UV Stable, Weather Resistant Sheet Molding Compound · September 2016. Paul Rettinger – Chromaflo...
Transcript of UV Stable, Weather Resistant Sheet Molding Compound · September 2016. Paul Rettinger – Chromaflo...
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September 2016
Paul Rettinger – Chromaflo Technologies, Inc.
Lora Mason – Ashland, Inc.
Mayur Shah – Continental Structural Plastics
UV Stable, Weather Resistant Sheet Molding Compound:
An Alternative Approach to Building Strong, Durable Transportation Components
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UV Stable, Weather Resistant Sheet Molding Compound:
• Part I: The Appearance Science Approach
• Part II: Durability Testing • Part III: Mechanical Properties • Part IV: Application • Part V: Conclusions
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Part I: The Appearance Science Approach
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Part I: The Appearance Science Approach
•
Appearance is that aspect of an object which enables us to identify an object for what it is.
-- Richard S. Hunter, 1975
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UV Stabilization
Color Science
Polymer Science
Additive Science
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Weathering Failure!
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Identified Causes of Weathering Failure:
• Resin selection • Glass selection • Filler selection • Colorant type and quantity • Low Profile Additive type and quantity • Thickening profile • Molding viscosity • Initiator selection • Inhibitor type and quantity • Mold surface condition • Mold performance • Mold temperature and flow of material
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A Common Cause of Failure:
• Failure to adequately cover or hide the glass • This can be due to dry glass • Lack of resin rich surface • Molding conditions • Behavior of low profile • Colorant often plays an important role in
covering and hiding glass
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Appearance Science
COLORANTS ADDITIVES
SUBSTRATE
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Rules Concerning Color Space
RED
YELLOW
BLACK GREEN
L* a*
b*
WHITE
BLUE
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Weathering Test Matrix:
• SAE J-1960-kJ, 4000 hours, boro/boro filters, Atlas Ci4000 Weather-O-Meter.
• SAE J-2527, 4000 hours, quartz/boro filters, Q-Sun Xe-3-HSQ (Q-Panel).
• ASTM G-155 Cycle 3a using Q-Sun Xe-3-HSQ (Q-Panel). • Outdoor direct exposure: ASTM G-147, 5° South, AZ and
SF, 2 years. • 1000 hours xenon arc =~ 1250 kJ @ 340 nm
=~ 1 year @ 5° south. • ASTM G-23 Sunshine Carbon Arc (SWOM), 1000 hours • Evaluation of multiple textured surfaces – texturing plays a
role in surface durability
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Weathering Test Matrix:
• Testing conducted and results correlated by each of four (4) parties: • Chromaflo • Ashland • CSP • Honda
• High priority on understanding and correlating differences between test methods and facilities.
• Appearance measurement: • Color Sphere Spectrophotometer (e.g. X-Rite Color-Eye 7000A),
Large Area View, 10° Observer, D65 Luminescence, CIEL*a*b* and CMC 2:1 color spaces.
• 60° Gloss using glossimeter (e.g. Byk Micro-Tri-Gloss) • Each reading represents average of three (3) readings on each of
multiple panels per reading interval
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20.000
21.000
22.000
23.000
24.000
25.000
26.000
27.000
28.000
29.000
30.000
0 0.5 1 1.5 2 2.5 3 3.5 4 4.5
L* (C
IEL*
a*b*
)
Years of Outdoor Exposure
Comparison of L* Drift of 50% Glass UV Stable SMC in Accelerated (Ci4000 SAE J1960kJ boro/boro) vs Natural (SAE J1976 5° SOB) Testing
UV Stable SMC 50% Glass Ci4000
UV Stable SMC 50% Glass 5° SOB South Florida
UV Stable SMC 50% Glass 5° SOB Arizona
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0
0.5
1
1.5
2
2.5
3
3.5
4
4.5
0 0.5 1 1.5 2 2.5 3 3.5 4 4.5
60° G
loss
Years of Outdoor Exposure
Comparison of Gloss Retention of 50% Glass UV Stable SMC in Accelerated (Ci4000 SAE J1960kJ boro/boro) vs Natural (SAE J1976 5° SOB) Testing
UV Stable SMC 50% Glass Ci4000
UV Stable SMC 50% Glass 5° SOB South Florida
UV Stable SMC 50% Glass 5° SOB Arizona
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Part II: Physical Durability Requirements and Testing
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Honda Rock Drop Test:
https://www.youtube.com/watch?v=ayOhO3D_90Y
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DVP&R Test Summary: Test Name Test Number UV SMC vs
Painted SMCUV SMC vs. Painted
SteelUV SMC vs.
ThermoplasticGloss Polish Change BI 010-02 Same Same Same
Scuff Resistance 10k cycles BN 108-04 Same Better SameAppearance Worse Better WorsePerformance Better Better WorseAppearance Same Better WorsePerformance Better Better Worse
Taber Abrasion 2000 cycle Appearance Worse Better Worse@ 250 gm Performance Same Better WorseSoap / Washer Fluid / Oil BI 113-01 Same Same Same
Acid (Sulfuric) BI 113-02 Same Same Same
Fuel Resistance BO 101-05 Same Same SameAppearance Better Better BetterPerformance Better Better Same
Thermal Shock BI 107-05 Same Same Same
Mar Resistance BI 161-01 Same Better Better
Environmental Cycle BQ 104-07 Same Same Better
Scratch Resistance (7 fingers) 5+2 BN 108-13 Same Same Better
Water Immersion BI 104-10 Same Same Same
QCT (24 Hour Salt Spray) BI 104-02 Same Same Same
Taber Abrasion 2000 cycle @ 1kg BN 108-02
Taber Abrasion 6000 cycle @ 1kg BN 108-02
Gravelometer SAE J400
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DVP&R Surface Durability:
UV SMC vs. Painted SMC
UV SMC vs. Painted Steel
UV SMC vs. Thermplastic
Same or Better (17 of 19 tests)
Same or Better (19 of 19 tests)
Same or Better (13 of 19 tests)
Worse (2 of 19 tests) Worse (0 of 19 tests) Worse (6 of 19 tests)
Summary of Jury Evaluation
UV composite is more durable than painted steel.
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DVP&R Surface Durability:
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Thermoplastic
Painted Steel
Painted SMC
UV SMC
Scratch Test Gravelometer Taber Scuff
Taber Abrader
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Part III: Mechanical Properties
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Typical Properties: Multi-lot Analysis
Property: Value UnitGlass Content 50 %Specific Gravity 1.73 Rel. DensityMoisture Absorption 0.73 %Flexural Strength, Mpa 266 MPaFlexural Modulus, Mpa 11,700 MPaTensile strength, Mpa 140 MPaTensile Modulus, Mpa 12,300 MPaCLTE(-30cto 30c),mm/mm/c 1.87E-05 mm/mm/cPoisson Ratio 0.38 N/A
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Weathered Mechanical Properties
0
20
40
60
80
100
120
140
160
0 0.5 1 1.5 2 2.5 3 3.5 4 4.5
Tens
ile S
tren
gth
MPa
Years of Outdoor Exposure
Analysis of Tensile Strength Retention over Time
Tensile Strength MPa South Florida
Tensile Strength MPa Arizona
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Weathered Mechanical Properties
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50
100
150
200
250
300
0 0.5 1 1.5 2 2.5 3 3.5 4 4.5
Flex
ural
Str
engt
h M
Pa
Years of Outdoor Exposure
Analysis of Flexural Strength Retention over Time
Flexural Strength MPa South Florida
Flexural Strength MPa Arizona
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Weathered Mechanical Properties
0
2000
4000
6000
8000
10000
12000
14000
16000
18000
0 0.5 1 1.5 2 2.5 3 3.5 4 4.5
Mod
ulus
Val
ues M
Pa
Years of Outdoor Exposure
Analysis of Modulus Characteristics over Time
Tensile Modulus MPa South Florida
Tensile Modulus MPa Arizona
Flexural Tangent Modulus MPa South Florida
Flexural Tangent Modulus MPa Arizona
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Part IV: Commercial Utilization
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Application Requirements:
+
Applications Requiring:
• UV Stability • A Paint-Free Solution • Structural Performance
Black Texture
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SMC Formulation
Component PPHR AROTRAN® 805 Resin Catalyst Inhibitor
Filler
104 1.5 1.2
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UVS-02610/AM-9033
Glass Reinforcement (% by weight)
24
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Current Commercial Application:
• CSP started manufacturing as CSP 834UV in 2015 • Currently being used in molding of Honda Ridgeline Bed • SMC is being produced at CSP-Van Wert,Ohio facility • Parts are molded at CSP, Salisbury, NC facility • Material has been validated and approved for use on
visible, textured, structural exterior parts at Honda • Approval status at GM: waiting for specification number • Panels with short vertical walls mold well • Panels with deep vertical wall may give some discoloration
due to lack of pressure
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Part V, Conclusions:
• Benefits of UV Stable SMC: • EPA Fuel Economy and weight reduction • Mechanical properties necessary to structural applications • Favorable cosmetic appearance • Durability to retain appearance and properties under
severe conditions • Improvement in cost, quality, and environmental concerns • Reduction in number of steps to completed product
• Limitations: • Complex molding geometries may present challenges • Need for texturing in molded application • Consistency in compounding and molding is critical
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THANK YOU!