UNITOR MARINE REFRIGERANTS

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Transcript of UNITOR MARINE REFRIGERANTS

Page 1: UNITOR MARINE REFRIGERANTS

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Page 2: UNITOR MARINE REFRIGERANTS

''Cooling means the transfer of thermal heat from a place where it is unwanted to a plaсewhere if does not disturb"

This is how the fаther of modernаir.сonditioning and refrigerationsystems defined the сooIingproсess' But in order to transferthermal heat from one p|aсe toanother, а trаnsport medium isrequired that аbsorbs the heаt atthe p|aсe where it is not wаntedand delivers it to the plaсe whereit does not disturb. Тhis is themain tаsk of any refrigerant,irrespeсtive of type, thermаI andсhemiсal properties orсomposition' No more, no less.Тhe driving forсe thаt makes therefrigerant move around in therefrigeration system is theсompressor' with the асtuаI heattransfer tаking plaсe in theevaporаtor (instаIled at the pIасewhere the heаt is unwanted)аndthe сondenser (instalIed at theрlасe where the heаt does notdisturb)' So it beсomes сIeаr thаtrefrigerants are essentia] mediаfor the funсtionаIity of anyrefrigeration system and shouldbe treated аs suсh.

Тhe purpose of this RefrigerаntHandling Guide is to assist youto proteсt both your investmentand the environment, and to pro-mote sаfetцonboаrd. !n addition,it сontains a refrigerаnt Iog thathelps you to асhieve improvedсontrol over your refrigera.tion сosts. continuous Ioggingof refrigerant сonsumption isrequired by some authorities(refer to the table on page 't5 inthis guide).

Willis Havilаnd carrier, ,|903

Disclaimer of eхpressed and implied warranties:

Аlthoughreasonablecarehasbeentakeninthеpreparationofthisbooklet,nowarrantiesorrepresеntationsastotheaccuracуorcompletenessoftheinfobegiven;norcanUnitorAsАassumeanуrsponsibilitуregardingthesuitabilitуofthisinformationfortheuser'sintendedpurposesorfortheconshould make a determination as to the suitabilitу of the information for thеir pafticular pиrpose(s)'

Page 3: UNITOR MARINE REFRIGERANTS

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Sаfe hand|ing when woгking with refrigerants

Charging and rесovery of гefrigerants

Еnvironmenta| System Inspeсtion

Еnviro Return Management

Refrigeгant quaIity

Compressor oil

Refrigerants overview - teсhniсa| and environmental data tab|e

Refrigeration ru|es аnd regulations (as,pgr p^,gJo'bеr 2003)

Glossary

Refrigerant log

Referenсes

Page 4: UNITOR MARINE REFRIGERANTS

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1. sAFЕ HANDLING WHЕN WoRKING WIтH REFRIGЕRANтS

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Тhe be|ow is generаI information for CFC, HCFC аnd HFC refrigerants. For more detaiIs pIease refer to the

аpp|iсabIe Unitor Safety Data Sheet (downIoadable from www.unitor.сom. SeIeсt Produсts and Serviсes and then

M.s'D.s (Мaterial Safety Data Sheets).

HAZARD IDЕNТlFlсATloN

Liquefied gas. Colourless. Slight ethereal odour.

Contaсt with |iquid may сause frostbite.

High сonсentrations or pro|onged eХposure may сause headaсhe and dizziness, as wel| as сausing anaesthetiс or other

сentral nervous system disordеrs.

InhaIation of |arge amounts of vapour may сause heaгt rhythm disturbanсes.

Depending on refrigerаnt type, it has a g|oba| waгming potentia| and it may bе fl'angетous to the ozone layеr. ' l

(Please гefer to tab|e on page 14 in this guide)'

HANDL|NG AND STORAGЕ

Storage

Do not expose сylinders to temperatures above 45 oC. Store as a сompressed gas' Keep in a we|l.venti|ated p|aсe. Keep

away from open flames, hot surfaсes and other sourсes of ignition. Тhe gas is norma|ly transported undeг pressure in gas

cylinders/pressuгized сontainers. ln саse of a |eak, gas or |iquid wiII flow out. Avoid heat, sparks and open fIames.

Sаfety Measures to proteсt persons

A|ways Wеar eye proteсtion and |eather gloves or other proteсtive gloves insu|ated against the сo|d. Proteсtive с|othing

shouId be woгn if there is a possibi|ity of direсt сontaсt or sp|ashes' Wear safety boots when hand|ing сy|inders. Never |ift a

сy|inder by the va|ve. A|ways keep the сy|inder сap on when moving the сy|inder. Consider the refrigeration system and

refrigerant сontainers to be fi|led unti| you know it is empty. Stop gas |eak if possib|e without risk. Wear se|f-сontained

breathing appаratus if high gаs оonсentrations are possible. Provide good ventilation' Smoking, eating and drinking are

forbidden in the work area

Safety Measures to proteсt the environment

Do not disсharge refrigerants into the environment. Use reсovery equipment. Еmpty сy|inders must be returned to thе

supp|ler. Contасt supplier for disposа| information.

Page 5: UNITOR MARINE REFRIGERANTS

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Proper methods for damage Iimitation and с|eanup

Stop |eak if possib|e without risk. Move the оylinde(s) to open air where the |eak wi|| not endanger the surroundings'

Prevent |iquid |eaking out of the сy|inder by turning the gas side up.

Еxposure Contro|

Rеfrigerant gases are heavier than air, and wi|| aссumulate a|ong the ground and may сause sufoсation by reduсing oxygen

avai|ab|e for breathing. Weaг se|f-сontained brеathing apparatus in сonfined arеas.

lN CAsЕ 0F ACCIDЕNTAL HUMAN ЕXPoSURЕ To GAs oR LIQUlD

General

Pгovide fresh air, kеep the patient wаrm and at гest.

|f in doubt, get mediсa| adviсe.

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InhаIаtion

High сonсentrations or pro|onged exposure may сause headaсhе аnd dizziness, as we|| аs anaesthetiс and otheг оentra|

nervous system disorders. Providе fгesh air, keep the patient warm and at rest. Mouth-to.mouth resusсitаtion аnd сaгdiaс

massage if neсessary.

Skin Gontасt

First aid tгeatment of frostbite аfter skin сontaсt with |iquid refrigerant: Flush with |aгge amounts of lukewаrm

water (about 40"C),

Do not remove с|othing if frostbitten.

Frostbite to be tгeated by a physiсian. Contaсt with gas or Vapour has no effeсt,

Eye Contaсt

Contaсt with gas or Vapour has no effeсt' In сase of sp|ashes or symptoms due to high Vapour сonсentrations, f|ush the eyes

immеdiate|y with a soft jet of prefeгably |ukewarm watеr for at |east 15 minutes. Get immediate mediсa| attention. Continue to

rinse.

alngestion

Is not сonsidered a potentia| risk.

DO NoТ INDUсЕ VOM|T|NG! Give the patient 1 - 2 glasses of water or preferab|y miIk to drink if the affeсted person is fu||y

сonsсious. Get immediate mediсa| adviсe.

MediсaI information

Do not give adrenaIin or equiva|ent mediсines.

Page 6: UNITOR MARINE REFRIGERANTS

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FIRE FIGHTING MEASURES

When mixed with air аnd/or oi|, F|uorine based refrigerants сan be сombustib|e under pressure.

Proper Fire Fighting Equipment

Cool the сylinder with |arge amounts of water from a safe distanсe.

Fire and ЕxpIosion Hazards

Cylindеrs may explode when heated.

Еire or high temperatures сauses formation of toxiс gases/vapours/fumes of: с0, HF and CoFz. HCFC,s wi|l form HCI in

аddition, and may also form CoCIz.

PersonaI Proteсtion when Fire fighting

|f refrigerants are invo|ved in fire, use self-сontained breathing apparatus.

other Information l . .l ' ' т' vlit,,

Remove gas сylinders from fire areа.

Do not move any сy|inder whiсh has been invo|ved in fire unti| it is сoo|ed down.

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Page 7: UNITOR MARINE REFRIGERANTS

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2. сHARGING AND REсoVERY oF RЕFRIGЕRANтS

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Praсtiсal adviсe for safe and environmentally sound сharging and reсovery work on refrigeration

maсhinery:

1' Read the MаteriaI Safety Data Sheets (]vlsDs) on aI| сompounds inсIuding refrigerant and oil that you are

Iikely to сome in сontaсt with.

Refrigerant MSDS are avai|able from Unitor's Internet web site (www.unitor.сom).

2. Never overfill recovery сylinders. OverfiIling may сause the reсovery сyIinder to explode.

Safety сodes гeсommend that recovery сy|inders aгe not fi||ed over B0% of their vo|ume with |iquid (the remаining

20% is used for thermal expansion). Use weighing sсa|e for fi|ling сontro|. |f the reсovеry unit stops on high

pressure this is an indiсation of overfi|ling.

3' Use onIy approved reсovery сylinders.

Do not use the reсovery unit с|ose to an area with combustible substanсes.

4' Do not mix refrigerants in a reсovery сyIinder.

5. Keep the lengths of reсovery hoses аs short aЬ possible аnd when inсreаsed throughput is required use

Iаrger diameter hoses.

6' The key to quiсk reсovery is to reсover the |iquid refrigerant first.

The Unitor reсommended reсovery set-up for both reсovery as we|l аs сharging operаtions is shown on the sоhematiс

drawing on page 11. For other arrangements, please сontaсt the nearest Unitor Customer Seгviсe for аssistanсe.

Page 8: UNITOR MARINE REFRIGERANTS

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Unitor's Refrigerant Reсovery Cylinders:. Aгe fitted with dua| port vaIves

о Are made to American standards

. Are identified speсifiсa||y for reсovery pUrposes

. Can hold the fo||owing rеfrigerant weights:

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Large Reсovery Cy|indeгs

Sma|I Reсoverv Тank

ЕDP 606-6325BB

EDP 606-596544

3. ENVIRoNMЕNтAL sYsтEM lNsPEстloN

The Еnvironmenta| System Inspeсtion programme (E'S.|.) is designed to dea| with a|| types of air-сonditioning systems,

provisron pIants and se|f-сontained marine air сonditioning units. Тhe ЕS| program inс|udes a |eak test, a teсhniсal system

status test, a system perfoгmanсe test and inspeсtoг's reсommendations and сonс|usions. This is to ensuгe that your

onboard refrigeration systems аre enviгonmentа||y sound and run at optima| operаting сonditions. tor more information on

the Е.S.I program, please сontaсt the nearest Unitor Customer Serviсe.

Refrigerant SmаII 21 ltr. Tank Larqe 56 ltr. Gvl.R-12 17 ko / 37 lbs 48 kq / 105 lbsR-22 17 kq / 37 lbs 45 ko / 99 IbsR-134a 17 ko / 37 lbs 45 kq / 99 IbsR-4014 17 kq / 37 lbs 45 ko / 99 lbsR-4044 13 ko / 29 lbs 36 ko / 79 lbsR-407C 15 kq / 33 lbs 41 ko / 90 lbsR-407D 16 kq / 35 lbs 44 kо / 97 |bsR-4094 17 kq / 37 lbs 47 ko / 103 IbsR-4104 13 kq / 29 lbs 36 ko / 79 lbsR-4134 17 ko / 37 Ibs 47 kq / 103 lbsR-4174 17 kq / 37 lbs 43 ko / 94 lbsR-502 16 ko / 35 lbs 44 kq / 97 lbsR-507 13 ks / 29 lbs 36 kq / 79 lbs

Page 9: UNITOR MARINE REFRIGERANTS

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4. ENvlRo RЕтURN MANAGЕMENт

The g|oba| ban on the produсtion and сonsumption of CtC's, Ha|ons and HCFC's (herein referred to as Ozone Dep|eting

Substanсes _ ODs), as гegu|ated by the 1987 Montreal ProtoсoI, leads to a signifiсant shift tosubstаnсes with zeгo ozone

Dep|etion Potential (ODP), |ike for examp|e HFC,s. |n order to |imit the emission of ODS to the atmosphеre inteгnational

treaties, major Flag States and C|assifiсation Soсieties foсus on handling of refrigeration systems in an environmentа| sound

manneг. Theгefore, any seгviсe on systems сontaining ODS (e"g. repairs, retrofits and сonversions) requires а system that

сan dea| with potential oDS waste in an environmenta||y sound mаnneг, utiIizing approved teсhno|ogies for reсovery,

reсyс|ing, reсIamation and disposa|.

Unitor is estab|ishing suсh a сonсept on a g|oba| basis. Тhe Еnviro Rеturn Management сonсept (Е.R.M.) wi|| сomp|y with a||

g|obal treaties and аgreements, |oсa| ruIes and regulations as wel| аs good praсtiсe. The Е.R.M' сonсept will be f|exib|e for

сhangesэf regu|ations and futuгe restriсtions on Gгeenhouse Gases that aгe гegu|ated by the Kyoto ProtoсoI.

Unitor Reсovery Paсkage

Page 10: UNITOR MARINE REFRIGERANTS

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5. RЕFRIGЕRANт QUALIтY AND lTs IMPAст 0N RЕFRIGЕRAтIoN MAсHINERY

|n oгder to aIIow troub|e.free and safe operation of гefгigeration systems, refrigerants must сomp|y with сertain qua|ity

standards - just аs сomprеssors, the сontroI systems, the piping and othеr essentia| сomponents have to meet speсifiс

qua|ity standards. A major qua|ity aspeсt with гegards to refrigerants is their purity' Еspeсia||y the moisture сontent in the

refrigerant is of great importаnсe: too muсh moisture can сause serious operationa| prob|ems. It is the invisib|e moisture or

water vapour that сan сause grеatest troub|e in any refrigeration system. A drop of watеr may |ook harm|ess enough, but to a

refrigeгation system it is enemy number one, as it is vеry easy to get in (e.g' through sub-qua|ity refrigerant сontaminated

with moisture), but extreme|y hard to гemove again. lf not e|iminated, it сan сause а great dea| of diffiсu|ty.

|vOlsTURЕ |N A RЕFRIGERATION SYSТЕM MAY сAUsЕ FOUR ТYPЕs oF PROBLЕMS:

Freeze ups

Freeze ups oссUг Wnen moisture, piсkеd up by the refrigerant starts to freeze, bui|ding.iф'сrysta|s that b|oсk the refrigerant

passage in nаrrow passageways, for example in the expansion va|ve. Тhis effeсt is сaI|ed intermittent сoo|ing, as the

сompressor after а while stops due to the bloсkage in the expansion va|ve and starts again when the iсe сrysta|s have

me|ted and a||owed the гefrigerant to pass through again. Тhis is a periodiсa| proсess of сonstant freezing and me|ting of the

moisture inside the system, сausing periodiсa| stop/start operation of the сompressor.

Corrosion

Motsture alone in form of water сan сause сorrosion, however, moisture p|us a refrigerant сontaining ChIorine (|ike for

examp|e the HCFC R-22 and it.s mixtuгes) сreates muсh more serious сorrosion, as the Chlorine wi|| s|ow|y hydrolyse with

the wаter аnd form Hydroсh|oriс Aсid (HC|) whiсh is aggressive to most metals. Heat adds signifiсantly to the problem by

aссe1eгating the aсid4orming proсеss. When it сomes to the HFC refrigerants, it is the oi| (espeсia||y po|yo|ester oils thаt are

very hygrosсopiс) that may deсompose at high temperatures forming aggressive Hydrofluoriс aсid with the moisture

сontained in the refrigerant.

Oi l s ludging

As refrigeгation oiI is high|y hydrosсopiс, it rapid|y аbsorbs moisture. Еspeсia|ly moisture сhanged into aсid from the

hydгo|yses with a refгigerant (see abovе) сan bе vеry dangеrous, as it emu|sifies with the refrigeration oi| io form aggressive

oi| s|udge that greatly reduсes it's |ubriсation propeгties, whiсh сan resu|t in serious сompressoг dаmage.

Sludge formation

When sludge foгmation is pгesent, the metal|iс suгfaсe is еatеn awаy due to high aсid сontеnt inside the system, and a so|id,

detaсhab|e produсt is formed. |t exists аs s|imy Iiquids, fine powders and granu|ar or stiсky so|ids and is сommonly known as

s1udge. Тhis sIudge сan сause a variety of prob|ems suсh аs b|oсkages of fine strainers, expansion va|ves and сapil|ary

tubes. And bесause sludge usua||y сontains aсid, it сan aIso be strongly сorroslve.

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Page 11: UNITOR MARINE REFRIGERANTS

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To reсtify prob|ems сaused by too muсh moisture inside refгigerаtion systems сan be a сost|y exerсise. lf the moisture enteгs

the system with the refrigerant it wi|| lead to сontinuous сost|y repairs that reсtify the сonsequenсes but do not eltтninate the

сause.

It is therefore important that refrigerants сomp|y with appropriate qua|ity standards with regards to their puгity.

In order to ensure tгoub|e-freе and save operation of your onboard refrigeration mасhinery, a|l.refrigerants supp|ied by Unitor

throughout the woгld сomp|y with the stringent AR| 700-1999 standard that defines and benсhmаrks the purity of thesе

substanсes. Тhe standard e.g. demands the moistuгe сontent to be |ess than .l0 ppm.

The Unitor reсommended reсovery set-up for both, reсovery as we|l as сharging operation (P|еase see page 7).

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Guidelines on Refrigeration Oils

Lubriсant se|eсtion for a гefrigeгation system is сritiсa| not on|y for the сompressor but also to ensure thаt the oi| does not

separate from the refгigeгant gas in any paгt of the p|ant.

|f the oi| type or supp|y manufасtuгeг is сhanged, inсompatibi|ity and henсe poor misсibitity within the p|ant сan сause

problems.

With the wide range of minera| and synthetiс produсts on the mаrket, сoup|ed with differеnt additive teсhnology, it is vita||y

importаnt to оheсk oi| misсibility prior to top-up with a different grade oiI. The a|ternative is to drain the oi| сomp|etely from a

refrigeгation system, whiсh сan be very diffiсu|t or even impossib|e without strenuous proсedures, During waгranty,

сomprеssor and/or system designers oftеn prohibit the use of non-approved refrigeration oi|s.

0il TestingA field test of oi| сan be done by visua||y inspeсting the oi| аnd use an oil aсid test kit to determine if the system has been

eхoosed to moisture. '} ],, 1-\1l]:

Oi| samp|es сan a|so be sent to a |aboratory for ana|ysis; this routine requires с|ean samp|e bottIes and is used for systems

сontaining large quantities of oi|.

0iI Changing ProсeduresRefеr to mаnufaсturers reсommendations on oi| сhange interva|s. Тhese may be annua||y or сou|d be more frequent if the oil

beсomes dark or сloudy.

A good ruIe is to renew the oi| if a majoг serviсe or гepair has been donе to the сompгessor or the system

Foг сhanging the oi| in a standаrd сondensing unit, it is normal to rep|асe the oi| сharge in the сompressoг сгаnkсase. |t is

also гeсommended to сIean or сhange the oiI fi|ter (if appliсab|e) and the refrigeгant drier fi|ter сorеs at the same time.

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o|L сHARGING

Proсedure is as fo|lows:1. Run pump down and shut down the unit

2. C|ose the serviсe va|ves on the сompressor

3. Ensure that any сrаnkсase oi| heaters are switсhеd off

4' Drain oil сareful|y fгom the сompressor сrankсase

5. |f the oi| has been drained out with the сompressor prеssurised, new oiI саn be оharjЪd with an oi|-fi||ing pump

сapаb|e of working against pressure

6. Fit the oiI pump to the oi| сontainer aссording to manufасturers instгuctions, attaсh pump to сompressor with a

сharging hose and |eаve the hose сonneсtion to сompгessor |oose. Pump oi| into the сharging hose unti| it is fi|led

This is nесessary to e|iminate air from entering into the system and to еnsuгe proper pump funсtioning when

working against a pressurised system

lf the сompressor has been opened for inspeсtion or repair

т ' Еnsure thаt the сomprеssor сrankсase is cIean

B' Run deep VaсUUm on the сompressor using a Vaсuum pump, preferably down tо'Q00 miсгon

9. Charge oiI using the vaсuum to suоk up the oiI from the сontаiner into the сrankсase

10. Remembeг to switсh on the сrankсase oi| heater if app|iсab|e and a||ow time for the oi| to be heаted before the unit

is put baсk in operation

Used refгigeгation oil must be returned to a waste reсeption faсility.

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7. REFRIGERANт ovERvlEW

The intention of the be|ow tab|e is to give a summary of the environmentа| and teсhniсa| data for the most used refrigerants.

* Min = Мineгa| oil, AB = Alkyl benzene, PAo = Po|yа|phao|efins, PoЕ = Polyo|ester oiI

** Appliсable to None-AгtiсIe-S сountries to the 1987 Montrea| Protoсo| on|y

RefrigerantASHRAЕ no

ODP GWP Repl.For

Chemiсa| name orсomposition

Group Oils * BoilingPoiпt "G

Remаrks

R.'11 4000 Triсhlorof|uoromethane Min, AB +23'т Produсtion and trade ended**

R.12 О'82 8500 DiсhIorodif|uoromethаne Min, AB -29.8 Produсtion аnd trade ended**

R.502 (\ '?А. 5590Mix R-22l115

(48.8/51.2) CFCMin, AB .45.3 Produсtion and trаde ended**

R.22 0 049 1 700 Ch Iorod if I uoromеthane HCFсMin, AB,

PAO-40.8 Produсtion and tгаde Iimited

Phase out 2030**

R4OTA 0,031 970 R-12 |liх R-22|152a|124(53/ 1 3/34)

HсFсMin, AB,

PAO.З4'4 Interim rep|aсement. Zeotrop'

Glide 4,9 K

R-1381 4 aI L 5600 Bromtrifluormethane HаIon

Min, AB-5т 'т

Мost|y used for fire fightingsystems' Produсtion andtrade endеd

R.134а 0 1 300 R-12 Tetraflourethane HFс POE -zo. ISingle refrigerantNo GIide

R-4044 0 3260 R-502 Miх R-125/,l43a/134aА4l52|4\

HFс PoЕ -4b.b Neaг.Azeotrop wiihGIide 0,7 K

R.407с 0 1525 R-22 Мiх R-32|125|1З4a(23125152\ HFс PoЕ -43.8 Zeotrop, GIide 7,4 K

R-4094 0,048 1290 МiхR.22|R124lR142b(60/25l1 5)

HсFс|\Лih, AЦ..

POE-35.4 Zeotrop. GIide 6 K

R-4104 0 1т25 R-22 Mix R-32/125(50/50) HFC P0Е -51.6

Neаr-Azeotrop with GIide<0,2K. Pressure approx 60%hiqheг than R-22

R-4134 0 1тт0 Mix R218/R1344/R6004(9.0/88.0/3.0)

Min, AB,PAO' PoЕ

-35.0 Zeotrop. GIide 5 K

R-507 0 3300 R-502 Mix R.125/143а(50/50) HFс POE -47.1 Azeotrop

R4174 0 'r950 R-22 Mix R-125/134al600(46.5/50/3.5) HFс

Min, AB,PAO' P0Е

-42.0 Zeotrop, GIide 5,6 K

R-717 0 AmmoniaMin, PAO -33.З FIammаbIe / Toxiс

R.7'14 0 1 Carbon dioxideMin, AB,

PAO. P0Е-78.4 Low Crit. Тemp./ high

nressure

R.290 0 -10 Propane HсMin, AB,PAo' 0Е

-42.1 Very flammable

14

Page 15: UNITOR MARINE REFRIGERANTS

Wжff r жщжr жжз*' ffi жузffiffwmщ ffi жжffi*.,, рr*{*t:t уtз*r i*зl*stgу*жt

Uпlт0вRЕFRIGЕRAтlol\ sЕRvlCЕ

8. REFRIGЕRAтION RULEs & REGULAтloNs

Nаtiona| аnd internationa| regu|atory bodies wi|| сontinue to regulate the environmenta| situation thгough the gгadual phase-

out of CFC and HCFC refrigerants. Most regu|atory work bui|ds upon Тhe 1987 Montгea| Protoсo| on Substanсes that

Deplete the ozone Layer. The ''No Vent,. ru|es from the U.S. Clean Aiг Aсt and other inteгnationa| аnd nationaI oDS emission

сontro| programs are examp|es of this woгk. Тhe fo||owing tab|e summarises the сurrent majoг regu|ations

RegutаtoryBody

Valid for сFс HсFсConsumption

(HCFC's) related to1989 reduсed to:

't9s7lЛoпtreаlProt,oсol

None-Artiсle-5сOuntries

Produсtion and tradewith CFC's is i||еgal(exсept foг essentiaI

use).

Produсtion & trаde gradually reduсed until fina| phase-out on Jan. ]ы 2030'

Jan' 1ы 2004: 65%Jan, 1 . t2010: 35%Jan. '1s12015:10%Jan. 1ы 2020: 0,5%Jan. 1,t2030: phased-out

Artiс|e-5 сountriesPгoduсtion аnd tradeleqal until Jan 1't 2010 Produсtion and trade disсontinued in one step on Jan' 1't 2040. Jan. l,t 2040: phased-out

Ес {Reg.)203712000

EU сountries and EUflagged ships

Not permitted

l||ega| in new systems, in disposable сontainers, and to vent to аtmosphere.Annually сheсk by approved paгty if totaI

refrigerant сharge > 3kg.

Jan. lst 2004: 30%Jan. 1st 2008: 25%Jаn. ,1st 2010: Virgin prod'

disсontinuedJan. 1st 2015: phased-out

Reg, Body VаIid for сFс HсFс HFс Serviсe [Vlax leаk

[tЛаrpo|7зl78

Parties to Annex Vl

Deliberate emissionspгohibited' Notallowed'in new

systems

Deliberаteemissionsprohibited.

Allowed in newsystems untilvear 2020

NA

Regu|ar surveys (|APP сert.)Reоovery system & сy|inders

mandatory. Used refrigerants tobe delivered to appropriate waste

reсeption faсiIities,

|Vlinimа| гeIeasesassoсiated With reсapture

and reсyс|ing Ofrefrigerants.

USA

{сAA608}

USA аnd US flaggedvessels

lllegal to import, andto vent to atmosphere

lllegal to vent toatmosphere.

Phаse out in newsystems from

201 0.

NA

Shall have reсovery сy|inders.Disposab|e сy|inders not a||owed.Reсovery асоording to ARI 740.Pump сapable of 500 miсrons.

US flagged ship only: EPAсeгtified serviсe engineer.

А/C systems: |f refr'сharge > 50 lbs 15%'

Provision svstem: 35%

(% oftota| refr' сharge inone year)

Netherlands

tsТ,EK).Тhe NetheгIands andDutсh flаgged vessels

Not permifted

|llegаl for newsystems withshaft power>50kw, in

existing OK toyear 201 5. lllegal

to vent toаtmosohere

NA

Reсovery system and сy|indersmandatory onboard. Vaсuumpump сapabIe of reaсhing 730miсrons' Log book mandatory'Serviсe engineer to be STЕKсertified' AnnuaI inspeсtion'

1 % of tota| сhaгgeаnnuа||y'

Sweden

{sWЕвAс}Sweden and Swedishflagged ships

Not permittedIllegal to reсharge

and to vent toatmosphere.

NAAnnual survey. Logbook is

mandatory.2% of tota| сhargе

annually.

DnVDnV о|assed ships Not permitted Permitted until

vear 2020.GWP < 3500 Fixed systems with Е|-motor

> 100 kW. Deteсtion of leakage,reсorded сonsumption figures

and reсovery units'

1 0% of total сhargeannually.Clаss Notation

CIeanNot permifted Not аl|owed GWP < 1890

LRS 'LRS с|assed ships Not peгmifted Permitted until

уear 2020.NA

Reсovery system & сy|inders +logbook mandatory

,!0% oftota| оhargeannuа||y'

R - Chаracter Not permifted Not permitted GWP < 1950

Aвs Еs notаtion Not permittedPermifted until

year 2020. GWP<= 2000

GWP <= 2000Reсovery system & оy|inders +

logbook mandatory10% oftota| сharge

annually.

GL Green Passpoгt Not permifted Permifted untilуear 2020'

GWP <= 3800Reсovery system & сylinders +logbook mandatory. Fixed leak

deteсtion svstem req'

10% oftota| сhargeannually.

The tаb|e is intended to be a guide|iпe only. Unitor takes no |egaI rеsponsibility in сase of errors or new regu|ations in the аbove tab|e' as appliсab|e ruIes

and гegu|ations are сonstant|y сhanging.

15

Page 16: UNITOR MARINE REFRIGERANTS

l*treщ*y;жrзt,

9. GLOSSARY

У&ж.n*|*тзщ ffiьзar{*..,, рr|:,i*.:! t*t,'l i

u]llтBвRffBlGЕ'RAТloN sЕRvlсE

Тhe be|ow tab|e explains the most used terms and abbreviations used when working with refrtgerants.

U.S. Air ino and Refriqeration InstituteAmeriсan Soсiety of Refr and Air-

oes not appreсiably сhange in сomposttlon 0r

tempeгatuй as it evaporates or сondenses under сonstant pгessure' Behaves like a sing|e refrigerant

and has no glide'Refiigeгant b|ends assigned R-500 seгies number destgnations by ANSliASHRAЕ 34

Mixture of 2 or more ref nts with different volatilitiesy itabgenated сhbюfluoroсarbon, e.g. R12, R500' R502

Еnvironmenta|burdеn: High 0DP, high GWP

FIuoroсaгbons, Peгf|uoroсarbon ; ated Fluoroсarbonse inсrease while vapour is boiled off at

сonstant pressure. (The most vo|atile сomponБnt ьoit off first) Usual|y used to desоribe the evapoгation

or сondensation of a zeotropiс bIenda сertain GWP. The Kyoto Protoсol

offiсevаIЩFu l | y ha l o gеna t eo t^ . y o r o с a fшe . f i g h t i n gagen t ' R egu l a t e dand i nqenЬral bjnned bу ihe Montгea| Protoсol. Ёnvironmental buгden: High oDP..Цigh GWP.

nejlrtane.Еnt/tronmelrtd burden: No 0DP, low GWP'

пi e.g"R-22andR-401AЕnvironmental burden: Low oDP, High GWP

droоarbon, e.g. R-134а, R.125

Environmental burden: No 0DPn of Greenhouse Gases not сontrol|ed

the Montrea|Protoоol, e.g. HFCs, Methane, Coz.Mineral refri oi l

tгibute to the depletion of the ozone

laver (i.e. have a сertain 0DP)е.g' R12,R22'Iue is R.11, whiсh has oDP=,1

сontain сhlorine or bгomIne.

aolefin rеfriqeration oiI

сonta iner ,e .g .areсOVeryсу l inder .NB:Never

reсover used refrigerants in to empty re!Ц-gglxцщyщщц" - - " ' - . . . J - .

Reuseofareсoveredгeтig@sssuсhasf iIteгinganddryingforremoval of oil, moistuгe and aсid from the1e.!щщц!

restore the substanсе to a speсified

e.o. ARI 700 - 1999of one sinqle сOmponent e.q.R-22 and R-1344

stbhй@efening van het Koe|teсhnisсh

Insta|laiebedгiif (Dutсrr non-profit organizatton to set standards for аnd monitor

Swedish AссreditationtoaссountthedireсtGWPandtheenergyсonsumрtI0n

1йui".j to run thе retrigeration system' The TЕWI is not а refrigeгanlspeсifiс infoгmation, but rather

* сomposition оr temperatuгe as it

iЫ#Ду:lT:oТ.iк:. a given pressure'сausing a temperature g{g:..tРlйl*Рl1*у:::;;:й0.;;й;;;;.;;ъ;ig;;tion in дшsllдsHRA.34 is a zeotrope. NB!AlIzeotropiс blends must

16

Page 17: UNITOR MARINE REFRIGERANTS

Ж*€raщ*r жжt" ffiжrъ*&жmщ ffiьзwffi*10. REFRIGЕRANт LoG "", рr****t у*wr i*v*st,r**tзt

u1l1т8BRЕFRIGЕRAI9N qчv!сЕ

Ёj=

zJЩ.лсl'щ

сФ

=o = . - ЯЕ Y x ^h ч Ё , . =

A Y :> r u i ia

Фe .=с ц т g' = > - h-у)- = =.

о-ээ=

ФбЕФt

с..эФ

Е̂с)o-сEOФо-a

ЕФФ

E эФ 9i i i ^

. o ' , : i '

! u хФ-t n :t r б

. g д 96E #Ё=

с(б. = ' > ,Фt

с.EяE5Ф

Ф(бo

Page 18: UNITOR MARINE REFRIGERANTS

Eж€ r * щ* r жrзk Ж жm ф& яухщ ffi жм **"'. рrоаeсf yо&jr ir,yesfmgflf

Ulllт0RRЕFпIGЕпAТ.ON sЕпvlсЕ

t.IJJz=o

йj=

zJцlслслцJ

сФ

=o - ч

; i * F . :. : J . а ЭO Y :>, (u ifa

БФ ЕЁ o ъ Э

.ч, * :i х.. \ = ' - .=

o-эз=:Фх(бЕФt

с.'ФЕЕФo-с

'F

OФo-a.ЕЕФбФ

.ч, >

Ё Фg

=^! u х

Фё( r б

. g б Р ^

! > \ с -Ф o

сб. = ' >Фt

F.Фя9.5<t)

ФФo

1B

Page 19: UNITOR MARINE REFRIGERANTS

Жж€ r * щ*r жyзk" ffi жra *&жm щ ffi жa ffi ж,". рr****t у*aзr igзv**t{ж*{з{.

U1llт0RRЕЕRlGЕRAТtoN sERvlсE

Ёj=

zJIJJaaлщ

сФ

я х ; ia^

"'i .jч Ё. Е

й Ё P - ->, ru ifa

бe .=с ц f l v' = > = ^.!2t- a Y'

g : . v . =

o-f,

з€Фх6Ес)х'

сt.

ФЕ

Eс)o-с

E

Фо.Ф

ЕФФU)

с эбФх х^.с'): -й,' - E х -Фй-0 . Ё

!0 .й.

Ф Et r Ф

_ t r Ф. g б Р а

E-*ё=

с(б. = ' >Фt

tr.ФяE5ct)

Фбо

19

Page 20: UNITOR MARINE REFRIGERANTS

Ж*#r l,щ*r жmk Wжrъ*&жwзщ &ызl-**,"" gзr*t**t у*язr itзv*strуз*tзt

U1llт0вRЕFRlGЕЕAТloN EERvlсЕ

Ёj=

zJщФФЩ

сU)

. 6 - чяЧ Ч^n * Ё . Ей ё P :> ( U i тU\

б Ф j :

. с P о :

.у'- * =,

. \= *=

эB:

a .хФЕФt

с.'ФЕ

EФo-сE

ФФ.сЕФФФ

E э( бФk k ^.e-, : -v'ё х -ФБt е

Е 6! u хФ_

Б €t r б

Eд 96E *Ёэ

сФ.:' >a

с)t

tr. 0яE5Ф

ФбО

Page 21: UNITOR MARINE REFRIGERANTS

*гз**i.:.12.З Iitre56 litre

12.3 l itre56 Iitre

56 Iitre

,l2.З |itre56 Iitre

12.5 kg57 kg

12.5 kg57 kg

Produсtnumber

591 905621591 905059

592 905620592 905557

b lue

b lue

0rа nge

0range

F i l l i ngweight

Single f lu id. Widely used for low, medium and h igh temperatureapp| icat ions (ЕT _40/+16.С) ' RеguIated by thе 1987 MontreaIProtoсoI.

Lj**q;*..;. ж- € З€*SingIe f|u id. Long-term rep|aсemеnt for R-12. Best performanсein medium аnd high temperature appliсations (ЕT _20/+25"C).

Suitable for new svstems and retrofits.

**Е*:.... ж- €* €&

ijtIiI

Т

Zeotropiс bIend' Inter im repIaоement foranсe in medium and h igh temperatureЗ0/+13.C). SuitabIe for retrofit purposes,

R-12. Best perform-appI icat ions (ЕT _

but regulated by the

Nеar-azeotropiс bIend. Long-term rep|aсement for R-502 and ;R-22. Best performanсе in low and medium temperature ,

lЩ-цlг-Ц]jt! 9l:EugЦ$_:jll.l.-yjlт9'll--.j - - *j .

'l987 MonшcalProtoсoI. -=J -**"-"''.,..'.. rc-4*€&

Zeotropiс bIend. Long-term rep|aсement for R-22. Bestpeгformanсe in medium and h igh temperaturе app| iсat ions(ЕТ _25l+13.С). suitab|e foг new systems and retrofits.

! i i, i l

: 1 11 I i

I 2.3 Iitre 9.5 kg ' ' 5f#,1905623594 90560645 kg

I

1-_'*=:Г II.*Г-i

594 905624594 905607

a

!

1 1 k g52 kg

j

0range-0rown i

orange-0rown i

1 2.5 kg57 kg

pinkpink

*!Эё.:::,,... Ж:€* *& i:Near-azeotropiс bIend' Long-term repIaсеment for R-22' Sultablе i lz.з l it l..for Iow, medium and high temperature appIiсations (ЕT _45/+8"C), sо tlt,..however, the оperation pressure Iimits this to neW systems on|y. !

*г:t*'. ж-€ €?&Zeotropic b|end, Long-term rep|aсemen| for R-22, suitab|e forIoW medium and high temperature app|iсations (ЕТ _З5/+25"C).

Unitor's preferred retrofit solution.

56 litre

ffi-**7 1 2.3 litre56 Iitre

It----**-+---j

51 kq

9.5 kg45 kg

9.5 kg

45 kg

594 905627594 905608

59з 905637

594 905628594 905610

i

I rose!

I f a a l

i teal

greу

Azeotropiс b|end. Long-term rep|aсement for R.502 and R-22'Best performanоe in Iow and medium temperature app| iоat ions i(ЕT _45/+8.С}. Used in new systrms. ]

Ет = ЕVap0rating Temperaturе

)o L't,J.j ' 1 R-12, R-22, R-409A ,R-5o2,R-717 i Spares сentres 605 664128Minera| 0 i I , 30 сst iilffi Б;i:56 ;i | ;oi;i;; ;;; i в lz,п ii, п +osA

''n-ьii,n-tп l spu'..' сentres 605 664136

A|ky|benzene,46сst : on i в-цоlд,R-417A ] SparesCentres i 0.R.дiкylБ.n,.n.. ов..t 0.R. ; п цolд, R-417A . spares сentres i 9. lPoIyolester,32сst j 5Lit ' . .un i п- lзцa,R-404A,R-407с,R4,|0A,R507A 1 Sparesсentres : 605587709PoIуo|ester,68 сst ; '--l-Litt. .un i -п-lзцa, в-цoцд, п.4!ZC, R.410A, B!!ZA- ; -pзrеsleлres -l q85 щ769]lAiiо test ;

' Kit ; Mineral oiI and Alky|benzene j Spares Centres : 606 540088

Page 22: UNITOR MARINE REFRIGERANTS