Towards the prediction of wine outcomes from grape ......fatty acid ethyl esters, acetate esters...
Transcript of Towards the prediction of wine outcomes from grape ......fatty acid ethyl esters, acetate esters...
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Towards the prediction of wine outcomes from grape
compositional measures
Bob Dambergs, Paul Smith
WS42 18 July 2012
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The Australian Wine
Research Institute
AWRI technology along the value chain
Working on the Value Chain from vineyard soil to point of sale, and beyond
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The Australian Wine
Research Institute
Some basic wine parameters
• F/T SO2
• Heat and cold stability
• pH
• TA
• Alcohol
• Sugar
• VA
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The Australian Wine
Research Institute
Classes of quality measures, based on process
• Grape metabolites directly extracted into wine
• Grape metabolites converted by mechanical processing
• Grape metabolites converted by yeast processing
• Grape metabolites converted by a combination of mechanical and yeast processing
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The Australian Wine
Research Institute Grape metabolites directly extracted into wine
• Rotundone
• Methoxypyrazine
• C13 norisoprenoids
– Beta-ionone
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(-)-Rotundone
• By GC-MS-O, rotundone was established as the principal aroma
impact compound for pepper aroma in grapes and wine.
• 20-25% of people can’t smell it
O
Wood, C.; Siebert, T. E.; Parker, M. et al. J. Agric. Food Chem. 2008, 56, 3738-3744 Siebert, T. E. et al. J. Agric. Food Chem. 2008, 56, 3745-3748
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• We can now start to look at what influences rotundone levels
• A large survey of commercial wines was undertaken to guide us
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AWRI TR #180 (June 2009)
Rotundone in Australian wines
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• Impact of viticulture on Rotundone?
Fruit exposure?
Leaf removal time?
Crop load?
Vine vegetative vigour?
rotundone
not detected
not detected
found in grape skins, leaves and stalks Increases during grape ripening
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The Australian Wine
Research Institute Methoxypyrazines
• Concentration in wines depend on • berry maturity • climate • fruit exposure • skin contact during winemaking, pressing
• Green bean, capsicum, asparagus • IBMP easily extractable
– concentration in free-run wine is principally determined by that in the grapes, while it is relatively unaffected by vatting conditions.
• Cabernet sauvignon, merlot, sauvignon blanc, semillon (not in pinot grapes, shiraz, chard, riesling)
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The Australian Wine
Research Institute
Wine aromas that are released or created from grape compounds (but a little help from yeast...)
• Terpenes;
– geraniol (skin), Linalool (throughout berry), Nerol (skin), alpha-terpineol
– Wine lactone
• C13 norisoprenoids
– Beta-Damascenone
• C-6 alcohols
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The Australian Wine
Research Institute Free Terpenes
• Geraniol (skin) & Nerol (skin) – young wines
• Linalool (throughout berry) & alpha-terpineol – older wines
• Rose, geranium, floral
• Enzyme and acid releases the glycosylated precursor from grapes
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The Australian Wine
Research Institute
Polyhydroxylated terpenes
• the polyhydoxylated monoterpenes make no direct contribution to the aroma although some of them are reactive and can easily rearrange during ferment to give pleasant and potent aromas;
• cis rose oxide – lychee, rose
• Wine lactone – coconut, lime
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The Australian Wine
Research Institute
• Grape berry metabolism
• Carotenoid degradation
• Bound to sugars: released from glycoside precursors
• Diverse aroma properties as a class
– damascenone sweet, fruity, cooked apple,
– ionone raspberry, berry, violets
C13 Norisoprenoids
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The Australian Wine
Research Institute
C13 Norisoprenoids during grape maturation
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C6-alcohols
1-hexanol
cis-3-hexenol
• Fresh cut grassy aroma in wine
• enzymatic oxidation of grape fatty acids by lipoxygenases,
• solids in ferment
• Role in green flavour unclear
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The Australian Wine
Research Institute
Wine aromas created by metabolic action of yeast
• Esters
• Alcohols
• 4-EP
• VA
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The Australian Wine
Research Institute Esters
fatty acid ethyl esters, acetate esters • fruity aromas • isoamyl acetate (3-methyl butyl acetate) banana • ethyl hexanoate pineapple
• slower rate of fermentation, increase in esters – ie lower temp
• yeast strain • juice composition: amino acid pattern • undergo chemical hydrolysis/reaching chemical equilibrium with storage • varietal differences can be significant • Very significant in defining sensory profile of the wine • Fatty acid derivatives role in esters
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The Australian Wine
Research Institute Higher Alcohols
• Yeast metabolism of amino acids and sugars. For e.g. Phenyl ethyl alcohol – from phenylalanine, (rose-like aroma)
• lsobutanol – Solvent, harsh
• Isoamyl alcohol – whiskey, malt, burnt
• 2-Phenylethyl alcohol – rose, lilac
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The Australian Wine
Research Institute
Grape metabolites influenced by mechanical and yeast effects
• Varietal thiols for Sauv Blanc (some riesling/chard)
• Tannin
• Colour
• Polysaccharides
• Fatty acids (short and medium chain)
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Fruity thiols
• Cysteine, glutathione conjugates, released by yeast metabolism
• Sauvignon Blanc, Riesling, Chardonnay, Cabernet Sauvignon
Aroma threshold
4-methyl mercaptopentanone 4-MMP 0.8 ng/L
3-mercaptohexanol 3-MH 60 ng/L
3-mercaptohexyl acetate 3-MHA 4 ng/L
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The Australian Wine
Research Institute
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The Australian Wine
Research Institute
Factors affecting fruity thiols
• Ripening - Low levels of precursors until commercial harvest
• Processing/transportation – precursors are sensitive to oxidation – a combination of both SO2 and Ascorbic acid
optimum
BUT very high SO2 suppresses conjugate formation
• Yeast choice – turn a Chardonnay into Sauvignon Blanc!!
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Grape colour correlates with wine colour
Riverland Shiraz trial
0.6 0.7 0.8 0.9 1.0 1.1 1.2 1.3 1.4
Grape colour (mg/g)
0
1
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3
4
Win
e c
olo
ur
(AU
)
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But grape colour does not equal wine colour
Anthocyanins are
not the final stable
colour in wine – they
react with tannin to
produce pigmented
tannins (or “pigmented
polymers”)
0 10 20 30 40 50 60 70 80 90 100 DAY
0
100
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300
Va
lue
The concentration of
M3G increases during
fermentation until taken
off skins, then it rapidly
declines, while
pigmented tannins
increase
M3G
Pigmented Tannins
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[PP] = 0.06 [ M3G ] + 0.04 [ T ] - 2.88
R2 = 0.92
PP: pigmented polymers
M3G: malvidin 3-glucoside
T: tannins
If we know the tannin and anthocyanin concentrations we
can predict final, stable wine colour
Predicting wine pigmented tannin potential
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Tannin correlates with commercial quality grading
2005-2007 Hardy Shiraz - but also applied to Fosters and Orlando wines
A B C D E F G H I
Quality grade
0
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Ta
nn
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ep
ica
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Mercurio, M.D., Dambergs, R.G., Cozzolino, D., Herderich, M.J, Smith, P. A. (2010) Relationship between red wine grades and phenolics 1. tannin and total phenolics concentrations. J. Agric. Food Chem., 58: 12313–12319
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The Australian Wine
Research Institute
Adel Morn Pad Tas Yarra
Region
0
1
2
3
Tann
in (
g/L
)Adel
BarCan
Clare
CoonaLang
MDar
Marg
Mva
lePad
PyrenRland
RuthSwan
Wra
t
Region
0
1
2
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4
5
Tan
nin
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)
AdelBar
CanClare
CoonaLang
MDar
Marg
Mud
Mva
lePad
PyrenRland
RuthSwan
Wra
t
Yarra
Region
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2
3
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5
6
Tan
nin
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)
Cabernet sauvignon Shiraz Pinot noir
Wine Tannin varies with region
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Tannin and pigment in context with
commercial wine styles
The Pinot Shop “...Avancé is a very charming pinot. The fruit has a sweet suppleness. It is quite delicate but there’s nice liveliness and freshness with florals and red berries..”
$29.50
The Pinot Shop “…Reveur (‘dreamer’) Pinot Noir is a pure but weighty wine with distinct charry-cherry characters. That’s from some good oak wrapped around vintage 2008’s ripe Coal Valley fruit. The tannins are round and chewy ……I suspect that the ripe tannins will smooth out into silky, luscious pinot..”
$46
Tannin 1.31 g/L Pigmented tannin 1.14 AU Total Pigment 8.11 AU
Tannin 1.84 g/L Pigmented tannin 1.56 AU Total Pigment 11.42 AU
i.e. Pinot tannin is worth $42,000/Kg
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Correlation of tannin and wine colour density: cool season
Cabernet Shiraz
Tan
nin
(e
pic
at. e
q. g
/L)
5
8 9 10 11 12 13 14 15 1
2
3
4
R= 0.47
Tan
nin
(e
pic
at. e
q. g
/L)
9 10 11 12 13 14 15 1
2
3 R= 0.42
Colour density (AU) Colour density (AU)
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Correlation of tannin and wine colour density: hot season
Cabernet Shiraz
R = 0.66 R = 0.78
5 10 15 20
Colour density (AU)
1
2
3
Tan
nin
(e
pic
at. e
q. g
/L)
5 10 15
Colour density (AU)
1
2
* Colour and data analysis performed by Dr. R. Dambergs
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A model of tannin extraction, desorption and adsorption during fermentation
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0.00
200000.00
400000.00
600000.00
800000.00
1000000.00
1200000.00
0 2 4 6 8 10
PA1
PA2
PA3
PA4/5
low MW polys
low MW polys
Medium MW polys grape derived
High MW polys yeast derived
Astringency modulation Hotness suppression? Texture/viscosity? Roles in white vs red?
Polysaccharides in Australian Shiraz across quality grades
Quality grade
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The Australian Wine
Research Institute environment
• 1,8-cineol (Eucalyptol)
• Smoke taint
• Regionality – other aromas from plants?
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The Australian Wine
Research Institute 1,8 cineole - Eucalyptol
• Terpenoid
• Eucalyptus, mint, camphor
• Can be both grape-derived and from eucalyptus trees near vineyards
• Cineole levels increase during skin contact
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The Australian Wine
Research Institute
• Out of 146 commercially available red
wines of various varieties we analysed,
40% of them contained 1,8-cineole above
reported detection threshold.
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The Australian Wine
Research Institute mysteries
• Benzyl mercaptan (struck flint)
• Low molecular weight sulphur compounds
• DMS
– Red wine character
– Partly grapes, partly yeast
– Blackcurrant, dark fruit at moderate levels
– Undesirable cooked veg at higher
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A tool to characterise and communicate Pinot Grigio and Pinot Gris wine ‘style’
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…and there is now a Grape and
Wine Tannin Portal
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BUT......................