Chemical Thermodynamics Chemical Thermodynamics Thermo Part 2 1.
Thermodynamics MEC220
description
Transcript of Thermodynamics MEC220
![Page 1: Thermodynamics MEC220](https://reader035.fdocuments.us/reader035/viewer/2022071921/55cf9b6d550346d033a607e2/html5/thumbnails/1.jpg)
1. (a) A vacuum gauge indicates a pressure of 0.1kgf/cm2 at the exit of a turbine. If the
mercury barometer gives local atmospheric pressure as 750 mm Hg, what is the absolute
pressure at the exit of the turbine in kPa? Take relative density of mercury as 13.6. (4
marks)
(b) An electric generator coupled to a windmill produces an average electric power
output of 15 kW. The power is used to charge a storage battery. Heat transfer from the
battery to the surroundings occurs at a constant rate of 1.8 kW. For 8h of operation,
determine the change in energy stored in the battery, in kJ. (4 marks)
2. (a) 5kg of air is contained in a vertical piston - cylinder assembly. The piston has mass
50 kg and face area 0.01m2 and atmosphere exerts a pressure of 100 kPa on the top of the
piston. Initially air occupies a volume of 5litres and it slowly reduces to 0.002m3 as its
specific internal energy decreases by 260 kJ/kg. Neglecting friction between the piston
and the cylinder wall and kinetic and potential energy changes, determine the heat
transfer to the air, in kJ. (6 marks)
(b) A piston cylinder assembly containing 1 kg of steam at 1 MPa and 60% quality is
heated. The piston does not move until the system pressure reaches 1.5MPa and then it
moves at constant pressure till the temperature becomes 400oC.Plot the process and
determine the work and the heat interactions. (8 marks)
3.a) Derive steady-state steady flow first law of thermodynamics equation for a flow
process (5 Marks)
b) Air, with a mass flow rate of 0.5kg/s, enters a steady flow compressor at 30oC and
leaves at 150oC. Upon leaving the compressor it is cooled in a heat exchanger to 30oC. In
the heat exchanger, water enters at 20oC and leaves at 50oC. Assuming air to be an ideal
gas with Cp = 1.005 kJ/kg, determine (a) the compressor power input and (b) the mass flow
rate of water (8 marks)
4.(a) Water is used as the working fluid in a Carnot cycle heat engine, where it changes
from saturated liquid to saturated vapor at 200°C as heat is added. Heat is rejected in a
constant-pressure process (also constant T) at 20 kPa. The heat engine powers a Carnot-
cycle refrigerator that operates between -15 oC and +20 oC, Find the heat added to the
![Page 2: Thermodynamics MEC220](https://reader035.fdocuments.us/reader035/viewer/2022071921/55cf9b6d550346d033a607e2/html5/thumbnails/2.jpg)
water per kg water. How much heat should be added to the water in the heat engine so the
refrigerator can remove 1 kJ from the cold space? ( 8 marks)
(b) Water at 200 kPa with x = 1.0 is compressed in a piston cylinder to 1 MPa and 350°C
in a reversible process. Find the sign convention for the work and the heat interactions.
(4 marks)
5. (a)Two air streams both at 200 kPa; one is of 1 kg/s at 400 K, and the other is of 2 kg/s
at 290 K. The two flows are mixed together in an insulated box to produce a single exit
flow at 200 kPa. Find the exit temperature and the total rate of entropy generation. (8
marks)
(b). A large slab of concrete, 5 m x 8 m x 0.3 m, is used as a thermal storage mass in a
solar-heated house. If the slab cools overnight from 23°C to l8°C in an house, what is the
change in entropy of i) the concrete slab, ii) the surroundings and iii) the net change in
entropy if the house is at l8°C? ( concrete = 2200 kg/m3, C concrete = 0.88 J/KgK) (8 marks)
6. State carnot's principles. Prove that for a given hot and cold reservoirs, maximum
efficiency will be for reversible heat engine. ( 5 marks)
7. The compression ratio of an air standard Otto cycle is 9.5.Prior to isentropic
compression process, the air is at 100kPa, 35C,and 600 cm3.the temperature at the end of
isentropic expansion process is 800K.Using specific heat values at room
temperature ,determine (a) the highest temperature and pressure in the cycle ;(b) the
amount of heat transferred in kJ; (c) thermal efficiency ; and(d) the mean effective
pressure.(8 marks)
8. Refrigerant-134 a enters the compressor of a refrigerator as superheated vapor at 0.14
MPa and -10 oC at a rate of 0.12 kg/s, and it leaves at 0.7 MPa and 50 C . the refrigerant
is cooled in the condenser to 24 C and 0.65 MPa, and it is throttled to
0.15MPa.Disregarding any heat transfer and pressure drops in the connecting lines
between the components ,show the cycle on a T-s diagram with respect to saturation
![Page 3: Thermodynamics MEC220](https://reader035.fdocuments.us/reader035/viewer/2022071921/55cf9b6d550346d033a607e2/html5/thumbnails/3.jpg)
lines, and determine (a) the rate of heat removal from the refrigerated space ,(b) power
input to the compressor ,(c)the isentropic efficiency of the compressor , and (d) the
coefficient of performance. (10 marks)
9. Using the four Gibbs equations, derive the Maxwell relations for a simple
compressible substance. (9 marks)