The Quantum Mechanical Model - Ms. Blanchette's...
Transcript of The Quantum Mechanical Model - Ms. Blanchette's...
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The Quantum Mechanical
Model Energy is quantized. It comes in chunks.
Quanta - the amount of energy needed to
move from one energy level to another.
Quantum leap in energy.
Schrödinger derived an equation that
described the energy and position of the
electrons in an atom
Treated electrons as waves
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Energy levels
for electrons.
Orbits are not circular
It can only tell us the
probability of finding
an electron a certain distance from
the nucleus – Uncertainty Principle.
The Quantum Mechanical
Model
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The electron is
found inside a
blurry “electron
cloud”
An area where
there is a chance of
finding an electron.
Draw a line at 90 %
The Quantum Mechanical Model
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Atomic Orbitals Principal Quantum Number (n) =
the energy level (shell) of the electron.
Within each energy level the complex math of Schrödinger's equation describes several shapes.
These are called atomic orbitals
Regions where there is a high probability of finding an electron.
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1 s orbital for every energy level
Spherical
shaped
Each s orbital can hold 2 electrons
Called the 1s, 2s, 3s, etc.. orbitals.
S orbitals
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P orbitals Start at the second energy level
3 different directions
3 different shapes (dumbell)
Each can hold 2 electrons
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D orbitals Start at the third energy level
5 different orientations
Each can hold 2 electrons
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F orbitals
Start at the fourth energy level
Seven different orientations
2 electrons per shape
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F orbitals
Images
J mol
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Which orbital is present at
every energy level?
s
p
f
d
All of the above
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How many electrons can a
p orbital hold?
2
6
it depends on the atom
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Summary
s
p
d
f
# of
shapes
Max
electrons
Starts at
energy level
1 2 1
3 6 2
5 10 3
7 14 4
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Filling order
Aufbau Principle = Lowest energy
fill first.
The energy levels overlap
The orbitals do not fill up order of
energy level.
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Showing Orbitals
Counting system
Each arrow is an
electron
Each box is an orbital
shape
Room for two electrons
Pauli Exclusion Principle
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Filling Orbitals
Hund’s Rule
Electrons occupy orbitals
signally until necessary
Fill one electron in each
orbital of an energy level
before pairing
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How do orbitals fill? Lowest energy first
Lowest energy level first
Lowest number first
All the s then p, f and finally d
It depends on the atom
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Incr
easi
ng e
ner
gy
1s
2s
3s
4s
5s
6s
7s
2p
3p
4p
5p
6p
7p
3d
4d
5d
6d
4f
5f
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Incr
easi
ng e
ner
gy
1s
2s
3s
4s
5s
6s
7s
2p
3p
4p
5p
6p
3d
4d
5d
7p 6d
4f
5f
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Electron Configurations
The way electrons are arranged in atoms.
Aufbau principle- electrons enter the lowest energy first.
This causes difficulties because of the overlap of orbitals of different energies.
Pauli Exclusion Principle- at most 2 electrons per orbital - different spins
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Electron Configuration
Hund’s Rule- When electrons
occupy orbitals of equal energy
they don’t pair up until they have
to.
Let’s determine the electron
configuration for Phosphorus
Need to account for 15 electrons
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The first to electrons
go into the 1s orbital
Notice the opposite
spins
only 13 more
Incr
easi
ng e
ner
gy
1s
2s
3s
4s
5s
6s
7s
2p
3p
4p
5p
6p
3d
4d
5d
7p 6d
4f
5f
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The next electrons
go into the 2s
orbital
only 11 more Incr
easi
ng e
ner
gy
1s
2s
3s
4s
5s
6s
7s
2p
3p
4p
5p
6p
3d
4d
5d
7p 6d
4f
5f
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• The next electrons
go into the 2p
orbital
• only 5 more Incr
easi
ng e
ner
gy
1s
2s
3s
4s
5s
6s
7s
2p
3p
4p
5p
6p
3d
4d
5d
7p 6d
4f
5f
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• The next electrons
go into the 3s
orbital
• only 3 more Incr
easi
ng e
ner
gy
1s
2s
3s
4s
5s
6s
7s
2p
3p
4p
5p
6p
3d
4d
5d
7p 6d
4f
5f
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Incr
easi
ng e
ner
gy
1s
2s
3s
4s
5s
6s
7s
2p
3p
4p
5p
6p
3d
4d
5d
7p 6d
4f
5f
• The last three electrons
go into the 3p orbitals.
• They each go into
separate shapes
• 3 unpaired electrons
• 1s22s22p63s23p3
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Label your Periodic Table
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Try out e- configuration with labeled
periodic table
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What is an unpaired electron? A positive electron
An electron in an orbital by itself
An electron in a shell/energy level by itself
An electron that is reactive
All of the above
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The easy way to remember
1s
2s 2p
3s 3p 3d
4s 4p 4d 4f
5s 5p 5d 5f
6s 6p 6d 6f
7s 7p 7d 7f
• 1s2
• 2 electrons
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Fill from the bottom up
following the arrows
1s
2s 2p
3s 3p 3d
4s 4p 4d 4f
5s 5p 5d 5f
6s 6p 6d 6f
7s 7p 7d 7f
• 1s2 2s2
• 4 electrons
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Fill from the bottom up
following the arrows
1s
2s 2p
3s 3p 3d
4s 4p 4d 4f
5s 5p 5d 5f
6s 6p 6d 6f
7s 7p 7d 7f
• 1s2 2s2 2p6 3s2
• 12 electrons
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Fill from the bottom up
following the arrows
1s
2s 2p
3s 3p 3d
4s 4p 4d 4f
5s 5p 5d 5f
6s 6p 6d 6f
7s 7p 7d 7f
• 1s2 2s2 2p6 3s2
3p6 4s2
• 20 electrons
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Fill from the bottom up
following the arrows
1s
2s 2p
3s 3p 3d
4s 4p 4d 4f
5s 5p 5d 5f
6s 6p 6d 6f
7s 7p 7d 7f
• 1s2 2s2 2p6 3s2
3p6 4s2 3d10 4p6
5s2
• 38 electrons
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Fill from the bottom up
following the arrows
1s
2s 2p
3s 3p 3d
4s 4p 4d 4f
5s 5p 5d 5f
6s 6p 6d 6f
7s 7p 7d 7f
• 1s2 2s2 2p6 3s2
3p6 4s2 3d10 4p6
5s2 4d10 5p6 6s2
• 56 electrons
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Fill from the bottom up
following the arrows
1s
2s 2p
3s 3p 3d
4s 4p 4d 4f
5s 5p 5d 5f
6s 6p 6d 6f
7s 7p 7d 7f
• 1s2 2s2 2p6 3s2
3p6 4s2 3d10 4p6
5s2 4d10 5p6 6s2
4f14 5d10 6p6 7s2
• 88 electrons
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Fill from the bottom up
following the arrows
1s
2s 2p
3s 3p 3d
4s 4p 4d 4f
5s 5p 5d 5f
6s 6p 6d 6f
7s 7p 7d 7f
• 1s2 2s2 2p6 3s2
3p6 4s2 3d10 4p6
5s2 4d10 5p6 6s2
4f14 5d10 6p6 7s2
5f14 6d10 7p6
• 118 electrons
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Rewrite when done
Group the energy levels together
• 1s2 2s2 2p6 3s2 3p6 3d10 4s2 4p6 4d10
4f14 5s2 5p6 5d105f146s2 6p6 6d10 7s2
7p6
• 1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6 5s2 4d10
5p6 6s2 4f14 5d10 6p6 7s2 5f14 6d10 7p6
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Exceptions to Electron
Configuration
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Orbitals fill in order
Lowest energy to higher energy.
Adding electrons can change the
energy of the orbital.
Filled and half-filled orbitals have a
lower energy.
Makes them more stable.
Changes the filling order of d orbitals
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Write these electron
configurations Titanium - 22 electrons
Vanadium - 23 electrons
Chromium - 24 electrons
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Write these electron
configurations Titanium - 22 electrons
1s22s22p63s23p64s23d2
Vanadium - 23 electrons
1s22s22p63s23p64s23d3
Chromium - 24 electrons
1s22s22p63s23p64s23d4 is expected
But this is wrong!!
![Page 42: The Quantum Mechanical Model - Ms. Blanchette's Chemistryblanchettechemlab.weebly.com/uploads/3/7/7/1/37713227/e_config... · The Quantum Mechanical Model ... 1s 2s 2p 3s 3p 3d 4s](https://reader030.fdocuments.us/reader030/viewer/2022040904/5e770c084ad7412de83ccd33/html5/thumbnails/42.jpg)
Chromium is actually
1s22s22p63s23p64s13d5
Why?
This gives us two half filled orbitals.
![Page 43: The Quantum Mechanical Model - Ms. Blanchette's Chemistryblanchettechemlab.weebly.com/uploads/3/7/7/1/37713227/e_config... · The Quantum Mechanical Model ... 1s 2s 2p 3s 3p 3d 4s](https://reader030.fdocuments.us/reader030/viewer/2022040904/5e770c084ad7412de83ccd33/html5/thumbnails/43.jpg)
Chromium is actually
1s22s22p63s23p64s13d5
Why?
This gives us two half filled orbitals.
![Page 44: The Quantum Mechanical Model - Ms. Blanchette's Chemistryblanchettechemlab.weebly.com/uploads/3/7/7/1/37713227/e_config... · The Quantum Mechanical Model ... 1s 2s 2p 3s 3p 3d 4s](https://reader030.fdocuments.us/reader030/viewer/2022040904/5e770c084ad7412de83ccd33/html5/thumbnails/44.jpg)
Chromium is actually
1s22s22p63s23p64s13d5
Why?
This gives us two half filled orbitals.
Slightly lower in energy.
The same principle applies to copper.
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Copper’s electron configuration
Copper has 29 electrons so we expect
1s22s22p63s23p64s23d9
But the actual configuration is
1s22s22p63s23p64s13d10
This gives one filled orbital and one half
filled orbital.
Remember these exceptions
s2d4 s1d5
s2d9 s1d10
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In each energy level
The number of electrons that can fit in
each energy level is calculated with
Max e- = 2n2 where n is energy level
1st
2nd
3rd