VERSITy FEB 20114 UNI BT SOIL - 3 GAS – WATER EQUILIBRIUM Air Water absorptiondesorption X(g)...
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Transcript of VERSITy FEB 20114 UNI BT SOIL - 3 GAS – WATER EQUILIBRIUM Air Water absorptiondesorption X(g)...
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VERSITy
FEB 20114
UNI
BT SOIL - 3
GAS – WATER EQUILIBRIUMAir
Water
absorption desorption
X(g)
X(aq)
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GAS – WATER EQUILIBRIUMPM
FEB 20142 | 2010
Polarity & distribution coefficients
Gas (air)
Water (dissolved)
KH
Kd
Particles (sorbet)
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GAS – WATER EQUILIBRIUMPM
FEB 2014
3 | 2010
POLARHydrophilicHigh water solubility
NON POLARHydrofobic (lipophilic)Low water solubility
Contact angle
Grease & oil
Charged subst (ions)
Soap /detergent
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GAS – WATER EQUILIBRIUMPM
FEB 2014
LOTUS EFFECT
4 | 2010
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GAS – WATER EQUILIBRIUMPM
FEB 20145
PHASE DISTRIBUTION
Koc and Kow relationship, From Curtis et al.
Kd = Cx,s/Cx,aq
Kd = KOC·fOC
(KOC = Kd/fOC)
KOW = Cx,oct/Cx,aq
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GAS – WATER EQUILIBRIUMPM
FEB 2014
”ABDULS FORMULA”Calculation of Kd based on KOW and foc:
Log(Kd) = 1.04·log(KOW)+log(foc) – 0.84 Valid for log(KOW) < 5 and foc > 1 % Ref: Miljøstyrelsen (2002) Guidelines on Remediation of Contaminated Sites. (p248)
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GAS – WATER EQUILIBRIUMPM
FEB 2014
A BALLOON WITH ATMOSPHERIC AIR CONTAIN 20 PPM (VOL) CO2. THE AIR IS HEATED AND EXPANDS. AS CONSEQUENCE OF THE EXPANSION THE CO2 CONCENTRATION IN THE BALLOON:1. Increases 2. Is unchanged 3. Decreases 4. I don't know...
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CONCENTRATION
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GAS – WATER EQUILIBRIUMPM
FEB 2014
THE BALLOON AGAIN: WHAT HAPPENS AS CONCEQUENCE OF THE EXPANSION WITH THE CO2 CONCENTRATIN IN MG/L ?1. It increases 2. It is unchanged 3. it decreases 4. I don't know
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GAS – WATER EQUILIBRIUMPM
FEB 20149
Substances Problem Sources
Heavy metals(Hg, Pb, Cd…)
Toxic & chronic effectsBio accumulation(strong sorption - Kd)
IndustryNon-point deposition: smoke, sludge and fertilizer
Mineral oil products(BTX, MTBE, PAH...)
Health. Taste + smell(indoor climate, water + skin contact)
Gasoline stations + tanks for oil heating
Chlorinated solvents(PCE, TCE..)
Cancer, toxicity.Bioaccumulation(indoor climate + water)
Dry cleaningMetal processingGraphic industry
PbCr
PCEBTX PAHThe Usual
Suspects…