

e

Gra

ndio

® F

low

Venu

s™

Pre

mis

e

TPH

3

Est

het

Cer

am X

Evo

Cer

am

Hel

io M

olar

®

Est

het

X® fl

ow

Tetr

ic®

Fl

ow

Venu

s™ F

low

SHR iNkAgE

30

25

20

15

10

5

0

lin.

shr

inka

ge [

µm]

Source: Prof. I. Krejci, University of Geneva, 2003. Data on file.

Gra

ndio

®

InTe

nS®

Tetr

ic® H

B

Defi

nite

®

Pro

digy

™ C

ond.

grandio® is significantly more fracture-

resistant than conventional composites.

VOCO is not the holder of the mentioned trademarks.

Extremely high surface hardness due to the use of

nano-fillers and high filler degree (87% by weight).

VOCO is not the holder of the mentioned trademarks.

Due to its high filler degree, grandio® exhibits

more tooth-like thermal expansion behavior for

long-term marginal integrity and reduced hot-cold

sensitivity.

VOCO is not the holder of the mentioned trademarks.

grandio® exhibits much lower levels of shrinkage

than conventional composites.

VOCO is not the holder of the mentioned trademarks.

CRA Salt Lake City, UT

REALITY Houston, TX

LSUHSC School of Dentistry, New Orleans, LA

The Dental Advisor Ann Arbor, MI

With compliments of your representative:

VC 8

4 0

01

80

0 U

S 0

61

0

tECHNiCAl DAtA :

gRANDio

tHE AwARD w iNN iNg UN ivERSAl NANo HybR iD CompoS itE w itH

oUtStAND iNg pERFoRmANCE AND SUpER ioR HANDl iNg

voCo’S ADvANCED NANo tECHNology SEtS A NEw bENCH mARk FoR CompoSitES

SUpERioRHANDliNg

www.dentaladviso r. com

Editors’ Choice+ + + + +

Filler content 87% by weight

71.4% by vol. DiN 13922

Shrinkage 1.57% by vol. University of manchester, gb

Surface hardness (micro vickers-hardness) 285 mHv University of Rostock, germany

wear rate 14 µm 3 body wear (ACtA 200,000)

Depth of cure 3mm/20 sec. iSo 4049

Radiopacity 250% Al iSo 4049

iNtRo kitS

grandio® syringe kit 5-4gm syringes (A1, A2, A3, A3.5, b2),shade guide REF 1800

grandio® Caps kit 50-0.25gm Caps (A1, A2, A3, A3.5, b2), shade guide REF 1830

REFillS: grandio® – 4gm syringe / grandio® Caps – 20-0.25gm Caps each

shade syringes capsshade syringes capsshade syringes

incisal

opaque A2

opaque A3.5

bl (bleach)

REF 1820

REF 1821

REF 1822

REF 1823

REF 1850

REF 1851

REF 1852

REF 1853

b2

b3

C2

C3

D2

D3

REF 1815

REF 1816

REF 1817

REF 1818

REF 1825

REF 1819

REF 1845

REF 1846

REF 1847

REF 1848

REF 1855

REF 1849

A1

A2

A3

A3.5

A4

b1

REF 1810

REF 1811

REF 1812

REF 1813

REF 1814

REF 1824

REF 1840

REF 1841

REF 1842

REF 1843

REF 1844

REF 1854

caps

Easygloss – one-step-polishing brush

6 diamond impregnated polishing brushes REF 2050

* Prices subject to change. ** at time of product launch

grandio

tHE AwARD wiNNiNg UNivERSAl NANo HybRiD CompoSitE witH oUtStANDiNg pERFoRmANCE AND SUpERioR HANDliNg