Barium (Elemental) and Selected Barium Compounds Barium (Elemental
UNITED STATES DEPARTMENT OF THE INTERIOR …Elemental-composition data on 162 samples from Egypt are...
43
UNITED STATES DEPARTMENT OF THE INTERIOR GEOLOGICAL SURVEY ELEMENTAL COMPOSITION OF GEOLOGIC MATERIALS FROM AREAS OF MINERALIZATION IN EGYPT - SEMIQUANTITATIVE ANALYSES by J. L. HARRIS, W. B. CRANDELL, AND D. W. GOLIGHTLY Open-File Report 81- This report is preliminary and has not been reviewed for conformity with U.S. Geological Survey editorial standards and stratigraphic nomenclature. Any use of trade names is for descriptive purposes only and does not imply endorsement by the USGS. 1981
Transcript of UNITED STATES DEPARTMENT OF THE INTERIOR …Elemental-composition data on 162 samples from Egypt are...
UNITED STATES DEPARTMENT OF THE INTERIOR
GEOLOGICAL SURVEY
ELEMENTAL COMPOSITION OF GEOLOGIC MATERIALS FROM AREAS
OF MINERALIZATION IN EGYPT - SEMIQUANTITATIVE ANALYSES
by
J. L. HARRIS, W. B. CRANDELL, AND D. W. GOLIGHTLY
Open-File Report 81-
This report is preliminary and has not been reviewed for conformity with U.S. Geological Survey editorial standards and stratigraphic nomenclature. Any use of trade names is for descriptive purposes only and does not imply endorsement by the USGS.
1981
CONTENTS
Page
Introduction .......................... 1
Procedure. ........................... 2
Results and Discussion ..................... 3
References Cited ........................ 5
ILLUSTRATION
Figure 1. Sample locations plotted on geologic map of Egypt 0 \tefs i'
TABLES
Table 1. Concentration ranges for elements determined by
computerized spectrographic analysis of silicate
rocks at the U.S. Geological Survey, Reston, Va. ; . . 6 Table 2. Sample description and origin ............ 7
Table 3. Concentrations of elements determined by direct-
current arc emission spectrography .......... 8
ELEMENTAL COMPOSITION OF GEOLOGIC MATERIALS FROM AREAS OF
MINERALIZATION IN EGYPT - SEMIQUANTITATIVE ANALYSES
by
J. L. Harris, W. B. Crandell, and D. W. Golightly
INTRODUCTION
Elemental-composition data on 162 samples from Egypt are
presented in this report. The sample materials include syenites, con
glomerates, clay, gypsum, limestone, greywackes, si Itstones, and
sulfide ores. All samples were collected by geologists of the
Egyptian Geological Survey (EGS) from regions of mineralization and
were made available for analysis by Ms. Mary Iskarider and Mr. Sabry
Holyle, EGS chemists who participated in a training program that was
arranged by the U.S. Geological Survey (USGS) and conducted in Reston,
Virginia, during part of the summer of 1980. A principal objective of
the EGS chemists was to thoroughly characterize this diverse collection
of geologic materials in terms of major-, minor-, and trace-element
concentrations. The materials thus characterized will serve as
valuable geochemical standards in future analyses of geologic samples
by the EGS analytical chemists. To this end, each of the 162 samples
was analyzed for 64 elements by semiquantitative direct-current arc
atomic-emission spectrography (SQ-AES). SQ-AES is a rapid survey
analysis technique that provides a relatively thorough examination of
the composition of materials. It thus furnishes information that
1
serves as a valuable descriptor of the material and as a good guide
toward subsequent quantitative estimations of elemental concentrations
by atomic emission and absorption spectrometry or by other techniques,
PROCEDURE
Prior to analysis, all samples were ground to approximately -100
mesh by the USGS grinding laboratory. A portion of each of these
ground samples was weighed into an aluminum weighing dish, diluted in
the weighing dish with high-purity graphite, transferred through a
stainless steel funnel into a graphite-cup electrode, tamped into the
electrode, and arced for spectrographic analysis. In this procedure,
15 mg of sample was always diluted with 30 mg of -200-mesh graphite
powder. The contents of the anodic-cup electrode were totally
vaporized into a 4-mm arc gap by a stepped current that commenced at
5 A for 20 s and then switched to 15 A for 130 s. The counter elec
trode (cathode) was a graphite rod. Excitation that produced atomic
spectra occurred in a 70% argon - 30% oxygen atmosphere that was
directed into the arc gap by a Helz jet (Helz, 1964). Spectral dis
persion of the optical radiation from the arc discharged was achieved
with a 3.4-m focal-length Ebert-mount spectrograph. The resulting
spectra, 230 - 470 nm, were recorded on a Kodak type 111-0 emulsion on
a glass-plate substrate 10.2 cm by 50.8 cm. Spectral information
was collected by a scanning microphotometer system that utilizes a
minicomputer for data storage and interpretation (Helz, 1973;
2
Thomas, 1979). Background-corrected relative peak intensities of 400
spectral lines were used to estimate concentrations of the 64 analysis
elements. This large set of spectral lines contains information that
allows coverage of a wide dynamic range, minimization of spectral
interference effects, and some valuable redundancy in concentration
estimates. Complete details of this spectrographic method have been
described by Dorrzapf (1973). The concentration ranges over which
these elements could be determined are listed in Table 1.
RESULTS AND DISCUSSION
Sample origins and descriptions are presented in Table 2.
Furthermore, sampling locations are indicated by circled numerals on
the geologic map shown in figure 1; the 8 line-code designations of
Table 2 correspond to the 8 location numbers in figure 1.
Results of analyses are summarized in Table 3. This table is
formatted for reporting results of silicate-rock analyses, and,
accordingly, first presents concentrations of the ten major rock-
forming elements in units of weight percent (centigrams/gram). Then,
concentrations of minor and trace elements are reported in parts per
million (micrograms/gram). Concentrations of major constituents are
recalculated as oxides and presented toward the bottom of each report
page. Also, at the bottom of each report page is a set of footnotes
that indicates limitations of the analytical method and whether
any special considerations apply to the reported results. Calibration
3
of the spectrographic analysis method was for silicate rocks. The
results of analyses by this method show a marked dependency on the
sample matrix composition that is attributable to sample transport
and excitation mechanisms in the direct-current arc source. Thus,
systematic errors can occur in determining elemental compositions of
sample matrices that greatly differ from the sample matrix of
aluminosilicates.
Spectral interference from sample matrix elements required
visual examination of each spectrum on the photoplate to determine
the concentrations of silica in samples X-131516 - X131518, X-131705,
X-131707, and X-131711, sodium in samples X-131104, X-131107,
X-131110, X-131111, X-131113 - X-131115, X-131117, X-131119 - X-131121,
X-131123, X-131204 - X-131223, X-131304, X-131311, X-131315 - X-131317,
X-131320, X-131322, X-131323, X-131404 - X-131408, and X-131508,
silver in samples X-131705 - X-131714, zinc in samples X-131622 -
X-131714, magnesium in sample X-131011, calcium in samples X-131516,
X-131608, X-131616, X-131706, X-131707, and X-131711, potassium in
sample X-131508, strontium in samples X-131217 and X-131516, lead
in samples X-131705 and X-131707 - X-131713, and zirconium in
samples X-131708 and X-131710.
Results from these visual comparisons of spectra from samples
and standards are entered on the report pages in place of the con
centration estimates made by the automated microphotometer system.
Elemental quantitative analyses have been made of the same samples
in this report by J. S. Kane and H. Smith (1981).
REFERENCES CITED
Dorrzapf, A. F., Jr., 1973, Spectrochemical computer analysis - argon -
oxygen d.c. arc method for silicate rocks: U.S. Geological Survey
Journal of Research, v. 1, no. 5, p. 559-562.
Egypt Geological Survey, 1979, Geological map of Egypt: Cairo,
scale 1:2,000,000
Helz, A. W., 1964, A gas jet for d.c. arc spectroscopy: U.S.
Geological Survey Professional Paper 475-D, p. D176-D178.
Helz, A. W., 1973, Spectrochemical computer analysis - instrumentation:
U.S. Geological Survey Journal of Research, v. 1, no. 4, p. 475-482,
Kane, J. S., and Smith, Hezekiah, 1981, Analysis of Egyptian Geological
Survey and Mining Department samples by rapid rock and atomic
absoft?tfcion procedures: U.S. Geological Survey Open-File Report
81-991, 59 p.
Thomas, C. P., 1979, A minicomputer-based emission spectrographic
analysis system dependent on scanning microphotometry: Applied
Spectroscopy, v. 33, no. 6, 604-612.
Tabl
e 1.
CONC
ENTR
ATIO
N RA
NGES
FOR E
LEME
NTS
DETE
RMIN
ED
BY C
OMPU
TERI
ZED
SPEC
TROG
RAPH
IC A
NALY
SIS
OF S
ILIC
ATE
ROCK
S AT T
HE U
.S.
GEOL
OGIC
AL S
URVEY, RE
STON
, VA.
OXIDE
FORM
ULAS
(WJO
RS)
SI02
AL203
FE203
MGO
CAO
NA20
K20
TI02
P205
MNO
CONCENTRATION
RANGE
(%)
0.00
99 -
0.08
8 -
0.01
1 -
0.00
52 -
0.0021 -
0.00
63 -
0.082
-0.0053 -
0.16
-
0.00
013-
73 60 34 50 44 11 13 25 11 60
ELEMEN
T CONCENTRATION
(TRACE)
RANGE
(PPM
)
AG AS AU B BA BE BI CD CE CO CR CU DY ER EU GA GD GE HF HO
0.10
150 10 4.
62.2
1.0
10 32 43 1.0
1.0
1.5
22 10 2.2
1.5
15 1.5
15 6.8
- 10,000
- 10
,000
- 1,500
320
- 3,
200
680
- 4,600
- 10,000
- 29
,000
- 10
,000
- 6,800
- 3,
200
- 1,
000
- 1 ,
000
- 1,
000
- 1,
000
- 1,000
- 10,000
- 10,000
- 1 ,
000
ELEM
ENT
MAC
E)
IN IR LA LI
LU MN MO NB ND NI
OS PB PD PR PT RE RH RU SB SC
CO
NC
ENTR
ATIO
N
RANG
E (P
PM
)
6.8
15 10 68 15
1.0
1.0
3.2
32 1.5
22 6.8
1.0
68 4.6
10 2.2
2.2
32 1.0
- 1
0,0
00
- 10,0
00
- 1
0,0
00
- 32,0
00
- 1
,00
0
-460,0
00
- 1
,000
- 1
,000
- 6
,80
0-
15
,00
0
- 6,8
00
- 1
,000
- 3,2
00
- 4
,60
0-
10
,00
0
- 10,0
00
- 1
0,0
00
- 6
,80
0-
10,0
00
- 1,0
00
ELEM
ENT
CO
NC
ENTR
ATIO
N
(TR
AC
E)
RANG
E (P
PM
)
SN SN SR TA TB TH TL TM U V w Y YB ZN ZR
10
-1.5
-
1.0
-
460
-32
-
22
-4.6
-
4.6
-
320
-1.0
-
10
-1.5
-
0.1
5-
15
-3
.2
-
1,0
00
10,0
00
460,0
00
10,0
00
3,2
00
10
,00
01
0,0
00
1,0
00
10
,00
01,0
00
10,0
00
10,0
00
1,0
00
10,0
00
32,0
00
THE ABOVE
RANGES A
PPLY FO
R IN
ITIA
L CA
LIBR
ATIO
N CONDITIONS O
F SEPTEMBER
NARR
OW T
HE RA
NGE.
1979.
IN S
OME
CASES
INTERFERENCES
WILL
Table 2. Sample Description and Origin
Line Code-i/
1
2
3
4
4
4
4
4
5
6
7
8
Number of
Samples
30
20
16
10
10
10
10
12
8
5
2
29
Sample 2/ Numbers-'
1S-30S
31S-50S
51S-66S
C1-C10
CL1-CL10
G1-G10
OL1-OL10
LG1-LG12
Eminel- Emine7, MakallB
Darhibl- DarhibS
Hamatal- Hamata2
1M-29M
Place of OriginRock Type
Syen i te
Syenite
Syenite
Conglom erate
Clay
Gypsum
Oil- tainted Limestone
Limegrit
Sulfide Ore
Sulfide Ore
Sulfide Ore
Grey- wackes, Silt- stones
Locality
Gabal Mishbih
Gabal Nigrub El Tahtani
Gabal Mal adobe
Umm Gheig Lead-Zinc Mine
Umm Gheig Lead-Zinc Mine
Umm Gheig Lead- Zinc Mine
Umm Gheig Lead-Zinc Mine
Urnrn Gheig Lead-Zinc Mine
Umm Samiuki Copper Mine
Darhib Talc Mine
Hamata Talc Mine
Wadi Hammamat
Latitude (N) deg.min.sec.
22.44.00
23.01.00
22.44.00
25.43.00
25.43.00
25.43.00
25.43.00
25.43.00
24.14.00
24.01.00
24.15.30
25.58.00
Longitude (E) deg.min.sec
34.43.00
35.02.00
34.50.00
34.31.15
34.31.15
34.31.15
34.31.15
34.31.15
34.49.00
35.01.00
35.13.00
33.33.00
V Sample-location number in figure 12/ These numbers occur in the Field Number row of Table 3.
TABLE
3.
CONCENTRATIONS OF ELEMENTS DETERMINED BY DIRECT-CURRENT ARC EMISSION SPECTROGRAPHY.
PAGE
i-A
CO
REPORT
JOB NO.
IN39
SPEC.LAB IIH59
PROGRAM NO
. 1280202
PLATE HO.
CE-I309
FOR'
NOHAHED 3.
8.
HOLYLE
DATE' 09/17/80
JOSEPH L.
HARRIS
U B.
CRANOELL
D. U.
COLIGHTLY
(ANALYST)
(PLATE RECORDER)
(PROJECT LEADER)
FIELD
1 SANPLE
SPECTRUH
81 AL FE HG CA HA K TI P NN AC
AS Atl
B BA BE BI CO CE CO CR CU OY ER EU GA CD GE HF NO IN IR LA LI LU HN HO HB NO NI
x * % J{ 55 %^ 5
5 * J5 *
PPH
PPH
PPH
PPH
PPH
PPH
PPH
PPH
PPH
PPH
PPH
PPH
PPH
PPH
PPH
PPH
PPH
PPH
PPN
PPH
PPH
PPH
PPH
PPH
PPH
PPH
PPH
PPH
PPH
PPH
IN
X-130916
16
328.6
6.2
2. 1
3.0
2.3
1.3
0.23
0. 13
0. 14
< 0.10
< 190
< 10 20
630 2.0
< 10
< 32
< 63 18
140 3J
< 22
< 10
< 2.
2
21<
19<
1 .9
< 19
< 6 .8
< 6.8
< 19 19
< 68
< 19
1400
< 1 .0
16<
32 94
2H
X-130917
17
348.2
9.0
1.7
2.4
3.0
1 .9
0.27
0. 11
0. 13
< 0.10
< 190
< 10 14
640 1
.9<
10<
32 96 20 130 48
< 22
< 10
< 2.2
17<
19<
1 .9
< 19
< 6.8
< 6 .8
< 19 23
< 68
< 19
1300
< 1 .0
9.7
< 32 99
3H
X-130918
18
32 8.3
C.4
1.8
2.3
2.7
1 .8
0.24
0.14
0.16 < 0.
10
< 19
0<
to 16990 1
.7<
10<
32<
43 22
170 49
< 22
< 10
< 2.2
18<
19<
1 .9
< 19
< 6.8
< 6 .8
< 19 19
< 68
< 19
1600
< 1 .0
10<
32 97
4H
X- 1309 19
19
297.1
7.9
2.0
2.9
2.0
0.98
0.94
0.14
0.17 < 0.
10
< 19
0<
10 18490 1.
9<
10<
321 10 27
320 48
< 22
< 10
< 2.2
17<
19<
1.9
< 19
< 6.8
< 6.8
< 19 46
< 68
< 19
1700
< 1.
017
< 32 98
9H
X-130920
24
307.8
6.4
1.9
2. 1
2.4
1 .6
0.29
0. 14
0. 18 < 0.
10
< 19
0<
10 1997
0 2. 1
< 10
< 32
< 43 23 190
32<
22
< 10
< 2.2
17<
19<
1.9
< 19
< 6.8
< 6. 8
< 15 22
< 68
< 19
1800
< 1.0
19<
32 60
6H
X-130921
21
328.2
6.7
1.8
2.3
2.4
1.6
0.32
0. 14
0.20 <
0 .10
< 19
0<
10 21970 2.3
< 10
< 32 90 22 160 49
< 22
< 10
< 2.2
17<
19<
1 .9
< 19
< 6 .8
< 6 .8
< 19 29
< 68
< 19
2000
< 1 .0
13<
32 98
7N
X-130922
22
317.2
9.8
1 .9
2.1
2.0
0.99
0.29
< 0.068
0.22 < 0.10
< 19
0<
10 2042
0 2.0
< 10
< 32
< 43 23 130 32
< 22
< 10
< 2.2
16<
19<
1 .9
< 19
< 6.8
< 6.8
< 19 24
< 68
< 19
2200
< 1 .0
7 .3
< 32 97
8H
X-130923
23
327.7
9.9
2.3
2.9
3.0
0.72
0.24
< 0.068
0 .17
0.26
< 19
0<
10 12460 1
.2<
10<
32<
43 29
300
390
< 22
< 10
< 2.2
16<
19<
1 .9
< 19
< 6.8
< 6 .8
< 19
< 10
< 68
< 19
1700
< 1 .0
6 .3
< 32
1 10
9H
X-130924
24
296.9
9.9
1 .7
2.0
2.4
1 .9
0.34
0.19
0.14 < 0. 10
< 19
0<
10 17970 2.
1<
10<
32<
43 21
140 33
< 22
< 10
< 2.2
16<
19<
1.9
< 19
< 6.8
< 6.8
< 19 29
< 68
< 19
1400
< 1.
01
1<
32 97
ION
X-130929
29
287.0
6.8
2.4
2.4
2 .3
1 .4
0.32
0. 12
0. 19
< 0,
< 19
0<
10 11490 1
< 10
< 32 99 29
360 33
< 22
< 10
< 2.
17<
19<
1<
19<
6.
< 6.
< 19 24
< 68
< 19
1900 1
,8.
< 32 89
10 7 2 9 8 8 2 4
TABLE
3. CONCENTRATIONS OF ELEMENTS DE7ERNINEO BY
0 1REC T-CURRENT ARC EfllSSIOH SPECTROCRAPHY--CONTI NUEO .
JOB HO. IH39 PAGE
1-B
FIELD
ISAMPLE
SPECTRUM
OS PPM
PB PPM
PO PPM
PR PPM
PT PPM
RE PPM
ftH
PPM
RU PPM
SB PPM
SC FPM
SH PPM
SH PPM
SR PPM
TA PPM
Tfl
PPM
TH PPM
TL PPM
TN PPM
U PPM
V PPM
V PPM
Y PPM
YB PPM
ZN PPM
ZR PPM
INX-1309U
16 < 22 120
< 1 .0
< 68
< 4.
6
< 10
< 2.2
< 2.2
< 32 14
< 10
< 1.5
240
< 460
< 32
< 22
< 4.
6<
4.6
< 320
100
< 10 193.0
74250
MAJORS RECALCULATED
8102
XAL203
51FE203
*MCO
SiCAO
X
NA20
*K20
*TI02
XP209
5tMHO
5t
69 168.9
3.5
4.2
3. 1
1.6
0.38
0.30
0. 18
2NX-130917
17 < 22 60
< 1 .0
< 68
< 4 .6
< 10
< 2.2
< 2 .2
< 32 17
< 10
< 1 .5
390
< 460
< 32
< 22
< 4 .6
< 4.6
< 320 80
< 10 19 2.5
56120
AS OXIDES
73 167.2
2.8
3.4
4.0
2.3
0.45
0.25
0. 17
3HX-130918
IB < 22 91
< 1 .0
< 68
< 4.6
< 10
< 2.2
< 2.2
< 32 15
< 10
< 1 .5
360
< 460
< 32
< 22
< 4.6
< 4.6
< 320 91
< 10 15 2.5
6618
0
69 169.2
3.0
3.2
3.6
2.2
0.40
0 .3
20.21
4MX-130919
19 < 22 39
< 1.
0<
68<
4.6
< 10
< 2.2
< 2.2
< 32 24
< 102.8
480
< 460
< 32
< 22
< 4.6
< 4.6
< 320
150
< 10 304.
487
240
62 13 11 3.3
3.5
2.7
1 .2
0.90
0.32
0.22
5HX-130920
20 < 22 32
< 1.
0<
68 < 4.6
< 10
< 2.2
< 2.2
< 32 18
< to
< 1.5
340
< 460
< 32
< 22
< 4.6
< 4.6
< 320
110
< 10 203.2
74280
64 15 9.2
3.2
2.9
3.2
1 .9
0.48
0.32
0.23
6HX-130921
21 < 22 40
< 1 .0
< 68
< 4 .6
< 10
< 2.2
< 2.2
< 32 18
< 102.1
430
< 460
< 32
< 22
< 4 .6
< 4 .6
< 320
110
< 10 213.9
99
190
69 169.6
3.0
3.2
3.2
1.9
0.53
0.32
0.26
7NX-130922
22 < 22 34
< 1 .0
< 68
< 4.6
< 10
< 2.2
< 2.2
< 32 19
< 10
< 1 .5
400
< 460
< 32
< 22
< 4.6
< 4.6
< 320
110
< 10 19 3.0
7819
0
66 148.3
3.2
2.9
2.7
1.2
0.48
< 0.
16
0.28
BHX-130923
23 < 22
120
< 1 .0
< 68
< 4 .6
< 10
< 2.2
< 2.2
< 32 15
< 10 3.3
380
< 460
< 32
< 22
< 4.6
< 4.6
< 320 87
< 10 13 2.2
7810
0
69 157.9
3.8
4 .1
4.0
0.87
0 .40
< 0.16
0.22
9HX-130924
24 < 22 49
< 1.
0<
68<
4.6
< 10
< 2.2
< 2.2
< 32 19
< 10
< 1.
5400
< 460
< 32
< 22
< 4.
6<
4.6
< 320 93
< 10 213.
192
170
62 13 7.9
2.8
2.8
3.2
1 .6
0.57
0.34
0.18
ION
X-130923
25 < 22 26
< 1.
< 68 < 4.
< 10
< 2
< 2.
< 32 17
< 10
< 1
.32
0<
460
< 32
< 22
< 4.
< 4.
< 32
0100
< 10 16 2.81 140
60 13 9.7
4 .0
3.4
3.1
1 .7
0.53
0.28
0.25
0 6 2 2 5 6 6 4
1. THE RELATIVE STANDARD DEVIATION FOR EACH REPORTED CONCENTRATIOH IS PLUS 50% AND MINUS 33*.
TABLE
3.
CONCENTRATIONS OF ELEMENTS DETERMINED BY DIRECT-CURRENT ARC EMISSION SPECTROCRAPHV--CONTINUEO.
PAGE
2-A
REPORT
JOB NO.
SPEC. LAB
FIELD
1 SAMPLE
SPECTRUM
SI
*AL
*FE
tNC
*CA
*
HA
*K
* *
TI
*P
*NN
*
AC PPM
Ai PPN
AU PPN
B PPN
BA PPM
BE PPN
BI PPN
CD PPN
CE PPN
CO PPN
CR PPN
CU PPN
DY PPN
ER PPN
EU PPN
GA PPN
CD PPN
CE PPN
NF PPM
HO PPN
IH PPN
IR PPH
LA PPN
LI PPN
LU PPH
HN PPN
HO PPN
NB PPN
ND PPN
NI PPN
INS9
.IIH39 HH
X-131004
4
326.9
9.9
1.8
3.3
27
4.96
0. 19
0. 13
0. 14 < 0.10
< 190
< 10 23
370 1
.7<
10<
32<
43 17
170 69
< 22
< 10
< 2 .2
19<
19<
1 .9
< 19
< 6.8
< 6.8
< 19 17
< 68
< 19
1400
< 1
012
< 32 9i
i
PROGRAH NO
PLATE NO.
12H
X-131009
9
338.
19.8
1.7
2. 1
1.7
1.6
0.23
< 0.068
0.14 < 0.10
< 130
< 10 38
470 2
.3<
10<
32<
43 19
120 32
< 22
< 10
< 2.2
19<
19<
1 .9
< 19
< 6.8
< 6.8
< 19 18
< (8
< 19
1400
< 1 .0
13<
32 92
. 1280202
CE-1310
13N
X-131006
6
32 8.0
7.1
2.2
3.8
2.6
0.93
0.23
0.16
0.17 < 0.
10
< 130
< 10
< 6.8
980 2.0
< 10
< 32
< 63 29
180 68
< 22
< 10
< 2.2
18<
19<
1 .9
< 19
< 6.8
< 6.8
< 19 18
< 68
< 19
1700
< 1 .0
13<
32 74
FORi
NOHANED S. S. HOLYLE
DATEt 09/17/80
14H
19H
16H
X-131007
X-131008
X-131009
7
317.4
6 .9
1.8
2.7
2.7
1 .6
0.27
< 0.068
0.14 < 0.10
< 190
< 10 17
720 1 .8
< 10
< 32
< 43 23
190 90
< 22
< 10
< 2.2
22<
19<
1.9
< 19
< 6.8
< 6.8
< 19 18
< 68
< 19
1400
< 1.0
6.8
< 32 60
8
348.4
6.0
2.0
2.8
3.0
1 .9
0.21
0. 16
0. 18 < 0.
10
< 19
0<
10 1743
0 2.0
< 10
< 32
< 63 20 190 47
< 22
< 10
< 2.2
20<
19<
1.9
< 19
< 6.8
< 6.8
< 19 12
< 68
< 19
1800
< 1.
09.9
< 32 60
9
236.9
9.2
3.3
2.2
2.3
0.69
0.22
0. 11
0. 12
< 0.10
< ISO
< 10 10
300
< 1 .0
< 10
< 32
< 43
23
290 91
< 22
< 10
< 2.2
16<
19<
1 .9
< 19
< 6 .8
< 6 .8
< 19 12
< 68
< 19
1200
< 1 .0
9.7
< 32 190
17H
X-131010
10
308.7
6.9
2.6
1.6
2.3
1.9
0.24
0.20
0. 19
< 0.10
< 190
< 10 28
990 2.3
< 10
< 32
< 43 26
140 49
< 22
< 10
< 2.2
23<
19<
1 .9
< 19
< 6 .8
< 6.8
< 19 19
< 68
< 19
1900
< 1 .0
14<
32 61
JOSEPH L
. HARRIS
(AHALYS1
U. B. CRAHDELL
(PLATE RECORDER
D. U. COLI6HTLY
(PROJECT LEADER
18H
I9H
20H
X-131011
X-131012
X-131013
11
30 107.4
3.9
3.2
2.3
1 .9
0.40
< 0.068
0.19
0. 1
7<
190
< 10 36
680
< 1.
0<
10<
32<
43<
1.0
190 70
< 22
140
< 2.2
22<
19<
1 .3
< 19
< 6.8
< 6.8
< 19 22
< 68
< 19
1900
< 1 .0
< 3.2
< 32 79
12
328.6
6.1
2.4
2.3
2 .6
1 .9
0.33
0.17
0.13 < 0.
10
< 190
< 10 19
910 2.
1<
10<
32<
43 27
170 47
< 22
< 10
< 2.
2
23<
19<
1.9
< 19
< 6.8
< 6.8
< 19 22
< 68
< 13
1300
< 1.
011
< 32 81
13
289.9
7.0
2.7
3.9
3.3
1 .3
0.39
0. 19
0.20 < 0.
< 19
0<
10 34340 1
.<
10<
32<
63 34 190 44
< 22
< 10
< 2.
30<
13<
1.16
< 6
< 6
< 19 20
< 68
< 19
2000
< 1
11<
32 100
10 9 2 9 8 8 0
TABLE
3. CONCENTRATIONS OF ELENENT8 DETERNINED BY DIRECT-CURRENT ARC EMISSION SPECTROGRAPHY--CONTIHUED.
JOB NO. IH39 PAGE
2-8
FIELD
1SAMPLE
SPECTRUH
OS PP
HPB
PP
HPD
PPH
PR PP
MPT PPM
RE PPM
RM PP
MRU
PPM
SB PP
MOf ^PM
w w
I*TT M
SH PP
MSN
PP
M911
PPH
TA PP
HTB PP
H
TH PP
HTL PP
HTH
PPH
U PP
MV
PPM
U PPM
Y PPH
YB PP
HZH
PPH
ZR PP
H
11H
X-131044
4
< 22 47 <
1 .4
< 68 < 4 .6
< 14
< 2.2
< 2.2
< 32 12
< 14
< 1.3
370
< 46
0<
32
< 22
< 4.6
< 4.6
< 32
0 94
< 10 143.
474 69
12N
X-131045
3
< 22 23
< 1 .0
< 68
< 4 .6
< 14
< 2.
2<
2.2
< 32 14
< 10
< 1.3
240
< 46
0<
32
< 22
< 4 .6
< 4.
6<
320 97
< 10 19 3.
177
200
13H
X-131406
6 < 22 71
< 1 .0
< 68
< 4.
6
< 14
< 2.
2<
2.2
< 32 18
< 14
< 1 .9
714
< 464
< 32
< 22
< 4.
6<
4.6
< 324
110
< 10 16 3.
494
220
14H
X-131447
7
< 22 89
< 1.4
< 68
< 4.6
< 10
< 2.2
< 2.
2<
32 14
< 14
< 1.
937
0<
464
< 32
< 22
< 4.6
< 4.
6<
324
114
< 10 14 2.
683 93
19H
X-131408
8
< 22 97 < 1.
0<
68 < 4.6
< 14
< 2.2
< 2.
2<
32 13
< 14
< 1.9
934
< 464
< 32
< 22
< 4.6
< 4.
6<
320
100
< 10 12 2.
883 94
16H
X-131449
9
< 22 12
< 1
< 68 < 4
< 10
< 2
< 2
< 32 19
< 14
< 1
270
< 46
0<
32
< 22
< 4
< 4
< 320 88
< 14 142
88 96
.0 .6 .2 .2 .9 .6 .6 .4
17H
X-131014
10 < 22 38
< 1
< 68
< 4
< 10
< 2
< 2
< 32 17
< 10
< 1
190
< 46
0<
32
< 22
< 4
< 4
< 324
1 10
< 14 16 3
114
230
.0 .6 .2 .2 .9 .6 .6 .7
18M
X-131411
11 < 22 29
< 1 .4
< 68
< 4 .6
< 14
< 2.
2<
2.2
< 32 20
< 14 11
234
< 46
4<
32
< 22
< 4.
6<
4.6
< 32
011
0
< 10 17 4
.21 10
130
19H
X-13141
12 < 22 94
< 1.
< 68
< 4.
< 14
< 2.
< 2.
< 32 24
< 14 2.
900
< 460
< 32
< 22
< 4.
< 4.
< 32
0140
< 10 19 3.89
140
2 0 6 2 2 9 6 6 9
24H
X-131013
13 < 22 44 < 1.0
< 68 < 4.6
< 10
< 2.2
< 2.
2<
32 17
< 14
< 1.
9324
< 464
< 32
< 22 < 4.6
< 4.6
< 32
4134
< 14 17 3.
312
010
0
HAJOR8 RECALCULATED AS OXIDES
8102
AL203
FE203
HGO
CAO
NA20
K20
T102
P209
HNO
* 51 51 51 51 * 51 51 * *
69 12 8. 3. 4. 3. 1. 0. 4. 0.
4 0 6 6 2 32 30 18
71 19 8 2. 2, 2. 1. 0<
0 4,
.3 .8 9 3 .9 38 . 16 18
69
19
10 3 9 3 0 0 0 0
.7 .3 .9 .64
.38
.37
.22
66 149 3 3 3 1 0
< 0 0
.3 .0 .8 .6 .9 .43
.16
.18
73 16 8.6
3.3
3.9
4 .4
1 .8
0.33
4.37
0.23
34 137.4
3.3
3. 1
3.1
0.78
4.37
0.29
4. 16
64 169 4 2 3 1 4 0 4
.9 .3 .2 . 1
.8 .40
.46
. 19
64 19
119 4 3 1 4
< 0 4
.8 .9 .1 .8 .67
.16
.19
69 16 8.7
4 .0
3.2
3.9
1.8
0.99
0.39
0.17
60 19 104.9
9.9
4.9
1.8
0.98
0.34
0.26
1. TNE RELATIVE STANDARD DEVIATION FOR EACH REPORTED CONCENTRATION IS
PLUS 34* AND MINUS 33*.
2. MAGNESIUM DETERMINED VISUALLY IN SPECTRUH 111.
TABLE 3.
CONCENTRATIONS OF ELEMENTS DETERMINED BY DIRECT-CURRENT ARC EMISSION 3PECTROCRAPHY--CONTIHUED.
PAGE
3-A
REPORT
JOB
HO.
IH39
8PEC.LA8.IIH39
FIELD
I 21N
SAMPLE
X-1310M
SPECTRUM
14
SI AL FE MC CA HA K TI P NH AC AS AU B BA BE BI CD CE CO CR CU DV ER EU CA CD CE HF HO IN IR LA LI LU HN MO NB HD HI
ft ft ft ft ft ft*ft ft ft ft
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPH
PPM
PPM
PPM
PPH
PPH
PPM
PPH
PPH
PPH
PPH
PPH
PPH
PPH
PPH
PPH
PPH
PPH
PPH
PPH
329.4
6.8
2.4
2.2
2.0
1.3
0.33
< 0
068
0 14 <
0.14
< 19
0<
10 94 90
\
1 .9
< 10
< 32
< 43 28 130 47
< 22
< 10
< 2.
2
24<
19<
1 .9
< 19
< 6 .8
< 6.
8<
19 26<
£8<
19
1400 <
1 .0
6.9
< 32 76
PROGRAM NO
PLATE NO.
22H
X-131019
19
29 107.3
2.6
2.9
1.7
1.9
0.36
0.20
0.17 < 0 .1
0<
190
< 10 36
730 2.
4<
10<
32<
43 31
140 8.
2<
22<
10<
2.2
29<
13<
1 .9
< 13
< 6 .8
< 6 .8
< 13 23
< 68
< 13
1700
1 .2
18<
32 87
. 1280202
CE-1310
23N
K-131016
16
30 10 3.4
2.7
2.8
2.2
1 .8
0.23
0.19
0.19 <
0. 10
< 13
0<
10 46620 2.
3<
10<
32<
63 28 170 32
< 22
< 10 2.
8
26<
19<
1 .9
< 19
< 6 .8
< 6 .8
< 13 11
< 68
< 19
1300
< 1 .0
19<
32 76
FORi
24H
X-131017
17
226.6
9.1
2.4
8.3
2.3
0.72
0.24
0.18
0.21 <
0. 10
< 190
< 10 27
440 1.
2<
10<
32<
63 19
110 92
< 22
< 10
< 2.
2
14<
19<
1.9
< 13
< 6.
8
< 6.8
< 19 29
< 68
< 19
2100
< 1.
09.
3<
32 40
NOHAHED 8.
8.
HOLYLE
DATE
i 09/17/80
23H
26H
X-131018
X-131019
18
319.4
7.2
2.3
2. 1
2.6
1 .6
0.31
< 0.068
0. 16 < 0. 10
< 13
0<
10 30 900 2.
0<
10<
32 84 29 170 63
< 22
< 10
< 2.2
22<
13<
1 .3
< 13
< 6.
8
< 6.8
< 13 21
< 68
< 13
1600 <
1 .0
14<
32 79
19
309.3
7.0
2.4
2.0
2.0
1.8
0.37
< 0.068
0. 13 < 0.10
< 13
0<
10 3836
0 2.1
< 10
< 32 76 29
130 69
< 22
< 10
< 2.2
22<
13<
1 .3
< 13
< 6.8
< 6.8
< 13 27
< 68
< 13
1300 <
1 .0
12<
32 71
27H
X-131020
20
224.9
3.7
3.3
3.3
2.3
0.28
0.21
0. 11
0.23 <
0.10
< 130
< 10 49
320
< 1 .0
< 10
< 32
< 63 28
380 66
< 22
< 10
< 2.
2
12<
19<
1.9
< 19
< 6.
8
< 6.
8<
19 13<
68<
19
2300
< 1 .0
< 3.
2<
3216
0
JOSEPH L.
HARRIS
(ANALYST
U. 8.
CRANDELL
(PLATE RECORDER
0.
V. GOLICHTLY
(PROJECT LEADER
28H
29H
IS
X-131021
X-131022
X-131023
21
327.
96.
32.
70.80
2.7
1 .1
0.28
< 0.068
0.048
< 0.
10
< 190
< 10 19
330 1
.4<
10<
32<
43 30
240 32
< 22
< 10
< 2.
2
17<
19<
1.3
< 13
< 6.8
< 6.8
< IS
< 10
< 68
< 19
480
< 1 .0
8.9
< 32
160
22
328.
36.1
2.3
2.6
2.3
1.3
0.31
< 0.068
0.13 <
0. 10
< 190
< 10 39
640 2.
2<
10<
32<
43 29
130 93
< 22
< 10
< 2.2
21<
19<
1.3
< 13
< 6.
8
< 6.
8<
13 26<
68<
13
1300
< 1.0
11<
32 34
23
227.
64.
90.
231 .3
9.8
4.9
0.20
0.097
0.33 <
0.<
130
< 10
< 4.
600 2.
< 10
< 32
< 43 <
1 .
< 1.
14<
22<
103.
39<
13<
1
< 13
< 6.
< 6.
< 13 39
< 68
< 13
3300
< 1.
67 393
10 6 6 0 0 1 3 8 8 0 ,8
TABLE 3.
CONCENTRATIONS OF ELEMENTS DETERMINED BY D IRECT-CURREMT ARC EMISSION SPECTROGRAPHY--CONT1NUED
J08 NO. IN99 PACE
3-B
FIELD I
SAMPLE
SPECTRUM
OS PPM
Pfl
PPM
PO PPM
PR PPM
PT PPM
RE PPM
RH PPM
RU PPM
sa .PP
M8C
«HPP
M
8M PPM
8N PPM
SR PPM
TA PPM
T8 PPM
TN PPM
TL PPM
TN PPM
U PPM
V PPM
U PPM
Y PPM
YB PPM
ZN PPM
ZR PPM
21N
X-131014
14 < 22 26
< 1 .0
< 68
< 4 .6
< 10
< 2.2
< 2.2
< 32 20
< 10
< 1 .5
. 230
< 440
< 32
< 22
< 4.6
< 4.6
< 32
0no
< 10 22 3.7
100
100
MAJORS RECALCULATED
8102
*AL203
*FE203
*MGO
*CAO
X
NA20
XK20
XTI02
XP2Q3
XMHO
9:
69 189.
74.
03.
1
2.7
1.8
0.98
< 0. 16
0. 18
22N
X-131019
19 < 22 27
< 1 .0
< 68
< 4.6
< 10
< 2.2
< 2.2
< 32 22
< 10
< 1 .9
400
< 460
< 32
< 22
< 4.6
< 4.6
< 320
110
< 10 234.3
94140
AS OXIDES
62 19 104.3
4. 1
2.3
1.8
0.60
0.46
0.22
23H
X-131016
16 < 22 39
< 1 .0
< 6B
< 4.6
< 10
< 2 .2
< 2.2
< 32 17
< 10
< 1 .9
120
< 46
0<
32
< 22
< 4.6
< 4.6
< 32
010
0
< 10 16 3.6
100
220
64 197.
74.9
3.9
3.0
2.2
0.38
0.44
0.19
24H
X-131017
17 < 22 43
< 1.
0<
68<
4.6
< 10
< 2.2
< 2.
2<
32 14
< 10
< 1.
9440
< 460
< 32
< 22
< 4.6
< 4.6
< 320 83
< 10 193.
2120
160
47 13 7.3
4.0
12 3.1
0.87
0.40
0.41
0 .27
29H
X-131018
18 < 22 30
< 1.0
< 68
< 4.6
< 10
< 2.2
< 2.2
< 32 18
< 101.7
410
< 460
< 32
< 22
< 4.6
< 4.
6<
320
120
< 10 193.
810
0140
66 18 10 4 .
12.9
3.3
1 .9
0.92
< 0. U
0.21
26N
X-131019
19 < 2222
< 1 .0
< 68
< 4.6
< 10
< 2.2
< 2.2
< 32 22
< 102.3
390
< 460
< 32
< 22
< 4 .6
< 4.6
< 320
140
< 10 244 .0
120
210
64 18 104.0
2.8
2.7
2.2
0.62
< 0. 16
0. 17
27M
X-131020
20 < 22 37
< 1 .0
< 68
< 4.6
< 10
< 2.2
< 2.
2<
32 14
< 10
< 1 .9
270
< 460
< 32
< 22
< 4 .6
< 4.
6<
320 70
< 10 111 .9
83 92
479.3
9.3
9.9
7.4
3.4
0.34
0.39
0.29
0.30
28N
X-131021
21 < 22 19
< 1 .0
< 68
< 4.6
< 10
< 2.2
< 2.2
< 32 18
< 10
< 1.9
160
< 46
0<
32
< 22
< 4.6
< .4.6
< 320
100
< 10 16 2.9
93190
69 199 .0
4 .9
1 . 1
3 .6
1 .3
0.47
< 0.16
0 .062
29H
X-131022
22 < 22 94
< 1.0
< 68
< 4
6
< 10
< 2.2
< 2.
2<
32 17
< 101.
7290
< 460
< 32
< 22
< 4.6
< 4.6
< 320
110
< 10 214.3
120
160
69 16 8.7
3.8
3.6
3.1
1 .8
0.92
< 0.
16
0.17
ISX-131023
23 < 228.8
< 1.0
< 68
< 4.6
< 10
< 2.2
< 2.
2<
328.8
< 10 9.9
99<
460
< 32
< 22
< 4.6
< 4.6
< 32
0<
1.0
< 10 193. 1
120
230
47 147.0
0. 38
1 .8
13 9.9
0.33
0.22
0.43
1. THE RELATIVE STANDARD DEVIATION FOR EACH REPORTED CONCENTRATION IS PLUS 90% AND MINUS 33X.
TABLE 3.
CONCENTRATIONS OF ELEMENTS DETERMINED BY DIRECT-CURRENT ARC EMISSION SPECTROCRAPHY--CONTIHUED.
PAGE
4-A
REPORT
JOB NO
. IN99
SPEC. LAB. IIN99
FIELD
1 2S
SANPLE
X-131144
SPECTRUM
4
SI
*AL
*FE
*NC
*Cf
t *
NA
. >.
K * *
TI
XP
*HN
>.
AC PPH
AS PPN
AU PPH
6 PPN
BA PPN
BE PPH
BI PPM
CD PPM
CE PPH
CO PPH
CR PPH
CU PPN
DY PPH
ER PPH
EU PPH
GA PPH
CD PPH
GE PPH
HF PPN
HO PPH
IN PPH
IR PPN
LA PPN
LI PPN
LU PPN
NN PPH
HO PPH
NB PPH
NO PPN
HI PPN
28 144.9
4.33
2.6
129.
44.29
< 4.468
4.23 < 4.19
< 19
9<
19<
4 .6
1994 2.
8<
14<
32 124 1
.9
6.9
2<S
< 22
< 104.
4
36 22
< 1 .9
< 19
< 6.8
< 6.8
< 19 43
< 68
< 19
2344 1
.814
4<
32 1 1
PROGRAN HO
PLATE NO.
38
X-131149
9
298.3
6.9
9. 11
4.89
9.4
9.4
4. 18
< 4.468
4.31 < 4.14
< 199
< 19
< 6.8
199 9.3
< 19
< 32 98
< 1 .9
3.9
16<
22<
19<
2 .2
96<
19<
1 .9
< 19
< 6.8
< 6.8
< 19 99
< 68
< 19
3199
< 1 .9
199 993.7
. 1280242
CE-1311
48
X-131146
6
24 114 .7
4 .2
32.1
119.6
9.16
9.12
4.24 < 4. 14
< 19
9<
19<
4.6
92
3.6
< 19
< 32
1 19 2.9
8.2
31<
22<
19<
2.2
49<
19<
1 .9
< 19
< 6 .8
< 6.8
< 19 64
< 68
< 19
2444 1
.313
9<
32 11
FOR)
NOHANED S.
S. HOLYLE
DATE! 99/17/84
9S
68
78
X-131107
X-131108
X-131149
7
29 12 4.9
4.31
2.3
B.4
9.9
4.22
4.493
9.21 < 4. 19
< 194
< 14
< 4.6
224 7.4
< 14
< 32
244 2.
1
9.4
16<
22<
14<
2.2
44 19<
1.9
< 19
< 6.8
< 6.8
< 19 97
< 68
< 19
2104
< 1.4
194 939.
1
8
39 11 3. 1
9.23
1 .6
11 6.1
9. 13
9.987
9.21 <
0. 19
< 19
9<
197.
I229 4.8
< 19
< 32
< 43 1.
8
3.7
12<
22<
19<
2.2
48<
19<
1.9
< 19
< 6.8
< 6.8
< 19 33
< 68
< 19
2199
< 1.9
139
< 32S.4
9
299.9
3.9
4. 11
1. 1
9.4
9.3
4.13
< 9.468
4.18 < 4. 14
< 19
4<
14<
4 .6
194 1
.9<
14<
32 129 1
.3
6.7
16<
22
< 19
< 2.2
41<
19<
1 .9
< 19
< 6.8
< 6 .8
< 19 69
< 68
< 19
1899
< 1 .9
71 736
.2
JOSEPH L.
HARRIS
(ANALYST
U.
B. CRANDELL
(PLATE RECORDER
D. U.
GOLIGHTLY
(PROJECT LEADER
88
98
198
118
X-131119
X-131111
X-131112
X-131113
19
28 114.
69.37
1.8
116.4
9.23
< 4.468
4. 18 < 4.14
< 19
4<
14<
4.6
129 3.8
< 19
< 32 99
1 .8
3.8
19<
22<
19<
2.2
36<
19<
1 .9
< 19
< 6.8
< 6.8
< 19 97
< 68
< 19
1899 1
.2149
< 324 .7
11
39 114 .9
9.93
2.6
199.3
4.23
4.19
4.462
< 4
. 14
< 194
< 14 8.3
1799 3.6
< 19
< 32
114 1 .8
4. 1
14<
22<
14 4.9
39<
19<
1 .9
< 19
< 6.8
< 6.8
< 19 92
< 68
< 19
629 3.9
199
< 324 .3
12
289.8
9.8
9.19
2.8
9.4
4.9
9.23
9.971
9.33 < 9. 19
< 19
9<
19<
4.6
464 4.9
< 14
< 32
184 1.
9
14 37<
22<
14<
2.2
49<
19<
1.9
< 19
< 6.8
< 6.8
< 19 78
< 68
< 19
3349 1 .4
139 38 19
13
31 13 9.4
9.34
2.4
9.4
9.2
4. 19
4.496
9.22 < 4.
< 19
4<
14<
4.294 2.
< 14
< 32 49 1. 3.
14<
22<
142.
34<
19<
1.<
19<
6.
< 6.
< 19 33
< 68
< 19
2299
< 1.
69<
324
19 6 1 2 9 6 9 8 8 9 .9
TABLE 3.
CONCENTRATIONS OF ELEMENTS DETERMINED BY DIRECT-CURRENT ARC EMISSION SPECTROGRAPHY--CONTINUED.
JOB NO. IN39 PAGE
4-8
FIELD
I8AHPLE
SPECTRUM
08 PPM
PB PPM
PD PPN
PR PPM
PT PPN
RE PPM
RH PPM
RU PPM
SB .PP
HSC*PPH
SN PPN
SH PPN
SR PPM
TA PP
NTB PPN
TH PPN
TL PPH
TH PPH
U PPN
V PPH
U PPN
Y PPH
YB PPN
ZN PPN
ZR PPN
28X-131104
4
< 22 13
< 1 .0
< 68
< 4.6
< 19
< 2.2
< 2.
2<
326.8
< 10 3.8
369
< 46
0<
32
< 22
< 4.
6<
4 .6
< 32
0 4 .7
< 10 192.5
70330
MAJORS RECALCULATED
8102
AL203
FE203
HGO
CAO
NA20
K20
TI02
P209
XHNO
1
60 197.0
0.93
3.6
166.0
0.42
< 0. 16
0.30
38X-131105
5
< 22 14
< 1.0
< 68
< 4 .6
< 10
< 2.2
< 2.2
< 323.7
< 10 17 33
< 460
< 32
< 22
< 4.6
< 4.6
< 320 2.4
< 10 204.0
99340
AS OXIDES
62 169.3
0.18
1.3
126.3
0.30
< 0. 16
0.40
48X-131106
6
< 22 20
< 1.0
< 68
< 4.6
< 10
< 2.2
< 2.2
< 323.4
< 10 9.3
49<
460
< 32
< 22
< 4.6
< 4 .6
< 320 1
.4
< 10 229.2
130
370
31 21 .7
0.38
2.9
13 .8
0 .2
70.28
0.31
38
X-131 107
7
< 22 20
< 1.0
< 68
< 4.«
< 10
< 2.2
< 2.2
< 324.6
11 13<
19<
460
< 32
< 22
< 4.6
< 4.6
< 320 3.
9
< 10 419.9
891300
62 237.
00.31
3.2
11 6.6
0.37
0.21
0.27
68X-131108
8
< 229.2
< 1.0
< 68
< 4.6
< 10
< 2.2
< 2.
2<
322.3
< 10 10
100
< 460
< 32
< 22 < 4.
6<
4.6
< 320 3.
2
< 10 193.
473
610
64 214 .4
0.38
2.2
13 7.4
0 .2
20 .2
00.27
78X-131 109
9
< 227.3
< 1 .0
< 68
< 4.6
< 10
< 2.2
< 2.2
< 322.2
< 107.
161
< 460
< 32
< 22
< 4 .6
< 4 .6
< 320 2.3
< 10 23 3.3
92
280
62 193.6
0. 18
1.9
126.4
0.22
( 0. 16
0.23
88X-131110
10 < 229.8
< 1 .0
< 68
< 4.6
< 10
< 2.2
< 2.2
< 325.7
< 10 10 87
< 46
0<
32
< 22
< 4.
6<
4 .6
< 32
0 2.3
< 10 222 .9
69380
60 216.
60.61
2.3
157.7
0.38
< 0.
16
0.23
98X-1311 1
111 <
22 11<
1 .0
< 68
< 4.6
< 10
< 2.2
< 2.2
< 326.7
< 10 5.3
370
< 460
< 32
< 22
< 4.6
< 4 .6
< 320 2.7
< 10 232.9
6461
0
64 217.0
0.88
3 .6
136 .4
0 .3
80 .3
40.080
10S
X-131 112
12 < 22 12
< 1.
0<
68
< 4.
6
< 10
< 2.2
< 2.2
< 323.6
< 10 21
< 13
( 460
< 32
< 22
< 4.6
< 4.6
< 320 2.
3
< 10 329.2
90790
60 19 8.3
0.32
3.9
12 3.9
0.38
0.16
0.43
1 IS
X-131 11
13 < 22 11
< 1.
< 68
< 4.
< 10
< 2.
< 2.
< 323.
< 106.
38<
460
< 32
< 22
< 4.
< 4.
< 320 2.
< 10 112.
90 120
66 257.2
0.96
2.8
12 6.3
0.32
0.22
0.28
3 0 6 2 2 7 1 6 6 0 4
1. TNE RELATIVE STANDARD DEVIATION FOR EACH REPORTED CONCENTRATION IS
PLUS 50% AND NINUS 33k
2. SODIUN DETERMINED VISUALLY IN
SPECTRA I'S 4,7,10.11 AND 13
.
TABLE
3.
CONCENTRATIONS OF ELEMENTS DETERMINED BY DIRECT-CURRENT ARC EMISSION SPECTROCRAPHY--CONTIHUED.
PAGE
3-A
REPORT
JOB
NO.
IN99
SP
EC. LA
B .I
IN99
FIELD I
128
SAMPLE
X-131114
SPECTRUM
14
81 AL FE HG CA NA K TI P HN AG AS AU B BA BE BI CD CE CO CR CU DY ER EU GA GO GE HF HO IN IR LA LI LU NN NO MB NO HI
X * * k k 55«r
5s % % *
PPH
PPH
PPH
PPH
PPH
PPH
PPH
PPH
PPH
PPH
PPH
PPH
PPH
PPH
PPH
PPH
PPH
PPH
PPH
PPH
PPH
PPH
PPH
PPH
PPM
PPH
PPH
PPH
PPH
PPN
28 143.
94.
231 .4
129.9
4. 18
< 4.468
4.21 <
4.14
< 19
4<
14<
4.6
88
9.2
< 14
< 32 134 1
.3
3.4
12<
22<
14<
2.2
41<
19<
1 .9
< 19
< 6.8
< 6.8
< 19 79
< 68
< 19
2144
< 1 .4
144 433.
2
PROGRAM NO
PLATE NO.
138
X-131113
19
27 147.4
1.2
4.5
113.2
4. 37
4.29
4.23 < 4.14
< 19
4<
14<
6.B
2444 3.
1<
14<
32 79 9.4
12 28<
22<
14 5.9
33<
15<
1 .9
< 13
< 6.
8
< 6.
8<
13 44<
68<
15
2344
1 .9
68<
32 11
. 1284242
CE-1311
148
X-131116
16
28 145.
24.15
1.6
11 6 .2
4.13
< 4.
468
4 .24 < 4.
14
< 13
4<
14<
4.6
72
7.6
< 14
< 32
184 1 .3
3 .4
22<
22<
14<
2.2
99<
19<
1 .9
< 19
< 6.8
< 6 .8
< 19 94
< 68
< 19
2444 < 1.
426
4 974 .4
FORi
158
X-13
1 117
17
34 12 5.3
4.27
2.5
9.4
9.4
4.17
4.14
4.22 < 4.
14
< 19
4<
14<
4.6
484 4.
8<
14<
32234 3.
7
6.4
144
< 22
< 14
< 2.2
48<
19<
1.9
< 13
< 6.
8
< 6.
8<
19114
< 68
< 19
22447.
233
0 996.
4
HOHAHED S.
S. HOLYLE
DATE
i 49/17/84
168
178
X-131118
X-131119
18
29 14 4.8
4.22
1 .8
14 5.4
4.24
< 4.468
4.24 < 4. 14
< 194
< 14
< 4.
6164 4.
2<
14<
32284 1.
9
6.6
17<
22<
14<
3.2
41 49<
1.9
< 19
< 6.
8
< 6.
8<
13 130
< 68
< 15
2440
< 1.0
144
94 3.2
19
24 114.4
4.65
2.9
8.4
4.7
4.31
4. 16
4. 19 < 4 .1
4<
154
< 14
< 4.6
1444
2.9
< 14
< 32
< 633 .9
23 18<
22<
14<
2.2
33 39<
1 .3
< 13
< 6.
8
< 6.8
< 13 69
< 68
< 19
1944 <
1 .4
88<
326.
1
188
X-131124
24
228.
94.3
4.17
1.7
9.4
3.2
4.26
4.487
4.29 < 4.
14<
194
< 14 8.
9444 3.
2<
14<
32344 1
.6
6.2
14<
22<
14<
2.2
34 96<
1 .9
< 19
< 6.8
< 6.
8<
15 72<
68<
19
2944
< 1 .4
74 414.
2
JOSEPH L.
HARRIS
(ANALYST)
U.
B. CRANDELL
(PLATE RECORDER)
D. U. GOLIGHTLY
(PROJECT LEADER)
19S
248
21S
X-131121
X-131122
X-131123
21
349.
77 .2
4.492
4.17
9.4
9.7
4.24
< 4.468
4.23 < 4.
14
< 194
< 14
< 4.6
144 7.
4<
14<
3216
4<
1 .4
3.2
12<
22<
14 3.4
92<
19<
1 .9
< 15
< 6.8
< 6.8
< 19 93
< 68
< 15
2344 <
1 .4
204 894 .2
22
329.
29.4
4.496
4.74
7.3
3.9
4.12
< 4.468
4.25 < 4. 14
< 19
4<
14 9.4
214 7.
9<
14<
3219
4<
1.4
3.9
16<
22<
14<
2.2
49<
19<
1.9
< 19
< 6.
8
< 6.8
< 13 87
< 68
< 13
2944
< 1.
0214 963.9
23
289.
34.
44.28
1.9
8.4
4.9
4. 19
< 4.468
4.21 <
4<
134
< 14
< 4
174 3
< 14
< 32 96
1 3 13<
22<
14<
2.
36<
13<
1.<
13<
6.
< 6.
< 13 34
< 68
< 13
2144 <
1.86
< 323.
. 14
.6 .4 .4 .9 2 9 8 8 4 8
TABLE
3. CONCENTRATIONS OF ELEMENTS DETERMINED BY DIRECT-CURRENT ARC EMISSION SPECTROCRAPHY--COMTIMUED.
JOB NO. IN99 PAGE
3-B
FIELD
SAMPLE
SPECTRUM
OS PPM
PB PPM
PO PPH
PR PPH
PT PPH
RE PPN
RH PPH
RU PPM
SB PPH
SC FPH
SH PPH
SN PPM
SR PPH
TA PPH
TB PPH
TH PPH
TL PPH
TH PPH
U PPM
V PPH
U PPH
Y PPH
YB PPH
.ZH PPM
ZR PPH
12S
X-131114
14 < 22 16
< 1 .0
< C9
< 4 .6
< 10
< 2.
2<
2.2
< 322.7
< 10 13 26
< 464
< 32
< 22
< 4.
6<
4.6
< 320 2.
3
< 10 279.
199
300
HAJQRS RECALCULATED
SI02
*AL203
*FE203
*MCO
*CAO
Jt
HA20
XK20
*T102
*P203
XHNO
>.
60 199.
60.38
2.0
166.6
0. 30
< 0. 16
0.27
138
X-1311 19
19 < 22 14
< 1 .0
< 68
< 4.6
< 10
< 2.2
< 2.2
< 329.3
< 10 3.7
710
< 460
< 32
< 22
< 4.6
< 4.6
< 320 33
< 10 13 2.2
77220
AS OXIDES
98 27 102.0
6.3
133.9
0.62
0.37
0.30
14S
X-13U16
16 < 22 16
< 1 .0
< 68
< 4 .6
< 10
< 2.2
< 2.2
< 322.0
11 23 49<
460
< 32
< 22
< 4.6
< 4.6
< 320 1
. 1
< 10 343.7
9110
00
60 197.4
0.23
2.2
137.3
0.22
< 0.16
0 .2
6
198
X-131 117
17 < 22 19
< 1.0
< 68
< 4.6
< 10
< 2.2
< 2.2
< 323.0
16 19260
< 460
< 32
< 22
< 4.6
< 4.6
< 320 3.
7
< 10 468.9
120
2400
64 237.
60.43
3.9
12 6 .5
0.28
0 .32
0.28
168
X-131 118
18 < 22 1?
< 1.0
< 68
< 4.
6
< 14
< 2.2
< 2.2
< 324.9
13 14 98<
460
< 32
< 22
< 4.6
< 4.6
< 32
0 2.8
< 10 416.0
120
470
62 19 6,9
0.37
2.3
13 6.0
0 . 3
3<
0. 1
60. 31
178
X-131 119
19 < 229.6
< 1 .0
< 68
< 4 .6
< 10
< 2.2
< 2.2
< 327.4
< 109.1
440
< 460
< 32
< 22
< 4.6
< 4 .6
< 320 7
,7
< 10 263.
082
420
31 216.3
1 . 1
4. 1
113.
70. 92
0.37
0.23
188
X-131120
20 < 227 .6
< 1 .0
< 68
< 4 .6
< 10
< 2.2
< 2.2
< 323.9
< 10 4
.012
0<
460
< 32
< 22
< 4 .6
< 4.6
< 320 2.4
< 10 283.
272
370
47 176.2
0.28
2. 4
123.
90.
4 J
0.20
0.32
198
X-131121
21 < 22 19
< 1 .0
< 68
< 4.6
< 10
< 2.2
< 2.2
< 329.4
10 14 41<
460
< 32
< 22
< 4.6
< 4 .6
< 320 3.3
< 10 396.0
120
690
64 18 100.19
0.24
126 .9
0.40
< 0.16
0.30
208
X-131122
22 < 22 14
< 1.
0<
68<
4.6
< 10
< 2.2
< 2.2
< 323.7
12 16 41<
460
< 32
< 22
< 4.6
< 4.6
< 320 3.0
< 10 489.9
180
770
69 177.7
0 . 1
61 .0
9 .9
4.2
0 .20
< 0 .1
60.32
218
X-13U23
23 < 227.
1<
1.0
< 68 < 4.
6
< 10
< 2.2
< 2.2
< 324.
1
< 104.3
99<
460
< 32
< 22
< 4.
6<
4.6
< 320 1.
6
< 10 232.9
7340
0
60 18 9.7
0.46
2. 1
11 3.9
0 .3
?<
0. 16
0.27
1. THE RELATIVE STANDARD DEVIATION FOR EACH REPORTED CONCENTRATION IS
PLUS 50% AND MINUS 33*.
2. SODIUM DETERMINED VISUALLY IH
SPECTRA l'3 14,15
, \ 7,
19 ,20,2 1
AND 23.
TABLE
3.
CONCENTRATIONS OF ELEMENTS DETERNIHED BY DIRECT-CURRENT ARC EMISSION SPECTROGRAPHY--CONT INUEO
PACE
6-A
00
REPORT
JOB 110.
SPEC. LAB
FIELD
tSAMPLE
SPECTRUM
SI
%AL
*
FE
*MC
XCA
*
MA
.*K
^55
TI
*P
*NN
X.
AC PPM
AS PPN
AU PPM
B PPM
BA PPN
BE PPM
Bl PPN
CD PPM
CE PPN
CO PPM
CR PPM
CU PPN
DY PPN
ER PPN
EU PPN
CA PPM
CD PPM
CE PPN
HF PPN
HO PPN
IN PPN
IR PPN
LA PPN
LI PPN
HI PPN
NH PPN
NO PPN
NB PPN
ND PPN
HI PPN
INS9
.IIN59 22S
X-131204
4
31 117.
00.29
1.9
104.7
0.21
< 0.068
0.45 <
) 10
< 15
0<
10<
6.8
1300 6.
6<
10<
32300 1
.2
7.8
20<
22 17<
2.2
43 39
< 1 .5
< 15
< 6.8
< 6 .8
< 15
130
< 68
< 15
4500
< 1 .0
300
120 5.
1
PROGRAM NO
PLATE NO.
. 1280202
CE-13J2
FOR)
HOHANED S.
S
DATEt 09/1
. HOLYLE
7/80
JOSEPH
L . HARRIS
(ANALYST
U.
B. CRANDELL
(PLATE RECORDER
D. U.
COLUHUY
(PROJECT LEADER
239
X-131205
5
30 144.8
0.22
2.2
9.0
5.4
0.22
< 0.068
0.28 < 0.10
< 150
< 10
< 6 .8
220 2.
1<
10<
32120 1
.2
7.4
17<
22<
10<
2.2
50<
15<
1 .5
< 15
< 6.8
< 6 .8
< 15 41
< 68
< 15
2800
< 1 .0
51 335.2
24S
X-131206
6
30 114.3
0.34
1.8
8.0
3.7
0 .26
< 0.068
0.19 < 0
. 10
< 15
0<
10<
4 .6
1700
2.0
< 10
< 32 88
1 .5
6.5
14<
22<
10 3.9
31<
15<
1 .5
< 15
< 6.8
< 6.8
< 15 42
< 68
< 15
1900
< 1 .0
40<
324 .4
258
X-131207
7
30 12 4.2
0.36
1.4
7.5
5.6
0 .27
< 0.068
0.24 < 0.10
< 15
0<
10 12960 1 .8
< 10
< 32
140 1 .3
6,8
18<
22<
103.9
35<
15<
1.5
< 15
< 6.8
< 6.8
< 15 54
< 68
< 15
2400
< 1.0
38 474.8
26S
X-13J208
8
33 16 3.5
0.27
1 .2
7.5
5.0
0.30
0.090
0. 1
1 < 0.10
< 15
0<
10<
4.6
1600 2.2
< 10
< 32 832.9
4 .3
13<
22<
104.7
38<
15<
1 .5
< 15
< 6.8
< 6.
8<
15 40<
68<
15
1 10
0<
1.0
62 82 11
27S
X-131209
9
29 118.0
0.24
3.2
9.0
5. 1
0.21
< 0.068
0.21 < 0.10
< 150
< 10
< 6.8
1100 4
.0<
10<
32
170
< 1 .0
6 .7
20<
22<
103.
7
45
< 15
< 1 .5
< 15
< 6.8
< 6 .8
< 15 68
< 68
< 15
2100
< 1 .0
84 474 .6
28S
X-131210
10
319.3
9. 1
0.24
1 .5
7.5
4.2
0.22
< 0.068
0.39 < 0.10
< 15
0<
10<
6 .8
350 5.9
< 10
< 32
210 1
.4
18 50<
22<
10 4 .3
46 20<
1 .5
< 15
< 6.8
< 6 .8
< 15 85
< 68
< 15
3900
< 1 .0
150 71 18
29S
X-13121 1
11
34 14 120.27
1 .7
9 .0
4 .8
0 .3
0<
0.068
0 .4
6
< 0. 10
< 150
< 10
< 6 .8
1700
7.6
< 10
< 32
270 5.
1
44110
< 22
< 10 3.9
67 15<
1.5
< IS
< 6.8
< 6.8
< 15
110
< 68
< 15
4600 10
200 91 19
308
X-131212
12
32 12 7.2
0.31
2.0
8.0
3.5
0.26
0.095
0.26 < 0.10
< 15
0<
10<
6.8
720 6.0
< 10
< 32
370 4.
2
29 48<
22<
10<
2. 2
46 64<
1.5
< 15
< 6.8
< 6.8
< IS
ISO
< 68
< 15
2600
< 1.
017
0140 14
3IS
X-13121
13
31 11 7.2
0.22
1 .
1
8.0
3.9
0 . 3
0<
0.068
0.32 < 0.
< 150
< 10
< 6.
1900 4.
< 10
< 32
210 1. 6.16
< 22
< 105.
48 24 < 1.
< 15
< 6.
< 6.
< 15 84
< 68
< 15
3200
< 1.
75 140 5.
3 10 8 3 4 6 4 5 8 8 0 8
TABLE
3. CONCENTRATIONS OF ELEMENTS DETERMINED BY DIRECT-CURRENT ARC EMISSION 9PECTROGRAPHY--COHTIHUED.
JOB NO. IH39 PAGE
6-B
FIELD
SAMPLE
I 22S
X-131204
SPECTRUM
4
OS PPM
PB PPM
PD PPM
PR PPM
PT PPM
RE PPM
RN PPM
RU PPM
SB PPM
SC PPH
SN PPM
SH PPM
SR PPM
TA PPM
TB PPM
TN PPM
TL PPM
TM PPM
U PPM
V PPM
U PPM
Y PPM
YB PPM
2M PPM
ZR PPM
MAJORS
8102
AL203
FE203
MGO
CAO
NA20
K2D
T 10
2P2D3
MNO
< 22 19
< 1 .0
73<
A .6
< 10
< 2 .2
< 2.
2<
32
v1
1
169.9
120
< 4(0
< 32
< 22
< 4 .6
< 4 .6
< 320 1
.9
< 10 739.2
120
1300
RECALCULATED
* 66
* 21
* 10
* 0.48
* 2.
7
* 13
* 3.7
* 0.35
9! <
0. 16
35 0.58
239
X-131205
3
< 229.3
< 1 .0
< 68
< 4 .6
< 10
< 2.2
< 2.2
< 324 .3
< 10 4
.433
< 460
< 32
< 22
< 4 .6
< 4 .6
< 320 1
.4
< 10 14 26
96240
AS OXIDES
64 276.9
0.37
3. 1
126.3
0.37
< 0. 16
0.36
249
X-131206
6 < 226.8
< 1 .0
< 68
< 4 .6
< 10
< 2.2
< 2.2
< 327.6
< 10
1 .6
410
< 460
< 32
< 22
< 4 .6
< 4 .6
< 320 2.3
< 10 18
1 .6
63230
64 216.2
0.56
2 .5
1 1 4 .5
0 .4
3<
0 .1
60 .2
3
259
X-13120?
7
< 228.0
< 1.0
< 68
< 4.6
< 10
< 2.2
< 2.2
< 328.9
< 10
< 1.
373
< 460
< 32
< 22
< 4.6
< 4.
6<
320 1 .9
< 10 21
1 .3
86190
64 236 .0
0.60
2 .0
10 6.8
0 .45
< 0 .1
60.31
26S
X-131208
8
< 22
< 6.8
< 1.
0<
68<
4.6
< 10
< 2.2
< 2.
2<
327.2
< 10
1 .6
320
< 46
0<
32
< 22
< 4.
6<
4.6
< 32
0 2.9
< 10 192.
141
310
71 303.0
0.43
1 .7
10 6.0
0 . 30
0.21
0. 14
278
X-131209
9
< 229.2
< 1 .0
< 68
< 4 .6
< 10
< 2.2
< 2.2
< 32 14 102.8
60
< 460
< 32
< 22
< 4.
6<
4.6
< 320 1
.6
< 10 263.
392
440
62 21 110. 40
4.3
126. 1
0.33
(0.16
0.27
289
X-131210
10 < 22 13
< 1 .0
< 68
< 4 .6
< 10
< 2 .2
< 2.2
< 327 .4
11<
1 .5
32<
460
< 32
< 22
< 4.6
< 4 .6
< 32
0 2.5
< 10 406.0
140
770
66 18 130.40
2. 1
103.
10.37
< 0.
16
0. 50
293
X-13121 1
11 < 22 21
< 1 .0
< 68
< 4 .6
< 10
< 2.2
< 2.2
< 326.4
13 21 69<
460
< 32
< 22
< 4 .6
< 4.
6<
320 6.
3
< 10 446.8
200
960
73 27 1 7 0.43
2.4
123.8
0 .5
0<
0 .1
60.59
309
X-131212
12 < 22 13
< 1.
079
< 4.6
< 10
< 2. 2
< 2.
2<
328. 1
16 21120
< 460
< 32
< 22
< 4.6
< 4.6
< 320 3.
3
< 10 536.
7130
680
69 23 10 0.51
2.8
11 4.2
0 .4
30.22
0.34
318
X-131213
13 < 22
< 6.8
< 1.
0<
68<
4.6
< 10
< 2.2
< 2.
2<
32 17
< 103.1
120
< 46
0<
32
< 22 < 4.
6<
4.6
< 32
0 1 .9
< 10 393.9
80490
66 21 10 0.37
1 .3
11 4 .7
0.30
< 0. 16
0.41
1. THE RELATIVE STANDARD DEVIATION FOR EACH REPORTED CONCENTRATION IS
PLUS 50% AND MINUS 33%.
2. SODIUM DETERMINED VISUALLY IN
SPECTRA I'S 4,3,6,7,8,9,10,11,12 AND 13
.
TABLE
3.
CONCENTRATIONS OF ELEMENTS PETERNIHED BY DIRECT-CURREHT ARC EMISSION SPECTROGRAPH Y--CONT I
HUED
PACE
7-A
INi O
REPORT
JOB HO.
INS 9
SPEC. LAB .IIH59
FIELD
1 32S
SAMPLE
X-131214
SPECTRUM
14
81
*AL
*
FE
XHG
X
CA
X
NA
XK
*X
TI
>.P
XMH
>.
AC PPM
A8 PPM
AU PPM
B PPH
BA PPM
BE PPH
Bl PPH
CD PPH
CE PPH
CO PPN
CR PPH
CU PPH
DY PPH
ER PPM
EU PPN
CA PPH
CD PPH
CE PPM
HF PPM
HO PPM
IN PPM
IR PPH
LA PPH
LI PPH
LU PPM
MH PPN
HO PPH
HB PPN
ND PPH
HI PPM
33 105.4
4. IS
1.6
8.0
4.9
0. 18
< 0.0(8
0. 1
3 < 0.10
< 15
0<
10 13410 5.
5<
10<
32 140 1
.2
7.2
17<
22<
10<
2.2
SO 19<
1 .5
< 15
< 6 .8
< 6 .8
< 15 82
< (8
< 15
1300
< 1 .0
70 754 .0
PROCRAN HO
PLATE NO
.
338
X-131215
15
> 34 14S.5
0. 16
I .7
9.0
S.9
0. 18
0.072
0. 18
< 0.10
< 150
< 10 5.9
300 6.3
< 10
< 32
210 2
.3
11 23<
22 11<
2 .2
39 39<
1 .5
< 15
< 6 .8
< 6 .8
< 15 88
< 68
< 15
1800 3
.1140 684 .9
. 1280202
CE-1312
34S
X-131216
It
33 125.5
0.14
0.66
8 .0
5.0
0.15
< 0.068
0.14 < 0
. 10
< 150
< 10 14
240 6.
1<
10<
3212
0 1 .4
8 .9
20<
22<
10<
2 .2
52<
IS<
1 .5
< 15
< 6 .8
< 6.8
< 15 63
< 68
< 15
1400
< 1 .0
92 725.9
FOR >
35S
X-131217
17
> 34 12 7
.6
0.14
1 .3
8.0
4.9
0.11
< 0.068
0.18 < 0. 10
< 150
< 10 19 87
7.9
< 10
< 32
130 1
. 1
7.8
22<
22<
102. 2
63<
19<
1.9
< 13
< 6.8
< 6.8
< 15 78
< 68
< 13
1800
< 1.0
160 903.2
NOHAHED S.
8. HOLYLE
DATEl 09/17/80
368
378
X-131218
X-131219
18
33 11 4 .8
0.33
3. 1
7.3
4 .0
0.20
< 0.068
0.21 < 0. 10
< 150
< 10
< 4.6
2000 4 .0
< 10
< 32 110 1 .4
6.4
20<
22<
105. 9
50<
IS<
1 5
< 13
< 6
8
< 6. 8
< 13 60
< 68
< 13
2100
< 1.0
68 666.
0
19
32 111
. 1
0.062
0.21
8.0
S.2
0.082
< 0.068
0.013
< 0.10
< 190
< 10
< 4 .6
1 100 2.4
< 10
< 32
< 43
< 1 .0
4 .2
9.2
< 22
< 103 .8
37
< 13
< 1.5
< 13
< 6 .8
< 6
.8<
15 41<
68
< 13
130
< 1 .0
23 553
.S
38S
X-131220
20
33 143.3
0.43
1 .7
8.0
4.3
0. 14
< 0.068
0.23 < 0.10
< 130
< 10
< 6.8
690 4
.5<
10<
32160 1
.1
11 35<
22<
10<
2 .2
91<
15<
1 .5
< 15
< 6 .8
< 6 .8
< 15 33
< 68
< 15
2500
< 1 .0
68 406 .7
JOSEPH
L . HARRIS
(ANALYST
U.
8. CRAMHELL
(PLATE RECORDER
D. U. GOLICHTLY
(PROJECT LEADER
39S
40S
41S
X-131221
X-131222
X-131223
21
> 34 104 .9
0.12
0 .5
4
7 .3
4 .5
0.11
< 0.068
0.048
< 0. 10
< 150
< 10 5.2
120 11
< 10
< 32
260 1
.3
14 30<
22 14 3. 1
60<
15<
1 .3
< 13
< 6 .8
< 6 .8
< 15
140
< 68
< 15
480
< 1
. 0250
140 6
. 7
22
33 14 3.2
0.18
0 .6
2
10 5.4
0.097
< 0.068
0.063
< 0. 10
< 150
< 10
< 4.
S440 2.3
< 10
< 32 48
< 1.
0
7. 2
18<
22<
10<
2.2
54<
IS<
1.9
< 15
< 6.8
< 6.8
< 15 24
< 68
< 13
630
< 1.
023 334.5
23
32 15 5.4
0. 16
0.80
8.0
4.3
0.26
< 0.068
0.35 < 0.
< 15
0<
10<
6.640 3.
< 10
< 32 160 1
.
7.19
< 22
< 103.
43 21<
1.<
13<
6.
< 6.
< 13 37
< 68
< 13
3300
< 1.
45 765.
10 8 0 4 4 8 5 8 8 0 0
TABLE
3. CONCENTRATIONS OF ELENEHT8 DETERMINED BY DIRECT-CURRENT ARC ENIS8ION SPECTROGRAPHY--CONTINUED.
JOB HO. 1NS3 PACE
7-B
FIELD
1Sf
tHPL
ESPECTRUH
OS PPH
PB PPN
PD PPH
PR PPH
PT PPH
RE PPH
RH PPH
RU PPH
SB PPH
SC *PH
SH PPH
SH PPH
SR PPH
TA PPH
TB PPH
TH PPH
TL PPH
TH PPH
U PPH
V PPH
y PPH
Y PPH
YB PPH
ZN PPH
ZR PPM
328
X-131214
14 < 229.8
< 1 .0
< 68
< 4 .6
< 10
< 2.2
< 2.2
< 322.9
< 107 .9
75<
460
< 32
< 22
< 4
.6<
4 .6
< 320 1
.0
< 10 346.6
170
430
HAJORS RECALCULATED
SI02
*AL203
*FE203
*HCO
*CAD
'4
NA20
XK20
55T102
>.P203
*NNO
*
71 197.
70.25
2.2
1 1 9.9
0.30
< 0. 16
0. 17
33S
X-131215
15 < 22 12
< 1 .0
< 68
< 4.6
< 10
< 2.2
< 2.2
< 323.7
11 8 .5
1 10
< 460
< 32
< 22
< 4 .6
< 4.6
< 320 4
.2
< 10 437.9
140
820
AS OXIDES
> 73 277.9
0.27
2.4
127. 1
0.30
0.17
0.23
349
X-131216
16 < 22 22
< 1 .0
< 68
< 4 .6
< 10
< 2.2
< 2.2
< 322.2
< 10 30 66
< 460
< 32
< 22
< 4.6
< 4.6
< 320 2.2
< 10 316.6
130
460
71 237 .9
0.23
0.92
1 1 6.0
0.23
< 0.16
0.18
35S
X-13121 7
17 < 22 19
< 1.
0<
68<
4.6
< 10
< 2.2
< 2.2
< 32
1 .4
10 27300
< 460
< 32
< 22
< 4.
6<
4.6
< 320 3.
7
< 10 349.3
180
800
> 73 23 11 0.23
1 .8
11 3.9
0.18
< 0.16
0.23
368
X-131218
18 < 22 13
< 1.
0<
68<
4.6
< 10
< 2.2
< 2. 2
< 329.7
< 103.5
260
< 460
< 32
< 22
< 4.6
< 4.6
< 320 3.3
< 10 296.3
140
300
71 216.9
0 .35
4.3
10 4 .8
0. 33
< 0. 16
0.27
37S
X-131219
19 < 22 12
< 1 .0
< 6B
< 4.6
< 10
< 2.2
< 2 .2
< 323.
7
< 104 .0
48<
460
< 32
< 22
< 4 .6
< 4 .6
< 320 1
.4
< 10 182
.171 180
69 211 .6
0. 1
00.29
116.3
0. 14
< 0.16
0.017
38S
X-131220
20 < 22 14
< 1 .0
< 68
< 4.6
< 10
< 2.2
< 2.2
< 324.8
< 10 10 68
< 460
< 32
< 22
< 4 .6
< 4.6
< 320 1
.3
< 10 286.0
180
370
71 277.9
0.71
2.4
113.2
0.23
< 0.16
0.32
393
X-131221
21 < 22 17
< 1 .0
< 68
< 4.6
< 10
< 2.2
< 2.2
< 322.6
18 20 44<
460
< 32
< 22
< 4 .6
< 4 .6
< 32
0 4.9
< 10 67 16
100
1100
> 73 197.0
0 .20
0.76
103.
40.18
< 0.16
0 .0
62
408
X-131222
22 < 22
< 6.8
< 1.
0<
68<
4.6
< 10
< 2.2
< 2. 2
< 322.4
< 102.4
46<
460
< 32
< 22
< 4.6
< 4
. 6<
320 1.
3
< 10 162. 1
32180
71 274.6
0 .30
0.87
13 6.3
0.16
< 0.16
0.084
41S
X-131223
23 < 229.
< 1.
< 68
< 4
< 10
< 2.
< 2.
< 32 14
< 103,
56<
460
< 32
< 22
< 4
< 4
< 32
0 1
< 10 233
82250
69 287.7
0.27
1 .
1
11 5.4
0.43
< 0. 1
60.45
0 0 6 2 2 6 6 6 5 .2
1. THE RELATIVE STANDARD DEVIATION FOR EACH REPORTED CONCENTRATION IS PLUS 30* AND H1NUS 33*.
2. 30D1UIK SPECTRfl I'S
1 4, 1
3, 16 ,
1 7 ,1 8
, 1 9, 20,
21
, 22
, 23 )
AND ST
ROII
T IUH< SPECTRUH 117) HERE DETERMINED VISUALLY.
TABLE
3.
CONCENTRATIONS OF ELEMENTS DETERMINED BY DIRECT-CURRENT ARC EMISSION SPECTROCR APHY- -CONT I
NUED .
PACE
8-A
ro
ro
REPORT
JOB NO .
SPEC. LAB
FIELD
1 8ANPLE
SPECTRUM
81
*AL
XFE
*NC
>.CA
>.
NA
. *
K *X
TI
XP
XHN
X
AC PPM
AS PPM
AU PPM
B PPM
BA PPM
BE PPM
61 PPN
CD PPM
CE PPN
CO PPM
CR PPN
CU PPN
DY PPN
ER PPM
EU PPN
CA PPN
CD PPN
GE PPM
HF PPN
HO PPN
IN PPN
IR PPN
LA PPN
LI PPN
LU PPN
HN PPN
NO PPN
NB PPN
ND PPM
NI PPN
IN93
.IIN39 428
X-131304
4
34 136.
20.
312.9
1 1 9. 1
4.24
0 11
4.21 <
0.10
< 190
< 10
< 6.8
1900 2.
2<
10<
32 110 2
.9
6 .6
21<
22<
10<
2.2
4? 19<
1 .9
< 15
< 6 .8
< 6 .8
< IS 26
< 68
< 19
2100
< 1 .0
59<
324 .9
PROGRAM NO.
1280202
PLATE NO
. CE-1313
436
448
X-131309
X-131306
9
> 349.4
9.3
0.079
0.71
9.6
4. 1
4.10
< 0.068
0. 19
< 0.10
< 19
0<
10 6.4
240 11
< 10
< 32
200
< 1 .0
7.1
21<
22<
10<
2.2
61 19<
1 .5
< 15
< 6.8
< 6 .8
< 19 87
< 68
< 19
1900 4
.9230 719 .3
6
34 1 1 6 .5
0.17
2.0
9.9
9 .0
0.19
< 0.068
0.31 < 0. 10
< 190
< 10
< 6.«
340 4
.6<
10<
32120 1 .3
8 .9
19<
22<
10 2.9
91<
19<
1 .9
< 19
< 6 .8
< 6 .8
< 19 41
< 68
< 19
3100
< 1 .0
84<
329 .0
FOR)
HOHANED S.
S. HOLYLE
DATE« 09/17/00
498
468
478
X-131307
X-131308
X-131309
7
> 34 12 7.
40.19
1 .5
9.9
4 .8
0.26
< 0.068
0.17 < 0.
10
< 15
0<
10<
6.8
910 9.9
< 10
< 32
1 10
1 .8
4.2
16<
22<
102.9
96<
19<
1.9
< 15
< 6.8
< 6.8
< 19 49
< 68
< 19
1700
< 1.
0100
< 324.5
8
27 10 9.0
0.27
4.6
8.3
3.2
0 .93
0.34
0.37 < 0.10
< 15
0<
10<
6.8
300 6.
0<
10<
32260 8.9
4.3
18<
22
< 103.0
96 18<
1 .3
< 19
< 6.8
< 6.8
< 19
140
< 68
< 19
3700 2.3
230
110 4.9
9
> 34 1
1 6.6
0. 1
61.
4
8.5
4.3
4.20
< 0.066
0.34 < 0.10
< 150
< 10
< 6.8
360 4.
2<
10<
32 130 1
.4
6 .6
20<
22<
10<
2.2
92 19<
I .5
< 19
< 6 .8
< 6 .8
< 19 99
< 68
< 13
3400
< I .0
62 695 .7
488
X-131310
10
33 128.
60.57
3. 1
7.3
3.0
0.51
< 0.068
0.20 < 0.10
< 19
0<
10<
6.8
790 6.
1<
10<
32180 4
.6
11 23<
22<
10<
2.2
43 30<
1 .5
< 13
< 6.8
< 6 .8
< 15
110
< 68
< 13
2000
< 1 .0
160 908.3
JOSEPH
L . HARRIS
(ANALYST
U.
B. CRANDELL
(PLATE RECORDER
0. y.
COL1GHTLY
(PROJECT LEADER
498
308
318
X-131311
X-131312
X-131313
11
32 116.6
0.20
2.8
103.
10.17
< 0.068
0.32 < 0.
10
< 13
0<
10<
4 .6
230 2.
7<
10<
32 341 .6
8.4
19<
22<
10 2.2
48<
IS<
1 .3
< 15
< 6.8
< 6 .8
< 15 27
< 68
< IS
3200 1
.3S3
< 324
. 7
12
> 34 14 3
.3
0.14
1 .2
9.2
4 .3
0.20
0.081
0.13 < 0. 10
< 130
< 10
< 6.8
760 1 .4
< 10
< 32
< 43
< 1.
0
6.4
18<
22<
102.3
39<
13<
1.3
< 13
< 6.8
< 6.8
< 13 34
< 08
< 13
1300
< 1.
040 444.6
13
> 34 13 4
.60.21
2.8
10 3.6
0. 1
9<
0.068
0.24 < 0,
< 13
0<
106
410 4.
< 10
< 32 94
1 .
6.19
< 22
< 10
< 2.
SO<
IS<
1.<
IS<
6.
< 6.
< IS 41
< 68
< 13
2400
< 1.
190
< 324.
10 6 9 2 7 2 3 8 8 0 6
TABLE
3. CONCENTRATIONS OF ELEMENTS DETERMINED BY DIRECT-CURRENT ARC EMISSION SPECTROGRAPHY--CONTIHUED
JOB NO. IN33 PACE
8-B
OJ
FIELD
SAMPLE
SPECTRUM
OS PPM
PB PPM
PD PPM
PR PPM
PT PPM
RE PPM
RN PPM
RU PPM
OB DO M
9 I
f |Tr n
8C 4PM
8N PPM
8N PPM
8R PPM
TA PPM
TB PPM
TH PPM
TL PPM
TM PPM
U PPM
V PPM
M PPM
Y PPM
YB PPM
ZN PPM
ZR PPM
428
X-131304
4
< 22 14
< 1 .0
< 68
< 4 .6
< 10
< 2.
2<
2.2
< 32
,
9 .6
< 10 17 130
< 460
< 32
< 22
< 4 .6
< 4.
6<
320 8
.1
< 10 142 .3
9320
0
MAJORS RECALCULATED
SI02
XAL203
XFE203
XHGO
XCAO
X
HA20
XK20
'/.TI02
XP203
XHHO
*
73 238. 9
0.51
4. 1
136. 1
0.40
0.23
0.27
43S
X-131303
3
< 22 23
< 1 .0
< 68
< 4 .6
< 10
< 2.2
< 2.2
< 32
1 .3
11 24 42<
460
< 32
< 22
< 4 .6
< 4.6
< 32
0 1 .9
< 10 479 .8
190
1700
AS OXIDES
> 73 187.6
0. 12
0.99
134.9
0. 17
< 0. 16
0. 23
448
X-131306
6
< 228.4
< I .0
< 68
< 4 .6
< 10
< 2.2
< 2.2
< 32 6.0
< 10 34 73
< 46
0<
32
< 22
< 4.6
< 4 .6
< 320 2.4
< 10 273.8
too
280
73 219.3
0.28
2.8
136.0
0.32
< 0.16
0 .4
0
43S
X-131307
7
< 22 12
< 1.0
< 68
< 4.
6
< 10
< 2.
2<
2.2
< 324.8
< 106.7
82<
460
< 32
< 22
< 4.6
< 4.6
< 320 4.
1
< 10 263.9
140
400
> 73 23 11 0
.32
2.1
13 3.8
0 .43
< 0.16
0 .22
46S
X-131308
8
< 22 20
< 1.
0<
68
< 4.
6
< 10
< 2.2
< 2.2
< 32 10 17 18
190
< 46
0<
32
< 22
< 4.6
< 4.6
< 320 34
< 10 739.3
170
1300
38 19 13 0. 43
6 . 4
11 3.9
0 . 8
80
. 78
0 . 4
8
47S
X-131309
9
< 228.2
< 1 .0
< 68
< 4
.6
< 10
< 2.2
< 2.2
< 326 .0
< 10 28 74
< 460
< 32
< 22
< 4 .6
< 4 .6
< 320 2.3
< 10 343 .0
140
280
) 73 219.4
0.27
2.0
113.4
0.33
< 0.
16
0.44
48S
X-131310
10 < 22 14
< 1 .0
< 68
< 4 .6
< 10
< 2.
2<
2.2
< 32 17 12 23
260
< 46
0<
32
< 22
< 4 .6
< 4 .6
< 320 3.7
< 10 688.6
140
1200
71 23 120.93
4. 3
103.6
0.83
< 0.
16
0. 26
498
X-13131 1
11 < 22 11
< 1 .0
< 68
< 4.6
< 10
< 2.2
< 2.2
< 324 .9
< 10
-93 75
< 46
0<
32
< 22
< 4.6
< 4 .6
< 32
0 2.2
< 10 16 3.3
130
290
69 219
.40 .33
3.9
136.1
0 .28
< 0
. 16
0.41
308
X-131312
12 < 229.
8<
1.0
< 68
< 4.6
< 10
< 2.2
< 2.2
< 326.
9
< 109.9
73<
460
< 32
< 22
< 4.6
< 4.6
< 320 2.
1
< 10 132.6
79160
> 73 277.
60.23
1 .7
12 3 .4
0.33
0.19
0.17
318
X-13131
13 < 22 12
< 1
.<
68<
4.
< 10
< 2.
< 2.
< 323.
< 108.
130
< 46
0<
32
< 22
< 4.
< 4.
< 32
0 2.
< 10 283.
170
1300
> 73 236.6
0.33
3.9
13 6.8
0. 32
< 0
. 16
0. 31
3 0 6 2 2 9 9 6 6 1 5
1. TNE RELATIVE STANDARD DEVIATION FOR EACH REPORTED CONCENTRATION IS PLUS 50* AND MINUS 33'X.
2. SODIUM DETERMINED VISUALLY IN SPECTRA I'S 4,7,8/9,10 AND 11.
TABLE
3.
CONCENTRATIONS OF ELEMENTS PETERNIHED BY DIRECT-CURRENT ARC EMISSION SPECTRQGRAPHY--COMTINUED.
PAGE
9-A
ro
REPORT
JOB HO.
IM59
SPEC. LAB .IIN93
FIELD
I 52
8 SAMPLE
X-1313M
SPECTRUM
14
SI
>.AL
*
FE
X.NC
XCA
*
HA
*K
* *
TI
*P
*HH
*
AC PPM
AS PPM
AU PPM
B PPM
BA PPM
BE PPM
BI PPM
CD PPM
CE PPM
CO PPM
CR PPM
CU PPM
DY PPM
ER PPM
EU PPM
GA PPM
CD PPM
GE PPN
HF PPN
HO PPM
IN PPM
1R PPN
LA PPN
LI PPM
LU PPM
NN PPN
NO PPN
NB PPM
NO PPN
NI PPN
34 103.6
0. 12
1.2
« *
A. 1
0. 19
< 0.066
0. 19 < 0 .1
0<
130
< 10
< 4 .6
380 7.
6<
10<
32200 1
.1
7.1
19<
22<
102.
2
41<
15<
1 .5
< 15
< 6.8
< 6.8
< 15
120
< 66
< 15
1900 <
1 .0
140
130 4
.4
PROGRAM HO
. PLATE HO
.
538
X-131313
15
33 134.3
0.22
2.6
105.0
0.20
< 0.068
0.32 < 0.10
< 150
< 10
< 4 .6
320 6
.0<
10<
32170 1
.3
6 .6
16<
22<
10<
2.2
48 19<
1 .5
< 15
< 6 .8
< 6 .8
< 15 75
< 68
< 15
3200 1
.3150 734 .3
1280202
CE-1313
543
X-131316
16
33 116.7
0.67
3.8
104 .2
0.34
0.16
0.28 < 0. 1
0<
150
< 10 7
. 71700 3.4
< 10
< 32 823.9
7. 1
19<
22<
10 4 .4
42<
IS<
1 .5
< 15
< 6 .8
< 6.8
< 15 50
< 68
< 15
2800
< 1 .0
74<
325 .0
FORi
NONANED S.
S. HOLYLE
DATE) 09/17/80
553
568
57S
X-131317
X-131318
X-131319
17
> 34 13 6
.7
0.54
2.7
10 4 .1
0 .3
4<
0.068
0.27 < 0.10
< 150
< 10
< 4.6
1400 4.
4<
10<
32150 2.3
6.3
16<
22<
104. 2
42<
15<
1.5
< 15
< 6.8
< 6.8
< 15 65
< 68
< 15
2700
< 1.
012
0 545. 0
18
33 13 4 .4
0. 18
1 .6
9.5
4 .5
0. 17
0.069
0.19 < 0.10
< 15
0<
10 6.3
470 3.
4<
10<
32 180 1.
8
8.4
18<
22 1 1 2.2
41<
15<
1.5
< 15
< 6.8
< 6.
8<
1512
0<
68<
15
1900
< 1.0
98 65 5.
6
19
338.6
3.5
0.097
0.94
8.5
4.4
0. 10
< 0.068
0.094
< 0.10
< 150
< 10
< 4 .6
420 4
.4<
10<
32370 1
.2
5.3
13<
22<
10<
2.2
40 H<
1 .5
< 15
< 6 .8
< 6.8
< 15 52
< 68
< 15
940
< 1 .0
170
58 4
.2
58S
X-131320
20
33 147.
10.61
3.3
104.
40.32
< 0.068
0.25 < 0.10
< 15
0<
10 5.2
1700 3.7
< 10
< 32
150 3.
3
6 .7
19<
22<
10 4 .3
44<
15<
1 .5
< IS
< 6 .8
< 6.8
< 15 62
< 68
< 13
2500
< 1 .0
89<
326
.0
JOSEPH L. HARRIS
(ANALYST
U. B. CRAHDELL
(PLATE RECORDER
D. U.
GOLIGHTLY
(PROJECT LEADER
598
60S
618
X-131321
X-131322
X-131323
21
33 104.1
0. 19
2.3
9.2
4 .0
0.17
< 0.068
0.18 < 0. 10
< 15
0<
10<
4 .6
1100
6.9
< 10
< 32
160 1 .2
7. 1
17<
22<
10 3.9
39<
15<
1 .5
< 15
< 6.8
< 6 .8
( 15 93
< 68
< IS
1800
< 1.
012
0 715.3
22
34 11 5.1
0. 15
2.6
9.2
4 .9
0.17
< 0.068
0.25 < 0.10
< 150
< 105.
3340 4.0
< 10
< 32
220 2.
0
10 22<
22 12<
2.2
45<
15<
1.5
< 15
< 15
< 6.8
< 15
110
< 68
< 15
2500 5.7
210 747.
7
23
33 11 6.0
0.53
2.9
10 4 .0
0.27
< 0.068
0.26 < 0.
< 15
0<
10<
6.1500 3.
< 10
< 32
< 632. 3.
14<
22<
103.
37<
15<
1.<
15<
6.
< 6.
< 15 36
< 68
< 15
2600
< 1.
60<
323.
10 8 1 4 9 9 5 8 8 0 9
TABLE
3. CONCENTRATIONS OF ELEMENTS DETERMINED BY 0IRECT-CURRENT ARC EN18810N SPECTROGRAPHY--COHTINUED.
JOB HO. IN39 PAGE
9-B
FIELD
SAMPLE
I 32
SX-131314
SPECTRUM
14
OS PPN
PB PPM
PD PPM
PR PPM
PI PPH
RE PPH
RH PPH
RU PPH
SB RPM
SC PPM
6N PPH
8N PPN
8R PPH
TA PPH
TB PPH
TN PPH
TL PPH
TH PPH
U PPN
V PPH
U PPN
Y PPH
Yfl
PPH
ZN PPM
2* PPH
MAJORS
SI02
AL203
FE203
HGO
CAO
HA20
K20
T102
P203
MHO
< 229.2
< 1 .0
< 68
< 4 .6
< 10
< 2.
2<
2.2
< 32
,4 .8
139.
411
0<
460
< 32
< 22
< 4 .6
< 4.6
< 320 2.
1
< 10 467 .0
160
390
RECALCULATED
X 73
X 19
X 3.
2X
0.20
X 1.7
X 11
X 4.9
X 0.25
>. <
0. 1
6X
0.23
338
X-131315
15 < 22 11
< 1 .0
< 68
< 4.6
< 10
< 2.2
< 2.2
< 324.6
< 10 12
120
< 460
< 32
< 22
< 4.6
< 4.6
< 320 1
.9
< 10 336.7
130
430
AS OXIDES
71 236.4
0.37
3.6
13 6.0
0.33
< 0. 16
0.41
348
X-131316
16 < 22 12
< 1 .0
< 68
< 4.6
< 10
< 2.2
< 2.2
< 32 11
< 10 8.0
450
< 460
< 32
< 22
< 4.6
< 4.6
< 320 9.6
< 10 233.6
170
430
71 219.6
1 .1
5.3
135.
10 .57
0.37
0.36
358
X-131317
17 < 22 14
< 1.
0<
68<
4.6
< 10
< 2.2
< 2.2
< 32 14
< 102.9
330
< 460
< 32
< 22
< 4.6
< 4.6
< 320 4.3
< 10 304.0
150
480
> 73 259.6
0.90
3.8
13 4 .9
0 .57
< 0.16
0 .3
3
368
X-131318
18 < 22 11
< 1.0
< 68
< 4.6
< 10
< 2.
2<
2.2
< 324.6
127.9
120
< 460
< 32
< 22
< 4.6
< 4.6
< 32
0 1.0
< 10 274.6
200
610
71 256.3
0 . 3
02.2
13 5.4
0 .28
0. 16
0. 25
573
X-131319
19 < 229.0
< 1 .0
< 68
< 4 .6
< 10
< 2.
2<
2.2
< 322.
6
< 104 .2
77<
460
< 32
< 22
< 4 .6
< 4.6
< 320 7.
2
< 10 283.9
6295
0
71 163.0
0. 16
1 .3
113.3
0. 17
< 0. 16
0. 12
588
X-131320
20 < 22 11
< 1 .0
< 68
< 4 .6
< 10
< 2.2
< 2 .2
< 32 11
< 10 6.
1430
< 460
< 32
< 22
< 4 .6
< 4 .6
< 320 9.7
< 10 274
.113
0460
71 27 101.
04.6
133.3
0.53
< 0.
16
0. 32
393
X-131321
21 < 22 12
< 1 .0
< 68
< 4 .6
< 10
< 2.2
< 2 .2
< 326.3
10 9.7
210
< 460
< 32
< 22
< 4.6
< 4 .6
< 32
0 1 .
1
< 10 396.2
140
470
71 195.9
0 .3
23.
2
124 .8
0 28
< 0.16
0 .2
3
608
X-131322
22 < 22 11
< 1.
0<
68<
4.6
< 10
< 2.
2<
2. 2
< 3r> 3
.8
14 10120
< 460
< 32
< 22
< 4.6
< 4.6
< 320 2.
3
< 10 376.3
150
1500
73 217.3
0 .25
3.6
12 5.9
0.28
< 0.16
0.32
613
X-131323
23 < 22 11
< 1
.<
68<
4.
< 10
< 2.
< 2.
< 32 1
1
< 103.
370
< 460
< 32
< 22
< 4.
< 4.
< 320 9.
< 10 172.
160
220
71 218.6
0.88
4 .
1
13 4.8
0.45
< 0.
16
0.34
0 6 2 2 7 6 6 0 5
1. THE RELATIVE STANDARD DEVIATION FOR EACH REPORTED CONCENTRATION IS
PLUS 30% AND MINUS 33*4.
2.
'H'
DENOTES THE OCCURRENCE OF AN UNRESOLVED INTERFERENCE.
3. SODIUM DETERMINED VISUALLY IN
SPECTRA I'S 15,16,17,20,22 AND 23.
TABLE 3.
CONCENTRATIONS OF ELEMENTS DETERMINED BY DIRECT-CURRENT ARC EMISSION SPECTROCRAPHY--COHTINUED.
PAGE
10-A
REPORT
JOB
HO.
SPEC. LAB
FIELD
1SAMPLE
SPECTRUM
SI
>.AL
%FE
*nc
%
CA
*
HA
V.K
^TI
*
P 55
HN
>.
AC PPN
AS PPN
AU PPM
B PPH
BA PPN
BE PPH
BI PPM
CD PPN
CE PPH
CO PPM
CR PPH
CU PPN
DY PPH
ER PPM
EU PPM
CA PPH
CD PPN
GE PPH
HF PPM
HO PPH
IN PPH
1R PP
MLA PPM
LI PPH
LU PPN
HN PPN
HO PPM
NB PPM
ND PPH
HI PPH
IN99
.IIN59 628
X-131404
4
> 34 137.3
0.56
3.0
10 3.9
0. 39
< 0.068
0.30 < 0.10
< 150
< 10
< 4 .6
1200 6
.9<
10<
32200 3.
5
5.B
17<
22<
104
.6
45<
15<
1 .5
< 15
< 6
.8
< 6
.8<
1511
0<
68<
15
3000
< 1 .0
74 764 .8
PROCRAH NO.
1280202
PLATE NO.
CE-1314
FOR;
HOHAHED S.
S. HQLYLE
DATE! 09/17/80
JOSEPH L. HARRIS
(ANALYST
U. B. CRANDELL
(PLATE RECORDER
D. U. GOLICHTLY
(PROJECT LEADER
63S
X-131405
5
> 34 147.7
0.60
2. 7
103.7
0.33
0. 16
0.28 < 0.10
< 13
0<
10<
6 .B
1 100 4
.9<
10<
32130 3.
2
8.3
20<
22<
10 3.8
49<
15<
1 5
< 15
< 6.8
< 6
.8<
15 55<
68<
IS
2800
< 1 .0
69<
325.6
648
X-131406
6
> 34 137 .6
0.63
2 .6
103.7
0.37
< 0.068
0.28 < 0. 10
< 15
0<
10<
6.8
900 4
.8<
10<
3213
0 3.3
6.4
20<
22<
to<
2 .2
44<
15<
1 .3
< 15
< 6 .8
< 6 .8
< 15 70
< 68
< 15
2800
< 1.
016
0 325 .4
658
X-131407
7
> 34 14 6.
40.63
2.5
10 4 .5
0.31
0.13
0.24 < 0. 1
0<
150
< 10
< 6.8
1600 4.
1<
10<
3213
0 3.0
6.8
32<
22<
to 4.4
44<
15<
1.5
< 13
< 6.8
< 6.8
< 13 40
< 68
< IS
2400
< 1.
068
< 326.
2
668
X-131408
8
> 34 18 5.3
0.24
2.8
11 6.8
0.24
0.081
0.26 < 0.
10
< 150
< 10
< 4.6
440 6.
3<
10<
32370 1.
3
7.7
13<
22<
10<
2.2
53
H<
1.5
< 15
< 6.8
< 6.8
< 15
180
< 68
< IS
2600
< 1.
0240
120 4.5
ClX-131409
9
0.76
0. 19
1.5
9.4
18
1.4
0. 16
0.0064
< 0.068
1.0 <
0 .1
0<
150
< 10 30 95
< 1 .0
< 10
< 32
< 63
1 .1
8.7
7.8
< 22
< 10
< 2.2
< 1 .5
< 15
< 1 .5
< 15
< 6.8
< 6
.8<
15 1 1
< 68
< 15
10000 2.6
< 3.2
< 323.
9
C2X-131410
10
1.0
0.55
1 .2
11 22
0.23
0.21
0.024
< 0.068
0.99
0.44
< ISO
< 10 34
170
< 1 .0
< 10
< 32
< 633.3
14 13<
22<
10<
2.2
< 1 .5
< 15
< 1 .5
< 15
< 6.8
< 6.8
< 15 14
< 68
< 15
9900 3
.5<
3 .2
< 325.9
C3X-13141 1
11
0.29
0.056
1 .2
8.2
15
1 .4
0.11
0 .0
039
0.084
1 .2
1 .2
< 150
< 10 50
390
< 1 .0
< 10
< 32
< 636.
1
2.5
8.9
< 22
< to
< 2.2
< 1 .5
< 15
< 1 .3
< 15
< 6.8
< 6 .8
< 15
< 10
< 68
< 15
12000 12
< 3.2
< 328.7
C4X-131412
12
2.5
0.76
1.9
12 23
0.32
0 .33
0.035
< 0.068
1 .1 <
0. 10
< 150
< 10 52
270
< 1.
0<
10<
32<
633.
1
23 12<
22<
10<
2.2
< 1.5
H<
1.5
< 13
< 6.8
< 6.8
< 15
< 10
< 68
< t5
11000 163.4
< 329.
t
C5X-13141
13
0.73
0. 18
0.89
7.3
23
0.40
0. 13
0.0070
< 0.068
0.92
0.<
150
< to 47 120
< 1
.<
10<
32<
633. 3. 6.
< 22
< to 2.
< 1
.<
15<
1.<
15<
6.
< 6.
< 15
< 10
< 68
< 15
9200 7.
< 3.
< 32 18
3 26 0 6 6 9 5 5 5 8 8 7 2
TABLE
3. CONCENTRATIONS OF ELENENTS DETERMINED BY DIRECT-CURRENT ARC EMISSION SPECTROCRAPHY--CONTINUED
JOB HO. IH39 PACE
IO-B
ro
FIELD
18ANPLE
SPECTRUM
OS PPH
Pfl
PPM
PD PPM
PR PPM
PT PPH
RE PPM
RH PPH
RU PPM
3B PPH
q p
M>H
« w FT n
SH PPH
SN PPM
SR PPM
TA PPH
TB PPM
TH PPH
TL PPH
TH PPH
U PPH
V PPH
V PPM
Y PPH
YB PPH
ZN PPM
ZR PPH
62S
X-131404
«
< 22 19
< 1.
070
< 4.6
< 10
< 2.2
< 2.2
< 32 10
< 109.3
420
< 460
< 32
< 22
< 4.6
< 4.6
< 320 10
< 10 343.
119
030
0
MAJORS RECALCULATED
SI02
5sAL203
*FE203
J|HGO
*CAO
*
NA20
*K20
XTI02
XP209
>.HNO
X
> 73 29 11 0
.93
4.2
134.
70.65
< 0. 16
0.39
63S
X-131405
9
< 22 12
< 1 .0
< 68
< 4 .6
< 10
< 2.2
< 2.2
< 32 10
< 10 9.
6430
< 460
< 32
< 22
< 4.
6<
4.6
< 320 9.
1
< 10 31 9.
118
0390
AS OXIDES
> 73 27 11
1 .0
3.8
134.9
0.99
0. 37
0. 36
643
X-131406
6
< 22 11
< 1 .0
< 68
< 4 .6
< 10
< 2.2
< 2.
2<
32 10
< 10 9.
0420
< 460
< 32
< 22
< 4.6
< 4.6
< 320 11
< 10 324 .2
190
770
> 73 25 11
1 .0
3.6
134.5
0.62
< 0.16
0.36
653
X-131407
7
< 22 16
< 1.
0<
68<
4.6
< 10
< 2.2
< 2.2
< 32 10
< 105.9
410
< 460
< 32
< 22
< 4.6
< 4.6
< 320 7.
3
< 10 213.9
160
290
> 73 279.2
1 .0
3.9
13 3 .4
0.92
0.30
0.31
668
X-131409
8
< 22 11
< 1.
068
< 4.6
< 10
< 2.2
< 4.
6<
327.
6
176.4
140
< 460
< 32
< 22
< 4.
6<
4. 6
< 320 3.
9
< 10 966.6
130
1200
) 73 347 .9
0 .40
3.9
19 8.2
0. 40
0. 19
0.34
ClX-131409
9
< 22 66
< 1 .0
< 68
< 4 .6
< 10
< 2.2
< 2.2
< 324.
9
< 10
< 1.9
360
< 460
< 32
< 22
< 4.6
< 4.6
< 320 30
< 103.1
0.32
890 49
1.6
0.36
2. 1
16 29
1.9
0. 1
90.01 1
< 0. 16
1 .3
C2
X-131410
10 < 22
170
< 1 .0
< 68
< 4 .6
< 10
< 2 .2
< 4.
6<
32 3.7
< 10
< 1.9
440
< 46
0<
32
< 22
< 4 .6
< 4.6
< 320 29
< 10 3.
70.27
1 10
0 31
2. 1
1.0
1.7
18 31
0.34
0.29
0.040
< 0. 16
1 .3
C3X-131411
11 < 22
210
< 1.0
< 68
< 4 .6
< 10
< 2.2
< 4 .6
< 32
1 .3
< 10
< 1 .3
430
< 460
< 32
< 22 40
< 4.6
< 320 20
< 10 4
.6<
0. 13
1600 72
0.62
0.11
1 .7
14 21
1 .9
0.13
0.0063
0.19
1 .6
C4X-131412
12 < 22
290
< 1.
0<
68<
4.6
< 10
< 2.2
< 4.6
< 322.
9
< 10
< 1.5
460
< 460
< 32
< 22
< 4.6
< 4.6
< 320 60
< 106. 3
0.33
830 63
3.4
1 .4
2.7
20 32
0.43
0.40
0.038
< 0.16
1 .4
C5X-13141
13 < 22 130
< 1.
< 68 < 4.
< 10
< 2.
< 4.
< 323.
< 10
< 1.
370
< 460
< 32
< 22
< 4.
< 4.
< 320 13
< 106. 0.
330 41
1.6
0.34
1 .3
12 32 0.34
0. 16
0.012
< 0. 16
1 .2
3 0 6 2 6 2 3 6 6 0 51
1. THE RELATIVE STANDARD DEVIATION FOR EACH REPORTED CONCENTRATION IS
PLUS 90% AND MINUS 33*
2. 'H'
DENOTES THE OCCURRENCE OF AN UNRESOLVED INTERFERENCE.
3. SODIUM DETERMINED VISUALLY IN SPECTRA f'S 4,3,6,7 AND 8.
TABLE
3.
CONCENTRATIONS OF ELEMENTS DETERMINED BY DIRECT-CURRENT ARC EMISSION SPECTROCRAPHY--CONTINUEO.
PACE
11-A
00
REPORT
JOB NO.
IN99
SPEC.LAB .IIN99
PROGRAM HO.
1280202
PLATE NO.
CE-1314
FORt
NOHAKEO S.
S. HOLYLE
OATEt 09/17X80
JOSEPH I. HARRIS
W. 6. CRANOELL
0. W.
GOLICHTLY
(ANALYST)
(PLATE RECORDER)
(PROJECT LEADER)
FIELD
1 8AHPLE
C6
X-131414
8PECTRUH
14
81
*AL
*FE
*HC
*CA
*
HA
.*K
**
TI
*P
XHN
%
AC PPH
A8 PPH
AU PPM
fi PPH
BA PPH
BE PPH
61 PPH
CO PPN
CE PPH
CO PPN
CR PPH
CO PPH
DY PPH
ER PPH
EU PPH
GA PPH
GO PPH
GE PPM
HF PPH
HO PPH
IN PPH
IR PPM
LA PPH
LI PPH
LU PPH
HN PPH
HO PPH
NB PPM
NO PPM
HI PPH
1 .2
0. 38
0.95
9.0
18
3.4
0.21
0.012
< 0.068
1. 1 <
0 .10
< 190
< 10 49 180
< 1 .0
< 10
< 32
< 63 2.3
8 .9
7.7
< 22
< 10
< 2
.2
< 1 .9
< 15
< 1 .9
< 19
< 6 .8
< 6.8
< 15
< 10
< 68
< 19
11000 6.0
< 3.
2<
329 .5
C7
X-131415
19
2.6
0.59
3.0
9.3
13
1.9
0.27
0.016
0. 10
1 .2
0.69
< 190
< 10
240
140
< 1 .0
< 10
< 32
< 632.
6
19 17<
22<
10<
2.2
< 1 .9
< 15
< 1 .9
< 19
< 6.
8
< 6.8
< 15
< 10
< 68
< 19
12000 41
< 3 .2
< 32 19
C8
X-131416
16
3.9
0.99
4 .3
6.2
9.3
2.0
0.55
0.035
0.072
1 .3 <
0 . 10
< 19
0<
10190
1300
< 1 .0
< 10
< 32
< 638.9
45290
< 22
< 10
< 2.2
3.7
< 15
< 1 .9
< 15
< 6 .8
< 6.8
< 15 11
< 68
< 19
13000 494 .5
< 32 34
C9
X-131417
17
1 .8
0.77
2.2
9.1
17 0.71
0.24
0.023
0.11
1 .2 <
0. 10
< 19
0<
10 94220
< 1.
0<
10<
32<
632.
3
17 13<
22<
10<
2.2
< 1.
9H
< 1.
9<
19<
6.8
< 6.8
< 19
< 10
< 68
< 19
12000 16
< 3.
2<
329.
3
CIO
X-131418
18
2.9
1 .4
2.9
6.0
15
1 .9
0.42
0.099
< 0.068
1 .
1
0.64
< 19
0<
10 69310
< 1.
0<
10<
32<
636.6
29 39<
22
< 10
< 2.2
2.4
< 19
< 1.
5<
19<
6.8
< 6. 8
< 19 14
< 68
< 19
1 1000 168.0
< 32 29
CL1
X-131419
19
33 119.
63.
49.
1
2.7
1.9
0.29
< 0.068
0.23 < 0.10
< 19
0<
1016
0290 1
.9<
10
< 32
< 639 .8
210
69<
22<
10<
2.2
26<
19<
1 .5
< 15
< 6.8
< 6.8
< 15 26 86
< 15
2300
< 1 .0
26<
32 33
CL2
X-131420
20
> 34 145.4
2.0
1.7
2.8
2. 1
0.37
0. 19
0.031 0.46
< 19
0<
10190
380 2.2
< 10
< 32
< 43S.B
220 68
< 22
< 10
< 2.2
28<
19<
1 .9
< 19
< 6 .8
< 6 .8
< 15 29
< 68
< 15
310 2
.625
< 32 33
CL3
X-131421
21
33 119.
11 .8
1 .3
3.2
1 .3
0.28
0.095
0.071 0.34
< 15
0<
1015
0300 2.0
< 10
( 32
< 43 23
220 70
< 22
< 10
< 2.2
27<
15<
1 .9
< 19
< 6.8
< 6.8
< 19 18
< 68
< 15
710
< 1.0
29<
32 27
CL4
X-131422
22
> 34 14 5.
32
.11 .6
3.6
2.0
0.39
0.12
0.031 1.
4<
150
< 10
190
390 2.
2<
10<
32<
43 9.
2
220 69
< 22
< 10
< 2.2
30<
19<
1.9
< 13
< 6.8
< 6.8
< 19 20
< 68
< 19
310
< 1.
031
< 32 29
CL5
X-131423
23
30 10 4.9
3. 1
4.7
3.0
1.9
0.30
0. 1
20. 17
0<
150
< 10
130
300 1
.<
10<
32<
439.
170
130
< 22
< 10
< 2.
29<
15<
1<
19<
6
< 6
< 15
< 10
< 68
< 15
1700
< 1
19<
32 27
99 8 0 2 9 8 8 0
TABLE
3. CONCENTRATIONS OF ELEMENTS DETERMINED BY DIRECT-CURRENT ARC EMISSION SPECTROGRAPHY--CONTINUED.
JOB NO. IN99 PAGE
1 I-B
IO
FIELD
ISAHPLE
SPECTRUM
08 PP
HPB
PP
HPO
PP
HPR PP
HPT PPH
RE PP
HRN
PP
HRU
PP
HSB fPH
8C<fPH
SH PP
M8N
PP
H8R
PPH
TA PPH
TB PPH
TH PPH
TL PP
HTH
PPH
U PP
HV
PPH
W PPH
Y PP
HYB
PPH
ZN PP
HZft
PPH
C6X-131414
14 < 22
260
< 1 .0
< 68
< 4.6
< 10
< 2.2
< 2.2
< 32
1 .3
< 10 3
.7990
< 46
0<
32
< 22 18
< 4 .6
< 320 28
< 103 .0
0.23
440 66
MAJORS RECALCULATED
8102
X
AL203
XFE203
XHC
O X
CAO
X
NA20
X
K20
XTI
02
XP209
XHN
O %
2.6
0.72
1.4
19 29
4.6
0.25
0.020
< 0. 16
1.4
C7X-131419
19 < 22
490
< 1 .0
< 68
< 4 .6
< 10
< 2.2
< 2.2
< 322 .6
< 10 9.
7320
< 46
0<
32
< 22
< 4.6
< 4 .6
< 32
0 78
< 10 6.
90 .28
1900 72
AS OXIDES
9.6
1.0
4.3
19 18
2.6
0.33
0.027
0.23
1 .6
C8X-131416
16 < 22
360
< 1 .0
< 68
< 4.
6
< 10
< 2.
2<
2.2
< 323.
3
< 10 3.
939
0<
460
< 32
< 22 43
< 4.
6<
320 63
< 10 6
.20.
19
1600 88
7 .5
1 .9
6 .2
107 .4
2.7
0 .66
0 .098
0.17
1 .7
C9X-131417
17 < 22
970
< 1.0
< 68
< 4.
6
< 10
< 2.
2<
2.2
< 322.4
< 10
< 1.9
900
< 460
< 32
< 22
< 4.6
< 4.
6<
320 39
< 109.9
0. 17
1900 83
3 .9
1 .5
3.2
15 24
0.96
0.29
0 .0
380.29
1 .6
CIO
X-131418
18 < 22
290
< 1.
0<
68 < 4.6
< 10
< 2.2
< 2.2
< 326.
2
< 10
< 1.
943
0<
460
< 32
< 22 23
< 4.
6<
320 63
< 10 120.76
1900 87
5.4
2.7
3.6
10 21
2. 6
0.91
0.098
< 0.
16
1 .4
CL1
X-131419
19 < 22 73
< 1 .0
< 68
< 4.
6
< 10
< 2.2
< 2.
2<
32 23
< 10
< 1 .5
290
< 460
< 32
< 22 < 4.6
< 4.6
< 320
110
< 10 224.
111
00 200
71 218.
09.6
7. 1
3.6
2.3
0.42
< 0. 16
0.30
CL2
X-131420
20 < 22
140
< 1 .0
< 6B
< 4 .6
< 10
< 2 .2
< 2.
2<
32 26
< 10
< 1 .9
280
< 46
0<
32
< 22
< 4 .6
< 4 .6
< 320
120
< 10 309.
9960
190
> 73 277.
73.3
2.4
3.8
2.9
0.62
0.34
0.040
CL3
X-131421
21 < 22
230
< 1 .0
< 68
< 4 .6
< 10
< 2.
2<
2.2
< 32 24
< 10
< 1 .9
170
< 460
< 32
< 22
< 4 .6
< 4 .6
< 320
1 10
< 10 234 .8
880
120
71 217.3
3.0
1 .B
4 .3
1 .6
0.47
0.22
0 .092
CL4
X-131422
22 < 22 53
< 1.0
< 68
< 4.
6
< 10
< 2.2
< 2.2
< 32 19
< 10
< 1.9
300
< 460
< 32
< 22
< 4.
«<
4.6
< 32
0110
< 10 249.
368
021
0
> 73 277.6
3.9
2.2
4.9
2.4
0.58
0 .2
80.040
CL9
X-131423
23 < 22 42 < 1.0
< 68 < 4.6
< 10
< 2.2
< 2.2
< 32 24
< 10 13
490
< 460
< 32
< 22 < 4.6
< 4.
6<
320
100
< 10 279.
1360
180
64 19 6.4
9. 1
6.6
4 .0
1 .8
0 .9
00.
280 .2
2
1. TNE RELATIVE STANDARD DEVIATION FOR EACN REPORTED CONCENTRATION IS
PLUS 90% AND MINUS 33*
2.
'H'
DENOTES THE OCCURRENCE OF AN UNRESOLVED INTERFERENCE.
'TABLE
3.
CONCENTRATIONS OF ELEMENTS OETERNINEO 8Y DIRECT-CURRENT ARC EMISSION SPECTROGRAPHY--CONTINUEO.
PAGE
12-A
CO O
REPORT
JOB NO.
IN39
SPEC. LAB IIN59
FIELD
I CL6
SAMPLE
X-131304
SPECTRUM
4
SI
XAL
XFE
X
NG
XCA
X
HA
XK
* X
TI
XP
*MM
>.
AC PPM
AS PPM
rtu PP
NB
PPN
8A PPN
BE PPN
61 PPN
CD PPH
CE PPN
CO PPN
CR PPH
CU PPN
DY PPN
ER PPN
EU PPH
CA PPN
CD PPR
CE PPH
HF PPH
HO PPH
IN PPH
IR PPH
LA PPR
LI PPH
LU PPH
HN PPH
HO PPH
HB PPR
HO PPM
HI PPN
28 9.
14.4
I .8
1.6
2.9
I .9
0.24
< 0.068
0.053 0 .36
< 150
< 10 94
280 1
.9<
10<
32<
43 6
.5
180
57
< 22
< 10
< 2.2
28
< 15
1 .6
< IS
< 6 .8
< 6 .8
< 19
< 10 80
< 15
330
< 1 .0
27
< 32 39
PROCRAH NO
PLATE NO
.
CL7
X-131503
5
26 8.4
4. 7
1.9
1.3
3.3
1.8
0.20
0.11
4.030 0 .58
< 190
< 10 84
310 2.1
< 10
< 32
< 43 3.3
240 37
< 22
< 10
< 2.2
26<
15(
1 .5
< 13
< 6.8
< 6.8
< 13 21
1 10
< 13
300
< 1 .0
26<
32 29
. 1280202
CE-I313
CL8
X-131306
6
27 9.0
4 .3
1 .8
1 3
2.8
1 .9
0.21
< 0 .0
(80 .023 0.41
< 130
< 10 92
290 1
.8<
10<
32<
433.
1
210 34
< 22
< 10
< 2.2
26<
15<
1 .3
< 13
< 6 .8
< 6.8
< 13 16
< 68
( 13
230
< 1 .0
32<
32 27
FORi
CL9
X-131307
7
20 7
.33.9
1 .5
1 .0
2.5
1 .2
0.22
< 0.068
0.049 0.27
< 130
< 10 86
240 1
.4<
10<
32<
43 9.4
160
120
< 22
< 10
< 2.2
23
< 13
< 1.3
< 13
< 6.8
< 6.8
< 13 18 97
< IS
490
< 10
30
< 3228
HOHAHEO 3.
8 OATEi 09/1
CLIO
X-131308
8
173.8
2.6
1 .3
0.99
101 .2
0.21
< 0.068
0 .036 0.
13
< 134
< 10 96
230 1.
7<
10<
32
91 24
140
38
< 22
< 10
< 2.2
21 37
< 1.3
< 13
< 6.8
< 6.
8<
13 19120
< 13
560
< 1.
013
< 32
24
. HOLYLE
7/80
Gl
X-131509
9
0. 18
0.071
0. 17
0. 18
27
> 6.8
0. 19
0.0038
< 0.068
0.014 0.
14
< 130
< 10
< 4 .6
29
< 1 .0
< 10
< 32
< 63 1
.4
5.7
3 .5
< 22
< 10
< 2 .2
< 1 .5
< 13
< 1.3
< 13
< 6 .8
< 6.8
< 13 19
< 68
< 13
140 3.1
3 .2
< 32 2
.2
G2
X-131310
10
0.20
< 0.046
0. 16
0. 13
17
1.6
0. 12
0.0042
< 0.068
0.037
< 0.10
< 130
< 103.7
120
< 1 .0
< 10
< 32
< 63
1 .1
5.7
3.8
< 22
< 10
< 2.2
< 1 .5
< 15
< 1 .3
< 13
< 6.8
< 6 .8
< 13 12
< 68
< 13
570 2
.7<
3.2
< 323
.0
JOSEPH L. HARRIS
(ANALYST
U.
8. CRANDELL
(PLATE RECORDER
0. U. GOLICHTLY
(PROJECT LEADER
G3
G4
G5
X-131511
X-131312
X-131313
11
0.29
< 0.046
0.28
0.16
19
0.077
0.10
0.0042
< 0.068
0.012
< 0. 10
< 130
< 10 19 8.9
< 1 .0
< 10
< 32
< 63
< 1 .0
3.3
3.8
< 22
< 10
< 2.2
< 1 .3
< 13
< I .3
< 13
< 6.8
< 6.8
< 13
< 10
< 68
< 15
120
< 1 .0
< 3.2
< 32
1 .6
12
0.21
< 0.04*
0.11
0.14
24
0 .090
0.11
< 0.0032
< 0.068
0 .033
< 0.10
< 130
< 10 16
480
< l.o
< 10
< 32
< 63
< 1.0
1 .9
2.2
< 22
< 10
< 2.2
< 1.3
< 13
< 1.3
< 13
< 6.8
< 6.8
< 13
< 10
< 68
< 13
330 4.0
< 3.2
< 32 1 .6
13
0 .030
< 0.046
0.086
0. 1
828
0.043
0. 12
< 0.0032
< 0.068
0 .026
< 0.
< 130
< 105.
28
< 1
.<
10<
32
< 63
< 1.
< 1. 2.
< 22
< 10
< 2.
< 1.
< 13
< 1.
< 13
< 6.
< 6.
< 13
< 10
< 68
< 13
260 5.
< 3.
< 32 2.
10 4 0 0 0 6 2 5 5 8 8 5 2 0
TABLE 3. CONCENTRATIONS OF ELEMENTS DETERMINED BY D IRECT-CURRENT ARC EMISSION SPECTROCRAPHY--CONT1HUED.
JOB NO. IN39 PACE
12-B
FIELD
ISAMPLE
SPECTRUM
OS PPN
PB PPM
PD PPH
PR PP
MPI
PPN
RE PPN
RH PPN
RU PPH
SB RPN
SC PTH
SH PPH
8N PPH
9R PPN
TA PPN
TB PPH
TH PPH
TL PPH
T« PPH
U PPN
V PPN
U PPH
Y PPH
YB PPH
ZN PPN
ZR PPH
CL6
X-131504
4
< 22 86
< 1 .0
< 68
< 4 .6
< 10
< 2.2
< 2.2
< 32
,21
< 1038
270
< 460
< 32
< 22
< 4 .6
< 4.
6<
320
100
< 10 184.7
620 95
HAJQRS RECALCULATED
SI02
XAL203
XFE203
*NCO
>,CAO
X
NA20
*K20
XTIQ2
XP205
XMHO
X
60 176.
33.
02.2
3.9
23
0. 40
< 0. 1
60.068
CL7
X-131309
5
< 22 80
< 1 .0
< 68
< 4 .6
< 10
< 2 .2
< 2 .2
< 32 14
< 10 4
.0290
< 460
< 32
< 22
< 4 .6
< 4 .6
< 32
0 94
< 10 204 .6
320
1 10
AS OXIDES
96 166.
72.3
1 .8
4.3
2.2
0. 33
0.23
0.039
CL8
X-131306
6
< 22 76
< 1 .0
< 68
< 4 .6
< 10
< 2.2
< 2.2
< 32 16
< 10 4
. 1
230
< 460
< 32
< 22
< 4.6
< 4 .6
< 32
011
0
< 10 18 4
.633
019
0
30 176.4
3.0
1 .8
3 .8
2.3
0 .3
3<
0 .1
60 .030
CL9
X-131307
7
< 22 90
< 1.
0<
68<
4.6
< 10
< 2.
2<
2.2
< 32 13
< 10 12
200
< 460
< 32
< 22
< 4.6
< 4.6
< 320 93
< 10 143.2
300
100
43 14 3.6
2.3
1 .4
3.4
1 .4
0.37
< 0 .1
60 .063
CLIO
X-131308
8
< 22 43 < 1.
0<
68<
4.6
< 10
< 2.2
< 2.2
< 32 17
< 106. 1
180
< 460
< 32
< 22
< 4.6
< 4.
6<
320 86
< 10 202
613
011
0
36 11 3 .7
2.2
1 . 4
131 .4
0.35
< 0
. 16
0 .0
72
ClX-131309
9
< 227 .8
< 1 .0
< 68
< 4.
6
< 10
< 2 .2
< 2.2
< 322.
0
< 10
< 1 .5
940
< 460
< 32
< 22 1
1<
4 .6
< 32
0 4 .6
H < 1 .3
< 0 .1
3H3 .9
0.39
0. 13
0.24
0.30
38
> 9.2
0.23
0.0097
< 0. 1
60.018
C2X-131510
10 < 22 18
< 1 .0
< 68
< 4 .6
< 10
< 2 .2
< 2.2
< 322 .5
< 10
< 1 .5
1300
< 460
< 32
< 22
< 4
.6<
4 .6
< 32
0 4 .4
< 10 2.0
< 0 .15
N7 .8
0.43
< 0.087
0.23
0.23
24
2.2
0. 13
0.0070
< 0.16
0.074
C3X-13131 1
11 < 22
< 6 .8
< 1 .0
< 68
< 4 .6
< 10
< 2.2
< 2.2
< 322.7
< 10 2
.92400
< 460
< 32
< 22
< 4 .6
< 4.6
< 320 3
.8
H<
1.3
< 0
. 19
H4 .3
0.62
< 0.087
0 .4
00.27
27
0.10
0 .1
20 .0070
< 0.16
0.016
C4X-131312
12 < 22
< 6.8
< 1.
0<
68<
4.6
< 10
< 2.
2<
2.2
< 322.9
< 10
< 1.3
20000
< 460
< 32
< 2P
< 4.6
< 4.6
< 320 3.
7
< 10
< 1 .5
< 0.13
H3.9
0 .4
3<
0 .0
870.16
0.23
34
0 .1
20.13
< 0.0033
< 0.16
0 .0
43
G5X-13151
13 < 22
< 6.
< 1.
< 68 < 4.
< 10
< 2.
< 2.
< 327.
< 103.
2200
< 460
< 32
< 22
< 4.
< 4.
< 32
0 91 H < 1
.<
0.H8.
0 11
< 0 .0
870. 12
0. 30
39
0 . 060
0. 13
< 0.0033
< 0
. 16
0 .0
34
3 8 0 6 2 2 0 0 6 6 3 13 8
1. THE RELATIVE STANDARD DEVIATION FOR EACH REPORTED CONCENTRATION IS
PLUS 50* AND MINUS 33*.
2.
'H'
DENOTES THE OCCURRENCE OF AH UNRESOLVED INTERFERENCE.
3. SODIUM AND POTASSIUM DETERMINED VISUALLY IN
SPECTRUM 18.
TABLE
3.
CONCENTRATIONS OF ELEMENTS DETERMINED BY OIRECt-CURREKT ARC EMISSION SPECTROGRflPHY--COHTINUEO .
PAGE
13-A
REPORT
JOB NO.
IN99
SPEC. LAB. IIH59
FIELD
1 C6
8ANPLE
X-131914
SPECTRUM
14
81
%AL
>.FE
*NC
*CA
%
HA
*K
> *
TI
*P
*NH
X
AC PPN
A9 PPN
AU PPH
B PPN
8A PPN
BE PPN
BI PPN
CD PPN
CE PPH
CO PPN
CR PPH
CU PPH
DY PPH
ER PPH
EU PPN
GA PPH
CD PPN
CE PPN
HF PPN
HO PPH
IN PPH
IR PPN
LA PPN
LI PPN
"fcU
PPH
HH PP^H
MO PPN
HB PPH
NO PPH
NI PPN
0.072
< 0.046
0. 12
0. 1
126
0. 10
0. 12
0.0036
< 0.068
0.014
< 0.10
< 19
0<
10<
4.6
890
< 1 .0
< 10
< 32
< 63
1 .0
1 .9
2 .6
< 22
< 10
< 2.2
< 1 .9
< 1?
< 1 .9
< 19
< 6.8
< 6 .8
< 19
< 10
< 68
< 19
140
< 1 .0
< 3.2
< 327
4
PROCRAH NO
. 1280202
PLATE HO.
CE-1319
07
G8
X-131315
X-131916
19
0.19
< 0.046
0.14
0.19
21
3.0
0. 17
< 0.0032
< 0.068
0.027
< 0 .1
0<
190
< 10
< 4.6
too
< 1 .0
< 10
< 32
< 63
1 .1
2.7
3.3
< 22
< 10
< 2 .2
< 1 .9
< 19
< 1.9
< 19
< 6
.8
< 6 .8
< 19
< 10
< 68
< 19
270 2
.6<
3.2
< 322
.1
16
1 .7
< 0.046
< 0
0074
< 0.0032
> 32
1 .6
0.13
< 0.0032
< 0.068
< 0.00010
< 0. 10
< 190
< 10
< 4.6
170
< 1 .0
< 10
< 32
< 434.9
9 .3
< 1 .9
< 22 H
< 2 .2
< 1 .9
< 19
< 1 .9
< 19
< 6.8
< 6.8
< 19 24
< 68
< 19
< 1 .0
< 1 .0
< 3.2
< 32 20
FOR:
G9
X-131917
17
0.31
< 0.046
0.12
0.11
> 32
0.17
0.14
0.0044
< 0.068
0.019
< 0. 10
< 19
0<
10<
4.6
290
< 1.0
< 10
< 32
< 63
1 .2
2.1
2.0
< 22
< 10
< 2.
2
< 1.
9<
19<
1.9
< 19
< 6.8
< 6.8
< 19
< 10
< 68
< 19
190 9.
86. 3
< 32
1 . 7
NOHANED S.
S. HOLYLE
DATE: 09/17/80
G10
LG1
X-131918
X-131919
18
0.34
< 0.046
0. 1
10.16
29
0.67
0. 13
0.0049
< 0.068
0.019
< 0.10
< 19
0<
10<
4.6
19
< 1.
0<
10<
32<
631.3
1.4
2. 9
< 22
< 10
< 2.2
< 1
. 9<
19<
1.9
< 19
< 6.8
< 6.8
< 19
< 10
< 68
< 19
190 4.0
< 3.
2<
321 .8
19
0.42
0. 19
2.3
1 . 3
14
1.4
0.097
0.0084
< 0.068
1.4
1 .2
< 190
< 10 44
290
< 1 .0
< 10
< 32
< 636
.4
3 .9
6 .6
< 22
< 10
< 2.2
< 1 .9
< 19
< 1 .9
< 19
< 6.8
< 6 .8
< 19 18
< 68
< 19
14000 14
< 3.2
< 32 43
LG2
X-131920
20
0.91
0.16
1.3
6.7
12
0.42
0. 11
0.0093
< 0.068
0.93 < 0.10
< 190
< 10 39
120
< 1 .0
< 10
< 32
< 63 N
4 .1
9.6
< 22
< 10
< 2.
2
< 1 .9
< 19
< 1 .9
< 19
< 6 .8
< 6.8
< 19
< 10
< 68
< 19
9300 11
< 3.2
< 329 .0
JOSEPH L. HARRIS
(ANALYST)
U. B. CRAHDELL
(PLATE RECORDER)
D.
U. GOLICHTLY
(PROJECT LEADER)
LG3
LG4
LG9
X-131921
X-131922
X-131923
21
0 .4
90.23
1 .8
6.4
12
1 .3
0.19
0.0080
< 0.068
1.1 <
0 . 10
< 190
< 10 39
210
< 1 .0
< 10
< 32
< 633.0
4 .4
9. 3
< 22
< 10
< 2.2
< 1.9
< 19
< 1.9
< 19
< 6.8
< 6 .8
< 19 11
< 68
< 19
1 1000 17 3
. 9<
32 22
22
0.46
0.31
1.6
9.7
16 0.34
0.11
0.014
< 0.068
1 .1
1 .2
< 19
0<
10 30230
< 1.0
< 10
< 32
< 637.
2
9.8
13<
22<
10<
2.2
< 1.9
< 19
< 1.
9<
13<
6.8
< 6.8
< 19
< 10
< 68
< 19
11000 13
< 3.2
< 32 28
23
0. 18
0.099
0.94
7.2
17 0.30
0.097
0.0092
< 0.068
1 .0 <
0.<
190
< 10 36 160
< 1.
< 10
< 32
< 63 3. 2. 4.
< 22
< 10
< 2.
< 1.
< 19
< 1.
< 19
< 6.
< 6.
< 19 21
< 68
< 19
10000 14
< 3.
< 328.
10 0 1 0 1 2 9 9 8 8 2 7
TABLE
3. CONCENTRATIONS OF ELEMENTS DETERNINED BY DIRECT-CURRENT ARC EMISSION SPECTROCRAPHY--CONTINUED.
JOB NO. IN99 PACE
I3-B
CO
FIELD
1SAHPLE
SPECTRUM
OS PPH
P8 PP
HPD
, PPH
PR PP
HPT
PP
H
RE PPH
RH PPH
ftU
PPH
SB PP
He r
ui M
O !
nr n
8ft
PPH
SN PPH
8R PP
HtA
PP
HTB
PP
H
Trt
PPH
TL PP
HTH PPH
U PP
HV
PPH
U PP
HY
PPH
YB PP
H2H PP
HZR PP
H
G6X-131514
14 < 22 < 6.8
< 1 .0
< 68
< 4 .6
< 10
< 2 .2
< 2.
2<
322 .8
< 10
1 .6
2400
< 460
< 32
< 22
< 4 .6
< 4 .6
< 320 3.
1
H < 1 .9
< 0.19
H4 .9
MAJORS RECALCULATED
8102
*AL203
\FE203
SSHG
O JJ
CAO
X
NA20
*K2
0 *
TI02
*
P205
SS
HNO
55
0. 19
< 0.
087
0. 1
70.
1836
0. 13
0. 15
0.0060
< 0.
16
0.018
G7X-131919
19 < 22
< 6.
8<
1 .0
< 68
< 4 .6
< 10
< 2.
2<
2.2
< 32
1 .9
< 10 3.
214
00<
460
< 32
< 22
< 4 .6
< 4 .6
< 320 4
.0
H<
1 .9
< 0.
19H 29
AS OXIDES
0.32
< 0.087
0. 20
0.32
29
]
4.0
0.21
< 0.0053
< 0. 16
0.035
G8X-131916
16 < 22
< 6.8
< 1 .0
< 68
< 4 .6
< 10
< 2.2
< 2.2
< 323
. 3
< 10 9.
215
00<
460
< 32
< 22
< 4.6
< 4.
6<
320 20 H
< 1 .9
< 0.
15
< 19 7.
4
3.6
< 0.087
< 0 .0
11<
0.0093
> 49
2 .2
0 .1
6<
0.0093
< 0.
16< 0.00013
69X-131917
17 < 22
< 6.8
< 1.0
< 68
< 4.6
< 10
< 2.2
< 2.2
< 328.0
< 10
< 1.9
2000
< 460
< 32
< 22
< 4.6
< 4.
6<
320 3.
4
< 10
< 1.9
< 0.
19
< 19 10
0.66
< 0.087
0.17
0.18
> 45
0 .2
30 .1
70.0073
< 0.16
0.019
CIO
X-131918
18 < 22 < 6.
8<
1.0
< 68
< 4.
6
< 10
< 2.2
< 2.2
< 323.0
< 104. 6
1700
< 46
0<
32
< 22
< 46
< 4.
6<
320 4.
8
< 10
< 1.9
< 0. 19
< 199.
3
0 .73
< 0.087
0. 16
0.27
41
0. 90
0. 1
60 .0075
< 0
. 16
0.019
LG1
X-131519
19 < 22 160
< 1 .0
< 68
< 4
.6
< 10
< 2
.2<
2.2
< 32
1 .8
< 10
< 1 .9
1100
< 460
< 32
< 22 19
< 4 .6
< 32
0 21
< 108.7
1 .1
3600 78
0.90
0. 28
3.3
12 20
1 .9
0. 12
0.014
< 0. 16
1 .8
LC2
X-131520
20 < 22
190
< 1 .0
< 68
< 4 .6
< 10
< 2.2
< 2.2
< 322 .0
< 10
< 1 .5
410
< 460
< 32
< 22 15
< 4 .6
< 320 21
< 10 7.2
0.64
1300 60
1 . 1
0.30
1.9
11 17
0.57
0. 13
0.016
< 0. 16
1 .2
LG3
X-131921
21 < 22
260
< 1 .0
< 68
< 4 .6
< 10
< 2 .2
< 2.2
< 32
1 .9
< 10
< 1 .9
920
< 460
< 32
< 22 28
< 4 .6
< 320 28
< 108.2
1 .
13900 67
1 .1
0.44
2 .6
11 17
1 .8
0. 18
0.013
< 0.16
1 .4
LG4
X-131922
22 < 22 84
< 1.
0<
68<
4.6
< 10
< 2.2
< 22
< 323.9
< 10
< 1.
9360
< 460
< 32
< 22 20
< 4.6
< 320 22
< 107. 1
0.99
830 89
0.99
0.59
2.3
16 22
0.46
0.13
0.023
< 0.16
1 .4
LG5
X-131923
23 < 22 79
< 1.
< 68
< 4.
< 10
< 2.
< 2.
< 321.
< 103.
390
< 460
< 32
< 22 12
< 4.
< 320 14
< 107. 0.
1200 76
0.39
0. 19
1 .3
12 24
0 .40
0 . 12
0.0087
< 0.
16
1 .3
0 6 2 2 7 1 6 3 30
1. TNE RELATIVE STANDARD DEVIATION FOR EACH REPORTED CONCENTRATION IS PLUS
SO'/
! AND MINUS 33*
2.
'H'
DENOTES THE OCCURRENCE OF AN
UNRESOLVED INTERFERENCE.
3. CALCIUM AND STROHT IUH(SPECTRUM 116) AND SIL ICOH<SPECTRA I'S 16,17,18) WERE DETERHINED VISUALLY.
TABLE 3
CONCENTRATIONS OF ELEMENTS DETERMINED BY DIRECT-CURRENT ARC EMISSION SPECTROCRAPHY--CONTIHUEO.
PACE
14-A
CO
REPORT
JOB NO.
8PEC.LAB
FIELD
fSAMPLE
SPECTRUM
81
XAL
*FE
*
HC
XCA
k
NA
>.K
*X
TI
%P
XHN
X
AC PPH
AS PPM
AU PPH
B PPM
BA PPM
BE PPN
81 PPN
CD PPH
CE PPH
CO PPH
CR PPM
CU PPH
Ot PPM
ER PPH
EU PPN
GA PPH
CD PPM
GE PPM
HF PPM
HO PPH
IN PPH
IR PPN
LA PPH
LI PPH
LU PPH
HH PPH
HO PPN
NB PPH
ND PPN
HI PPH
INS9
.IIN99 LC6
X-131604
4
0.68
0.39
2. 1
7.2
19
0 39
0. 18
0.017
< 0.068
1.3
1 .3
< 190
< 10 29
220
< 1 .0
< 10
< 32
< 63 4
.0
8 .2
320
< 22
< 10
< 2 .2
< 1 .5
< 19
< 1 .5
< 19
< 6.8
< 6 .8
< 19 13
< 68
< 19
13000 24
< 3 .2
< 32 19
PROGRAM HO.
1280202
PLATE HO.
CE-1316
FORi
HOHAHED S.
S.
HOLYLE
DATE: 09/17^80
JOSEPH
L . HARRIS
( ANALYS
U. 8. CRANDELL
(PLATE RECORDE
D.
U. COLIGHTLY
(PROJECT LEADE
LC7
X-131603
5
1. 1
0.64
1.6
8.6
18
0.53
0. 18
0.023
< 0.068
1.9
1 .6
< ISO
< 10 41 190
< 1 .0
< 10
< 32
< 637.
9
14 19<
22<
10<
2 .2
< 1 .5
< 19
< 1.9
< 19
< 6.8
< 6 .8
< 19 20
< 68
< 19
19000 24
< 3.2
< 32 40
LC6
X-131606
6
0 .38
0.16
1 .9
6.2
19
0.38
0.12
0.0080
< 0.068
0 .86
0.38
< 19
0<
10 31 99
< 1 .0
< 10
< 32
< 634 .0
9.0
220
< 22
< 10
< 2.2
< 1.9
< 19
< 1.
9<
19<
6.8
< 6 .8
< 19
< 10
< 68
< 15
8600 10
< 3.2
< 32 39
LG9
X-131607
7
0.29
0.078
2.4
9.4
18 0 .6
20.099
0.0068
< 0.068
1 .2 <
0. 10
< 190
< 10 97
190
< 1.0
< 10
< 32
< 63
1 .4
3.3
7.7
< 22
< 10
< 2.2
< 1.9
< 19
< 1.
9<
19<
6.8
< 6.8
< IS 19
< 68
< 19
12000 1 1 3.8
< 328.
8
LG10
X-131608
8
0.47
0. 16
1 .7
8. 1
10 0.69
0. 13
0.0069
< 0.068
1 .2 <
0. 10
< 19
0<
10 47
130
< 1.0
< 10
< 32
< 431.8
9.9
7.8
< 22
< 10
< 2.2
< 1-
9<
19<
1.9
< 19
< 6.8
< 6.8
< 19 1
1<
68<
19
12000 29 < 3.
2<
32 16
LG11
X-131609
9
0.40
0.23
0.89
8.7
20
0.29
0. 19
0.0098
< 0.068
0.89
0.31
< 19
0<
10 24 180
< 1 .0
< 10
< 32
< 63 2
.9
6.8
7 .2
< 22
< 10
< 2.2
< 1 .9
H<
1 .9
< 19
< 6.8
< 6 .8
< 19
< 10
< 68
< 19
8900 14
< 3.
2<
32 19
LC12
X-131610
10
0.32
0.095
0.83
7.0
14
1.7
0. 19
0.0047
< 0.068
0.93 < 0.10
< 190
< 10 41
230
< 1 .0
< 10
< 32
< 63
1 .3
2 .9
4.1
< 22
< 10
< 2.2
< 1 .9
H<
1 .5
< 15
< 6.8
< 6 .8
< 15
< 10
< 68
< 19
9340 4.5
< 3.2
< 325
.4
OL1
X-13161 1
11
0.042
< 0.046
0.39
6.5
14
0.92
0.099
< 0.0032
< 0.068
0.37 < 0. 10
< 19
0<
10 5.5
250
< 1.0
< 10
< 32
< 63
1 .
1
1 .4
7.8
< 22
< 10
< 2.2
< 1 .5
H<
1 .5
< 15
< 6.8
< 6.8
< 15
< 10
< 68
< 15
3700 1
.7<
3.2
< 325.4
OL2
X-131612
12
0.057
< 0.046
1 .3
7.3
17 0.61
0.087
0.0033
< 0.068
0.83
0.40
< 150
< 10 9.0
170
< 1.
0<
10<
32<
633.5
1.7
25<
22<
10<
2. 2
< 1.
5<
19<
1.9
< 19
< 6.8
< 6.8
< 19
< 10
< 68
< 19
8300 3.
4<
3.2
< 324.
3
OL3
X-13161
13
0.074
< 0.046
1 .4
6.4
12 0.40
< 0.068
0.0038
< 0.068
0.87
1 .
< 19
0<
10 19 89
< 1
.<
10<
32<
63 4. 2.
300
< 22
< 10
< 2.
< 1.
< 19
< 1.
< 19
< 6.
< 6.
< 19
< 10
< 68
< 19
8700 4.
< 3.
< 323.
3 0 0 6 7 2 5 5 8 8 2 2 7
TABLE
3. CONCENTRATIONS OF ELEMENTS OETERNIHED BY DIRECT-CURRENT ARC EMISSION SPECTROGRAPHY --CONTINUED.
JOB NO. IH39 PAGE
14-8
FIELD
1 SAMPLE
SPECTRUM
OS PB PD PR PT
RE RH RU SB 9C SN 9H 3R TA TB TH
00
,itn
' L TN U V V Y YB zn ZR
PPH
PPH
PPH
PPM
PPM
PPH
PPM
PPM
PPM
FPH
PPH
PPH
PPM
PPM
PPH
PPM
PPM
PPH
PPH
PPM
PPH
PPM
PPM
PPH
PPH
LG6
X-131604
4
< 22 170
< 1 .0
< «8
< 4 .6
< 10
< 2 .2
< 2.2
< 322 .7
< 10
< 1 .3
470
< 460
< 32
< 22 41
< 4 .6
< 320 29
< 108 .8
0.84
1800 73
LG7
X-131609
9
< 22
140
< 1 .0
< 68
< 4.6
< 10
< 2 .2
< 2.2
< 326.9
< 10
< 1.9
470
< 460
< 32
< 22 21
< 4 .6
< 320 43
< 10 141 .4
1300
100
LG8
X-131606
£
< 22
390
< 1 .0
< 68
< 4 .6
< 10
< 2.2
< 2 .2
< 326 .9
< 10
< 1 .9
390
< 460
< 32
< 22 26
< 4.6
< 320 28
< 10 9.9
0. 70
910 39
LG9
X-131607
7
< 22
260
< 1.0
< 68
< 4.
6
< 10
< 2.
2<
2.2
< 321.0
< 10
< 1.9
900
< 460
< 32
< 22 29
< 4.
6<
320 28
< 104. 9
0.60
2900 77
LG10
X-131608
8
< 22 96
< 1.
< 68
< 4.
< 10
< 2.
< 2.
< 322.
< 10
< 1,
920
< 460
< 32
< 22
< 4
< 4.
< 320 27
< 104, 0.
1900 74
0 6 2 2 4 ,9 6 6 6 33
LG1
1 X-131609
9
< 22 97
< 1
< 68
< 4
< 10
< 2
< 2
< 323
< 10
< 1
670
< 460
< 32
< 22
< 4
< 4
< 32
0 22
< 104 0
460 38
,0 ,6 .2 .2 .3 .9 .6 6 .2 .34
LG12
X-131610
10 < 22 26
< 1
< 68
< 4
< 10
< 2
< 2
< 32
1
< 10 9
910
< 460
< 32
< 22
< 4
< 4
< 320 21
< 10 3 0
370 42
.0 .6 .2 .2 .2 .4 .6 .6 .4 .27
OL1
X-131611
11 < 22 100
< 1
< 68
< 4
< 10
< 2
< 2
< 32
1
< 10
< 1
920
< 460
< 32
< 22
< 4
< 4
< 320 11
< 101
< 0
970 17
.0 .6 .2 .2 .3 .9 .6 .6 .6 . 19
OL2
X-131612
12 < 22
210
< 1.
0<
68<
4.6
< 10
< 2.
2<
2.2
< 321.
9
< 10
< 1.9
430
< 460
< 32
< 22 19
< 4.6
< 320 30
< 101.9
0. 1
8690 41
OL3
X-131613
13 < 22
340
< 1.
< 68
< 4
< 10
< 2
< 2.
< 32 1
.
< 10
< 1
920
< 460
< 32
< 22
< 4.
< 4.
< 320 24
< 10
< 1
< 0.
780 38
0 6 2 2 3 9 6 6 9 19
MAJORS RECALCULATED AS OXIDES
SI02
AL203
FE203
HGO
CAO
NA20
K20
T102
P209
HNO
>. X X X X X X X '4 X
1 ,
0 312 21
0. 0 0,<
0 1
9 .74 0 93 22 .028
. 16
.7
2 1 214 29
0 0 0<
0 1
.4 .2 .3 .71
.22
.038
. 16
. 9
0 0 210 21
0 0 0<
0 1
.81
.30
.7 .91
.19
.013
.16
.1
0 0 3 16 29
0 ,
0 0<
0 1
.62
.19
,4 .84
.12
.01
1.1
6.6
1 .
0 2. 13 14 0 0 0<
0 1
0 30 4 .88 16 .012 16 . 6
0 0 114 28
0 0, 0<
0 1
.86
. 44
.3 .34
. 18
.016
. 16
. 1
0. 0 1.12 20
2 0 0<
0. 1
69 18 2 3 18 0078
16 2
0<
0 011 20
0 0<
0<
0 0
.090
.087
.90
.70
.12
.0093
. 16
.48
0<
0 112 24
0 0 0<
0 1
.12
.087
.9 .82
.11
.0099
.16
. 1
0<
0 2 11 17 0<
0 0<
0 1
. 16
,087
0 .94
.082
.006
3. 1
6. 1
1. THE RELATIVE STANDARD DEVIATION FOR EACH REPORTED CONCENTRATION IS PLUS 50* AND MINUS 33*
2.
'H'
DENOTES THE OCCURRENCE OF AN UNRESOLVED INTERFERENCE.
3. CALCIUM DETERMINED VISUALLY
IN SPECTRUM 18.
TABLE
3.
CONCENTRATIONS OF ELEMENTS DETERMINED BY 01RECT-CURRENT ARC EMISSION SPECTROCRAPHY--COHTINUED.
PACE
19-A
REPORT
JOB NO.
IN39
SPEC. LAB. IIH59
FIELD
I OL4
SAMPLE
X-131614
SPECTRUM
14
St AL FE NG CA
HA
K TI P MN AC A8 AU B BA
BE Bl C6 CE CO CR CU i>Y
EREU GA GO til!
HF HO IN IR LA LI LU HN HO NB NO NI
X * * * * 35* * * * *
PPH
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPN
PPM
PPH
PPM
PPN
PPH
PPM
PPM
PPH
PPM
PPM
PPM
PPN
PPM
PPM
PPM
PPN
PPM
PPM
0. 13
< 0.046
1.3
8.6
14 0.45
0. 17
< 4.4432
< 4.468
1 .
1
1 .6
< 15
4<
14 44 74
< 1 .4
< 14
< 32
< 63
< 1 .0
2 .2
520
< 22
< 10
< 2 .2
< 1 .9
< 13
< 1 .5
< 15
< 6.8
< 6 .8
< 15
< 10
< 68
< 13
11000 6
. 1<
3 .2
< 32
( I .5
PROGRAM HO
PLATE NO.
OL3
X-131615
13
0.968
< 4.046
1.2
7.4
16
0. 19
0.13
< 0.0032
< 0.068
1. 1 <
0 .10
< 139
< 19 9.
4119
< 1 .9
< 19
< 32
< 63
1 .3
2.5
349
< 22
< 14
< 2.
2
< 1 .5
< 13
< 1 .5
< 15
< 6.B
< 6 .8
< 13
< 19
< 68
< 15
11999 5
.9<
3 .2
< 327 .9
. 1289292
CE-1316
OL6
X-131616
16
0.49
0.29
2.3
14 20
> 0.46
0.15
0.015
< 0.068
1 .3
1 .9
< 130
< 19 29
100
< 1 .0
< 10
< 32
< 636.8
12 39<
22<
19<
2 .2
< 1 .3
< 15
< 1 .3
< 13
< 6 .8
< 6.8
< 13
< 19
< 68
< 15
13999 8.3
3.8
< 328.3
FOR:
OL7
X-131617
17
9.32
4.17
2.6
9.2
18 4.11
9.13
0.0089
< 0.068
0.95 < 4. 10
< 139
< 14 14
144
< 1.4
< 14
< 32
< 638.
4
4.4
194
< 22
< 14
< 2.2
< 1.
3<
13<
1.3
< 13
< 6.
8
< 6.8
< 13
< 14
< 68
< 13
9544 4.5
< 3.2
< 32 13
MOHAMED S.
S. HOLYLE
DATE! 49/17/89
OL8
OL9
X-131618
X-131619
18
0.071
< 9.946
9.36
7.9
13 0.37
0. 16
< 0.4432
< 0.468
4.41 < 9. 14
< 154
< 14
< 4.6
12
< 1.4
< 10
< 32
< 63
1 .3
1. 7
6.8
< 22
< 10
< 2.2
< 1.
3<
15<
1.5
< 15
< 6.8
< 6.8
< 13
< 10
< 68
< 13
4100 4.
1<
3.2
< 32
1 .9
19
4.466
< 4.446
4.44
7.3
13 4.14
4. 16
< 4.4032
< 0.06B
0.43 < 0.
10
< 13
0<
10<
4 .6
20
< 1 .0
< 19
< 32
< 63
< 1 .9
1 .3
4 .0
< 22
< 10
< 2.2
< 1 .3
< 13
< 1 .3
< 13
< 6 .8
< 6.8
< 15
< 10
< 68
< 15
4399 5.3
< 3.2
< 32
< 1 .5
OL19
X-131629
29
9. 13
< 9.046
0.44
14 17
4.24
< 4.468
< 0.0432
< 4.468
4.70 < 0.10
< 13
9<
19 5 .3
1 19
< 1 .0
< 19
< 32
< 63
< 1 .9
1 .5
6.8
< 22
< 19
< 2.2
< 1 .5
< 15
< 1 .5
< 15
< 6.8
< 6.8
< 15
< 19
< 68
< 15
7999 5
.1<
3 .2
< 324 .9
JOSEPH L. HARRIS
(ANALYST
U. B. CRANDELL
(PLATE RECORDER
D. V. GOLIGHTLY
(PROJECT LEADER
DARHI81-1
DARHIB2-2
DARHIB3-3
X-131621
X-131622
X-131623
21
289.933
6.1
9.7
9.087 H
0.30
0.4042
< 0.068
0.030
709
< 13
9<
10<
6 .8
< 2.2
< 1 .0
38329
< 437.
1
2. 1
> 3299
< 22
< 10
< 2.2
6.8
< 13
< 1 .3
< 13
< 6.8
< 6.8
< 15
< 19
< 68
< 15
399
170 3.3
< 329.5
22
4 .9
9.24
141.
89.59 H
< 9.068
0.919
< 9.0«8
0.951
1999
< 15
0<
19<
6.8
16
< 1.
9530
3009
< 433.
3
19>
3299
< 22
< 19
< 2.
2
32<
13<
1.3
< 13
< 6.8
< 6.8
< 13
< 19
< 68
< 13
319
629 4.
6<
32 34
23
18 9.057
16 4.4
0. 11 H
< 9.968
< 9.9032
< 0.968
0.022
300
< 15
0<
10<
6. 2.
< 1
.38
759 51 16
2.>
3299
< 22
< 19
< 2.
12<
15<
1.<
15<
6.
< 6.
< 13
< 19 H
< 13
229 383.
< 328.
8 8 9 3 2 5 8 8 9 3
TABLE
3. CONCENTRATIONS OF ELEMENTS DETERMINED BY DIRECT-CURRENT ARC EMISSION SPECTROCRAPHY--CONTINUED.
JOB NO. IH59 PAGE
19-8
FIELD
SAMPLE
1 OL4
X-131614
SPECTRUM
14
08 PPM
PB PPM
PD PPM
PR PPM
PT PPM
RE PPM
RH PPM
RU PPM
SB PPM
SC P>M
SM PPM
8N PPM
SR PPM
TA PPM
TB PPM
TH PPM
TL PPM
TM PPM
U PPM
V PPM
U PPM
Y PPM
Yt PPM
ZM PPM
ZR PPM
MAJORS
SI02
AL203
«203
MCO
CAO
HA20
K20
TI02
P209
HNO
< 22
320
< 1 .0
< 68
< 4 .6
< 10
< 2.2
< 2.2
< 32 1
.0
< 10
< t .5
720
< 460
< 32
< 22
< 4 .6
< 4.
6<
320 1 1
< 10
< 1 .9
< 0.19
850 74
RECALCULATED
>. 0.28
* <
0.087
* 1.
9>,
14*
20
* 0.61
* 0.
20
>. <
0.0093
* <
0. 16
* 1.
4
OL9
X-131615
19 < 22
290
< 1 .0
< 60
< 4 .6
< 10
<
2 .2
< 2.2
< 32
1 .2
< 10
< I .5
510
< 460
< 32
< 227.3
< 4.6
< 320 19
< 10
< 1 .5
< 0.19
400 66
AS OXIDES
0. 19
< 0.087
1. 7
12 22
0. 20
0. 18
< 0.0093
< 0.
16
1 .4
OL6
X-131616
16 < 22
220
< 1 .0
< 6B
< 4 .6
< to
< 2.2
< 2.2
< 321.9
< 10
< 1 .9
870
< 460
< 32
< 22
< 4.6
< 4.6
< 320 32
< 10
< 1 .9
< 0. 19
440 96
1 .1
0.59
3.3
23 28
> 0.62
0.18
0 .025
< 0. 16
1 .7
OL7
X-131617
17 < 22
240
< 1.
0<
68<
4.6
< 10
< 2.2
< 2.
2<
321.
9
< 10
< 1.
5990
< 460
< 32
< 22
< 4.
6<
4.6
< 320 42
< 10
< 1.
5<
0. 19
490 90
0.69
0.32
3.7
19 25
0.15
0.16
0.019
< 0.16
1 .2
OL8
X-131618
18 < 22
79<
t.O
< 68
< 4.6
< 10
< 2.2
< 2.2
< 32
1 .7
< 10
< 1.9
310
< 46
0<
32
< 22
< 4.6
< 4.6
< 32
0 9.0
< 10
< 1.9
< 0. 19
120 14
0. 19
< 0.087
0.80
13 18 0.90
0. 1
9<
0.0093
< 0
. 16
0.93
OL9
X-131619
19 < 22 38
< 1 .0
< 68
< 4.6
< 10
< 2.2
< 2.2
< 32
1 .7
< 10
< 1 .9
930
< 46
0<
32
< 22
< 4 .6
< 4.6
< 32
0 6.3
< 10
< 1 .9
< 0.19
170 14
0. 14
< 0.087
0.63
12 18
0. 19
0. 1
9<
0.0093
< 0.16
0.96
OLIO
X-131620
20 < 22 60
< 1 .0
< 68
< 4.6
< 10
<
2.2
< 2.2
< 32
< 1 .0
< to
< 1 .9
3900
< 460
< 32
< 22
< 4 .6
< 4 .6
< 320 9.
6
< 10 2.0
< 0
. 19
260 31
0. 32
< 0.087
0.57
17 24
0.32
< 0.082
< 0.0053
< 0. 16
0.90
DARHIB1-1
X-131621
21 < 22
1600
< 1 .0
< 68
< 4.6
< 10
< 2.2
< 2.2
< 32
< t .0
< 10 4
.73 .0
< 460
< 32
< 22
< 4 .6
< 4.6
< 320 48
< 10 2.0
< 0.
19
100000
< 3.2
600.10
8.7
16 0.12 H
0.36
0 .0
070
< 0.16
0.039
DARHIB2-2
X-131622
22 < 22
40000
< 1.
0<
68<
4.6
< 10
< 2.2
< 2.2
< 32
1 .4
< 10 273.3
< 460
< 32
< 22
< 4.6
< 4.6
< 320 47
< 104.6
< 0.19
> 1000CO
< 3.
2
8.6
0.45
203.0
0.70 H
< 0.082
0 .0
32<
0.16
0.066
DARHIB3-3
X-131623
23 < 22
1200 < t.
< 68 < 4.
< 10
<
2.<
2.<
32<
1.
< 10 IS
< t.
< 460
< 32
< 22
< 4.
< 4.
< 320 17
< 10
< 1.
< 0.
> 100000
< 3.
390. 1
1 237.3
0. 15 H
< 0.082
< 0.0093
< 0.
16
0.028
0 6 2 2 0 0 6 6 9 19 2
1. THE RELATIVE STANDARD DEVIATION FOR EACH REPORTED CONCENTRATION IS
PLUS 50* AND MINUS 33*.
2.
'H'
DENOTES THE OCCURRENCE OF AH UNRESOLVED INTERFERENCE.
3. CALCIUM AND STRONT IUM(SPECTRUM 116) AND ZINC(SPECTRA I'S 22,23) WERE DETERMINED VISUALLY.
TABLE
3.
CONCENTRATIONS OF ELEMENTS DETERMINED BY 01RECT-CURRENT ARC EMISSION SPECTROGRAPHY--CONTINUED.
PAGE
16-A
CO 00
REPORT
JOB HO.
IN59
SPEC.LA8 .IIN59
FIELD
I DARHIB4-4
SAMPLE
X-131705
SPECTRUM
5
91 AL FE NG CA
HA K TI P NN flc AS AU
B BA BE BI cp CE CO CR CU DY ED EU CA GO CE NF HO IN IR LA
LI LU MM MO HI HD HI
* * * * * X*
* * X %
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
PPM
1 1 0.047
4.8
3.0
2.5
H<
0.068
< 0.0032
< 0.068
0.065
300
< 15
0<
10<
4.6
17
< 1 .0
260
3000 543 .0
9 .6
> 3200
< 22
< 10
< 2.2
44 H1 .6
< 15
< 6 .8
H<
15<
10<
68<
19
650
730
< 3.2
< 32 41
PROGRAM HO.
1280202
PLATE NO.
CE-1317
DARHIBS-5
EHINE1-6
X-131706
X-13170?
6
210.098
9.2
6. 1
0. 70 H
< 0.068
0.0040
< 0.068
0.03S 70
< 190
< 10
< 6 .8
< 2.
2
< 1 .0
15940 651 .9
2 .4
> 3200
< 22
< 10
< 2.2
12 N<
1 .5
< 15
< 6 .8
H<
15<
10<
68<
15
350 32
< 3 .2
< 32 11
7
13<
0.046
5.0
5.S
0.70 H
< 0.068
< 0.0032
0.091
1 .1 13
0<
ISO
< 10
< 4 .6
< 2.2
< 1 .0
14610
< 43
< 1.0
1 .4
> 3200
< 22
< 10
< 2 .2
15 H3 .4
< 15
< 6 .8
< 6 .8
< 15
< 10
< 68
< IS
1 10006.3
< 3 .2
< 327.3
FOR!
EHINE2-7
X-131708
B
4.1
0.093
4 .2
6.0
0.41 H
< 0.068
0.010
0.39
13
300
170
< 10 19
< 2.
2
< 1.
020
250
< 43
< 1.
0
6.9
> 3200
< 22
< 10
< 2.
2
13<
19 23<
19<
6.8
< 6.
8<
19<
10<
68<
19
130000 3.
712
< 32 47
MOHAHED 8.
S. HOLYLE
DATE) 09X17/80
EHIHE3-8
EHINE4-9
X-131709
X-431710
9
4 .
1<
0.046
5.0
3.3
2.2
H<
0.068
0.0037
< 0.068
0.93 130
< 150
< 10
< 4.6
< 2.2
< 1.0
421200
< 43 < 1.0
1 .3
> 3200
< 22
< 10
< 2.
2
15<
IS1.
3<
13<
6.8
< 6.8
< 15
< 10
< 68
< 15
9300 27 < 32
< 323. 9
10 1.9
< 0.046
4.6
9.5
3.2
H<
0.068
0.0062
0.73
IS
400
350
< 10 13 28
< 1 .0
20
210
< 63 <
1 .0
3.7
> 3200
< 22
< 10
< 2.2
3.7
< 15
< 1 .3
< IS
< 6 .8
< 6 .8
< 15
< 10
< 68
< 15
190000 17 13
< 32 39
EHIHE5-10
X-131711
1 1
110.23
6.8
1.1
0. 70 H
< 0.068
< 0.0032
0. 18
0.76 300
< 190
< 10
< 6 .8
180
< 1 .0
26290
< 433.2
9.7
> 3200
< 22
< 10
< 2.2
11<
159.5
< 15
< 6 .8
< 6
.8<
15<
10<
68<
13
7600 45
< 3.
2<
326
.8
JOSEPH L. HARRIS
(ANALYST
U. B. CRANDELL
(PLATE RECORDER
D. U. GOLICHTLY
(PROJECT LEADER
EHINE6-11
EHINE7-12
HAHATA1-13
X-131712
X-131713
X-131714
12
8.4
0.16
7 .2
0.75
0.41 H
< 0.068
0.016
0.17
0.62 430
< 13
0<
10 22180
< 1 .0
30230
< 436.4
12>
3200
< 22
< 10
< 2.2
13<
IS 18<
15<
6 .8
< 6.8
< 15 13
< 68
< 15
6200
440
< 3.2
< 324 .9
13
4 .3
0.075
6.3
0.24
1 .0
H<
0.068
0.016
< 0.069
0.75 130
< 130
< 106.
782
< 1.
0<
10520
< 43
1 .0
11>
3200
< 22
< 10
< 2.
2
23<
19 11<
19<
6.8
< 6.8
< 19
< 10
< 69
< 19
7500
280
< 3.2
< 323.3
14
19 0.068
7.2
5.8
4.0
H<
0.069
0.0041
< 0.069
0.036 60
< 15
0<
10<
6. 2.
< 1.
< 10
1200
< 43 20
1 .
> 3200
< 22
< 10
< 2. 4.
H<
1.<
IS<
6.
H<
15<
10<
69<
IS
560 7. 4.
< 322.
8 3 0 2 2 9 3 8 2 3 3
TABLE
3. CONCENTRATIONS OF ELEHEHTS DETERMINED BY DIRECT-CURRENT ARC EMISSION 3PECTROGRAPHY--CONTINUED .
JOB NO. INS9 PACE
16-B
FIELD
1SANPLE
8PECTRUN
08 PP
HP8 PP
HPO PP
HPR
PPH
PT PP
H
RE PP
HRH PP
HRU PP
HSB PP
H9C <FPH
8H PPM
SN PP
H8R PP
HTA PPH
TB PPH
TH PPN
TL PP
HTH
PP
HU
PPH
V PP
H
U PP
HY
PPH
Y8 PPH
ZN PP
HZ« PP
H
DARHIB4-4
X-131705
3
< 22
1800
0<
1 .0
< 68
< 4 .6
< 10
< 2 .2
< 2.2
< 32
,
1 .3
< 109 .6
< 1 .0
< 460
< 32
< 22
< 4.6
< 4.
6<
320
110
< 10
< 1 .3
< 0.
13>
100000 < 3 .2
NAJOR8 RECALCULATED
8102
XAL203
XFE203
XHG
O X
CAO
X
HA20
XK2
0 X
TI02
X
P203
XHN
O X
240.089
6.9
3.0
3.3
H<
0.08
2<
0.0033
< 0.
160.084
DARHIB3-3
X-131706
6
< 22
380
< 1 .0
H<
4 .6
< 10
< 2.2
< 2.2
< 321 .1
< 10 16
< 1 .0
< 460
< 32 H
< 4.
6<
4.6
< 320 42
< 10 1
.90.
16>
100000
< 3.2
AS OXIDES
430.
19
13 10 0.98 H
< 0.082
0.0067
< 0.
16
0.043
EMINE1-
6X-131707
7
< 22
3800
0<
1 .
< 68
< 4.
< 10
< 2.
< 2
.<
32<
1 .
< 10 2.
< 1
.<
460
< 32 H
< 4.
< 4
.<
320 7.
< 10
< 1
.<
0.>
100000
230
28 < 0.087
7.2
9 .1
0.98 H
< 0.082
< 0.0053
0 .2
11 .4
0 6 2 2 0 3 0 6 6 8 3 15
EHIHE2-7
X-131708
8
< 22
26000
< 1.0
< 68
< 4.6
< 22
< 2.2
< 2.2
< 321.
3
< 10
< 1.
3<
1.0
< 460
< 32 H
< 4.
6<
4.6
< 320 79
< 10
< 1.
3<
0. 15
> 100000
< 3.2
8.8
0.18
6.0
10 0.57 H
< 0.082
0 .0
170 .89
17
EN1NE3-8
X-131709
9
< 22
12000
< 1.
0<
68<
4.6
< 10
< 2.2
< 2.2
< 321.
3
< 10
< 1.
3<
1.0
< 460
< 32 H
< 4.6
< 4.6
< 320 3.
6
< 10
< 1.
3<
0. 13
> 100000
210
8.8
< 0.
087
7.2
5 . 9
3. 1
H<
0.082
0 . 0062
< 0. 1
61 .2
ENINE4-9
X-131710
10 < 22
70000
< 1 .0
< 68
< 4 .6
< 10
< 2.2
< 2.2
< 322.2
< 10
< 1 .3
7.9
< 460
< 32 H
< 4 .6
< 4.6
< 320 79
< 10
< 1 .3
< 0.13
> 100000
< 3.2
4. 1
< 0.087
6.6
9. 1
4.3
H<
0.082
0.010
1.7
19
EHIHE5-10
X-131711
11 < 22
26000
< 1 .0
< 68
< 4 .6
< 10
< 2.2
< 2.2
< 32
1 .0
< 10 9.5
7.8
< 460
< 32 H
< 4 .6
< 4 .6
< 320 82 H2.3
0.37
> 100000
< 3 .2
240.44
9.7
1 .8
0.98 H
< 0.082
< 0.0053
0.41
0.98
EH1NE6-11
X-131712
12 < 22
18000
< 1 .0
< 68
< 4.6
< 10
< 2.2
< 2.2
< 321 .3
< 10 141.
3<
460
< 32 H
< 4 .6
< 4 .6
< 320
100
< 10 4.
30.91
> 100000
< 3.2
180.30
101 .2
0.57 H
< 0.082
0.027
0.39
0.80
EHINE7-12
X-131713
13 < 22
12000
< 1.
0<
68<
4.6
< 10
< 2.2
< 2.2
< 321.
7
< 10 18
< 1.
0<
460
< 32 H
< 4.6
< 4.6
< 32
0 76 H<
1.3
0.90
> 100000
< 3.2
9.2
0.14
9 .0
0.40
1 .4
H<
0.082
0 .0
27<
0.16
0.97
HAHATA1-
X-13171
14 < 22
720
< 1.
H<
4.
< 10
< 2.
< 2.
< 321.
< 104.
< 1.
< 460
< 32 H < 4.
< 4.
< 32
0 9.
H<
1.<
0.)
100000
< 3.
410.
13
10 9.6
3.6
H<
0.082
0.0068
< 0.
16
0.072
13 4 0 6 2 2 3 6 0 6 6 9 3 13 2
1. THE RELATIVE STANDARD DEVIATION FOR EACH REPORTED CONCENTRATION 18 PLUS 50% AND NINUS 33X.
2.
'H'
DENOTES THE OCCURRENCE OF AN UNRESOLVED INTERFERENCE.
3. AG,ZN(SPECTRA I'S
9 THRU 14)/CA<SPECTRA I'S 6,7,11 ),PB<SPECTRA I'S 5,7 THRU 13 ),SI<SPECTRA I
10) WERE DETERMINED VISUALLY
S 3/7,11) AND ZR (SPECTRA I'S
8.
TABLE
3.
CONCENTRATIONS OF ELEMENTS DETERMINED BY
01RECT-CURRENT ARC EMISSION SPECTROGRAPHY--CONTINUED.
PACE
17-A
REPORT
JOB NO.
IH39
SPEC.LAB I1H59
PROGRAM NO
. 1280202
PLATE NO.
CE-1317
FOR:
HOHANED S.
S. HOLYLE
OATEl 09/17/84
JOSEPH L. HARRIS
V.
B. CRANDELL
0. U. GOLIGHTLY
(ANALYST)
(PLATE RECORDER)
(PROJECT LEADER)
FIELD
1 HAHATA2-14
SAHPLE
X-131715
SPECTRUM
15
91 AL FE HG CA
MA K TI P MM AC AS AU
-P»
B0
BA BE BI CD
CE CO CR CU OY ER EU GA GO GE HF HO IN IR LA LI LU MH MO NB NO NI
* * * % *
. *
* * jj v. *
PPM
PPH
PPH
PPH
PPM
PPH
PPH
PPH
PPH
PPH
PPH
PPH
PPH
PPH
PPH
PPH
PPH
PPH
PPH
PPH
PPH
PPM
PPH
PPM
PPM
PPH
PPH
PPH
PPH
PPH
113.
17. 1
3.5
0.020
0.30
1 .8
0. 1
3<
0.068
0.27
3.7
< 150
< 10
< « .8
24
< 1 .0
< 10
< 32
< 43 29
3.6
370
< 22
< 10
< 2 .2
25<
15<
1 .5
< IS
< 6 .8
< «
.B<
13<
10<
68<
15
2700 4
.34 .4
< 327.2
HAKAL15
X-131716
It
30 8.
0(.3
2.0
6 1
3.3
1. 1
0.43
0.22
0. 17
0<
130
< 10
< 6
440
< 1
< 10
< 32
< 63 33
212
0<
22<
10<
2
21<
15<
1<
15<
t
< 6
< 15 27
< 68
< 15
1700 421
< 327
.40
.8 .0 .2 .2 .5 .8 .8 .1 .4
TABLE 3.
CONCENTRATIONS OF ELENEHTS DETERMINED BY 0IRECT-CURRENT ARC EMISSION SPECTROGRflPHY--CONTIHUED.
JOB NO. IM31 PACE
17-B
FIELD
1 BANPLE
8PECTRUH
08 PB PO PR PT RE RH RU 9B 8C SM SH SR TA TB TN TL TH U V U Y YB ZR ZR
PPH
PPN
PPH
PPH
PPH
PPH
PPH
PPH
PPH
P*H
PPH
PPH
PPH
PPH
PPH
PPH
PPH
PPH
PPN
PPH
PPH
PPH
PPH
PPH
PPH
HAHATA2
X-1317
IS < 22 130
< 1
< 68
< 4
< 10
< 2
< 2
< 32 15
< 10
< 1
< 1
< 460
< 32
< 22
< 4
< 4
< 32
0180
< 102 0
930 19
-14
IS .0 .6 .2 .2 .3 .0 .6 .6 .3 .23
HAKAL13
X-131716
16 < 22 33
< 1
< 68
< 4
< 10
< 2
< 2
< 32 12
< 10 4
380
< 460
< 32
< 22
< 4
< 4
< 32
01 10
< 10 16 3.
300
140
.0 .6 .2 .2 .5 .6 6 8
MAJORS RECALCULATED AS OXIDES
v SIQ2
. AL203
FE203
HGO
CAO
NA20
K20
TI02
P20S
MHO
* J5 55 * * 3 X * 5! X
243.
109, 0 0 2 0
< 0. 0
9 1 028
40 2 22 16 33
64 IS9. 3. 8. 4. 1 0. 0. 0.
0 3 3 5 3 75 50 22
1. THE RELATIVE STANDARD DEVIATION FOR EACH REPORTED CONCENTRATION IS PLUS 50* AND MINUS 333
