This Safety Data Sheet does not form part of the approved label. Following the instructions on the pesticide Product Label for the specified uses should ensure that the product is used safely and efficaciously for those uses.

SAFETY DATA SHEETEU Regulation No. 1907/2006, Annex IIRevised edition no: 1 Date: 17/01/2013 Supersedes: 17/01/2013 R-20226-DPD

SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING1.1 Product identifierTrade name SERGEANT MAJORChemical formula Lambda-cyhalothrin: C23H19ClF3NO31.2. Relevant identified uses of the substance or mixture and uses advised againstRelevant identified uses InsecticideUses advised against None under normal conditions.1.3. Details of the supplier of the safety data sheet Adama Agricultural Solutions UK Ltd Unit 15, Thatcham Business Village, Colthrop Way, Thatcham, Berkshire RG19 4LW Telephone: (01635) 860555Email ukenquiries@adama.com1.4. Emergency telephone number National Chemical Emergency Centre - Tel: 01865 407333 (24 hours)

SECTION 2. HAZARDS IDENTIFICATION2.1. Classification of the substance or mixtureClassification 67/548/EEC (DSD) - 1999/45/EC (DPD) Xn; R65 N; R50-532.2. Label elementsLabelling 1999/45/EC (DPD)

Symbol(s)

Xn: Harmful. N: Dangerous for the environment.

R Phrase(s) R50/53 - Very toxic to aquatic organisms, may cause long term adverse effects in the aquatic environment. R65 - Harmful: may cause lung damage if swallowed.

S Phrase(s) S02 - Keep out of the reach of children. S13 - Keep away from food, drink and animal feedingstuffs. S20/21 - When using, do not eat, drink or smoke. S35 - This material and its container must be disposed of in a safe way. S57 - Use appropriate container to avoid environmental contamination. S62 - If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label.

2.3. Other hazardsOther hazards None under normal conditions.SAMPLE

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTSComponents : This product is considered to be hazardous and contains hazardous components.

Substance name Concentration CAS No. EC No. Index No. REACH Reg. Classification % w/w

Lambda-cyhalothrin 50 g/l 91465-08-6 415-130-7 607-252-00-6 ---- T+; R26(ISO) T; R25 Xn; R21 N; R50-53 (M fact. = 10000) --------------------------------- Acute Tox. 2 - H330 Acute Tox. 3 - H301 Acute Tox. 4 - H312 Aquatic Acute 1 - H400 Aquatic Chronic 1 - H410

Naphtha solvent > 10% 64742-94-5 ---- 649-424-00-3 ---- Xn; R65heavy petroleum --------------------------------- Asp. Tox 1 - H304

SECTION 4. FIRST AID MEASURES4.1. Description of first aid measuresFirst aid measuresInhalation Remove victim to fresh air. Keep victim warm and at rest. If breathing is difficult, give oxygen.If not breathing, give artificial respiration. Obtain medical attention.Skin contact Remove affected clothing and wash all exposed skin area with soap and water, followed by warm water rinse. Wash clothing separately before re-use. Consult a doctor in the event of any complaints.Eye contact Wash out with plenty of water with the eyelid held wide open. Immediately consult an eye specialist.4.2. Most important symptoms and effects, both acute and delayedIrritation to lungs and upper respiratory tract shown as rhinitis, pharyngites and pneumonia.May cause dermatitis, eye irritation, corneal oedema and chemical burns.Inhalation may cause lung irritation and lung oedema.4.3. Indication of any immediate medical attention and special treatment neededNote to physician There is no specific antidote. Treat symptomatically and give supportive therapy.

SECTION 5. FIREFIGHTING MEASURES5.1. Extinguishing mediaSuitable extinguishing mediaFor small fire: foam, dry chemical, carbon dioxide.For large fire: water spray, water fog, foam.

5.2. Special hazards arising from the substance or mixtureSpecific hazards Irritating fumes, COx, NOx, chlorides, fluorides, ammonia, toxic.5.3. Advice for firefightersProtection against fire Wear proper protective equipment. Self-contained breathing apparatus.Special procedures Fight fires from a protected location. Dike fire control water for later disposal.

SECTION 6. ACCIDENTAL RELEASE MEASURES6.1. Personal precautions, protective equipment and emergency proceduresFor emergency respondersWear suitable protective clothing, gloves and eye/face protection and chemical resistant boots.6.2. Environmental precautionsEnvironmental precautionsDo not discharge into drains or the environment, dispose to an authorised waste collection point. If the product has contaminated surface water, inform the appropriate authorities.6.3. Methods and material for containment and cleaning upClean up methods Absorb in sand or other inert material. Sweep or shovel spills into appropriate container for disposal. Wash away with plenty of water. Prevent entry to sewers and public waters.6.4. Reference to other sectionsSAMPLE

SECTION 7. HANDLING AND STORAGE7.1. Precautions for safe handlingHandling Avoid contact with skin and eyes. Do not breathe spray. Do not breathe vapour.When using do not eat, drink or smoke.Wash hands thoroughly after handling.7.2. Conditions for safe storage, including any incompatibilitiesPacking HDPE containersStorage Keep locked up. Keep container tightly closed. Keep only in the original container in a cool, well ventilated place.Avoid exposure to excessive heat or cold.7.3. Specific end use(s)

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION8.1. Control parametersTLV© Not established (L-Cyhalothrin)8.2. Exposure controlsFacilities storing or utilising this material should be equipped with an eyewash facility and safety shower. Wash clothing before re-using. Wash hands thoroughly after handling.Personal protectionRead the label before use.Respiratory protection During spraying wear suitable respiratory equipment.Hand protection Wear suitable gloves.Skin protection Wear suitable protective clothing.Eye protection Chemical goggles or safety glasses.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES9.1. Information on basic physical and chemical propertiesAppearance Capsule - suspension.Colour Off-white, opaque.Odour Paint-like.Odour threshold Not available.pH 5-8 (1%).Melting point/freezing point Data not available.Initial boiling point - boiling range Data not available.Flash point >95°C.Evaporation rate Data not available.Flammability Not flammable.Explosion limits (lower - upper) Data not available.Vapour pressure Data not available.

Vapour density Data not available.Relative density 1.0327 g/ml.Solubility Not applicable.Partition coefficient: n-octanol/water Data not available.Auto-ignition temperature Data not available.Decomposition temperature Data not available.Viscosity Data not available.Explosive properties Not explosive.Oxidising properties Data not available.9.2. Other informationNot available

SECTION 10. STABILITY AND REACTIVITY10.1. Reactivity10.2. Chemical stabilityChemical stability Stable under normal conditions.10.3. Possibility of hazardous reactionsHazardous reactions None known.10.4. Conditions to avoidConditions to avoid Protect from sunlight, open flame and sources of heat. Decomposes upon heating.10.5. Incompatible materialsMaterials to avoid Avoid contact with: strong acids, strong bases.10.6. Hazardous decomposition productsHazardous decomposition products Toxic and irritating fumes, COx, NOx, chlorides, fluorides, ammonia.

SECTION 11. TOXICOLOGICAL INFORMATION11.1. Information on toxicological effectsAcute toxicity

- Oral, Rat LD50 (mg/kg) >2000- Dermal, Rat LD50 [mg/kg] >2000- Inhalation, Rat LC50 [mg/l/4h] 1.08 Maximum concentration attainable. Not adequate for classification.

Skin corrosion/irritation Not irritantSerious eye damage/irritation Not irritantRespiratory or skin sensitisation Non sensitiserGerm cell mutagenicity Not mutagenicCarcinogenicity Not carcinogenicReproductive toxicity Not considered to be toxic for the reproductive system.STOT-single exposure Not availableSTOT-repeated exposure Not availableAspiration hazard Not available

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SECTION 12. ECOLOGICAL INFORMATION12.1. ToxicityEcological effects information For Lamda-cyhalothrinAcute toxicity96 H-LC50 - Rainbow trout [µg/l] 0.2448 H-EC50 - Daphnia magna [µg/l] 0.36EC50 Algae [µg/l] >1000 (96 hours)LD50 Birds [mg/kg] >3950 (Mallard duck)

Long term exposure12.2. Persistence - degradability12.3. Bioaccumulative potential12.4. Mobility in soil12.5. Results of PBT and vPvB assessmentNot available12.6. Other adverse effectsNone known

SECTION 13. DISPOSAL CONSIDERATIONS13.1. Waste treatment methodsGeneral Dispose of this material and its container at hazardous or special waste collection point.

SECTION 14. TRANSPORT INFORMATION14.1. UN numberUN No. 3082Hazard label(s)

9 : Miscellaneous dangerous substances and articles.

14.2. UN proper shipping nameLand transport - ADR/RID ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Lambda-cyhalothrin 50 g/l)Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Lambda-cyhalothrin 50 g/l)H.I. no. 90Sea transport - IMO-IMDG ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Lambda-cyhalothrin 50 g/l)Air transport - ICAO/IATA ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Lambda-cyhalothrin 50 g/l)

14.3. Transport hazard class(es)Land transport - ADR/RID 9Sea transport - IMO-IMDG 9IMO-IMDG - class or division 9Air transport - ICAO/IATA 914.4. Packing groupLand transport - ADR/RID IIIPacking group IIISea transport - IMO-IMDG IIIAir transport - ICAO/IATA III14.5. Environmental hazardsIMDG-Marine pollution Marine pollutant - polluant marin14.6. Special precautions for userSee transport documents.14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC CodeNot applicable.

SECTION 15. REGULATORY INFORMATION15.1. Safety, health and environmental regulations/legislation specific for the substance or mixtureEnsure all national/local regulations are observed.15.2. Chemical Safety AssessmentNot applicable.

SECTION 16. OTHER INFORMATIONList of relevant R phrases (heading 3) R21 - Harmful in contact with skin.R25 - Toxic if swallowed.R26 - Very toxic by inhalation.R50/53 - Very toxic to aquatic organisms, may cause long term adverse effects in the aquatic environment.R65 - Harmful: may cause lung damage if swallowed.

List of relevant H phrases (Section 3) H301 - Toxic if swallowed.H304 - May be fatal if swallowed and enters airways.H312 - Harmful in contact with skin.H330 - Fatal if inhaled.H400 - Very toxic to aquatic life.H410 - Very toxic to aquatic life with long lasting effects.

DISCLAIMER OF LIABILITY The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.

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