Value added products from rice bran and its applicationricebranoil.co.in/pdf/B19- new- Presentation...
Transcript of Value added products from rice bran and its applicationricebranoil.co.in/pdf/B19- new- Presentation...
Fumi Tsuno
Tsuno Foods & Rice Fine Chemicals Co., Ltd.
Value added products from rice bran and
its application
Foundation : Feb. 1947
Incorporated : Feb. 1949
President : Fumi Tsuno
Capital : Tsuno Foods=JPY 50 million
Tsuno Rice=JPY 50 million Tsuno Transport.=JPY 15 million
Tsuno Development=JPY 3 million
Employees : about 350
Sales : about JPY 20 billion
Factories : Wakayama, Osaka, Takarazuka, Yashiro, Saitama
R&D : Wakayama, Yashiro
Outline of TSUNO
Hiroshima office
Himeji office
Takarazuka factory
Yashiro factory
Kantou factory(Saitama)
Wakayama factory and head office
Tokyo office
Osaka factory
Factories and Offices in Japan
The Ratio of Nutrient Components
in White Rice to Brown Rice
90% 90%
81%
30% 94%
15%
30%
50%
19%
29%
34%
90%
34%
70%
34%
20%
45%
20%
24%
6.0%
40%
vitamin B1
(0.54 mg)
vitamin B2
(0.060 mg)
energy
(350 Kcal) moisture
(16 g) protein
(6.8 g)
lipid
(2.7 g)
carbohydrate
(74 g)
dietary
fiber
(3.0 g)
ash
(1.2 mg)
calcium
(9.0 mg)
magnesium
(110 mg) phosphorus
(290mg) iron
(2.1 mg)
sodium
(1.0 mg)
potassium
(230 mg)
zinc
(1.8 mg)
manganese
(2.1 mg)
niacin
(6.3 mg)
vitamin B6
(0.45 mg)
vitamin E
(1.4 mg)
folate (27 µg)
White
rice
The figures in parentheses indicate the weight of each component per 100 g of brown rice
rice bran oil
tocopherol
tocotrienol
-oryzanol
ferulic acid
cerebroside
polycosanol
sterol
inositol
phytic acid rice bran protein
Rice Bran
94 % of carbohydrates is
contained in white rice,
and 70 % of lipid in rice
bran.
Raw material Performance of antioxidation
About Special Rice Oil
4 Endurance !
5 No bad smell !
6 No bad taste !
non GMO
Allergen-free
Made in Japan
1
2
3
7
8
9
For Long term preservation
For Skin care
For Health
Rice bran oil canola oil Soy bean oil
4. Endurance !
After heating 180℃, 48 hr
Performance of antioxidation
acrolein
propanal Canola oil
Rice bran oil
66ppb
344ppb
1270ppb
287ppb
Analysis of the smell of the oil (Heating at 180℃, 2hr)
Smell Taste
bad
good
CH2 O
O
CH3
Y. Endo et al. (2013) J Am Oil Chem Soc:959 - 964
5. No bad smell ! !
oleic acid linoleic acid linolenic acid Vitamin E γ - Oryzanol
Rice bran oil 45% 35% 1% 1000 ppm 0.2 %
Canola oil 63% 19% 9% 520 ppm 0 %
6. No bad taste !
smell volatile substance
FOOD
Smell and taste mechanism
taste water soluble substances
acrolein propanal
b.P ≒ 60℃ Water soluble
- Oryzanol
Tocotrienol
Vitamin-E
Plant Sterol
Improvement in menopausal symptoms
Improvement in hyperlipemia
Antioxidant
Arteriosclerosis prevention effect
Cholesteremia prevention effect
Antitumor effect
Antioxidant
Cholesterol lowering properties
Cholesterol Lowering effect
Hyperlipemia prevention effect
Active ingredients of Rice Bran Oil
7. For health
Administered
Ingredients
Administered
Dose Pharmacologic Effect Reference
Rice bran oil 60 g ↓TC, LDL-C Suzuki & Oshima ,1970
Rice bran oil 50 g ↓TC, LDL-C, ↑HDL-C Tsuji et al., 1989
Rice bran oil 50 g ↓TC, LDL-C, TG Reghuram et al., 1989
-Oryzanol 300 mg ↓TC, LDL-C, ↑HDL-C Yoshino et al., 1989a,
1989b
-Oryzanol 100 mg ↓TC, LDL-C, Apo B Sasaki et al., 1990
-Oryzanol 300 mg ↓TC, LDL-C, TG, ↑HDL-C Ishihara et al., 1982
Ishihara, 1984
Tocotrienol 200 mg
↓TC, LDL-C, Apo B
↓Lpa, platelet aggregation
Qureshi et al. 1997
Effect of Rice Bran Oil and its Ingredients
on Human Lipid Metabolism
Sugano, Shokuhin Kako Gijutsu, 22(1), 26-30, 2002, in Japanese
Fiscal year 1999 Vegetable oil JAS ranking debrief report, p. 72. Japan Institute of oil inspection Foundation.(2000)
7.9
13.6
12.5
16.5
23.4
21.1
0 5 10 15 20 25
Safflower Oil
Cotton Seed Oil
Soybean Oil
Corn Oil
Rice Bran Oil
Canola Oil
(hrs)
Oxidative Stability of Vegetable Oil (AOM Test)
The longer bar represents the higher the oxidative stability. Rice bran oil showed
the highest oxidative stability among six types of vegetable oils.
The comparison of oxidative stability among six vegetable oils by Active Oxygen Method (AOM)
8. For Long term preservation
Researcher (year) prescription effect
M. Kamimura et al. (1963)1)
30 mg/day
1 week
skin temperature (increase)
blood amount of the skin surface (increase)
M. Kitamura et al. (1977)2)
300 mg/day
1~2 month
Urticaria (improve)
Alopecia (improve)
Pururitus (improve)
R. Hayakawa et al. (1994)3)
100 mg/day
4 month
skin surface lipid (increase)
(1 month later)
1)M. Kamimura et al.:Dermatology and urology , 30, 5, 341-344 (1963) 2)M.kitamura et al.: Journal of New Remedies & Clinics, 26, 11, 2011-2022 (1977) 3)R. Hayakawa et al.: Acta Dermatologica Kyoto, 89, 1, 115-119 (1994)
9. For skin care
・humidity retention improvement ・Roughness improvement
Rice Bran Oil PRO-15 30
Appearance Clear, pleasant to the palate & lovely
flavor
Red brown
semisolid
Color (Lovibond
method)
Yellow 30
Red 3.5
Yellow 40
Red 6.0 N/A
Water & impurities 0.1 0.1 N/A
Acid value 0.1 0.2 3.0
Saponification value 180 - 195 180 - 195 130 - 150
Iodine value 92 - 115 92 - 115 N/A
Unsaponifiables 3.5% 6.0% N/A
Peroxide value 2.0meq/kg 10.0meq/kg 5.0meq/kg
-Oryzanol 0.1 – 0.3%* 1.2 – 1.7% 28.5 – 31.5% *Reference value
The above is the values as of March 2013
RBO, PRO-15, 30
VALUE ADDED PRODUCTS
FROM RICE BRAN
★INOSITOL
★GAMMA-ORYZANOL ★FERULIC ACID
★IP6
★WATER SOLUBLE CONCENTRATES ★RICE MAGNESIUM ★PROTEIN
★OIL SOLUBLE CONCENTRATES
★GLYCOSYL CERAMIDE ★POLYCOSANOL
Antioxidant
Anti-inflammatory effect
Anti-diabetic effect
Anti-allergic effect
Improvement in hyperlipemia
Improvement in menopausal symptoms
Improvement in stress-related disorder Chronic gastritis, irritable colon syndrome, ulcer
Autonomic nerve imbalance
Unique compound found in rice
H3CO
HO
O
O
Gamma Oryzanol
• Antioxidant effect
• Antibacterial effect
• Prevention of discoloration
• Raw material of Vanillin
• Alzheimer disease healing effect
• Prevention of muscular fatigue, hypertention
• Antitumor activity of breast, liver and colon
Polyphenol from rice bran Succeeded in the development of effective
extraction method in cooperation with
Wakayama Prefecture Technology Center
H3CO
HO
OH
O
Ferulic Acid
Phytosterol + Triterpene alcohol: 15%
Tocopherol: 3.0%
Tocotrienol: 3.0%
Oil Soluble Concentrates
• Antioxidant effect
• Hypocholesterolemic effect
• Suppressive effect on hyperlipidemia
• Anticancer effect
OH
OHNH
O
OH
OH
OHO
O
CH2OH
Main component of cerebroside
(composed of 9 to 11 kinds of molecular species)
Glycosyl Ceramide
• Moisture protection to dry skin and improvement
in atopic dermatitis (oral ingestion)
• Whitening ability (suppression of melanin formation )
• Immunostimulating effect
• Antiaging effects
• Anticancer effect
(suppression of induction of colon cancer)
OH
Main component, Octacosanol (C28)
Polycosanol
• Inhibition of cholesterol synthesis
• Reduction in sdLDL
• Antithrombogenic activity
• Improvement effect of instantaneous force and
enduring strength
• Increase in basal metabolism
• Vitamin B group component (Rich in colostrum, Essential vitamin for infant)
• Half sweetness of sucrose
• Prevention of fat accumulation in the liver
• Depression of serum cholesterol
Performance of Vitamin B
Sugar alcohol from rice bran
OH
OH
OH
OH
OH
OH
12 3
4
5
6
Inositol
• pH adjustment effect
• Chelating effect
• Antioxidant action
• Approved as GRAS in the US
Acidic solution from
rice bran O
O
O
P OH
P
PO
HO
O
P OH
O
HO
P OHHO
O
P
O
OHHOOH
HO
OH
OH
O
O
IP6 (Phytic acid / Phytin)
• Defatted rice bran extract
• Rich in physiologically functional ingredients
– dietary fiber, a natural vitamin B group (B1, B2 and B6)
• High proportion of minerals including calcium and
magnesium
• Contains about 30% of a physiological activities substance
IP6 (Phytic acid)
• Antioxidant effect
• Chelating effect
• Free from GMO
Water-soluble concentrates
Equivalent magnesium supplementation quality as that
of other sources
Soluble in acidic solution
Tasteless & Odorless
It mainly exists as magnesium phosphate, and contains
more than 12.0% magnesium.
Rice Magnesium
(Magnesium Phosphate)
The first magnesium extracted
from plant origin
Unique protein from rice bran
carrying health function
• Obtained from defatted rice bran
• Well-balanced amino acid composition
• Different from protein composition of
white rice
Rice Bran Protein
(g/100g edible portion)
Amino acid composition
Amino acid value: 96
(by use of the FAO/WHO/UNU (1985) amino acid
requirement pattern for children of preschool age)
Arg 6.52 Ala 4.08
Lys 3.74 Gly 3.69
His 2.17 Pro 2.83
Phe 3.08 Glu 9.02
Thy 2.19 Ser 3.02
Leu 4.72 Thr 2.47
Ile 2.46 Asp 5.54
Met 1.27 Trp 1.07
Val 3.94 Cys 1.03
Extracted naturally from rice bran
GMO Free, BSE / TSE Free, non allergy
GMP Halal Kosher
High Quality under Strictly
Control Management
ISO 9001 + 14001
Tremendous Possibilities of Products from Rice Bran
Antioxidants
UV Absorbers
Lipid Metabolic Stimulator
Anti-Bacterial Materials
Emulsifier
Liver Function Promoters
Natural Mineral Chelator
Physiologically Functional Oil
Moisturizer
Hair Grower
Emollient
Whitening Agent
Bath Agent
Antiaging