Valence Technology, Inc. Saphion “Safety – Built In” · PDF fileValence...

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Valence Technology, Inc. Saphion ® “Safety – Built In” Alastair Johnston EMEA Sales Director Version: 15 th November 2005

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Page 1: Valence Technology, Inc. Saphion “Safety – Built In” · PDF fileValence Technology, Inc. Saphion® “Safety – Built In” Alastair Johnston EMEA Sales Director Version: 15th

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Valence Technology, Inc.

Saphion® “Safety – Built In”

Alastair JohnstonEMEA Sales Director

Version: 15th November 2005

Page 2: Valence Technology, Inc. Saphion “Safety – Built In” · PDF fileValence Technology, Inc. Saphion® “Safety – Built In” Alastair Johnston EMEA Sales Director Version: 15th

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Corporate Overview1989: Founded as a R&D company focused on Lithium-ion polymer technology

>600 issued and pending patents worldwide

2002: New management team from Dell, emphasis on Sales and Marketing

2003: Launched Saphion® Lithium-ion technology: First phosphate based battery chemistry on the market

2003: Launched first N-Charge™ Power System: Consumer product showcasing Saphion technology

2004: Launching K-Charge™ & U-Charge™ Power System: Large format energy storage system.

2004: Move into the cell pack markets with the IFR 18650 and P545 cells.

2004: Set up Valence owned powder plant and pack assembly factory in China

2004: Set up EMEA Sales Office, in Mallusk, N.Ireland

2006: Q1 Launch of U Charge high volume production

Page 3: Valence Technology, Inc. Saphion “Safety – Built In” · PDF fileValence Technology, Inc. Saphion® “Safety – Built In” Alastair Johnston EMEA Sales Director Version: 15th

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Valence Locations & Partners

SinbonN Charge pack assembly

Battery OEMChinaLi-polymer cellsCylindrical cells

Mallusk, N.IrelandSales, EngineeringEmployees: 5

Advanced Labs, EnglandAdvanced Battery ResearchEmployees: 4

Henderson, NevadaBattery TestEmployees: 20

Austin, Texas, HQEngineering, SalesEmployees: 45

Cell Pack Assembly PlantSuzhouEmployees:130

Powder PlantSuzhouEmployees: 50

System Engineering ShanghaiEmployees: 30

Page 4: Valence Technology, Inc. Saphion “Safety – Built In” · PDF fileValence Technology, Inc. Saphion® “Safety – Built In” Alastair Johnston EMEA Sales Director Version: 15th

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Saphion Technology & Safety®

Page 5: Valence Technology, Inc. Saphion “Safety – Built In” · PDF fileValence Technology, Inc. Saphion® “Safety – Built In” Alastair Johnston EMEA Sales Director Version: 15th

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The PO4 advantage

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P Co

O O

Coordination and location determine bond distance and

strength

Tightly bound Oxygen = safety

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Relative bond energies

Raman Spectroscopy stretching bands:

P-O : 1100 cm-1

Co-O (LCO): 540 cm-1

The P-O bond is stronger than the Co-O bond.

LCO PO4

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LiFePO4 vs. LiCoO2: DSC

LiCoO2: large exotherm onset at 147°C results in cell safety problemLiFePO4 exotherm smaller and onset at much higher temperature

LiCoO2 only Whole cellJES 146(9) Maleki et al. (Motorola): commercial LiCoO2/graphite cell charged to 4.2V

JES 148(3) Yamada et al.

Li0.5CoO2 0.5LiCoO2 +1/6Co3O4 + 1/6O2

Co3O4 3CoO + ½ O2

Page 8: Valence Technology, Inc. Saphion “Safety – Built In” · PDF fileValence Technology, Inc. Saphion® “Safety – Built In” Alastair Johnston EMEA Sales Director Version: 15th

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Various Chemistries Reactivity

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P1a LMO LCO LNO

Hea

t Flo

w (J

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Theoretical basis for safety advantages of phosphates

Intrinsic Safety of Cathode Materials

Page 9: Valence Technology, Inc. Saphion “Safety – Built In” · PDF fileValence Technology, Inc. Saphion® “Safety – Built In” Alastair Johnston EMEA Sales Director Version: 15th

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Phosphate Safety Comparison Video

http://www.valence.com/SafetyVideo.asp

Phosphate remains thermally stable under extreme abuse

Page 10: Valence Technology, Inc. Saphion “Safety – Built In” · PDF fileValence Technology, Inc. Saphion® “Safety – Built In” Alastair Johnston EMEA Sales Director Version: 15th

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Abuse Characterization Summary

����������Abuse RequirementsUL1642 Third Edition (april 26, 1995), latest ammendment Jun 24, 1999

Test Description Saphion LCOElectrical Tests

section 10 short curcuit testat room temp connect terminals with wire <0.1mOhm Pass Passat 60C connect terminals with wire <0.1mOhm Pass Pass

section 11a Abnormal Charge a 3 times recommended charge rate for 48hr minimum Pass PassMechanical Tests

section 12 crush applied load of 13kN between flat plates Pass Passsection 13 impact drop 20lbs from 2 ft onto 5/8in diameter bar Pass Passsection 14 shock 75G initial, 125-175G peak Pass Passsection 15 vibration ramp 10-55-10Hz in 90 minutes, 1.6mm excursion Pass Pass

Environmental Testssection 18a heating (hot box) ramp to 150C, hold for 10 minutes Pass Passsection 18b temperature cycling ramp temp between -40 and 70C, 10X Pass Passsection 18c altitude simulation 6hrs at 11.6kPa Pass Pass

Abuse CharacterizationTest Description Saphion LCO

Nail Penetration JSBA standard Pass FailRound Bar Crush slow crush to deform cell to induce short Pass FailSeries/Parallel testing simulate proposed battery design

3 parallel Nail penetration do safety devices in cell stop propagation Pass Fail4 series NP on during charge do safety devices in cell stop propagation Pass Fail

Hot Box (extended) UL hot box with 150C hold Pass Failadditional failsafe testing application test to fail

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Round Bar Crush Test

Round Bar Crush Test - Oxide18650 S/N 162153 - Temperature vs. Voltage

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Cell vented with heavy sparks and heavy smoke.

Round Bar Crush Test - Phosphate18650 S/N 341387 - Temperature vs. Voltage

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Overcharge Test - Phosphate 18650 (2 Cells in parallel supply set to 3.6A, 5.0V)

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Cell insulated in styrofoam to simulate battery enclosure

Overcharge Test - Oxide 18650 (2 Cells in Parallel supply set to 3.6A, 5.0V)

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Cell insulated in styrofoam to simulate battery enclosure

Overcharge Test

Excess Lithium in cobalt cells causes cell to continue to charge until “safety” device is activated. Despite this activation, the cell goes into thermal runaway 15 minutes later, reaching 760C.

Saphion® cells have NO excess lithium. After fully charging, the cell quickly reaches the 5V setpoint and the current tapers. The temperature reaches only 50C.

Page 13: Valence Technology, Inc. Saphion “Safety – Built In” · PDF fileValence Technology, Inc. Saphion® “Safety – Built In” Alastair Johnston EMEA Sales Director Version: 15th

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Nail Pen Test - Oxide 18650's S/N 204040 - Temp. vs. Voltage, Current

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Nail penetrated cell

Nail Pen Test - Phosphate 18650's S/N 341488 - Temp. vs. Voltage, Current

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3 cells in parallel with cells mounted side by side numbered 1-3 from left to right. Nail Pen cell #2.

Nail penetrated cell

Nail Penetration Test

Page 14: Valence Technology, Inc. Saphion “Safety – Built In” · PDF fileValence Technology, Inc. Saphion® “Safety – Built In” Alastair Johnston EMEA Sales Director Version: 15th

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Page 15: Valence Technology, Inc. Saphion “Safety – Built In” · PDF fileValence Technology, Inc. Saphion® “Safety – Built In” Alastair Johnston EMEA Sales Director Version: 15th

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Products and Segments

Watt Hours

K-Charge

N-Charge

U-Charge

Cells

OEMs and Pack Builders

Portable Power50 – 300 Wh

Motive Power500 – 85000 Wh

Backup PowerKWh - MWh

Page 16: Valence Technology, Inc. Saphion “Safety – Built In” · PDF fileValence Technology, Inc. Saphion® “Safety – Built In” Alastair Johnston EMEA Sales Director Version: 15th

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N-Charge™ PowerSystem Family

A family of power sources to facilitate complete mobility

Sleek polymer models for thin and light notebooks

Modular and scaleable models for DTR and mainstream notebooks

Lightweight and compact for ultimate portability

Uses notebook PC adapter for recharging

Provides fast recharge and long cycle life

Page 17: Valence Technology, Inc. Saphion “Safety – Built In” · PDF fileValence Technology, Inc. Saphion® “Safety – Built In” Alastair Johnston EMEA Sales Director Version: 15th

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U-Charge™ Power System

A lightweight, high-energy alternative to conventional lead acid batteries designed for wheelchairs, scooters, ebikes and more…

High performance, intelligent, reliable batteries

Safe, environmentally friendly, Saphion® Lithium-ion technology

Low maintenance, long cycle life = Lower lifetime costs!

Twice the runtime and 1/3 less weight compared to Lead Acid

Fits easily into established 12V and 24V platforms

Page 18: Valence Technology, Inc. Saphion “Safety – Built In” · PDF fileValence Technology, Inc. Saphion® “Safety – Built In” Alastair Johnston EMEA Sales Director Version: 15th

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K-Charge™ Power System

Kilowatt to megawatts of energy storage for the utility, network and vehicular markets

High performance, intelligent, reliable batteries

The safest Lithium-ion technology available

Flexible form factor

Less volume and lower weight

Fast recharge time, excellent cycle life

Page 19: Valence Technology, Inc. Saphion “Safety – Built In” · PDF fileValence Technology, Inc. Saphion® “Safety – Built In” Alastair Johnston EMEA Sales Director Version: 15th

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Segway Pack Technical Data

* Rated value, however 30A continuous has been tested with no ill effects.

30 ampsPeak Current

16 Amps *Continuous Current

400 WhPack Capacity

92Number of cells per pack

Valence Saphion IFR 18650eCell Used

5.5 kgsWeight

360 x 150 x 82Max Dimensions (l x w x h) mm