These aren’t really ‘properties’ – more like definitions that relate to what’s happening...

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PROPERTIES OF MATERIALS: MORE THAN PHYSICAL AND CHEMICAL

Transcript of These aren’t really ‘properties’ – more like definitions that relate to what’s happening...

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Slide 2 These arent really properties more like definitions that relate to whats happening microscopically. The goal here is to relate structure to properties. Slide 3 The kinds and relative count of elements, ions or other constituents in a material; chemical formula, percent in an alloy, etc. Note that a single composition can have different structures, for instance allotropes of sulfur or polymorphs in iron- carbon systems. The basic starting point is: Composition Bonding Metals metallic elements metallic Ceramics metals + nonmetals ionic & covalent Polymers carbon, hydrogen covalent Slide 4 Atomic scale order; the manner in which atoms or ions are spatially arranged. It is defined in terms of unit cell geometry. A material with long-range order is called crystalline (contrasted with amorphous). Slide 5 The structural features that can be seen using a microscope, but seldom with the naked eye; ranges from glassy to crystalline; includes grain boundaries and phase structures. Slide 6 These are the standard properties that we teach in chemistry class. Slide 7 Solid, liquid or gas; not as simple as it may seem. Slide 8 Mass of a material per unit volume. Low density, high strength materials are desirable for manufacturing aircraft and sporting equipment. Slide 9 The physical attraction for iron, inherent in a material or induced by moving electric fields. Iron, cobalt, nickel and gadolinium are inherently ferromagnetic. Slide 10 The maximum amount of a solute that can be added to a solvent. Solubility is complex in some solid materials, for instance the ones that form eutectic mixtures; a good starting point to discuss complex phase diagrams. Slide 11 Resistance of a material (usually liquid) to flow. Plastics and glasses become less viscous with increasing temperature. Slide 12 The concepts of stress, strain, elasticity, deformation and failure are necessary to understand and interpret mechanical properties. Slide 13 The ability of a material to be reshaped in all directions (plastic deformation) without failure; related to ductility and sometimes called workability; an important characteristic of metals. Slide 14 The ability of a material to change shape (deform) usually by stretching along its length; closely related to tensile strength. Slide 15 Strength is not a precisely defined mechanical property, as there are many types of strength. Collectively, it means the ability of a material to stand up to forces being applied without it bending, breaking, shattering or deforming. Slide 16 The resistance to being permanently deformed or bent; measured by distance of penetration into the material. There are several scales used to measure hardness. Slide 17 A characteristic of a material that relates to its response to sudden blows or shocks. Toughness can be expressed as the amount of energy required for creating or propagating a crack. Slide 18 The absence of ductility; failure by sudden fracture (no plastic deformation); characteristic of ceramic materials. Slide 19 The ability of a material to absorb force and flex in different directions, returning to its original position once the stress is removed. Polymers are desirable for their elasticity. Slide 20 For the sake of this summary, electricity is defined as the flow of electrons. Slide 21 A measure of how easily a material allows electrical current to flow through. Metals like copper, aluminum and iron have much higher electrical conductivities than ceramics, plastics, glass and rubber. Slide 22 The reciprocal of electrical conductivity; a measure of a materials resistance to the flow of electric current. Resistivity is an important concept in semiconductors; depends on electronic structure, temperature and microstructure. Slide 23 Generally, lack of reactive chemistry is desirable for materials; this is a good place to look through those MSD sheets. Slide 24 A measure of a materials ability to damage or disrupt the metabolism of living tissue; can be acute or chronic; can be administered by contact, inhalation, ingestion, or injection. The dose makes the poison. Slide 25 Corrosion is an electrochemical process that is closely related to the activity series. An ion high on the list will replace a metal lower on the list. Mg > Al > Zn > Cr > Fe > Sn > Ni > Cu > Ag > Au Corrosion is strongly dependent on environmental variables. Slide 26 A materials ability to catch fire and burn; important for organic materials and reactive metals. Slide 27 Use in or on the human body without eliciting a rejection response from the surrounding body tissues; includes materials made of polymers, metals, ceramics, and composites. Slide 28 Think about heating a rod: it gets hot, it expands, it conducts heat, it may soften or melt. Slide 29 The efficiency of a material in absorbing heat. High specific heat means a material heats fast and cools down fast. By definition, the specific heat of a material is the energy required to raise the temperature of 1 g of that material by 1 C. Slide 30 Nearly all materials expand when heated and contract when cooled. The extent to which this happens is the coefficient of thermal expansion. Bridges are designed with expansion joints so they dont buckle due to thermal expansion. Slide 31 Thermal conductivity is the rate at which heat flows through a material. It depends on the flow of both electrons and phonons. Slide 32 The temperature at which liquid begins to form as a material is heated. Not all materials have distinct melting points, and many materials have phase transition temperatures in which crystal structure changes.