V. RAW QC - US Environmental Protection Agency · V. RAW QC E.P.A. CASE NO. ... page 8-9 ol 63: II...

V. RAW QCE.P.A. CASE NO.

•A, DFTPPflllxtmtTaDH 'F Mtimxl BMnH Swii<VoKMo IH3LI 'K. Mum gp*i SemWoWiH• PtftormiriM SUnilaid Form • Surromu R«sov«y ' Sunogili Recovery Form• Ctranitogram • Tenmive ID bil • TenMlwe 10 Usl• SoKtrun > Cr»om»lo«r«ni|a|/ai*>tit«lion • Ckomilofl• EICP Rtpon Rtport• M/ZUitng • MwSpKlnn • MwSMCtrun

•B, MMMnMi •Ux-ySMrcn • .IMwftMl. Ptflom*™ Stinua Form '<»• "*»« ** P"**" I"81' ''•• gw""" "«"»• Swclnm • Sungni fl«cov«tv F<xm volil™• EJCP • CHromilognm(i|/QiMtillon • SurrogM Rtwv«<y Form• M/Z Luting Alport • Tffllltlvt ID Ull

•0, Crrarrtogrwy CH«H OM 'H. mat B«h TCDD ' CJomjjiQmKil/QwillWlo• SwTogiliRKOVKyForm • Mm9pKttun

• UM*yS«vcli'-I, M«n»Sp*«VOA|HSl) , amvati RKOV«CV Forni

•D, Inwurnrl Urft IHSl) , surosM RicovKy Form . TimiiKi ID iSl• SwogiUHKOVKy • Tmlitwi ID Ul • Chron»!ogrm|i|/QuMtMon• TmtrtvtlDWI • Cnromitog»ini!/Qtwililinon Rtpod• CWocrwogrtmlil/OuinWiliwi Ripon • MiwSoKtrum

> MuiSaKtrun . UowySwcn

•E. MWwdBHnHVOAIHSl) . SurrogiM Rtcovny Form• SurrrgMlHKOVDy i TtnlMvilDUil . Cr«omilognm(i|/0u«iltti»nTMIIrvilDUM • OMfom«loorim(i|/Qwtitmtlon

H* CnromilooiinidliOuwMiiKxi Riport • Mms«cmmRiWt • MmSMCtrum •> UDfvy Swell

• QC Sam MM• S«qu«KI IHMIIM H rtqufW

The items deliverable under blanks and mntrlx aplKea and duplicate matrix spikes aectlonahave been described In similar aectlona ol the Indexed labs (or the samples, % Recoveryand RPD criteria are described In the Summary, Section II.C, Blank criteria applied are asfollows, (ram Exhibit E, page 8-9 ol 63:II an HSL compound Is detected In the blank, the blank value Is utilized In the calculation ofthe sample according to the following options, Results of reagent blank analysis shall bereported using the Organic Analysis Data Sheet (see Exhibit B).1, If the concentration In the blank Is less than or equal to '/i of the method detection

limit (reference Exhibit C: HSL Compounds and Method Detection Limits), the blankvalue Is Ignored,

2, If the concentration In the blank Is greater than Vi of the method detection limit and Isless than or equal to Vi the concentration detected In a sample, subtract the concen-tration In the blank from the concentration In the sample, Record the corrected valueand Indicate that this has been done by placing a "C" In the flag column of the datasheet. 012866

3, If the concentration In the blank Is greater than Vi of the method detection limit and Ifthe blank concentration Is greater than '/i the concentration detected In a sample,correction Is not possible and the compound should be reported as "ND" but with a"B" In the flag column of the data sheet, The cause of this high blank should be deter-mined and corrected before additional samples are analyzed, 001113

012867

89

SEHl-VOLATUE INSTRUMENT TUNE AND PERFORMANCE

CASE HO. ______ CONTRACTOR Htid CmpuChm CONTRACT HO. 68-01.6762 t6B-01-6BS6LON LEVEL —— KD. LEVEL ——— HIGH LEVEL ————————MATER SOU/SEP. ~~~~—————— " '

, , OFTPP File NMC:Oite: titt>l& Shift: __'

MmSIufto70}27J97

198

199

175

K5

MlM2

443

OFTPPIon Abundance Criteria30, nn to 60. nn «'nf w« ionless thmi 9 nn t of piss (pna» 69 r*l«Hv» phundineeless than 2.00% of imss 6940.00 to 60.00 S of MSS 198lets than l.flMC of mice 198

bite ptik. 100 otretntS.OO to 9.nn « af mn« 1BB

jo OQ »« in nn i «* iu« ioa

jirjaitr thin i-00* °f "IH.JSB_orntnt but Itti MIS thin 443greater thin 40.001 of miss 19817.00 to ?3.rm ef mis* 44?

t Mlitlv* Abundin»

38.11— ^ —— »!_ft.ss- .. ' . '

J

49.74-———

/fa. oo*-*8

/t,.o7l.*27-Bt

{,+.87/!•&. . Ut'3f\*.

ind 1FB Ptrtonmnct utiuiti;The DFTPP perfonunct results were reviewed end found to be within the specifiederlterli, „ . .

8f_________Zlutoiniii11t oittDevlitloni Required ObservedDitt/THM/'lnitrumtnt File MuBber Compound •/» Abundinee Abundince

inmiu Pite«0Pentichlorophenol Response Firtor • Arei 118 X to

lenitdlne Detect ible Qtes D »?,_.,Ares (Counts) 40 ng ftirAnthricenP • 33<>2-OI.H-lutyl Phtnilete Siturited Q Yes QUo'» Figure 1n ( _ . ) Is I of MSS 69 012868

Figure 1n ( " , ) Is » of MSS 6?1 Figure 1. I , )1.<*~M> . ' hti 1/31/M>

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UI8T DATA: DH840222A19 • 724 BABE fl/E: 198722/84 11:41:00 + 9:03 RIC: 19992.

'LEl 1UL •7090(11084) ON t!9

43 0.00 MINIMA (1IN INTEN: 0. MAX INTEN: 2340.3 • 0 MAXIMA

X RA MASS X RA

43 3.21 198 100.0090 8.93 199 A. 9891 38.12 204 1.9792 0.98 .209 3.8999 2.18 20A IB. 739A 2.78 207 1.7997 4.32 217 3.89A3 1.07 221 3. A3 - •A9 48.99 334 B. 3871 1.79 339 1.7974 3.21 227 3.9079 9.81 244 3.907A 2.2A 299 33.9777 44.10 29A 4.4978 2.91 298 1.1979 3.78 374 8.41BO 3.09 379 16.07Bl 4.19 37A 1.7983 1.37 39A 3.0393 3.AB 323 1.0397 1.03 3A19 1.3398 1.84 433 3. A399 3.39 441 7.8A101 1.41 442 64.87

1.37 443 11.84'09 . 1.33107 12.86 .108 1. A7 5110 32.91 -111 4.19 -117 9.21 ?133 1.94127 49.74128 2.99129 18.38130 0.90139 0.89141 1. A7148 1.79149 7.9919A 1.411A7 3.721AB 1.90

0.940.90

179 3.31180 3.01189 1.411BA 9.87187 3.99196 3.3A

012872

SEMI-VOLATILE INSTRUMENT TUHE AND PERFORHAUCE

CASE NO. ______ CONTRACTOR Head CenpuChetn CONTRACT NO. 68-01 .67«. 68-01 -6B£fLOW LEVEL —— NED. LEVEL —— HUH LEVEL

S01L/SED. _ . OTHER (SPtciMName:

!H"nIB

KL70,J7

19719B

199

mus441

442

443

1 'DFTPP

ton AtiunJince Criteria30. OH to. 60. nn X nf mass 1QRless thin P.np 1i of nj s $Q

nut to p*1it1«t ibundanetless thin 2.00* of miss 6940.00 to 60.00 t of mass 198lets than 1.0m af m»s« 198bate peak. 100 percentS.on to 9.on t of mi« laa10 oo +« in nn * nf «»» 100

j£CAtsr_thM l.OOX Of m|s_s_l£fl_oraient but lest MSI than 443greater thin 40. OCX of mass1 19817. nn to ?3.nn* of m«» 449

t Rilatlve Abundance

5£ &: J

C. *4* 4 4-——— ' ( . 1Z

<A SS'S• ——1 oo. ooIT Co23. 19"2. C»l-7.1 L• i-) . 41 I'2--?-?- i/J.flzn

anaiFBrtrfofiiinct Utiultti

The DFTPP performance results were reviewed and found to be within the specifiedcriteria. L

DateOevlatlont Required ObiervedBatt/Tl»t/lnitrunent File Number Compound mil Abundance Abundanet

initials Bateunti!

———— *°.. <reiM6•entichlorophenol Response Factor* Area 1M X |Qknildlne Detectable H-YM |J to f , < *Am (Counts) 40 ng DlTTAnthriee V 1 <• (* T,DLN-lutyl Phthilate Saturated Q Y» Qw

1 FlgunlnC . )1s«ofws69 . Ql°873« Figure in ( , )1.lofH.s 19 / 1 jFigure 1. ( , ) It I of «» *« ^&L 1/31/84,

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MEAD COMPUCHEflI MASS LIST PATA: DHB40209B19 « 760 BASE M/E: 198(02/09/84 18:31:00 + 9:30 RIC: 19992,I SAMPLE: 1UL DFTPP 11009<7090>QNIM9fV

43 0,00 MINIMA MIN INTEN: 0, MAX INTEN: 2036.444 « 0 MAXIMAMASS X RA MASS X RA i

43 2.01 179 2,8090 13.36 1BO 1,42 • ,91 96.68 ' 186 10.7192 2,70 187 2, 1699 1,67 196 2,0196 2,01 ' 198 100,0097 9. 99 " • "-199 9, 6062 l.OB 204 2,7963 2,90 209 3,7369 64.44 206 19,3074 3, 19 207 1. 9779 B, 84 217 4, 1776 2.01 221 3,09"77 93,94 . 224 9.4378 3, 99 229 1.0879 3.68 227 4.0880 2. 11 244 8,4081 4.86 299 40,6282 1.42 296 9,7983 1.08 298 1.96

1,08' 274 3,733,0? 279 23,28 :

99 1,03 276 2.60 . .97 1,03 2?7 1,2898 3, 19 -296 4.6799 3.19 ?323 2,11101 1,62 "365 2.01104 1, IB "423 3, 00109 1,33 :441 7,96107 14.44 '442 64,44108 2.36 = 443 12.77110 33.30 444 1.03111 4.72117 6. 19 i123 1,03127 '' .49, 98 '•12B 3. 99 Z129 17, 93130 1,3B139 0,98141 1.28148 2,69 ,-199 0,98196 1,23161 1,13 =169 1,08 t166 0.98

3.09

S 012877

CASE NO. ______ CONTRACTOR Mead ConpuChem CONTRACT NO. 68-01.676? .68-01-6866LOW LEVEL"" —— MED. LEVEL —— HIGH LEVEL JZHZZZZMATER ___ZZZZZ SOIL/SED. JZZHZZm OTHER (Specify)

.- . DFTPP File Name:Date: 7-/^/gV Shift: _I

NanSI

6B

so70

127

197

198

199

275

36S

441

442443

DFTPPIon Abundance Criteria30. 0(1 to 60. nn t of mass 1QAless thin 9.nn J gf pis's 69

m«« 69 r*lst1v§ sbundanceless than 2.00X of mass 69•40.00 to 60.00,f of mass 198less than l.nnt nf m»M 198

taise peak. 100 oereentS.OO to 9. On t of m»« 198

10 00 tn 911 fJO % nf mfff 100

greater than l.OOX of m«4is_12i_oresant but leas Mass than 443greater than 40.00S of mass 19817. nn to 23 .nn* of mass ut

1 Relative Abundancett<o- ••• ( . ,»5-3.6— • i .'i1S"d.*?5—1 OO. 66

«:«.n-.t-iI.L1/O.V6t7.fli/. VO (0 .W)3

TjFTPP ind BFB Pertorminct Hiiuitsi

The DFTPP performance results mre revlcMed and found to be within the specifiedcriteria,

invP~l Pevlitlons Required flbierved

Date/TlM/ln»trufflent File Mumber Compound 111/2 Abundance Abundance

untlais Date

— n Ar>i Mt rmCentachlorophinol Response Factor • Area 186 X 50 • |6./( |Benildlne Detectable RTes Hte _ - ' ——Area (Counts) 40 ng OlTrAnthracent - ?17DLK-Butyl Phthalate Saturated Q Yes1 Figure In ( , ) 1s S of MSS 69 0128732 Figure In ( , ) 1s X of mss M3 Figure in { . )\H*mu* Revision Date !/31/84,

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MEAD COPIPUCHEMMASS LIST DATA: DHB40202B14 ft 782 BASE M/E: 19802/02/84 20:48:00 + 9:46 RIC: 13496,SAMPLE: 1UL DFTPP 10911(7090)QN«14#782

ri44 0,00 MINIMA M1N INTEN: 0, MAX INTEN: 1894,443 ft 0 MAXIMAMASS X RA MASS X RA

44 3,38 , 227 2.4890 13.67 244 8.7691 98.90 299 43. 14 ' .92 2.22 296 3,2396 1,90 298 1.6997 3.99 274 3.96 '" ' •63 1.98 279 17.6369 93,64 " 276 1.9074 3.91 - 296 2.6979 9.86 369 1.6977 93,27 423 2.7978 2.48 441 10.4079 1.90 442 67.0980 1,64 : 443 11.4081 2, B9 .83 1,2193 3,3898 2.3299 2.27 r101 1. 98107 12.62

^ .108-.- .1.37 'Wf 110 32. 98 r .

' 111 3.96'117 6,60 i123 1.32127 90,99128 2,79129 17.99 -_130 1,48 :141 1.64 :148 1.74149 1. 98167 3.22168 2, 99179 1.74180 1.48186 10. 96187 2,64196 1.69198 100.00199 9.86204 2. 11 =209 3.70206 19.98207 1,90 "217 3.33

y =24 IS • 012882v 229 1, 98

f

5EH1- VOLATILE INSTRUMENT TUNE AND PERFORMANCE

CASE NO. ______ CONTRACTOR Hetd CompuChem CONTRACT NO. 68-01.67*53. 68-01 -6866LOW LEVEL —— MED. LEVEL —— HIGH LEVEL ' 'HATER " ' "" 50IL/SED. _________ OTHER (Specify)

, . DfTPP File Name;Date OlMf/84- Shift: /y AliaT¥?t;

HissSI68

KO

70

127

197

198

199

275

365

441

442

443

DFTPPIon Abundance Criteria30. HO to 60. nn' t nf mass 14R

lets than 2.nfljj gf rnass 69

rni<! fifl r«1>t1ve ibundanceless than 2. OOX of mass 6940.00 to 60.00 t of mass 198

less than l.fint of mat<: 19H

base peak, 100 percent5. no to 9. on % of mice iaa30 00 fn 30 nn t nf one* IQfl

greater than l.OOX of mass 198 _present but less mass than 443greater than 40.00% of mass 19817. On to 23. (HI* of m»« 443

t Relative Abundance

57, SS0-(*f ' ( LW^57*2' - '•— — * ' f . izwz.— • -"fte.oo7,»1IS.Kt-n9.4-131. tom '< a is

and bFB Ptrtonninet msuits;

The DFTPP performance results Mere reviewed and found to be *1th1n the specifiedcriteria.

Trmlels Date[""""| Deviations Required Observed

Pate/T1mt7lnstrumtnt File Number Compound nil Abundance Abundance

Initials _IDateioiments!————Pentichlorophenol Responsejactor • Area 188 X 50lonzldlne Detectable Rfes QuoArea (Counts) 40 ng DliTAnthracene •01-N-Butyl Phthalate Saturated Q Yes1 Figure In (• . ) 1s t of Mis 692 Figure In ( , ) 1s % of mass M 0128833FlBur,M . )U%nf mass 442 Revision Date 1/31/84,

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MEAD CQMPUCHEhInASS LIST DATA: DH840131A19 tt 809 BASE M/E: 198101/31/84 13:90:00 + 10:07 RIC: 37376,IS AMPLE: 1UL &7090U091U ON *19

0,00 MINIMA MIN INTEN: 0. MAX INTEN: 4800.444 ft 0 MAXIMAMASS X RA MASS X RA MASS X RA

43 1.69 117 7.08 206 19.6744 0.46 118 0.96 207 8,3949 0, 90 182 0. 98 208 0.9690 14.19 123 1.31 211 1,3391 97.98 124 0.60 216 0.9692 2.71 129 0.89 217 4,06 ... .99 1.96 127 47.92 218 0,4896 1.21 • 128 4.08 221 3.7997 4.81 129 17.04 223 1.0061 0.79 130 1.29 224 9.9462 0.73 134 0.90 229 2.2963 2.39 139 1.27 227 3.7969 1. 19 136 0.98 228 0,6067 0.73 137 1.00 229 0.7968 0.69 141 1.98 242 0.9669 97.42 142 0.83 244 7.6971 0.79 143 0.79 249 0.8973 0.44 147 1.12 246 1.2174 3.96 148 1.71 299 40.0079 7,37 14.9 0.44 296 9.6974 2.90 193 0.90 298 1.9677 46.98 194 0.42 899 0.90

3.18 199 1.23 869 0.6779 3,83 196 1.98 273 1.4680 8,90 198 0,96 274 3.7781 4.21 199 0.92 279 18.7988 1.19 160 0.69 276 2.1083 1.31 161 0.81 877 1.3989 0.77 169 1.10 296 4.2986 0.73 166 0.60 297 0.9491 1. 12 £67 3.98 303 0.4692 1.00 168 1.69 319 0.9293 4.29 1"73 0.48 316 0,9294 0.60 174 0,71 383 1,7199 0.46 179 1.19 334 1.3996 0.68 176 0.96 392 0,4298 2.48 177 0.46 394 0,4499 3.71 £79 2,44 369 1.73100 0.44 180 1.62 378 0.69101 1.83 181 0,96 373 0.44103 0.79 189 1.37 403 0.98104 1.87 186 11,31 481 0.60109 1.62 187 3.89 488 0.48107 14,60 188 1.37 483 2.87108 8. 19 192 0,98 424 0.87109 0,79 CT3 0,92 441 8,48110 29.29 196 2,21 442 97.00111 3.92 198 100,00 443 9.79a 2 0.62 19.9 7,08 444 0.87

3 0.48 204 2.04 012887441. A 1.M QABl A 11 " *W

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CASE NO. ______ CONTRACTOR Mead CompuChern CONTRACT NO. 6B-01.67'ri2,68-01-6866LOW LEVEL —— MED. LEVEL _________ HISH LEVEL 'HATER __ZHHIIi SOIL/SED. . OTHER (Soee'lM

.. , DFTPP File Name: DI+&yol3l&lC.Date: //?//5?V Shift: tt Analyst;

Nass51

68

so70127

197

198

199

275

365

441

442

443

JDFTPP .Ion Abundance Criteria

30. nn to 60. nn 1 nf mass liftIMS thiQ^^QQ l pf puss SQ

miss 69 relative abundanceless than 2. OOX of mass 69•40.00 to 60.00 t of mass 198

less than LOOK of mass 1QR

base peak. 100 percent

S.On to 9. On t of mass 108

JO M fn 9H r)n « nf 011 5 10B

.sredttr than 1-°QX °f mas? 198present but less mass than 443greater than 40.00% of mass 19817. On to 23.fin« of mass 44?

f Relative Abundance^ ?/J7

—— ••• ( . »»

4r€) to.SC,0. ^ • <a.S>2- 4. /O—/oo.ooC.-«2?-^ /'7.?21-C.l.6\41.11

. °|. 3\ (/9.» )3BFTPP and^FOerforlance itesults:

The DFTPP performance results Mere reviewed and found to be within the specifiedcriteria. . , o. /> <.-

" 'i n i t i a l s D a t e

I"| Deviations Required ObservedDate/Tlme/lnstrument File Number Compound n/i Abundance Abundance

inuuis pate.onments:

40 Area 266 . ...Pentachlorophanol Response Factor • Area 188 X go • J0"u |Benzldlne Detectable W es DN2-«irsa<Area (Counts) 40 ng DllTAnthracene • 7 T°T?DI-N-Butyl Phthalate Saturated fj Yes Q-No .'» Figure In { . ) Is « of IMS 69z Figure 1n ( , ) Is * of mass C93 Figure 1n( . ) Is * nf mass M2 Revision Date 1/31/84,

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HEAD GQMPUCHEttDATA: DHB40131B16 * BOS BASE M/E: 19S

1/31/84 20:10:00 + 10:01 RIG: 70696,-LE: lUL DFTPP 10911<70SO)QN»16tBfrl41 0.00 MINIMA MIN INTEN: 0. MAX INTEN: 9034.

s * x RA 'MABB x RA MASS x RA MASS x RA41 0. BO 112 0.49 1BO 2.40 273 0.9343 0.71 116 0.64 1B1 1.80 274 3.4444 0 BO 117 678 184 0.83 279 17.8290 19.36 118 0.37 189 1.93 276 2.9691 91 77 122 084 186 11.99 277 1.4492 284 123 1 SB 187 3.32 278 0.2893 0.29 124 0.73 1BB 0.70 293 0.4999 0.91 129 0,61 189 0.99 296 3.9996 1.89 127 44.10 191 0.39 297 0.4097 4.89 128 3.79 192 0.89 303 0.9961 0.70 129 17.66 193 1.13 319 0.47 •62 0.69 130 1.29 196 2.92 316 0.39 .63 8.38 131 0,22 198100.00 323 1.9464 0.31 - 134 0,86 199 6.87 324 0.3969 0.96 - 139 1.76 200 0.60 327 0.2267 0.27 136 0.81 201 0.33 328 0.2869 60.46 137 1.02 203 0.60 334 0,8870 0.49 141 2.38 204 2.99 339 0. 9073 0.74 142 0.72 209 4.36 346 0.3374 4.13 143 0,78 206 IB. 93 392 0.4279 7.36 146 0,29 207 2. 99 393 0.4876 2.81 147 1.96 208 0.76 394 0.6177 49.11 148 1.92 210 0.92 369 1.6278 3.96 149 0.84 211 0.94 372 0.8079 3.40 191 0.92 216 0.43 402 0.40K 2.62 192 0.23 217 4.22 403 0.42Bl 4.62 193 1. 16 218 0.49 421 0,47gl. 27 194 0, 90 221 3.77 422 0.38

1.06 199 1.64 222 0.79 423 3. 1989 0. Bl 196 2.26 223 0.89 424 0.7686 1.10 197 0.94 224 9.90 441 7.01B7 0.48 198 0.39 229 2.99 442 49.11

-j?l 0.60 199 ,0,43 227 4.22 443 9.31W2 1.03 160 0. 97 228 0.62 444 1.0993 4.40 163 0.88 229 0. 9994 0.33 162 0.39 231 0.3999 0.32 169 0.91 234 0.3996 0.40 £66 0.79 237 0.3397 0.91 T67 4.00 242 0.2398 2.98 168 2.40 243 0.3099 2.97 169 0.40 244 7.72101 1.83 1)71 0.22 249 1.12104 1.09 1.72 0.40 246 1.60109 1.29 173 0.39 247 0.34106 0.43 t74 0.90 299 36.92107 13.81 t79 1.60 296 9.90108 2. IB 176 0. 94 297 0.39109 0.42 *77 0.89 298 1.99110 28.86 178 0.29 299 0.22111 4.24 179 2.81 269 0.78

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012892

.1 29 CO!*?'*

CASE NO. ______ CUNIMUUK ntao LompuLnem tumn«*.i nu.LOM LEVEL —— MED. LEVEL . ~~~ HIGH LEVEL. .

SOIL/SED. . OTHER (Specify)DFTPP File Name:

Date: //10/f* Shift: g. Analyst:———— —————————

MassSI

68

($_70127

197

198

199

275

36S

441

442

443

DFTPPIon Abundance 'Criteria30 - 60 percent of mass 198less than 2 percent of mass 69

irmss S9 relative abundanceless than 2 percent of mass 6940 > 60 percent of pass 198less than 1 percent of nass 198base peak. 100 percent5 - 9 per cent of MSI 198

10 • 30 percent of MIS 198greater than 1 percent of mass 198present but less mass than 443greater than 40 percent of Mass 19E17 > 23 percent of mass 442

t Relative Abundance//

— < i1"ffz ' "•' .— i S¥7 .— .,tWXt-)2.£+C9 ( 20 «3

BFTPP and BFB Performance Results;

f~~l The DFTPP performance results were reviewed and found to be within the specifiedcriteria.

FI Deviations Required ObservedPate/Time/Instrument File Number Compound m/z Abundance Abundance

Dm

initials_________Dateommants:———— *° *rea 266Pentachlorophonol Response Factor • Area 186 X 50lenzldlne Detectable FjVes Q NoArea (Counts) 40 ng DlFAnthracenF• ?Qt£2/D1'N*Butyl Phthalete Saturated Q Yes EfNo1 Figure In ( ) 1s H of ia» 692 Figure 1n ( ) 1s S of lass i? 012893

^J 3 Flour* 1n f ) lit f nf MSS 442 k .. Of)l|<f:'}• ™ w tf "

FORM VI1——— Revision Date H/3.B/B3

CBIr

»•i

™

1-S

*j

^

-

' —1

J\

w

s-IV

C

r

p

.._ s-i — •

... —— .

i—, —————— jj.^ . .. —— .

_ _. . ^t ' •. N... . . .

.. .„. . _ —— . —

m•

a-J i ' . W

•

)a

s^J M £ H* »

On «| M m u^* o

*^ M ^

•- 1 3ui —— y a!-oi•S I""*'S w)r P.

-g • 1

I - —••• i^ W

HI 1

si

- ——— s• Ul

012894_a

SPffl-

h?si-

$

.1

*•• OJ M> 0

.S. T . P. T

38j

i01 01

s

01

?? |

A'A29

is

01

01

g v 8 r S 8. . . T

I . ft a 10w :.!-

Ul

HEAD conrucMenIMASB LIST DATA: DF840i3oci9 » lit BASE M/E: t9B101/30/84 0:17:00+ 9:59 RIC: 21036,Sf* LE: 1UL DFTPP (10911)V, 49 TO *BOO SUMMED - »846 X2. 00

91 0, 00 MINIMA MIN INTEN: 0. MAX INTEN: 3912.443 tt 0 MAXIMAMASS X RA MASS 7. RA

91 41.12 229 1.99 ' .92 9.07 227 3.0261 1.29 244 7.2369 91.99 299 39.94 - '77 23.98 296 9.2186 1. 29 .: 298 2, 1999 1.40 269 1,17101 2. 16 273 1. 14107 8. 43 274 3. 19108 0.14 279 16.97110 28,64 276 1.99119 8. 42 277 1.29117 9.97 296 3.93127 46.81 303 1.20189 17.28 323 1.28130 1.77 324 1.42134 2.39 369 1.91136 1.99 423 2.82139 1.88 426 1.22,141 3,73 441 6,41

*:;ty42 1.37 4.42 49.62 .""199 4.47 443 9,37196 3.64 :197 1. 28 i168 3, 67 : "171 1.22 J179 2. 82 :177 2. 82 a179 3', 93 -180 1. 42 "181 2. 49 ~189 1. 48 '186 12.27 H187 3. 49188 3. 93 -189 2, 91 I191 1. 94 *194 1.49 T19S 1. 99196 1, 97198 100.00 . ~199 7. 92202 1. 37204 2. 99206 8, 14207 2,79

222 1. 20

CASE NO. ______ CONTRACTOR Head CompuChem CONTRACT NO. 68-01.67MLOW LEVEL —— MED. LEVTiL I ', —— HIGH LEVEL,

SOIL/SED. 7 ; OTHER fSoeeTfy), f DFTPP File Name: _____^^___

Date: //wW Shift: _ c- Analyst: 75V.

Nass51

68

to70

127

197

198

199

275

365

441

442443

DFTPP ,Ion Abundance Criteria30 • 60 percent of MSS 198less than 2 oercent of lass 69

m/m 69 relative abundanceless than 2 oercent of lass 6940 • 60 percent of Mass 198less than 1 percent of mass 198base peak. 100 percent5 • 9 per cent of eiass 19B10 • 30 percent of pass 198greater than 1 percent of Mass 198present but less Mass than 443greater than 40 percent of Mass 19117 • 23 percent of mass 442

1 Relative Abundance4&- :' . f i157 ' •— ••• '. , )zffy—/t>G-?/?M

-?

<fe>

9 ( 2.2. 13.urTrP ana are Performance Results;

I"""! The DFTPP performance results ware reviewed end found to be within the specifiedcriteria.

initials • Datef"~| Deviations Required Observed

nate/Tlme/lnstrument File Number Compound m/: Abundance Abundance

i n i t i a l s D a t e———— <° *rea 266 rTTPentachlorophenol Response- Factor • Area IBS X so •r_Ieni1d1ne Detectable 0res D"0 ——Area (Counts) 40 ng DlFAnthracene*DI-H-Butyl Phthalate Saturated y res'! Figure In ( ) 1s % of Mass 692 Figure M ) 1st of Mass « ' 0123933 Flour* In ( ) Is * nf Mass 442

FORM VII

w

CDg g .8• rn V,

J JT~

« -

CJI"** 4fl® =

S

CS

i50 fflOJfl

„"!

mm29

01 A i i i T i i i i

01

OIUI•• 0

42 a

09 «NJ

5s01 --)«

»8 i

8

-s

,s , 8 .. ,B

I

0|- "-M »*„ tf

5 01

2s 001148

MEAD COMPUCHEdMASS LIST DATA: DH840130C14 tt 647 BASE M/E: 19801/30/84 1:03:00 + 8:05 RIC: 19728.SAMPLE: 1UL DFTPP (10911)»647 - #900 XI, 00|39 0.00 MINIMA MIN INTEN: 0. MAX INTEN: 1946.443 tt 0 MAXIMAMASS X RA MASS X RA

49 6.63 229 3,6991 60.02 227 9.7692 3.34 244 10,7496 0.67 246 2,8863 3.89 299 37.0969 4. 62 ' • 296 9. 6067 0,97 298 2.6769 97. 14 ' 273 2. 6279 10.38 274 3.6077 96.32 279 18.7678 9.14 276 3.8079 1.18 278 2,7780 2.62 296 4.9281 4.11 318 2.9789 4.93 339 4.7391 3,44 369 4,0193 9, 46 423 3. 6098 6.68 441 6,7899 4. 93 442 40. 18101 2.98 443 9.04107 16.. 99108 3.49 ':110 38.23 1117' 9.66122 2. 98 I127 49.69129 29, 13 S137 3. 39 =141 9. 19 .-148 2,72 r196 4.92167 6, 68 ~168 9. 96177 3. 03 ?179 4,11180 2, 83 *186 14.80 -187 4, 06191 2, 88 i196 9. 81198 100. 00199 7,76 I204 9. 09209 3, 24 :206 20.99207 0. 72Z1Z 2l7a •217 7.09221 10. 69

012903

!•• O'OUSO

VOLATILE INSTRUMENT TUKE AND FUFMHANCE

CASE NO.' •_____ CONTRACTOR Head CaaouChem CONTRACT «. 6B.Q1-6762LOK LEVEL —— MED. LEVEL HIGH LEVEL JZIZIZHATER __~"~~ SOIL/SEO. "~~~~"~~"~ OTHER (Specify) ——

IFB Fill Hem:.Date; 'I'fi &J Shin; ft AneUst;

Massto75

. 9596173174175

176

177

' 1EIIon Abundance Criteria15 • 40 'percent of ness 9530-60 percent of MSS 95bin puk. 100 percentS • 9 percent of MSI 95less than 1 percent of MSS 95greater than 50 percent of MIS 955*9 percent of MIS 174critter than 95 percent, butless thin 101 percent of 1745.9 percent of MIS 176

i Relative Abundance

50,9 //Ofl.CO '"' '.<o.az .-0-4A¥7

4.37 « I.A fl

feO.N-7 ( WO<D )3

*t>K i fcfl )2•FB Performance Results:1*"""! The IFB performance reiulti were reviewed ind found

initialsf"""1 Deviations

Dateline/Instrument File Number CoMpound i/z

to be within thupedf ltd.

HieRequired ObiervedAbundance Abundance'

initieis DateSQMMents;

» Value In ( ) U « of Mil 1741 Value In ( ) Is » of MIS 176J Value In { • ) Ii 1 of MIS 174 FORH Ml

MvlllynftMintt/M/U

fr 29 Ml

S

S .. Sg8•" wl •>,'s.... . {-.

:=-8 ___=====—————————————————————————58

•81 •—-———-

23091152 '

S3 8R * » ^ ? " ?t'' '* ><?'

y

s

B01

Si-

3 P S g a g

IS

•. SS091153

MEAD CQMPUCHEMMABB tIST DATA', BFB40ia7Bll « 147 BASE M/E', 9501/37/84 17'. 30i 00 t 7;2B RIC', 36416,SAMPLE! aUL BFB 10886>pJ147 - *15 XI. 00

37 0, 00 MINIMA MIN INTEN', 0. MAX INTEN'. 6608,177 • 0 MAXIMAMASS X RA

37 11. 68SB 10. as39 1.5440 8. 4449 8. 3650 34.56 '"' '51 10, 9755 0, 3956 6, 3057 5, 4361 3. 0363 B, 08 •63 8. 3168 16, 5669 18, 5673 8.1174 39. 6975 50.9176 6,0479 15. 74 .60 4.93

,& 61 15.47W 63 4. 56

' 63 1. 50 •67 3, 6966 4,1893 3. 9693 5. 9594 14, 4895 100,0096 6. 33174 60, 47175 4. 37176 60.47177 4, 18

012907

VOLATILE INSTRUMENT TUNE AND PERFORMANCE .

CASE NO. ______ CONTRAaOR Heed ComouChem CONTRACT NO. 6B.Q1-676?LOW IEVEI —— MED. LEVEL —— HIGH LEVEL " '

S01L/SED. ._ OTHER (Specify!,IFB Flit MM: ftpy«aia.-?c (I

Pete; 'irPllfi* . Shift; r Analyst;

Mm50

75

. 9596173174175176

177

' IFBIon Abumiance Criteria15 •> 40 percent of mass 9530 • 60 oercent of MSI 95base peak, 100 percent5-9 oercent of MSI 95less than 1 percent of MSS 95greater thin 50 percent of Mass 955 • 9 percent of MSI 174greater thin 95 percent, butleu than 101 percent of 1745-9 percent of Mass 176

% Relative Abundance

tn.13}00.ao •*.**'. '..: —————— .

S2.9/P3-2* i £ $

S-2./2. ( W )3

3 £2 ( 7 )2•BFB Performance Kesuits:

nn

The BFB ptrfonaanct results were reviewed ind founderlttrli.

TrilmTiDeviationsDate/Time/lnstrument File dumber Compound n/i

inTtTilt

to be within the specifiediLJiy

OKIRequired ObservedAbundance Abundance

•

batecements:

Vilut 1n ( ) Ii t of MII 174Value in ( 93 ) 1s » of MII 176

I Value 1n ( 7 :) It I of MII 174 FORH VI1 01290"—""" Itvlilon Bate n/09/83•EH

' r fei fsAt < "J

f 29

E 8

-31

5- ' —& •' • "" ' I!....———————— • jj

______________________^ . ' ' I

™ •

•R

Co

X>

ifl

MEAD COMPUCHEMMASS LIST ' DATA) 6FB40127C11 # 145 BASE M/E', 9B01/27/84 7ii2',00 + 7', S3 RIC: BBB33,SAMPLE: SUL OF BFBttiOS86(700B)F)145 TO #146 SUMMED - #34 XI. 00

36 0, 00 MINIMA MIN INTEN', 0. MAX INTEN'. 16640,867 # 0 MAXIMAMASS % RA

36 9. 6737 11.3138 117539 5, 3641 1,98 - .49 & 82 .50 3a 6951 10.72 '-55 0.6656 5,4557 6.0461 6,2562 E 6563 7,5066 17,1669 16,2070 0,5071 8,2473 a 46 .74 20.41

Kto 75 .51, 73Rf 76 6.65

•79 15,05BO 3; 1661 16.2062 2.4967 2.6766 2.7092 4.2693 5.5194 16.3595 100, 0096 6,94141 0.98174 52.98175 a 28176 5E12177 a 63267 0.63

0129U

VOLATILE INSTRUMENT TUNE AND PERFQRHAHCE

1 CASE NO. ______ CONTRACTOR Mead CompuChem CONTRACT M. 68-01-676?. w uyE|> —— mo, LEVEL"~~~"~"""~ HIGH LEVELHATER SOIL/SEP. OTHER

IFB F1lt Mfflti BFftJP/J? AllDate; """ ' Shin; Aniliit:

Miss5075

. 1596173174175176

177

HIon Abundance Criteria15 • 40 perctnt of Mass 9530 • 60 percent of MIS 95MM peak, 100 percent5-9 percent of MSS 95less than 1 percent of MSS 95greater than 50 percent of MSS 955 • 9 percent of MSS 174greater than 95 percent , butless thin 101 percent of 1745*9 percent of MSI 176

> Relative Abundance

SZ.O/OO.OS. 1 •• ' '.. '<MJStf.O3,? ( t..*\ V

«,sT ( ***4.0 ( 7.C. )2

BFB Performance Results:r""~i The IFB performance results ware reviewed ind found to

erlttrli, /..i &(mm tu

)"""1 OtvlitlonsDite/Tim/lnstrument File Number Compound •/!

•

be within the lotclfltdJ?-*?J-8</

milRequired ObservedAbundance Abundance

•

initials DateOMments;

1 Value In ( ) Is t of MII 1742 Value In ( ) Is X of MIS 1769 VllUt 1n ( ) It S Of Mil 174 FORH Vll 012912

•EH

(Ei

•a

~~ &&!8- «, MflBS——"5j •"' ' •"•

8 ~ "' ' S 'a

sr.

I:

S *-si Is?

>•:.•" :<'•:>

012913SfjSc&

. . MEAD CQMPUCHEMMASS LIST DATA: 6Fa4012<ftl9 # 187 BASE M/E; 95101127/83 8:09:00 + 9:30 RIC: 77056,sfltE; 2 UL BFB #10606 ON #19

36 0,00 MINIMA MIN INTEN: 0, MAX INTEN: 14320,177 # 0 MAXIMA

MASS % RA MASS X RA

36 1.79 142 1.6637 9,97 153 0,54 • .38 6,47 174 55,0339 S. 64 17S 3,7840 13.59 176 53.46 "" '41 6.91 177 3,9542 1.34 :43 11.4044 15.1145 6,6547 1.0849 S, 37SO 24,1951 8,3255 4,9556 2. 4057 9.6458 4,6259 0.66 . ;.61 S. 16

4,924,17

67 1,67 !:68 11.52 :

- 69 14. 89 :70 1,5971 3,0473' 6,3074 16,76.75 32,0176 4.9977 0.9379 2,8480 0.6481 3,7482 1, 2883 1.6785 1.4687 4,7388 6,3391 1,5692 2,2693 4.6894 10,98"95 108,0096 8,0997 1,55

A»0.66

115 0,78141 a. si

si-

is1

PiIs

g

ii P ii P

micstt •Jgf

J "* "* H 5

s*

28-8"

e

wil ii i il P ii P il P»«913

Ffl

AS

m

TO 8en

00 8

M - " " - " 5

m

8!

Owl ( * 90 10

88 P ' 8§ P 8£ P W \MW^

« * ffl S S r- *

IB*

|u<r

g

•aPB|s§**S

Ol

M

ffi I01&21S

285

Ul

s s •'H. HS

gg P 012923

29 M

flMPLITUDE x.2S uV-SKCondi, (EnUryird * 3.37!

-1 o S e3ffl ? ? ?•bri»nM

33aa,•,B tt

*NXn23.

.i <n ;'Off. J,

-to «>• "

sia r

.25-'

012924

*?

Report i 3053. 11 Channel i ?.%p)in SD MI) TnjpctPrt flt 3.1 1 54 1 56 ON ,TAN 25,ERTD Method i PAKOS S«i] i SEQPH Subp<i/8ani>i I/HO Bt'l . i 1081 -width MV/Min DfiJjM Min-Ar Bunch,500 .300 fl.OO 30 AutoSup-link D«T ID-ivl ' Ref-RTU XRTU XDn-f T«oNO n.nii i) ,;in 5,0 tno.oo NOActwal run tinei ?5,0)7 ninHtos '• . ,

Enrt«i< not on b*f>«line

RT ITM Factor Area UC/MI.

,S9 0.00 , 10000F.+OI, R59PD. BB 85919.977.64 0,0(1 .10000F.+01 505, BH 505.1P579 0,00 .lOOOOFtO! 49, BB 4R.711

l.(\?. 0,00 , 10000F+01 35H. BR 358,00(1l,4:t 0,00 ,10001)5+1)1 996. BB 996,3131.72 01 Oil ,10000F.+ (I1 1349. BB 1349,1?.51.94 0,00 ,10000Rtfl1. 3334, BB 3334.406!?,37 0.00 10000F. + 01 )537. Bh »537,156g.M 0,00 .innnoRtin 11.5 m us.4392.H6 0.00 .lOOOOK+Ot 75314, BH 75314,4373.70 0.00 .100001^+01 4fi!>, BB 4B3.063n.69 0,0(1 ,10000F.+ Q1 ?.fl34. BR KB34.0008.14 0,00 .10000F+01. 63A9S, BB fcaA9f!,3759.R6 0,00 .10IIOOF.+ P1 MI759. BB 10759.000U.flS 0,00 ,1000flF,+m 3R\60, BB 3B160.37515.92 0,00 .10000F.+01 15?.6. BR • 15?5,75ll

f! !ll"'J,'So ,'lOIIOOE+Ol 3)573! BF 31573,'flOOTotal Arna = H56970. Total UR/lH. « 31,573.000Procesiefl rtat* f*lp. PP(MI) RAW dflta fUi«. R?.01Q

012923

AMPLITUDE x.2S uV-seconcU (EnUrywJ A

-i

SB*"

o o Q «a a o oCD ® CP **

MD

3B wrl

sa^ *30 10

-JZR

WO

Ol-Mo

7s. ?»•• Jn

^(B M

8?:«m

21.67•Ja

.36

2.56

SSs— 6.91

9.9S

w " 012928

-• • C')l. 11. '....™_.,.....ul 29

Import i 6766.00 Channel i 7^Vpl*. Ml) Tnjected at PJiQPiE). UN JAN !?6, 19H4(-.5TO Muthodi PACK07 SPT SF.Q73 Subsq/Hanpi 1/1.0 Btlt ll»

s;'-w!soho rSK "Wl MinufiroB.fgUah DvTfl H-...J R,f-RTU

Actual run tint) ?5,017 ninutrngnitnit not on banaline

RT ITH Factor Ar»a MB/MI.

,03 0.00 .lOOOQE+Ol 11301. BB 11300.B9B.30 0,00 .10(1006+01 302433, BS 30P433.370.63 0,00 .IOOOOI-+01 7096. BB 7096,484~~ " "" 10000F.+01 8179, BH «17fl,61.7

—— -- 2345. BB jftffl.iOOOOFl+Ol 3074. Bfi ..........,lOUOOKtnt 37095. BB 2709S.14B.1000QF.+01 35150, RB 25149,703

0IIF.+01 fl74B. .10000F.+01 6111,

0.00 .lOOOOIt+01 35493.O.OQ .100QOF.+Q1 939517, BB0.00 .lOOOOE+Ot K6816. BB0.00 .10QQQF.+01 956900. BB ,0,00 .10000g+l)l . !!6541. BB 36541., 1)620,00 ,1QOOOrT>Ol .1BB5, BR 1HR4.5310..00 ,1000.0E+01 • 177BB, BB, 177HR,2SO

. 0.00 .100QOK+01 5098. RB " 5097.50017,94-17,9* .49713F.-II7 76H4, BB ,000' *I)BC

0,00 .lOflnOE+fll 606573. BB 60657H.5000,00 .lOOOOKtOl 1314, BB 1313.750Total Are-* » 4478769, Total Mtt/MI. « 1313.750

fl]f> P7310 Raw data flle>i R731Q

012927

AMPLITUDE X.2S uY-I«ond* lEnUrqtd X 2.66)M »• M: S S S 8

srSM *

lauA••

•o !•B M

NX

•-NOH

.32?j:?9

2.51

12.69

13.31

1E.0C.

\ 16.01

J^is.as

* "" 012928

Ke>porti 6731.00 Channel> 7SacipliM UJ) HO Injected at El^'libO UN JAN 24, IVtMESTD Methodi PACK07 Ueq i SiEWa iiubsq/SaMp i 1/11) Btli 10BX-rtJty ..hV/Mln Dfti m,oAr gnth

Actual run tinei 25,017 MinutesEndnd not on

RT ITH Factor Art* HG/HL N«nt

.30 0,00 .10I100E+01 3002S6, BS 300M5.7SO,6i! 0,00 , IDOOOLlUl 101U&, HB 101l)<;.64fl.70 0.00 .1UOOOI;+01 UVW. BB 8963,180.Vi! 0,00 JOUUDHIll i'bMl, UH i!<J6ll.i4i

1.2V 0.00 .lOOOQIvtOl 84713. Bfl 249U.016l.W 0,00 .IOOOOhM'01 ?6ilVU. BU ii6HVlJ,062..... o.oo .looiioii+oi 2.17/6. BB 23776.109> SI 0,00 lOlDOe+01 1429916 131489916 000J.i!2 0.00 ,10000L'+U1 Vliil. bU V131.VB14.7V 0,00 .IDOOOtCiOt 9U11, BB 9310,9385,6V 0,00 .IQQOOEfOl S44i. BB 11441,063I 94. 0 00 10000 01 9171)73, BB 919071!.750B.3'J 0,00 ,JOQOOM'Ul S730V. UB 2'/:iOU,tl7!>10,01! 0,00 .lOOOOI-ll'Ot V393'j4. BB 9J7354.000ID,BE) 0,00. .lOOOOt.HOI 3VlVi!4, UU aViVi'3,8712,0V 0 00 .lOOUOtlrUl 10IU, Bti 1B8D.S6313,31.0,00 .lUOOOLI'IOl i'/V6V, BB l'/r/60,6i.5IS.U'.i 0,00 .lUUUOliUll >>?&>, Btl Q92S.250iy'.S'/'o'.oo '.ioooueioi t>4L*V '. SB 542 6',7so

Toti) Area • 4347322, Total HU/HI - itti&tt.,7'JOr'roce»sed dstfi filei HVIHO K*H data filf>i K71J1U

012929

012930

29

INSTRUMENT BLANK ^ LlvlUiqU1d

SL m

j&njm

^ INSTRUMENT ILANKft

Low Level Liquid

flab "»••! Head Cce"puChem •I lab

A. SURR06ATE Pl« KESULTS

COMPOUND

M>To1uim

IM.l-Dlcnloroethane

IroMfluorBMnuni

" .

•

i

FRACTION

VOA

VOA

VOA

CONC(ug/i )

n.6i(*.au.)

£,' •

Surrojitts onijQAddldlug/l. )

20

20

20

tRecovery

80,5^0,2T

012932

88

ft

'ft

9F-&*

-gu1®

PROCEDURE; RK DIAGNOSTIC REPORT 1/37/84 lc' i.DATA FILE'. 06840137811REFERENCE: VE37

METHOD'. V237 INITIALIZATION OPTION', S PROCESSING OPTION', 3.,,... REPORT'. V237S1r">•: —— STANDARDS ——— X —— PUUS UNKNOWNS —— X - LIST NAMES - >PROC USED POSS RMS PROC USED POSS RMS STANDARD/UNKNOWN

3 2 1 0 44 5 1 97 V237S1/V837U1

< COMPOUND X ———————— SEARCH ———————— X SAT X ———— CHRO —NO LIB ENTRY REF PRED SEL DELTA PEAKS FIT PEAKS fl/E TOP DELT*1 PI 1 161 163 163 , 1 982 139 163S P2 i -337 33B . . . , , "' 79' 3383 P3 1 416 416 416 . 1 974 . 85.' 4164 PI 2 -29 38 . . , , 505 PI 3 48 43 . . . 946 PI 4 52 S3 . . . 637 PI 5 6B 69 . . . 64B PI 6 102 103 . . , . . 64 1049 PI 7 -111 112 . . , SB 1131 0 P I B -111 1 1 2 . . . . . 5 611 PI 9 124 125 . , . 5312 PI 10 139 140 . . . , 1011 3 P I 1 1 1 2 9 1 3 0 . . . . . 7 614 PI 12 152 153 . , . 9615 PI 13 176 177 , . , . , 6516 PI 14 190 191 . . . ' . 961 7 P I 1 5 2 0 2 2 0 3 . . . . . 6 3 2 0 3

»*1B P I 1 6 -216 2 1 7 . . . . . 6 3 2 1 5;!''19 PI • 17 213 314 . . , . , '7220 PI IB' 240 841 . . ' . , . . 97 . ,21 PI 19 -248 849 . , . . 1 1 7 ,22 P2 2 251 852 . . , . 4323 P2 3 256 359 , . . , 12724 P2 4 284 285 . , . 6525 P2 5 290 891 . . • • • ' • • _ • 75... ...26 P2 6 301 302 . . . . :~ "L. 130 30027 P2 7 310' 311 —,-- • 7B- , •--28 P2 B 315 316 , . . , 9729 P2 9 -315 316 . . . , 7530 P2 10 -314 315 . , . 1273 1 P 2 1 1 -336 33 7 . . . . . 6 3 3 3 9 '32 P2 12 366 367 . . . 17333 P2 13 374 375 . , SB34 P3 2 405 405 . . . 5635 P3 3 • -411 411 . . . . 63 .36 P3 4 412 412 . , •-. . . 164 41237 P3 5 436 436 , , . . 93 43638 P3 6 459 459 . . . . . 112 45939 P3 7 495 495 . . . , , 10640 P3 B 566 566 . . . . 10441 P3 9 5B8 5BB , . . , 10642 P4 2 -214 215 214 -1 1 964' . 65 21443 P4 3 433 433 433 , 1 993 , 100 43344 P4 4 540 540 ,541 1 1 949 , 176 541

' 012935

28 OOM8S

QUANTXTrtTXQN REPORT FILE'. CBB40127B11

DATA'. CBB40127B11, TI01/87/84 17i4i',00nEi 5ML H30+5UL 10B83M.OBB8

TTED BY i 11 ANALYST'. 7EB

AMOUNT-AREA * REF. AMNT/(REF. AREA)t RESP, FACT)RESP. FAC, FROM LIBRARY ENTRY

NO NAME1 t BROMOCHLOROMETHANE (IS)2 221 CHLOROMETHANE3 220 BROMOMETHANE4 231 VINYL CHLORIDE ... .5 209 CHLOROETHANE6 222 METHYLENE CHLORIDE7 252 ACETONE (2-PROPANONE)B 201 ACROLEIN9 202 ACRYLONITRILE10 230 TRICHLOROFLUOROMETHANE11 254 CARBON DISULFIDE12 216 1,1-DICHLOROETHYLENE13 214 1.1-DZCHLOROETHANE14 226 TRANS-i, 2-DICHLOROETHYLENE15 211 CHLOROFORM16 215 1, 8-DICHLOROETHANE17 253 2-BUTANONEIB 227 1.1,1-TRICHLOROETHANE19 206 CARBON TETRACHLORIDE20 * 2-BROMO-l-CHLOROPROPANE

257 VINYL ACETATE22 212 BROMODXCHLOROMETHANE23 217 1.2-DICHLOROPROPANE24 250 TRANB-1, 3-DICHLOROPROPENE25 229 TRICHLOROETHYLENE26 203 BENZENE27 286 1,1, 2-TRICHLOROETHANE26 216 CIS-1, 3-DICHLOROPROPENE29 -206 DIBROMOCHLOROMETHANE30 210 3-CHLOROETHYL VINYL ETHER31 205 BROMOFORM32 256 4-METHYL-2-PENTANONE33 * DICHLOROBUTANE34 255 2-HEXANONE35 223 1. i, 2, 2-TETRACHLOROETHANE36 -224 TETRACHLOROETHENE37 225 TOLUENESB 207 CHLOROBENZENE39 219 ETHYLBENZENE40 251 STYRENE41 239 0-XYLENE42 » D4-1,2-DICHLOROETHANE43 * DB-TOLUENE44 t ^BROMOFLUOROBENZENE

NO M/E SCAN TIME REF RRT METH AREA(HCHT) AMOUNT ^^

2S

73Q'01293

NO M/E SCAN TIME REF RRT METH AREA(HGHT) AMOUNT V.TO1 130 163 B: 17 1 1. 000 ft, BV 31839. 80. 000 UG/L 13, 5'2 NOT FOUND3 NOT FOUND

NOT FOUNDNOT FOUND

6 84 104 5:17 1 0.638 ABB 1612. 0, 891 UG/L 0,67 58 113 5:45 1 0. 693 A*BB 1064. . 30, 305 UG/L 80. 5.-.6 NOT FOUND9 NOT FOUND10 NOT FOUND11 N3T FOUNDIS MOT FOUND13 NOT FOUND14 NOT FOUND - •15 83 203 10:19 1 1.845 ABB 19B1. 0.4B2 UG/L 0,3;16 62 215 10:56 1 1,319 ABB 917, 0. 345 UG/L 0.2:17 NOT FOUNDIB NOT FOUND19 NOT FOUND80 79 336 17:11 80 1,000 ABB 31621. 80, 000 UC/L 13,5'21 NOT FOUND22 NOT FOUND23 NOT FOUND24 NOT FOUND25 130 300 15:15 1 1.840 ABB 127T. 0. 601 UG/L 0.4.26 NOT FOUND27 NOT FOUND2B NOT FOUND29 NOT FOUND30 63 339 17:14 1 2,080 AtBB 440. 0. 669 UC/L 0.41.

(ftSjfi NOT FOUND32 NOT FOUND '33 '55 416 21:09 33 1,000 ABB 47747. 20, 000 UG/L 13,5'34 NOT FOUND35 NOT FOUND36 164 412 20:57 1 2,528 AtBB 1487. 0, 600 UC/L 0.5-37 98 436 22:10 1 2. 675 A BB 3015. 0. 636 UC/L 0. 4'i3B 112 459 23:80 1 2,616 ABB 666, 0. 193 UC/L 0,1'39 NOT FOUND40 NOT FOUND41 NOT FOUND42 65 214 10:53 1 1, 313 A BV 56460, 16. 669 UG/L 11. 4-.43 100 433 22:01 1 2,656 A BB 99563, 17.516 UC/L 11. 8-:44 176 541 27:30 1 3,319 A BB 72519, 16,140 UC/L 18. 3".

NO RET(U) RATIO RRT(L) RATIO AMNT AMNT(L) R. FAC R. FAC(L) RATIO1 8:06 1,02 1,000 1, 00 20.00 80.00 1.000 1.000 1, 002 1:25 0,175 60. 00 0,9353 2:08 0.863 BO, 00 1,3834 2:36 0,319 60.00 1,196B 3:24 0,419 BO. 00 0,6766 5:08 1,03 0,631 1.01 0.89 60. 00 0, 016 1,656 0, 017 5:35 1,03 0,667 1. 01 30. 31 599. 99 0, 002 0,038 0, OSB 5:38 0,687 799. 99 0,047 __9 6:15 0,769 799.99 0, iA3fV1293710 7:01 0.668 60.00 4.064 *

w

60. 00 5, 11518 7:41 0, 944 80, OC 1, 071

8:57 1. 100 80, 00 0. 865'14 9:36 1, 181 80. 03 1. 79015 10:13 1. 01 1, 356 0, 99 0.48 80, 00 0, 023 3. 763 0. 0116 10: S6 1. 00 1, 344 0, 98 0, 35 80, 00 0. 010 8, 433 0. 0017 10:50 1, 331 599. 99 0. 049IB 12:09 1,494 80,00 3,50319 18:33 1,544 80, 00 8. 85320 17:08 1. 00 1, 000 1. 00 20,00 8Q, 00 1. 000 1. 000 1. 0021 13:42 1,562 80,00 1. 554 •'28 13:07 1, 618 80, 00 0, 26723 14:86 1,775 80. 08 ... 0. 56524 14:41 1,606 80,00 3,53525 15:15 1.00 1,875 0,98 0,60 80,00 0.015 1/947 0.0126 15:43 1,931 80, 00 6.03927 15:56 1.968 60, 00 1.14526 15:56 1,962 BO. 00 1,44189 15:52 1,950 60,00 1.57730 17:08 1. 01 8,094 0, 99 0, 67 BO, 00 0. 005 0. 608 0. 0131 IB: 33 2.261 60. 00 0. 98732 19:01 2,337 120, 00 0,19333 81:09 1. 00 1,000 1, 00 20. 00 20. 00 1, 000 1, 000 1. 0034 20:32 2,525 120.00 0.39635 20:50 2,562 60.00 1,15936 20:54 1.00 2,569 0, 96 0,60 60.00 0. 016 1.634 0. 0137 22:10 1,00 2.725 0. 9B 0,64 60.00 0, 035 4.343 0, 0136 23:17 1,00 2.662 0, 96 0.19 60,00 0, 010 4.099 0. 0039 25:10 3.094 BO. 00 2. 65340 28:43 3.531 BO, 00 4.42641 89:50 3,669 . BO, 00 3,21842 10:50 ii 00 1, 331 0, 99 16, B9 80, 00 3, 585 3, 061 . 0. 8443 81: SB 1, 00 8,700 0, 9B 17.58 80. 00 4, 559 5, 805 0. 8844 87:84 1. 00 3, 369 0, 99 IB, 14 20. 00 3. 381 3. 661 0. 91

012938

28

INSTRUMENT BLANKLow Level Liquid

t§Wit»» Hid* . Mild CereuCMff CM* NiM _LM> tuftU 10 No. (LUlMt W7 R W : Aiioctatri tm>\mWlRrj<J/yZ, tt)

Si SSL U9/1i an \tn-tn-t «efoi»t»________ND

(iwrfrl»1tj Militant HaireM Meteraat

BU

012939

INSTRUMENT BLANK

ft Low Level Liquid

Lib Rime; Head CompuChemLib Simple I.D. No.

A. SURROGATE SPIKE RESULTS

COMPOUND

d8-To1uene

d'-l,2-D1enloroethane

BnxMfluorobanzene

'*

•

FRACTIONVOA

VOA

VOA

CONC(ug/i )

/7<y/U/&*>

^Surrogates only)spineAdded (uj/1. )20

20

20

•

•

IRecoveryOw

4/%£

•

_ . _

012940

..•.,-fc... 89 '

'1091199

PROCEDURE.' RK DIAGNOSTIC REPORT 1/27/83 9:10:41DATA FILE; CB840127A19REFERENCE.' V337OlETHQOi V237 INITIALIZATION OPTION: 3 PROCESSING OPTION: 3

REPORT; V237S1

•C —— STANDARDS ——— X —— PLUS UNKNOWNS —— X - LIST NAMES - >PROC USED POSS RMS PROC USED POSS RMS STANDARD/UNKNOWN

3 3 1 24 44 6 1 69 V837S1/V837U1

1 PI 1 168 168 168 . 1 9B9 , 130 -168 , 1S PS 1 35.4 3S5 3SS , 1 748 . 79 ' 354 -1 i3 P3 1 436 437 437 . I 995 , 53 437 . 14 Pi 8 86 86 , , 50 26 . 15 PI 3 -39 39 ,. 946 PI 4 49 49 . , . . . . 687 PI S 65 65 . , . 648 Pi 6 103 103 , , . . . 64 103 . 19 PI 7 -115 US , . . . 58 116 a1 0 P I 8 -114 1 1 4 , . 5 611 PI 9 188 188 . . . . 53IS Pi 10 144 144 , , . 10113 PI 11 133 133 . , 76 134 . ,t14 Pi 18 458 -158 , , ... 96 . . ,IS PI 13 184 -164 . . . 63

PI 14 199 -199 . . 96PI IS 811 .811 . . . 83 813 , 1

,18 'PI ' 16 286 7886 . . . . 6819 PI 17 -884 :S84 . . 78 886 , 120 PI 13 850 =850 , 9781 PI 19 858-" 859 . . . . 11722 pa 2 -263F 864 . . 43"33" f1 ——"3. 8 7 1 8 7 8 . . . — — . 1 8 7 , .84 Pa 4 397: 898 . -;•• '6S" 897 , 1"8 5 P a S 303- 3 0 4 . . . . . 7 5 , , ,86 Pa 6 315i 316 . , , 13087 PS 7 384. 385 78 385 , 88 8 P a 8 330:. 3 3 1 . . . . . 9 7 . . .89 P£ 9 -330- 331 .. 75 , ' .30 PS 10 -388 389 . . 18731 PS 11 -358 353 . . . . 63 354 138 PS 18 384 3B5 , , , 17333 PS 13 398 393 . . , . 5834 P3 8 485 486 . . . 5835 P3 3 -438. 433 . . 6336 PS 4 438L 433 . . , 16437 P3 9 437' 458 . . , . , 9238 P3 6 481 468 , . , 11839 P3 7 385.. 526 . . . . 10640 P3 8 680- 688 , . 10441 P3 9 6S81' 654 , . . 10648 P4 1 -834 884 825 1 1 996 .63 885. nQ.ytf 1

P4 2 454' 453 454 -1 I 997 . 100 4SQ1&3? iP4 3 585 586 587 1 1 983 , 176 586 -1 1

.JL.W.

QUANTICATION REPORT FILE: CBB40127A19

&TA: CB840127A19, TI783 8:26:00

SAMPLE. S ML H20 + 5 UL 10888%10888 ON *19SUBMITTED BY.' #19 ANALYST: 633

AMOUNT'AREA * REF. AMNT/1REF, AREA)» RESP. FACT)RESP. FAC. FROM LIBRARY ENTRY

NO NAME1 * BROMOCHLOROMETHANE (IS)8 221 CHLOROMETHANE3 820 6ROMOMETHANE4 831 VINYL CHLORIDE3 809 CHLOROETHANE6 888 METHYUENE CHLORIDE7 258 ACETONE (2-PROPANONE>8 201 ACROLEIN9 208 ACRYLONITRILE10 230 TRICHLOROFLUOROMETHANE11 234 CAR80N DISULFIDEIS 216 1,1-DICHLOROETHYLENE13 214 1,1-OICHLOROETHANE14 886 TRANS-li 8-DICHLOROETHYLENEIS 811 CHLOROFORM16 213 1, 8-DICHLOROETHANE17 853 8-BUTANONE18 8S7 1,1.1-TRICHLOROETHANE

totf 806 CARBON TETRACHLORIDE"ab * 8-8ROMO-1-CHLOROPROPANE81 857 VINYL ACETATE88 212 6ROMODICHLOROMETHANE23, 817 1, 8-DICHLOROPRCPANE24 230 TRAN8-1.3-DICHLOROPROPENE83 289 TRICHLOROETHYLENE26 203 BENZENE87 -888 1, i, S-TRICHLOROETHANE88 818 CIB-1, 3-DICHLOROPROPENE89 80S DIBROMOCHLOROMETHANE30 810 8-CHLOROETHYL VINYL ETHER31 80S 6ROMOFORM38 836 4-METHYL-8-PENTANONE33 * OICHLOROBUTANE34 235 8-HEXANONE33 883 1,1, 8, a-TETRACHLOROETHANE36 884 TETRACHLOROETHENE37 235 TOLUENE36 207 CHLOROBENZENE39 219 ETHYLBENZENE40 851 8TYRENE41 239 0-XYLENE48 tt D4-1.8-DICHLOROETHANE43 ' tt DB-TOLUENE44 « BROMOFLUOROBEN.ZENE

y» M/E 6CAN TIME REF RRT METH AREA(HGHT) AMOUNT

NO M,'E SCAN TIME REF RRT METH AREA(HCHT) AMOUNT V.TOT1 130 167 8: a? 11, 000 A BB 60BS5, 80, 000 UG/L 15. 61

ft SO 26 1.-19 1 0.156 A BV 351. 0. 078 UG/L 0,06d NOT FOUND4 NOT FOUND5 NOT FOUND6 84 103 5:14 1 0. 617 A BB 4343, 0. 846 UC/L 0.667 58 116 5:54 1 8. 695 A*BB 1484. 7.031 UG/L 5,508 NOT FOUND9 NOT FOUND10 NOT FOUND ' '11 76 134 6:49 1 0. 80S ABB 396, 0, 035 UC/L 0,0318 NOT FOUND ... .13 NOT FOUND14 NOT FOUNDIS S3 813 10:50 1 1,275 ABB 4761, 0,577 UG/L 0,4516 NOT FOUND17 78 S26 11:89 1 1.353 ABB 1588, 5. 789 UG/L 4.4718 NOT FOUND19 NOT FOUND80 79 334 18:00 80 1, 000 A 8B 43768. 80. 000 UC/L 13, 6181 NOT FOUND88 NOT FOUND23 65 297 IS: 06 1 i. 778 A BB 490, 0.394 UG/L 0, 3124 NOT FOUND85 NOT FOUND26 78 385 16:31 1 1.946 A*BB 463, 0. OBI UG/L 0,0437 NOT FOUNDJW NOT FOUNDW* NOT FOUND • • •30 63 '334 18:00 1 2,120 ABB 8683, 8. 306 UG/L 1, BO31 NOT FOUND38 NOT FOUND33 35 437 88:13 33 1.000 ABB 133153, 80, 000 UG/L 15,6134 NOT FOUND35 NOT FOUND36 NOT FOUND37 NOT FOUND38 NUT FOUND39 NOT FOUND40 NOT FOUND41 NOT FOUND42 65 885 11:86 1 1,347 A BV 154385, IB, 856 UC/L 14,8543 100 454 23:05 1 8. 719 A BB 163053. 17.498 UG/L 13, 6544 176 596 29> 47 1 3. 509 A 6B 163611, 15.348 UG/L 11, 98

NO RET (L) RATIO RRT(L) RATIO AMNT AMNT(L) R, FAC R, F AC (L) RATIO1 7:34 1, 07 1.000 1. 00 80,00 80. 00 1, 000 1,000 1,008 1:28 0.96 0.160 0.97 0, 07 80. 00 . 0. 001 1. 601 0.00fl S: 02 0.837 60.00 3,8844 2:38 0,896 80.00 3.8785 3: SI 0,391 80. 00 1,8466 5; 17 0.99 0,615 1,00 0.85 80.00 0.018 1689 0.017 3:57 0.99 0.692 1.00 7. OS 399.99 0. 001 0,069 0,018 5:54 0.686 799,98 0.118

Lj 6:36 0,769 799.98 0.815 A .„*$> 7:88 0*858 80.00 8.762QJ.2945

NO RET<L) RATIO RRT(L) RATIO AMNT AMNT<L) R, FAC R, FAC(L) RATIOU 6:49 1 80 0, 793 1, 01 8, 83 80. 08 0. 082 3, 744 8. 80ft 8:05 8, 941 88, 88 0. 771la 9:84 1.895 80,00 0,59514 18:13 1,189 88,88 1. 18S15 10:58 1 80 1.360 1 01 8, 58 80, 00 0, 020 8, 726 8. 0116 11:33 1.343 80.88 2. S7917 11:39 1 88 1337 1. 01 5. 73 599. 99 0. 001 0, 091 0, 8118 13:49 1.491 . 88,00 1899..19 13:13 1538 80.88 1.881. .80 18:06 0. 99 1808 1, 80 80, 00 80. 00 1, 880 1 080 1 0881 13:88 1, 568 80.88 1, 68988 13:50 1609 80. 80 - 0. 15783 IS: IS 0, 99 1, 769 1. 01 0. 39 88,00 0, 808 0, 489 8. 8884 13:38 1885 80,88 8.00483 16:87 1.876 60.00 111186 16:34 1 80 1989 i. 01 0.05 80.88 0, 088 3,138 8.8087 16:33 1964 60.80 118988 16:33 1,964 80,80 0,98189 16:46 1.953 80,88 1.04830 18:00 1 80 8.895 101 8. 31 80, 00 8, 811 0. 383 0. 8331 19:34 8,878 80.88 0,87438 88:03 8.331 180. 80 0. 306aa 82:19 i, oo 1000 i. 00 ae. 00 ao, 00 1000 i. ooo i, 0034 81:48 3,587 180.80 8, 67135 23:01 8.562 88,00 8. 11836 28:04 8.368 88.08 115137 83:83 8.788 80.88 8.839

fcrg 84:33 8,858 . 88,08 8,834M 86:58 • 3. 184 80, 88 1 57140 31:46 3.698 88, 88 3.38141 33:81 3,888 80,80 193448 11:86 1.0.0 . 1 331 1, 81 IB, 86 30, 80 8, 537 2. 780 0. 9143 83:11 1.00 ' '£, 698 1. 01 17. 49 30, 88 8. 681 3. 06S 0, 8744 89:56 0, 99 3,485 1, 81 15.35 88. 80 8, 698 3. 505 8. 77

012948

ftLM la*)! ID No.

INSTRUMENT BLANKLow Level Liquid

Mon<«rtarHr Pel Mart tareMa MttanM)

MiltlMfM

«-<n>

IQrXM

la,| 012947

ioe-o»* »iB»HMttt«. fMM

,.——™_Jra,, w.jmim..

INSTRUMENT BLANK

ft Low Level Liquid

Lab Ham; Head CompuChem ,.lab Sample I.D. No._

A. SURROGATE SPUE RESULTS

COMPOUND

dB-Toluene

d4.l,2-01cnloroethane

Irooofluorobenzene

^

'

FRACTIONVOA

VOA

VOA

CONC(ug/i )

A9mm

^Surrogates only)Added (U9/1. )

20

20

20

' i

%Recovery

9k0.5?J

...

012943

11 2?

ft

C/l

1

012943r« •

j}900

•"

r

Sri?ml29

J O .0

^PROCEDURE: RK DIAGNOSTIC REPORT 1/87/84 b; ,i,i 18DATA FILE: CBB40.127C11REFERENCE: V837

METHOD: V837 INITIALIZATION OPTION'. 8 PROCESSING OPTION'. 3ft REPORT: V837S1

< —— STANDARDS ——— X —— PLUS UNKNOWNS —— X - LIST NAMES - >PROC USED POSS RMS , PROC USED POSS RMS STANDARD/UNKNOWN

3 1 1 0 44 4 1 70 V337S1/VS37U1

44 COMPOUNDS PROCESSED, 4 FOUND

< COMPOUND X ————---—— SEARCH ————————— X SAT X ———— • CHWO — - — • >NO LIB ENTRY REF PRED SEL DELTA PEAKS FIT -PEAKS n/E TOP DELTA n¥r':S1 PI 1 -160 162 168 . 1 979 --430 • 163 12 P8 i -336 340 , . , . . 79 . 337 13 P3 1 -415 428 , . . , , 55 ' ,4 P I 8 - 8 8 8 9 . . . . S O .5 PI 3 -41 48 . . . . 946 P I 4 - 5 1 5 8 . . . . . 6 87 PI 5 -66 67 . 64 ,B Pi 6 -100 101 . . . , , 84 183 19 P i 7 -109 1 1 0 , . . . . 5 610 PI 8 -109 110 , ... 5611 PI 9 -188 123 , ... 5318 PI 10 -137 136 , ... 10113 PI 11 -187 186 . . , , . 7614 Pi 18 -150 151 , . , " , 9615 PI 13 -175 176 . . . . 6516 PI 14 -168 189 . . . , , 96,V7 PI 15 -800 881 . . . . B3 881 1

OB PI . 16 -814 815 ... . - 681 9 P i 1 7 -818 8 1 3 . . . . . 7 8 . '8 0 P i I B -838 8 3 9 , ' . . . 9 78 1 P i 1 9 -846 ' 8 4 7 . . . . . 1 1 78 8 P 8 8 -850 8 5 1 . . . , ' . 4 383 P8 3 -857 258 18784 P8 4 -883 884 . . . . _ 6585 P8 5- -868 889 . . . ' . -~—— 75" " '.~8V~P2~' ~6 -899 300 . . . . •" . " 130 89.9 _£87 P8 7 -308 309 . . . . " 78" "'.'""2 6 P 8 8 -313 3 1 4 . . . . . 9 7 ,89 P2 9 -313 314 753 0 P 8 1 0 -318 3 1 3 . . . . . 1 8 731 P8 11 -334 335 63 33B 138 Pa 18 -364 366 , . , . . 17333 P8 13 -373 375 , ... SB .34 P3 8 -403 405 SB - ,35 P3 • 3 -409 411 83 . '36 P3 4 -410. 418 . . , , . 164 410 S37 P3 5 -435 437 . . . , , 98 437 S3B P3 6 -457 459 , . . . . ,U23 9 P 3 7 -494 4 9 6 . . . . . 1 0 640 P3 B -564 566 10441 P3 9 -586 586 . . . - , - . 10648 P4 8 -218 213 213 . 1 966 65 213 143 P4 3 -431 433 438 -1 i 993 100 438 i

P4 4 -538 340 540 . i 94? , 176 539 -. 1

012951

[QUANTITATION REPORT FILE: CBQ40187C11

DATA: CBB40127C11. TIOi/37/84 7:30:00SAMPLE: 5ML H80 + 5UL(10882*10888)flMXTTED BY: 11 ANALYST: 817

AMOUNT-AREA » REF, AMNT/tREF. AREA)* RESP. FACT)RESP. FAC. FROM LIBRARY ENTRY

NO NAME1 * BROMOCHLOROMETHANE (IS)3 221 CHLOROMETHANE ' '3 220 BROMOMETHANE4 231 VXNYL CHLORIDE ... .5 209 CHLOROETHANE6 222 METHYLENE CHLORIDE7 252 ACETONE (2-PROPANONE)B 201 ACROLEIN9 202 ACRYLONITRILE10 230 TRICHLOROFLUOROMETHANE11 254 CARBON DI8ULFXDE18 216 i. i-DICHLOROETHYLENE13 214 1*1-DICHLOROETHANE14 826 TRAN8-1, 2-DICHLOROETHYLENE15 211 CHLOROFORM16 215 1. 8-DICHLOROETHANE17 233 2-BUTANONEIB 227 1.1. i-TRICHLOROETHANE19 206 CARBON TETRACHLORIDE20 .tt 2-BROHO-l-CHLOROPROPANEwlk 237 VXNYL ACETATE"J5 • 218 BROMODICHLOROMETBANE23 817 i, 8-DICHLOROPROPANE24 230 TRANB-i, 3-DICHLOROPROPENE25 289 TRICHLOROETHYLENE26 203 BENZENE27 228 1.1. 2-TRICHLOROETHANE26 816 CXS-li 3-DICHLOROPROPENE29 . 20B DXBROMOCHLOROMETHANE30 210 2-CHLOROETHYL VINYL ETHER31 205 BROMOFORM38 236 4-METHYL-2-PENTANONE33 * DICHLOROBUTANE34 255 2-HEXANONE33 223 1.1. 2. 2-TETRACHLOROETHANE36 224 TETRACHLOROETHENE37 225 TOLUENE36 207 CHLOROBENZENE39 219 ETHYLBENZENE40 231 STYRENE41 239 0-XYLENE42 * D4-1,2-DXCHLOROETHANE43 t DB-TOLUENE44 I BROMOFLUOROBENZENE

NO M/E SCAN TIME REF RRT METH AREA«HOHT) AMOUNT XTO'

W : 012952

NO M/E SCAN TIME REF RRT METH AREA(HGHT) AMOUNT '/.TO'1 130 168 8:14 1 1, 000 A BB 16595, 20. 000 UC/L 17, 8V8 NOT FOUND

JPH NOT FOUND•» NOT FOUND5 NOT FOUND6 84 103 3:14 .1 0,636 ABB 641, 0, 390 UG/L 0,3-7 NOT FOUNDB NOT FOUND9 NOT FOUND10 NOT FOUND11 NOT FOUND12 NOT FOUND13 NOT FOUND - •14 NOT FOUND15 83 201 10:13 1 1.841 ABB 1761, 0. 461 UG/L 0.4'16 NOT FOUND17 NOT FOUNDIB NOT FOUND19 NOT FOUND20 79 337 17:08 80 1000 ABB 26316, 20, 000 UG/L 17,2:81 NOT FOUND22 NOT FOUND23 NOT FOUND24 NOT FOUND85 130 899 15:18 1 1 B46 AtBB 1093, 0. 538 UG/L 0, 4-.86 NOT FOUND27 NOT FOUND2B NOT FOUND?9 NOT FOUND

63 338 17:11 1 2.086 ABB 336, 0, 599 UG/L 0. Si31 NOT FOUND •32 NOT FOUND33 NOT FOUND34 NOT FOUND35 NOT FOUND36 164 ' 410 80:50 1 2. 531 AtBB 957, 0. 574 UG/L 0, 4*37 92 437 82:13 1 2. 698 AtBB 2466. 0.557 UG/L 0. 4v36 NOT FOUND39 NOT FOUND40 NOT FOUND41 NOT FOUND42 65 813 10:50 1 1.315 A BV 50458. 16.198 UG/L 13, 9i43 100 438 81: SB 1 2, 667 A BB 97675. 18,949 UC/L 16, 3-44 176 539 87:84 1 3.387 A BB 62523. 17.841 UG/L 15. 3<-

NO RET(L) RATIO RRT(L) RATIO AMNT AMNT(L) R. FAC R, FAC(L) RATIO1 8:08 1.01 1,000 1,00 20.00 20,00 1.000 1.000 1.008 1) 25 0, 175 60.00 1,2263 2:05 0.256 60.00 1.6524 2:36 0, 319 BO. 00 1.5105 3:81 0.412 60,00 0,6706 3s 05 103 0, 625 1,08 0,39 60,00 0.809 1768 0,007 5:38 0,661 599.99 0.024B Si 32 0, 681 „ 799,99 0.0529 6:12 0,763 799.99 ' 0.115

6:58 ft 856 ' 60,00 4, 282012953

NO RET(L) RATIO RRT(L) RATIO AMNT AMNT(L) R, FAC R, FAC(L) RATIO11 6:87 0, 794 60, 00 5, 66612 7:37 0. 937 80, 00 1. 889.,13 8:54 1 094 80, 00 0. 977r> 9:33 1 175 80, 00 S. 08015 10:10 101 1 850 0, 99 0.46 80. 00 0, 084 4. 159 0. 0116 10:53 1. 337 80, 00 S. 58317 16t 47 1. 385 599. 99 0. 039IB 18:06 1. 467 80. 00 4. 04619 18:30 1 537 . 60. 00 3, 25620 17:05 100 1 000 1, 00 20, 00 20, 00 1 000 1. 000' 1.0021 12:42 1.562 60.00 1.637 •22 13:04 1.606 80, 00 0. 29223 14:23 1.769 60,00 „. 0..62324 14:36 1 600 60. 00 3, 77625 13:12 100 1.669 0.99 0.54 60.00 0.015 2,1BB 0,0126 15:39 1 925 BO, 00 6, 67327 13:55 1956 60.00 11532B 13:55 1956 60.08 1,48889 13:52 1950 60.00 1,67430 16:59 101 2,087 1.00 0,60 60,08 0. 005 0.604 0.0131 IS: 30 2,275 60, 00 0.93132 18: SB 2. 331 120, 08 0,15933 21:06 1.000 20.08 1.00034 20:29 S. 519 180.08 0, 30535 20:47 2.536 80.00 1,06736 20:50 1.00 2. 562 0. 99 0. 57 60. 00 0. 013 1 794 0.0137 22:07 1.00 2.719 0, 99 0.56 60, 00 0, 033 4,764 0.0136 23:14 2.656 60, 00 4,40039 25:07 3.067 ' 60, 00 ,2.943

K.AO 28:40 ;3.525 ,60.00 4.570 •?"ll 29:47 . 3.663 . 60.00 3.30942 10:47 i. 00 1, 325 0, 99 16.19 . 20. 00' 8, 713 , 3. 351 0, 6143 81:55 100 8.694 0.99 IB, 95 20.00 5. 253 5. S44 0,9544 27; 21 100 3. 368 0.99 17. B4 80.00 3. 362 3, 769 0, B9

012954

012958

U.S. ENVIRMENTM. PROTECTION AGENCY-OP Snplt MgnagMMt OUIct. Box BIB, Altxiddrla, VA 22315 - 70J/557-24M

__, ORGANICS ANALYSIS DATA SHEETftLtbOTItory NlMt H»«il CaiBuCrmn____________ CM* NuntUT! _Lib SMpli ID No.) AjioA.0 80 Rtport No.iSMpltHHTlxi Llauld ContTKt No.l (oft-6l-6Dlti R»U«» Autlxrliid Byt _____________ Dit» SMpU RtcilvidiAssociated samples; I^ICJCi________________________ SCMIVOLATILE COWOUNDS

CONCENTRATIONl (LOS>CDIUM HI8H (elect* Oflt)DATE EXTRACTED/niCPAl

DATE ANALYZED!POCCNT MOISTURE!

Multiply Otltetlofl Ililtt by I Qer loQcr£| "^(ChKk Box for Apfroprlit* Ftetor)

J__ CAM or yg/Kg fit S£L(elrelt OM)

SEMI-VOLATILE LOW LIQUIDOR5AKICS ANALYSIS DATA SHEET • Pige 3

Hb Nitnc; Mud CompuChercLib Simpli 1.0. No.j__t_fcc___> __SS QOS

A. SURROGATE SPUE RESULTS

COMPOUND

2-Fluorophtnol

2,4,6-TrlDromoph«nol

0-Phinol ——— .

DS-MltrobMMDt.

Di4 P-T«rptieny1 '

2-Fluo«oW?h»n.. ..... ————————— ,

'• _... _ ..„...«„.'.•.„. —— :.:..

"=;. — _...,.._ — .. .

FRACTION

SEMIVOA

SEKIVOA

SEH1VOA

SEMIVOA

SEMIVOA

SEHIVOA

CONC ( U9/T)

tx)!

lO^r-

3Um| CO

CIG——

....... ..

(SurrogatesSplKI

Added ( uo/1)

103

100

100

103

103

ion

or__)I

Ricovery

Dl

1,04"3<-qi

. 1 oo.

R3

W -3.012953

ft

—

a

—

!

S

-

~

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S

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5

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1

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—

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•

w

-

8

s

g

w

g

M

g

P*

g

S

II

1

*

g

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g

-

g

.

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g

2

w

...

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M

g

JO

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5

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5

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012953

Vj

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i0

1014

N

(P-L j ) - - - - - -

5.*

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i I

mnrubitfc" »•'

MI610 WENOLW*v473 HHILINE ..,,.,..,...........411 IWU-CKLOROETHtDETHER ....601 2-CHLOROPIOOL .............421 1,3*D1CHLOROBEHZENE ........422 1,4.01CHU»OBEHZENE ........474 KNZVL ALCOHOL .............420 1.2.01CHLOMBEHZEHE.,.......620 2-HEWfLPHMOL ,.,,,.,..,.,412 B1S12.CHLOR01SOPROPYLWHER622 4.KTHYLPKEHOL .............

14 " - 442 N-Hl'TROSO>Dl-N.PROPYLAniHE .15 _ .436 HEXACHLOROEMNE ...........16 ~ " WO"" N1TROBENZEHE'•,.:,.,........,.IB 436 ISOPHORONE ...;............^ ME" 2-NmOPHENDL .............20- 603 •2,4-DinETHTLpHCNOL .........21 • 410 BIS(2'CHLORO(tt '625 BEHZ01C ACID ...

602 :2,4.01CHLOROPHENOL——-~-' - «-t«tCHLOROBW

..............

4 0 «,•!-•439 HAPfflHALE ....

'' i75..-4.CHLOROAHUlNE ....434 HEXACHLOROBIHAOIEHE

S 608 NCHLORO.H.MMOL ......

S stSSSiS30 , SM-TMCHLOWPHEHOL.... •i S VJ****** '" '« «| tlcHLOMHAPHTHAlttE ...» -* 479 WBTWWIW •"••"•""•S6 425 DlrOT<riMTHALA« ..........„ 402 MEHAPHWLEtlE ......••••»•?B «8 2,6.0WnROTOL«EHE .....M"

^ - - "'TJI

' .'COMPOUND LIST NO. ____»'.' ———— IDENTIFIER SEMI-VOLATILES .. LOK LEVEL LIQUID

, QUANT.COMPOUND REPORT CORRECTION RESULTS OET LIMIT

^COUNTER NUMBER COMPOUNDS_____ VALUE K FACTOR "(us/I) (U9/D

39 478 2-NITROANILlNE40 401 ACENAPHTHENE41 605 2,4-DINlTROPHENOL42 607 4-N1TROPHENOL43 476 D1BENZOFURAN44 427 2,4-DINlTROTOLUENE45 424 01ETHYLPHTHALATE46 417 4.CHLOROPHENYL PHENYL ETHER.......47 432 FLUORENE .........................48 480 4-NITROANIL1NE49 604 4,6-DINlTRO-O-CRESOLSO 443 DIPHENYLAMINE (H-NITROSO)51 430 1,2-DIPHENYLHYDRAZINE (AZOBENZENE)

" S3 414 4'BROMOPHENYL PHENYL ETHER_ 54 433 HEXACHLOROBENZENE

55 609 _PJHTACHLOROPHENOL56 444 PHENANTHRENE

~ j 57 403 _JWJHRACENESB 426 OMJ-BUTYLPHTHALATE59 431 FLUORANTHENE61 445 PYREHE ...,,

^ 62_ 404 BENZID1NEjT. 415 BUTYLBENZYLPHTHALATETjtl *2'3 3,3'.OICHLOI10BENZIOINE

65 " 405 BENZOIA)ANTHRACENE66 413 BIS(2-ETHYLHEXYL)PHTHALATE67 418 CHRYSENE .................•e 429 DI-N.OCTYLPHTHALATE70~ . 407 lENZOIBlFLUORANTHENE71 409 KNZO(K)FLUORANTHENE72 406 IENZO(A)PYREHE ........73 437- INOENO(1,2,3.C,0)PYRENEJ4__ 419 01BENZO(A,H)ANTHRACENEIi 408' IEHZO(6,H,1)PERYLENE ..(SM uleulitlons ind surrogitts on btek)

012962

COMPUCHEM NO. 60 DATE ______ 3 of 2COMPOUND LIST NO. ___ ———— ——————

jf^ ——— IDENTIFIER SEM1-VOLAT1LE5 - LOW LEVEL LIQUID

QUANT.QUANT. REPORT

COMPOUND SURROGATE REPORT AMOUNT t tt ACCEPTABLENUMBER COMPOUNDS VALUE SPIKED RECOVERY RAHSE

619 2-FIUOROPHENOL t / ! _i__"_] 1' (25-115)612 DS-PHENOL <4 S \ _*_ _ % (is-9'o)'447 OS-NITROBENZENE h M i )jj_ ~ 'M. (42-131)44a,..-2-FLUOROBIPHENYL i I (a ! M_ ~ *1 (50-154)62B.-TRIBROMOPHENOL j^ j ___ ~ IbH (47-123J*471 Ojo-fYRENE '.y j M_ I \\J i MA )*496 OH-TERPHENYL ' *£ iD» ." IQC) (54-ns)*

—— - t Atcovery ...

v f — — • CORRECTION FACTOR CALCULATION!

Pintfr-intrictlon vo1iirit(i"Vl 1000 nil Dilution-JSL'Tpj MIC, .MII Tor BK > ioi. iinipit ixiricito \m) * Fitter * 2——— ' (mil 1000 nil

LOT * " iii | " ______ x z •

QUANT REPORT AMOUNT SPIKED CONVERSION FACTOR;

"""100 u1 '•'• Flnil Extnet Vol. W) Dilution(wowrt-surrogtM waifl (ui) * wrTorueunBi TOP IIT * Fietor •

(111) * J-" 111

JRT 11/83

012963

2oft

... .w S • 9 w

oop_

*

is?

w

SI-

'S,. PIL\ ~§'

88-3!

Si \

"VA

lO

i=K

8

01 965

PROCEDURE: RK DIAGNOSTIC REPORT 2/09/8423:16:DATA FILE: CM020040B14REFERENCE! F3CC7

METHOD: FSCC7 INITIALIZATION OPTION: 2 PROCESSING OPTION: 3ft REPORT: FSCC7S1

< ——— STANDARDS ——— X —— PLUS UNKNOWNS —— X - LIST NAMES - ?PROC USED POSS RriS PROC USED POSS RMS STANDARD/UNKNOWN

6 6 I 43 94 6 1 49 FSCC7S1/FSCC7U16 6 1 49 34 13 1 77 FSCC7S2/FSCC7U2

< COMPOUND X ———————— SEARCH ———————— X SAT X ———— CHRO —————NO LID ENTRY REF PRED SEL DELTA PEAKS FIT PEAKS' 11/E TOP DELTA REAP1 Cl2 C23 C34 C49 C96 C6

-789 789 789-1094 1094 1094-1446 1446 1449 -1-1773 1773 1773-2376 2376 2376

983 , 150 789980 . 136 1094982 , 164 1449965 , 188 1773828 . 240 2379 -1

-2661 2661 2661 , 1 888 , 264 26617 C l 2 -292 2 9 2 . . . . . 7 4 . .8 C l 3 -793 7 5 3 . . . . . 9 4 . ,9 Cl 4 -75B 798 . ... , .9310 Cl 9 -758 758 . , , , . 93 .1 1 C l 6 -797 7 5 7 . . . . . '12812 Cl 7 -780: 7QO , . . , 14613 Cl B -792. 792 , . . . 14614 Cl 9 -834 B34 . , , , 10819 Cl 10 -82B 828 , , , , 1 4 616 Cl 11 -869- 869 , , , 108 .17 Cl 12 -B67: B67 . ! • , , , 1 2 1

• 18 Cl 13 -899 B99 , , , , .., 10B , . ' '19 Cl 14 -896 896 . . , . . 1 3 020 Cl 19 -BB.9 809 , . , 11721 Cl 16 -9)4 914 , . , , 12322 C2 2 -968 968 , . . , . S323 C2 3 -982 982 . , , 1392 4 C 2 4 -1008 1008 . . . . . 1 2 ? . .29 C2 9 -1028 1028 9326 C2 6 -1067 1067 10527 C2 7 -1039 103S 1622 8 C 2 8 -1049 1049 . . . . . 1 8 0 . .29 C2 9 -109B 1098 . . . , 1283 0 C 2 1 0 -1091 1091 . . . . . 1 2 7 . .3 1 C 2 1 1 -1109 1109 . . . . . 2 2 5 . .32 C2 12 -1209 1209 , . , . . 1073 3 C 2 1 3 -1211 1211 . . . . . 1 1 9 . .3 4 C 2 1 4 -1269 1269 . . . . . 2 3 7 . ,39 C2 19 -1288 1288 19636 C2 16 -1299 1295 1963 7 C 3 2 -1.31B 1318 . . . . . 1 6 2 , .3 8 C 3 3 -1360 1360 . . . . . 1 3 8 . .39 C3 4 -1417 1417 , , , . . 1634 0 C 3 9 -1409 1409 . . . . . 1 9 2 . .4 1 C 3 6 -1428 1428 , . . . . 1 6 9 . .42 C3 7 -1453 1453 . . , , , 13B , .43 C3 B -1'453 1453 . , , . 1544 4 C 3 9 -1476 1476 . . . . . 1 8 4 . .45 C3 10 -150B 1908 , . . , 10946 C3 11 -1489 1489 , . . . . . . 1 6 8 fltOQfm47 C3 12 -151E 1512 . , _. . . «.-... 169 Ul«3«u48 C3 13 -1580 1380 . , * *» . V91£f-*<»9 1977. •'' '-—• . i

90 C3 15 -1566 1566 , • , , , , 1 0 051 C3 16 -1626 1626 , . , . . 1 3 8 .52 C3 17 -1601 • 1601 . , , . 19893 C3 18 -1607 1607 , . . , 16954 C3 19 -1612 1612 7755 C4 2 -1685 1689 . . . . 24856 C4 3 -1707 1707 , . , , , 2B4 .57 C4 4 -1753 1753 . , . . 26698 C4 9 -1779 1779 . . , , . 178 .99 C4 6 -1788 1788 . . . . 17860 C4 7 -1990 1990 149 199061 C4 8 -204B 2048 . , . , 20262 C9 2 -2096 2096 , . . . , 202 ...63 C9 3 . , , , . . 184 • ..64 C9 4 -2285 2285 , . . . 14969 C9 9 . , , , . . 29266 C9 6 -2372 2372 , . . , ,'" 22867 C9 7 -2431 2431 . . . . 14968 C9 8 -2381 2381 , . . , 2286 9 C 9 9 -2964 2964 . . . . . 1 4 9 296970 C6 2 -2604 2604 . . . . 29271 C6 3 -2609 2609 . , , , 29272 C6 4 -2666 2666 , . , , 29273 C6 9 -2910 2910 . . . , 27674 C6 6 -2920 2920 , , . . 27879 C6 7 -297B 2978 , . . . 27676 C7 2 -964 969 966 177 C7 3 -792 792 79278 C7 4 -910 910 911 179 C7 • 9 -1307 1307 130780 C7 6 -1626 1626 168681 C7 7 -2092 2092 2093 182 C7 .8 -2192 2192 2193 . J 982 , 244 2193

,96?

QUANT I TAT I ON REPORT FILE: OH020040B14

DATA: OH020040B14. TI02/09/84 21:93:00

^SAMPLE; 1UL 20040<2/3/B4)QN»14SUBHITTED BY: 14 ANALYST: 755

AMOUNT-AREA * REF, AUNT/ (REF. AREA)* RESP. FACT)RESP. FAC. FROM LIBRARY ENTRY

NO NAME1 *D4-1.4-DICHl.OROBENZENE (IS)2 441 N-NITROSODIMETHYAMINE3 610 PHENOL4 473 ANILINE9 411 B IS (2-CHLQROETHYL) ETHER6 '601 2-CHLOROPHENQL7 421 i. 3-DICHLOROBENZENEB 422 1,4-DICHLQRQBENZENE9 474 BENZYL ALCOHOL10 420 1,2-DICHLOROBENZENE11 620 2-METHYLPHENOL12 412 BIS(2-CHLOROISOPROPYL)ETHER13 622 4-I1ETHYLPHENOL14 442 N-NITRQSD-DI-N-PROPYLAMINE19 436 HEXACHLOROETHANE16 440 NITROBENZENE17 #460 D'B-NAPHTHALENE us>IB 438 ISOPHORONE19 606 2-NITROPHENOL

-,. 20 603 2. 4-DIMETHYLPHENOLfcrl 21 410 DIS(2-CHLQROETHOXY)METHANE.'

22 629 BENZOIC ACID23 602 2, 4-DICHLOROPHENOL24 446 1,2, 4-TRICHLOROBENZENE29 439 NAPHTHALENE26 479 4-CHLOROANILINE27 434 HEXACHLQRQBUTADIENE2B 60S P-CHLORD-M-CRESQL29 477 2-METHYLNAPHTHALENE30 439 HEXACHLQRQCYCLOPENTADIENE31 611 2i4, 6-TRICHLQRQPHENOL32 626 2,4, 5-TRICHLOROPHENOL33 *D10-ACENAPHTHENE (IS)34 416 2-CHLORONAPHTHALENE39 479 3-NITROANILINE36 425 DIMETHYLPHTHALATE37 402 ACENAPHTHYLENE38 428 2. 6-D1NITROTOLUENE39 478 2-NITROANILINE40 401 ACENAPHTHENE41 605 2. 4-DINITRQPHENOL42 607 4-NITROPHENOL43 476 DIBENZOFURAN44 427 2, 4-DINITROTOLUENE45 424 DIETHYLPHTHALATE46 417 4-CHLQRQPHENYL PHENYL ETHER

012963

001213

NO NAME47 432 FLUORENE48 480 4-NITROANILINE49 604 4!6-DINITRO-O-CRESOL50 443 DIPHENYLAMINE (N-NITRQSO)51 430 1,2-DIPHENYLHYDRAZINE (AZOBENZENE)52 #467 D10-PHENANTHRENE (IS)53 414 4-BRQMOPHENYL PHENYL ETHER54 433 HEXACHLQROBENZENE55 609 PENTACHLOROPHENOL96 444 PHENANTHRENE ' '97 403 ANTHRACENE58 426 DI-N-BUTYLPHTHALATE ... .99 431 FLUORANTHENE60 *459 D12-CHRYSENE (IS)61 449 PYRENE62 404 BENZIDENE63 415 BUTYLBENZYLPHTHALATE64 423 3i3'-DICHLOROBENZIDINE69 409 BENZO(A)ANTHRACENE66 413 BIS(2-ETHYLHEXYL)PHTHALATE67 418 CHRYSENE68 429 DI-N-OCTYLPHTHALATE69 #D12~BENZO(A)PYRENE (IS)70 407 BENZO(B)FLUORANTHENE71 409 BENZO(K)FLUDRANTHENE72 406 BENZO(A)PYRENE73 437 INDENO(1.2.3-C,D)PYRENE74 419 DIBENZO(A<H)ANTHRACENE79 408 BENZO(0,H, DPERYLENE76 619' 2-FLUQROPHENOL (SURROGATE)77 D9-PHENOL (SURROGATE) •78 447 D9-NITROBENZENE (SURROGATE)79 448 2-FLUOROBIPHENYL (SURROGATE)80 TRIBROMOPHENOL (SURROGATE)81 D10-PYRENE (SURROGATE)B2 D14-TERPHENYL (SURROGATE)

NO rl/E SCAN TIME REF RRT METH AREA(HGHT) AMOUNT 7.TOT1 190 789 9:92 1 1.000 ABB 43129. 40.000 NO 3.972 NOT FOUND3 NOT FOUND4 NOT FOUND9 NOT FOUND6 NOT FOUND7 NOT FOUNDB NOT FOUND9 NOT FOUND10 NOT FOUND11 NOT FOUND12 NOT FOUND13 NOT FOUND14 NOT FOUND19 NOT FOUND16 NOT FOUND17 136 1054 13: 10 17 1,000 A BB 9587B, 40,000 NO 3.97IB NOT FOUND '

012969

NO M/E SCAN TIME REF RRT METH AREA(HGHT) AMOUNT '/.TOT19 NOT FOUND20 NOT FOUND21 NOT FOUND22 NOT FOUND23 NOT FOUND24 NOT FOUND25 NOT FOUND26 NOT FOUND27 NOT FOUND28 NOT FOUND • .29 NOT FOUND30 NOT FOUND31 NOT FOUND "' '32 NOT FOUND33 164 1445 18:04 33 1.000 ABB 90969, 40. 000 NO 3.9734 NOT FOUND39 NOT FOUND36 NOT FOUND37 NOT FOUND38 NOT FOUND39 NOT FOUND40 NOT FOUND41 NOT FOUND42 NOT FOUND43 NOT FOUND44 NOT FOUND49 149 1977 19:43 33 1.091 ABB 1401. 0. 796 NO 0.0846 NOT FOUND47 'NOT FOUND48 NOT FOUND49 ' NOT FOUND90 NO! FOUND91 NOT FOUND92 1BB 1773 22:10 92 1,000 A BV 84393, 40. 000 NO 3.9793 NOT FOUND94 NOT FOUND99 NOT FOUND56- NOT FOUND57 NOT FOUND • -SB 149 1950*24:22 92 1.100 ABB 769, 0. 261 NO 0,0399 NOT FOUND60 240 2379 29:41 60 1.000 A BV 32400, 40, 000 NO 3,9761 NOT FOUND62 NOT FOUND63 NOT FOUND64 NOT FOUND69 NOT FOUND66 NOT FOUND67 NOT FOUND6B 149 2969 32:04 60 1,080 ABB 1007, 0. 979 NO 0,0669 264 2661 33:16 69 1.000 ABB 13196, 40. 000 NO 3,9770 NOT FOUND71 NOT FOUND72 NOT FOUND73 NOT FOUND74 NOT FOUND :

75 NOT FOUND76 112 966 7:04 1 0.717 A BV 61436. BB. 918 NO 8,8377 99 792 9:24 17 0.713 A BV 41903, 44.458 NS 4. 4278 82 911 11:23 17 0.864 ABB 97600. 113.611 NO 11,2979 172 1307 16:20 17 1.240 ABB 194829. 115.603 NO 11.4980 330 1686 20:17 33 1.125 ABB 23899. 130, 275 NO 12.9481 212 2093 26: 10 60 0.881 A BV 217755. 147. 722 NO 14,6882 244 2153 26:98 52 1,214 A BV 153779, 124.917 NO 12,41

NO RET(L) RATIO RRT(L) RATIO AMNT AMNT(L) R. FAC R. FAC(L) RATIO1 9:52 1.00 1.000 1.00 40,00 40,00 1.000 1.000 1.002 3:39 0. 370 50.00 0. 3803 9; 25 0.994 90,00 "' ' 0.9894 9; 28 0.961 90.00 ."1.0099 9:28 0.961 90,00 0,9926 9:28 0.999 90.00 0.7267 9:49 0.989 90.00 0.8488 9:949 10:2510 10:2111 10:5212 10:5013 11:1414 11:1215 11:0716 11:2917 13:10 1.00

004 90.00 0.920057 90.00 .0.439049 90.00 0.801101 90,00 0, 974099 90.00 0.200139 90,00 0,678136 90.00 0.119127 90.00 0.287158 90.00 0.380000 1.00 40,00 40.00 II000 1.000 1.00

IB 12:06 0.918 90,00 0,98919 12:16 0.932 90,00 0.196

i 20 12:36 • 0,996 50.00 0/303. 21 12:91 • 0.979 50.00 0.431

22 13:20 1.012 ' 250,00 0.13323 12:56 . ..0.983 90.00 0.29224 13:07 ' 0.999 90,00 0.39229 13:1326 13:3827 13:4928 19:0429 19:08 . .30 19:4931 16:0632 16:1133 18:04 1,00

004 90,00 1.105035 249.99 0. 149048 90.00 0. 189143 90,00 0.335149 90.00 0.243200 90,00 0,079223 90.00 0.291 .229 249,99 0, 1BO000 1,00 40,00 40.00 1.000 1.000 1.00

34 16:28 0.911 50.00 1.20939 17:00 0,941 249.99 0.38436 17:43 0.980 90.00 1.35437 17:37 0.974 90.00 0.81938 17:91 0.98B 90,00 0.29839 18:10 .005 249.99 0.031.40 18:10 „ ;. .009 90.00 1. 11441 16:27 ' * .021 249.99 0.09642 18:91 ,043 129,00 0. 10943 18:37 ,030 90,00 1.67844 18:94 .046 90,00 0.34949 19:49 1,00 1.093 1.00 0. BO 90,00 0,022 1.381 0,0246 19:43 : 1,091 50.00 0.518

*012971

88 WWW

47 19:34 .083 90.00 1.38748 20: 19 . 124 249. 79 0.00349 20:01 .107 249,99 0,10850 20:05 .111 90.00 0.27391 20:09 .115 50.00 1.29152 22:10 1.00 1.000 1.00 40,00 40,00 1,000 1,000 1.00S3 21:04 0,990 50.00 0. 1BO54 21:20 0,963 90.00 0.23795 21:55 0.989 ' 90,00 0..09656 22:14 1.003 90.00 1.131,57 22:21 1,008 90.00 0,989SB 24:22 1.00 1.100 1.00 0,26 50.00 0,007 1.396 0,0159 25:36 1,155 50.00 '" '0.95960 29:42 1,00 1.000 1.00 40,00 40,00 1.000 .-1.000 1,0061 26: 12 0.882 90.00 2,02962 26:99 0.90S 90.00 0.01063 28:34 0,962 90.00 0.97464 30:43 1,007 90,00 0.01B69 29:39 0.998 90.0066 30:23 1.023 90,0067 29:46 1.002 90.0068 32:03 1,00 1,079 1,00 0,97' 90.00 0.02969 33:16 1,00 1,000 1,00 40,00 40.00 1,000

879472037163 0.01000 1.00

70 32:33 0.979 90.00 .49971 32:37 0.980 50.00 .33772 33:19 1.002 50,00 ,03973 36:22 1.094 90.00 0.38374 36:30 1.097 90.00 0.34879 37:13 1.119 90.00 '0.34876 7:0377 9:2478 11:2279 16:2080 80:19Bl 26:09

00 0,715 1,00 88.92 • 50.00 1,140 0,641 '1.7800 0,713 1,00 44/46 SO.'00 0,346 0,389 0.8900 0,863 1.00 113,61 50,00 0,614' 0,398 2.27.00 1,240 1.00 119.60 90.00 1.626 0.703 2.3100 1,124 1.00 130.28 90.00 0.379 0,144 2,6100 0,880 1,00 147,72 90.00 9,377 1,820 2,96

82 26:94 1,00 1,214 1,00 124.92 90.00 1.498 0, 9B3 2.50

012972

U.S. ENVIROMCNTM. PROTECTION ASENCr-ClP SmpU Htnigmnt OfficeI P.O. Box BIB, AfmimfU, VA 22313 - 703/997-2490

_v, ORWHICS ANALYSIS DATA SHEETrnLibcrttory NIMI mid CaicuCtmn ________ ___ Cut Nu-bri ,Lib lHpl* ID Ito.l Q-UCi3q _______ , QC Riport No.i |M| 344SMpI* Mrtrlm LlaulD ___________ ___ Contriet No.t laft"M "Diti ItelMU Auttwrlnd Byt .____________ 0«t» Swpl* Rtetlvid:Associated simples: _____ .________________________ SEHIVOUTII.E CCWOWCS

CONCENTRATION: L<%jbllM HIGH (Clreli DM)OATE EXTRACTEO/WPAflOl .

BATE AHAI.YZEO:FOWNT MOISTURE!

Multiply Otttetlon ll«lt» by I Qor loQorJ_j £-(Clwck Box for Approprlit* Ftcter)

__£, orj?X« SL CA5I(elreli DM) (clrcl* OM)

""""'""

SEMI-VOLATILE LOW LIQUIDORGANICS ANALYSIS DATA SHEET - Pige 3

Lib Nine1. Hud CompuChercLib Simpll l.D. Ho.j_j£03 __ QSS QOS gf Blink


COMPOUND

2-Fluorophenol

2,4,6-TrlDrpjiophenol

0-Phinol ——— •

• DS-NUrobtntene

Dj4 P-Terptienyl

- — 2-ffuof oblphtnyl

... ———— .

- - ————— -

— .— .;

FRACTION

SEMIVOA

SEMIVOA

SEMIVOA

SEMIVOA

SEMIVOA

SEMIVOA

CONC ( ug/1)

W

O<&

<£ID

Qx0(U

°14-

*"™~ """

isufroaitei.put

Added ( uo/1)

103

100

100

103

100

ion

• -

omjj~~lRtcovery

4*b

^

.3JD

ft

.

^

......._

•*.•'

012974

V 2101297'.

I

ii

S EH

Bl*I

I

j'ust *

2.CH-OROPHENOL1,3-WWI.OROBENIENt

HEXACHLOROEWNE«TROBEME1SOPHORONE

WPHTHAIEHE4.CHLOROANIIMHEXACHLOROBUTAD1ENE ....»••- .u.M>n.M.C(lSOL ..."••"•

VVw

.'COMPOUND LIST NO. ___.' ———— IDENTIFIER SEM1-VOLAT11E5 •• LOK' LEVEL LIQUID

QUANT.i COMPOUND REPORT CORRECTION RESULTS OET LIMIT^JOUNTER mm COMPOUNDS VALUE x FACTOR •(ug/D (.9/11

39 47B 2-NITROANUM40 401 ACENAPHTHENi41 605 2.4-D1NITROPHENOL42 607 4.HITROPHENOL43 476 DIBENZOFURAN44 427 2.4'DIHITROTOLUENE45 424 D1ETHYLPHTHALATE

„.. 46 417 4-CHLMOPHENYL WENYL ETHER.......47 432 FLUORENE .........................48 480 4-NITROANILINE49 60« 4.6-DIN1TRO-0-CRESOL50 443 DIPHENfLAWNE (N-NITROSO).SI 430 1,2-DIPHENY.HYDRAZINE (AZOBENZENE)53 414 4-BROMOPHENYL PHENYL ETHER

... .54 433 HEXACHLOROBENZENE... 55 609 _WHTACHLOROPHENOL

._.,S6 44« PHENANTHRENEk,'::$ 57 40? —ANTHRACENE

58 426 DI-N-BUTYLPHTHALATE...59,.. 431 FLUORANTHENE

61.. 445 PYRENE ....._62_ 404 BENZIDINE_63_ 415 BUTYLBENZYLPHTHALATEJ6i_. 423 3,3'-DICHLOROBENZIDINE65 405 BENZO(A)ANTHRACENE66.... 413 B1SI2-ETHYLHEXYUPHTHALATE67 - 418 CHRVSENE .................68 429* DI-N-OCTYLPHTHALATE70. 407' BENZO(B)FLUORANTH£NE71 409 BENZO(K)FLUORANTHENE72. . 406 IENZO(A)PYRENE ........73 43T INDENO(l,2.3-C.D)PYRiNEJ4__ 419 01BENZO(A,H)AMTHRACENE75 408" BEWO(6,H,I)PERYLENE

(Ste eileulitlons in. wrrogitts on pick)

.fr 89

COMPUCHEM NO. 1 DATE ____ 3 Of 2LIST NO. __ '——*~ —————— IDENTIFIER 5EM1-VOLAT1LES - LOK LEVEL LIQUIDQUANT.

QUANT. REPORTCOMPOUND SURROGATE REPORT AMOUNT t" ACCEPTABLEDUMBER COMPOUNDS VALUE SPIKED RECOVERY HAN6E

619 2-FIUOROPHENOL 2* BO«T"'T1 t% (25-115)'612 OS-PHENOL >q BO*. __ _?g (is-90)447 OS-HITKOBENZENE m BO*. gg- (42-131)<4TT-FLUOROB1PHENYL «- BOj_~ ?«/ (50-154)62B'™TR1BROMOPHENOL fj 60* *?8 (47-123)*47i DIQ-PYRENE ff¥ 504 _ /ta ( HA )*496 " DH-TERPHENYI to so» , __ 9S '(

—— .. *For~A.risory P«rpo«$ Only" « »*ea»try . Quint iwprt Ylllie . .„.

_ .. .. - — , — * UUllll HIPUI I MIIUUIIL JplHBU " *UU«

*'^ " ' "" I ' • CORRECTION FACTOR CALCULATION;

F1ni1 mtnetlon vo1imt(p1 1 1000 ml Dilution•"••• " urn ior «ie,,jmi for BH * 101, wnpic .xiricica im) * Fictor * 2 •

:'(T»D , loop Hi /1.1UI. X ^(S'C' (Ml) " ' K 2 • •c-

QUANT REPORT AMOUNT SPIKED CONVERSION FACTOR;

100 u1 "_____ FlMlI trtfietVol. Ml DilutionMount SMrrogiM mata tup » »i ior MIO, ui ror m * Fietor

.... 100 uf;_____ ; Ml——nnr* 1.0 m i

JRT 11/83

Jl

»8-gj®3

s

r-J>-

1

1

O

JW

^

, "iNm? ,_ „

-S ^

20

BS.w (Ss

JO1

m" S

3S ___("M N)•8

g

COS

^li-l " a

PROCEDURE: RK DIAGNOSTIC REPORT 2/10/B4 0;2<?:2DATA FILE: QM020039B14REFERENCE: FBCC7

METHOD; FSCC7 INITIALIZATION OPTION: S PROCESSING OPTION: 3REPORT: FSCC7S1

< —— STANDARDS ——— X —— PLUS UNKNOWNS —— X - LIST NAMES - >PROC USED POSS RMS PROC USED POSS RMS STANDARD/UNKNOWN

6 6 1 60 94 6 1 60 FSCC7S1/FSCC7U16 6 1 60 34 13 1 147 FSCC7S2/FSCC7U2

COMPOUND X ————————— SEARCH ————————— >< SAT..X .———— CHRO •—D LIB ENTRY REF PRED SEL DELTA PEAKS FIT PEAKS M/£ TOP DELTA

B Cl 3 '-793 744 . . . . . 94 ' .9 Cl 4 '-793 749 , , , . . 931 0 C l 9 -79S 7 4 9 . . . . . 9 3 .11 Cl 6 -797 748 , , . . 12812 Cl 7 -780 771 . . . . 14613 Cl 8 -792: 783 . , , . 14614 Cl 9 -834 829 , . . , 1081 9 C l 1 0 -828 8 1 9 . . . . . 1 4 616 Cl 11 -869 860 , • , , , . 1 0 817 Cl 12 -867" 898 , , . . . 1 2 118 Cl • 13 -B99 890 . , . , 10819 Cl 14 -896 887 . , , , 13020 Cl 19 -889- 880 . . . . 11721 Cl 16 -9E4 909 , , , . 1232 2 C 2 2 -96"B 9 9 9 . . . . ..._8223 C2 3 -982 973 . , . , 13924 C2 4 -100~8 999 . . . . 1222 5 C 2 9 -1028 1019 . . . . . 9 3 .2 6 C 2 6 -1067 1098 . . . . . 1 0 9 .27 C2 7 -103*9 1026 16228 C2 8 -1049 1040 . , . . 18029 C2 9 -109B 1049 1283 0 C 2 1 0 -10W 1082 . . . . . 1 2 7 .3 1 C 2 1 1 -1109 1096 . . . . . 2 2 9 .3 2 C 2 1 2 -1209 1196 . . . . . 1 0 7 ,3 3 C 2 1 3 -12U 1202 . . . . . 1 1 9 .34 C2 14 -1269 1296 , . Y , 23739 C2 19 -12BB 1279 19636 C2 16 -1299 1286 . . . . . 196 .37 C3 2 -1318 1309 , , . . . 1 6 238 C3 3 -1360 1391 13839 C3 4 -1417 1408 . , , . . 1 6 340 C3 9 -1W9 1400 19241 C3 6 -1428 1419 16942 C3 7 -1*93 1444 13843 C3 8 -1493 1444 , ' . . , . 1 9 4 fUO44 C3 9 -1476 1467 184 VlG49 C3 10 -1S08 1499 , . . ...... 10946 C3 11 -1489 1480 . . , /»A--, . , 1 6 847 C3 12-1912 1903 . ,L «o. VV4##!J. 16940 C3 13 -19BO 1971 , . . . , 1 4 9 1968

90 C3 18 -1966 1997 . . . . 16691 C3 16 -1626 1617 . . . . 13892 C3 17 -1601 1992 ' . . . 19893 C3 IB -1607 1998 . . . , 1699 4 C 3 1 9 -1612 1603 . . . . . 7 7 ,99 C4 2 -1689 1676 . . , . 24896 C4 3 -1707 1698 . . . . 28497 C4 4 -1793 1744 , . . , 2669B C4 9 -1779 1770 . . . . 17899 C4 6 -1788 1779 . . . . 17860 C4 7 -1990 1941 149 194061 C4 8 -2048 203? . . . . 20262 C9 2 '-2096 20B7 . . . . - , 202 •' .63 C9 3 , . . . . . 184 ' '.64 C9 4 -2289 2276 , . . , 14969 C9 5 , , . . . . ,- 29266 C9 6 -2372 2363 , . . . , 228 ,67 C9 .7 -2431 2422 . . . . 14968 C9 8 -2381 2372 . . . . 22869 C9 9 -2964 2999 . . . . , 1 4 9 29967 0 C 6 2 -2604 2994 . . . . . 2 9 271 C6 3 -2609 2999 29272 C6 4 -2666 2696 29273 C6 9 -2910 2900 27674 C6 6 -2920 2910 2787 9 C 6 7 -2978 2968 . . . . . 2 7 676 C7 2 -964 996 999 377 C7 3 -792 744 749 178 C7 4 -910 902 901 -179 C7 9 -1307 129B 1296 -280 C7 6 -1626 1617 1616 -181 C7 7 -2092 2083 208382 C7 B -2192 21'43 2143 ,

986 , 112 999BBO . 99 749988 . 82 901989 . 172 1296996 . 330 1616931 . 212 2083.983 , 244 2143

.„ *•

QUANTITATION REPORT FILE: OH020039B14

DATA: GH020039B14, TI02/09/84 23:31:00

ft SAMPLE: 1UL 20039(2/3/84)ON(tl4SUBMITTED BY: 14 ANALYST: 759

AMOUNT-AREA • REF, AMNT/(REF, AREA)* RESP.FACT)RESP, FAC. FROM LIBRARY ENTRY

NO NAME1 *D4-1.4-DICHLOROBENZENE (IS)2 441 N-NITROSODIMETHYAMINE3 610 PHENOL - •4 473 ANILINE9 411 B IS O-CHLORQETHYL) ETHER6 601 2-CHLOROPHENOL7 421 1,3-DICHLOROBENZENE6 422 1.4-DICHLOROBENZENE9 474 BENZYL ALCOHOL10 420 l.S-DICHLORQBENZENE11 620 2-METHYLPHENQL12 412 8ISC!-CHLOROISQPROPYL>ETHER13 622 4-METHYLPHENOL14 442 N-N1TROSO-DI-N-PROPYLAMINE15 436 HEXACHLORQETHANE16 440 NITROBENZENE1'.' #460 DB-NAPHTHALENE (IS)16 438 ISOPHORONE19 606 2-NITROPHENUL

_v_ SO .603 2. 4-DIMETHYLPHENULff? SS 410 B1S(2-CHLOROETHOXY)METHANE '

22 625 BENZOIC ACID .£3 602 2.4-DICHLORQPHENOL24 446 1.2,4-TRICHLORQBENZENE25 439 NAPHTHALENESfe 475 4-CHLORQANILINE£7 434 HEXACHLOROBUTADIENE2B 60S P-CHLORQ-M-CRE3QL29 477 2-METHYLNAPHTHALENE30 435 HEXACHLORQCYCLQPENTADIENE31 611 2/4>6-TRICHLOROPHENOL32 626 Z, 4,9-TRICHLOROPHENOL33 *D10-ACENAPHTHENE (IS)34 416 2-CHLQRONAPHTHALENE39 479 3-NITROANILINE36 429 DIMETHYLPHTHALATE37 402 ACENAPHTHYLENE38 428 2. 6-DINITROTOLUENE39 478 2-NITROANILINE40 401 ACENAPHTHENE41 609 2.4-DIN1TROPHENQL42 607 4-NITROPHENDL43 476 OIBENZOFURAN44 427 2,4-DINlTRQTOLUENE:49 424 DIETHYLPHTHALATE46 417 4-CHLORQPHENYL PHENYL ETHER

VJ184m

NO NAME47 432 FLUQRENE48 480 4-NITROANILINE49 604 4.6-DINITRO-O-CRESOL90 443 DIPHENYLAMINE (N-NITROSO)51 430 li2-DIPHENYLHYDRAZINE (AZOBENZENE)92 #467 D10-PHENANTHRENE (IS)93 414 4-BROMOPHENYL PHENYL ETHER94 433 HEXACHLOROBENZENE99 609 PENTA'CHLOROPHENOL96 444 PHENANTHRENE97 403 ANTHRACENE98 426 DI-N-BUTYLPHTHALATE89 431 FLUORANTHENE60 *499 D12-CHRYSENE (IS)61 449 PYRENE62 404 BENZIDENE63 419 BUTYLBENZYLPHTHALATE64 423 3.3'-DICHLOROBENZIDINE69 409 BENZO(A)ANTHRACENE66 413 BIS(2-ETHYLHEXYL)PHTHALATE67 4)8 CHRYSENE68 429 DI-N-OCTYLPHTHALATE69 »D12-BENZO(A)PYRENE (IS)70 407 BENZO(B)FLUQRANTHENE71 409 BENZO(K)FLUORANTHENE72 406 BENZO(A)PYRENE73 437 INDENO(1.2,3-C.D>PYRENE74 419 DIBENZO(A. H)ANTHRACENE79 408 BENZOtG, H. DPERYLENE76 619 2-FLUOROPHENOL (SURROGATE)77. D5-PHENOL (SURROGATE)78 447 D9-NITROBENZENE (SURROGATE)79 448 2-FLUOROBIPHENYL (SURROGATE)BO TRIBROMOPHENOL (SURROGATE)SI D10-PYRENE (SURROGATE)82 D14-TERPHENYL (SURROGATE)

NO M/E SCAN TIME REF RRT METH AREA(HGHT) AMOUNT '/.TOT1 190 780 9:45 1 1.000 ABB 46331, 40. 000 NO 7,782 NOT FOUND3 NOT FOUND4 NOT FOUND8 NOT FOUND6 NOT FOUND7 NOT FOUND8 NOT FOUND9 NOT FOUND10 NOT FOUND11 NOT FOUND12 NOT FOUND13 NOT FOUND14 NOT FOUND18 NOT FOUND16 NOT FOUND17 136 1044 13:03 17 1,000 A BV 102278, 40,000 NO 7,78IB NOT FOUND

29 01298529 3012,73

NO M/E SCAN TIME REF RRT METH AREA(HGHT) AMOUNT '/.TOT19 NOT FOUND

db 20 NOT FOUNDrl 21 NOT FOUND

22 NOT FOUND23 NOT FOUND24 NOT FOUND25 NOT FOUND26 NOT FOUND27 NOT FOUND28 NOT FOUND29 NOT FOUND30 NOT FOUND31 NOT FOUND32 NOT FOUND33 164 1436 17:97 33 1.000 ABB 93989. 40.000 NO 7,7834 NOT FOUND39 NOT FOUND36 NOT FOUND37 NOT FOUND38 NOT FOUND39 NOT FOUND40 NOT FOUND41 NOT FOUND42 NOT FOUND43 NOT FOUND44 NOT FOUND49 149 1968 19:36 33 1,092 ABB 881. 0. 473 NG 0,0946 NOT FOUND

tai) 47 NOT FOUND'. 48 NOT FOUND

49 NOT FOUND90 NOT FOUND91 NOT FOUND92 188 1764 22:03 92 1.000 ABB 93226, 40,000 NG 7. 7893 NOT FOUND94 NOT FOUND99 NOT FOUND96 NOT FOUND57 NOT FOUND58 149 1940 24:15 52 1,100 ABB 914, 0,281 NG 0.0599 NOT FOUND60 240 2366 29:34 60 1,000 ABB 33445, 40, 000 NG 7,7861 NOT FOUND62 NOT FOUND63 NOT FOUND64 NOT FOUND69 NOT FOUND66 NOT FOUND67 NOT FOUND68 149 2996 31:57 60 1.080 ABB 1429, 0,790 NG 0.1569 264 2692 33:09 69 1.000 ABB 13227, 40.000 NG 7.7870 NOT FOUND71 NOT FOUND72 NOT FOUND

, 73 NOT FOUND "V 74 NOT FOUND

I

01298

79 NOT FOUND76 112 959 6:59 i 0,717 A BV 1744B. 23, 508 NG 4.5777 99 745 9'19 17 0,714 A BV 10195, 10. 23B NG 1,9978 82 901 11:16 17 0,863 A BV 37425. 40,838 NG 7.9479 172 1296 16: 12 17 i. 241 A BB 84392. 46,919 NG 9. 12BO 330 1616 20:12 33 1.129 ABB 7619, 39.209 NG 7,6281 212 2083 26:02 60 0, SBO A BV 97B70. 64.319 NG 12. 9082 244 2143 26:47 92 1.219 A BV 69927, 48.479 NG 9,42

NO RET(L) RATIO RRT(L) RATIO AMNT AMNT(L) R, FAC R. FACtL.) RATIO1 9:92 0.99 1.000 1,00 40.00 40,00 1,000 1.000 1.002 3:39 0,370 50,00 — • 0,3803 9:25 0,954 90,00 0,9894 9:28 0,961 90,00 '1,0099 9:28 0,961 90,00 0,9926 9:28 0.999 SO, 00 0,7867 9:49 0,989 SO, 00 0. B488 9:94 1.004 90,00 0,9209 10:29 1.057 30.00 0.43910 10:21 1.049 90.00 0.60111 10:92 1,101 90,00 0.97412 10:80 1,099 50.00 0.20013 11:1414 11:1218 11:0716 11:2817 13: 10 0,99

139 SO. 00 0.678136 SO, 00 0.119127 50.00 0,2B7198 90.00 0.380000 1.00 40.00 40,00 1.000 1.000 1.00

18 12:06 0.918 • 30.00 0.98919' 12:16 • • 0,932 ' 80.00 0.15620 12:36 •.,0,956 • 50,00 0.30321 12:51 0,975 • . 90.00 0.43122 13:20 1.012 290,00 0,13323 12:96 0.982 90.00 0,29224 13:07 0,999 90,00 0,39229 13:13 1,004 90,00 1,10926 13:38 1,035 249,99 0.14927 13:49 1.04B 90,00 0,18828 19:04 1.143 80.00 0.33929 19:08 1,149 90.00 0,24330 19:49 I 1.200 90.00 0.07931 16:06 1,222 90.00 0.291 •32 16:11 1.229 249.99 0.18033 IB: 04 0,99 1.000 1,00 40,00 40,00 1.000 1,000 1.0034 16:26 0,911 80.00 1.20939 17:00 0,941 249.99 0.38436 17:43 0,980 90.00 1,39437 17:37 0,974 90,00 0,61938 17:91 0,9BB 90,00 0,29B39 18:10 1,005 249.99 0.03140 16:10 1.009 90.00 1.11441 16:27 1,021 249.99 0.08842 18:91 1.043 129.00 0.10943 16:37 1,030 90.00 1.67844 16:94 1,046 90.00 0,34949 19:49 0.99. 1.093 1.00 0.47 90,00 0,013 1.381 0.0146 19:43 1,091 90.00 0.918

If fl

47 19:34 1.0B3 90.00 1.2B748 20:19

f»k 49 20:0190 20:0591 20:,0992 22:10 0.99

124 249.99 0,003107 249.99 0. 100111 90.00 0.273119 90.00 1.291000 1.00 40.00 40.00 1,000 1.000 1.00

93 21:04 0,950 90.00 0.18094 21:20 0,963 90.00 0.23799 21:99 ' 0,989 90.00 0..09696 22:14 1.003 90.00 1..131,97 22:21 1,008 90.00 0.98998 24:22 0,99 1,100 1.00 0.28 90,00 0,008 1.396 0.0199 29:36 1,199 30.00 "" '0.99960 29:42 1.00 1.000 1.00 40.00 40.00 1.000 .1,000 1.0061 26:12 0,882 90.00 2.02962 26:99 0,908 90.00 0.01063 26:34 0,962 90,00 0.97464 30:43 1,007 90.00 0.01869 29:39 0,998 90,00 1.27966 30:23 1,023 90.00 1,47267 29:46 1.002 90.00 1.08768 32:03 1.00 1,079 1,00 0.79 30.00 0,034 2.162 0,0269 33:16 1,00 1,000 1.00 40.00 40.00 1.000 1.000 1,0070 32:33 0,979 30.00 1.49971 32:37 0,980 90.00 1.33772 33:19 1.002 30.00 1.03973 36:22 1,094 90.00 '0.38374 36:30 1,097 30.00 0.34879 37: 13 1. 119 90.00 0.34876 7:03 0,99 0,719 1.00 23.91 30,00 0,301 0.641 0.4777 .9:24 0,99 0,713' 1.00 10,24 90.00 0.080 0,389 0.2078 11:22 0,99 0,863 1.00 40.84 30,00 0,293 0,398 0.8279 16:20 0,99 1,240 1.00 46.92 90.00 0,660 0,703 0.9480 20:19 0.99 1,124 1.00 39.21 90.00 0,113 0.144 0.7861 26:09 1.00 0,880 1,00 64.32 90.00 2.341 1.820 1.2962 26:54 1,00 1,214 1,00 46,48 30.00 0.366 0.983 0.97

012983

U.S. ENVIRONMENTAL PROTECTION A«NCY-OP Smplt Mintjwwit OfficeP.O. Box III, Attxtnfrli, VA 223)3 - 703/997-2490

ORMNICS ANALYSIS DATA S*ET

libcrttory N-wi Mud CorouCh-i ' ______ ___ Cnt Nunb-r: .Lit 9M?U ID No.i _____ iC 'a - ______ QC R-sort HB.IiMpI* Hrtrlxi UlaulO ____________ __ Contrict No.i (n -Dit* N*U-M AultKTlHd BH __ _________ __ Diti SMpli RMilvid:Associated simples:

SEMIVOUTILE CONFOUNDS

CONCCKIIUTIONl ©MEDIUM HIM (elrell OM)DATE EXTrVem/fREPAREOl J?.| g4

DATE ANA.TSDI A-Z-m.roan MOISTMCI

Multiply DttKtlon ll-lti by I Q or 10 Q or |_f _____(Clnck Box for Approprlftt Factor)

CAM or ug/Kg £*£, ___(clrcli oot)

July, 1M3

ft SEMI-VOLATILE I CM LIQUIDOR6AN1CS ANALYSIS DATA SHEET • Pige 3

Lib Name! Htid CompuChemLib Simple I.D. No._13J%2__- __ SS Q DS


COMPOUND

2-Flgorophtnol

2,4,6-Trl.romoprienol

D-Phenol

05-mtroben.ene

DIA P-Terphenyl

2-Fluorobl phenol

FRACTIONSEMIVOA

SEK1VOA

SEMIVOA

SEMIVOA

SEMIVOA

SEMIVOA

CONC ( ug/1)

(06

lyo30

' So<&>-(<&——

-

(Surrogates only)Spue

Added ( uo/1)

10D

100

100

' 103

103

10(1

——— -.

\Recovery

U»0

37)

3,0

50<$>*.-»O

-... ......_

29 063237 i

• COMPOUND LIST NO. ___——— IDEKT1FIEP. SEMI-VOLATILES - LOK LEVEL LIQUID •

QUANT.COMPOUND REPORT CORRECTION RESULTS DET. L1K1T

COUSTER NUMBER COMPOUNDS_____ VALUE K FACTOR • (-9/11 (uo711

2 441 N-N1TROSOD.1«ETHYLA*!IKE .....3 610 PHENOL .....................4 473 ANILINE ....................5 411 IIS(2-CHLOROETHYL)ETHER ....6 601 2-CHLOROPHENOL .............7 421 1,3-DlCHLOROBENZENE ........8 422 1,4-OICHLOROflENZENE ........9 474 IENZTL ALCOHOL ......,«,....10 420 1,2-OICHLOROBENZENE.........11 620 2-METHYLPHENOL ............12 412 BIS(2-CHLOROISOPROPYL)ETHER13 622 4-METHYLPHENOL .............

. U . .-..442. N-NITROSO-DI-H-PROPYLAMINE .15 436 HEXACHLOROETHANE ...........16 ™ 440> NITROBENZENE ...............18 . JL3B 1SOPHORONE .................19 606 2-NITROPHENOL ..............

..*4...._20.__,603 2,4-DIMETHYLPHENOL .........'21 410 BISI2.CHLOROETHOXY)r1£THANE .

__.-22- .—tK- BENZ01C ACID ...............23 602- 2,4-DICHLOROPHENOL .........

.—- 24-——446: 1,2,4-TRICHLOROBENZENE .....25 439; NAPHTHALENE ................

~ 2"f 475 4-CHLOROANILINE ............27 434 HEXACHLOROBUTADIENE ........28 608" P-CHLORO-rKRESOL ..........29 477 2-KETHYLNAPTHALENE .........30 435 HEXACHLOROCYCLOfENTADlEHE ..31 611 2,4,6.TRlCKLOfWHEWL.......32 626 2,4,5-TRICHLOROfHENOL ......34 416 2-CHLORONAPHTHALENE ........35 479 3.NITKO>NILINE .............36 425 OlMrTHYLPHTKALATE ..........37 402 ACENAPHTHYLENE .............38 428 2,6-OINITROTOLUENE .........

PLEASE COMPLETE CORRECTION FACTOR CALCULATIONS ON THIRD SHEET OF THE COMPOl

• V 89012993

IUND LIST!!!

UHD L S . ——— IDENTIFIER SEMI-VOLATILES '•• LOK1 LEVEL LIQUID

QUANT.COMPOUND REPORT CORRECTIOK RESULTS OE7 L1KS7HUNTER NUMBER COMPOUNDS___ VALUE * FACTOR MIU/D ' "'39 47fi 2-NITROANILINE40 401 ACENAPHTHENE41 605 2,4-DINmOPKENOL42 607 44HTROPHENOL43 476 018ENZOFURAN44 427 2,4-DINlTROTOLUENE.45 424 OIETHYLPHTHALATE4f 417 4.CHLOROPHENYL PHENYL ETHER.......47 432 FLUORENE48 480 4-NITROANILINE49 604 4,6-DlNlTRO-O-CRESOL50 443 01PHENYLAMINE (N-NHROSO)51 430 1,2-DIPKENYLHYDRAZINE (AZOBENZENE),S3 414 4-BROHOPHENYL PHENYL ETHER54 433 HEXACHLOROBENZENE55 609 PENTACKLOROPHENOL56 444 PHENANTHRENE

4 57 , 403 ANTHRACENESB 426 DI-N-BUTYLPHTHALATE59 431 FLUORANTHENE61 445 PYRENE62 404 BENZ1DINE63 415 BUTYLBENZYLPHTHALATE64 423 3,3'.OICHLOROB.itfiDINE65 405 8ENZO(A)ANTHRACENE66 413 8IS(2.CTHYLHEXYL)PHTHALATE.67 418 CHRYSENE68 429 Dl-N-OCTYLPHTHALATE70 407 KttOlllrlUMWITKENE71 409 K«0(K)FLUOfWrHEHE.72 406 KNZO(A)PYRENE73 437 1MENO(1,2,3'C,WVRENE74 419 DlBEmO(A,H)MTHRACENE75 408 BENZO(8,H,HPERYLENE

, (SM eileulitlont tm) wrrogiu» en tick)012994

'I gg

- „. COMPUCHEM NO. _____ OATE ______ 3 of 2^COMPOUND LIST NO. ____ ————— ——————

———— IDENTIFIER SEMI-VOLATILES - LOK LEVEL LIQUID

QUANT.QUANT. REPORT ._

COMPOUND SURROGATE REPORT MOUNT » n ACCEPTABLENUMBER . COMPOUNDS VALUE SPIKED RECOVERY IANGE

619 2-FUIOROPHENOL612 DS-PHENDL447 Ds>NlTM»ENZENE #" 7 I SO 4 <A 4*. 142-131)

~ '- T48~2-FLUOROBIPHENYL ID 1<* 804 l,t> S (50-154)628' TR1BROMOPHENOL /^_____t BO « a/1 S9 (47-123)*471 OIO-PYRENE qi *>5 sot _ <&no i HA )*496 CH-TERPHENYL 'Z- sot . _. g»4 {S4-iiB)«

«Fer-Adv1iory Purpoiei Only

! » ttuBflL WUU « 100S

" CORRECTION FACTOR CALCULATION!

Flnil >»tnct1on vo1u«e(nH 1000 il ______ Dilution"~Mirw ACIC, ifi for UN * 101 . Mipie utricieo inn ) * Fictor x 2 »

MJ (ml) 1000 nll.n rji * iaoa (•» * __1__ x 2 •

OUAKT REPORT AHOUNT SPIKED CONVERSION FACTOR;

__.OO.V F1«i11 Entr.etVel. M\ DilutionNMuni surrogate AQded (ui) * MI Tor MIQ, HI TOT M * Fitter •

100 'ul____ \< Q~ luTT* mi

JRT 11/83

012993***.%

29

MISCELLANEOUS CAICUIATIOHS

ICilculBtlofi faploytd;

CONPOUNO RESPONSE FACTOR CALCULATION

$» ^X •

012993

23

012997

ftBig

IS-

r s

993

'PROCEDURE; RK DIAGNOSTIC REPORT 2/03/84 11:32:03DATA FILE: OJ019872A19REFERENCE: FSCC7

METHOD: FSCC7 INITIALIZATION OPTION: 2 PROCESSING OPTION: 3In REPORT: FSCC7S1

< —— STANDARDS ——— X —— PLUS UNKNOWNS —— X - LIST NAMES - >PROC USED POSS RMS PROC USED' PQSS RMS STANDARD/UNKNOWN

6,6 1 86 94 fr 1 26 FSCC7B1/FSCC7U16 l 6 1 26 34 8 1 69 FSCC7S3/FSCC7U2

82 COMPOUNDS PROCESSED* 8 FOUND ' ,

9 1 C 3 1 6 -1467 1468 . . . . . 1 3 892 C3 17 -1496 1497 , • , . . . 1 9 893 C3 IB -1460 1461 ' ". '. . . . 1699 4 C 3 1 9 -1464 1469 . . . . . 7 79 9 C 4 2 -1922 1923 . . . . . 2 4 8ft C4 3 -1947 1948 294- / C 4 4 -1983 19B4 . . . . . 2 6 698 C4 9 -1606 1607 . , , . . 1 7 3 160699 C4 6 -1613 1614 . , . . 1786 0 C4 7 -1720 1721 . . . . 149 172061 C4 B -1821 1821 , , , , 202 '182162 C9 2 -1861 1861 , ' , . . . 2 0 2 I86063 C9 3 -1897 1897 1ST 1B9764 C9 4 -1990 1990 . , . . 14969 C9 9 -20B9 20B9 , . , . 29266 C9 6 -2080 2080 . '228 '67 C9 7 -2103 2103 , , , . 149 .' .68 C9 8 -2088 20BB . , . . 22869 C9 9 -2240 2240 . . . . . 149 224270 C6 2 -2331 2331 , . . . 29271 C6 3 -2331 2331 . , . . 29272 C6 4 -2422 2421 , , . . 29273 C6 9 -2B93 2B92 . . . . 27674 C6 6 -2910 2909 , . . . 27879 C6 7 -3027 3029 , . . . 27676 C7 2 -620 622 , . . . 11277 C7 3 -766 768 . . . . . 99 .78 07 4 -908 910 , . . . 8279 C7 9 -1220 1221 1222 1 1 990 , 172 122880 C7 6 -1482 1483 330 148681 C7 7 -1897 1897 , , . . 2 1 2 1897

C7 8 -1893 1893. 1892 -1 ' 1 9BB . 244 1892

013000

IQUANTITATIQN REPORT FILE: ojoi9872Ai9[DATA: GJ019872A19, TI

1403/84 10:48:00Isf JLE: 1UL W19B72J + <3UL 10999 #033) ON #19(SUBMITTED BY: ttis ANALYST: 699LMOUNT-AREA * REF, AMNT/<REF, AREA)* RESP, FACT)fRESP. FAC. FROM LIBRARY ENTRYNO NAME1 *D4-1,4-DICHLQRQBENZENE (IS)2 441 N-N1TRQSQDIMETHYAMINE3 610 PHENOL4 473 ANILINE9 411 BIS(2-CHLOROETHYL)ETHER6 601 2-CHLOROPHENOL7 421 1,3-DICHLOROBENZENEB 422 1.4-DICHLORQBENZENE9 474 BENZYL ALCOHOL10 420 1,2-DICHLOROBENZENE11 620 2-METHYLPHENOL12 412 BI8<2-CHLORQI80PROPYL)ETHER13 622 4-rlETHYLPHENOL14 442 N-N1TRQSO-DI-N-PROPYLAMINE19 436 HEXACHLORQETHANE16 440 NITROBENZENE17 #460 DB-NAPHTHALENE (IS)IB 438 ISOPHRONE19 606 2-NITRQPHENOL(•% 603 2.4-D1METHYLPHENOLS? 410 B IS (2-CHLOROETHOXY) METHANE22 -629 BENZOIC'ACID23 602 2,4-DICHLORQPHENdL24 446 1,2,4-TRICHLOROBENZENE29 439 NAPHTHALENE26 479 4-CHLQROANILINE27 434 HEXACHLQROBUTADIENE28 60S P-CHLORO-M-CRESOL29 477 2-METHYLNAPHTHALENE30 439 HEXACHLOROCYCLOPENTADIENE31 611 2, 4, 6-TRICHLORQPHENQL32 626 2, 4, S-TRICHLOROPHENQL33 »D10-ACENAPHTHENE (IB)34 416 2-CHLORONAPHTHALENE39 479 3-NITROANILINE36 429 DIMETHYLPHTHALATE37 402 ACENAPHTHYLENE38 42B 2,6-DINITROTQLUENE39 478 2-NITRQANILINE40 401 ACENAPHTHENE41 609 2,4-DINITROPHENOL42 607 4-NITROPHENOL43 476 DIBENZOFURAN44 427 2,4-DINITROTQLUENE49 424 DIETHYLPHTHALATE/"i 417 4-CHLOROPHENYL PHENYL ETHER

013001

mm

NO NAME47 432 FLUQRENE4fl 480 4-NITROANILINEfl 604 4,6-DINITRO-O-CRESOL80 443 DIPHENYLAMINE (N-NITROSO)91 430 1,2-DIPHENYLHYDRAZINE (AZOBENZENE)92 *467 D10-PHENANTHRENE (IS)93 414 4-DROMOPHENYL PHENYL ETHER94 433 HEXACHLOROBENZENE99 609 PENTACHLOROPHENOL96 444 PHENANTHRENE ' ,97 403 ANTHRACENE98 426 DI-N-BUTYLPHTHALATE99 431 FLUORANTHENE "" '60 *499 D12-CHRYSENE (IS)61 449 PYRENE62 404 BENZIDENE63 419 BUTYLBENZYLPHTHALATE64 423 3,3'-DICHLOROBENZIOINE69 409 BENZO(A)ANTHRACENE66 413 BIS(2-ETHYLHEXYL)PHTHALATE67 418 CHRYSENE68 429 DI-N-OCTYLPHTHALATE69 *D12-BENZO(A)PYRENE (IS)70 407 BENZQ(B)FLUORANTHENE71 409 BENZO(K)FLUORANTHENE72 406 BENZO(A)PYRENE73 437 INDENO(1,2.3-C.D)PYRENE74 419 DIBENZO*A, H)ANTHRACENE,38 408 BENZO(OiHi DPERYLENE'•jr. 619 2-FLUOROPHENOL (SURROGATE)77 D9-PHENOL (3URROGATE)78 447 DS-NITROBENZENE (SURROGATE)79 44B 2-FLUQROBIPHENYL (SURROGATE)80 TRIBROMOPHENOL (SURROGATE)81 D10-PYRENE (SURROGATE)62 014-TERPHENYL (SURROGATE)

NO M/E SCAN TIME REF RRT METH AREA(HOHT). AMOUNT XTOT1 190 812 10:09 1 1.000 A BV 42430. 40,000 NO 9,792 NOT FOUND3 NOT FOUND4 NOT FOUND9 NOT FOUND6 NOT FOUND7 NOT FOUND8 NOT FOUND9 NOT FOUND10 NOT FOUND11 NOT FOUND12 NOT FOUND13 f!OT FOUND14 NOT FOUND19 NOT FOUND16 NOT FOUND17 136 1026 12:49 17 1,000 A BV 97692. 40.000 NO 9.79

l 82 992 11:94 17 0.928 AW 1183. 0.617 NO

NO M/E SCAN TIME REF RRT METH AREA(HGHT) AMOUNT XTQT19 NOT FOUND,20 NOT FOUND) NOT FOUND

y2 NOT FOUND23 NOT FOUND24 NOT FOUND29 128 1030 12:92 17 1.004 A BB 1499, 0. 993 NO 0, 1426 NOT FOUND27 NOT FOUND28 NOT FOUND29 NOT FOUND30 NOT FOUND31 NOT FOUND "" '32 NOT FOUND33 164 1339 16:44 33 1.000 A BV 49824. 40.000 NO 9.7934 NOT FOUND39 NOT FOUND36 NOT FOUND37 NOT FOUND38 NOT FOUND39 NOT FOUND40 NOT FOUND41 NOT FOUND42 NOT FOUND43 NOT FOUND44 NOT FOUND49 149 1431 17:93 33 1,069 A#BB 489. 0.290 NO 0.0646 NOT FOUND-47 NOT FOUND•":B NOT FOUND49 NOT FOUND90 NOT FOUND91 NOT FOUND92 188 1602 20:01 92 1.000 A BV 78940, 40.000 NG 9.7993 NOT FOUND94 NOT FOUND99 NOT FOUND, ...'96' 178 1606. 20:04 92 1.002 ABB 770. 0.367 NG 0,0997 NOT FOUND" '98 149 1720 21:30 92 1.074 ABB 2391, 0.746 NG 0.1899 202 1821 22:46 92 1. 137 A BB 901. 0.229 NO 0,0660 240 2083 26:02 60 1,000 A BV 93948. 40,000 NO 9,7961 202 I860 23:19 60 0.893 ABB 1093. 0.499 NO 0.1162 184 1897* 23: 13 60 0.892 A BB 6B9. 36. 163 NO ° °*-63 NOT FOUND64 NOT FOUND69 NOT FOUND66 NOT FOUND67 NOT FOUND68 149 2242 28:01 60 1.076 ABB 4449. 1.480 NO 0.3669 264 2413 30:10 69 1.000 A BV 41873. 40,000 NO 9,7970 NOT FOUND7 1 N O T FOUND . . .72 NOT FOUND . .73 NOT FOUND_> NOT FOUND : „„,.^ 013003

79 NOT FOUND"^ NOT FOUND. ..' NOT FOUND78 NOT FOUND79 172 1222 19:16 17 1,191 A BV 90349. 30,392 NO 7,4480 330 I486 18:34 33 1,110 A BV 3029, 19, 931 NO 3,8081 212 1897 23: 13 60 0, B92 A BV 82916. 41. 193 NO 10.0782 244 1892 23:39 92 1,181 A BV 98897, 40,936 NO 10.02

NO RET(L) RATIO RRT(L) RATIO AMNT AMNT(L) R. FAC R.FAC(L) RATIO1 10:07 1.00 1.000 1.00 40.00 40.00 1.000 1.000 1,002 4:99 0, 489 90,00 ... 0.4393 9:36 0,948 90.00 0.9034 9:39 0, 947 90.00 0.629g 9:43 0.960 90.00 1.0066 9:47 0.967 90.00 0.7287 10:03 0.993 90.00 0.863B 10: 10 1.004 90.00 0.9399 10:31 1,038 90.00 0.398 '10 10:32 1.041 90.00 0.84711 10:47 1.069 90,00 0.69912 10:49 1.069 90.00 0,27213 11:06 1.096 90.00 0.79414 11:07 1.098 90.00 0.14819 11:10 1.102 90.00 0.41616 11:23 1,129 90.00 0.38317 12:49 1.00 1,000 1.00 40,00 40.00 1.000 1.000 1.0018 11:93 1.00 0.928 1,00 0,62 90,00 0,010 0,784 0.01'-) '12:04 0.941 ' 90.00 0,196*. 12:11 0.991 90.00 0.31121 12:24 0.968 90.00 0.49922 12:41 0. 990 290.00 0. 13023 12:39 0.982 90.00 0.27724 12:44 0.994 90.00 0.33729 12:92 1.00 1.004 1.00 0.99 90.00 0.012 i. 108 0.0126 13:0727 13: 1628 14:0929 14:2230 14:9231 19:0932 19:1033 16:43 1.00

024 290. 00 0.233039 90.00 0. 187104 90.00 ' 0,396122 90.00 0.337161 90.00 0.079178 90.00 0. 179184 290.00 0. 1B7000 1.00 40.00 40.00 1.000 1,000 1.00

34 19:27 0.924 90.00 1.14039 19:49 0.946 290.00 0.41236 16:17 0.974 90.00 1.34337 16:23 0.980 90.00 1,79438 16:29 0.982 90.00 0.28239 16:48 1.004 290.00 0.02940 16:48 1.004 90.00 1.08241 17:00 1.016 290.00 0.04042 17:20 1.037 129.00 0.03743 17:09 1.029 90.00 1.61844 17:18 1.034 90.00 0,402' 17:92 1,00 1.068 1,00 0.29 90.00 0.008 1.996 0.01O 17:97 1/073 90.00 0.490 -

a 9 00125!

47 17:9948 18:20. 18:12Iw 18:1991 18: 1892 20; 01 1.00

072 90.00 1,246096 290.00 0,039oaa 290, oo o, 132091 90.00 0,827094 • 90,00 1.999000 1,00 40.00 40.00 1. 000 1.000

93 19:01 0,991 90.00 0. 18994 19:20 0,966 90.00 0.23299' 19:47 0.989 90.00 0.089,.96 20:04 1,00 1.003 1.00 0.37 90.00 0,008 1.062' Q. 0197 20; 10 1,007 90.00 1.01398 21:30 1,00 1.074 1.00 0.79 90,00 0,024 1.997 0,0199 22:46 1,00 1.137 1.00 0.23 90.00 0.009'" 1. 10B 0.0060 26:02 1.00 1.000 1.00 40.00 40.00 1.000 1.000 1.0061 23: 16 1,00 0,893 1.00 0.46 90.00 0.016 1.712 0.0162 23:13 1,00 0.892 1.00 36.16 90.00 0.010 0.014 0,7263 24:92 0.999 90.00 0.90064 26:07 1.003 90.00 0.03669 26:00 0,999 90.00 1.28966 26: 17 1,010 90.00 1.31967 26:06 1,002 90.00 1.3486B 28:00 1.00 1.079 1.00 1.48 90.00 0.066 2.246 0,0369 30: 10 1.00 1,000 1.00 40.00 40.00 1.000 1.000 1.0070 29:08 0.966 90.00 1.48171 29:08 0.966 90.00 ' 1,48172 30:16 1.003 90.00 1.11073 36: 10 • 1. 198 90.00 0.34474 36:22 1.209 90.00 0.404"A 37:90. 1.294 ' 90.00 0.3091 '•:' 7:49 0.769' 90.00 0.48977 9:34 0.747'" 90.00 0.3397B 11:21 0.886 90.00 0,44779 13:15 1,00 1,190 1,00 30.39 90.00 0.412 0.678 0.61BO IB: 31 1.00 1. 10B 1,00 19.93 90.00 0.049 0. 197 0,3181 23:13 1.00 0,892 1.00 41.19 90.00 1.233 1.498 0,8282 23:40 1.00 1,182 1,00 40.94 90.00 0.996 0,789 0.82

013003

i U.S. ENVIRONMENTAL PROTECTION AGENCY-OP Sonplt H«niJ-»nt 0(11MP.O. Box 818. Altxindrla, VA 22313 • 703/997-2490

ORGANIC5 ANALYSIS DATA SHEET

Libcrttory N«»i H-ad Cancueinn Cm NuRb-T!Lib S-pU ID Ho.! iq^ft _________ W Ripcrt ""•• '$•»)• Hrtrlxi liquid ___________ _____ Oontriet No.: fa^ • Q I -Diti RtliMi AuttiorlMd By: _________ ____ 0»ti SMpI* RteilvidtAssociated samples! jq|9fl . ________

. ___________ 5SMI»OLATILE COMPOUNDS

CONCEKTRATIONKlCOIUM HIGH (clrclt ont)DATE CimiAntD/F

DATE AHALTZHIIPOtCJHT MOISTWEl

Multiply DitKtlon llMlti by I Q or t o . . . __(ChKK Box for AftproprltttFKtor)

__. _v_ or ut/Xg £__ ___«. or ugAg(elreli ON) (clrcU otw)

~ SEMI-VOLATILE LOH LIQUID' ORGAN!CS ANALYSIS DATA SHEET - Pige 3

Lib -.-•! Hiid COfflPuCheir,

A. SURROSATE SPIKE RESULTS

CONC (U9/D 1 Addt."j: uQ/H j Recover

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' 3 610 PHENOL«73-mm411 •flSlt-CW.OROETHYDETKER601 NCHLOROPHENOL421 1.3.01CHLOROKHKNE ........422 M-OICHLOROIENZENE474 KNZYL ALCOHOL

10 420 1,2-OlCM.OROIEN.EKE11 620 2-KETHYLPHENOL12 412 I1S(2-CNLOROISOPROPYL)ETHER13 622 4*KETHYLPKENOL14 442 N-NITROSO-Dl-N-PROmNIINEIS 436 HEXACKLOROETHANE16 440 N1TROIEN7ENEIt 438 1SOPHORONE19 606 2-N1TROPHENOL20 603 8,4-OIMETHYLPHENOL21 410 •ISU'CKLOMETHOXYWETHMIE22 625 IENZ01CAC1D23 602 t,4.01CHLOROPHENOL24 446 1,2,4-TRlCKLOROIENZENE25 439 NAPHTHALENE26 475 4-CHLOROAN1LINE27 434 HEXACHLOROBUTADIENCtt «8 MH.ORO-IWRESOLM 477 t-KTHTUMPTHALCNEN 435 NEXACHLOROCYCLOPEHTWIENE ..31 111 2,4,6-TRlCHLOROPHENOL.......12 116 1,4,1-TRICW.OROPKENOL14 416 2'CaORONAPHTHM.INEIS 471 1-MTROANlLlNtM 42S llrtTHTLrMTWUTE ..........17 402 ACCNAPHTHYLtNE ...U 416 2,6'D1N1TROTOLUENE

»

PLEASE COMPLETE CORRECTION FACTOR CALCULATIONS ON THIRD MEET OF IKE COrK mi| ft w *» '.*4*/-» \t >i

29 478 M1TROANILM40 401 _MENAPHTKEtyi4142 607 .' falTROPHENOL43 476 tiKNZOFURAN44 427 I,44IN1TROTOLVENE.45 424 D1ETHYLPHTHALATE .................4f -417 44HLOROPKENYL PHENYL ETHER.......,47 432 FLUORENE48 480 MITROANILINE49 604 4,6-OlNlTRO-O.CRESOL,SO 443 DIPKENYLWINE (N-MITROSO) .......If- .. .430 1,2.DIPHENYLHYDRAZ1NE (AZ06EHZENE),S3 —414 4.BROHOPHENYL PKENYL ETHER .......,

• 54"- -433 . KEXACKLOROBENZEHE65 • "609 ', PENHCHLOROPHENOL66 —441 PHENANTHRENE ...

) S7——403 ANTHRACENEso 426 '"om-BUTYLPHTHALATE

. ||——43} fLUORANTHENE61——445 'PYRENE

» 62——404 ; SENZ1D1NE- 63——415 ' BUTYLBENZYLPHTNALATE

64-——423 ; 3,3'-DlCHLOROBENH01NI65 405 :'KNZO(A)ANTHRACENE ...............66 • 413 B1S(2.ETHYLHEXTL)PHTKAUT£........67 418 CHRYSENE .........

~ M——429 ..DM-OCmPHTHALATE.....70 407 KNZO(I)FLUORANTHENE .............,71 409 ' KNZO(K)FLUORANTHENE..............,72 406 KIIZO(A)PYRE1IE ................... (71——417 ; '|NOENO(l,2,W,OJPtl£NE .......... (74 419 B1BENZO(A|N)AKTKRACENE ............75 408 ' lENZOIMillKRYLENE ...

i MlcuUtloni ind lurrojitii en tack)J013011

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ROCCDURE: RK DIAflNOSTIC REPORT 1/31/84 0:16;DATA FILE; QJ019319B16REFERENCE: FSCC7

METHOD: FSCC7 INITIALIZATION OPTION: 2 PROCESSING OPTION: 3- REPORT: FSCC7B1

< —— STANDARDS ——— X —— PLUS UNKNOWNS —— X - LIST NAMES - >PROC USED POSS RI-IS PROC USED POSS RMS STANDARD/UNKNOWN

6 « 4 84 94 6 1 84 F8CC7B1/PSCC7U16 6 1 84 34 18 1 80 raCC7B3/P8CC7U3

< COMPOUNDNO LIB ENTRY1 Cl2 C23 C34 C49 C96 C67 Cl0 Cl9 Cl10 Cl11 Cl12 Cl13 Cl14 Cl19 Cl16 Cl.-:* ciIB Cl19 Cl80 ClM Cl82 C283 C284 C229 C226 C237 C288 C229 C230 C231 C232 C233 C234 C239 C236 C237 G338 G339 C340 C341 C342 C33 C3

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91 C398 C393 C394 C399 C4J* C4) C4

98 C499 C460 C461 C468 C963 C964 C969 C966 C967 C968 C969 C970 0671 C678 C673 C674 C679 C676 C777 C778 C779 0780 C781 C788 C7

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OATA: OJ019319B16. TI01/30/84 23:31:00

_ .MITTED BY: IUL 1931 ANALYST: 16

AMOUNT-AREA t REF. AMNT/(REF, AREA)* RESP. FACT)RESP. FAC. FROM LIBRARY ENTRY

NO NAME1 *D4-li4-DICHLOROBENZENE US)2 441 N-NITR080DIMETHYAMINE3 610 PHENOL4 473 ANILINE9 411 •IB(2-CHLOROETHYL)ETHER6 601 a-CHLOROPHENOL7 421 1,3-DICHLORQBENZENEB 422 li4-DICHLOROBENZENE9 474 BENZYL ALCOHOL .10 420 Ii 2-DICHLOROBENZENE11 620 2-METHYLPHENYL18 412 II8(3-CHLOROI80PROPYL)ETHER13 688 4-rCTHYLPHENOL14 448 N-NITROSO-DI-N-PROPYLAHINE19 436 HEXACHLOROETHANE16 440 NITROBENZENE17 *460 D8-NAPHTHALENE (18)18 438 ISOPHRONE19 606 a-NITROPHENOL20 603 2.4-DIMETHYLPHENOL,'* 410 IIB<a-CHLOROETHOXY)l1ETHANE•O. 689 BENZOIC ACID83 602 814-DICHLOROPHENOL24 446 li2i4-TRICHLOROBENZENE29 439 NAPHTHALENE86 479 4-CHLOROANILINE87 434 HEXACHLOROBUTADIENE88 608 P-CHLORO-M-CRESOL89 477 a-METHYLNAPHTHALENE30 439 HEXACHLOROCYCLOPENTADIENE31 611 2.4( 6-TRICHLOROPHENOL32 626 8.4,9-TRICHLOROPHENOL33 •DIO-ACENAPHTHENE (IB)34 416 8-CHLORONAPHTHALENE39 479 3-NITROANILINE36 489 DIMETHYLPHTHALATE37 408 ACENAPHTHYLENE38 488 8.6-DINITROTOLUENE39 478 2-NITROANILINE40 401 ACENAPHTHENE41 609 8.4-DINITROPHENOL48 607 4-NITROPHENOL43 476 DIBENZOFURAN44 487 2,4-DINITROTOLUENE49 424 DXETHYLPHTHALATE46 417 4-CHLOROPHENYL PHENYL ETHER

013013

29

NO NAME47 432 FLUORENE48 480 4-NITROANILINE.M 604 4,6-DINITRO-O-CRESOL3 443 DIPHENYLAMINE (N-NITR080)91 430 1.2-DIPHENYLHYDRAZINE (AZOBENZENE)92 *467 D10-PHENANTHRENE (IS)93 414 4-BRQMOPHENYL PHENYL ETHER94 433 HEXACHLOROBENZENE '99 609 PENTACHLOROPHENQL96 444 PHENANTHRENE97 403 ANTHRACENE98 426 DI-N-BUTYLPHTHALATE99 431 FLUORANTHENE ... .60 *499 D18-CHRYBENE (IS)61 449 PYRENE68 404 BENZIDENE63 419 BUTYLBENZYLPHTHALATE64 483 3.3'-DICHLOROBENZIDINE69 409 BENZO(A)ANTHRACENE66 413 BI8(a-ETHYLHEXYL)PHTHALATE67 418 CHRYBENE68 489 DI-N-OCTYLPHTHALATE69 tDia-BENZO(A)PYRENE (IB)70 407 BENZO(B)FLUORANTHENE71 409 BENZO(H)FLUORANTHENE78 406 BENZO(A)PYRENE73 437 INDENO(1.8.3-CiD)PYRENE74 419 DIBENZO(A, H)ANTHRACENE79 408 BENZO(Oi H,IJPERYLENE:# 619 a-FLUOROPHENOL (SURROGATE)n D9-PHENOL (SURROGATE)78 447 OS-NITROBENZENE (SURROGATE)79 448 B-FLUOROBIPHENYL (SURROGATE)80 TRIBRONOPHENOL (SURROGATE)Bl D10-PYRENE (SURROGATE)88 D14-TERPHENYL (SURROGATE)

NO M/E SCAN TIME REF RRT METH AREA(HOHT) AMOUNT XTQT1 190 734 9:10 1 1.000 ABB 99090. 40.000 NO 9.018 NOT FOUND3 NOT FOUND4 NOT FOUND9 NOT FOUND6 NOT FOUND7 NOT FOUNDB NOT FOUND9 NOT FOUND10 NOT FOUND11 NOT FOUND18 NOT FOUND13 NOT FOUND .14 NOT FOUND19 NOT FOUND'16 NOT FOUND17 136 949 11:49 17 1.000 A BV 104811. 40.000 NG 9.01<fl NOT FOUND

* *a oi3019

NO M/E SCAN TIME REF RRT METH AREA(HOHT) AMOUNT JCTOT19 NOT FOUND80 NOT FOUND^ NOT FOUND_J NOT FOUND23 NOT FOUND24 NOT FOUND29 NOT FOUND26 NOT FOUND27 NOT FOUND26 NOT FOUND29 NOT FOUND30 NOT FOUND31 NOT FOUND ... .33 NOT FOUND33 164 1296 19:42 33 1.000 A BB 99970. 40.000 NO 9.0134 NOT FOUND39 NOT FOUND36 163 1221 19:16 33 0.972 A BB 444. 0.233 NO 0.0937 NOT FOUND36 NOT FOUND39 NOT FOUND40 NOT FOUND41 NOT FOUND43 NOT FOUND43 NOT FOUND44 NOT FOUND49 149 1346 16:49 33 1.072 A BB 2929. t. 428 NO 0.3246 NOT FOUND47 NOT FOUND

. "IB NOT FOUND49 NOT FOUND90 169 1377 17:13 33 1.096 ABB 369. 0.977 NO 0,2891 NOT FOUND98 188 1917 18:98 92 1.000 A BV 90799. 40.000 NO 9.0193 NOT FOUND94 NOT FOUND99 NOT FOUND96 NOT FOUND97 NOT FOUND98 149 1639 80:26 92 1.078 A BB 8876. 0.719 NG 0. 1699 NOT FOUND60 840 1998 84:94 60 1.000 A BB 99909. 40.000 NO .9.0161 NOT FOUND63 NOT FOUND63 NOT FOUND64 NOT FOUND69 NOT FOUND66 149 2003 89:02 60 1.006 A«BB 8399. 1.394 NO 0.3167 NOT FOUND68 149 8131 86:38 60 1.070 A BB 4086. 1.899 NO 0.8969 264 2309 88:49 69 1.000 A BV 91746. 40.000 NO 9.0170 NOT FOUND71 NOT FOUND78 NOT FOUND73 NOT FOUND

013020

. . m» ta

NO M/E SCAN TIME REF RRT METH AREA(HOHT) AMOUNT XTOT79 NOT FOUND /*£$' 3.176 112 994 6:89 1 0.799 A BV "TSOTT: l7r4WNC 3.94H NOT FOUND IOf$V iQ.4 82 829 10:22 17 0.877 A BV 43993, 30. 936 NG 6.8879 172 1139 14:14 17 1.809 A BV 66937. 39,480 NG 7.9980 330 1398 17:28 33 1.113 ABB 7991. 32.700 NG 7.3781 812 1770 22:07 60 0.889 A BV 82630. 42.991 NG 9. 9982 244 1806 22:34 92 1.191 A BV 63118, 39,247 NG 8.84

NO RET(L) RATIO RRT(L> RATIO AttNT AMNT(L> R. FAG R. FAC(LV RATIO1 9:18 1.00 1.000 1.00 40.00 40.00 1.000 1.000 1.003 4:88 0.486 90.00 0.6813 B: 40 0.943 90.00 ... 0.8774 8:40 0.943 90.00 0.6689 8:48 0.997 90.00 0.8206 8:92 0.963 90.00 0.704

:07 0.990 90.00 0.8611334369092

10111213 10:0814 10:0919 10:1816 10:8917 '11:90 1.00

003 90.00 0.886039 . 90.00 0.480043 90.00 0.789069 90.00 0.931078 90.00 0.838

, 108 90.00 0.600, 103 90.00 0. 138109 90.00 0.387133 90.00 0.376,000 1.00 40.00 40.00 1.000 1.000 1.00

18 10:99 0.988 90.00 0.81419 11:09 0.937 90.00 0.838;.|> 11:13 0.948 .90.00 0.33031 11:89 . . ..0.969 90.00 0.49683 11:40 " 0.986 890.00 0.884 ,83 11:36 ..0.980 90.00 0.34184-11:49 " v 0.993 90.00 0.39789 11:92 .003 90.00 1.13426 12:08 .029 290.00 0.33037 18:17 .038 90.00 0.88188 13:10 .118 90..00 0.41189. 13:83 . . 131 90.00 0.31830 13:93 ' '1.173 90.00 0.10831 14:09 . „. .190 90.00 0.81938 14:10 • . 197 390.00 0.88033 19:43 1.00 .000 1.00 40.00 40.00 1.000 1.000 1.0034 14:87 0.919 90.00 1.81139 14:49 0.943 290.00 0.39936 19:17 1.00 0,972 1,00 0.23 90.00 0.006 1.371 0.0037 19:22 . .0.978 90.00 1.30038 19:29 "0.981 90.00 0.30839 19:44 . . 1.001 290.00 0.33640 19:47 ; .1.004 90.00 1.06341 19:97 " M.014 890.00 0.10342 16:1043 16:0844 16:1649 16:91 1.00

16:99

028 129.00 0. 189026 90.00 1.690039 90.00 - 0.496072 1.00 1.43 90.00 0.042 1.476 0.03.076 90.00 0.930 013021

47 16:99 1.076 90.00 1.29348 17:06 1.087 890.00 0.082

17:10 1.092 250.00 0.17017:12 1,00 1,094 1,00 0.98 90.00 0,009 0.278 0.02

91 17:16 1.099 90.00 1.82698 18:98 1.00 1.000 1.00 40.00 40.00 1,000 1.000 1.0093 18:00 0.949 90.00 0.20994 18:18 0.964 90.00 0.29199 10:43 0.986 90.00 0.11696 19:0197 19:0798 20:27 1.0099 21:4160 24:99 1.00

003 90.00 1.003008 90.00 0.948078 1.00 0.72 90.00 0.080 1.394 0.01143 90.00 ... 1.918000 1,00 40.00 40.00 1.000 1.000 1.00

61 82:11 0.891 90.00 1.90762 82:90 0.906 90.00 0.03163 83:46 0,994 90.00 0.89864 86:99 0.997 90.00 0.08969 84:98 0,998 90.0066 89:09 1.00 1.007 1.00 1.39 90.00 0,03467 84:9868 86:38 1.0069 88:91 1.00

78 88:9973 34:8874 34:31

008 90.00069 1.00 1.30 90.00 0.098 8.217 0.03000 1.00 40.00 40.00 1.000

70 87:47 0.963 90.00

.380

. 231 0. 03107

.000 1.00

.06871 87:91 0.969 90.00 1.007

003 90.00 0.996191 90.00 0.840197 90.00 0.788

79 39:99 1.849 90.00 0.8866:99 1.00 0.793 1.00 17.49 90.00 0.819 0.686 0.39B: 40 0.732 90.00 0.410

78 10:8379 14:1680 17:8981 82:09B2 22:39

00 0,87800 1.20900 1.11200 0. BB900 1.190

00 30.94 90,00 0.339 0.948 0.6100 39.48 90.00 0.914 0.724 0.7100 32.70 90.00 0.119 0.176 0.6900 4299 90.00 1.188 1.389 0.8900 39.39 90,00 0.996 0.709 0.78

013022

U.S. ENVIRONWNTAI. PROTECTION AOENCT-CU1 S«-)U MOMgwwit Olflci1 P.O. Box 816, AltKindrll, VA «3I) - 709/997-2490

ORSANICS ANALYSIS DATA SHEET

LiWitery NM*I M».<l Cmiaiim___________ Cut NumbiriLib Si-pi. ID No.i ISatio___________ 96 R-port No.i.Sopli Milrlxi llould________________ CoMriet No.t ,Diti «.)••« Auttiorliid By: ,____________ Oit» Smalt R«cilv«dtAssociated samples! f^/^o <g?~_____________________________ 5SHI»OUTII.E CWOUNDS

PDWHT NOISTUIttl

l (AHgi < - -t 4 -<te.

l-'C.'Ua.q-

COfKZNTRATIONl MEDIUM HISH Iclrclt OM)DATE EXTMCTED/MgA

DATS

Multiply 0»ttctlon llnlti by I Q or to(ChtcK Box for Approprlft* Ftcter)

ug/l ug/l___. or ug/Kg ___ ___ or ugAg

(clrclt OM) (elrelt OM)10U

'-s SEMI-VOLATILE LCM LIQUIDOR5ANICS ANALYSIS DATA SHEET - Page 3

Lib mint! Htid CompuCheir,Lib Simple 1.0. No.J_jJ__J__ __SS _]DS Jjj Blink

A. SURROSATE SPIKE RESULTS

COMPOUND

2-F1uerophtno1

2,<,6-TrlDPomopheno1

0-Phinol

DS-NUrobtn»ne

OIA P-T'erphenyl

.-Fluoroblphenyl

,

'

FRACTION

SEMIVOA

SEKIYOA

SEH1VOA

SEMIYOA

SEKIVOA

SEKIVOA

CONC ( ug/l)

b

(« -

-..<to

Oc

QDSk

Oq_

EE_.

isurroanei only)5P1M

Added ( uc/1)

103

100

100

103

100

100

r: •:._ ..

iRecovery

<_(_.

(c.>-

3<00

fcxnfo

013024

.-i It° i 2<_> m S 3(0 IS™ H 01 IBS S

?h i8 ii!™ 01

51 C!

s?ai

00127*

•o

N

30I I -vl-lj^- I I

89

1 COMPOUND LIST N*^ • ' ——— IDENTIFIER SEMI-VOLATILES - IW LEVEL LIQUID

QUANT.COMPOUM REPORT CORRECT10K RESULTS DET. Lite

">--fOUr!TER NUKBER COMPOUNDS_____ VALUE x FACTOR _ • W11 (UP'11

2 441 N-NITROSODIMETHYLAK1HE .....3 610 PHENOL .....................4 473 ANILINE ....................5 411 B1S(2-CHLOROETHYL)ETHER ....6 601 2-CHLOROPHENOL .............7 421 1,3-DICHLOROBENZENE ........8 422 1,4-DICHLOROBENZENE ........9 474 BENZYL ALCOHOL .............10 420 1,2-DICHLOROBENZENE.........U 620 2-METHYLPHENOL ............12 412 BISI2-CHLOROISOPROPYDCTHERIS 622 4-HETHYLPHENOL .............14 ' 442 N-NITROSO-DI-N-PROPYLAHINE .

...15-.,. 436 HEXACHLOROETHANE ...........16 440 NITROBENZENE ...............18 — 43B 1SOPHORONE .................19 606 2-NITROPHENOL

J 20 603 2,4-DIMETHYLPHENOL ........' 21 410 BIS(2-CHLOROETHOXY)METHANE

22 625 BENZOIC ACID23 602 2,4'OICHLOROPHENOL ....24 446 1,2,4-TRICHLOROBENZENE

.... 25--—435 NAPHTHALENE ...........26 ' 475 4-CHLOROAN1LINE .......27 434 KEXACHLOROBUTAOIENE ...28 COB P.CHLORO-M-CRESOL29 477 2-METHYLNAPTHALENE .......30 435 HEXACKLOROCYCLOPENTADIENE31 611 2,4,6-TIIICHLOROPHENOL.....32 626 2,4,5-TWCHLOROPHENOL ....34 416 2-CHLORONAPHTHALENE ......35 479 J-NITROANILIHE ...........36 425 D1HCTHYLPHTHALATE ........37 402 ACENAPHTHYLENE ...........3B 42B 2,6-OINITROTOLUENE

PLEASE COMPLETE CORRECTION FACTOR CALCULATIONS ON THIRD SHEET OF THE

I .. e«S73

LIST Nn" ——— IDENTIFIER SEMI-VOLATILE* - LOK LEVEL LIQUID

QUANT.COMPOUND REPORT CORRECTION RESULTS DE7 LIP"NUHBEP CWOUHSS_____ VALUE n FACTOR •<U9/U (ug/11

39 47R 2-NITROAN1LM40 401 ACENAPHTHENi ..41 605 2,4-DINITROPHENOL42 607 4«NITROPHENOL43 476 DIBENZOFURAN44 427 2,4-DlNlTROTOLUENE.45 424 DIETHYLPHTHALATE46 417 4-CHLOROPHENYL PHENYL ETHER.......47 432 FLUORENE48 480 4-NITROAN1LINE49 604 4,6'DINITRO-O-CRESOL50 443 01PHENYLAM1NE (N-NITROSO) .......51 430 1,2-DIPHENYLHYDRAZINE (AZOBENZENE),53 414 4-BROHOPHENYL PHENYL ETHER54 433 HEXACHLOROBENZENE55 609 PENTACHLOROPHENOL56 444 PHENANTHRENE57 403 ANTHRACENESB 426 ,DI-N-BUTYLPHTHALATE59 431 FLUORANTHENE61 445 PYRENE ......62 404 BENZIDINE63 415 BUTYLBENZYLPHTHALATE64 423 3,3'-DICHLOROBENZlDINE65 405 IENZOIA)ANTHRACENE66 413 IIS(2-ETHYLHEXYL)PHTHALATE.67 41B CHRYSENE ..................W 429 Ol-N-OCTYLPHTHALATE70 407 KNZO(B)FLUORAHTKENE71 409 KNZO(K)FLUORANTHENE.72 406 K«0(A)PYRENE73 437 INOENO(1,2,3-C,DJPYRENE74 419 D1BEHZO(A,H)AHTHRACENE75 408 KNZO(6,H,I)PERYLENE ............. ____ 4 _j;_ 20'

(See eileulitlons ind surrogates on tack)

013023

COMPUCHEM NO. ________,; DATE ______ 3 ofCOMPOUND LIST NO. ____ ""I

———— IDENTIFIER SErll-VOLATILES - LOK' LEVEL L10U1C

QUANT.QUANT. REPORT

COMPOUND SURROGATE RtPOP.T AMOUNT %* ACCEPTABLENUMBER . COMPOUNDS VALUE SPIKED RECOVERY RAH6E

619 2-FLUOROPHENOL & SOtTTTl &6» 125 115)612 DS-PHENOL /? so* „ 3? (15-90)447 OS-NITROBENZENE 3s- «u 7& '(42.131)448 2-FLUOROBIPHENYL 3f 504 _ Jf) .(50-154)"MB" TRIBROMOPHENOL 3/ SO* _| 1*2 (47-123)»471 DIO-PYRENE 47 M* <t+ ( NA )»496 DH-TERPHENYL f/ -so t , __ __g2, (54-iiB)«

*Ftir 'Advisory Purposes Only

... " Utepvery • Qum feljofl lj__t. ....... „ 100;tjuMiib nvpwrfc IVIUUhb apiiscu " 1WU«

CORRECTION FACTOR CALCULATION;

.FlJii.1 extrictlon voluirjelfl) 1000 »1 Dilution^im ror «1(:, wn Tor BK ~ " 101. stinpie .mraeieo mi) * Factor . * 2 •

i.o mi(Bl) . __lMO_Bl ;

111 X /

UAKT REPORT AMOUNT SPIKED CONVERSION FACTOR;

— •• 100 ul ______ Final Ixtraet Vol. (•!) Dilution.MMURJI surrogate waia (ui) * wi tor «eia, MI Tor M x Fictor_— 100:iil_____ ^ W)

" " j u i l x i.u HI

,*•

JRT 11/83

013029

Is*"^ *

-a

•'

|MM80

38.58

8

88.

S

g

-i

in

i

§!q!

___.*.-

88Ol|031

PROCEDURE: RK DIA8NOSTIC REPORT 1/27/84 8:10;97DATA FILE: OH019306C16REFERENCE' FBCC7

METHOD: FSCC7 INITIALIZATION OPTION: S PROCESSING OPTION: 3^ REPORT: FSCC781

< —— STANDARDS ——— >C —— PLUS UNKNOWNS —— X - LIST NAMES - >PROC USED POSS RMS PROC USED POSS RMS STANDARD/UNKNOWN

6 6 1 197 94 6 1 197 FBCC7BI/FBCC7U16 6 1 197 34 13 1 118 F8CC7B2/F8CC7U2

< COMPOUND X ———————— SEARCHNO LIB ENTRY REF PRED BEL, DELTA1 Cl2 C8a cs4 C49 C96 C6

•733 733 733-949 944 943-1898 1899 1894-1919 1914 1919-1996 1988 1990-8311 8301 8899

7 Cl 3 -396 3988 Cl 3 -691 691V Cl 4 -690 69010 Cl 9 -701 70111 Cl 6 -706 70618 Cl 7 -787 78713 Cl B -739 73914 Cl 9 -768 76819 Cl 10 -769 76916 Cl 11 -784 . 784

tfjt.7 Cl 18 *7B7 787IB Cl 13 -BOB 808

' 19 Cl 14 -BIO 80980 Cl 19 -814 81381 Cl 16 -838 83188 C8 8 -678 87189 C8 3 -889 88484 C8 4 -896 89989 C8 9 -913 91886 C8 6 -933 93887 C8 7 -989 98488 C2 B -939 93829 C8 9 -949 94830 C8 10 -966 96431 C8 11 -981 97938 C8 18 -1098 109033 C8 13 -1070 106834 C8 14 -1110 110839 C8 19 -1186 118336 C8 16 -1133 113037 C3 8 -1199 119838 C3 3 -1184 118139 C3 4 -1883 188040 C3 9 -1830 188741 C3 6 -1839 183248 03 7 -1899 1896W C3 B -1864- 1861

S«44 C3 9 -1876 187349 C3 10 -1898 188846 C3 11 -1898 188847 C3 18 -1303 189948 C3 13 -1390 134649 C3 14 -1399 1391

91 C3 16 -1369 136992 C3 17 -1376 137893 C3 18 -1379 137994 C3 19 -1384 138099 C4 8 -1441 1437M C4 3 -1469 1461> C4 4 -1498 149396 C4 9 -1983 191899 C4 6 -1931 198660 C4 7 -1638 163361 C4 B -1737 173168 C9 8 -1777 177163 C9 3 .64 C9 4 -1909 189869 C9 966 C9 6 -1993 198667 C9 7 -8011 300368 C9 B -8001 199369 C9 9 -8136 818870 C6 8 -8887 881871 C6 3 -8838 888378 C6 4 -8318 830973 C6 9 -8791 873974 C6 6 -8766 879479 C6 7 -8880 886776 C7 8 -990 991 99177 C7 3 -689 689 690 178 C7 4 -889 888 88879 C7 9 -1140 1138 1137 -180 C7 6 -1400 1396 1396•1 C7 7 -1773 1767 1768 182 C7 8 -1808 1808 1803 1

9B9969982979999930987

13819816977248284266178178149 1633802202184149892.888 . .149 8000888 •" .149 8188898898898876878876118 99199 69088 888178 1137330 1399818 1768844 1803

1

1

1

1

J ' ; 013033

riTATION REPORT FILE: OH019306C16

DATA: OH019306C16, TI01/87/84 7:30:00P*f LE: 1UL 19306 + 9UU IS (10910)_ JMITTED BV: 16 ANALYST: 794AMOUNT-AREA » REF. AMNT/(REF. AREA)* RESP, FACT)fREBP. FAC. FROM LIBRARY ENTRYNO NAME1 »D4-1,4-DICHLOROBENZENE (IS)8 441 N-NITR080DIMETHYAMINE3 610 PHENOL4 473 ANILINE9 411 •I8(8-CHLOROETHYL)ETHER6 601 a-CHLOROPHENOL7 481 1,3-DICHLOROBENZENE8 488 1,4-DICHUOROBENZENE9 474 BENZYL ALCOHOL10 480 1,2-DICHLOROBENZENE11 680 2-METHYLPHENYL18 418 II8(8-CHLOROI80PROPYL)ETHER13 688 4-HETHYLPHENOL14 448 N-NXTR080-DI-N-PROPYLAMINE19 436 HEXACHLOROETHANE16 440 NITROBENZENE17 *460 De-NAPHTHALENE (IS>IB 438 I80PHRONE19 606 8-NITROPHENOL80 603 814-DIMETHYLPHENOL

410 BIBta-CHLOdOGTHOXYXIETHANE689 BENZOIC ACID

83 608 8,4-DICHLOROPHENOL84 446 1.8i4-TRICHLOROBENZENE89 439 NAPHTHALENE86 479 4-CHLOROANILINE87 434 HEXACHLORDBUTAOIENE88 608 P-CHLORCH1-CRE80L89 477 a-METHYLNAPHTHALENE30 439 HEXACHLOROCYCLOPENTADIENE31 611 8,4,6-TRICHLOROPHENOL38 686 8,4, 9-TRICHLOROPHENOL33 •DIO-ACENAPHTHENE (18)34 416 a-CHLORONAPHTHALENE39 479 3-NITROANIHNE36 489 DIMETHYLPHTHALATE37 408 ACENAPHTHYLENE38 488 3,6-DINITROTOLUENE39 478 2-NITROANILINE40 401 ACENAPHTHENE41 609 8.4-DINITROPHENOL48 607 4-NITHOPHENOL43 476 DIBENZOFURAN44 487 2,4-DINITROTOLUENE49 484 DIETHYLPHTHALATE46 417 4-CHLOROPHENYL PHENYL ETHER

01303429

NO NAME47 438 FLUORENE48 460 4-NITROANILINEf\ 604 4, 6-DINITRO-O-CREBOL\J 443 DIPHENYLAMINE (N-NITR08Q>91 430 1,8-DIPHENYLHYDRAZINE (AZOBENZENE)98 t467 DlO-PHENANTrMENE (IS)93 414 4-BROMOPHENYL PHENYL ETHER94 433 HEXACHLOROBENZENE99 609 PENTACHLOROPHENOL96 444 PHENANTHRENE97 403 ANTHRACENE98 486 DI-N-BUTYLPHTHALATE99 431 FLUORANTHENE - '60 *499 D18-CHRY8ENE (18)61 449 PYRENE68 404 BENZIDENE63 419 BUTYLBENZYLPHTHALATE64 483 3,3'-DICHLOROBENZIDINE69 409 BENZO(A)ANTHRACENE66 413 BIS(2-ETHYLHEXYL)PHTHALATE67 418 CHRYBENE68 489 DI-N-OCTYLPHTHALATE69 «Dia-BENZO(A)PYRENE (IB)70 407 BENZO(B)FLUORANTHENE71 409 BENZOdOFLUONANTHENE78 406 BENZO(A)PYRENE73 437 INDENO(l,8,a-C,D>PYRENE74 419 DIBENZO( A, H) ANTHRACENE79 408 BENZO(0,H, DPERYLENE(rS 619 2-FLUOROPHENOL ( SURROGATE)ft D9-PHENOL (SURROGATE) '78 447 D9-NITROBENZENE (SURROGATE)179 448 8-FLUOROBIPHENYL (SURROGATE)80 TRIBROnOPHENOL (SURROGATE)81 D10-PYRENE (SURROGATE)88 D14-TERPHENYL (SURROOATE)

NO N/E SCAN TIME REF RRT METH AREA(HCHT) AMOUNT XTOT1 190 738 9: 09 1 1. 000 A BB 19348. 40. 000 NO B. 868 NOT FOUND3 NOT FOUND4 NOT FOUND9 NOT FOUND6 NOT FOUND7 NOT FOUND8 NOT FOUND9 NOT FOUND10 NOT FOUND11 NOT FOUND18 NOT FOUND13 .NOT FOUND14 NOT FOUND19 NOT FOUND16 NOT FOUND17 136 943 11:47 17 1.000 ABB 31689. 40. 000 NO 8.86

013035

NO M/E SCAN TIME REF RRT METH AREA(HGHT) AMOUNT XTOT19 NOT FOUND80 NOT FOUND1 NOT FOUNDi NOT FOUND83 NOT FOUND84 NOT FOUND89 NOT FOUND86 NOT FOUND87 NOT FOUND88 NOT FOUND89 NOT FOUND30 NOT FOUND31 NOT FOUND - •38 NOT FOUND33 164 1894 19:40 33 1.000 ABB 19997. 40.000 NG 8.8634 NOT FOUND39 NOT FOUND36 NOT FOUND37 NOT FOUND38 NOT FOUND39 NOT FOUND40 NOT FOUND41 NOT FOUND48 NOT FOUND43 NOT FOUND44 NOT FOUND49 NOT FOUND46 NOT FOUND47 NOT FOUND

(/_a NOT FOUND•7* NOT FOUND90 NOT FOUND91 NOT FOUND98 188 1914 18:99 92 1.000 A BB 34983. 40.000 NG 8.8693 NOT FOUND94 NOT FOUND99 NOT FOUND96 NOT FOUND97 NOT FOUND98 149 1633 80:29 98 1.079 A BB 919. 0.669 NG 0. 1499 NOT FOUND60 840 1989 84:98 60 1.000 A BB 83981. 40.000 NO 8.2661 NOT FOUND68 NOT FOUND63 NOT FOUND64 NOT FOUND69 NOT FOUND66 149 8000 89:00 60 1.006 ABB 896. 1.108 NG 0.8367 NOT FOUND68 149 8188 86:36 60 1.070 ABB 1413. 0.987 NO 0.2069 864 8899 88:44 69 1.000 ABB 81199. 40.000 NG 8.8670 NOT FOUND71 NOT FOUND78 NOT FOUND73 NOT FOUND•»4 NOT FOUND^ 89 013038

79 NOT FOUND76 112 991 6:93 1 0.793 A BV 8949, 33. 118 NO 6.84-77 99 690 B: 37 17 0.732 A BB 6404. 19.041 NO 3.93'8 82 828 10:21 17 0.878 A BB 19816, 39.069 NO 7.2479 172 1137 14:13 17 1.206 ABB 80799. 39.069 NO 7.2480 330 1399 17:26 33 1,112 ABB 3774. 31.660 NG 6.93

1 9:10 1.00 1.000 1.00 40.00 40.00 1.000 1.000 1.008 4:87 0.486 90.00 0.9943 8:38 0.943 90.00 ... 1.1944 8:37 0.941 90.00 1.3079 8:46 0.996 90.00 0.986

:49 0.963 90.00 0.788:09 0.998 90.00 0.868ill31344890

10111813 10:0614 10:0719 10:1016 10:8417 11:49 1.00

003 90.00 0.987040 90.00 0.919,044 90.00 0.826070 90.00 0.693074 90.00 0.846108 90.00 0.768109 90.00 0.188111 90.00 0.496139 90.00 0.409000 1.00 40.00 40.00 1.000 1.000 1.00

18 10:94 0.983 90.0019 11:04 0.937 90.00

11:18 0.948 90.0011:89 0.966 90.00

88 11:40 • 0.987 290.0083 11:34 0.979 90.0084 11:44 3 £ 0.994 90.0089 11:9286 18:0487 18:1688 13:0989 13:8830 - 13:9831 14:0438 14:1033 19:43 1.00

004 90.00 1.111022 890.00 0.482038 90.00 0.839113 90.00 0.431138 90.00 0.436179 90; 00 . 0.186198 90.00 0.863199 290.00 0.809000 1.00 40.00 40.00 1.000 1.000 1.00

34 14:86 0.918 90.0039 14:48 0.941 890.0036 19:17 0.978 90.0037 19:88 0.978 90.0038 19:86 "0.988 90.0039 19:44 1.001 890.0040 19:4841 19:9748 16:0943 16:0944 16:1749 16:98«6 16:96

009 90.00 1.113014 890.00 0.147087 189.00 0.490087 90.00 1.683036 90.00 0.911073 90.00 1.813.077 90.00 0.970

013037

48 17:07-*» 17:183 17:14

91 17:IB98 IB: 99 1.00

1.19808B 890.00 0.384094 890.00 0,814096 90.00 0.689100 90.00 1.989000 1.00 40.00 40.00 1.000 1.000

93 18:01 0.949 90.00 0. 19994 18:19 0.964 90.00 0.84699 18:43 0.986 90.00 0. 14196 19:08 1.003 90.00 1.079'97 19:08 1.008 90.00 0.86898 80:88 1.00 1.078 1.00 0.67 90.00 0.021 1.966 0.0199 81:43 1.144 90.00 ...1.80260 84:97 1.00 1.000 1.00 40.00 40.00 1.000 1.000 1.0061 88:13 0.890 90.00 1.39468 88:90 0.906 90.00 0.03163 83:49 0.994 90.00 0.96064 86:99 0.997 90.00 0.08969 84:99 0.998 .90.00 1.47966 89:08 0.9967 89:0168 86:48 1.0069 88:93 0.99

008 1.00 1.10 90.00 0.029 1.899 0.08003 90.00 1.044070 1.00 0.99 90.00 0.047 8.389 0.08000 1.00 40.00 40.00 1.000 1.000 1.00

70 87:90 0.964 90.00 1.80471 87:94 0.966 90.00 0.79878 88:98 .003 90.00 0.89373 34:83 .190 90.00 0.73974 34:34 .197 90.00 0.83379 36:00 .846 90.00 0.689

6:988:37

78 10:2279 14:1980 17:3081 88:1088 82:36

00 0.790 1.00 33.18 90.00 0.449 0.678 0.6600 0.789 1.00 19.04 . 90.00 0.168 0.489 0.3800 0.877 1.00 39.06 90.00 0.399 0.969 0.7000 1.806 1.00 39.07 90.00 0.924 0.747 0.7000 1.113 1.00 31.66 90.00 0.194 0.243 0.6300 0.888 1.00 46.78 90.00 1.243 1.389 0.9400 1. 190 1.00 41.41 90.00 0.663 0. BOO 0. S3

013033

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013040

29 001287013041

U.S. ENVIftONttOTAL PROTECTION AGENCY - CLP Sunpli Minigmwnt OfI letP.O. Bex BIB, Altxindrli, Vlrgtnll 22313 - 703/357-2490

ORSWICS ANALTSIS DMA SHEET

Cnumttiiiti , Cm Nuinwr Q- 3-3 _Uborftory Nw«iLib implf ID Nfli iqa-Hl* ___________ « Rtport No. I Vl /

''IMP)* MltrlM UmU ________________ Confrict No.t to'g-'OI - i»T(o3-fiiti Rilt«i AirtlwrlitO By! . ____________ _ Oitt Smpl* Rtetlvtdi _ _____ , _____

youTinsCONCENTRATION! LOV MEDIUM HIGH (clrclt) CONCENTRATION! (__,UCWflir HIGH (clrclt out)DATE EXTRACTEO/HlEPWEDi _______________ DATE EXTrWOEO/WWWEOiOATt ANALREOi ______________________ DATE ANAltHOl l-oil»iX4KRCSMT WISTWi __________________ rtRCSNTAssociated samples: Associated samples toVfeO \Q19T1 -Multlply Ottirtlon llnlti by t or ____ Multiply Otttetlon llnlti by I %or

(Cl** Bo» for Approprliti Fictor) (ChtcX ton far Approprlitt Fictor)ug/lCAW or ugAg

(clrclt ont)

BIOXIN5

COtfflNTHATIONl rtSJ) WOIUM HIGH (elreli)DATE EnHACTEB/WEMdEDl __ _______DATE MM.YBO! "~

Associated samples: ._ ___ gg/]or ugAg

i — —— — • —— — (clrclt wit)2,3,7,8-tftrKltlarodlbinio-IIM6I 1146-01-8 B-dloiiln 0.004U

PESTICIDE LOK' LIQUIDOftGANlCS ANALYSIS DATA SHEET • P«ge 3

u .-fi8iAfc-J.l2dt-' D* D»


'""""COBWiJND ——Dlbutychldrdtndait

.. ——

-*—-» -*, _ |

. ——————....... — . _____

, — -. .. ——— .

. ——————

._ -:., ___________... ——————— ,

. -. ——— .......

.. ,_f . __________

FRACTION

PESTICIDE

CONC ( ue/1

. ———

•

'

... —— .

(5urf.;t:tsSpUt . •

Added (uc/1 )

0.5

..

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•

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013043

' 29

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COMPUCHEM HO.

IDENTIFIER PESTICIDES (LOH LEVEL-HATER)

COMPOUND LIST - NO. ____

R_ NUMBER COMPOUND NAME_____ RESULT0701 ALDRIN .............0702 ALPHA-BHC ..........0703 BETA-BHC .........0704 6AKMA-BHC .........0705 DELTA-BHC .......

~ 0706 CHLORDANE ——•-—0707 4,4'-DDT .......0708 4,4'-DDE ............0709 4,4'-DDD •-——...........0710 DIELDRIN .............0711 ALPHA-ENDOSULFAN .....

. . " 0712 BETA-ENDOSULFAN .——•——0713 ••"' ENDOSULFAN SULFATE —-—

—- 0714 ENDRIN ...............6715 ENDRIN ALDEHYDE <—--——

/- - 0716 HEPTACHLOR ——»———«0717 HEPTACHLOR EPOXIDE ——

' 0718 PCB-1242 —-————

20. * 0720 PCB-1221 ———•"21 r 0721 PCB-1232......22. 0722 PCB-124823. 0723 PCB-1260.....24. 0724 PCB-1016.....25. 0725 TOXAPHENE ——•

QUANT.COMPOUND SURROGATE; s RECOVERY REPORT CORRECTION AMOUNT s 'NUMBER COMPOUNDS HINOOM VALUE FACTOR RESULT SPIKED RECOVERY

0738 DIBUTYL CHLORENDATE (67-114)* ___ ___ __£(_ I&B ffi013043

J*Ady1$ory L1«tt ...

'

HMI'UTUDE x..'j uV»s*conds (EnUrgeJ x 14.31J

. 89

K'eporti 673£',IHI Channel '/IT 1VR4C. Injpded at Ml i4Hil (I (,IN ,i*N i'4, JVIH

Mpthocli PAiiKliy i.ier|i WtiH'/L1 UulHi'i/HAnpi 1/11 B t l i nSI- width MV/Min Delay Min-Ar Hunch

,'JHO ,41111 II. Ill) 101)1) Ai)foSuii' link DM! 1D"I.M1 h'ef'IMW XIMH Zlnt-f 1 pu

NU II. Hi) i) ,.il) S.ll iOD.ili) ,. NOActu#J run tiMfi -S.OT/ Minutes

lindfld not onNo reference peak found

K'l ll'M factor Area fit/Ml ,

..II****** ,100111)!' nil ,.«6'jll61. lift 64,421.),CV****** ,1000llt.'Mll lOlll,, Hill .lib'/,y6****** .iiiooiii;mi iiiitv, m ..SBl , ir/*m** . luuflOk'idi tut,!;, so

1. '/!!*{**** .lUUIIOK'MIl ;>US'j. SB .1)562 . 1 '/****** , 1 II U U U M + 0 1 'Ab't'A 1 , Bill , VP „. . . ,_2 , VII****** , UlUOllK'Hlj 4V11, till , OVi!3.y»****** ..ti)i)i)i)u+oi y.6i), s» ,14?4.76****** .iiiuoo-'i'fii 4i»yyi;, an u,i4ss.yy****** ,10 on UK 'Mil io;!4. SB ,0366 , Vb'*»i***« J,IIU(IOI.;'IU1 1L'161, Up i;4ll•/ . 6V*m*« ,,tl)l)l)l)l''Hll 13U, SM .11.69,66****** .ifi(if)0k:+ui r/tis;',, SB i,>z<6.ta.yy****** .iiiiiiiDiM'Ui HUH. so .D.DU'i.ttU*;**** . KKIOUtMdl £41111.',, UK 4r/414.6V****** ,10HI)l)KM)t 4l)y4. Htt ' J9bU,,M,*****# , lllfll)UI,.lUJ 7'/6VV. t;iH I.HI'.IJIV. 6V****** ,101)1)01' ill I ll)H4y41. iJlil .1.40!!)i:u,v7*m** ,111 no in: <i in i.4:r., BH .OM81,<;y****** ,100001; MM Ul-U, Slil ,l)4£

Tola* Area • <M,?7M, Total HIVMI =data <'i)ei I"/;<:M Kow data CJ)f?i

013047

091533

fldCLlTUDE x.2S uV-*tcond. (Enlarged x 2.55)

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, .NVIMMCNTM, PROTECTION MCNCY - CU> Iwplt MmpMlt Off letto, ton HI, MMMfrla, Vlrglnli M313 - TO/HM4M

CHWHICS/WAI.YIIS DATA SHEET

I litioritory NMI ComuHi*- _____ ___ C«t NinMr ._____ __ __Lit S*vli ID Not |QO-AU- « Rmort Ho7T3 7 /f Infill d-trlm Jlauld _______________ Ccnfpict No.)I Dili MliMi Atrftarli* lyi ____________ . 0§fi tapli lUcil-di

VOLATIUS RITieiDCS

tCNOCNTIUTIOHl LW MEDIUM HIM (clrcll) , OONCfNTMTIONl (__) MEDIUM «IBM (elrcll em)BATEDAT. NW.TZDI ._____________________ DAT! AMAUBDI ..___WWW MDHTW-l __________________ f-WIT MOHTttRSl __Associated samples; . A.$oeiated samplesMultiply Dtttetlon Haiti by 1 O^D ——— Multiply OitKtlon ll.lti ty 1 J_JorJ_] ___(CM* ta for Approprltti Fietor) IChMk to* for Aotrcorlitt Factor)

l|/l "8/1CAW or >|Ag m CAM or ggAg(elreli OM) (clrcli OM)

lOT-OXhtn>aO_HE>J3'ruansfi.

l_UlMIL'_- _)

r^UlB.____:lyfllti titriclilBriai

___

*i*y»rm*m'r.!l*«-rehiofottft»ft»luicararrrancriraErra;..-wfliampm___,

;.;-itificMBT8«tMinF» _.___JJL!____I._____IE g. S!!'°r'*tB!!'*. .1! y i-|Moreitriy|»ln

?) jOJ-OO-i jlyln__________O.

3EInyl »thtr

rtmranncitanramracmE;urarmjiKiiKamu JKimK rirac: rearemin

mr-.IVI__tm_b_n|_SEZ5_i

£_____•_

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PROCEDURE-. RK DIAGNOSTIC REPORT 2/03/84 11:23: 23DATA FILE-. TCOJL9246A03FWeERENCE: TC

'METHOD-. TC INITIALIZATION OPTION: S PROCEBSINC OPTION: 3REPORT-. TC8

. < —— STANDARDS ——— X — PLUS UNKNOWNS — X - LIST NAMES - >PROC USED POSS RMS PROC USED POB8 RtlB STANDARD/UNKNOWN

S Z 1 ISO 7 9 1 • 66 TCS/TCU

7 COMPOUND. PROCESSED. S FOUND ' •

< COMPOUND X ———————— SEARCH ———————— X BAT X. —I—— CHRO ————— >NO LIB ENTRY REF PREO 9EL DELTA PEAKS PIT PEAKS M/E TOP DELTA PEAKS1 TC 1 -691 6B7-B8 1 1-31 . 332 ' 6M . 12 TC 2 -.71 667 466 -1 1 966 . 32. 646 . 23 TC 3 -670 663 666 1 1 9B6 . 322 666 . 24 TC 4 -671 666 666 . 1 986 237 667 1 15 TC 5 -692 6B_ . . . . 3__ 6B7 26 TC 6 -691 6B7 . . . . 322 690 17 TC 7 -692 668 .88 . 1 972 . 2S7 .

013053

eg MJ203

MEAD COMPUCHEMOUANTITATMN REPORT FILE'. TC019S46A05

_ATA: TC019246A05, TI02/85/84 10:54:99SAMPLE; 2ULS SAMPLE #192468-069/327 FOR TCDD ON «5SUBMITTED BV: «S ANALYST: 615

AMOUNT-AREAWCHT) * REF. AMNT/(REF, AREA(HCHT)* RESP. FACT)RESP. FAC. FROM LIBRARY ENTRY

NO NAME1 »13C12-2< 3*7. B-TCDD(INTERNAL STANDARD) - •2 1.2.3.4-TCDD3 1,2,3,4-TCDD4 1,2,3,4-TCDOS 2,3,7,8-TCDD6 2,3,7.8-TCDD7 2,3,7, B-TCDD

NO M/E SCAN TIME REF RRT ICTH AREA(HCHT) AMOUNT XTOT1 332 668 15:34 1 1 ««0 A BV 1124760. 200. 000 PC/UL 19.942 329 666 19:04 1 0.968 A*BV 979631. 229.007 PC/UL -2. B33 322 666 19:04 1 0.968 A«BV 1303830. 223.674 PC/UL 32. SO4 297 667 19:05 1 0.969 A BV 916389, 338.346 PC/UL 33,735 320 687 19:32 it, 999 A»VB 32066, ft B77 PC/UL 0. BB6 322 690 13:36 1 JL 003 A W 637ft i. 310 PC/UL 0.137 NOT FOUND

K *K> RET<L) RATIO RRT<L) RATIO AMNT AMNT<L) R FAC R. FAC(L) RATIO1 13'. 31 10010001.00 200.00 200.00 1000 1000 1002 15-. 00 100 0.966 100 229.01 200.00 0.871 0.761 1193 13; 00 100 0.966 100 229,67 200.00 1199 1037 1134 19-.01 100 0.96B 100 338,33 200.00 0.459 0.371 1693 19-.32 1,00 1.001 100 a 88 200.00 0.029 0,642 0.046 19:32 100 1001 100 131 200.00 0.006 0.893 0.017 19:32 1,001 200.00 0.340

013054

3 £ g ' P S .* S P

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013057

IO 013053

I U.S. ENVIRONMENTAL PROTECTION AGENCY - CLP Sttpll Mirtfjtmtnt Off let| P.O. Bo« 816, Alixindrli, Vlrglnli 2291} - 709/997-2490

ORGAN I CS ANALYSIS DATA SHEET

Llbwitory Nr»: CtmuOim _____ ____ Cwi Numbr |33-5' t.-,l. ID No. ~"Smpli Hitrlx: Uguld^ ___________ __ Centrist No.iOiti Riltm Agthorliid Byt . ___________ __ Diti Surf It Rtctlvtdi

PESTICIDES

CONCENTRATION) (jCojp MEDIUM HIGH (clrcjt) -.. CONCENTRATION) (_35) MEDIUM HIGH (clrcl* Oflt)DATE EXTflAfltO/rW/WEDl ("^_'_/ °m EXTMSTEO/PREPWEDi ____________DATE AHALTZEOt _____ I-»-7--*<>• DATE ANALTZED) __________________PERCENT MOISTURE) ____________________ «««NT MOISTURE)Associated samples; 3^ /q|y-7_ Associated samplesMultiply Dtttetlon ll"lt» by I HOT Q _____ Multiply Dtttetlon llnlti by I |_] w

Bw for Apprpprlitt Ftttor) _^ IChtek ton for AppropMiti Tietor)PPI CAM

i

. . . .S,5,7,8-t.trichlorodlb«nio-o.OMU

013053

VOLATILE LOW LIQUID-^ ORGAN1CS ANALYSIS DATA SHEET - Pige 3

tab Name; Head CotnpuChemLab Simplt I.D. No. /T/P/ P_] SS [] OS j_] Blank

A. SURROGATE SPIKE RESULTS.... .. —

COMPOUND -

dB-Toluene

d4-l,2-D1cn!oroethane

BromoftBorobenzene

* ————— •'•'•" - P ————

.. ______......... .... —— _

- — ——————

..........

t - ....

FRACTION

VOA

VOA

VOA

CONC< ug/l )

It'b

/(&

l?<*

•

(SurrogatesAdd?dP'9/i )

20

20

20

....

>nl__Recovery

13

py&

•

-."-.».....—

013060

i

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5

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^ 013061

.•,-.• ..v.wf:,,., ...,'*TE, */ /y-

cill..-p.*. N, Jf/ • /, :•. ,''.;,, ." .-. .,.......,— 013062> J A«un -7T Lot

COMPUCHEM NO. . DATE ____ 1 Of 2•COMPOUND' LIST NO. __ —————— IDENTIFIER VOLAT1LES - LOH LEVEL LIQUIDQUANT.

,_ COMPOUND REPORT CORRECTION RESULTS DETECTIONJOUHTER NUMBER COMPOUNDS_____ VALUE * FACTOR • (u9/11 LIMITIug/11

2. 221 CHLOROMETHANE3. 220 BROMOMETHANE4. 231 VINYL CHLORIDE5. 209 CHLOROETHANE6. 222 HETHYLENE CHLORIDE7. 252 ... ACETONEB. 201 ACROLEIN9. "~202 ACRYLONITRILE10. 230 TRICHLOROFLUOROMETHANE

' H> 254 ...CARBON DISULFIDE12. 216 1,1-DICHLOROETHYLENE13. "214 ""TTDICHLOROETHANE14. --—226——TRANS-1,2-DICHLOROETHYLENE15, _._2H__MLJ1BOFORM16. 215 1,2-Dl'CHLOROETHANE17. 253 2-BUTANONE18, _227-—-htrf-TRICHLOROETHANE19. 206 .J.CAR.P TETRACHLORIDE21. 257 VINYL ACETATE"22. 212BROMODICHLOROMETHANE ......23_. .—.17—ITMICHLOROPROPANE .....

250 TRANS.1.3.D1LHLOROPROPENE25. 229 TRICHLOROETHYLENE ........ ____L26. '203 BENZENE .................. _1027. 226——.Th.-TRICHLOROETHANE ....28. 218 CIS-1.3. DICHLOROPROPENE..29. 208 DIBROMOCHLOROMETHANE ...'..30. 210——EffiOTWETHYLVlNYL ETHER....31. 205 -BROMOFORM

•32. 256 4-HETHYL-2-PENTANONE .....34. 255 2-HEXANONE35. 223 1,172,2-TETRACHLOROETHANE.

PLEASE COMPLETE CORRECTION FACTOR CALCULATIONS ON SECOND SHEET OF THE COMPOUND LIST!!!

COMPUCHEM NO. _____ DATE ______ Of 2'COMPOUND LIST NO. ___ —————

——— IDENTIFIER VOLATILE5 - LOH LEVEL LIQUID

~) QUANT.COMPOUND REPORT CORRECTION RESULTS DETECTION

COUNTER NUMBER COMPOUNDS_____ VALUE x FACTOR • (ug/l) • LIMlT(ug/1)

36. 224 TETRACHLOROETHENE.37, 225 TOLUENE...........3B. 207 CHLOROBENZENE.....39. 219 ETHYLBENZENE .....40. 251 STYRENE...........41. .239 0-XYLENE..........

QUANT.COMPOUND SURROGATE REPORT AMOUNT % T t RECOVERYNUMBER COMPOUNDS VALUE SPIKED RECOVERY HINOOH

258 D4-1,2,DICHLOROETHANE (SURR) W."U 20.0 fr\ (90-130)*233 OB-TOLUENE (SURR).......... i?.i_ 20.0 <ft W-wj247 BROMOFLUOROBENZENE (SURR). . Q. 20.0 • fo (67-127)*

^Advisory Halts .

.CORRECTION FACTOR CALCULATION:

_. r 5300 ulVolume of Simple Analyzed tun

5000 ul(Ul)

I Recovery • Quint. Report Vilue._ mount spued "

JRT 11/63

jAWW4" '"" * ••' v ,'

.o

2.1

•PROCEDURE; RK DIAGNOSTIC REPORT A/27/B4 AA:!i";"A4DATA FILE: CN019A8AAAAREFERENCE: V237

METHOD'. V237 INITIALIZATION OPTION-. Z PROCESSING OPTION: 3^ REPORT: V237BA

< —— STANDARDS ——— >< —— PLUS UNKNOWNS —— X - LIST NAMES - >PROC USED POSS RMS PROC USED POSS RMS STANDARD/UNKNOWN

3 2 A 0 44 10 A 33 VS37SA/V237UA

44 COMPOUNDS PROCESSED, AO FOUND '

< COMPOUND X ———————— SEARCH ———————— X BAT X ———— CHRO ———- 3-NO LIB ENTRY REF PRED BEL DELTA PEAKS FIT PEAKS M/E TOP DELTA PEAKSA PI A A6A A62 A62 , A 9B0 "_30- 162 AB P2 A -337 337 . . , Tt.- 33B A3 P3 A 4A6 4A6 4A6 , A 979 S3 4A6 A4 P A 2 2 9 3 0 . . . . . 3 0 .B P A 3 4 8 4 3 . . . . . 9 4 .6 P A 4 5 2 5 3 , . . . . 6 2 ,7 P A 3 6 8 6 9 . . . . . 6 4B PA 6 102 A83 . . . . .84 A.3 A9 P A 7 -AAA A A S . . . . . 3 8

AO PA B -AAA AA2 . , , . , 361A PA 9 A24 A23 . . , . . 33A2 PA A0 A39 A40 . . . , . A0A .A3 PA AA A29 A30 . . . , . 76A4 PA AS A32 A32 A53 A A 970 , 96 A32 -. A"A 3 P A A 3 A 7 6 A 7 6 . . . . . 6 5 .16 PA A4 A90 A90 , , , , . 96 .

A3 202 202 . ' . . ' . , 63 202 A...A6 -2A6 2A6 . . . . . . . 62 2A3 . A.

A9 PA • A7 2A3 2A3 . . . , , 72 .2 0 P A A B 2 4 0 2 4 0 . . . . . 9 72 A P A A 9 -246 2 4 8 . . . . . A A 7 ,2 2 P 2 2 2 3 1 2 5 1 . . . . . 4 3 ,23 P2 3 238 258 , . . , A2724 P2 4 2B4 2B4 . . . , _,__. ..65:.-. -.-..23—.pg-___,.S- 290 290 __..75 _.._.._,_ __

~ 26"~'P2' 6 30A 30A 300 -A A 967 ... A30 300 ' A ~27 P2 7 3A0 - 3A0 3A0 , A 994 7B 3A0 A26 P2 B 3A5 3A3 , , , . 9729 P2 9 -3A5 3A3 . , . , , 73 .30 P2 A0 -3A4 3A4 . , . , , A27 . '3 A P 2 A A -336 3 3 6 . , . . . 6 3 3 3 9 132 P2 A2 366 366 . . . . , A7333 P2 A3 374 374 , . . 5634 P3 2 405 405 . . , 5835 P3 3 -4AA 4AA . . . . , 6336 P3 4 4A2 4A2 , , . , . A64 4A2 237 P3 5 436 436 436 . A 990 92 436 A36 P3 A 459 459 459 . A 992 AA2 439 A39 P3 7 495 495 , . . , 106 496 240 P3 6 566 • 566 . . , , , A04 566 24A P3 9 366 568 , . , " , A06 568 242 P4 2 -2i4 2A4 2A4 . A 952 65 2A4 A43 P4 3 , 433 433 433. , A 990 , A00 433 A

. J P4 4 540" 540 340 . A 958 A76 540 1w 0130G3

••w f ••.7 Pi

'••« PA

j QUANTITATION REPORT FILE: CNOA91S1AA1

DATA: CN0A9ABAAAA. TI0A/27/84 10:55:00SAMPLE: s ML t A9ABA + s UL 1001 + IBBBB •»• AOBBS' IBMXTTEO BY: AA ANALYST'. 377

AMOUNT-AREA * REF, AUNT/(REF, AREA)* RESP, FACT)RESP. FAC. FROM -LIBRARY ENTRY

NO NAME1 t BROMOCHLOROMETHANE (IS)2 221 CHLOROMETHANE ' •3 220 BROMOMETHANE4 231 VXNYL CHLORIDE3 209 CHLOROETHANE6 222 METHYLENE CHLORIDE7 252 ACETONE <2-PROPANONE>B 201 ACROLEXN9 202 ACRYLONITRILE10 230 TRXCHLOROFLUOROMETHANE11 254 CARBON DI8ULFXDE12 216 1. i-DICHLOROETHYLENE13 214 1,1-DICHLOROETHANE14 226 TRANB-A, 2-DICHLOROETHYLENE15 211 CHLOROFORM16 215 1,2-DICHLOROETHANE17 253 2-BUTANONEIB 227 A, 1,1-TRXCHLOROETHANE19 206 CARBON TETRACHLORIDE20 » 2-BROMO-l-CHLOROPROPANE

257 VXNYL ACETATE '212 BROMODXCHLOROMETHANE

2 3 2 1 7 A , 2-D1CHLOROPROPANE . . .24 250 TRANB-A, 3-DICHLOROPROPENE25 229 TRICHLOROETHYLENE26 203 BENZENE27 •226 A, 1, S-TRXCHLOROETHANE26 216 C1S-A, 3-DICHLOROPROPENE29 206 DXBROMOCHLOROMETHANE30 2A0 2-CHLOROETHYL VINYL ETHER3A 205 BROI10FORM32 256 4-METHYL-2-PENTANONE33 ft OXCHLOROBUTANE34 255 2-HEXANONE35 223 A, 1. 2, 2-TETRACHLOROETHANE36 224 TETRACHLOROETHENE37 225 TOLUENE38 207 CHLOROBENZENE39 SA9 ETHYLBENZENE40 251 STYRENE41 239 0-XYLENE42 t D4-A, 2-DICHLOROETHANE43 * OS-TOLUENE44 » BROMOFLUOROBENZENE

NO M/E 8CAN TIME REF RRT METH AREA(HGHT) AMOUNT 7.TO

O '"

NO M/E SCAN TIME REF RRT METH AREA(HGHT) AMOUNT ?CTO'A 130 162 8:14 1 1.000 ABB 20332, 20. 000 UG/L B, B:2 NOT FOUND

-S3 NOT FOUND4 NOT FOUND5 NOT FOUND6 64 103 5: A4 1 0, 636 A BB 3801. 1. 5A4 UG/L 0. 6-7 NOT FOUND •B NOT FOUND9 NOT FOUND10 NOT FOUND11 NOT FOUND12 96 <_Ss-> 7:44 10.93B A BB 33523, c aa. Bts UC/J—i£_£s £13 NOT FOUND14 NOT FOUND13 63 20J2 10:16 1 1,247 ABB 2694. 0. 644 UC/L 8, 2"16 62 -.OS? 10s36 1 1. 327 A BB A3359. <£94"9~ UG/L 2, A'-tfW")17 NOT FOUND —————————J""18 NOT FOUND19 NOT FOUND20 79 338 17:11 20 A, 000 A BB 29A40. 20. 000 UC/L B, 5'.21 NOT FOUND22 NOT FOUND23 NOT FOUND24 NOT FOL25 130 Opa? iSi A3 1 1. B52 A BB 46717. fjaji67 UC/L 9. i-:26 76 J9TE) A3: 43 1 A. 9A4 A BB 134117, £ 2025 UC/L B,27 NOT FOUND ^2B NOT FOUND29 NOT FOUND40 63 339 17:14 1 2.093 A.BB. 347. 0, 520 UG/L 0, 2i31 NOT FOUND32 NOT FOUND33 55 416 21: 09 33 1, 000 A BB 40435, 20. 000 UG/L B, 5'.34 NOT FOUND35 NOT FOUND36 164 4AS 20:37 1 2.343 A«BB AA3B, e__AO-UG/L —— 0-2-37 92 -<36j 22: A0 A S. 69A A BB 95837. (357774 UC"36 112 £59)23:20 1 2.833 ABB A027B2, Css B«i UC/i «» 7;r39 106 496 25: 13 1 3, 062 A»BB 479, 0. 165 UG/L 0, 0"40 A04 566 26: 46 A 3. 494 AtBB 562. 0. A79 UG/L 0, 0641 ,106 566 29: 53 1 3, 630 AtBB 1539. 0, 660 UG/L 0, 2842 65 2A4 A0: 53 A A. 32A A BB 50243, A6, 709 UG/L '7, A:43 100 433 22: 01 A 2, 673 A BB 95451, AB. 63A UG/L 7. 9344 A76 540 27: 27 A a 333 A BV 63280, A7. 340 UG/L 7. 3-

NO RET<L) RATIO RRT (L) RATIO AMNT AMNT(L) R. FAC R. FAC(L) RATIOA 8: Al A. 0A A, 000 1, 00 20, 00 20, 00 A, 000 1, 000 1, 002 Is 28 0,180 40,00 1,2633 2:08 0, 26A 40.00 A, 7414 2s 39 0. 323 40, 00 1. 5735 3s 27 0.422 40.00 0.9086 3: 11 1. 01 0, 634 1, 00 1. 51 40. 00 0. 069 A, B20 0, 047 5: 39 0, 669 300, 00 0. 036B 5s 39 0, 6B9 400, 00 0, 0479 6s AB 0. 770 400, 00 0, ASA

J7-.04 01663 40.00 4.446

|» 29 .

11 6:33 0. BOA 40. 00 3, 471IS 7s 44 A. 00 0, 944 0. 99 SB. B4 40. 00 0, B24 A, A43 0.72o43 8:57 A. 093 40.00 0, BBS14 9s 39 1. ABO 40.00 A. 934AS 10: A6 A, 00 A. 255 0, 99 0. 64 40. 00 0, 066 4. AA5 0, 02A6 AO: 56 A, 00 A. 335 0. 99 4, 95 40, 00 0, 333 2, 695 0, A2A7 AO: 50 • A, 323 300. 00 0. 057A8 12:12 A. 491 40,00 3.745A9 A2-.33 A. 534 40.00 2,94920 17: AA i, 00 A. 000 A. 00 20. 00 20. 00 A. 000 A, 000 A, 0021 12:46 A. 559 40.00 A, 085 •22 A3:07 A. 602 40.00 0.26323 14s 26 1.764 40.00 ... 0..64524 14s 41 1.793 40.00 3,63125 13:15 1.00 A. 663 0. 99 2A. 57 40,00 A. A49 2,' A3A . 0, 5426 A3:43 A, 00 Ar.925 0. 99 20, 02 40.00 3.298 6, 5BB 0, SO27 16s 01 1.957 40.00 1.2402B 16s 01 1.957 40.00 1.52B29 15:53 1.944 40.00 1,66130 17s 05 1.01 2.067 1, 00 0,52 40,00 0,009 0.656 0.0131 16:33 2.267 40,00 0.90532 19:01 2. 323 60.00 0,21033 21:09 1,00 1,000 1, 00 20, 00 20.00 1,000 1,000 1,0034 20:35 2,516 60.00 0.44135 20s 54 ".~ 2.553 ' 40.00 1.31436 20s 54 1,00 i 2.: 553 1.00 0.64 40,00 0.028 1,780 0.0237 22:10 1,00 "-& 708 0.99 19,77 40,00 2.337 4,767 0,4938 23s 20 100 2,651 0.99 22.84 40.00 2,528 4,426 0,5739 25:10 A. 00 3, 075' A. 00 0. A6 40. 00 0,012 2. 856 0, 00

26:46 1, 00 . 3. 516 0. 99 0. IB 40, 00 0, 014 3.194 0, 0029:53 1.00 3.652 0.99 ' 0.66 '40.00 0.038 2,295 0,02

42 10s 50 1.00 1.323 1.00 16,71 20,00 2.471 2,958 0, 6443 2is SB A. 00 r 2.683 A. 00 AB, 63 20.00 4.695 5, 039 0. 9344 27s 27 A. 00 3.354 0. 99 A7. 34 20.00 3. AA2 3.390 0,87

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U.S. ENVIRONICNTAl PROTECTION AGENCY • CU» Smpli Minigmnt OtdetP.O. BDII 616, Almanorlo, Vlrjlnli 22313 - 703/997-2490

ORGANICS ANALYSIS DATA SHEET

tiboritory Nmi Camuemm Cut Nui»b<r _Lib Sli-plt ID KOI /*=? / (P2- QC Riport No,Smplt Mitrlxt ryajia______________, Contnet No.tIiti Rtltui Airtherlitd By: _____________, Dili Smpli Rmlvtd:

PESTICIDES

CONCENniATIONtAO^FlDIUM HI OH (clrclt) ..,._ CON_!NTRATIOHI (J3J) MEDIUM. HISH (elrclt IDATE EXTRACTM/PI-P/WEDl _____^-^3 -g*7 DATE EXTRttTED/PREPWEDi _________DATE AMAlTItOl _____ l-JH-6^ DATE ANAlYTOi _______________TOICENT MOIITUI-l ' PERCtNT MOISTURE!Associated sanples; Wfo q|j>7~^__-^ Associated samplesMultiply Dttictlon llnlti by I ]2or|_] ______ Multiply Dtttttlon ll-lti by I Jljor j_J ,_____(CM* Bo« for Approprlitt Fictor) ^ (Chtck Bo« for Apprcprlitt Ficter)

ug/lm CAM or ugAg •(clrclt oni)jji BS? la."———

July, 196!

VOLATILE LOW LIQUID> ORGANICS ANALYSIS DATA SHEET - Page 3

Lib Name! Head CompuChemLib Sample I.D. Ho,_J_?______ P SS _3 DS DBl»nlt

A, SURROGATE SPIKE RESULTS

COMPOUND "

dB-Toluene

d4-l,2-D1cl)1oroethane

Brofflofliocootniine

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COMPUCHEM NO. _____ DATE ______ Of 2•COMPOUND LIST NO. ____ ————— ——————

———— IDENTIFIER VOLATILES - LOH LEVEL LIQUID

^ QUANT.COMPOUND REPORT CORRECTION RESULTS DETECTION

COUNTER NUMBER COMPOUNDS_____ VALUE x FACTOR • (un/1) LIMIT!ug/11

36. 224 ' TETRACHLOROETHENE......... ____ [ \ *j37. 225 TOLUENE..................38. 207 CHLOROBENZENE............39. 219 ETHYLBENZENE .....,..,.,,40. 2S1 STYRENE..................41. 239 0-XYLENE.,,..............

QUAHT.COMPOUND SURROGATE REPORT AMOUNT . T (RECOVERYNUMBER COMPOUNDS VALUE SPIKED RECOVERY HINDOH

2SB D4-1,2,DICHL;OROETHANE (SURR) -lJo 20.0 (90-130)*233 DB-TOLUENE -ISURR),., ,.,.„. ityq.. 20.0 ' °i°\" (84-ii4)247 BROMOFLUOROBENZENE (SURR). . 1T.ID 20.0 9 S (67-127)*

•Advisory Limits

• CORRECTION FACTOR CALCULATION:

5300 ulVolume or sample Analyzed lull

5000 ul_____(Ul)

*

I Rtcovwy • Quant. Report Valuemount spuea * •w*

JRT 11/83013086

s coa !?'/»t

. COMPUCHEM NO. _____ DATE ______ 1 of 2FT "'COMPOUND LIST NO. ___ ————— ——————

——— IDENTIFIER VOLATILE5 - LOH LEVEL LIQUID

QUANT.COMPOUND REPORT CORRECTION RESULTS DETECTIONNUMBER COMPOUNDS_____ VALUE X FACTOR • (ua/1) LIMIT!ua/1)

2. 221 CHLOROMETHANE ............3. 220 BROMOMETHANE .............4. 231 VINYL CHLORIDE ...........5. 209 CHLOROETHANE..............6. 222 METHYLENE CHLORIDE .......7. 252 ACETONE ..................8. .—201 ACROLEIN .................9. 202 ACRYLONITRILE .,..,...,...10. 230 TRICHLOROFLUOROMETHANE ...11. 254 CARBON DISULFIDE .........12. 216 1,1-DICHLOROETHYLENE .....13. 2ir—1,1-DICHLOROETHANE .......14. 226 TRANS-1,2-DICHLOROETHYLENE

-.-.15. 211' ' CHLOROFORM ............... ___16. 215' " 1,2-01'CHLOROETHANE ....... _____17. 253 2-BUTANONE ..............

" 18. 227 1,1,1-TRICHLOROETHANE....19,' 206 CARBON TETRACHLORIDE ....21. 257 VINYL ACETATE ............22. 212 BROMODICHLOROMETHANE .....,23, 217 1,2-D1CHLOROPROPANE ......*24. 250 TRANS-1,3-DICHLOROPROPENE,25. 229 TRICHLOROETHYLENE ........ __J26. 203 BENZENE ....,.,..,.....,.. \\27. 228 1,1,2-TRICHLOROETHANE ....28. 218 CIS-1,3, DICHLOROPROPENE.,29. 208 DIBROMOCHLOROMETHANE ...'..30. 210 CHLOROETHYLVINYL ETHER....31. 205 BROMOFORM ................•32. 256 4-KTHYL-2-PEHTANONE .....34. 255 2-HEXANONE ...............35. 223 1,1,2,2-TETRACHLOROETHANE.

2005510555s

Al 5. 510555

1001005

SJPLEASE COMPLETE CORRECTION FACTOR CALCULATIONS ON SECOND SHEET OF THE COMPOUND LIST! 11013087

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PROCEDURE'. RK DIAGNOSTIC REPORT 1/H7/B4 1-124:33DATA FILE i CN0191B2A11REFERENCE', V237

METHOD', V237 INITIALIZATION OPTION'. 2 PROCESSING OPTION: 3.•*"») REPORT'. V237S1

< —— STANDARDS ——— X —— PLUS UNKNOWNS —— X - LIST NAMES - >PROC USED POSS RMS PROC USED POSS RMS STANDARD/UNKNOWN

3 a 1 0 44 10 i 4S V237S1/V337U1

44 COMPOUNDS PROCESSED. 10 FOUND

CODPCNO LIBi Pi 1 161 161 161 . 1 976 . -130- 161 12 P2 1 -337 337 , . . 79 . 338 13 P3 1 416 416 416 . i 965 , 33' 416 14 P I - 2 9 2 8 . . . . . S B .5 P i 3 4 2 4 1 . . . . . 9 4 .6 P i 4 3 2 5 1 . , . . . 6 2 .7 PI 5 68 66 . , . . 64 .B PI 6 102 102 . , . . . 84 101 19 P I 7 -111 1 1 1 . . . . . 5 8

10 PI B -111 111 . , . , , 56 .11 PI 9 124 124 . , . , 531 2 P I 1 0 1 3 9 1 3 9 . , . . . 1 0 1 . . .13 PI 11 129 129 , , . 7614 PI 12 152 .152 152 , i 978 , 96 151- -_. 1_5 PI 13 176 176 . . . ... 65 176 "" ' " 1.16 Pi 14 190 190 . . . . . 9617 .PI '15 202 202 . . . . . 83 202 1

PI .16 -2.16 216 . . • , . -. 62 215 - - - i19 PI ' 17 ' 213 213 . •. . , 72SO PI 18 240 : 240 , . . 9721 Pi 19 -248- 248 . . . . . 1172 2 P 2 2 2 3 1 2 5 1 . . . . . 4 3 ,83 P2 3 258 258 . . , . 12724 P2 4 284 284 . , . , . 6525 P2 5 290 290 . , . , - -•;- ~75;''" 7_6-~T_—*••_ 301, 301 300 -1 i 972 ' -. ' 130 300---.- ——__87 P2 7 310 310 310 . 1 994 .'78 '310 ' "~ "'£~SB P2 8 315315 . . . , 9729 P2 9 -315- 315 , , . . , 75 ,3 0 P 2 1 0 -314 3 1 4 . . . . . 1 2 73 1 P 2 1 1 -336 3 3 6 . . . . . 6 332 P2 12 366 366 . , . . . 17333 P2 13 374 374 , . . , SB34 P3 2 405 405 , . . 583 5 P 3 3 -411 41 1 , . ' . . , 8 3 .36 P3 4 412 412 . . , . 164 411 137 P3 5 436 436 436 . 1 992 92 436 138 PS 6 459 459 459 . 1 987 112 459 139 P3 7 495 495 . . . , 106 496 240 pg B S66 566 104 565 141 P3 9 588- 588 ... ... , 106 588 142 P4 2 -214 214 213 -1 1 960 , 65 213 143 P4 3 433 433 433 . 1 988 . 100 432 -3. 1

P4 4 544 540 540 , 1 953 176 540 1

OUANTITATION REPORT FILE', CN0191BSA11

DATA: CN019182A11. TZ.01/27/84 11: 50:00OMPLE: 5 ML # 19182 + 5 UL 1001 + 10BBB * 10B82SUBMITTED BY: 11 ANALYST: 577

AMOUNT-AREA * REF, AMNT/tREF. AREA)* RESP, FACT)RESP, FAC. FROM -LIBRARY ENTRY

NO NAME1 * BROMOCHLOROMETHANE (IS) '.'2 221 CHLOROMETHANE3 220 BROMOMETHANE4 231 VINYL CHLORIDE - -5 209 CHLOROETHANE6 228 METHYLENE CHLORIDE7 888 ACETONE (2-PROPANONE)B 201 ACROLEIN9 208 ACRYLONITRILE

. 10 830 TRICHLOROFLUOROMETHANE11 254 CARBON DISULFIDE12 216 Ii i-DICHLOROETHYLENE13 214 i. 1-DICHLOROETHANE14 826 TRANS-i, a-DICHLOROETHYLENE15 811 CHLOROFORM16 818 1.2-DICHLOROETHANE17 253 2-BUTANONEIB 227 1,1.1-TRXCHLOROETHANE19 806 CARBON TETRACHLORIDE

t 2-BROMO-l-CHLOROPROPANE857 VINYL ACETATE

22 212 BROnODICHLOROMETHANE83 . a? 1» 8-DICHLOROPROPANE84 250 TRANB-i, 3-DICHLOROPROPENE89 829 TRZCHLOROETHYLENE26 803 BENZENE87 228 1, Ii a-TRICHLOROETHANE2B . 818 CIS-1, 3-DICHLOROPROPENE29 808 DIBROMOCHLOROMETHANE ;30 210 2-CHLOROETHYL VINYL ETHER31 205 BROMOFORM38 . 856 4-METHYL-2-PENTANONE33 * DXCHLOROBUTANE34 235 2-HEXANONE35 223 i, i, 2, 2-TETRACHLOROETHANE36 224 TETRACHLOROETHENE37 225 TOLUENE38 807 CHLOROBENZENE .39 219 ETHYLBENZENE4.0 851 STYRENE41 839 0-XYLENE •42 i D4-1,2-DICHLOROETHANE43 , tt. DB-TOLUENE44 « BROMOFLUOROBENZENE

NO M/E SCAN TIME REF RRT METH AREA<HOHT) AMOUNT XTO'o013091

29

NO M/E SCAN TIME REF RRT METH AREA(HCHT) AMOUNT1 130 161 B: 11 1 1. 000 A BB 19132, 20, 000 UC/L 8, 0*

K_ NOT FOUND'3 NOT FOUND4 NOT FOUND5 NOT FOUND6 84 101 5:08 1 0, 627 A BB 2512, 1. 443 UG/L 0.587 NOT FOUND •B NOT FOUND9 NOT FOUND10 NOT FOUND11 NOT FOUND12 96 £5> 7:41 i 0. 93B A BB 33597,13 65 176 8:57 1 1.093 ABB 650, 0-.76B.UC/L 0,3114 NOT FOUND15 83 2-3. 10:16 i 1, 255 A BB 318B, 0. BIO UC/L 8,3316 62 li 10:56 1 1. 335 A BB 14820, C'5.516 UC/L B. 2£**» 17 NOT FOUND ——————————*""'IB NOT FOUND19 NOT FOUND20 79 336 17:11 20 1. 000 A BB 37986, 80, 000 UG/L B. 0c21 NOT FOUND82 NOT FOUND23 NOT FOUND24 NOT FOUND,25 130 304K 15:15 i 1. 863 A BB 45904,26 78 I.8J& 15:45 1 1. 925 A BV 134582.27 ,NOT FOUND2B NOT FOUND

NOT FOUND , .NOT FOUND . . .

31 NOT FOUND32 NOT FOUND33 55 416 21:09 33 1. 000 A BB 39830, 20. 000 UG/L B, 0e34 NOT FOUND35 NOT FOUND36 164 411 20:54 i 8.553 ABB 1590. _0, ,9J3-.._C/,U. ...,0.3837 92 436 88:10 1 2.708 A BB 98875, Cil. -Hi UC/L _B.j£j-536 112 459 23:20 1 2. 851 A BB 105229. 34, BB9 uc7L la. a*39 106 496 85s 13 1 3. 081 A*BB 548, 0,201 UG/L 0. OS40 104 565 88:43 1 3. 509 A BB 514. 0, 168 UG/L 0,0741 106 588 29:53 1 3. 652 A BB 1206. 0, 549 UC/L 0.2242 65 813 10:50 1 1.383 ABB 49961, 17.657 UC/L .7,1243 100 432 21: SB 1 2. 663 A BB 96047. 19, 923 UG/L B, 0344 176 540 27:27 1 3. 354 A BB 65579, 19, 097 UG/L 7.7tf

NO RET (L) RATIO RRT <L) RATIO AMNT AMNT(L) R. FAC R, FACIL) RATIO1 8-.11 1.00 1.000 1.00 20.00 80,00 1.000 1.000 1.002 1:28 0,180 40.00 1.863J3 2:08 0.261 40.00 1.7414 8:39 0.323 40.00 1.5735 3:27 0.422 40,00 0.9086 9:11 0.99 0,634 0, 99 1.44 40.00 0.066 1.620 0.047 5:39 0,689 300, 00 0.036B 5:39 0,689 400.00 0.0479 ' 6: IB 0.770 400.00 0.131

7:04 0,863 40.00 4.446013092

NO RET(L) RATIO RRT(L) RATIO AMNT AMNT(L) R. FAC R, FAC(L) RATIO11 6:33 0, 801 40, 00 3, 471-43 7:44 0, 99 0. 944 0. 99 30.73 40. 00 0. 878 i, 143 0, 77.'3 8:57 1,00 1.093 1,00 0,77 40,00 0.017 0,885 0,0214 9:39 1.180 40,00 1,93415 10:16 1. 00 1, 255 1, 00 0,61 40.00 0. 083 4. 115 0, 0216 10:56 1. 00 1. 335 1. 00 5,52 40.00 0. 372 2, 695 0. 1417 10:50 ' 1. 323 300.00 0, 057 •IB 12:12 1.491 40.00 3.74519 12:33 1.534 40.00 2.94?.20 17:11 i. 00 1.000 1, 00 20,00 20. ,00 1. 000 1.000 1.0021 18:46 1.559 40,00 1, 08528 13:07 1.602 40.00 0, 28323 14:26 1.764 40.00 " 0/64524 14:41 .1.795 40.00 3,. 63125 15:15 1,00-,1863 1,00 82.52 40.00 1.200 2,131 0.5626 15:45 1.00 1 925 1. 00 81.35 40, 00 3. 517 6, 588 0, 5327 16:01 1.957 40.00 1.2408B 16:01 1957 40.00 1.52829 15:55 1944 40.00 1,66130 17:05 2.087 40.00 0.65631 18:33 2.267 40.00 0.90538 19:01 2.323 60.00 0.21033 81:09 1 00 1 000 1. 00 20.00 20. 00 1 000 1.000 1. 0034 20:35 .2.516 60.00 0.44135 80:54 J 2.353 40.00 1.31436 80:54 100 2.553 1.00 0.93 40.00 0, 048 1.780 0. 0837 88:10 l.'OO -2,~706 1,00 81.6B 40.00 2,384 4.767 0.5438 83:20' 1,00 2.851 1.00 84. B5 40,00 2.750 4,426 0,68

85:10 1, 00 3, 075 1. 00 0. 80 40, 00 0. 014 • 2. 856 0, 0110 88:46 1,00 3, 516 1, 00 0. 17 40. 00 0. 013 3. 194 0. 0041 89:53 1. 00 3. 652. 1. 00 0.55 40. 00 0. 032 2, 295 0. 0148 10: SO 1 00 .1 323 1. 00 17.66 20, 00 2. 611 2, 958 0, 8643 81:58 1,00 ''2,683 1,00 19.92 20.00 5.020 S. 039 1.0044 87:27 1,00 3. 354 1,00 19.10 80.00 3.428 3,590 0, 95

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Associated samples:

ji|<)«DiuM HIGHBATE KTIIAeTlB/WWAI.01 I-Z

DME ANALTBBl /- *PnCtNT MOIITWI.I

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SEMI-VOLATILE LOW LIQUIDORGANICS ANALYSIS DATA SHEET • Pige 3

Lib Name; _ Mead JtanpuChemLib Simple I.D. Mo. /9/frA M SS Q OS Q B1lnk


COMPOUND2-Fluorophinol

2,4,6-Trlbromophenol

O-Phenol — '

D5*NUrob«nzene

D.4 P-Terphenyl

2-FlIorWfjStrenyl

.. — ...

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COMPOUND LIST KS," ——— IDENTIFIER SEMMOLAT1LE5 •- LOK LEVEL LIQUID

QUANT.COMPOUND REPORT CORRECTION RESULTS OET. LIK3THUMBER COMPOUNDS_____ VALUE n FACTOR « tug/1)

441 N-NITROSODIM.THYLAMIN!:610 PHENOL473 ANILINE411 IIS(2-CHLOROETHYl)ETHERMl 2-CHLOROPHENOL421 1,3-DICHLOROBENZENE422 1,4-OICHLOROBENZENE474 BENZYL ALCOHOL420 1,2'DICHLOROBENZENE.620 2-HETHYLPHENOL412 BISI2-CKLORDISOPROPYDETHER622 4-METHYLPHENOL442 N-NITROSO-DI-N-PROPYLAM1NE436 HEXACHtOROETHANE

ISOPHORONEZ-NITROPHENOL2,4-OIMETHYLPHENOLBIS(2-CHtOROETHOXY)METHANEBEHZOi: ACID .............2,4-DICHLOROPHENOL .......1.2.4-TRICHLOROBEN2ENE ..... 3°> __ ; _ 7PNAPHTHALENE

26 475 4-CHLOROAN1LINE ............27 434 KEXACHLOROBUTA01ENE ........28 MB P HLORO -CRESOL .......... _2. __ _ *•+29 477 2-METHYLIUPTHALCN.M 435 KXACHLOROCVCLOPENTADICNE ..31 ill 2,4,6-TRICHLOMPHEIIOL.......12 126 1,4,5-TmCW.MOPHEHOL34 416; t*CW.ORONAPHTHALENE3S 479" 3-NITROANI.m36 42S D^NETMYLPHTHALATE37 402 MCNAPHTHYLCNE36 428 2,«*DINITROTOLUENE

PLEASE COMPLETE CORRECTION FACTOR CALCUUT10NS ON THIRD SHEET OF THE COMPOUND LIST! 1 1

Hf _

101010'1010201010'

•COMPOUND LIST NC. ——— IDENTIFIER SEMMOLATILE5 - LOK LEVEL LIQUID

QUANT... COMPOUND REPORT CORRECTION RESULTS CET LIKI1COUNTER NUHBEP. COMPOUNDS_____ VALUE x FACTOR "dig/I 1 (-9/11

39 478 2-NITROANIL1NE40 401 ACENAPHTHENE41 605 2,4-DINITROPHENOL42 607 4fNITROPHENOL43 476 D1BENZOFURAN44 427 2,4-OINlTROTOLUENE45 424 OlETHYLPHTKALATE46 417 4-CHLOROPHENYL PHENYL ETHER.......47 432 FLUORENE48 480 4.N1TROANIL1NE49 604 4,6-DINITRO-O-CRESOL50 443 OIPKENYLAH1NE (N-NITROSO)51 430 1,2-DIPHENYLHYDRAZINE (AZOBENZENE)53 414 4-BROHOPHENYL PHENYL ETHER .......54 433 HEXACHLOROBENZENE55 609 PENTACHLOROPKENOL56 44. PHENANTHRENE

'•'4 57 403 ANTHRACENE58 426 DI-N-BUTYLPHTHALATE59 431 FLUORANTHENE61 445 PYRENE

_ (...,.—4M .EQUINE

64- •-- 423 3,3'-DlCHLOROBENZlDINE65 405 BENZOIAIANTHRACENE66 413 llS(2-ETHYLHEm)PHTHALKTE.67 418 CHRYSENE ..................68 429 "OI-NOCTYLPHTHALATE70 407 UWOIBJFLUORANTHEHE71 409 K«0(K)FLUOWHTHENE.,............72 406 KNZOIAWRENE .........73 437 !MENO(l,2,3-C,0)PYRENt74- 419 , D1BENZO(A,H)AHTHRACENE75 408 IENZO(fi,H,I)PERYLENE ...

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1 £900.1357

••** • COMPUCHEM NO. _____ DATE ______ 3 Of 2' 'COMPOUND LIST NO. ___ '————— '—————

——— IDENTIFIER 5EMMOLAT1LE5 - LOH LEVEL LIQUID

QUANT.QUANT. REPORT

COMPOUND SURROGATE REPORT MOUNT ft" ACCEPTABLE•UMBER . COMPOUNDS VALUE SPIKED RECOVERY RANGE

619 J-FIUOROPHENDL _______r M+TTT1 fff (25-115)612 DS.PHENOL "•*•*< ?;>• tot _ 5O (is-w)W^PS-WTRMWZENE 3$ 50 4 7 (42-131)44B""2.FLUOROB1PHENYL 31-? 504 _ >T (50-154)626 TRIBROMOPHENOL J9 504 ~?d ' (47-123)*471 OIO-PYRENE 4*2. 504 sv ( HA )*496._DI«-TERPHENYL 37 504 < ?«/• (54-iiB)«

"" *FbTiKo7liory Purpoiu Only„.. ._.** t.Recavery

CORRECTION FACTOR CALCULATION;

voluffif (fil) 1000 il Dilutiontor K\ct .mi tor BU * 101, wpie txtncieo imi) * Factor * 2

/ : (nl) 1000 Hi

——- ',, OUACT REPORT AMOUNT SPIKED CONVERSION FACTOR;

———100 ul'. _____ FlMl Eitnet Vol. M) Dilutionw»unv,surrogitt MOM iun R MI Tar wia, MI for w » Fictor •

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PROCEDURE: RK DIAONOSTIC REPORT 1/30/B4 6:32:'DATA FILE: 6H0191B3C14REFERENCE: FSCC7

•in., METHOD: FSCC7 INITIALIZATION OPTION: 2 PROCESSING OPTION: 3' ' REPORT: FSCC7S1

< —— STANDARDS ——— X —— PLUS UNKNOWNS —— X - LIST NAMES - >pnoc USED POSS Rns PROC USED POSS RUB STANDARD/UNKNOWN

- 6 1 31 34 7 1 32 FBCC7S1/FSCC7U16 6 1 31 34 13 1 73 FSCC782/F8CC7U2

82 COMPOUNDS PROCESSED) 14 FOUND '.

< COMPOUND XNO LIB ENTRY1 Cl2 C23 C34 C49 C96 C67 Cl8 Cl9 Cl10 Cl11 Cl12 Cl13 Cl14 Cl19 Cl

*4 16 Cl~, 17 Cl

IB Cl19 Cl20 Cl21 Cl22 C223 C224 C229 C226 C227 C228 C229 C230 C231 C232 C233 C234 CZ39 C236 C2' 37 C338 C339 C340 C341 C342 C3

44 C349 C346 C347 C34B C3 13

9U .4 13 -tO->t IDfU31 C3 16 -1699 169B92 C3 17 -1674 167393 C3 IB -16BO 167994 C3 19 -16B9 16B499 C4 2 -1799 173B

' 96 C4 3 -1784 178397 C4 4 -1B29 182B98 C4 9 -1838 189799 C4 6 -1867 186660 C4 7 -2023 202261 C4 8 -2131 213062 C9 2 .-2181 218063 CS 3 ' •' .64 CS 4 -2364 236369 C9 9 -2472 247166 CS 6 -2460 249967 C3 -.7 -2907 290668 C9 8 -2469 246869 C9 9 -2642 264170 C6 2 -2694 269371 C6 3 -2699 269872 C6 4 -2761 276073 C6 9 -3069 306874 C6 •• 6 -3081 30BO79 C6 7 -3197 319676 C7 2 -614 613 611 -277 C7 .3 -B01 800 BOO78 C7 4 -971 970 97079 C7> 9 -1373 1372 1372BO C7 6 -1701 1700 1700Bl C7 7 -2177 2176 217662 C7 B -2232 2231 2231

B-4894979969936889983

too ,1 3 8 . . .1 9 8 . .1677 7 . . .2 4 8 . . .2 8 4 . . .266 1B2B . 11 7 8 . . .1 7 8 . . .149 2022 . 12 0 2 . . .202 2179 , 1184 •' .149 ' -. , .2 9 2 . . .2 2 8 . . .14? 2306 . 12 2 8 . . .149 2642 . 12 9 2 . . .2 9 2 . . .2 9 2 . . .2 7 6 . . .2 7 8 . . .276112 611 , J99 BOO82 970172 1372330 1699 -i212 2173 -1244 2231

013117

001302

QUANTITATION REPORT FILE: OH019183C14

DATA: QH0191B3C14.TI_ 01/30/84 3:90:00rlSAMPLE: 1UU 19163 •> 9UL IS (10910)

SUBMITTED BY: 14 ANALYST: 794

AMOUNT-AREA * REF. AUNT/(REF. AREA)* RESP. FACT)RESP. FAC. FROM LIBRARY ENTRY

NO NAME1 *D4-1,4-DICHLOROBENZENE (IS)2 441 N-NITROSODIMETHYAMINE3 610 PHENOL4 473 ANILINE - •9 411 BI8(2-CHLOROETHYL>ETHER6 601 2-CHLOROPHENOL7 421 1,3-DICHLOROBENZENE8 422 1,4-DICHLOROBENZENE9 474 BENZYL ALCOHOL10 420 1,2-DICHLOROBENZENE11 620, 2-METHYLPHENOL12 412 BIS(2-CHLOROISOPROPYL)ETHER13 622 4-HETHYLPHENOL14 442 N-NITROBQ-DI-N-PROPYLAMINE19 436 HEXACHLOROETHANE16 440 NITROBENZENE17 *460 DB-NAPHTHALENE (IS)IB 438 I80PHORONE19 606 2-NITROPHENDL

^ 20 603 2,4-DIMETHYLPHENOLW 21 410 BIS(2-CHLOROETHOXY>nETHANE

22 629 BENZQIO ACID23 602 2,4-DICHLOROPHENOL24 446 1,Z,4-TRICHLOROBENZENE29 439 NAPHTHALENE26 479 4-CHLOROANILINE27 434 HEXACHLOROBUTADIENE28 608 P-CKLORO-M-CRESOL29 477 2-METHYLNAPHTHALENE30 439 HEXACHLOROCYCLOPENTADIENE31 611 2.4,6-TRICHLOROPHENOL32 626 2.4,9-TRICHLOROPHENOL33 *D10-ACENAPHTHENE (IS)34 416 2-CH-ORONAPHTHALENE39 479 3-NITROANILINE36 429 DIMETHYLPHTHALATE37 402 ACENAPHTHYLENE38 428 2,6-DINITROTQLUENE39 47B 2-NITROANILINE40 401 ACENAPHTHENE

* 41 609 2,4-DINITROPHENOL42 607 4-NITROPHENOL43 476 DIBENZOFURAN44 427 2,4-DINITROTOLUENE49 424 DIETHYLPHTHALATE46 417 4-CHLOROPHENY.L PHENYL ETHER . 013118

28

NO NAME47 432 FLUORENE

«. 46 480 4-NITROANILINE1 49 604 4,6-DINITRO-O-CRESOL

30 443 DIPHENYLAMINE (N-NITROSO)31 430 1,2-DIPHENYLHYDRAZINE (AZOBENZENE)32 *467 D10-PHENANTHRENE (15)33 414 4-BRDMOPHENYL PHENYL ETHER31 433 HEXACHLOROBENZENE33 609 PENTACHLOROPHENOL36 444 PHENANTHRENE '37 403 ANTHRACENE38 426 DI-N-BUTYLPHTHALATE39 431 FLUORANTHENE - •60 «499 D12-CHRYBENE (IS)61 443 PYRENE62 404 BENZIDENE63 413 BUTYLBENZYLPHTHALATE64 423 3,3'-DICHLOROBENZIDINE63 403 BENZOtA)ANTHRACENE66 413 BIS(2-ETHYLHEXYL)PHTHALATE67 41B CHRYSENE6B 429 DI-N-OCTYLPHTHALATE69 *D12-BENZO(A)PYRENE (IB)70 407 BENZO(B)FLUORANTKENE71 409 BENZO(K)FLUORANTHENE72 406 BENZO(A>PYRENE73 437 INDENO(1,2,3-C,D)PYRENE74 419 DIBENZO(A,H)ANTHRACENE

^73 408 BENZO(0,H, DPERYLENE"• 76 619 2-FLUOROPHENOL (SURROGATE)

7 7 D3-PHENOL (SURROGATE) . . . . .78 447 03-NITROBENZENE (SURROGATE)79 448 2-FLUOROBIPHENYL (SURROGATE)80 TRIBROMOPHENOL (SURROGATE)81 D10-PYRENE (SURROGATE)82 D14-TERPHENYL (SURROGATE)

NO M/E SCAN TIME REF RRT METH AREA(HGHT) AMOUNT XTOT1 190 846 10:34 1 1.000 ABB 33001, 40.000 NG2 NOT FOUND3 94 802 10:01 1 0,948 A BB 23273. 2V. 302 NO4 NOT FOUND3 93 812 10:09 1 0.960 A BB 470.6 126 611 10:08 1 0.939 ABB 27876.7 NOT FOUND8 146 849 10:37 1 1.004 ABB 28151. .3?-4A--HO _. 3.429 NOT FOUND10 NOT FOUND11 NOT FOUND

' 12 NOT FOUND >13 NOT FOUND14 130 933 11:99 1 1.126 ABB 16419. m» «M M° 14.9019 NOT FOUND16 NOT FOUND17 136 1118 13:96 17 1.000 ABB 79346. 40.000 NO 3.66

j IB NOT FOUND .

013119L to r?j1lJp if * * •*' -r JJ u tit,I

NO M/E SCAN TIME REF RRT METH AREA(HOHT) AMOUNT 5CTQT19 NOT FOUND20 NOT FOUND21 NOT FOUND22 NOT FOUND23 NOT FOUND24 ISO 1111 13:33 17 0.994 ABB 21091. 38.712 N8 3.3429 NOT FOUND — ""26 NOT FOUND27 NOT FOUND28 107 1264-19:48 17 1.131 ABB 26422. 41, 918 NO 3.8029 NOT FOUND ~30 NOT FOUND31 NOT FOUND - -32 NOT FOUND33 164 1917 18:38 33 1.000 ABB 39883. 40. 000 NO 3.6634 NOT FOUND39 NOT FOUND36 NOT FOUND37 NOT FOUND38 NOT FOUND39 NOT FOUND40 194 1924 19: 03 33 1. 009 A BB 34268. 39,091 NO 3. 9741 NOT FOUND /•-42 109 1970 19:37 33 1,039 A BV 17267. ?7 "a* Hg 8, 9jj43 NOT FOUND44 169 1980 19! 49 33 1. 042 A BB 12910. 32.080 NO 2. 9349 NOT FOUND46 NOT FOUND47 NOT FOUND46 NOT FOUND49 NOT FOUND90 NOT FOUND91 NOT FOUND32 18B 1831 23: 08 92 1. 000 A BB 37489. 40, 000 NO 3. 6693 NOT FOUND94 NOT FOUND99 266 1626 22: 91 92 0, 968 A BB 4287. J4. 207 NO 2. 2296 NOT FOUND ""97 NOT FOUND : ; .98 149 2022 29: 16 92 1. 092 A BB 63240. 21* 393 NO 2. 6999 NOT FOUND - .60 240 2461 30: 46 60 1. 000 A BB 32199. 40. 000 NG • 3. 6661 202 2179 27: 14 60 0. 8B9 A BB 60399. 40, 899 NG 3. 7462 NOT FOUND : • ;63 NOT FOUND64 NOT FOUND ' •69 NOT FOUND66 149 2906 31:19 60 1.018 A VB 997. 0.841NG 0.0867 NOT FOUND68 149 2642 33: 01 60 1. 074 A BB 1769. 0. 998 NO 0. 0969 264 2794 34: 29 69 1. 000 A BB 28998. 40, 000 NG 3. 66.70. NOT FOUND • . .71 NOT FOUND72 NOT FOUND73 NOT FOUND

013120

NO M/E SCAN TIME REF RRT METH AREA(HGHT) AMOUNT XTOT79 NOT FOUND

j-» 76 112 611 7:38 1 0,722 ABB 1B6B6, 32. 969 NG 2.98r ' 77 99 BOO 10:00 17 0.716 A BV 21960. 24.809 NG 2.27

7B B2 970 12:07 17 0.968 A BB 29420. 34.922 NG 3.2079 172 1372 17:09 17 1.227 ABB 42216, 32. 136 NO 2.9480 330 1699 21:14 33 1.120 ABB 4398. 39.004 NO 3.2081 212 2173 27:11 60 0. BB4 A BV 33328. 42.302 NO 3.8782 244 2231 27:33 32 1.209 A BV 33B44. 37, 117 NO 3.40

NO RET(L> RATIO RRT(L> RATIO AMNT AMNT(L) R. FAC R, FAC(L) RATIO'1 10:33 1.00 1.000 1.00 40.00 40.00 1.000 1.000 1.002 4:22 0,412 30.00 0.9003 10:02 1.00 0,948 1.00 29.30 90.00 0.978 -0.966 0,994 9:99 .0,937 90.00 0.9939 10:10 1.00 0.960 1.00 0.91 90.00 0.011 1.049 0.016 10:09 1.00 0,999 t. 00 43.96 90.00 0.637 0.731 0.877 10:29 0.991 90.00 0.7898 10:38 1.00 1.003 1.00 37.42 90.00 0.643 0, B60 0.799 11:07 1.090 90.00 0.40210 11:06 .048 90.00 0.79911 11:31 .089 90.00 0.94812 11:33 ,091 90.00 0.23913 11:99 7126 90.00 0.62414 11:93 1.00 .123 1,00 198.43 90.00 0.379 0.118 3.1719 11:92 . . .122 90.00 0.40116 12: It ' ' .191 90.00 0.39817 13:99 1,00 .000 1.00 40.00 40.00 1,000 1.000 1.00IB 12:91 0.919 • 90.00 0.663

.** 19 13:03 0.933 , 90.00 0. 174• 20 13:19 0.992 , ' 90,00 0.414

21 13:34' 0.971 90.00 0.46122 13:99 1,000 290,00 0. 10823 13:42 , 0.979 90.00 0.24824 13:99 1.00 "0.999 1,00 38.71 90.00 0.224 0.289 0.7729 14:0226 .14:22•27 14 3728 19:49 1.0029 19:9930 16:4031 16:99

004 90,00 1, 190027 249,99 " 0. 146043 90,00 0, 143130 1.00 41.92 90,00 0.261 0.336 0.63143 90.00 0.263191 90.00 0. 124

. .• 210 90.00 0. 19332 17:01 ; 11.217 249.99 0.14933 18:96 1.00 f. 000 1.00 40.00 40.00 1.000 1.000 1.0034 17:20 0.914 90.00 1.07039 17:91 0.941 249.99 0.36136 18:33 0.978 90,00 1.23437 18:31 0.976 90.00 1.11038 18:42 0.986 90.00 0.29939 19:0040 19:04 1.0041 19:1942 19:39 1.0043 19:31

001 249.99 0.036003 1.00 39.09 90.00 0.687 0. B80 0.780-B 249.99 0. 124036 1.00 97.33 129.00 0. 139 0, 178 0.78029 90.00 1.424

44 19:46 1.00 1,042 1.00 32.02 90.00 0.291 0.392 0,6449 20:37 1.086 90 00

20:37 • 1.086 90.00

29

47 20:3148 20:4449 20:9990 21:0091 21:0492 23:09 1.00

081 90.00 1.017093 249.99 0.033103 249.99 0. 191107 90.00 0.390110 90.00 1.711000 1.00 40.00 40.00 1.000 1.000 1.00

93 21:99 0,990 90.00 0.16994 22:18 0.963 90.00 0.22299 22:92 1..00 0,988' 1.00 24,21 90.00 0.060 0.123 0.48.96 23:13 * 1,003 90.00 1.17897 23:20 1,008 90.00 0.998'98 29:17 1.00 1.092 1.00 29.39 90.00 0.680 1.497 0.9999 26:38 1.131 30.00 ... .1.19160 30:48 1.00 1.000 1.00 40.00 40.00 ,1.000 J. 000 1.0061 27:16 1.00 0.883 1.00 40,86 30.00 1.909 ' 1.841 0.8262 30:01 0.908 90.00 0.01063 29:33 0.939 90.00 1.04064 30:94 1.003 90.00 0.04369 30:49 0,998 90.00 1.40966 31:20 1.0067 30:9268 33:01 1.0069 34:27 1.00

017 1.00 0.84 90.00 0.029 1.473 0,02002 90.00 1. 179072 1,00 1.00 90.00 0.044 2.197 0,02000 1.00 40.00 40,00 1.000 1.000 1.00

70 33:40 . 0.978 90.00 1.46071 33:44 0,979 90,00 0.90972 34:31 ,002 90.00 1.13173 36:22 .114 90.00 0.64974 38:31 .118 90.00 0.93979 39:28 ,149 90.00 0.61776 7:4077 10:0178 12:0879 17:1080 21:1681 27:13 1.00 0,884 1.00 42.30 90.00 1.330 1.972 0,8382 27:94 1,00 1.209 1.00 37.12 90,00 0.471 0.634 0,74

00 0,729 l.O'O 32.. 97 90,00 0.427 0.696 '0,6900 0.716 1.00 24. Bl 90.00 ' 0.229 0.461 0.9000 0.868 1,00 34.92 90.00 0.312 0.447 0.7000 1,227 1.00 32.14 90.00 0.448 0.697 0.6400 1. >21 1.00 39.00 90.00 0.087 0. 129 0,70

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SEMI-VOLATILE LOW LIQUIDORGANIC* ANALYSIS DATA SHEET • Pige 3

Lib Nime! Head CompuChemLab Simile I.P. No. /?/# < Q SS RJDS


COMPOUND

2-F1uoropheno1

2,4,6-Trlbromophenol

D-Phenol

OS-Nitrobenzene

Dj4 P-Terphenyl

2-Fluoroblphenyl

t

FRACTION

SEMIVOA

SEMIVOA

SEMIVOA

SEMIVOA

SEMIVOA

SEMIVOA

CONC ( ug/l)

$14

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3,ir

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7*70

(Surrogates only)Spike

Added (jg/1)

100

100

100

100

100

100

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013143

U.S. ENHROV5N7A1. PROTECTION ADEN:*-!.' Souplt Mo'igi-4't OK IceP.O. B:» 6ie, Altmnorli, VA 22J1! - T03/H7-J495

f*^ ORGANIC! ANA'.TSIS DATA SHEET

il&critory NliWI Mm Cir.guih*- Cm.IS Sirvlt ID Na.r | <?!<?-* R OC Riport No.:

trlK; Lloule________________ Contnct No.:Dito Rtlini MhcrliiS By! ,____________ Pcti Simplt flictl»«8!Assodited samples:

CONCCNTTIATION: (UyKDIW HIBH Ulrcji oni)PATE EXTRACTED/PREPARED! 3-3.{

PATE ANALTZEBl Ji -21PERCENT HOISTUHEI

Multiply Oittetlon llmlti ty 1 Qor 10 Fl"" ITf *^(Cnick Bo« lor Approprliti Fitter)

JM_ CAS« . orubiig fit CAi« or ugAj(clrclt DM) (clrctt on»)

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luwuin.n fiu. _____ urn.COMPOUND LIST NO.

, ——— IDENTIFIER SEMMOLAT1LES - LOK1 LEVEL L10U

QUANT.-_. COMPOUND REPORT CORRECTION RESULTS OET. LIMIT('' COUHTER NUMBER COHPOUNOS_____ VALUE, X FACTOR • (ug/1) (uo/11

2 441 N-NITROSODIMETHYLAMINE3 610 PHENOL4 473 ANILINE5 411 BISI2-CHLOROETHYDETHER6 601 2-CHLOROPHENOL7 421 1,3-DICHLOROBENZENEB 422 1,4-DICHLOROBENZENE ........ Jo.9 474 -BENZYL ALCOHOL .............10 420 1,2-DICHLOROBENZENE.........11 620 2-METHYLPHENOL ............12 412 BISI2-CHLOROISOPROPYDETHER13 622 4-METHYLPHENOL ............14 442 N*NITROSO*D1*N-PROPYLAM1NE15 436 HEXACHLOROETHANE ..........16 440 NITROBENZENE ..............18 438 1SOPHORONE ................. So.19 .606 2-NITROPHENOL .............

• 20 603 2,4*DIMETHYLPHENOL ........21 ' 410 ' BIS(2-CHLOROETHOXY)M'ETHANE22 625 BENZOIC ACID ..............23 602 2,4*DICHLOROPHENOL ........

...——M_._. 445 1,2,4-TRICHLOROBENZENE ..... -H25 _ 439 NAPHTHALENE .............."26""" 475 4-CHLOROANILINE ..........27 434 HEXACHLOROBUTADIENE ......26 603 P-CHLORO-M-CRESOL ........29 477 2-NETHYLNAPTHALENE .,..,..30 435 KEXACHLOROCYCLOPENTADIEHE31 611 2,4,6-TRICHLOROPHENOL,,...32 626 2,4,5-TRlCHLOROPHENOL ....34 416. 2-CKLORONAPHTHALENE ......35 479 3-NITROANILINE ...........36 425 DIMETHYLPHTHALATE ........37 402 ACENAPHTHYLENE ...........38 428 2>D1N1TROTOLUENE .......

10.

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1010101010

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10'</o. 20:

10 j10:

______ -10'20

2010010!

q... 10...10501020201010100»l100

10——(U31<52

PLEASE COMPLETE CORRECTION FACTOR CALCULATIONS ON THIRD SHEET OF THE COMPOUND LIST!!!

CCWUCHEM NO.•COMPOUND LIST NO. ___— IDENTIFIER SEMl-VOLATlLES ** LOK1 LEVEL LIQUID

QUANT.• COMPOUND REPORT CORRECTION RESULTS DET LIMIT

PUNTER NUMBER COMPOUNDS_____ VALUE x FACTOR ' "' ' "'

39 478 2-NITROAN1LINE ...................40 401 ACENAPHTHENE .....................41 605 2,4-DINlTROPHENOL ................42 607 4-NITROPHENOL ....................43 476 D1BENZOFURAN .,,.......,...,....,.44 427 2,4-DINITROTOLUENE,,.......,..,,..45 424 DIETHYLPHTHALATE ...,.,,.,....,..

., 4(1 _._4n 4-CHLOROPHENYL PHENYL ETHER.......47 —432 FLUORENE .........................4B 480 4-NITROAN1L1NE ........,......,,.,49 -604 4,6-DINITRO-O-CRESOL .,.,,,,,..,..SO 443 01PHENYLAMINE (N-NITROSO) .......

__ 51 _...430 1,2-DIPHENYLHYDRAZlNE (AZOBENZENE)- - 53 --414 • 4-BROMOPHENYL PHENYL ETHER ...,,,,_.. ..54 ....43.3 HEXACHLOROBENZENE ................

55 609 PENTACHLOROPHENOL .,..........,,,,56 -—444 PHENANIHBEJIE ,,,..,..............,

..'.. ' 57 -- 403 ANTHRACENE',,,.................,..,.....58 ....426 DI-N-BUTYLPHTHALATE ..............

59 .—43V. FLUORANTHENE .....................„. ei —445- PYRENE ...........................———(2 —404- BENZIDINE ........................———63 ——4K- BUTYLBENZYLPHTHALATE ...........

64 —423- 3,;3'.DICHLOROBEN2IDINE ...........65 405 BENZOIA)ANTHRACENE ..............66 413 BISIZ-ETHYLHEXYDPHTHALATE........67 418 CHRYSENE .........................68 429 DI-N-OCTYLPHTHALATE ..............70 407 BEN*0(B)FLUORANTHENE .............71 409 BENZO(K)FLUORANTHENE,.............

• 72 406 IE«0(A)PYRENE ...................73 437 I«IENO(1,2,3.C,D)PYRENE ..........

—-74 —419- DIBEHZO(A,H)AHTHRACENE ...........75 408 IEHZO|6,H,I)PERYLENE .............

j(See uleulitlont in. lurrogites on b*ck)

013153

COMPUCHEM NO. J9lM/l DATE ______ 3 of 2COMPOUND LIST NO. ___

——— IDENTIFIER 5EM1-VOLATILES - LOK LEVEL LIQUID

QUANT.QUANT. REPORT

COMPOUND SURROGATE REPORT AMOUNT . t tt ACCEPTABLENUMBER L COMPOUNDS VALUE SPIKED RECOVERY RANGE

619 2-FLUOROPHENOL 3 Z- 504r"Tl £4. (25-115)ci2 DS-PHENOL /? so* _ ?/*-• lis-90 )447 DS-HITROBENZENE ?/ KM <Tg (42*131)448 2-FUIOROBIPHENYL ______ ______ I ~7$ 150-154)628 TRIBROMOPHENOL ? " 80 t 7 (47-123)*471 DIQ-PYRENE TI _______ t09 i HA i*496 DJ4-TERPHENYL 3ej 50 * • 7 (54*118)*

•For Advisory Purposes Only" t Ricovery • Qgnt Rtport Vilue

yllAlll RE|JUI I HIIUUIIL J(JH(U * 1UU«

i...') , ~ •

• CORRECTION FACTOR CALCULATION!

F1n»1 tKtrictlen vc1u-ie(i"1) 1000 nil Dilution_ "iim Tor KK'. .mi 'for'UN * TOI, iimpit txtnctea mi) * Fictor * 2 »

(ml) . 1000 mlTXmT * _? W) » ____ x 2

OUAKT REPORT AMOUNT SPIKED CONVERSION FACTOR;

100 uV______ F1n.UKtr.et Vol. (irt) DilutionMouni surrogate waea lull * wi for MIO, ui ror IN n Fictor

100 ul ___ f ' W)i

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COMC1 °13153

PROCEDURE: RK DIAGNOSTIC REPORT 2/22/84 3:23:81OATA FIL_: CR0191B4C20REFERENCE: FSCC7

TrlOD; FSCC7 INITIALIZATION OPTION: 2 PROCESSING OPTION! 3riEPORTs FSCC7S1

< —— STANDARDS ——— >< —— PLUS UNKNOWNS —— X - LIST NAMES - >PROC USED POSS RMS PROC USED POSS RMS STANDARD/UNKNOWN

4 4 i 38 3 2 - 2 1 SB FBCC781/FSCC7U12 2 1 0 30 9 i US FSCC7S2/FSCC7U2

< COMPOUND X ———————— SEARCH ———————— X SAT X ~——r CHRO ————— >NO LIB ENTRY REF PRED 8EL DELTA PEAKS FIT PEAKS M/E TOP DELTA PEAKSi Cl i -602 602 602 . 1 9B3 199 6*02 . 12 C2 1 -768 768 768 . 1 980 136 768 . 13 C3 1 -1913 1913 1913 . 1 996 164 1013 . 14 C4 1 -1217 1218 1218 . 1 988 188 1218 . 1S C l 2 -293 2 9 1 . . . . . 7 4 . . .6 Cl 3 -569 568 568 . 1 .993 . 94 568 . A.7 C l 4 -569 5 6 8 , , . . . 9 3 . . .B Cl 5 -577 576 . . . 93 579 19 Cl 6 -581 580 579 -1 1 991 . 128 579 . 110 Cl 7 -598 597 . , , 14611 Cl B -604 603 . . . . , 146 603 . .112 Cl 9 -626-- 625 . . . . . 108 . . ,1 3 C l 1 0 -627- 6 2 6 . . . . . 1 4 6 . . .14 Cl 11 -644 643 . . . 10815 Cl 12 -648 647 . . . .' , 121,1'..)C1 13 -662- 661 . . . . • . , . 10817 Cl 14 -664. ,663 663 , . , 1 996 . 130 '663 .1I B C l 1 5 -66fc 6 6 5 . . . . . 1 1 7 . . .19 Cl 16 -680 679 . . . . 12320 C2 2 -678 677 , . . . 62 677 321 C2 3 -721 720 . . , 13922 C2 4 -730 729 , . , . 1222 3 C 2 5 -744 7 4 3 . . . . . 9 3 . . .24 C2 6 -757 757 . . , 10525 C2 7 -753 753 . , . 16226 C2 8 -764 764 763 -1 1 997 . 180 763 . 127 C2 9 -772 772 . . . . 12828 C2 10 -785 785 , . . . . 127 ...29 C2 11 -797 797 . . , . 22530 C2 12 -852 B52 852 . 1 998 , 107 852 . .t3 1 C 2 1 3 -866 8 6 6 . . . . . 1 1 5 . . .3 2 C 2 1 4 -898 B 9 8 . . . . . 2 3 7 . . .3 3 C 2 1 5 -914 9 1 4 , . . . . 1 9 6 . . .34 C2 16 -914 914 . . . 19635 C3 2 -933 933 , , . 16236 ,C3 3 -95S 955 . . . . . 138 .37 C3 4 -986 986 . . . . . 163 . . .SB C3 5 -99.1 991 , . . . . 15239 C3 6 -'995 995 , . . 16540 C3 7 -1014 1014 . . . , , 138 . . .41 C3 B -1017 1017 1018 1 1 993 , 154 1018 . _A-4£ .03 9 -1027 4-B27 . . , , , 184 Ql3l5l74_WC3 10 -1Q38 1039 1038 -1 1 994 . 109 1038 . 14 4 C 3 1 1 -1040 1041 . . . . . 1 6 8 . . .45 C3 12 -1048 1049 1049 , 1 988 165 1048 -1 146 C3 13 -1086 1087 149 1085 , t47 C3 14 -1090 1091 . , . *g P01 *-*'** • - ' .48 C3 15-1088 1089 . . . *8 / 166'

" B 0 C 3 1 7 -1105 1106 . . . .5 1 C 3 I B -1108 1109 . . . .8 2 C 3 1 9 -1112 1113 . . . .53 CS 1 -1591 1592 1592 . 1 83354 C6 1 -1833 1833 1833 . 1 907

C 4 2 -1157 1159 . . . .C 4 3 -1175 1177 . . . .

51 C4 4 -1201 1203 1202 -1 i 987S B C 4 5 -1220 1222 . . . .5 9 C 4 6 -1227 1229 . . . .60 C4 7 -1313 1314 .61 C4 8 -1388 1389 .62 C5 2 -1419 1420 1420 . 1 9976 3 C S 3 -139- 1391 . . . .64 CS 4 -1521 1522 .65 CS 5 -1589 1589 .6 6 C S 6 -15B9 1589 . . . .6 7 C S 7 -1606 1606 . . . .6 B C S B -1595 1595 . . . .6 9 C S 9 -1702 1702 . . . .7 0 C 6 2 -1768 1768 . . . .7 1 C 6 3 -1773 1773 . . . .7 2 C 6 4 -1839 1838 . . . .7 3 C 6 5 -2177 2175 . . . .74 C6 6 -2190 21B8 . , . ,7 5 C 6 7 -2278 2276 . . . .7 6 C 7 2 -456 4 6 0 . . . .77 C7 3 -568 572 574 2 1 53678 C7 4 -678 682 , ...79 C7 5 -921 924 922 -2 1 987BO C7 6 -1124 1126 1125 -1 1 981Bl C7 7 -1417 1418 1418 . 1 9386» C7 B -1445 1446 1446 , 1 9BB

1 9 8 . . .169 '.7 7 . . .240 .1592 , 1264 1832 -1 12 4 8 , , ,2 8 4 . . .266 1202 , 11 7 8 . . .1 7 8 . . .149 1313 . 12 0 2 , , .202 1420 . 1184 /'149 . ' .2 5 2 . . .228 • .149 1603 . 8228 .149 1703 . 12 5 2 . . .2 5 2 , , ,2 5 2 . . .2 7 6 . . .2 7 8 . . .2 7 6 , , ,1 1 2 . . .9 9 . . .62172 921 -1 i330 1124 -1 i212 1418 , 1244 1446 , 1

013153

QUANTITATION REPORT FILE: GR0191B4C20

DATA: GR019184C20, TIOaf-i2/B4 4:13: 00siL'LEi 1UL 19184 + 5UL IS (11081)SUBMITTED BY' 20 ANALYST: 754

AMOUNT-AREA * REF. AMNT/(REF, AREA)* RESP. FACT)RESP, FAC. FROM LIBRARY ENTRY

NO NAME1 «D4-1,4-DICHLtfROBENZENE (IS)2 441 N-NITROSODIMETHYAMINE3 610 PHENOL4 473 ANILINE5 411 BIB(2-CHLOROETHYL)ETHER6 601 2-CHLOROPHENOL7 421 1,3-DICHLOROBENZENE8 422 1,4-DICHLOROBENZENE9 474 BENZYL ALCOHOL10 420 1,2-DICHLOROBENZENE11 620 2-METHYLPHENOL12 412 BIB(2-CHLOROI80PROPYL)ETHER13 622 4-METHYLPHENOL14 442 N-NITROBO-DI-N-PROPYLAMINE15 436 HEXACHLOROETHANE16 440 NITROBENZENE17 «460 DB-NAPHTHALENE (IS)IB 438 I80PHORONE19 .606 2-NITROPHENOL

603 2,4-DIMETHYLPHENOL410•BIS(2-CHLOROETHOXY)METHANE

22 625 BENZOIC ACID23 602 2i 4-DICHLOROPHENOL24 446 1. 2, 4-TRICHLOROBENZENE25 439 NAPHTHALENE26 475 4-CHLOROANILINE27 434 HEXACHLOROBUTADIENE28 608 P-CHLORO-M-CRE80L29 477 2-METHYLNAPHTHALENE30 435 HEXACHLOROCYCLOPENTADIENE31 611 2,4,6-TRICHLOROPHENOL32 626 2, 4, 5-TRICHLOROPHENOL33 *D10-ACENAPHTHENE (IS)34 416 2-CHLORONAPHTHALENE35 479 3-NITROANILINE36 425 D1METHYLPHTHALATE37 402 ACENAPHTHYLENESB 428 2,6-DINITROTOLUENE39 478 2-NITROANILINE40 .401 ACENAPHTHENE41 60S 2,4-DINITROPHENOL42 607 4-NJCTROPHENOL43 476 QIBENZOFURAN44 427 2,4-DINITROTOLUENE '45 424 DIETHYLPHTHALATE4'= 417 4-CHLOROPHENYL PHENYL ETHER

2a

NO NAME47 432 FLUORENE

480 4-NITROANILINE604 4, 6-DINITRO-O-CRESOL

50 443 DIPHENYLAMINE (N-NITROSO)51 430 1, 2-DIPHENYLHYDRAZINE (AZOBENZENE)52 t467 D10-PHENANTHRENE (IS)53 414 4-BROMOPHENYL PHENYL ETHER54 433 HEXACHLOROBENZENE55 609 PENTACHLOROPHENOL56 444 PHENANTHRENE57 403 ANTHRACENE58 426 DI-N-BUTYLPHTHALATE59 431 FLUORANTHENE •- •60 »459 D12-CHRYSENE (IS)61 445 PYRENE62 404 BENZIDENE63 415 BUTYLBENZYLPHTHALATE64 423 3,3'-DICHLOROBENZIDINE65 405 BENZO(A)ANTHRACENE66 413 BISI2-ETHYLHEXYDPHTHALATE67 418 CHRYSENE68 429 DI-N-OCTYLPHTHALATE69 *D12-BENZO(A)PYRENE (IS)70 407 BENZO(B)FLUORANTHENE71 409 BENZO(K)FLUORANTHENE72 406 BENZO(A)PYRENE73 437 XNDENO (1. 2, 3-C, D) PYRENE74 419 _!BENZO<A, H)ANTHRACENE7".,. 408 BENZOtG, H, DPERYLENEf.>,J 619 2-FLUOROPHENOL (SURROGATE)77 D5-PHENOL (SURROGATE) . "78 447 OS-NITROBENZENE (SURROGATE)79 448 2-FLUOROBIPHENYL (SURROGATE)80 TRIBROMOPHENOL (SURROGATE)Bl D10-PYRENE (SURROGATE)82 D14-TERPHENYL (SURROGATE)

NO M/E SCAN TIME REF RRT METH AREA(HGHT) AMOUNT %TOT1 150 602 7:31 11.000 A 88 42654. 40. 000 NC 3, 812 NOT FOUND3 94 568 7:06 1 0.944 A BV 19841.4 NOT FOUND5 93 579 7:14 1 0.962 ABB 1020.6 128 579 7:14 1 0.962 A BV 43532.7 NOT FOUNDB 146 603 7:32 1 1.002 A BB 23900.9 NOT FOUND10 NOT FOUND11 NOT FOUND12 NOT FOUND13 NOT FOUND14 130 663 B: 17 1 1. 101 A BB 1877S.15 NOT FOUND16 NOT FOUND17 136 768 9:36 17 1.000 A BB 71B61,

82 677 8:28- 17 0.882 A«BB ' 31392,

NO M/E SCAN TIME REF RRT METH AREA(HCHT) AMOUNT %TOT19 NOT FOUND2f*«|NOT FOUND21 NOT FOUND22 NOT FOUND23 NOT FOUND24 180 763 9:32 17 0, 993 A BB 17139. (jj§I_2_l_NG_ 2. 7625 NOT FOUND26 NOT FOUND27 NOT FOUND28 107 852 101-39 17 1. 109 A BV 30723, C43.J3B N(T) • 4,, 1229 NOT FOUND30 NOT FOUND31 NOT FOUND32 NOT FOUND33 164 1013 12:40 33 1. 000 A BB 33365. 40.000 NG 3, 8134 NOT FOUND35 NOT FOUND36 NOT FOUND37 NOT FOUND38 NOT FOUND39 NOT FOUND40 154 1018 12:43 33 1, 005 A BB 36442.41 NOT FOUND42 109 1038 12: SB 33 1. 025 A BV 26176.43 NOT FOUND ' , _44 165 1048 13:06 33 1. 035 A BB 13470. L 37. 932 N45 149 1085 13:34 33 1. 071 A 88 499. 0.352 N46 NOT FOUND4QNOT FOUND4B NOT FOUND49 NOT FOUNDSO NOT FOUND51 NOT FOUND52 188 1218 15:13 52 1. 000 A BV 54610. 40. 000 NG 3. 81S3 • NOT FOUND54 NOT FOUND .,———_——..55 266 1202 15:01 52 0, 987. A BB 7165, C25-eB4 NC> 2-56 NOT FOUND • —————~~57 NOT FOUND58 149 1313 16:25 52 1. 078 A BV 42796.59 NOT FOUND60 240 1592 19:54 60 1000 A BV 31814, 40. OOP NC61 202 1420 17:45 60 0.892 A BV 67978. f_4. 647 NG62 NOT FOUND W-—————'63 NOT FOUND64 NOT FOUND65 NOT FOUND66 149 1603 20:02 60 1, 007 A*VB 4179. 3.998 NC 0. 3867 NOT FOUND6B 149 1703 21:17 60 1.070 A BV 6638, 3, 954 NG 0.3869 264 1832 22:54 69 1. 000 A VB 30039, 40. 000 NG 3. 8170 NOT FOUND71 NOT FOUND72 NOT FOUND7? .NOT FOUND7WNOT FOUND

013161

NO M/E SCAN TIME REF RRT METH AREA(HCHT) AMOUNT XTOT75 NOT FOUND /

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NO RET(L) RATIO RRT(L) RATIO AMNT AMNT(L) R, FAC R, FAC(L) RATIO1 7:31 1 00 1000 1, 00 40,00 40, 00 1000 1, 000 1 002 3:40 0,487 50,00 0.9803 7:07 1.00 0.945 1,00 19,16 50.00 0.372 "0.971 0.384 7:07 0.945 50.00 0.77BT5 7:13 100 0.958 1.00 1,26 SO, 00 0,019 0.760 0.036 7:16 100 0.965 100 54,61 50, 00 0.854 0.782 1 097 7:28 0.993 50, 00 0.626B 7:33 1.00 1003 100 29,83 50, 00 0.448 0.751 0.609 7:49 1040 50, 00 0.34810 7:50 1042 50, 00 0.59711 8:03 1070 50, 00 0.59512 8:06 1076 50,00 0.21113 8:16 1100 50,00 0.59114 8:18 100 1103 1,00 154,56 50,00 0.352 0.114 3.0915 8:19 1106 50,00 0.44616 8:30 1.130 50,00 0.26117 9:36 1.00 1000 100 40,00 40,00 1000 1000 10018 8:28 1.00 0.883 1.00 29,67 50.00 0.349 0.589 0.59V) 9:01 0.939 . 50,00 . 0.199 .2t> 9:07 ' 0.951 . 50,00, 0.27921 9:18 0,969 " 50,00 0.44322 9:28 0.986 250,00 0.11623 9:25 0.960 50.00 0.34824 9:33 1 00 0.995 100 28,91 50,00 0.191 0.330 0.5825 9:39 1005 50.00 125726 9:49 1022 249,99 0,48627 9:58 ' 1-038 50,00 0.21328 10:39 100 1109 100 43.24 50,00 0,342 0.396 0. 6629 10:49 1128 50,00 0.33730 11:13 1169 50,00 0.20831 11:25 1190 300,00 0.15232 11:25 1190 300, 00 0,15233 12:40 1 00 1000 100 40,00 40, 00 1000 1000 10034 11:40 0.921 50.00 1.17935 11:56 0.943 249.99 0.47536 12:19 0.973 50.00 140437 12:23 0.978 50.00 1.6263B 12:26 0.982 SO. 00 0.28639.12:40 1.001 249.99 0.39540 12:43 100*1004 100 41,22 50.00 0.873 1059 0.8241 12:50 1.014 249,99 0.14942 12:58 100 1025 1.00 100,01 125,00 0,251 0,314 0.8043 13:00 1027 50,00 1.65144 13:06 100 1035 1.00 37,93 '50,00 0,323 0.425 0.764? 13:34 100 1072 1.00 0,35 50.00 0.012 1.696 0.014l_y>13:37 1.076 50,00 0.551 Q13JB2

29

47 13:36 1 074 50, 00 1. 1694B~.13:46 1087 249.99 0,3534' 13:49 1091 249,99 0,21650 13:51 1094 50,00 0, 77851 13:54 1,098 50.00 150152 15:13 1 00 1000 1 00 40, 00 40, 00 1 000 1 000 1 0053 14:28 0,951 50.00 0,23654 14:41 0.965 50.00 0. 30255 15:01 1 00 0.987 1 00 25, BB 50, 00 0, 105 0, 203 .0, 5256 15:15 £.002 50.00 1.085 •.57 15:20 1.008 50.00 0.970SB 16:25 1. 00 1079 100 IB, 79 50. 00 0, 627 1 668 0. 3859 17:21 1.141 50.00 "I 24760 19:53 1, 00 1000 100 40, 00 40. 00 1, 000 1 000- 1 0061 17:44 1,00 0.892 1.00 54,65 50.00 1,709 1564 10962 19:53 1,000 50.00 0.01063 19:01 0,956 50.00 0.90064 19:52 0,999 50.00 0.43565 19:52 0.999 50,00 150266 20:04 i, 00 1009 100 4. 00 50,00 0, 105 1 314 0, 0867 19:56 1.003 50.00 109868 21:16 1.00 1070 100 3,95 50.00 0.167 2,111 0.0869 22:55 100 1000 100 40, 00 40.00 1,000 1000 10070 22:06 0,965 50.00 136671 22:10 0.967 50.00 0. B6172 22:59 1.003 50.00 102173 27:13 1188 50.00 0.79374 27:22 1.195 • 50,00 0.6307r ,28:28 • 1243 • 50,00 0.677 •7.••' 5:42 0...757 , 50.00 0.591 ,77 7:06 • 0.740 50,00 0.49678 8:28 0.683 50,00 0,51779 11:31 1, 00 1199 100 35, 00 50.00 0, 484 0, 691 0, 7080 14:03 1,00 1110 1,00 36, ,26 50,00 0,210 0.289 0,73Bl 17:43 1 00 0.891 100 51 16 50.00 1,475 1441 10262 18:04 100 1187 100 38.92 50.00 0,681 0.875 0,78

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WOMICS ANALYSIS DATA SHEET

Cut NuniMT i?333»Li* Sinpl. ID NBI "" '<W4_r 5C Rt»or1 HoSwplf MitrlM Lloulii ______________ Contrirt No.; £>t'Q[~67fo&'Dm niliui Auttiorlirt By! _____________ Bit* impli Rtstlyidi

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PESTICIDE LOS LIQ::DDRUNKS ANALYSIS DATA SHEET - Page 3

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COMPOUND LIST - NO. ____

COMPUCHEMCOMPOUND

COUNTER NUMBER COHPOUNP NAME_____ RESULT DETECTION LIMIT (ug/1)0701 ALDRIN ................... jQ 0.10702 ALPHA-BHC ................ -0.1 •

3, 0703 BETA-BHC ................ 0.1 '4. 0704 GAMMA-BHC ................ ?,$ 0.15, 0705 DELTA-BHC ................ 0.16, 0706 CHLORDANE ................ 0.17, 0707 4,4'.DOT ................ M 0.18, 0708 4,4'*DDE ................. 0.19, 0709 4,4'-DDD ................. 0.110. 0710 DIELDRIN ................. 3,f 0.111." 0711 ALPHA-ENDOSULFAH ......... 0.112. 0712 BETA-ENOOSULFAN .......... 0.1

' 13. 0713 • ' ENDOSULFAN SULFATE ——— 0.114. 0714 ' ENDRIN ................... y4 0.115. 0715 ENDRIN ALDEHYDE ———- 0.116. / 0716 •HEPTACHLOR————— $J o.i

._lLu__ 0717 HEPTACHLOR EPOXIDE ——— .. 0.118. 0718 PCB-1242 ................. 0,119.- - 0719 PCB-'254 ................. 0.120. 0720 PCB-1221 ................. 0.121. 0721 PCB-1232 ................. 0.122. 0722 PCB-1248 ................. 0.123, " 0723 PCB-1260 ................. 0,124. 0724 PCB.1016 ———......... 0.125, 0725 TOXAPHENE ................ 0.1

QUANT,COMPOUND SURROGATE. . RECOVERY REPORT CORRECTION AMOUNT .NUMBER COMPOUNDS H1NOOH VALUE FACTOR RESULT SPIKED RECOVERY

, 0738 DIBUTYL CHLORENDATE |67-114)» ___ . _______ _ff _ {/ 0

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CR5ANIC5 ANALTSIS DATA SHEET

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1 fiW*St*9 PcB*> 1260 fiTIl~3SICMe*wit1ft»n» qlj 11129") l!67«*ll*2 PC6*lOlfi • 6. 1'.

4S») 79*cs*4 HuerolricMoromttnim gu |113»)1! 01*39*2 *o«iontnt u.i.iffisv

I24.4B-I ehl ro bro->9nf*hin( ^ ^ a_

lit 1D9*B6*3 tolutn* 9U177IK! 7! .01*4 ,invi e«leriSi ————————— Jl|

6 -64-1 letton* 190U7 •' i-3 l»b itinen. JOOU CON

»li*7t«t _*t

OIQIIINS

SNTHATIONl rtSS WDIUH HI.H (clrclt)C [XTRACTtD/nEPMEDt

ninont IROU DATL MIN.'liiuiI«*1D>I 4*i«tm»l-2*Btn1inon» . 1901) PIUHMT WIITlll.! . .IOO*42*9^|3710&*Q9*4 vln99*47*6 o*ll

J

"' "* ID•eititt lall n»» odated samples: Ua/i

IH98I 1748-Ol-t D-dlo«ln 0.004L1

July, 19.3

^ PESTICIDE LOW LIQUIDft ORGAMCS ANALYSIS DMA SHEET . Page 3

Lab Hamt; Head CompuChemlib Samale 1.0. No. A?/fife p SS Q DS p Blank


013200

SI?

__, S? *•• P' -Q •«

Ol

i

?u\

0\ I

COHPUCHEH NO. /<r//^DATE_

IDENTIFIER PESTICIDES (LOH LEVEL-HATER)

COMPOUND LIST - NO. ________

COHPUCHEHCOMPOUND

COUNTER NUMBER COMPOUND NAME RESULT DETECTION LIMIT (X9/U1. 0701 ALDRIN ———......—. #0 0,1Z. 0702 ALPHA-BHC ——............ '"O.I13, 0703 BETA-BHC —————. 0.1 '4. 0704 GAHHA-BHC —-——— tf.b 0,15. 0705 DELTA-BHC -————.- 0,16. 0706 CHLORDANE ——————- 0.17. . 0707 4,4'-DDT —•——•——— $'0 0,18. 0708 4.4'-DDE ................. 0.1

•"§.——" 0709 4,4'-DDD ................. 0.11Q,_.._ 0710 DIELDRIN ................. fit) 0.111. 0711 ALPHA-ENDOSULFAN ——— 0,1

. 12...... 071Z BETA-ENDOSULFAN .......... 0.113. 0713"' ENDOSULFAN SULFATE-—.. , ' 0.1

'

OIBUTYL CHL.ORENDATE (67-114)*

^Advisory tlMlt

i.oi'i|iiH;ni<>i'i fwiiif»r= iy.ii.ii. C.M.HI _;«;<

Vr, iiiMis or weight ex'1'f'.iir: led"- .1F:niii.l l xtrai. 1 V(UuHfes lw!.i|ijil= i':|):i. i u U on I ,•>.< torsi iwr ii wo.givi i actor" l

Ihi-. i:,ui: ii.i ai i, on i iiuisti on .it1,....

Areatt<ft<\ * Urn Conr * Uuliirion Hi l. nt *

• •"•••••. ««• ,i.t •• •»...»» i_--t-i * « .n« -»)««( .HIM MI t«M»M>M BHUI-I •-»*•.> , <»•»Voiui-if or Weiym / Dry Weujlit tA'ri

Oata Pnr i.!onpouncl UAMHA .bill.;-anpie Afpa -• IIHStandard Area s 401Utandard lloncentfation =• ,4

o-r GAnnw Hill; IE, 4,Oi;Vv;',

i or uonpoimcl HITACHI. 1)1;flfipe fii'fja = Ml;Qtanaara Area = .!,&&litanaarn Concentration = .4Concentration of tlU'TAUiMJi; IF. t.illiMlV ncj/1

Data For Uonpoupda«Mp.e firea = av(.,Standard Area B 401Utandarri ConcenU'ation ~ ,t ,(Joricentrrition of ALDIilN is 3,9UI)i£; ug/l

IMta For Liflrtpnund OIELDRUJUflrip,le Area = 4t'/Standard Area = t4SStttnaard Uoncentrrttion a AUoncpntfiitjon o!' lULUUKlN is a.V'J'lO? ug/,1

Data I'or llompounr.! liNSanpie Ar'ea a id!'Standard Area = ,.f?0titandarrt Concenira'lion = ,1Concentre tion of LNUK'IN is 4,lt.';r,(IB

Data I'or Unnpoimfl DOiSanpip Ar-pa * dOVStandard Area = U4?liiandarrj Concentration B ,4Uoncflntration of UU'I ' is -),'/6 a5 ug/l

013203

AMPLITUDE: x.as uv-»econ..

013204

Hpporti 30*3,!?) ChannpJi 3 CIR3M 99SaMplei PP WSC, Injected at Sai-)7i3S ON JAN 35,F.STI) Method. PAKOH SB<!' SF.GIPO 8«bfiq/8anpi J./12 Btli JSSl-w1,rtth MY/Mln l>pl.*'i Mi,n-Ar Runrh

,500 ,300 0.0(1 30 Auto .Sup-Unk DvT TI)-l,Ml. Ref-Rjg XRTUNO 0.0(1 0 .30 5,0 100,00 N(l

Actual run ttnm 3S.OOB nini»t»s •'

RT ITM Factor Area UB/MI. Narw

,29 1.37 .iOnOOF>01. 325518, SB 285518.280" 2.41 .10000E+OJ 255. SB 255,148

-.9!> .lOOOOG+Ot 4950. 8B 4949.781, 10000F.+IM 1689. BB 1689,430.10000F+01. ' 895, SB 295,359.10QOOF.401 194. SB 1P3.695.inOOOF+01. 61,0, SB 610,344, 10000F.+01 83. SB 83,383.10000E+01 371, SB 371. ,1,17,100005+01 303. SB 30?,695.*——— .. -.._ ... no() AlpHA BH(,

, ,.lOOOOE+01 364, SB 364.469.10000F,+Ot 6\),5. SB 6114,563

31B,'l3 3B,3'8 .'10'S60'E'-05 40Jfl'Sfl,' SB • ,-4?89.86 46'. S3 .10697F.-OS ' 50363. SB .054 .

11,84 55,89 .14B39F.-05 309460, SB ,459 PP'DDT73,36 175liaE-nS 1536, SB ,003 ENBOSULFAN SULFAI'F89.30 . .lOOOOF+0) 3770. SB 3769,500, . . ,

.19100,00 .17U8F.-06 59022. SB .010 *1)BCTot») Ar«a si 27J.7339, Total UG/ML -> 5903R.OOOProrptni«>d data film P!?flja Raw data filpi R301S

89 OOliCO

0. Sample Preparation PackageThis section Includes the GC/FID chromatogram and QC Screen Data Sheet lor thevolatlles fraction ol samples associated with this case, CompuChem screens only thevolatlles fraction; all other fractions are. prepared as "low samples, and diluted Ifnecessary to Bring analytes within the calibration ranges lor quanlllatlon,

013203

GC SCREEN DATA SHEET

Laboratory Name___Head CompuChem 'Case Number________,33 %a>

SampleID Number

£U&

(4ttt>

FractionVOAB/N/APesticidesD1ox1o

VOAB/N/APesticides01 ox1 n

VOAB/N/A1PesticidesD1 oxln



VOAB/N/APesticidesD1ox1n


GCDetectable*

Medium LevelMb

Dateof

Screenl-2tf-B*f

Level ofGC/MS

Analysis**L. •

*Answer Yes or No.**Ind1cate"M" for medium level SC/MS analysis. 013907Indicate^" for low level GC/MS analysis. u*

AMPLITUDE x.2S uV-seconds (Enlarged x 182,92)- N M w *_! i- CD n n>

19 (9 CDj. i s § §0 =

DXTJ

inH

a(9XVI

*H>M

oSaniPIx9

~o at-JD at

»o*(.aiuoz

.rs

> 6.21

12.97

16.21

O ?* 013 03

Reportt 37)3,00 Channs'J i 4Sannlei W8 19180 Injected at 8i3li05 ON ,TAN 24, 1,984ZERO Method i HF.XA04 Seq i BF.Q46 Swbiq/Sa-pi !/ 1 Btli 1Sl-Hidsth HV/jJty D,);! Hlnffi gunch

ttftflnh -W| HH.,1 Ref-gJU *|TU

Actual run tlnei 20,017 MinutesSignal > 1 ooltEnded, Jnot on baseline

RT ITH Factor Area AREA X Nan*

,78 0,00 .iOOOOE+Ol 405. BB ,001" ".00 ,!,OOOOE+01 8124, ",00 .: pOOOE+Ol; 8492,

ifi.'SS O.'OQ ,'i!000"0~E+fli 22545,' W j 3610,90 O'.OO .lOOOOE+Oll 48854

;+!!* WB>H 78

9.8912.00 0,00 .J.OOOOE+0. 54155. HH .118612.97 0,00 .100005+04. 60390704, HS 95.82215,21 O.OQ .10000E+01 233425), HS 3.704

Total Artt « 63023560. Total AREA X « 2334251,500fip|Pract.ii'd data film P4601 Raw data file. R4601

013209


Laboratory Name___Head CompuChem____________Case Number________

SampleID Number£MA/

Mir?

FractionVOAB/N/APesticidesDloxln

VOAB/N/APesticidesDloxln


VOA 'B/N/APesticidesDloxln




GCDetectable*

Medium Leveln/\

,

;

Dateof

Screen('it/-ff

Level ofGC/MS

Analysis**<_. .

*Answer Yes or No.*'inqicate"M" for medium level GC/MS analysis.Indicate1!" for low level GC/MS analysis. A n

013310

*• OW..C5

AMPLITUDE x.25 uV-seconds (EnUrged x 188.93)fO M « *

' S 8 S 8

2-I*

" <n

PIX9

-n

pi

_CISszN

.79

6.22

12.9?

15.21

013311301 WtS

<_ Report i 3714,00 Channeli 4Sanplei VS 19187 Injected at 8iS5.14 ON JAN 24, 1984ZERO Methodi HEXA04 Seqi 8EQ46 Subsq/Sanpi V 2 Btl' 2Si-width MV/Min DpJ-w Min-Ar Bunch

.500 .300 I).00 100 AutoSup~Unk DvT JD™Lv.- RUT*"SX** XB.TW * AMI 3"_T e$$NO 000 0 130 51U ifl 0,0 0 NU

Actual run tinei 30.017 ninutesSianal > 1 voltEnded not on baneline

RT ITH Factor Area AREA X Nan*

lOOQOE+Ot 357. BB .00110000E+Q) 5090, BB .00"lOOOOE+Oli U6B7, BH ,0110000E+01 16722. HH ,026lOOOOE+Oi 6985. HH .OilIQOOOE+fll 19333, HH ,030

,'lOOOOF+D! 5090! BB ,'008026.Oil

',10000^+01 27546'. HH '.043:iimt$l. ' i..lB:.tl :!»10000F.+01 122484, HH .19310000E+01 101936, fH ,160-----+01 223flSi, HI .3511+0 i 65574. \H .193

172431. HH ,586.IQOOOE+fll 372431,iOOOOE+Oi 601.48816. MS , »4.561,10000E+Oi 2334247, HS 3.670

Are* • 63608184, Total ARF.A X • 2334247.000Proce.ied data filti P4602 Raw data, file* R4602

013?12


Laboratory Name___Head CompuChemCase Number_______,3.33A

SampleID Number

tttek

•








GCDetectable*

Medium LevelAJG

Dateof

ScreenI-M-N

Level of-GC/MS '

Analysis**"• u.

*Answer Yes or No. ,,**Ind1cate"M" for medium level GC/MS analysis. (H3?,l->indtcateV for low level GC/MS analysis. u

AMPLITUDE x.2S uV-seconds (Enlarged x 181.30)in N N «* -2 H. o> in ro

(B S) S SM. ® 2 2 S

i

-e oJOB B

'S

O IB >n <n_o 0

OlD(BZW

0

6.23

0139,14

Report i 3715,00 Channel > 4ianplei VS 19188 Injected at 9i 19.39 ON J'AN 24, J984ZERO Method i HEXA04 Seqi SKQ46 Subsq/Sanp. I/ 3 Btli 3

B.gjU.11 W| JD-Ul R

Actual run tin«< 20,008 ninutenSignal > 1 voltEnded not on baseline

RT XTM Factor Area AREA % Nane

.78 0,00 .lOOOOE+Qt 163, BB .000...23 0,00 .10000E+01 J??34. BB .006.9.2? 0.00 .IQOpOE+gj 5S?S?. K\ -ISS

75.-79

U'.30 0,00 ',10000E+01 48543. HH .106w.a MI .Hiii|3| JMlf.B _•.»

6.23 0,00 .10000E+01 2934. BB .0069 29 0.00 .IOOOOE+01 58357, BH .128

10 22 0 00 .10QOOF.+01 63430. H .13910 61 0 00 10000E+05. 79855, HH .175fO 97 0 00 lOOOOE+Oi 81809. HH .17?

il',97 O'.OO ,___.....12.97 0.00 .lOOOQE+01 45056824.' HS 98,'623

Total Area « 45685728. Total AREA X * 45056824.000Processed data file. P4603 Raw data file> R4603

GC SCREEN DATA SHEETft

Laboratory Name___Mead CompuChem______,Case Number_________,33-3.-b_____

SampleID NumberAZM?

witf

•

FractionVOAB/N/APesticidesD1ox1n







GCDetectable*

Medium LevelA/0

Dateof

Screen/-AU'Ptf

Level ofGC/MS '

Analysis**/_'

'Answer Yes or No.**Ind1cate"M" for medium level GC/MS analysis.

Indicate"!." for Tow level GC/MS analysis,

is

fltlPLITUDE x.25 uV-seconds (Enlarged x 101.14)jn N W W2 r.

3S

9,09CFf

IA

o> in roCl _ CD S>IB (9 IB 9

.79

6.22

11.80

ia.ee

Report. 3718,00 ChanneJ i 4 C*R333 R3664Sanplei V8 19189 Injected at Uil9iil ON JAN H4, 1984ZERO Method i HF.XA04 Seqi SEQ46 Subsn/Sanp . )/ 4 Btli 4Si-width MV/Min Delay • Mln-Ar Bunch

.500 ,300 Q.Ofl 100 AutoSuo-Unh DvT ID-Lvl Ref-RTW XRTW XDU-f Iso

NO 0.00 0' ,3(1 5,0 100.00 NOActual run tine. 20.017 ninutas

Signal > 1 voltEnded not on baseline

RT ITM Factor Area . AREA X Namt

,79 O.OQ .10000E+01 351. BB .0016,22 0.00 .10000E+01 7457,9,31 0.00 , J.OOOOEXM 20711.

o .10,61 O.OQ .1000QE+01 47299, HH ,07610.92 0.00 .10000F.+0! 74248, HH .119ii-l§ 5-8S .iJ8S8S+8} 3W11,80 0,00 .10000E+01 264R47. .-13,00 0.00 .10000E+01 61791008. HS 99.163

Total Area • 62312736, Total AREA X • 61791008,000Processed data file. P46Q4 Raw data film R4604

'

013213


Laboratory Name ___ Mead CompuChem _Case Number

SampleID Number

/63-tt"

/9l<tO

•








GCDetectable*

Medium LevelAlt\

•

Dateof

ScreenI'&kFf

Level ofGC/MS

Analysis**^ .

*Answer Yes or No. «< c»0l 3**In.1cate"N" for medium level GC/MS analysis, V\& 'IndfcateV for low level GC/MS analysis.

AMPLITUDE x..S uV-seconds (Enlarged x 181.87)

H.®

I

7VI

r1 <"

IiI Z» <B

CD c~B a89 CB

u

HO IB

ffIB

N W *_ S SIB IB (B

11,80

13.08

16.22

*"

Report. 3719.00 Channel i 4 C»8333 R3665VS 19190 Injected at Ui43i33 ON JAN ?A, 1984

ZERO Method i HEXA04 Soqi SEQ46 Subnq/Sanpi I/ 5 Btl. 5Si-width MV/Min 'Delay Min-Ar

.500 ,300 0,00 100 AutoSuR-Unk J,J. IW..J Rf.jp »|T|f

Act'ual run tinet 20 ,017 ninniesSignal > i voltEnded not on taasolini

' RT ITH Factor Area AREA X Nan*

,_5 0.00 .10000E+01 429. BV ,001.38 0 00 ----- - -•-- •-S, 00:88

8,159,31

0.00 ,1001- — 1001

"WHi i+o-i m•>01 6(1641m4!

016D30097

10 35 0.00 lOOOOe+Qi 23657. HH ,03810.63 0.00 .100005+01 67723. HH ,10810.92 0.00 .lOOOOE+01 99830. HH ,15911,32 0 00 10000^+01 48299. HH 97711

, .11,80 0.00 .10000E+01 310938. HH ,49513,00 0,00 . .10000E+01 59741336. HS 95,078

15,22 O.QQ .10QOOE+0) 2376314. HS 3.788Total Area " 62834072. Total AREA X •' 2376314.500Proressed data filet P4605 Raw data fil.i R460S


Laboratory Name ___ Mead CompuChemCase Number

SampleID Number

&3ML

ttHl

'








GCDetectable*

Medium LevelAid

Dateof

ScreenA--A/V

Level ofGC/MS

Analysis**L- •

(• *Answer Yes or No.i **Ind1cate"M" for medium level GC/MS analysis.r W Indicate1!" for low level GC/MS analysis,i,v

flMPUTUDE x.2S uV-seconcl$ (En Urged x 100.61)30 W N W AC >- CD in M

8 8 S S8 (9 (B 03<» a» o <s

2.8

M

I <"

8.3m

2Smwo

i in N? * m , . _ ..._ _, lio.eeT)A I.(M)_Z<n

16.74

Report i 3720.00 Channel i 4 C*R333 R3666Sanplei MS 19191 Injected at lZ>i07i55 ON JAN 34, 1984ZERO Method i HF.XA04 Seqi SF.1.46 Subsq/Sanp. i/ 6 Btl. 6Si-width MV/Min Delay Mln-Ar Bunch

,500 .300 ' 0.0(1 100 AutoSufio-UnK Wg «H.,J Ref1JW ^ jflljf jjg.

Actual run tinm 20.008 ninutesl > 1 voltnot on baselineSignal > 1 voltEnded

RT ITH Factor Area AREA % Nane

9.35 0.00 .10000E+01 71118. BH .34710.64 O.OQ ,10QOOE+Oi 148780. HH .72711,01 0,00 .10000E+01 74225. HH .36311.33 0,00 .iOOOOE+Oi 51758, HH ,25311.86 0.00 ,100001+01 202293. HH .98811.98 0.00 .lOOOQE+01 106755. HH .52113.00 0.00 ,10000E+Oi 19782832. H8 96,61615.74 0.00 .10000F.+Q1 37957. TT .185

Total Arna • 20475716, Total AREA X • 37957.350Processed data file. P46Q6 Raw data file. R4606


Laboratory Name___Head CompuChemCase Number_____£2, •>>*>

SampleID Number

&3W7

/ 9/7.2

•

FractionVOAB/N/APesticidesD1ox1n







GCDetectable*

Medium Levellift

Dateof

Screen/-Jtfty

Level of.GC/MS

Analysis**L^ .

'Answer Yes or No.**Ind1cate"M" for medium level GC/MS analysis.Indicated" for low level GC/MS analysis. , QrtO^

89 00;

AMPLITUDE x.25 uV-secgnds (EnUrged x 100.75)

|L_.

N Wm in8 8(B 8(8 18

tt.l .80n

E. o»,58

NW*z I ( SJ n

f390 a I ~antttM!. u

019>

NN

IS N00 .n 01-O 8J*OlDozh. 8

13.00

16,22

N

-«v Report' 3721,00 Channel i 4 C*!»3333 R3667Sanpl*< W -7192 Tnjected at 12.32.08 ON JAN 24, 1984ZERO Method) HEXA04 Snip SEQ46 Sub*q/Sa«ip. i/ 7 Bt). < 7

. SugjUnk Jvj. ID-UJ Ref-gJW XRTjf »fliljf

' Actual pun tinti 20,008 Minute*Signal > 1 volt _Ended not *n bateline

RT ITM Factor Area AREA X Nani

.10000E+01 355. BB .001

.10000E+01 7475. BV ,012

.10000E+01 HS38. BH 014.

.lOIOOE+01 5464. W ,009.ill OOE+01 4845, HH 008

.illOQE+01 13035, 4H ,021

.11 OOE+fll 11773. HH .019OE+Oi 24134. 4H ,0390_+0t 46087. HH .974

:i8.101

,1111''" OE+lil 27155.'

OE+ll 86817E+*Si vat 95'8?2

OOOOE+Oi. 285B375. H8 3,638Area • 62080128, , Total AREA X • '2258375,500

ProcetMd data file. P4607 Raw data filti R4607

89

V. RAW QC - US Environmental Protection Agency · V. RAW QC E.P.A. CASE NO. ... page 8-9 ol 63: II...

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