United States Environmental Protection Agency · GE Global Operations - EHS 159 Plastics Avenue...

$: United States Environmental Protection Agency · GE Global Operations - EHS 159 Plastics Avenue Pittsfield, MA 01201 July 24, 2015 Superfund Records Center SITE f7|r-BREAK OTHER \)i{,$
GE Global Operations - EHS

159 Plastics Avenue Pittsfield, MA 01201

July 24, 2015

Superfund Records Center SITE f7|r-BREAK

OTHER \ ) i { , Mr Richard Fisher (OSRR07-1) ~~ — U S Environmental Protection Agency EPA New England (MC HBO) 5 Post Office Square - Suite 100 Boston, MA 02109-3912

Re GE-Pittsfield/Housatonic River Site Groundwater Management Area 4 (GECD340) Monitoring Event Evaluation Report - Spring 2015

Dear Mr Fisher

Enclosed (in hard copy and on a compact disc) is the General Electric Company's (GE's) Long-Term

Monitoring Program Monitoring Event Evaluation Report - Spring 2015 for Groundwater Management Area (GMA) 4 (also known as the Plant Site 3 GMA) This report was prepared pursuant to Attachment H to the Statement of Work for Removal Actions Outside the River and in accordance with GE's March 2012 Baseline Assessment Final Report and Long-Term Monitoring

Program Proposal for Groundwater Management Area 4, as approved by EPA

The enclosed report summarizes the activities performed at GMA 4 during spring 2015, excluding the activities performed under the post-closure groundwater monitoring program for the On-Plant Consolidation Areas (OPCAs) It includes the results of the latest round of sampling and analysis of groundwater from the GMA 4 monitoring wells and an assessment of those results A separate report will be submitted on the spring 2015 activities under the OPCA post-closure groundwater monitoring program

Please feel free to contact me with any questions or comments

Sincerely yours,

Richard W Gates Senior Project Manager - Environmental Remediation Global Operations - Environment, Health and Safety

Enclosure

OneEHS SDMS DocID 581116

2

cc Dean Taghaferro, EPA Timothy Conway, EPA (cover letter only) Christopher Ferry, ASRC Primus (cover letter + CD-ROM) Scott Campbell, Avatar (2 hard copies + CD-ROM) Michael Gorski, MDEP (cover letter+, CD-ROM) Eva Tor, MDEP (cover letter only by e-mail) Jane Rothchild, MDEP (cover letter only by e-mail) John Ziegler, MDEP (cover letter + CD-ROM) Karen Pelto, MDEP (cover letter only) Nancy E Harper, MA AG (cover letter only) Robert Leitch, USACE (cover letter + CD-ROM) Nate Joyner, Pittsfield Dept of Community Development (cover letter + CD-ROM) Shannon Reilly, General Dynamics Rich Taikowski, Purenergy, LLC Kevin Boland, CSX Transportation (cover letter + CD-ROM) Property Owner - Tax Parcel K10-11-5 (cover letter + CD-ROM) Roderic McLaren, GE (cover letter only) Matthew Calacone, GE Gregory Hencir, AECOM James Bieke, Sidley Austin John Ciampa, Spectra Environmental Public Information Repositories GE Internal Repository

Prepared for: Prepared by: General Electric AECOM Pittsfield, MA Chelmsford, MA 60331701 July 22, 2015

Groundwater Management Area 4 Long-Term Monitoring Program Monitoring Event Evaluation Report Spring 2015

Prepared for: Prepared by: General Electric AECOM Pittsfield, MA Chelmsford, MA 60331701 July 22, 2015

Groundwater Management Area 4 Long-Term Monitoring Program Monitoring Event Evaluation Report Spring 2015

_________________________________ Prepared By Gregory M. Hencir Project Manager

_________________________________ Reviewed By Laura A. Kelmar, PE Project Director

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Contents

1.0 Introduction ............................................................................................................... 1-1

1.1 GMA 4 Description ......................................................................................................1-1

1.2 Format of Document ...................................................................................................1-2

2.0 Groundwater Monitoring Activities .......................................................................... 2-1

2.1 Monitoring Well Inspections and Repairs ......................................................................2-1

2.2 Groundwater Elevation Monitoring ...............................................................................2-1

2.3 Groundwater Sampling and Analysis ...........................................................................2-2

3.0 Groundwater Analytical Results ............................................................................... 3-1

3.1 Summary of Results and Comparison to Performance Standards .................................3-1

3.2 Data Quality Assessment ............................................................................................3-2

4.0 Assessment of Groundwater Quality ....................................................................... 4-3

4.1 General Assessment of Groundwater Quality Data .......................................................4-3

4.2 Evaluation of Need for Further Assessment or Other Response Action .........................4-4

5.0 Future Activities ........................................................................................................ 5-1

5.1 Evaluation of Need for Program Modifications ..............................................................5-1

5.2 Field Activities Schedule ..............................................................................................5-1

5.3 Reporting Schedule .....................................................................................................5-1

6.0 References ................................................................................................................ 6-1

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List of Tables Table Title

1 Groundwater Sampling Program Summary – Spring 2015

2 Groundwater Elevation Monitoring Program Summary – Spring 2015

3 Monitoring Well Construction Summary

4 Groundwater Elevation Data – Spring 2015

5 Field Parameter Measurements

6 Groundwater Analytical Results Compared to MCP Method 1 GW-2 and GW-3 Standards and UCLs

List of Figures Figure Title

1 Site Plan

2 Monitoring Wells in GMA 4 Long-Term Monitoring Program

3 Groundwater Contour Map

List of Appendices Appendix Title

Appendix A Well Maintenance and Groundwater Sampling Logs

Appendix B Laboratory Analytical Reports (on CD-ROM)

Appendix C Data Validation Report

Appendix D Select Graphs on Historical Groundwater Quality Data

Appendix E Summary Statistics on Historical Groundwater Quality Data

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List of Acronyms and Abbreviations AMSL Above mean sea level bgs Below ground surface BMP Below Measuring Point CD Consent Decree EPA Environmental Protection Agency FSP Field Sampling Plan GE General Electric Company GMA Groundwater Management Area LNAPL Light non-aqueous phase liquid MCP Massachusetts Contingency Plan MDEP Massachusetts Department of Environmental Protection µg/L Micrograms per liter NAPL Non-aqueous-phase liquid OPCA On-Plant Consolidation Area PCB Polychlorinated biphenyl PCE Tetrachloroethylene PDB Passive diffusion bag PGC Pittsfield Generating Company QAPP Quality Assurance Project Plan RAA Removal Action Area SGS SGS Environmental Services, Inc. SOW Statement of Work TCE Trichloroethylene UCL Upper Concentration Limit USGS United States Geological Survey VOC Volatile organic compound

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1.0 Introduction

On October 27, 2000, a Consent Decree (CD) executed in 1999 by the General Electric Company (GE), the United States Environmental Protection Agency (EPA), the Massachusetts Department of Environmental Protection (MDEP), and several other government agencies was entered by the United States District Court for the District of Massachusetts. The CD governs (among other things) the performance of response actions to address polychlorinated biphenyls (PCBs) and other hazardous constituents in soil, sediment, and groundwater in several Removal Action Areas (RAAs) located in or near Pittsfield, Massachusetts that collectively comprise the GE-Pittsfield/Housatonic River Site (the Site).

For groundwater and non-aqueous-phase liquid (NAPL), the RAAs at and near the GE Pittsfield facility have been divided into five separate Groundwater Management Areas (GMAs). These GMAs are described, together with the Performance Standards established for the response actions at and related to them, in Section 2.7 of the Statement of Work for Removal Actions Outside the River (SOW) (Appendix E to the CD), with further details presented in Attachment H to the SOW (Groundwater/ NAPL Monitoring, Assessment, and Response Programs). This report relates to the Plant Site 4 Groundwater Management Area, also known as and referred to herein as GMA 4, excluding the groundwater sampling activities associated with the Hill 78 and Building 71 On-Plant Consolidation Areas (OPCAs), which are located within the boundary of GMA 4, but are subject to a separate groundwater monitoring program.

In accordance with the CD and Attachment H of the SOW, baseline groundwater monitoring within GMA 4 began in 2000 and continued with extended baseline monitoring (known as the interim monitoring program) from Spring 2002 through Fall 2011, ending after closure of the OPCAs and the completion of the soil-related remediation work at the areas within GMA 4. In March 2012, GE submitted a Baseline Assessment Final Report and Long-Term Monitoring Program Proposal for Groundwater Management Area 4 (GMA 4 Long-Term Monitoring Proposal), which was conditionally approved by EPA on May 11, 2012. The long-term monitoring program proposed in that report was initiated in Spring 2012. The last prior report submitted under this program, the Long-Term Monitoring Program Monitoring Event Evaluation Report, Fall 2014 (GMA 4 Fall 2014 Report), was submitted on February 23, 2015 and conditionally approved by EPA on May 1, 2015.

GE conducted the most recent round of the required long-term groundwater elevation monitoring and sampling activities in Spring 2015. This report describes the groundwater monitoring conducted during the Spring 2015 monitoring period, presents the results obtained, and provides GE’s assessment of those results.

1.1 GMA 4 Description GMA 4 is located within the mid-eastern portion of the GE Plant Area and encompasses the Hill 78 and Building 71 OPCAs. It includes the Hill 78 Area-Remainder RAA and the portion of the Unkamet Brook Area RAA located to the west of Plastics Avenue. GMA 4 occupies an area of approximately 68 acres, generally bounded by Tyler Street/Tyler Street Extension to the north, Merrill Road to the south, Plastics Avenue to the east, and New York Avenue to the west, as illustrated on Figure 1. The Hill 78 and Building 71 OPCAs (subject to a separate groundwater monitoring program) are located within the central portion of this GMA, which also contains a power generating facility operated by Pittsfield Generating Company (PGC) under a ground lease from GE. The eastern portion of this GMA is mostly paved or covered by Buildings OP-1 and OP-2, which contain operations of General Dynamics Corporation conducted under contract with the U.S. Department of the Navy. (GE continues to own the land beneath those buildings.)

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The Removal Action performed by GE at the Hill 78 Area-Remainder RAA generally included site preparation, soil removal/replacement, and property restoration. These activities were conducted in phases between October 2007 and December 2008, with certain additional restoration activities conducted in April 2010. A Final Completion Report for the Hill 78 Area-Remainder Removal Action was submitted to EPA on August 30, 2011 and EPA issued a Certificate of Completion for this RAA on September 6, 2011.

With respect to the portion of the Unkamet Brook Area RAA that is located within GMA 4 (i.e., the portion west of Plastics Avenue), GE’s April 2011 Revised Final Removal Design/Removal Action Work Plan for Unkamet Brook Area-West, as approved by EPA, demonstrates that no soil remediation is necessary in that portion of this RAA.

Small amounts of light non-aqueous-phase liquid (LNAPL) were occasionally detected at former GMA 4 well H78B-8R from May 1999 to May 2001 and from June 2002 to June 2003, when that well was decommissioned as part of the OPCA construction. Measurable LNAPL has never been recorded in any adjacent or downgradient locations. Since the decommissioning of well H78B-8R in 2003, LNAPL has not been observed at any wells within GMA 4.

Very few constituents have been consistently detected in groundwater at GMA 4, and the observed detections were sporadic, resulting in an apparent scattered distribution of occasionally detected constituents throughout the baseline groundwater monitoring program. The sampling program was optimized based on the analytical results obtained throughout the program, concluding in the need for further analysis of volatile organic compounds (VOCs) only. In accordance with EPA’s May 8, 2014 conditional approval of the GMA 4 Fall 2013 Trend Evaluation Report and an April 3, 2014 communication between EPA and GE, passive diffusion bags (PDBs) are now utilized for this groundwater quality monitoring.

1.2 Format of Document This report consists of six sections. A basic description of each section follows.

Section 1. Presents an introduction and background to the long-term monitoring program.

Section 2. Describes the groundwater-related activities performed at GMA 4 in Spring 2015.

Section 3. Presents the analytical results obtained during the Spring 2015 sampling event, a summary of the applicable groundwater quality Performance Standards identified in the CD and SOW, and a comparison of the Spring 2015 results to those Performance Standards.

Section 4. Provides an overall assessment of groundwater quality at GMA 4, including an evaluation of the analytical dataset for the wells that were sampled as part of the Spring 2015 sampling event, and an assessment of the need for follow-up investigations or response actions.

Section 5. Evaluates the need for modifications to the long-term monitoring program for GMA 4 and presents the schedule for future field and reporting activities related to groundwater quality at GMA 4.

Section 6. References previous reports and documents.

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Additional supporting information is provided in tables, figures, and appendices.

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2.0 Groundwater Monitoring Activities

The activities conducted as part of the long-term groundwater monitoring program in Spring 2015 involved measurement of groundwater levels and the collection and analysis of groundwater samples at select monitoring wells within and downgradient of GMA 4, as summarized in Tables 1 and 2. Table 1 presents the long-term groundwater quality sampling program and Table 2 summarizes the long-term groundwater elevation monitoring program. The groundwater elevation monitoring program summarized in Table 2 also includes several adjacent monitoring wells in the OPCA area and GMA 1 as well as wells monitored by EPA at the Allendale School property. The monitoring wells in these programs are shown on Figure 2, and a summary of monitoring well construction details for each such well is provided in Table 3. GE also performed inspections of the monitoring wells, as summarized in Appendix A. Groundwater elevation monitoring and well inspections were performed mainly on April 6, 2015 and the collection of groundwater samples for analysis was conducted on April 20. This section discusses the field procedures used to perform the activities listed above, as well as the methods used to analyze the groundwater samples. All activities were performed in accordance with GE’s approved Field Sampling Plan/Quality Assurance Project Plan (FSP/QAPP), dated July 2013, and the EPA-approved GMA 4 Long-Term Monitoring Program Proposal.

2.1 Monitoring Well Inspections and Repairs Routine monitoring well inspections were performed on April 6, 2015, with one well inspected on April 13. A summary of those inspections, including information regarding any potential sediment deposition and the need for any maintenance, is provided as Table A-1 in Appendix A.1 As shown in that table, no maintenance issues requiring repairs were noted during the Spring 2015 monitoring period.

2.2 Groundwater Elevation Monitoring In early April 2015, groundwater elevations were recorded in 12 monitoring wells in GMA 4, along with several adjacent monitoring wells at GMA 1 and the OPCA area and at wells monitored by EPA at the Allendale School property. Groundwater elevations measured in Spring 2015 are provided in Table 4. A Spring 2015 groundwater contour map is included as Figure 3.

Consistent with prior monitoring results, no NAPL was observed in any of the GMA 4 monitoring wells during the groundwater elevation and sampling activities conducted in Spring 2015.

As shown on Figure 3, the groundwater flow directions are generally consistent with those observed during previous seasonal monitoring events. A comparison of the groundwater elevation contours with the top-of-till contours presented in the Long-Term Monitoring Program Monitoring Event Evaluation Report for Spring 2014 (approved by EPA on September 11, 2014) continues to show, as stated in that report, that groundwater elevations are generally correlated with changes in the elevation of the glacial till interface. Specifically, groundwater generally flows from north to south, although variations exist corresponding to changes in the topography of the ground surface and/or the

1 In the GMA 4 Fall 2014 Report, Table A-1 indicated that several wells in GMA 4 (RF-15 and UB-MW-5) and the OPCA area (78-3 and UB-MW-6) had potential sediment deposition of greater than one foot and would be re-assessed for re-development in Spring 2015. However, these wells were not re-developed because they showed no differences of greater than one foot when re-measured during the Spring 2015 gauging round, as shown in Table A-1 in Appendix A.

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glacial till interface, including a prominent groundwater depression across the western portion of the GMA.

The EPA monitoring data from the Allendale School property are generally consistent with the groundwater contours presented in the GMA 4 and OPCA semi-annual reports since Spring 2008. Groundwater elevations are highest at the locations adjacent to the school and decrease to the south (i.e., groundwater flows from the Allendale School property toward the OPCAs), providing confirmation that the OPCAs are downgradient from the Allendale School property.

In addition, at EPA’s direction, GE reviewed the Housatonic River flow data collected at the U.S. Geological Survey (USGS) gauging station in Coltsville, Massachusetts during the groundwater elevation monitoring and sampling events. The peak daily river flow data ranged from 228 to 679 cubic feet per second (cfs) during the groundwater elevation monitoring and sampling period from April 6 through 20, 2015. A peak instantaneous flow rate of 679 cfs was recorded on April 14, 2015, during a light rain event.

2.3 Groundwater Sampling and Analysis Long-term groundwater sampling was completed at the four monitoring wells in the long-term sampling program on April 20, 2015. These wells are listed in Table 1 and shown on Figure 2. Each well was sampled via PDB in accordance with EPA’s May 8, 2014 conditional approval of the GMA 4 Fall 2013 Trend Evaluation Report and an April 3, 2014 communication between EPA and GE.

The PDBs were deployed on April 6, 2015. After the PDBs had equilibrated (for a period of greater than two weeks as per regulatory guidelines), they were removed on April 20, 2015 and samples were collected. PDBs do not require low-flow purging; however, field parameters (including depth to water, temperature, pH, specific conductivity, turbidity, dissolved oxygen, and, oxidation-reduction potential) were measured, utilizing a peristaltic pump to retrieve a water sample and an In-Situ SmarTroll® to make the measurements, as documented in Table 5.

The collected groundwater samples were submitted to SGS Environmental Services Inc. (SGS), located in Wilmington, North Carolina, for laboratory analysis. The samples collected during this event were submitted for analysis of VOCs via EPA Method 8260.

Following receipt of the analytical data from the laboratories, the preliminary results were reviewed for completeness, validated, and compared to the applicable Performance Standards, which are based on the Massachusetts Contingency Plan (MCP) Method 1 GW-2 and GW-3 standards, and to the MCP Upper Concentration Limits (UCLs) for groundwater, as summarized in Table 6 and discussed in Section 3.1.

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3.0 Groundwater Analytical Results

This section summarizes the laboratory analytical results for the groundwater samples collected in Spring 2015 and compares them to the applicable GW-2 and GW-3 Performance Standards and to the MCP UCLs for groundwater. It also summarizes the data quality assessment of those data. A further assessment of those results is presented in Section 4.

3.1 Summary of Results and Comparison to Performance Standards The analytical results for the groundwater samples collected in Spring 2015 are summarized in Table 6. That table also compares the results to the applicable GW-2 and GW-3 Performance Standards and to the MCP groundwater UCLs. The laboratory analytical reports are provided in Appendix B.

The Performance Standards applicable to groundwater at GMA 4 are specified in Section 2.7 and Attachment H (Section 4.1) of the SOW. In general, the Performance Standards for groundwater quality are based on the groundwater classification categories designated in the MCP. The MCP identifies three potential groundwater categories that may be applicable to a given site. One of these, GW-1 groundwater, applies to groundwater that is a current or potential source of potable drinking water. None of the groundwater at any of the GMAs at the Site is classified as GW-1. However, the remaining MCP groundwater categories are applicable to GMA 1 and are described below:

GW-2 groundwater is defined as groundwater that is a potential source of vapors to the indoor air of buildings. Groundwater is classified as GW-2 if it is located within 30 feet of an existing occupied building and has an average annual depth below ground surface (bgs) of 15 feet or less.2

GW-3 groundwater is defined as groundwater that discharges to surface water. By MCP definition, all groundwater at a site is classified as GW-3 since it is considered to ultimately discharge to surface water.

The four monitoring wells sampled within GMA 4 during Spring 2015 (GMA4-7S, GMA4-8, GMA4-9, and H78B-16) do not meet the definitional requirements for GW-2 wells. However, as required by EPA, the analytical results from those wells are compared to the MCP Method 1 GW-2 standards as benchmarks for informational purposes only. In addition, the results from these four wells are compared with the MCP Method 1 GW-3 standards (for long-term compliance) and to the MCP UCLs for groundwater.

Based on laboratory analytical results from the Spring 2015 long-term monitoring event, VOCs were not reported or estimated (J-flagged)3 at concentrations exceeding laboratory reporting limits with the following exceptions:

2 In addition, the SOW specifies a concentration of 5 parts per million (ppm), equivalent to 5,000 micrograms per liter (µg/L), of total VOCs as a notification level for GW-2 wells located within 30 feet of a school or occupied residential structure and as a trigger level in GW-2 wells (if associated with an exceedance of a GW-2 standard) for the proposal of interim response actions. 3 J-flagged indicates an estimated value.

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Acetone was estimated in the samples collected from all four wells sampled (GMA4-7S, GMA4-8, GMA4-9 and H78B-16) at concentrations ranging from 11.30 J micrograms per liter (µg/L) to 33.00 J µg/L. These results are well below the GW-2 benchmark level of 50,000 µg/L and the GW-3 standard at the same level.

2-Butanone (also known as methyl ethyl ketone) was estimated at a concentration of 3.12 J µg/L in the sample collected from well GMA4-8. This result is well below the GW-2 benchmark level of 50,000 µg/L and the GW-3 standard at the same level.

Chloroform was estimated in the sample collected from GMA4-7S at a concentration of 0.85 J µg/L (with duplicate of 0.87 J µg/L), which is well below the GW-2 benchmark level of 50 µg/L and the GW-3 standard of 20,000 µg/L.

Tetrachloroethylene (PCE) was detected or estimated in samples from wells GMA4-9 and H78B-16 at concentrations of 89.20 µg/L and 0.22 J µg/L, respectively. The concentration detected at well GMA4-9 is above the GW-2 benchmark level of 50 µg/L, but is well below the GW-3 Performance Standard of 30,000 µg/L.

Trichloroethylene (TCE) was detected or estimated in samples collected from wells GMA4-7S, GMA4-9 and H78B-16 at concentrations of 0.19 J µg/L, 2.80 J µg/L and 20.20 µg/L, respectively. The concentration detected at H78B-16 exceeded the GW-2 benchmark level of 5 µg/L, but is well below the GW-3 Performance Standard of 5,000 µg/L.

Total VOC concentrations ranged from 14.54 µg/L detected in the sample collected from GMA4-7S to 125 µg/L in the sample collected from GMA4-9. None of the samples exhibited total VOC concentrations above the notification level of 5,000 µg/L for certain GW-2 wells.

In summary, the only constituents that exceeded the GW-2 benchmark levels were PCE in well GMA4-9 and TCE in well H78B-16 (both of which have previously exceeded the GW-2 benchmarks in those wells); and no compounds were detected in any sample collected during the Spring 2015 monitoring event above their corresponding MCP Method 1 GW-3 standards or above the MCP UCLs for groundwater.

3.2 Data Quality Assessment The laboratory data were validated in accordance with the approved FSP/QAPP, with the Data Validation Report provided as Appendix C. As shown in that memo, 96.4% of the Spring 2015 groundwater quality data are considered to be useable, which is greater than the minimum required usability of 90% as specified in the FSP/QAPP.

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4.0 Assessment of Groundwater Quality

An overall assessment of the groundwater quality data at GMA 4 has been conducted based on the laboratory results obtained during the Spring 2015 groundwater sampling event, supplemented with historical groundwater analytical data obtained during the course of the GMA 4 baseline, interim, and long-term groundwater monitoring programs, when applicable to evaluate variations and/or potential trends in constituent concentrations in GMA 4 groundwater.

The following sections present the results of that overall assessment of groundwater quality and an evaluation of the need for follow-up investigations, assessments, or interim response actions.

4.1 General Assessment of Groundwater Quality Data As noted above, the analytical results for the groundwater samples collected in Spring 2015 are summarized in Table 6, which compares results to the MCP Method 1 GW-2 standards (for benchmark purposes only) and GW-3 standards (for compliance) and to the MCP UCLs for groundwater. These results are discussed below in the context of the historical analytical dataset for these wells. Graphs of concentrations over time for the two wells sampled during Spring 2015 that have shown exceedances of the GW-2 benchmark levels for PCE (well GMA4-9) or TCE (well H78B-16) are provided in Appendix D. Summary statistics of the historical results at the four wells in the long-term sampling program are provided in Appendix E.

As shown in Table 6, 2-butanone, a common laboratory contaminant, was estimated in monitoring well GMA4-8 at a concentration of 3.12 J µg/L, which is far below the GW-2 and GW-3 standards of 50,000 µg/L. This is the first occurrence of 2-butanone in samples collected from any of the four monitoring wells in the GMA 4 long-term sampling program. GE will continue to monitor 2-butanone (along with other VOCs) in GMA 4 to determine if the occurrence of 2-butanone is an anomaly.

Of the monitoring wells sampled during Spring 2015 (GMA4-7S, GMA4-8, GMA4-9 and H78B-16), no constituent has ever been detected at a concentration greater than its respective GW-3 standard or UCL. Only three VOCs have ever been detected above GW-2 benchmark levels in samples collected from these four monitored wells: TCE and vinyl chloride in well H78B-16 and PCE in well GMA4-9. The results for these constituents in these wells are discussed further below. Total VOC concentrations have not been measured above the GW-2 notification level of 5,000 µg/L in any well sampled.

TCE has been detected during all 20 sampling events at well H78B-16, with an average concentration of 61.90 µg/L, which is above the current GW-2 benchmark level of 5 µg/L, but well below the GW-3 Performance Standard of 5,000 µg/L (see graph for this well in Appendix D). In the Spring 2015 sampling event, TCE was detected in this well at a concentration of 20.20 µg/L, which is again above the GW-2 benchmark level, but is below the average concentration of TCE in well H78B-16 and significantly less than the peak concentrations in 2003 and 2004 (160-180 µg/L). Over the last five years, concentrations of TCE in well H78B-16 have fluctuated between 15 and 80 µg/L (with one PDB sample at 110 µg/L during Fall 2013) and have shown no clear trend.

Vinyl chloride has been detected in the majority of the samples collected from well H78B-16 (14 of 20 sampling events), with an average concentration of 3.90 µg/L (above the GW-2 benchmark level of 2 µg/L). However, as in Fall 2014, that constituent was not detected in Spring 2015.

PCE has been detected in all sampling rounds at well GMA4-9, with an average concentration of 93.20 µg/L, which is above the GW-2 benchmark level of 50 µg/L, but well below the GW-3

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Performance Standard of 30,000 µg/L (see graph for this well in Appendix D). In the Spring 2015 sampling round, PCE was detected in this well at a concentration of 89.20 µg/L, which is again above the GW-2 benchmark level, but is slightly below the average concentration of PCE in well GMA4-9 and well below the peak concentrations in 2009-2011 (175 to 356 µg/L). In the more recent years, there is no clear trend in PCE concentrations in this well, with concentrations sometimes exceeding the GW-2 benchmark level and sometimes not.

As the long-term monitoring program at GMA 4 progresses, GE will conduct additional trend evaluations, including an additional statistical trend assessment following the Fall 2015 sampling round.

4.2 Evaluation of Need for Further Assessment or Other Response Action As summarized above, VOCs within GMA 4 were not detected or estimated above the GW-3 Performance Standards or UCLs. Two compounds, TCE and PCE, were detected above their associated GW-2 benchmark levels in monitoring wells H78B-16 and GMA4-9, respectively.

As indicated above, recent TCE concentrations detected in monitoring well H78B-16 have decreased below the peak levels of 2003 and 2004 (160-180 µg/L). Concentrations in Fall 2014 and Spring 2015 were 32.50 µg/L and 20.20 µg/L, respectively, both of which remain above the GW-2 benchmark level of 5 µg/L, but are below the average concentration (61.90 µg/L) detected at this location. Recent PCE concentrations detected in monitoring well GMA4-9 have decreased below peak levels detected in 2009 through 2011 (175-356 µg/L), with concentrations fluctuating from as low as 1.41 µg/L (in Fall 2014) to 97.80 µg/L (in Spring 2014). GE is further addressing VOCs in this area by sampling downgradient location GMA4-7S as part of the long-term monitoring program. Well GMA4-7S is upgradient of occupied buildings along and to the south of East Street and is more relevant to the assessment of GW-2 compliance. No constituents have ever been detected at levels above their respective GW-2 benchmark levels at this location. In addition, as part of its OPCA post-closure groundwater monitoring program, GE is performing GW -2 monitoring at several monitoring wells upgradient of well H78B-16, including three GW-2 compliance wells (i.e., wells H78B-15, OPCA-MW-4, and OPCA-MW-5R) located near the PGC facility building. As will be discussed in more detail in GE’s forthcoming OPCA Post-Closure Groundwater Monitoring Event Evaluation Report – Spring 2015, the results from those three GW-2 compliance wells have shown no constituent concentrations above applicable GW-2 standards in Spring or Fall 2014 or again in Spring 2015.

GE proposes to continue to sample wells GMA4-7S, GMA4-8, GMA4-9, and H78B-16 under the current long-term monitoring program for GMA 4. Based on the results from the Spring 2015 sampling round, no consistent increasing trends in constituent concentrations are evident, and there have been no wells at which any detected concentration suggests the need for an interim response action. If any exceedances of the groundwater-related Performance Standards are observed at GMA 4, GE will evaluate the need for appropriate response actions and will propose necessary actions for EPA approval. As discussed further in Section 5.3, GE will include a more detailed discussion of trends in groundwater quality at these wells in the next Long-Term Trend Evaluation Report for GMA 4, which is scheduled to be submitted following the Fall 2015 sampling event.

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5.0 Future Activities

GE has reviewed the results of its groundwater-related activities conducted at GMA 4 in Spring 2015, including the groundwater analytical data from the Spring 2015 sampling event and prior analyses, for results that would indicate the need to modify the long-term monitoring program. The results of the evaluation of the need for program modifications are discussed in Section 5.1 below. This section also summarizes the approved activities and schedule for upcoming long-term monitoring events and associated reporting activities.

5.1 Evaluation of Need for Program Modifications Based on the results of the Spring 2015 sampling round and the evaluation of data relative to the applicable Performance Standards (further detailed in Section 4), GE does not propose to make any modifications to the locations to be sampled or analyses to be performed as part of the long-term monitoring program. The need for such modifications will be evaluated further in the Long-Term Trend Evaluation Report for GMA 4 following the Fall 2015 sampling event.

5.2 Field Activities Schedule GE anticipates that the Fall 2015 semi-annual long-term monitoring event for GMA 4 will take place in October 2015. A round of groundwater elevation monitoring at the GMA 4 wells (and adjacent areas) where such monitoring is required will be performed at that time, followed by PDB deployment. PDBs will be retrieved and sampled at least two weeks after deployment. Prior to performance of these field activities, GE will provide EPA with 7 days advance notice to allow the assignment of oversight personnel.

5.3 Reporting Schedule Under the previously approved reporting schedule for this GMA, Long-Term Trend Evaluation Reports for GMA 4 are to be prepared at two-year intervals over the duration of the long-term monitoring program, unless an alternate schedule is proposed by GE and approved by EPA. The next Long-Term Trend Evaluation Report for GMA 4 is scheduled to be submitted in place of the Fall 2015 Monitoring Event Evaluation Report. That report will be submitted within 75 days following receipt of the final analytical data packages from the Fall 2015 sampling event. In accordance with the GMA 4 Long-Term Monitoring Proposal, that report will include a presentation of the Fall 2015 groundwater monitoring and sampling results, and will also present an overall assessment of the data from the long-term monitoring program at this GMA, including a statistical evaluation of potential groundwater quality trends at this GMA and an evaluation of the need for any modifications to the long-term monitoring program.

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6.0 References

AECOM, Groundwater Management Area 4 Long-Term Monitoring Program Monitoring Event Evaluation Report, Fall 2014, February 2015.

ARCADIS, Groundwater Management Area 4 Long-Term Monitoring Program Monitoring Event Evaluation Report for Spring 2014, July 2014.

ARCADIS, Field Sampling Plan/Quality Assurance Project Plan (FSP/QAPP), General Electric Company, Pittsfield, Massachusetts, Revision 5, July 2013.

ARCADIS, Baseline Assessment Final Report and Long-Term Monitoring Program Proposal for Groundwater Management Area 4, March 2012.

EPA, Letter from Fisher (EPA) to Gates (GE), EPA Conditional Approval of General Electric’s February 23, 2015 submittal titled Groundwater Management Area 4, Monitoring Event Evaluation Report – Fall 2014, GE-Pittsfield/Housatonic River Site, May 1, 2015.

EPA, Letter from Fisher (EPA) to Gates (GE), EPA Conditional Approval of General Electric’s March 7, 2014 submittal titled Groundwater Management Area 4, Long-Term Trend Evaluation Report for Fall 2013, GE-Pittsfield/Housatonic River Site, May 8, 2014.

EPA, Letter from Fisher (EPA) to Gates (GE), EPA Conditional Approval of General Electric’s March 5, 2012 submittal titled Groundwater Management Area 4, Baseline Assessment Final Report and Long-Term Monitoring Program Proposal for Groundwater Management Area 4, GE-Pittsfield/Housatonic River Site, May 11, 2012.

EPA, Letter from Fisher (EPA) to Gates (GE), EPA Approval of, and Certificates of Completion for, General Electric’s submittal entitled Final Completion Report for the Hill 78 Area-Remainder Removal Action, September 6, 2011.

Tables

GMA4-8 GW-2 Sentinel, GW-3 General/Source Area Sentinel Semi-AnnualGMA4-9 GW-2 Sentinel, GW-3 Perimeter (Downgradient) Semi-AnnualH78B-16 GW-2 Sentinel, GW-3 General/Source Area Sentinel Semi-AnnualGMA4-7S GW-2 Sentinel, GW-3 General/Source Area Sentinel Semi-AnnualNotes:All samples collected using passive diffusion bags.

Pittsfield, Massachusetts

Analysis

Table 1Groundwater Sampling Program Summary

Long-Term Monitoring ProgramGroundwater Management Area 4

General Electric Company

VOCs = Volatile organic compounds analyzed by EPA method 8260.

Well IDMonitoringFrequency

Monitoring Well Usage

VOCs

XXXX

Table 1 GMA 4 Sampling Summary.xlsx Page 1 of 1

060B-R Semi-AnnualGMA4-2 Semi-AnnualGMA4-3 Semi-AnnualH78B-16 Semi-AnnualNY-3 Semi-AnnualRF-14 Semi-AnnualRF-15 Semi-AnnualUB-MW-5 Semi-AnnualGMA4-5 Semi-AnnualGMA4-8 Semi-AnnualGMA4-9 Semi-AnnualGMA4-7S Semi-Annual

PZ-1 Semi-AnnualPZ-2 Semi-AnnualPZ-3 Semi-AnnualPZ-4 Semi-AnnualSCH-1 Semi-Annual

78-1 Semi-Annual78-6R Semi-AnnualGMA4-6 Semi-AnnualH78B-15 Semi-AnnualOPCA-MW-1RR Semi-AnnualOPCA-MW-2R Semi-AnnualOPCA-MW-3 Semi-AnnualOPCA-MW-4 Semi-AnnualOPCA-MW-5R Semi-AnnualOPCA-MW-6 Semi-AnnualOPCA-MW-7 Semi-AnnualOPCA-MW-8R Semi-Annual78-2 Semi-Annual78-3 Semi-AnnualGMA4-1 Semi-AnnualGMA4-4 Semi-AnnualGMA4-8 Semi-AnnualGMA4-9 Semi-AnnualH78B-13R Semi-AnnualH78B-17R Semi-AnnualNY-2 Semi-AnnualNY-4 Semi-AnnualUB-MW-6 Semi-Annual

ESI-05 Semi-AnnualESI-20 Semi-AnnualNotes:1. Allendale School Wells Gauged by EPA.


GMA 1 Monitoring Wells

Table 2Groundwater Elevation Monitoring Program Summary


General Electric Company

Well IDMonitoringFrequency

Allendale School (see Note 1)

OPCA Monitoring Wells

GMA 4 Monitoring Wells

Table 2 GMA 4 Gauging Summary.xlsx Page 1 of 1

Survey Coordinates

Northing EastingGMA 4 Monitoring Wells

060B-R 534740.20 135328.00 2.00 1,003.04 1,002.79 12.00 10.00 991.04 981.0478-4 535014.00 136554.90 4.00 998.81 998.52 5.31 15.00 993.50 978.50

78-5R 534944.00 136219.20 2.00 997.96 997.36 4.00 15.00 993.96 978.96GMA4-2 536218.10 137516.30 2.00 1,006.56 1,006.30 9.93 10.00 996.63 986.63GMA4-3 536289.20 137999.50 2.00 1,004.64 1,004.36 16.59 10.00 988.05 978.05H78B-16 535040.80 136495.50 1.00 995.60 999.16 3.60 10.00 992.00 982.00

NY-3 535508.40 135077.10 2.00 1,005.79 1,005.30 10.12 15.00 995.67 980.67RF-14 536833.60 137753.70 4.00 1,002.23 1,001.91 7.33 15.00 994.90 979.90RF-15 535638.20 137803.00 2.00 1,012.61 1,012.18 9.43 15.00 1,003.18 988.18SCH-4 535975.46 136030.74 2.00 1,012.27 1,014.05 7.90 10.00 1,004.37 994.37

UB-MW-5 536364.60 137001.00 2.00 1,006.70 1,006.48 7.42 10.00 999.28 989.28Wells Downgradient of GMA 4

GMA4-7S 534591.50 136528.70 2.00 999.90 1,001.64 10.00 15.00 989.90 974.90GMA4-7D 534592.50 136535.50 2.00 1,000.00 1,002.15 25.00 15.00 975.00 960.00

COMM-MW-6 534133.10 136707.80 2.00 988.04 987.65 8.00 10.00 980.04 970.04Additional Nearby Wells Monitored In Spring 2015 (see Note 3)OPCA Sampling Wells

78-1 536143.00 136345.00 4.00 1,026.56 1,026.32 7.16 15.00 1,019.40 1,004.4078-6 535917.90 135919.00 4.00 1,012.33 1,012.00 3.00 15.00 1,009.33 994.33

78-6R 535909.40 135904.70 4.00 1,012.08 1,011.70 3.27 14.60 1,008.81 994.22GMA4-6 535774.20 135658.40 2.00 1,009.63 1,009.13 3.01 10.00 1,006.62 996.62H78B-15 535408.90 136705.20 0.75 1,010.30 1,012.68 6.50 10.00 1,003.80 993.80

OPCA-MW-1RR 535367.60 135561.10 2.00 1,016.63 1,016.42 18.00 10.00 998.63 988.63OPCA-MW-2R 535176.60 135892.10 2.00 1,016.80 1,018.84 10.00 15.00 1,006.80 991.80OPCA-MW-3 535299.60 136188.90 2.00 1,015.27 1,014.83 17.97 10.00 997.30 987.30OPCA-MW-4 535570.50 136222.30 2.00 1,019.27 1,018.67 12.07 10.00 1,007.20 997.20

OPCA-MW-5R 535630.00 136477.40 2.00 1,016.61 1,016.29 11.22 10.00 1,005.39 995.39OPCA-MW-6 535449.70 136901.20 2.00 1,022.82 1,022.24 15.12 10.00 1,007.70 997.70OPCA-MW-7 535673.70 136835.80 2.00 1,027.26 1,026.54 14.36 10.00 1,012.90 1,002.90

OPCA-MW-8R 535981.60 136687.00 3.00 1,028.80 1,030.70 5.10 20.00 1,023.70 1,003.70Additional Wells Monitored Under Post-Closure Program for the OPCAs

78-2 536411.70 136892.70 4.00 1,034.44 1,033.94 5.54 15.00 1,028.90 1,013.9078-3 535126.60 137132.70 3.00 1,007.28 1,006.87 9.18 15.00 998.10 983.10

GMA4-1 535134.40 136407.20 2.00 1,012.35 1,012.01 13.30 15.00 999.05 984.05GMA4-4 535332.20 135149.40 2.00 996.55 999.64 4.95 15.00 991.60 976.60GMA4-8 535107.40 135562.70 2.00 1,020.90 1,020.42 10.00 22.00 1,010.90 988.90GMA4-9 535004.40 136153.10 2.00 1,000.00 1,002.28 3.00 12.00 997.00 985.00

H78B-13R 534740.20 135327.90 2.00 993.23 992.93 5.00 15.00 988.23 973.23H78B-17R 534996.00 136659.20 4.00 999.20 1,000.31 14.30 9.30 984.90 975.60

NY-2 534802.40 135675.80 4.00 993.70 996.54 9.50 15.00 984.20 969.20NY-4 535669.20 135360.10 2.00 1,024.54 1,024.69 17.00 15.00 1,007.54 992.54

UB-MW-6 535541.50 137463.00 2.00 1,021.09 1,020.12 26.54 10.00 994.55 984.55Allendale School Property Monitoring Wells/Piezometers (see Note 4)

Allendale-PZ-1 535900.23 135753.22 1.25 NR 1,005.60 NR 1.50 1,002.10 1,000.60Allendale-PZ-2 536112.14 135563.58 1.25 NR 1,009.89 NR 1.50 1,006.39 1,004.89Allendale-PZ-3 536396.28 135728.63 1.25 NR 1,010.43 NR 1.50 1,006.93 1,005.43Allendale-PZ-4 536116.06 136119.15 1.25 NR 1,007.96 NR 1.50 1,004.46 1,002.96

SCH-1 536574.57 135606.24 2.00 1,017.59 1,017.11 9.20 10.00 1,008.39 998.39GMA 1 Monitoring Wells

ES1-05 534749.31 135063.74 2.00 1,023.25 1,022.75 34.86 10.00 988.39 978.39ES1-20 535314.82 134924.90 0.75 997.82 1,001.56 6.00 10.00 991.82 981.82

Commercial Street Site Monitoring WellGMA4-5 534525.10 136816.60 2.00 993.28 993.16 7.72 10.00 985.56 975.56

Notes:1. AMSL - Above mean sea level.2. BGS - Below ground surface.

Top of Screen

Elevation (Feet AMSL)

5. Certain monitoring wells were modified and re-surveyed during Spring 2012. Current well specification and elevation data are provided above.

3. These additional wells were monitored by GE or EPA as part of groundwater monitoring programs at groundwater management areas adjacent to GMA 4. The data obtained at these wells was utilized to supplement monitoring results from the GMA 4 sampling wells and additional monitoring locations in the preparation of groundwater elevation contour mapping.

Table 3Monitoring Well Construction Summary

Long-Term Groundwater Monitoring ProgramGroundwater Management Area 4

General Electric CompanyPittsfield, Massachusetts

4. The Allendale School Property Monitoring Wells/Piezometers are monitored by EPA.

Well ID Well Diameter (Inches)

Ground Surface Elevation

(Feet AMSL)

Measuring Point Elevation

(Feet AMSL)

Depth to Top of Screen

(Feet BGS)

Screen Length (Feet)

Base of Screen

Elevation (Feet AMSL)

Table 3 GMA 4 Well Construction.xlsx Page 1 of 1

GMA 4 Long-Term Monitoring Program Wells Sampled In Spring 2015GMA4-7S 4/6/2015 999.90 1,001.64 16.69 984.95GMA4-8 4/6/2015 1,020.90 1,020.42 25.43 994.99GMA4-9 4/6/2015 1,000.00 1,002.28 9.15 993.13H78B-16 4/6/2015 995.60 999.16 11.26 987.90

Other GMA 4 Wells Monitored In Spring 2015060B-R 4/6/2015 1,003.04 1,002.79 15.35 987.44GMA4-2 4/6/2015 1,006.56 1,006.30 11.92 994.38GMA4-3 4/6/2015 1,004.64 1,004.36 17.52 986.84

NY-3 4/6/2015 1,005.79 1,005.30 14.86 990.44RF-14 4/6/2015 1,002.23 1,001.91 8.53 993.38RF-15 4/6/2015 1,012.61 1,012.18 14.04 998.14

UB-MW-5 4/6/2015 1,006.70 1,006.48 13.74 992.74Wells Monitored and Sampled Under Post-Closure Program For The OPCAs

78-1 4/6/2015 1,026.56 1,026.32 7.10 1,019.2278-6R 4/6/2015 1,012.08 1,011.70 6.02 1,005.68

GMA4-6 4/6/2015 1,009.63 1,009.13 8.70 1,000.43H78B-15 4/6/2015 1,010.30 1,012.68 13.08 999.60

OPCA-MW-1RR 4/6/2015 1,016.63 1,016.42 16.57 999.85OPCA-MW-2R 4/6/2015 1,016.80 1,018.84 22.76 996.08OPCA-MW-3 4/6/2015 1,015.27 1,014.83 20.86 993.97OPCA-MW-4 4/6/2015 1,019.27 1,018.67 14.55 1,004.12

OPCA-MW-5R 4/6/2015 1,016.61 1,016.29 12.16 1,004.13OPCA-MW-6 4/6/2015 1,022.82 1,022.24 15.27 1,006.97OPCA-MW-7 4/13/2015 1,027.26 1,026.54 14.98 1,011.56

OPCA-MW-8R 4/6/2015 1,028.80 1,030.70 15.40 1,015.30Additional Wells Monitored Under Post-Closure Program For The OPCAs

78-2 4/6/2015 1,034.44 1,033.94 9.17 1,024.7778-3 4/6/2015 1,007.28 1,006.87 15.97 990.90

GMA4-1 4/6/2015 1,012.35 1,012.01 22.31 989.70GMA4-4 4/6/2015 996.55 999.64 11.34 988.30

H78B-13R 4/6/2015 993.23 992.93 9.52 983.41H78B-17R 4/6/2015 999.20 1,000.31 12.76 987.55

NY-2 4/6/2015 993.70 996.54 16.57 979.97NY-4 4/6/2015 1,024.54 1,024.69 6.10 1,018.59

UB-MW-6 4/6/2015 1,021.09 1,020.12 19.73 1,000.39Allendale School Property Monitoring Wells / Piezometers North of GMA 4 (Monitored by EPA)

PZ-1 4/6/2015 NR 1,005.60 1.85 1,003.75PZ-2 4/6/2015 NR 1,009.89 0.73 1,009.16PZ-3 4/6/2015 NR 1,010.43 0.42 1,010.01PZ-4 4/6/2015 NR 1,007.96 -0.10 1,008.06

SCH-1 4/6/2015 1,017.59 1,017.11 3.29 1,013.82GMA 1 Monitoring Wells

ES1-05 4/7/2015 1,023.25 1,022.75 38.00 984.75ES1-20 4/7/2015 997.82 1,001.56 12.92 988.64

Commercial Street Site Monitoring WellGMA4-5 4/6/2015 993.28 993.16 10.99 982.17

Notes:1. AMSL - Above mean sea level.2. BMP - Below measuring point.

Spring 2015 Groundwater

Elevation(Feet AMSL)

3. EPA observed the top of PVC riser at PZ-4 to be submerged 0.10 feet below water in the flush mount casing and standing water was visible in proximity to the piezometer in the adjacent wetland area. As such, EPA recorded depth to water as -0.10 feet.

Table 4Groundwater Elevation Data - Spring 2015

Long-Term Groundwater Monitoring ProgramGroundwater Management Area 4


Well Number DateGround Surface

Elevation(Feet AMSL)

Measuring Point Elevation

(Feet AMSL)

Spring 2015Depth to Water

(Feet BMP)

Table 4 GMA 4 GW Elevation - Spring 2015.xlsx Page 1 of 1

GMA4-7S 7.75 7.55 446.5 102 9.40 83.7GMA4-8 10.79 6.93 2,656.5 188 2.66 266.1GMA4-9 7.31 7.32 1,644.9 115 6.33 211.9H78B-16 9.43 7.22 833.1 229 5.10 164.4

Notes:1. Field parameters collected with a peristaltic pump to assess water quality just after the passive diffusion bags were removed.


Table 5Field Parameter Measurements - Spring 2015Long-Term Groundwater Monitoring Program

Groundwater Management Area 4General Electric Company

Oxidation-Reduction Potential

(mV)

pH(Standard Units)Well ID Temperature

(Degrees Celsius)

Specific Conductivity

(µS/cm2)

Turbidity(NTU)

Dissolved Oxygen(mg/L)

Table 5 GMA 4 WQ Parameters - Spring 2015.xlsx 1 of 1

Table 6Spring 2015 Groundwater Analytical Results

Groundwater Management Area 4General Electric CompanyPittsfield, Massachusetts

Sample ID: GMA4-7S GMA4-8 GMA4-9 H78B-16Date Collected: 4/20/2015 4/20/2015 4/20/2015 4/20/2015

SDG: 31500724 31500724 31500724 31500724ParameterVolatile Organics (µg/L)2-Butanone 50,000 50,000 100,000 ND(25.00) [ND(25.00)] 3.12 J ND(125) ND(25.00)Acetone 50,000 50,000 100,000 13.50 J [14.00 J] 25.80 J 33.00 J 11.30 JChloroform 50 20,000 100,000 0.85 J [0.87 J] ND(1.00) ND(5.00) ND(1.00)Tetrachloroethylene 50 30,000 100,000 ND(1.00) [ND(1.00)] ND(1.00) 89.20 0.22 JTrichloroethylene 5 5,000 50,000 0.19 J [ND(1.00)] ND(1.00) 2.80 J 20.20Total VOCs Not Listed Not Listed Not Listed 14.54 [14.87] 28.92 125 31.72

Notes:

2. Although MCP Method 1 GW-2 standards are listed, none of these wells is a GW-2 compliance well; concentrations are compared to theGW-2 standards solely for benchmark purposes.3. ND = Analyte was not detected. The number in parentheses is the associated reporting limit.4. Only constituents detected in at least one sample are shown.5. Field duplicate sample results are presented in brackets.

Data Qualifiers:J - Indicates an estimated value.

MCP METHOD 1 GW-3 STANDARD

MCP UCL FOR GROUNDWATER

MCP METHOD 1 GW-2 STANDARD

1. Samples were collected by AECOM and submitted to SGS Environmental Services, Inc. in Wilmington, North Carolina for analysis of volatile organic compounds. Sample results have been validated in accordance with GE’s EPA-approved Field Sampling Plan/Quality Assurance Project Plan (July 2013).

Table 6 GMA 4 Data vs Standards-Spring 2015.xlsx Page 1 of 1

Figures

GMA1

GMA1-PLANT SITE 1

GMA3GMA 3-PLANT SITE 2

GMA4 GMA 4-PLANT SITE 3

GMA5

GMA 5-FORMER

OXBOWS A&C

GENERAL ELECTRIC COMPANY

PITTSFIELD/HOUSATONIC RIVER SITE

PITTSFIELD, MASSACHUSETTS

GMA 4

SITE OVERVIEW

FIGURE 1

~------------------------~------~ ~ It

.Ill

~ ~

<:::.

...... ~

~ <(S

~ ~

l ct ~ -~ Vi "isl ±

500

fGMA41

0 1,000

~ ~""----<:> AS-COM ~"~.·:l __ ~~::~~~~--------------------------------------------------------------------------~------~G:R:A~P:H~IC~S~C~A~LE~IN~F=E~E~T----_t~~~~~~:r~R:!··::::::::::I::::::_ ______ j_ ______________________ _J ______________ ~ :: DATE: 0 7 I 1 7/ 201 5 ~

PITTSFIELD\HOUSATONIC RIVER SITE


GMA4

MONITORING WELL LOCATIONS

SPRING 2015

FIGURE 2

~ ~~------------------------------------------------------------------------------------------------------------------------~--------------------------------------------~ 1 .......

-0GMA 4-4

...... ~

~~~~~~:=:-.--~ ~

l ct -~ ~

<'l "isl

L-----

HLL 78 COHSOIJDAllON AREA

± ~ -IS AS'COM 150 o c5..: ~---

-0GMA 4-2

300

~~--LEGEND

APPROXIM ATE GROUNDWATER MANAGEMENT AR EA 4 BOUND AR Y

~A4-2 GMA4 MONITORING WELL

+PZ-1

~788-15

NOTES

EXISTIN G MON ITOR ING WELL / PIEZOMETER MONITORED BY EP A

OPCA MONITORING WELL

WELL SAMP LED IN SPRING 2015 AS PART OF GMA 4 PROGRAM

1. MAPPING IS BASED ON AUTOCAD DRAWIN G FILE (P LAN T3 .CAD) AS PROVIDED BY GE AND ADDITIONAL INFORMATION FR OM THE MCP PH ASE II SCOPE OF WORK AND PROPOSAL FOR THE RCRA FACILI TY IN VESTIGATION 90'BRIEN & GERE EN GINEERS , IN C., FEBRUARY 1996) AS WELL AS SUPPLEMENTAL SITE SURVEY INFORMATION OBTAINED BY HILL ENGI NEER S, PLANNER S & ARCHITECHTS (WEEK OF MAY 29,1997) . LOCATION S EAST OF THE PARKING LOT DIGITI ZED FROM MARCH 2000 AIR PHOTO AND AR E APPROXIMATE.

2 . NOT ALL PHYSICAL FEATURES SHOWN .

3. SITE BOUNDAR Y IS APPROXIM ATE .

4 . ALL MONITORING WELL LOCATI ONS AR E APPROXIMATE.

iti ~~------------------------------------------------------------~-------G~R~A~PH~IC~S~CA~L~E~IN~F~EE~T----------------~D-M-E: ~07~/~16~/~20~15~~DR_w_N:~CC~D------._----------~------------------~----------~

PITTSFIELD\HOUSATONIC RIVER SITE


GMA4

WATER TABLE CONTOUR MAP

SPRING 2015

FIGURE 3

I

[:(

~ ~ ..... .!.. <:::. ~ ..... ~ '::i I

'<!-

~ ~ ~

.5(1 {l ~ I ~

~ d ..... <:>,

.,1

i ·~

~ lilt ~I <::i)

«:> ..... ~

I '<!-..... 9-8 ~

\ ~ '-5

~ ~ ~ 1:l:::

~ ..... ~ ..... ~ <(S

~ ~

l ct

\ -~ ~

<'l "isl ± ~ -IS c5..: A: COM iti ~

NY-3 0 986.84

PZ-3 0 1010.01

NY-2 01024.77

--1020----1018--

973

NOTES

LEGEND

APPR OXIMATE GROUNDWATER MANAGEMENT AR EA 4 BOUNDARY

BOUNDARY OF BUILDING 71 AND HILL 78 ON-PLAN T CO NSOLID ATI ON ARE AS REMOVAL ACTION AR EA

GROUNDWATER ELE VA TI ON GMA4 MONITORIN G WELL

GROUNDWATER ELE VA TI ON WELL/ PIEZOMETER MONITORED BY EP A

GROUNDWATER ELE VATION OPCA MONITORIN G WELL

WATER TABLE ELEVATION CONTOURS IN FEET, 2-FOOT INTER VAL

APPROXIM ATE DIRECTION OF GROUNDWATER FLOW

MEASURED FEET ABOVE MEAN SEA LE VEL ON APRIL 6 AND 7, 2015. OPCA-MW- 7 MEASURED ON AP RIL 13,2015

1. MAPPIN G IS BASED ON AUTOCAD DRAWING FILE (P LAN T3.CAD ) AS PROVIDED BY GE AND ADD ITI ONAL INFORMATI ON FR OM THE MCP PH ASE II SCOPE OF WORK AND PROPOSAL FOR THE RCRA FACILITY IN VESTIGATI ON 90'BRIEN & GERE ENGINEERS, INC., FEBRU ARY 1996) AS WELL AS SUPPLEMENTAL Sl TE SUR VEY INFORM ATION OBTAINED BY HILL EN GINEERS, PLANNERS & ARC HITECHTS (WEEK OF MAY 29 ,1 997) . LOCATIONS EAST OF THE PARK ING LOT DIGITIZED FROM MARCH 2000 AIR PHOTO AND AR E APPROX IM ATE .

2. NOT ALL PHYSICAL FEATURES SHOWN.

3. SITE BOUND ARY IS AP PROXIM ATE.

4. ALL MONITORING WELL LOCATI ONS AR E APPROXIMATE.

Appendix A Well Maintenance and Groundwater Sampling Logs

WellName

Inspection Date

Base of Well Elevation

(Feet AMSL)

Fall 2014Measured Base of

Well Elevation(Feet AMSL)

Spring 2015Measured Base of

Well Elevation(Feet AMSL)

Spring 2015 Difference From Base of Well

Elevation(Feet)

Maintenance CompletedJanuary 2015 through June 2015

GMA 4 Monitoring Wells060B-R 4/6/2015 980.63 * 980.29 980.76 0.13GMA4-2 4/6/2015 986.63 986.54 987.10 0.47GMA4-3 4/6/2015 978.05 977.94 978.29 0.24H78B-16 4/6/2015 982.00 982.22 982.46 0.46NY-3 4/6/2015 980.67 980.76 980.98 0.31RF-14 4/6/2015 979.90 979.06 979.51 -0.39RF-15 4/6/2015 991.42 * 991.65 992.22 0.80UB-MW-5 4/6/2015 992.25 * 991.90 992.57 0.32GMA4-5 4/6/2015 975.38 974.98 975.55 0.17GMA4-8 4/6/2015 988.60 988.60 988.62 0.02GMA4-9 4/6/2015 984.50 983.56 984.30 -0.20GMA4-7S 4/6/2015 974.60 974.87 975.27 0.67OPCA Sampling Wells78-1 4/6/2015 1004.40 1003.93 1004.16 -0.2478-6R 4/6/2015 993.66 * 993.80 993.97 0.31GMA4-6 4/6/2015 996.62 996.59 996.68 0.06H78B-15 4/6/2015 993.80 993.51 994.74 0.94OPCA-MW-1RR 4/6/2015 988.33 988.32 988.46 0.13OPCA-MW-2R 4/6/2015 991.50 991.67 991.89 0.39OPCA-MW-3 4/6/2015 987.30 987.28 987.66 0.36OPCA-MW-4 4/6/2015 997.20 997.23 997.42 0.22OPCA-MW-5R 4/6/2015 995.39 994.77 994.89 -0.50OPCA-MW-6 4/6/2015 997.70 998.02 998.30 0.60OPCA-MW-7 4/13/2015 1002.90 1001.92 1002.12 -0.78OPCA-MW-8R 4/6/2015 1003.20 1003.87 1004.11 0.91Additional Wells Monitored Under Post-Closure Program for the OPCAs78-2 4/6/2015 1013.90 1013.03 1013.54 -0.3678-3 4/6/2015 983.10 988.14 982.55 -0.55GMA4-1 4/6/2015 984.00 984.20 984.29 0.29GMA4-4 4/6/2015 976.60 976.58 976.74 0.14GMA4-8 4/6/2015 988.60 988.60 988.84 0.24GMA4-9 4/6/2015 984.50 983.56 984.52 0.02H78B-13R 4/6/2015 973.23 973.05 973.24 0.01H78B-17R 4/6/2015 975.60 975.26 975.38 -0.22NY-2 4/6/2015 970.42 * 970.02 970.27 -0.15NY-4 4/6/2015 992.80 * 992.23 993.44 0.64UB-MW-6 4/6/2015 984.55 985.22 985.53 0.98

Notes:1.

2. "Spring 2015 Difference From Base of Well Elevation" should be considered to be the amount of sediment deposition.3. Feet AMSL: Feet above mean sea level

Table A-1Monitoring Well Maintenance Table - Spring 2015



“Base of Well Elevation” represents either the measured base of well elevation at construction or, for wells marked with asterisks (which were recently re-developed), the base of well elevation measured following re-development.

]Table A-1 GMA 4 - Spg 15.xlsx Page 1 of 1

Well ID: Site/GMA Name: GE Pittsfield GMA4PID Background (ppm): Operator Name:Well Headspace (ppm): Date:

Weather: Mostly Cloudy, 42°FWell Information 4/6/2015

Reference Point Marked: yes Sample Time:Height of Reference Point: 1001.64 ft Meas. From Top of PVC Sample ID:

Well Diameter: 2 in Duplicate ID:Screen Interval Depth: 10-25 ft Meas. From Top of PVC MS/MSD:

Depth to Water: 16.69 ft Meas. From Top of PVC Split Sample ID:Well Total Depth: 26.37 ft Meas. From Top of PVC

Length of Water Column: 9.68 ftVolume of Water in Well: 0.21 ft3 Evacuation Method:

Intake Depth of Pump/Tubing: 17.5 ft Meas. From Top of PVC Water Meter Model:Water Meter SN:

Evacuation Information Turbidity Make/Model:Pump Start Time: Pump Model/Type:Pump Stop Time: Tubing Type:

Duration of Pumping: Tubing Diameter:Total Volume Pumped: 6 2 4 7 5 3

Did Well Go Dry? Samples Collected by Same Method as Evacuation?1 8 3 6 9 4 7

Time Pump Rate Total Gallons Water Level Temp. pH Spec. Cond. Turbidity DO ORP24 hr L/min Removed ft TIC °C s.u. µS/cm2 NTU mg/L mV

+/- 3% +/- 0.1 +/- 3% +/- 10% +/- 10% +/- 10 mv< 1.0 NTU < 0.1 mg/L

4/6/15 10:52 PDB installed N/A 16.69 8.60 7.61 1256.4 N/A 9.76 73.54/20/15 16:05 PDB removed N/A 16.3 7.75 7.55 446.5 102.0 9.40 83.7

* The stabilization criteria for each filed parameter (three consecutive readings collected at 3- to 5-minute intervals) is listed in each column heading.

*(FSP/QAPP SOP Appendix D, Rev5, dated 2013)

Observations/Sampling Method Deviations: Measurements collected to assess water qualityPDB length = 24 inches, diameter = 1.75 inchesGMA4-EB-042015 collected at this well

Redevelop Well? NoMaintenance Needed? No

Analytical Parameters Required: VOCsAnalytical Parameters Collected: VOCs

Sample Destination:Laboratory: SGSDelivered Via: FedEx Overnight

Field Sampling Coordinator: Chris French

Low-Flow Groundwater Sampling Record

GMA4-7SN/A C. French, G. WhiteN/A 4/6/2015

4/20/2015 16:05GMA4-7S-042015

Dup-1-042015N/AN/A

Equipment:Low-Flow

In-Situ SmarTroll®#N/A

Hach 2100N/A GeoPump/PeristalticN/A PolyethyleneN/A 0.175 inN/AN/A no, well sampled using passive diffusion bag (PDB)

Stabilization Parameters*

Last 5 Readings

Variance in Last 3 Readings

Low-Flow Sampling Stabilization Summary

Intake Depth of Pump/Tubing: 21 ft Meas. From Top of PVC Water Meter Model:Water Meter SN:





+/- 3% +/- 0.1 +/- 3% +/- 10% +/- 10% +/- 10 mv< 1.0 NTU < 0.1 mg/L




Observations/Sampling Method Deviations: Measurements collected to assess water qualityPDB length = 24 inches, diameter = 1.75 inches






Last 5 Readings



N/A GeoPump/PeristalticN/A PolyethyleneN/A 0.175 inN/AN/A no, well sampled using passive diffusion bag (PDB)


Hach 2100

Equipment:Low-Flow

N/A 4/6/2015

4/20/2015 14:35GMA4-8-042015

N/AyesN/A


GMA4-8N/A C. French, G. White

Intake Depth of Pump/Tubing: 9 ft Meas. From Top of PVC Water Meter Model:Water Meter SN:





+/- 3% +/- 0.1 +/- 3% +/- 10% +/- 10% +/- 10 mv< 1.0 NTU < 0.1 mg/L




Observations/Sampling Method Deviations: Measurements collected to assess water qualityPDB length = 24 inches, diameter = 1.75 inches






Last 5 Readings





Hach 2100

Equipment:Low-Flow

N/A 4/6/2015

4/20/2015 15:00GMA4-9-042015

N/AN/AN/A


GMA4-9N/A C. French, G. White

Well Diameter: 1 in Duplicate ID:Screen Interval Depth: 3.6-13.6 ft Meas. From Top of PVC MS/MSD:



Intake Depth of Pump/Tubing: 8.5 ft Meas. From Top of PVC Water Meter Model:Water Meter SN:





+/- 3% +/- 0.1 +/- 3% +/- 10% +/- 10% +/- 10 mv< 1.0 NTU < 0.1 mg/L

4/6/15 10:38 PDB installed N/A 11.26 8.65 7.04 371.5 N/A 8.72 99.84/20/15 15:30 PDB removed N/A 11.37* 9.43 7.22 833.1 229.0 5.10 164.4



Observations/Sampling Method Deviations: Measurements collected to assess water qualityPDB length = 24 inches, diameter = 1.75 inches*Water level potentially skewed due to PDB displacement.






Last 5 Readings





Hach 2100

Equipment:Low-Flow

N/A 4/6/2015

4/20/2015 15:30H78B-16-042015

N/AN/AN/A


H78B-16N/A C. French, G. White

Appendix B Laboratory Analytical Reports

Report Number: 31500724

Client Project: GE Pittsfield 60331701

Laboratory Report of Analysis

Gregory Hencir

AECOM

250 Apollo Drive

Chelmsford, MA 01824

Dear Gregory Hencir,

Enclosed are the results of the analytical services performed under the referenced project for the received

samples and associated QC as applicable. The samples are certified to meet the requirements of the National

Environmental Laboratory Accreditation Conference Standards. Copies of this report and supporting data will be

retained in our files for a period of five years in the event they are required for future reference. All results are

intended to be used in their entirety and SGS is not responsible for use of less than the complete report. Any

samples submitted to our laboratory will be retained for a maximum of thirty (30) days from the date of this report

unless other arrangements are requested.

If there are any questions about the report or services performed during this project, please call Michael D. Page

at (910) 350-1903. We will be happy to answer any questions or concerns which you may have.

Thank you for using SGS North America Inc. for your analytical services. We look forward to working with you

again on any additional analytical needs.

Sincerely,

SGS North America Inc.

__________________________________________________________________

Jeannie Milholland Date

QA [email protected]

To:

Print Date: 05/21/2015 N.C. Certification # 481

This document is issued by the Company under its General Conditions of Service accessible at http://www.sgs.com/en/Terms-and-Conditions.htm. Attention is drawn

to the limitation of liability, indemnification and jurisdiction issues defined therein.

Any holder of this document is advised that information contained hereon reflects the Company’s findings at the time of its intervention only and within the limits of

Client’s instructions, if any. The Company’s sole responsibility is to its Client and this document does not exonerate parties to a transaction from exercising all their

rights and obligations under the transaction documents. Any unauthorized alteration, forgery or falsification of the content or appearance of this document is unlawful

and offenders may be prosecuted to the fullest extent of the law.

1/224

Revised Report

1/224

Laboratory Qualifiers

Report Definitions

DL Method, Instrument, or Estimated Detection Limit per Analytical Method

CL Control Limits for the recovery result of a parameter

LOQ Reporting Limit

DF Dilution Factor

RPD Relative Percent Difference

LCS(D) Laboratory Control Spike (Duplicate)

MS(D) Matrix Spike (Duplicate)

MB Method Blank

Qualifier Definitions

* Recovery or RPD outside of control limits

B Analyte was detected in the Lab Method Blank at a level above the LOQ

U Undetected (Reported as ND or < DL)

J Estimated Concentration.

E Amount detected is greater than the Upper Calibration Limit

TIC Tentatively Identified Compound

ND Not Detected

P RPD > 40% between results of dual columns

D Spike or surrogate was diluted out in order to achieve a parameter result within instrument calibration

range

Samples requiring manual integrations for various congeners and/or standards are marked and dated by the analyst. A

code definition is provided below:

M1 Mis-identified peak

M2 Software did not integrate peak

M3 Incorrect baseline construction (i.e. not all of peak included; two peaks integrated as one)

M4 Pattern integration required (i.e. DRO, GRO, PCB, Toxaphene and Technical Chlordane)

M5 Other - Explained in case narrative

Note Results pages that include a value for "Solids (%)" have been adjusted for moisture content.


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Sample Summary

Client Sample ID Lab Sample ID Collected Received Matrix

GMA4-8-042015 31500724001 04/20/2015 14:35 04/22/2015 09:57 Water

GMA4-9-042015 31500724004 04/20/2015 15:00 04/22/2015 09:57 Water

H78B-16-042015 31500724005 04/20/2015 15:30 04/22/2015 09:57 Water

GMA4-75-042015 31500724006 04/20/2015 16:05 04/22/2015 09:57 Water

GMA4-EB-042015 31500724007 04/20/2015 16:05 04/22/2015 09:57 Water

Cooler 6 Trip Blank 31500724008 04/22/2015 09:57 Water

Dup-1-042015 31500724009 04/20/2015 00:00 04/22/2015 09:57 Water


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Case Narrative

Report Revisions:

1. Revised summary form 7A for batch VMS3598 added for 8260 CCV to include correct %D forMethacrylonitrile and Methyl Methacrylate (pages 213-214)

2. Revised raw data for batch VMS3598 added for 8260 CCV to include correct %Dev forMethacrylonitrile and Methyl Methacrylate (page 222)

Sample Receipt Observations:

The samples were received on April 22, 2015 at 09:57 via courier. The samples arrived in good conditionwith a temperature of 0.9 °C.

Volatiles Report:

The samples were analyzed for Volatiles according to the guidelines of method SW8260B. Sample IDGMA4-9-042015 was analyzed on a 5X dilution in order to obtain a result within the calibration range of theinstrument. Four compounds do not meet QAAP established control limits for the MS/MSD of sample IDGMA4-8-042015 due to probable matrix interference. Methylene chloride recovery is above QAAPestablished control limits in the LCSD associated with batch VMS3598; none of the associated samples havehits for this compound. ICAL points 50 and 70 were dropped for Chloroethane on MSD4. The high point forthe APX9 ICAL of MSD4 is 20 PPB. The second source calibration verification for the APX9 ICAL of MSD4was prepped using different concentrations. The Methacrylonitrile was prepped at 100 ppm and the MethylMethacrylate was prepped at 240 ppm.

NC Certification #4814/224

Revised Report

4/224

Detectable Results Summary

Client Sample ID: GMA4-8-042015

Lab Sample ID: 31500724001-A UnitsParameter Result

2-Butanone ug/LSW-846 8260B 3.12 JAcetone ug/L25.8



Acetone ug/LSW-846 8260B 33.0 JTetrachloroethene ug/L89.2Trichloroethene ug/L2.80 J

Client Sample ID: H78B-16-042015


Acetone ug/LSW-846 8260B 11.3 JTetrachloroethene ug/L0.220 JTrichloroethene ug/L20.2



Acetone ug/LSW-846 8260B 13.5 JChloroform ug/L0.850 JTrichloroethene ug/L0.190 J

Client Sample ID: Dup-1-042015


Acetone ug/LSW-846 8260B 14.0 JChloroform ug/L0.870 J


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Revised Report

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Revised Report

7/224

Data Sheet

Workorder 31500724

Work ID GE Pittsfield 60331701

Client

Profile

GENERAL ELECTRICCOMPANY - MAUpdated GMA Wells-AECOM[2644]

Created

Status

Report

PO

4/22/2015 15:50

CO

REVLET_RPT

111216909

31500724001 GMA4-8-042015

Sample Type

Matrix Water

Status RPPaying sample Collected

Received

4/20/2015 14:35

4/22/2015 09:57

Billable Acodes

SW8260-XXW VOA, SW8260, Full List, W

Container ID Type Preservative CC Container Utilization

31500724001-A 40MLCG HCL OK SW5030-W, SW8260B-W

31500724001-B 40MLCG HCL OK

31500724001-C 40MLCG HCL OK

31500724002 GMA4-8-042015 MS

Sample Type

Matrix Water

Status RPClient billable MatrixSpike

Collected

Received

4/20/2015 14:35

4/22/2015 09:57

Billable Acodes




31500724002-C 40MLCG HCL OK

31500724002-B 40MLCG HCL OK

31500724003 GMA4-8-042015 MSD

Sample Type

Matrix Water

Status RPClient billable MatrixSpike D

Collected

Received

4/20/2015 14:35

4/22/2015 09:57

Billable Acodes



31500724003-B 40MLCG HCL OK

31500724003-C 40MLCG HCL OK


Page 1 of 3

Friday, May 22, 2015 2:16:09 PM

5002.1.0.0

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Revised Report

8/224

Data Sheet

Workorder 31500724


Client

Profile


Created

Status

Report

PO

4/22/2015 15:50

CO

REVLET_RPT

111216909

31500724004 GMA4-9-042015

Sample Type

Matrix Water


Received

4/20/2015 15:00

4/22/2015 09:57

Billable Acodes



31500724004-C 40MLCG HCL OK

31500724004-B 40MLCG HCL OK


31500724005 H78B-16-042015

Sample Type

Matrix Water


Received

4/20/2015 15:30

4/22/2015 09:57

Billable Acodes




31500724005-C 40MLCG HCL OK

31500724005-B 40MLCG HCL OK

31500724006 GMA4-75-042015

Sample Type

Matrix Water


Received

4/20/2015 16:05

4/22/2015 09:57

Billable Acodes



31500724006-C 40MLCG HCL OK


31500724006-B 40MLCG HCL OK

Page 2 of 3

Friday, May 22, 2015 2:16:09 PM

5002.1.0.0

9/224

Revised Report

9/224

Data Sheet

Workorder 31500724


Client

Profile


Created

Status

Report

PO

4/22/2015 15:50

CO

REVLET_RPT

111216909

31500724007 GMA4-EB-042015

Sample Type

Matrix Water


Received

4/20/2015 16:05

4/22/2015 09:57

Billable Acodes



31500724007-C 40MLCG HCL OK


31500724007-B 40MLCG HCL OK

31500724008 Cooler 6 Trip Blank

Sample Type

Matrix Water


Received 4/22/2015 09:57

Billable Acodes




31500724009 Dup-1-042015

Sample Type

Matrix Water


Received

4/20/2015 00:00

4/22/2015 09:57

Billable Acodes




31500724009-B 40MLCG HCL OK

31500724009-C 40MLCG HCL OK

Page 3 of 3

Friday, May 22, 2015 2:16:09 PM

5002.1.0.0

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Revised Report

10/224

Sample Data

SW-846 8260B


11/224

Revised Report

11/224


Client Project ID: GE Pittsfield 60331701

Lab Sample ID: 31500724001-A

Lab Project ID: 31500724

Collection Date: 04/20/2015 14:35

Received Date: 04/22/2015 09:57

Matrix: Water

DL LOQ/CLResult Qual Units DFParameter

Results by SW-846 8260B

Results of GMA4-8-042015

Date Analyzed

1,1,1,2-Tetrachloroethane ND ug/L 1U 1.000.201 04/24/2015 21:04

1,1,1-Trichloroethane ND ug/L 1U 1.000.0600 04/24/2015 21:04



1,1-Dichloroethane ND ug/L 1U 1.000.0860 04/24/2015 21:04

1,1-Dichloroethene ND ug/L 1U 1.000.0960 04/24/2015 21:04

1,2,3-Trichloropropane ND ug/L 1U 1.000.130 04/24/2015 21:04

1,2-Dibromo-3-chloropropane ND ug/L 1U 5.001.40 04/24/2015 21:04

1,2-Dibromoethane ND ug/L 1U 1.000.0920 04/24/2015 21:04


1,2-Dichloropropane ND ug/L 1U 1.000.285 04/24/2015 21:04

1,4 Dioxane ND ug/L 1U 10014.4 04/24/2015 21:04

2-Butanone 3.12 ug/L 1J 25.00.523 04/24/2015 21:04

2-Chloroethylvinyl ether ND ug/L 1U 25.01.87 04/24/2015 21:04

2-Hexanone ND ug/L 1U 5.000.586 04/24/2015 21:04

4-Methyl-2-pentanone ND ug/L 1U 5.000.469 04/24/2015 21:04

Acetone 25.8 ug/L 125.00.813 04/24/2015 21:04

Acetonitrile ND ug/L 1U 20.011.5 04/24/2015 21:04

Acrolein ND ug/L 1U 25.04.26 04/24/2015 21:04

Acrylonitrile ND ug/L 1U 25.02.06 04/24/2015 21:04

Allyl chloride ND ug/L 1U 1.000.216 04/24/2015 21:04

Benzene ND ug/L 1U 1.000.132 04/24/2015 21:04

Bromodichloromethane ND ug/L 1U 1.000.206 04/24/2015 21:04

Bromoform ND ug/L 1U 1.000.170 04/24/2015 21:04

Bromomethane ND ug/L 1U 1.000.106 04/24/2015 21:04

Carbon disulfide ND ug/L 1U 1.000.0860 04/24/2015 21:04

Carbon tetrachloride ND ug/L 1U 1.000.0520 04/24/2015 21:04

Chlorobenzene ND ug/L 1U 1.000.0954 04/24/2015 21:04

Chloroethane ND ug/L 1U 1.000.147 04/24/2015 21:04

Chloroform ND ug/L 1U 1.000.0640 04/24/2015 21:04

Chloromethane ND ug/L 1U 1.000.0610 04/24/2015 21:04

Chloroprene ND ug/L 1U 1.000.162 04/24/2015 21:04

Dibromochloromethane ND ug/L 1U 1.000.0880 04/24/2015 21:04

Dibromomethane ND ug/L 1U 1.000.251 04/24/2015 21:04

Dichlorodifluoromethane ND ug/L 1U 5.000.0660 04/24/2015 21:04

cis-1,3-Dichloropropene ND ug/L 1U 1.000.104 04/24/2015 21:04

trans-1,3-Dichloropropene ND ug/L 1U 1.000.0832 04/24/2015 21:04

Ethyl Benzene ND ug/L 1U 1.000.0656 04/24/2015 21:04

Ethyl methacrylate ND ug/L 1U 1.000.127 04/24/2015 21:04

Isobutyl alcohol ND ug/L 1U 50.06.07 04/24/2015 21:04

Methyl iodide ND ug/L 1U 1.000.0570 04/24/2015 21:04

Methyl methacrylate ND ug/L 1U 1.000.0985 04/24/2015 21:04


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Revised Report

12/224






Received Date: 04/22/2015 09:57

Matrix: Water




Date Analyzed

Methylacrylonitrile ND ug/L 1U 10.01.42 04/24/2015 21:04

Methylene chloride ND ug/L 1U 5.000.0750 04/24/2015 21:04

Propionitrile ND ug/L 1U 20.02.22 04/24/2015 21:04

Styrene ND ug/L 1U 1.000.0750 04/24/2015 21:04

Tetrachloroethene ND ug/L 1U 1.000.0750 04/24/2015 21:04

Toluene ND ug/L 1U 1.000.0660 04/24/2015 21:04

Trichloroethene ND ug/L 1U 1.000.0870 04/24/2015 21:04

Trichlorofluoromethane ND ug/L 1U 1.000.0690 04/24/2015 21:04

Vinyl acetate ND ug/L 1U 2.000.303 04/24/2015 21:04

Vinyl chloride ND ug/L 1U 1.000.0700 04/24/2015 21:04

Xylene (total) ND ug/L 1U 2.000.200 04/24/2015 21:04

trans-1,2-Dichloroethene ND ug/L 1U 1.000.0990 04/24/2015 21:04

trans-1,4-Dichloro-2-butene ND ug/L 1U 5.001.03 04/24/2015 21:04

Surrogates

4-Bromofluorobenzene 100 % 162.0-132 04/24/2015 21:04

Dibromofluoromethane 97.0 % 158.0-133 04/24/2015 21:04

Toluene d8 101 % 165.0-127 04/24/2015 21:04

Batch Information

Prep Batch: VXX5659

Prep Method: SW-846 5030B

Prep Date/Time: 04/27/2015 08:28

Prep Initial Wt./Vol.: 40 mL

Prep Extract Vol: 40 mL

Analytical Batch: VMS3597

Analytical Method: SW-846 8260B

Instrument: MSD4

Analyst: JHL


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Revised Report

14/224

Data File Acq On Sample Mise Integrator: Quant Time:

Qlantitation Report (Not Reviewed)

D:\Hpche \l\Data\VMS3597\0424421.D 24 Apr 2'15 9:04pm 0724 1

RTE Apr 27 0' :19:56 2015

Vial: Operator: Inst Multiplr:

21 JHL MSD4 1.00

Quant Method : D:\Hp,hem\Methods\8260-W\VMS3595.M Quant Title : VMS35f5_8260/6200/624 Water ICAL QLast Update : Fri A'r 24 11:45:19 2015 Response via : Ini ti 1 Calibration ~~ 2 7•/\~ DataAcq Meth:MSD4_AC' .M 1'

~~~~~~~~~~~~~~~~~~-!--------------~~:~-~=~~--~=~~~~~=--=~~=-~~~:~-~=~~~~~~ 1) Fluorobenzene <IS> 5.189 70 32585 30.00 ppb 0.00

42) 1-chloro-3-flu~robenze. 7.818 95 63633 30.00 ppb 0.00 56) 1,2-dichlorobe!ilizene-04. 9.520 152 64124 30.00 ppb 0.00

System Monitoring C mpounds ~ 24) dibromof1uorom thane 4.245 113 40375 29.05 ppb 0.00

Spiked Amount 30.000 Range 86 118 Recovery 96.83% / 26) 1,2-dichloroet ane-d4 4.870 65 43313 30.61 ppb 0.00

Spiked Amount 30.000 Range 64 - 130 Recovery 102.03% 36) toluene-dB 6.746 98 156684 30.33 ppb 0.00

Spiked Amount 30.000 Range 82 - 117 Recovery 101.10% 52) 4-bromof1uorob nzene 8.738 95 69607 30.09 ppb 0.00 Spiked Amount 30.000 Range 85- 115 Recovery 100.30%

Target Compounds 10) acetone 19) 2-butanone 35) 4-methyl-2-pen anone 41) carbon disulfi1e 77) naphthalene

2.357 4.445 7.048 1.877

10.357

43 11744 43 24 68 43 258 76 602

128 304

~ppb Qvalue

100 ~ppb 92

..,-0. 17 ppb # 43 0.11 ppb # 79

Jl., e s ppb # 72

(#) = qualifier out of range (m) = manual integration (+) = signals summed

VMS3595.M Mon Apr 27 0 :19:56 2015 Page: 1

15/224

Revised Report

15/224

Data File Acq On Sample Mise

J Quantltatlon Report (Qedit}

D:\Hpch m\l\Data\VMS3597\042442l.D 24 Apr .015 9:04 pm 0724 1 A

Integrator: RTE Quant Time: Apr 27 8:42:26 2015

Quant Method D:\H chem\Methods\8260-W\VMS3595.M Quant Title VMS3 95 8260/6200/624 Water ICAL QLast Update Fri tPr-24 11:45:19 2015 Response via Initlal Calibration DataAcq Meth·MSD4 A'Q M -


21 JHL MSD4 1.00

\"bundance 8000

lon 43.00 (42.70 to43.70): 0424421.0\data.ms--·------· !on 58.00 {57.70 io 58.70}: 0424421.0\data.ms

7000

6000 2.~57

5000 ~ 4000

I; 3000

2000 I

10 1000

I I ~'I \\t I 0

1.4o ~ ·-rcr

ime--> 1.50 1.60 1.70 1.80 1.90 2.00 2.10 2.20 2.30 2.40 2.50 2.60 2.70 2.80 2.90 3.00 3.10 3.20 f'lbundance

.1 Scan 567 (2.357 min): 0424421.0\data.ms

4000

2000 58.1

39.0 ~ 94.0 -y-r-11'-c f-~~~ T"T'~c-rr·

s5 mlz--> 30 35 40 45 50 55 60 65 70 75 80 90 95 Abundance , Scan 184 (1.858 min) 1i2S414.D\data.ms (-174) (-)

I .0

5000

49.0 58.1

I 84.0

39.0 ~~~~ r53.q I' 69.9 I, I 88.0 ~r-r-r"""T ' ,~

I ' ' I I I I I ' I I i I

m/z--> 30 35 40 45 50 55 60 65 70 75 80 85 90 95 TIC: 0424421.0\data.ms

(10) acetone (T)

2.357min (+0.003) 25.83 p b

response 11744

I on Exp% Act%

43.00 100 100

58.00 34.90 35.16

0.00 0.00 0.00

0.00 0.00 0.00

VMS3595.M Mon A p r 2 12:58:25 2015 Pa

.

..,--~-

3.30

-,---,------,-100

-~ 100

.. -

ge. 1

16/224

Revised Report

16/224

Data File Acq On : Sample : Mise : Integrator: Quant Time:

1

I Quantitation Report (Qedit)

D:\Hpch~m\1\Data\VMS3597\0424421.D 24 Apr 0724 1

RTE Apr 27

'015 9:04pm A

8:42:26 2015

Quant Method : D:\H chem\Methods\8260-W\VMS3595.M Quant Title : VMS3 95 8260/6200/624 Water ICAL QLast Update : Fri pr-24 11:45:19 2015 Response via : Init al Calibration DataAcq Meth:MSD4 AIQ.M

-------rbundance lon ·43.00 (42.70 to 43".70): 0424421.0\data.ms

!on 72100 ( 1.70 to 72.70): 0424421 .D\data.ms

1400

1200

1000 4.~45

800 I

600 I

I I 400

. li ~ .. 200 J~\ 0 I

frime--> ,-r,--, ,-,,

3.50 3.60 3.70 3.80 3.90 4.00 4.10 4.20 4.30 4.40 4.50 4.60 4.70 4.80 Abundance Scan 1288 (4.445 min): 0424421.0\data.ms I 1000 4 .1 '

500

I 72.0

Vial: 21 Operator: JHL Inst : MSD4 Multiplr: 1. 00

m ..

4.9o 5.00 5.10 5.20

I

---· ---

T' 5.30 5.40

\ntz--> f'\bundance

h-,~~~ 1''"'"'~4-,--r-1~~T,,- '1-~"'"'~~-,-,--~,---l-J -,-,-l-,~TTTTTT,-r-~rrrr~~~-,--,~TT~~r-•'· -.--.,~TT-,-rrr 35 40 45 50 55 60 65 70 75 80 8

1

5 910 9'5 100 105 110 115 120 I 30

4 .0 Scan 463 (3.559 min): 11284'14.0\data.ms (-451) H --~-~

5000

m/z-->

I I

391.0 ' 49.0 53.0 57.0 61.0

h--~,-,---.. r,-+14-,-H+t,-+,1- I, I I I ' I ' I I 30 35 40 45 50 55 60

(19) 2-butanone (T)

4.445min (+0.003) 3.12 ppb

response 2468

I on Exp% Act%

43.00 100 100

72.00 24.70 28.49

0.00 0.00 0.00

0.00 0.00 0.00

75.0

I

' I ' ' .~1, 11 I I ' I ' I '8~ ~I 86.~' I ' '9~ 0'

110.0

~.;-!!,!_4,:;·::,.0 ~~~ L I ' 'I

65 70 75 80 85 90 95 100 105 110 115 120 TIC: 0424421.0\data.ms

IL_: ------1------·-·-----·--------~_j VMS3595.M Mon Apr 27 2:58:35 2015 Page: 1

17/224

Revised Report

17/224

Quantitation Report (Not Reviewed)

Vial: Data File Acq On Sample Mise Integrator:

D:\Hpchem\1\Data\VMS3597\0424421.D 24 Apr 2015 9:04pm Operator: 0724 1 A Inst

Multiplr: RTE

Quant Time: Apr 27 07:19:56 2015

Quant Method D:\Hpchem\Methods\8260-W\VMS3595.M Quant Title VMS3595 8260/6200/624 Water ICAL QLast Update Fri Apr-24 11:45:19 2015 Response via Initial Calibration DataAcq Meth:MSD4_ACQ.M

------rdiu1 ~-- ·· ·

I

l:IC_:_OA24421.D\data.ms

' i

500000

I 450000 1

4000001

350000!

300000\

i 250000\

!

2000001

i

1500001 !

100000j

50000,

w

~ ~

j I

~ !

~ 'I

1

11

~0- , It

1

',,'

, ~ I:

II ~ :1 I li

>-_ • c g ~ <: " >-;; • J

21 JHL MSD4 1.00

-------- - ----·-------

>-_ • c • • ;; ~ ~ • c

1 ,'1 I 1: ~Y~~~,..,-~..,-~ -'',-~...,~J.,-,-~---,-, -,IJ,..,.,.-, -r---C'-o-\y,..~~---,-~-r-:-~---,-~..,.,-~-

4.50 5.00 .. _5~00 6.50 7.00 7.50 8.00 ___ 8_.5Q __ 9.0()_ 9.50 1Qc0Q__10.~0. 11.00_11.50 _12,00 __ _

VMS3595.M Mon Apr 27 07:19:57 2015 Page: 2

18/224

Revised Report

18/224

1

buantitation Report (Not Reviewed)

Data File D:\Hpch~m\1\Data\VMS3597\0424421.D Vial: 21 Acq On 24 Apr 015 9:04pm Operator: JHL Sample 0724 1 A Inst MSD4 Mise Multiplr: 1.00 Integrator: RTE

Quant Title : VMS2 75 8260 APX9-W ICAL If 1 (

QLast Update: Fri .pr 24 14:17:48 2015 /)0 Response via : Initial Calibration ~ DataAcq Meth:MSD4 Ad:Q.M ~·l1,{)

-------~~~~~~~~-~-1---------------~~~~-~=~~--~==~~~==--~~~=-~~~~=-~=~~~~~~ Internal Standards 1) Fluorobenzene <IS>

13) 1-chloro-3-f1forobenze. 15) 1,2-dichlorobenzene-04.

System Monitoring tompounds 8) 1,2-dichloroe,hane-d4 Spiked Amount 30.000

12) toluene-dB Spiked Amount 30.000

14) 4-brornofluoro enzene Spiked Amount 30.000

Target Compounds

5.189 70 7.818 95 9.520 152

65 - 140

4.870 Range 64

6. 74 6 Range 82 -

8.738 Range 85 -

98 117 95 115

32585 30.00 ppb 0.00 63633 30.00 ppb 0.00 64124 30.00 ppb 0.00

43313 30.21 ppb 0.00 Recovery 100.70% / 156684 30.55 ppb 0.00 Recovery 101.83%

69607 29.96 ppb 0.00 Recovery 99.87%

Qvalue

(#) = qualifier ou of range (rn) = manual integration (+} = signals summed

VMS3596.M Mon Apr 27 08:35:29 2015 Page: 1

19/224

Revised Report

19/224

~uant1tation Report (Not Reviewed)

Data File D:\Hpch~m\l\Data\VMS3597\042442l.D Vial: 21 Acq On 24 Apr l015 9:04 pm Operator; JHL Sample 0724 1 A Inst MSD4 Mise Multiplr: 1.00 Integrator: RTE. Quant Time: Apr 27 ~8:35:29 2015

Quant Method D:\Hnchem\Methods\APIX-W\VMS3596.M Quant Title VMS2S75 8260 APX9-W ICAL QLast Update Fri 1 pr 24 14:17:48 2015 Response via Init.al Calibration DataAcq Meth:MSD4_A,Q.M

I bundance -----------Tic: 0424421.Didata.ms I

520000

500000

480000

460000

440000

420000

400000

380000

360000

340000

320000

300000

280000

260000

240000

220000

200000

180000

160000 I

140000

120000

100000

80000

'!! ,-w v ~ • N c • D e 0

~ ~ ~

'!! ,-w v ~ 0 • e

"' • c • N c • D e 0 , ~ E ~ ..

II

60000

::: .... rlc •~JJt~.~~~c--r-. ~L.JJ~~~-~-VM;:;,~ ~00 MOe '~:c 'f ;::",; ,~:0, ~--- 7.00 8.00 9.00 10.00 _jjj)O_P_a-::0~

2

I

I






Received Date: 04/22/2015 09:57

Matrix: Water




Date Analyzed












1,4 Dioxane ND ug/L 5U 50072.0 04/27/2015 16:36

2-Butanone ND ug/L 5U 1252.62 04/27/2015 16:36

2-Chloroethylvinyl ether ND ug/L 5U 1259.35 04/27/2015 16:36

2-Hexanone ND ug/L 5U 25.02.93 04/27/2015 16:36


Acetone 33.0 ug/L 5J 1254.07 04/27/2015 16:36

Acetonitrile ND ug/L 5U 10057.5 04/27/2015 16:36

Acrolein ND ug/L 5U 12521.3 04/27/2015 16:36

Acrylonitrile ND ug/L 5U 12510.3 04/27/2015 16:36


Benzene ND ug/L 5U 5.000.660 04/27/2015 16:36


















Isobutyl alcohol ND ug/L 5U 25030.4 04/27/2015 16:36




20/224

Revised Report

20/224






Received Date: 04/22/2015 09:57

Matrix: Water




Date Analyzed



Propionitrile ND ug/L 5U 10011.1 04/27/2015 16:36

Styrene ND ug/L 5U 5.000.375 04/27/2015 16:36

Tetrachloroethene 89.2 ug/L 55.000.375 04/27/2015 16:36

Toluene ND ug/L 5U 5.000.330 04/27/2015 16:36

Trichloroethene 2.80 ug/L 5J 5.000.435 04/27/2015 16:36







Surrogates



Toluene d8 105 % 565.0-127 04/27/2015 16:36

Batch Information

Prep Batch: VXX5662


Prep Date/Time: 04/27/2015 09:50





Instrument: MSD4

Analyst: BWS


21/224

Revised Report

21/224

22/224

Revised Report

22/224



D:\Hpchem\1\Data\VMS3598\0427418.D 27 Apr 2015 4:36pm 0724 4 x5 A


Quant Method D:\Hpchem\Methods\8260-W\VMS3595.M Quant Title VMS3595 8260/6200/624 Water ICAL QLast Update Fri Apr-24 11:45:19 2015 Response via Initial Calibration OataAcq Meth:MSD4_ACQ.M


18 BWS MSD4 1. 00

Compound R.T. Qion Response Cone Units Dev(Min)

Internal Standards 1) Fluorobenzene <IS> 5.189 70 33231 30.00 ppb 0.00

42) 1-chloro-3-fluorobenze. 7.821 95 71086 30.00 ppb 0.00 56) 1,2-dichlorobenzene-D4. 9.520 152 73707 30.00 ppb 0.00

System Monitoring Compounds 24) dibromofluoromethane 4.245 113 42045 29.67 ppb 0.00

Spiked Amount 30.000 Range 86 118 Recovery 98.90% 26) 1,2-dichloroethane-d4 4.870 65 43468 30.12 ppb 0.00

/ Spiked Amount 30.000 Range 64 - 130 Recovery 100.40% o.oo/ 36) toluene-dB 6.747 98 165287 31.38 ppb Spiked Amount 30.000 Range 82 - 117 Recovery 104.60%

52) 4-bromofluorobenzene 8.739 95 79836 30.90 ppb 0.00 Spiked Amount 30.000 Range 85 - 115 Recovery 103.00%

Target Compounds Qvalue 10) acetone 2.360 43 2957 ~ppb 99 18) cis-1,2-dichloroethene 3.620 96 1655 ppb 95 19) 2-butanone 4.451 43 471 Q.§8 ppb # 51 21) chloroform 4.016 83 1023 0.28 ppb # 76 29) trichloroethene .5.3,65 95 1244 ~ppb 89 44) tetrachloroethene 7.120 166 44090 ppb 99

{#) = qualifier out of range (m) = manual integration (+) = signals summed

VMS3595.M Tue Apr 28 09:26:13 2015 Page: 1

23/224

Revised Report

23/224

Quantitation Report (Qedit)





Abundance lon 43.00 (42.70 to 43.70): 0427418.0\data.ms lon 58.00 (57.70 to 58.70): 0427418.0\data.ms

2000

Abundance

2000

1000

I 'm/zM-> Abundance

5000

1.40 1.50 1.60 1.70 1.80 1.90 2.00

4 .0

(1 0) acetone (T)

2.360min (+0.006) 6.59 ppb

response 2957

I on Exp% Act%

43.00 100 100

58.00 34.90 35.59

0.00 0.00 0.00

0.00 0.00 0.00

:;. ~ 2.10 2.20 2.30 2.40 2.50 2.60 2.70

Scan 568 (2.360 min): 0427418.0\data.ms

I ' ' 75

·TIC: 0427418.0\data.ms

VMS3595.M Tue Apr 28 11:24:14 2015

Vial: 18 Operator: BWS Inst MSD4 Multiplr: 1.00

\ :!.. .'"' 2.80 2.90 3.00 3.10 3.20 3.30

84.0

I I, 88.0

I I I I ' ' I I ' 80 85 90 95 100

Page: 1

I

24/224

Revised Report

24/224



D:\Hpchem\l\Data\VMS3598\0427418.D 27 Apr 2015 4:36pm 0724 4 x5 A


Quant Method D:\Hpchem\Methods\8260-W\VMS3595.M Quant Title VMS3595 8260/6200/624 Water ICAL QLast Update Fri Apr~24 11:45:19 2015 Response via Initial Calibration DataAcq Meth:MSD4~ACQ.t"i

~bundance lon 96.00 (95.70 to-96.70): 0427418.0\data.ms lon 61.00(60.70to61.70): 0427418.0\data.ms

1400 !on 98.00 (97.70 to 98.70): 0427418.0\data_rns

1200

1000

800 3 0

600

400 \!

200 i ' I 1

1

1 ·. I 0 I

TTT"


A

18 BWS MSD4 1. 00

ime--> 2.60 2.70 2.80 2.90 3.00 3.10 3.20 3.30 3.40 3.50 3.60 3.70 3.80 3.90 4.00 4.10 4.20 4.30 4.40 4.50 4.6o ftbundance Scan 1003 (3.620 min): 0427418.0\data.ms

800 61.0

96.0

600 44.0

.~, JJ I 400

I 200 I' I' 'I' I I I I I

i 15 i2o m/z--> 30 35 40 45 50 55 60 65 70 75: 80 85 90 95 . 100 105 110 125 130 135 140 145 150 ~bundance Scan 351 (2.876 min): 1128414.0\data.ms (-341) (·)

61.0

96.0

5000

Jl, 37.0 47.0 j ,I 69.9 141.9

5'o TCTj I' I I I I I '''I II I II I I II I ' 'I' I'

'm!z--> 30 35 40 45 50 55 65 70 75 80 85 90 95 100 105 110 115 120 125 130 135 140 145 150 TIC: 0427418.0\data.ms

· (18) cis-1 ,2-dichloroethene (T)

3.620min (-0.000) 0.73 ppb

response 1655 .. '

len Exp% Act% l

96.00 100 100

.61.00 133.00 124.35

98.00 64.30 64.84

0.00 0.00 0.00 "

.. VMS3595.M Tue Apr 28 11:24:21 2015 !'

Page: 1

25/224

Revised Report

25/224



D:\Hpchem\l\Data\VMS3598\0427418.D 27 Apr 2015 4:36 pm 0724 4 x5 A


Quant Method D:\Hpchem\Methods\8260-W\VMS3595.M Quant Title VMS3595 8260/6200/624 Water ICAL QLast Update Fri Apr-24 11:45:19 2015 Response via Initial Calibration DataAcq Meth:MSD4 ACQ.M

~bundance ·-

ion 95.00 (94.70 iO 95.70): 0427418.0\data.ms ion 130.00 12 .70 to 130.70): 0427418.0\data.ms

1000 !on 132.00 13 .10 to 132.70) 0427418.0\data.ms

800 5. 65

600

I 400

I I

200 I

0 . I ' I I

frime--> 4.40 4.50 4.60 4.70 4.80 4.90 5.00 5.10 5.20 5.30 5.40 5.50 5.60 5.70 fbundance. Scan 1606 (5.365 min): 0427418.0\data.ms

9 .9 .. 600

400 44.0

I 59.9

L., ~ \ i

30 7'o ,.,

> 35 40 45 50 55 60 65 75 80 85 90 95 100 105 {'\bundance Scan 645 (4.669 min): 1128414.0\data.ms (-633) (-)

9 .0

5000 60.0

37.0 4~0 ~~L 81.9 I 1 .~9.9 64.9 71.9 . I 45 5o 55 60 s5 7'o

I I I 'I I I I

rntz--> 30 35 40 75 80 85 90 95 100 105 . TIC: 0427418.0\data.ms

: (29) trichloroethene (T)

5.365min (-0.001) 0.56 ppb '"'

response 1244

I on Exp% Act% )

95.00 100 100

130.00 99.00 89.12 ' . 132.00 96.10 84.71

0.00 0.00 0.00 ._,,

VMS3595.M Tue Apr 28 11:24:33 2015'


5.80 5.90 6bo

18 BWS MSD4 1. 00

...

6.10 6.20 6.30

129.9

I 110 115 120 125 130 135 140

12 .

·.135.9

110 115 120 125 130 135 140

.'·

Page: 1

--

'

26/224

Revised Report

26/224






rbundance lon 166.00 (165.70 to 166.70): 0427418.0\data.ms lon 168.00 (167.70 to 168.70): 0427418.0\data.ms !on 129.00 {i28JO to i29.70): 0427418.0\data.ms

! 40000

30000 7.r

20000 ~~ 10000 11 it

0 I ILl .I , I


Time~-> 6.10 6.20 6.30 6.40 6.50 6.60 6.70 6.80 6.90 7.00 7.10 7.20 7.30 7.40 7.50 7.60 7.70 Abundance Scan 2212 (7.120 min): 0427418.0\data.ms

30000

128.9 20000

94.0 10000

T I ' 59.0

8~.~ 37.0 I 65.4

18 BWS MSD4 1. 00

A

7.80 7.90 8.00

16 .9

8.10

lmiz··> 5o r~-1 ,: .',"', '.JI I ' I II I' " L

30 35 40 45 55 60 65 70 75 80 85 90 95 100 105 110 115 120 125 130 135 140 145 150 155 160 165 170 175 180 Abundance Scan 959 (6.583 min) 11284':4.0\data.ms (·951) (·)

16 .9

128.9

5000 93.9 ..

37.0 T 5~.0 69.9

81,.9 I 116.9 I I

fl1/z--> 30 35 40 45 5o 55 60 65 70 75 80 85 90 95 1oo 1o5 1·16 115 120 1·25 13o 135146 145 1·50 155 16o 165 110 175 18o ·TIC: 0427418.0\data.ms

(44) tetrachloroethane (T)

7.120min (+0.000) 17.84ppb

" response 44090

I on Exp% Act% ..

166.00 100 100 !

168.00 47.20 47.46 ;

. 129.00 69.00 70.28

0.00 0.00 0.00 . '

.

VMS3595.M Tue Apr 28 11;24:42 2015 Page: 1

27/224

Revised Report

27/224




RTE Apr 28 09:26:13 2015



Abundance TIC: 0427418.0\data.ms

6000001

' i 55oooo 1

500000

450000·

400000 w

"' ~ • 350000 c • -- " 2

300000 "' A.

>c w v • c • • c

~ 250000 ~ e • ~ ~ e 0 g

_200000 ;j' 2 w w • ..; c • " ' "' • • c

150000 E •

I ;;

! >-_ e • g e • ~ c .. • ;; E -~

100000 • e ~ >-_

e "

~ • 0 " ~ c

" >- • >-_ -~ ~ ;; c • • ~ ~

g g c 50000 ~ ~ " 0 -~ .2 ~ 0

• 1j "' :s

o,.----r-r,·· lrime--> ' 4.00 ' 1.00 1.50 2.00 2.50 3.00 3.50 4.50 5.00 5.50 6.00 6.50 7.00 7.50

VMS3595.M Tue Apr 28 09:26:14 2015

"'

18 BWS MSD4 1. 00

A• w v • c • N c • ~ e 0 , " M e ~

~

8.00 8.50

w • c ~ c • ~ e 0 , .. E e ~'

I

' 9.00

"' A.

w v ~

I 0 • c • N ! c • ~ e ..

,_

' i '

' 11 :oo 9.50 10.00 10.50 11.50 12.00

Page: 2

28/224

Revised Report

28/224





Quant Method D:\Hpchem\Methods\APIX-W\VMS3596.M Quant Title VMS3596 8260 APX9-W ICAL QLast Update Fri Apr 24 14:17:48 2015 Response via Initial Calibration DataAcq Meth:MSD4 ACQ.M


18 BWS MSD4 1. 00


Internal Standards 1) Fluorobenzene <IS>

13) 1-chloro-3-fluorobenze. 15) 1,2-dichlorobenzene-D4.

System Monitoring Compounds 8) 1,2-dichloroethane-d4 Spiked Amount 30.000


14) 4-bromofluorobenzene Spiked Amount 30.000

Target Compounds

5.189 7.821 9.520

70 95

152

65 - 140

98 117 95

4.870 Range 64

6.747 Range 82

8.739 Range 85 - 115

33231 30.00 ppb 0.00 71086 30.00 ppb 0.00 73707 30.00 ppb 0.00

434 68 29.73 ppb 0.00 Recovery 99.10%

1652 87 31.60 ppb 0.00 Recovery 105.33%

79836 30.76 ppb 0.00 Recovery 102.53%

Qvalue


VMS3596.M Tue Apr 28 09:35:46 2015 Page: 1

I

29/224

Revised Report

29/224

Quantitation Report. (i'j'ot Reviewed)

Data File Acq On Sample Mise Inte·grator: Quant Time:

D:\Hpchem\1\Data\VMS3598\0427418.D 27 Apr 2015 4:36pm 0724 4 x5 A ·

RTE Apr 28 09:35:46 2015

Quant Method D:\Hpchem\Methods\APIX-W\VMS3596.M Quant Title VMS3596 8260 APX9-W ICAL QLast Update Fri Apr 24 14:17:48 2015 Response via Initial Calibration DataAcq Meth:MSD4_ACQ.M

bundance TIC: 0427418.0\data.ms

600000

550000

500000

450000

400000

"' 00

350000 ~ • ~

300000

"' A.

250000 "' v • c • N c • ~ e 0

200000 i¥.

150000 "' :g • c

i 0

100000 " ~ '"!

50000


"' ;:· •00 v

~

18 BWS MSD4 1.00

ime-·> 0

f--1T .o ,~0~..,...,;=2'1'.0 ,=or"r'T"cr3'i .. .,b:o~""_~r~74..,_p:o~~===5~.o:o~~===6=.~~-'+-7-r. o.Lo'~~-!'8--,.0-0~----r!\-s-.oro.,..._,~c,..,1-0'.o'o~·-,-, ,1~1.r0?0~~1~2 QQj VMS3596.M Tue Apr 28 09:35:46 2015 Page: 2






Received Date: 04/22/2015 09:57

Matrix: Water



Results of H78B-16-042015

Date Analyzed












1,4 Dioxane ND ug/L 1U 10014.4 04/24/2015 21:31

2-Butanone ND ug/L 1U 25.00.523 04/24/2015 21:31


2-Hexanone ND ug/L 1U 5.000.586 04/24/2015 21:31


Acetone 11.3 ug/L 1J 25.00.813 04/24/2015 21:31


Acrolein ND ug/L 1U 25.04.26 04/24/2015 21:31



Benzene ND ug/L 1U 1.000.132 04/24/2015 21:31






















30/224

Revised Report

30/224






Received Date: 04/22/2015 09:57

Matrix: Water



Results of H78B-16-042015

Date Analyzed




Styrene ND ug/L 1U 1.000.0750 04/24/2015 21:31

Tetrachloroethene 0.220 ug/L 1J 1.000.0750 04/24/2015 21:31

Toluene ND ug/L 1U 1.000.0660 04/24/2015 21:31

Trichloroethene 20.2 ug/L 11.000.0870 04/24/2015 21:31







Surrogates



Toluene d8 101 % 165.0-127 04/24/2015 21:31

Batch Information

Prep Batch: VXX5659


Prep Date/Time: 04/27/2015 08:28





Instrument: MSD4

Analyst: JHL


31/224

Revised Report

31/224

32/224

Revised Report

32/224

Qlant1tation Report (Not Reviewed)

Data File D:\Hpche \1\Data\VMS3597\0424422.D Vial: 22 Acq On 24 Apr 2 15 9:31pm Operator: Sample 0724 5 r Inst Mise Multiplr: Integrator: RTE Quant Time: Apr 27 Or:19:59 2015

Quant Method D:\Hpfhem\Methods\8260-W\VMS3595.M Quant Title VMS35f5 8260/6200/624 Water ICAL QLast Update Fri Afr-24 11:45:19 2015 Response via Initifl Calibration

JHL MSD4 1.00

Compound R.T. Qion Response Cone Un1ts Dev(Mln)

DataAcq Meth:MSD4 ACI.M

------------------- ------------------------------------------------------Internal Standards

1) Fluorobenzene IS> 5.189 70 32116 30.00 ppb 0.00 42) 1-chloro-3-fluprobenze. 7.818 95 62984 30.00 ppb 0.00 56) 1,2-dichloroberzene-04. 9.520 152 64273 30.00 ppb o.oo

System Monitoring cbmpounds / 24) dibromofluorom~thane 4.245 113 40567 29.62 ppb 0.00 ~

Spiked Amount [30.000 Range 86 - 118 Recovery 98.73% / 26) 1,2-dichloroet ane-d4 4.870 65 42583 30.53 ppb 0.00


Spiked Amount 30.000 Range 82 - 117 Recovery 100.57% 52) 4-bromofluorob nzene 8.736 95 68981 30.13 ppb 0.00

Spiked Amount 30.000 Range 85 - 115 Recovery 100.43%

Target Compounds ~ppb

Qvalue 10) acetone 2.360 43 4 97 5 93 12) trans-1,2-dich oroethene 2. 432 96 250 ~ppb # 59 18) cis-1 1 2-dichlo oethene 3.620 96 12218 . ppb 98 19) 2-butanone 4.448 43 2244 ~ppb # 89 29) trichloroethen 5.368 95 43413 : ppb 96 41) ~:~~~~h~;~~!~~l e 1.879 76 578 ..(l._.J,.±- pp b # 79 44) ne 7.120 166 487 ~ppb # 92

------------------- ------------------------------------------------------


VMS3595.M Mon Apr 27 07:19:59 2015 Page: 1

33/224

Revised Report

33/224


Data File Acq On Sample

: D:\Hpc~em\1\Data\VMS3597\0424422.D : 24 Apr 2015 9:31 pm : 0724 5 A

Mise : Integrator: RTE Quant Time: Apr 27 08:42:56 2015

Quant Method : D:\ pchem\Methods\8260-W\VMS3595.M Quant Title : VMS 595 8260/6200/624 Water ICAL QLast Update : Fri Apr-24 11:45:19 2015 Response via : Ini ial Calibration DataAcq Meth:MSD4_~CQ.M

3000

2500

2000

1500

1000

500

ion 43.00 (42.70 to 43.70): 0424422.0\data.ms ion 58.00 (57.70 to 58.70): 0424422.0\data.ms

I

1!1

Vial: 22 Operator: JHL Inst : MSD4 Muitiplr: 1. 00

I~ _I __ J!Lu hl___lj_l'\.1_~------·--- _ Oj-----

~rr~TT"~-rr+-rr~TT"~n ".,. ,- rr···· --~~--, ime--> 1.40 1.50 1.60 1.70 1.80 1.90 2.00 2.10 2.20 2.30 2.40 2.50 2.60 2.70 2.80 2.90 3.00 3.10 3.20 3.30

('lbundance

2000

Scan 568 (2.360 min): 0424422.0\data.ms

1000

30

5000

581.1

69.9 1 I 1 I I 1

60 65 70 75 TIC: 0424422.0\data.ms

--~~~~~~--+~- -~~~~- .. ---VMS3595.M Mon Apr 27 12:58:49 2015

I

80

84.0

I, I ?~c;.0 ,.-r-~-,-,-~TT'~-~ 85 90 95 100

Page: 1

34/224

Revised Report

34/224



D:\Hpch rn\1\Data\VMS3597\0424422.D 24 Apr '015 9:31 prn 0724 5 A


Quant Method : D:\H chern\Methods\8260-W\VMS3595.M Quant Title : VMS3: 95 8260/6200/624 Water ICAL QLast Update : Fri pr-24 11:45:19 2015 Response via : Initial Calibration DataAcq Meth·MSD4 A~Q M -

Abundance ion 96.00 (95.70 to 96.70): 0424422.0\data.ms 10000 ion 61.00 (60.70 to 61.70): 0424422.0\data.ms

ion 98.00 (97.70 to 98.70): 0424422.0\data.ms

8000

6000 ~ 3~· 0

4000 I

I 2000

I I

0 l IJ I \1 l ·~

Vial: Operator: Inst Mu1tiplr:

~ ~ I

22 JHL MSD4 1. 00

.

ime--> 2.60 2.70 2.8o 2.90 3.0 1 3.10 3.20 3.30 3.40 3.50 3.60 3.70 3.80 3.90 4.00 4.10 4.20 4.30 4.4o Abundance Scan 1003 (3.620 min): 0424422.0\data.ms

6000 6r 96.0

4000 ' '

2000

l,l_ 37.0 "j:0 49.0 I

mfz.-> 30 35 40 4's 50 55 60 65 7'o 75 8'o B15 90 95 100 105 110 115 120 125 130 1:\s

Abundance 611.0

Scan 351 (2.876 min): 1128414.0\data.ms (-341) (-)

96.0

5000

~~~h, '

1,1 lm/z-->

37.0 47.0

4'o s'o' 5s ..-,T""Tr~

30 35 45 60 65 70 75 80 85 90 95 100 105 110 115 120 125 130 135 TIC: 0424422.0\data.ms

(18) cis-1,2-dichloroethene (T)

3.620min (·0.000) 5.58 ppb

response 12218

ion Exp% Act%

96.00 100 100

61.00 133.00 129.65

98.00 64.30 64.14

0.00 0.00 0.00

VMS3595.M Mon Apr 27 12:58:52 2015

r•~

4.50 4.60 I

140 n"T"

145 150

141.9

140 1.\s"110

Page: 1

35/224

Revised Report

35/224

Data File Acq On :

J Quantltation Report (Qedit)

D:\Hpch m\l\Data\VMS3597\0424422.D 24 Apr 015 9:3l.prn

Sample : 0724 5 A Mise : Integrator: RTE Quant Time: Apr 27 18:42:56 2015

Quant Method : D:\H chern\Methods\8260-W\VMS3595.M Quant Title : VMS3,95 8260/6200/624 Water ICAL QLast Update : Fri pr-24 11:45:19 2015 Response via : Init al Calibration DataAcq Meth:MSD4 ArQ.M

Vial: Operator: Inst : Multiplr:

22 JHL MSD4 1. 00

!Abundance 35000

30000

len 95.00 (94.70 to 95.70): 0424422.0\data.ms ion '130.00 (129.70 to 130.70): 0424422.0\data.ms !on 132.00 {131,70 to 132.70): 0424422.D\data_rns I

25000

20000

15000

10000

5aaa A. 0~--------------+-------~

I

I

I

I. I ime-->

c.-,..,~~C'"~T"~TT~lrT~··~o~·~c·,~r~~:~ ~-~~~~~~~~~~~~ : C ~ 4.40 4.50 4.60 4.l0 .80 4.90 5.00 5.10 5.20 5.30 5.40 5.50 5.60 5.70 5.80 5.90 6.00 6.10 6.20 6.30

Abundance

20000

10000

Scan 1607 (5.368 min): 0424422.0\data.ms 9 .0

47.0 J60.0 I

12

I ' ' ' ' , r~-c+o+rl>-1 :r~5~.9~· ~. ~~--"T

I

-~-cr3rt7~.0··~-1-~~-l .1.~, -~-.T~I,! :I,' I I'. rrr/Z··> 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 110

f un:Cdc:a=-nc=ec--"''-----"''- ----scano45 ( 4.669 min) 1128414. D\data.ms ( -633) (-) 115 120 125 __ 1._,3..,0__.1,_35,____,.14"'0'-- --

9 .0 12

5000 60.0

m/z--> TIC: 0424422.0\data.ms

(29) trichloroethene (T)

5.368min (+0.002) 20.21 pp

response 43413

I on Exp% Act%

95.00 100 100

130.00 99.00 94.23

132.00 96.10 92.30

L: 0.00 0.00

- --------------- _j VMS3595.M Mon Apr 27 12:59:18 2015 Page: 1

36/224

Revised Report

36/224


1


D:\Hpc~em\l\Data\VMS3597\0424422.D 24 Apr 2015 9:31 pm 0724 5 A


Quant Method D:\ pchem\Methods\8260-W\VMS3595.M Quant Title VMS 595 8260/6200/624 Water ICAL QLast Update Fri Apr-24 11:45:19 2015 Response via Ini,ial Calibration DataAcq Meth:MSD4 CQ.M

"-bundance ton 166.00 (165.70 to 166.70): 0424422.0\data.ms 600 ion 168.00 (167.70 to 168.70): 0424422.0\data.ms

!on i29.00 {128.70 to 129.70): 0424422.0\dataxns

500

400 7]20

300

II I

200

100 I

0 I I ~

Vial: 22 Operator: JHL Inst MSD4 Multiplr: 1. 00

h"-ime--> 6.10 6.20 6.30 6.4o 6.5b 6.60 6.70 6.80 6.90 7.00 7.10 7.20 730 7.40 ~~ 7.50 7.60 7.70 7.80 7.90 fbundance Scan 2212 (7.120 min): 0424422.0\data.ms

16 .9

300 128.8 44.0

200

93.8

---·

8.00 81o

II I r'l.., o 1 o, • I I

I 16o"1'6~"1io 1i~"1~o 1~5 1'~o"t'~5 1.\o"t'.\~· 15o 155 1so 165 170 1?6 180 mlz--> 30 35 40 45 50 55 60 65 70 75 80 85 90 95 ~bundance Scan 959 (6.583 min) 1128414.0\data.ms (-951) (-)

16 .9

128.9

5000 93.9

' ' ' , .',''', .,,,.,.1,11 C""C' 'C''"w " C

410 ~ 9.0 81.9 II ' 37.0 1-r' 69.9 I '

m/z--> 3'o I'CToT' I I I' ''I' I 'I I

35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 110 115 120 125 130 135 140 145 150 155 160 165 170 175 180 TIC: 0424422.0\data.ms

(44) tetrachloroethene (T)

7.120min (-0.000) 0.22 ppb

response 487

I on Exp% Act%

166.00 100 100

168.00 47.20 37.50#

129.00 69.00 71.50

0.00 0.00 0.00

------------

VMS3595.M Mon Apr 27 12:59:22 2015 Page: 1

'

37/224

Revised Report

37/224



D:\Hpchem\1\Data\VMS3597\0424422.D 24 Apr 2015 9:31 pm 0724 5 A

RTE Apr 27 07:19:59 2015


Vial: Operator: Inst Mul tiplr:

l.;.b_undance TIC: 0424422. Dldata.ms

! !

5000001

4500001

4000001

3500001

3000001

25000J

,J 1500001

1000001 >-• ;g 01 ~ c 0

" • 0

>->-_ ~ ~ • • ~ ~ e e 2 0 £ ~ ~

1-:"'9 0._

~ . """ .9,;, ·o ~c

·~

VMS3595.M Mon Apr 27 07:20:00 2015

'" ~ "' • ' ~ '" " E • e c 0 ~ , = • 0 ~ E e >-_ e 0 • ~ ~ c ~ • 5 •

"" e .; ~ ~ 0

c :;; • ;; • j .Q

~-

22 JHL MSD4 1. 00

~~--~~~-~---~--~~-~~-

Page: 2

38/224

Revised Report

38/224

1

~uantitation Report (Not

D:\Hpchim\1\Data\VMS3597\0424422.D 24 Apr '015 9:31pm

Reviewed}


0724 5 A

Integrator: RTE Quant Time: Apr 27 '8:35:32 2015

Quant Quant QLast

Method Title Update

D:\H,chem\Methods\APIX-W\VMS3596.M VMS2175 8260 APX9-W ICAL Fri pr 24 14:17:48 2015

Vial: Operator: Inst Mu1tip1r:

22 JHL MSD4 1.00

!fw) Response via Init al Calibration k/ ? / DataAcq Meth:MSD4_ACCQ.M 1•2- .{J

Compound l R.T. Qion Response Cone Units Dev(Min)

~:~r~f~~;~~;~~i~~~l;:;~:~::~-----;~;~;---~;----~i;;;----;~~~~-;;;------~~~g 15) 1,2-dich1orobtnzene-D4. 9.520 152 64273 30.00 ppb 0.00

System Monitoring fornpounds s) 1,2-dichloroeJhane-d4 4.s7o 65 42583 30.13 ppb o.oo Spiked Amount 30.000 Range 64 - 140 Recovery 100.43%

12) toluene-dB 6.746 98 153578 30.38 ppb 0.00 Spiked Amount 30.000 Range 82 - 117 Recovery 101.27%

14) 4-bromofluorolenzene 8.736 95 68981 30.00 ppb 0.00 Spiked Amount 30.000 Range 85- 115 Recovery 100.00%

Target Compounds Qvalue 3) Acetonitrile 2. 832 40 257 ~ppb # 1

~:~-:-:::::::::-::r-::-:::::-~:~-:-::::::-:::::::::::-~:~-:-:::::::-::::::

VMS3596.M Mon Apr 27 r8:35:32 2015 Page: 1

/ ../

39/224

Revised Report

39/224


Data File 0:\Hpc em\1\0ata\VMS3597\0424422.0 Acq On 24 Apr 2015 9:31 pm Sample 0724 5 A Mise Integrator: RTE Quant Time: Apr 27 08:35:32 2015

Quant Method 0:\ pchem\Methods\APIX-W\VMS3596.M Quant Title VMS'575 8260 APX9-W ICAL QLast Update Fri Apr 24 14:17:48 2015 Response via Ini ial Calibration OataAcq Meth:MS04_pCQ.M

f"bundance --~~--u-~~-c--- TIC: 0424422.0\dala.ms 540000

520000

500000

480000

"' 460000 -;;· "' " • 440000 0 • N 0 • D

420000 e 0 0

" 400000 ~ ~

380000 :i

360000

340000

320000

300000

280000

260000

240000

220000

200000

180000

160000

140000

120000

100000

80000

60000


"' ,· "' " ~ 'i: 0

~

"' • 0

~ • D e g ~ E e D ~

22 JHL MS04 1. 00

:~+-,-~~~~~-=-;"~~~=rc~-t~ _j ~~~J,~~-'-T-~-,-1\-"T"",_,!L ~-r-~,--r-r i

"-'"'"·m..,ec:··:::_> _ _,1".o..,.o __ _.,2"'.o,.o._ _ _.3"i . .,..o,_ ___ 24,-,-.o--_o __ 5--, . ..,.oo___ 6.oo 7 .oo 8.oo 9.oo 1 0.09_ -~ _l1_.QO ______ 12.oo ___ ,

VMS3596.M Mon Apr 27 08:35:32 2015 Page: 2






Received Date: 04/22/2015 09:57

Matrix: Water




Date Analyzed












1,4 Dioxane ND ug/L 1U 10014.4 04/24/2015 21:58

2-Butanone ND ug/L 1U 25.00.523 04/24/2015 21:58


2-Hexanone ND ug/L 1U 5.000.586 04/24/2015 21:58


Acetone 13.5 ug/L 1J 25.00.813 04/24/2015 21:58


Acrolein ND ug/L 1U 25.04.26 04/24/2015 21:58



Benzene ND ug/L 1U 1.000.132 04/24/2015 21:58








Chloroform 0.850 ug/L 1J 1.000.0640 04/24/2015 21:58














40/224

Revised Report

40/224






Received Date: 04/22/2015 09:57

Matrix: Water




Date Analyzed




Styrene ND ug/L 1U 1.000.0750 04/24/2015 21:58


Toluene ND ug/L 1U 1.000.0660 04/24/2015 21:58

Trichloroethene 0.190 ug/L 1J 1.000.0870 04/24/2015 21:58







Surrogates



Toluene d8 101 % 165.0-127 04/24/2015 21:58

Batch Information

Prep Batch: VXX5659


Prep Date/Time: 04/27/2015 08:28





Instrument: MSD4

Analyst: JHL


41/224

Revised Report

41/224

42/224

Revised Report

42/224


I alantitation Report (Not

D:\HpcheJ\1\Data\VMS3597\0424423.D 24 Apr 2115 9:58pm 0724 6

Integrator: RTE Quant Time: Apr 27 0 :20:02 2015

Reviewed)


Quant Method D:\Hp,hem\Methods\8260-W\VMS3595.M Quant Title VMS35'5 8260/6200/624 Water ICAL QLast Update Fri A,r-24 11:45:19 2015 Response via Initi 1 Calibration DataAcq Meth:MSD4 AC .M

23 JHL MSD4 1. 00


Internal Standards 1) Fluorobenzene ~IS> 5.189 70 31645 30.00 ppb 0.00

42) 1-chloro-3-flufrobenze. 7.818 95 62147 30.00 ppb 0.00 56) 1,2-dichlorobe~zene-04. 9.520 152 64576 30.00 ppb 0.00

System Monitoring Cpmpounds 4.245 113 39425 29.21 ppb 0.00 24) dibromofluorom thane

Spiked Amount 30.000 Range 86 - 118 Recovery 97.37% / 26) 1,2-dichloroet ane-d4 4.870 65 42370 30.83 ppb 0.00

/ Spiked Amount 30.000 Range 64 - 130 Recovery 102.77% 36) toluene-dB 6.747 98 151806 30.26 ppb 0.00 Spiked Amount 30.000 Range 82 - 117 Recovery 100.87%

52) 4-bromofluorob nzene 8.736 95 68639 30.38 ppb 0.00 Spiked Amount 30.000 Range 85 - 115 Recovery 101.27%

Target Compounds Qvalue 10) acetone 2.354 43 5903 cq-~ppb 99 19) 2-butanone 4.439 43 1171 . ppb # 51 21) chloroform 4.002 83 2994 ~ppb 86 29) trichloroethenb 5.368 95 399 ppb 88 32) bromodichlorom thane 5.982 83 435 J:J ;;b8 ppb # 88 35) 4-methyl-2-pen a none 7.042 43 292 B~~O ppb # 43 41) carbon disulfi e 1.880 76 487 ..G.el'i ppb # 79


VMS3595.M Mon Apr 27 17:20:02 2015 Page: 1

43/224

Revised Report

43/224

1


D:\Hpc~em\1\Data\VMS3597\0424423.D Data File Acq On Sample Mise Integrator: Quant Time:

24 Apr 2015 9:58 pm 0724 6 A

RTE Apr 27 08:43:29 2015

Quant Method D:\ pchem\Methods\8260-W\VMS3595.M Quant Title VMS 595 8260/6200/624 Water ICAL QLast Update Fri Apr-24 11:45:19 2015 Response via : Initial Calibration DataAcq Meth·MSD4 ACQ M -

"-bundance lon 43.00 (42.70 to 43.70): 0424423.0\data.ms 4000 ion 58.00 (57.70 to 58.70): 0424423, 0\data.ms

3500

3000 2. 54

2500

I 2000

1500 I

1000 I

0 500

0 ,\ I . I \)itlM --.---,--, '' r

ime~-> 1.40 1.50 1.60 1.70 1.80 1.90 2.00 2.10 2.20 2.30 2.40 2.50 2.60 2.70 ~bundance Scan 566 (2.354 min): 0424423.0\data.ms

.1

2000

1000 T 39.9

30 ' mlz--> 35 40 45 50 ,55 60 65 70 75 .. "'bundance Scan 184 (1.858 min): 1 128414.0\da\a.ms (-174) (·)

.0

5000

49.0 58.1 I

I, I ?~·~--rr- I I 39.0 I I 69.9

·I I I I I ' I ' I ' I ' ' ' mlz--> 30 35 40 45 50 55 60 65 70 75

TIC: 0424423.0\data.ms

(10) acetone (T)

2.354min (+0.000) 13.50 p b

response 5903

I on Exp% Act%

I 43.00 100 100

58.00 34.90 35.45 ' I 0.00 0.00 0.00

0.00 0.00 0.00

-

VMS3595.M Mon Apr 27 12:59:46 2015


'l

23 JHL MSD4 1.00

2.80 2.90 3.00 3.10 3.20

89.0 94.1 I I ' I ' ' '

80 85 90 95

84.0

I II ! ?~-O I"'

80 85 90 95

~,

I

-3.30

j

I

I ' ' '

100

I '

~

100

Page: 1

44/224

Revised Report

44/224



0:\Hpch m\1\Data\VMS3597\0424423.D 24 Apr '015 9:58pm 0724 6 A

RTE Apr 27 18:43:29 2015

Quant Method : D:\Hichem\Methods\8260-W\VMS3595.M Quant Title : VMS3, 95 8260/6200/624 Water ICAL QLast Update : rri pr-24 11:45:19 2015 Response via : Initfal Calibration DataAcq Meth:MSD4_A~Q.M

1500

1000

500

Ot------ ---+-

lon 83.00 (82.70 to 83.70): 0424423.0\data.ms ion 85.00 (8470 to 35.70): 0424423.0\data.ms


23 JHL MSD4 1. 00

l

ho~~CTT~,-,~nrclf~n~~~·~TT~ ~~~~~~~~-~ ~·~~~~~~ ime--> 3.00 3.10 3.20 3.30 3. 0 3.50 3.60 3.70 3.80 3.90 4.00 4.10 4.20 4.30 4.40 4.50 4.60 4.70 4.80 4.90 5.00

rbundance Scan 1135 (4.002 min): o:;2~423.D\data.ms

1000

500 44.0

1L

' _I I ,.

~~- ·~ 165 125

·~ m/z--> 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 110 115 120 130 rbundance Scan 402 (3.187 min): 1128414.0\data.ms (-390) (·)

8 .0

5000

~·J~ 47.'

3o 37.0 42.0 ~ 55.1 71.1 117.9

35 ·~~- 50 ~~ ~- -,-i-,---

m/z--> 65 70 75 80 85 90 95 100 105 110 115 120 125 130 TIC: 0424423.0\data.ms

(21) chloroform (TC)

4.002min (-0.003) 0.85 ppb

response 2994

I on Exp% Act%

83.00 100 100

85.00 63.60 52.32

J 0.00 0.00 0.00

0.00 0.00 0.00

I --

VMS3595.M Mon Apr 27 12:59:50 2015 Page: l

45/224

Revised Report

45/224


D:\Hpch 24 Apr 0724 6

Integrator: RTE Quant Time: Apr 27


rn\1\Data\VMS3597\0424423.D 015 9:58 prn A

8:43:29 2015

Quant Method Quant Title QLast Update

D:\Hpchern\Methods\8260-W\VMS3595.M VMS3595 8260/6200/624 Water ICAL Fri pr-24 11:45:19 2015

1 c 1 .b Response v1a : In1t~a a l rat1on OataAcq Meth:MSD4_ACQ.M

'Abundance ion 95.00 (94.70 to 95.70): 0424423.Didata.ms

400 ion 130.00,(12~.70 to 130.70): 0424423.0\data.ms ion 132.00 {13 7C tc 1:32_"70): 0424423.0\datruns

' '

300 5. 68

200 I

I 100

'I

0 . Ll~_JIL_I 4.so

c

5.2o ,.

" ime--> 4.40 4.50 4.70 .80 4.90 5.00 5.10 5.30 5.40 5.50 5.60 5.70

Abundance Scan 1607 (5.368 min): 0424423.D\data.ms 4 .0

300 95.0

200

59.9 I ., 4's

•" n r··rl----.---r-r-T~": r 1 ,c

1oo .,

mlz--> 30 35 40 50 55 60 65 70 75 80 85 90 95 105 ~bundance Scan 645 14.669 rl-lin) 1128414. D\data. ms (·633) (·)

9 .0

5000 60.0

37.0 47.0

,.,],1 ,6,4,.9,' 81.9 .99.9 I 71.9 I ' 4'o sol

I ' I I ' .

mlz--> 30 35 45 55 60 65 70 75 80 85 90 95 100 105 TIC: 0424423.Didata.ms

(29) trichloroethane (T)

I 5.368min (+0.002) 0.19ppb

response 399

ion Exp% Act%

95.00 100 100

130.00 99.00 92.28

132.00 96.10 78.25

0.00 0.00 0.00

------·

VMS3595.M Mon Apr 27 13:00:07 2015


23 JHL MSD4 1. 00

I ! I

I

----

s.9o 6.1o ~

5.80 6.00 6.20 6.30

129.9

~IL, 110 115 120 125 130 135 140

12 .

135.9 '"'l

110 115 120 125 130 135 140

Page: 1

46/224

Revised Report

46/224




RTE Apr 27 07:20:02 2015

Quant Method D:\Hpchem\Methods\8260-W\VMS3595.M Quant Title VMS3595 8260/6200/624 Water ICAL QLast Update Fri Apr 24 11:45:19 2015 Response via Initial Calibration DataAcq Meth:MSD4_ACQ.M


rbu5~~1 TIC: 0424423.0\data.ms

' 5000001

I 450000

400000i

!

350000j

'

30ooooi !

250000! ' !

200000j

I

150000j

100000: ~. 0 ~ ~

" ~

50000j .a g c ll 0 € u ~ •

VMS3595.M Mon Apr 27 07:20:03 2015

"' ' "' " 0 c 0

~ 0

D • 0 , " ~ ~ y

23 JHL MSD4 1.00

"' • c 0 N c 0

D • g ~ E ~ ~

J "' ,-"' " ~ 9 ~ ~ c 0 ~ •

Page: 2

47/224

Revised Report

47/224


juantitation Report (Not

D: \Hpchelm\1 \Data\VMS3597\0424423. D 24 Apr 2015 9:58 pm 0724 6 A

Mise Integrator: RTE Quant Time: Apr 27 08:35:35 2015

Reviewed)


23 JHL MSD4 1.00

Quant Method D:\HJchem\Methods\APIX-W\VMS3596.M Quant Title : VMS2~75 8260 APX9-W ICAL ~ >( QLast Update : Fri ~pr 24 14:17:48 2015 t;vJ;

~~~~~~:~;~~~;~~;~~:]::~:::~:~::~~~-~~:~-~=~~--~=~~~~~=--~~~=-~~~~~-~=~;~~~~~~ Internal Standards

1) Fluorobenzene <IS> 5.189 70 31645 30.00 ppb 0.00 13) 1-chloro-3-fl orobenze. 7.818 95 62147 30.00 ppb 0.00 15) 1,2-dichlorob nzene-04. 9.520 152 6457 6 30.00 ppb 0.00

System Monitoring 1ompounds 8) 1,2-dichloroeihane-d4 4.870 65 42370 30. 43 ppb 0.00 Spiked Amount 30.000 Range 64 - 140 Recovery 101.43%


14) 4-bromofluoro,enzene 8.736 95 68639 30.25 ppb 0.00 Spiked Amount 30.000 Range 85 - 115 Recovery 100.83%

Qvalue Target Compounds 3) Acetonitrile

--------------=~~~=---~~------===----~~~~--~-----= (#) = qualifier ou of range (m) = manual integration (+) = signals summed

VMS3596.M Mon Apr 27 08:35:35 2015 Page: 1

J

/

48/224

Revised Report

48/224

1

luantitation Report (Not Reviewed)

Data File D:\Hpchim\1\Data\VMS3597\0424423.D

~~~~~:;:~:: ~~;~:~ ~~':,,,:,::,:m Quant Method : D:\Hfchem\Methods\APIX-W\VMS3596.M Quant Title : VMS2j'75 8260 APX9-W ICAL QLast Update : Fri ~pr 24 14:17:48 2015 Response via : Initfal Calibration DataAcq Meth:MSD4_A•Q.M


rocbccuc-n'd"ac-ncccec-----------+----- --- TTC:o4.24423.D\d-ata.rns--· -------

540000

520000

500000 '!! ,· "' v ~ 480000 0 • '!! c ,· 460000

"' v • c w • • ~ c

440000

• • ~ N

~ c • ~

"' e 0 M , e '5

420000

400000

~ E e ~ 380000

360000

340000

320000

300000

280000

260000

240000

220000

200000

180000

160000

140000

120000

100000

80000

60000

40000

23 JHL MSD4 1.00

IL h- 2000:\-t--~T T=j=7A ~-p-:'-ll~ ,. . ~,-r·.,--,;.\-r-~·•~-+',~-c'~·· J~~~~~- --~~-,"-[ ime--> 1.00 2.00 3.10 4.00 5.00 _6_.0_0 ___ .. 7.00 8.00 9.00 10.00 11.00 12.00

VMS3596.M Mon Apr 27 08:35:35 2015 Page: 2

Client Sample ID: GMA4-EB-042015





Received Date: 04/22/2015 09:57

Matrix: Water



Results of GMA4-EB-042015

Date Analyzed












1,4 Dioxane ND ug/L 1U 10014.4 04/24/2015 22:24

2-Butanone ND ug/L 1U 25.00.523 04/24/2015 22:24


2-Hexanone ND ug/L 1U 5.000.586 04/24/2015 22:24


Acetone ND ug/L 1U 25.00.813 04/24/2015 22:24


Acrolein ND ug/L 1U 25.04.26 04/24/2015 22:24



Benzene ND ug/L 1U 1.000.132 04/24/2015 22:24






















49/224

Revised Report

49/224

Client Sample ID: GMA4-EB-042015





Received Date: 04/22/2015 09:57

Matrix: Water



Results of GMA4-EB-042015

Date Analyzed




Styrene ND ug/L 1U 1.000.0750 04/24/2015 22:24


Toluene ND ug/L 1U 1.000.0660 04/24/2015 22:24








Surrogates



Toluene d8 101 % 165.0-127 04/24/2015 22:24

Batch Information

Prep Batch: VXX5659


Prep Date/Time: 04/27/2015 08:28





Instrument: MSD4

Analyst: JHL


50/224

Revised Report

50/224

51/224

Revised Report

51/224

~uantitation Report (Not Reviewed)


D:\Hpchlm\1\Data\VMS3597\0424424.D 24 Apr '015 10:24 pm 0724 7 A



D:\H,chem\Methods\8260-W\VMS3595.M VMS3,95 8260/6200/624 Water ICAL Fri pr-24 11:45:19 2015

Response via Init al Calibration DataAcq Meth:MSD4 A Q.M


24 JHL MSD4 1.00

(/wj t{·l1·f)



42) 1-chloro-3-fl orobenze. 56) 1,2-dichlorob nzene-04.

System Monitoring 24) dibromofluoro

Spiked Amount 26) 1,2-dichloroe

Spiked Amount 36) toluene-dB Spiked Amount

52) 4-bromofluoro Spiked Amount

Target Compounds 10) acetone

ompounds ethane

30.000 hane-d4

30.000

30.000 , enzene

30.000

41) carbon disulf'de

5.189 7.818 9.520

4.242 Range 86

4.870 Range 64

6.747 Range 82 -

8.736 Range 85 -

2.357 1.874

70 95

152

113 118 65 130 98 117 95 115

43 76

31823 63546 66458

39086 Recovery

30.00 30.00 30.00

28.80

41831 30.27 Recovery

153179 30.37 Recovery


ppb ppb ppb

ppb 96.00%

ppb 100.90% ppb 101.23% ppb 102.23%

0.00 0.00 0.00

0.00 j

0.00 /

0.00

0.00

938 432

-2.3 I ppb Q Q8 ppb

Qvalue 92

# 79

(#) = qualifier ou of range (m) = manual integration (+) = signals summed

VMS3595.M Mon Apr 27 07:20:05 2015 Page: 1

52/224

Revised Report

52/224



D:\Hpchern\1\Data\VMS3597\0424424.D 24 Apr 2015 10:24 prn 0724 7 A

RTE Apr 27 07:20:05 2015

Quant Method D:\Hpchern\Methods\8260-W\VMS3595.M Quant Title VMS3595 8260/6200/624 Water ICAL QLast Update Fri Apr 24 11:45:19 2015 Response via Initial Calibration DataAcq Meth:MSD4_ACQ.M


24 JHL MSD4 1.00

----li!tijj;(~a~n~~tta~m~~ce~~~ ·==--=~cc·cc-=======~=-=-=-~-=-=-=-=--=-=-==-=-=--=-=-=-=-=====:_~ ~j~'iiC:-05:·Jl4422-44<4~2A4JJrut1dliiatiiiaumnsS:-:::~::::::::::-:::~:::-::::::-::::-:::~~~ ============----~ ::-::-:::-::::--::-·::---:::-:::-:::::-::-~ ==~---1 5500001

;!2

5000001

4500001

I 400000!

I i

3500001

3000001 I I

Z5ooooi I

zooooo[

I 150000!

100000

I 500001

'

"' 1i ro jj E E 0 , ~ E E

" ~ ~~

II,

'I f,

j o+-· ,,------.----,--·-,-----,----,-··..-. . ~ ~ ,~, -,-----r-r-~~~--,-~

_ __1Jlll_15_Q__2 OQ__],§_Q__~.oo 3.50 4.00

VMS3595.M Mon Apr 27 07:20:06 2015

"' .;

"% I " lj • £ • !' E ~ II .2

~ 'I " !I i

II <1

I II ,,~1·

' 4.~0__5,~0

"' ' "' " • " ~ • ~ E 0 , " ~ ~ :!

II

'I II

'.i

II I' jl I

I . I I I 6.00 B,50 7.00 J.5~ 8~00

"' • " ~ • ~ e 0 , ~ 0 E E ~ ~

'. 8.50 9.00 ··------------

A~

"' " v

~ " • N

" • ~ E 0

II ,I ,I '

I

:I . . . . . • . . . . . . . . I 9.50 10.00 10~50 11.00 11.50 12.00 I ~-- ~------------ - -------

Page: 2

53/224

Revised Report

53/224

Qlantltation Report (Not Reviewed)

Data File D:\Hpche \1\Data\VMS3597\0424424.D Vial: 24 Acq On 24 Apr 2 15 10:24 pm Operator: Sample 0724 7 i' Inst Mise Multiplr: Integrator: RTE Quant Time: Apr 27 0!:35:38 2015

Quant Method: D:\Hp hem\Methods\APIX-W\VMS3596.M Quant Title VMS25 5 8260 APX9-W ICAL QLast Update : Fri A r 24 14:17:48 2015 ,

DataAcq Meth:MSD4_AC .M

JHL MSD4 1.00

Response via : Initirl Calibration


~~~~~~~~:~~~~~~~~=-[:::----------:~:::---~:----:::::----::~::-:::------:~:0 13) 1-chloro-3-flubrobenze. 7.818 95 63546 30.00 ppb 0.00 15) 1,2-dichlorobefzene-o4. 9.520 152 66458 3o.oo ppb o.oo

System Monitoring Clmpounds 8) 1,2-dichloroet ane-d4 4.870 65 41831 29.87 ppb 0.00 Spiked Amount 30.000 Range 64 140 Recovery 99.57% /



Target Compounds Qvalue

(#) = qualifier ou of range (m) = manual integration (+) = signals summed

VMS3596.M Mon Apr 27 08:35:38 2015 Page: 1

/

54/224

Revised Report

54/224

duantitation Report (Not Reviewed)

Data File D: \Hpch m\1\Data\VMS3597\0424424.D Acq On 24 Apr 015 10:24 pm Sample 0724 7 A Mise Integrator: RTE Quant Time: Apr 27 18:35:38 2015

Quant Method D:\H•chem\Methods\APIX-W\VMS3596.M Quant Title VMS2 75 8260 APX9-W ICAL QLast Update Fri pr 24 14:17:48 2015 Response via Init al Calibration DataAcq Meth:MSD4_A,Q.M


24 JHL MSD4 1. 00

rbundance TIC: 0424424.0\data.ms ----l

540000

I.

520000

500000

1 480000

I

460000

440000

I 420000

400000

380000

360000

340000

320000

300000

280000

260000

240000

220000

200000

180000

160000

140000

120000

100000

80000

60000

"' ,· "' v • c • ~ • ~ e 0 0

" M

I! 2

~

"' ,· "' v v 0 • c ~

':! c • N c • ~ e 0 0

\5 E ~ .;

::::: ~ II

I ol-,~--,-';=r=;=;=cc=r=fo,~TF~J~-1 -Fr~L~h-~...,.l',...,,-..,J'I,-,-._,.,~~rT"T-,-,...,~~ ~ime-·> 1.oo 2.o_o __ ~ __ 4.00 _ ___§,QQ __ 6cOo__ __ 7,QQ_ _ __Mil___~'!.o __ 1,_,oco.o,_o,__ 11.00 ___1LQQ_

VMS3596.M Mon Apr 27

1

08:35:38 2015 Page: 2

i

Client Sample ID: Cooler 6 Trip Blank




Collection Date:

Received Date: 04/22/2015 09:57

Matrix: Water



Results of Cooler 6 Trip Blank

Date Analyzed












1,4 Dioxane ND ug/L 1U 10014.4 04/27/2015 12:12

2-Butanone ND ug/L 1U 25.00.523 04/27/2015 12:12


2-Hexanone ND ug/L 1U 5.000.586 04/27/2015 12:12


Acetone ND ug/L 1U 25.00.813 04/27/2015 12:12


Acrolein ND ug/L 1U 25.04.26 04/27/2015 12:12



Benzene ND ug/L 1U 1.000.132 04/27/2015 12:12






















55/224

Revised Report

55/224

Client Sample ID: Cooler 6 Trip Blank




Collection Date:

Received Date: 04/22/2015 09:57

Matrix: Water



Results of Cooler 6 Trip Blank

Date Analyzed




Styrene ND ug/L 1U 1.000.0750 04/27/2015 12:12


Toluene ND ug/L 1U 1.000.0660 04/27/2015 12:12








Surrogates


Dibromofluoromethane 102 % 158.0-133 04/27/2015 12:12

Toluene d8 99.0 % 165.0-127 04/27/2015 12:12

Batch Information

Prep Batch: VXX5662


Prep Date/Time: 04/27/2015 09:50





Instrument: MSD4

Analyst: BWS


56/224

Revised Report

56/224

57/224

Revised Report

57/224



D:\Hpchem\l\Data\VMS3598\0427408.D 27 Apr 2015 12:12 pm 0724 8 A




8 BWS MSD4 1. 00



42) 1-ch1oro-3-fluorobenze. 56) 1,2-dichlorobenzene-04.

System Monitoring Compounds 24) dibromofluoromethane

Spiked Amount 30.000

5.189 7.821 9.520

4.242 Range 86

70 95

152

113 - 118

30926 30.00 ppb 0.00 62100 30.00 ppb 0.00 65097 30.00 ppb 0.00

40278 30.54 ppb 0.00 Recovery 101.80%

/ 26) 1,2-dichloroethane-d4 Spiked Amount 30.000

36) toluene-dB

4.870 65 41280 30.73 ppb O.OJ Range 64 - 130 Recovery 102.43%

6. 74 6 98 146236 29.83 ppb 0.0 Spiked Amount 30.000


Target Compounds 10) acetone 41) carbon disulfide

Range 82 - 117 8.738 95

Range 85 115

2.349 43 1.882 76

Recovery 99. 4 3% 68582 30.38 ppb 0.00 Recovery 101.27%

Qvalue 423 ~pb # 40 744 ppb # 67


VMS3595.M Mon Apr 27 13:03:22 2015 Page: 1

58/224

Revised Report

58/224




RTE Apr 27 13:03:22 2015



rbundance

5500001


I 1

5000001

450000

4000001

I

3500001

I 00 .;

300000 - l: c • 00

:§ -;;-00

250000 " • c ~ c • ~

200000 e 0 0 u:

00 00

• -.i c -.,

150000 • • 5 c • • E 5 e • 0 e 0 ~

100000 'E .2 >--_ E ;z_ • e ~ ~

'§ 'a

:5 >-o • 50000 c c 0

~ " ~ 0 •

0 ime~-> 1.00 1.50 2.00 2.50 3.00 • 3.50 4_00 4.50 5.00 5.50 6.00 6.50 7.00 7.50

.

VMS3595.M Mon Apr 27 13:03:23 2015

00 ;;-00

" • c

~ • ~ e 0 0 ~

" i!

~

8 BWS MSD4 1.00

' 8.00 8.50

00 • c • N c • ~ e 0 0

'E E e ~

9.00

N c • ~ j

I

I I

' 9.50 10.00 10.50 11.00 11.50 12.00

Page: 2

59/224

Revised Report

59/224



D:\Hpchern\1\Data\VMS3598\0427408.D 27 Apr 2015 12:12 prn 0724 8 A

RTE Apr 27 13:03:59 2015



8 BWS MSD4 l. 00



13) 1-chloro-3-fluorobenze. 15) 1,2-dichlorobenzene-04.




Target Compounds

5.189 7.821 9.520

70 95

152

65 4.870 Range 64

6. 74 6 Range 82 -

8.738

- 140 98 117 95

Range 85 - 115

30926 30.00 ppb 0.00 62100 30.00 ppb 0.00 65097 30.00 ppb 0.00

41280 30.34 ppb 0.00 Recovery 101.13%

146236 30.04 ppb 0.00

I Recovery 100.13% 68582 30.25 ppb 0.00 Recovery 100.83%

Qvalue


VMS3596.M Mon Apr 27 13:03:59 2015 Page: 1

60/224

Revised Report

60/224






fbundanca TIC: 0427408.0\data.ms 560000

540000

520000

500000

480000 .

460000 00

440000 ;; '{} • 420000 0

~ .11

400000 e 0 ,

380000 ~ ~

360000 ;!

340000

320000 oo.

300000 00 ~ • 0 •

280000 :§

260000

240000 "' ' 00 v 220000 • 0

~ • 200000 D

e 0 , 0:

180000 ~~

160000

140000 oo. ~ ~ • 120000 0 • ti e

100000 ~

80000 ~

60000

40000

20000

0 -r=--, . ime~-> 1.00 2.00 3.00 4.00 5_.00 6.00 7.00 8.00

VMS3596.M Mon Apr 27 13:03:59 2015

00 • 0 • N 0 • D e 0 , '8 E e D ..


"' ,· 00 v

~ 0

9.00 10.00

8 BWS MSD4 1. 00

11.00 12.00

Page: 2






Received Date: 04/22/2015 09:57

Matrix: Water



Results of Dup-1-042015

Date Analyzed












1,4 Dioxane ND ug/L 1U 10014.4 04/24/2015 22:51

2-Butanone ND ug/L 1U 25.00.523 04/24/2015 22:51


2-Hexanone ND ug/L 1U 5.000.586 04/24/2015 22:51


Acetone 14.0 ug/L 1J 25.00.813 04/24/2015 22:51


Acrolein ND ug/L 1U 25.04.26 04/24/2015 22:51



Benzene ND ug/L 1U 1.000.132 04/24/2015 22:51








Chloroform 0.870 ug/L 1J 1.000.0640 04/24/2015 22:51














61/224

Revised Report

61/224






Received Date: 04/22/2015 09:57

Matrix: Water



Results of Dup-1-042015

Date Analyzed




Styrene ND ug/L 1U 1.000.0750 04/24/2015 22:51


Toluene ND ug/L 1U 1.000.0660 04/24/2015 22:51








Surrogates



Toluene d8 103 % 165.0-127 04/24/2015 22:51

Batch Information

Prep Batch: VXX5659


Prep Date/Time: 04/27/2015 08:28





Instrument: MSD4

Analyst: JHL


62/224

Revised Report

62/224

63/224

Revised Report

63/224

~uantitation Report (Not Reviewed)

~~~a0~ile ~~\~~~h~~~~\D~~~~~M~!597\0424425.D Oper~!~~: ~~L Sample 0724 9 ]A Inst MSD4 Mise Multiplr: 1.00 Integrator: RTE Quant Time: Apr 27 7:20:08 2015

Response Vla : Inlt.al Calibrat1on DataAcq Meth:MSD4_A Q.M

Quant Method : D:\HJchem\Methods\8260-W\VMS3595.M Quant Title : VMS3J95 8260/6200/624 Water ICAL QLast Update : Frl lpr-24 11:45:19 2015

Compound R.T. Qion Response Cone Units Dev(Min) ------------------1-------------------------------------------------------Internal Standards

1) Fluorobenzene <IS> 5.189 70 29809 30.00 ppb 0.00 42) 1-chloro-3-fl orobenze. 7.821 95 59871 30.00 ppb 0.00 56) 1,2-dichlorob~nzene-04. 9.520 152 64191 30.00 ppb 0.00

System Monitoring iompounds / 24) dibromofluoroTethane 4.242 113 37479 29.48 ppb 0.00

Spiked Amount 30.000 Range 86 - 118 Recovery 98.27% 26) 1,2-dichloroejhane-d4 4.870 65 40425 31.22 ppb 0.00/


Spiked Amount 30.000 Range 82 - 117 Recovery 102.63% 52) 4-bromofluoro.enzene 8.738 95 67308 30.93 ppb 0.00

Spiked Amount 30.000 Range 85- 115 Recovery 103.10%

Target Compounds ~ppb

Qvalue 10) acetone 2.354 43 5760 95 19) 2-butanone 4.450 43 1102 l 52- ppb 94 21) chloroform 3.999 83 2875 ~ppb 97 32) bromodichloro ethane 5.982 83 4 68 Q.2:t ppb # 92 35) 4-methyl-2-pe tanone 7.045 43 324 0.23 ppb # 43 41) carbon disulf 'de 1. 874 76 539 ..0 J J ppb # 79

(#) = qualifier ou of range (rn) = manual integration (+) = signals summed

VMS3595.M Mon Apr 27 07:20:08 2015 Page: 1

64/224

Revised Report

64/224



D:\Hpch~m\1\Data\VMS3597\0424425.D 24 Apr 015 10:51 pm 0724 9 A

RTE Apr 27 08:44:14 2015

Quant Method D:\H~chem\Methods\8260~W\VMS3595.M Quant Title VMS3595 8260/6200/624 Water ICAL QLast Update Fri pr-24 11:45:19 2015 Response via Initlial Calibration DataAcq Meth:MSD4_ACQ.M

Vial: Operator: Inst Multip1r:

25 JHL MSD4 1. 00

"'["bc-unccdccaccn-:ce=------------l--~------.,o:::n:--.4"3'".o"'o'(4~2'."70""to:-4"'3;c.7'-0"'):'0"4"24'4•'2"5".D"I"dc:;at"'a-=.m:cs;-~------ --~~--~--~ -~!on 58.00 (57.70 to 58.70): 0424425.0\data.ms

3500

I 3000

I 2. 54

:1\\\

1000

50:t--~-- ----1--- ~~-~----~ _L _j~\~\li'L~----'-----~-~---~-------

2500

2000

1500

f-r,~~"T"·~.-~ ''"'T" ,-,T-.--r··~· 'T'"'-,-~,-- ---;-,---, ,·T"'""'I'-,---r-,1---.--r--o-• -f""-1"--,-,-l~ r,-.,---r-r~·~~ ime--> 1.40 1.50 1.60 1.70 1.80 1.90 2.00 2.10 2.20 2.30 2.40 2.50 2.60 2.70 2.80 2.90 3.00 3.10 3.20 3.30

Scan 566 (2.354 min): 0424425.0\data.ms f'.bundance .1

2000

1000 58.1

4o.o I 89.o 94.o h-c-c-~~r-t-rc-H-+-,-,-~"0~~-~~-~;~TT~~--,TT~-.-.~TTTTT..;cr;-,-~->"r~~..-~~ ff!,lz--> 30 35 40 45 5'o 55 60 65 70 75 80 · 85 90 95 ~bundance .O Scan 184 (1.858 min): 1 128414.D\data.ms (-174) (-)

100

5000

imtz-->

58.1

I ~-0

if-1-+-r-r-H-+,+~;.;-.rc~r-.,-, ~~·~· T: ~~6;c, 9-r,·'T~~·~"'' ~·~· ~· ''~~+I ,,-11,_8;., 8+-.o-,-,,~~'' ,,~.~~.,~~ w ~ ro n w 85 ~ n 100

49.0

39.0 I, I ?~-0 I

3'o 315

1-++t-"1 I I 40 45 50 55 --


(1 0) acetone (T)

2.354min (+0.000) 13.98 ppb

response 5760

I on Exp% Act%

43.00 100 100

58.00 34.90 32.27

0.00 0.00 0.00

0.00 0.00 0.00

~--------- ------~----------~-- ~ ------- _______________ j VMS3595.M Mon Apr 2C 13:00:56 2015 Page: 1

65/224

Revised Report

65/224


Quant Method Quant Title QLast Update Response via


D:\Hpc em\1\Data\VMS3597\0424425.D 24 Apr 2015 10:51 pm 0724 9 A

RTE Apr 27 08:44:14 2015

Ini ial Calibration DataAcq

D:\ pchem\Methods\8260-W\VMS3595.M VMS~595_8260/6200/624 Water ICAL Fri Apr 24 11:45:19 2015

Meth:MSD4_fCQ.M

~bundance ..

I On 83.00 (82.70.io 83.70): 0424425.0\data.ms

1600 I on 85.00 (84.70 to 85 70): 0424425.0\data.ms

' 1400

1200 3.Q99

1000

~ 800

600 i \11 II 1

1

400 I

200 I II

I I 0 I 1

1

1 I --·· .,

·~ ' 4.\o ime--> 3.00 3.10 3.20 3.30 3..40 3.50 3.60 3.70 3.80 3.90 4.00 4.20 4.30

)'\bundance Scan 1134 (3.999 min): 0424425.0\data.ms 1000 8 .0

500

4r

L"~· . .,-,--,-m/z--> 30 35 40 45 50 55 60 65 70 75 80 85 90 95

Vial: Operator: Inst Mu1 tip1r:

.

4.40 4.50 4.60

100 16s 110 )'\bundance Scan 402 (3.187 min): 1128414.0\data.ms (-390) (-)

I 8 .0

5000

47.p

! 37.0 42.0 55.1 71.1 .I ,,-; t·,-r-r~ ~

11o /nlz--> 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 TIC: 0424425.0\data.ms

(21) chloroform (TC)

3.999min (·0.006) 0.87 ppb

response 2875

I on Exp% Act%

83.00 100 100

85.00 63.60 60.94

0.00 0.00 0.00

0.00 0.00 0.00

VMS3595.M Mon Apr 27 13:01:02 2015

25 JHL MSD4 1.00

4.70 4.80

,. 115 120

117.9

115 120

~~ 4.90 5.00

p· 125 130

--~-

-~-,··,----,~

125 130

Page: 1

66/224

Revised Report

66/224



D:\Hpchern\1\Data\VMS3597\0424425.D 24 Apr 2015 10:51 pm 0724 9 A

RTE Apr 27 07:20:08 2015


500000!

I

450000,

4000001

~50000,

3000001 !

250000

2000ooi

150000' !

100000

5oooo:

I oi ~ime--> _ 1.00

VMS3595.M Mon Apr 27 07:20:09 2015


~-A

"' 'i • c • N c • ~ ~ ~ .Q ~ y

25 JHL MSD4 1. 00

"' If • N c • ~ e 0 , '5 E

~

~-A

"' 'i ~

~ • N c • ~ • ~

Page: 2

67/224

Revised Report

67/224


Qrlant2tat2on Report (Not Reviewed)

D:\Hpche \1\Data\VMS3597\0424425.D Vial: 25 24 Apr 2 15 10:51 pm Operator: JHL 0724 9 Inst MSD4

Mul tiplr: 1. 00 Integrator: RTE Quant Time: Apr 27 0 :35:41 2015

Quant Method D:\Hpchem\Methods\APIX-W\VMS3596.M Quant Title VMS25 5 8260 APX9-W ICAL QLast Update Fri A r 24 14:17:48 2015 Response via Initi 1 Calibration DataAcq Meth:MSD4 AC .M


Internal Standards 1) Fluorobenzene KIS> 5.189 70 29809 30.00 ppb 0.00

13) 1-chloro-3-flubrobenze. 7.821 95 59871 30.00 ppb 0.00 15) 1,2-dichlorobe zene-04. 9.520 152 64191 30.00 ppb 0.00

System Monitoring c mpounds 8) 1,2-dichloroet ane-d4 4.870 65 40425 30.82 ppb 0.00

/ Spiked Amount 30.000 Range 64 - 140 Recovery 102.73%

/ 12) toluene-dB 6. 74 6 98 145496 31.01 ppb 0.00 Spiked Amount 30.000 Range 82 117 Recovery 103.37% -

14) 4-bromofluorob nzene 8.738 95 67308 30.79 ppb 0.00 Spiked Amount 30.000 Range 85 - 115 Recovery 102.63%



VMS3596.M Mon Apr 27 '8:35:41 2015 Page: 1

68/224

Revised Report

68/224

buantitation Report (Not Reviewed)

Data File D: \Hpch m\1\Data\VMS3597\0424425.D Acq On 24 Apr 015 10:51 pm Sample 0724 9 A Mise Integrator: RTE Quant Time: Apr 27 8:35:41 2015

Quant Method : D:\Hrchem\Methods\APIX-W\VMS3596.M Quant Title : VMS2t75 8260 APX9-W ICAL QLast Update : Fri pr 24 14:17:48 2015 Response via : Init

1

'al Calibration DataAcq Meth:MSD4 A Q.M

===-------. ----1 ~bundance I 54oooo

I :::::: 480000

460000

440000

420000

400000

380000

360000

340000

320000

300000

280000

260000

240000

220000

200000

180000

160000

140000

120000

100000

80000

60000


"' ' w

" • c • ~ • ~ e 0 , ~

~ .Q

"II


'!! ,· w

" ~ 'Z c • w •.

c • ~ • ~ e 0 , = 0 E e ~ .,

25 JHL MSD4 1.00

. -1

~ T-'T''T; =;c_J\__=-;.. · ~ UJ~~..,-~~-"r,-r-r~-ll-;-r~,.J!,.....-~"'-.,-~~ •, -.-~~,.,-~~J ime--> 1.oo __ '"2.,.oo_ ·~- _ 4.oo__. 5.00 6.00 LO_O ___ ~QQ__ 9,QQ__1o .. "oo.,_ _ _,11.00 12.00


1

08:35:41 2015 Page: 2

QC, Blanks Data

SW-846 8260B


69/224

Revised Report

69/224

SW-846 8260B VXX5659


70/224

Revised Report

70/224

Batch Summary

SW-846 8260B SW-846 5030BAnalytical Method: Prep Method:

VXX5659

04/27/2015 08:28

Prep Batch:

Prep Date:

Client Sample ID Analysis Date Instrument AnalystLab Sample ID Analytical Batch

LCS for HBN 74466 [VXX/5659] 04/24/2015 17:01 MSD4 JHL165933 VMS3597

LCSD for HBN 74466 [VXX/5659] 04/24/2015 17:28 MSD4 JHL165934 VMS3597

MB for HBN 74466 [VXX/5659] 04/24/2015 18:22 MSD4 JHL165935 VMS3597

GMA4-8-042015 04/24/2015 21:04 MSD4 JHL31500724001 VMS3597

GMA4-8-042015 MS 04/25/2015 01:33 MSD4 JHL31500724002 VMS3597

GMA4-8-042015 MSD 04/25/2015 02:00 MSD4 JHL31500724003 VMS3597

H78B-16-042015 04/24/2015 21:31 MSD4 JHL31500724005 VMS3597

GMA4-75-042015 04/24/2015 21:58 MSD4 JHL31500724006 VMS3597

GMA4-EB-042015 04/24/2015 22:24 MSD4 JHL31500724007 VMS3597

Dup-1-042015 04/24/2015 22:51 MSD4 JHL31500724009 VMS3597


71/224

Revised Report

71/224

Surrogate Summary Form 2


Matrix: Water

Work Order: 31500724



12-DCE-D4 4-BFB Dibromofluor

omethane

TOL-D8

Dup-1-042015 103 98 103

GMA4-75-042015 101 97 101

GMA4-8-042015 100 97 101

GMA4-8-042015 MS 104 100 103

GMA4-8-042015 MSD 106 99 103

GMA4-EB-042015 102 96 101

H78B-16-042015 100 99 101

LCS for HBN 74466 [VXX/5659] 90 98 98 102

LCSD for HBN 74466 [VXX/5659] 99 102 99 101

MB for HBN 74466 [VXX/5659] 102 100 97 100

Control Limits

1,2-Dichloroethane-d4 12-DCE-D4 64.0-140

4-Bromofluorobenzene 4-BFB 62.0-132

Dibromofluoromethane Dibromofluoromethan 58.0-133

Toluene d8 TOL-D8 65.0-127


72/224

Revised Report

72/224


Analytical Date/Time: 04/24/2015 15:29

Instrument: MSD4

Filename: 0424410.D

Analyst: JHL

SW-846 8260B

Internal Standard/Retention Time Window Summary Form 8

RT High RT LowRT Area Area High Area LowPARAMETER

1,2-Dichlorobenzene-d4 9.52 10.02 9.02 67174 134348 33587

Fluorobenzene 5.19 5.69 4.69 35929 71858 17965

1-Chloro-3-fluorobenzene 7.82 8.32 7.32 65892 131784 32946

RT RT RTArea Area Area

IS1 IS2 IS3

CUSTOMER SAMPLE

5.19 59512 7.82 113669 9.52 109938LCS for HBN 74466 [VXX/5659]

5.19 37622 7.82 69812 9.52 71581LCSD for HBN 74466 [VXX/5659]

5.19 35858 7.82 67612 9.52 68581MB for HBN 74466 [VXX/5659]

5.19 32585 7.82 63633 9.52 64124GMA4-8-042015

5.19 32116 7.82 62984 9.52 64273H78B-16-042015

5.19 31645 7.82 62147 9.52 64576GMA4-75-042015

5.19 31823 7.82 63546 9.52 66458GMA4-EB-042015

5.19 29809 7.82 59871 9.52 64191Dup-1-042015

5.19 30193 7.82 62184 9.52 65915GMA4-8-042015 MS

5.19 26654 7.82 55181 9.52 61124GMA4-8-042015 MSD


73/224

Revised Report

73/224



Instrument: MSD4

Filename: 0424411.D

Analyst: JHL

SW-846 8260B




Fluorobenzene 5.19 5.69 4.69 37236 74472 18618



IS1 IS2 IS3

CUSTOMER SAMPLE

5.19 59512 7.82 113669 9.52 109938LCS for HBN 74466 [VXX/5659]

5.19 37622 7.82 69812 9.52 71581LCSD for HBN 74466 [VXX/5659]

5.19 35858 7.82 67612 9.52 68581MB for HBN 74466 [VXX/5659]

5.19 32585 7.82 63633 9.52 64124GMA4-8-042015

5.19 32116 7.82 62984 9.52 64273H78B-16-042015

5.19 31645 7.82 62147 9.52 64576GMA4-75-042015

5.19 31823 7.82 63546 9.52 66458GMA4-EB-042015

5.19 29809 7.82 59871 9.52 64191Dup-1-042015

5.19 30193 7.82 62184 9.52 65915GMA4-8-042015 MS

5.19 26654 7.82 55181 9.52 61124GMA4-8-042015 MSD


74/224

Revised Report

74/224

75/224

Revised Report

75/224

Tune File Tune Time

GC/MS QA-QC ~heck Report

D:\Hpchem\l\Dala\VMS3597\0424409.D 24 Apr 2015 6:02 pm

Daily Calibration File : D:\Hpchem\l\Data\4042315\0423409.D

40657 74598 75739

File Sample Surrogate Recovery % Internal Standard Responses =========================~=============================================== No Quant Results for D:\H~chem\l\Data\VMS3597\0424409.D --------------------c----~1-----------------------------------------------No Quant Results for D:\Hdchem\l\Data\VMS3597\0424410.D

042441l.D QCKOlO

0424412.D 165933 LCS

0424413. D 165934 LCS

0424414.D R

0424415.D 165935 MB

0424416.D 0696 2 A

0424417.D 0697 5 A

0424418.D 0697 4 A

0424419.D 0697 3 A

0424420. D 0713 2 A

042442l.D 0724 1 A

0424422.D 0724 5 A

0424423.D 0724 6 A

0424424.D 0724 7 A

0424425.D 0724 9 A

0424426.D 0726 2 A

0424427.D 0725 3 A

0424428.D

100 101 100 101 37236

98 90 102 98 59512

99 99 101 102 37622

97 101 100 100 37099

97 102 100 100 35858

97 102 100 100 32578

97 101 100 101 34403

97 102 101 100 35026

96 99 100 100 34597

97 101 101 102 34190

97 102 101 100 32585

99 102 101 100 32116

97 103 101 101 31645

96 101 101 102 31823

98 104 103 103 29809

96 103 101 102 31530

98 104 103 102 32853

68960 71022

113669 109938

69812 71581

70325 70710

67612 68581

61552 61780

65684 66093

67175 67635

66333 66447

66234 67172

63633 64124

62984 64273

62147 64576

63546 66458

59871 64191

63293 66877

66935 68940

76/224

Revised Report

76/224

0725 4 A 97 1103 101 103 29660 59934 63630 -------------~------------ ----------------------------------------------0424429.D

0725 8 A 97 104 102 102 29642 60674 63393

--------------------------1----------------------------------------------0424430.D

0725 9 A 98 05 103 103 29452 60326 63802 -------------------------- ----------------------------------------------042443l.D

0724 2 A- 100 03 103 104 30193 62184 65915

0424432.D 0724 3 A- 99 . 08 103 106 26654 55181 61124

(fails) - fails 12hr time check * - fails criteria

Created: Mon Apr 27 07:25:03 2015 MSD4

Blank ID: MB for HBN 74466 [VXX/5659]

Blank Lab ID: 165935

Prep Batch: VXX5659

Matrix: Water

Analysis Date/Time: 04/24/2015 18:22


Method Blank Summary Form 4

Client Sample ID Lab Sample ID Filename Date Analyzed Analyst

LCS for HBN 74466 [VXX/5659] 165933 04/24/2015 17:010424412.D JHL

LCSD for HBN 74466 [VXX/5659] 165934 04/24/2015 17:280424413.D JHL

GMA4-8-042015 31500724001 04/24/2015 21:040424421.D JHL

H78B-16-042015 31500724005 04/24/2015 21:310424422.D JHL

GMA4-75-042015 31500724006 04/24/2015 21:580424423.D JHL

GMA4-EB-042015 31500724007 04/24/2015 22:240424424.D JHL

Dup-1-042015 31500724009 04/24/2015 22:510424425.D JHL

GMA4-8-042015 MS 31500724002 04/25/2015 01:330424431.D JHL

GMA4-8-042015 MSD 31500724003 04/25/2015 02:000424432.D JHL


77/224

Revised Report

77/224



Matrix: Water


Method Blank

Parameter Result LOQ/CLDL Units DFQual

QC for Samples:

31500724001, 31500724005, 31500724006, 31500724007, 31500724009

Dichlorodifluoromethane ND 5.000.0660 ug/L 1U

Chloromethane ND 1.000.0610 ug/L 1U

Vinyl chloride ND 1.000.0700 ug/L 1U

Bromomethane ND 1.000.106 ug/L 1U

Chloroethane ND 1.000.147 ug/L 1U

Trichlorofluoromethane ND 1.000.0690 ug/L 1U

Acrolein ND 25.04.26 ug/L 1U

1,1-Dichloroethene ND 1.000.0960 ug/L 1U

Acetone ND 25.00.813 ug/L 1U

Acetonitrile ND 20.011.5 ug/L 1U

Allyl chloride ND 1.000.216 ug/L 1U

Methylene chloride ND 5.000.0750 ug/L 1U

trans-1,2-Dichloroethene ND 1.000.0990 ug/L 1U

Acrylonitrile ND 25.02.06 ug/L 1U

1,1-Dichloroethane ND 1.000.0860 ug/L 1U

Chloroprene ND 1.000.162 ug/L 1U

2-Butanone ND 25.00.523 ug/L 1U

Propionitrile ND 20.02.22 ug/L 1U

Methylacrylonitrile ND 10.01.42 ug/L 1U

Chloroform ND 1.000.0640 ug/L 1U

1,1,1-Trichloroethane ND 1.000.0600 ug/L 1U

Carbon tetrachloride ND 1.000.0520 ug/L 1U

Isobutyl alcohol ND 50.06.07 ug/L 1U

Benzene ND 1.000.132 ug/L 1U


Trichloroethene ND 1.000.0870 ug/L 1U

1,2-Dichloropropane ND 1.000.285 ug/L 1U

Dibromomethane ND 1.000.251 ug/L 1U

Bromodichloromethane ND 1.000.206 ug/L 1U

Methyl methacrylate ND 1.000.0985 ug/L 1U

1,4 Dioxane ND 10014.4 ug/L 1U

2-Chloroethylvinyl ether ND 25.01.87 ug/L 1U

cis-1,3-Dichloropropene ND 1.000.104 ug/L 1U

4-Methyl-2-pentanone ND 5.000.469 ug/L 1U

Toluene ND 1.000.0660 ug/L 1U

Methyl iodide ND 1.000.0570 ug/L 1U

trans-1,3-Dichloropropene ND 1.000.0832 ug/L 1U

Ethyl methacrylate ND 1.000.127 ug/L 1U

Vinyl acetate ND 2.000.303 ug/L 1U

Carbon disulfide ND 1.000.0860 ug/L 1U



78/224

Revised Report

78/224



Matrix: Water


Method Blank


QC for Samples:

31500724001, 31500724005, 31500724006, 31500724007, 31500724009

Tetrachloroethene ND 1.000.0750 ug/L 1U

2-Hexanone ND 5.000.586 ug/L 1U

Dibromochloromethane ND 1.000.0880 ug/L 1U

1,2-Dibromoethane ND 1.000.0920 ug/L 1U

Chlorobenzene ND 1.000.0954 ug/L 1U

1,1,1,2-Tetrachloroethane ND 1.000.201 ug/L 1U

Bromoform ND 1.000.170 ug/L 1U


1,2,3-Trichloropropane ND 1.000.130 ug/L 1U

Ethyl Benzene ND 1.000.0656 ug/L 1U

Styrene ND 1.000.0750 ug/L 1U

Xylene (total) ND 2.000.200 ug/L 1U

1,2-Dibromo-3-chloropropane ND 5.001.40 ug/L 1U

trans-1,4-Dichloro-2-butene ND 5.001.03 ug/L 1U

Surrogates

1,2-Dichloroethane-d4 102 64.0-140 % 1

Dibromofluoromethane 97.0 58.0-133 % 1

Toluene d8 100 65.0-127 % 1

4-Bromofluorobenzene 100 62.0-132 % 1

Batch Information

Prep Batch: VXX5659


Prep Date/Time: 4/27/2015 8:28:58AM





Instrument: MSD4

Analyst: JHL


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Revised Report

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Revised Report

80/224


1

~uantitation Report (Not

D:\Hpchlm\1\Data\VMS3597\0424415.D 24 Apr ~015 6:22 pm 165935 B

RTE Apr 27 17:19:37 2015

Reviewed)


Quant Method D:\H chem\Methods\8260-W\VMS3595.M Quant Title VMS3,95 8260/6200/624 Water ICAL QLast Update Fri tpr 24 11:45:19 2015 Response via Init al Calibration DataAcq Meth:MSD4 A Q.M

15 JHL MSD4 1.00



42} 1-chloro-3-fl orobenze. 56) 1,2-dichlorob nzene-04.

System Monitoring 1ornpounds

5.189 7.818 9.520

70 95

152

35858 67612 68581

30.00 ppb 30.00 ppb 30.00 ppb

24) dibromofluoro ethane 4.245 113 44410 29.04 ppb Spiked Amount 30.000 Range 86- 118 Recovery 96.80%

0.00 0.00 0.00

0.00

0.00

/ 26) 1,2-dichloroelhane-d4 4.870 65 47454 30.47 ppb Splked Amount 30.000 Range 64 - 130 Recovery 101.57%

36) toluene-dB 6.746 98 170159 29.94 ppb O.oo/ Splked Amount 30.000 Range 82 - 117 Recovery 99.80%

52) 4-bromofluoro enzene 8.738 95 73493 29.90 ppb 0.00 Splked Amount l 30.000 Range 85- 115 Recovery 99.67%

Target Compounds Qvalue 12) trans-1,2-dlc,loroethene 2.427 96 211 n 0~ ppb # 64

-~~~-===~=~-~~=~==t~=------------~~~2~---2~-----~~~~-----~~~~-~~~--~----== (#) = qualifier ou of range (rn) = manual integration (+) = signals summed

VMS3595.M Mon Apr 27 7:19:37 2015 Page: 1

81/224

Revised Report

81/224



D:\Hpchem\l\Data\VMS3597\0424415.D 24 Apr 2015 6:22 pm 165935 MB




15 JHL MSD4 1. 00

------~~Fam~~~============~~================~======~n~424~c!J~t~s=====================~========================~------founa-ance I

' I 550000j

I ' I

500000'

450000 I

400000:

i '

350oooj

30ooooi

250000!

20ooooj

t 500001 ~

~ • I ~ 1000001 ~ e • ~ ~ ~ ~ "' "' "-50000 c 0 " " c • ~ 0

il

1[ I 'I ;.,II I

oL_,-c·~, ... """"C-~--,cc··· r;,~~,L II 1 1!.~~-r-;~.-.,-,-J-\il..,~~--+'-,-~..,--l ,~ ~-'-' ~.,--r-----r,..--c--, --~. ~~~~~ Tme--_> ___ 1,_00 ___ L50 __ _2,0Q _2jijl_ ~.QO __ :L50 'lQQ__'l§Q.-~0_0 5.50 6.00 6.50 7.00 7.50 . S,QQ__§~OO 9.50 10.00 _1Q_50_ 11.00 11.50 1i00

VMS3595.M Mon Apr 27 07:19:38 2015 Page: 2

82/224

Revised Report

82/224

' Qrl antitation Report (Not Reviewed)

Data File Acq On

D:\Hpche, \1\Data\VMS3597\0424415.D 24 Apr 2' 15 6:22 pm

Sample 165935 Mise Integrator: RTE Quant Time: Apr


:35:14 2015

D:\Hp,hem\Methods\APIX-W\VMS3596.M VMS25 5 8260 APX9-W ICAL Fri A,r 24 14:17:48 2015

Response via Initi 1 Calibration DataAcq Meth:MSD4 AC' .M


15 JHL MSD4 1. 00

Compound R.T. Qion Response Cone Units Dev(Min) ~~~~~~~~-~~~~~~~~~-r------------------------------------------------------

1) Fluorobenzene <IS> 5.189 70 35858 30.00 ppb 0.00 13) 1-chloro-3-flurrobenze. 7.s1s 95 67612 3o.oo ppb o.oo 15) 1,2-dichlorobe zene-04. 9.520 152 68581 30.00 ppb 0.00~

System Monitorlng C'mpounds 8) 1,2-dichloroethane-d4 4.870 65 47454 30.08 ppb 0.00 \ Spiked Amount 30.000 Range 64 - 140 Recovery 100.27% /


14) 4-bromofluorob~nzene 8.738 95 73493 29.77 ppb Splked Amount 30.000 Range 85 - 115 Recovery 99.23%

Target Compounds Qvalue ------------------- ------------------------------------------------------

0.00


VMS3596.M Mon Apr 27 0::35:14 2015 Page: 1

83/224

Revised Report

83/224


Data File D: \Hpc em\1\Data\VMS3597\0424415.D Acq On 24 Apr 2015 6:22 pm Sample 165935 MB Mise Integrator: RTE Quant Time: Apr 27 08:35:14 2015

Quant Method D:\ pchem\Methods\APIX-W\VMS3596.M Quant Title : VMSJ575 8260 APX9-W ICAL QLast Update : Fri Apr 24 14:17:48 2015 Response via : Ini ial Calibration DataAcq Meth:MSD4 CQ.M

bundance TIC: d424415.D\data.ms

5800001

560000

540000

520000 "' ,·

500000 00 v • c

480000 • N c • ~ 460000

e 0 , ., M

440000 " .Q

4200001 J

I 400000

380000 00

360000

340000 i 320000

300000

280000

2600001 ~ ' 00 v • c

240000 • N c • ~ 220000

e 0 , 0:

200000

180000

160000 00 oi

140000 "% c • 120000 .: e

.Q

100000 ~-80000


"' ,· 00 v v

'J c • 00 • c • N c • ~ e 0 , 15 E e ~

15 JHL MSD4 1.00

60000 j 40000! l 2000:L~~"~1r ,JL-l L~-~~~~J-~~: ~-,-l-~-,-,~c~·c-rr-,-,-.,r··---~r-~

ime··> 1.00 2.00 ~0 5.00 6.00 7.00 8.00 9.00 10.0Q___.1_1j)0 ___ 1bQQ __


1

08:35:14 2015 Page: 2

Blank Spike ID: LCS for HBN 74466 [VXX/5659]

Blank Spike Lab ID: 165933

Date Analyzed: 04/24/2015 17:01

Spike Duplicate ID: LCSD for HBN 74466 [VXX/5659]

Spike Duplicate Lab ID: 165934

Date Analyzed: 04/24/2015 17:28


Blank Spike Summary

Matrix: Water

Parameter Spike Result Rec (%) Spike Result Rec (%) RPD (%)CL

Blank Spike (ug/L)

RPD CL

Spike Duplicate (ug/L)

31500724001, 31500724005, 31500724006, 31500724007, 31500724009QC for Samples:

Dichlorodifluoromethane 5.00 5.27 0.0105 5.00 5.27 105 33.0-170 30.00

Chloromethane 5.00 5.43 0.55109 5.00 5.40 108 57.0-132 30.00

Vinyl chloride 5.00 5.45 4.1109 5.00 5.23 105 59.0-138 30.00

Bromomethane 5.00 5.64 1.1113 5.00 5.70 114 51.0-134 30.00

Chloroethane 5.00 5.86 10117 5.00 5.30 106 64.0-145 30.00

Trichlorofluoromethane 5.00 5.44 0.92109 5.00 5.39 108 64.0-133 30.00

Acrolein 125 98.9 2679 125 129 104 56.0-131 30.00

1,1-Dichloroethene 5.00 5.24 0.76105 5.00 5.28 106 71.0-128 30.00

Acetone 25.0 21.6 2486 25.0 27.4 110 52.0-140 30.00

Methylene chloride 5.00 5.20 1.1104 5.00 5.26 105 70.0-113 30.00

trans-1,2-Dichloroethene 5.00 5.37 1.7107 5.00 5.28 106 57.0-138 30.00

Acrylonitrile 125 101 2680 125 131 105 55.0-141 30.00

1,1-Dichloroethane 5.00 5.11 1.2102 5.00 5.17 103 72.0-134 30.00

2-Butanone 25.0 19.3 2877 25.0 25.5 102 58.0-134 30.00

Chloroform 5.00 5.13 2.9103 5.00 5.28 106 74.0-124 30.00

1,1,1-Trichloroethane 5.00 5.20 0.39104 5.00 5.18 104 76.0-119 30.00

Carbon tetrachloride 5.00 5.13 0.78103 5.00 5.17 103 75.0-120 30.00

Benzene 5.00 5.13 1.7103 5.00 5.22 104 78.0-122 30.00

1,2-Dichloroethane 5.00 4.68 1294 5.00 5.30 106 76.0-119 30.00

Trichloroethene 5.00 5.25 2.1105 5.00 5.14 103 78.0-125 30.00

1,2-Dichloropropane 5.00 4.99 2.6100 5.00 5.12 102 74.0-124 30.00

Dibromomethane 5.00 4.50 1690 5.00 5.26 105 71.0-128 30.00

Bromodichloromethane 5.00 4.87 2.697 5.00 5.00 100 72.0-120 30.00

2-Chloroethylvinyl ether 125 103 1183 125 115 92 65.0-128 30.00

cis-1,3-Dichloropropene 5.00 4.95 4.299 5.00 5.16 103 73.0-122 30.00

4-Methyl-2-pentanone 25.0 19.5 2778 25.0 25.5 102 65.0-124 30.00

Toluene 5.00 5.14 2.1103 5.00 5.25 105 82.0-122 30.00

Methyl iodide 5.00 4.74 2.895 5.00 4.61 92 55.0-123 30.00

trans-1,3-Dichloropropene 5.00 4.66 6.293 5.00 4.96 99 70.0-125 30.00

Vinyl acetate 12.5 11.4 2791 12.5 14.9 119 40.0-141 30.00

Carbon disulfide 5.00 5.58 3.6112 5.00 5.38 108 65.0-132 30.00

1,1,2-Trichloroethane 5.00 4.28 1986 5.00 5.19 104 76.0-121 30.00


84/224

Revised Report

84/224



Date Analyzed: 04/24/2015 17:01



Date Analyzed: 04/24/2015 17:28


Blank Spike Summary

Matrix: Water


Blank Spike (ug/L)

RPD CL


31500724001, 31500724005, 31500724006, 31500724007, 31500724009QC for Samples:

Tetrachloroethene 5.00 5.04 3.3101 5.00 5.21 104 59.0-112 30.00

2-Hexanone 25.0 18.8 2975 25.0 25.3 101 56.0-133 30.00

Dibromochloromethane 5.00 4.32 1386 5.00 4.92 98 67.0-122 30.00

1,2-Dibromoethane 5.00 4.13 2283 5.00 5.13 103 74.0-119 30.00

Chlorobenzene 5.00 4.95 4.299 5.00 5.16 103 77.0-133 30.00

1,1,1,2-Tetrachloroethane 5.00 4.78 5.996 5.00 5.07 101 73.0-119 30.00

Bromoform 5.00 4.04 1681 5.00 4.74 95 62.0-127 30.00

1,1,2,2-Tetrachloroethane 5.00 4.01 2980 5.00 5.36 107 68.0-129 30.00

1,2,3-Trichloropropane 5.00 3.96 2779 5.00 5.20 104 67.0-126 30.00

Ethyl Benzene 5.00 5.30 2.3106 5.00 5.18 104 76.0-123 30.00

Styrene 5.00 5.32 2.3106 5.00 5.20 104 76.0-121 30.00

1,2-Dibromo-3-chloropropane 30.0 23.4 2378 30.0 29.4 98 62.0-130 30.00

trans-1,4-Dichloro-2-butene 25.0 20.5 2282 25.0 25.6 102 61.0-132 30.00

Surrogates

1,2-Dichloroethane-d4 90 99 64.0-140

Dibromofluoromethane 98 99 58.0-133

Toluene d8 102 101 65.0-127

4-Bromofluorobenzene 98 102 62.0-132

Batch Information



Instrument: MSD4

Analyst: JHL

Prep Batch: VXX5659


Prep Date/Time: 04/27/2015 08:28

Spike Init Wt./Vol.: 40 mL Extract Vol: 40 mL

Dupe Init Wt./Vol.: 40 mL Extract Vol: 40 mL


85/224

Revised Report

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Revised Report

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1


Data File D:\Hpcheb\1\Data\VMS3597\0424412.D Vial: 12 Acq On 24 Apr 2p15 5:01 pm Operator: JHL Sample 165933 LCI S Inst Mise Multiplr: Integrator: RTE Quant Time: Apr 27 08:52:01 2015

MSD4 1. 00

Quant Method D:\Hp~hem\Methods\8260-W\VMS3595.M Quant Title VMS3505 8260/6200/624 Water ICAL /( 1~ QLast Update Fri Apr-24 11:45:19 2015 t.J~ Response via : Initipl Calibration ~

DataAcq Meth:MSD4_AC[.M 'f-l. 7•1)

Compound R.T. Qlon Response Cone Un1ts Dev(Min) ------------------- ------------------------------------------------------Internal Standards

1) Fluorobenzene ~IS> 5.189 70 59512 30.00 ppb 0.00 42) 1-chloro-3-flubrobenze. 7.818 95 113669 30.00 ppb 0.00 56) 1,2-dichlorobe[zene-o4. 9.520 152 109938 3o.oo ppb o.oo/

System Monitoring Compounds 24) dibromofluorom thane 4.245 113 74891 29.51 ppb 0.00

Spiked Amount 30.000 Range 86 - 118 Recovery 98.37% 26) 1,2-dichloroet ane-d4 4.870 65 70098 27.12 ppb

Spiked Amount 30.000 Range 64 130 Recovery 90.40% 36) toluene-dB 6. 746 98 289164 30.65 ppb

Spiked Amount 30.000 Range 82 117 Recovery 102.17% 52) 4-bromofluorobenzene 8.738 95 121763 29.47 ppb Spiked Amount 30.000 Range 85 115 Recovery 98.23%

0.00/

0.00

0.00

Target Compounds Qvalue 2) dichlorodifluo orne thane 1.007 85 23690 5.27 ppb 100 3) chloromethane 1.119 50 26324 5.43 ppb 100 4) vinyl chloride 1.165 62 27890 5.45 ppb 99 5) bromomethane 1.358 96 15694 5. 64 ppb 100 6) chloroethane 1.436 64 13607 5.86 ppb 95 7) trichlorofluor methane 1.527 101 29974 5.44 ppb 98 8) acrolein 2.117 56 53970 98. 94 ppb 99 9) 1,1-dichloroet ene 1.862 96 18788 5.24 ppb 98

10) acetone 2.360 43 17904 21.61 ppb 99 11) methylene chlo, ide 2.299 84 20732 5.20 ppb 94 12) trans-1,2-dich oroethene 2. 430 96 21703 5.37 ppb 98 13) acrylonitrile 3.081 53 108477 100.51 ppb 97 14) MTBE 2.545 73 43190 4.31 ppb 96 15) 1,1-dichloroet ane 3.006 63 36840 5. 11 ppb 99 16) DlPE 2.916 45 59234 4. 8 7 ppb 97 17) 2,2-dichloropr pane 3.747 77 24012 5.18 ppb 97 18) cis-1,2-dichlo oethene 3.617 96 21453 5.28 ppb 96 19) 2-butanone 4.442 43 27909 19.29 ppb 100 20) bromochloromet ane 3.871 130 10667 4. 94 ppb 95 21) chloroform 4.005 83 33987 5.13 ppb 96 22) 1,1,1-trichlor ethane 4.233 97 28123 5.20 ppb 97 23) carbon tetrach or ide 4.135 117 21799 5.13 ppb 98 25) 1,1-dichloropr pene 4.395 75 28 683 5.26 ppb 97 27) benzene 4.697 78 81317 5.13 ppb 99 28) 1,2-dichloroet ane 4.948 62 21807 4 . 6 8 ppb 97 29) trichloroethenr 5.368 95 208 99 5.25 ppb 98 30) 1,2-dichloropr·pane 5.892 63 20864 4.99 ppb 98 31) dibromomethane 5.788 93 927 5 4.50 ppb 94 32) bromodichlorom thane 5.982 83 21747 4.87 ppb 98 33) 2-chloroethyl 1inyl ether 6. 567 106 31771 103.21 ppb 99 34) cis-1,3-dichlo opropene 6.584 75 28629 4.95 ppb 99 35) 4-methyl-2-pen anone 7.169 43 54691 19.46 ppb 98 37) toluene 6.790 92 4 6770 5.14 ppb 98 38) iodomethane 1.961 142 27734 4.74 ppb 100 39) trans-1,3-dich oropropene 7.184 75 21037 4.66 ppb 99 40) Vinyl acetate 3.321 43 74181 11. 40 ppb 99 41) carbon disulfi' e 1.877 76 56017 5.58 ppb 98 43) 1, 1, 2-trichlor, ethane 7.317 83 11697 4.28 ppb 97 44) tetrachloroethrne 7.120 166 19914 5.04 ppb 97

VMS3595.M Mon Apr 27 0 :52:01 2015 Page: 1

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Revised Report

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1

Q~anti tat ion Report (Not Reviewed)

Data File D:\Hpcheb\l\Data\VMS3597\0424412.D Vial: 12 Acq on 24 Apr 2e15 5:01pm Operator: JHL

MSD4 1. 00

Sample 165933 LCI S Inst Mise Multiplr: Integrator: RTE Quant Time: Apr 27 0~:52:01 2015

Quant Method : D:\Hpchem\Methods\8260-W\VMS3595.M Quant Title : VMS35~5 8260/6200/624 Water ICAL QLast Update : Fri Apr-24 11:45:19 2015 Response via : Initi~l Calibration DataAcq Meth:MSD4_ACQ.M

-------~~:~~~~~----~--------------~~~~-~=~~--~==~~~==--~~~=-~~=~=-~=~~~~~~ 45) 1,3-dlchloropr pane 7.534 76 24162 4.31 ppb 98 46) 2-hexanone 7. 838 43 38620 18.78 ppb 99 47) dibromochlorom thane 7.453 129 13206 4.32 ppb 92 48) 1,2-dibromoeth ne 7.618 107 12244 4.13 ppb 98 49) chlorobenzene 8. 009 112 47963 4. 95 ppb 99 50) 1,1,1,2-tetrac loroethane 8.058 131 14995 4.78 ppb 98 51) bromoform 8.437 173 6393 4.04 ppb 98 53) bromobenzene 8.788 156 17902 4.87 ppb 98 54) 1,1,2,2-tetrac loroethane 8.860 83 13197 4.01 ppb 97 55) 1,2,3-trichlor propane 8.924 110 3770 3.96 ppb # 84 57) ethy1benzene 8.041 106 25047 5.30 ppb 99 58) m/p-xylene 8.136 106 59649 10.56 ppb 98 59) styrene 8.432 104 46342 5.32 ppb 99 60) o-xylene 8.400 106 28580 5.22 ppb 97 61) isopropylbenze[e 8.585 105 72989 5.33 ppb 100 62) n-propyl benze e 8.814 91 83438 5.39 ppb 99 63) 2-chloroto1uen 8.892 126 16336 5.30 ppb 98 64) 4-chlorotoluen 8.982 126 16791 5.34 ppb 93 65) 1,3,5-trimethylbenzene 8.921 105 54241 5.33 ppb 97 66) tert-butylbenzlone 9.083 119 45690 5.30 ppb 100 67) 1,2,4-trimethy benzene 9.118 105 55019 5.43 ppb 99 68) sec-butylbenze e 9.173 105 66039 5.37 ppb 99 69) 1,3-dich1orobe zene 9.277 146 31324 5.22 ppb 99 70) 4-isopropyltol ene 9.245 119 52901 5.39 ppb 99 71) 1,4-dichlorobe zene 9.320 146 30988 5.19 ppb 98 72) 1,2-dichlorobe zene 9.526 146 28387 5.00 ppb 98 73) n-butylbenzene 9.448 91 44163 5.44 ppb 99 74) 1,2-dibromo-3- hloropr. 9.902 75 9803 23.38 ppb 99 75) 1,2,4-trichlor,benzene 10.209 180 14589 4.97 ppb 94 76) hexachlorobuta,iene 10.192 225 6216 5.23 ppb 97 77) naphthalene 10.360 128 27072 4.28 ppb 98 78) trans-1,4-Dich oro-2-b. 8.950 53 17988 20.53 ppb 93 79) 1,2,3-trichlor, benzene 10.444 180 12140 4. 64 ppb 94

(#) = qualifier out of range (rn) = manual integration (+) = signals summed

VMS3595.M Mon Apr 27 0 :52:01 2015 Page: 2

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Revised Report

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Data File Acq On

D:\Hpchem\l\Data\VMS3597\0424412.D 24 Apr 2015 5:01pm

Sample 165933 LCS Mise Integrator: RTE Quant Time: Apr 27 08:52:01 2015

Quant Method D:\Hpchem\Methods\8260-W\VMS3595.M Quant Title VMS3595_8260/6200/624 Water ICAL QLast Update Fri Apr 24 11:45:19 2015 Response via Initial Calibration DataAcq Meth:MSD4_ACQ.M

600000

500000

00 oi

"' >-_ j • >-- 0 c

l!e->-_ >-_ • >- >--~ ~ @'c 1-_ ~ O.oi • 1-:2 a) • • 0 • "

,__, j~~ air, g: ~ ~ D ~ 1'E ~~ >-_ ·r:::.2 -a;-ffiffi ""C~ a. "

l>-.2{) 00 >-_ >--• E

~ E! a.£ S..e ~ • c 0 £'9

~ .52 E! ~ () :Ciii 0 6ii!i ~-§

c ,~ -~ ON e-2• :§ eE! r-:. E .... -~- • ,= g: "'7-1- ~ iSQe •c~ .. -0

"9.2.52 E<D ~ E•e ::s1 ~ 3:-"' u.i w:c • • o!!i ~.!.! ..... .!:..c:,E:~ . ~

~.52 """~"' -,; -7:Mg~g -.:§ ~~ ooll wc::f:!!l- 0"9 c

.o..Q:S ~ Sl"=> 5 ·G~~:c~ B =o-8> {) .E 0 ""..c (.) (.) ~ •

VMS3595.M Mon Apr 27 08:52:02 2015


12 JHL MSD4 1. 00

>-_ •

t

Page: 3

89/224

Revised Report

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I Qrl antitation Report (Not Reviewed}

Data File D:\Hpche1

\1\Data\VMS3597\0424413.D Vial: 13 Acq On 24 Apr 2015 5:28 pm Operator:

~~:~le 165934 L~1, SD ~~~~iplr: Integrator: RTE Quant Time: Apr 27 0~:52:04 2015

Quant Method D:\Hpfhem\Methods\8260-W\VMS3595.M Quant Title VMS35p5_8260/6200/624 Water ICAL QLast Update Fri Afr 24 11:45:19 2015 Response via lniti~l Calibration DataAcq_ Meth:MSD4_ACf.M

JHL MSD4 1.00

Compound I R.T. Qion Response Cone Units Dev(Min)

~~~~~~~~-~~~~~~;~~-r------------------------------------------------------

1) Fluorobenzene KIS> 5.189 70 37622 30.00 ppb 0.00 42) l-chloro-3-fluprobenze. 7.818 95 69812 30.00 ppb 0.00 56) l,2-dichloroberzene-D4. 9.520 152 71581 30.00 ppb o.oo

System Monitoring Compounds 24) dibromofluorom~thane

Spiked Amount 30.000 26) 1,2-dichloroet ane-d4

Spiked Amount 30.000 36) toluene-dB

Spiked Amount 30.000 52) 4-bromofluorob nzene Spiked Amount 30.000

Target Compounds 2) dichlorodifluo orne thane 3) chloromethane 4) vinyl chloride 5) bromomethane 6) chloroethane 7) trichlorofluoromethane 8) acrolein 9) 1,1-dichloroet ene

10) acetone 11) methylene chlo, ide 12) trans-1,2-dich oroethene 13) acrylonitrile 14) MTBE 15) 1,1-dichloroet ane 16) DlPE 17) 2,2-dichloropropane 18) "''-'·'-d'o'''oto"'''"'' 19) 2-butanone 20) brornochloromet ane 21) chloroform 22) 1,1,1-trichlor~ethane 23) carbon tetrach oride 25) 1,1-dichloroprbpene 27) benzene 28) 1,2-dichloroet ane 29) trichloroethen[ 30) 1,2-dichloropropane 31)

113 118 65

- 130

4.248 Range 86 -

4.870 Range 64

6.747 Range 82 -

8.736 Range 85

1.004 1.119 1.165 1.358 1.431 1.524 2.117 1.862 2.357 2.299 2.427 3.081 2.543 3.006 2.919 3.744 3.614 4.442 3.872 4.008 4.236 4.135 4.396 4.700 4.949 5.366 5. 892 5.785

98 117 95 115

85 50 62 96 64

101 56 96 43 84 96 53 73 63 45 77 96 43

130 83 97

117 75 78 62 95 63 93 dibromomethanel

32) brornodichlororn thane 5.982 83 33) 2-chloroethyl ~inyl ether 6.564 106 34) cis-1,3-dich1o opropene 6.582 75 35) 4-methyl-2-penranone 7.169 43 37) toluene 6.793 92 38) iodornethane 1.958 142 39) trans-1,3-dichloropropene 7.184 75 40) Vinyl acetate 3.321 43 41) carbon disulfi~e 1.877 76 43) 1,1,2-trichlor~ethane 7.317 83 44) tetrachloroethl ne 7.120 166

VMS3595.M Mon Apr 27 0~:52:04 2015



179826 30.15 Recovery


14957 5.27 16570 5.40 16920 5.23 10024 5.70

7773 5.30 18770 5.39 44 650 129.49 11962 5.28 14403 27.42 13264 5.26 134 91 5.28 89481 131.15 32035 5.06 23549 5.17 39466 5.14 15139 5.17 13572 5.29 23366 25.54

7335 5.38 22131 5.28 17729 5.18 13875 5.17 18247 5.29 52241 5.22 15614 5.30 12924 5.14 13539 5. 12

6851 5.26 14119 5.00 23437 115.20 18873 5.16 45252 25.47 30170 5.25 17039 4.61 14164 4.96 61143 14.87 34133 5.38

8715 5.19 12 641 5.21

ppb 98.63%

ppb 99.03%

ppb 100.50% ppb 101.83%

0.00

0.00

0.00

0.00

Qvalue ppb 99 ppb 99 ppb 95 ppb 97 ppb 90 ppb 100 ppb 97 ppb 98 ppb 98 ppb 98 ppb 98 ppb 98 ppb 98 ppb 100 ppb 99 ppb 93 ppb 94 ppb 99 ppb 97 ppb 94 ppb 99 ppb 100 ppb 99 ppb 97 ppb 98 ppb 96 ppb 100 ppb 98 ppb 100 ppb 99 ppb 97 ppb 98 ppb 100 ppb 98 ppb 98 ppb 97 ppb 98 ppb 98 ppb 96

Page: 1

/ /

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Revised Report

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Data File D:\Hpche~\1\Data\VMS3597\0424413.D Acq On 24 Apr 2bl5 5:28 pm Sample 165934 L SO Mise Integrator: RTE Quant Time: Apr 27 0 :52:04 2015

Quant Title : VMS35 5 8260/6200/624 Water ICAL QLast Update : Fri A r-24 11:45:19 2015 Response via : Initi l Calibration


13 JHL MSD4 1.00

DataAcq Meth:MSD4_AC .M

-~;)-~~;~~~~~~~~~~~[~~~~---------;~;;~-~=;~--~=~;;~~=--=~;~~~~~~~-~=~~~~~; 46) 2-hexanone t 7.841 43 31898 25.26 ppb 98 47) dibromochlororn

1

ethane 7.453 129 9241 4.92 ppb 99 48) 1,2-dibrornoethlane 7.618 107 9334 5.13 ppb 99 49) ch1orobenzene 8.006 112 30705 5.16 ppb 100 50) 1,1,1,2-tetraclhloroethane 8.058 131 9768 5.07 ppb 99 51) bromoform 8.440 173 4764 4.74 ppb 97 53) brornobenzene 8.788 156 11961 5.30 ppb 97 54) 1,1,2,2-tetrach1oroethane 8.860 83 10833 5.36 ppb 97 55) 1,2,3-trichloropropane 8.924 110 3045 5.20 ppb 99 57) ethylbenzene 8.041 106 15946 5.18 ppb 92 58) rn/p-xyl~ne 8.139 106 37786 10.28 ppb 99 59) styrene 8.435 104 29478 5.20 ppb 97 60) a-xylene 8.400 106 18019 5.06 ppb 99 61) isopropylbenze

1

ne 8.585 105 45793 5.13 ppb 98 62) n-propyl benzene 8.814 91 52919 5.25 ppb 100 63) 2-chlorotoluede 8.892 126 10327 5.14 ppb 97 64) 4-chlorotolue~e 8.979 126 10636 5.19 ppb 97 65) 1,3,5-trirneth~lbenzene 8.921 105 34854 5.26 ppb 96 66) tert-butylben~ene 9.083 119 29114 5.19 ppb 100 67) 1,2,4-trirneth~lbenzene 9.118 105 35139 5.32 ppb 99 68) sec-butylbenz~ne 9.173 105 42085 5.25 ppb 99 69) 1,3-dichlorob~nzene 9.277 146 20311 5.20 ppb 99 70) 4-isopropy1tojuene 9.245 119 33639 5.26 ppb 99 71) 1,4-dichlorobenzene 9.321 146 20367 5.24 ppb 99 72) 1,2-dich1oroblnzene 9.523 146 19168 5.19 ppb 98 73) n-butylbenzen 9.448 91 27677 5.23 ppb 99 74) 1,2-dibromo-3 chloropr... 9.902 75 8029 29.41 ppb 95 75) 1,2,4-trichlo obenzene 10.206 180 9840 5.15 ppb 99 76) hexachlorobut diene 10.192 225 4036 5.21 ppb 96 77) naphthalene 10.357 128 20851 5.06 ppb 99 78) trans-1,4-Dic loro-2-b... 8.950 53 14582 25.57 ppb 90 79) 1,2,3-trichlo obenzene 10.441 180 8936 5.25 ppb 100

(#) = qualifier ou of range {m) = manual integration {+) = signals summed

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Revised Report

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D:\Hpchem\1\Data\VMS3597\0424413.D 24 Apr 2015 5:28 pm 165934. LCSD

RTE Apr 27 08:52:04 2015


VMS3595.M Mon Apr 27 08:52:05 2015


13 JHL MSD4 1.00

Page: 3

Original Sample ID: 31500724001 (GMA4-8-042015)

MS Sample ID: 31500724002

MSD Sample ID: 31500724003

Analysis Date: 04/24/2015 21:04

Analysis Date: 04/25/2015 01:33

Analysis Date: 04/25/2015 02:00

Matrix: Water


Matrix Spike Summary

Parameter Sample Spike Result Rec (%) Spike Result Rec (%) RPD (%)

Matrix Spike (ug/L) Spike Duplicate (ug/L)

CL RPD CL

QC for Samples: 31500724001, 31500724005, 31500724006, 31500724007, 31500724009

1,1,1,2-Tetrachloroethane ND 5.00 4.33 5.00 3.84 77 1287 20.0069.0-120

1,1,1-Trichloroethane ND 5.00 4.91 5.00 4.38 88 1198 20.0078.0-121

1,1,2,2-Tetrachloroethane ND 5.00 5.12 5.00 5.15 103 0.58102 20.0076.0-136

1,1,2-Trichloroethane ND 5.00 4.75 5.00 4.54 91 4.595 20.0065.0-128

1,1-Dichloroethane ND 5.00 5.03 5.00 4.57 91 9.6101 20.0072.0-134

1,1-Dichloroethene ND 5.00 5.16 5.00 4.60 92 11103 20.0064.0-130

1,2,3-Trichloropropane ND 5.00 4.97 5.00 4.98 100 0.2099 20.0010.0-218

1,2-Dibromo-3-chloropropane ND 30.0 25.5 30.0 27.0 90 5.785 20.0020.0-171

1,2-Dibromoethane ND 5.00 4.57 5.00 4.42 88 3.391 20.0079.0-123

1,2-Dichloroethane ND 5.00 5.38 5.00 4.99 100 7.5108 20.0071.0-127

1,2-Dichloropropane ND 5.00 5.00 5.00 4.51 90 10100 20.0077.0-129

2-Butanone 3.12 25.0 26.0 25.0 30.2 121 * 15104 20.0036.0-107

2-Chloroethylvinyl ether ND 125 ND 125 ND 0 *0 * 20.0017.0-283

2-Hexanone ND 25.0 21.5 25.0 23.5 94 8.986 20.0042.0-111

4-Methyl-2-pentanone ND 25.0 26.4 25.0 28.1 112 6.2105 20.006.90-166

Acetone 25.8 25.0 47.8 25.0 57.6 127 * 1988 * 20.0018.0-85.0

Acrolein ND 125 125 125 144 115 14100 20.000.00-424

Acrylonitrile ND 125 139 125 157 126 12111 20.0085.0-175

Benzene ND 5.00 5.05 5.00 4.53 91 11101 20.0078.0-122

Bromodichloromethane ND 5.00 4.83 5.00 4.29 86 1297 20.0074.0-123

Bromoform ND 5.00 4.23 5.00 3.98 80 6.185 20.0052.0-122

Bromomethane ND 5.00 5.30 5.00 5.12 102 3.5106 20.0010.0-284

Carbon disulfide ND 5.00 4.82 5.00 4.60 92 4.796 20.0069.0-129

Carbon tetrachloride ND 5.00 4.67 5.00 4.13 83 1293 20.0072.0-122

Chlorobenzene ND 5.00 4.50 5.00 4.14 83 8.390 20.0077.0-133

Chloroethane ND 5.00 6.33 5.00 5.29 106 18127 20.0010.0-233

Chloroform ND 5.00 5.15 5.00 4.68 94 9.6103 20.0074.0-128

Chloromethane ND 5.00 5.46 5.00 5.14 103 6.0109 20.0072.0-138

Dibromochloromethane ND 5.00 4.13 5.00 3.81 76 8.183 20.0069.0-117

Dibromomethane ND 5.00 5.15 5.00 4.90 98 5.0103 20.0071.0-137

Dichlorodifluoromethane ND 5.00 5.31 5.00 4.93 99 7.4106 20.0042.0-166

cis-1,3-Dichloropropene ND 5.00 4.29 5.00 3.89 78 9.886 20.0067.0-132

trans-1,3-Dichloropropene ND 5.00 4.46 5.00 4.26 85 4.689 20.0045.0-144

Ethyl Benzene ND 5.00 4.26 5.00 3.64 73 * 1685 20.0074.0-126

Methyl iodide ND 5.00 4.33 5.00 3.83 77 1287 20.0041.0-126

Methylene chloride ND 5.00 5.21 5.00 4.78 96 8.6104 20.0049.0-155


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Revised Report

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Original Sample ID: 31500724001 (GMA4-8-042015)

MS Sample ID: 31500724002

MSD Sample ID: 31500724003

Analysis Date: 04/24/2015 21:04

Analysis Date: 04/25/2015 01:33

Analysis Date: 04/25/2015 02:00

Matrix: Water


Matrix Spike Summary

Parameter Sample Spike Result Rec (%) Spike Result Rec (%) RPD (%)

Matrix Spike (ug/L) Spike Duplicate (ug/L)

CL RPD CL

QC for Samples: 31500724001, 31500724005, 31500724006, 31500724007, 31500724009

Styrene ND 5.00 4.30 5.00 3.64 73 1786 20.0073.0-123

Tetrachloroethene ND 5.00 4.46 5.00 4.00 80 1189 20.0046.0-153

Toluene ND 5.00 5.06 5.00 4.60 92 9.5101 20.0082.0-122

Trichloroethene ND 5.00 4.91 5.00 4.42 88 1198 20.0078.0-125

Trichlorofluoromethane ND 5.00 5.52 5.00 5.04 101 9.1110 20.0077.0-132

Vinyl acetate ND 12.5 14.3 12.5 13.8 111 3.6114 20.000.00-355

Vinyl chloride ND 5.00 5.14 5.00 4.83 97 6.2103 20.0068.0-137

trans-1,2-Dichloroethene ND 5.00 5.05 5.00 4.73 95 6.5101 20.0075.0-124

trans-1,4-Dichloro-2-butene ND 25.0 22.2 25.0 21.2 85 4.689 20.0026.0-149

Surrogates

4-Bromofluorobenzene 106104 62.0-132

Dibromofluoromethane 99100 58.0-133

Toluene d8 103103 65.0-127

Batch Information



Instrument: MSD4

Analyst: JHL

Prep Batch: VXX5659


Prep Date/Time: 04/27/2015 08:28

MS Init Wt./Vol.: 40 mL Extract Vol.: 40 mL

MSD Init Wt./Vol.: 40 mL Extract Vol.: 40 mL


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1

QLantitation Report (Not

D:\Hpche~\l\Data\VMS3597\042443l.D 25 Apr 2 15 1:33am 0724 2 -MS

Integrator: RTE Quant Time: Apr 27 :20:26 2015

Reviewed)


31 JHL MSD4 1.00

Quant Title : VMS35 5_8260/6200/624 Water ICAL ~ QLast Update : Fri A r 24 11:45:19 2015

Quant Method : D:\Hp~hem\Methods\8260-W\VMS3595.M t ... / J Response via : Ini ti 1 Calibration / DataAcq Meth:MSD4_AC .M q.}1.1)

;;;;;;;;~;:;:~;;~;-[--···-- ······--RC"C_O>on __ nooponoo __ conc_Pncoo_Pon<M<n>

l) Fluorobenzene fiS> 5.189 70 30193 30.00 ppb 0.00 42) l-chloro-3-flu[robenze. 7.821 95 62184 30.00 ppb 0.00 56) 1,2-dichlorobe zene-D4. 9.520 152 65915 30.00 ppb 0.00

System Monitoring C1

_mpounds / 24) dibromofluorom~ethane 4.245 113 38514 29.91 ppb 0.00

Spiked Amount 30.000 Range 86- 118 Recovery 99.70% 26) 1,2-dichloroet ane-d4 4.870 65 40473 30.86 ppb 0.00

Spiked Amount 30.000 Range 64 - 130 Recovery 102.87% / 36) toluene-dB 6.746 98 147627 30.85 ppb O.OOvf

Spiked Amount 30.000 Range 82 - 117 Recovery 102.83% 52) 4-bromofluorob nzene 8.738 95 70541 31.21 ppb 0.00

Spiked Amount 30.000 Range 85- 115 Recovery 104.03%

Target Compounds Qvalue 2) dichlorodifluo orne thane 1.004 85 12113 5.31 ppb 98 3) chloromethane 1.119 50 13427 5.46 ppb 97 4) vinyl chloride 1.165 62 13341 5. 14 ppb 97 5) bro¥lornethane 1.361 96 7477 5.30 ppb 94 6) chloroethane 1.438 64 7451 6.33 ppb 97 7) trichlorofluor methane 1.524 101 15418 5.52 ppb 97 8) acrolein 2.117 56 34 678 125.31 ppb 99 9) 1,1-dichloroet ene 1.862 96 9390 5.16 ppb 97

10) acetone 2.354 43 20230 47.77 ppb 99 11) methylene chlo' ide 2.302 84 10539 5.21 ppb 95 12) trans-1,2-dich oroethene 2.430 96 10353 5.05 ppb 95 13) acrylonitrile 3.081 53 76183 139.14 ppb 97 14) MTBE 2.545 73 25793 5.08 ppb 99 15) 1,1-dichloroet ane 3.006 63 18391 5.03 ppb 98 16) DIPE 2.922 45 30749 4.99 ppb 97 17) 2,2-dichloropr pane 3.744 77 10434 4.44 ppb 98 18) cis-1,2-dichlo oethene 3.622 96 10186 4.95 ppb 99 19) 2-butanone 4.445 43 19118 26.04 ppb 96 20) bromochloromet ane 3.869 130 5683 5. 19 ppb 96 21) chloroform 4.005 83 17322 5.15 ppb 98 22) ,,,,,_,c,cb>ncf"'"""R 4.233 97 13493 4. 91 ppb # 72 23) carbon tetrach oride 4.135 117 10067 4. 67 ppb 98 25) 1,1-dichloropr pene 4.401 75 13921 5.03 ppb 98 27) benzene 4.702 78 40576 5.05 ppb 100 28) 1,2-dichloroet ane 4.948 62 12719 5.38 ppb 98 29) trichloroethenr 5.365 95 9910 4.91 ppb 99 30) 1,2-dichloropropane 5.895 63 10620 5.00 ppb 99 31) dibromomethane I 5.788 93 5389 5.15 ppb 96 32) bromodichloromtthane 5.982 83 10952 4 . 8 3 ppb 97 34) cis-1,3-dichlo opropene 6.587 75 12598 4.29 ppb 96 35) 4-methyl-2-pentanone 7.169 43 37583 26.36 ppb 98 37) Cn>oone f 6.790 92 23368 5.06 ppb 99 38) 1odomethane 1.963 142 12861 4.33 ppb 98 39) trans-1,3-dlch oropropene 7.187 75 10212 4.46 ppb 100 40) V1nyl acetate 3.321 43 47166 14.29 ppb 99 41) carbon disulfi?e 1.877 76 24539 4.82 ppb 99 43) 1,1,2-trlchloroethane 7.317 83 7110 4.75 ppb 100 44) tetrachloroethtne 7.120 166 964 6 4.46 ppb 99 45) 1,3-dichloropr pane 7.534 76 14567 4.75 ppb 98

VMS3595.M Mon Apr 27 0~:20:26 2015 Page: 1

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1



D:\Hpche~\l\Data\VMS3597\042443l.D 25 Apr 2?15 1:33am 0724 2 -MS

Integrator: RTE Quant Time: Apr 27 0 1 :20:26 2015


hem\Methods\8260-W\VMS3595.M 5 8260/6200/624 Water ICAL r-24 11:45:19 2015



31 JHL MSD4 1.00


46) 2-hexanone 47) dibromochlorom thane 48) 1,2-dibromoeth ne 49) Chlorobenzene so) 1,1,1,2-tetracrloroethane 51) bromoform 53) bromobenzene 54) 1,1,2,2-tetrachloroethane ss> 1,2,3-trichlorr

1

propane 57) ethylbenzene 58) rn/p-xylene 59) styrene 60) a-xylene 61) isopropylbenzepe 62) n-propyl benzeke

~~; ~=~~i~~~~~i~:~k 65) 1,3,5-trlmethy~benzene 66) tert-butylbenzrne 67) 1,2,4-trlmethyfbenzene 68) sec-butylbenze~e

69) 1,3-dichlorobehzene 70) 4-lsopropyltol~ene 71) 1,4-dichlorobe zene 72) 1,2-dichlorobe zene 73) n-butylbenzene 74) 1,2-dibromo-3- hloropr. 75) 1, 2, 4-trlchlorrbenzene 76) hexachlorobutatl1ene

78) trans-1,4-Dlchl oro-2-b. 79) 1,2,3-trlchlor benzene

7.841 7.456 7.618 8.009 8.061 8.440 8.788 8.860 8. 924 8.041 8.139 8.434 8.400 8.585 8.814 8.892 8.979 8.921 9.083 9.118 9.173 9.277 9.245 9.320 9.523 9.448 9.899

10.206 10.189 10.357

8.950 10.441

43 129 107 112 131 173 156

83 110 106 106 104 106 105

91 126 126 105 119 105 105 146 119 146 146

91 75

180 225 128

53 180

24173 6902 7407

23849 7423 3700 9351 9217 2593

12076 28987 22440 13814 35100 40153

7971 8255

26820 22066 26815 31564 15649 24966 15670 15352 20044

6400 7257 2817

16150 11645

6605

21.49 4.13 4. 57 4.50 4.33 4.23 4.65 5.12 4.97 4 • 2 6 8.56 4.30 4.21 4.27 4.32 4.31 4.38 4.39 4.27 4. 41 4.28 4.35 4.24 4.38 4.51 4.12

25.46 4.12 3.95 4.26

22.17 4.21

ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb

#

#

97 97 99 99 98 99 99

100 95 93 96

100 95 99 99 96 99 97 99 98 99 99 98 99 97 98 91 97 94 99 80 98

77) naphthalene l ------------------- ------------------------------------------------------

(#) qualifier out of range (m) = manual integration (+) = signals summed

VMS3595.M Mon Apr 27 0 :20:26 2015 Page: 2

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D:\Hpchem\1\Data\VMS3597\0424431.D 25 Apr 2015 1:33 am 0724 2 A-MS

RTE Apr 27 07:20:26 2015

Quant Method D:\Hpchern\Methods\8260-W\VMS3595.M Quant Title VMS3595 8260/6200/624 Water ICAL QLast Update Fri Apr 24 11:45:19 2015 Response via Initial Calibration DataAcq Meth:MSD4_ACQ.M


li\liundance~ --------- TIC: 0424431 ~Didata.ms

600000

550000

500000;

450000!

400oool

350000: ' !

i

300000J

i 2500ooi

i '

200oooi

150000~

100000j

VMS3595.M Mon Apr 27 07:20:27 2015

31 JHL MSD4 1. 00

I ! I

Page: 3

97/224

Revised Report

97/224

I alantitation Report (Not Reviewed)

Data File D:\Hpche~- \1\Data\VMS3597\0424432.D

~~~p~~ ~~ 2~p~ 2~b=~SD 2:00 am Mise Integrator: RTE Quant Time: Apr 27 0 :20:29 2015


32 JHL MSD4 1.00

Quant Method : D:\Hpchem\Methods\8260-W\VMS3595.M Quant Title : VMS35i

1

5_8260/6200/624 Water ICAL QLast Update : Fri A r 24 11:45:19 2015 Response via : Ini ti 1 Calibration J / DataAcq Meth:MSD4_ACQ.M -,.t7•1)

~~~~~~~~~~~~~~~~~~-t--------------~~~~-~=~~--~==~~~==--=~~~-~~~~=-~=~~~~~~ 1) Fluorobenzene fiS> 5.192 70 26654 30.00 ppb 0.00

42) 1-chloro-3-flubrobenze. 7.818 95 55181 30.00 ppb 0.00 56) 1,2-dichloroberzene-04. 9.520 152 61124 3o.oo ppb o.oo

System Monitoring Compounds 24) dibromofluorom thane

Spiked Amount 30.000 26) 1,2-dichloroet ane-d4


Spiked Amount 30.000 52) 4-brornofluorobenzene


Target Compounds 2) dichlorodifluo orne thane 3) chloromethane 4) vinyl chloride 5) brornomethane 6) chloroethane 7) Cc,ch,ocoCCooc~mcc>cooc 8) acrolein 9) 1,1-dichloroet ene

10) acetone 11) methylene chlo ide 12) trans-1,2-dich oroethene 13) acrylonitrile I

14) MTBE 15) 1,1-dichloroet~ane 16) DIPE 17) 2,2-dichloroprfpane 18) cis-1,2-dichlo oethene 19) 2-butanone 20) bromochlorornet~ane 21) chloroform 22) 1,1,1-trichlor,ethane 23) carbon tetrach·oride 25) 1,1-dichloroprtpene 27) benzene 28) 1,2-dichloroet ane 29) trichloroethen 30) 1,2-dichloropr pane 31) dibrornornethane 32) brornodichlororn thane 34) cis-1,3-dichlo opropene 35) 4-rnethyl-2-pen anone 37) toluene 38) iodornethane

4.245 Range 86

4.870 Range 64

6.750 Range 82

8.739 Range 85

1.001 1.119 1.168 1.358 1.436 1.527 2.114 1. 862 2.357 2.302 2.430 3.078 2.546 3.006 2.919 3.744 3.620 4.442 3.869 4.002 4.234 4.132 4.399 4.700 4.949 5.366 5.893 5.791 5.985 6.584 7.169 6.790 1.958

39) trans-1,3-dich oropropene Vinyl acetate ;

7.184 40) 3.321 41) carbon disulfi,e 1.877 43) 1,1,2-trichlor ethane 7.317 44) tetrachloroeth ne 7.120 45) 1,3-dichloropr 'pane 7.534

VMS3595.M Mon Apr 27 0 :20:29 2015

113 118 65 130 98 117 95 115

85 50 62 96 64

101 56 96 43 84 96 53 73 63 45 77 96 43

130 83 97

117 75 78 62 95 63 93 83 75 43 92

142 75 43 76 83

166 76

33859 29.78 ppb Recovery 99.27%

37337 32.25 ppb Recovery 107.50%

131129 31.04 ppb Recovery 103.47%

63540 31.68 ppb Recovery 105.60%

0.00/

0.00

o.oo/

0.00

Qvalue 9916 4 . 93 ppb 99

11162 5. 14 ppb 96 11080 4 . 8 3 ppb 100

6373 5.12 ppb 99 5495 5.29 ppb 97

12419 5.04 ppb 100 35098 143.67 ppb 98

7379 4.60 ppb 99 21536 57.55 ppb 100

8544 4 . 7 8 ppb 95 8560 4.73 ppb 98

75961 157.15 ppb 96 22110 4.93 ppb 97 14766 4.57 ppb 98 24435 4 . 4 9 ppb 99

8164 3.93 ppb 94 8265 4.55 ppb 98

19597 30.24 ppb 98 462 6 4.79 ppb 98

13899 4.68 ppb 94 10605 4.38 ppb # 76

78 67 4.13 ppb 92 11011 4.51 ppb 98 32164 4.53 ppb 96 10410 4.99 ppb 100

7878 4.42 ppb 99 8454 4.51 ppb 97 4523 4.90 ppb 98 8591 4.29 ppb 96

10067 3.89 ppb 99 35333 28.07 ppb 99 18721 4.60 ppb 96 10034 3.83 ppb 99

8 619 4.26 ppb 99 40299 13.83 ppb 98 20682 4.60 ppb 98

6025 4.54 ppb 94 7 663 4.00 ppb 94

12011 4.42 ppb 100

Page: 1

98/224

Revised Report

98/224

Data File Acq On Sample Mise Integrator:

1

Qrl antitation Report (Not Reviewed)

D:\Hpche \1\Data\VMS3597\0424432.D 25 Apr 2?15 2:00 am

Vial:

Quant Time:


;;;4

2~ or~::~29 2015

D:\Hp~hem\Methods\8260-W\VMS3595.M VMS35t5_8260/6200/624 Water ICAL Fri A r 24 11:45:19 2015

Response via Initi 1 Calibration DataAcq Meth:MSD4 AC .M

Operator: Inst Multiplr:

32 JHL MSD4 1. 00

Compound R.T .. Qion Response Cone Units Dev(Min)

46) 2-hexanone 7. 841 43 23481 23.52 ppb 98 47) dibromochloromethane 7.456 129 5650 3.81 ppb 99 48) 1,2-dibromoethtne 7.621 107 6355 4.42 ppb 100 49) chlorobenzene 8. 009 112 19457 4.14 ppb 99 50) 1,1,1,2-tetrachloroethane 8.058 131 5842 3.84 ppb 99 51) bromoform I 8.440 173 3050 3.98 ppb 99 53) bromobenzene 8.788 156 7504 4.20 ppb 94 54) 1,1,2,2-tetracrloroethane 8.860 83 8225 5.15 ppb 100 55) 1,2,3-trichlor[propane 8.924 110 2303 4.98 ppb 93 57) ethylbenzene 8.041 106 9560 3.64 ppb 97 58) m/p-xylene 8.139 106 23332 7.43 ppb 98 59) styrene 8.435 104 17636 3.64 ppb 100 60) o-xylene 8. 400 106 10897 3. 58 ppb 90 61) isopropylbenze e 8.585 105 28006 3.68 ppb 99 62) n-propyl benzere 8.814 91 32305 3.75 ppb 99 63) 2-chlorotoluenf 8. 892 126 6489 3. 78 ppb 98 64) 4-chlorotoluenr 8.979 126 6534 3.74 ppb 99 65) 1,3,5-trimethy~benzene 8.921 105 20944 3.70 ppb 99 66) tert-butylbenztne 9.083 119 17625 3.68 ppb 97 67) 1,2,4-trimethy,benzene 9.118 105 21365 3.79 ppb 98 68) sec-butylbenze e 9.173 105 25660 3.75 ppb 99 69) 1,3-dichloroberzene 9.277 146 12722 3.82 ppb 98 70) 4-isopropyltol\'ene 9.245 119 20011 3. 66 ppb 98 71) 1,4-dichloroberzene 9.321 146 12807 3.86 ppb 99 72) 1,2-dichlorobefzene 9.523 146 12643 4.01 ppb 99 73) n-butylbenzene 9.448 91 16339 3.62 ppb 98 74) 1,2-dibromo-3-fhloropr. 9.900 75 6300 27.02 ppb 90 75) 1,2,4-trichlorf.benzene 10.207 180 6013 3.68 ppb 99 76) hexachlorobutariene 10.189 225 2408 3.64 ppb 97 77) naphthalene 10.357 128 15069 4.28 ppb 99 78) trans-1,4-Dich oro-2-b... 8.950 53 10345 21.24 ppb # 79

-=~~-~~~~==~~~=~~~~t~=~==~=-----~~~~~~--~~~-----==~~-----=~~=-~~~------~00 (#) = qualifier out of range (m) = manual integration (+) = signals summed

VMS3595.M Mon Apr 27 0 :20:29 2015 Page: 2

99/224

Revised Report

99/224



D:\Hpchem\1\Data\VMS3597\0424432.D 25 Apr 2015 2:00 am 0724 3 A-MSD

RTE Apr 27 07:20:29 2015



~ridarlce TIC: 0424432.0\clata.ms 1

55ooool

500000

450oooi

4000ool j I

350000!

3000ooi

I 2500001

! 200000·

100000

I

500001

VMS3595.M Mon Apr 27 07:20:30 2015

32 JHL MSD4 1. 00

Page: 3

l I

I

i

SW-846 8260B VXX5662


100/224

Revised Report

100/224

Batch Summary

SW-846 8260B SW-846 5030BAnalytical Method: Prep Method:

VXX5662

04/27/2015 07:22

Prep Batch:

Prep Date:

Client Sample ID Analysis Date Instrument AnalystLab Sample ID Analytical Batch

LCS for HBN 74748 [VXX/5662] 04/27/2015 08:45 MSD4 BWS166017 VMS3598

LCSD for HBN 74748 [VXX/5662] 04/27/2015 09:11 MSD4 BWS166018 VMS3598

MB for HBN 74748 [VXX/5662] 04/27/2015 10:31 MSD4 BWS166019 VMS3598

GMA4-9-042015 04/27/2015 16:36 MSD4 BWS31500724004 VMS3598

Cooler 6 Trip Blank 04/27/2015 12:12 MSD4 BWS31500724008 VMS3598

2A-042115 MS 04/27/2015 19:46 MSD4 BWS31500725006 VMS3598

2A-042115 MSD 04/27/2015 20:13 MSD4 BWS31500725007 VMS3598


101/224

Revised Report

101/224

Surrogate Summary Form 2


Matrix: Water

Work Order: 31500724



12-DCE-D4 4-BFB Dibromofluor

omethane

TOL-D8

2A-042115 MS 106 101 107

2A-042115 MSD 107 100 107

Cooler 6 Trip Blank 101 102 99

GMA4-9-042015 103 99 105

LCS for HBN 74748 [VXX/5662] 98 103 99 105

LCSD for HBN 74748 [VXX/5662] 97 103 99 104

MB for HBN 74748 [VXX/5662] 99 102 97 103

Control Limits

1,2-Dichloroethane-d4 12-DCE-D4 64.0-140

4-Bromofluorobenzene 4-BFB 62.0-132

Dibromofluoromethane Dibromofluoromethan 58.0-133

Toluene d8 TOL-D8 65.0-127


102/224

Revised Report

102/224



Instrument: MSD4

Filename: 0427402.D

Analyst: BWS

SW-846 8260B




Fluorobenzene 5.19 5.69 4.69 41530 83060 20765



IS1 IS2 IS3

CUSTOMER SAMPLE

5.19 34299 7.82 71241 9.52 73737LCS for HBN 74748 [VXX/5662]

5.19 35344 7.82 72989 9.52 75127LCSD for HBN 74748 [VXX/5662]

5.19 32996 7.82 68616 9.52 69703MB for HBN 74748 [VXX/5662]

5.19 30926 7.82 62100 9.52 65097Cooler 6 Trip Blank

5.19 33231 7.82 71086 9.52 73707GMA4-9-042015

5.19 32003 7.82 68996 9.52 752642A-042115 MS

5.19 33649 7.82 72330 9.52 778292A-042115 MSD


103/224

Revised Report

103/224



Instrument: MSD4

Filename: 0427405.D

Analyst: BWS

SW-846 8260B




Fluorobenzene 5.19 5.69 4.69 32326 64652 16163



IS1 IS2 IS3

CUSTOMER SAMPLE

5.19 34299 7.82 71241 9.52 73737LCS for HBN 74748 [VXX/5662]

5.19 35344 7.82 72989 9.52 75127LCSD for HBN 74748 [VXX/5662]

5.19 32996 7.82 68616 9.52 69703MB for HBN 74748 [VXX/5662]

5.19 30926 7.82 62100 9.52 65097Cooler 6 Trip Blank

5.19 33231 7.82 71086 9.52 73707GMA4-9-042015

5.19 32003 7.82 68996 9.52 752642A-042115 MS

5.19 33649 7.82 72330 9.52 778292A-042115 MSD


104/224

Revised Report

104/224

105/224

Revised Report

105/224

Tune File Tune Time

GC/MS QA-QC Check Report

D:\Hpchem\1\Data\VMS3598\0427401.D 27 Apr 2015 7:51am

Daily Calibration File : D:\Hpchem\1\Data\4042315\0423409.D

40657 74598 75739

File Sample Surrogate Recovery % Internal Standard Responses ========================================================================= 042740l.D

TUNE

0427402.D QCK010

0427403.D 166017 LCS

0427404.D 166018 LCS

97 92 103 102 72401

100 95 105 103 41530

99 98 105 103 34299

99 97 104 103 35344

No Quant Results for D:\Hpchem\1\Data\VMS3598\0427405.D

0427406.D R

0427407.D 166019 MB

0427408.D 0724 8 A

0427409.D 0725 10 A

0427410 .D 0724 11 A

97 97 103 102 33428

97 99 103 102 32996

102 102 99 101 30926

99 109 103 104 21609

98 107 103 104 25165

152991* 155633*

87278 89400

71241 73737

72989 75127

68930 69718

68616 6.9703

62100 65097

44755 49223

52227 56649

---------------------------------------------------------~-----------·----0427411.D

0726 3 A 98 101 103 103 35380 74198 78137

0427412. D 0734 1 A 97 102 103 102 34736 72686 76722

0427413.D 0734 5 A 99 102 105 103 33357 71083 74098

0427414.D 0734 7 A 98 101 104 104 33084 69371 73873

0427415.D 0734 8 A 98 103 104 103 33245 70206 73695

0427416. D 0749 1 A 99 101 105 102 32562 69051 72827

0427417.D 0749 2 A 99 101 103 104 33398 70403 74605

0427418.D 0724 4 x5 99 100 105 103 33231 71086 73707

0427419.D 0726 1 x50 98 100 104 103 34966 74851 78556

106/224

Revised Report

106/224

0427420.D 0734 6 x50 98 100 104 104 33615 71620 75579

0427421.D .0725 1 x20 98 101 104 104 33q07 7_:2_111_ _____ 1_6}~5

0427422.D 0725 2 x20 98 102 104 104 31970 67693 72130

0427423.D 0749 3 x20 99 103 104 105 31529 66810 71832

0427424.D 0725 5 x40 98 102 103 103 31317 66228 70424

0427425.D 0725 6 x40 101 102 107 106 32003 68996 75264

0427426.D (fails) 0725 7 x40 100 101 107 107 33649 72330 77829


Created: Tue Apr 28 09:34:06 2015



Prep Batch: VXX5662

Matrix: Water

Analysis Date/Time: 04/27/2015 10:31


Method Blank Summary Form 4

Client Sample ID Lab Sample ID Filename Date Analyzed Analyst

LCS for HBN 74748 [VXX/5662] 166017 04/27/2015 08:450427403.D BWS

LCSD for HBN 74748 [VXX/5662] 166018 04/27/2015 09:110427404.D BWS

Cooler 6 Trip Blank 31500724008 04/27/2015 12:120427408.D BWS

GMA4-9-042015 31500724004 04/27/2015 16:360427418.D BWS

2A-042115 MS 31500725006 04/27/2015 19:460427425.D BWS

2A-042115 MSD 31500725007 04/27/2015 20:130427426.D BWS


107/224

Revised Report

107/224



Matrix: Water


Method Blank


QC for Samples:

31500724004, 31500724008

Dichlorodifluoromethane ND 5.000.0660 ug/L 1U

Chloromethane ND 1.000.0610 ug/L 1U

Vinyl chloride ND 1.000.0700 ug/L 1U

Bromomethane ND 1.000.106 ug/L 1U

Chloroethane ND 1.000.147 ug/L 1U

Trichlorofluoromethane ND 1.000.0690 ug/L 1U

Acrolein ND 25.04.26 ug/L 1U

1,1-Dichloroethene ND 1.000.0960 ug/L 1U

Acetone ND 25.00.813 ug/L 1U

Acetonitrile ND 20.011.5 ug/L 1U

Allyl chloride ND 1.000.216 ug/L 1U

Methylene chloride ND 5.000.0750 ug/L 1U

trans-1,2-Dichloroethene ND 1.000.0990 ug/L 1U

Acrylonitrile ND 25.02.06 ug/L 1U


Chloroprene ND 1.000.162 ug/L 1U

2-Butanone ND 25.00.523 ug/L 1U

Propionitrile ND 20.02.22 ug/L 1U

Methylacrylonitrile ND 10.01.42 ug/L 1U

Chloroform ND 1.000.0640 ug/L 1U


Carbon tetrachloride ND 1.000.0520 ug/L 1U

Isobutyl alcohol ND 50.06.07 ug/L 1U

Benzene ND 1.000.132 ug/L 1U


Trichloroethene ND 1.000.0870 ug/L 1U

1,2-Dichloropropane ND 1.000.285 ug/L 1U

Dibromomethane ND 1.000.251 ug/L 1U

Bromodichloromethane ND 1.000.206 ug/L 1U

Methyl methacrylate ND 1.000.0985 ug/L 1U

1,4 Dioxane ND 10014.4 ug/L 1U

2-Chloroethylvinyl ether ND 25.01.87 ug/L 1U

cis-1,3-Dichloropropene ND 1.000.104 ug/L 1U

4-Methyl-2-pentanone ND 5.000.469 ug/L 1U

Toluene ND 1.000.0660 ug/L 1U

Methyl iodide ND 1.000.0570 ug/L 1U

trans-1,3-Dichloropropene ND 1.000.0832 ug/L 1U

Ethyl methacrylate ND 1.000.127 ug/L 1U

Vinyl acetate ND 2.000.303 ug/L 1U

Carbon disulfide ND 1.000.0860 ug/L 1U



108/224

Revised Report

108/224



Matrix: Water


Method Blank


QC for Samples:

31500724004, 31500724008

Tetrachloroethene ND 1.000.0750 ug/L 1U

2-Hexanone ND 5.000.586 ug/L 1U

Dibromochloromethane ND 1.000.0880 ug/L 1U

1,2-Dibromoethane ND 1.000.0920 ug/L 1U

Chlorobenzene ND 1.000.0954 ug/L 1U


Bromoform ND 1.000.170 ug/L 1U


1,2,3-Trichloropropane ND 1.000.130 ug/L 1U

Ethyl Benzene ND 1.000.0656 ug/L 1U

Styrene ND 1.000.0750 ug/L 1U

Xylene (total) ND 2.000.200 ug/L 1U

1,2-Dibromo-3-chloropropane ND 5.001.40 ug/L 1U

trans-1,4-Dichloro-2-butene ND 5.001.03 ug/L 1U

Surrogates

1,2-Dichloroethane-d4 99.0 64.0-140 % 1

Dibromofluoromethane 97.0 58.0-133 % 1

Toluene d8 103 65.0-127 % 1

4-Bromofluorobenzene 102 62.0-132 % 1

Batch Information

Prep Batch: VXX5662


Prep Date/Time: 4/27/2015 7:22:24AM





Instrument: MSD4

Analyst: BWS


109/224

Revised Report

109/224

110/224

Revised Report

110/224



D:\Hpchem\1\Data\VMS3598\0427407.D 27 Apr 2015 10:31 am 166019 MB

RTE Apr 27 13:03:19 2015



7 BWS MSD4 1.00





Spiked Amount 30.000 Range 86 - 118 Recovery 96.97%

/

2 6) 1,2-dichloroethane-d4 4.870 65 42420 29.60 ppb 0.0/' Spiked Amount 30.000 Range 64 - 130 Recovery 98.67% 36) toluene-dB 6.747 98 161498 30.88 ppb 0.0

Spiked Amount 30.000 Range 82 - 117 Recovery 102.93% 52) 4-bromofluorobenzene 8.736 95 76267 30.58 ppb 0.00 Spiked Amount 30.000 Range 85 - 115 Recovery 101.93%

Target Compounds Qvalue 41) carbon disulfide 1.879 76 899 o....-'!:1ippb # 73 --------------------------------------------------------~~-~-------------


VMS3595.M Mon Apr 27 13:03:19 2015 Page: 1

111/224

Revised Report

111/224




RTE Apr 27 13:03:19 2015



~bundance

I 600000 TIC: 0427407.0\data.ms

550000

!

500000

450000 I

400000

I 00

350000! .;

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300000

"' ,-00 . v

250000 ~ • N c • ~ e 0

200000 , u:

00 ~ ~ ~ •

150000 jj 0 • E ~ e e 0 , ..

' '!i !_ 100000 ~ E e u .g '§ u .,

50000 c 0

" ~ 0

1.00 I ' I ' frime--> 1.50 2.00 2.50 3.00 3.50 4.00 4.50 5.00 5.50 6.00 6.50 7.00 7.50

VMS3595.M Mon Apr 27 13:03:20 2015

"'

7 BWS MSD4 1. 00

,-00 v • c

~ • ~ e 0 , " ~ i1 q

I

I

' 8.00 8.50

':} c

~ • ~ e 0 ;g E e· ;,

9.00

"' ,-00 v ~ 0 • c • N c • ~

I ' 9.50 10.00 10.50 11.00 11.50 12.00

Page: 2

112/224

Revised Report

112/224




RTE Apr 27 13:03:56 2015



7 BWS MSD4 1. 00




5.189 7.818 9.520

70 95

152

65

32996 68616 69703

42420

30.00 ppb 0.00 30.00 ppb 0.00 30.00 ppb 0.00

29.22 ppb 0.00 I System Monitoring Compounds

8) 1,2-dichloroethane-d4 Spiked Amount 30.000


4.870 Range 64

6.747 Range 82 -

8.736 Range 85

- 140 98 117 95 115

Recovery 161498

Recovery

97.40% / 31.10 ppb 0.00 103.67%

14) 4-bromofluorobenzene 7 6267 30.44 ppb 0.00 Spiked Amount 30.000 Recovery 101.47%



VMS3596.M Mon Apr 27 13:03:56 2015 Page: 1

113/224

Revised Report

113/224



D:\Hpchem\l\Data\VMS3598\0427407.D 27 Apr 2015 10:31 am 166019 MB

RTE Apr 27 13:03:56 2015


f'\bundance TIC: 0427407.0\data.ms 600000

580000

560000

540000

520000 '!!

500000 A. 00 v

480000 • c • N c

460000 Jl e 0 ,

440000 " ~ 420000 ~ 400000

380000

360000 00

340000 00 '); c •

320000 ~

300000

280000

260000 "' A. 00

240000 v • c • N

220000 c • ~ e 0

200000 , u:

180000

160000

"' 140000 ~

'l c • 120000 ~ e 100000 ~

~ 80000

60000

40000

20000

0 ime--> 1.00 2.00 3.00 . 4.00 5.00 6.00 7.00 8.00

VMS3596.M Mon Apr 27 13:03:57 2015

00 oi c • N c Jl e 0 , ;; E e :/


'!! A• 00 v ~ D • c 2

9.00 10.00

7 BWS MSD4 1. 00

11.00 12.00

Page: 2



Date Analyzed: 04/27/2015 08:45



Date Analyzed: 04/27/2015 09:11


Blank Spike Summary

Matrix: Water


Blank Spike (ug/L)

RPD CL


31500724004, 31500724008QC for Samples:

Dichlorodifluoromethane 5.00 5.62 4.4112 5.00 5.87 117 33.0-170 30.00

Chloromethane 5.00 5.86 3.8117 5.00 6.09 122 57.0-132 30.00

Vinyl chloride 5.00 5.61 4.0112 5.00 5.84 117 59.0-138 30.00

Bromomethane 5.00 6.22 2.5124 5.00 6.38 128 51.0-134 30.00

Chloroethane 5.00 6.68 4.8134 5.00 7.01 140 64.0-145 30.00

Trichlorofluoromethane 5.00 5.91 5.8118 5.00 6.26 125 64.0-133 30.00

Acrolein 125 135 3.6108 125 140 112 56.0-131 30.00

1,1-Dichloroethene 5.00 5.57 3.4111 5.00 5.76 115 71.0-128 30.00

Acetone 25.0 27.9 4.4111 25.0 26.7 107 52.0-140 30.00

Methylene chloride 5.00 5.43 4.5109 5.00 5.68 114* 70.0-113 30.00

trans-1,2-Dichloroethene 5.00 5.54 2.1111 5.00 5.66 113 57.0-138 30.00

Acrylonitrile 125 136 2.2109 125 139 111 55.0-141 30.00

1,1-Dichloroethane 5.00 5.45 3.4109 5.00 5.64 113 72.0-134 30.00

2-Butanone 25.0 24.7 0.8199 25.0 24.5 98 58.0-134 30.00

Chloroform 5.00 5.40 3.5108 5.00 5.59 112 74.0-124 30.00


Carbon tetrachloride 5.00 5.34 3.5107 5.00 5.53 111 75.0-120 30.00

Benzene 5.00 5.28 3.5106 5.00 5.47 109 78.0-122 30.00

1,2-Dichloroethane 5.00 5.37 1.5107 5.00 5.45 109 76.0-119 30.00

Trichloroethene 5.00 5.24 1.7105 5.00 5.33 107 78.0-125 30.00

1,2-Dichloropropane 5.00 5.30 2.1106 5.00 5.41 108 74.0-124 30.00

Dibromomethane 5.00 5.28 1.1106 5.00 5.34 107 71.0-128 30.00

Bromodichloromethane 5.00 5.30 2.4106 5.00 5.43 109 72.0-120 30.00

2-Chloroethylvinyl ether 125 124 1.699 125 126 101 65.0-128 30.00

cis-1,3-Dichloropropene 5.00 5.37 2.2107 5.00 5.49 110 73.0-122 30.00

4-Methyl-2-pentanone 25.0 24.9 0.8199 25.0 24.7 99 65.0-124 30.00

Toluene 5.00 5.37 2.4107 5.00 5.50 110 82.0-122 30.00

Methyl iodide 5.00 4.31 8.086 5.00 4.67 93 55.0-123 30.00

trans-1,3-Dichloropropene 5.00 5.28 0.0106 5.00 5.28 106 70.0-125 30.00

Vinyl acetate 12.5 15.8 0.0126 12.5 15.8 126 40.0-141 30.00

Carbon disulfide 5.00 5.67 2.4113 5.00 5.81 116 65.0-132 30.00



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Revised Report

114/224



Date Analyzed: 04/27/2015 08:45



Date Analyzed: 04/27/2015 09:11


Blank Spike Summary

Matrix: Water


Blank Spike (ug/L)

RPD CL


31500724004, 31500724008QC for Samples:

Tetrachloroethene 5.00 4.72 3.994 5.00 4.91 98 59.0-112 30.00

2-Hexanone 25.0 21.6 0.4686 25.0 21.5 86 56.0-133 30.00

Dibromochloromethane 5.00 4.64 0.093 5.00 4.64 93 67.0-122 30.00

1,2-Dibromoethane 5.00 4.49 1.890 5.00 4.57 91 74.0-119 30.00

Chlorobenzene 5.00 4.70 2.794 5.00 4.83 97 77.0-133 30.00


Bromoform 5.00 4.57 1.591 5.00 4.50 90 62.0-127 30.00


1,2,3-Trichloropropane 5.00 4.67 2.493 5.00 4.56 91 67.0-126 30.00

Ethyl Benzene 5.00 4.61 4.792 5.00 4.83 97 76.0-123 30.00

Styrene 5.00 4.67 2.793 5.00 4.80 96 76.0-121 30.00

1,2-Dibromo-3-chloropropane 30.0 25.5 0.3985 30.0 25.6 85 62.0-130 30.00

trans-1,4-Dichloro-2-butene 25.0 22.8 0.091 25.0 22.8 91 61.0-132 30.00

Surrogates

1,2-Dichloroethane-d4 98 97 64.0-140

Dibromofluoromethane 99 99 58.0-133

Toluene d8 105 104 65.0-127

4-Bromofluorobenzene 103 103 62.0-132

Batch Information



Instrument: MSD4

Analyst: BWS

Prep Batch: VXX5662


Prep Date/Time: 04/27/2015 07:22

Spike Init Wt./Vol.: 40 mL Extract Vol: 40 mL

Dupe Init Wt./Vol.: 40 mL Extract Vol: 40 mL


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D:\Hpchem\l\Data\VMS3598\0427403.D 27 Apr 2015 8:45 am 166017 LCS

RTE Apr 27 09:05:56 2015



3 BWS MSD4 1.00



42) 1-chloro-3-fluorobenze. 7.818 95 71241 30.00 ppb 0.00 56) 1,2-dichlorobenzene-04. 9.520 152 73737 30.00 ppb 0.00


~ Spiked Amount 30.000 Range 86 118 Recovery 99.37% 26) 1,2-dichloroethane-d4 4.873 65 43793 29.40 ppb 0.00/


Spiked Amount 30.000 Range 82 - 117 Recovery 104.73% 52) 4-bromofluorobenzene 8.736 95 80092 30.93 ppb 0.00

Spiked Amount 30.000 Range 85 115 Recovery 103.10%

Target Compounds Qvalue 2) dichlorodifluoromethane 1.004 85 14543 5. 62 ppb 98 3) chloromethane 1.117 50 16370 5.86 ppb 99 4) vinyl chloride 1.168 62 16544 5. 61 ppb 99 5) bromomethane 1.361 96 9968 6.22 ppb 95 6) chloroethane 1.441 64 8940 6.68 ppb 95 7) trichlorofluoromethane 1.530 101 18770 5.91 ppb 99 8) acrolein 2.117 56 42369 134.78 ppb 100 9) 1,1-dichloroethene 1. 8 62 96 114 99 5.57 ppb 94

10) acetone 2.357 43 13339 27.85 ppb 97 11) methylene chloride 2.305 84 12468 5.43 ppb 93 12) trans-1,2-dichloroethene 2.430 96 12900 5.54 ppb 94 13) acrylonitrile 3.078 53 84760 136.27 ppb 96 14) MTBE 2.543 73 29537 5.12 ppb 98 15) 1,1-dichloroethane 3.012 63 22633 5.45 ppb 99 16) DIPE 2.919 45 38284 5.46 ppb 98 17) 2,2-dichloropropane 3.747 77 15547 5.82 ppb 96 18) cis-1,2-dichloroethene 3.623 96 12545 5.36 ppb 97 19) 2-butanone 4.442 43 20565 24.66 ppb 97 20) bromochloromethane 3.869 130 6755 5.43 ppb 93 21) chloroform 4.002 83 20614 5.40 ppb 98 22) 1,1,1-trichloroethane 4.236 97 16745 5.37 ppb 98 23) carbon tetrachloride 4.135 117 13084 5.34 ppb 97 25) 1,1-dichloropropene 4.398 75 16666 5.30 ppb 96 27) benzene 4.702 78 48243 5.28 ppb 98 28) 1,2-dichloroethane 4.949 62 14430 5.37 ppb 97 29) trichloroethene 5.366 95 12019 5.24 ppb 96 30) 1,2-dichloropropane 5.895 63 12765 5.30 ppb 96 31) dibromomethane 5.791 93 6267 5.28 ppb 99 32) bromodichloromethane 5.982 83 13641 5.30 ppb 99 33) 2-chloroethyl vinyl ether 6.564 106 23682 124.25 ppb 99 34) cis-1,3-dichloropropene 6.584 75 17917 5.37 ppb 97 35) 4-methyl-2-pentanone 7.166 43 40273 24.86 ppb 98 37) toluene 6.790 92 28133 5.37 ppb 98 38) iodomethane 1.964 142 14518 4.31 ppb 100 39) trans-1,3-dichloropropene 7.184 75 13743 5.28 ppb 98 40) Vinyl acetate 3.324 43 59220 15.80 ppb 99 41) carbon disulfide 1.880 76 32749 5. 67 ppb 99 4 3) 1,1,2-trichloroethane 7.314 83 7879 4.60 ppb 98 44) tetrachloroethene 7.120 166 11690 4.72 ppb 98

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RTE Apr 27 09:05:56 2015



3 BWS MSD4 1. 00


45) 4 6) 47) 48) 4 9) 50) 51) 53) 54) 55) 57) 58) 59) 60) 61) 62) 63) 64) 65) 66) 67) 68) 69) 70) 71) 72) 73) 74) 75) 7 6) 77) 78) 79)

1,3-dichloropropane 2-hexanone dibromochloromethane 1,2-dibromoethane chlorobenzene 1,1,1,2-tetrachloroethane bromoform bromobenzene 1,1,2,2-tetrachloroethane 1,2,3-trichloropropane ethylbenzene m/p-xylene styrene a-xylene isopropyl benzene n-propyl benzene 2-chlorotoluene 4-chlorotoluene 1,3,5-trimethylbenzene tert-butylbenzene 1,2,4-trimethylbenzene sec-butylbenzene 1,3-dichlorobenzene 4-isopropyltoluene 1,4-dichlorobenzene 1,2-dichlorobenzene n-butylbenzene 1,2-dibromo-3-chloropr. 1,2,4-trichlorobenzene hexachlorobutadiene naphthalene trans-1,4-Dichloro-2-b. 1,2,3-trichlorobenzene

7.531 7.838 7.453 7.618 8.006 8.058 8.437 8.788 8.860 8.924 8.041 8.139 8.432 8.400 8.585 8.814 8.892 8.979 8.921 9.083 9.118 9.173 9.277 9.245 9.320 9.523 9.448 9.900

10.206 10.189 10.357

8.950 10.441

76 43

129 107 112 131 173 156

83 110 106 106 104 106 105

91 126 126 105 119 105 105 146 119 146 146

91 75

180 225 128

53 180

16019 27768

8899 8335

28536 9236 464 6

10906 9682 2787

14 618 35075 27275 16743 42264 4 9039

9663 10036 31960 26861 32282 38786 18814 30928 18946 17745 25610

7167 9017 3791

18416 13378

8067

4.56 ppb 21.55 ppb

4.64 ppb 4.49 ppb 4.70 ppb 4.70 ppb 4.57 ppb 4.73 ppb 4.69 ppb 4.67 ppb 4.61 ppb 9.26 ppb 4.67 ppb 4.56 ppb 4.60 ppb 4.72 ppb 4.67 ppb 4.76 ppb 4.68 ppb 4.65 ppb 4.75 ppb 4.70 ppb 4.68 ppb 4.70 ppb 4.74 ppb 4.66 ppb 4.70 ppb

25.48 ppb 4.58 ppb 4.75 ppb 4.34 ppb

22.77 ppb 4.60 ppb

99 97 96 98 99 97 93 97 98 92 91 97

100 100

99 100

98 95

100 99 99 99 98 99 99 96 99 91 98 98 99 91 98

(#) = qual-ifier out of range (m) = manual integration (+) = signals summed

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550000.

I

VMS3595.M Mon Apr 27 09:05:57 2015


3 BWS MSD4 1. 00

Page: 3

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D:\Hpchem\1\Data\VMS3598\0427404.D 27 Apr 2015 9:11 am 166018 LCSD




4 BWS MSD4 1. 00




System Monitoring Compounds o.oo/ 24) dibromofluoromethane 4.248 113 44565 29.56 ppb Spiked Amount 30.000 Range 86 - 118 Recovery 98.53%

2 6) 1,2-dichloroethane-d4 4.873 65 44527 29.01 ppb 0.00 '/ Spiked Amount 30.000 Range 64 - 130 Recovery 96.70%

36) toluene-dB 6.747 98 174522 31.15 ppb 0.00 Spiked Amount 30.000 Range 82 117 Recovery 103.83%


Target Compounds Qvalue 2) dichlorodifluoromethane 1.007 85 1564 9 5.87 ppb 98 3) chloromethane 1.119 50 17541 6.09 ppb 97 4) vinyl chloride 1.168 62 17761 5.84 ppb 98 5) bromomethane 1.361 96 10534 6.38 ppb 96 6) chloroethane 1.439 64 9659 7.01 ppb 98 7) trichlorofluoromethane 1.527 101 20458 6.26 ppb 99 8) acrolein 2.117 56 45428 140.23 ppb 98 9) 1,1-dichloroethene 1.862 96 12256 5.76 ppb 99

10) acetone 2.357 43 13147 26. 65 ppb 97 11) methylene chloride 2.299 84 13448 5.68 ppb 95 12) trans-1,2-dichloroethene 2.433 96 13585 5.66 ppb 97 13) acrylonitrile 3.078 53 88809 138.56 ppb 98 14) MTBE 2.545 73 30973 5.21 ppb 97 15) 1,1-dichloroethane 3.012 63 24136 5.64 ppb 98 16) DIPE 2.919 45 40101 5.55 ppb 97 17) 2,2-dichloropropane 3.744 77 16309 5.93 ppb 96 18) cis-1,2-dichloroethene 3.622 96 13254 5.50 ppb 93 19) 2-butanone 4.442 43 21047 24.49 ppb 99 20) bromochloromethane 3.869 130 7230 5.64 ppb 93 21) chloroform 4.005 83 21983 5.59 ppb 98 22) 1,1,1-trichloroethane 4.236 97 18048 5. 62 ppb 98 23) carbon tetrachloride 4.135 117 13959 5.53 ppb 98 25) 1,1-dichloropropene 4.398 75 17862 5.51 ppb 99 27) benzene 4.702 78 51494 5.47 ppb 98 28) 1,2-dichloroethane 4.951 62 15073 5. 45 ppb 98 29) trichloroethene 5.363 95 12592 5.33 ppb 93 30) 1,2-dichloropropane 5.895 63 13451 5.41 ppb 96 31) dibromomethane 5.788 93 6536 5.34 ppb 98 32) bromodichloromethane 5.982 83 14416 5.43 ppb 99 33) 2-ch1oroethyl vinyl ether 6.567 106 24877 126.04 ppb 9.8 34) cis-1,3-dichloropropene 6.584 75 18871 5.49 ppb 98 35) 4-methyl-2-pentanone 7.166 43 41142 24.65 ppb 98 37) toluene 6.793 92 29725 5.50 ppb 99 38) iodomethane 1.963 142 16241 4. 67 ppb 95 39) trans-1,3-dichloropropene 7.184 75 14153 5.28 ppb 97 4 0) Vinyl acetate 3.321 43 61013 15.79 ppb 98 41) carbon disulfide 1.879 76 34594 5.81 ppb 99 43) 1,1,2-trichloroethane 7.317 83 8362 4.76 ppb 97 44) tetrachloroethene 7.120 166 12465 4.91 ppb 96

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RTE Apr 27 09:24:12 2015



4 BWS MSD4 1. 00


45) 4 6) 47) 48) 4 9) 50) 51) 53) 54) 55) 57) 58) 59) 60) 61) 62) 63) 64) 65) 66) 67) 68) 69) 70) 71) 72) 73) 74) 75) 76) 77) 78) 79)

1,3-dichloropropane 2-hexanone dibromochloromethane 1,2-dibromoethane chlorobenzene 1,1,1,2-tetrachloroethane bromoform bromobenzene 1,1,2,2-tetrachloroethane 1,2,3-trichloropropane ethyl benzene m/p-xylene styrene o-xylene isopropylbenzene n-propyl benzene 2-chlorotoluene 4-chlorotoluene 1,3,5-trimethylbenzene tert-butylbenzene 1,2,4-trimethylbenzene sec-butylbenzene 1,3-dichlorobenzene 4-isopropyltoluene 1,4-dichlorobenzene 1,2-dichlorobenzene n-butylbenzene 1,2-dibromo-3-chloropr. 1,2,4-trichlorobenzene hexachlorobutadiene naphthalene trans-1,4-Dichloro-2-b .. 1,2,3-trichlorobenzene

7.534 7.838 7.453 7.618 8.006 8.058 8.437 8.788 8.860 8.924 8.038 8.139 8.432 8.400 8.585 8.814 8.889 8.979 8.921 9.083 9.118 9.173 9.277 9.245 9.320 9.523 9.448 9.902

10.206 10.189 10.357

8.950 10.441

76 43

129 107 112 131 173 156

83 110 106 106 104 106 105

91 12 6 126 105 119 105 105 146 119 146 146

91 75

180 225 128

53 180

16970 28393

9115 8 694

30063 9705 4 676

11587 10070

2793 15608 37322 28568 17423 44837 51754

9992 10394 34058 28094 34318 41091 20009 32720 19818 18640 27022

7323 9330 3952

18177 13620

8196

4.72 ppb 21.50 ppb


25.56 ppb 4.65 ppb 4. 8 6 ppb 4.20 ppb

22.75 ppb 4.58 ppb

99 99 93 99

100 96 99 99 95 92 94 99 98 94 99 98 97 99

100 98 97 98 99 99 98 97

100 96 97 95 99 91 99


VMS3595.M Mon Apr 27 09:24:12 2015 Page: 2

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Revised Report

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RTE Apr 27 09:24:12 2015


350000

VMS3595.M Mon Apr 27 09:24:13 2015

~ . • 5 • "' c

" "' 5 • e ~ ;::


"' o5 u • c ~ li

4 BWS MSD4 1.00

~.

!

Page: 3

Prep, Standard, Run Logs

SW-846 8260B


122/224

Revised Report

122/224

123/224

Revised Report

123/224

I

leAl: v,~ 35"1\(q

X:~tf vx VM S: 35''tf

Instrument:

Vial Sample ID

#

1 _7We. 2

I~AL-!

3 2. 4 3 5 i 6 5 7 ,v (tJ

8 ~AP~~ 9

"'vtJ~ 10 Ce.APX:~ 11 Ae1Co1o 12 /&5tt33- U1 13

lfJ~'I3l/ - LtSb 14 f( 15 lGPJ3S' • 111~ 16 loi& - 2 A-17 ~ql - 5' A 18 - ~ A 19 'v - 3 It-20 tl3 - z ~ 21 12~ - l .4 22 - s A 23 - ~ A-24 ~+ A 25 II ' -9 A-

EIXT

l\11{

It~( ll\'

I

Sequen ce Pullsheet SGS Environm ental Laboratories. Inc

MSD4

Dilution Comment Vial Sample ID EXT Dilution Comment

#

'fVI'# f-. 26 12&-Z. A- K'/tt>~f1

APllC-w I~ 27 1ZS- 3 4 28 ~ ~ A-29 ~ 8 A 30 ' -~ 4 1/ 31 12~ . 2 (),- tyl)

/ 32 ~ ~ 3 Ll- M5h ,fl>. "'':}r'el!f/fl

I oN1-'f ;fl. ;.~" 33 ~. {JIWJ 34

~~ 35

etv Vlf!J 36

~111'6 ALL 37

38

39

40

fuol,rP~ 41

42

43

44 /

ILf onl~ 45

I

fj'I.(,;;{Af, 46

47

48

49

~ 1,.-50

V045.082007.3

124/224

Revised Report

124/224

VXX: 'flll, 1,.VMS: Jfli~

Instrument:

Vial Sample ID

#

1 L.c... 2 O.~t.;)

3 '"'{)! 7 4 ff,(qot r 5 uMxet 6 It 7 l ~t,ol1 8 07~'i'*'J A-9 o1z.;-- ~~ A 10 ! ~n A 11

D 7l<..- j /.\' 12 ,..- • ,. 13

_¥f)\-, I+

14 o/V v/_ A-

1r 073tt--t A

rr -:?.A

1:1 -1 A ~ IJ

"' -r Dr

\, :: 071/~ -I 4 -c.:: -1r - 2..- /.} "' \II

~ VI ~ 0 7 ttj -"1 A ~'l

~

~ 1777.1.,-1 Pr

~ 0 7~1/ -~ Pr

~ oTt~ '-'1 A ~ lt -1- Pr

EXT

t(.,~

{,.tJi>

.MA

Sequence Pullsheet SGS Environmental Laboratories. Inc

MSD4 Date: ' O'(Z-]t.C

Dilution Comment Vial

Sample ID EXT Dilution Comment #

./ .?, o?!.(9 -3 A- I v Zs»~ ¥-u. .. /111r / ~ o7ZS"-5 A K!{ow ~

,q..tt / NttS \ '-?;. o72)-~ A- 110 1<-'IP«>

~~~~ I 'DI-- / ;r o72S"-/ Pr ft7}j) X. '{Pt>:>

/ « ll ... ID••f

i 1;; (( 10'~' .

O: ,f.; l_ lt"t

flW. Mf., ~ 33

,~,i

(! v 34

11•" 35

"'~ . 36

181'"/S )<. ( t"•t 37 lt'f-r"'B

(j TC. 'X 38

I> 1 E ¥- +- f"'T6. - 39

<tlf.o/Af'! 40

41

42

43

44 .

45

'IS" 46

'(.. S'i? 47

)(..50 48

'J( ll>.:> 49

1-t<~O v 50

V045.082007.3

125/224

Revised Report

125/224Re~ew An•lyol· ~

~ )·~1-<) MSD4 Runlog SGS Environmental Services, Inc.

Method: ___ 8,2'e6:!:0·:!W!CIA"'P'-'X"9"'1A,B;,B"S'----

~J ).L7·(J

\]fY)S)~) /vr1J 3J'l'

Initial Cal. Curve: VMS35Q0°'MS36911 VIVIS3568'

Matrix: Water v y; )C (;{, Si Batch: VMS3597

FILENAME

0424409.0

0424410.0

0424411.0

0424412.0

0424413.0

0424414.0

0424415.0

0424416.0

0424417.0

0424418.0

0424419.0

0424420.0

0424421.0

0424422.0

0424423.0

0424424.0

0424425.0

0424426.0

0424427.0

0424428.0

0424429.0

0424430.0

0424431.0

0424432.0

0424433.0

SAMPLE ID I DILUTION DATE I TIME COMMENTS

TUNE 41241201515:02 v C.CAEX9 4124120~5.15.:29 L QCK010 41241201515:56 a/

165933 LCS 4/241201517:01 A-tt NJ / 165934 LCSD 412412015 17:28 ,L. ._./

R 41241201517:55

165935 MB 41241201518:22 / 0696 2 A 41241201518:50 L_ 0697 5 A 41241201519:16 / 0697 4 A 41241201519:43 ./ 0697 3 A 412412015 20:10 I/ 0713 2 A 412412015 20:37 ./ 0724 1 A 412412015 21:04 .../

0724 5 A 412412015 21:31 .../

0724 6 A 412412015 21:58 .../

0724 7 A 412412015 22:24 ./ 0724 9 A 412412015 22:51 / 0726 2 A 412412015 23:18 1/ 0725 3 A 412412015 23:45 I../ 0725 4 A 412512015 0:12 / 0725 8 A 412512015 0:39 LL 0725 9 A 412512015 1 :06 ./

0724 2 A·MS 4125120151:33 1/__. 0724 3 A·MSD 412512015 2:00 1/

R I · 412512015 2:27

Water Stds: CUJve=V12·233CN12·223D·I QC=V12·226CN12-2260-IV Air stds: Primary= Secondary=

pH

/ / / ./ ./

./ / ,., ,.,

,....,..

~ ../ I/ / / I/ i./

METHOD OPER

JHL

JHL

JHL

JHL

JHL

JHL

JHL

~ JHL

JHL

JHL

v JHL

1l.E. i>IJ('f JHL

.... ,_, .. JHL

JHL

JHL

JHL

JHL

JHL

JHL

JHL

JHL

,v JHL

JHL

JHL

JHL

Page Number..=:':/..:~==., V024.112202.1

126/224

Revised Report

126/224

Matrix:

FILENAME

0427401.0

0427402.0

0427403.0

0427404.0

0427405.0

0427406.0

0427407.0

0427408.0

0427409.0

0427410.0

0427411.0

0427412.0

0427413.0

0427414.0

0427415.0

0427416.0

0427417.0

0427418.0

0427419.0

0427420.0

0427421.0

0427422.0

0427423.0

0427424.0

0427425.0

0427428.0

0427427.0

0427428.0

0427429.0

Review Analyst __ _

MSD4 Runlog SGS Envfronmont.af Services. Inc.

lilitial eat 8atve. 8260-WI8260-SUAPIX-SUAPIX-W

Water 1/xr. .)1,0 2..-----SAMPLE 10 I DILUTION DATE I TIME COMMENTS

TUNE 412il2015 7:51 ,/ QCK010 4/27/2015 8:18 t/

166017 LCS 4/2712015 8:45 /HI f<~'fJ / 166018 LCSO 4/27/2015 9:11 .lr ./

CCAPX9 4/27/2015 9:38 / R 4/27/201510:05

166019MB 4/27/2015 10:31 / 0724 8 A 4/27/2015 12:12 ./

0725 10 A 4/27/201512:35 ../

0724 11 A 4/27/201512:59 / 0726 3 A 4/27/201513:26

./

0734 1 A 4/27/2015 13:54 .,

0734 5 A 4/27/2015 14:21 I_.... 0734 7 A 4/27/2015 14:48 1/ 0734 8 A 4/27/201515:15 ..../

0749 1 A 4/27/2015 15:42 1./ 0749 2 A 4/27/201516:09 I/

0724 4 xs A 4/27/201516:36 ./ 0726 1 ;.:.50 A 4/27/2015 17:04 ./ 0734 6 x50 A 4127/2015 17:31 /

0725 1 X200 A 4/27/2015 17:58 ..../ 0725 2 x200 A 4/27/201518:25 v 0749 3 x2ooo A 4/27/2015 18:52 1.....-

0725 5 x4000 A 4/27/201519:19 v 0725 6 x4000 MS-A 4/27/2015 19:46

i,./

0725 7 x4000 MSO-A . 4!2712015 20:13 / R 4/27/2015 20:40

R 4/27/2015 21:06

R 4/27/201521:33

Water stds: Curve=V12-233CN12-2230-1 0C=V12-228CN12-2260-1V Air Stds: Primary= Secondary=

Batch:

pH

/ ../ ./

/ ../ ../

1/ ./ ../

/ I./ ../

../

../

../ / I/

' I-" ./

VMS3598

METHOD

ru.o!H1

fUm(A/'1

OPER

BWS

BWS

BWS

BWS

BWS

BWS

BWS

BWS

BWS

BWS

BWS

BWS

BWS

BWS

BWS

BWS

BWS

BWS

BWS

BWS

BWS

BWS

BWS

BWS

BWS

BWS

BWS

BWS

BWS

Page Number: =l~l == V024.112202.1

Initial Calibration Data

SW-846 8260B


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Revised Report

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SGS North America, Inc.

Lab Name: SGS Environmental Services Inc. Contract:

Lab Code: NC00919 Case No.: SAS No.: SDG No.:

Instrument ID: MSD4 Calibration Date(s): 04/23/15

Heated Purge: (Y/N) N Calibration Times: 18:05-21:15

GC Column: DB-624 ID: 0.2 (mm)

LAB FILE ID: RRF10.0 = 0423404.D RRF20.0 = 0423405.D

RRF50.0 = 0423408.D RRF75.0 = 0423410.D RRF100.0 = 0423411.D

RRF RRF RRF RRF RRF ICAL %

10.0 20.0 50.0 75.0 100.0 RRF RSD

2.28 2.11 2.39 2.36 2.28 2.26 3.96

2.54 2.35 2.56 2.53 2.44 2.44 3.57

2.76 2.51 2.65 2.66 2.59 2.58 4.28

1.46 1.30 1.46 1.47 1.46 1.40 5.17

1.20 1.14 1.27 1.17 5.33

2.68 2.52 2.97 2.98 2.86 2.78 5.95

0.325 0.257 0.271 0.277 0.298 0.275 9.23

1.85 1.74 1.81 1.91 1.82 1.81 2.99

0.658 0.492 0.421 0.413 0.430 0.465 18.0

2.16 1.92 2.02 2.10 1.99 2.01 3.96

2.18 1.92 2.00 2.14 2.06 2.04 4.28

0.641 0.525 0.550 0.521 0.543 0.544 7.56

5.75 4.79 4.89 5.14 5.06 5.05 6.13

4.06 3.54 3.59 3.74 3.49 3.63 5.20

7.19 6.08 5.96 6.16 5.82 6.13 7.27

2.45 2.21 2.33 2.53 2.35 2.34 4.71

2.10 1.94 2.05 2.19 2.07 2.05 3.85

0.852 0.694 0.692 0.721 0.740 0.729 7.56

1.08 0.986 1.11 1.16 1.11 1.09 4.74

3.47 3.11 3.37 3.59 3.36 3.34 4.41

2.68 2.47 2.76 3.02 2.84 2.73 6.03

1.97 1.89 2.17 2.48 2.35 2.14 9.63

1.25 1.24 1.28 1.32 1.31 1.28 2.03

2.80 2.60 2.73 2.94 2.79 2.75 3.63

1.34 1.30 1.30 1.29 1.32 1.30 1.63

8.60 7.68 7.94 8.35 7.87 7.98 4.02

2.57 2.24 2.32 2.42 2.33 2.35 4.47

2.04 1.88 1.98 2.17 2.04 2.00 4.33

2.25 2.00 2.11 2.21 2.11 2.11 4.06

1.06 0.963 1.03 1.10 1.08 1.04 4.12

2.16 1.99 2.26 2.57 2.46 2.25 8.51

0.126 0.108 0.174 0.282 0.296 0.183 40.0

2.88 2.63 2.93 3.25 3.05 2.92 6.66

1.59 1.29 1.39 1.44 1.45 1.42 6.79

4.73 4.72 4.78 4.76 4.75 4.75 0.521

5.00 4.39 4.56 4.78 4.49 4.58 4.47

3.25 2.72 2.97 3.19 2.91 2.95 6.32

2.12 1.96 2.29 2.64 2.56 2.28 10.7

4.12 3.21 3.36 2.86 3.04 3.28 11.2

5.37 4.71 5.00 5.41 5.34 5.06 5.51

Vinyl acetate

carbon disulfide

cis-1,3-dichloropropene

4-methyl-2-pentanone

toluene-d8

toluene

iodomethane

trans-1,3-dichloropropene

1,2-dichloroethane

trichloroethene

1,2-dichloropropane

dibromomethane

bromodichloromethane

2-chloroethyl vinyl ether

1,1,1-trichloroethane

carbon tetrachloride

dibromofluoromethane

1,1-dichloropropene

1,2-dichloroethane-d4

benzene

DIPE

2,2-dichloropropane

cis-1,2-dichloroethene

2-butanone

bromochloromethane

chloroform

acetone

methylene chloride

trans-1,2-dichloroethene

acrylonitrile

MTBE

1,1-dichloroethane

vinyl chloride

bromomethane

chloroethane

trichlorofluoromethane

acrolein

1,1-dichloroethene

6A

VOLATILE ORGANICS INITIAL CALIBRATION DATA

COMPOUND

dichlorodifluoromethane

chloromethane

page 1 of 2 FORM VI VOA-1 0LM04.2

128/224

Revised Report

128/224





Heated Purge: (Y/N) N Calibration Times: 18:05-21:15



RRF50.0 = 0423408.D RRF75.0 = 0423410.D RRF100.0 = 0423411.D


10.0 20.0 50.0 75.0 100.0 RRF RSD

0.789 0.665 0.714 0.747 0.736 0.722 5.04

1.08 0.958 1.04 1.12 1.06 1.04 4.54

1.60 1.42 1.46 1.51 1.48 1.48 3.65

0.603 0.493 0.530 0.554 0.562 0.543 6.27

0.723 0.683 0.814 0.958 0.943 0.807 13.0

0.837 0.722 0.768 0.826 0.817 0.782 5.54

2.77 2.46 2.53 2.68 2.54 2.56 4.32

0.804 0.756 0.834 0.922 0.881 0.828 6.84

0.391 0.353 0.438 0.556 0.561 0.445 18.1

1.10 1.08 1.09 1.09 1.09 1.09 0.386

1.00 0.925 0.958 1.03 0.984 0.970 3.71

0.925 0.823 0.863 0.879 0.894 0.869 3.70

0.268 0.218 0.252 0.259 0.263 0.252 6.03

1.30 1.21 1.30 1.39 1.30 1.29 4.31

1.56 1.45 1.56 1.66 1.56 1.54 4.10

2.21 2.09 2.46 2.67 2.51 2.38 8.02

1.58 1.37 1.52 1.60 1.49 1.49 4.96

3.82 3.47 3.82 4.01 3.74 3.74 4.38

4.24 3.92 4.31 4.56 4.26 4.23 4.42

0.914 0.799 0.844 0.880 0.827 0.842 4.51

0.909 0.818 0.859 0.902 0.848 0.858 3.71

2.80 2.48 2.83 3.03 2.83 2.78 5.68

2.41 2.25 2.37 2.49 2.32 2.35 3.26

2.67 2.60 2.85 2.99 2.78 2.77 4.46

3.32 3.11 3.42 3.61 3.39 3.36 4.33

1.73 1.64 1.62 1.69 1.59 1.64 3.12

2.62 2.37 2.75 2.98 2.80 2.68 6.97

1.73 1.55 1.63 1.71 1.60 1.63 3.86

1.69 1.52 1.53 1.60 1.50 1.55 4.11

2.03 1.95 2.29 2.54 2.39 2.22 9.11

0.117 0.104 0.112 0.121 0.125 0.114 5.99

0.819 0.743 0.789 0.888 0.850 0.801 6.30

0.313 0.314 0.318 0.356 0.343 0.324 5.34

1.81 1.56 1.69 1.88 1.90 1.73 7.81

0.258 0.215 0.237 0.251 0.248 0.239 6.19

0.753 0.663 0.695 0.778 0.746 0.714 5.79

1,2-dibromo-3-chloropropane

1,2,4-trichlorobenzene

hexachlorobutadiene

naphthalene

trans-1,4-Dichloro-2-butene

1,2,3-trichlorobenzene

sec-butylbenzene

1,3-dichlorobenzene

4-isopropyltoluene

1,4-dichlorobenzene

1,2-dichlorobenzene

n-butylbenzene

n-propyl benzene

2-chlorotoluene

4-chlorotoluene

1,3,5-trimethylbenzene

tert-butylbenzene

1,2,4-trimethylbenzene

1,2,3-trichloropropane

ethylbenzene

m/p-xylene

styrene

o-xylene

isopropylbenzene

chlorobenzene

1,1,1,2-tetrachloroethane

bromoform

4-bromofluorobenzene

bromobenzene

1,1,2,2-tetrachloroethane

1,1,2-trichloroethane

tetrachloroethene

1,3-dichloropropane

2-hexanone

dibromochloromethane

1,2-dibromoethane

6A


COMPOUND


129/224

Revised Report

129/224

130/224

Revised Report

130/224

MSD4 Runlog SGS Environmental Services, Inc.

Method: _ __:8:::2:::.60:_·..:..W::.:V8::.::2:.:::6:::.0·..::S:::Uc...A::...P.::.IX.:...-S:::;L::....__ lnttial Cal. Curve: VMS3595NMS3581NMS3484

Matrix Water/Soil Batch· VMS3595

FILENAME SAMPLE ID I DILUTION DATE I TIME COMMENTS pH METHOD OPER

0423401.0 R 4/23/2015 15:28 - "' 8260-W JHL

0423402.D R 4/23/2015 15:55 - "' 8260-W JHL ..

0423403.0 TUNE 4/23/2015 17:38 - "' 8260-W JHL

0423404.D ICAL1 4/23/2015 18:05 "' "' 8260-W JHL

0423405.0 ICAL2 4/23/2015 18:32 "' "' 8260-W JHL

0423406.D ICAL3 4/23/2015 18:59 "' "' 8260-W JHL

0423407:D •.

ICAL4 4/23/2015 19:26 "' "' 8260-W JHL

0423408.D ICAL5 4/23/2015 19:53 "' "' 8260-W JHL

0423409.D ICAL6 4/23/2015 20:21 "' "' 8260-W JHL

0423410.0 ICAL7 4/23/2015 20:48 "' "' 8260-W JHL

0423411.D ICAL8 4/23/2015 21:15 ;, "' 8260-W JHL

0423412.D R 4/23/2015 21:42 - "' 8260-W JHL

0423413.D QCK010 4/23/2015 22:08 ICV Pass- Bromomethane above DOD Criteria "' 8260-W JHL

Review Analyst: CJ:-) Soil Stds: Curve=V12-233A/BN12-233A!B QC=V12-226AIBN12,226A/B Water Stds: Curve=V12-233CN12-233D-I QC=V12-226CN12-226D-IV

Air Stds: Primary= Secondary= Page Number:

V-:-0~2:--4:-. 1:--1-=-22-=-o=-=2~.1

131/224

Revised Report

131/224

M51>~ 8l~o-w- ~~l-vxx: ti(Pt. Sequence Pullsheet

SGS Environmental Laboratories. Inc.

VMS: 35'1\5 Instrument: MSD4 Date:

Vial Sample 10 EXT Dilution Comment

# Vial

Sample 10 EXT Dilution Comment #

1 R ./ 26

2 1{ / 27

3 TiJN"E ..,/ 28

4 IML.i ,/ 29

5 2 ....-- 30

6 3 / 31

7 4 / 32

8 5 .... 33

9 lJJ

,/" 34

10 f ..- 35

11 .v 8 ./ 36

12 'R ./ 37

13 Qei<OIO \<!..'< ~-(' ~~'

38

14 39

15 40

16 41

17 42

18 43

19 44

20 45

21 46

22 47

23 48

24 49

25 50

V045.082007.3

132/224

Revised Report

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Data Path Data File Acq On Operator Sample Mise ALS Vial

Integration

Method Title Last Update

~undance 800000

600000

400000

200000

BFB

D:\Hpchem\1\Data\4042315\ 0423403.D 23 Apr 2015 5:38 pm JHL TUNE

3 Sample Multiplier: 1

File: rteint.p

D:\Hpchem\Methods\8260-W\VMS3595.M VMS3595 8260/6200/624 Water lCAL

Fri Apr 24 10:27:39 2015


I I I I,

I[ lj

II '

I

il '

o~~':"l~:"l~"~~~~~~"~"n' ~-~:,~+h~~~~Trn,,¥A.,~,~,~~"~"~ ime·-> 6.80 7.00 7.20 7.40 7.60 7.80 8.00 8.20 8.40 8.60 8.80 9.00 9.20 9.40 9.60 9.80 10.00 10.20 10.40 10.60

1'\bundance Average of 8.733 to 8.738 min.: 0423403.0\data.ms (-) 140000 99.1

120000 174.0

100000

80000

75.1 60000

40000

50.1 20000

3~;1 0

>n1z--> Io 40

,[ I II 6~: 0 II ,Ill _II ~TC'~f,.J~~;;~~!)i,~.,~ TCCf' lilT ''"~~!!-,~"~ " 265.1

50 60 70 80 90_10Q __ 1.1Q_l2.0 130 140 150 160 170 180 190 200 210 220 230 240 250 260 270

AutoFind: Scans 2769, 2770, 2771; Background Corrected with Scan 2760

I Target I Rel. to I Lower I Upper I Mass I Mass I Lirni t% 1 Lirni t%

50 95 15 40 75 95 30 60 95 95 100 100 96 95 5 9

173 174 0.00 2 174 95 50 100 175 174 5 9 176 174 95 101 177 176 5 9

Rel. Abn%

17.8 46.8

100.0 6.7 0.7

82.5 7.4

96.7 6.8

Raw Abn

24557 64496

137717 92 69

757 113653

8412 109872

7514

Result Pass/Fail

PASS PASS PASS PASS PASS PASS PASS PASS PASS

I ' I ! ' I

/

/ It·

VMS3595.M Fri Apr 24 10:45:58 2015 Page: 1

133/224

Revised Report

133/224

Tune File Tune Time


D:\Hpchem\1\Data\4042315\0423403.0 23 Apr 2015 5:38 pm

Daily Calibration File : D:\Hpchem\1\Data\4042315\0423409.0

40657 74598 75739

File Sample Surrogate Recovery % Internal Standard Responses ========================================================================= 0423404.D

I CALl

0423405.D ICAL2

0423406.D ICAL3

0423407.D ICAL4

0423408.D ICAL5

0423409.D ICAL6

0423410 .D ICAL7

0423411.D ICAL8

98 103 99 101

97 100 99 99

98 98 100 100

100 102 101 100

100 100 100 100

101 99 100 100

103 99 100 100

102 101 100 100

35828 65704 66599

38664 70512 70204

41978 76571 77063

38579 72250 73002

37772 69982 70466

40657 74598 75739

38958 71978 73287

35085 64587 66464 -------------------------------------------------------------------------0423412 .D

R

0423413.D QCKOlO

97 100 100 101 35736

99 99 101 101 35614


Created: Fri Apr 24 12:56:06 2015 MSD4

'

65937 66867

66044 66878

134/224

Revised Report

134/224

Initial Calibration Report SGS Environmental Services

Instrument Method Matrix Cal. Date

MSD4 VMS3595.M Water

Last Modified Fri Apr 24 11:44:34 2015 Number of levels 8

Cal Files by ID 0.5 ; D:\Hpchem\1\Data\4042315\0423404.0 1 ; D:\Hpchem\1\Data\4042315\0423405.0 5 ; D:\Hpchem\1\Data\4042315\0423407.0 10 ; D:\Hpchem\1\Data\4042315\0423408.0 50 ; D:\Hpchem\1\Data\4042315\0423410.0 70 ; D:\Hpchem\1\Data\4042315\0423411.0 2 ; D:\Hpchem\1\Data\4042315\0423406.0 20 ; D:\Hpchem\1\Data\4042315\0423409.0

Calibration Level ID Concentration (ppb)

dichlorodifluoromethane chloromethane

·vinyl chlOride bromomethane chloroethane trichlorofluoromethane acrolein 1,1-dichloroethene acetone methylene chloride trans-1,2-dichloroethene acrylonitrile MTBE 1,1-dichloroethane DIPE 2,2-dichloropropane cis-1,2-dichloroethene 2-butanone bromochloromethane chloroform 1,1,1-trichloroethane carbon tetrachloride dibromofluoromethane 1,1-dichloropropene 1~2-dichloroethane-d4 benzene 1 1 2-dichloroethane trichloroethene. 1,2-dichloropropane dibromomethane bromodichloromethane 2-chloroethyl vinyl ether

0.5; 1; 5; 10; 50; 70; 2; 20; 0.5; 1.0; 5.0; 10.0; 50.0; 70.0; 2.0; 20.0; AvgRF

;2.279 ;2.114 ;2.199 ;2.387 ;2.356 ;2.286 ;2.199 ;2.297 2.265 ;2.539 ;2.349 ;2.348 ;2.557 ;2.529 ;2.444 ;2.367 ;2.432 2.445 ;2.7iis ;2.509 ;2.423 ;2.649 ;:L664 ;2.593 ;2.48i ;2.566 2.581 ;1.462 ;1.299 ;1.324 ;1.455 ;1.472 ;1.456 ;1.327 ;1.416 1.402 ;1.204 ;1.136 ;1.154 ;1.269 ; ~;<:?::>;1.173 ;1.085 1.170 ;2.683 ;2.516 ;2.690 ;2.966 ;2.977 ;2.856 ;2.651 ;2.870 2.776 ;0.325 ;0.257 ;0.260 ;0.271 ;0.277 ;0.298 ;0.248 ;0.263 0.275 ;1.849 ;1.743 ;1.781 ;1.815 ;1.908 ;1.818 ;1.751 ;1.789 1.807 ;0.658 ;0.492 ;0,.458 ;0.421 ;0.413 ;0.430 ;0.449 ;0.}98 0.465 ;2.157 ;1.920 ;1.979 ;2.016 ;2.095 ;1.989 ;1.936 ;1;'989 ·; 2.010 ;2.180 ;1.915 ;2.025 ;2.000 ;2.142 ;2.055 ;1.977 ;2.000 2.037 ;0.641 ;0.525 ;0.538 ;0.550 ;0.521 ;0.543 ;0.518 ;0.517 0.544 ;5.751 ;4.793 ;5.039 ;4.893 ;5.140 ;5.060 ;4.839 ;4.861 5.047 ;4.063 ;3.541 ;3.579 ;3.595 ;3.735 ;3.487 ;3.558 ;3.512 3.634 ;7.194 ;6.079 ;5.955 ;5.963 ;6.166 ;5.817 ;6.009 ;5:845 6.128 ;2.448 ;2.211 ;2.258 ;2.334 ;2.527 ;2.351 ;2.219 ;2~338 2.336 ;2.105 ;1.941 ;2.016 ;2.051 ;2.188 ;2.067 ;1.960 ;2:044 2.047 ;0.852 ;0.694 ;0.751 ;0.692 ;0.721 ;0.740 ;0.701 ;0.684 0.729 ;1.082 ;0.986 ;1.094 ;1.108 ;1.164 ;1.112 ;1.053 ;1.100 1.087 ;3.475 ;3.112 ;3.263 ;3.366 ;3.587 ;3.362 ;3.224 ;3.326 3.339 ;2.686 ;2.471 ;2.680 ;2.762 ;3.019 ;2.840 ;2.592 ;2.776 2.728 ;1.971 ;1.892 ;2.089 ;2.174 ;2.482 ;2.353 ;1.952 ;2.221 2.142 ;1.253 ;1.243 ;1.284 ;1.284 ;1.315 ;1.310 ;1.259 ;1.288 1.280 ;2.803 ;2.601 ;2.693 ;2.734 ;2.939 ;2.795 ;2.690 ;2.749 2.750 ;1.339 ;1.298 ;1.323 ;1.298 ;1.291 ;1.316 ;1.273 ;1.285 1.303 ~8;601 ;7.678 ;7.800 ;7.943 ;8.353 ;7.873 ;7.755 ;7.~78 7.985 ;2.569 ;2.239 ;2.346 ;2.320 ;2.424 ;2.329 ;2.267 ;2.293 2.348 ;2.043 ;1.877 ;2.004. ;1.980 ;2.174 ;2:045 ;1.945 ;1.~83 2.006 ;2.252 ;2.001 ;2.085 ;2.106 ;2.214 ;2.106 ;2.030 ;2.073 2.108 ;1:062 ;0.963 ;1.048 ;1.034 ;1.099 ;1.076 ;1.001 ;1.028 1.039 ;2.164 ;1.993 ;2.184 ;2.256 ;2.569 ;2.456 ;2.076 ;2.321 2.253 ;0.126 ;0.108 ;0.144 ;0.174 ;0.282 ;0.296 ;0.123 ;0.207 0.183

%RSD 3.961 3.569 4.284 5.167 5.333 5.952 9.230 2.989

- 'to f'P6

17.975 / - 1.-(WEI}L 3.959 4.279 7.556 6.133 5.197 7. 270 4.708 3.846 7.566 4.739 4.411 6.029 9.634 2.028 3.631 1. 635 4.024 4.472 4.333 4. 058 4.125 8.509 ./

40.018 '(' -

135/224

Revised Report

135/224

cis-1,3-dichloropropene ;2.880 ;2.627 ;2.864 ;2.931 ;3 .249 ;3.052 ;2.718 ;3.008 2.916 6.662 4-methyl-2-pentanone ; 1. 594 ; 1. 288 ; 1. 4 74 ;1.389 ;1.437 ;1.450 ; 1. 316 ;1.386 1.417 6.792 toluene-dB ;4.730 ;4. 721 ;4.798 ;4. 775 ;4.760 ;4.754 ;4.743 ;4.763 4.755 0.521 toluene ;5.002 ;4.387 ;4.521 ;4.560 ;4.780 ; 4. 4 90 ;4.439 ;4.499 4.585 4.469 iodomethane ;3.246 ;2.725 ;2.846 ; 2. 966 ;3.194 i2.909 ;2.767 ;2:942 2.949 6.325 trans-1,3-dichloropropene ;2.118 ; 1. 958 ;2.241 i2.292 ;2.637 ;2.561 ;2.022 ;2'.'385 2.277 10.694 Vinyl acetate i4.115 ;3.214 ;3.214 ;3.356 ;2.864 i3.045 ;3.249 ;3.174 3.279 11. 24 7 carbon disulfide ;5.371 ;4.707 ;4.865 ;5.000 ;5.407 ;5.338 ;4.781 ;4.983 5.056 5.513 1,1,2-trichloroethane ;0.789 ;0.665 ;0.711 ;0.714 ;0.747 ;0.736 ;0.703 ;0.709 0.722 5.044 tetrachloroethene ;1.077 ;0.958 ; 1. 021 ; 1. 044 ; 1.118 ; 1. 064 ;1.014 i1.046 1. 043 4.539 1,3-dichloropropane ; 1. 597 ; 1. 424 ; 1. 453 ;1.457 ;1.509 ; 1. 4 77 ;1.458 ;1.449 1.478 3.653 2-hexanone ;0.603 ;0.493 ;0.557 ;0.530 ;0.554 ;0.562 ;0.510 ;0.533 0.543 6.267 dibromochloromethane ;0.723 ;0.683 ;0.764 ;0.814 ;0.958 ;0.943 ; 0. 711 ;0,858 0.807 13.025 1,2-dibromoethane ;0.837 ;0.722 ;0.772 ;0.768 ;0.826 ;0.817 ;0.728 ;0.783 0.782 5.538 chlorobenzene ;2.772 ;2.466 ;2.459 ;2.529 ;2.679 ;2.535 ;2.492 ;2.524 2.557 4.323 1,1,1,2-tetrachloroethane ;0.804 ;0.756 ;0.796 ;0.834 ;0.922 ;0.881 ; 0. 772 ;0.856 0.828 6.836/ bromoform ;0.391 ;0.353 ;0.408 ;0.438 ;0.556 ;0.561 i0.371 ;0.481 0.445 18.095 - QvltDR-WrtC.. 4-bromofluorobenzene ;1.097 ; 1. 084 ;1.089 ; 1. 093 ; 1. 089 ; 1. 088 ; 1. 089 ; 1. 096 1. 090 0.386 bromobenzene ; 1. 004 ;0.925 ;0.935 ;0.958 ; 1. 034 ;0.984 ;0.955 ;0.968 0.970 3.711 1 1 1,2,2-tetrachloroethane ;0.925 ;0.823 ;0.864 ;0.863 ;0.879 ;0.894 ;0.834 ;0.870 0.869 3.697 1,2,3-trichloropropane ;0.268 ;0.218 ;0.253 ;0.252 ;0.259 ;0.263 ;0.248 ;0.251 0.252 6.031 ethylbenzene ;1.305 i1.212 ; 1. 251 ;1.300 ; 1. 395 ; 1. 304 ; 1. 243 ;L 305 1.289 4.308 m/p-xylene ;1.560 ; 1. 44 7 ;1.502 ; 1. 559 ;1.658 ; 1. 558 ; 1. 490 ; 1. 552 1.541 4.101 styrene ;2.211 ;2. 08.8 ;2.324 ;2.458 ;2.667 ~ 2. 512 ;2.245 ;2.494 2.375 8.016 o.:xylene.- ;1.579 ;1.370

.. i1.441 ; 1. 516 ; 1. 598 ;1.490 ; 1. 453 .; 1.493 1.493 4.957

isopropylbenzene ;3.824 ;3.475 i3.628 ;3.819 ;4.007 ;3.736 ; 3. 611 i3.804 3.738 4.381 n-propyl benzene ;4.238 ;3.921 ; 4 .134 ;4.309 ;4.556 ;4.255 ;4.090 ;4.313 4.227 4.416 2 _-: chlorotol uene ;0.914 i0.799 ;0.813 ; 0 .. 844 ;0.880 ;0.827 ;0.820 .;0 . .836 0.842 4.511 4-chlorotoluene ;0.909 ;0.818 ;0.838 ;0.859 ;0.902 i0.848 ;0.838 ;0.854 0.858 3.707 1,3,5-trimethylbenzene i2.796 ;2.480 ;2.731 ; 2. 827 ;3.033 ;2.829 ;2.686 ;2.844 2.778 5.679 tert-butylbenzene _.,;_2.408 ;2.250 ;2.281 ;2.371 ;2.489 L~. 325 ;2.305 ;2, 3?_3 2.350 3.263 172~4-trimEit:tiYlbenzene ;2.669';2.597 ;2. 739 ;2 .848 ;2.987 ;2.779 ;2.681 ; 2 .. 838 2.767 4.464 sec-butylbenzene ;3.323 ;3.108 ;3.302 ;3.425 ;3.613 ;3 .393 ;3 .276 ;3 .417 3.357 4.330 1,3-dichlorobenzene ; 1. 732 ; 1. 640 ; 1. 581 ; 1. 626 ; 1. 690 ; 1. 592 ; 1. 620 ;L 608 1. 636 3.124 4-isopropyltoluene ;2.621 ;2.370 ;2.595 ;2.754 ;2.976 ;2.802 ;2.542 ;2.782 2. 680. 6.972 1,4-dichlorobenzene i1.730 ; 1. 554 ; 1. 568 ; 1. 635 ; 1. 711 ; 1. 605 ; 1. 612 ;1. 608 1.628 3.856 1,2-dichlorobenzene ; 1. 687 ;1.518 ; 1. 498 ; 1. 528 ;1.598 ; 1. 505 ; 1. 535 ; 1. 519 1.548 4.108 n-butylbenzene i2.027 ;1.954 ;2.122 ;2.287 ;2.544 ;2.391 ;2.084 ;2.324 2.217 9.109 1,2-dibromo-3-chloropropane ;0.117 i0.104 ;0.115 ;0.112 ;0.121 i0.125 ;0.107 ; 0.115 0.114 5.987

-1 1 2,4-trichlorobehzene ;0.819 ;0.743 ;0.750 ;0.789 ;0.888 ;0.850 ;0.764 ;0.809 0.801 6.298 hexachlorobutadiene ; 0. 313 ;0.314 ;0.311 ;0.318 ;0.356 ;0.343 ;0.309 ;0.330 0.324 5.345 naphthalene · ; 1. 814 ; 1. 561 ; 1. 673 ; 1. 692 ;1.880 i 1. 900 ; 1. 544 ; 1. 753 1. 727 7.809 trans-1 1 4-Dichloro-2-butene ;0.258 ; 0. 215 ;0.241 ;0.237 ; 0. 251 i0.248 ;0.220 ;0.241 0.239 6.194 1,2,3-trichlorobenzene ;0.753 ;0.663 ;0.677 ;0.695 ;0.778 ;0.746 ;0.682 ;0.717 0.714 5.794

136/224

Revised Report

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Linear Regression Correlation Coefficient Results

Method VMS3595.M

Cal Files : D:\Hpchem\1\Data\4042315\0423409.D 0.5 : D:\Hpchem\1\Data\4042315\0423404.D 1 : D:\Hpchem\1\Data\4042315\0423405.D 5 : D:\Hpchem\l\Data\4042315\0423407.D 10 D:\Hpchem\1\Data\4042315\0423408.D 50 : D:\Hpchem\1\Data\4042315\0423410.D 70 : D:\Hpchem\1\Data\4042315\0423411.D 2 : D:\Hpchem\1\Data\4042315\0423406.D 20 : D:\Hpchem\1\Data\4042315\0423409.D

Compound Formula or RF dichlorodifluoromethane RF=2.265 chloromethane RF=2.445 vinyl chloride RF=2.581 bromomethane RF=l. 402 chloroethane RF=1.170 trichlorofluoromethane RF=2.776 acrolein RF=0.275 1,1-dichloroethene RF=l. 807 acetone y=0.42322 X- 0.00395 methylene chloride RF=2.010 trans-1,2-dichloroethene RF=2.037 acrylonitrile RF=0.544 MTBE RF=5.047 1,1-dichloroethane RF=3.634 DIPE RF=6.128 2,2-dichloropropane RF=2.336 cis-1,2-dichloroethene RF=2.047 2-butanone RF=0.729 bromochloromethane RF=l. 087 chloroform RF=3.339 1,1,1-trichloroethane RF=2.728 carbon tetrachloride RF=2.142 dibromofluoromethane RF=l. 280 1,1-dichloropropene RF=2.750 1,2-dichloroethane-d4 RF=l. 303 benzene RF=7.985 1,2-dichloroethane RF=2.348 trichloroethene RF=2.006 1,2-dichloropropane RF=2.108 dibromomethane RF=l. 039 bromodichloromethane RF=2.253 2-chloroethyl vinyl ether y=0.00157x2+ 0.21139x- 0.21198 cis-1,3-dichloropropene RF=2.916 4-methyl-2-pentanone RF=1. 417 toluene-dB RF=4.755 toluene RF=4.585 iodomethane RF=2.949 trans-1.,-3 -dichloropropene RF=2. 277 Vinyl acetate RF=3.279 carbon disulfide RF=5.056 1,1,2-trichloroethane RF=O. 722 tetrachloroethene RF=1.043 1,3-dichloropropane RF=l. 478 2-hexanone RF=0.543 dibromochloromethane RF=0.807 1,2-dibromoethane RF=0.782 chlorobenzene RF=2.557 1,1,1,2-tetrachloroethane RF=0.828

Correlation Coefficient

Method (r'2) Avg RF Avg RF Avg RF Avg RF Avg RF Avg RF Avg RF Avg RF

0.999/ Linear Avg RF Avg RF Avg RF Avg RF Avg RF Avg RF Avg RF Avg RF Avg RF Avg RF Avg RF Avg RF Avg RF Avg RF. Avg RF Avg RF Avg RF Avg RF Avg RF Avg RF Avg RF Avg RF

0.999 / Quadratic Avg RF Avg RF Avg RF Avg RF Avg RF Avg RF Avg RF Avg RF Avg RF Avg RF Avg RF Avg RF Avg RF Avg RF Avg RF Avg RF

137/224

Revised Report

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bromofOJ:in y=o. o3o27x2+: 0.499i2x- 0. ()1144 -='QUS:drctt1C 0."999 / 4-bromofluorobenzene RF=l. 090 Avg RF bromobenzene RF=0.970 Avg RF 1,1,2,2-tetrachloroethane RF=0.869 Avg RF 1,2,3-trichloropropane RF=O. 252 Avg RF ethylbenzene RF=1.289 Avg RF m/p-xylene RF=1.541 Avg RF styrene RF=2.375 Avg RF o-xylene RF=l. 493 Avg RF isopropylbenzene RF=3.738 Avg RF n-propyl benzene RF=4.227 Avg RF 2-chlorotoluene RF=0.842 Avg RF 4-chlorotoluene RF=0.858 Avg RF 1,3,5-trimethy1benzene RF=2.778 Avg RF tert-butylbenzene RF=2. 350 Avg RF 1,2,4-trimethylbenzene RF=2.767 Avg RF· sec-butylbenzene RF=3.357 Avg RF 1,3-dichlorobenzene RF=1.636 Avg RF 4-isopropyltoluene RF=2.680 Avg RF 1,4-dichlorobenzene RF=1.628 Avg RF 1, 2 -di-chlorobenzene RF=l. 548 Avg RF n-butylbenzene RF=2.217 Avg RF 1,2-dibromo-'3-chloropropane RF=0.114 •Avg RF 1,2,4-trich1orobenzene RF=0.801 Avg RF hexachlorobutadiene RF=0.324 Avg RF naphthalene RF=l. 727 Avg RF' trans-1,4-Dichloro-2-butene RF=0.239 Avg RF 1,2,3-trichlorobenzene RF=0.714 Avg RF

* Correlation Coefficent is < 0.990

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Revised Report

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D:\Hpchem\1\Data\4042315\0423404.0 23 Apr 2015 6:05pm ICAL1



4 JHL MSD4 1. 00

Quant Method D:\Hpchem\Methods\8260-W\VMS3595.M Quant Title VMS3595 8260/6200/624 Water ICAL QLast Update Fri Apr 24 11:45:19 2015 Response via Initial Calibration DataAcq Meth:MSD4 ACQ.M





Spiked Amount 30.000 26) 1,2-dichloroethane-d4


Spiked Amount 30.000 52) 4-bromofluorobenzene


Target Compounds 2) dichlorodifluoromethane 3) chloromethane 4) vinyl chloride 5) bromomethane 6) chloroethane 7) trichlorofluoromethane 8) acrolein 9) 1,1-dichloroethene

10) acetone 11) methylene chloride 12) trans-1,2-dichloroethene 13) acrylonitrile 14) MTBE 15) 1,1-dichloroethane 16) DIPE 17) 2,2-dichloropropane 18) cis-1,2-dichloroethene 19) 2-butanone 20) bromochloromethane 21) chloroform 22) 1,1,1-trichloroethane 23) carbon tetrachloride 25) 1,1-dichloropropene 27) benzene 28) 1,2-dichloroethane 29) trichloroethene 30) 1,2-dichloropropane 31) dibromomethane 32) bromodichloromethane

5.189 7.818 9.520

4.245 Range 86

4.873 Range 64

6.747 Range 82

8.736 Range 85

33) 2-chloroethyl vinyl ether

1.004 1.117 1.168 1.358 1.436 1.527 2.117 1.859 2.360 2.299 2.430 3.081 2.548 3.009 2. 925 3.750 3.623 4.442 3.869 3.996 4.239 4.135 4.393 4. 697 4.952 5.363 5.893 5.785 5.988 6.567 6.584 7.169 6.790 1.961 7.184 3.321 1.877 7.314 7.120

34) cis-1,3-dichloropropene 35) 4-methyl-2-pentanone 37) toluene 38) iodomethane 39) trans-1,3-dichloropropene 40) Vinyl acetate 41) carbon disulfide 43) 1,1,2-trichloroethane 44) tetrachloroethene

VMS3595.M Fri Apr 24 11:55:03 2015

70 95

152

113 118 65 130 98 117 95 115

85 50 62 96 64

101 56 96 43 84 96 53 73 63 45 77 96 43

130 83 97

117 75 78 62 95 63 93 83

106 75 43 92

142 75 43 76 83

166

35828 65704 66599

44903 Recovery

30.00 ppb 30.00 ppb 30.00 ppb

29.39 ppb

0.00 0.00 0.00

0.00

47958 30.82 97.97%

ppb 102.73% ppb

0.00 Recovery

169451 29.84 0.00 Recovery

72048 30.17 99.47%

ppb 100.57%

0.00 Recovery

1361 1516 1651

873 719

1602 4859 1104 1966 1288 1302 9571 3434 2426 4296 14 62 1257 2545

646 2075 1604 1177 1674 5136 1534 1220 1345

634 1292 1876 1720 4760 2987 1938 1265 6143 3207

864 1179

0.50 ppb 0.52 ppb 0.54 ppb 0.52 ppb 0.51 ppb 0.48 ppb

14.80 ppb 0.51 ppb 4.17 ppb 0.54 ppb 0.54 ppb

14.73 ppb 0.57 ppb 0.56 ppb 0.59 ppb 0.52 ppb 0.51 ppb 2.92 ppb 0.50 ppb 0.52 ppb 0.49 ppb 0.46 ppb 0.51 ppb 0.54 ppb 0.55 ppb 0.51 ppb 0.53 ppb 0.51 ppb 0.48 ppb

37.17 ppb 0.49 ppb 2.81 ppb 0.55 ppb 0.55 ppb 0.47 ppb 1.57 ppb 0.53 ppb 0.55 ppb 0.52 ppb

Qvalue 89 93

# 88 # 35 # 81

86 100

# 92 89 88 90 94 95

# 84 98 93 90 95 84 85 97 95 96 99

# 73 100

# 95 88

# 89 97

# 88 91 94 93 92 99

# 91 94 92

Page: 1

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Revised Report

139/224


Data File Aeq On Sample Mise

D:\Hpchem\1\Data\4042315\0423404.0 23 Apr 2015 6:05pm I CALl




4 JHL MSD4 1. 00

Compound R.T. Qion Response ~one Units Dev(Min)

45) 46) 47) 48) 49) 50) 51) 53) 54) 55) 57) 58) 59) 60) 61) 62) 63) 64) 65) 66) 67) 68) 69) 70) 71) 72) 73) 74) 75) 7 6) 77) 78) 79)

1,3-diehloropropane 2-hexanone dibromoehloromethane 1,2-dibromoethane ehlorobenzene 1,1,1,2-tetraehloroethane bromoform bromobenzene 1,1,2,2-tetraehloroethane 1,2,3-triehloropropane ethylbenzene m/p-xylene styrene o-xylene isopropylbenzene n-propyl benzene 2-ehlorotoluene 4-ehlorotoluene 1,3,5-trimethylbenzene tert-butylbenzene 1,2,4-trimethylbenzene see-butylbenzene 1,3-dichlorobenzene 4-isopropyltoluene 1,4-diehlorobenzene 1,2-diehlorobenzene n-butylbenzene 1,2-dibromo-3-chloropr. 1,2,4-triehlorobenzene hexaehlorobutadiene naphthalene trans-1,4-Diehloro-2-b. 1,2,3-triehlorobenzene

7.531 7.841 7.453 7.618 8.006 8.058 8.437 8.791 8.857 8.924 8.041 8.139 8.435 8.400 8.585 8.814 8.892 8.979 8.921 9.083 9.118 9.173 9.277 9.245 9.321 9.523 9.448 9.900

10.207 10.189 10.357

8.950 10.441

76 43

129 107 112 131 173 156

83 110 106 106 104' 106 105

91 12 6 12 6 105 119 105 105 146 119 146 146

91 75

180 225 128

53 180

174 9 3301

792 917

3035 880 428

1099 1013

294 1449 34 64 2454 1753 4245 4704 1015 1009 3103 2673 2963 3688 1923 2909 1920 1872 2250

780 909 347

2014 1433

836

0.54 ppb 2.78 ppb 0.45 ppb 0.54 ppb 0.54 ppb 0. 4 9 ppb 1.08 ppb 0.52 ppb 0.53 ppb 0.53 ppb 0.51 ppb 1.01 ppb 0.47 ppb 0.53 ppb 0.51 ppb 0.50 ppb 0.54 ppb 0.53 ppb 0.50 ppb 0.51 ppb 0.48 ppb 0. 4 9 ppb 0.53 ppb 0.49 ppb 0.53 ppb 0.54 ppb 0. 4 6 ppb 3.07 ppb 0.51 ppb 0.48 ppb 0.53 ppb 2.70 ppb 0.53 ppb

#

#

#

#

97 98 90 95 96 94 97 89 95 87 81 96 93 94

100 96 87 85 97 96 95 97 95 95 98 75 96 96 85 98 97 79

100


VMS3595.M Fri Apr 24 11:55:03 2015 Page: 2

140/224

Revised Report

140/224






5500001

5000001

VMS3595.M Fri Apr 24 11:55:04 2015


!!! A.

"' v ~ • N c • ~ e 0 , ::\

" " ~

4 JHL MSD4 1. 00

!!!. A

"' v

"' ~ • N c • ~ e 0 , 'E E e ~

Page: 3

141/224

Revised Report

141/224



D:\Hpchem\1\Data\4042315\0423405.0 23 Apr 2015 6:32 pm ICAL2


Vial: 5 Operator: JHL Inst MSD4 Multiplr: 1. 00







Spiked Amount 30.000 36) toluene-dB Spiked Amount 30.000



10) acetone 11) methylene chloride 12) trans-1,2-dichloroethene 13) acrylonitrile 14) MTBE 15) 1,1-dichloroethane 16) DIPE 17) 2,2-dichloropropane 18) cis-1,2-dichloroethene 19) 2-butanone 20) bromochloromethane 21) chloroform 22) 1,1,1-trichloroethane 23) carbon tetrachloride 25) 1,1-dichloropropene 27) benzene 28) 1,2-dichloroethane 29) trichloroethene 30) 1,2-dichloropropane 31) .dibromomethane 32) bromodichloromethane

5.189 7.818 9.520

70 95

152

113 118 65

4.248 Range 86

4.870 Range 64

6.747 Range 82 -

8.738 Range 85

- 130 98 117 95 115

1.007 1.119 1.168 1.358 1.439 1.524 2.117 1.862 2.357 2.302 2.427 3.081 2.548 3.012 2.919 3.744 3.614 4.448 3.866 4.005 4.233 4.135 4.393 4.700 4.951 5.368 5.895 5.788 5. 979

85 50 62 96 64

101 56 96 43 84 96 53 73 63 45 77 96 43

130 83 97

117 75 78 62 95 63 93 83

33) 2-chloroethyl vinyl ether 6. 567 6.581 7.172 6.793 1.963 7.184 3.321 1.877 7.317 7.123

106 75 43 92


VMS3595.M Fri Apr 24 11:55:06 2015

142 75 43 76 83

166

38664 70512 70204

48069 Recovery

30.00 ppb 30.00 ppb 30.00 ppb

29.15

0.00 0.00 0.00

0.00

50204 29.90

ppb 97.17%

ppb 99.67%

ppb 99.27%

ppb 99.40%

0.00 /

0.00 Recovery

182539 29.78 Recovery


2725 3028 3233 1674 14 64 3242 8296 2247 3168 2475 24 68

16901 6177 4564 7834 2850 2502 4473 1271 4011 3184 2438 3352 9895 2885 2419 2579 1241 2569 3472 3386 8298 5654 3512 2523

10357 6066 1563 2252



24.10 ppb 0.95 ppb 0.97 ppb 0.99 ppb 0.95 ppb 0.95 ppb 4. 76 ppb 0.91 ppb 0.93 ppb 0.91 ppb 0.88 ppb 0.95 ppb 0.96 ppb 0.95 ppb 0.94 ppb 0.95 ppb 0.93 ppb 0.88 ppb


0.00

Qvalue 99 98 92 93 89 98 99

# 90 97 95 87 92 95 98 97

# 90 92 99

# so 99 91 98

# 91 98 97 95

# 94 97 86 90 97 98 95 97 98 99

# 98 97 98

Page: 1

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Revised Report

142/224


Data File Acq On Sample Mise Integ-rator: Quant Time:

D:\Hpchem\1\Data\4042315\0423405.D 23 Apr 2015 6:32 pm ICAL2

RTE Apr 24 11:55:06 2015



5 JHL MSD4 1.00


45) 4 6) 47) 48) 4 9) 50) 51) 53) 54) 55) 57) 58) 59) 60) 61) 62) 63) 64) 65) 66) 67) 68) 69) 7 0) 71) 72) 73) 74) 75) 7 6) 77) 78) 79)

1,3-dichloropropane 2-hexanone dibromochloromethane 1,2-dibromoethane chlorobenzene 1,1,1,2-tetrachloroethane bromoform bromobenzene 1,1,2,2-tetrachloroethane 1,2,3-trichloropropane ethylbenzene m/p-xylene styrene o-xylene isopropylbenzene n-propyl benzene 2-chlorotoluene 4-chlorotoluene 1,3,5-trirnethylbenzene tert-butylbenzene 1,2,4-trimethylbenzene sec-butylbenzene 1,3-dichlorobenzene 4-isopropyltoluene 1,4-dichlorobenzene 1,2-dichlorobenzene n-butylbenzene 1,2-dibrorno-3-chloropr. 1,2,4-trichlorobenzene hexachlorobutadiene naphthalene trans-1,4-Dichloro-2-b. 1,2,3-trichlorobenzene

7.531 7.841 7.453 7.618 8.009 8.061 8.437 8.788 8. 860. ,8. 924 8.041 8.139 8.434 8.400 8.585 8.814 8.892 8.982 8.921 9.083 9.118 9.173 9.277 9.245 9.320 9.523 9.448 9.902

10.206 10.192 10.357

8.950 10.441

76 43

129 107 112 131 173 156'

83 110 106 106 104 106 105

91 12 6 126 105 119 105 105 146 119 146 146

91 75

180 225 128

53 180

3347 5796 1605 1696 5796 1776

829 2174 1935

512 2836 6771 4887 3207 8133 917 6 1870 1915 5803 5265 6077 7273 3837 5545 3636 3553 4572 14 60 1738

735 3652 2516 1552

0.96 ppb 4.54 ppb 0.85 ppb 0.92 ppb 0.96 ppb 0.91 ppb 1.39 ppb 0.95 ppb 0.95 ppb 0.87 ppb 0.94 ppb 1.88 ppb 0.88 ppb 0.92 ppb 0.93 ppb 0.93 ppb 0.95 ppb 0.95 ppb 0.89 ppb 0.96 ppb 0.94 ppb 0.93 ppb 1.00 ppb 0.88 ppb 0.95 ppb 0.98 ppb 0.88 ppb 5.45 ppb 0.93 ppb 0.97 ppb 0.90 ppb 4.50 ppb 0.93 ppb

#

#

#

#

96 98 95 96 99

100 96 97 99 87 93 98 95 93 99 97 94 89 98 98 97 99 97 99 99

.. 87 . 99 97 99 92 99 76 97

(#) = qualifier out of range (m) = manual iDtegration (+) = signals summed

VMS3595.M Fri Apr 24 11:55:06 2015 Page: 2

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Revised Report

143/224




RTE Apr 24 11:55:06 2015


VMS3595.M Fri Apr 24 11:55:07 2015


5 JHL MSD4 1.00

Page: 3

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Revised Report

144/224




RTE Apr 24 11:55:09 2015


6 JHL MSD4 1.00

Quant Method D:\Hpchem\Methods\8260-W\VMS3595.M Quant Title VMS3595_8260/6200/624 Water ICAL QLast Update Fri Apr 24 11:45:19 2015 Response via Initial Calibration DataAcq Meth:MSD4 ACQ.M







5.189 7.818 9.520

70 95

152

113 118 65 130 98


4.245 Range 86 -

4.870 Range 64 -

6.747 Range 82

8.739 Range 85

- 117 52) 4-bromofluorobenzene



10) acetone 11) methylene chloride 12) trans-1,2-dichloroethene 13) acrylonitrile 14) MTBE 15) 1,1-dichloroethane 16) DIPE 17) 2,2-dichloropropane 18) cis-1,2-dichloroethene 19) 2-butanone 20) bromochloromethane 21) chloroform 22) 1,1,1-trichloroethane 23) carbon tetrachloride 25) 1,1-dichloropropene 27) benzene 28) 1,2-dichloroethane 29) trichloroethene 30) 1,2-dichloropropane 31) dibromomethane 32) bromodichloromethane 33) 2-chloroethyl vinyl ether 34) cis-1,3-dichloropropene 35) 4-methyl-2-pentanone 37) toluene 38) iodomethane 39) trans-1,3-dichloropropene 40) Vinyl acetate 41) carbon disulfide 43) 1,1,2-trichloroethane 44) tetrachloroethene

VMS3595.M Fri Apr 24 11:55:09 2015

1.004 1.119 1.165 1.358 1.431 1.527 2.114 1.865 2.357 2.299 2.433 3.081 2.546 3.006 2.922 3.750 3. 620 4.445 3.866 4. 002 4.233 4.141 4.399 4.703 4.949 5.366 5.892 5.788 5.982 6.570 6.584 7.169 6.793 1.961 7.184 3.324 1.877 7.317 7.120

95 115

85 50 62 96 64

101 56 96 43 84 96 53 73 63 45 77 96 43

130 83 97

117 75 78 62 95 63 93 83

106 75 43 92

142 75 43 76 83

166

41978 76571 77063

52841

30.00 ppb 30.00 ppb 30.00 ppb

29.51

0.00 0.00 0.00

Recovery ppb

98.37% ppb

97.73% ppb

99.73% ppb

99.83%

0.00

o.oo/ 0.00


199100 29.92 Recovery


6153 6623 6944 3715 3283 7418

17337 4899 6288" 5417 5534

36239 13543

9957 16817

6209 5485 9803 2946 9022 7255 5464 7528

21702 6345 5442 5681 2802 5811 8627 7607

18415 12423

7744 5660

22731 13380

3587 5177


45.06 ppb 1.94 ppb

10.90 ppb 1.93 ppb 1.94 ppb


'58. 40 ppb 1.86 ppb 9.29 ppb 1.94 ppb 1.88 ppb 1.78 ppb 4.95 ppb 1.89 ppb 1.95 ppb 1.95 ppb

0.00

Qvalue 97 96 99 93 91 97 98 93 94 95 98 95 99 98 91 97 97 97 97 93 97 95 98 98 97 96

# 97 96 99

100 99 98 97 94 95 99

# 95 95 97

Page: 1

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Revised Report

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RTE Apr 24 11:55:09 2015

Quant Method D:\Hpchem\M~thods\8260-W\VMS3595.M Quant Title VMS3595 8260/6200/624 Water ICAL QLast Update Fri Apr-24 11:45:19 2015 Response via Initial Calibration DataAcq Meth:MSD4_ACQ.M


6 JHL MSD4 1.00


4 5) 4 6) 4 7) 48) 49) 50) 51) 53) 54) 55) 57) 58) 59) 60) 61) 62) 63) 64) 65) 66) 67) 68) 69) 70) 71) 72) 73) 74) 75) 76) 77) 78) 79)

1,3-dichloropropane 2-hexanone dibromochloromethane 1,2-dibromoethane chlorobenzene 1,1,1,2-tetrachloroethane bromoform bromobenzene

'1,1,2,2-tetrachloroethane 1,2,3-trichloropropane ethyl benzene m/p-xylene styrene a-xylene isopropylbenzene n-propyl benzene 2-chlorotoluene 4-chlorotoluene 1,3,5-trimethylbenzene tert-butylbenzene 1,2,4-trimethylbenzene sec-butylbenzene 1,3-dichlorobenzene 4-isopropyltoluene 1,4-dichlorobenzene 1,2-dichlorobenzene n-butylbenzene 1,2-dibromo-3-chloropr. 1,2,4-trichlorobenzene hexachlorobutadiene naphthalene trans-1,4-Dichloro-2-b. 1,2,3-trichlorobenzene

7.534 7.841 7.456 7.618 8.009 8.058 8.440 .8. 788 8.860 8. 924 8.038 8.139 8.435 8.400 8.588 8.814 8. 8 92 8. 979 8.921 9.083 9.118 9.173 9.277 9.245 9.321 9.526 9.448 9.902

10.206 10.192 10.357

8.950 10.441

76 43

129 107 112 131 173 156

83 110 106 106 104 106 105

91 126 126 105 119 105 105 146 119 146 146

91: 75

180 225 128

53 180

7443 13017

3632 3716

12722 3941 1893 4874 4259 1266 6384

15311 11533

74 66 18552 21011

4215 4305

13799 11843 13772 16828

8325 13059

8280 7885

10705 3302 3925 1590 7930 5663 3506

1.97 9.40 1. 76 1.86 1.95 1.87 2.16 1.97 1.92 1.97 1.93 3.87 1. 89 1.95 1.93 1. 94 1.95 1.95 1. 93 1.96 1.94 1.95 1.98 1.90 1.98 1.98 1.88

11.23 1. 91 1.91 1.79 9.22 1.91

ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb

#

#

97 100

98 95 99 98 95 97 93 96 98

100 99 98 98 98 98 94 98 97

100 98

100 100

98 96 98 97 93 96

100 86 90

(#) = qualifier out of range (m) = manual integration (+) = signals sumnle-d

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Data File Acq On Sample Mise Integrator; Quant Time:


RTE Apr 24 11:55:09 2015


250000

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Vial: Operator; Inst Multiplr:

6 JHL MSD4 1. 00

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7 JHL MSD4 1. DO

Quant Method D:\Hpchem\Methods\8260-W\VMS3595.M Quant Title VMS3595 8260/6200/624 Water ICAL QLast Update Fri Apr-24 11:45:19 2015 Response via Initial Calibration DataAcq Meth:MSD4 ACQ.M







Spiked Amount 30.000 52) 4-bromofluorobenzene Spiked Amount 30.000



5.192 7.821 9.520

4.245 Range 86

4.873 Range 64

6.746 Range 82

8.738 Range 85


1.004 1.119 1.168 1.358 1.436 1.524 2.117 1.862 2. 360 2.302 2.432 3.078 2.548 3.009 2. 922 3.747 3.622 4.442 3.869 4.005 4.236 4.138 4.398 4.699 4.951 5.368 5.895 5.788 5.985 6. 567 6.584 7.169 6.790 1.960 7.184 3.321 1.877 7.317 7.120


VMS3595.M Fri Apr 24 11:55:12 2015

-

-

-

-

70 95

152

113 118 65 130 98 117 95 115

85 50 62 96 64

101 56 96 43 84 96 53 73 63 45 77 96 43

130 83 97

117 75 78 62 95 63 93 83

106 75 43 92

142 75 43 76 83

166

38579 30.00 ppb 0.00 72250 30.00 ppb 0.00 73002 30.00 ppb 0.00

49553 30.12 ppb 0.00 Recovery 100.40%

51031 30.46 ppb 0.00 RecoverY 101.53%

185112 30.27 ppb 0.00 Recovery 100.90%

78666 29.95 ppb 0.00 Recovery 99.83%

14138 15095 15582

8515 7418

17298 41727 11452 14712 12724 13021 86424 32400 23014 38289 14517 12960 24131

7037 20979 17230 13435 17315 50153 15085 12883 13406

6740 14045 23085 18418 47388 29068 18301 14411 51667 31278

8560 12293


118.01 ppb 4.93 ppb

27.31 ppb 4.92 ppb 4.97 ppb


25.73 ppb 5.03 ppb 4.89 ppb 4.91 ppb 4.88 ppb 4.90 ppb 4.88 ppb 5.00 ppb 4.99 ppb 4.94 ppb 5.05 ppb 4.85 ppb

111.90 ppb 4.91 ppb

26.01 ppb 4.93 ppb 4.83 ppb 4.92 ppb

12.25 ppb 4.81 ppb 4.93 ppb 4.90 ppb

Qvalue 100

98 98 97 98 99 97 98 99 93

100 99 99 99 96 98 97 98 94 99 99 98 97 97

100 99

# 100 97 98 97 99 98

100 100

99 100

99 98 98

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RTE Apr 24 11:55:12 2015



7 JHL MSD4 1. 00


45) 4 6) 47) 4 8) 4 9) 50) 51) 53) 54) 55) 57) 58) 59) 60) 61) 62) 63) 64) 65) 66) 67) 68) 69) 70) 71) 72) 73) 74) 7 5) 76) 77) 78) 79)

1,3-dichloropropane 2-hexanone dibrornochloromethane 1,2-dibromoethane chlorobenzene 1,1,1,2-tetrachloroethane bromoform bromobenzene 1,1,2,2-tetrachloroethane 1,2,3-trichloropropane ethylbenzene rn/p-xylene styrene o-xylene isopropylbenzene n-propyl benzene 2-chlorotoluene 4-chlorotoluene 1,3,5-trimethylbenzene tert-butylbenzene 1,2,4-trimethylbenzene sec-butylbenzene 1,3-dichlorobenzene 4-isopropyltoluene 1,4-dichlorobenzene 1,2-dichlorobenzene n-butylbenzene 1,2-dibromo-3-chloropr. 1,2,4-trichlorobenzene hexachlorobutadiene naphthalene trans-1,4-Dichloro-2-b. 1,2,3-trichlorobenzene

7.534 7.841 7.456 7.618 8.009 8.061 8.440 8.788 8.860 8.924 8.041 8.139 8.434 8. 4 00 8.585 8.814 8.892 8.982 8. 921 9.083 9.121 9.173 9.277 9.245 9.320 9.526 9.451 9.902

10.206 10.189 10.357

8.950 10.441

76 43

129 107 112 131 173 156

83 110 106 106 104 106 105

91 126 126 105 119 105 105' 146 119 146 146

91 75

180 225 128

53 180

17494 33564

9203 9291

29607 9588 4910

11264 10407

3051 15226 36542 28278 17538 44147 50300

9895 10195 33226 27754 33331 40178 19241 31568 19082 18229 25821

8403 9125 3784

20351 14 672

8233

4.91 ppb 25.68 ppb


30.18 ppb 4.68 ppb 4.79 ppb 4.84 ppb

25.22 ppb 4.74 ppb

98 100

99 100

98 98 96

100 95 97 97 99 97 98 97 99 95 92 98 99 98 99 99 98 98 98 98 97 98 96 99 90 98


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D:\Hpchem\1\Data\4042315\0423407.D 23 Apr 2015 7:26pm ICAL4

RTE Apr 24 11:55:12 2015



I bundance TIC: 0423407.Didata.ms

w

~ oi ~

5 c • • :§ >; c ., >;

'ji e 0

~

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Page: 3

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Data File Acg On Sample Mise Integrator: Quant Time:


RTE Apr 24 11:55:15 2015

Vial: 8 Operator: Inst Multiplr:

JHL MSD4 1.00



Internal Standards 1) Fluorobenzene <IS> 5.189

42) 1-chloro-3-fluorobenze ... 7.818 56) 1,2-dichlorobenzene-04 ..






Target Compounds 2} dichlorodifluoromethane 3} chloromethane 4) vinyl chloride 5) bromomethane 6) chloroethane 7) trichlorof1uoromethane 8) acrolein 9) 1,1-dichloroethene

10) acetone 11) methylene chloride 12) trans-1,2-dichloroethene 13) acrylonitrile 14) MTBE 15) 1,1-dichloroethane 16) DIPE 17) 2,2-dichloropropane 18) cis-1,2-dichloroethene 19) 2-butanone 20) bromochloromethane 21) chloroform 22) 1,1,1-trichloroethane 23) carbon tetrachloride 25) 1,1-dichloropropene 27) benzene 28) 1,2-dichloroethane 29} trichloroethene 30) 1,2-dichloropropane 31) dibromomethane 32) bromodichloromethane

9.520

4.245 Range 86

4.870 Range 64

6.747 Range 82

8.739 Range 85

33) 2-ch1oroethyl vinyl ether

1.004 1.117 1.165 1.355 1.436 1.524 2.117 1.859 2.354 2.302 2.430 3.081 2.546 3.006 2.919 3.747 3. 620 4.442 3. 8 69 4.005 4.234 4.135 4.399 4.700 4.949 5.366 5.893 5.788 5.982 6. 567 6.584 7. 169 6.790 1.961 7.184 3.321 1.877 7.317 7.120

34) cis-1,3-dichloropropene 35) 4-methyl-2-pentanone 37) toluene 38) iodomethane 39} trans-1,3-dichloropropene 40) Vinyl acetate 41) carbon disulfide 43) 1,1,2-trichloroethane 44) tetrachloroethene

VMS3595.M Fri Apr 24 11:55:15 2015

70 95

152

113 118 65 130 98 117 95 115

85 50 62 96 64

101 56 96 43 84 96 53 73 63 45 77 96 43

130 83 97

117 75 78 62 95 63 93 83

106 75 43 92

142. 75 43 76 83

166

37772 30.00 ppb 0.00 69982 30.00 ppb 0.00 70466 30.00 ppb 0.00

48487 30.10 ppb 0.00 Recovery 100.33%

49023 29.88 ppb 0.00 Recovery 99.60%

180365 30.12 ppb 0.00 Recovery 100.40%

764 64 30.06 ppb 0.00 Recovery 100.20%

30050 32193 33347 18322 15973 37338 85395 22848 26482 25382 25186

173015 61600 45260 75078 29390 25829 43554 13955 42384 34774 27378 34419

100008 29214 24924 26522 13025 28410 54886 36899 87443 57408 37342 28855

105640 62956 16659 24358


246.67 ppb 10.04 ppb 49.98 ppb 10.03 ppb

9.82 ppb 252.58 ppb

9.69 ppb 9.89 ppb 9.73 ppb 9.99 ppb

10.02 ppb 47.43 ppb 10.19 ppb 10.08 ppb

·10.12 ppb 10.15 ppb


10.02 ppb 223.88 ppb 10.05 ppb 49.02 ppb

9.94 ppb 10.06 ppb 10.07 ppb 25.59 ppb

9.89 ppb 9.90 ppb

10.01 ppb

Qvalue 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100

Page: 1

./

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Vial: 8 Operator: JHL Inst MSD4 Mu1tip1r: 1.00


45) 4 6) 47) 48) 49) 50) 51) 53) 54) 55) 57) 58) 59) 60) 61) 62) 63) 64) 65) 66) 67) 68) 69) 70) 71) 72) 73) 74) 75) 76) 77) 78) 7 9)

1,3-dichloropropane 2-hexanone dibromochloromethane 1,2-dibrornoethane chlorobenzene 1,1,1,2-tetrachloroethane bromoform brornobenzene 1,1,2,2-tetrachloroethane 1,2,3-trichloropropane ethylbenzene rn/p-xylene styrene a-xylene isopropylbenzene n-propyl benzene 2-chlorotoluene 4-chlorotoluene 1,3,5-trirnethylbenzene tert-butylbenzene 1,2,4-trimethylbenzene sec-butylbenzene 1,3-dichlorobenzene 4-isopropyltoluene 1,4-dichlorobenzene 1,2-dichlorobenzene n-butylbenzene 1,2-dibrorno-3-chloropr ... 1,2,4-trichlorobenzene hexachlorobutadiene naphthalene trans-1,4-Dichloro-2-b ... 1,2,3-trichlorobenzene

7.534 7.841 7. 456 7.618 8.009 8.058 8.440 8.788 8.860 8.924 8.041

,8 .139 8. 432 8.400 8.585 8.814 8.892 8.979 8.921 9.083 9.118 9.173 9.277 9.245 9.321 9.523 9.448 9.900

10.207 10.189 10.357

8.950 10.441

76 43

129 107 112 131 173 156

83 110 106 106 104 106 105

91 12 6 126 105 119< 105 105 146 119 146 146

91 75

180 225 128'

53 180

33987 61772 18985 17916 58999 194 60 10224 22356 20121

5887 30526 73238 57733 35606 89694

101205 19834 20166 66412 55692 66901 80455 38193 64 685 38395 35895 53725 15725 18530

7474 39732 27806 16319

9.86 48.79 10.09

9.83 9.89

10.08 9.29 9.88 9.93

10.03 10.08 20.24 10.35 10.16 10.22 10.19 10.03

'10.00 10.18 10.09 10.29 10.20

9.94 10.28 10.04

9.87 10.32

.58.51 9.84 9.81 9.79

49.52 9.73

ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb

100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100

(#) ~ qualifier out of range (m) ~ manual integration (+) ~ signals summed

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RTE Apr 24 11:55:15 2015


VMS3595.M Fri Apr 24 11:55:16 2015


8 JHL MSD4 1. 00

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RTE Apr 24 11:55:18 2015

Vial: 9 Operator: Inst Multiplr:

JHL MSD4 1.00




42) 1-chloro-3-fluorobenze .. . 56) 1,2-dichlorobenzene-04 .. .

5.189 70 7.818 95 9.520 152








4.245 Range 86

4.873 Range 64

6.747 Range 82

8.738 Range 85 -


1.004 1.117 1.165 1.358 1.433 1.524 2.117 1. 8 62 2.357 2.299 2.430 3.081 2.545 3.006 2.919 3.747 3.617 4.442 3.869 4.005 4.233 4.135 4.398 4.700 4.949 5.368 5.895 5.791 5.985 6.570 6.584 7. 169 6.793 1.961 7.184 3.324 1.877 7.317 7.120


VMS3595.M Fri Apr 24 11:55:18 2015

113 118 65 130 98 117 95 115

85 50 62 96 64

101 56 96 43 84 96 53 73 63 45 77 96 43

130 83 97

117 75 78 62 95 63 93 83

106 75 43 92

142 75 43 76 83

166

40657 74598 75739

52363

30.00 ppb 30.00 ppb 30.00 ppb

30.20

0.00 0.00 0.00

Recovery ppb 100.67% ppb

0.00/

0.00 52262 29.60 Recovery

193655 30.05 RecoverY


98.67% ppb 100.17% ppb 100.47%

0.00

0.00

622 68 65908 69558 38389 29422 77788

178454 48488 53957 53900 54212

350310 131743

95189 158425

63366 55408 92683 29813 90157 75246 60187 74518

213518 62155 53759 56200 27862 62909

140292 81519

187845 121957

79742 64639

215087 135052

35258 52014

20.29 ppb 19. 89 ppb 19.88 ppb 20.21 ppb 18.55 ppb 20.68 ppb


475.13 ppb 19.2 6 ppb 19.33 ppb 19.07 ppb 20.02 ppb 19.98 ppb 93.76 ppb 20.23 ppb 19.92 ppb 20.35 ppb 20.73 ppb 19.99 ppb 19.73 ppb 19.53 ppb 19:77 ppb 19.67 ppb 19.79 ppb 20.61 ppb


Qvalue 98 99 97 97 99

100 99

100 99 96 97 98 98 99 99 95 98 98 99 99 98 99 99 99

100 99

# 97 98 99 95 98 99

100 98 99 99 99 97

100

Page: 1

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Data File Aeq On Sample Mise Integrator: Quant Time:

D:\Hpchem\1\Data\4042315\0423409.0 23 Apr 2015 8:21 prn ICAL6

RTE Apr 24 11:55:18 2015


Vial: 9 Operator: JHL Inst MSD4 Multiplr: 1.00

Compound R.T. Qion Response Cone Units Dev(Min·)

45) 46) 47) 48) 4 9) 50) 51) 53) 54) 55) 57) 58) 59) 60) 61) 62) 63) 64) 65) 66) 67) 68) 69) 70) 71) 72) 73) 74) 75) 7 6) 77) 78) 79)

1,3-diehloropropane 2-hexanone dibromoehloromethane 1,2-dibromoethane ehlorobenzene 1,1,1,2-tetraehloroethane bromoform bromobenzene 1,1,2,2-tetraehloroethane 1,2,3-triehloropropane ethylbenzene rn/p-xylene styrene a-xylene isopropylbenzene n-propyl benzene 2-ehlorotoluene 4-ehlorotoluene 1,3,5-trirnethylbenzene tert-butylbenzene 1,2,4-trimethylbenzene see-butylbenzene 1,3-diehlorobenzene 4-isopropyltoluene 1,4-diehlorobenzene 1,2-diehlorobenzene n-butylbenzene 1,2-dibrorno-3-ehloropr ... 1,2,4-triehlorobenzene hexaehlorobutadiene naphthalene trans-1,4-Diehloro-2-b ... 1,2,3-triehlorobenzene

7.534 7.841 7.456 7. 621 8.009 8.058 8.440 8.788. 8.860 8.924 8.041 8.139 8.434 8.400 8.588 8.814 8.892 8.982 8.921 9.083 9.118 9.173 9.277 9.245 9. 323. 9.523 9.448 9.899

10.206 10.189 10.357

8.950 10.441

76 43

129 107 112 131 173 156

83 110 106 106 104 106 105

91 126 126 105 119 105 105 146 119 146 146

91 75

180 225 128

53. 180

72069 132602

42657 38962

125525 42554 23912 48123 43254 12494 65917

156743 125950

75409 192059 217771

42204 43106

143625 119813 143283 172537

81207 140454

81213 76683

117361 34734 40829 16674 88501 60946 36210

19.61 ppb 98.2 6 ppb 21.2 6 ppb 20.05 ppb 19.74 ppb 20.68 ppb 19.21 ppb 19.94 ppb

'20.02 ppb 19.97 ppb 20.25 ppb 40.29 ppb 21.01 ppb 20.01 ppb 20.35 ppb 20.41 ppb 19.8 6 ppb 19.90 ppb 20.48 ppb 20.19 ppb 20.51 ppb 20.36 ppb 19.66 ppb 20.76 ppb 19.76 ppb 19.62 ppb 20.97 ppb

120.23 ppb 20.18 ppb

'20. 36 ppb 20.30 ppb

100.99 ppb 20.09 ppb

99 98 97 99 98 99 97 99

'99 97

100 99 97 95 98 99 98 95 99 99 99 99 98

100 99 99 99 99 98 95 99 96

100


VMS3595.M Fri Apr 24 11:55:18 2015 Page: 2

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Revised Report

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Data File Acq On Sample Mise , . Integrator:


RTE Quant Time: Apr 24 11:55:18 2015


1200000

1100000

1000000

700000

600000 >-• '2 'E "' ~ '" >c ~~ ~~ • "' >- ~1-:1-_ 1-.m ~ ::;.. >c :5 Q) Q) <Ji'i% a.

>- Q) c: c: "'0~ 0 • <Ji 0

l e R~ -c:o n • oO

.2e'lilu~ie N • • 0 ~ ..c: a.e1- o· ~ • 0 ~~~g~'e-- D ee •

~ oo

~:§~~-;;~ ~ ~ 5 .v. "9 E .2 .e "'"5 ~ o~e-5)3 '9

D ~

VMS3595.M Fri Apr 24 11:55:19 2015

"' ,· "' " v ...... ~ ~<D oO • >c N • ~· 0 e" • -D • ...~·

<;j ·oE e ~.2~ 0 0 e ~'0-

" .Q ~iii~ 'ii :s 0 N_o

E-E e e D D

"


"' 00

I >- >-<Ji 1-<Ji 0 .~ • o• ~ .~

2l ~~ _2 EE!~ ..c: ooo:a .g Qfi:E

I

"'r5~ N-~E

' :::~~ rl

,Q " u "!

I

9 JHL MSD4 1. 00

>-. •

i

Page: 3

156/224

Revised Report

156/224



D:\Hpchem\1\Data\4042315\0423410.D 23 Apr 2015 8:48 pm ICAL7




10 JHL MSD4 1. 00


Internal Standards 1) Fluorobenzene <IS> 5. 189 70 38958 30.00 ppb 0.00



Spiked Amount 30.000 Range 86 - 118 Recovery 102.77% 26) 1,2-dichloroethane-d4 4.870 65 50311 29.73 ppb 0.00


Spiked Amount 30.000 Range 82 117 Recovery 100.10% 52) 4-bromofluorobenzene 8.738 95 78400 29. 97 ppb 0.00 Spiked Amount 30.000 Range 85 - 115 Recovery 99.90%

Target Compounds Qvalue 2) dichlorodifluoromethane 1.004 85 153005 52.03 ppb 99 3) chloromethane 1.119 50 164216 51.71 ppb 99 4) vinyl chloride 1.168 62 172945 51.60 ppb 100 5) bromornethane 1.358 96 95593 52.52 ppb 99 6) chloroethane 1.428 64 37496 24. 68 ppb 99 7) trichlorofluoromethane 1.516 101 193288 53. 62 ppb 100 8) acrolein 2.117 56 449401 1258.58 ppb 100 9) 1,1-dichloroethene 1.862 96 123909 52.81 ppb 99

10) acetone 2.357 43 133981 244.06 ppb 99 11) methylene chloride 2.299 84 136037 52.12 ppb 98 12) trans-1,2-dichloroethene 2.430 96 139070 52.57 ppb 99 13) acrylonitrile 3.084 53 845513 1196.78 ppb 97 14) MTBE 2.545 73 333766 50.93 ppb 99 15) 1,1-dichloroethane 3.006 63 242521 51.40 ppb 99 16) DIPE 2.922 45 400384 50.31 ppb 97 17) 2,2-dichloropropane 3.747 77 164055 54.09 ppb 98 18) cis-1,2-dichloroethene 3.620 96 142062 53.45 ppb 100 19) 2-butanone 4.439 43 234210 247.27 ppb 100 20) bromochloromethane 3.869 130 75577 53.52 ppb 98 21) chloroform 4.005 83 232902 53.71 ppb 100 22) 1,1,1-trichloroethane 4.233 97 196023 55.33 ppb 97 23) carbon tetrachloride 4.132 117 161181 57.95 ppb 100 25) 1,1-dichloropropene 4.398 75 190811 53.42 ppb 99 27) benzene 4.699 78 542389 52.31 ppb 98 28) 1,2-dichloroethane 4.948 62 157386 51. 61 ppb 100 29) trichloroethene 5.365 95 141182 54.19 ppb 100 30) 1,2-dichloropropane 5.895 63 143725 52.4 9 ppb 97 31) dibromomethane 5.791 93 71336 52.88 ppb 96 32) brornodichlorornethane 5.982 83 166808 57.02 ppb 98 33) 2-chloroethyl vinyl ether 6.576 106 457892 1287.40 ppb 85 34) cis-1,3-dichloropropene 6.587 75 210936 55.70 ppb 100 35) 4-rnethyl-2-pentanone 7.169 43 4 6 64 50 253.54 ppb 99 37) toluene 6.793 92 310392 52.13 ppb 98 38 ) iodornethane 1.961 142 207375 54.14 ppb 99 39) trans-1,3-dichloropropene 7.187 75 171189 57.90 ppb 98 4 0) Vinyl acetate 3.324 43 464950 109.19 ppb 99 41) carbon disulfide 1.877 76 351054 53.47 ppb 99 43) 1,1,2-trichloroethane 7.317 83 89596 51.75 ppb 97 44) tetrachloroethene 7.120 166 134068 53.59 ppb 98

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Data File Acq On Sample Mise lntegrator: Quant Time:


RTE Apr 24 11:55:21 2015

Quant Method D:\Hpchem\Methods\8260-W\VMS3595.M Quant Title VMS3595 8260/6200/624 water ICAL QLast Update Fri Apr-24 11:45:19 2015 Response via Initial Calibration DataAcq Meth:MSD4 ACQ.M


10 JHL MSD4 1. 00

Compound R.T. Qlon Response Cone Units Dev(Min)

45) 46) 47) 48) 4 9) 50) 51) 53) 54) 55) 57) 58) 59) 60) 61) 62) 63) 64) 65) 66) 67) 68) 69) 70) 71) 72) 73) 74) 75) 7 6) 77) 78) 79)

1,3-diehloropropane 2-hexanone dibromoehloromethane 1,2-dibromoethane ehlorobenzene 1,1,1,2-tetraehloroethane bromoform bromobenzene 1,1,2,2-tetraehloroethane 1,2,3-triehloropropane ethylbenzene m/p-xylene styrene o-xylene isopropylbenzene n-propyl benzene 2-ehlorotoluene 4-ehlorotoluene 1,3,5-trimethylbenzene tert-butylbenzene 1,2,4-trimethylbenzene see-butylbenzene 1,3-diehlorobenzene 4-isopropyltoluene 1,4-diehlorobenzene 1,2-diehlorobenzene n-butylbenzene 1,2-dibromo-3-ehloropr. 1,2,4-triehlorobenzene hexaehlorobutadiene naphthalene trans-1,4-Diehloro-2-b. 1,2,3-triehlorobenzene

7.534 7.841 7. 456 7.618 8.009 8.061 8.440 8.788 8.860 8.924 8.041 8.139 8.434 8.400 8.588 8.814 8. 892 8.982 8. 921 9.083 9.121 9.173 9.277 9.245 .9. 323 9.526 9.448 9.899

10.206 10.189 10.357

8.950 10.441

76 43

129 107 112 131 173 156'

83 110 106 106 104 106 105

91 126 126 105 119 105 105 146 119 146 146

91 75

180, 225 128

53 180

181070 332099 114939

99073 321433 110583

66680 124095 105423

31031 170372 405144 325742 195221 489455 556432 107501 110233 370428 304058 364842 441300 206444 363458 209035 195182 310676

88866 108423

43539 229610 153433

95024

51.06 ppb 255.05 ppb

59.38 ppb 52.83 ppb 52.39 ppb 55.70 ppb 51.09 ppb 53.30 ppb 50.56 ppb 51.41 ppb 54.09 ppb

107.63 ppb 56.15 ppb 53.54 ppb 53.60 ppb

·53.89 ppb 52.27 ppb 52.58 ppb 54.58 ppb 52.96 ppb 53.97 ppb 53.81 ppb 51.65 ppb 55.52 ppb 52.56 ppb 51.60 ppb

'57.37 ppb 317.91 ppb

55.38 ppb 54.94 ppb 54.43 ppb

262.75 ppb 54.49 ppb

99 98 97 99 99 99 97 99 97 95 96 98 97 99 97 99

. 98' 94 99

100 97 99 99

100 99 98 9.9 98 98 99 99 92 99


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Data File Acq On Sample Mise, Integrator: Quant Time:


RTE Apr 24 11:55:21 2015

Quant Method D:\Hpchem\Methods\8260-W\VMS3595.M Quant Title VMS3595_8260/6200/624 Water ICAL QLast Update Fri Apr 24 11:45:19 2015 Response via Initial Calibration DataAcq Meth:MSD4 ACQ.M

" >-c r-• ;-_ c ~ • 5 • ~~

;- 'ji ;-_

:!f E -" !I • •

.. i-:g e

0

E~'6 • ~~ ~.2 £~ eQ;{5 :c£i ..cf:!:s

~

VMS3595.M Fri Apr 24 11:55:22 2015


10 JHL MSD4 1. 00

;-_ •

t ;-

Page: 3

159/224

Revised Report

159/224




Integrator; RTE Quant Time: Apr 24 11:55:24 2015

Vial: 11 Operator: JHL Inst MSD4 Multiplr: l. 00




42) 1-chloro-3-fluorobenze .. . 5.189 7.818 9.520 56) 1,2-dichlorobenzene-04 .. .

System Monitoring Compounds 24) dibromofluorornethane



4.242 Range 86 -

4.870 Range 64 -

6.747

70 95

152

113 118 65 130 98

Spiked Amount 30.000 52) 4-bromofluorobenzene Spiked Amount 30.000

Range 82 - 117 8.739 95

Range 85 - 115


10) acetone 11) methylene chloride 12) trans-1,2-dichloroethene 13) acrylonitrile 14) MTBE 15) 1,1-dichloroethane 16) DIPE 17) 2,2-dichloropropane 18) cis-1,2-dichloroethene 19) 2-butanone 20) bromochloromethane 21) chloroform 22) 1,1,1-trichloroethane 23) carbon tetrachloride 25) 1,1-dichloropropene 27) benzene 28) 1,2-dichloroethane 29) trichloroethene 30) 1,2-dichloropropane 31) dibromomethane 32) bromodichloromethane 33) 2-chloroethyl vinyl ether 34) cis-1,3-dichloropropene 35) 4-methyl-2-pentanone 37) toluene 38) iodomethane 39) trans-1,3-dichloropropene 40) Vinyl acetate 41) carbon disulfide 43) 1,1,2-trichloroethane 44) tetrachloroethene

VMS3595.M Fri Apr 24 11:55:24 2015

1.001 1.117 1.165 1.355 1.425 1.508 2.117 1.856 2.360 2.299 2.427 3.084 2.543 3.003 2.919 3.744 3.617 4.442 3.872 4.002 4.231 4.132 4.399 4.700 4.949 5.366 5.895 5.791 5.982 6.576 6.587 7.169 6.793 1.958 7.184 3.321 1.871 7.317 7.120

85 50 62 96 64

101 56 96 43 84 96 53 73 63 45 77 96 43

130 83 97

117 75 78 62 95 63 93 83

106 75 43 92

142 75 43 76 83

166

35085 64587 664 64

45951 Recovery

30.00 ppb 30.00 ppb 30.00 ppb

30.71

46157 30.29

ppb 102.37% ppb 100.97% ppb

Recovery 166778 29.99

Recovery 70299 29.94

Recovery

99.97% ppb

99.80%

0.00 0.00 0.00

0.00

0.00 / 0.00

0.00

187141 200041 212295 119195


Qvalue 98

43038 233807 609600 148798 175887 162799 168259

1112339 414236 285426 476177 192497 169189 303034

91026 275207 232471 192610 228780 644535 190672 167 4 4 3 172397

88047 201096 606143 249849 593524 367586 238153 209665 623104 436955 110881 160389

1895.70 ppb 70.42 ppb

355.64 ppb 69.25 ppb 70.63 ppb

1748.27 ppb 70.18 ppb 67.17 ppb 66.44 ppb

'70. 4 7 ppb 70.69 ppb

355.24 ppb 71.58 ppb 70.47 ppb 72.8 6 ppb 76.89 ppb 71.12 ppb 69.02 ppb 69.42 ppb 71.36 ppb 69.91 ppb 72.47 ppb 76.33 ppb

1735.52 ppb 73.26 ppb

358.22 ppb 68.55 ppb 69.04 ppb 78.74 ppb

162.49 ppb 73.89 ppb 71.37 ppb 71. 45 ppb

100 99 99 98 99 99 99 98 97 98 98 98 99 98 99

100 99 97 99 96 98

100 97 99

100 99 97 98 80 98 99 98 98 99 98 99 98 99

Page: 1

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Revised Report

160/224

Quantitation Report (NOt Reviewed)

Data File Acg On Sample Mise Integrator: Quant Time:

D:\Hpchern\1\Data\4042315\0423411.0 23 Apr 2015 9:15 prn ICALS

RTE Apr 24 11:55:24 2015

Quant Method D:\Hpchem\Methods\8260-W\VMS3595.M Quant Title VMS3595 8260/6200/624 Water ICAL QLast Update Fri Apr-24 11:45:19 2015 Response via Initial Calibration DataAcg Meth:MSD4 ACQ.M


11 JHL MSD4 1. 00


45) 4 6) 47) 48) 4 9) 50) 51) 53) 54) 55) 57) 58) 59) 60) 61) 62) 63) 64) 65) 66) 67) 68) 69) 70) 71) 72) 73) 74) 7 5) 76) 77) 78) 79)

1,3-dichloropropane 2-hexanone dibromochloromethane 1,2-dibromoethane chlorobenzene 1,1,1,2-tetrachloroethane bromoform

·bromobenzene 1,1,2,2-tetrachloroethane 1,2,3-trichloropropane ethylbenzene rn/p-xylene styrene a-xylene isopropylbenzene n-propyl benzene 2-chlorotoluene 4-chlorotoluene 1,3,5-trimethylbenzene tert-butylbenzene 1,2,4-trimethylbenzene sec-butylbenzene 1,3-dichlorobenzene 4-isopropyltoluene 1,4-dichlorobenzene 1,2-dichlorobenzene n-butylbenzene 1,2-dibromo-3-chloropr. 1,2,4-trichlorobenzene hexachlorobutadiene naphthalene trans-1,4-Dichloro-2-b. 1,2,3-trichlorobenzene

7.534 7.841 7. 456 7. 621 8.009 8.061 8.440 8. 788' 8.860 8.924 8.041 8.139 8.435 8.400 8.585 8.814 8.892 8.982 8. 921 9.083 9.121

.9 .173 9.277 9.245 9.323 9. 52 6 9.448 9.900

10.206 10.192 10.357

8.950 10.441

76 43

129 107 112 131 173 156

83 110 106 106 104 106 105

91 126 126 105 119 105 105 146 119 146 146·

91 75

180 225 128

53 180

222525 423177 142098 123173 381992 132786

84495 148320 134739

39565 202277 483348 389552 231041 579464 659942 128279 1314 62 438700 360533 430937 526175 246872 434542 248956 233383 370760 115939 131852

53244 294731 192349 115630

69.93 362.18

81.81 73.20 69.39 74.53 69.54 70.99 72.02 73.05 70.81

141.59 '74.04 69.8 6 69.97 70.47 68.78 69.14 71.28 69.24 70.29 70.75 68.10 73.19 69.03 68.03 75.50

457.34 74.27 74.08 77.03

363.21 73.11

ppb ppb ppb ppb pp)::> ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb ppb

98 97 97

100 99 99 98 99 98 96 95 97 97 99 98

100 97 92

100 99 98 99 99 99 99 97 98 99 97 99

100 91 99


VMS3595.M Fri Apr 24 11:55:24 2015 Page: 2

161/224

Revised Report

161/224




RTE Quant Time: Apr 24 11:55:24 2015


>- " >- ~ 1-. >-_ >-• • c • C:l-f- l-ID:~ c • • ~ ~ ~ .g: :g_ vt-_

1~ ~ >-~~ >c >- e R~ ·gJ ~ ~ ~ E f uc

• .. • • .2e~u:;: ~ N =

~~ ~ Q ~ 8" 0 f-:.li -- c "" ..,.,, • •e 0 u"" E ~ ~ ~ ~~e • ~~~a~~~ ~ ~ i~ ~ •'Oo§o ~ em£ 5 "" -~N E--f! iS

'5-55 ..ceE 0 NE£ rs:'f!i N f g '0

VMS3595.M Fri Apr 24 11:55:25 2015

~.1-:. •• ~ !a >-_

• A- c ~---~ "' • " ~ • oo

~.2.2 • 0 c m-5-5 • g ~ ~ E'Ei'Ei

0 ~<'t~ • E ~ e-e • Q ~ ~

d' "


" 1-_ 1-1-. ~ ~ ~~ c • ~ ~R " 8 mel-_ g

5 E~ :;: e:s~ .g m3«> ~ ~~ j~E ~~

11 JHL MSD4 1. 00

Page: 3

162/224

Revised Report

162/224



D:\Hpchem\1\Data\4042315\0423412.0 23 Apr 2015 9:42 pm R

RTE Apr 24 12:10:05 2015


12 JHL MSD4 1.00






Spiked Amount 30.000 26) 1,2-dichloroethane~d4




Target Compounds 2) dichlorodifluoromethane 3) chloromethane 4) vinyl chloride 5) bromomethane 8) acrolein 9) 1,1-dichloroethene

10) acetone 11) methylene chloride 12) trans-1,2-dichloroethene 13) acrylonitrile 14) MTBE 16) DIPE 18) cis-1,2-dichloroethene 19) 2-butanone 20) bromochloromethane 25) 1,1-dichloropropene 27) benzene 28) 1,2-dichloroethane 29) trichloroethene 31) dibromomethane 32) bromodichloromethane

5.186 7.818 9.520

4.245 Range 86

4.870 Range 64

6.747 Range 82

8.736 Range 85


1.001 1.119 1.165 1.358 2.117 1.856 2.360 2.296 2.427 3.084 2.551 2.919 3.617 4.445 3.866 4.398 4.694 4.951 5.363 5.788 5.985 6.567 6.584 7.169 6.790 1.958 7.184 3.319 1.874 7.314 7.117 7.534 7.841 7.453 7.618 8.009 8.437 8.788 8.860

34) cis-1,3-dichloropropene 35) 4-methyl-2-pentanone 37) toluene 38) iodomethane 39) trans-1,3-dichloropropene 40) Vinyl acetate 41) carbon disulfide 43) 1,1,2-trichloroethane 44) tetrachloroethene 45) 1,3-dichloropropane 46) 2-hexanone 47) dibromochloromethane 48) 1,2-dibromoethane 49) chlorobenzene 51) bromoform 53) bromobenzene 54) 1,1,2,2-tetrachloroethane

VMS3595.M Fri Apr 24 12:10:06 2015

70 95

152

113 118 65 130 98

- 117 95 115

85 50 62 96 56 96 43 84 96 53 73 45 96 43

130 75 78 62 95 93 83

106 75 43 92

142 75 43 76 83

166 76 43

129 107 112 173 156

83

35736 65937 668 67

30.00 ppb 30.00 ppb

.30.00 ppb

0.00 0.00 0.00

44580 29.25 0.00 Recovery

46496 29.96

ppb 97.50%

ppb 0.00 Recovery

170498 30.10 99.87%

ppb 100.33% ppb 101.13%

0.00 Recove.ry


217 3597 4356 2218

14821 1361

11189 1966 5292

34337 1692

593 1989

13228 950

1431 1032

966 1448

995 315

2088 1174

10603 918

1970 1562 5157

29493 466 711

1092 11087

367 995

2003 435 973

1609

0.08 ppb 1.23 ppb 1.42 ppb 1.33 ppb

45.25 ppb 0.63 ppb

22.47 ppb 0.82 ppb 2.18 ppb

52.98 ppb 0.28 ppb 0.08 ppb 0.82 ppb

15.22 ppb 0.73 ppb 0.44 ppb 0.11 ppb 0.35 ppb 0.61 ppb 0.80 ppb 0.12 ppb

38.02 ppb 0.34 ppb 6.28 ppb 0.17 ppb 0.56 ppb 0.58 ppb 1.32 ppb 4.90 ppb 0.29 ppb 0.31 ppb 0.34 ppb 9.29 ppb 0.21 ppb. 0.58 ppb 0.36 ppb 1.08 ppb 0. 4 6 ppb 0.84 ppb

0.00

Qvalue # 43

95 89 90

100 85 99 94 93 97

# 91 # 67

90 94 97 98 98

# 73 96 92

# 88 95 98 98 96 99 96

100 98 95 95 94 98 94

# 87 # 88

90 97 97

Page: 1

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Revised Report

163/224







12 JHL MSD4 1.00


55) 57) 58) 59) 60) 61) 62) 63) 64) 65) 66) 67) 68) 69) 70) 71) 72) 73) 74) 75) 76) 77) 78) 7 9)

1,2,3-trichloropropane ethylbenzene m/p-xylene styrene o-xylene isopropylbenzene n-propyl benzene 2-ehlorotoluene 4-ehlorotoluene 1,3,5-trimethylbenzene tert-butylbenzene 1,2,4-trimethylbenzene see-butylbenzene 1,3-diehlorobenzene 4-isopropyltoluene 1,4-diehlorobenzene 1,2-diehlorobenzene n-butylbenzene 1,2-dibromo-3-ehloropr. 1,2,4-triehlorobenzene hexaehlorobutadiene naphthalene trans-1,4-Diehloro-2-b .. 1,2,3-triehlorobenzene

8.924 8.041 8.139 8.435 8.400 8.588 8.814

.8. 892 8.979 8.921 9.086 9.121 9.173 9.277 9.245 9.320 9.526 9.448 9.902

10.209, 10.192 10.360

8.950 10.441

110 106 106 104 106 105.

91 126 126 105 119 105 105 146 119 146 146

91 75

180 225 128

53 180

478 528

1538 1635

578 1801 3334

605 965

2122 1761 2476 3714 2743 3079 3254 2593 3887 3066 3343 2381

11899 2378 3896


12.02 ppb 1.87 ppb 3.29 ppb 3.09 ppb 4. 4 6 ppb 2.45 ppb

#

#

#

79 80 98

100 97

100 97 98 85 95 94 99 99 99 95 98 88 99 95 94 99 99 78 98


VMS3595.M Fri Apr 24 12:10:06 2015 Page: 2

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Revised Report

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RTE Apr 24 12:10:05 2015


VMS3595.M Fri Apr 24 12:10:06 2015


12 JHL MSD4 1. 00

Page: 3

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Evaluate Continuing Calibration Report


D:\Hpchem\1\Data\4042315\0423413.0 23 Apr 2015 10:08 pm QCK010

RTE Apr 24 11:48:52 2015



13 JHL MSD4 1. 00

* ~""'~" 0(..} ? zo•t. fAvs-r 1E "- 'l.•of • .h roJ. SU.O -~

\CV P~S€s roJC. ~tkoB/e. ~ ~t~(t,

Min. Max.

RRF 0.000 20%

Min. Max.

Rel. Re1.

Area Area

80% 120%

Max. R.T. Dev 0.50min

1 IS 2 T 3 TP 4 TC 5 T 6 T 7 T 8 T 9 TC

10 T 11 T 12 T 13 T 14 T 15 TP 16 T 17 T 18 T 19 T 20 T 21 TC 22 T 23 T 24 s 25 T 26 s 27 T 28 T 29 T 30 TC 31 T 32 T 33 T 34 T 35 T 36 s 37 TC 38 T 39 T 40 T 41 T

42 IS 43 T 44 T 45 T 4 6 T 47 T 48 T 49 TP 50 T

RRF Dev

Compound

Fluorobenzene <IS> dichlorodif1uoromethane chloromethane vinyl chloride bromomethane chloroethane trichlorofluoromethane acrolein 1,1-dichloroethene acetone methylene chloride trans-1,2-dichloroethene acrylonitrile MTBE 1,1-dichloroethane DIPE 2,2-dichloropropane cis-1,2-dichloroethene 2-butanone bromochloromethane chloroform 1,1,1-trich1oroethane carbon tetrachloride dibromofluoromethane 1,1-dichloropropene 1,2-dichloroethane-d4 benzene 1,2-dichloroethane trichloroethene 1,2-dichloropropane dibromomethane bromodichloromethane 2-chloroethyl vinyl ether cis-1,3-dichloropropene 4-methyl-2-pentanone toluene-dB toluene iodomethane trans-1,3-dichloropropene Vinyl acetate carbon disulfide

1-chloro-3-fluorobenzene <I 1,1,2-trichloroethane tetrachloroethene 1,3-dichloropropane 2-hexanone dibromochloromethane 1,2-dibromoethane chlorobenzene 1,1,1,2-tetrachloroethane

VMS3595.M Fri Apr 24 11:51:11 2015

AvgRF

1.000 2.265 2.445 2.581 1.402 1.170 2.776 0.275 1.807 0. 4 65 2.010 2.037 0.544 5.047 3.634 6.128 2.336 2.047 0.729 1.087 3.339 2.728 2.142 1.280 2.750 1.303 7.985 2.348 2.006 2.108 1.039 2.253 0.183 2.916 1. 417 4.755 4.585 2.949 2.277 3.279 5.056

1.000 0.722 1.043 1.478 0.543 0.807 0.782 2.557 0.828

CCRF

1.000 2.452 2. 628 2.843 1.690 1. 316 3.053 0.285 1.990 0.432 2.178 2.314 0.560 5.226 3.797 6.345 2.344 2.244 0.710 1.190 3.588 2.940 2.281 1.273 2.971 1.288 8.532 2.484 2.177 2.239 1.122 2.384 0.170 3.122 1. 4 72 4.796 4.903 2.992 2.473 3.114 6.048

1.000 0.758 1.109 1.542 0.551 0.864 0.826 2.696 0.879

%Dev Area% Dev(min)

0.0 -8.3 -7.4

-10.2 * -20. 6# -12.5 -10.0 .-3.8 -10.1

7.1 -8.3

-13.6 -2.9 -3.6 -4.5 -3.5 -0.3 -9.7 2.7

-9.4 -7.4 -7.7 -6.5

0.5 -8.0 1.2

-6.8 -5.8 -8.5 -6.2 -8.0 -5.8

6.6 -7.1 -3.9 -0.8 -6.9 -1.4 -8.6 5.0

-19.6

0.0 -5.1 -6.4 -4.3 -1.5 -7.1 -5.7 -5.4 -6.2

94 97 97

101 110

98 97 99

103 97

102 109

96 101 100 100

95 103

97 101 100 100

99 93

102 94

101 101 104 100 102 100

92 100 100

95 101

95 102

87 114

94 100 100 100

98 100 102 101

99

0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00

0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00

Page: 1

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Revised Report

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D:\Hpchem\1\Data\4042315\0423413.0 23 Apr 2015 10:08 pm QCKOlO




13 JHL MSD4 1.00

Min. RRF Max. RRF Dev

0.000 Min. Rel. Area 20% Max. Rel. Area

80% Max. R.T. Dev 0.50min 120%

Compound AvgRF CCRF %Dev Area% Dev(min)

51 TP bromoform 0.445 0.460 -3.4 99 0.00 52 s 4-bromofluorobenzene 1.090 1.106 -1.4 96 0.00 53 T bromobenzene 0.970 1.041 -7.3 103 0.00 54 TP 1,1,2,2-tetrachloroethane 0.869 0.893 -2.8 98 0.00 55 T 1,2,3-trichloropropane 0.252 0.260 -3.5 97 0.00

56 IS 1,2-dichlorobenzene-04 <IS> 1.000 1.000 0.0 95 0.00 57 TC ethyl benzene 1.289 1. 392 -8.0 102 0.00 58 T m/p-xylene 1.541 1.653 -7.3 101 0.00 59 T styrene. 2.375 2.638 -11.1 102 0.00 60 T a-xylene 1.493 1.593 ·-6.7 100 0.00 61 T isopropylbenzene 3.738 4. 02 6 -7.7 100 0.00 62 T n-propyl benzene 4.227 4.574 -8.2 101 0.00 63 T 2-chlorotoluene 0.842 0.885 -5.1 99 0.00 64 T 4-chlorotoluene 0.858 0.921 -7.3 102 0.00 65 T 1,3,5-trimethylbenzene 2.778 3.018 -8.6 101 0.00 66 T tert-butylbenzene 2.350 2.522 -7.3 101 0.00 67 T 1,2,4-trimethylbenzene 2. 767 3.034 -9.6 101 0.00 68 T sec-butylbenzene 3.357 3.646 -8.6 101 0.00 69 T 1,3-dichlorobenzene 1.636 1.737 -6.2 101 0.00 70 T 4-isopropyltoluene 2.680 2.917 -8.8 101 0.00 71 T 1,4-dichlorobenzene 1. 628 1.757 -7.9 102 0.00 72 T 1,2-dichlorobenzene 1.548 1. 628 -5.2 101 0.00 73 T n-butylbenzene 2.217 2.433 -9.8 101 0.00 74 T 1,2-dibromo-3-chloropropane 0.114 0.115 -0.2 98 0.00 75 T 1,2,4-trichlorobenzene 0.801 0.851 -6.1 102 0.00 76 T hexachlorobutadiene 0.324 0.343 -5.6 102 0.00 77 T naphthalene 1.727 1.832 -6.1 103 0.00 78 T trans-1,4-Dichloro-2-butene 0.239 0.246 -2.9 99 0.00 79 T 1,2,3-trichlorobenzene 0.714 0.759 -6.3 104 0.00

(#) ~ Out of Range SPCC' s out 0 CCC's out = 0

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Revised Report

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RTE Apr 24 11:51:27 2015



13 JHL MSD4 1. 00


Internal Standards 1) Fluorobenzene <IS> 5.189 70 35614 30.00 ppb

0.00/ 42) 1-chloro-3-fluorobenze. 7.821 95 66044 30.00 ppb 0.00 56) 1,2-dichlorobenzene-04. 9.520 152 66878 30.00 ppb 0.00








4.242 Range 86

4.870 Range 64

6. 74 6 Range 82

8.738 Range 85


1.004 1. 117 1. 165 1.358 1.433 1.527 2.117 1.859 2.354 2.302 2.430 3.081 2.542 3.003 2.919 3.747 3. 620 4.445 3.871 4.005 4.233 4.132 4.395 4.699 4.948 5.365 5.892 5.788 5.982 6. 567 6.584 7.169 6.793 1.958 7.187 3.321 1.877 7.317 7.120


VMS3595.M Fri Apr 24 11:51:27 2015

-

-

-

113 118 65 130 98 117 95 115

85 50 62 96 64

101 56 96 43 84 96 53 73 63 45 77 96 43

130 83 97

117 75 78 62 95 63 93 83

106 75 43 92

142 75 43 76 83

166

45322 29. 84 ppb 0.00 Recovery 99.47%

45854 29. 65 ppb 0.00 Recovery 98.83%

170794 30.25 ppb 0.00 Recovery 100.83%

73052 30.43 ppb 0.00 Recovery 101.43%

29110 31192 33755 20066 15628 36241 84707 23622 25629 25854 27472

166117 62043 45076 75329 27821 26643 42123 14123 42592 34896 27076 352 69

101284 29489 25842 26574 13319 28297 50568 37064 87377 58208 35517 29360 92405 71796 16694 24425

10.83 ppb 10.74 ppb 11.02 ppb

"12.06 ppb 11.25 ppb 11.00 ppb


257.21 ppb 10.36 ppb

.10. 45 ppb 10.35 ppb 10.03 ppb 10.97 ppb 48.65 ppb 10.94 ppb 10.74 ppb 10.77 ppb 10.65 ppb 10.80 ppb 10.68 ppb 10.58 ppb 10.85 ppb 10.62 ppb 10.80 ppb 10.58 ppb

219.64 ppb 10.71 ppb 51.95 ppb 10.69 ppb 10.14 ppb 10.8 6 ppb 23.74 ppb 11.96 ppb 10.51 ppb 10.64 ppb

Qvalue 97 98 98 99 98 99 99 97 99 98 97 96 98 99 98 98 99 99 96 98 99 95

100 98 99 97 99 96 99

100 99 99 98 97

100 99 98 98 97

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/ tb-

(rrJ>

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Revised Report

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RTE Apr 24 11:51:27 2015



13 JHL MSD4 1.00


45) 4 6) 47) 48) 49) 50) 51) 53) 54) 55) 57) 58) 59) 60) 61) 62) 63) 64) 65) 66) 67) 68) 69) 70) 71) 72) 73) 74) 75) 7 6) 77) 78) 79)

1,3-dichloropropane 2-hexanone dibromochloromethane 1,2-dibromoethane chlorobenzene 1,1,1,2-tetrachloroethane bromoform bromobenzene 1,1,2,2-tetrachloroethane 1,2,3-trichloropropane ethyl benzene m/p-xylene styrene a-xylene isopropylbenzene n-propyl benzene 2-chlorotoluene 4-chlorotoluene 1,3,5-trimethylbenzene tert-butylbenzene 1,2,4-trimethylbenzene sec-butylbenzene 1,3-dichlorobenzene 4-isopropyltoluene 1,4-dichlorobenzene 1,2-dichlorobenzene n-butylbenzene 1,2-dibromo-3-chloropr ... 1,2,4-trichlorobenzene hexachlorobutadiene naphthalene trans-1,4-Dichloro-2-b ... 1,2,3-trichlorobenzene

7.534 7.841 7.453 7. 621 8.009 8.058 8.440 8.788 8.860 8.924 8.041 8.139 8.434 8.400 8.585 8.814 8.892 8.979 8.921 9.083 9.118 9.173 9.277 9.245 ·9. 320 9.523 9.448 9.899

10.206 10.189 10.357

8.950 10.441

76 43

129 107 112 131 173 156

83 110 106 106 104 106 105

91 126 126 105 119 105 105 146 119 146 146

91 75

180 225 128

53 180'

33938 60647 19018 18189 59343 19346 10122 22919 19670

5730 31037 73693 58804 35506 89750

101977 19730 20527 67284 56230 67633 81273 38726 65017 39159 36302 54239 15342 18963

7638 40850 27430 16920


9.71 ppb 10.73 ppb

.10.28 ppb 10.35 ppb 10.80 ppb 21.45 ppb 11.11 ppb 10.67 ppb 10.77 ppb 10.82 ppb 10.51 ppb 10.73 ppb 10.86 ppb 10.73 ppb 10.96 ppb 10.86 ppb 10.62 ppb 10.88 ppb 10.79 ppb 10.52 ppb 10.98 ppb 60.14 ppb 10.61 ppb 10.56 ppb 10.61 ppb 51.47 ppb 10.63 ppb

99 99 97 99 99 99 99 98 98 96 99 99 98 95 99 99 96 98 98 98 98 99 99 99 99 99

100 96 97 98 99 96 97

(#) = qualifier out of range (m) '=manual integration (+) = signals summed

VMS3595.M Fri Apr 24 11:51:27 2015 Page: 2

169/224

Revised Report

169/224




RTE Apr 24 11:51:27 2015


550000

500000

450000

400000

300000

250000 .. _ • " i •

VMS3595.M Fri Apr 24 11:51:28 2015


13 JHL MSD4 l. 00

Page: 3





Heated Purge: (Y/N) Y Calibration Times: 11:47



RRF20.0 = 0424405.D RRF30.0 = 0424406.D RRF50.0 = 0925434.D


5.0 10.0 20.0 30.0 50.0 RRF RSD

1.10 0.994 1.07 1.09 1.06 3.51

0.089 0.09 0.086 0.091 0.089 6.56

3.01 2.64 2.74 2.79 2.79 4.31

0.997 1.04 1.08 1.20 1.07 6.89

0.031 0.045 0.047 0.054 0.044 17.2

1.26 1.32 1.40 1.58 1.39 10.0

1.29 1.33 1.31 1.35 1.32 1.90

1.59 1.66 1.86 2.13 1.84 13.3

0.201 0.210 0.218 0.240 0.215 6.17

0.004 0.01 0.01 0.011 0.009 29.9

4.73 4.71 4.68 4.74 4.72 0.780

1.10 1.11 1.09 1.09 1.10 0.643

0.383 0.301 0.310 0.315 0.333 10.4

Propionitrile

1,4-Dioxane

toluene-d8

4-bromofluorobenzene

Pentachloroethane

Chloroprene

Methacrylonitrile

Isobutyl alcohol

Methyl methacrylate

1,2-dichloroethane-d4

Ethyl methacrylate

6A


COMPOUND

Allyl chloride

Acetonitrile


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Revised Report

170/224

171/224

Revised Report

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MSD4 Runlog SGS Environmental Services, Inc.

Method: 8260-W/APIX-W/8260-SUAPIX-SL Initial Cal. Curve: VMS3595/APIX-WNMS3581NMS3484

Matrix·

FILENAME

0424401.D .

0424402.0

0424403.D

0424404.D

0424405.D

0424406.D

0424407.0

0424408.D

0424409.D

0424410.D

Review Analyst W

Water/Soil Batch· VMS3596

SAMPLE ID I DILUTION DATE I TIME COMMENTS pH METHOD OPER

TUNE 4/24/2015 11 :20 Tune Pass ~ APIX-W JHL

ICAL1 4/24/2015 11:47 ICALPass ~ APIX-W JHL


ICAL3 4/24/2015 12:40 ICAL Pass ~ APIX-W JHL




CCAPX9 4/24/2015 14:28 Second Source Verification for Curve Mx ~ APIX-W JHL

TUNE 4/24/2015 15:02 Tune Pass

CCAPX9 4/24/201 5 15:29 ICV/CCV Pass

Soil Stds: Curve=V12-233A/BN12-233A/B QC=V12-226A/BN12-226A/B Water Stds: Curve=V12-233CN12-233D-1 QC=V12-226CN12-226D-IV

Air Stds: Primary= Secondary=

~ APIX-W JHL

~ APIX-W JHL

Page Number: V-:-0:-2-4,.-. 1,-.,1-2-20::-:2:-:.1

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Revised Report

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BFB

D:\Hpchem\1\Data\VMS3596\ 0424401.0 24 Apr 2015 11:20 am JHL TUNE


Integration File: rteint.p

Method D:\Hpchem\Methods\APIX-W\VMS3596.M Title VMS2575 8260 APX9-W ICAL Last Update Fri Apr 24 14:17:48 2015


800000

II ' 600000 I

400000

200000

0 :" ime--> 6.80 7.00 7.20 7.40 7.60 7.80 8.00 8.20 8.40 8.60 8.80 9.00 9.20

.

' 9.40 9.6o

Abundance Average of 8.733 to 8.739 min.: 0424401.0\data.ms (-) 95.1

150000

174.0

100000

75.1

50000

116.9 129.9 142.9154.9 193.0 207.1

9.80 10.00 10.20 10.40 10.60

249.0 265.1

00

, 11 I 0 I

3ji:,,,,,I~,J ~ ,. 180 190 200 210 22o 230 240 25o 260 2~ mfz •• > 30 40 50 60 70 80 90 100 110 120 130 140 150 160o170

AutoFind: Scans 27 69' 2770, 2771; Background Corrected with Scan 2760

I Target I Re1. to I Lower I Upper Re1. Raw Result I Mass I Mass I Limit% I Limit% Abn% Abn Pass/Fail ----------------------------------------------------------------------

50 95 15 40 17.8 27477 PASS I 75 95 30 60 46.7 72123 PASS. I 95 95 100 100 100.0 154581 PASS I 96 95 5 9 6.7 10371 PASS I

/

/ 173 174 0.00 2 0.6 816 PASS

:10-174 95 50 100 83.6 129224 PASS

i 1~r!f' 175 174 5 9 7.1 9227 PASS 176 174 95 101 97.7 126240 PASS 177 176 5 9 6.7 8513 PASS

----------------------------------------------------------------------

VMS3596.M Fri Apr 24 14:28:41 2015 Page: 1

173/224

Revised Report

173/224


Tune File D:\Hpchem\l\Data\4042415\042440l.D Tune Time 24 Apr 2015 11:20 am ~,.t/"'

(v"'' ~6qc;_, Daily Calibration File : D:\Hpchem\l\Data\4042415\0424406.D

30823 57169 58401

File Sample Surrogate Recovery % Internal Standard Responses ========================================================================= 0424402.D

I CALl

0424403.D ICAL2

0424404.D ICAL3

0424405.D ICAL4

0424406.D ICAL5

0424407.D ICAL6

0424408.D CCAPX9

95 100 100

96 99 99

98 99 101

97 99 100

103 101 100

101 101 100

100 101 100

{fails) - fails 12hr time check

36015

33871

32422

33493

30823

34347

37070

* - fails criteria

Created: Fri Apr 24 15:23:37 2015 MSD4

66440 66375

62066 62361

59166 60707

61669 62321

57169 58401

63930 65326

68841 70277

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Revised Report

174/224

Method

Cal Files

Compound Allyl chloride Acetonitrile Chloroprene

Linear Regression Correlation Coefficient Results

VMS3596.M

0.5 ' D'\Hpchem\l\Data\4042415\0424402.D 2 , D,\Hpchem\l\Data\4042415\0424404.D 5 , D'\Hpchem\l\Data\4042415\0424405.D 10 D'\Hpchem\l\Data\4042415\0424406.D 20 , D'\Hpchem\l\Data\4042415\0424407.D 50 ' D'\Hpchem\l\data\VMS2575\0925434.D 1 , D,\Hpchem\l\Data\4042415\0424403.D

Formula or RF RF=l.063 RF=0.089 RF=2.793

Methacrylonitrile RF=l. 074 Isobutyl alcohol Y=0.04888 x- 0.00204 Methyl methacrylate RF=l. 394 1,2-dichloroethane-d4 RF=l.320 Ethyl methacrylate RF=l. 846 Propionitrile RF=0.215 l,4-Dioxane Y=0.00980 X+ 0.00217 toluene-dB RF=4. 722 4-bromofluorobenzene RF=l.095 Pentachloroethane RF=0.333

* Correlation Coefficent is < 0.990

Correlation Coefficient

Method (r•2) Avg RF Avg RF Avg RF Avg RF Linear Avg RF Avg RF Avg RF Avg RF Linear Avg RF Avg RF Avg RF

0.995 /

0.990/

175/224

Revised Report

175/224

Instrument Method

Initial Calibration Report SGS Environmental Services

Matrix Cal. Date Last Modified

Number of levels

MSD4 VMS3596.M NA 24 Apr 2015 11:47 am Fri Apr 24 14:16:23 2015 7

Cfiu!JM~]> /o l..o fl-'6 ftf{T'ItC/f<AU E:TH-bi" TP /0 f1'8

Cal Files by ID 0.5 ; D:\Hpchem\1\Data\4042415\0424402.D 2 ; D:\Hpchem\l\Data\4042415\D424404.D 5 ; D:\Hpchem\1\Data\4042415\0424405.D 10 ; D:\Hpchem\1\Data\4042415\0424406.D 20 ; D:\Hpchem\1\Data\4042415\0424407.D 50 ; D:\Hpchem\1\data\VMS2575\0925434.D 1 ; D:\Hpchem\1\Data\4042415\0424403.D

Calibration Level ID O.Si 2i SilO; 20i 50; l; Concentration (ppb)

Allyl chloride Acetonitrile Chloroprene Methacrylonitrile Isobutyl alcohol Methyl methacrylate 1,2-dichloroethane-d4 Ethyl methacrylate Propionitrile l,4-Dioxane toluene-dB 4-bromofluorobenzene Pentachloroethane

0.5; 2.0; 5.0; lD.Oi 20.0; SO.Oi l.Oi ;1.101 ;0.994 ;1.073 ;1.088 ;1.063 ;~;1.061 ;0.089 ;0.090 ;0.086 ;0.091 ;0.079 ;~;0.097 i3.009 ;2.645 ;2.736 i2.789 ;2.775 i~;2.807 i

;0.997 ;1.040 ;1.079 ;1.196 ;1.116 ;~;1.015 ;0.031 ;0.045 ;0.047 ;0.054 ;0.048 ;r "'lD.041 ;1.263 ;1.321 ;1.402 ;1.579 ;1.542 ;c:::::::' ;1.255 ;1.288 ;1.331 ;1.312 ;1.353 ;1.339 ~;1.298 ;1.588 ;1.662 ;1.865 ;2.130 ;2.150 ;~ ;1.679 ;0.201 ;0.210 ;0.218 ;0.240 ;0.214 >:'" j ::>;0.208 ;0.004 ;0.010 ;0.010 ;0.011 ;0.010 ;c::::::::::>,0.009 ;4.727 ;4.707 ;4.680 ;4.744 ;4.781 ;c-==>;4.694 ;1.096 ;1.106 ;1.089 ;1.094 ;1.100 ; c:=:>.L088 ;0.383 ;0.301 ;0.310 ;0.315 ;~;~;0.354

AvgRF 1. 063 0.089 2.793 1. 074 0.044 1.394 1.320 1. 846 0. 215 0.009 4.722 1. 095 0.333

%RSD 3.510 6.557 4.309 6.890 /

17 .184 .( - /...t.IEit(L 10.038 1. 904

13. 317 6.175 /

2 9 . 8 9 0 ,r- l..t"EII'-0.780 0.643

10.417- 10 Pf>8

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Revised Report

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D:\Hpchem\1\Data\VMS3596\0424402.D 24 Apr 2015 11:47 am ICAL1

RTE Apr 24 14:29:25 2015



2 JHL MSD4 1. 00




System Monitoring Compounds 8) 1,2-dichloroethane-d4 4.867 65 46380 29.27 ppb 0.00 Spiked Amount 30.000 Range 64 - 140 Recovery 97.57%


14) 4-bromofluorobenzene 8.735 95 72800 30.01 ppb 0.00 Spiked Amount 30.000 Range 85 115 Recovery 100.03%

Target Compounds Qvalue 2) Allyl chloride 2.218 76 661 0.52 ppb # 67 3) Acetonitrile 2.762 40 1063 9.99 ppb # 72 4) Chloroprene 2.980 53 1806 0.54 ppb 96 5) Methacrylonitrile 4.795 41 5982 4.64 ppb 97 6) Isobutyl alcohol 5.125 43 936 17.20 ppb # 96 7) Methyl methacrylate "6. 191 41 758 0.45 ppb 98 9) Ethyl methacrylate 7.363 69 953 0.43 ppb 97

10) Propionitrile 4.781 54 2418 9.36 ppb 100 11) 1,4-Dioxane 6.199 88 220 12.07 ppb # 72 16) Pentachloroethane 9. 092 167 424 0.58 ppb 91

--------------------------------------------------------------------------


VMS3596.M Fri Apr 24 14:29:25 2015 Page: 1

/

177/224

Revised Report

177/224

Quantitation Report (Not Re-viewed)

Data File Acq On Sample Mise Integrator·: Quant Time:

D:\Hpchem\l\Data\VMS3596\0424402.D 24 Apr 2015 11:47 am I CALl

RTE Apr 24 14:29:25 2015


fA.bundance

540000


520000

500000

480000

460000

440000

420000

400000

380000

360000 "' "' • 340000 c • :§ .. 320000

300000 . i

280000

"' 260000 ,· "' " •

240000 c

~ • D

220000 e 0

i' i

200000 ' i

180000

160000

~ l: 140000 c • ~ ~

120000 .. .Q ji u 100000

"'· ~ I ';} .. E

• u ~

c 'C • .Q . ~ ~ jj c e ~

B 0 I ~t5

80000

60000

40000

i • l • ~ • E

1-w 20000 .

. , 2.00 3.00 4.00 5.00 6.00 7.00

VMS3596.M Fri Apr 24 14:29:26 2015

"' " "' " • c

~ • D e 0 ,

~ :1' J.

8.00

"' ,; c • ~

.11 e 0 , ';; E e ~


"' -;;·

"' v ~ 0 • c ~

• c • jj e

I • ~

9.00 10.00

2 JHL MSD4 1.00

11'oo .. 12.00

Page:

.

..

.

1 .• •

2

178/224

Revised Report

178/224



D:\Hpchem\1\Data\VMS3596\0424403.D 24 Apr 2015 12:13 pm ICAL2




3 JHL MSD4 l. 00




System Monitoring Compounds 8) 1,2-dichloroethane-d4 4.870 65 43961 29.50 ppb 0.00 Spiked Amount 30.000 Range 64 - 140 Recovery 98.33%



Target Compounds Qvalue 2) Allyl chloride 2.221 76 1198 l. 00 ppb 100 3) Acetonitrile 2.763 40 2186 21.85 ppb 84 4) Chloroprene 2.980 53 3169 1.00 ppb 95 5) Methacrylonitrile 4.789 41 11462 9.45 ppb 96 6) Isobutyl alcohol 5.122 43 2332 43.51 ppb 98 7) Methyl methacrylate 6.188 41 1417 0.90 ppb 96 9) Ethyl methacrylate 7.363 69 1896 0.91 ppb 98

10) Propionitrile 4.778 54 4 692 19.31 ppb 97 11) 1,4-Dioxane 6.199 88 1027 86.17 ppb 96 16) Pentachloroethane 9.095 167, 735 1.06 ppb 86

--------------------------------------------------------------------------(#) = qualifier out of range (m) = manual integration (+) = signals summed

VMS3596.M Fri Apr 24 14:29:28 2015 Page: 1

/

179/224

Revised Report

179/224


Data File Acq On Sample Mise Integrat-or: Quant Time:


RTE Apr 24 14:29:28 2015

Quant Method D:\Hpchem\Methods~APIX-W\VMS3596.M Quant Title VMS2575 8260 APX9-W ICAL QLast Update Fri Apr 24 14:17:48 2015 Resporise via Initial Calibration DataAcq Meth:MSD4_ACQ.M


520000 i

500000

480000

460000 ;,

"' 440000 ,· "' v • e

420000 i • N e • ~ e 400000 0 ,

::1 : e 380000

~ 360000

" 340000

"' "' 320000

'Z e • I , '8

300000

280000

260000

"' " ' 240000 "' v • e • 220000 N e • j ~ e

200000 0

ii' :

180000

160000 ..

140000 "' ~ u • e 120000 • 5 ~ i

100000 ~ ··.

80000 ~ : =

11l c

:ffi I 60000 ';} ~ I r> u

'C ~ " •

~ .u ~ ll 40000 0 " e I

E

~ j~ g "' 20000

~.~ I~ ' 0 1.00

. ., ime--> -, 2.00 3.00 4.00 5.00 6.00 7.00 8.00

.· . :

VMS3596.M Fri Apr 24 14:29:28 2015

Vial: Operator: Inst

.I:'l __ u_l tip~_r_:

"' ,· "' v ~

'Z 'e

~ e • ~ • ~ e 0 , ~ 0 E e ~

"

~ • ~ ~ 0

11 • Q.

I

9.00 10.00

3 JHL MSD4 1.00

11.00 -

'.

< .. <

. ·.· :.

· ..

12.00

Page: 2

180/224

Revised Report

180/224




RTE Apr 24 14:29:31 2015



4 JHL MSD4 1. 00




System Monitoring Compounds 8) 1,2-dichloroethane-d4 4.868 65 43169 30.26 ppb 0.00 Spiked Amount 30.000 Rang·e 64 140 Recovery 100.87%



Target Compounds Qvalue 2) Allyl chloride 2.215 76 2148 l. 87 ppb 100 3) Acetonitrile 2.768 40' 3890 40. 61 ppb 89 4) Chloroprene 2.980 53 5716 1.89 ppb 91 5) Methacrylonitrile 4.792 41 22477 19.37 ppb 98 6) Isobutyl alcohol 5.122' 43 4892 93.86 ppb 97 7) Methyl methacrylate 6.188 41 2856 l. 90 ppb 97 9) Ethyl methacrylate 7.363 69 3593 1.80 ppb 98

10) Propionitrile 4.775 54 9076 39.02 ppb 98 11) 1,4-Dioxane 6.196 88 2080 189.73 ppb 99 16) Pentachloroethane 9.095 167 1220 1.81 ppb 96

--------------------------------------------------------------------------'

(#) = qualifier out of range (m) = manUal ifltegration (+) = signals summed

VMS3596.M Fri Apr 24 14:29:31 2015 Page: 1

181/224

Revised Report

181/224

Quantitatibn Report, (Not Reviewed)

Data' File Acq On Sample Mise



Quant Method D:\Hpchem\Methods\APIX-W\VMS3596.M Quant Title VMS2575 8260 APX9-'.W ICAL QLast Update Fri Apr 24 14:17:48 2015 Response via Initial Calibration DataAcq Meth:MSD4_ACQ.M

f'lbundance ·TIC: 0424404.0\data.ms

500000 !

480000

460000

440000 "' • A ,, 00

420000 v • c ~ c

400000 • D

!' • 0 0

380000 ;1: e

' 2

360000 ~

340000 ..

320000 00 oj

'l c

300000 • ~ !

280000

260000

240000 "' ,· 00 v

" • 220000 c • N c • D

200000 • 0

" i ~

180000 .

160000

140000

¥ " 120000 c • £ • I

100000 I ! 80000

.... ~

I • " fj

0 ·m

' 60000 • • ·l! .;, u K 0 'C • c • ~ 5 ~ • ti

·e: e a. E 40000 ~

B o ~ ~15 ~

20000

0 ~Ji A A II I

1.00 -~--,- r

ime--> 2.00 3.00 4.00 5.00 6.00 . 7.00! 8.00

VMS359q.M Fri Apr 24 14:29:31 2015

':} c

~ • D • 0 0

'6 E • ~

Vial: Operator: Inst Mul·tipl-r:

"' ,· 00 v ~

~ c

• • ] ;; ~ • a.

I 9.00. 10.00

4 JHL MSD4 1. 00.

11.00

.

'

"

;

•• !

12'oo ·

Page: 2

I

182/224

Revised Report

182/224

Quantitation Report (Not Reviewed)·






5 JHL MSD4 1. 00




System Monitoring Compounds 8) 1,2-dichloroethane-d4 4.873 65' 43929 29.81 ppb 0.00 Spiked Amount 30.000 Range 64 - 140 Recovery 99.37%

12) toluene-dB .6. 744 98 156752 29.73 ppb 0.00 Spiked Amount 30.000 Range 82 - 117 Recovery 99.10%


Target Compounds Qvalue 2) Allyl chloride 2.215 76 5991 5.05 ppb 98 3) Acetonitrile 2.760 40 9582 96.84 ppb 95 4) Chloroprene 2.980 53, 15271 4.90 ppb 97 5) Methacrylonitrile 4.792 41 60206 50.22 ppb 99 6) Isobutyl alcohol 5.122 43 13105 241.39 ppb # 97 7) Methyl methacrylate o6. 191 41 7828 5.03 ppb 99 9) Ethyl methacrylate 7.366 69 10412 5.05 ppb 97

10) Propionitrile 4.775 54 24362 101.39 ppb 96 11) 1,4-Dioxane 6.197 88 5329 480.35 ppb 94 16) Pentachloroethane 9.092 167 3217 4. 66 ppb 98

(#) = qualifier out of range (m) = manual integration (+) = signals sumffied

VMS3596.M Fri Apr 24 14:29:34 2015 Page: .1

I

183/224

Revised Report

183/224

Quantitation Report (rot Reviewed)

Data File Acq On s.3.rnpie Mise Integrator: Quant Time:

D:\Hpchem\1\Data\VMS3596\0424405.D 24 Apr 2015 1:07 PIT\ ICAL4

RTE Apr 24 14:29:34 2015

Quant Method D:\Hpchem\Methods\APIX-W\VMS3596.M Quant Tit_1e VMS2575 8260 APX9-W ICAL QLast Update Fri Apr 24 14:17:48 2015 Response via Initial Calibration DataAcq Meth:MSD4_ACQ.M

f'lbundance TIC: 0424405.D\data.ms .

500000 .. 480000

460000 i

"" 440000 A

' "' v ' ~-• 420000 ~ • ~ e

400000 0 ,

.. :;: e

380000 ~ 360000 r 340000

' "' 320000 00

~ c ~

300000 li "

280000

260000 !

"" 240000 A-

"' v • c

220000 ~ • ~ e 200000 0

&' ' "

180000 I ~ . .,

160000 0

I ~ 140000 fi

- :-t "J ' ~ ' 120000 c

-~ 100000

.e -~ 2

t 3 ' % 80000 " " I 0

• • ~ c fi ·c • 1l 60000 ~ ~ . E

0 ~] :;;; 1"-

jts ~

40000 ;;: ill

• .. ' 20000 LJJL__ ~ '

0 h frime--> 1.00 2.oo ' 3.bo 4.00 5.00 6.00 7.00 ... 8.00 --

VMS3596.M Fri Apr 24 14:29:34 2015

"' • c

~ ~ e g \; E e !I'


"" A

"' v 9 • c

• c • ~ • e 0

" 0

11 • ~

9.00 10.00

5 JHL MSD4 1.00

11.00

i

. -··I

--·-· .. -

12.00

Page: 2

184/224

Revised Report

184/224

Quantitation Report (Not Reviewed}


D:\Hpchem\l\Data\VMS3596\0424406.D 24 Apr 2015 1:34 pm ICAL5



6 JHL MSD4 1.00







14) 4-bromofiuorobenzene Spiked Amount 30.000

Target Compounds 2) Allyl chloride 3) Acetonitrile 4) Chloroprene 5) Methacrylonitrile 6) Isobutyl alcohol 7) Methyl methacrylate 9) Ethyl methacrylate

10) Propionitrile 11) 1,4-Dioxane 16) Pentachloroethane

5.189 7.818 9.520

4.870 Range 64

6.747 Range 82

8.736 Range 85

2.215 2.766 2.980 4.792 5.122 6.188 7.366 4.775 6.197 9.092

70 95

152

65 140 98 117 95 115

76 40 53 41 43 41 69 54 88

167

30823 57169 58401

41702

30.00 ppb 30.00 ppb 30.00 ppb

30.75

0.00 0.00 0.00

0.00 Recovery

146239 .30.14 Recovery

ppb 102.50% ppb 100.47% ppb

0.00

62518 29.95 0.00 Recovery 99.83%

11174 18742 28653

122906 27635 16223 21886 49257 11630

6137

10.23 ppb 205.83 ppb

9.98 ppb 111.40 ppb 551.50 ppb •11.33 ppb 11.54 ppb

222.75 ppb 1148.21 ppb

9.48 ppb

Qvalue 100 100 100 100 100 100 100 100 100 100

-----------------------------------~--------------------------------------


VMS3596.M Fri Apr 24 14:29:37 2015 Page: 1

185/224

Revised Report

185/224

Quantitation Report {Not Reviewed)

Data File Acq On Sample Misc. Int·egrator: Quant Time:


RTE Apr 24 14:29:37 2015


bundance TIC: 0424406.0\data.ms

480000

460000

.. 440000

420000 "' ! ' "' v • 0 400000 ~ • ~ E 380000 0 , =

"' e 360000 .. ~ 340000

320000 I

"' 00 ~ • 300000 0

~ • ~ ·E 2 280000 ~ 0 • ~ "

260000

" .. 240000

"' ;:· "' " ! • 0

220000 ~ 0 • ~ e : 0

200000

180000 ,j'

160000 :I

~ • I 0

" " ~ % • ~ . ·~

~ . • • : " 5 ~ • E

~ i l ~ "'

140000

120000

100000

80000

60000 • ..

' i' i • II

4.00 I

8.00 5.00 6.00 7.00 ~1--r-~~sLl~

ime--> 1.00 2.00 3.00

VMS3'596.M Fri Apr 24 14:29:37 2015

"' •. 0 • N 0

Jl e 0 , '6 E e ~

.f

Vial: Operator: Inst .Multipl.r:

"' A•

"' .v ~

'j; 0

~ • jj e ~ g 0 • 0.

9.00 10.00

6 JHL MSD4 1. 00

11.00

,.• · .. '

·' . .. .....

. ..

12.00

Page: 2

186/224

Revised Report

186/224




RTE Apr 24 14:29:40 2015



7 JHL MSD4 1.00




System Monitoring Compounds 8) 1,2-dichloroethane-d4 4.870 65 45975 30.42 ppb 0.00 Spiked Amount 30.000 Range 64. - 140 Recovery 101.40%


14) 4-bromofluorobenzene 8.739 95 70329 30.13 ppb 0.00 Spiked Amount 30.000 Range 85 - 115' Recovery 100.43%

Target Compounds Qvalue 2) Allyl chloride 2.215 76. 24333 19.99 ppb 99 3) Acetonitrile 2.763 40' 36352 358.26 ppb 94 4) Chloroprene 2. 977 53 63532 19.87 ppb 98 5) ,Methacrylonitrile 4.792 41 255612 207.92 ppb 100 6) Isobutyl ,alcohol 5.125 43 54637 977.53 ppb 99 7) Methyl methacrylate 6.188 41 35299 22.12 ppb 99 9) Ethyl methacrylate 7.366 69 4 9242 23.30 ppb 98



VMS3596.M Fri Apr 24 14:29:40 2015 Page: 1

I

187/224

Revised Report

187/224

Quantitation ~eport; (Not Reviewed)




Quant Method D:\Hpchem\Methods\APIX-W\VMS3596.M Quant Title VMS2575 8260 APX9~W ICAL QLast Update Fri Apr 24 14:17:48 2015 Response via Initial Calibration DataAcq Meth:MSD4_ACQ.M

·TIC: 0424407. Did at a. ms

560000 ;

540000

520000

500000

480000 . ~'

"' ,. "' 460000 " • c •

440000 I' ~ • ~ e 420000

0

~ 400000

e !

380000

·" 360000

"' 340000

320000

.; ~ • ' c • I ~

300000

280000

260000 "

240000

220000 j' .

' 200000 !l

180000

160000

140000

120000

* i'i • ~ jj • E

"' "' • <l. ~

1!:)

i ~-

100000 I ..

.

60000

40000

20000

o~.-~~~~~~~· ime--> 1.00 2.00 3.00 5.00 6.0

c i 0 7.00 i 8.00

--~-.--,-,

4.00

VMS3596.M Fri Apr 24 14:29:40 2015

"' • c

~ • ~ e 0 , '5 E e ~

'

Vial: Operator: Inst Mu1.tiplr:

"' A

"' " ~ ~ c ~ c • ~ e ~

~-

• c • "' • e .Q

;; " c • 0.

9.00 10.00

7 JHL MSD4 1. 00

11.00

I .• ··• I··

'

.

. ..

.

12.00.

Page: 2

188/224

Revised Report

188/224



D:\Hpchem\1\Data\VMS3596\0424408.D 24 Apr 2015 2:28 pm CCAPX9

RTE Apr 24 15:04:24 2015

Vial: 8 Operator: JHL Inst MSD4 Multiplr: 1.00

Quant Method D:\Hpchem\Methods\APIX-W\VMS3596.M Quant Title VMS2575 8260 APX9-W ICAL

ztf) ~tLE CA1.4&MT/O"' \(EAII'ICitT""

EJI= &we 5-r~ MllC..

~ CDr><-)S ~(J($b e J)lff'EJ.!N( QLast Update Fri Apr 24 14:16:23 2015 Response via Initial Calibration DataAcq Meth:MSD4_ACQ.M ~'"'~··· N/UIT CQ.(" VStb M 1{.\1'



13) 1-chloro-3-fluorobenze .. . 15) 1,2-dichlorobenzene-04 .. .



14) 4-bromofluorobenzene

5.189 7.818 9.520

70 95

152

65 140 98 117 95


4.870 Range 64

6.747 Range 82 -

8.736 Range 85 - 115

Target Compounds 2) Allyl chloride 2.213 76 3) Acetonitrile 2.768 40' 4) Chloroprene 5) Methacrylonitrile ~

2.977 53 4.795 41

6) Isobutyl alcohol 5.125 43 7) Methyl methacrylate~ 6.188 41 9) Ethyl methacrylate 7.363 69

10) Propionitrile 4.775 54 11) 1,4-Dioxane 6.194 88 16) Pentachloroethane 9.095 167

37070 68841 70277

30.00 ppb '30.00 ppb 30.00 ppb

0.00 0.00 0.00


176196 30.20 Recovery

75780 30.15 Reco:very

6567 5.00 14706 134.29 17514 5.07 36601 • 27.58 36510 605.71

109471 .. 63.57 11854 5.20 33031 124.20 26609 2190.33

2615 3.36

ppb 99.57%

ppb 100.67% ppb 100.50%

0.00 v 0. 00 w-0. 00 ~l~'S'

~value ppb t 100 ppb/ 96 ppb ./ 98 ppb/ t 98 ppb ;:::- 98 ppb 97 ppb./ 96 ppb/..,.. 100 ppb;/' 98 ppb 93


• /f1Grlflt~J.QI(trtt.Jt6 s.l'uC&'I> <2. 25ff"" /fl "riftS

• rvfemr MEft(tf<P( ure jft,r4P @ t,o ffM .. tN 71/1'

VMS3596.M Fri Apr 24 15:04:25 2015

~ ... ,~ f!t,Mttfu.'( s..~) $ttJMI<-E (NfWHII"t.V'/ 5 f'fil-t)

Page: 1

189/224

Revised Report

189/224



D:\Hpchem\l\Data\VMS3596\0424408.D 24 Apr 2015 2:28 pm CCAPX9

RTE Apr 24 15:04:24 2015


Abundance :TIC: 0424408.D\data.ms

580000

560000

540000

520000

500000 '!l ,· "' v

480000 • c • N c

460000 • ~ e i 0 ,

440000 :\

" .Q

420000 ~ 400000

380000 "'· 2 ~

i '? 360000 • c • • ,

~ :;; 340000 E

~ i· 320000 (\ .. • c 300000 • X

.Q

280000 '!l ,· "' 260000 v • c • N c

240000 ll • 0

220000 if i

200000 • ' 180000

160000 "'·

140000 i! ·= =

120000 i • 100000 '" -~ ']0

" • -~ 0 .; 1l • 80000 ~ c e ~

'C • • .. ~

=<: c. E ·E ~ "' 60000 ~ g- 5

~ ~" w

40000

20000 l l ! 0 T ime--> 1.00 2.00 3.00 4.00 5.00 6.00 7.00 i 8.00

VMS3596:M Fri Apr 24 15:04:25 2015

~ c • ~ • ~ e 0 , ';; E • ~

I

.

Vial: Operator: Inst Multlplr:

'!l A

"' v v

" • c

.

.

• c • 5 • • ~ 0 s c • a.

9.00 10~00

8 JHL MSD4 1.00

-----.-,-----.-,-:. -.-:-;----y.~·~'::·--

...

·. ···.·

I

,•,

... · .

. . .· .. 11.00 . . . 12~00

Page: 2

190/224

Revised Report

190/224


BFB

D:\Hpchem\l\Data\VMS3597\ 0424409.0 24 Apr 2015 3:02pm JHL TUNE



Method D:\Hpchem\Methods\8260-W\VMS3595.M Title VMS3595 8260/6200/624 Water ICAL Last Update Fri Apr 24 11:45:19 2015

fbundance TIC: 0424409.0\data.ms

400000

300000 I

200000 I 100000

0 frime--> 6.80 7.00 7.20 7.40 7.60 7.80 8.00 8.20 8.40 8.60 8.80 9.00 9.2o 9.40 9.60 9.80 10.00 10.20 10.40 10.60

. fl\b"'lllllll\'6' Average of 8.736 to 8.741 min.: 0424409.0\data.ms (-) 95.1

174.0

60000

40000 75.1

:

20000 50.1

3~,0 6~? II 11 8~ 1o 142.9

0 I' 105.9 116.9 129.8 154.8

mlz--> 3'o 40 50 60 7'o 80 90 100 110 1zo 130 140 150 1so 170 180


I Target I Rel. to I Lower I Upper Rel. Raw Result I Mass I Mass I Limit% I Limit% Abn% Abn Pass/Fail ----------------------------------------------------------------------I 50 95 15 40 17_4 13336 PASS I 75 95 30 60 47'. 1 36035 PASS,. I 95 95 100 100 100.0 7657 9 PASS I 96 95 5 9 6.6 5050 PASS I 173 174 0.00 2 0.7 435 PASS I 174 95 50 100 87.3 66864 PASS I '·175 174 5 9 7.1 4769 PASS I 176 174 95 101 97.4 65112 PASS I 177 176 5 9 6.5 4242 PASS ----------------------------------------------------------------------

/

~.~

VMS3595.M Fri Apr 24 16:46:27 2015 Page: 1

191/224

Revised Report

191/224




RTE Apr 24 16:46:35 2015


10 JHL MSD4 1. 00










5.186 7.818 9.520

4. 8 67 Range 64,-

6.746 Range 82 -

8.736 Range 85 -

70 95

152

65 140 98 117 95 115

2.215 76, 2.763 40' 2.974 53 ;4.792 41 5.122' 43 6.188 41 7.363 69 .4.772 54 6.196- 88 9.095 167

35929 65892 67174

47555

30.00 ppb 30.00 ppb 30.00 ppb

30.08

0.00 0.00 0.00

0.00 Recovery

ppb 100.27% ppb 100.13% ppb 100.67%

0.00 / 169869 30.04 Recovery


5755 7614

15406 59495

7458 7593

10525 21386

3074 3004

4.52 ppb 71.73 ppb

4.61 ppb 4 6. 2 6 ppb

128.65 ppb 4.55 ppb 4.76 ppb

82.97 ppb 255.24 ppb

4.03 ppb

0. 00 1~;,, Qvalue

98 93 98 99 96 98 98 99 97 96


"

VMS3596.M Fri Apr 24 16:46:35 2015 Page: 1

192/224

Revised Report

192/224

Quantitation Report· (Not Reviewed)

Da.ta File Acq On Sample Mise Integrator: Quant Time:

D:\Hpchem\1\Data\VMS3597\0424410.D 24 Apr 2015 3:29pm ·• CCAPX9 .

RTE Apr 24 16:46:35 2015

Quant Method D:\Hpchem\Methods\APIX-W\VMS3596.M Quant Title VMS2575 8260 APX9-W ICAL QLast Update Fri Apr 24 14:16:23 2015 Re'Spon-se via Initial Calibration DataAcq Meth:MSD4_ACQ.M

!Abundance TIC: 0424410.0\data.ms 560000

r 540000

520000 ' ' 500000

"" ' 480000 :•! "' ; v • c

460000 • ~ ll e

440000 I' 0 , ! :\

" 420000 . ' ~ '( l

400000

380000 ... 360000 "' ro

~ • 340000 c ~

I :s ' 320000

: .300000 l

I

280000

"' 260000 -;:- ... "' v •

240000 c • N c • D

220000 e !' 0 0 ~

20000'0 .

' 180000 ~

160066 c B

"' 0

i !'' 140000

c

120000 ~ § '

! ' 100000 :.m . t • 80000

0 ' f;

1'! • !! ' ·~ c ·c " ) B . ~ E

60000 ;; 'S e ~ ~

~ '§ :§ i " f' 40000 .. J 20000 1 L Jl 0

ime--> • 1. 00 2.00 3.00 4.00 5.00 6.00 : 7.00. 8.00' - ' VMS3596,M Fri Apr 24 16:46:36 2b1·5:

~ c • N c ll e 0 , 'E E e D ..

I

'

I


.

"" ' "' v <l ~

.

• c • t ~ 0

11 • a.

9.00 10.00

10 JHL MSD4 1. 00

11.00

· ...

; . .• .

' • ••• 1:

.• ···,·I,

I

..... •

12.00

Page: 2

193/224

Revised Report

193/224




RTE Apr 27 12:24:56 2015

Quant Method D:\Hpchem\Methods\APIX-W\VMS3596.M Quant Title VMS3596 8260 APX9-W ICAL QLast Update Fri Apr 24 14:16:23 2015 Response via Initial calibration DataAcq Meth:MSD4_ACQ.M


10 JHL MSD4 1.00

Compound R.T. Qion Response Cone Units Dev{Min)


13) 1-chloro-3-fluorobenze .. 7.818 95 65892 30.00 ppb 0.00 15) 1,2-dichlorobenzene-04. 9.520 152 67174 30.00 ppb 0.00

System Monitoring Compounds 8) 1,2-dichloroethane-d4 4.867 65 47555 30.08 ppb 0.00

30.000 64 - 140 100.27% ./ Spiked Amount Range Recovery 12) toluene-dB 6.746 98 1698 69 30.04 ppb

: ::vt/6 Spiked Amount 30.000 Range 82 117 Recovery 100.13%

14) 4-bromofluorobenzene 8.736 95 72648 30.20 ppb Spiked Amount 30.000 Range 85 - 115 Recovery 100.67%

Target Compounds Qvalue 2) Allyl chloride 2.215 76 5755 4.52 ppb 98 3) Acetonitrile 2.763 40 7614 71.73 ppb 93 4) Chloroprene 2.974 53 15406 4.61 ppb 98 5) Methacrylonitrile 4.792 41 59495 4 6. 26 ppb 99 6) Isobutyl alcohol 5.122 43 7458 128.65 ppb 96 7) Methyl methacrylate 6.188 41 7593 4.55 ppb 98 .9) Ethyl methacrylate 7.363 69 10525 4.76 ppb 98


{#) = qualifier out of range {m) = manual integration {+) = signals summed

VMS3596.M Mon Apr 27 12:24:57 2015 Page: 1

194/224

Revised Report

194/224



D:\Hpchem\1\Data\VMS3597\0424410.D 24 Apr 2015 3:29pm CCAPX9

RTE Apr 27 12:24:56 2015


560000

540000

rbundance TIC: 0424410.D\data,ms

520000

500000

"' ,· 480000 "' v

• c • 460000 N c • ~ • 440000 0 , ;1:

" 420000 :§ J.

400000

380000

360000 "' "' 'l 340000 c •

~ 320000

300000

280000

"' 260000 ,· "' v •

240000 ~ • I ~

220000 • 0 , u:

200000

180000 i

~ .t c

160000 0

~ ,2'>.

140000 i! c • 120000 >i e

.Q

·" I

100000 t 2

() ~

80000 0 • • 1'! •

~ c .s ·c " ~ 1 • .Q . ~ E 60000 u E § .,

~

~ ·;: :c

I ~

.Qu Ul

40000 ~

20000 ! Jl ! ! 0 imeMM> 1.00 2.00 3.00 4.00 5.00 6.00 7.00 8.00

VMS3596.M Mon Apr 27 12:24:57 2015

"' • c ~ c • ~ • 0 , .. E e ~


"' ,· "' v ~

~ c

• c • ji e 0

" 0

~ • ~

9.00 10.00

10 JHL MSD4 1.00

11.00

!

12.00

Page: 2

Tune Data

SW-846 8260B


195/224

Revised Report

195/224

Volatile Organic Instrument Performance Check Form 5



Instrument: MSD9

Filename: 0424409.D

m/e Ion Abundance Criteria % Relative Abundance

Bromofluorobenzene (BFB)

Analyst: JHL

50 15.0 - 40.0% of mass 95 17.40

75 30.0 - 60.0% of mass 95 47.10

95 Base peak, 100% relative abundance 100.00

96 5.0 - 9.0 of mass 95 6.60

173 Less than 2.0% of mass 174 0.70

174 50.0 - 100% of mass 95 87.30

175 5.0 - 9.0% of mass 174 7.10

176 95.0 - 101% of mass 174 97.40

177 5.0 - 9.0% of mass 176 6.50

Client Sample ID Lab Sample ID Analysis Date

LCS for HBN 74466 [VXX/5659] 165933 04/24/15 17:01

LCSD for HBN 74466 [VXX/5659] 165934 04/24/15 17:28

MB for HBN 74466 [VXX/5659] 165935 04/24/15 18:22

GMA4-8-042015 31500724001 04/24/15 21:04

H78B-16-042015 31500724005 04/24/15 21:31

GMA4-75-042015 31500724006 04/24/15 21:58

GMA4-EB-042015 31500724007 04/24/15 22:24

Dup-1-042015 31500724009 04/24/15 22:51

GMA4-8-042015 MS 31500724002 04/25/15 1:33

GMA4-8-042015 MSD 31500724003 04/25/15 2:00


196/224

Revised Report

196/224

197/224

Revised Report

197/224

Data Path Data File Ac q On Op era tor Sa mple Ml sc AL s Vial

: : : : :

BFB

D:\Hpc~em\1\Data\VMS3597\ 0424409 D 24 Apr 2015 JHL TUNE

3:02pm

9 Sanple Multiplier: 1

Integration File: teint.p

Method : D:\Hpcrem\Methods\8260-W\VMS3595.M Title : VMS359' 8260/6200/624 Water ICAL Last Update : Fri Apr 24 11:45:19 2015

l'lbund-an_c_e---·----f-----.. -------~T"'IC":"'0424409D\data.ms

400000

·-··--·-·-]

I I

300000

200000

100000

OY,-m"'Tm"'Tm-rf-m': bP'~II' ), . ~ b : ' : ~ ' I " ' I ' ' I ' I ' I • ime·-> 6.80 7.00 7.20 7.~0 7.60 7.80 8.00 8.20 SAO 8.60 8.80 9.00 9.20 9.40 9.60 9.80 10.00 10.20 10.40 10.60

f'lbu'lllillllil' Average of 8.73~r 8.741 min: 0424409.0\data.ms (·)

174.0

60000

I 40000 75.1

20000 50.


I Target I Rel. to I Lower I Upper I Rel. I Raw I Result I I Mass I Massi I Llmit% I Limit% I Abn% I Abn I Pass/Fail I

~---;~---~----~~---~----~;--~----;~--~--~;~;--~----~;;;~-~---~;~~----~ I 75 I 95 I 30 I 60 I 47.1 I 36035 I PASS I I 95 I 9~ I 100 I 100 I 100.0 I 76579 I PASS I I 96 I 95 I 5 I 9 I 6.6 I 5050 I PASS I I 173 I 17~ I 0.00 I 2 I 0.7 I 435 I PASS I I 174 I 9~ I 50 I 100 I 87.3 I 66864 I PASS I I 175 I 171 I 5 I 9 I 7.1 I 4769 I PASS I I 176 I 17J I 95 I 101 I 97.4 I 65112 I PASS I

'--'''---'---''1---'-----' -'-----' -'---'''--'------''''-' ___ c'''----'

/ (Jw) tf, l7·t(

VMS3595.M Mon Apr 21 08:22:49 2015 Page: 1

Volatile Organic Instrument Performance Check Form 5



Instrument: MSD4

Filename: 0427401.D

m/e Ion Abundance Criteria % Relative Abundance

Bromofluorobenzene (BFB)

Analyst: BWS

50 15.0 - 40.0% of mass 95 18.20

75 30.0 - 60.0% of mass 95 47.70

95 Base peak, 100% relative abundance 100.00

96 5.0 - 9.0 of mass 95 6.80

173 Less than 2.0% of mass 174 0.70

174 50.0 - 100% of mass 95 82.70

175 5.0 - 9.0% of mass 174 7.20

176 95.0 - 101% of mass 174 97.00

177 5.0 - 9.0% of mass 176 7.20

Client Sample ID Lab Sample ID Analysis Date

LCS for HBN 74748 [VXX/5662] 166017 04/27/15 8:45

LCSD for HBN 74748 [VXX/5662] 166018 04/27/15 9:11

MB for HBN 74748 [VXX/5662] 166019 04/27/15 10:31

Cooler 6 Trip Blank 31500724008 04/27/15 12:12

GMA4-9-042015 31500724004 04/27/15 16:36

2A-042115 MS 31500725006 04/27/15 19:46

2A-042115 MSD 31500725007 04/27/15 20:13


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Revised Report

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Revised Report

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Data Path Data File Acq,Qn Operator Sample Mise ALS Vial

BFB

D:\Hpchem\1\Data\VMS3598\ 0427401.0 27 Apr 2015 7:51 am BWS TUNE



Method D:\Hpchem\Methods\8260-W\VMS.3595.M Title VMS3595 8260/6200/624 Water ICAL Last Update : Fri Apr 24 11:45:19 2015

.. TIC: 042740(0\data.ms rbundance

1000000 I

800000 I

'

600000

400000

200000

0 ' ~l ' " .

ime--> 6.80 7.00 7.20 7AO 7.60 7.80 8,00 8.20 8.40 8.60 8.80 9.00 9.20

.. . -- -------

' 9.so 9AO 9,60 10.00 10.20 10AO 10.60

Abundance Average of 8.733 to 8.738 min.: 0427401.0\data.ms (·)

I 9q.1

150000 174.0

100000 75.1

50000 50.1

37.~ II ,II 1330 193.0 207.1 220.9 235.0 249.1 265.1 0-::c'~' ~,,,, 106.911~.0 . 147.9 16?.9 -.-n'r mlz--> 30 40 so 60 70 80 90 100 1·1o 120 130 140 1so 160 170 1il0 190 200 210 220 230 240 250 260 270

AutoFind: Scans 27 69' 2770, 2771; Background Corrected with Scan 2760

I Target I Rel. to I Lower I Upper Rel. Raw Result I Mass I Mass I Limit% I Limit% Abn% Abn Pass/Fail ----------------------------------------------------------------------

50 95 15 40 18.2 31640 PASS 75 95 30 60 47.7 83139 PASS 95 95 100 100 100.0 174293 PASS 96 95 5 9 6.8 11879 PASS

173 174 0.00 2 0.7 970 PASS 174 95 50 100 82.7 144184 PASS 175 174 5 9 7.2 10359 PASS 176 174 95 101 97.0 139893 PASS 177 176 5 9 7.2 1004 6 PASS

----------------------------------------------------------------------

/ !J~J ~-t l·tl"

VMS3595.M Mon Apr 27 09:05:45 2015 Page: 1

Continuing Calibration Data

SW-846 8260B


200/224

Revised Report

200/224

Instrument ID: MSD4 Calibration Date: 04/24/15 Time: 15:56

Lab File ID: 0424411.D Init. Calib. Date: 04/22/15

EPA Sample No.: QCK010 Init. Calib. Time: 21:38

Heated Purge: (Y/N) Y


ICAL CCAL MAXRRF RRF %D0.828 0.8232.73 2.7290.869 0.9470.722 0.7323.63 3.5541.81 1.787 20.02.75 2.7390.714 0.7120.252 0.2680.801 0.7872.77 2.7850.114 0.1180.782 0.7981.55 1.5281.00 1.0001.00 1.0002.35 2.3772.11 2.084 20.02.78 2.7881.64 1.5841.48 1.5041.63 1.6090.008 0.005*1.00 1.0001.00 1.0002.34 2.4220.729 0.7420.183 0.1830.842 0.8270.543 0.5721.09 1.0980.939 1.1030.858 0.8442.68 2.7161.42 1.5120.465 0.4460.076 0.0640.275 0.2840.544 0.5600.911 0.961

acrylonitrile -3.0Allyl chloride -5.5

Acetonitrile 16.3acrolein -3.3

4-methyl-2-pentanone -6.7acetone 4.1

4-chlorotoluene 1.64-isopropyltoluene -1.3

4-bromofluorobenzene -0.74-bromofluorobenzene -17.4

2-chlorotoluene 1.82-hexanone -5.4

2-butanone -1.72-chloroethyl vinyl ether -0.0

1-chloro-3-fluorobenzene <I 0.02,2-dichloropropane -3.7

1,4-Dioxane 31.91-chloro-3-fluorobenzene 0.01,2-dichlorobenzene-D4 <IS> 0.0

1,2-dibromoethane -2.01,2-dichlorobenzene 1.3

1,2,4-trimethylbenzene -0.61,2-dibromo-3-chloropropane -2.8

1,2,3-trichloropropane -6.61,2,4-trichlorobenzene 1.8

1,1-dichloropropene 0.41,2,3-trichlorobenzene 0.2

1,1-dichloroethane 0.10 2.21,1-dichloroethene 1.1

1,1,2,2-tetrachloroethane 0.30 -9.01,1,2-trichloroethane -1.5

1,1,1,2-tetrachloroethane 0.61,1,1-trichloroethane -0.0

7A

VOLATILE CONTINUING CALIBRATION CHECK

MINCOMPOUND RRF %D

page 1 of 2 FORM VII VOA-1 0LM04.2

201/224

Revised Report

201/224

ICAL CCAL MAXRRF RRF %D7.985 7.8950.970 0.9701.087 1.1222.253 2.2210.445 0.4441.402 1.4055.056 4.8312.142 2.1242.557 2.5211.170 1.3453.339 3.341 20.02.445 2.4302.394 2.5732.047 2.0392.916 2.9460.807 0.8161.280 1.2741.039 1.0582.265 2.2766.128 5.9341.582 1.7581.289 1.275 20.01.000 1.0001.000 1.0000.324 0.3152.949 2.7950.038 0.0253.738 3.7001.541 1.5060.920 0.9941.195 1.2682.010 2.0055.047 5.0702.217 2.2774.227 4.2311.727 1.7391.493 1.446

1.30 1.3171.09 1.0984.75 4.767

4-bromofluorobenzene -0.7toluene-d8 -0.2

o-xylene 3.1

1,2-dichloroethane-d4 -1.1

n-propyl benzene -0.1naphthalene -0.7

MTBE -0.5n-butylbenzene -2.7

Methyl methacrylate -6.1methylene chloride 0.3

m/p-xylene 2.2Methacrylonitrile -7.9

Isobutyl alcohol 34.5isopropylbenzene 1.0

hexachlorobutadiene 3.0iodomethane 5.2

Fluorobenzene <IS> 0.0Fluorobenzene <IS> 0.0

Ethyl methacrylate -11.1ethylbenzene 1.1

dichlorodifluoromethane -0.5DIPE 3.2

dibromofluoromethane 0.5dibromomethane -1.8

cis-1,3-dichloropropene -1.0dibromochloromethane -1.2

Chloroprene -7.5cis-1,2-dichloroethene 0.4

chloroform -0.0chloromethane 0.10 0.6

chlorobenzene 0.30 1.4chloroethane -14.9

carbon disulfide 4.4carbon tetrachloride 0.9

bromoform 0.10 0.3bromomethane -0.2

bromochloromethane -3.2bromodichloromethane 1.4

benzene 1.1bromobenzene 0.0

7A


MINCOMPOUND RRF %D


202/224

Revised Report

202/224

BATCH: VMS3597 Date Analyzed: 04/24/15

Filename: 0424411.D Instrument: MSD4

ICAL Batch: VMS3595

Compound TV (ug/L) Result (ug/L) %Driftacetone 50 52.93 5.92-chloroethyl vinyl ether 250 232.60 -7.0bromoform 10 9.40 -6.0

Results for 8260 CCV

Page 1 of 1203/224

Revised Report

203/224

204/224

Revised Report

204/224


E~aluate Contlnuing Callbration

D:\Hpcher\l\Data\VMS3597\04244ll.D 24 Apr 2015 3:56 pm QCK010

Integrator: RTE Quant Time: Apr 27 0'8:23:25 2015

Quant Method : D:\Hp~bhem\Methods\8260-W\VMS3595.M Quant Title : VMS3595 8260/6200/624 Water ICAL QLast Update : Fri A r-24 11:45:19 2015 Response via : Initial Calibration DataAcq Meth:MSD4 AC .M

Report


11 JHL MSD4 1. 00



80% Max. R.T. Dev 0.50min 120%

1 IS 2 T 3 TP 4 TC 5 T 6 T 7 T 8 T 9 TC

10 T 11 T 12 T 13 T 14 T 15 TP 16 T 17 T 18 T 19 T 20 T 21 TC 22 T 23 T 24 s 25 T 2 6 s 27 T 28 T 29 T 30 TC 31 T 32 T 33 T 34 T 35 T 36 s 37 TC 38 T 39 T 40 T 41 T

Compound

Fluorobenzene <IS> dichlorodifl~oromethane chloromethane vinyl chlorile bromomethane chloroethane trichlorofluolromethane acrolein 1,1-dichloroe~thene acetone methylene chloride trans-1,2-di

1

hloroethene acrylonitrile MTBE I

1,1-dichloroJthane DIPE 2,2-dichloro ropane cis-1,2-dich~oroethene 2-butanone I

bromochlorom~thane

chloroform _1 1,1,1-trichl~roethane

carbon tetradhloride dibrornofluor9methane 1,1-dichloro~ropene

1,2-dichloro~thane-d4

benzene _I

1,2-dichloroethane trichloroethdne 1,2-dichloro~ropane dibromomethaiJe bromodichlor~methane 2-chloroethy vinyl ether cis-1,3-dich oropropene 4-methyl-2-p ntanone toluene-dB toluene iodomethane trans-1,3-di ,hloropropene Vinyl acetat carbon disul ide

42 IS 1-chloro-3-f uorobenzene <I 43 T 1,1,2-trichl ,roethane 44 T tetrachloroelhene 45 T 1,3-dichloro,ropane 46 T 2-hexanone 47 T dibromochlor,rnethane 48 T 1,2-dibromoe~hane

49 TP chlorobenzen~ 50 T 1,1,1,2-tetr,chloroethane

VMS3595.M Mon Apr 27 ~8:23:49 2015

AvgRF

1.000 2.265 2.445 2.581 1.402 1.170 2.776 0.275 1.807 0. 4 65 2.010 2.037 0.544 5.047 3.634 6.128 2.336 2.047 0.729 1.087 3.339 2.728 2.142 1.280 2.750 1.303 7.985 2.348 2.006 2.108 1.039 2.253 0.183 2.916 1.417 4.755 4.585 2.949 2.277 3.279 5.056

1.000 0.722 1.043 1.478 0.543 0.807 0.782 2.557 0.828

CCRF

1.000 2.276 2.430 2.519 1.405 1.345 2.879 0.284 1.787 0.446 2.005 2.011 0.560 5.070 3.554 5.934 2.422 2.039 0.742 1.122 3.341 2.729 2.124 1.274 2.739 1.317 7.895 2.377 1.929 2.084 1.058 2.221 0.183 2.946 1.512 4.767 4.537 2.795 2.310 4.087 4.831

1.000 0.732 1.051 1.504 0.572 0.816 0.798 2.521 0.823

%Dev Area% Dev(rnin)

0.0 -0.5 0.6 2.4

-0.2 -14.9 -3.7 -3.3 1.1 4 . 1 0.3 1.3

-3.0 -0.5 2.2 3.2

-3.7 0.4

-1.7 -3.2 -0.0 -0.0 0.9 0.5 0.4

-1.1 1.1

-1.2 3.9 1.2

-1.8 1 . 4

-0.0 -1.0 -6.7 -0.2 1.0 5.2

-1.5 -24.6#

4 . 4

0.0 -1.5 -0.8 -1.7 -5.4 -1.2 -2.0 1.4 0.6

99 94 94 94 95

104 96

103 97

104 98 99

101 102

97 98

102 98

106 100

98 97 96 98 99

100 98

101 96 98

101 97

103 99

107 98 98 93 99

120# 95

99 101

99 102 106

99 102

98 97

0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 o .'oo 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00

0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00

Page: 1

205/224

Revised Report

205/224


Etaluate Continulng Callbration

D:\Hpche~\l\Data\VMS3597\042441l.D 24 Apr 2115 3:56pm QCKOlO

RTE Quant Time: Apr 27 0 :23:25 2015


D:\Hpfhem\Methods\8260-W\VMS3595.M VMS35 5 8260/6200/624 Water ICAL Fri A r-24 11:45:19 2015


Min. Max.

RRF RRF Dev

0.0 0 20%

Min. Max.

Rel. Area Rel. Area

80% 120%

Max.

Compound AvgRF CCRF

51 52 s 53 T 54 55 T

TP

TP

56 IS 57 TC 58 T 59 T 60 T 61 T 62 T 63 T 64 T 65 T 66 T 67 T 68 T 69 T 70 T 71 T 72 T 73 T 74 T 75 T 76 T 77 T 78 T 79 T

bromoform 4-brornofluoro brornobenzene

enzene

1, 1, 2, 2-tetra1

hloroethane 1,2,3-trichlo~opropane

1,2-dichloroblnzene-04 <IS> ethylbenzene rn/p-xylene styrene a-xylene isopropylbenzene n-propyl benzene 2-chlorotoluene 4-chlorotoluene 1,3,5-trimethylbenzene tert-butylbe~lzene 1,2,4-trimet ylbenzene sec-butylbenzene 1,3-dichloro~enzene 4-isopropyltjluene 1,4-dichloro~enzene 1,2-dichloro9enzene n-butylbenze:Je 1,2-dibrorno-~-chloropropane

1,2,4-trichl9robenzene hexachlorobu1adiene naphthalene trans-1,4-Diahloro-2-butene 1,2,3-trichl9robenzene

0.445 1.090 0.970 0.869 0.252

1.000 1. 289 1.541 2.375 1.493 3.738 4.227 0.842 0.858 2.778 2.350 2. 767 3.357 1.636 2.680 1. 628 1.548 2.217 0.114 0.801 0.324 1.727 0.239 0.714

0.444 1.098 0.970 0.947 0.268

1.000 1.275 1.506 2. 392 1. 44 6 3.700 4.231 0.827 0.844 2.788 2.317 2.785 3.381 1. 584 2.716 1.609 1.528 2.277 0.118 0.787 0.315 1.739 0.258 0.712

Report


R.T. Dev

11 JHL MSD4 1.00

0.50min

%Dev Area% Dev(min)

0.3 -0.7

0.0 -9.0 -6.6

0.0 1 . 1 2.2

-0.7 3.1 1.0

-0.1 1 . 8 1.6

-0.4 1. 4

-0.6 -0.7 3.2

-1.3 1.2 1.3

-2.7 -2.8 1.8 3.0

-0.7 -8.1

0.2

100 99

100 108 105

101 99 97 98 96 98 99 99 99 99 99 99 99 98 99 99

101 100 106 101 100 104 110 103

0.00 0.00 0.00 0.00 0.00

0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00

--------------------l-----------------------------------------------------

(#) =Out of Rang SPCC's out= 0 CCC's out=/

/

/

VMS3595.M Mon Apr 27 18:23:49 2015 Page: 2

206/224

Revised Report

206/224

duantitation Report (Not Reviewed)


D:\Hpche \1\Data\VMS3597\0424411.D 24 Apr 2015 3:56 pm QCK010


Vi<Jl: Operator: Inst Multiplr:

11 JHL MSD4 1.00

Quant Method : D: \Hplchem\Methods\8260-W\VMS3595 .M Quant Title : VMS3595 8260/6200/624 Water ICAL QLast Update : Fri Aipr-24 11:45:19 2015 Response via : Initilal Calibration DataAcq Meth:MSD4_ACQ.M






Spiked Amount 30.000 36) toluene-dB Spiked Amount 30.000


Target Compounds 2) dichlorodifluoromethane 3) chloromethane 4) vinyl chloride 5) bromomethane 6) chloroethane 7) trichlorofluorkomethane 8) acrolein 9) 1,1-dichloroet ene

10) acetone 11) methylene chloride 12) trans-1,2-dichloroethene 13) acrylonitrile 14) MTBE 15) 1,1-dichloroet ane 16) DIPE 17) 2,2-dichloropropane 18) cis-1,2-dichloboethene 19) 2-butanone t 20) bromochloromet ane 21) chloroform 22) 1,1,1-trichlorol ethane 23) carbon tetrach~oride 25) 1,1-dichloropro~pene 27) benzene 28) 1, 2-dichloroetl ane 29) trichloroethen 30) 1,2-dichloroprbpane 31) dibromomethanel-

5.189 7.818 9.520

70 95

152

113 118 65

- 130

4.245 Range 86 -

4.870 Range 64

6.746 Range 82

8.738 Range 85 -

98 - 117

95 115

85 50 62 96 64

101 56 96 43 84 96 53 73 63 45 77 96 43

130 83 97

32) bromodichlorom~thane 33) 2-chloroethyl flnyl ether 34) cls-1,3-dichlofopropene

1.007 1.119 1.165 1.358 1.441 1.527 2.117 1. 862 2.357 2.299 2.429 3.081 2.545 3.009 2. 922 3.750 3.619 4.445 3.868 4.005 4.236 4.135 4.398 4.699 4.948 5.365 5.895 5.791 5.982 6.567 6.584 7.169 6.790 1.960 7.184 3.321 1.876 7.317 7.120

117 75 78 62 95 63 93 83

106 75 43 92

35) 4-methyl-2-pen anone 37) toluene 38) lodomethane 39) trans-1,3-dich oropropene 40) V1nyl acetate 41) carbon d1sulfl~e 43) 1,1,2-trlchlor~ethane 44) tetrachloroethene

VMS3595.M Mon Apr 27 ob:23:26 2015

142 75 43 76 83

166

37236 68960 71022

47429 Recovery

30.00 ppb 30.00 ppb 30.00 ppb

29.86 ppb

49055 30.33 99.53%

ppb 101.10% ppb 100.23% ppb 100.70%

Recovery 177509 30.07

Recovery 75717 30.21 Recovery

0.00 0.00 0.00

0.00 /

0.00

o.oo/

0.00

28247 30158 31270 17434 16689 35730 88104 22175 27655 24884 24963

10.05 ppb 9.94 ppb 9.76 ppb

10.02 ppb 11.49 ppb 10.37 ppb

Qvalue 99 99 99 99

173893 62929 44108 73654 30058 25302 4 6049 13928 414 67 33868 26357 33996 97997 29499 23944 258 62 13132 27573 56653 36567 93844 56318 34 694 28669

126823 59966 16837 24149

258.15 ppb 9.89 ppb

52.93 ppb 9.97 ppb 9.87 ppb

257.52 ppb 10.05 ppb

9.78 ppb 9.68 ppb

10.37 ppb 9.96 ppb

50.86 ppb 10.32 ppb 10.00 ppb 10.00 ppb

9.91 ppb 9.96 ppb 9.89 ppb

10.12 ppb 9.61 ppb 9.88 ppb

10.18 ppb 9. 8 6 ppb

232.60 ppb 10.10 ppb 53.37 ppb

9.90 ppb 9.48 ppb

10.15 ppb 31.16 ppb

9.56 ppb 10.15 ppb 10.08 ppb

100 95

100 99 98 96 98

100 98 98 99 99 98 99 96 99 98 99 99 99 98 98 99 97 98 99 99 99 96 99 98

100 99 97 98

Page: 1

207/224

Revised Report

207/224

1

QLantitation Report (Not Reviewed)

Data File D:\Hpche~\l\Data\VMS3597\0424411.D Acq On 24 Apr 2[15 3:56 pm Sample QCKOlO Mise Integrator: RTE Quant Time: Apr 27 08:23:25 2015

Quant Method : D:\Hp~hem\Methods\8260-W\VMS3595.M Quant Title : VMS35~5_8260/6200/624 Water ICAL QLast Update : Fri A r 24 11:45:19 2015 Response via : Initi l Calibration


11 JHL MSD4 1. 00

DataAcq Meth:MSD4_ACQ.M

Compound ~~ R.T. Qion Response Cone Units Dev(Min) -------------------t-----------------------------------------------------~

45) 1,3-dichloropropane 7.534 76 34561 10.17 ppb 100 46) 2-hexanone I 7.841 43 65747 52.70 ppb 100 47) dibromochloromethane 7.453 129 18768 10.12 ppb 98 48) 1,2-dibromoeth ne 7.618 107 18335 10.20 ppb 99 49) chlorobenzene 8.006 112 57941 9.86 ppb 99 50) 1,1,1,2-tetrac loroethane 8.058 131 18910 9.94 ppb 97 51) bromoform 8.440 173 10195 9.40 ppb 97 53) bromobenzene 8.788 156 22297 10.00 ppb 99 54) 1,1,2,2-tetrac loroethane 8.860 83 21775 10.90 ppb 97 55) 1,2,3-trichlor propane 8.924 110 6162 10.66 ppb 100 57) ethylbenzene 8.041 106 30181 9.89 ppb 98 58) rn/p-xylene 8.139 106 71323 19.55 ppb 99 59) styrene 8.434 104 56634 10.07 ppb 99 60) o-xylene 8.400 106 34243 9.69 ppb 94 61) isopropylbenze e 8.585 105 87596 9.90 ppb 99 62) n-propyl benze e 8.814 91 100161 10.01 ppb 99 63) 2-chlorotoluenf' 8.892 126 19569 9.82 ppb 97 64) 4-chlorotoluenro 8.982 126 19988 9.84 ppb 93 65) 1,3,5-trimethy~benzene 8.921 105 66014 10.04 ppb 98 66) tert-butylbenz~ne 9. 083 119 54858 9. 86 ppb 99 67) 1,2,4-trimethytbenzene 9.118 105 65928 10.06 ppb 99 68) sec-butylbenze e 9.173 105 80034 10.07 ppb 100 69) 1,3-dichlorobe zene 9.277 146 37492 9.68 ppb 97 70) 4-isopropyltol ene 9.245 119 64295 10.13 ppb 100 71) 1,4-dichlorobetzene 9.320 146 38089 9.88 ppb 98 72) 1,2-dichlorobe zene 9.526 146 36176 9.87 ppb 99 73) n-butylbenzene 9.448 91 53910 10.27 ppb 99 74) 1,2-dibrorno-3- hloropr. 9.899 75 16711 61.69 ppb 94 75) 1,2,4-trichlor~1 benzene 10.206 180 18626 9.82 ppb 95 76) hexachlorobuta iene 10.189 225 7447 9.70 ppb 100 77) naphthalene 10.357 128 41174 10.07 ppb 99 78) trans-1,4-Dich oro-2-b... 8.950 53 30576 54.03 ppb 95 79) 1,2,3-trichlor benzene 10.441 180 16861 9.98 ppb 98


VMS3595.M Mon Apr 27 01 :23:26 2015 Page: 2

208/224

Revised Report

208/224



D:\Hpchem\l\Data\VMS3597\04244ll.D 24 Apr 2015 3:56pm QCKOlO

RTE Apr 27 08:23:25 2015


550000

500000

jf!_me-->

VMS3595.M Mon Apr 27 08:23:26 2015

~ ~ " -~

J 1

i

I


'!! ,-"' " ~ ~ " • ~ e 0 , ~ §

~ "'-~ " ~ • , jj

11 JHL MSD4 1. 00

~-• c • ! E

"'-• " ~ " • ~ e 0 , 'jj E e " ~

'!! ,-"' " ~ ':i: " • N

" • ~ e

i ~ • ~ §

" f

I II I, i iII

I 1 I I 9.50 1 0_.0_0 __ 1QliQ..~=~~11~·~50~~12=.0~0~

Page: 3



ICAL Batch: VMS3596

Compound TV (ug/L) Result (ug/L) %DriftIsobutyl alcohol 250 128.65 -48.51,4-Dioxane 500 255.24 -49.0


Page 1 of 1209/224

Revised Report

209/224

210/224

Revised Report

210/224

Eva.luate con-c.1nu1ng \....ct.L.LJ.JLc:tL_l_ull );'._=!::-''-'-'--'-


D:\Hpchem\l\Data\VMS3597\0424410.D 24 Apr 2015 3:29 pm CCAPX9

Integrator: RTE Quant Time: May 21 09:10:17 2015



10 JHL MSD4 1.00



50% Max. R.T. Dev 0.50min 150%


1 IS 2 3 4 5 6 7 8 s 9

10 11 12 s

13 IS 14 s

15 IS 16

Fluorobenzene <IS> Allyl chloride Acetonitrile Chloroprene Methacrylonitrile Isobutyl alcohol Methyl methacrylate 1,2-dichloroethane-d4 Ethyl methacrylate Propionitrile 1,4-Dioxane toluene-dB

1-chloro-3-fluorobenzene Pentachloroethane

(#) ~ Out of Range

VMS3596.M Tue May 26 07:56:10 2015

1.000 0.911 0.076 2.394 0.920 0.038 1.195 1.131 1.582 0.184 0.008 4.047

1.000 0.939

1.000 0.277

1.000 0.961 0. 064 2.573 0.994 0.025 1.268 1.324 1.758 0.179 0.005 4.728

1.000 1.103

1.000 0.268

0.0 107 -5.5 96 16.3 79 -7.5 101 -7.9 99 34.5# 57 -6.1 97

-17.0 108 -11. 1 101

3.2 88 31.9# 58

-16.8 108

0.0 107 -17.4 108

0.0 108 3.2 93

SPCC's out= 0 CCC's out= 0

0.00 0.00 o:oo 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00

0.00 0.00

0.00 0.00

Page: 1

211/224

Revised Report

211/224

, Qrantitation Report (Not Reviewed)

Data File D:\Hpche~\1\Data\VMS3597\0424410.D Vial: 10 Acq On 24 Apr 2b15 3:29 pm Operator: JHL Sample CCAPX9 l Inst MSD4 Mise Multiplr: 1.00 Integrator: RTE

::::: :::::dA~rD~~H:l~:::::t::::\APIX-W\VMS3596.M Quant Title : VMS25f5 8260 APX9-W ICAL QLast Update : Fri Apr 24 14:17:48 2015 Response via : Initifl Calibration DataAcq Meth:MSD4 ACr.M

Compound R.T. Qion Response Cone Units Dev(Min) ~~~~~~~~-~~~~~~~~~-[------------------------------------------------------

1) Fluorobenzene fiS> 5.186 70 35929 30.00 ppb 0.00 13) l-chloro-3-fluorobenze. 7.818 95 65892 30.00 ppb 0.00 15) 1,2-dichlorobefzene-D4. 9.520 152 67174 3o.oo ppb o.oo

System Monitoring Compounds 8) 1,2-dichloroettane-d4 Spiked Amount 30.000


14) 4-bromofluorob nzene Spiked Amount 30.000

Target Compounds 2) Allyl chloride 3) Acetonitrile 4) Chloroprene 5) Methacrylonitr' le 6) Isobutyl alcoh· l 7) Methyl methacr, late 9) Ethyl methacry ate

10) Propionitrile 11) 1,4-Dioxane 16) Pentachloroeth ne

4.867 Range 64

6. 74 6 Range 82

8.736 Range 85

2.215 2.763 2.974 4.792 5.122 6.188 7.363 4.772 6.196 9.095

65 140 98 117 95 115

76 40 53 41 43 41 69 54 88

167


169869 30.04 Recovery


5755 4. 52 7614 71.73

15406 4 . 61 59495 4 6. 26

7458 128.65 7593 4.55

10525 4.76 21386 82.97

3074 255.24 3004 4.03

ppb 100.27% ppb 100.13% ppb 100.67%

0.00

0.00

0.00

Qvalue ppb 98 ppb 93 ppb 98 ppb 99 ppb 96 ppb 98 ppb 98 ppb 99 ppb 97 ppb %

------------------- ------------------------------------------------------


VMS3596.M Mon Apr 27 0::35:11 2015 Page: 1

/

212/224

Revised Report

212/224

uantitation Report (Not Reviewed)

Data File D:\Hpch m\1\Data\VMS3597\0424410.D Acq On 24 Apr 015 3:29 pm Sample CCAPX9 Mise Integrator: RTE Quant Time: Apr 27 8:35:11 2015

Quant Method D:\H chem\Methods\APIX-W\VMS3596.M Quant Title VMS2 75 8260 APX9-W ICAL QLast Update Fri pr 24 14:17:48 2015 Response via Init·al Calibration DataAcq Meth:MSD4 A' Q.M

~- bundance 560000

540000

520000

500000

480000

460000

440000

420000

400000

380000

360000

340000

320000

300000

280000

260000

240000

220000

200000

180000

160000

140000

120000

100000

80000

60000


* *

"' ,· "' v • c • ~ • D e g ::1

" 0

" J.

"' • c • N c • D e 0 , '5 E e D

"


j j

"' ,· "' v 11

" c

10 JHL MSD4 1.00

_1-~~~J

40000

20000

j_: i :i !

J~t.~. ,.Jl,-!h-jl.~.,.l',J·~·~,-~~~--,~ VMS3596.M Mon

2.00 ~ 4.00 5.00 6.00 -~_].00 __ 8,00 9.00 10.00 __ 11.00 12.00

Apr 27

1

08:35:12 2015 Page: 2

ICAL CCAL MAX

RRF RRF %D

0.828 0.866

2.73 3.327

0.869 0.827

0.722 0.689

3.63 4.330

1.81 2.161 20.0

2.75 3.233

0.714 0.672

0.252 0.228

0.801 0.785

2.77 2.919

0.114 0.100

0.782 0.725

1.55 1.516

1.00 1.000

1.00 1.000

2.35 2.621

2.11 2.457 20.0

2.78 2.925

1.64 1.645

1.48 1.406

1.63 1.652

0.008 0.006*

1.00 1.000

1.00 1.000

2.34 3.125

0.729 0.701

0.183 0.185

0.842 0.854

0.543 0.466

1.09 1.118

0.939 1.106

0.858 0.872

2.68 2.832

1.42 1.430

0.465 0.409

0.076 0.085

0.275 0.250

0.544 0.503

0.911 1.208

acrylonitrile 7.6

Allyl chloride -32.5

Acetonitrile -11.4

acrolein 8.9

4-methyl-2-pentanone -0.9

acetone 12.0

4-chlorotoluene -1.6

4-isopropyltoluene -5.7

4-bromofluorobenzene -2.5


2-chlorotoluene -1.4

2-hexanone 14.2

2-butanone 3.9

2-chloroethyl vinyl ether -1.1

1-chloro-3-fluorobenzene <I 0.0

2,2-dichloropropane -33.8

1,4-Dioxane 24.8

1-chloro-3-fluorobenzene 0.0

1,2-dichlorobenzene-D4 <IS> 0.0

1,2-dibromoethane 7.2

1,2-dichlorobenzene 2.1

1,2,4-trimethylbenzene -5.5

1,2-dibromo-3-chloropropane 12.3

1,2,3-trichloropropane 9.3

1,2,4-trichlorobenzene 2.1

1,1-dichloropropene -17.6

1,2,3-trichlorobenzene 5.9

1,1-dichloroethane 0.10 -19.1

1,1-dichloroethene -19.6

1,1,2,2-tetrachloroethane 0.30 4.9

1,1,2-trichloroethane 4.6

1,1,1,2-tetrachloroethane -4.6

1,1,1-trichloroethane -21.9

7A


MIN

COMPOUND RRF %D


213/224

Revised Report

213/224

ICAL CCAL MAX

RRF RRF %D

7.985 9.314

0.970 0.975

1.087 1.263

2.253 2.699

0.445 0.434

1.402 1.483

5.056 5.992

2.142 2.641

2.557 2.565

1.170 1.459

3.339 3.962 20.0

2.445 2.646

2.394 3.144

2.047 2.377

2.916 3.519

0.807 0.819

1.280 1.275

1.039 1.134

2.265 2.445

6.128 7.205

1.582 1.691

1.289 1.321 20.0

1.000 1.000

1.000 1.000

0.324 0.314

2.949 3.066

0.038 0.034

3.738 3.841

1.541 1.577

0.920 1.018

1.195 1.386

2.010 2.358

5.047 5.522

2.217 2.412

4.227 4.418

1.727 1.5131.493 1.498

1.30 1.243

1.09 1.118

4.75 4.992


toluene-d8 -5.0

o-xylene -0.3

1,2-dichloroethane-d4 4.6

n-propyl benzene -4.5

naphthalene 12.4

MTBE -9.4

n-butylbenzene -8.8

Methyl methacrylate -16.0

methylene chloride -17.3

m/p-xylene -2.3

Methacrylonitrile -10.6

Isobutyl alcohol 10.8

isopropylbenzene -2.7

hexachlorobutadiene 3.2

iodomethane -4.0

Fluorobenzene <IS> 0.0

Fluorobenzene <IS> 0.0

Ethyl methacrylate -6.9

ethylbenzene -2.4

dichlorodifluoromethane -8.0

DIPE -17.6

dibromofluoromethane 0.4

dibromomethane -9.2

cis-1,3-dichloropropene -20.7

dibromochloromethane -1.5

Chloroprene -31.3

cis-1,2-dichloroethene -16.1

chloroform -18.6

chloromethane 0.10 -8.2

chlorobenzene 0.30 -0.3

chloroethane -24.7

carbon disulfide -18.5

carbon tetrachloride -23.3

bromoform 0.10 2.3

bromomethane -5.8

bromochloromethane -16.2

bromodichloromethane -19.8

benzene -16.6

bromobenzene -0.4

7A


MIN

COMPOUND RRF %D


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ICAL Batch: VMS3595

Compound TV (ug/L) Result (ug/L) %Driftacetone 50 48.63 -2.72-chloroethyl vinyl ether 250 234.73 -6.1bromoform 10 9.22 -7.8


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D:\Hpchem\1\Data\VMS3598\0427402.D 27 Apr 2015 8:18am QCK010




2 BWS MSD4 1.00



80% Max. R.T. Dev O.SOmin 120%


1 IS 2 T 3 TP 4 TC 5 T 6 T 7 T 8 T 9 TC

10 T 11 T 12 T 13 T 14 T 15 TP 16 T 17 T 18 T 19 T 20 T 21 TC 22 T 23 T 24 s 25 T 26 s 27 T 28 T 29 T 30 TC 31 T 32 T 33 T 34 T 35 T 36 s 37 TC 38 T 39 T 40 T 41 T

42 IS 43 T 44 T 45 T 4 6 T 47 T 48 T 49 TP 50 T

Fluorobenzene <IS> dichlorodifluoromethane chloromethane vinyl chloride bromomethane chloroethane trichlorofluoromethane acrolein 1,1-dichloroethene acetone methylene chloride trans-1,2-dichloroethene acrylonitrile MTBE 1,1~dichloroethane DIPE 2,2-dichloropropane cis-1,2-dichloroethene _2-butanone bromochloromethane chloroform 1,1.,1-trichloroethane carbon tetrachloride dibromofluoromethane 1,1-dichloropropene 1,2-dichloroethane-d4 benzene 1,2-dichloroethane trichloroethene 1,2-dichloropropane dibromomethane bromodichloromethane 2-chloroethyl vinyl ether cis-1,3-dichloropropene 4-methyl-2-pentanone toluene-dB toluene iodomethane trans-1,3-dichloropropene Vinyl acetate carbon disulfide

1-chloro-3-fluorobenzene <I 1,1,2-trichloroethane tetrachloroethene 1,3-dichloropropane 2-hexanone dibromochloromethane 1,2-dibromoethane chlorobenzene 1,1,1,2-tetrachloroethane

VMS3595.M Mon Apr 27 09:06:24 2015

1.000 2.265 2.445 2.581 1.402 1.170 2.776 0.275 1.807 0.465 2.010 2.037 0.544 5.047 3.634 6.128 2.336 2.047 0.729 1.087 3.339 2.728 2.142 1.280 2.750 1.303 7.985 2.348 2.006 2.108 1.039 2.253 0.183 2.916 l. 417 4.755 4.585 2.949 2.277 3.279 5.056

1.000 0.722 1.043 1.478 0.543 0.807 0.782 2.557 0.828

1.000 2.445 2.646 2.715 1.483 1.459 3.145 0. 250 2.161 0.409 2.358 2.389 0.503 5.522 4.330 7.205 3.125 2.377 0.701 1.263 3.962 3.327 2.641 1. 275 3.233 1. 243 9.314 2.621 2.262 2.457 1.134 2.699 0.185 3.519 1.430 4.992 5.289 3.066 2.710 4.424 5.992

1.000 0.689 1.060 1.406 0.466 0.819 0.725 2.565 0.866

0.0 -8.0 -8.2 -5.2 -5.8

724.7# -13.3

8.9 -19.6

12.0 -17.3 -17.3

7.6 -9.4

-19.1 -17.6 -33.8# -16.1

3.9 -16.2 -18.6 -21.9# -23.3#

0.4 -17.6

4.6 -16.6 -11.6 -12.8 -16.5 -9.2

-19.8 -1.1

-20.7# -0.9 -5.0

-15.4 -4.0

-19.0 -34.9# -18.5

0.0 4.6

-1.7 4.9

14.2 -1.5 7.2

-0.3 -4.6

110 113 114 113 112 126# 117 101 131# 107 129# 131# 101 124# 132# 133# 147# 127# 111 125# 129# 132# 134# 109 130# 105 129# 124# 12 6# 128# 121# 132# 116 132# 113 115 128# 114 130# 145# 132#

125# 120# 127# 120# 110 126# 118 127# 129#

0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00

0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00

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D:\Hpchem\l\Data\VMS3598\0427402.D 27 Apr 2015 8:18 am QCKOlO


Quant Method D:\Hpchem\Methods\8260-W\VMS3595.M Quant Title VMS3595 8260/6200/624 Water lCAL QLast Update Fri Apr-24 11:45:19 2015 Response via Initial Calibration DataAcq Meth:MSD4_ACQ.M


2 BWS MSD4 1. 00



80% Max. R.T. Dev 0.50min 120%


51 TP bromoform 0.445 0.434 2.3 124# 0.00 52 s 4-bromofluorobenzene 1.090 1.118 -2.5 128# 0.00 53 T brornobenzene 0.970 0.975 -0.4 127# 0.00 54 TP 1,1,2,2-tetrachloroethane 0.869 0.827 4. 9 120 0.00 55 T 1,2,3-trich1oropropane 0.252 0.228 9.3 113 0.00

56 IS 1,2-dichlorobenzene-04 <IS> 1.000 1.000 0.0 127# 0.00 57 TC ethyl benzene 1.289 1.321 -2.4 129# 0.00 58 T m/p-xylene 1. 541 1.577 -2.3 128# 0.00 59 T styrene 2.375 2.496 -5.1 129# 0.00 60 T a-xylene 1.493 1.498 -0.3 125# 0.00 61 T isopropylbenzene 3.738 3.841 -2.7 128# 0.00 62 T n-propy1 benzene 4.227 4.418 -4.5 130# 0.00 63 T 2-chlorotoluene 0.842 0.854 -1.4 128# 0.00 64 T 4-ch1orotoluene 0.858 0.872 -1.6 129# 0.00 65 T 1,3,5-trimethylbenzene 2.778 2.925 -5.3 131# 0.00 66 T tert-butylbenzene 2.350 2.416 -2.8 129# 0.00 67 T 1,2,4-trimethylbenzene 2.767 2.919 -5.5 130# 0.00 68 T sec-butylbenzene 3.357 3.507 -4.5 130# 0.00 69 T 1,3-dichlorobenze~e 1.636 1.645 -0.5 128# 0.00 70 T 4-isopropyltoluene 2.680 2.832 -5.7 130# 0.00 71 T 1,4-dichlorobenzene 1. 628 1.652 -1.5 128# 0.00 72 T 1,2-dichlorobenzene 1.548 1. 516 2. 1 126# 0.00 73 T n-butylbenzene 2.217 2.412 -8.8 134# 0.00 74 T 1,2-dibromo-3-chloropropane 0.114 0.100 12.3 114 0.00 75 T 1,2,4-trichlorobenzene 0.801 0.785 2.1 126# 0.00 76 T hexachlorobutadiene 0.324 0.314 3.2 125# 0.00 77 T naphthalene 1.727 1.513 12.4 113 0.00 78 T trans-1,4-Dichloro-2-butene 0.239 0.228 4 . 8 122# 0.00 79 T 1,2,3-trichlorobenzene 0.714 0.672 5.9 123# 0.00 --------------------------------------------------------------------------

( #) ~ Out of Range SPCC's out ~ 0 CCC's out ~ 0

/ /

/

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D:\Hpchem\1\Data\VMS3598\0427402.D 27 Apr 2015 8:18 am QCK010

RTE Apr 27 09:05:52 2015


2 BWS MSD4 1.00












5.189 7.818 9.520

70 95

152

113 118 65 130 98

4.245 Range 86

4.873 Range 64

6.747 Range 82

8.736 Range 85 -

- 117 95 115

85 50 62 96 64

101 56 96 43 84 96 53 73 63 45 77 96 43

130 83 97

117 75 78 62 95 63 93 83


1.007 1.119 1.168 1.361 1.439 1.527 2.114 1.865 2.357 2.302 2.433 3.081 2.545 3.009 2.919 3.747 3.620 4.439 3.872 4.008 4.236 4.135 4.401 4.702 4.949 5.368 5.895 5.791 5.982 6.567 6.584 7.169 6.790 1.961 7.187 3.324 1.880 7.317 7.120

106 75 43 9.2


VMS3595.M Mon Apr 27 09:05:53 2015

142 75 43 76 83

166

41530 87278 89400

52935 Recovery

30.00 ppb 30.00 ppb 30.00 ppb

29.89

51637 28.63

ppb 99.63%

ppb Recovery

207338 31.50 Recovery


95.43% ppb 105.00% ppb 102.53%

0.00 0.00 0.00

0.00 /

0.00

o.oo/ 0.00

33845 36630 37587 20534 20198 43544 86649 29918 28326 32640 33078


Qvalue 100

99

174037 76440 59935 99735 43264 32904 48532 17490 54846 46055 36566 44 762

128939 3628 6 31317 34013 15702 37362 63881 48714 98984 73223 42448 37510

153121 82951 20036 30845


231.08 ppb 10.94 ppb 11.91 ppb 11.76 ppb 13.38 ppb 11.61 ppb 48.06 ppb 11.62 ppb 11. 86 ppb 12.19 ppb 12.33 ppb 11.76 ppb 11.66 ppb 11.16 ppb 11.28 ppb 11.65 ppb 10.92 ppb 11.98 ppb

234.73 ppb 12.07 ppb 50.47 ppb 11.54 ppb 10.40 ppb 11.90 ppb 33.73 ppb 11.85 ppb

9.54 ppb 10.17 ppb

100 98 97 99 97 97 99 94 97

100 98 99 98 99 98 98 99 98 98 99 98 98 99 97 98 98 98 99 99 99 97 96

100 99 98 96 97

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D:\Hpchem\l\Data\VMS3598\0427402.D 27 Apr 2015 8:18 am QCK010

RTE Apr 27 09:05:52 2015



2 BWS MSD4 1.00


45) 4 6) 47) 48) 49) 50) 51) 53) 54) 55) 57) 58) 59) 60) 61) 62) 63) 64) 65) 66) 67) 68) 69) 7 0) 71) 72) 73) 74) 75) 7 6) 77) 78) 7 9)

1,3-dichloropropane 2-hexanone dibromochloromethane 1,2-dibromoethane chlorobenzene 1,1,1,2-tetrachloroethane bromoform bromobenzene 1,1,2,2-tetrachloroethane 1,2,3-trichloropropane ethylbenzene m/p-xylene styrene a-xylene isopropylbenzene n-propyl benzene 2-chloroto1uene 4-chlorotoluene 1,3,5-trimethy1benzene tert-butylbenzene 1,2,4-trimethylbenzene sec-butylbenzene 1,3-dichlorobenzene 4-isopropyltoluene 1,4-dichlorobenzene 1,2-dichlorobenzene n-buty1benzene 1,2-dibromo-3-chloropr. 1,2,4-trich1orobenzene hexachlorobutadiene naphthalene trans-1,4-Dichloro-2-b. 1,2,3-trichlorobenzene

7.534 7.838 7.453 7.618 8.009 8.058 8.440 8.788 8.860 8.924 8.041 8.139 8.432 8.400 8.585 8.814 8.892 8.979 8.921 9.083 9.118 9.173 9.277 9.245 9.320 9.523 9.448 9.900

10.206 10.189 10.360

8.950 10.441

76 43

129 107 112 131 173 156

83 110 106 106 104 106 105

91 126 126 105 119 105 105 146 119 146 146

91 75

180 225 128

53 180

40903 6774 9 23828 21096 74634 25186 12 635 28354 24055

6635 39358 93991 74385 44 630

114447 131645

25443 25977 87162 72003 86989

104495 49014 84383 49215 45181 71877 17944 23387

9355 45089 33921 20016

9.51 ppb 42.91 ppb 10.15 ppb

9.28 ppb 10.03 ppb 10.46 ppb

9.22 ppb 10.04 ppb

9.51 ppb 9.07 ppb

10.24 ppb 20.47 ppb 10.51 ppb 10.03 ppb 10.27 ppb 10.45 ppb 10 .14 ppb 10.16 ppb 10.53 ppb 10.28 ppb 10.55 ppb 10.45 ppb 10.05 ppb 10.57 ppb 10.15 ppb

9.79 ppb 10.88 ppb 52.62 ppb

9.79 ppb 9.68 ppb 8.76 ppb

47.62 ppb 9.41 ppb

100 99 96 97 99 98 96 99 96 93

100 99

100 95 98 99 98 97 98

100 100 100

98 99

100 99

100 94 99 98 99 96 99


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D:\Hpchem\1\Data\VMS3598\0427402.D 27 Apr 2015 8:18 am QCK010

RTE Apr 27 09:05:52 2015



rbundanre

. 9000001

850000

800000

750000

7000001

650000

6000001

l 550000

500000

450000\

400000

350000

300000 ,.

250000 ,. ,. .- ~ c • • 200000 .s .s

Ji ,. . q) !5

150000. ~B Gi~~

e~ !§ffio ~ ... ~~ ~~ ~~:s ~i?

" 0

VMS3595.M Mon Apr 27 09:05:53 2015

TIC: 0427402.0\data.ms t ~ ~ ., ~ ~ ~

2 BWS MSD4 1.00

Page: 3



ICAL Batch: VMS3596

Compound TV (ug/L) Result (ug/L) %DriftIsobutyl alcohol 250 174.84 -30.11,4-Dioxane 500 282.53 -43.5


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0427405_ccal.txtEvaluate Continuing Calibration Report

Data File : D:\Hpchem\1\Data\VMS3598\0427405.D Vial: 5Acq On : 27 Apr 2015 9:38 am Operator: BWSSample : CCAPX9 Inst : MSD4Misc : Multiplr: 1.00Integrator: RTEQuant Time: May 27 15:22:07 2015

Quant Method : D:\Hpchem\Methods\APIX-W\VMS3596.MQuant Title : VMS3596 8260 APX9-W ICALQLast Update : Fri Apr 24 14:16:23 2015Response via : Initial CalibrationDataAcq Meth:MSD4_ACQ.M

Min. RRF : 0.000 Min. Rel. Area : 50% Max. R.T. Dev 0.50minMax. RRF Dev : 20% Max. Rel. Area : 150%

Compound AvgRF CCRF %Dev Area% Dev(min)-------------------------------------------------------------------------1 IS Fluorobenzene <IS> 1.000 1.000 0.0 97 0.002 Allyl chloride 0.911 1.208 -32.5# 109 0.003 Acetonitrile 0.076 0.085 -11.4 95 0.004 Chloroprene 2.394 3.144 -31.3# 111 0.005 Methacrylonitrile 0.920 1.018 -10.6 46 0.006 Isobutyl alcohol 0.038 0.034 10.8 70 0.007 Methyl methacrylate 1.195 1.386 -16.0 0.008 S 1,2-dichloroethane-d4 1.131 1.276 -12.8 94 0.009 Ethyl methacrylate 1.582 1.691 -6.9 88 0.0010 Propionitrile 0.184 0.197 -6.7 87 0.0011 1,4-Dioxane 0.008 0.006 24.8# 57 0.0012 S toluene-d8 4.047 4.928 -21.8# 102 0.00

13 IS 1-chloro-3-fluorobenzene 1.000 1.000 0.0 109 0.0016 Pentachloroethane 0.277 0.331 -19.5 117 0.00--------------------------------------------------------------------------

(#) = Out of Range SPCC's out = 0 CCC's out = 0

VMS3596.M Mon Jun 22 11:11:25 2015

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D:\Hpchem\1\Data\VMS3598\0427405.D 27 Apr 2015 9:38 am CCAPX9

RTE Apr 27 09:57:06 2015



5 BWS MSD4 1. 00


Internal Standards 1) Fluorobenzene <lS>







5.189 70 7.818 95 9.520 152

65 4.870 Range 64

6.746 Range 82 -

8.736 Range 85

- 140 98 117 95 115

2.215 76 2.765 40 2.980 53 4.792 41 5.122 43 6.188 41 7. 363 69 4.775 54 6.196 88 9.095 167

32326 66715 67859

41252 Recovery

30.00 30.00 30.00

29.00

159305 31.31 Recovery


6507 5. 68 9118 95.48

16938 5. 63 27433 23.71

9143 174.84 89619 59.68

9113 4.58 21220 91.50

3054 282.53 3748 4.98

ppb ppb ppb

ppb 96.67%

ppb 104.37% ppb 100.97%

0.00 0.00 0.00

0.00 /

o.oo/ 0.00

Qvalue ppb 99 ppb 97 ppb 96 ppb 97 ppb 95 ppb 99 ppb 96 ppb 99 ppb # 56 ppb 94

(#) = qualifier out of range (m) = manual integration {+) = signals summed

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D:\Hpchem\1\Data\VMS3598\0427405.D 27 Apr 2015 9:38 am CCAPX9

RTE Apr 27 09:57:06 2015


I bundance TIC: 0427405.0\data.ms

560000

540000

520000

500000

"' 480000 A

"' v

460000 • c I • N

I c • 440000

~

e g :1 420000 e .Q

400000 ~

380000

360000

340000 "' 00 u • c

320000 • , 9

300000

280000 ~ ~ • 5

260000 • E

"' ;;; A li 240000 "' v ~

• c

220000 • N c • ~ . e 200000 0

2 ~

' 180000 ' 160000 I 140000 "' ~

~ • 120000 ~

I 100000

I t ~ • 80000 u c ~ ·c I • -~ • ·a. .8 li ~ e 8 e II E

60000 ~ .Q ~ 3 <( ~ ~ I

;;; 0 5

I w

40000

20000

~ ' ! 0 ! I •

8.00 ime--> 1.00 2.00 3.00 4.00 5.00 6.00 7.00

VMS3596.M Mon Apr 27 09:57:07 2015

"' " c • N c Jl e 0 , ;; E e ~


"' ' "' v v

" • c

• c • li e .Q jj • . c • ~

9.00 10.00

5 BWS MSD4 1.00

11.00

I

I

12.00

Page: 2

Appendix C Data Validation Report

AECOM 978-905-2100 tel 250 Apollo Drive 978-905-2101 fax Chelmsford, MA 01824

Memorandum

DVR_31500724_VOC.docx1500724_VOC

Project GE - Pittsfield Page 1

Laboratory SGS, Wilmington, NC

Laboratory SDG 31500724

Analyses/Method VOC by SW-846 8260B

Validation Level Tier II

AECOM Project Number 60331701.4.2.4

Prepared by Paula DiMattei AECOM/Chelmsford, MA Completed: June 3, 2015

Reviewed by Lori Herberich AECOM/Chelmsford, MA Completed: June 7, 2015

SUMMARY

The samples listed below were collected by AECOM Environment from General Electric Company’s (GE’s) Groundwater Management Area (GMA) 4 on April 20, 2015 and submitted to SGS in Wilmington, NC for analysis.

SDG Sample ID Matrix/Sample Type Analysis

31500724

COOLER 6 TRIP BLANK Trip Blank VOCs DUP-1-042015 Field Duplicate of GMA4-75-042015 VOCs GMA4-75-042015 Groundwater VOCs GMA4-8-042015 Groundwater VOCs GMA4-9-042015 Groundwater VOCs GMA4-EB-042015 Equipment blank VOCs H78B-16-042015 Groundwater VOCs

VOCs = Volatile Organic Compounds by SW-846 8260B

Data validation activities were conducted with reference to:

Test Methods for Evaluating Solid Waste, Physical/Chemical Methods SW846, specifically SW-846 Method 8260B, Volatile Organic Compounds by Gas Chromatography/Mass Spectrometry (USEPA, 1996);

EPA New England, Environmental Data Review Program Guidance (USEPA, April 2013);

USEPA Contract Laboratory Program National Functional Guidelines for Superfund Organic Methods Data Review (June 2008); and

The Data Validation Annex A in General Electric Company’s Field Sampling Plan/Quality Assurance Project Plan (FSP/QAPP) (revised July 2013).

A Tier 1 Plus review, as defined in EPA Region 1 2013 guidance, was performed on all of the data. This Tier 1 Plus review is equivalent to the Tier II review (EPA Region 1 1993 guidance) described in the FSP/QAPP. A Tier 1 Plus review of all data was deemed necessary in order to fulfill the requirements of the FSP/QAPP since QC issues were identified for each parameter reviewed, affecting all samples.

AECOM 2

The National Functional Guidelines cited above were modified to accommodate the non-CLP methodologies. In the absence of method-specific information or project-specific requirements, AECOM’s professional judgment was used as appropriate.

REVIEW ELEMENTS

Sample data were reviewed for the following elements, where applicable to the method:

Data completeness (chain-of-custody [COC])/sample integrity Holding times and sample preservation Instrument tuning Initial calibration/continuing calibration verification Laboratory blanks/trip blanks/equipment blanks Surrogate spike recoveries Matrix spike (MS) and/or matrix spike duplicate (MSD) results Field duplicate results Laboratory control sample (LCS)/laboratory control sample duplicate (LCSD) results Internal standard results Sample results/reporting issues

The symbol ( ) indicates that no validation qualifiers were applied based on this parameter. The symbol ( ) indicates that a QC nonconformance resulted in the qualification of data. Any QC nonconformance that resulted in the qualification of data is discussed below. In addition, nonconformances or other issues that were noted during validation, but did not result in qualification of data, may be discussed for informational purposes only.

The data appear valid as reported and may be used for decision making purposes. Selected data points were estimated, negated, and/or rejected due to nonconformances of certain QC criteria (see discussion below). Qualified sample results are presented in Table 1.

DISCUSSION

Data Completeness/Sample Integrity

The data package was reviewed and found to meet acceptance criteria for completeness:

The COCs were reviewed for completeness of information relevant to the samples and requested analyses, and for signatures indicating transfer of sample custody.

The laboratory sample login sheet(s) were reviewed for issues potentially affecting sample integrity, including the condition of sample containers upon receipt at the laboratory.

Completeness of analyses was verified by comparing the reported results to the COC requests and any subsequent communications between AECOM and the laboratory.

Holding Times and Sample Preservation

All VOC samples were received properly preserved to a pH of <2. One compound, 2-chloroethylvinyl ether, was rejected (R) in all VOC samples since the samples were received acid preserved. As noted below under MS/MSD nonconformances, 2-chloroethylvinyl ether does not recover in an acid matrix.

AECOM 3

All samples were analyzed within the method specified holding times for the VOC analyses.

Instrument Tuning

All instrument tuning met QC acceptance criteria.

Initial Calibration/Continuing Calibration Verification

The percent relative standard deviations (%RSDs) and the response factors (RFs) of all target compounds in the initial calibrations (IC) and the percent differences or percent drifts (%Ds) in the continuing calibration verification standards (CCVs) met QC acceptance criteria for the VOC analyses with the following exceptions noted in the tables below.

IC or CCV Date Analyzed Compound RF Actions

Detects Nondetects

IC 4/24/15 Isobutyl alcohol 0.044 J R Associated Samples: All samples in this SDG CCV 4/24/15 Isobutyl alcohol 0.025 J R Associated Samples: GMA4-8-042015, H78B-16-042015, GMA4-EB-042015 and DUP-1-042015 CCV 4/27/15 Isobutyl alcohol 0.034 J R Associated Samples: Cooler 6 Trip blank and GMA4-9-042015

CCV Date Analyzed

Compound %D or %Drift

Actions

Detects Nondetects

CCV 4/24/15 Isobutyl alcohol* 48.5 J UJ 1,4-Dioxane 49.0 J UJ

Associated Samples: GMA4-8-042015, H78B-16-042015, GMA4-EB-042015 and DUP-1-042015 CCV 4/27/15 Isobutyl alcohol 30.1 J UJ

1,1,1-Trichloroethane 21.9 J UJ Allyl chloride 32.5 J UJ Carbon tetrachloride 23.3 J UJ Chloroethane 24.7 J UJ Chloroprene 31.3 J UJ cis-1,3-Dichloropropene 20.7 J UJ Methacrylonitrile 44.7 J UJ Methyl methacrylate 1292 J UJ 1,4-Dioxane 43.5 J UJ

Associated Samples: Cooler 6 Trip blank and GMA4-9-042015 *Previously qualified as rejected due to low RF in IC and CCV; no further qualifiers applied

Laboratory Blanks/Trip Blanks/Equipment Blanks

Target compounds were not detected in the laboratory method blanks, equipment blank, or trip blank associated with the samples in this data set.

Surrogate Spike Recoveries

AECOM 4

The surrogate percent recoveries (%Rs) were within the QAPP QC acceptance limits for all sample analyses.

MS/MSD Results

The laboratory spiked 45 of 55 target compounds into the MS and MSD. Only five target compounds (1,1-dichloroethane, trichloroethene, benzene, toluene, chlorobenzene) were listed in the QAPP as spiking compounds. The MS and MSD recoveries were evaluated using the QAPP for the five target compounds listed in the QAPP and using the laboratory QC limits for the remaining 50 compounds.

MS/MSD analyses were performed on sample GMA4-8-042015. The MS/MSD %Rs and relative percent differences (RPDs) were reviewed for conformance with the QAPP and laboratory QC acceptance criteria. All QC acceptance criteria were met except for the following.

Compound MS %R

MSD %R RPD QC Limits Actions

%R RPD Detects Nondetects 2-Butanone ok 121 ok 36-107 20 J+ none 2-Chloroethylvinyl ether 0 0 ok 17-283 20 J- R Acetone 88 127 ok 18-85 20 J+ none Ethylbenzene ok 73 ok 74-126 20 J- UJ Note: The nondetect results for 2-chloroethylvinyl ether were rejected in all samples in this SDG since the samples were received at the laboratory acid preserved. Acid preservation causes lack of recovery of this compound.

Field Duplicates Results

Field duplicate RPDs were reviewed for conformance with the QC acceptance criterion of <30% for aqueous matrices. All field duplicate precision criteria were met.

LCS/LCSD Results

The laboratory spiked 45 of 55 target compounds into the LCS and LCSD. The QC acceptance limits from the QAPP were used to evaluate the five target compounds (1,1-dichloroethane, trichloroethene, benzene, toluene, chlorobenzene) that were listed as spike compounds. The remaining compounds were evaluated using laboratory QC acceptance limits.

The %R for methylene chloride exceeded the QC acceptance limits in the LCSD associated with samples Cooler 6 Trip blank and GMA4-9-042015. Methylene chloride was not detected in either sample; therefore, data are not impacted.

Internal Standard Results

All internal standards met QC acceptance criteria.

Sample Results/Reporting Issues

Results reported between the detection limit (DL) and the LOQ were qualified as estimated (J) by the laboratory; these qualifiers were retained during data validation unless superseded by validation qualifiers.

AECOM 5

Select sample results were reported from a dilution analysis due to the elevated concentration of target compounds present in the sample. Sample LOQs were adjusted accordingly by the laboratory.

ATTACHMENTS

Attachment A: Validation Qualifier Codes and Explanation

Attachment B: Reason Codes and Explanation

AECOM 6

Table 1 - Data Validation Summary of Qualified Data

Sample ID Matrix Compound Result QL Units Validation Qualifiers

Validation Reason

COOLER 6 TRIP BLANK WQ Methyl Methacrylate 1.00 ug/l UJ c COOLER 6 TRIP BLANK WQ Isobutyl Alcohol 50.0 ug/l R c COOLER 6 TRIP BLANK WQ Chloroethane 1.00 ug/l UJ c COOLER 6 TRIP BLANK WQ 1,1,1-Trichloroethane 1.00 ug/l UJ c COOLER 6 TRIP BLANK WQ Carbon Tetrachloride 1.00 ug/l UJ c COOLER 6 TRIP BLANK WQ Chloroprene 1.00 ug/l UJ c COOLER 6 TRIP BLANK WQ Methacrylonitrile 10.0 ug/l UJ c COOLER 6 TRIP BLANK WQ 2-Chloroethylvinylether 25.0 ug/l R p COOLER 6 TRIP BLANK WQ 1,4-Dioxane 100 ug/l UJ c COOLER 6 TRIP BLANK WQ Allyl Chloride 1.00 ug/l UJ c COOLER 6 TRIP BLANK WQ cis-1,3-Dichloropropene 1.00 ug/l UJ c

DUP-1-042015 WG Isobutyl Alcohol 50.0 ug/l R c DUP-1-042015 WG 1,4-Dioxane 100 ug/l UJ c DUP-1-042015 WG 2-Chloroethylvinylether 25.0 ug/l R p

GMA4-75-042015 WG Isobutyl Alcohol 50.0 ug/l R c GMA4-75-042015 WG 1,4-Dioxane 100 ug/l UJ c GMA4-75-042015 WG 2-Chloroethylvinylether 25.0 ug/l R p GMA4-8-042015 WG Ethylbenzene 1.00 ug/l UJ m GMA4-8-042015 WG 2-Butanone 3.12 25.0 ug/l J m GMA4-8-042015 WG Isobutyl Alcohol 50.0 ug/l R c GMA4-8-042015 WG Acetone 25.8 25.0 ug/l J m GMA4-8-042015 WG 1,4-Dioxane 100 ug/l UJ c GMA4-8-042015 WG 2-Chloroethylvinylether 25.0 ug/l R p GMA4-9-042015 WG Methyl Methacrylate 5.00 ug/l UJ c GMA4-9-042015 WG Isobutyl Alcohol 250 ug/l R c GMA4-9-042015 WG Chloroethane 5.00 ug/l UJ c GMA4-9-042015 WG 1,1,1-Trichloroethane 5.00 ug/l UJ c GMA4-9-042015 WG Carbon Tetrachloride 5.00 ug/l UJ c GMA4-9-042015 WG Chloroprene 5.00 ug/l UJ c GMA4-9-042015 WG Methacrylonitrile 50.0 ug/l UJ c GMA4-9-042015 WG 1,4-Dioxane 500 ug/l UJ c GMA4-9-042015 WG 2-Chloroethylvinylether 125 ug/l R p GMA4-9-042015 WG Allyl Chloride 5.00 ug/l UJ c GMA4-9-042015 WG cis-1,3-Dichloropropene 5.00 ug/l UJ c

GMA4-EB-042015 WG Isobutyl Alcohol 50.0 ug/l R c GMA4-EB-042015 WG 1,4-Dioxane 100 ug/l UJ c GMA4-EB-042015 WG 2-Chloroethylvinylether 25.0 ug/l R p H78B-16-042015 WG Isobutyl Alcohol 50.0 ug/l R c H78B-16-042015 WG 1,4-Dioxane 100 ug/l UJ c H78B-16-042015 WG 2-Chloroethylvinylether 25.0 ug/l R p

Notes:

Refer to Attachment A for validation qualifier definitions. Refer to Attachment B for validation reason code definitions. Where the sample result is nondetect, there will be no value in the result column.

AECOM 7

Attachment A Qualifier Codes and Explanation

AECOM 8

Qualifier Explanation

J The analyte was positively identified; the associated numerical value is the approximate concentration of the analyte in the sample.

J+ Estimated result, bias is likely to be high. The analyte was positively identified; the associated numerical value is the approximate concentration of the analyte in the sample with a potential high bias.

J- Estimated result, bias is likely to be low. The analyte was positively identified; the associated numerical value is the approximate concentration of the analyte in the sample with a potential low bias.

U (“ND”) The analyte was analyzed for, but was not detected above the reported sample quantitation limit (ND is also used for this project to indicate non-detected compounds.)

UJ (“ND J”)

The analyte was not detected above the reported sample quantitation limit. However, the reported quantitation limit is approximate and may or may not represent the actual limit of quantitation necessary to accurately and precisely measure the analyte in the sample (ND J is also used for this project to indicate non-detected compounds in this category.)

R The sample results are rejected due to serious deficiencies in the ability to analyze the sample and meet quality control criteria. The presence or absence of the analyte cannot be verified.

AECOM 9

Attachment B Reason Codes and Explanation

AECOM 10

Reason Code Explanation

be Equipment blank (or trip blank) contamination

bl Laboratory blank contamination

bm Missing blank information

c Calibration issue

cl Clean-up standard recovery

cr Chromatographic resolution

d Reporting limit raised due to chromatographic interference

fd Field duplicate RPDs

g Chromatographic pattern match issue

h Holding times

i Internal standard areas

ip DDT/Endrin breakdown

k Estimated Maximum Possible Concentrations

l LCS recoveries

lc Labeled compound recovery

ld Laboratory duplicate RPDs (matrix duplicate, MSD, LCSD)

m Matrix spike recovery

nb Negative laboratory blank contamination

p Chemical preservation issue

r Dual column precision

q Quantitation issue

s Surrogate recovery

sp Sample preparation issue

su Evidence of ion suppression

t Temperature preservation issue

v Compound identification issue

x Low % solids

y Serial dilution results

z ICS results

Appendix D Select Graphs on Historical Groundwater Quality Data

202

356

175

21.407.07

39

22.70 13.60

97.80

1.41

89.2092

0

50

100

150

200

250

300

350

400

Conc

entr

atio

n (µ

g/L)

Sample Date

Appendix D Well GMA4-9 Historical PCE Concentrations Groundwater Monitoring Program for GMA 4 Spring 2015General Electric Company - Pittsfield, Massachusetts

PCE (LF) PCE (PDB) PCE (PDB) Duplicate PCE Average Concentration GW-2 Standard

Notes:1. This well is not a compliance well for GW-2 standards. However, concentrations are compared to the GW-2 Standard of 50 µg/L (illustrated as a solid line below) solely for benchmark purposes.2. The GW-3 standard is 30,000 µg/L.3. The MCP UCL is 100,000 µg/L.4. The average detected TCE concentration at this well is 93.20 µg/L (Illustrated as the dashed line below).5. Passive diffusion bag (PDB) samples are being compared to low-flow samples. PDB sample values are illustrated in yellow and red below, while low-flow sample values are illustrated in blue.

81

76

24

34

160

180

110

22 21

38

47

80

40

4330

73 7580

71

38 40

110

1532

.50

20.2

0

0

20

40

60

80

100

120

140

160

180

200

Conc

entr

atio

n (µ

g/L)

Sample Date

Appendix D Well H78B-16 Historical TCE Concentrations Groundwater Monitoring Program for GMA 4 Spring 2015General Electric Company - Pittsfield, Massachusetts

TCE (LF) TCE Duplicate TCE (PDB) GW-2 Standard Average TCE Concentration

Notes:1. This well is not a compliance well for GW-2 standards. However, concentrations are compared to the GW-2 Standard of 5 µg/L (illustrated as a solid line below) solely for benchmark purposes. 2. The MCP GW-3 Standard is 5,000 µg/L.3. The MCP UCL is 50,000 µg/L.4. The average detected TCE concentration at this well is 61.90 µg/L (Illustrated as the dashed line below).5. Passive diffusion bag (PDB) samples are being compared to low-flow samples . PDB sample values are illustrated in yellow below, while low-flow sample values are illustrated in blue and red.

Appendix E Summary Statistics on Historical Groundwater Quality Data

Table E-1GMA4-7SSummary Statistics on Historical Groundwater Quality DataLong-Term Monitoring ProgramGroundwater Management Area 4General Electric CompanyPittsfield, MassachusettsSpring 2015

Location ID: Method 1 Method 1 MCP Detection Minimum Maximum Median Arithmetic Geometric StandardDate Collected: GW-2 GW-3 UCL Frequency Detect Detect Value Average Mean DeviationSample Name: Standards Standards for Groundwater

Volatile Organics (µg/L)Acetone 50,000 50,000 100,000 4/10 1.05 17.20 10.00 10.80 7.30 8.39Chloroform 50 20,000 100,000 2/10 0.61 0.87 0.61 0.73 0.69 0.24Tetrachloroethylene 50 30,000 100,000 5/10 0.48 11.20 1.00 2.08 1.22 3.13Trichloroethylene 5 5,000 50,000 8/10 0.17 0.40 0.50 0.62 0.52 0.33Total VOCs Not Listed Not Listed Not Listed 8/10 0.48 17.81 11.60 14.30 7.39 14.90

Notes:

1. Historical analytical data between 2009 and 2015 provided by ARCADIS and AECOM.2. Sample results were validated in accordance with GE’s EPA-approved Field Sampling Plan/Quality Assurance Project Plan in effect at the time of the analyses.3. Only constituents which were detected during at least one prior sampling event and were analyzed during the Spring 2015 sampling event are summarized.4. Statistical calculations for events where multiple samples were collected from one location (e.g. low-flow and passive diffusion bag samples) were conducted treating the initial

sample for that event as a parent and the other sample type (e.g. passive diffusion bag sample) as a split. For locations with duplicate and/or split analytical results, if there is a detection in any of the samples for a location during a single monitoring event, a single detection is reported when calculating the detection frequency. Minimum and maximum detects are the minimum and maximum from all analytical results, treating duplicate and split samples separately. Medians, arithmetic averages, and geometric means are calculated by treating the arithmetic average of paired duplicate results, split samples and primary samples each as a single result. One half of the associated reporting limit is used for any non-detected results in the summary statistics presented.

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Table E-2GMA4-8Summary Statistics on Historical Groundwater Quality DataLong-Term Monitoring ProgramGroundwater Management Area 4General Electric CompanyPittsfield, MassachusettsSpring 2015


Volatile Organics (µg/L)2-Butanone 50,000 50.000 100,000 1/9 3.12 3.12 5.00 8.79 6.17 7.72Acetone 50,000 50,000 100,000 4/9 2.90 45.00 10.00 14.90 10.20 13.70Xylenes (total) 3,000 5,000 100,000 1/9 0.26 0.26 1.00 0.92 0.80 0.50Total VOCs Not Listed Not Listed Not Listed 4/9 2.90 45.00 28.92 30.50 22.80 18.90

Notes:



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Table E-3GMA4-9Summary Statistics on Historical Groundwater Quality DataLong-Term Monitoring ProgramGroundwater Management Area 4General Electric CompanyPittsfield, MassachusettsSpring 2015


Volatile Organics (µg/L)Acetone 50,000 50,000 100,000 2/11 33.00 44.30 25.00 38.50 21.70 41.50Chloroform 50 20,000 100,000 3/11 1.27 2.08 1.40 2.57 1.54 2.89cis 1,2-Dichloroethylene 20 50,000 100,000 1/3 0.61 0.61 0.56 0.56 0.55 0.08Tetrachloroethylene 50 30,000 100,000 11/11 1.41 356.00 39.00 93.20 38.60 111.00Total Xylene 3,000 5,000 100,000 1/11 2.12 2.12 2.12 3.97 2.18 3.85Trichloroethylene 5 5,000 50,000 9/11 0.19 7.00 1.40 2.48 1.38 2.48Total VOCs Not Listed Not Listed Not Listed 11/11 11.86 363.00 47.98 103.00 58.50 110.00

Notes:



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Table E-4H78B-16Summary Statistics on Historical Groundwater Quality DataLong-Term Monitoring ProgramGroundwater Management Area 4General Electric CompanyPittsfield, MassachusettsSpring 2015


Volatile Organics (µg/L)1,1,1-Trichloroethane 4,000 20,000 100,000 7/20 0.34 9.00 1.93 2.14 1.44 2.061,1-Dichloroethane 2,000 20,000 100,000 7/20 0.18 5.00 1.50 1.79 1.14 1.561,1-Dichloroethylene 80 30,000 100,000 1/20 0.35 0.35 0.50 1.27 0.82 1.521,2-Dichloroethane 5 20,000 100,000 4/20 0.25 2.80 1.00 1.79 1.22 1.52Acetone 50,000 50,000 100,000 3/20 6.91 36.70 5.00 10.60 7.47 9.61Benzene 1,000 10,000 100,000 1/20 0.60 0.60 1.00 1.99 1.21 2.31Chlorobenzene 200 1,000 10,000 16/20 0.44 49.00 2.67 8.46 3.27 13.40Chloroform 50 20,000 100,000 4/20 0.14 1.25 1.63 1.84 1.18 1.53cis 1,2-Dichloroethylene 20 50,000 100,000 1/1 0.47 49.00 26.80 26.80 26.80 Insufficient DataMethylene Chloride 2,000 50,000 100,000 3/20 0.16 1.48 2.50 3.15 2.39 2.59Tetrachloroethylene 50 30,000 100,000 15/20 0.22 3.10 1.00 1.28 0.91 1.16trans 1,2-Dichloroethylene 80 50,000 100,000 8/20 0.19 2.00 1.10 1.60 1.09 1.33Trichloroethylene 5 5,000 50,000 20/20 14.70 180.00 41.10 61.90 48.00 47.20Trichlorofluoromethane Not Listed Not Listed Not Listed 2/20 0.41 0.62 1.50 2.13 1.39 2.26Vinyl Chloride 2 50,000 100,000 14/20 0.28 19.00 1.00 3.90 1.72 5.47Total VOCs Not Listed Not Listed Not Listed 20/20 14.94 241.90 53.32 80.30 61.10 63.90

Notes:



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