VACUUM PIPE CLEANER - media.bluestonepim.com · lifting the upper and lower lids. ... Eye injuries...

Wilhelmsen Ships Service AS

VACUUM PIPE CLEANER

Catalogue number: 740498

Version No: 11.33

Safety Data Sheet (Conforms to Regulation (EC) No 2015/830)

Issue Date: 05/05/2016

Print Date: 10/05/2016

Initial Date: 18/04/2016

S.REACH.NOR.EN

SECTION 1 IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY / UNDERTAKING

1.1.Product Identifier

Product name VACUUM PIPE CLEANER

Synonyms 740498

Other means ofidentification

740498

1.2. Relevant identified uses of the substance or mixture and uses advised against

Product CategoryChemical

PC35 Washing and cleaning products (including solventbased products)

Relevant identifieduses

Acid cleaner - Product declaration number offshore: 304539

Uses advised against Not Applicable

1.3. Details of the supplier of the safety data sheet

Registered companyname

Wilhelmsen Ships Service AS Wilhelmsen Ships Service AS*For quotations or productinformation contact your localCustomer Services

Address Strandveien 20 Lysaker 1366 NorwayWillem Barentszstraat 50 Rotterdam3165AB Netherlands

For other suppliers and/or contactdetails please visit our website -https://wssdirectory.wilhelmsen.com/#/networkdirec Norway

Telephone +47 67 58 40 00 +31 10 4877 777 Not Available

Fax Not Available +31 10 4877888 Not Available

Websitehttps://www.wilhelmsen.com/services/maritime/compan

https://www.wilhelmsen.com/services/maritime/compa

https://wssdirectory.wilhelmsen.com/#/networkdirec

Email [email protected] [email protected] Not Available

1.4. Emergency telephone number

Association /Organisation

Giftinformasjonssentralen - 24 timerInternational NCEC (24hr)/Dutchnat. poison centre

Not Available

Emergency telephonenumbers

+47 22591300 + 44 1865 407333 Not Available

Other emergencytelephone numbers

Not Available + 31 30 274 88 88 Not Available

SECTION 2 HAZARDS IDENTIFICATION

2.1.Classification of the substance or mixture

Considered a hazardous mixture according to Reg. (EC) No 1272/2008 and their amendments. Not classified as Dangerous Goods fortransport purposes.

Classificationaccording to

Skin Corrosion/Irritation Category 2, Eye Irritation Category 2

Continued...

regulation (EC) No

1272/2008 [CLP] [1]

Legend:1. Classified by Chemwatch; 2. Classification drawn from EC Directive 67/548/EEC - Annex I ; 3. Classification drawn from ECDirective 1272/2008 - Annex VI

2.2. Label elements

CLP label elements

SIGNAL WORD WARNING

Hazard statement(s)

H315 Causes skin irritation.

H319 Causes serious eye irritation.

Supplementary statement(s)Not Applicable

CLP classification (additional)Not Applicable

Precautionary statement(s) Prevention

P101 If medical advice is needed, have product container or label at hand.

P102 Keep out of reach of children.

P103 Read label before use.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

Precautionary statement(s) Response

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P337+P313 If eye irritation persists: Get medical advice/attention.

P302+P352 IF ON SKIN: Wash with plenty of water and soap.

P332+P313 If skin irritation occurs: Get medical advice/attention.

P362+P364 Take off contaminated clothing and wash it before reuse.

Precautionary statement(s) StorageNot Applicable

Precautionary statement(s) DisposalNot Applicable

REACh - Art.57-59: The mixture does not contain Substances of Very High Concern (SVHC) at the SDS print date.

SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS

3.1.SubstancesSee 'Composition on ingredients' in Section 3.2

3.2.Mixtures

1.CAS No2.EC No3.Index No4.REACH No

%[weight] Name Classification according to regulation (EC) No 1272/2008 [CLP]

1.5329-14-62.226-218-83.016-026-00-04.01-2119488633-28-XXXX,01-2119846728-23-XXXX

5-10Eye Irritation Category 2, Skin Corrosion/Irritation Category 2, Chronic Aquatic Hazard

Category 3; H319, H315, H412 [3]

Legend: 1. Classified by Chemwatch; 2. Classification drawn from EC Directive 67/548/EEC - Annex I ; 3. Classification drawn from EC

sulfamicacid


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Directive 1272/2008 - Annex VI 4. Classification drawn from C&L

SECTION 4 FIRST AID MEASURES

4.1. Description of first aid measures

General

If skin or hair contact occurs:Immediately flush body and clothes with large amounts of water, using safety shower if available. Quickly remove all contaminated clothing, including footwear. Wash skin and hair with running water. Continue flushing with water until advised to stop by the Poisons InformationCentre. Transport to hospital, or doctor.

If this product comes in contact with the eyes: Immediately hold eyelids apart and flush the eye continuously with running water. Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionallylifting the upper and lower lids. Continue flushing until advised to stop by the Poisons Information Centre or a doctor, or for at least 15 minutes. Transport to hospital or doctor without delay. Removal of contact lenses after an eye injury should only be undertaken by skilled personnel. If fumes or combustion products are inhaled remove from contaminated area. Lay patient down. Keep warm and rested. Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aidprocedures. Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocketmask as trained. Perform CPR if necessary. Transport to hospital, or doctor, without delay. For advice, contact a Poisons Information Centre or a doctor at once. Urgent hospital treatment is likely to be needed.

If swallowed do NOT induce vomiting. If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway andprevent aspiration. Observe the patient carefully. Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious. Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink. Transport to hospital or doctor without delay.

Eye Contact

If this product comes in contact with the eyes: Immediately hold eyelids apart and flush the eye continuously with running water. Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionallylifting the upper and lower lids. Continue flushing until advised to stop by the Poisons Information Centre or a doctor, or for at least 15 minutes. Transport to hospital or doctor without delay. Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.

Skin Contact

If skin or hair contact occurs:Immediately flush body and clothes with large amounts of water, using safety shower if available. Quickly remove all contaminated clothing, including footwear. Wash skin and hair with running water. Continue flushing with water until advised to stop by the Poisons InformationCentre. Transport to hospital, or doctor.

Inhalation

If fumes or combustion products are inhaled remove from contaminated area. Lay patient down. Keep warm and rested. Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aidprocedures. Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocketmask as trained. Perform CPR if necessary. Transport to hospital, or doctor, without delay.

Ingestion

For advice, contact a Poisons Information Centre or a doctor at once. Urgent hospital treatment is likely to be needed.

If swallowed do NOT induce vomiting. If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway andprevent aspiration. Observe the patient carefully. Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious. Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink. Transport to hospital or doctor without delay.

4.2 Most important symptoms and effects, both acute and delayedSee Section 11


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4.3. Indication of any immediate medical attention and special treatment neededTreat symptomatically.For acute or short term repeated exposures to strong acids:

Airway problems may arise from laryngeal edema and inhalation exposure. Treat with 100% oxygen initially. Respiratory distress may require cricothyroidotomy if endotracheal intubation is contraindicated by excessive swelling Intravenous lines should be established immediately in all cases where there is evidence of circulatory compromise. Strong acids produce a coagulation necrosis characterised by formation of a coagulum (eschar) as a result of the dessicating action of the acid onproteins in specific tissues.

INGESTION:Immediate dilution (milk or water) within 30 minutes post ingestion is recommended.

DO NOT attempt to neutralise the acid since exothermic reaction may extend the corrosive injury. Be careful to avoid further vomit since re-exposure of the mucosa to the acid is harmful. Limit fluids to one or two glasses in an adult. Charcoal has no place in acid management. Some authors suggest the use of lavage within 1 hour of ingestion.

SKIN:Skin lesions require copious saline irrigation. Treat chemical burns as thermal burns with non-adherent gauze and wrapping. Deep second-degree burns may benefit from topical silver sulfadiazine.

EYE:Eye injuries require retraction of the eyelids to ensure thorough irrigation of the conjuctival cul-de-sacs. Irrigation should last at least 20-30 minutes.

DO NOT use neutralising agents or any other additives. Several litres of saline are required. Cycloplegic drops, (1% cyclopentolate for short-term use or 5% homatropine for longer term use) antibiotic drops, vasoconstrictive agents or artificialtears may be indicated dependent on the severity of the injury. Steroid eye drops should only be administered with the approval of a consulting ophthalmologist).

[Ellenhorn and Barceloux: Medical Toxicology]

SECTION 5 FIREFIGHTING MEASURES

5.1. Extinguishing mediaThere is no restriction on the type of extinguisher which may be used. Use extinguishing media suitable for surrounding area.

5.2. Special hazards arising from the substrate or mixture

Fire Incompatibility None known.

5.3. Advice for firefighters

Fire Fighting

Alert Fire Brigade and tell them location and nature of hazard. Wear breathing apparatus plus protective gloves in the event of a fire. Prevent, by any means available, spillage from entering drains or water courses. Use fire fighting procedures suitable for surrounding area.

DO NOT approach containers suspected to be hot.

Fire/Explosion Hazard

Non combustible. Not considered to be a significant fire risk. Acids may react with metals to produce hydrogen, a highly flammable and explosive gas. Heating may cause expansion or decomposition leading to violent rupture of containers. May emit corrosive, poisonous fumes.

May emit poisonous fumes. May emit corrosive fumes.

SECTION 6 ACCIDENTAL RELEASE MEASURES

6.1. Personal precautions, protective equipment and emergency proceduresSee section 8

6.2. Environmental precautionsSee section 12

6.3. Methods and material for containment and cleaning up

Minor Spills

Clean up all spills immediately. Avoid breathing vapours and contact with skin and eyes. Control personal contact with the substance, by using protective equipment. Contain and absorb spill with sand, earth, inert material or vermiculite. Wipe up.

Major Spills

Moderate hazard. Clear area of personnel and move upwind. Alert Fire Brigade and tell them location and nature of hazard.


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Wear breathing apparatus plus protective gloves. Prevent, by any means available, spillage from entering drains or water course.

6.4. Reference to other sectionsPersonal Protective Equipment advice is contained in Section 8 of the SDS.

SECTION 7 HANDLING AND STORAGE

7.1. Precautions for safe handling

Safe handling

Avoid all personal contact, including inhalation. Wear protective clothing when risk of exposure occurs. Use in a well-ventilated area. Prevent concentration in hollows and sumps.

DO NOT enter confined spaces until atmosphere has been checked.

Fire and explosionprotection

See section 5

Other information

7.2. Conditions for safe storage, including any incompatibilities

Suitable container

Lined metal can, lined metal pail/ can. Plastic pail. Polyliner drum. Packing as recommended by manufacturer. Check all containers are clearly labelled and free from leaks.

Storageincompatibility

Sulfamic acid:reacts violently with chlorine, nitric acid, fuming nitric acid, strong bases, chlorine, hypochlorous acid, strong oxidisingagents, sulfides, cyanides or when heated with nitrates, nitrites is strongly acidic in aqueous solution hydrolyses to ammonium bisulfate at elevated temperatures is incompatible with alkylene oxides, aliphatic amines, alkanolamines, amides, ammonia, epichlorohydrin, organicanhydrides, isocyanates, metal nitrates/ nitrites, oxidisers, vinyl acetate, common metals and their alloys, water

Contact with metals may result in the evolution of hydrogen (H2) which can form explosive mixtures in air.

Avoid strong bases.

+ X + O + + +

X — Must not be stored together

0 — May be stored together with specific preventions

+ — May be stored together

7.3. Specific end use(s)See section 1.2

SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION

8.1. Control parameters

DERIVED NO EFFECT LEVEL (DNEL)

Not Available

PREDICTED NO EFFECT LEVEL (PNEC)

Not Available

OCCUPATIONAL EXPOSURE LIMITS (OEL)

INGREDIENT DATA

Source Ingredient Material name TWA STEL Peak Notes

Not Available Not Available Not Available Not Available Not Available Not Available Not Available

EMERGENCY LIMITS


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Ingredient Material name TEEL-1 TEEL-2 TEEL-3

sulfamic acid Sulfamic acid 9.5 mg/m3 100 mg/m3 630 mg/m3

Ingredient Original IDLH Revised IDLH

sulfamic acid Not Available Not Available

8.2. Exposure controls

8.2.1. Appropriateengineering controls

Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designedengineering controls can be highly effective in protecting workers and will typically be independent of worker interactions toprovide this high level of protection.The basic types of engineering controls are:Process controls which involve changing the way a job activity or process is done to reduce the risk.Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker andventilation that strategically "adds" and "removes" air in the work environment. Ventilation can remove or dilute an aircontaminant if designed properly.

8.2.2. Personalprotection

Eye and faceprotection

Safety glasses with unperforated side shields may be used where continuous eye protection is desirable, as in laboratories;spectacles are not sufficient where complete eye protection is needed such as when handling bulk-quantities, where there isa danger of splashing, or if the material may be under pressure.Chemical goggles.whenever there is a danger of the material coming in contact with the eyes; goggles must be properlyfitted.Full face shield (20 cm, 8 in minimum) may be required for supplementary but never for primary protection of eyes; theseafford face protection.Alternatively a gas mask may replace splash goggles and face shields.Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants.

Skin protection See Hand protection below

Hands/feet protectionElbow length PVC gloves When handling corrosive liquids, wear trousers or overalls outside of boots, to avoid spills entering boots.

Body protection See Other protection below

Other protection

Overalls. P.V.C. apron. Barrier cream. Skin cleansing cream.

Thermal hazards Not Available

Recommended material(s)

GLOVE SELECTION INDEX

Glove selection is based on a modified presentation of the:

"Forsberg Clothing Performance Index". The effect(s) of the following substance(s) are taken into account in the

computer-generated selection: VACUUM PIPE CLEANER

Material CPI

BUTYL A

NEOPRENE A

VITON A

NATURAL RUBBER C

PVA C

* CPI - Chemwatch Performance IndexA: Best SelectionB: Satisfactory; may degrade after 4 hours continuous immersionC: Poor to Dangerous Choice for other than short term immersion

NOTE: As a series of factors will influence the actual performance of theglove, a final selection must be based on detailed observation. -* Where the glove is to be used on a short term, casual or infrequentbasis, factors such as "feel" or convenience (e.g. disposability), maydictate a choice of gloves which might otherwise be unsuitable followinglong-term or frequent use. A qualified practitioner should be consulted.

Respiratory protectionParticulate. (AS/NZS 1716 & 1715, EN 143:000 & 149:001, ANSI Z88 ornational equivalent)

Where the concentration of gas/particulates in the breathing zone,approaches or exceeds the "Exposure Standard" (or ES), respiratoryprotection is required.Degree of protection varies with both face-piece and Class of filter; thenature of protection varies with Type of filter.

Required MinimumProtection Factor

Half-FaceRespirator

Full-FaceRespirator

Powered AirRespirator

up to 10 x ES -AUS P2 --PAPR-AUS /Class 1 P2

up to 50 x ES --AUS / Class 1P2

-

up to 100 x ES - -2 P2 -PAPR-2 P2 ^

^ - Full-faceA(All classes) = Organic vapours, B AUS or B1 = Acid gasses, B2 = Acidgas or hydrogen cyanide(HCN), B3 = Acid gas or hydrogen cyanide(HCN),E = Sulfur dioxide(SO2), G = Agricultural chemicals, K = Ammonia(NH3),Hg = Mercury, NO = Oxides of nitrogen, MB = Methyl bromide, AX = Lowboiling point organic compounds(below 65 degC)


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8.2.3. Environmental exposure controlsSee section 12

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

9.1. Information on basic physical and chemical properties

Appearance Not Available

Physical state LiquidRelative density

(Water = 1)1.2

Odour Not AvailablePartition coefficient

n-octanol / waterNot Available

Odour threshold Not AvailableAuto-ignition

temperature (°C)Not Available

pH (as supplied) Not ApplicableDecomposition

temperatureNot Available

Melting point /freezing point (°C)

>250 Viscosity (cSt) Not Available

Initial boiling pointand boiling range (°C)

Not AvailableMolecular weight

(g/mol)Not Available

Flash point (°C) Not Available Taste Not Available

Evaporation rate Not Available Explosive properties Not Available

Flammability Not Available Oxidising properties Not Available

Upper Explosive Limit(%)

Not AvailableSurface Tension

(dyn/cm or mN/m)Not Available

Lower Explosive Limit(%)

Not AvailableVolatile Component

(%vol)Not Available

Vapour pressure (kPa) Not Available Gas group Not Available

Solubility in water(g/L)

Miscible pH as a solution (20%) 1.1

Vapour density (Air =1)

Not Available VOC g/L Not Available

9.2. Other informationNot Available

SECTION 10 STABILITY AND REACTIVITY

10.1.Reactivity See section 7.2

10.2.Chemical stabilityUnstable in the presence of incompatible materials.Product is considered stable.Hazardous polymerisation will not occur.

10.3. Possibility ofhazardous reactions

See section 7.2

10.4. Conditions toavoid

See section 7.2

10.5. Incompatiblematerials

See section 7.2

10.6. Hazardousdecomposition

productsSee section 5.3

SECTION 11 TOXICOLOGICAL INFORMATION

11.1. Information on toxicological effects

Inhaled

The material can cause respiratory irritation in some persons. The body's response to such irritation can cause further lungdamage.Corrosive acids can cause irritation of the respiratory tract, with coughing, choking and mucous membrane damage. Theremay be dizziness, headache, nausea and weakness.


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Not normally a hazard due to non-volatile nature of product

The material has NOT been classified by EC Directives or other classification systems as "harmful by inhalation". This isbecause of the lack of corroborating animal or human evidence.

Ingestion

Ingestion of acidic corrosives may produce burns around and in the mouth, the throat and oesophagus. Immediate pain anddifficulties in swallowing and speaking may also be evident.

The material has NOT been classified by EC Directives or other classification systems as "harmful by ingestion". This isbecause of the lack of corroborating animal or human evidence.

Skin Contact

Skin contact with acidic corrosives may result in pain and burns; these may be deep with distinct edges and may heal slowlywith the formation of scar tissue.Skin contact is not thought to have harmful health effects (as classified under EC Directives); the material may still producehealth damage following entry through wounds, lesions or abrasions.Open cuts, abraded or irritated skin should not be exposed to this materialEntry into the blood-stream, through, for example, cuts, abrasions or lesions, may produce systemic injury with harmfuleffects. Examine the skin prior to the use of the material and ensure that any external damage is suitably protected.

EyeIf applied to the eyes, this material causes severe eye damage.Direct eye contact with acid corrosives may produce pain, tears, sensitivity to light and burns. Mild burns of the epitheliagenerally recover rapidly and completely.

Chronic

Repeated or prolonged exposure to acids may result in the erosion of teeth, swelling and/or ulceration of mouth lining.Irritation of airways to lung, with cough, and inflammation of lung tissue often occurs.Long-term exposure to respiratory irritants may result in disease of the airways involving difficult breathing and relatedsystemic problems.Substance accumulation, in the human body, may occur and may cause some concern following repeated or long-termoccupational exposure.

VACUUM PIPECLEANER

TOXICITY IRRITATION

Not Available Not Available

sulfamic acid

TOXICITY IRRITATION

dermal (rat) LD50: >2000 mg/kg[1] Eye (rabbit): 20 mg - moderate

Oral (rat) LD50: ca.1450 mg/kg[1] Eye (rabbit): 250 ug/24 h - SEVERE

Skin (human): 4 %/5 days (I)- mild

Skin (rabbit): 500 mg/24 h-SEVERE

Legend: 1. Value obtained from Europe ECHA Registered Substances - Acute toxicity 2.* Value obtained from manufacturer's SDS. Unless otherwise specified data extracted from RTECS - Register of Toxic Effect of chemical Substances

VACUUM PIPECLEANER

Oral (Rat) LC50: 3160 mg/kg

Asthma-like symptoms may continue for months or even years after exposure to the material ceases. This may be due to anon-allergenic condition known as reactive airways dysfunction syndrome (RADS) which can occur following exposure to highlevels of highly irritating compound. Key criteria for the diagnosis of RADS include the absence of preceding respiratorydisease, in a non-atopic individual, with abrupt onset of persistent asthma-like symptoms within minutes to hours of adocumented exposure to the irritant. A reversible airflow pattern, on spirometry, with the presence of moderate to severebronchial hyperreactivity on methacholine challenge testing and the lack of minimal lymphocytic inflammation, withouteosinophilia, have also been included in the criteria for diagnosis of RADS. RADS (or asthma) following an irritating inhalationis an infrequent disorder with rates related to the concentration of and duration of exposure to the irritating substance. for acid mists, aerosols, vapoursData from assays for genotoxic activity in vitro suggest that eukaryotic cells are susceptible to genetic damage when thepH falls to about 6.5. Cells from the respiratory tract have not been examined in this respect. Mucous secretion may protectthe cells of the airways from direct exposure to inhaled acidic mists, just as mucous plays an important role in protecting thegastric epithelium from its auto-secreted hydrochloric acid. ln considering whether pH itself induces genotoxic events in vivoin the respiratory system, comparison should be made with the human stomach, in which gastric juice may be at pH 1-2under fasting or nocturnal conditions, and with the human urinary bladder, in which the pH of urine can range from <5 to > 7and normally averages 6.2. Furthermore, exposures to low pH in vivo differ from exposures in vitro in that, in vivo, only aportion of the cell surface is subjected to the adverse conditions, so that perturbation of intracellular homeostasis may bemaintained more readily than in vitro.

SULFAMIC ACID

for acid mists, aerosols, vapoursData from assays for genotoxic activity in vitro suggest that eukaryotic cells are susceptible to genetic damage when thepH falls to about 6.5. Cells from the respiratory tract have not been examined in this respect. Mucous secretion may protectthe cells of the airways from direct exposure to inhaled acidic mists, just as mucous plays an important role in protecting thegastric epithelium from its auto-secreted hydrochloric acid. ln considering whether pH itself induces genotoxic events in vivoin the respiratory system, comparison should be made with the human stomach, in which gastric juice may be at pH 1-2under fasting or nocturnal conditions, and with the human urinary bladder, in which the pH of urine can range from <5 to > 7and normally averages 6.2. Furthermore, exposures to low pH in vivo differ from exposures in vitro in that, in vivo, only aportion of the cell surface is subjected to the adverse conditions, so that perturbation of intracellular homeostasis may bemaintained more readily than in vitro.


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Legend: – Data available but does not fill the criteria for classification – Data required to make classification available – Data Not Available to make classification

The material may produce severe irritation to the eye causing pronounced inflammation. Repeated or prolonged exposure toirritants may produce conjunctivitis.The material may cause severe skin irritation after prolonged or repeated exposure and may produce on contact skinredness, swelling, the production of vesicles, scaling and thickening of the skin. Repeated exposures may produce severeulceration.

Asthma-like symptoms may continue for months or even years after exposure to the material ceases. This may be due to anon-allergenic condition known as reactive airways dysfunction syndrome (RADS) which can occur following exposure to highlevels of highly irritating compound. Key criteria for the diagnosis of RADS include the absence of preceding respiratorydisease, in a non-atopic individual, with abrupt onset of persistent asthma-like symptoms within minutes to hours of adocumented exposure to the irritant. A reversible airflow pattern, on spirometry, with the presence of moderate to severebronchial hyperreactivity on methacholine challenge testing and the lack of minimal lymphocytic inflammation, withouteosinophilia, have also been included in the criteria for diagnosis of RADS. RADS (or asthma) following an irritating inhalationis an infrequent disorder with rates related to the concentration of and duration of exposure to the irritating substance.

Acute Toxicity Carcinogenicity

SkinIrritation/Corrosion

Reproductivity

Serious EyeDamage/Irritation

STOT - SingleExposure

Respiratory or Skinsensitisation

STOT - RepeatedExposure

Mutagenicity Aspiration Hazard

SECTION 12 ECOLOGICAL INFORMATION

12.1. Toxicity

Ingredient Endpoint Test Duration (hr) Species Value Source

sulfamic acid EC50 384 Crustacea 6.40973mg/L 3

sulfamic acid LC50 96 Fish 14.2mg/L 4

sulfamic acid NOEC 1560 Fish 0.025mg/L 2

sulfamic acid EC50 48 Crustacea 71.6mg/L 2

sulfamic acid EC50 72 Algae or other aquatic plants 33.8mg/L 2

Legend:

Extracted from 1. IUCLID Toxicity Data 2. Europe ECHA Registered Substances - Ecotoxicological Information - Aquatic Toxicity3. EPIWIN Suite V3.12 - Aquatic Toxicity Data (Estimated) 4. US EPA, Ecotox database - Aquatic Toxicity Data 5. ECETOCAquatic Hazard Assessment Data 6. NITE (Japan) - Bioconcentration Data 7. METI (Japan) - Bioconcentration Data 8. VendorData

Harmful to aquatic organisms.

Ecotoxicity:The tolerance of water organisms towards pH margin and variation is diverse. Recommended pH values for test species listed in OECD guidelines arebetween 6.0 and almost 9. Acute testing with fish showed 96h-LC50 at about pH 3.5

DO NOT discharge into sewer or waterways.

12.2. Persistence and degradability

Ingredient Persistence: Water/Soil Persistence: Air

sulfamic acid HIGH HIGH

12.3. Bioaccumulative potential

Ingredient Bioaccumulation

sulfamic acid LOW (LogKOW = -4.3438)

12.4. Mobility in soil

Ingredient Mobility

sulfamic acid LOW (KOC = 6.124)

12.5.Results of PBT and vPvB assessment


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P B T

Relevant available data Not Available Not Available Not Available

PBT Criteria fulfilled? Not Available Not Available Not Available

12.6. Other adverse effectsNo data available

SECTION 13 DISPOSAL CONSIDERATIONS

13.1. Waste treatment methods

Product / Packagingdisposal

Recycle wherever possible. Consult manufacturer for recycling options or consult local or regional waste management authority for disposal if nosuitable treatment or disposal facility can be identified. Treat and neutralise at an approved treatment plant. Treatment should involve: Neutralisation with soda-ash or soda-limefollowed by: burial in a land-fill specifically licenced to accept chemical and / or pharmaceutical wastes or Incineration in alicenced apparatus (after admixture with suitable combustible material). Decontaminate empty containers with 5% aqueous sodium hydroxide or soda ash, followed by water.

Waste treatmentoptions

Not Available

Sewage disposaloptions

Not Available

SECTION 14 TRANSPORT INFORMATION

Labels Required

Marine Pollutant NO

Land transport (ADR): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS

14.1.UN number Not Applicable

14.2.Packing group Not Applicable

14.3.UN propershipping name

Not Applicable

14.4.Environmentalhazard

Not Applicable

14.5. Transport hazardclass(es)

Class Not Applicable

Subrisk Not Applicable

14.6. Specialprecautions for user

Hazard identification (Kemler) Not Applicable

Classification code Not Applicable

Hazard Label Not Applicable

Special provisions Not Applicable

Limited quantity Not Applicable

Air transport (ICAO-IATA / DGR): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS

14.1. UN number Not Applicable

14.2. Packing group Not Applicable

14.3. UN propershipping name

Not Applicable

14.4. Environmentalhazard

Not Applicable


ICAO/IATA Class Not Applicable

ICAO / IATA Subrisk Not Applicable

ERG Code Not Applicable


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Cargo Only Packing Instructions Not Applicable

Cargo Only Maximum Qty / Pack Not Applicable

Passenger and Cargo Packing Instructions Not Applicable

Passenger and Cargo Maximum Qty / Pack Not Applicable

Passenger and Cargo Limited Quantity Packing Instructions Not Applicable

Passenger and Cargo Limited Maximum Qty / Pack Not Applicable

Sea transport (IMDG-Code / GGVSee): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS




Not Applicable


Not Applicable


IMDG Class Not Applicable

IMDG Subrisk Not Applicable


EMS Number Not Applicable


Limited Quantities Not Applicable

Inland waterways transport (ADN): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS




Not Applicable


Not Applicable


Not Applicable Not Applicable


Classification code Not Applicable


Limited quantity Not Applicable

Equipment required Not Applicable

Fire cones number Not Applicable

Transport in bulk according to Annex II of MARPOL and the IBC codeNot Applicable

SECTION 15 REGULATORY INFORMATION

15.1. Safety, health and environmental regulations / legislation specific for the substance or mixture

SULFAMIC ACID(5329-14-6) IS FOUND ON THE FOLLOWING REGULATORY LISTS

European Customs Inventory of Chemical Substances ECICS (English)

European Union - European Inventory of Existing Commercial ChemicalSubstances (EINECS) (English)

European Union (EU) Annex I to Directive 67/548/EEC on Classificationand Labelling of Dangerous Substances - updated by ATP: 31

European Union (EU) Regulation (EC) No 1272/2008 on Classification,Labelling and Packaging of Substances and Mixtures - Annex VI

This safety data sheet is in compliance with the following EU legislation and its adaptations - as far as applicable - : 67/548/EEC, 1999/45/EC, 98/24/EC,92/85/EC, 94/33/EC, 91/689/EEC, 1999/13/EC, Commission Regulation (EU) 2015/830, Regulation (EC) No 1272/2008 and their amendments as well asthe following British legislation: - The Control of Substances Hazardous to Health Regulations (COSHH) 2002 - COSHH Essentials - The Management ofHealth and Safety at Work Regulations 1999

15.2. Chemical safety assessment


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For further information please look at the Chemical Safety Assessment and Exposure Scenarios prepared by your Supply Chain if available.

National Inventory Status

Australia - AICS Y

Canada - DSL Y

Canada - NDSL N (sulfamic acid)

China - IECSC Y

Europe - EINEC /ELINCS / NLP

Y

Japan - ENCS Y

Korea - KECI Y

New Zealand - NZIoC Y

Philippines - PICCS Y

USA - TSCA Y

Legend:Y = All ingredients are on the inventoryN = Not determined or one or more ingredients are not on the inventory and are not exempt from listing(see specific ingredientsin brackets)

SECTION 16 OTHER INFORMATION

CONTACT POINT

- For quotations contact your local Customer Services - https://wssdirectory.wilhelmsen.com/#/customerservices - - Responsible for safety data sheetWilhelmsen Ships Service AS - Prepared by: Product HSE Manager, - Email: Email: [email protected] - Telephone: Tel.: +31 104877775

Full text Risk and Hazard codes

H412 Harmful to aquatic life with long lasting effects.

Other informationClassification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by theChemwatch Classification committee using available literature references.A list of reference resources used to assist the committee may be found at: www.chemwatch.net

The SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards areRisks in the workplace or other settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current oravailable engineering controls must be considered.

For detailed advice on Personal Protective Equipment, refer to the following EU CEN Standards:EN 166 Personal eye-protectionEN 340 Protective clothingEN 374 Protective gloves against chemicals and micro-organismsEN 13832 Footwear protecting against chemicalsEN 133 Respiratory protective devices

Definitions and abbreviationsPC－TWA: Permissible Concentration-Time Weighted AveragePC－STEL: Permissible Concentration-Short Term Exposure LimitIARC: International Agency for Research on CancerACGIH: American Conference of Governmental Industrial HygienistsSTEL: Short Term Exposure LimitTEEL: Temporary Emergency Exposure Limit。IDLH: Immediately Dangerous to Life or Health ConcentrationsOSF: Odour Safety FactorNOAEL :No Observed Adverse Effect LevelLOAEL: Lowest Observed Adverse Effect LevelTLV: Threshold Limit ValueLOD: Limit Of DetectionOTV: Odour Threshold ValueBCF: BioConcentration FactorsBEI: Biological Exposure Index


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