The RIAR DOVITA-1/2 P&T Program – Current Results of the ...€¦ · The RIAR DOVITA-1/2 P&T...
22
The RIAR DOVITA-1/2 P&T Program – Current Results of the 15-year R&D activities State Scientific Center Research Institute of Atomic Reactors Dimitrovgrad-10, Ulyanovsk region, 433510, Russia e-mail: [email protected] M.V. Kormilitsyn, A.V.Bychkov, O.V. Skiba, A.G. Osipenko
Transcript of The RIAR DOVITA-1/2 P&T Program – Current Results of the ...€¦ · The RIAR DOVITA-1/2 P&T...
The RIAR DOVITA-12 PampT Program ndashCurrent Results of the 15-year RampD activities
State Scientific Center Research Institute of Atomic ReactorsDimitrovgrad-10 Ulyanovsk region 433510 Russia
e-mail kormilitsynniiarru
MV Kormilitsyn AVBychkov OV Skiba AG Osipenko
Experience in Closed Fuel Cycle including pyrochemical processes
Research Institute on Atomic reactors ndash RIAR (Dimitrovgrad) is most Russian RampD center of non-aqueous methods developmentPyrochemical investigation - from early 1960-sDemonstration of fluoride volatility reprocessing technology ndash 1970sDemonstration facility for pyrochemical MOX-fuel production for fast reactor ndash from late 1970-sPyroelectrochemical reprocessing experience ndash 1990-2003Preparation for industrial application ndash from 1990-sStudy on transmutation cycle nitride fuel and other applications ndashfrom 1990s
Dry technologies for MA fuel reprocessing andpreparationOxide fuel application as the most widely studied oneVibropacking automated technology of the fuel pinproductionIntegrated disposition of fuel reprocessing and fuelelement refabrication facilities on the same site with thereactorTA The whole complex of approaches will permit acreation of the compact plant for Transmutation ofActinides
Since 1992 RIAR has been performing own RampD DOVITA Program
Experience in adding of minor actinidesin fuel compositions and results of irradiation
Irradiated(UNp)O2 fuel19 burn-up
Pyrochemical technology of adding Np into oxide fuel(5-20) has been developed
Performance of vi-pack fuel with (UNp)O2 fuel hasbeen validated experimentally to ~20 burnup inBOR-60
No evidence of significant difference in performanceof fuel rods with (UNp)O2 fuel compared with UO2 orMOX fuel rods has been noticed
Pyrochemical process of codeposition of Am withMOX fuel (2-4) has been developed
Methods of AmREE separation in melts has beentested
Special vi-pack targets containing Am oxide withUO2 or inert matrix have been developed
Transmutation of Np Am Cm is being studied inBOR-60
New times considerationDOVITA DOVITA-2
1992Dry technologiesOxide fuel with MAVi-packIntegrated disposition same site with the reactorTA Transmutation of Actinides
2006-2008Dry technologiesOn-site reprocessingVarious type of fuel with MAIntegration of MA recycling into FR Closed Fuel Cycle TA - Transmutation of Actinides
DOVITA-2
Fuel type Stages
Oxide vi-pack
Oxide pellet
Nitride pellet vi-pack
Metal Molten salt
Concept Studies
+ + + +- +
RampD + -+ +- - +
Fuel Production
+ - - - -
Irradiation Testing
+ - - - -
PIE + - - - ----
Reprocessing -+ - -+ - +-DOVITA-1
Research area of pyrochemical and non-aqueous MAFP partitioning in frame DOVITA-2 Program
Meltsmedia
Electrochemical methods Oxides Precipi-tation
Metalli-zation
Liquid cathodes
Solid cathodes
Anodic dissol-n
EChem oxide titration
Chlorides Cd Bi Ga Al
Al + + + +Fluorides Bi Ga Al
Pb - + + + -Cl- F- Cd Bi Ga
Al PbAl + + + -
Molibdates - + - - + -RTIL Ga Zn Cu Ni
Al hellip + - - -+ Methods of Volatility of Fluorides and or Chlorides
ISTC Project 3261 (2006-2008)
Study of Cm thermodynamicsin molten chloridesObjectives
Reactions of formation for oxygen Cm compounds- equilibrium constants for reactions of Cm oxygen compoundsformation versus temperature- equilibrium constants for reactions of Cm oxygen compoundsformation versus the inverse effective radius of solvent cathion
1st Year is completed
Reactions of formation for oxygen-free Cm compounds- standard potential for redox pair versus temperature- standard potential for redox pair versus the inverse effective radius of solvent cathion
Simulation of Cm behavior in molten chloridesPourbaix diagrams
Collaborators ndash ITU CIEMAT CEA KTH
Recent RIAR activities in frame of DOVITA-2 Program
Gas supply tube
Sluice
Oxygen sensor
Salt
Thermocouple
Reference electrode AgAg+
Oxygen pump
Potentiometric titration of CmCl3
ISTC project 3261 Current Results
Potentiometric titration of CmCl3
Applied methodsbull main - titration by BaO
bull combined - in case of absence of Section on preliminary experimental curve for CmO+ formation
titration by current through the electric circuit ldquooxygen pumprdquo ndash ldquocounter electroderdquo and then by BaO
ISTC project 3261 Current Results
Oxygen pump after experiment
Cm dioxide deposit
Oxygen pumpZrO2(Sc2O3)Pt(O2)
Reference electrodePyrexSalt+AgCl(075molkg)AgPt(Ar)
Oxygen sensorZrO2(Y2O3)Pt(O2)
Counter electrodePyrexSalt C
ISTC project 3261 Current Results
Conditions of experiments
Salt Amount of Runs
Temperature rangeoC
Range of Cm content in melt
molekgNaCl-2CsCl 11 550-750 (11-14)10-3
3LiCl-2KCl 7 450-650 (19-79)10-3
NaCl-KCl 3 750-850 (50-69)10-3
ISTC project 3261 Current Results
Salt ingot with CmCl3
NaCl-2CsCl+CmCl3(14middot10-2molekg) LiCl-KCl+CmCl3(55middot10-3molekg)
NaCl-KCl + CmCl3(50middot10-3molekg)
ISTC project 3261 Current Results
Experimental constants of CmO+ CmOCl and Cm2O3 dissociation in molten chlorides at different temperatures molality scale
Melt T oC pK(CmO+) pK(CmOCl) pK(Cm2O3)
NaCl-2CsCl 556 42+02 79+02 201+03
650 34+02 75+02 185+03
750 37+02 67+02 168+03
3LiCl-2KCl 450 25+02 62+02 155+05
550 24+02 57+02 127+05
650 083+01 52+02 125+05
NaCl-KCl 750 26+02 59+02 129+04
800 24+02 58+02 126+04
850 13+01 56+02 121+04
ISTC project 3261 Current Results
Comparison with literature data on other actinidesDependence of dissociation constant for actinides upon temperature in LiCl-KCl
0
5
10
15
20
25
1 11 12 13 14
1000T 1000K
pK m
olal
ity sc
ale
CmO+(RIAR)
CmOCl (RIAR)
Cm2O3(RIAR)
AmO+[Lambertin]
AmOCl Lambertin]
Am2O3 [Lambertin]
Pu2O3 [Martinot]
Pu2O3 [Picard]
PuOCl [Picard]
ISTC project 3261 Current Results
Recent RIAR activities in frame of DOVITA-2 Program
RampD for production of vi-pack oxide Fuel with MAUnder continuation
RampD for production of vi-pack nitride Fuel with MAUnder development
RampD for production oxide pellet fuel with MAUnder development
RampD for production metallic fuel with MAFeasibility Stage
Molten Salt chemistry of Am and Cm for fluoridesUnder preparation
Partitioning of MAREE in molten chloridesfluorides liquid cathodesreductive extractionOxide precipitation
Official Investment Frames forRussian Nuclear Renaissance
Federal Tasks Program ldquoDevelopment of Nuclear Power Complex of Russia on a period of 2007 - 2015 ldquo - accepted in 2006
- NPP construction
Federal Tasks Program ldquoNuclear and Radiation Safetyrdquo (2008-2015) - accepted in 2007
- RAW Heritage
Federal Tasks Program ldquoNew Generation Nuclear Energy Technologiesrdquo (2010-2020) ndash on a final preparation Stage
- Innovations
Federal Tasks Program ldquoNew Generation Nuclear Energy Technologiesrdquo
RIAR planned participation
bull Multi-functional Fast Research Reactor (MFRR) - 2016bull Large Multi-Purpose Pyrochemical Reprocessing Complex -
2015Molten salt Reprocessing Facility
capacity ndash up to 2 500 kg of SNF per Year (fuel type oxide nitride metallic IMF)
Fluoride volatility Reprocessing Facility capacity ndash up to 500 kg of SNF per Year (mainly ndash LWR SNF)
bull New Lab for Experimental and Innovative Fuel Production ndash2010-1012 (incl Fuel and Targets with MA)
bull Demonstration of Closing Fuel Cycle based on Pyrochemical technologies -2016-2020- on a levels
Up to 50 spent FAs of BN-600800Full scale CFC for MFRR from initial fuel loading Other experimental implementations
Characteristic Value
Maximum flux Фmax ncm2middotsec ~ 60middot1015
Thermal power MWth ~ 150
Electric power MWe ~ 50
Number of independent experimental loops (~1 MWth sodium heavy metal and gas coolant + salt coolants)
3 (+1 behind reactor vessel)
Driven Fuel Vi-pack MOX (PuN+UN)
Core height mm 400-500
Maximum heat rate kWl 1100
Fuel Cycle Full Scale Closed FC based on Pyro Processes
Test Fuel Innovative FuelsMA Fuels and targets
Maximum fluence in one year ncm2 ~ 12middot1023 (up to 55dpa)
Design lifetime 50 year
RR creation time (no more than years) 9 (2008 ndash 2016)
New Russian Sodium Fast Research Reactor ndashMulti-functional Fast Research Reactor (MFRR)
Location ndash RIAR site
Start of BN Closed fuel Cycle based on RIAR technologies
2011 - start of vi-pack MOX-fuel production for BN-8002012 ndash start of BN-800 operation2016hellip2018 ndash demonstration of BN-800 closed fuel cycle technologies
Key final official decisionsMOX-fuel production by pyroelectrochemistry andvibropackingTrend to closing of fuel cycle by compact drytechnologiesDevelopment and testing of new fuel and newtechnologies
RIAR RampD International cooperation in the field of advanced FC
Fuel production Repro-cessing
PampT Other Cladding materials
ConceptStudies
Funda-mental StudiesMOX other
France - MA oxide
- AmCm recovery
Pyro + FS Cm
INPRO - - - - - - CPP RUS-2
-
Japan MOX vibro
- MOX MAREEsepar Fluorex
MoO42-
ODS FS MA
Korea - - Metalliz vibro-DUPIC
MAREEsepar
Pyro - - -
US TRU fuel
UREX+1
TRU fuel
- - - Pu in RTILrsquos
EU - MA nitride
- - MSR fuel - - Cm
Red color ndash DOVITA-12 activities
- The RIAR DOVITA-12 PampT Program ndash Current Results of the 15-year RampD activities
- Experience in Closed Fuel Cycle including pyrochemical processes
- Since 1992 RIAR has been performing own RampD DOVITA Program
- Experience in adding of minor actinidesin fuel compositions and results of irradiation
- Slide Number 5
- New times considerationDOVITADOVITA-2
- DOVITA-2
- Research area of pyrochemical and non-aqueous MAFP partitioning in frame DOVITA-2 Program
- Slide Number 9
- Slide Number 10
- Slide Number 11
- Slide Number 12
- Slide Number 13
- Slide Number 14
- Slide Number 15
- Slide Number 16
- Slide Number 17
- Official Investment Frames for Russian Nuclear Renaissance
- Federal Tasks Program ldquoNew Generation Nuclear Energy Technologiesrdquo RIAR planned participation
- Slide Number 20
- Start of BN Closed fuel Cycle based on RIAR technologies
- RIAR RampD International cooperation in the field of advanced FC
-
Experience in Closed Fuel Cycle including pyrochemical processes
Research Institute on Atomic reactors ndash RIAR (Dimitrovgrad) is most Russian RampD center of non-aqueous methods developmentPyrochemical investigation - from early 1960-sDemonstration of fluoride volatility reprocessing technology ndash 1970sDemonstration facility for pyrochemical MOX-fuel production for fast reactor ndash from late 1970-sPyroelectrochemical reprocessing experience ndash 1990-2003Preparation for industrial application ndash from 1990-sStudy on transmutation cycle nitride fuel and other applications ndashfrom 1990s
Dry technologies for MA fuel reprocessing andpreparationOxide fuel application as the most widely studied oneVibropacking automated technology of the fuel pinproductionIntegrated disposition of fuel reprocessing and fuelelement refabrication facilities on the same site with thereactorTA The whole complex of approaches will permit acreation of the compact plant for Transmutation ofActinides
Since 1992 RIAR has been performing own RampD DOVITA Program
Experience in adding of minor actinidesin fuel compositions and results of irradiation
Irradiated(UNp)O2 fuel19 burn-up
Pyrochemical technology of adding Np into oxide fuel(5-20) has been developed
Performance of vi-pack fuel with (UNp)O2 fuel hasbeen validated experimentally to ~20 burnup inBOR-60
No evidence of significant difference in performanceof fuel rods with (UNp)O2 fuel compared with UO2 orMOX fuel rods has been noticed
Pyrochemical process of codeposition of Am withMOX fuel (2-4) has been developed
Methods of AmREE separation in melts has beentested
Special vi-pack targets containing Am oxide withUO2 or inert matrix have been developed
Transmutation of Np Am Cm is being studied inBOR-60
New times considerationDOVITA DOVITA-2
1992Dry technologiesOxide fuel with MAVi-packIntegrated disposition same site with the reactorTA Transmutation of Actinides
2006-2008Dry technologiesOn-site reprocessingVarious type of fuel with MAIntegration of MA recycling into FR Closed Fuel Cycle TA - Transmutation of Actinides
DOVITA-2
Fuel type Stages
Oxide vi-pack
Oxide pellet
Nitride pellet vi-pack
Metal Molten salt
Concept Studies
+ + + +- +
RampD + -+ +- - +
Fuel Production
+ - - - -
Irradiation Testing
+ - - - -
PIE + - - - ----
Reprocessing -+ - -+ - +-DOVITA-1
Research area of pyrochemical and non-aqueous MAFP partitioning in frame DOVITA-2 Program
Meltsmedia
Electrochemical methods Oxides Precipi-tation
Metalli-zation
Liquid cathodes
Solid cathodes
Anodic dissol-n
EChem oxide titration
Chlorides Cd Bi Ga Al
Al + + + +Fluorides Bi Ga Al
Pb - + + + -Cl- F- Cd Bi Ga
Al PbAl + + + -
Molibdates - + - - + -RTIL Ga Zn Cu Ni
Al hellip + - - -+ Methods of Volatility of Fluorides and or Chlorides
ISTC Project 3261 (2006-2008)
Study of Cm thermodynamicsin molten chloridesObjectives
Reactions of formation for oxygen Cm compounds- equilibrium constants for reactions of Cm oxygen compoundsformation versus temperature- equilibrium constants for reactions of Cm oxygen compoundsformation versus the inverse effective radius of solvent cathion
1st Year is completed
Reactions of formation for oxygen-free Cm compounds- standard potential for redox pair versus temperature- standard potential for redox pair versus the inverse effective radius of solvent cathion
Simulation of Cm behavior in molten chloridesPourbaix diagrams
Collaborators ndash ITU CIEMAT CEA KTH
Recent RIAR activities in frame of DOVITA-2 Program
Gas supply tube
Sluice
Oxygen sensor
Salt
Thermocouple
Reference electrode AgAg+
Oxygen pump
Potentiometric titration of CmCl3
ISTC project 3261 Current Results
Potentiometric titration of CmCl3
Applied methodsbull main - titration by BaO
bull combined - in case of absence of Section on preliminary experimental curve for CmO+ formation
titration by current through the electric circuit ldquooxygen pumprdquo ndash ldquocounter electroderdquo and then by BaO
ISTC project 3261 Current Results
Oxygen pump after experiment
Cm dioxide deposit
Oxygen pumpZrO2(Sc2O3)Pt(O2)
Reference electrodePyrexSalt+AgCl(075molkg)AgPt(Ar)
Oxygen sensorZrO2(Y2O3)Pt(O2)
Counter electrodePyrexSalt C
ISTC project 3261 Current Results
Conditions of experiments
Salt Amount of Runs
Temperature rangeoC
Range of Cm content in melt
molekgNaCl-2CsCl 11 550-750 (11-14)10-3
3LiCl-2KCl 7 450-650 (19-79)10-3
NaCl-KCl 3 750-850 (50-69)10-3
ISTC project 3261 Current Results
Salt ingot with CmCl3
NaCl-2CsCl+CmCl3(14middot10-2molekg) LiCl-KCl+CmCl3(55middot10-3molekg)
NaCl-KCl + CmCl3(50middot10-3molekg)
ISTC project 3261 Current Results
Experimental constants of CmO+ CmOCl and Cm2O3 dissociation in molten chlorides at different temperatures molality scale
Melt T oC pK(CmO+) pK(CmOCl) pK(Cm2O3)
NaCl-2CsCl 556 42+02 79+02 201+03
650 34+02 75+02 185+03
750 37+02 67+02 168+03
3LiCl-2KCl 450 25+02 62+02 155+05
550 24+02 57+02 127+05
650 083+01 52+02 125+05
NaCl-KCl 750 26+02 59+02 129+04
800 24+02 58+02 126+04
850 13+01 56+02 121+04
ISTC project 3261 Current Results
Comparison with literature data on other actinidesDependence of dissociation constant for actinides upon temperature in LiCl-KCl
0
5
10
15
20
25
1 11 12 13 14
1000T 1000K
pK m
olal
ity sc
ale
CmO+(RIAR)
CmOCl (RIAR)
Cm2O3(RIAR)
AmO+[Lambertin]
AmOCl Lambertin]
Am2O3 [Lambertin]
Pu2O3 [Martinot]
Pu2O3 [Picard]
PuOCl [Picard]
ISTC project 3261 Current Results
Recent RIAR activities in frame of DOVITA-2 Program
RampD for production of vi-pack oxide Fuel with MAUnder continuation
RampD for production of vi-pack nitride Fuel with MAUnder development
RampD for production oxide pellet fuel with MAUnder development
RampD for production metallic fuel with MAFeasibility Stage
Molten Salt chemistry of Am and Cm for fluoridesUnder preparation
Partitioning of MAREE in molten chloridesfluorides liquid cathodesreductive extractionOxide precipitation
Official Investment Frames forRussian Nuclear Renaissance
Federal Tasks Program ldquoDevelopment of Nuclear Power Complex of Russia on a period of 2007 - 2015 ldquo - accepted in 2006
- NPP construction
Federal Tasks Program ldquoNuclear and Radiation Safetyrdquo (2008-2015) - accepted in 2007
- RAW Heritage
Federal Tasks Program ldquoNew Generation Nuclear Energy Technologiesrdquo (2010-2020) ndash on a final preparation Stage
- Innovations
Federal Tasks Program ldquoNew Generation Nuclear Energy Technologiesrdquo
RIAR planned participation
bull Multi-functional Fast Research Reactor (MFRR) - 2016bull Large Multi-Purpose Pyrochemical Reprocessing Complex -
2015Molten salt Reprocessing Facility
capacity ndash up to 2 500 kg of SNF per Year (fuel type oxide nitride metallic IMF)
Fluoride volatility Reprocessing Facility capacity ndash up to 500 kg of SNF per Year (mainly ndash LWR SNF)
bull New Lab for Experimental and Innovative Fuel Production ndash2010-1012 (incl Fuel and Targets with MA)
bull Demonstration of Closing Fuel Cycle based on Pyrochemical technologies -2016-2020- on a levels
Up to 50 spent FAs of BN-600800Full scale CFC for MFRR from initial fuel loading Other experimental implementations
Characteristic Value
Maximum flux Фmax ncm2middotsec ~ 60middot1015
Thermal power MWth ~ 150
Electric power MWe ~ 50
Number of independent experimental loops (~1 MWth sodium heavy metal and gas coolant + salt coolants)
3 (+1 behind reactor vessel)
Driven Fuel Vi-pack MOX (PuN+UN)
Core height mm 400-500
Maximum heat rate kWl 1100
Fuel Cycle Full Scale Closed FC based on Pyro Processes
Test Fuel Innovative FuelsMA Fuels and targets
Maximum fluence in one year ncm2 ~ 12middot1023 (up to 55dpa)
Design lifetime 50 year
RR creation time (no more than years) 9 (2008 ndash 2016)
New Russian Sodium Fast Research Reactor ndashMulti-functional Fast Research Reactor (MFRR)
Location ndash RIAR site
Start of BN Closed fuel Cycle based on RIAR technologies
2011 - start of vi-pack MOX-fuel production for BN-8002012 ndash start of BN-800 operation2016hellip2018 ndash demonstration of BN-800 closed fuel cycle technologies
Key final official decisionsMOX-fuel production by pyroelectrochemistry andvibropackingTrend to closing of fuel cycle by compact drytechnologiesDevelopment and testing of new fuel and newtechnologies
RIAR RampD International cooperation in the field of advanced FC
Fuel production Repro-cessing
PampT Other Cladding materials
ConceptStudies
Funda-mental StudiesMOX other
France - MA oxide
- AmCm recovery
Pyro + FS Cm
INPRO - - - - - - CPP RUS-2
-
Japan MOX vibro
- MOX MAREEsepar Fluorex
MoO42-
ODS FS MA
Korea - - Metalliz vibro-DUPIC
MAREEsepar
Pyro - - -
US TRU fuel
UREX+1
TRU fuel
- - - Pu in RTILrsquos
EU - MA nitride
- - MSR fuel - - Cm
Red color ndash DOVITA-12 activities
- The RIAR DOVITA-12 PampT Program ndash Current Results of the 15-year RampD activities
- Experience in Closed Fuel Cycle including pyrochemical processes
- Since 1992 RIAR has been performing own RampD DOVITA Program
- Experience in adding of minor actinidesin fuel compositions and results of irradiation
- Slide Number 5
- New times considerationDOVITADOVITA-2
- DOVITA-2
- Research area of pyrochemical and non-aqueous MAFP partitioning in frame DOVITA-2 Program
- Slide Number 9
- Slide Number 10
- Slide Number 11
- Slide Number 12
- Slide Number 13
- Slide Number 14
- Slide Number 15
- Slide Number 16
- Slide Number 17
- Official Investment Frames for Russian Nuclear Renaissance
- Federal Tasks Program ldquoNew Generation Nuclear Energy Technologiesrdquo RIAR planned participation
- Slide Number 20
- Start of BN Closed fuel Cycle based on RIAR technologies
- RIAR RampD International cooperation in the field of advanced FC
-
Dry technologies for MA fuel reprocessing andpreparationOxide fuel application as the most widely studied oneVibropacking automated technology of the fuel pinproductionIntegrated disposition of fuel reprocessing and fuelelement refabrication facilities on the same site with thereactorTA The whole complex of approaches will permit acreation of the compact plant for Transmutation ofActinides
Since 1992 RIAR has been performing own RampD DOVITA Program
Experience in adding of minor actinidesin fuel compositions and results of irradiation
Irradiated(UNp)O2 fuel19 burn-up
Pyrochemical technology of adding Np into oxide fuel(5-20) has been developed
Performance of vi-pack fuel with (UNp)O2 fuel hasbeen validated experimentally to ~20 burnup inBOR-60
No evidence of significant difference in performanceof fuel rods with (UNp)O2 fuel compared with UO2 orMOX fuel rods has been noticed
Pyrochemical process of codeposition of Am withMOX fuel (2-4) has been developed
Methods of AmREE separation in melts has beentested
Special vi-pack targets containing Am oxide withUO2 or inert matrix have been developed
Transmutation of Np Am Cm is being studied inBOR-60
New times considerationDOVITA DOVITA-2
1992Dry technologiesOxide fuel with MAVi-packIntegrated disposition same site with the reactorTA Transmutation of Actinides
2006-2008Dry technologiesOn-site reprocessingVarious type of fuel with MAIntegration of MA recycling into FR Closed Fuel Cycle TA - Transmutation of Actinides
DOVITA-2
Fuel type Stages
Oxide vi-pack
Oxide pellet
Nitride pellet vi-pack
Metal Molten salt
Concept Studies
+ + + +- +
RampD + -+ +- - +
Fuel Production
+ - - - -
Irradiation Testing
+ - - - -
PIE + - - - ----
Reprocessing -+ - -+ - +-DOVITA-1
Research area of pyrochemical and non-aqueous MAFP partitioning in frame DOVITA-2 Program
Meltsmedia
Electrochemical methods Oxides Precipi-tation
Metalli-zation
Liquid cathodes
Solid cathodes
Anodic dissol-n
EChem oxide titration
Chlorides Cd Bi Ga Al
Al + + + +Fluorides Bi Ga Al
Pb - + + + -Cl- F- Cd Bi Ga
Al PbAl + + + -
Molibdates - + - - + -RTIL Ga Zn Cu Ni
Al hellip + - - -+ Methods of Volatility of Fluorides and or Chlorides
ISTC Project 3261 (2006-2008)
Study of Cm thermodynamicsin molten chloridesObjectives
Reactions of formation for oxygen Cm compounds- equilibrium constants for reactions of Cm oxygen compoundsformation versus temperature- equilibrium constants for reactions of Cm oxygen compoundsformation versus the inverse effective radius of solvent cathion
1st Year is completed
Reactions of formation for oxygen-free Cm compounds- standard potential for redox pair versus temperature- standard potential for redox pair versus the inverse effective radius of solvent cathion
Simulation of Cm behavior in molten chloridesPourbaix diagrams
Collaborators ndash ITU CIEMAT CEA KTH
Recent RIAR activities in frame of DOVITA-2 Program
Gas supply tube
Sluice
Oxygen sensor
Salt
Thermocouple
Reference electrode AgAg+
Oxygen pump
Potentiometric titration of CmCl3
ISTC project 3261 Current Results
Potentiometric titration of CmCl3
Applied methodsbull main - titration by BaO
bull combined - in case of absence of Section on preliminary experimental curve for CmO+ formation
titration by current through the electric circuit ldquooxygen pumprdquo ndash ldquocounter electroderdquo and then by BaO
ISTC project 3261 Current Results
Oxygen pump after experiment
Cm dioxide deposit
Oxygen pumpZrO2(Sc2O3)Pt(O2)
Reference electrodePyrexSalt+AgCl(075molkg)AgPt(Ar)
Oxygen sensorZrO2(Y2O3)Pt(O2)
Counter electrodePyrexSalt C
ISTC project 3261 Current Results
Conditions of experiments
Salt Amount of Runs
Temperature rangeoC
Range of Cm content in melt
molekgNaCl-2CsCl 11 550-750 (11-14)10-3
3LiCl-2KCl 7 450-650 (19-79)10-3
NaCl-KCl 3 750-850 (50-69)10-3
ISTC project 3261 Current Results
Salt ingot with CmCl3
NaCl-2CsCl+CmCl3(14middot10-2molekg) LiCl-KCl+CmCl3(55middot10-3molekg)
NaCl-KCl + CmCl3(50middot10-3molekg)
ISTC project 3261 Current Results
Experimental constants of CmO+ CmOCl and Cm2O3 dissociation in molten chlorides at different temperatures molality scale
Melt T oC pK(CmO+) pK(CmOCl) pK(Cm2O3)
NaCl-2CsCl 556 42+02 79+02 201+03
650 34+02 75+02 185+03
750 37+02 67+02 168+03
3LiCl-2KCl 450 25+02 62+02 155+05
550 24+02 57+02 127+05
650 083+01 52+02 125+05
NaCl-KCl 750 26+02 59+02 129+04
800 24+02 58+02 126+04
850 13+01 56+02 121+04
ISTC project 3261 Current Results
Comparison with literature data on other actinidesDependence of dissociation constant for actinides upon temperature in LiCl-KCl
0
5
10
15
20
25
1 11 12 13 14
1000T 1000K
pK m
olal
ity sc
ale
CmO+(RIAR)
CmOCl (RIAR)
Cm2O3(RIAR)
AmO+[Lambertin]
AmOCl Lambertin]
Am2O3 [Lambertin]
Pu2O3 [Martinot]
Pu2O3 [Picard]
PuOCl [Picard]
ISTC project 3261 Current Results
Recent RIAR activities in frame of DOVITA-2 Program
RampD for production of vi-pack oxide Fuel with MAUnder continuation
RampD for production of vi-pack nitride Fuel with MAUnder development
RampD for production oxide pellet fuel with MAUnder development
RampD for production metallic fuel with MAFeasibility Stage
Molten Salt chemistry of Am and Cm for fluoridesUnder preparation
Partitioning of MAREE in molten chloridesfluorides liquid cathodesreductive extractionOxide precipitation
Official Investment Frames forRussian Nuclear Renaissance
Federal Tasks Program ldquoDevelopment of Nuclear Power Complex of Russia on a period of 2007 - 2015 ldquo - accepted in 2006
- NPP construction
Federal Tasks Program ldquoNuclear and Radiation Safetyrdquo (2008-2015) - accepted in 2007
- RAW Heritage
Federal Tasks Program ldquoNew Generation Nuclear Energy Technologiesrdquo (2010-2020) ndash on a final preparation Stage
- Innovations
Federal Tasks Program ldquoNew Generation Nuclear Energy Technologiesrdquo
RIAR planned participation
bull Multi-functional Fast Research Reactor (MFRR) - 2016bull Large Multi-Purpose Pyrochemical Reprocessing Complex -
2015Molten salt Reprocessing Facility
capacity ndash up to 2 500 kg of SNF per Year (fuel type oxide nitride metallic IMF)
Fluoride volatility Reprocessing Facility capacity ndash up to 500 kg of SNF per Year (mainly ndash LWR SNF)
bull New Lab for Experimental and Innovative Fuel Production ndash2010-1012 (incl Fuel and Targets with MA)
bull Demonstration of Closing Fuel Cycle based on Pyrochemical technologies -2016-2020- on a levels
Up to 50 spent FAs of BN-600800Full scale CFC for MFRR from initial fuel loading Other experimental implementations
Characteristic Value
Maximum flux Фmax ncm2middotsec ~ 60middot1015
Thermal power MWth ~ 150
Electric power MWe ~ 50
Number of independent experimental loops (~1 MWth sodium heavy metal and gas coolant + salt coolants)
3 (+1 behind reactor vessel)
Driven Fuel Vi-pack MOX (PuN+UN)
Core height mm 400-500
Maximum heat rate kWl 1100
Fuel Cycle Full Scale Closed FC based on Pyro Processes
Test Fuel Innovative FuelsMA Fuels and targets
Maximum fluence in one year ncm2 ~ 12middot1023 (up to 55dpa)
Design lifetime 50 year
RR creation time (no more than years) 9 (2008 ndash 2016)
New Russian Sodium Fast Research Reactor ndashMulti-functional Fast Research Reactor (MFRR)
Location ndash RIAR site
Start of BN Closed fuel Cycle based on RIAR technologies
2011 - start of vi-pack MOX-fuel production for BN-8002012 ndash start of BN-800 operation2016hellip2018 ndash demonstration of BN-800 closed fuel cycle technologies
Key final official decisionsMOX-fuel production by pyroelectrochemistry andvibropackingTrend to closing of fuel cycle by compact drytechnologiesDevelopment and testing of new fuel and newtechnologies
RIAR RampD International cooperation in the field of advanced FC
Fuel production Repro-cessing
PampT Other Cladding materials
ConceptStudies
Funda-mental StudiesMOX other
France - MA oxide
- AmCm recovery
Pyro + FS Cm
INPRO - - - - - - CPP RUS-2
-
Japan MOX vibro
- MOX MAREEsepar Fluorex
MoO42-
ODS FS MA
Korea - - Metalliz vibro-DUPIC
MAREEsepar
Pyro - - -
US TRU fuel
UREX+1
TRU fuel
- - - Pu in RTILrsquos
EU - MA nitride
- - MSR fuel - - Cm
Red color ndash DOVITA-12 activities
- The RIAR DOVITA-12 PampT Program ndash Current Results of the 15-year RampD activities
- Experience in Closed Fuel Cycle including pyrochemical processes
- Since 1992 RIAR has been performing own RampD DOVITA Program
- Experience in adding of minor actinidesin fuel compositions and results of irradiation
- Slide Number 5
- New times considerationDOVITADOVITA-2
- DOVITA-2
- Research area of pyrochemical and non-aqueous MAFP partitioning in frame DOVITA-2 Program
- Slide Number 9
- Slide Number 10
- Slide Number 11
- Slide Number 12
- Slide Number 13
- Slide Number 14
- Slide Number 15
- Slide Number 16
- Slide Number 17
- Official Investment Frames for Russian Nuclear Renaissance
- Federal Tasks Program ldquoNew Generation Nuclear Energy Technologiesrdquo RIAR planned participation
- Slide Number 20
- Start of BN Closed fuel Cycle based on RIAR technologies
- RIAR RampD International cooperation in the field of advanced FC
-
Experience in adding of minor actinidesin fuel compositions and results of irradiation
Irradiated(UNp)O2 fuel19 burn-up
Pyrochemical technology of adding Np into oxide fuel(5-20) has been developed
Performance of vi-pack fuel with (UNp)O2 fuel hasbeen validated experimentally to ~20 burnup inBOR-60
No evidence of significant difference in performanceof fuel rods with (UNp)O2 fuel compared with UO2 orMOX fuel rods has been noticed
Pyrochemical process of codeposition of Am withMOX fuel (2-4) has been developed
Methods of AmREE separation in melts has beentested
Special vi-pack targets containing Am oxide withUO2 or inert matrix have been developed
Transmutation of Np Am Cm is being studied inBOR-60
New times considerationDOVITA DOVITA-2
1992Dry technologiesOxide fuel with MAVi-packIntegrated disposition same site with the reactorTA Transmutation of Actinides
2006-2008Dry technologiesOn-site reprocessingVarious type of fuel with MAIntegration of MA recycling into FR Closed Fuel Cycle TA - Transmutation of Actinides
DOVITA-2
Fuel type Stages
Oxide vi-pack
Oxide pellet
Nitride pellet vi-pack
Metal Molten salt
Concept Studies
+ + + +- +
RampD + -+ +- - +
Fuel Production
+ - - - -
Irradiation Testing
+ - - - -
PIE + - - - ----
Reprocessing -+ - -+ - +-DOVITA-1
Research area of pyrochemical and non-aqueous MAFP partitioning in frame DOVITA-2 Program
Meltsmedia
Electrochemical methods Oxides Precipi-tation
Metalli-zation
Liquid cathodes
Solid cathodes
Anodic dissol-n
EChem oxide titration
Chlorides Cd Bi Ga Al
Al + + + +Fluorides Bi Ga Al
Pb - + + + -Cl- F- Cd Bi Ga
Al PbAl + + + -
Molibdates - + - - + -RTIL Ga Zn Cu Ni
Al hellip + - - -+ Methods of Volatility of Fluorides and or Chlorides
ISTC Project 3261 (2006-2008)
Study of Cm thermodynamicsin molten chloridesObjectives
Reactions of formation for oxygen Cm compounds- equilibrium constants for reactions of Cm oxygen compoundsformation versus temperature- equilibrium constants for reactions of Cm oxygen compoundsformation versus the inverse effective radius of solvent cathion
1st Year is completed
Reactions of formation for oxygen-free Cm compounds- standard potential for redox pair versus temperature- standard potential for redox pair versus the inverse effective radius of solvent cathion
Simulation of Cm behavior in molten chloridesPourbaix diagrams
Collaborators ndash ITU CIEMAT CEA KTH
Recent RIAR activities in frame of DOVITA-2 Program
Gas supply tube
Sluice
Oxygen sensor
Salt
Thermocouple
Reference electrode AgAg+
Oxygen pump
Potentiometric titration of CmCl3
ISTC project 3261 Current Results
Potentiometric titration of CmCl3
Applied methodsbull main - titration by BaO
bull combined - in case of absence of Section on preliminary experimental curve for CmO+ formation
titration by current through the electric circuit ldquooxygen pumprdquo ndash ldquocounter electroderdquo and then by BaO
ISTC project 3261 Current Results
Oxygen pump after experiment
Cm dioxide deposit
Oxygen pumpZrO2(Sc2O3)Pt(O2)
Reference electrodePyrexSalt+AgCl(075molkg)AgPt(Ar)
Oxygen sensorZrO2(Y2O3)Pt(O2)
Counter electrodePyrexSalt C
ISTC project 3261 Current Results
Conditions of experiments
Salt Amount of Runs
Temperature rangeoC
Range of Cm content in melt
molekgNaCl-2CsCl 11 550-750 (11-14)10-3
3LiCl-2KCl 7 450-650 (19-79)10-3
NaCl-KCl 3 750-850 (50-69)10-3
ISTC project 3261 Current Results
Salt ingot with CmCl3
NaCl-2CsCl+CmCl3(14middot10-2molekg) LiCl-KCl+CmCl3(55middot10-3molekg)
NaCl-KCl + CmCl3(50middot10-3molekg)
ISTC project 3261 Current Results
Experimental constants of CmO+ CmOCl and Cm2O3 dissociation in molten chlorides at different temperatures molality scale
Melt T oC pK(CmO+) pK(CmOCl) pK(Cm2O3)
NaCl-2CsCl 556 42+02 79+02 201+03
650 34+02 75+02 185+03
750 37+02 67+02 168+03
3LiCl-2KCl 450 25+02 62+02 155+05
550 24+02 57+02 127+05
650 083+01 52+02 125+05
NaCl-KCl 750 26+02 59+02 129+04
800 24+02 58+02 126+04
850 13+01 56+02 121+04
ISTC project 3261 Current Results
Comparison with literature data on other actinidesDependence of dissociation constant for actinides upon temperature in LiCl-KCl
0
5
10
15
20
25
1 11 12 13 14
1000T 1000K
pK m
olal
ity sc
ale
CmO+(RIAR)
CmOCl (RIAR)
Cm2O3(RIAR)
AmO+[Lambertin]
AmOCl Lambertin]
Am2O3 [Lambertin]
Pu2O3 [Martinot]
Pu2O3 [Picard]
PuOCl [Picard]
ISTC project 3261 Current Results
Recent RIAR activities in frame of DOVITA-2 Program
RampD for production of vi-pack oxide Fuel with MAUnder continuation
RampD for production of vi-pack nitride Fuel with MAUnder development
RampD for production oxide pellet fuel with MAUnder development
RampD for production metallic fuel with MAFeasibility Stage
Molten Salt chemistry of Am and Cm for fluoridesUnder preparation
Partitioning of MAREE in molten chloridesfluorides liquid cathodesreductive extractionOxide precipitation
Official Investment Frames forRussian Nuclear Renaissance
Federal Tasks Program ldquoDevelopment of Nuclear Power Complex of Russia on a period of 2007 - 2015 ldquo - accepted in 2006
- NPP construction
Federal Tasks Program ldquoNuclear and Radiation Safetyrdquo (2008-2015) - accepted in 2007
- RAW Heritage
Federal Tasks Program ldquoNew Generation Nuclear Energy Technologiesrdquo (2010-2020) ndash on a final preparation Stage
- Innovations
Federal Tasks Program ldquoNew Generation Nuclear Energy Technologiesrdquo
RIAR planned participation
bull Multi-functional Fast Research Reactor (MFRR) - 2016bull Large Multi-Purpose Pyrochemical Reprocessing Complex -
2015Molten salt Reprocessing Facility
capacity ndash up to 2 500 kg of SNF per Year (fuel type oxide nitride metallic IMF)
Fluoride volatility Reprocessing Facility capacity ndash up to 500 kg of SNF per Year (mainly ndash LWR SNF)
bull New Lab for Experimental and Innovative Fuel Production ndash2010-1012 (incl Fuel and Targets with MA)
bull Demonstration of Closing Fuel Cycle based on Pyrochemical technologies -2016-2020- on a levels
Up to 50 spent FAs of BN-600800Full scale CFC for MFRR from initial fuel loading Other experimental implementations
Characteristic Value
Maximum flux Фmax ncm2middotsec ~ 60middot1015
Thermal power MWth ~ 150
Electric power MWe ~ 50
Number of independent experimental loops (~1 MWth sodium heavy metal and gas coolant + salt coolants)
3 (+1 behind reactor vessel)
Driven Fuel Vi-pack MOX (PuN+UN)
Core height mm 400-500
Maximum heat rate kWl 1100
Fuel Cycle Full Scale Closed FC based on Pyro Processes
Test Fuel Innovative FuelsMA Fuels and targets
Maximum fluence in one year ncm2 ~ 12middot1023 (up to 55dpa)
Design lifetime 50 year
RR creation time (no more than years) 9 (2008 ndash 2016)
New Russian Sodium Fast Research Reactor ndashMulti-functional Fast Research Reactor (MFRR)
Location ndash RIAR site
Start of BN Closed fuel Cycle based on RIAR technologies
2011 - start of vi-pack MOX-fuel production for BN-8002012 ndash start of BN-800 operation2016hellip2018 ndash demonstration of BN-800 closed fuel cycle technologies
Key final official decisionsMOX-fuel production by pyroelectrochemistry andvibropackingTrend to closing of fuel cycle by compact drytechnologiesDevelopment and testing of new fuel and newtechnologies
RIAR RampD International cooperation in the field of advanced FC
Fuel production Repro-cessing
PampT Other Cladding materials
ConceptStudies
Funda-mental StudiesMOX other
France - MA oxide
- AmCm recovery
Pyro + FS Cm
INPRO - - - - - - CPP RUS-2
-
Japan MOX vibro
- MOX MAREEsepar Fluorex
MoO42-
ODS FS MA
Korea - - Metalliz vibro-DUPIC
MAREEsepar
Pyro - - -
US TRU fuel
UREX+1
TRU fuel
- - - Pu in RTILrsquos
EU - MA nitride
- - MSR fuel - - Cm
Red color ndash DOVITA-12 activities
- The RIAR DOVITA-12 PampT Program ndash Current Results of the 15-year RampD activities
- Experience in Closed Fuel Cycle including pyrochemical processes
- Since 1992 RIAR has been performing own RampD DOVITA Program
- Experience in adding of minor actinidesin fuel compositions and results of irradiation
- Slide Number 5
- New times considerationDOVITADOVITA-2
- DOVITA-2
- Research area of pyrochemical and non-aqueous MAFP partitioning in frame DOVITA-2 Program
- Slide Number 9
- Slide Number 10
- Slide Number 11
- Slide Number 12
- Slide Number 13
- Slide Number 14
- Slide Number 15
- Slide Number 16
- Slide Number 17
- Official Investment Frames for Russian Nuclear Renaissance
- Federal Tasks Program ldquoNew Generation Nuclear Energy Technologiesrdquo RIAR planned participation
- Slide Number 20
- Start of BN Closed fuel Cycle based on RIAR technologies
- RIAR RampD International cooperation in the field of advanced FC
-
New times considerationDOVITA DOVITA-2
1992Dry technologiesOxide fuel with MAVi-packIntegrated disposition same site with the reactorTA Transmutation of Actinides
2006-2008Dry technologiesOn-site reprocessingVarious type of fuel with MAIntegration of MA recycling into FR Closed Fuel Cycle TA - Transmutation of Actinides
DOVITA-2
Fuel type Stages
Oxide vi-pack
Oxide pellet
Nitride pellet vi-pack
Metal Molten salt
Concept Studies
+ + + +- +
RampD + -+ +- - +
Fuel Production
+ - - - -
Irradiation Testing
+ - - - -
PIE + - - - ----
Reprocessing -+ - -+ - +-DOVITA-1
Research area of pyrochemical and non-aqueous MAFP partitioning in frame DOVITA-2 Program
Meltsmedia
Electrochemical methods Oxides Precipi-tation
Metalli-zation
Liquid cathodes
Solid cathodes
Anodic dissol-n
EChem oxide titration
Chlorides Cd Bi Ga Al
Al + + + +Fluorides Bi Ga Al
Pb - + + + -Cl- F- Cd Bi Ga
Al PbAl + + + -
Molibdates - + - - + -RTIL Ga Zn Cu Ni
Al hellip + - - -+ Methods of Volatility of Fluorides and or Chlorides
ISTC Project 3261 (2006-2008)
Study of Cm thermodynamicsin molten chloridesObjectives
Reactions of formation for oxygen Cm compounds- equilibrium constants for reactions of Cm oxygen compoundsformation versus temperature- equilibrium constants for reactions of Cm oxygen compoundsformation versus the inverse effective radius of solvent cathion
1st Year is completed
Reactions of formation for oxygen-free Cm compounds- standard potential for redox pair versus temperature- standard potential for redox pair versus the inverse effective radius of solvent cathion
Simulation of Cm behavior in molten chloridesPourbaix diagrams
Collaborators ndash ITU CIEMAT CEA KTH
Recent RIAR activities in frame of DOVITA-2 Program
Gas supply tube
Sluice
Oxygen sensor
Salt
Thermocouple
Reference electrode AgAg+
Oxygen pump
Potentiometric titration of CmCl3
ISTC project 3261 Current Results
Potentiometric titration of CmCl3
Applied methodsbull main - titration by BaO
bull combined - in case of absence of Section on preliminary experimental curve for CmO+ formation
titration by current through the electric circuit ldquooxygen pumprdquo ndash ldquocounter electroderdquo and then by BaO
ISTC project 3261 Current Results
Oxygen pump after experiment
Cm dioxide deposit
Oxygen pumpZrO2(Sc2O3)Pt(O2)
Reference electrodePyrexSalt+AgCl(075molkg)AgPt(Ar)
Oxygen sensorZrO2(Y2O3)Pt(O2)
Counter electrodePyrexSalt C
ISTC project 3261 Current Results
Conditions of experiments
Salt Amount of Runs
Temperature rangeoC
Range of Cm content in melt
molekgNaCl-2CsCl 11 550-750 (11-14)10-3
3LiCl-2KCl 7 450-650 (19-79)10-3
NaCl-KCl 3 750-850 (50-69)10-3
ISTC project 3261 Current Results
Salt ingot with CmCl3
NaCl-2CsCl+CmCl3(14middot10-2molekg) LiCl-KCl+CmCl3(55middot10-3molekg)
NaCl-KCl + CmCl3(50middot10-3molekg)
ISTC project 3261 Current Results
Experimental constants of CmO+ CmOCl and Cm2O3 dissociation in molten chlorides at different temperatures molality scale
Melt T oC pK(CmO+) pK(CmOCl) pK(Cm2O3)
NaCl-2CsCl 556 42+02 79+02 201+03
650 34+02 75+02 185+03
750 37+02 67+02 168+03
3LiCl-2KCl 450 25+02 62+02 155+05
550 24+02 57+02 127+05
650 083+01 52+02 125+05
NaCl-KCl 750 26+02 59+02 129+04
800 24+02 58+02 126+04
850 13+01 56+02 121+04
ISTC project 3261 Current Results
Comparison with literature data on other actinidesDependence of dissociation constant for actinides upon temperature in LiCl-KCl
0
5
10
15
20
25
1 11 12 13 14
1000T 1000K
pK m
olal
ity sc
ale
CmO+(RIAR)
CmOCl (RIAR)
Cm2O3(RIAR)
AmO+[Lambertin]
AmOCl Lambertin]
Am2O3 [Lambertin]
Pu2O3 [Martinot]
Pu2O3 [Picard]
PuOCl [Picard]
ISTC project 3261 Current Results
Recent RIAR activities in frame of DOVITA-2 Program
RampD for production of vi-pack oxide Fuel with MAUnder continuation
RampD for production of vi-pack nitride Fuel with MAUnder development
RampD for production oxide pellet fuel with MAUnder development
RampD for production metallic fuel with MAFeasibility Stage
Molten Salt chemistry of Am and Cm for fluoridesUnder preparation
Partitioning of MAREE in molten chloridesfluorides liquid cathodesreductive extractionOxide precipitation
Official Investment Frames forRussian Nuclear Renaissance
Federal Tasks Program ldquoDevelopment of Nuclear Power Complex of Russia on a period of 2007 - 2015 ldquo - accepted in 2006
- NPP construction
Federal Tasks Program ldquoNuclear and Radiation Safetyrdquo (2008-2015) - accepted in 2007
- RAW Heritage
Federal Tasks Program ldquoNew Generation Nuclear Energy Technologiesrdquo (2010-2020) ndash on a final preparation Stage
- Innovations
Federal Tasks Program ldquoNew Generation Nuclear Energy Technologiesrdquo
RIAR planned participation
bull Multi-functional Fast Research Reactor (MFRR) - 2016bull Large Multi-Purpose Pyrochemical Reprocessing Complex -
2015Molten salt Reprocessing Facility
capacity ndash up to 2 500 kg of SNF per Year (fuel type oxide nitride metallic IMF)
Fluoride volatility Reprocessing Facility capacity ndash up to 500 kg of SNF per Year (mainly ndash LWR SNF)
bull New Lab for Experimental and Innovative Fuel Production ndash2010-1012 (incl Fuel and Targets with MA)
bull Demonstration of Closing Fuel Cycle based on Pyrochemical technologies -2016-2020- on a levels
Up to 50 spent FAs of BN-600800Full scale CFC for MFRR from initial fuel loading Other experimental implementations
Characteristic Value
Maximum flux Фmax ncm2middotsec ~ 60middot1015
Thermal power MWth ~ 150
Electric power MWe ~ 50
Number of independent experimental loops (~1 MWth sodium heavy metal and gas coolant + salt coolants)
3 (+1 behind reactor vessel)
Driven Fuel Vi-pack MOX (PuN+UN)
Core height mm 400-500
Maximum heat rate kWl 1100
Fuel Cycle Full Scale Closed FC based on Pyro Processes
Test Fuel Innovative FuelsMA Fuels and targets
Maximum fluence in one year ncm2 ~ 12middot1023 (up to 55dpa)
Design lifetime 50 year
RR creation time (no more than years) 9 (2008 ndash 2016)
New Russian Sodium Fast Research Reactor ndashMulti-functional Fast Research Reactor (MFRR)
Location ndash RIAR site
Start of BN Closed fuel Cycle based on RIAR technologies
2011 - start of vi-pack MOX-fuel production for BN-8002012 ndash start of BN-800 operation2016hellip2018 ndash demonstration of BN-800 closed fuel cycle technologies
Key final official decisionsMOX-fuel production by pyroelectrochemistry andvibropackingTrend to closing of fuel cycle by compact drytechnologiesDevelopment and testing of new fuel and newtechnologies
RIAR RampD International cooperation in the field of advanced FC
Fuel production Repro-cessing
PampT Other Cladding materials
ConceptStudies
Funda-mental StudiesMOX other
France - MA oxide
- AmCm recovery
Pyro + FS Cm
INPRO - - - - - - CPP RUS-2
-
Japan MOX vibro
- MOX MAREEsepar Fluorex
MoO42-
ODS FS MA
Korea - - Metalliz vibro-DUPIC
MAREEsepar
Pyro - - -
US TRU fuel
UREX+1
TRU fuel
- - - Pu in RTILrsquos
EU - MA nitride
- - MSR fuel - - Cm
Red color ndash DOVITA-12 activities
- The RIAR DOVITA-12 PampT Program ndash Current Results of the 15-year RampD activities
- Experience in Closed Fuel Cycle including pyrochemical processes
- Since 1992 RIAR has been performing own RampD DOVITA Program
- Experience in adding of minor actinidesin fuel compositions and results of irradiation
- Slide Number 5
- New times considerationDOVITADOVITA-2
- DOVITA-2
- Research area of pyrochemical and non-aqueous MAFP partitioning in frame DOVITA-2 Program
- Slide Number 9
- Slide Number 10
- Slide Number 11
- Slide Number 12
- Slide Number 13
- Slide Number 14
- Slide Number 15
- Slide Number 16
- Slide Number 17
- Official Investment Frames for Russian Nuclear Renaissance
- Federal Tasks Program ldquoNew Generation Nuclear Energy Technologiesrdquo RIAR planned participation
- Slide Number 20
- Start of BN Closed fuel Cycle based on RIAR technologies
- RIAR RampD International cooperation in the field of advanced FC
-
DOVITA-2
Fuel type Stages
Oxide vi-pack
Oxide pellet
Nitride pellet vi-pack
Metal Molten salt
Concept Studies
+ + + +- +
RampD + -+ +- - +
Fuel Production
+ - - - -
Irradiation Testing
+ - - - -
PIE + - - - ----
Reprocessing -+ - -+ - +-DOVITA-1
Research area of pyrochemical and non-aqueous MAFP partitioning in frame DOVITA-2 Program
Meltsmedia
Electrochemical methods Oxides Precipi-tation
Metalli-zation
Liquid cathodes
Solid cathodes
Anodic dissol-n
EChem oxide titration
Chlorides Cd Bi Ga Al
Al + + + +Fluorides Bi Ga Al
Pb - + + + -Cl- F- Cd Bi Ga
Al PbAl + + + -
Molibdates - + - - + -RTIL Ga Zn Cu Ni
Al hellip + - - -+ Methods of Volatility of Fluorides and or Chlorides
ISTC Project 3261 (2006-2008)
Study of Cm thermodynamicsin molten chloridesObjectives
Reactions of formation for oxygen Cm compounds- equilibrium constants for reactions of Cm oxygen compoundsformation versus temperature- equilibrium constants for reactions of Cm oxygen compoundsformation versus the inverse effective radius of solvent cathion
1st Year is completed
Reactions of formation for oxygen-free Cm compounds- standard potential for redox pair versus temperature- standard potential for redox pair versus the inverse effective radius of solvent cathion
Simulation of Cm behavior in molten chloridesPourbaix diagrams
Collaborators ndash ITU CIEMAT CEA KTH
Recent RIAR activities in frame of DOVITA-2 Program
Gas supply tube
Sluice
Oxygen sensor
Salt
Thermocouple
Reference electrode AgAg+
Oxygen pump
Potentiometric titration of CmCl3
ISTC project 3261 Current Results
Potentiometric titration of CmCl3
Applied methodsbull main - titration by BaO
bull combined - in case of absence of Section on preliminary experimental curve for CmO+ formation
titration by current through the electric circuit ldquooxygen pumprdquo ndash ldquocounter electroderdquo and then by BaO
ISTC project 3261 Current Results
Oxygen pump after experiment
Cm dioxide deposit
Oxygen pumpZrO2(Sc2O3)Pt(O2)
Reference electrodePyrexSalt+AgCl(075molkg)AgPt(Ar)
Oxygen sensorZrO2(Y2O3)Pt(O2)
Counter electrodePyrexSalt C
ISTC project 3261 Current Results
Conditions of experiments
Salt Amount of Runs
Temperature rangeoC
Range of Cm content in melt
molekgNaCl-2CsCl 11 550-750 (11-14)10-3
3LiCl-2KCl 7 450-650 (19-79)10-3
NaCl-KCl 3 750-850 (50-69)10-3
ISTC project 3261 Current Results
Salt ingot with CmCl3
NaCl-2CsCl+CmCl3(14middot10-2molekg) LiCl-KCl+CmCl3(55middot10-3molekg)
NaCl-KCl + CmCl3(50middot10-3molekg)
ISTC project 3261 Current Results
Experimental constants of CmO+ CmOCl and Cm2O3 dissociation in molten chlorides at different temperatures molality scale
Melt T oC pK(CmO+) pK(CmOCl) pK(Cm2O3)
NaCl-2CsCl 556 42+02 79+02 201+03
650 34+02 75+02 185+03
750 37+02 67+02 168+03
3LiCl-2KCl 450 25+02 62+02 155+05
550 24+02 57+02 127+05
650 083+01 52+02 125+05
NaCl-KCl 750 26+02 59+02 129+04
800 24+02 58+02 126+04
850 13+01 56+02 121+04
ISTC project 3261 Current Results
Comparison with literature data on other actinidesDependence of dissociation constant for actinides upon temperature in LiCl-KCl
0
5
10
15
20
25
1 11 12 13 14
1000T 1000K
pK m
olal
ity sc
ale
CmO+(RIAR)
CmOCl (RIAR)
Cm2O3(RIAR)
AmO+[Lambertin]
AmOCl Lambertin]
Am2O3 [Lambertin]
Pu2O3 [Martinot]
Pu2O3 [Picard]
PuOCl [Picard]
ISTC project 3261 Current Results
Recent RIAR activities in frame of DOVITA-2 Program
RampD for production of vi-pack oxide Fuel with MAUnder continuation
RampD for production of vi-pack nitride Fuel with MAUnder development
RampD for production oxide pellet fuel with MAUnder development
RampD for production metallic fuel with MAFeasibility Stage
Molten Salt chemistry of Am and Cm for fluoridesUnder preparation
Partitioning of MAREE in molten chloridesfluorides liquid cathodesreductive extractionOxide precipitation
Official Investment Frames forRussian Nuclear Renaissance
Federal Tasks Program ldquoDevelopment of Nuclear Power Complex of Russia on a period of 2007 - 2015 ldquo - accepted in 2006
- NPP construction
Federal Tasks Program ldquoNuclear and Radiation Safetyrdquo (2008-2015) - accepted in 2007
- RAW Heritage
Federal Tasks Program ldquoNew Generation Nuclear Energy Technologiesrdquo (2010-2020) ndash on a final preparation Stage
- Innovations
Federal Tasks Program ldquoNew Generation Nuclear Energy Technologiesrdquo
RIAR planned participation
bull Multi-functional Fast Research Reactor (MFRR) - 2016bull Large Multi-Purpose Pyrochemical Reprocessing Complex -
2015Molten salt Reprocessing Facility
capacity ndash up to 2 500 kg of SNF per Year (fuel type oxide nitride metallic IMF)
Fluoride volatility Reprocessing Facility capacity ndash up to 500 kg of SNF per Year (mainly ndash LWR SNF)
bull New Lab for Experimental and Innovative Fuel Production ndash2010-1012 (incl Fuel and Targets with MA)
bull Demonstration of Closing Fuel Cycle based on Pyrochemical technologies -2016-2020- on a levels
Up to 50 spent FAs of BN-600800Full scale CFC for MFRR from initial fuel loading Other experimental implementations
Characteristic Value
Maximum flux Фmax ncm2middotsec ~ 60middot1015
Thermal power MWth ~ 150
Electric power MWe ~ 50
Number of independent experimental loops (~1 MWth sodium heavy metal and gas coolant + salt coolants)
3 (+1 behind reactor vessel)
Driven Fuel Vi-pack MOX (PuN+UN)
Core height mm 400-500
Maximum heat rate kWl 1100
Fuel Cycle Full Scale Closed FC based on Pyro Processes
Test Fuel Innovative FuelsMA Fuels and targets
Maximum fluence in one year ncm2 ~ 12middot1023 (up to 55dpa)
Design lifetime 50 year
RR creation time (no more than years) 9 (2008 ndash 2016)
New Russian Sodium Fast Research Reactor ndashMulti-functional Fast Research Reactor (MFRR)
Location ndash RIAR site
Start of BN Closed fuel Cycle based on RIAR technologies
2011 - start of vi-pack MOX-fuel production for BN-8002012 ndash start of BN-800 operation2016hellip2018 ndash demonstration of BN-800 closed fuel cycle technologies
Key final official decisionsMOX-fuel production by pyroelectrochemistry andvibropackingTrend to closing of fuel cycle by compact drytechnologiesDevelopment and testing of new fuel and newtechnologies
RIAR RampD International cooperation in the field of advanced FC
Fuel production Repro-cessing
PampT Other Cladding materials
ConceptStudies
Funda-mental StudiesMOX other
France - MA oxide
- AmCm recovery
Pyro + FS Cm
INPRO - - - - - - CPP RUS-2
-
Japan MOX vibro
- MOX MAREEsepar Fluorex
MoO42-
ODS FS MA
Korea - - Metalliz vibro-DUPIC
MAREEsepar
Pyro - - -
US TRU fuel
UREX+1
TRU fuel
- - - Pu in RTILrsquos
EU - MA nitride
- - MSR fuel - - Cm
Red color ndash DOVITA-12 activities
- The RIAR DOVITA-12 PampT Program ndash Current Results of the 15-year RampD activities
- Experience in Closed Fuel Cycle including pyrochemical processes
- Since 1992 RIAR has been performing own RampD DOVITA Program
- Experience in adding of minor actinidesin fuel compositions and results of irradiation
- Slide Number 5
- New times considerationDOVITADOVITA-2
- DOVITA-2
- Research area of pyrochemical and non-aqueous MAFP partitioning in frame DOVITA-2 Program
- Slide Number 9
- Slide Number 10
- Slide Number 11
- Slide Number 12
- Slide Number 13
- Slide Number 14
- Slide Number 15
- Slide Number 16
- Slide Number 17
- Official Investment Frames for Russian Nuclear Renaissance
- Federal Tasks Program ldquoNew Generation Nuclear Energy Technologiesrdquo RIAR planned participation
- Slide Number 20
- Start of BN Closed fuel Cycle based on RIAR technologies
- RIAR RampD International cooperation in the field of advanced FC
-
Research area of pyrochemical and non-aqueous MAFP partitioning in frame DOVITA-2 Program
Meltsmedia
Electrochemical methods Oxides Precipi-tation
Metalli-zation
Liquid cathodes
Solid cathodes
Anodic dissol-n
EChem oxide titration
Chlorides Cd Bi Ga Al
Al + + + +Fluorides Bi Ga Al
Pb - + + + -Cl- F- Cd Bi Ga
Al PbAl + + + -
Molibdates - + - - + -RTIL Ga Zn Cu Ni
Al hellip + - - -+ Methods of Volatility of Fluorides and or Chlorides
ISTC Project 3261 (2006-2008)
Study of Cm thermodynamicsin molten chloridesObjectives
Reactions of formation for oxygen Cm compounds- equilibrium constants for reactions of Cm oxygen compoundsformation versus temperature- equilibrium constants for reactions of Cm oxygen compoundsformation versus the inverse effective radius of solvent cathion
1st Year is completed
Reactions of formation for oxygen-free Cm compounds- standard potential for redox pair versus temperature- standard potential for redox pair versus the inverse effective radius of solvent cathion
Simulation of Cm behavior in molten chloridesPourbaix diagrams
Collaborators ndash ITU CIEMAT CEA KTH
Recent RIAR activities in frame of DOVITA-2 Program
Gas supply tube
Sluice
Oxygen sensor
Salt
Thermocouple
Reference electrode AgAg+
Oxygen pump
Potentiometric titration of CmCl3
ISTC project 3261 Current Results
Potentiometric titration of CmCl3
Applied methodsbull main - titration by BaO
bull combined - in case of absence of Section on preliminary experimental curve for CmO+ formation
titration by current through the electric circuit ldquooxygen pumprdquo ndash ldquocounter electroderdquo and then by BaO
ISTC project 3261 Current Results
Oxygen pump after experiment
Cm dioxide deposit
Oxygen pumpZrO2(Sc2O3)Pt(O2)
Reference electrodePyrexSalt+AgCl(075molkg)AgPt(Ar)
Oxygen sensorZrO2(Y2O3)Pt(O2)
Counter electrodePyrexSalt C
ISTC project 3261 Current Results
Conditions of experiments
Salt Amount of Runs
Temperature rangeoC
Range of Cm content in melt
molekgNaCl-2CsCl 11 550-750 (11-14)10-3
3LiCl-2KCl 7 450-650 (19-79)10-3
NaCl-KCl 3 750-850 (50-69)10-3
ISTC project 3261 Current Results
Salt ingot with CmCl3
NaCl-2CsCl+CmCl3(14middot10-2molekg) LiCl-KCl+CmCl3(55middot10-3molekg)
NaCl-KCl + CmCl3(50middot10-3molekg)
ISTC project 3261 Current Results
Experimental constants of CmO+ CmOCl and Cm2O3 dissociation in molten chlorides at different temperatures molality scale
Melt T oC pK(CmO+) pK(CmOCl) pK(Cm2O3)
NaCl-2CsCl 556 42+02 79+02 201+03
650 34+02 75+02 185+03
750 37+02 67+02 168+03
3LiCl-2KCl 450 25+02 62+02 155+05
550 24+02 57+02 127+05
650 083+01 52+02 125+05
NaCl-KCl 750 26+02 59+02 129+04
800 24+02 58+02 126+04
850 13+01 56+02 121+04
ISTC project 3261 Current Results
Comparison with literature data on other actinidesDependence of dissociation constant for actinides upon temperature in LiCl-KCl
0
5
10
15
20
25
1 11 12 13 14
1000T 1000K
pK m
olal
ity sc
ale
CmO+(RIAR)
CmOCl (RIAR)
Cm2O3(RIAR)
AmO+[Lambertin]
AmOCl Lambertin]
Am2O3 [Lambertin]
Pu2O3 [Martinot]
Pu2O3 [Picard]
PuOCl [Picard]
ISTC project 3261 Current Results
Recent RIAR activities in frame of DOVITA-2 Program
RampD for production of vi-pack oxide Fuel with MAUnder continuation
RampD for production of vi-pack nitride Fuel with MAUnder development
RampD for production oxide pellet fuel with MAUnder development
RampD for production metallic fuel with MAFeasibility Stage
Molten Salt chemistry of Am and Cm for fluoridesUnder preparation
Partitioning of MAREE in molten chloridesfluorides liquid cathodesreductive extractionOxide precipitation
Official Investment Frames forRussian Nuclear Renaissance
Federal Tasks Program ldquoDevelopment of Nuclear Power Complex of Russia on a period of 2007 - 2015 ldquo - accepted in 2006
- NPP construction
Federal Tasks Program ldquoNuclear and Radiation Safetyrdquo (2008-2015) - accepted in 2007
- RAW Heritage
Federal Tasks Program ldquoNew Generation Nuclear Energy Technologiesrdquo (2010-2020) ndash on a final preparation Stage
- Innovations
Federal Tasks Program ldquoNew Generation Nuclear Energy Technologiesrdquo
RIAR planned participation
bull Multi-functional Fast Research Reactor (MFRR) - 2016bull Large Multi-Purpose Pyrochemical Reprocessing Complex -
2015Molten salt Reprocessing Facility
capacity ndash up to 2 500 kg of SNF per Year (fuel type oxide nitride metallic IMF)
Fluoride volatility Reprocessing Facility capacity ndash up to 500 kg of SNF per Year (mainly ndash LWR SNF)
bull New Lab for Experimental and Innovative Fuel Production ndash2010-1012 (incl Fuel and Targets with MA)
bull Demonstration of Closing Fuel Cycle based on Pyrochemical technologies -2016-2020- on a levels
Up to 50 spent FAs of BN-600800Full scale CFC for MFRR from initial fuel loading Other experimental implementations
Characteristic Value
Maximum flux Фmax ncm2middotsec ~ 60middot1015
Thermal power MWth ~ 150
Electric power MWe ~ 50
Number of independent experimental loops (~1 MWth sodium heavy metal and gas coolant + salt coolants)
3 (+1 behind reactor vessel)
Driven Fuel Vi-pack MOX (PuN+UN)
Core height mm 400-500
Maximum heat rate kWl 1100
Fuel Cycle Full Scale Closed FC based on Pyro Processes
Test Fuel Innovative FuelsMA Fuels and targets
Maximum fluence in one year ncm2 ~ 12middot1023 (up to 55dpa)
Design lifetime 50 year
RR creation time (no more than years) 9 (2008 ndash 2016)
New Russian Sodium Fast Research Reactor ndashMulti-functional Fast Research Reactor (MFRR)
Location ndash RIAR site
Start of BN Closed fuel Cycle based on RIAR technologies
2011 - start of vi-pack MOX-fuel production for BN-8002012 ndash start of BN-800 operation2016hellip2018 ndash demonstration of BN-800 closed fuel cycle technologies
Key final official decisionsMOX-fuel production by pyroelectrochemistry andvibropackingTrend to closing of fuel cycle by compact drytechnologiesDevelopment and testing of new fuel and newtechnologies
RIAR RampD International cooperation in the field of advanced FC
Fuel production Repro-cessing
PampT Other Cladding materials
ConceptStudies
Funda-mental StudiesMOX other
France - MA oxide
- AmCm recovery
Pyro + FS Cm
INPRO - - - - - - CPP RUS-2
-
Japan MOX vibro
- MOX MAREEsepar Fluorex
MoO42-
ODS FS MA
Korea - - Metalliz vibro-DUPIC
MAREEsepar
Pyro - - -
US TRU fuel
UREX+1
TRU fuel
- - - Pu in RTILrsquos
EU - MA nitride
- - MSR fuel - - Cm
Red color ndash DOVITA-12 activities
- The RIAR DOVITA-12 PampT Program ndash Current Results of the 15-year RampD activities
- Experience in Closed Fuel Cycle including pyrochemical processes
- Since 1992 RIAR has been performing own RampD DOVITA Program
- Experience in adding of minor actinidesin fuel compositions and results of irradiation
- Slide Number 5
- New times considerationDOVITADOVITA-2
- DOVITA-2
- Research area of pyrochemical and non-aqueous MAFP partitioning in frame DOVITA-2 Program
- Slide Number 9
- Slide Number 10
- Slide Number 11
- Slide Number 12
- Slide Number 13
- Slide Number 14
- Slide Number 15
- Slide Number 16
- Slide Number 17
- Official Investment Frames for Russian Nuclear Renaissance
- Federal Tasks Program ldquoNew Generation Nuclear Energy Technologiesrdquo RIAR planned participation
- Slide Number 20
- Start of BN Closed fuel Cycle based on RIAR technologies
- RIAR RampD International cooperation in the field of advanced FC
-
ISTC Project 3261 (2006-2008)
Study of Cm thermodynamicsin molten chloridesObjectives
Reactions of formation for oxygen Cm compounds- equilibrium constants for reactions of Cm oxygen compoundsformation versus temperature- equilibrium constants for reactions of Cm oxygen compoundsformation versus the inverse effective radius of solvent cathion
1st Year is completed
Reactions of formation for oxygen-free Cm compounds- standard potential for redox pair versus temperature- standard potential for redox pair versus the inverse effective radius of solvent cathion
Simulation of Cm behavior in molten chloridesPourbaix diagrams
Collaborators ndash ITU CIEMAT CEA KTH
Recent RIAR activities in frame of DOVITA-2 Program
Gas supply tube
Sluice
Oxygen sensor
Salt
Thermocouple
Reference electrode AgAg+
Oxygen pump
Potentiometric titration of CmCl3
ISTC project 3261 Current Results
Potentiometric titration of CmCl3
Applied methodsbull main - titration by BaO
bull combined - in case of absence of Section on preliminary experimental curve for CmO+ formation
titration by current through the electric circuit ldquooxygen pumprdquo ndash ldquocounter electroderdquo and then by BaO
ISTC project 3261 Current Results
Oxygen pump after experiment
Cm dioxide deposit
Oxygen pumpZrO2(Sc2O3)Pt(O2)
Reference electrodePyrexSalt+AgCl(075molkg)AgPt(Ar)
Oxygen sensorZrO2(Y2O3)Pt(O2)
Counter electrodePyrexSalt C
ISTC project 3261 Current Results
Conditions of experiments
Salt Amount of Runs
Temperature rangeoC
Range of Cm content in melt
molekgNaCl-2CsCl 11 550-750 (11-14)10-3
3LiCl-2KCl 7 450-650 (19-79)10-3
NaCl-KCl 3 750-850 (50-69)10-3
ISTC project 3261 Current Results
Salt ingot with CmCl3
NaCl-2CsCl+CmCl3(14middot10-2molekg) LiCl-KCl+CmCl3(55middot10-3molekg)
NaCl-KCl + CmCl3(50middot10-3molekg)
ISTC project 3261 Current Results
Experimental constants of CmO+ CmOCl and Cm2O3 dissociation in molten chlorides at different temperatures molality scale
Melt T oC pK(CmO+) pK(CmOCl) pK(Cm2O3)
NaCl-2CsCl 556 42+02 79+02 201+03
650 34+02 75+02 185+03
750 37+02 67+02 168+03
3LiCl-2KCl 450 25+02 62+02 155+05
550 24+02 57+02 127+05
650 083+01 52+02 125+05
NaCl-KCl 750 26+02 59+02 129+04
800 24+02 58+02 126+04
850 13+01 56+02 121+04
ISTC project 3261 Current Results
Comparison with literature data on other actinidesDependence of dissociation constant for actinides upon temperature in LiCl-KCl
0
5
10
15
20
25
1 11 12 13 14
1000T 1000K
pK m
olal
ity sc
ale
CmO+(RIAR)
CmOCl (RIAR)
Cm2O3(RIAR)
AmO+[Lambertin]
AmOCl Lambertin]
Am2O3 [Lambertin]
Pu2O3 [Martinot]
Pu2O3 [Picard]
PuOCl [Picard]
ISTC project 3261 Current Results
Recent RIAR activities in frame of DOVITA-2 Program
RampD for production of vi-pack oxide Fuel with MAUnder continuation
RampD for production of vi-pack nitride Fuel with MAUnder development
RampD for production oxide pellet fuel with MAUnder development
RampD for production metallic fuel with MAFeasibility Stage
Molten Salt chemistry of Am and Cm for fluoridesUnder preparation
Partitioning of MAREE in molten chloridesfluorides liquid cathodesreductive extractionOxide precipitation
Official Investment Frames forRussian Nuclear Renaissance
Federal Tasks Program ldquoDevelopment of Nuclear Power Complex of Russia on a period of 2007 - 2015 ldquo - accepted in 2006
- NPP construction
Federal Tasks Program ldquoNuclear and Radiation Safetyrdquo (2008-2015) - accepted in 2007
- RAW Heritage
Federal Tasks Program ldquoNew Generation Nuclear Energy Technologiesrdquo (2010-2020) ndash on a final preparation Stage
- Innovations
Federal Tasks Program ldquoNew Generation Nuclear Energy Technologiesrdquo
RIAR planned participation
bull Multi-functional Fast Research Reactor (MFRR) - 2016bull Large Multi-Purpose Pyrochemical Reprocessing Complex -
2015Molten salt Reprocessing Facility
capacity ndash up to 2 500 kg of SNF per Year (fuel type oxide nitride metallic IMF)
Fluoride volatility Reprocessing Facility capacity ndash up to 500 kg of SNF per Year (mainly ndash LWR SNF)
bull New Lab for Experimental and Innovative Fuel Production ndash2010-1012 (incl Fuel and Targets with MA)
bull Demonstration of Closing Fuel Cycle based on Pyrochemical technologies -2016-2020- on a levels
Up to 50 spent FAs of BN-600800Full scale CFC for MFRR from initial fuel loading Other experimental implementations
Characteristic Value
Maximum flux Фmax ncm2middotsec ~ 60middot1015
Thermal power MWth ~ 150
Electric power MWe ~ 50
Number of independent experimental loops (~1 MWth sodium heavy metal and gas coolant + salt coolants)
3 (+1 behind reactor vessel)
Driven Fuel Vi-pack MOX (PuN+UN)
Core height mm 400-500
Maximum heat rate kWl 1100
Fuel Cycle Full Scale Closed FC based on Pyro Processes
Test Fuel Innovative FuelsMA Fuels and targets
Maximum fluence in one year ncm2 ~ 12middot1023 (up to 55dpa)
Design lifetime 50 year
RR creation time (no more than years) 9 (2008 ndash 2016)
New Russian Sodium Fast Research Reactor ndashMulti-functional Fast Research Reactor (MFRR)
Location ndash RIAR site
Start of BN Closed fuel Cycle based on RIAR technologies
2011 - start of vi-pack MOX-fuel production for BN-8002012 ndash start of BN-800 operation2016hellip2018 ndash demonstration of BN-800 closed fuel cycle technologies
Key final official decisionsMOX-fuel production by pyroelectrochemistry andvibropackingTrend to closing of fuel cycle by compact drytechnologiesDevelopment and testing of new fuel and newtechnologies
RIAR RampD International cooperation in the field of advanced FC
Fuel production Repro-cessing
PampT Other Cladding materials
ConceptStudies
Funda-mental StudiesMOX other
France - MA oxide
- AmCm recovery
Pyro + FS Cm
INPRO - - - - - - CPP RUS-2
-
Japan MOX vibro
- MOX MAREEsepar Fluorex
MoO42-
ODS FS MA
Korea - - Metalliz vibro-DUPIC
MAREEsepar
Pyro - - -
US TRU fuel
UREX+1
TRU fuel
- - - Pu in RTILrsquos
EU - MA nitride
- - MSR fuel - - Cm
Red color ndash DOVITA-12 activities
- The RIAR DOVITA-12 PampT Program ndash Current Results of the 15-year RampD activities
- Experience in Closed Fuel Cycle including pyrochemical processes
- Since 1992 RIAR has been performing own RampD DOVITA Program
- Experience in adding of minor actinidesin fuel compositions and results of irradiation
- Slide Number 5
- New times considerationDOVITADOVITA-2
- DOVITA-2
- Research area of pyrochemical and non-aqueous MAFP partitioning in frame DOVITA-2 Program
- Slide Number 9
- Slide Number 10
- Slide Number 11
- Slide Number 12
- Slide Number 13
- Slide Number 14
- Slide Number 15
- Slide Number 16
- Slide Number 17
- Official Investment Frames for Russian Nuclear Renaissance
- Federal Tasks Program ldquoNew Generation Nuclear Energy Technologiesrdquo RIAR planned participation
- Slide Number 20
- Start of BN Closed fuel Cycle based on RIAR technologies
- RIAR RampD International cooperation in the field of advanced FC
-
Gas supply tube
Sluice
Oxygen sensor
Salt
Thermocouple
Reference electrode AgAg+
Oxygen pump
Potentiometric titration of CmCl3
ISTC project 3261 Current Results
Potentiometric titration of CmCl3
Applied methodsbull main - titration by BaO
bull combined - in case of absence of Section on preliminary experimental curve for CmO+ formation
titration by current through the electric circuit ldquooxygen pumprdquo ndash ldquocounter electroderdquo and then by BaO
ISTC project 3261 Current Results
Oxygen pump after experiment
Cm dioxide deposit
Oxygen pumpZrO2(Sc2O3)Pt(O2)
Reference electrodePyrexSalt+AgCl(075molkg)AgPt(Ar)
Oxygen sensorZrO2(Y2O3)Pt(O2)
Counter electrodePyrexSalt C
ISTC project 3261 Current Results
Conditions of experiments
Salt Amount of Runs
Temperature rangeoC
Range of Cm content in melt
molekgNaCl-2CsCl 11 550-750 (11-14)10-3
3LiCl-2KCl 7 450-650 (19-79)10-3
NaCl-KCl 3 750-850 (50-69)10-3
ISTC project 3261 Current Results
Salt ingot with CmCl3
NaCl-2CsCl+CmCl3(14middot10-2molekg) LiCl-KCl+CmCl3(55middot10-3molekg)
NaCl-KCl + CmCl3(50middot10-3molekg)
ISTC project 3261 Current Results
Experimental constants of CmO+ CmOCl and Cm2O3 dissociation in molten chlorides at different temperatures molality scale
Melt T oC pK(CmO+) pK(CmOCl) pK(Cm2O3)
NaCl-2CsCl 556 42+02 79+02 201+03
650 34+02 75+02 185+03
750 37+02 67+02 168+03
3LiCl-2KCl 450 25+02 62+02 155+05
550 24+02 57+02 127+05
650 083+01 52+02 125+05
NaCl-KCl 750 26+02 59+02 129+04
800 24+02 58+02 126+04
850 13+01 56+02 121+04
ISTC project 3261 Current Results
Comparison with literature data on other actinidesDependence of dissociation constant for actinides upon temperature in LiCl-KCl
0
5
10
15
20
25
1 11 12 13 14
1000T 1000K
pK m
olal
ity sc
ale
CmO+(RIAR)
CmOCl (RIAR)
Cm2O3(RIAR)
AmO+[Lambertin]
AmOCl Lambertin]
Am2O3 [Lambertin]
Pu2O3 [Martinot]
Pu2O3 [Picard]
PuOCl [Picard]
ISTC project 3261 Current Results
Recent RIAR activities in frame of DOVITA-2 Program
RampD for production of vi-pack oxide Fuel with MAUnder continuation
RampD for production of vi-pack nitride Fuel with MAUnder development
RampD for production oxide pellet fuel with MAUnder development
RampD for production metallic fuel with MAFeasibility Stage
Molten Salt chemistry of Am and Cm for fluoridesUnder preparation
Partitioning of MAREE in molten chloridesfluorides liquid cathodesreductive extractionOxide precipitation
Official Investment Frames forRussian Nuclear Renaissance
Federal Tasks Program ldquoDevelopment of Nuclear Power Complex of Russia on a period of 2007 - 2015 ldquo - accepted in 2006
- NPP construction
Federal Tasks Program ldquoNuclear and Radiation Safetyrdquo (2008-2015) - accepted in 2007
- RAW Heritage
Federal Tasks Program ldquoNew Generation Nuclear Energy Technologiesrdquo (2010-2020) ndash on a final preparation Stage
- Innovations
Federal Tasks Program ldquoNew Generation Nuclear Energy Technologiesrdquo
RIAR planned participation
bull Multi-functional Fast Research Reactor (MFRR) - 2016bull Large Multi-Purpose Pyrochemical Reprocessing Complex -
2015Molten salt Reprocessing Facility
capacity ndash up to 2 500 kg of SNF per Year (fuel type oxide nitride metallic IMF)
Fluoride volatility Reprocessing Facility capacity ndash up to 500 kg of SNF per Year (mainly ndash LWR SNF)
bull New Lab for Experimental and Innovative Fuel Production ndash2010-1012 (incl Fuel and Targets with MA)
bull Demonstration of Closing Fuel Cycle based on Pyrochemical technologies -2016-2020- on a levels
Up to 50 spent FAs of BN-600800Full scale CFC for MFRR from initial fuel loading Other experimental implementations
Characteristic Value
Maximum flux Фmax ncm2middotsec ~ 60middot1015
Thermal power MWth ~ 150
Electric power MWe ~ 50
Number of independent experimental loops (~1 MWth sodium heavy metal and gas coolant + salt coolants)
3 (+1 behind reactor vessel)
Driven Fuel Vi-pack MOX (PuN+UN)
Core height mm 400-500
Maximum heat rate kWl 1100
Fuel Cycle Full Scale Closed FC based on Pyro Processes
Test Fuel Innovative FuelsMA Fuels and targets
Maximum fluence in one year ncm2 ~ 12middot1023 (up to 55dpa)
Design lifetime 50 year
RR creation time (no more than years) 9 (2008 ndash 2016)
New Russian Sodium Fast Research Reactor ndashMulti-functional Fast Research Reactor (MFRR)
Location ndash RIAR site
Start of BN Closed fuel Cycle based on RIAR technologies
2011 - start of vi-pack MOX-fuel production for BN-8002012 ndash start of BN-800 operation2016hellip2018 ndash demonstration of BN-800 closed fuel cycle technologies
Key final official decisionsMOX-fuel production by pyroelectrochemistry andvibropackingTrend to closing of fuel cycle by compact drytechnologiesDevelopment and testing of new fuel and newtechnologies
RIAR RampD International cooperation in the field of advanced FC
Fuel production Repro-cessing
PampT Other Cladding materials
ConceptStudies
Funda-mental StudiesMOX other
France - MA oxide
- AmCm recovery
Pyro + FS Cm
INPRO - - - - - - CPP RUS-2
-
Japan MOX vibro
- MOX MAREEsepar Fluorex
MoO42-
ODS FS MA
Korea - - Metalliz vibro-DUPIC
MAREEsepar
Pyro - - -
US TRU fuel
UREX+1
TRU fuel
- - - Pu in RTILrsquos
EU - MA nitride
- - MSR fuel - - Cm
Red color ndash DOVITA-12 activities
- The RIAR DOVITA-12 PampT Program ndash Current Results of the 15-year RampD activities
- Experience in Closed Fuel Cycle including pyrochemical processes
- Since 1992 RIAR has been performing own RampD DOVITA Program
- Experience in adding of minor actinidesin fuel compositions and results of irradiation
- Slide Number 5
- New times considerationDOVITADOVITA-2
- DOVITA-2
- Research area of pyrochemical and non-aqueous MAFP partitioning in frame DOVITA-2 Program
- Slide Number 9
- Slide Number 10
- Slide Number 11
- Slide Number 12
- Slide Number 13
- Slide Number 14
- Slide Number 15
- Slide Number 16
- Slide Number 17
- Official Investment Frames for Russian Nuclear Renaissance
- Federal Tasks Program ldquoNew Generation Nuclear Energy Technologiesrdquo RIAR planned participation
- Slide Number 20
- Start of BN Closed fuel Cycle based on RIAR technologies
- RIAR RampD International cooperation in the field of advanced FC
-
Potentiometric titration of CmCl3
Applied methodsbull main - titration by BaO
bull combined - in case of absence of Section on preliminary experimental curve for CmO+ formation
titration by current through the electric circuit ldquooxygen pumprdquo ndash ldquocounter electroderdquo and then by BaO
ISTC project 3261 Current Results
Oxygen pump after experiment
Cm dioxide deposit
Oxygen pumpZrO2(Sc2O3)Pt(O2)
Reference electrodePyrexSalt+AgCl(075molkg)AgPt(Ar)
Oxygen sensorZrO2(Y2O3)Pt(O2)
Counter electrodePyrexSalt C
ISTC project 3261 Current Results
Conditions of experiments
Salt Amount of Runs
Temperature rangeoC
Range of Cm content in melt
molekgNaCl-2CsCl 11 550-750 (11-14)10-3
3LiCl-2KCl 7 450-650 (19-79)10-3
NaCl-KCl 3 750-850 (50-69)10-3
ISTC project 3261 Current Results
Salt ingot with CmCl3
NaCl-2CsCl+CmCl3(14middot10-2molekg) LiCl-KCl+CmCl3(55middot10-3molekg)
NaCl-KCl + CmCl3(50middot10-3molekg)
ISTC project 3261 Current Results
Experimental constants of CmO+ CmOCl and Cm2O3 dissociation in molten chlorides at different temperatures molality scale
Melt T oC pK(CmO+) pK(CmOCl) pK(Cm2O3)
NaCl-2CsCl 556 42+02 79+02 201+03
650 34+02 75+02 185+03
750 37+02 67+02 168+03
3LiCl-2KCl 450 25+02 62+02 155+05
550 24+02 57+02 127+05
650 083+01 52+02 125+05
NaCl-KCl 750 26+02 59+02 129+04
800 24+02 58+02 126+04
850 13+01 56+02 121+04
ISTC project 3261 Current Results
Comparison with literature data on other actinidesDependence of dissociation constant for actinides upon temperature in LiCl-KCl
0
5
10
15
20
25
1 11 12 13 14
1000T 1000K
pK m
olal
ity sc
ale
CmO+(RIAR)
CmOCl (RIAR)
Cm2O3(RIAR)
AmO+[Lambertin]
AmOCl Lambertin]
Am2O3 [Lambertin]
Pu2O3 [Martinot]
Pu2O3 [Picard]
PuOCl [Picard]
ISTC project 3261 Current Results
Recent RIAR activities in frame of DOVITA-2 Program
RampD for production of vi-pack oxide Fuel with MAUnder continuation
RampD for production of vi-pack nitride Fuel with MAUnder development
RampD for production oxide pellet fuel with MAUnder development
RampD for production metallic fuel with MAFeasibility Stage
Molten Salt chemistry of Am and Cm for fluoridesUnder preparation
Partitioning of MAREE in molten chloridesfluorides liquid cathodesreductive extractionOxide precipitation
Official Investment Frames forRussian Nuclear Renaissance
Federal Tasks Program ldquoDevelopment of Nuclear Power Complex of Russia on a period of 2007 - 2015 ldquo - accepted in 2006
- NPP construction
Federal Tasks Program ldquoNuclear and Radiation Safetyrdquo (2008-2015) - accepted in 2007
- RAW Heritage
Federal Tasks Program ldquoNew Generation Nuclear Energy Technologiesrdquo (2010-2020) ndash on a final preparation Stage
- Innovations
Federal Tasks Program ldquoNew Generation Nuclear Energy Technologiesrdquo
RIAR planned participation
bull Multi-functional Fast Research Reactor (MFRR) - 2016bull Large Multi-Purpose Pyrochemical Reprocessing Complex -
2015Molten salt Reprocessing Facility
capacity ndash up to 2 500 kg of SNF per Year (fuel type oxide nitride metallic IMF)
Fluoride volatility Reprocessing Facility capacity ndash up to 500 kg of SNF per Year (mainly ndash LWR SNF)
bull New Lab for Experimental and Innovative Fuel Production ndash2010-1012 (incl Fuel and Targets with MA)
bull Demonstration of Closing Fuel Cycle based on Pyrochemical technologies -2016-2020- on a levels
Up to 50 spent FAs of BN-600800Full scale CFC for MFRR from initial fuel loading Other experimental implementations
Characteristic Value
Maximum flux Фmax ncm2middotsec ~ 60middot1015
Thermal power MWth ~ 150
Electric power MWe ~ 50
Number of independent experimental loops (~1 MWth sodium heavy metal and gas coolant + salt coolants)
3 (+1 behind reactor vessel)
Driven Fuel Vi-pack MOX (PuN+UN)
Core height mm 400-500
Maximum heat rate kWl 1100
Fuel Cycle Full Scale Closed FC based on Pyro Processes
Test Fuel Innovative FuelsMA Fuels and targets
Maximum fluence in one year ncm2 ~ 12middot1023 (up to 55dpa)
Design lifetime 50 year
RR creation time (no more than years) 9 (2008 ndash 2016)
New Russian Sodium Fast Research Reactor ndashMulti-functional Fast Research Reactor (MFRR)
Location ndash RIAR site
Start of BN Closed fuel Cycle based on RIAR technologies
2011 - start of vi-pack MOX-fuel production for BN-8002012 ndash start of BN-800 operation2016hellip2018 ndash demonstration of BN-800 closed fuel cycle technologies
Key final official decisionsMOX-fuel production by pyroelectrochemistry andvibropackingTrend to closing of fuel cycle by compact drytechnologiesDevelopment and testing of new fuel and newtechnologies
RIAR RampD International cooperation in the field of advanced FC
Fuel production Repro-cessing
PampT Other Cladding materials
ConceptStudies
Funda-mental StudiesMOX other
France - MA oxide
- AmCm recovery
Pyro + FS Cm
INPRO - - - - - - CPP RUS-2
-
Japan MOX vibro
- MOX MAREEsepar Fluorex
MoO42-
ODS FS MA
Korea - - Metalliz vibro-DUPIC
MAREEsepar
Pyro - - -
US TRU fuel
UREX+1
TRU fuel
- - - Pu in RTILrsquos
EU - MA nitride
- - MSR fuel - - Cm
Red color ndash DOVITA-12 activities
- The RIAR DOVITA-12 PampT Program ndash Current Results of the 15-year RampD activities
- Experience in Closed Fuel Cycle including pyrochemical processes
- Since 1992 RIAR has been performing own RampD DOVITA Program
- Experience in adding of minor actinidesin fuel compositions and results of irradiation
- Slide Number 5
- New times considerationDOVITADOVITA-2
- DOVITA-2
- Research area of pyrochemical and non-aqueous MAFP partitioning in frame DOVITA-2 Program
- Slide Number 9
- Slide Number 10
- Slide Number 11
- Slide Number 12
- Slide Number 13
- Slide Number 14
- Slide Number 15
- Slide Number 16
- Slide Number 17
- Official Investment Frames for Russian Nuclear Renaissance
- Federal Tasks Program ldquoNew Generation Nuclear Energy Technologiesrdquo RIAR planned participation
- Slide Number 20
- Start of BN Closed fuel Cycle based on RIAR technologies
- RIAR RampD International cooperation in the field of advanced FC
-
Oxygen pump after experiment
Cm dioxide deposit
Oxygen pumpZrO2(Sc2O3)Pt(O2)
Reference electrodePyrexSalt+AgCl(075molkg)AgPt(Ar)
Oxygen sensorZrO2(Y2O3)Pt(O2)
Counter electrodePyrexSalt C
ISTC project 3261 Current Results
Conditions of experiments
Salt Amount of Runs
Temperature rangeoC
Range of Cm content in melt
molekgNaCl-2CsCl 11 550-750 (11-14)10-3
3LiCl-2KCl 7 450-650 (19-79)10-3
NaCl-KCl 3 750-850 (50-69)10-3
ISTC project 3261 Current Results
Salt ingot with CmCl3
NaCl-2CsCl+CmCl3(14middot10-2molekg) LiCl-KCl+CmCl3(55middot10-3molekg)
NaCl-KCl + CmCl3(50middot10-3molekg)
ISTC project 3261 Current Results
Experimental constants of CmO+ CmOCl and Cm2O3 dissociation in molten chlorides at different temperatures molality scale
Melt T oC pK(CmO+) pK(CmOCl) pK(Cm2O3)
NaCl-2CsCl 556 42+02 79+02 201+03
650 34+02 75+02 185+03
750 37+02 67+02 168+03
3LiCl-2KCl 450 25+02 62+02 155+05
550 24+02 57+02 127+05
650 083+01 52+02 125+05
NaCl-KCl 750 26+02 59+02 129+04
800 24+02 58+02 126+04
850 13+01 56+02 121+04
ISTC project 3261 Current Results
Comparison with literature data on other actinidesDependence of dissociation constant for actinides upon temperature in LiCl-KCl
0
5
10
15
20
25
1 11 12 13 14
1000T 1000K
pK m
olal
ity sc
ale
CmO+(RIAR)
CmOCl (RIAR)
Cm2O3(RIAR)
AmO+[Lambertin]
AmOCl Lambertin]
Am2O3 [Lambertin]
Pu2O3 [Martinot]
Pu2O3 [Picard]
PuOCl [Picard]
ISTC project 3261 Current Results
Recent RIAR activities in frame of DOVITA-2 Program
RampD for production of vi-pack oxide Fuel with MAUnder continuation
RampD for production of vi-pack nitride Fuel with MAUnder development
RampD for production oxide pellet fuel with MAUnder development
RampD for production metallic fuel with MAFeasibility Stage
Molten Salt chemistry of Am and Cm for fluoridesUnder preparation
Partitioning of MAREE in molten chloridesfluorides liquid cathodesreductive extractionOxide precipitation
Official Investment Frames forRussian Nuclear Renaissance
Federal Tasks Program ldquoDevelopment of Nuclear Power Complex of Russia on a period of 2007 - 2015 ldquo - accepted in 2006
- NPP construction
Federal Tasks Program ldquoNuclear and Radiation Safetyrdquo (2008-2015) - accepted in 2007
- RAW Heritage
Federal Tasks Program ldquoNew Generation Nuclear Energy Technologiesrdquo (2010-2020) ndash on a final preparation Stage
- Innovations
Federal Tasks Program ldquoNew Generation Nuclear Energy Technologiesrdquo
RIAR planned participation
bull Multi-functional Fast Research Reactor (MFRR) - 2016bull Large Multi-Purpose Pyrochemical Reprocessing Complex -
2015Molten salt Reprocessing Facility
capacity ndash up to 2 500 kg of SNF per Year (fuel type oxide nitride metallic IMF)
Fluoride volatility Reprocessing Facility capacity ndash up to 500 kg of SNF per Year (mainly ndash LWR SNF)
bull New Lab for Experimental and Innovative Fuel Production ndash2010-1012 (incl Fuel and Targets with MA)
bull Demonstration of Closing Fuel Cycle based on Pyrochemical technologies -2016-2020- on a levels
Up to 50 spent FAs of BN-600800Full scale CFC for MFRR from initial fuel loading Other experimental implementations
Characteristic Value
Maximum flux Фmax ncm2middotsec ~ 60middot1015
Thermal power MWth ~ 150
Electric power MWe ~ 50
Number of independent experimental loops (~1 MWth sodium heavy metal and gas coolant + salt coolants)
3 (+1 behind reactor vessel)
Driven Fuel Vi-pack MOX (PuN+UN)
Core height mm 400-500
Maximum heat rate kWl 1100
Fuel Cycle Full Scale Closed FC based on Pyro Processes
Test Fuel Innovative FuelsMA Fuels and targets
Maximum fluence in one year ncm2 ~ 12middot1023 (up to 55dpa)
Design lifetime 50 year
RR creation time (no more than years) 9 (2008 ndash 2016)
New Russian Sodium Fast Research Reactor ndashMulti-functional Fast Research Reactor (MFRR)
Location ndash RIAR site
Start of BN Closed fuel Cycle based on RIAR technologies
2011 - start of vi-pack MOX-fuel production for BN-8002012 ndash start of BN-800 operation2016hellip2018 ndash demonstration of BN-800 closed fuel cycle technologies
Key final official decisionsMOX-fuel production by pyroelectrochemistry andvibropackingTrend to closing of fuel cycle by compact drytechnologiesDevelopment and testing of new fuel and newtechnologies
RIAR RampD International cooperation in the field of advanced FC
Fuel production Repro-cessing
PampT Other Cladding materials
ConceptStudies
Funda-mental StudiesMOX other
France - MA oxide
- AmCm recovery
Pyro + FS Cm
INPRO - - - - - - CPP RUS-2
-
Japan MOX vibro
- MOX MAREEsepar Fluorex
MoO42-
ODS FS MA
Korea - - Metalliz vibro-DUPIC
MAREEsepar
Pyro - - -
US TRU fuel
UREX+1
TRU fuel
- - - Pu in RTILrsquos
EU - MA nitride
- - MSR fuel - - Cm
Red color ndash DOVITA-12 activities
- The RIAR DOVITA-12 PampT Program ndash Current Results of the 15-year RampD activities
- Experience in Closed Fuel Cycle including pyrochemical processes
- Since 1992 RIAR has been performing own RampD DOVITA Program
- Experience in adding of minor actinidesin fuel compositions and results of irradiation
- Slide Number 5
- New times considerationDOVITADOVITA-2
- DOVITA-2
- Research area of pyrochemical and non-aqueous MAFP partitioning in frame DOVITA-2 Program
- Slide Number 9
- Slide Number 10
- Slide Number 11
- Slide Number 12
- Slide Number 13
- Slide Number 14
- Slide Number 15
- Slide Number 16
- Slide Number 17
- Official Investment Frames for Russian Nuclear Renaissance
- Federal Tasks Program ldquoNew Generation Nuclear Energy Technologiesrdquo RIAR planned participation
- Slide Number 20
- Start of BN Closed fuel Cycle based on RIAR technologies
- RIAR RampD International cooperation in the field of advanced FC
-
Conditions of experiments
Salt Amount of Runs
Temperature rangeoC
Range of Cm content in melt
molekgNaCl-2CsCl 11 550-750 (11-14)10-3
3LiCl-2KCl 7 450-650 (19-79)10-3
NaCl-KCl 3 750-850 (50-69)10-3
ISTC project 3261 Current Results
Salt ingot with CmCl3
NaCl-2CsCl+CmCl3(14middot10-2molekg) LiCl-KCl+CmCl3(55middot10-3molekg)
NaCl-KCl + CmCl3(50middot10-3molekg)
ISTC project 3261 Current Results
Experimental constants of CmO+ CmOCl and Cm2O3 dissociation in molten chlorides at different temperatures molality scale
Melt T oC pK(CmO+) pK(CmOCl) pK(Cm2O3)
NaCl-2CsCl 556 42+02 79+02 201+03
650 34+02 75+02 185+03
750 37+02 67+02 168+03
3LiCl-2KCl 450 25+02 62+02 155+05
550 24+02 57+02 127+05
650 083+01 52+02 125+05
NaCl-KCl 750 26+02 59+02 129+04
800 24+02 58+02 126+04
850 13+01 56+02 121+04
ISTC project 3261 Current Results
Comparison with literature data on other actinidesDependence of dissociation constant for actinides upon temperature in LiCl-KCl
0
5
10
15
20
25
1 11 12 13 14
1000T 1000K
pK m
olal
ity sc
ale
CmO+(RIAR)
CmOCl (RIAR)
Cm2O3(RIAR)
AmO+[Lambertin]
AmOCl Lambertin]
Am2O3 [Lambertin]
Pu2O3 [Martinot]
Pu2O3 [Picard]
PuOCl [Picard]
ISTC project 3261 Current Results
Recent RIAR activities in frame of DOVITA-2 Program
RampD for production of vi-pack oxide Fuel with MAUnder continuation
RampD for production of vi-pack nitride Fuel with MAUnder development
RampD for production oxide pellet fuel with MAUnder development
RampD for production metallic fuel with MAFeasibility Stage
Molten Salt chemistry of Am and Cm for fluoridesUnder preparation
Partitioning of MAREE in molten chloridesfluorides liquid cathodesreductive extractionOxide precipitation
Official Investment Frames forRussian Nuclear Renaissance
Federal Tasks Program ldquoDevelopment of Nuclear Power Complex of Russia on a period of 2007 - 2015 ldquo - accepted in 2006
- NPP construction
Federal Tasks Program ldquoNuclear and Radiation Safetyrdquo (2008-2015) - accepted in 2007
- RAW Heritage
Federal Tasks Program ldquoNew Generation Nuclear Energy Technologiesrdquo (2010-2020) ndash on a final preparation Stage
- Innovations
Federal Tasks Program ldquoNew Generation Nuclear Energy Technologiesrdquo
RIAR planned participation
bull Multi-functional Fast Research Reactor (MFRR) - 2016bull Large Multi-Purpose Pyrochemical Reprocessing Complex -
2015Molten salt Reprocessing Facility
capacity ndash up to 2 500 kg of SNF per Year (fuel type oxide nitride metallic IMF)
Fluoride volatility Reprocessing Facility capacity ndash up to 500 kg of SNF per Year (mainly ndash LWR SNF)
bull New Lab for Experimental and Innovative Fuel Production ndash2010-1012 (incl Fuel and Targets with MA)
bull Demonstration of Closing Fuel Cycle based on Pyrochemical technologies -2016-2020- on a levels
Up to 50 spent FAs of BN-600800Full scale CFC for MFRR from initial fuel loading Other experimental implementations
Characteristic Value
Maximum flux Фmax ncm2middotsec ~ 60middot1015
Thermal power MWth ~ 150
Electric power MWe ~ 50
Number of independent experimental loops (~1 MWth sodium heavy metal and gas coolant + salt coolants)
3 (+1 behind reactor vessel)
Driven Fuel Vi-pack MOX (PuN+UN)
Core height mm 400-500
Maximum heat rate kWl 1100
Fuel Cycle Full Scale Closed FC based on Pyro Processes
Test Fuel Innovative FuelsMA Fuels and targets
Maximum fluence in one year ncm2 ~ 12middot1023 (up to 55dpa)
Design lifetime 50 year
RR creation time (no more than years) 9 (2008 ndash 2016)
New Russian Sodium Fast Research Reactor ndashMulti-functional Fast Research Reactor (MFRR)
Location ndash RIAR site
Start of BN Closed fuel Cycle based on RIAR technologies
2011 - start of vi-pack MOX-fuel production for BN-8002012 ndash start of BN-800 operation2016hellip2018 ndash demonstration of BN-800 closed fuel cycle technologies
Key final official decisionsMOX-fuel production by pyroelectrochemistry andvibropackingTrend to closing of fuel cycle by compact drytechnologiesDevelopment and testing of new fuel and newtechnologies
RIAR RampD International cooperation in the field of advanced FC
Fuel production Repro-cessing
PampT Other Cladding materials
ConceptStudies
Funda-mental StudiesMOX other
France - MA oxide
- AmCm recovery
Pyro + FS Cm
INPRO - - - - - - CPP RUS-2
-
Japan MOX vibro
- MOX MAREEsepar Fluorex
MoO42-
ODS FS MA
Korea - - Metalliz vibro-DUPIC
MAREEsepar
Pyro - - -
US TRU fuel
UREX+1
TRU fuel
- - - Pu in RTILrsquos
EU - MA nitride
- - MSR fuel - - Cm
Red color ndash DOVITA-12 activities
- The RIAR DOVITA-12 PampT Program ndash Current Results of the 15-year RampD activities
- Experience in Closed Fuel Cycle including pyrochemical processes
- Since 1992 RIAR has been performing own RampD DOVITA Program
- Experience in adding of minor actinidesin fuel compositions and results of irradiation
- Slide Number 5
- New times considerationDOVITADOVITA-2
- DOVITA-2
- Research area of pyrochemical and non-aqueous MAFP partitioning in frame DOVITA-2 Program
- Slide Number 9
- Slide Number 10
- Slide Number 11
- Slide Number 12
- Slide Number 13
- Slide Number 14
- Slide Number 15
- Slide Number 16
- Slide Number 17
- Official Investment Frames for Russian Nuclear Renaissance
- Federal Tasks Program ldquoNew Generation Nuclear Energy Technologiesrdquo RIAR planned participation
- Slide Number 20
- Start of BN Closed fuel Cycle based on RIAR technologies
- RIAR RampD International cooperation in the field of advanced FC
-
Salt ingot with CmCl3
NaCl-2CsCl+CmCl3(14middot10-2molekg) LiCl-KCl+CmCl3(55middot10-3molekg)
NaCl-KCl + CmCl3(50middot10-3molekg)
ISTC project 3261 Current Results
Experimental constants of CmO+ CmOCl and Cm2O3 dissociation in molten chlorides at different temperatures molality scale
Melt T oC pK(CmO+) pK(CmOCl) pK(Cm2O3)
NaCl-2CsCl 556 42+02 79+02 201+03
650 34+02 75+02 185+03
750 37+02 67+02 168+03
3LiCl-2KCl 450 25+02 62+02 155+05
550 24+02 57+02 127+05
650 083+01 52+02 125+05
NaCl-KCl 750 26+02 59+02 129+04
800 24+02 58+02 126+04
850 13+01 56+02 121+04
ISTC project 3261 Current Results
Comparison with literature data on other actinidesDependence of dissociation constant for actinides upon temperature in LiCl-KCl
0
5
10
15
20
25
1 11 12 13 14
1000T 1000K
pK m
olal
ity sc
ale
CmO+(RIAR)
CmOCl (RIAR)
Cm2O3(RIAR)
AmO+[Lambertin]
AmOCl Lambertin]
Am2O3 [Lambertin]
Pu2O3 [Martinot]
Pu2O3 [Picard]
PuOCl [Picard]
ISTC project 3261 Current Results
Recent RIAR activities in frame of DOVITA-2 Program
RampD for production of vi-pack oxide Fuel with MAUnder continuation
RampD for production of vi-pack nitride Fuel with MAUnder development
RampD for production oxide pellet fuel with MAUnder development
RampD for production metallic fuel with MAFeasibility Stage
Molten Salt chemistry of Am and Cm for fluoridesUnder preparation
Partitioning of MAREE in molten chloridesfluorides liquid cathodesreductive extractionOxide precipitation
Official Investment Frames forRussian Nuclear Renaissance
Federal Tasks Program ldquoDevelopment of Nuclear Power Complex of Russia on a period of 2007 - 2015 ldquo - accepted in 2006
- NPP construction
Federal Tasks Program ldquoNuclear and Radiation Safetyrdquo (2008-2015) - accepted in 2007
- RAW Heritage
Federal Tasks Program ldquoNew Generation Nuclear Energy Technologiesrdquo (2010-2020) ndash on a final preparation Stage
- Innovations
Federal Tasks Program ldquoNew Generation Nuclear Energy Technologiesrdquo
RIAR planned participation
bull Multi-functional Fast Research Reactor (MFRR) - 2016bull Large Multi-Purpose Pyrochemical Reprocessing Complex -
2015Molten salt Reprocessing Facility
capacity ndash up to 2 500 kg of SNF per Year (fuel type oxide nitride metallic IMF)
Fluoride volatility Reprocessing Facility capacity ndash up to 500 kg of SNF per Year (mainly ndash LWR SNF)
bull New Lab for Experimental and Innovative Fuel Production ndash2010-1012 (incl Fuel and Targets with MA)
bull Demonstration of Closing Fuel Cycle based on Pyrochemical technologies -2016-2020- on a levels
Up to 50 spent FAs of BN-600800Full scale CFC for MFRR from initial fuel loading Other experimental implementations
Characteristic Value
Maximum flux Фmax ncm2middotsec ~ 60middot1015
Thermal power MWth ~ 150
Electric power MWe ~ 50
Number of independent experimental loops (~1 MWth sodium heavy metal and gas coolant + salt coolants)
3 (+1 behind reactor vessel)
Driven Fuel Vi-pack MOX (PuN+UN)
Core height mm 400-500
Maximum heat rate kWl 1100
Fuel Cycle Full Scale Closed FC based on Pyro Processes
Test Fuel Innovative FuelsMA Fuels and targets
Maximum fluence in one year ncm2 ~ 12middot1023 (up to 55dpa)
Design lifetime 50 year
RR creation time (no more than years) 9 (2008 ndash 2016)
New Russian Sodium Fast Research Reactor ndashMulti-functional Fast Research Reactor (MFRR)
Location ndash RIAR site
Start of BN Closed fuel Cycle based on RIAR technologies
2011 - start of vi-pack MOX-fuel production for BN-8002012 ndash start of BN-800 operation2016hellip2018 ndash demonstration of BN-800 closed fuel cycle technologies
Key final official decisionsMOX-fuel production by pyroelectrochemistry andvibropackingTrend to closing of fuel cycle by compact drytechnologiesDevelopment and testing of new fuel and newtechnologies
RIAR RampD International cooperation in the field of advanced FC
Fuel production Repro-cessing
PampT Other Cladding materials
ConceptStudies
Funda-mental StudiesMOX other
France - MA oxide
- AmCm recovery
Pyro + FS Cm
INPRO - - - - - - CPP RUS-2
-
Japan MOX vibro
- MOX MAREEsepar Fluorex
MoO42-
ODS FS MA
Korea - - Metalliz vibro-DUPIC
MAREEsepar
Pyro - - -
US TRU fuel
UREX+1
TRU fuel
- - - Pu in RTILrsquos
EU - MA nitride
- - MSR fuel - - Cm
Red color ndash DOVITA-12 activities
- The RIAR DOVITA-12 PampT Program ndash Current Results of the 15-year RampD activities
- Experience in Closed Fuel Cycle including pyrochemical processes
- Since 1992 RIAR has been performing own RampD DOVITA Program
- Experience in adding of minor actinidesin fuel compositions and results of irradiation
- Slide Number 5
- New times considerationDOVITADOVITA-2
- DOVITA-2
- Research area of pyrochemical and non-aqueous MAFP partitioning in frame DOVITA-2 Program
- Slide Number 9
- Slide Number 10
- Slide Number 11
- Slide Number 12
- Slide Number 13
- Slide Number 14
- Slide Number 15
- Slide Number 16
- Slide Number 17
- Official Investment Frames for Russian Nuclear Renaissance
- Federal Tasks Program ldquoNew Generation Nuclear Energy Technologiesrdquo RIAR planned participation
- Slide Number 20
- Start of BN Closed fuel Cycle based on RIAR technologies
- RIAR RampD International cooperation in the field of advanced FC
-
Experimental constants of CmO+ CmOCl and Cm2O3 dissociation in molten chlorides at different temperatures molality scale
Melt T oC pK(CmO+) pK(CmOCl) pK(Cm2O3)
NaCl-2CsCl 556 42+02 79+02 201+03
650 34+02 75+02 185+03
750 37+02 67+02 168+03
3LiCl-2KCl 450 25+02 62+02 155+05
550 24+02 57+02 127+05
650 083+01 52+02 125+05
NaCl-KCl 750 26+02 59+02 129+04
800 24+02 58+02 126+04
850 13+01 56+02 121+04
ISTC project 3261 Current Results
Comparison with literature data on other actinidesDependence of dissociation constant for actinides upon temperature in LiCl-KCl
0
5
10
15
20
25
1 11 12 13 14
1000T 1000K
pK m
olal
ity sc
ale
CmO+(RIAR)
CmOCl (RIAR)
Cm2O3(RIAR)
AmO+[Lambertin]
AmOCl Lambertin]
Am2O3 [Lambertin]
Pu2O3 [Martinot]
Pu2O3 [Picard]
PuOCl [Picard]
ISTC project 3261 Current Results
Recent RIAR activities in frame of DOVITA-2 Program
RampD for production of vi-pack oxide Fuel with MAUnder continuation
RampD for production of vi-pack nitride Fuel with MAUnder development
RampD for production oxide pellet fuel with MAUnder development
RampD for production metallic fuel with MAFeasibility Stage
Molten Salt chemistry of Am and Cm for fluoridesUnder preparation
Partitioning of MAREE in molten chloridesfluorides liquid cathodesreductive extractionOxide precipitation
Official Investment Frames forRussian Nuclear Renaissance
Federal Tasks Program ldquoDevelopment of Nuclear Power Complex of Russia on a period of 2007 - 2015 ldquo - accepted in 2006
- NPP construction
Federal Tasks Program ldquoNuclear and Radiation Safetyrdquo (2008-2015) - accepted in 2007
- RAW Heritage
Federal Tasks Program ldquoNew Generation Nuclear Energy Technologiesrdquo (2010-2020) ndash on a final preparation Stage
- Innovations
Federal Tasks Program ldquoNew Generation Nuclear Energy Technologiesrdquo
RIAR planned participation
bull Multi-functional Fast Research Reactor (MFRR) - 2016bull Large Multi-Purpose Pyrochemical Reprocessing Complex -
2015Molten salt Reprocessing Facility
capacity ndash up to 2 500 kg of SNF per Year (fuel type oxide nitride metallic IMF)
Fluoride volatility Reprocessing Facility capacity ndash up to 500 kg of SNF per Year (mainly ndash LWR SNF)
bull New Lab for Experimental and Innovative Fuel Production ndash2010-1012 (incl Fuel and Targets with MA)
bull Demonstration of Closing Fuel Cycle based on Pyrochemical technologies -2016-2020- on a levels
Up to 50 spent FAs of BN-600800Full scale CFC for MFRR from initial fuel loading Other experimental implementations
Characteristic Value
Maximum flux Фmax ncm2middotsec ~ 60middot1015
Thermal power MWth ~ 150
Electric power MWe ~ 50
Number of independent experimental loops (~1 MWth sodium heavy metal and gas coolant + salt coolants)
3 (+1 behind reactor vessel)
Driven Fuel Vi-pack MOX (PuN+UN)
Core height mm 400-500
Maximum heat rate kWl 1100
Fuel Cycle Full Scale Closed FC based on Pyro Processes
Test Fuel Innovative FuelsMA Fuels and targets
Maximum fluence in one year ncm2 ~ 12middot1023 (up to 55dpa)
Design lifetime 50 year
RR creation time (no more than years) 9 (2008 ndash 2016)
New Russian Sodium Fast Research Reactor ndashMulti-functional Fast Research Reactor (MFRR)
Location ndash RIAR site
Start of BN Closed fuel Cycle based on RIAR technologies
2011 - start of vi-pack MOX-fuel production for BN-8002012 ndash start of BN-800 operation2016hellip2018 ndash demonstration of BN-800 closed fuel cycle technologies
Key final official decisionsMOX-fuel production by pyroelectrochemistry andvibropackingTrend to closing of fuel cycle by compact drytechnologiesDevelopment and testing of new fuel and newtechnologies
RIAR RampD International cooperation in the field of advanced FC
Fuel production Repro-cessing
PampT Other Cladding materials
ConceptStudies
Funda-mental StudiesMOX other
France - MA oxide
- AmCm recovery
Pyro + FS Cm
INPRO - - - - - - CPP RUS-2
-
Japan MOX vibro
- MOX MAREEsepar Fluorex
MoO42-
ODS FS MA
Korea - - Metalliz vibro-DUPIC
MAREEsepar
Pyro - - -
US TRU fuel
UREX+1
TRU fuel
- - - Pu in RTILrsquos
EU - MA nitride
- - MSR fuel - - Cm
Red color ndash DOVITA-12 activities
- The RIAR DOVITA-12 PampT Program ndash Current Results of the 15-year RampD activities
- Experience in Closed Fuel Cycle including pyrochemical processes
- Since 1992 RIAR has been performing own RampD DOVITA Program
- Experience in adding of minor actinidesin fuel compositions and results of irradiation
- Slide Number 5
- New times considerationDOVITADOVITA-2
- DOVITA-2
- Research area of pyrochemical and non-aqueous MAFP partitioning in frame DOVITA-2 Program
- Slide Number 9
- Slide Number 10
- Slide Number 11
- Slide Number 12
- Slide Number 13
- Slide Number 14
- Slide Number 15
- Slide Number 16
- Slide Number 17
- Official Investment Frames for Russian Nuclear Renaissance
- Federal Tasks Program ldquoNew Generation Nuclear Energy Technologiesrdquo RIAR planned participation
- Slide Number 20
- Start of BN Closed fuel Cycle based on RIAR technologies
- RIAR RampD International cooperation in the field of advanced FC
-
Comparison with literature data on other actinidesDependence of dissociation constant for actinides upon temperature in LiCl-KCl
0
5
10
15
20
25
1 11 12 13 14
1000T 1000K
pK m
olal
ity sc
ale
CmO+(RIAR)
CmOCl (RIAR)
Cm2O3(RIAR)
AmO+[Lambertin]
AmOCl Lambertin]
Am2O3 [Lambertin]
Pu2O3 [Martinot]
Pu2O3 [Picard]
PuOCl [Picard]
ISTC project 3261 Current Results
Recent RIAR activities in frame of DOVITA-2 Program
RampD for production of vi-pack oxide Fuel with MAUnder continuation
RampD for production of vi-pack nitride Fuel with MAUnder development
RampD for production oxide pellet fuel with MAUnder development
RampD for production metallic fuel with MAFeasibility Stage
Molten Salt chemistry of Am and Cm for fluoridesUnder preparation
Partitioning of MAREE in molten chloridesfluorides liquid cathodesreductive extractionOxide precipitation
Official Investment Frames forRussian Nuclear Renaissance
Federal Tasks Program ldquoDevelopment of Nuclear Power Complex of Russia on a period of 2007 - 2015 ldquo - accepted in 2006
- NPP construction
Federal Tasks Program ldquoNuclear and Radiation Safetyrdquo (2008-2015) - accepted in 2007
- RAW Heritage
Federal Tasks Program ldquoNew Generation Nuclear Energy Technologiesrdquo (2010-2020) ndash on a final preparation Stage
- Innovations
Federal Tasks Program ldquoNew Generation Nuclear Energy Technologiesrdquo
RIAR planned participation
bull Multi-functional Fast Research Reactor (MFRR) - 2016bull Large Multi-Purpose Pyrochemical Reprocessing Complex -
2015Molten salt Reprocessing Facility
capacity ndash up to 2 500 kg of SNF per Year (fuel type oxide nitride metallic IMF)
Fluoride volatility Reprocessing Facility capacity ndash up to 500 kg of SNF per Year (mainly ndash LWR SNF)
bull New Lab for Experimental and Innovative Fuel Production ndash2010-1012 (incl Fuel and Targets with MA)
bull Demonstration of Closing Fuel Cycle based on Pyrochemical technologies -2016-2020- on a levels
Up to 50 spent FAs of BN-600800Full scale CFC for MFRR from initial fuel loading Other experimental implementations
Characteristic Value
Maximum flux Фmax ncm2middotsec ~ 60middot1015
Thermal power MWth ~ 150
Electric power MWe ~ 50
Number of independent experimental loops (~1 MWth sodium heavy metal and gas coolant + salt coolants)
3 (+1 behind reactor vessel)
Driven Fuel Vi-pack MOX (PuN+UN)
Core height mm 400-500
Maximum heat rate kWl 1100
Fuel Cycle Full Scale Closed FC based on Pyro Processes
Test Fuel Innovative FuelsMA Fuels and targets
Maximum fluence in one year ncm2 ~ 12middot1023 (up to 55dpa)
Design lifetime 50 year
RR creation time (no more than years) 9 (2008 ndash 2016)
New Russian Sodium Fast Research Reactor ndashMulti-functional Fast Research Reactor (MFRR)
Location ndash RIAR site
Start of BN Closed fuel Cycle based on RIAR technologies
2011 - start of vi-pack MOX-fuel production for BN-8002012 ndash start of BN-800 operation2016hellip2018 ndash demonstration of BN-800 closed fuel cycle technologies
Key final official decisionsMOX-fuel production by pyroelectrochemistry andvibropackingTrend to closing of fuel cycle by compact drytechnologiesDevelopment and testing of new fuel and newtechnologies
RIAR RampD International cooperation in the field of advanced FC
Fuel production Repro-cessing
PampT Other Cladding materials
ConceptStudies
Funda-mental StudiesMOX other
France - MA oxide
- AmCm recovery
Pyro + FS Cm
INPRO - - - - - - CPP RUS-2
-
Japan MOX vibro
- MOX MAREEsepar Fluorex
MoO42-
ODS FS MA
Korea - - Metalliz vibro-DUPIC
MAREEsepar
Pyro - - -
US TRU fuel
UREX+1
TRU fuel
- - - Pu in RTILrsquos
EU - MA nitride
- - MSR fuel - - Cm
Red color ndash DOVITA-12 activities
- The RIAR DOVITA-12 PampT Program ndash Current Results of the 15-year RampD activities
- Experience in Closed Fuel Cycle including pyrochemical processes
- Since 1992 RIAR has been performing own RampD DOVITA Program
- Experience in adding of minor actinidesin fuel compositions and results of irradiation
- Slide Number 5
- New times considerationDOVITADOVITA-2
- DOVITA-2
- Research area of pyrochemical and non-aqueous MAFP partitioning in frame DOVITA-2 Program
- Slide Number 9
- Slide Number 10
- Slide Number 11
- Slide Number 12
- Slide Number 13
- Slide Number 14
- Slide Number 15
- Slide Number 16
- Slide Number 17
- Official Investment Frames for Russian Nuclear Renaissance
- Federal Tasks Program ldquoNew Generation Nuclear Energy Technologiesrdquo RIAR planned participation
- Slide Number 20
- Start of BN Closed fuel Cycle based on RIAR technologies
- RIAR RampD International cooperation in the field of advanced FC
-
Recent RIAR activities in frame of DOVITA-2 Program
RampD for production of vi-pack oxide Fuel with MAUnder continuation
RampD for production of vi-pack nitride Fuel with MAUnder development
RampD for production oxide pellet fuel with MAUnder development
RampD for production metallic fuel with MAFeasibility Stage
Molten Salt chemistry of Am and Cm for fluoridesUnder preparation
Partitioning of MAREE in molten chloridesfluorides liquid cathodesreductive extractionOxide precipitation
Official Investment Frames forRussian Nuclear Renaissance
Federal Tasks Program ldquoDevelopment of Nuclear Power Complex of Russia on a period of 2007 - 2015 ldquo - accepted in 2006
- NPP construction
Federal Tasks Program ldquoNuclear and Radiation Safetyrdquo (2008-2015) - accepted in 2007
- RAW Heritage
Federal Tasks Program ldquoNew Generation Nuclear Energy Technologiesrdquo (2010-2020) ndash on a final preparation Stage
- Innovations
Federal Tasks Program ldquoNew Generation Nuclear Energy Technologiesrdquo
RIAR planned participation
bull Multi-functional Fast Research Reactor (MFRR) - 2016bull Large Multi-Purpose Pyrochemical Reprocessing Complex -
2015Molten salt Reprocessing Facility
capacity ndash up to 2 500 kg of SNF per Year (fuel type oxide nitride metallic IMF)
Fluoride volatility Reprocessing Facility capacity ndash up to 500 kg of SNF per Year (mainly ndash LWR SNF)
bull New Lab for Experimental and Innovative Fuel Production ndash2010-1012 (incl Fuel and Targets with MA)
bull Demonstration of Closing Fuel Cycle based on Pyrochemical technologies -2016-2020- on a levels
Up to 50 spent FAs of BN-600800Full scale CFC for MFRR from initial fuel loading Other experimental implementations
Characteristic Value
Maximum flux Фmax ncm2middotsec ~ 60middot1015
Thermal power MWth ~ 150
Electric power MWe ~ 50
Number of independent experimental loops (~1 MWth sodium heavy metal and gas coolant + salt coolants)
3 (+1 behind reactor vessel)
Driven Fuel Vi-pack MOX (PuN+UN)
Core height mm 400-500
Maximum heat rate kWl 1100
Fuel Cycle Full Scale Closed FC based on Pyro Processes
Test Fuel Innovative FuelsMA Fuels and targets
Maximum fluence in one year ncm2 ~ 12middot1023 (up to 55dpa)
Design lifetime 50 year
RR creation time (no more than years) 9 (2008 ndash 2016)
New Russian Sodium Fast Research Reactor ndashMulti-functional Fast Research Reactor (MFRR)
Location ndash RIAR site
Start of BN Closed fuel Cycle based on RIAR technologies
2011 - start of vi-pack MOX-fuel production for BN-8002012 ndash start of BN-800 operation2016hellip2018 ndash demonstration of BN-800 closed fuel cycle technologies
Key final official decisionsMOX-fuel production by pyroelectrochemistry andvibropackingTrend to closing of fuel cycle by compact drytechnologiesDevelopment and testing of new fuel and newtechnologies
RIAR RampD International cooperation in the field of advanced FC
Fuel production Repro-cessing
PampT Other Cladding materials
ConceptStudies
Funda-mental StudiesMOX other
France - MA oxide
- AmCm recovery
Pyro + FS Cm
INPRO - - - - - - CPP RUS-2
-
Japan MOX vibro
- MOX MAREEsepar Fluorex
MoO42-
ODS FS MA
Korea - - Metalliz vibro-DUPIC
MAREEsepar
Pyro - - -
US TRU fuel
UREX+1
TRU fuel
- - - Pu in RTILrsquos
EU - MA nitride
- - MSR fuel - - Cm
Red color ndash DOVITA-12 activities
- The RIAR DOVITA-12 PampT Program ndash Current Results of the 15-year RampD activities
- Experience in Closed Fuel Cycle including pyrochemical processes
- Since 1992 RIAR has been performing own RampD DOVITA Program
- Experience in adding of minor actinidesin fuel compositions and results of irradiation
- Slide Number 5
- New times considerationDOVITADOVITA-2
- DOVITA-2
- Research area of pyrochemical and non-aqueous MAFP partitioning in frame DOVITA-2 Program
- Slide Number 9
- Slide Number 10
- Slide Number 11
- Slide Number 12
- Slide Number 13
- Slide Number 14
- Slide Number 15
- Slide Number 16
- Slide Number 17
- Official Investment Frames for Russian Nuclear Renaissance
- Federal Tasks Program ldquoNew Generation Nuclear Energy Technologiesrdquo RIAR planned participation
- Slide Number 20
- Start of BN Closed fuel Cycle based on RIAR technologies
- RIAR RampD International cooperation in the field of advanced FC
-
Official Investment Frames forRussian Nuclear Renaissance
Federal Tasks Program ldquoDevelopment of Nuclear Power Complex of Russia on a period of 2007 - 2015 ldquo - accepted in 2006
- NPP construction
Federal Tasks Program ldquoNuclear and Radiation Safetyrdquo (2008-2015) - accepted in 2007
- RAW Heritage
Federal Tasks Program ldquoNew Generation Nuclear Energy Technologiesrdquo (2010-2020) ndash on a final preparation Stage
- Innovations
Federal Tasks Program ldquoNew Generation Nuclear Energy Technologiesrdquo
RIAR planned participation
bull Multi-functional Fast Research Reactor (MFRR) - 2016bull Large Multi-Purpose Pyrochemical Reprocessing Complex -
2015Molten salt Reprocessing Facility
capacity ndash up to 2 500 kg of SNF per Year (fuel type oxide nitride metallic IMF)
Fluoride volatility Reprocessing Facility capacity ndash up to 500 kg of SNF per Year (mainly ndash LWR SNF)
bull New Lab for Experimental and Innovative Fuel Production ndash2010-1012 (incl Fuel and Targets with MA)
bull Demonstration of Closing Fuel Cycle based on Pyrochemical technologies -2016-2020- on a levels
Up to 50 spent FAs of BN-600800Full scale CFC for MFRR from initial fuel loading Other experimental implementations
Characteristic Value
Maximum flux Фmax ncm2middotsec ~ 60middot1015
Thermal power MWth ~ 150
Electric power MWe ~ 50
Number of independent experimental loops (~1 MWth sodium heavy metal and gas coolant + salt coolants)
3 (+1 behind reactor vessel)
Driven Fuel Vi-pack MOX (PuN+UN)
Core height mm 400-500
Maximum heat rate kWl 1100
Fuel Cycle Full Scale Closed FC based on Pyro Processes
Test Fuel Innovative FuelsMA Fuels and targets
Maximum fluence in one year ncm2 ~ 12middot1023 (up to 55dpa)
Design lifetime 50 year
RR creation time (no more than years) 9 (2008 ndash 2016)
New Russian Sodium Fast Research Reactor ndashMulti-functional Fast Research Reactor (MFRR)
Location ndash RIAR site
Start of BN Closed fuel Cycle based on RIAR technologies
2011 - start of vi-pack MOX-fuel production for BN-8002012 ndash start of BN-800 operation2016hellip2018 ndash demonstration of BN-800 closed fuel cycle technologies
Key final official decisionsMOX-fuel production by pyroelectrochemistry andvibropackingTrend to closing of fuel cycle by compact drytechnologiesDevelopment and testing of new fuel and newtechnologies
RIAR RampD International cooperation in the field of advanced FC
Fuel production Repro-cessing
PampT Other Cladding materials
ConceptStudies
Funda-mental StudiesMOX other
France - MA oxide
- AmCm recovery
Pyro + FS Cm
INPRO - - - - - - CPP RUS-2
-
Japan MOX vibro
- MOX MAREEsepar Fluorex
MoO42-
ODS FS MA
Korea - - Metalliz vibro-DUPIC
MAREEsepar
Pyro - - -
US TRU fuel
UREX+1
TRU fuel
- - - Pu in RTILrsquos
EU - MA nitride
- - MSR fuel - - Cm
Red color ndash DOVITA-12 activities
- The RIAR DOVITA-12 PampT Program ndash Current Results of the 15-year RampD activities
- Experience in Closed Fuel Cycle including pyrochemical processes
- Since 1992 RIAR has been performing own RampD DOVITA Program
- Experience in adding of minor actinidesin fuel compositions and results of irradiation
- Slide Number 5
- New times considerationDOVITADOVITA-2
- DOVITA-2
- Research area of pyrochemical and non-aqueous MAFP partitioning in frame DOVITA-2 Program
- Slide Number 9
- Slide Number 10
- Slide Number 11
- Slide Number 12
- Slide Number 13
- Slide Number 14
- Slide Number 15
- Slide Number 16
- Slide Number 17
- Official Investment Frames for Russian Nuclear Renaissance
- Federal Tasks Program ldquoNew Generation Nuclear Energy Technologiesrdquo RIAR planned participation
- Slide Number 20
- Start of BN Closed fuel Cycle based on RIAR technologies
- RIAR RampD International cooperation in the field of advanced FC
-
Federal Tasks Program ldquoNew Generation Nuclear Energy Technologiesrdquo
RIAR planned participation
bull Multi-functional Fast Research Reactor (MFRR) - 2016bull Large Multi-Purpose Pyrochemical Reprocessing Complex -
2015Molten salt Reprocessing Facility
capacity ndash up to 2 500 kg of SNF per Year (fuel type oxide nitride metallic IMF)
Fluoride volatility Reprocessing Facility capacity ndash up to 500 kg of SNF per Year (mainly ndash LWR SNF)
bull New Lab for Experimental and Innovative Fuel Production ndash2010-1012 (incl Fuel and Targets with MA)
bull Demonstration of Closing Fuel Cycle based on Pyrochemical technologies -2016-2020- on a levels
Up to 50 spent FAs of BN-600800Full scale CFC for MFRR from initial fuel loading Other experimental implementations
Characteristic Value
Maximum flux Фmax ncm2middotsec ~ 60middot1015
Thermal power MWth ~ 150
Electric power MWe ~ 50
Number of independent experimental loops (~1 MWth sodium heavy metal and gas coolant + salt coolants)
3 (+1 behind reactor vessel)
Driven Fuel Vi-pack MOX (PuN+UN)
Core height mm 400-500
Maximum heat rate kWl 1100
Fuel Cycle Full Scale Closed FC based on Pyro Processes
Test Fuel Innovative FuelsMA Fuels and targets
Maximum fluence in one year ncm2 ~ 12middot1023 (up to 55dpa)
Design lifetime 50 year
RR creation time (no more than years) 9 (2008 ndash 2016)
New Russian Sodium Fast Research Reactor ndashMulti-functional Fast Research Reactor (MFRR)
Location ndash RIAR site
Start of BN Closed fuel Cycle based on RIAR technologies
2011 - start of vi-pack MOX-fuel production for BN-8002012 ndash start of BN-800 operation2016hellip2018 ndash demonstration of BN-800 closed fuel cycle technologies
Key final official decisionsMOX-fuel production by pyroelectrochemistry andvibropackingTrend to closing of fuel cycle by compact drytechnologiesDevelopment and testing of new fuel and newtechnologies
RIAR RampD International cooperation in the field of advanced FC
Fuel production Repro-cessing
PampT Other Cladding materials
ConceptStudies
Funda-mental StudiesMOX other
France - MA oxide
- AmCm recovery
Pyro + FS Cm
INPRO - - - - - - CPP RUS-2
-
Japan MOX vibro
- MOX MAREEsepar Fluorex
MoO42-
ODS FS MA
Korea - - Metalliz vibro-DUPIC
MAREEsepar
Pyro - - -
US TRU fuel
UREX+1
TRU fuel
- - - Pu in RTILrsquos
EU - MA nitride
- - MSR fuel - - Cm
Red color ndash DOVITA-12 activities
- The RIAR DOVITA-12 PampT Program ndash Current Results of the 15-year RampD activities
- Experience in Closed Fuel Cycle including pyrochemical processes
- Since 1992 RIAR has been performing own RampD DOVITA Program
- Experience in adding of minor actinidesin fuel compositions and results of irradiation
- Slide Number 5
- New times considerationDOVITADOVITA-2
- DOVITA-2
- Research area of pyrochemical and non-aqueous MAFP partitioning in frame DOVITA-2 Program
- Slide Number 9
- Slide Number 10
- Slide Number 11
- Slide Number 12
- Slide Number 13
- Slide Number 14
- Slide Number 15
- Slide Number 16
- Slide Number 17
- Official Investment Frames for Russian Nuclear Renaissance
- Federal Tasks Program ldquoNew Generation Nuclear Energy Technologiesrdquo RIAR planned participation
- Slide Number 20
- Start of BN Closed fuel Cycle based on RIAR technologies
- RIAR RampD International cooperation in the field of advanced FC
-
Characteristic Value
Maximum flux Фmax ncm2middotsec ~ 60middot1015
Thermal power MWth ~ 150
Electric power MWe ~ 50
Number of independent experimental loops (~1 MWth sodium heavy metal and gas coolant + salt coolants)
3 (+1 behind reactor vessel)
Driven Fuel Vi-pack MOX (PuN+UN)
Core height mm 400-500
Maximum heat rate kWl 1100
Fuel Cycle Full Scale Closed FC based on Pyro Processes
Test Fuel Innovative FuelsMA Fuels and targets
Maximum fluence in one year ncm2 ~ 12middot1023 (up to 55dpa)
Design lifetime 50 year
RR creation time (no more than years) 9 (2008 ndash 2016)
New Russian Sodium Fast Research Reactor ndashMulti-functional Fast Research Reactor (MFRR)
Location ndash RIAR site
Start of BN Closed fuel Cycle based on RIAR technologies
2011 - start of vi-pack MOX-fuel production for BN-8002012 ndash start of BN-800 operation2016hellip2018 ndash demonstration of BN-800 closed fuel cycle technologies
Key final official decisionsMOX-fuel production by pyroelectrochemistry andvibropackingTrend to closing of fuel cycle by compact drytechnologiesDevelopment and testing of new fuel and newtechnologies
RIAR RampD International cooperation in the field of advanced FC
Fuel production Repro-cessing
PampT Other Cladding materials
ConceptStudies
Funda-mental StudiesMOX other
France - MA oxide
- AmCm recovery
Pyro + FS Cm
INPRO - - - - - - CPP RUS-2
-
Japan MOX vibro
- MOX MAREEsepar Fluorex
MoO42-
ODS FS MA
Korea - - Metalliz vibro-DUPIC
MAREEsepar
Pyro - - -
US TRU fuel
UREX+1
TRU fuel
- - - Pu in RTILrsquos
EU - MA nitride
- - MSR fuel - - Cm
Red color ndash DOVITA-12 activities
- The RIAR DOVITA-12 PampT Program ndash Current Results of the 15-year RampD activities
- Experience in Closed Fuel Cycle including pyrochemical processes
- Since 1992 RIAR has been performing own RampD DOVITA Program
- Experience in adding of minor actinidesin fuel compositions and results of irradiation
- Slide Number 5
- New times considerationDOVITADOVITA-2
- DOVITA-2
- Research area of pyrochemical and non-aqueous MAFP partitioning in frame DOVITA-2 Program
- Slide Number 9
- Slide Number 10
- Slide Number 11
- Slide Number 12
- Slide Number 13
- Slide Number 14
- Slide Number 15
- Slide Number 16
- Slide Number 17
- Official Investment Frames for Russian Nuclear Renaissance
- Federal Tasks Program ldquoNew Generation Nuclear Energy Technologiesrdquo RIAR planned participation
- Slide Number 20
- Start of BN Closed fuel Cycle based on RIAR technologies
- RIAR RampD International cooperation in the field of advanced FC
-
Start of BN Closed fuel Cycle based on RIAR technologies
2011 - start of vi-pack MOX-fuel production for BN-8002012 ndash start of BN-800 operation2016hellip2018 ndash demonstration of BN-800 closed fuel cycle technologies
Key final official decisionsMOX-fuel production by pyroelectrochemistry andvibropackingTrend to closing of fuel cycle by compact drytechnologiesDevelopment and testing of new fuel and newtechnologies
RIAR RampD International cooperation in the field of advanced FC
Fuel production Repro-cessing
PampT Other Cladding materials
ConceptStudies
Funda-mental StudiesMOX other
France - MA oxide
- AmCm recovery
Pyro + FS Cm
INPRO - - - - - - CPP RUS-2
-
Japan MOX vibro
- MOX MAREEsepar Fluorex
MoO42-
ODS FS MA
Korea - - Metalliz vibro-DUPIC
MAREEsepar
Pyro - - -
US TRU fuel
UREX+1
TRU fuel
- - - Pu in RTILrsquos
EU - MA nitride
- - MSR fuel - - Cm
Red color ndash DOVITA-12 activities
- The RIAR DOVITA-12 PampT Program ndash Current Results of the 15-year RampD activities
- Experience in Closed Fuel Cycle including pyrochemical processes
- Since 1992 RIAR has been performing own RampD DOVITA Program
- Experience in adding of minor actinidesin fuel compositions and results of irradiation
- Slide Number 5
- New times considerationDOVITADOVITA-2
- DOVITA-2
- Research area of pyrochemical and non-aqueous MAFP partitioning in frame DOVITA-2 Program
- Slide Number 9
- Slide Number 10
- Slide Number 11
- Slide Number 12
- Slide Number 13
- Slide Number 14
- Slide Number 15
- Slide Number 16
- Slide Number 17
- Official Investment Frames for Russian Nuclear Renaissance
- Federal Tasks Program ldquoNew Generation Nuclear Energy Technologiesrdquo RIAR planned participation
- Slide Number 20
- Start of BN Closed fuel Cycle based on RIAR technologies
- RIAR RampD International cooperation in the field of advanced FC
-
RIAR RampD International cooperation in the field of advanced FC
Fuel production Repro-cessing
PampT Other Cladding materials
ConceptStudies
Funda-mental StudiesMOX other
France - MA oxide
- AmCm recovery
Pyro + FS Cm
INPRO - - - - - - CPP RUS-2
-
Japan MOX vibro
- MOX MAREEsepar Fluorex
MoO42-
ODS FS MA
Korea - - Metalliz vibro-DUPIC
MAREEsepar
Pyro - - -
US TRU fuel
UREX+1
TRU fuel
- - - Pu in RTILrsquos
EU - MA nitride
- - MSR fuel - - Cm
Red color ndash DOVITA-12 activities
- The RIAR DOVITA-12 PampT Program ndash Current Results of the 15-year RampD activities
- Experience in Closed Fuel Cycle including pyrochemical processes
- Since 1992 RIAR has been performing own RampD DOVITA Program
- Experience in adding of minor actinidesin fuel compositions and results of irradiation
- Slide Number 5
- New times considerationDOVITADOVITA-2
- DOVITA-2
- Research area of pyrochemical and non-aqueous MAFP partitioning in frame DOVITA-2 Program
- Slide Number 9
- Slide Number 10
- Slide Number 11
- Slide Number 12
- Slide Number 13
- Slide Number 14
- Slide Number 15
- Slide Number 16
- Slide Number 17
- Official Investment Frames for Russian Nuclear Renaissance
- Federal Tasks Program ldquoNew Generation Nuclear Energy Technologiesrdquo RIAR planned participation
- Slide Number 20
- Start of BN Closed fuel Cycle based on RIAR technologies
- RIAR RampD International cooperation in the field of advanced FC
-
