MOLTEN CARBONATE FUEL CELLS ANSALDO FUEL CELLS: Experience & Experimental results
Title Building Momentum 1. Title 2 We will cover... Fuel Cells Why Alkaline Fuel Cells? Markets and...
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Transcript of Title Building Momentum 1. Title 2 We will cover... Fuel Cells Why Alkaline Fuel Cells? Markets and...
Title
Building Momentum
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TitleTitle
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We will cover...
• Fuel Cells• Why Alkaline Fuel Cells?• Markets and Applications• Manufacturing• Independent Review• Intellectual Property • Road to Commercialisation
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TitleTitle
… it’s a bit like a battery that works continuously generating electricity without combustion…
HYDROGENHYDROGEN
AIRAIR
HEATHEAT
WATERWATER
ELECTRICITYELECTRICITY
What is a Fuel Cell?
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Schematic of the original fuel cell
TitleTitle
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Fuel Cell TechnologiesFuel Cell type
Alkaline
Molten Carbonate
Solid Oxide
PEM(Proton Exchange
Membrane)
Direct Methanol
Phosphoric Acid
There are many chemistries that can
generate electricity...
...all involve reacting hydrogen with oxygen to form water, electricity
and heat in the presence of a catalyst
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Fuel Cell TechnologiesType Operating
Temp
Alkaline 70oC
Molten Carbonate
600 - 700oC
Solid Oxide600 - 1000oC
PEM50-100oC
Direct Methanol 60 - 90oC
Phosphoric Acid 150 - 200oC
Industrially pure water is a product of the
reaction, so an operating temperature above 100oC generates
steam...
...which requires additional product
safety engineering and increases
manufacturing costs
TitleTitle
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Fuel Cell TechnologiesType Operating
TempElectrical Efficiency
Alkaline 70oC 55 – 60%
Molten Carbonate
600 - 700oC 45 - 47%
Solid Oxide 600 - 1000oC 35 – 43%
PEM 50-100oC 25 - 35%
53 – 58%
Direct Methanol 60 - 90oC 30 – 35%
Phosphoric Acid 150 - 200oC 40 – 50%
Fuel cells generate
electricity directly without
combustion or mechanical steps
such as do engines or turbines ....
... this makes fuel cells the most
efficient devices for generating electricity from
fuel
TitleTitle
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Fuel Cell TechnologiesType Operating
TempElectrical Efficiency
Applications
Alkaline 70oC 55-60%Industrial Stationary
SpaceMilitary
Molten Carbonate
600 - 700oC 45 - 47% Large utilityLarge distributed
generation
Solid Oxide 600 - 1000oC 35 – 43% Auxiliary power
PEM 50-100oC 25 - 35%
53 – 58%
Back up power
Transportation
Direct Methanol 60 - 90oC 30 – 35% Portable power
Phosphoric Acid 150 - 200oC 40 – 50% Industrial Stationary
Different fuelcell types aresuitable for differentapplications...
TitleTitle
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Fuel Cell TechnologiesType Operating
TempElectrical Efficiency
Applications
Alkaline 70oC 55 – 60%Industrial Stationary
SpaceMilitary
Molten Carbonate
600 - 700oC 45 - 47% Large utilityLarge distributed
generation
Solid Oxide 600 - 1000oC 35 – 43% Auxiliary power
PEM 50-100oC 25 - 35%
53 – 58%
Back up power
Transportation
Direct Methanol 60 - 90oC 30 – 35% Portable power
Phosphoric Acid 150 - 200oC 40 – 50% Industrial Stationary
Of all the fuel cell types Alkaline is the most efficient and does not have to be engineered for higher pressures that result from steam
TitleTitle
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Fuel Cell TechnologiesFuel Cell type
Alkaline
Molten Carbonate
Solid Oxide
PEM
Direct Methanol
Phosphoric Acid
Alkaline fuel cells are a proven technology...
...used in manned US and Russian space missions and in submarines to provide power and drinking
water
TitleTitle
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Historically......historically alkaline fuel
cells have also been demonstrated in a wide variety of applications...
... but were unable to compete against low fossil fuel costs
because...
TitleTitle
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Fuel Cell TechnologiesType Operating
TempElectrical Efficiency
Applications
AlkalineTraditional platinum
70oC 60% SpaceMilitary
Molten Carbonate
600 - 700oC 45 - 47% Large utilityLarge distributed
generation
Solid Oxide 600 - 1000oC 35 – 43% Auxiliary power
PEM 50-100oC 25 - 35%
53 – 58%
Back up power
Transportation
Direct Methanol 60 - 90oC 30 – 35% Portable power
Phosphoric Acid 150 - 200oC 40 – 50% Industrial Stationary
...Platinum catalysts added significant cost and also required pure oxygen as
well as hydrogen... which is essentially rocket fuel
TitleTitle
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Fuel Cell TechnologiesType Operating
TempElectrical Efficiency
Applications
AlkalineAFC Energy
non-platinum70oC 55 – 60%
Industrial stationary
Distributed energy
AlkalineTraditional platinum
70oC 60% SpaceMilitary
Molten Carbonate
600 - 700oC 45 - 47% Large utilityLarge distributed
generation
Solid Oxide 600 - 1000oC 35 – 43% Auxiliary power
PEM 50-100oC 25 - 35%
53 – 58%
Back up power
Transportation
Direct Methanol 60 - 90oC 30 – 35% Portable power
Phosphoric Acid 150 - 200oC 40 – 50% Industrial Stationary
...AFC Energy has re-engineered the proven alkaline technology removing cost. Platinum has been replaced with ceramic
based catalysts at less than 5% of the cost of platinum...
...and oxygen is taken from air...
... This opens up the market for large-scale industrial
power generation....
TitleTitleLow risk business model
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... Our proto-type system was tested in the field and led to...
... Our first market is the surplus hydrogen generated from the production of chlorine and caustic soda. Our first customer is Akzo Nobel.
TitleTitle
Electronics/ Fluid controls
Alkaline electrolyte tank
Cartridge docking
Cartridge assembly
... the Beta System: Modular Power
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Fuel cell stack in cartridge
TitleTitleBeta System Design
... the Beta System is designed for low lifetime cost of ownershipIt is easily mass produced, assembled and installed.
It operates continuously and is controlled remotely, hot swapping” means the Beta System does not have to be shut down even when electrode cartridges are changed.
It is modular and designed for heat recovery
...the result is a low cost per MWeh over the lifetime of the installation
CHP = Combined Heat and PowerMWeh = Megawatt hours of Electricity
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TitleTitle
Beta System: Fuel Cell Development
At the end of their useful life cartridges are removed and disassembled. Electrodes are cleaned and reused…
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... a refurbished cartridge is only a third of the cost of a new cartridge of the same power.
TitleTitleBeta System:
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...Designed for easy containerising or skid mounting...
TitleTitle
Multi-megawatt Power Plant (6MW)
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...Designed for large-scale installations...
TitleTitle
Markets
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TitleTitleMarkets
....for this reason AFC Energy is focussed directly on the chlor-alkali market where waste hydrogen is readily available and the electricity is required on site ... Other sources of hydrogen usually require an intermediate step... Several countries such as Korea, USA and Germany offer financial incentives for electricity produced from fuel cells, making them more attractive.
...essentially AFC Energy’s alkaline fuel cell generates electrical power from hydrogen fuel at the lowest unit cost...
...the economics of any particular application depend upon the cost of the fuel and the value of the outputs, principally the electricity....
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TitleTitle
Installations successfully trialled by AFC EnergyInstallations currently planned by AFC Energy
Municipal Waste
Natural Gas
Biogas
Coal
Waste H2
Feedstock Fuel Processing
Plasma Gasification
MethaneReforming
Underground Coal Gasification Water
Power
Heat
Gas
Sol
id
Utilised Output
Low OxygenAir
H2
Ammonia Cracking
AFC
Water Gas Shift
H2 Purification
Raw Syngas(Mainly H2+CO)
Mainly H2+CO2
H2 + N2
Syngas Clean
Clean Syngas
Markets: Sources of Hydrogen
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TitleTitle
Chlor-alkali: AkzoNobel
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...two commercial systems were installed at AkzoNobel’s Bitterfeld plant in Germany, Q4 2011...
...an agreement is in place for further supply...
AFC Energy works closely with AkzoNobel to demonstrate the commercial fuel cell system
TitleTitle
... Our primary market is Chlor-alkali, where hydrogen availability is plentiful...
...it consumes 1% of the world’s electricity…
…and produces 1.65 million tonnes of hydrogen a year as a by-product...
…Globally this industry can support more than 3000 MWe of generating capacity
Chlor-alkali Market
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TitleTitle
• Ordinary household waste can be converted into hydrogen.
• UK generates 60 million tonnes of carbon-based waste every year… equivalent of 15,000 MW of electricity.
• Fuel cell increases output efficiency of Waste to Energy plants by c.40%.
• AFC Energy is accessing this market through Waste2Tricity Limited (W2T)
• W2T is gaining commercial traction and positioning WtE facilities so that they are fuel cell ready...
Waste to Energy Market
WtE = Waste to EnergyAFC Energy owns 25% of Waste2Tricity Limited
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TitleTitle
...with planning permission now in place Air Products' Tees Valley Renewable Energy Facility will generate 49MW of renewable power. In the longer-term, Air Products' plant has the potential to produce renewable hydrogen and is being considered for a demonstration of AFC Energy’s fuel cell technology. This would involve alkaline fuel cells generating power, alongside more conventional CCGT, using hydrogen separated from the syngas stream.
Waste to Energy Market: Tees Valley
CCGT = Combined Cycle Gas Turbine 25
TitleTitle
…AFC Energy has partnered with Linc Energy...
…gasification underground using Linc Energy’s technology largely eliminates the ecological impact of coal…
…coal gasification enables CCS whilst producing hydrogen…
…alkaline fuel cells increase power generation efficiency from 30% to c. 50%...
Market: Clean Coal
CCS = Carbon Capture and Storage 26
TitleTitleSteel Making
Coke Oven Gas released from coal during the coking process is c. 55% hydrogen which can be separated for use in fuel cells.
It is also possible to generate hydrogen using the hot (1500
oC) slag to break water
molecules apart.
Companies including Nippon Steel, POSCO and Tata Steel are actively working on hydrogen generation projects.
...AFC Energy is in discussions with potential partners
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TitleTitleOther Applications
There are a range of other potential applications, including:
• distributed energy from reformed natural gas or biogas
• in association with intermittent renewables where electrolysers generate hydrogen from surplus power
• UPS for applications such as telecoms and data centres
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TitleTitle
Q. How will AFC scale up production?
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TitleTitle• AFC Energy is Investing in automated
production and assembly.
• Lower Cost production• Develop production team• Drive cost reduction and quality
• Volume Ramp• Using standard industrial technologies• High volumes
Manufacturing
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TitleTitle
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2012 2013 2014 2015 2016 2017
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£1.0•Longevity
•Power Density
•BoM saving
•Manufacturing economies of scale
•Automated Production
•Value engineering
Anticipated Beta system cost profile
Factors affecting stack costs
BoM = Bill of MaterialsFC = Fuel Cell
Applications like FC vehicles and replacements for domestic boilers, which need 100,000’s units to achieve target costs... AFC Energy needs just two customers!
TitleTitle
Q. How do investors know what technical progress is being made?
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CPI Independent Review - highlights
... unlike any other company developing fuel cells AFC Energy’s technical and manufacturing progress is regularly reviewed by an independent assessor and a summary of the review is published.
... The Centre for Process Innovation has been carrying out the review and is given unrestricted access to AFC Energy’s work and people.
TitleTitle
Q. What protection does AFC Energy have for its Alkaline fuel cells?
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TitleTitle
...present IP portfolio includes 12 families of patents... to ‘ring-fence’ unique aspects of AFC’s technology. More patent applications in the pipeline......
Intellectual Property (IP)
...AFC Energy is the first in its field to re-engineer alkaline fuel cells using modern materials, process, modelling and manufacture.
... there had been little patenting of anything to do with alkaline fuel cells since the 1960’s...
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TitleTitle
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Road to commercialisation
Commercial System Sales
ESCo installations
Commercial Demonstration & Early Adopter
Licence fees/royalties
Grant Funded projects
Q1/2012...
ESCo = Energy Supply Company
TitleTitle
Experienced Board
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Tim Yeo - chairman Ian Williamson - CEO Ian Balchin – CSO Dr Gene Lewis - CTO
David Marson - FD Mitchell Field - NED David Smith – NEDLinc Energy
Sir John Sunderland - NED
CSO = Chief Strategic OfficerCTO = Chief Technical Officer
TitleTitleSummary
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• AFC Energy is re-engineering proven fuel celltechnology to compete with conventional power generation• First contracts, licences and grants secured• First market, waste hydrogen from the chlorine industry• Second market waste to energy – where alkaline fuel cell systems are being
designed into WtE power stations• Capable of rapid scale up with automated assembly• progress is independently monitored and published• Intellectual property secured• ESCo is the preferred route to market - selling electricity not plant.
AFC Energy’s alkaline fuel cell systems will enable a transformation to a hydrogen economy
TitleTitleLegal
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• This document and the information presented verbally to you (together, “the Presentation”) does not constitute an admission document, a prospectus or listing particulars relating to the Company, nor does it constitute or form part of any offer or invitation to purchase, sell or subscribe for, or any solicitation of any such offer to purchase, sell or subscribe for, any securities in the Company nor shall this Presentation or any part of it, or the fact of its distribution, form the basis of, or be relied on in connection with, any contract thereof.• The Presentation is confidential and is being supplied to you solely for your information and may not be reproduced, redistributed or passed on, directly or indirectly to any other person or published in whole or part, for any purpose.• Recipients of the Presentation who are considering trading in the Ordinary Shares of the Company are reminded that no reliance may be placed for any purpose whatsoever on the information, representations or undertakings contained in this Presentation nor their completeness; no liability is accepted for any such information, representation or opinions and this Presentation should not be considered a recommendation by the Company or Allenby Capital or any of their respective affiliates.• Information in this Presentation must not be relied as having been verified, authorised or approved by the Company. Neither the Company, nor the directors, officers or employees, nor other person makes any guarantee, representation or warranty, express or implied, as to the accuracy, completeness or fairness of the information and opinions contained in this Presentation, nor does the Company accept any responsibility or liability whatsoever for any loss howsoever arising from any use of this Presentation or its contents or otherwise arising in connection therewith.• Certain market data used in this Presentation has been obtained from industry reports. Industry reports generally state that the information contained in them has been obtained from sources believed to be reliable. The Company has not independently verified such data. Whilst the Company has complied and extracted market