Today’s Outline - February 03, 2014csrri.iit.edu/~segre/phys406/14S/lecture_05.pdfToday’s...
Transcript of Today’s Outline - February 03, 2014csrri.iit.edu/~segre/phys406/14S/lecture_05.pdfToday’s...
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Today’s Outline - February 03, 2014
• Relativistic correction
• Spin-orbit coupling
• Zeeman effect
Office Hours: Monday & Wednesday 10:00-11:00 or by Appt.
Homework Assignment #03:Chapter 6: 9, 17, 21, 24, 25, 32due Monday, February 10, 2014
Tutoring sessions:Thursday & Friday, 12:00–13:45, 121 E1
C. Segre (IIT) PHYS 406 - Spring 2014 February 03, 2014 1 / 7
![Page 2: Today’s Outline - February 03, 2014csrri.iit.edu/~segre/phys406/14S/lecture_05.pdfToday’s Outline - February 03, 2014 Relativistic correction Spin-orbit coupling Zeeman e ect O](https://reader035.fdocuments.us/reader035/viewer/2022070217/6122876b38aab531eb1918f2/html5/thumbnails/2.jpg)
Today’s Outline - February 03, 2014
• Relativistic correction
• Spin-orbit coupling
• Zeeman effect
Office Hours: Monday & Wednesday 10:00-11:00 or by Appt.
Homework Assignment #03:Chapter 6: 9, 17, 21, 24, 25, 32due Monday, February 10, 2014
Tutoring sessions:Thursday & Friday, 12:00–13:45, 121 E1
C. Segre (IIT) PHYS 406 - Spring 2014 February 03, 2014 1 / 7
![Page 3: Today’s Outline - February 03, 2014csrri.iit.edu/~segre/phys406/14S/lecture_05.pdfToday’s Outline - February 03, 2014 Relativistic correction Spin-orbit coupling Zeeman e ect O](https://reader035.fdocuments.us/reader035/viewer/2022070217/6122876b38aab531eb1918f2/html5/thumbnails/3.jpg)
Today’s Outline - February 03, 2014
• Relativistic correction
• Spin-orbit coupling
• Zeeman effect
Office Hours: Monday & Wednesday 10:00-11:00 or by Appt.
Homework Assignment #03:Chapter 6: 9, 17, 21, 24, 25, 32due Monday, February 10, 2014
Tutoring sessions:Thursday & Friday, 12:00–13:45, 121 E1
C. Segre (IIT) PHYS 406 - Spring 2014 February 03, 2014 1 / 7
![Page 4: Today’s Outline - February 03, 2014csrri.iit.edu/~segre/phys406/14S/lecture_05.pdfToday’s Outline - February 03, 2014 Relativistic correction Spin-orbit coupling Zeeman e ect O](https://reader035.fdocuments.us/reader035/viewer/2022070217/6122876b38aab531eb1918f2/html5/thumbnails/4.jpg)
Today’s Outline - February 03, 2014
• Relativistic correction
• Spin-orbit coupling
• Zeeman effect
Office Hours: Monday & Wednesday 10:00-11:00 or by Appt.
Homework Assignment #03:Chapter 6: 9, 17, 21, 24, 25, 32due Monday, February 10, 2014
Tutoring sessions:Thursday & Friday, 12:00–13:45, 121 E1
C. Segre (IIT) PHYS 406 - Spring 2014 February 03, 2014 1 / 7
![Page 5: Today’s Outline - February 03, 2014csrri.iit.edu/~segre/phys406/14S/lecture_05.pdfToday’s Outline - February 03, 2014 Relativistic correction Spin-orbit coupling Zeeman e ect O](https://reader035.fdocuments.us/reader035/viewer/2022070217/6122876b38aab531eb1918f2/html5/thumbnails/5.jpg)
Today’s Outline - February 03, 2014
• Relativistic correction
• Spin-orbit coupling
• Zeeman effect
Office Hours: Monday & Wednesday 10:00-11:00 or by Appt.
Homework Assignment #03:Chapter 6: 9, 17, 21, 24, 25, 32due Monday, February 10, 2014
Tutoring sessions:Thursday & Friday, 12:00–13:45, 121 E1
C. Segre (IIT) PHYS 406 - Spring 2014 February 03, 2014 1 / 7
![Page 6: Today’s Outline - February 03, 2014csrri.iit.edu/~segre/phys406/14S/lecture_05.pdfToday’s Outline - February 03, 2014 Relativistic correction Spin-orbit coupling Zeeman e ect O](https://reader035.fdocuments.us/reader035/viewer/2022070217/6122876b38aab531eb1918f2/html5/thumbnails/6.jpg)
Today’s Outline - February 03, 2014
• Relativistic correction
• Spin-orbit coupling
• Zeeman effect
Office Hours: Monday & Wednesday 10:00-11:00 or by Appt.
Homework Assignment #03:Chapter 6: 9, 17, 21, 24, 25, 32due Monday, February 10, 2014
Tutoring sessions:Thursday & Friday, 12:00–13:45, 121 E1
C. Segre (IIT) PHYS 406 - Spring 2014 February 03, 2014 1 / 7
![Page 7: Today’s Outline - February 03, 2014csrri.iit.edu/~segre/phys406/14S/lecture_05.pdfToday’s Outline - February 03, 2014 Relativistic correction Spin-orbit coupling Zeeman e ect O](https://reader035.fdocuments.us/reader035/viewer/2022070217/6122876b38aab531eb1918f2/html5/thumbnails/7.jpg)
Today’s Outline - February 03, 2014
• Relativistic correction
• Spin-orbit coupling
• Zeeman effect
Office Hours: Monday & Wednesday 10:00-11:00 or by Appt.
Homework Assignment #03:Chapter 6: 9, 17, 21, 24, 25, 32due Monday, February 10, 2014
Tutoring sessions:Thursday & Friday, 12:00–13:45, 121 E1
C. Segre (IIT) PHYS 406 - Spring 2014 February 03, 2014 1 / 7
![Page 8: Today’s Outline - February 03, 2014csrri.iit.edu/~segre/phys406/14S/lecture_05.pdfToday’s Outline - February 03, 2014 Relativistic correction Spin-orbit coupling Zeeman e ect O](https://reader035.fdocuments.us/reader035/viewer/2022070217/6122876b38aab531eb1918f2/html5/thumbnails/8.jpg)
Relativistic correction review
The lowest order relativisticcorrection is
applying first order perturba-tion theory
with the Schrodinger equa-tion
p2ψ = 2m(E − V )ψ
given that⟨1
r
⟩=
1
n2a⟨1
r2
⟩=
1
(l + 1/2)n3a2
H ′r = − p4
8m3c2
E 1r =
⟨H ′r
⟩= − 1
8m3c2⟨p2ψ|p2ψ
⟩= − 1
2mc2[e2 − 2E 〈V 〉+ 〈V 2〉]
= − 1
2mc2
[(En)2 + 2En
(e2
4πε0
)⟨1
r
⟩+
(e2
4πε0
)2⟨1
r2
⟩]
E 1r = −(En)2
2mc2
[4n
l + 1/2− 3
]
C. Segre (IIT) PHYS 406 - Spring 2014 February 03, 2014 2 / 7
![Page 9: Today’s Outline - February 03, 2014csrri.iit.edu/~segre/phys406/14S/lecture_05.pdfToday’s Outline - February 03, 2014 Relativistic correction Spin-orbit coupling Zeeman e ect O](https://reader035.fdocuments.us/reader035/viewer/2022070217/6122876b38aab531eb1918f2/html5/thumbnails/9.jpg)
Relativistic correction review
The lowest order relativisticcorrection is
applying first order perturba-tion theory
with the Schrodinger equa-tion
p2ψ = 2m(E − V )ψ
given that⟨1
r
⟩=
1
n2a⟨1
r2
⟩=
1
(l + 1/2)n3a2
H ′r = − p4
8m3c2
E 1r =
⟨H ′r
⟩= − 1
8m3c2⟨p2ψ|p2ψ
⟩= − 1
2mc2[e2 − 2E 〈V 〉+ 〈V 2〉]
= − 1
2mc2
[(En)2 + 2En
(e2
4πε0
)⟨1
r
⟩+
(e2
4πε0
)2⟨1
r2
⟩]
E 1r = −(En)2
2mc2
[4n
l + 1/2− 3
]
C. Segre (IIT) PHYS 406 - Spring 2014 February 03, 2014 2 / 7
![Page 10: Today’s Outline - February 03, 2014csrri.iit.edu/~segre/phys406/14S/lecture_05.pdfToday’s Outline - February 03, 2014 Relativistic correction Spin-orbit coupling Zeeman e ect O](https://reader035.fdocuments.us/reader035/viewer/2022070217/6122876b38aab531eb1918f2/html5/thumbnails/10.jpg)
Relativistic correction review
The lowest order relativisticcorrection is
applying first order perturba-tion theory
with the Schrodinger equa-tion
p2ψ = 2m(E − V )ψ
given that⟨1
r
⟩=
1
n2a⟨1
r2
⟩=
1
(l + 1/2)n3a2
H ′r = − p4
8m3c2
E 1r =
⟨H ′r
⟩= − 1
8m3c2⟨p2ψ|p2ψ
⟩= − 1
2mc2[e2 − 2E 〈V 〉+ 〈V 2〉]
= − 1
2mc2
[(En)2 + 2En
(e2
4πε0
)⟨1
r
⟩+
(e2
4πε0
)2⟨1
r2
⟩]
E 1r = −(En)2
2mc2
[4n
l + 1/2− 3
]
C. Segre (IIT) PHYS 406 - Spring 2014 February 03, 2014 2 / 7
![Page 11: Today’s Outline - February 03, 2014csrri.iit.edu/~segre/phys406/14S/lecture_05.pdfToday’s Outline - February 03, 2014 Relativistic correction Spin-orbit coupling Zeeman e ect O](https://reader035.fdocuments.us/reader035/viewer/2022070217/6122876b38aab531eb1918f2/html5/thumbnails/11.jpg)
Relativistic correction review
The lowest order relativisticcorrection is
applying first order perturba-tion theory
with the Schrodinger equa-tion
p2ψ = 2m(E − V )ψ
given that⟨1
r
⟩=
1
n2a⟨1
r2
⟩=
1
(l + 1/2)n3a2
H ′r = − p4
8m3c2
E 1r =
⟨H ′r
⟩= − 1
8m3c2⟨p2ψ|p2ψ
⟩
= − 1
2mc2[e2 − 2E 〈V 〉+ 〈V 2〉]
= − 1
2mc2
[(En)2 + 2En
(e2
4πε0
)⟨1
r
⟩+
(e2
4πε0
)2⟨1
r2
⟩]
E 1r = −(En)2
2mc2
[4n
l + 1/2− 3
]
C. Segre (IIT) PHYS 406 - Spring 2014 February 03, 2014 2 / 7
![Page 12: Today’s Outline - February 03, 2014csrri.iit.edu/~segre/phys406/14S/lecture_05.pdfToday’s Outline - February 03, 2014 Relativistic correction Spin-orbit coupling Zeeman e ect O](https://reader035.fdocuments.us/reader035/viewer/2022070217/6122876b38aab531eb1918f2/html5/thumbnails/12.jpg)
Relativistic correction review
The lowest order relativisticcorrection is
applying first order perturba-tion theory
with the Schrodinger equa-tion
p2ψ = 2m(E − V )ψ
given that⟨1
r
⟩=
1
n2a⟨1
r2
⟩=
1
(l + 1/2)n3a2
H ′r = − p4
8m3c2
E 1r =
⟨H ′r
⟩= − 1
8m3c2⟨p2ψ|p2ψ
⟩
= − 1
2mc2[e2 − 2E 〈V 〉+ 〈V 2〉]
= − 1
2mc2
[(En)2 + 2En
(e2
4πε0
)⟨1
r
⟩+
(e2
4πε0
)2⟨1
r2
⟩]
E 1r = −(En)2
2mc2
[4n
l + 1/2− 3
]
C. Segre (IIT) PHYS 406 - Spring 2014 February 03, 2014 2 / 7
![Page 13: Today’s Outline - February 03, 2014csrri.iit.edu/~segre/phys406/14S/lecture_05.pdfToday’s Outline - February 03, 2014 Relativistic correction Spin-orbit coupling Zeeman e ect O](https://reader035.fdocuments.us/reader035/viewer/2022070217/6122876b38aab531eb1918f2/html5/thumbnails/13.jpg)
Relativistic correction review
The lowest order relativisticcorrection is
applying first order perturba-tion theory
with the Schrodinger equa-tion
p2ψ = 2m(E − V )ψ
given that⟨1
r
⟩=
1
n2a⟨1
r2
⟩=
1
(l + 1/2)n3a2
H ′r = − p4
8m3c2
E 1r =
⟨H ′r
⟩= − 1
8m3c2⟨p2ψ|p2ψ
⟩= − 1
2mc2[e2 − 2E 〈V 〉+ 〈V 2〉]
= − 1
2mc2
[(En)2 + 2En
(e2
4πε0
)⟨1
r
⟩+
(e2
4πε0
)2⟨1
r2
⟩]
E 1r = −(En)2
2mc2
[4n
l + 1/2− 3
]
C. Segre (IIT) PHYS 406 - Spring 2014 February 03, 2014 2 / 7
![Page 14: Today’s Outline - February 03, 2014csrri.iit.edu/~segre/phys406/14S/lecture_05.pdfToday’s Outline - February 03, 2014 Relativistic correction Spin-orbit coupling Zeeman e ect O](https://reader035.fdocuments.us/reader035/viewer/2022070217/6122876b38aab531eb1918f2/html5/thumbnails/14.jpg)
Relativistic correction review
The lowest order relativisticcorrection is
applying first order perturba-tion theory
with the Schrodinger equa-tion
p2ψ = 2m(E − V )ψ
given that⟨1
r
⟩=
1
n2a⟨1
r2
⟩=
1
(l + 1/2)n3a2
H ′r = − p4
8m3c2
E 1r =
⟨H ′r
⟩= − 1
8m3c2⟨p2ψ|p2ψ
⟩= − 1
2mc2[e2 − 2E 〈V 〉+ 〈V 2〉]
= − 1
2mc2
[(En)2 + 2En
(e2
4πε0
)⟨1
r
⟩+
(e2
4πε0
)2⟨1
r2
⟩]
E 1r = −(En)2
2mc2
[4n
l + 1/2− 3
]
C. Segre (IIT) PHYS 406 - Spring 2014 February 03, 2014 2 / 7
![Page 15: Today’s Outline - February 03, 2014csrri.iit.edu/~segre/phys406/14S/lecture_05.pdfToday’s Outline - February 03, 2014 Relativistic correction Spin-orbit coupling Zeeman e ect O](https://reader035.fdocuments.us/reader035/viewer/2022070217/6122876b38aab531eb1918f2/html5/thumbnails/15.jpg)
Relativistic correction review
The lowest order relativisticcorrection is
applying first order perturba-tion theory
with the Schrodinger equa-tion
p2ψ = 2m(E − V )ψ
given that⟨1
r
⟩=
1
n2a⟨1
r2
⟩=
1
(l + 1/2)n3a2
H ′r = − p4
8m3c2
E 1r =
⟨H ′r
⟩= − 1
8m3c2⟨p2ψ|p2ψ
⟩= − 1
2mc2[e2 − 2E 〈V 〉+ 〈V 2〉]
= − 1
2mc2
[(En)2 + 2En
(e2
4πε0
)⟨1
r
⟩+
(e2
4πε0
)2⟨1
r2
⟩]
E 1r = −(En)2
2mc2
[4n
l + 1/2− 3
]
C. Segre (IIT) PHYS 406 - Spring 2014 February 03, 2014 2 / 7
![Page 16: Today’s Outline - February 03, 2014csrri.iit.edu/~segre/phys406/14S/lecture_05.pdfToday’s Outline - February 03, 2014 Relativistic correction Spin-orbit coupling Zeeman e ect O](https://reader035.fdocuments.us/reader035/viewer/2022070217/6122876b38aab531eb1918f2/html5/thumbnails/16.jpg)
Relativistic correction review
The lowest order relativisticcorrection is
applying first order perturba-tion theory
with the Schrodinger equa-tion
p2ψ = 2m(E − V )ψ
given that⟨1
r
⟩=
1
n2a⟨1
r2
⟩=
1
(l + 1/2)n3a2
H ′r = − p4
8m3c2
E 1r =
⟨H ′r
⟩= − 1
8m3c2⟨p2ψ|p2ψ
⟩= − 1
2mc2[e2 − 2E 〈V 〉+ 〈V 2〉]
= − 1
2mc2
[(En)2 + 2En
(e2
4πε0
)⟨1
r
⟩+
(e2
4πε0
)2⟨1
r2
⟩]
E 1r = −(En)2
2mc2
[4n
l + 1/2− 3
]
C. Segre (IIT) PHYS 406 - Spring 2014 February 03, 2014 2 / 7
![Page 17: Today’s Outline - February 03, 2014csrri.iit.edu/~segre/phys406/14S/lecture_05.pdfToday’s Outline - February 03, 2014 Relativistic correction Spin-orbit coupling Zeeman e ect O](https://reader035.fdocuments.us/reader035/viewer/2022070217/6122876b38aab531eb1918f2/html5/thumbnails/17.jpg)
Relativistic correction review
The lowest order relativisticcorrection is
applying first order perturba-tion theory
with the Schrodinger equa-tion
p2ψ = 2m(E − V )ψ
given that⟨1
r
⟩=
1
n2a⟨1
r2
⟩=
1
(l + 1/2)n3a2
H ′r = − p4
8m3c2
E 1r =
⟨H ′r
⟩= − 1
8m3c2⟨p2ψ|p2ψ
⟩= − 1
2mc2[e2 − 2E 〈V 〉+ 〈V 2〉]
= − 1
2mc2
[(En)2 + 2En
(e2
4πε0
)⟨1
r
⟩+
(e2
4πε0
)2⟨1
r2
⟩]
E 1r = −(En)2
2mc2
[4n
l + 1/2− 3
]C. Segre (IIT) PHYS 406 - Spring 2014 February 03, 2014 2 / 7
![Page 18: Today’s Outline - February 03, 2014csrri.iit.edu/~segre/phys406/14S/lecture_05.pdfToday’s Outline - February 03, 2014 Relativistic correction Spin-orbit coupling Zeeman e ect O](https://reader035.fdocuments.us/reader035/viewer/2022070217/6122876b38aab531eb1918f2/html5/thumbnails/18.jpg)
Magnetic field at the electron
p
p
B L
e
r
The “normal” view of a hydro-gen atom has the electron rotatingabout the proton (really just havingangular momentum)
In the electron’s frame of referenceit is the opposite
The “rotating” proton has angular momentum and produces a magneticfield at the position of the electron
This magnetic field produces a per-turbative torque on the electron’smagnetic moment from the Biot-Savart law
L = rmv
=2πmr2
τ
since ~B ‖ ~L
H = −~µ · ~B
B =µ0i
2r=
i
2ε0c2r=
e
2ε0c2τ r
~B =1
4πε0
e
mc2r3~L
C. Segre (IIT) PHYS 406 - Spring 2014 February 03, 2014 3 / 7
![Page 19: Today’s Outline - February 03, 2014csrri.iit.edu/~segre/phys406/14S/lecture_05.pdfToday’s Outline - February 03, 2014 Relativistic correction Spin-orbit coupling Zeeman e ect O](https://reader035.fdocuments.us/reader035/viewer/2022070217/6122876b38aab531eb1918f2/html5/thumbnails/19.jpg)
Magnetic field at the electron
L
e
p
B
r
The “normal” view of a hydro-gen atom has the electron rotatingabout the proton (really just havingangular momentum)
In the electron’s frame of referenceit is the opposite
The “rotating” proton has angular momentum and produces a magneticfield at the position of the electron
This magnetic field produces a per-turbative torque on the electron’smagnetic moment from the Biot-Savart law
L = rmv
=2πmr2
τ
since ~B ‖ ~L
H = −~µ · ~B
B =µ0i
2r=
i
2ε0c2r=
e
2ε0c2τ r
~B =1
4πε0
e
mc2r3~L
C. Segre (IIT) PHYS 406 - Spring 2014 February 03, 2014 3 / 7
![Page 20: Today’s Outline - February 03, 2014csrri.iit.edu/~segre/phys406/14S/lecture_05.pdfToday’s Outline - February 03, 2014 Relativistic correction Spin-orbit coupling Zeeman e ect O](https://reader035.fdocuments.us/reader035/viewer/2022070217/6122876b38aab531eb1918f2/html5/thumbnails/20.jpg)
Magnetic field at the electron
e
p
B L
r
The “normal” view of a hydro-gen atom has the electron rotatingabout the proton (really just havingangular momentum)
In the electron’s frame of referenceit is the opposite
The “rotating” proton has angular momentum
and produces a magneticfield at the position of the electron
This magnetic field produces a per-turbative torque on the electron’smagnetic moment from the Biot-Savart law
L = rmv
=2πmr2
τ
since ~B ‖ ~L
H = −~µ · ~B
B =µ0i
2r=
i
2ε0c2r=
e
2ε0c2τ r
~B =1
4πε0
e
mc2r3~L
C. Segre (IIT) PHYS 406 - Spring 2014 February 03, 2014 3 / 7
![Page 21: Today’s Outline - February 03, 2014csrri.iit.edu/~segre/phys406/14S/lecture_05.pdfToday’s Outline - February 03, 2014 Relativistic correction Spin-orbit coupling Zeeman e ect O](https://reader035.fdocuments.us/reader035/viewer/2022070217/6122876b38aab531eb1918f2/html5/thumbnails/21.jpg)
Magnetic field at the electron
e
p
B L
r
The “normal” view of a hydro-gen atom has the electron rotatingabout the proton (really just havingangular momentum)
In the electron’s frame of referenceit is the opposite
The “rotating” proton has angular momentum and produces a magneticfield at the position of the electron
This magnetic field produces a per-turbative torque on the electron’smagnetic moment from the Biot-Savart law
L = rmv
=2πmr2
τ
since ~B ‖ ~L
H = −~µ · ~B
B =µ0i
2r=
i
2ε0c2r=
e
2ε0c2τ r
~B =1
4πε0
e
mc2r3~L
C. Segre (IIT) PHYS 406 - Spring 2014 February 03, 2014 3 / 7
![Page 22: Today’s Outline - February 03, 2014csrri.iit.edu/~segre/phys406/14S/lecture_05.pdfToday’s Outline - February 03, 2014 Relativistic correction Spin-orbit coupling Zeeman e ect O](https://reader035.fdocuments.us/reader035/viewer/2022070217/6122876b38aab531eb1918f2/html5/thumbnails/22.jpg)
Magnetic field at the electron
e
p
B L
r
The “normal” view of a hydro-gen atom has the electron rotatingabout the proton (really just havingangular momentum)
In the electron’s frame of referenceit is the opposite
The “rotating” proton has angular momentum and produces a magneticfield at the position of the electron
This magnetic field produces a per-turbative torque on the electron’smagnetic moment
from the Biot-Savart law
L = rmv
=2πmr2
τ
since ~B ‖ ~L
H = −~µ · ~B
B =µ0i
2r=
i
2ε0c2r=
e
2ε0c2τ r
~B =1
4πε0
e
mc2r3~L
C. Segre (IIT) PHYS 406 - Spring 2014 February 03, 2014 3 / 7
![Page 23: Today’s Outline - February 03, 2014csrri.iit.edu/~segre/phys406/14S/lecture_05.pdfToday’s Outline - February 03, 2014 Relativistic correction Spin-orbit coupling Zeeman e ect O](https://reader035.fdocuments.us/reader035/viewer/2022070217/6122876b38aab531eb1918f2/html5/thumbnails/23.jpg)
Magnetic field at the electron
e
p
B L
r
The “normal” view of a hydro-gen atom has the electron rotatingabout the proton (really just havingangular momentum)
In the electron’s frame of referenceit is the opposite
The “rotating” proton has angular momentum and produces a magneticfield at the position of the electron
This magnetic field produces a per-turbative torque on the electron’smagnetic moment
from the Biot-Savart law
L = rmv
=2πmr2
τ
since ~B ‖ ~L
H = −~µ · ~B
B =µ0i
2r=
i
2ε0c2r=
e
2ε0c2τ r
~B =1
4πε0
e
mc2r3~L
C. Segre (IIT) PHYS 406 - Spring 2014 February 03, 2014 3 / 7
![Page 24: Today’s Outline - February 03, 2014csrri.iit.edu/~segre/phys406/14S/lecture_05.pdfToday’s Outline - February 03, 2014 Relativistic correction Spin-orbit coupling Zeeman e ect O](https://reader035.fdocuments.us/reader035/viewer/2022070217/6122876b38aab531eb1918f2/html5/thumbnails/24.jpg)
Magnetic field at the electron
e
p
B L
r
The “normal” view of a hydro-gen atom has the electron rotatingabout the proton (really just havingangular momentum)
In the electron’s frame of referenceit is the opposite
The “rotating” proton has angular momentum and produces a magneticfield at the position of the electron
This magnetic field produces a per-turbative torque on the electron’smagnetic moment from the Biot-Savart law
L = rmv
=2πmr2
τ
since ~B ‖ ~L
H = −~µ · ~B
B =µ0i
2r=
i
2ε0c2r=
e
2ε0c2τ r
~B =1
4πε0
e
mc2r3~L
C. Segre (IIT) PHYS 406 - Spring 2014 February 03, 2014 3 / 7
![Page 25: Today’s Outline - February 03, 2014csrri.iit.edu/~segre/phys406/14S/lecture_05.pdfToday’s Outline - February 03, 2014 Relativistic correction Spin-orbit coupling Zeeman e ect O](https://reader035.fdocuments.us/reader035/viewer/2022070217/6122876b38aab531eb1918f2/html5/thumbnails/25.jpg)
Magnetic field at the electron
e
p
B L
r
The “normal” view of a hydro-gen atom has the electron rotatingabout the proton (really just havingangular momentum)
In the electron’s frame of referenceit is the opposite
The “rotating” proton has angular momentum and produces a magneticfield at the position of the electron
This magnetic field produces a per-turbative torque on the electron’smagnetic moment from the Biot-Savart law
L = rmv
=2πmr2
τ
since ~B ‖ ~L
H = −~µ · ~B
B =µ0i
2r
=i
2ε0c2r=
e
2ε0c2τ r
~B =1
4πε0
e
mc2r3~L
C. Segre (IIT) PHYS 406 - Spring 2014 February 03, 2014 3 / 7
![Page 26: Today’s Outline - February 03, 2014csrri.iit.edu/~segre/phys406/14S/lecture_05.pdfToday’s Outline - February 03, 2014 Relativistic correction Spin-orbit coupling Zeeman e ect O](https://reader035.fdocuments.us/reader035/viewer/2022070217/6122876b38aab531eb1918f2/html5/thumbnails/26.jpg)
Magnetic field at the electron
e
p
B L
r
The “normal” view of a hydro-gen atom has the electron rotatingabout the proton (really just havingangular momentum)
In the electron’s frame of referenceit is the opposite
The “rotating” proton has angular momentum and produces a magneticfield at the position of the electron
This magnetic field produces a per-turbative torque on the electron’smagnetic moment from the Biot-Savart law
L = rmv
=2πmr2
τ
since ~B ‖ ~L
H = −~µ · ~B
B =µ0i
2r=
i
2ε0c2r
=e
2ε0c2τ r
~B =1
4πε0
e
mc2r3~L
C. Segre (IIT) PHYS 406 - Spring 2014 February 03, 2014 3 / 7
![Page 27: Today’s Outline - February 03, 2014csrri.iit.edu/~segre/phys406/14S/lecture_05.pdfToday’s Outline - February 03, 2014 Relativistic correction Spin-orbit coupling Zeeman e ect O](https://reader035.fdocuments.us/reader035/viewer/2022070217/6122876b38aab531eb1918f2/html5/thumbnails/27.jpg)
Magnetic field at the electron
e
p
B L
r
The “normal” view of a hydro-gen atom has the electron rotatingabout the proton (really just havingangular momentum)
In the electron’s frame of referenceit is the opposite
The “rotating” proton has angular momentum and produces a magneticfield at the position of the electron
This magnetic field produces a per-turbative torque on the electron’smagnetic moment from the Biot-Savart law
L = rmv
=2πmr2
τ
since ~B ‖ ~L
H = −~µ · ~B
B =µ0i
2r=
i
2ε0c2r=
e
2ε0c2τ r
~B =1
4πε0
e
mc2r3~L
C. Segre (IIT) PHYS 406 - Spring 2014 February 03, 2014 3 / 7
![Page 28: Today’s Outline - February 03, 2014csrri.iit.edu/~segre/phys406/14S/lecture_05.pdfToday’s Outline - February 03, 2014 Relativistic correction Spin-orbit coupling Zeeman e ect O](https://reader035.fdocuments.us/reader035/viewer/2022070217/6122876b38aab531eb1918f2/html5/thumbnails/28.jpg)
Magnetic field at the electron
e
p
B L
r
The “normal” view of a hydro-gen atom has the electron rotatingabout the proton (really just havingangular momentum)
In the electron’s frame of referenceit is the opposite
The “rotating” proton has angular momentum and produces a magneticfield at the position of the electron
This magnetic field produces a per-turbative torque on the electron’smagnetic moment from the Biot-Savart law
L = rmv
=2πmr2
τ
since ~B ‖ ~L
H = −~µ · ~B
B =µ0i
2r=
i
2ε0c2r=
e
2ε0c2τ r
~B =1
4πε0
e
mc2r3~L
C. Segre (IIT) PHYS 406 - Spring 2014 February 03, 2014 3 / 7
![Page 29: Today’s Outline - February 03, 2014csrri.iit.edu/~segre/phys406/14S/lecture_05.pdfToday’s Outline - February 03, 2014 Relativistic correction Spin-orbit coupling Zeeman e ect O](https://reader035.fdocuments.us/reader035/viewer/2022070217/6122876b38aab531eb1918f2/html5/thumbnails/29.jpg)
Magnetic field at the electron
e
p
B L
r
The “normal” view of a hydro-gen atom has the electron rotatingabout the proton (really just havingangular momentum)
In the electron’s frame of referenceit is the opposite
The “rotating” proton has angular momentum and produces a magneticfield at the position of the electron
This magnetic field produces a per-turbative torque on the electron’smagnetic moment from the Biot-Savart law
L = rmv =2πmr2
τ
since ~B ‖ ~L
H = −~µ · ~B
B =µ0i
2r=
i
2ε0c2r=
e
2ε0c2τ r
~B =1
4πε0
e
mc2r3~L
C. Segre (IIT) PHYS 406 - Spring 2014 February 03, 2014 3 / 7
![Page 30: Today’s Outline - February 03, 2014csrri.iit.edu/~segre/phys406/14S/lecture_05.pdfToday’s Outline - February 03, 2014 Relativistic correction Spin-orbit coupling Zeeman e ect O](https://reader035.fdocuments.us/reader035/viewer/2022070217/6122876b38aab531eb1918f2/html5/thumbnails/30.jpg)
Magnetic field at the electron
e
p
B L
r
The “normal” view of a hydro-gen atom has the electron rotatingabout the proton (really just havingangular momentum)
In the electron’s frame of referenceit is the opposite
The “rotating” proton has angular momentum and produces a magneticfield at the position of the electron
This magnetic field produces a per-turbative torque on the electron’smagnetic moment from the Biot-Savart law
L = rmv =2πmr2
τ
since ~B ‖ ~L
H = −~µ · ~B
B =µ0i
2r=
i
2ε0c2r=
e
2ε0c2τ r
~B =1
4πε0
e
mc2r3~L
C. Segre (IIT) PHYS 406 - Spring 2014 February 03, 2014 3 / 7
![Page 31: Today’s Outline - February 03, 2014csrri.iit.edu/~segre/phys406/14S/lecture_05.pdfToday’s Outline - February 03, 2014 Relativistic correction Spin-orbit coupling Zeeman e ect O](https://reader035.fdocuments.us/reader035/viewer/2022070217/6122876b38aab531eb1918f2/html5/thumbnails/31.jpg)
Magnetic field at the electron
e
p
B L
r
The “normal” view of a hydro-gen atom has the electron rotatingabout the proton (really just havingangular momentum)
In the electron’s frame of referenceit is the opposite
The “rotating” proton has angular momentum and produces a magneticfield at the position of the electron
This magnetic field produces a per-turbative torque on the electron’smagnetic moment from the Biot-Savart law
L = rmv =2πmr2
τ
since ~B ‖ ~L
H = −~µ · ~B
B =µ0i
2r=
i
2ε0c2r=
e
2ε0c2τ r
~B =1
4πε0
e
mc2r3~L
C. Segre (IIT) PHYS 406 - Spring 2014 February 03, 2014 3 / 7
![Page 32: Today’s Outline - February 03, 2014csrri.iit.edu/~segre/phys406/14S/lecture_05.pdfToday’s Outline - February 03, 2014 Relativistic correction Spin-orbit coupling Zeeman e ect O](https://reader035.fdocuments.us/reader035/viewer/2022070217/6122876b38aab531eb1918f2/html5/thumbnails/32.jpg)
Electron magnetic dipole
This magnetic field interacts withthe electron dipole ~µ which can becalculated classically
Consider a ring of charge q andmass m rotating about its axis withperiod τ
the magnetic moment is the currenttimes the area of the loop while itsangular momentum, S is the mo-ment of inertia times the angularvelocity
The so-called, gyromagnetic ratio,γcl is the ratio of these two quanti-ties independent of r and τ
q,m
S µ
r
µ = iA =qπr2
τ
S = Iω =2πmr2
τ
γcl =µ
S=
qπr2
τ· τ
2πmr2=
q
2m
C. Segre (IIT) PHYS 406 - Spring 2014 February 03, 2014 4 / 7
![Page 33: Today’s Outline - February 03, 2014csrri.iit.edu/~segre/phys406/14S/lecture_05.pdfToday’s Outline - February 03, 2014 Relativistic correction Spin-orbit coupling Zeeman e ect O](https://reader035.fdocuments.us/reader035/viewer/2022070217/6122876b38aab531eb1918f2/html5/thumbnails/33.jpg)
Electron magnetic dipole
This magnetic field interacts withthe electron dipole ~µ which can becalculated classically
Consider a ring of charge q andmass m rotating about its axis withperiod τ
the magnetic moment is the currenttimes the area of the loop while itsangular momentum, S is the mo-ment of inertia times the angularvelocity
The so-called, gyromagnetic ratio,γcl is the ratio of these two quanti-ties independent of r and τ
q,m
S µ
r
µ = iA =qπr2
τ
S = Iω =2πmr2
τ
γcl =µ
S=
qπr2
τ· τ
2πmr2=
q
2m
C. Segre (IIT) PHYS 406 - Spring 2014 February 03, 2014 4 / 7
![Page 34: Today’s Outline - February 03, 2014csrri.iit.edu/~segre/phys406/14S/lecture_05.pdfToday’s Outline - February 03, 2014 Relativistic correction Spin-orbit coupling Zeeman e ect O](https://reader035.fdocuments.us/reader035/viewer/2022070217/6122876b38aab531eb1918f2/html5/thumbnails/34.jpg)
Electron magnetic dipole
This magnetic field interacts withthe electron dipole ~µ which can becalculated classically
Consider a ring of charge q andmass m rotating about its axis withperiod τ
the magnetic moment is the currenttimes the area of the loop while itsangular momentum, S is the mo-ment of inertia times the angularvelocity
The so-called, gyromagnetic ratio,γcl is the ratio of these two quanti-ties independent of r and τ
q,m
S µ
r
µ = iA =qπr2
τ
S = Iω =2πmr2
τ
γcl =µ
S=
qπr2
τ· τ
2πmr2=
q
2m
C. Segre (IIT) PHYS 406 - Spring 2014 February 03, 2014 4 / 7
![Page 35: Today’s Outline - February 03, 2014csrri.iit.edu/~segre/phys406/14S/lecture_05.pdfToday’s Outline - February 03, 2014 Relativistic correction Spin-orbit coupling Zeeman e ect O](https://reader035.fdocuments.us/reader035/viewer/2022070217/6122876b38aab531eb1918f2/html5/thumbnails/35.jpg)
Electron magnetic dipole
This magnetic field interacts withthe electron dipole ~µ which can becalculated classically
Consider a ring of charge q andmass m rotating about its axis withperiod τ
the magnetic moment is the currenttimes the area of the loop
while itsangular momentum, S is the mo-ment of inertia times the angularvelocity
The so-called, gyromagnetic ratio,γcl is the ratio of these two quanti-ties independent of r and τ
q,m
S µ
r
µ = iA =qπr2
τ
S = Iω =2πmr2
τ
γcl =µ
S=
qπr2
τ· τ
2πmr2=
q
2m
C. Segre (IIT) PHYS 406 - Spring 2014 February 03, 2014 4 / 7
![Page 36: Today’s Outline - February 03, 2014csrri.iit.edu/~segre/phys406/14S/lecture_05.pdfToday’s Outline - February 03, 2014 Relativistic correction Spin-orbit coupling Zeeman e ect O](https://reader035.fdocuments.us/reader035/viewer/2022070217/6122876b38aab531eb1918f2/html5/thumbnails/36.jpg)
Electron magnetic dipole
This magnetic field interacts withthe electron dipole ~µ which can becalculated classically
Consider a ring of charge q andmass m rotating about its axis withperiod τ
the magnetic moment is the currenttimes the area of the loop
while itsangular momentum, S is the mo-ment of inertia times the angularvelocity
The so-called, gyromagnetic ratio,γcl is the ratio of these two quanti-ties independent of r and τ
q,m
S µ
r
µ = iA
=qπr2
τ
S = Iω =2πmr2
τ
γcl =µ
S=
qπr2
τ· τ
2πmr2=
q
2m
C. Segre (IIT) PHYS 406 - Spring 2014 February 03, 2014 4 / 7
![Page 37: Today’s Outline - February 03, 2014csrri.iit.edu/~segre/phys406/14S/lecture_05.pdfToday’s Outline - February 03, 2014 Relativistic correction Spin-orbit coupling Zeeman e ect O](https://reader035.fdocuments.us/reader035/viewer/2022070217/6122876b38aab531eb1918f2/html5/thumbnails/37.jpg)
Electron magnetic dipole
This magnetic field interacts withthe electron dipole ~µ which can becalculated classically
Consider a ring of charge q andmass m rotating about its axis withperiod τ
the magnetic moment is the currenttimes the area of the loop
while itsangular momentum, S is the mo-ment of inertia times the angularvelocity
The so-called, gyromagnetic ratio,γcl is the ratio of these two quanti-ties independent of r and τ
q,m
S µ
r
µ = iA =qπr2
τ
S = Iω =2πmr2
τ
γcl =µ
S=
qπr2
τ· τ
2πmr2=
q
2m
C. Segre (IIT) PHYS 406 - Spring 2014 February 03, 2014 4 / 7
![Page 38: Today’s Outline - February 03, 2014csrri.iit.edu/~segre/phys406/14S/lecture_05.pdfToday’s Outline - February 03, 2014 Relativistic correction Spin-orbit coupling Zeeman e ect O](https://reader035.fdocuments.us/reader035/viewer/2022070217/6122876b38aab531eb1918f2/html5/thumbnails/38.jpg)
Electron magnetic dipole
This magnetic field interacts withthe electron dipole ~µ which can becalculated classically
Consider a ring of charge q andmass m rotating about its axis withperiod τ
the magnetic moment is the currenttimes the area of the loop while itsangular momentum, S is the mo-ment of inertia times the angularvelocity
The so-called, gyromagnetic ratio,γcl is the ratio of these two quanti-ties independent of r and τ
q,m
S µ
r
µ = iA =qπr2
τ
S = Iω =2πmr2
τ
γcl =µ
S=
qπr2
τ· τ
2πmr2=
q
2m
C. Segre (IIT) PHYS 406 - Spring 2014 February 03, 2014 4 / 7
![Page 39: Today’s Outline - February 03, 2014csrri.iit.edu/~segre/phys406/14S/lecture_05.pdfToday’s Outline - February 03, 2014 Relativistic correction Spin-orbit coupling Zeeman e ect O](https://reader035.fdocuments.us/reader035/viewer/2022070217/6122876b38aab531eb1918f2/html5/thumbnails/39.jpg)
Electron magnetic dipole
This magnetic field interacts withthe electron dipole ~µ which can becalculated classically
Consider a ring of charge q andmass m rotating about its axis withperiod τ
the magnetic moment is the currenttimes the area of the loop while itsangular momentum, S is the mo-ment of inertia times the angularvelocity
The so-called, gyromagnetic ratio,γcl is the ratio of these two quanti-ties independent of r and τ
q,m
S µ
r
µ = iA =qπr2
τ
S = Iω
=2πmr2
τ
γcl =µ
S=
qπr2
τ· τ
2πmr2=
q
2m
C. Segre (IIT) PHYS 406 - Spring 2014 February 03, 2014 4 / 7
![Page 40: Today’s Outline - February 03, 2014csrri.iit.edu/~segre/phys406/14S/lecture_05.pdfToday’s Outline - February 03, 2014 Relativistic correction Spin-orbit coupling Zeeman e ect O](https://reader035.fdocuments.us/reader035/viewer/2022070217/6122876b38aab531eb1918f2/html5/thumbnails/40.jpg)
Electron magnetic dipole
This magnetic field interacts withthe electron dipole ~µ which can becalculated classically
Consider a ring of charge q andmass m rotating about its axis withperiod τ
the magnetic moment is the currenttimes the area of the loop while itsangular momentum, S is the mo-ment of inertia times the angularvelocity
The so-called, gyromagnetic ratio,γcl is the ratio of these two quanti-ties independent of r and τ
q,m
S µ
r
µ = iA =qπr2
τ
S = Iω =2πmr2
τ
γcl =µ
S=
qπr2
τ· τ
2πmr2=
q
2m
C. Segre (IIT) PHYS 406 - Spring 2014 February 03, 2014 4 / 7
![Page 41: Today’s Outline - February 03, 2014csrri.iit.edu/~segre/phys406/14S/lecture_05.pdfToday’s Outline - February 03, 2014 Relativistic correction Spin-orbit coupling Zeeman e ect O](https://reader035.fdocuments.us/reader035/viewer/2022070217/6122876b38aab531eb1918f2/html5/thumbnails/41.jpg)
Electron magnetic dipole
This magnetic field interacts withthe electron dipole ~µ which can becalculated classically
Consider a ring of charge q andmass m rotating about its axis withperiod τ
the magnetic moment is the currenttimes the area of the loop while itsangular momentum, S is the mo-ment of inertia times the angularvelocity
The so-called, gyromagnetic ratio,γcl is the ratio of these two quanti-ties
independent of r and τ
q,m
S µ
r
µ = iA =qπr2
τ
S = Iω =2πmr2
τ
γcl =µ
S=
qπr2
τ· τ
2πmr2=
q
2m
C. Segre (IIT) PHYS 406 - Spring 2014 February 03, 2014 4 / 7
![Page 42: Today’s Outline - February 03, 2014csrri.iit.edu/~segre/phys406/14S/lecture_05.pdfToday’s Outline - February 03, 2014 Relativistic correction Spin-orbit coupling Zeeman e ect O](https://reader035.fdocuments.us/reader035/viewer/2022070217/6122876b38aab531eb1918f2/html5/thumbnails/42.jpg)
Electron magnetic dipole
This magnetic field interacts withthe electron dipole ~µ which can becalculated classically
Consider a ring of charge q andmass m rotating about its axis withperiod τ
the magnetic moment is the currenttimes the area of the loop while itsangular momentum, S is the mo-ment of inertia times the angularvelocity
The so-called, gyromagnetic ratio,γcl is the ratio of these two quanti-ties
independent of r and τ
q,m
S µ
r
µ = iA =qπr2
τ
S = Iω =2πmr2
τ
γcl =µ
S
=qπr2
τ· τ
2πmr2=
q
2m
C. Segre (IIT) PHYS 406 - Spring 2014 February 03, 2014 4 / 7
![Page 43: Today’s Outline - February 03, 2014csrri.iit.edu/~segre/phys406/14S/lecture_05.pdfToday’s Outline - February 03, 2014 Relativistic correction Spin-orbit coupling Zeeman e ect O](https://reader035.fdocuments.us/reader035/viewer/2022070217/6122876b38aab531eb1918f2/html5/thumbnails/43.jpg)
Electron magnetic dipole
This magnetic field interacts withthe electron dipole ~µ which can becalculated classically
Consider a ring of charge q andmass m rotating about its axis withperiod τ
the magnetic moment is the currenttimes the area of the loop while itsangular momentum, S is the mo-ment of inertia times the angularvelocity
The so-called, gyromagnetic ratio,γcl is the ratio of these two quanti-ties
independent of r and τ
q,m
S µ
r
µ = iA =qπr2
τ
S = Iω =2πmr2
τ
γcl =µ
S=
qπr2
τ· τ
2πmr2
=q
2m
C. Segre (IIT) PHYS 406 - Spring 2014 February 03, 2014 4 / 7
![Page 44: Today’s Outline - February 03, 2014csrri.iit.edu/~segre/phys406/14S/lecture_05.pdfToday’s Outline - February 03, 2014 Relativistic correction Spin-orbit coupling Zeeman e ect O](https://reader035.fdocuments.us/reader035/viewer/2022070217/6122876b38aab531eb1918f2/html5/thumbnails/44.jpg)
Electron magnetic dipole
This magnetic field interacts withthe electron dipole ~µ which can becalculated classically
Consider a ring of charge q andmass m rotating about its axis withperiod τ
the magnetic moment is the currenttimes the area of the loop while itsangular momentum, S is the mo-ment of inertia times the angularvelocity
The so-called, gyromagnetic ratio,γcl is the ratio of these two quanti-ties
independent of r and τ
q,m
S µ
r
µ = iA =qπr2
τ
S = Iω =2πmr2
τ
γcl =µ
S=
qπr2
τ· τ
2πmr2=
q
2m
C. Segre (IIT) PHYS 406 - Spring 2014 February 03, 2014 4 / 7
![Page 45: Today’s Outline - February 03, 2014csrri.iit.edu/~segre/phys406/14S/lecture_05.pdfToday’s Outline - February 03, 2014 Relativistic correction Spin-orbit coupling Zeeman e ect O](https://reader035.fdocuments.us/reader035/viewer/2022070217/6122876b38aab531eb1918f2/html5/thumbnails/45.jpg)
Electron magnetic dipole
This magnetic field interacts withthe electron dipole ~µ which can becalculated classically
Consider a ring of charge q andmass m rotating about its axis withperiod τ
the magnetic moment is the currenttimes the area of the loop while itsangular momentum, S is the mo-ment of inertia times the angularvelocity
The so-called, gyromagnetic ratio,γcl is the ratio of these two quanti-ties independent of r and τ
q,m
S µ
r
µ = iA =qπr2
τ
S = Iω =2πmr2
τ
γcl =µ
S=
qπr2
τ· τ
2πmr2=
q
2m
C. Segre (IIT) PHYS 406 - Spring 2014 February 03, 2014 4 / 7
![Page 46: Today’s Outline - February 03, 2014csrri.iit.edu/~segre/phys406/14S/lecture_05.pdfToday’s Outline - February 03, 2014 Relativistic correction Spin-orbit coupling Zeeman e ect O](https://reader035.fdocuments.us/reader035/viewer/2022070217/6122876b38aab531eb1918f2/html5/thumbnails/46.jpg)
Quantum gyromagnetic ratio
For an electron, the magnetic moment is a result of the intrinsic angularmomentum, or “spin”
This is not the classical value butclose to two times bigger, due torelativistic theory
where ge ≈ 2 + α/π = 2.002
The perturbing Hamiltonian is thus
but since the electron is in an ac-celerating frame of reference, theThomas precession correction mustbe applied which leads to replacingge → (ge − 1) and results in thefinal spin-orbit correction Hamilto-nian
~µ = γe~S = −gee
2m~S
H ′ = −~µ · ~B =gee
2m
1
4πε0
e
mc2r3~S · ~L
= ge
(e2
8πε0
)1
m2c2r3~S · ~L
H ′so ≈
(e2
8πε0
)1
m2c2r3~S · ~L
C. Segre (IIT) PHYS 406 - Spring 2014 February 03, 2014 5 / 7
![Page 47: Today’s Outline - February 03, 2014csrri.iit.edu/~segre/phys406/14S/lecture_05.pdfToday’s Outline - February 03, 2014 Relativistic correction Spin-orbit coupling Zeeman e ect O](https://reader035.fdocuments.us/reader035/viewer/2022070217/6122876b38aab531eb1918f2/html5/thumbnails/47.jpg)
Quantum gyromagnetic ratio
For an electron, the magnetic moment is a result of the intrinsic angularmomentum, or “spin”
This is not the classical value butclose to two times bigger, due torelativistic theory
where ge ≈ 2 + α/π = 2.002
The perturbing Hamiltonian is thus
but since the electron is in an ac-celerating frame of reference, theThomas precession correction mustbe applied which leads to replacingge → (ge − 1) and results in thefinal spin-orbit correction Hamilto-nian
~µ = γe~S
= −gee
2m~S
H ′ = −~µ · ~B =gee
2m
1
4πε0
e
mc2r3~S · ~L
= ge
(e2
8πε0
)1
m2c2r3~S · ~L
H ′so ≈
(e2
8πε0
)1
m2c2r3~S · ~L
C. Segre (IIT) PHYS 406 - Spring 2014 February 03, 2014 5 / 7
![Page 48: Today’s Outline - February 03, 2014csrri.iit.edu/~segre/phys406/14S/lecture_05.pdfToday’s Outline - February 03, 2014 Relativistic correction Spin-orbit coupling Zeeman e ect O](https://reader035.fdocuments.us/reader035/viewer/2022070217/6122876b38aab531eb1918f2/html5/thumbnails/48.jpg)
Quantum gyromagnetic ratio
For an electron, the magnetic moment is a result of the intrinsic angularmomentum, or “spin”
This is not the classical value butclose to two times bigger, due torelativistic theory
where ge ≈ 2 + α/π = 2.002
The perturbing Hamiltonian is thus
but since the electron is in an ac-celerating frame of reference, theThomas precession correction mustbe applied which leads to replacingge → (ge − 1) and results in thefinal spin-orbit correction Hamilto-nian
~µ = γe~S
= −gee
2m~S
H ′ = −~µ · ~B =gee
2m
1
4πε0
e
mc2r3~S · ~L
= ge
(e2
8πε0
)1
m2c2r3~S · ~L
H ′so ≈
(e2
8πε0
)1
m2c2r3~S · ~L
C. Segre (IIT) PHYS 406 - Spring 2014 February 03, 2014 5 / 7
![Page 49: Today’s Outline - February 03, 2014csrri.iit.edu/~segre/phys406/14S/lecture_05.pdfToday’s Outline - February 03, 2014 Relativistic correction Spin-orbit coupling Zeeman e ect O](https://reader035.fdocuments.us/reader035/viewer/2022070217/6122876b38aab531eb1918f2/html5/thumbnails/49.jpg)
Quantum gyromagnetic ratio
For an electron, the magnetic moment is a result of the intrinsic angularmomentum, or “spin”
This is not the classical value butclose to two times bigger, due torelativistic theory
where ge ≈ 2 + α/π = 2.002
The perturbing Hamiltonian is thus
but since the electron is in an ac-celerating frame of reference, theThomas precession correction mustbe applied which leads to replacingge → (ge − 1) and results in thefinal spin-orbit correction Hamilto-nian
~µ = γe~S = −gee
2m~S
H ′ = −~µ · ~B =gee
2m
1
4πε0
e
mc2r3~S · ~L
= ge
(e2
8πε0
)1
m2c2r3~S · ~L
H ′so ≈
(e2
8πε0
)1
m2c2r3~S · ~L
C. Segre (IIT) PHYS 406 - Spring 2014 February 03, 2014 5 / 7
![Page 50: Today’s Outline - February 03, 2014csrri.iit.edu/~segre/phys406/14S/lecture_05.pdfToday’s Outline - February 03, 2014 Relativistic correction Spin-orbit coupling Zeeman e ect O](https://reader035.fdocuments.us/reader035/viewer/2022070217/6122876b38aab531eb1918f2/html5/thumbnails/50.jpg)
Quantum gyromagnetic ratio
For an electron, the magnetic moment is a result of the intrinsic angularmomentum, or “spin”
This is not the classical value butclose to two times bigger, due torelativistic theory
where ge ≈ 2 + α/π = 2.002
The perturbing Hamiltonian is thus
but since the electron is in an ac-celerating frame of reference, theThomas precession correction mustbe applied which leads to replacingge → (ge − 1) and results in thefinal spin-orbit correction Hamilto-nian
~µ = γe~S = −gee
2m~S
H ′ = −~µ · ~B =gee
2m
1
4πε0
e
mc2r3~S · ~L
= ge
(e2
8πε0
)1
m2c2r3~S · ~L
H ′so ≈
(e2
8πε0
)1
m2c2r3~S · ~L
C. Segre (IIT) PHYS 406 - Spring 2014 February 03, 2014 5 / 7
![Page 51: Today’s Outline - February 03, 2014csrri.iit.edu/~segre/phys406/14S/lecture_05.pdfToday’s Outline - February 03, 2014 Relativistic correction Spin-orbit coupling Zeeman e ect O](https://reader035.fdocuments.us/reader035/viewer/2022070217/6122876b38aab531eb1918f2/html5/thumbnails/51.jpg)
Quantum gyromagnetic ratio
For an electron, the magnetic moment is a result of the intrinsic angularmomentum, or “spin”
This is not the classical value butclose to two times bigger, due torelativistic theory
where ge ≈ 2 + α/π = 2.002
The perturbing Hamiltonian is thus
but since the electron is in an ac-celerating frame of reference, theThomas precession correction mustbe applied which leads to replacingge → (ge − 1) and results in thefinal spin-orbit correction Hamilto-nian
~µ = γe~S = −gee
2m~S
H ′ = −~µ · ~B =gee
2m
1
4πε0
e
mc2r3~S · ~L
= ge
(e2
8πε0
)1
m2c2r3~S · ~L
H ′so ≈
(e2
8πε0
)1
m2c2r3~S · ~L
C. Segre (IIT) PHYS 406 - Spring 2014 February 03, 2014 5 / 7
![Page 52: Today’s Outline - February 03, 2014csrri.iit.edu/~segre/phys406/14S/lecture_05.pdfToday’s Outline - February 03, 2014 Relativistic correction Spin-orbit coupling Zeeman e ect O](https://reader035.fdocuments.us/reader035/viewer/2022070217/6122876b38aab531eb1918f2/html5/thumbnails/52.jpg)
Quantum gyromagnetic ratio
For an electron, the magnetic moment is a result of the intrinsic angularmomentum, or “spin”
This is not the classical value butclose to two times bigger, due torelativistic theory
where ge ≈ 2 + α/π = 2.002
The perturbing Hamiltonian is thus
but since the electron is in an ac-celerating frame of reference, theThomas precession correction mustbe applied which leads to replacingge → (ge − 1) and results in thefinal spin-orbit correction Hamilto-nian
~µ = γe~S = −gee
2m~S
H ′ = −~µ · ~B
=gee
2m
1
4πε0
e
mc2r3~S · ~L
= ge
(e2
8πε0
)1
m2c2r3~S · ~L
H ′so ≈
(e2
8πε0
)1
m2c2r3~S · ~L
C. Segre (IIT) PHYS 406 - Spring 2014 February 03, 2014 5 / 7
![Page 53: Today’s Outline - February 03, 2014csrri.iit.edu/~segre/phys406/14S/lecture_05.pdfToday’s Outline - February 03, 2014 Relativistic correction Spin-orbit coupling Zeeman e ect O](https://reader035.fdocuments.us/reader035/viewer/2022070217/6122876b38aab531eb1918f2/html5/thumbnails/53.jpg)
Quantum gyromagnetic ratio
For an electron, the magnetic moment is a result of the intrinsic angularmomentum, or “spin”
This is not the classical value butclose to two times bigger, due torelativistic theory
where ge ≈ 2 + α/π = 2.002
The perturbing Hamiltonian is thus
but since the electron is in an ac-celerating frame of reference, theThomas precession correction mustbe applied which leads to replacingge → (ge − 1) and results in thefinal spin-orbit correction Hamilto-nian
~µ = γe~S = −gee
2m~S
H ′ = −~µ · ~B =gee
2m
1
4πε0
e
mc2r3~S · ~L
= ge
(e2
8πε0
)1
m2c2r3~S · ~L
H ′so ≈
(e2
8πε0
)1
m2c2r3~S · ~L
C. Segre (IIT) PHYS 406 - Spring 2014 February 03, 2014 5 / 7
![Page 54: Today’s Outline - February 03, 2014csrri.iit.edu/~segre/phys406/14S/lecture_05.pdfToday’s Outline - February 03, 2014 Relativistic correction Spin-orbit coupling Zeeman e ect O](https://reader035.fdocuments.us/reader035/viewer/2022070217/6122876b38aab531eb1918f2/html5/thumbnails/54.jpg)
Quantum gyromagnetic ratio
For an electron, the magnetic moment is a result of the intrinsic angularmomentum, or “spin”
This is not the classical value butclose to two times bigger, due torelativistic theory
where ge ≈ 2 + α/π = 2.002
The perturbing Hamiltonian is thus
but since the electron is in an ac-celerating frame of reference, theThomas precession correction mustbe applied which leads to replacingge → (ge − 1) and results in thefinal spin-orbit correction Hamilto-nian
~µ = γe~S = −gee
2m~S
H ′ = −~µ · ~B =gee
2m
1
4πε0
e
mc2r3~S · ~L
= ge
(e2
8πε0
)1
m2c2r3~S · ~L
H ′so ≈
(e2
8πε0
)1
m2c2r3~S · ~L
C. Segre (IIT) PHYS 406 - Spring 2014 February 03, 2014 5 / 7
![Page 55: Today’s Outline - February 03, 2014csrri.iit.edu/~segre/phys406/14S/lecture_05.pdfToday’s Outline - February 03, 2014 Relativistic correction Spin-orbit coupling Zeeman e ect O](https://reader035.fdocuments.us/reader035/viewer/2022070217/6122876b38aab531eb1918f2/html5/thumbnails/55.jpg)
Quantum gyromagnetic ratio
For an electron, the magnetic moment is a result of the intrinsic angularmomentum, or “spin”
This is not the classical value butclose to two times bigger, due torelativistic theory
where ge ≈ 2 + α/π = 2.002
The perturbing Hamiltonian is thus
but since the electron is in an ac-celerating frame of reference, theThomas precession correction mustbe applied which leads to replacingge → (ge − 1) and results in thefinal spin-orbit correction Hamilto-nian
~µ = γe~S = −gee
2m~S
H ′ = −~µ · ~B =gee
2m
1
4πε0
e
mc2r3~S · ~L
= ge
(e2
8πε0
)1
m2c2r3~S · ~L
H ′so ≈
(e2
8πε0
)1
m2c2r3~S · ~L
C. Segre (IIT) PHYS 406 - Spring 2014 February 03, 2014 5 / 7
![Page 56: Today’s Outline - February 03, 2014csrri.iit.edu/~segre/phys406/14S/lecture_05.pdfToday’s Outline - February 03, 2014 Relativistic correction Spin-orbit coupling Zeeman e ect O](https://reader035.fdocuments.us/reader035/viewer/2022070217/6122876b38aab531eb1918f2/html5/thumbnails/56.jpg)
Quantum gyromagnetic ratio
For an electron, the magnetic moment is a result of the intrinsic angularmomentum, or “spin”
This is not the classical value butclose to two times bigger, due torelativistic theory
where ge ≈ 2 + α/π = 2.002
The perturbing Hamiltonian is thus
but since the electron is in an ac-celerating frame of reference, theThomas precession correction mustbe applied which leads to replacingge → (ge − 1) and results in thefinal spin-orbit correction Hamilto-nian
~µ = γe~S = −gee
2m~S
H ′ = −~µ · ~B =gee
2m
1
4πε0
e
mc2r3~S · ~L
= ge
(e2
8πε0
)1
m2c2r3~S · ~L
H ′so ≈
(e2
8πε0
)1
m2c2r3~S · ~L
C. Segre (IIT) PHYS 406 - Spring 2014 February 03, 2014 5 / 7
![Page 57: Today’s Outline - February 03, 2014csrri.iit.edu/~segre/phys406/14S/lecture_05.pdfToday’s Outline - February 03, 2014 Relativistic correction Spin-orbit coupling Zeeman e ect O](https://reader035.fdocuments.us/reader035/viewer/2022070217/6122876b38aab531eb1918f2/html5/thumbnails/57.jpg)
Spin-orbit correction
The spin-orbit interaction does not commute with ~L or ~S and so the spinand orbital angular momentum are no longer separately conserved (ml andms are not “good” quantum numbers).
But H ′so still commutes with L2 and S2 as well as the total angular
momentum ~J = ~L + ~S so these quantities are conserved (and l , s, j , mj
are all “good” quantum numbers!
This can be used to recast the spin-orbit Hamiltonian
J2 = (~L + ~S) · (~L + ~S) = L2 + S2 + 2~L · ~S
~L · ~S =1
2(J2 − L2 − S2)
C. Segre (IIT) PHYS 406 - Spring 2014 February 03, 2014 6 / 7
![Page 58: Today’s Outline - February 03, 2014csrri.iit.edu/~segre/phys406/14S/lecture_05.pdfToday’s Outline - February 03, 2014 Relativistic correction Spin-orbit coupling Zeeman e ect O](https://reader035.fdocuments.us/reader035/viewer/2022070217/6122876b38aab531eb1918f2/html5/thumbnails/58.jpg)
Spin-orbit correction
The spin-orbit interaction does not commute with ~L or ~S and so the spinand orbital angular momentum are no longer separately conserved (ml andms are not “good” quantum numbers).
But H ′so still commutes with L2 and S2 as well as the total angular
momentum ~J = ~L + ~S so these quantities are conserved (and l , s, j , mj
are all “good” quantum numbers!
This can be used to recast the spin-orbit Hamiltonian
J2 = (~L + ~S) · (~L + ~S) = L2 + S2 + 2~L · ~S
~L · ~S =1
2(J2 − L2 − S2)
C. Segre (IIT) PHYS 406 - Spring 2014 February 03, 2014 6 / 7
![Page 59: Today’s Outline - February 03, 2014csrri.iit.edu/~segre/phys406/14S/lecture_05.pdfToday’s Outline - February 03, 2014 Relativistic correction Spin-orbit coupling Zeeman e ect O](https://reader035.fdocuments.us/reader035/viewer/2022070217/6122876b38aab531eb1918f2/html5/thumbnails/59.jpg)
Spin-orbit correction
The spin-orbit interaction does not commute with ~L or ~S and so the spinand orbital angular momentum are no longer separately conserved (ml andms are not “good” quantum numbers).
But H ′so still commutes with L2 and S2 as well as the total angular
momentum ~J = ~L + ~S so these quantities are conserved (and l , s, j , mj
are all “good” quantum numbers!
This can be used to recast the spin-orbit Hamiltonian
J2 = (~L + ~S) · (~L + ~S) = L2 + S2 + 2~L · ~S
~L · ~S =1
2(J2 − L2 − S2)
C. Segre (IIT) PHYS 406 - Spring 2014 February 03, 2014 6 / 7
![Page 60: Today’s Outline - February 03, 2014csrri.iit.edu/~segre/phys406/14S/lecture_05.pdfToday’s Outline - February 03, 2014 Relativistic correction Spin-orbit coupling Zeeman e ect O](https://reader035.fdocuments.us/reader035/viewer/2022070217/6122876b38aab531eb1918f2/html5/thumbnails/60.jpg)
Spin-orbit correction
The spin-orbit interaction does not commute with ~L or ~S and so the spinand orbital angular momentum are no longer separately conserved (ml andms are not “good” quantum numbers).
But H ′so still commutes with L2 and S2 as well as the total angular
momentum ~J = ~L + ~S so these quantities are conserved (and l , s, j , mj
are all “good” quantum numbers!
This can be used to recast the spin-orbit Hamiltonian
J2 = (~L + ~S) · (~L + ~S)
= L2 + S2 + 2~L · ~S
~L · ~S =1
2(J2 − L2 − S2)
C. Segre (IIT) PHYS 406 - Spring 2014 February 03, 2014 6 / 7
![Page 61: Today’s Outline - February 03, 2014csrri.iit.edu/~segre/phys406/14S/lecture_05.pdfToday’s Outline - February 03, 2014 Relativistic correction Spin-orbit coupling Zeeman e ect O](https://reader035.fdocuments.us/reader035/viewer/2022070217/6122876b38aab531eb1918f2/html5/thumbnails/61.jpg)
Spin-orbit correction
The spin-orbit interaction does not commute with ~L or ~S and so the spinand orbital angular momentum are no longer separately conserved (ml andms are not “good” quantum numbers).
But H ′so still commutes with L2 and S2 as well as the total angular
momentum ~J = ~L + ~S so these quantities are conserved (and l , s, j , mj
are all “good” quantum numbers!
This can be used to recast the spin-orbit Hamiltonian
J2 = (~L + ~S) · (~L + ~S) = L2 + S2 + 2~L · ~S
~L · ~S =1
2(J2 − L2 − S2)
C. Segre (IIT) PHYS 406 - Spring 2014 February 03, 2014 6 / 7
![Page 62: Today’s Outline - February 03, 2014csrri.iit.edu/~segre/phys406/14S/lecture_05.pdfToday’s Outline - February 03, 2014 Relativistic correction Spin-orbit coupling Zeeman e ect O](https://reader035.fdocuments.us/reader035/viewer/2022070217/6122876b38aab531eb1918f2/html5/thumbnails/62.jpg)
Spin-orbit correction
The spin-orbit interaction does not commute with ~L or ~S and so the spinand orbital angular momentum are no longer separately conserved (ml andms are not “good” quantum numbers).
But H ′so still commutes with L2 and S2 as well as the total angular
momentum ~J = ~L + ~S so these quantities are conserved (and l , s, j , mj
are all “good” quantum numbers!
This can be used to recast the spin-orbit Hamiltonian
J2 = (~L + ~S) · (~L + ~S) = L2 + S2 + 2~L · ~S
~L · ~S =1
2(J2 − L2 − S2)
C. Segre (IIT) PHYS 406 - Spring 2014 February 03, 2014 6 / 7
![Page 63: Today’s Outline - February 03, 2014csrri.iit.edu/~segre/phys406/14S/lecture_05.pdfToday’s Outline - February 03, 2014 Relativistic correction Spin-orbit coupling Zeeman e ect O](https://reader035.fdocuments.us/reader035/viewer/2022070217/6122876b38aab531eb1918f2/html5/thumbnails/63.jpg)
Spin-orbit eigenvalues
Looking at the spin-orbit Hamiltonian again
H ′so ≈
(e2
8πε0
)1
m2c2r3~S · ~L
The eigenvalues of ~L · ~S are⟨~L · ~S
⟩=
~2
2[j(j + 1)− l(l + 1)− s(s + 1)]
and the expectation value of 1/r3 (the other term in the spin-orbitHamiltonian) is ⟨
1
r3
⟩=
1
l(l + 1/2)(l + 1)n3a3
C. Segre (IIT) PHYS 406 - Spring 2014 February 03, 2014 7 / 7
![Page 64: Today’s Outline - February 03, 2014csrri.iit.edu/~segre/phys406/14S/lecture_05.pdfToday’s Outline - February 03, 2014 Relativistic correction Spin-orbit coupling Zeeman e ect O](https://reader035.fdocuments.us/reader035/viewer/2022070217/6122876b38aab531eb1918f2/html5/thumbnails/64.jpg)
Spin-orbit eigenvalues
Looking at the spin-orbit Hamiltonian again
H ′so ≈
(e2
8πε0
)1
m2c2r3~S · ~L
The eigenvalues of ~L · ~S are⟨~L · ~S
⟩=
~2
2[j(j + 1)− l(l + 1)− s(s + 1)]
and the expectation value of 1/r3 (the other term in the spin-orbitHamiltonian) is ⟨
1
r3
⟩=
1
l(l + 1/2)(l + 1)n3a3
C. Segre (IIT) PHYS 406 - Spring 2014 February 03, 2014 7 / 7
![Page 65: Today’s Outline - February 03, 2014csrri.iit.edu/~segre/phys406/14S/lecture_05.pdfToday’s Outline - February 03, 2014 Relativistic correction Spin-orbit coupling Zeeman e ect O](https://reader035.fdocuments.us/reader035/viewer/2022070217/6122876b38aab531eb1918f2/html5/thumbnails/65.jpg)
Spin-orbit eigenvalues
Looking at the spin-orbit Hamiltonian again
H ′so ≈
(e2
8πε0
)1
m2c2r3~S · ~L
The eigenvalues of ~L · ~S are⟨~L · ~S
⟩=
~2
2[j(j + 1)− l(l + 1)− s(s + 1)]
and the expectation value of 1/r3 (the other term in the spin-orbitHamiltonian) is ⟨
1
r3
⟩=
1
l(l + 1/2)(l + 1)n3a3
C. Segre (IIT) PHYS 406 - Spring 2014 February 03, 2014 7 / 7
![Page 66: Today’s Outline - February 03, 2014csrri.iit.edu/~segre/phys406/14S/lecture_05.pdfToday’s Outline - February 03, 2014 Relativistic correction Spin-orbit coupling Zeeman e ect O](https://reader035.fdocuments.us/reader035/viewer/2022070217/6122876b38aab531eb1918f2/html5/thumbnails/66.jpg)
Spin-orbit eigenvalues
Looking at the spin-orbit Hamiltonian again
H ′so ≈
(e2
8πε0
)1
m2c2r3~S · ~L
The eigenvalues of ~L · ~S are⟨~L · ~S
⟩=
~2
2[j(j + 1)− l(l + 1)− s(s + 1)]
and the expectation value of 1/r3 (the other term in the spin-orbitHamiltonian) is
⟨1
r3
⟩=
1
l(l + 1/2)(l + 1)n3a3
C. Segre (IIT) PHYS 406 - Spring 2014 February 03, 2014 7 / 7
![Page 67: Today’s Outline - February 03, 2014csrri.iit.edu/~segre/phys406/14S/lecture_05.pdfToday’s Outline - February 03, 2014 Relativistic correction Spin-orbit coupling Zeeman e ect O](https://reader035.fdocuments.us/reader035/viewer/2022070217/6122876b38aab531eb1918f2/html5/thumbnails/67.jpg)
Spin-orbit eigenvalues
Looking at the spin-orbit Hamiltonian again
H ′so ≈
(e2
8πε0
)1
m2c2r3~S · ~L
The eigenvalues of ~L · ~S are⟨~L · ~S
⟩=
~2
2[j(j + 1)− l(l + 1)− s(s + 1)]
and the expectation value of 1/r3 (the other term in the spin-orbitHamiltonian) is ⟨
1
r3
⟩=
1
l(l + 1/2)(l + 1)n3a3
C. Segre (IIT) PHYS 406 - Spring 2014 February 03, 2014 7 / 7