THALLIUM DATA · 2020. 12. 11. · -3.2-2.6 s7z.dev.-1 o 1 € height (absorbance' apea...

I / 651/3-

THALLIUM DATA

RR103223

cu9

8

1 *G fc£ • t

a ifS S o0 *

$

ine

* £

l_ tfl O4 - 1 - Ue 9O JOO B

0ina

fV

00 —1

u O U

< o —

0322^

•s :I S ,———————————^—————————————————H-^- .b

Ou

in O*f0in0U

- K% <§

V

To 4- In

§VI0i

* €> 0— •03

• O «0>

xSM<3

k^

®-S

OfYSV

1

a

os:S in^ soJ 435 • iz «•O — t-— 0 051 o t.3 S o

! I *J ^_l « Q

Q

^V/N

— (A§"0 4-

-«•

•8

>vo

CX5

in

i

fip

ID

OI0g-

I/Is

0 4" «

III

ARI03225

.•CONT:I>] PEAK HEIGHT <ABSOPBANCEI o' PEAK AREA IABS-SECONDS1 0

READ! 58.4

MEAN* 58-3 3T3.DEV.* 0.2

53.3E-50: READING 3PEATEP THAN HI

59.4 STANDARD 3

TL- 10 os Q tsftuq'lJL)PEAfr HEIGHT (ABSCPBAIMCE; 0PEAK AREA : ABS-SECONDS) 0

PEAD : 51-4 An -7 • / >............... .............y. ti «< /.' ~ LPEAK HEI3HT -' ABSCPBANCE1 0PEAK AREA 1 AE'S-SECINirS 0

READ; 5!. 5

MEAN* 51.4 ST;.DEV.= 3.3

PEAK HEIGHT • ABS^EAMCE- oPEAK AREA (ABS-SECCNES) "

READ! -l.S

PEAK HEI'HT ' ABSCRBANCE ) 0PEAK AREA ( ABS-SECCNrS1 0

PEAD: -2.S

MEAN« -2.1 S7C.DEV.' 0.7

PEAK HEIGHT • A3SORBANCE • 0PEAK AREA .'ABS-3ECONE3) 0

READ: -2.:

PEAK HEIGHT IABSOPBANCEI oPEAK AREA I ABS-SECONDS! 0

READ: -2.5

MEAN» -2.3 3TD.DEV.» 0-2

TL- iooa /$l&/)Jl QfiJL 6PEAK HEIGHT (ABSORBANCE) 0

' PEAK AREA (ABS-SECONDS) 0

' READS 19.5 £jeZ /... ... ....................... __.__/W/.'

PEAK HEIGHT (ABSORBANCE) 0PEAK AREA (ABS- SECONDS) 0

READ: 18.9

MEAN« 19.2 STC.DEV.s 0.4

TI_ 1009 $7//053-O/£PEAK HEIGHT < ABSOPEANCE ) 0PEAK AREA (ABS-SECONDS) 0

llHCMi -2.0

AA.524-375

C;EF,

CHEST iTA!"

AA.5-4.310

^ /i/ /L Jt /

AA *.5"!. 317

::E~.

AA- C32- 32 1

.034

.021

COEF.

.022

.019

AA.020.018

COEF.

.243

. 149

AA.233. 145

COEF.

AA.039.063

:AA0. 3380.220

.VAP.« 0.33 .'

JD APD

3.3373. 131

-.,0. 3373, 131

Vtp. = " • " 't.

3AA

:•. 704

•3 . -3060.300

VA? . - 33 . 32 i

:AA3.0060.002

ZAAo.:o4•3.000

VAP.« 10.50 t

ZAA0. 1440.073

t ..-.. ........<T ZAA

0. 1400.076

VAR.3 2. 15 *

ZAA0.0070.002

BC0 . 2660. 133

BCC.2390. 1 19

BC0 . 2350. 12S

BG0. 3293-017

0-3320.021

0. 31"0.017

3.013P. 017

BG0. 1000.071

BG0.0990.069

BG0.0360.060

26

PEAK HEIGHT 'A350P3ANCE '=EAK AREA .'ABS-SECGNSS'

PEAD: -2-3

PEAK HEIGHT 'ABSCPEAMCEIPEAK AREA (ABS-SECONDS!

PEAD : -2.0

1EAN= -2.4 S7Z.DEV.S

3.;?: -:.•:::

OS- T&bAA ZAA

3.026 O.CCe3. 732 7 . 072

zoC . 0243.730

FG3.02S•3.030

TL- 1 O 1

PEAKPEAK

PEAD:

PEAKPEAK

READ:

MEAN-

Tt-

PEAKPEAK

HEIGHT 'APSOPBANCE)AREA (ASS -SECONDS)

-1.9

HEIGHT (ABSOPEANCE)AREA IABS-SECCNDS'

-3.2

-2.6 S7Z.DEV.-

1 O 1 €

HEIGHT (ABSORBANCE'APEA (ABS-SECONDS)

A

0

03

0.9

00

AA.034. 029

AA. 033.024

AA.034.021

n0

0-0

COEF.VAR. »

0C

ZAA.ooe.303

ZAA.C05.032

35. 85 S

ZAA.003.000

00

00

00

BG. 334. 326

BC.032.026

BC.033.021

PEAK HEIGHT 'PEAK APEA

READ: -3,6

*!EAN* -3.1 STD.DEV.. 0.5 COEF.VAR,. 20.26 t*********»»«*»«***»«jTU 101S f<___ __ _

AA ZAA BCPEAK HEIGHT (ABSORBANCE) 0.596 0.344 0.232PEAK AREA (ABS-SECONDS) 0.322 0.186 0.137

1U... ........................AA ff ZAA BG

PEAK HEIGHT (ABSORBANCE) 0.381 0.332 0.250PEAK AREA (ABS-SECONDS) 3.322 0.184 0.138

READ: 49.4

(1EAN« 49.6 STD.DEV.- 0.4 COEF.VAR.- C.79 t»**«»»»«»»»*»**««»»«»»*«»»»****«»*»»»»»«»#»«»»*«*»»***»**»»»»****»*«»»*4*»»»»»»»

. AA ZAA BG; PEAK HEIGHT (ABSORBANCE) 0.027 o.oos 0.023!PEAK AREA (ABS-SECONDS) 0.031 0.301 0.030

PEAD: -2.4

AA ZAA BGPEAK HEIGHT (ABSORBANCE) 3.023 3.005PEAK AREA (ABS-SECONDS; 0.02S O.OOG

I*JREAD? -2.7 11R

HEIGHT ABSORBANCE' __AREA 1ABS- SECONDS 3.~f«~" 3.

>

i1

t11

(i

ii

MEAN* 23.1 3Tj.

TL. 1 O23 _ Q

PEAK HEIGHT (AESOREANCE'PEAK AREA (ASS-SECONDS'

PEAD: 13.9

PEAK HEIGHT 'ABSCFBANCE!PEAK AREA ( AB3-SECCND5 '•

READ : 13.3

MEANs 13.3 3T7) .

3o sTL. 1 O2-*

PEAK HEIGHT (ABSORBANCE1PEAK AREA (ABS- SECONDS)

PEADi -3.3

PEAK HEIGHT (ABSOP3ANCE)PEAK AREA ' AES-SECGNDS i

\D - -3,3

MEAN- -3.3 S77j .

PEAK HEIGHT (A3SCPSAN3.E)PEAK APEA i ABS-SECONDS •

PEAK HEIGHT (ABSCPBANCE)PEAK AREA (ABS-SECONDS'

READ: 17.9

MEAN- 17,3 STO.

TI- 1026 Q&Ji

PEAK HEIGHT (ABSORBANCE)PEAK AREA (ASS-SECONDS'

P.EADl -3.0

PEAK HEIGHT (ABSOPBANCE)PEAK AREA 1 ABS- SECONDS'

READs -3.1

MEAN- -3.0 S77I.**4*« »«»»*•»»»»«»»»**»»*

TL. lOST" QC(PEAK HEIGHT t ABSORB ANC ElPEAK AREA (ABS-SECONDS)

DEV . = 0 . S

33

"\0

DEV . » 0.1

>DF t dtQ/xJL

00

00

DEV . » 0 . C

njLAQjiteO' 0

0

3Q

DEV . » 0 . 3

• J xxX/A t -00

A

0

DEV.* 0.0*»***»»**»*****_-X)u<7 '-v

00

CQEF.VAR.

) ( JU<jl-l)AA ' '. 135. 1 = 3

AA '. 196. 151

C:EF.VAP,

^AA.044. 323

AA. 347.031

COEF.VAP.

fy/k).241. 147

JU&Qt&lAA ^.236.152

COEF.VAR.

AA.031.019

AA.032.019

COEF.VAR.*»»***tt*»»*««

AA.354,303

= 3.35

ZAA3.1113 . 075

£'ZAA0.111o.o-e

= 3. 42

ZAA3. "'4

0.012

ZAA0.0040.003

* 1 . 29

ZAA3. 12SO.C68

ZAA0. 1270,072

- 4.77

ZAA0.0060.001

ZAA0.0060.002

« 0.33'***»»***

ZAA0.3200. 177

7

EC0.3SS0.077

BC0.0330.373

•t

BC-•3. 3420.031

BC0.0470.033

I

BC0. 1130.073

BC0. Illo.oao

BC0.0290.020

BG0.0310.021

t»»»»»»*»»««§»»»»»»»

BG0.2330.126

JPEAD: ' °........... ........y.. ..........

PEAK HEIGHT ABSOPBANCE'PEAK APEA 'A?S-=E:ONDS:PEAD: -2.2

MEAN* -;,= 3~Z. ?£'/.=

TL 1 O32

PEAK APEA .'A33-5ErCNC5'

AA ZAA3.34S 7.0030.033 3.:-3i

:.s ::£?.<*>., s». -z •

<LO*- &2SitfU)

•iA ZiA

3 . ' 5; .-. . -qg

BC0 . 04g3. 332

0.034

PEAK HEIGHT 'AESCPBANCE'PEAK APEA ;ABS -SECONDS'

READ: 24.1

MEAN- 24.7 S~Z.3EV.»

TL. 1033 _/£)/

PEAK HEIGHT <ABSCRBA?*:E:PEAK AREA 'AES-3E:ON2S>

PEAD: -2.4

PEAK HEIGHT 'ABSOPBANCE.PEAK AREA 'ABS-SECONDS1-

READ: -I. I

MEAN- -1." 372. DEV. *

TL, 103-4 -/QA-clisUQPEAK HEIGHT : ABSOPBADCE 'PEAK APEA • ABS-3EC3NCS!

PEAD: -2.3

PEAK HEICHT 'APSOPE'ANCE)PEAK APEA ( ABS- SECONDS '

PEAD: -2.4

r ,0.

0.8

0.0,

0.0.

0.9

0.0.

£>/3.0.

AA293130

AA035033

AA033033

AA050037

^AA032053

Q -AA0. '.590 . 394

::EF.VAP.= 3.37 \

ZAA5.010•3.001

ZAA0.3107-. 003

C"EF. VAB. = T4. 30 1

ZAA0.0030.301

DZAA0.0113,00!

B:o. :300.095

BG0.3530.032

BG0.0530.05C

BG0. 0433.056

BG3.0490.033

MEAN- -2.4 STZ.5EV.- 0.1 COEF.VAP.« 3.33 t• *«»»*»«»»»»»»»»»»»*»»»«t»»»»»»«»»»«*HH*»l«»»»**»»«*«*»*»*«*t»**»***»»«»»H»»»*

TL, 1 O3S —/ / A1 ' AA ZAA BG

' PEAK HEIGHT (ABSOPBANCE' 3.033 0.033 0.030PEAK APEA (ABS-SECONDS 0.047 0.001 0.046

READ: -2.2

AA ZAA BG'' PEAK HEIGHT ' ABSOPBANCE' 0.033 3.009 0.030PEAK AREA (ABS-3ECONE3 0.049 0.002 0.047

< READ: -2.0

MEAN- -2.1 =72.DEV.- 3.1 COEF.VAR." 3,32 T»*#«»»««•»•«#»•«»»•««*•«*»•«»***»»**»»••»»*«*•*•»******•**•«**••*»*•*»•••»•»*»*«

ARI03229

MEAN-

TL,

PEAKPEAK

READ:

PEAKPEAK

READ:

MEAN-

TL,

PEAKPEAK

READ;

PEAKPEAK

READ:

-2,0

2ooa

........ JC.S7Z-.DEV.

-A/>1HEIGHT (ABSORBANCE)AREA (ABS-SECONDS)

-0.9

HEIGHT (ABSORBANCE)AREA iABS-SECONDS)

-2.3

-1.7

2OO9

STD.DEV.

~/SAHEIGHT (ABSCRBANCE)AREA (ABS-SECONDS)

-2.2

HEIGHT (ABSOPBANCE)AREA i ABS-SECONDS;-2.4

a ^J ^*r ^^T

0.0.

0.0.

1. 1

0.0.

0.0.

COEF.

AA047034

AA049052

COEF.

AAC35079

AA060073

VAR.a 35.16

ZAA0.0090.006

ZAA3.C093,000

VAR.= 65.43

ZAA0.0120.002

ZAA-3.0113,001

I

BG0.0440.048

BC0.0460. 052

BC0.0363.077

BG0.0610.072

MEAN- -2.3 3T2.EEV.= 0.1 COEF.VAP.= 5.97 tt»««*t*«*»»«*»*«**»«**«***«»«»««*»«»**«»*»ttt»*«**«»******««*****»**»*»»******»*

TL. 2010 -/(» AL{J> AA ZAA BG

PEAK HEIGHT (ABSOPBANCE) 0.075 O.OC7 0.073PEAK AREA (ABS-SECONDS) 0.095 0.002 0.093

READl -2.0

PEAKPEAK

READ:

MEAN-

HEIGHT 'ABSORBANCE)AREA (ABS-3E:3NDS:

-'.,3

-1.9 S73.DEV.-

AA0.0730.095

0. 1

ZAA0.0113.003

COEF.VAS.- 4.63 V.

EG0.0800. 392

TL, 2011

Jt

i

•i&

PEAK HEIGHT (ABSORBANCE)PEAK AREA (ABS-SECONDS)

READ: -1.3


READ: -0.4

MEAN- -0.9 S7D.DEV.-*********»*«*»»******»***»***»*<HTL, 2012 _/7 fi£)Q


READ! -1.3... ————— .---.---.-....... —— -.

PEAK HEIGHT, WlSMAJJCfW o n"FXMt MI* »if W$P}/ 3 0 .

AA0.0680.077

AA0.0630.079

0.7***********

/^ AA0.0880. 129

...0/...3

AAo.oat0.13»

ZAA0.0100.003

ZAA0.0030.003

COEF.VAR.- 79.90 Ii*»***»*«* ************

ZAA0.0120.003

Pb

ZAA0.0100.004

BG0.0660.072

BC0.0610.071

!•**»»•**»***»»*

BC0.0830.123

BC0.0900.193

TASK;"

ARSENIC DATA

ft-R 10323!

<

<

[i>)hiiif.

(

•

1

\

^

I

>

•*

^

Q

t

^

>

*

I

rr3

>->

[A3

6s -8--*• o sra i »«/» a noby certify that allMng procedures exc(»

•e-f aa aUI —

2" wO A

o" a<A a.•••8a«<

9-*o

8noUI

a5!?lowed accord li

"$e-t

iUI

aa.

r

d

<r

i?

o

c.

b

u

O

6

00jo

<V

LU

\

Jo

&

#s

[ivQ

••,

»

*

A

5L>

teSi

r

£

AJ

>

-t

^

Q

^

CM

*

i00U)

o

I'

u

=0o

f0

Oo

s

L-

*

=

o0

*0

Oiit

P

PI

S

5

s

c

5

d

*

in

• ^

"0o

f-J

^

fx»

?t*

^

i5•c.IM

•+,

suWl

l>o

Gi04~J

7|

Oit]

y

J;

o

ft^

O

£

I

'—

I

O

•**

"\

0

0

b30

)

i

1

JDb

Uio3

£§

co

r

V

U)

I

i

r

S

X.

^

^

p

-O

f

O

ol5"

r?>

n

zoo

-n2

Tt * 0

3 (OI O •— 1

ss5§=^2^— C Q. —

? O

33

D

7 o a

R 1 ft 3?

O

S

o

antrat lor

•

32

mmsin•*

S

o$$«

i"4

100-0

•

>9G>IB<UI•*

X Oo o5- i? sB a

••

AnV*

O

Contraci

ise Numbers _

^

1a0

TJ

ii

1

m•»ED13

CN

s.

-4-

«

TJS

*J

O>

k

«fcc1aICL

H-

i_^_^•

* -Q

4-

I

1 IIzo

ioi/5

<

w>

i

<

C1"**.

4-e

2.UJ

'

I0 g>

Ua.>>o(00

_l+-Ku tfl4- Ue 0o 4o 1

0tfia0

«nL.0

|• •

7 O

5 I

§ O0 X

4->

1

r*»itxi

0

I

4»

4-UIeI

•c

4-

4-9

u

_l

_J

0

——— 7»~

•*

C 6 *^*** O Cu.o=s

XaI

at

0

0 *O tflJC 0 0 4"— •O3 —a."o L. eto < H- 3

. ,tj "3 t

^m • •

O » tZ

||

* • tf

5oiu

+•

< (f 1

0

Is

&

rj0V

1<X,

)^

0

M

r-7"

C

C

K

^

O1

\XOCr-

JO<X

«s

CX

0NJ

*4

C

C"Si

05

Do

r0

V

*«,

0

V

^ 1^^

^

V?.

<r

\f*Oo

J]"

^

.1

*

1bm

orCO

O

o>

o-«V3

~

S3

0•

S0^r

—

.7\Jo-

^

Oo

*

cr

<*;?

C *

f<v

<•

V

O

V

1

.

OC3cYn

5

Ofr

V

Oi

OfV

1

00c*;f

2

fc

V

^*

(•

0

V

t

«

* *•^

f3

U)

or

V

t

^

r

.

!»

P

tfl

rO

V

OaV

'

OC

^

rtr

V

O•P|\j

1

06J

C1

t

0>

K-*1.

.

s~

c1

_^o-eO

^TN" F1

G' *.^ >

r

o-

^'

fr- oX,

C

Q^

,

^*r

cO•r "^

'A^— %

CK9po

rfo0V

"*"

^

•iVJ

1

^ rJ^v i

•*

•oo•oID•»-tfl

1L.3Uo

c•oou

^*o

50u•

o3

"98

"ou§u4-

15•o uie »a <oM —0 Otf» <*-— Mn cC 4-

fc— 0~n xe m4- U^M 5

U9 O,

w nf 1

ARI03233

I0 L.

%

e

a

UJ

JO

flu4-

0

M O4- U O

0tfl

5

O 0UJ 4

J fi— — •§ Qa, o t. S= b O O

23 e u* J 5

UI 3

•^« £c?cQ O T V ' ~ 1"~1' ~ 1^ -~l •*•"*—4-1— -*— ~ ftj

0 §

o

*tflo

9

U tfl4- L.e 9O 4O s

120

— L,0 0 — •

QS3. u O OO 9.i i 1u *

iui— 0 4- «h0 4- tfl ~CO

M a.f si

"0 O 4-C C —

tZ 0 =

tfla

4

** at

93i_ —

000 -p tflJC 9 9 4-— T3 3 —a.-o k. eto<»- =

<xk ,o i

U —

o at u

e^ c4-£

.2*

•«vO * • 10i o y 4j

To o jo o a

>u

dt'i c£|

0?2

(X3 «O

—

«Joo

a

^ ^

"

ro

»{V-t

c-

\G~

O

r--

fo

Cfe

^O

^ VI

0

:r•**

rb

OSrt

«+•^Q1

fO

Oo

VT

^O~•

o

r4"•

crT-

^ *

$l

(

r—

^

•3«!» «0

m^

a.*

^• N.

M

CT

1C

aV

Ci-*

-sj

G

^— -

•3-

.j

C|o

1

V

Qri

1

" ,

'-0*~-^

^

^

^1jK\-1

**>*.

rix-

CM

Q

J

i

rvro<}

-3

f B 03<:3j•

.-, . ... ... . . , . . . . . . ' (^

•OO

in

u

O

9OU

IM0

o

0

S-_tS tfiO £UI —

— (A0 ao 4-

0. .-8-*

«

\

PEAK AREA (ABS-SECONDS)/^' ^^ Q. 33S " 0.271 0.065

MEAN- 40.3 STD.DEV.' O.S COEF.VAR." 1.38 X

40.3 E-23s READING GREATER THAN HIGHEST STANDARD.itttttnt****** *****************************************************************

40. 1 STANDARD 2»»«»»**»**t*»*tt*«*««*»»»*»*»**»****»***»*»*»»**»*»***»«»»»tt»*»t**»»***«»»»«»*»AS

AA AA-8C BCPEAK HEIGHT (ABSORBANCE) 0.7S9 0.749 0.024PEAK AREA (ABS-SECONDS) 0 . 4SS 0.399 0 . 06S

39.2

A A AA-BG BGPEAK HEIGHT (ABSOPBANCE) 0.749 0.729 0.023PEAK AREA (ABS-SECONDS) 0.475 0.412 t O.OS4

(CONTINUED)61. 1

MEAN- SO.2 STD.DEV.« 1,4 COEF.VAR.a 2,27 t

60.2 E-25: READING GREATER THAN HIGHEST STANDARD.****************************»***********t*ntt***********************************

60.1 STANDARD 3************************* ************.****Jt****f *********************************AS 1001 UJS3T1-M "Ht I /oo-/ -<-

AA AA-EC BGPEAK HEIGHT (ABSORBANCE) O.S16 0.394 0.023PEAK AREA (ABS-SECONDS1 0.373 0.306 0.067

45.6

AA AA-BG SGPEAK HEIGHT (ABSORBANCE) 0.603 0.378 0.023PEAK AREA (ABS-SECONDS) 0.376 0.309 0.068

46.0

MEAN" 43.8 STD.DEV." 0.3 COEF.VAR." 0.63 X****»*•»»*•***»*••»***••**••**•»»»»*»***»•»••**»»*•**•»•»»•*••••»•»»»•»»•»*•»**«

AS 1002A A AA-BG BG

PEAK HEIGHT (ABSORBANCE) 0.024 0.008 0.024PEAK AREA (ABS-SECONDS) 0.039 -0.006 0.065

0.3

A A AA-BC BGPEAK HEIGHT (ABSORBANCE) 0.026 0.008 0.024PEAK AREA (ABS-SECONDS) 0.053 -0.010 0.064

-0.3

MEAN-. 0.0 STD.DEV.- 0.4 COEF.VAR.- 99.99 X»*»»*••»•«**••«••*•«#•»»••»»»•»•••*•••»••*•**•*«•**•*•*•*•**•*»•****»*»********«AS 1003 SjUe. soso P ti-a

AA AA-BC BCPEAK HEIGHT (ABSORBANCE) 0.028 0.007 0.027PEAK AREA (ABS-SECONDS) 0.056 -0.010 0.063

-0.3 _____________............................. ^ AA-BC BC " ,


-0.4

NEAN."""-0~3~ STD.OEV.. J;,,,. ; .. ..J.,,..,AE«I»0\? 7 "? £HE -******-Or"****STD"EV?-*******"r****COEF?VAR?**"|?irr* ^ O t3/TV?... ..-,,....,,.,................*••..•»•*»••»••••*»•••••»»•*••••*•»•**•****»

\ 37.6..................... y. ...........


38.2

MEAN' 37.9 STD.DEV,'

AS 1010 -If 1

PEAK HEIGHT IABSORBANCE)PEAK AREA (ABS-SECONDS)

33.0

PEAK HEIGHT (ABSOPBANCE)PEAK AREA (ABS-SECONDS)

37.6

MEAN' 37.3 STD.DEV.'

AS 1 O 1 1 C aJj i


2.4

PEAK HEIGHT (AESORBANCE)PEAK AREA (ABS-SECONDS)

-0,2

MEAN' 1. 1 STD.DEV. «

AA AA-BC0.513 o,3400.553 0.233

0,4 COEF.VAR. a 1.15 *

AA AA-BG0.612 0. 3410.639 0.254

A A AA-BC0.619 0.3520,542 0.231

0.3 COEF.VAR.* 0.72 1-

AA AA-BG0.098 0.0330.129 0.009

AA AA-BG0.033 0.0110.063 -0.009

1.9 COEF.VAR.' 99.99 *

ASS 1O12 OJS37f-/W (.*4<t>) ^fX-ti-c.

1 O 1 2 (CONTINUED)AA AA-BC

PEAK HEIGHT (ABSORBANCE) 0.609 0.582PEAK AREA (ABS-SECONDS) 0.369 0.300

44.7


44.9


AS 1O13 $Zfc 30J-0


-0.3


-1. 1

MEAN" -0.7 STD.DEV."

AS 1 O 1 •* Q He. (jrm


20.3

PEAK HEIGHT i ABSORBANCE)PEAK AREA (ABS-SECONDS)

20.6

MEAN- 20.3 STD.DEV.-

MEAN- 20.3 STD.DEV.-

---.- E-02» ELECTRONIC*»•••••**••••«••••••«*•«•••••»•••»«

AA AA-BC0.5S2 0.5630.365 0.301

O.I COEF.VAR.' 0.18 t

H-IfoA A AA-BC

0.096 0.0080.059 -0.009

A A AA-BC0.028 0.0060.052 -0.015

0.6 COEF.VAR.- 85.69 t.

<SP£* C ie lOOY. .-CO.A A AA-BG

0.325 0.3010.191 0.132

A A AA-BG0.333 0.3100.196 0.134

0.2 COEF.VAR.' 1.08 t

29.0 COEF.VAR.- 99.99 %

RANGE OF INSTRUMENT EXCEEDED

BG '0.2SO0.397

BC0,2720.335

BC0,2740,391

BG0,0700, 120

BC0.0300.072

BG0.0270.069

BC0.0260.064

BG0. 1140.078

BC0.0240.066

BG0.0260.059

BG0.0260.062

. •

AS 10 IS 7 7 I 10 5"*? -o I I'.AAa Q \ \ \ .1 Afc-Bfc * BG

PEAK HEIGHT (ABSOR1ANCE) 0.7lQr\ » U 0.623 0.179PEAK AREA (ABS-SECONDS) 0.762 0.308 0.234 i

PEAK HEI3HT ( ABSORB/5(«E •"•"' -^ 'PEAK AREA ( ABS-SECOJTCS )

17,3


17.3

MEAN" 17.4 STD. DEV. » 0

AS 1 02 1 ~f)j

1 O2 1 (CONTINUED)


0.3

PEAK HEIGHT iABSORBANCE)PEAK AREA (ABS-SECONDS)

-0.2

MEAN. 0.3 STD.DEV.' 0

AS 1 O2 1 —OS.


2.6


3. 1

MEAN" 2.3 STD.DEV.. 0

— O A - *

AS 1022


3.3


3.8

MEAN- 3.3 STD.DEV.- 0

AS 1 023 QjJ &.


3.4


2.3

MEAN* 2.3 STD.DEV.. 0

AS 1023 Q^J &-L


2.2

PEAK HEIGHT (ABSORBANCE) " >>PEAK AREA (ASS- SECONDS)

AA0. 2760. |30

AA0,2310. 192

.2 COEF.VAR

i : too

AA0.0350.069

AA0.0310.053

.7 . COEF.VAR

AA0.3351.057

AA0.3421. 149

.4 COEF.VAR

AA0.3551.234

AA0.3701.235

,1 COEF.VAR

Z*AA

0. 1710.307

AA0. 1080.222

.8 COEF.VAR

AA0.0830. 173

Io8S2380. 149

0. I 1 l

AA-BG0,2490, 1 13

,. 1.14

AA-BC0-010-0.002

AA-BC0.011-0.009

.' 99.99

AA-BC0,0230.010

AA-BG0.0260.014

.- 13.17

AA-BC0.0290.019

AA-BC0.0320.018

. - 1 . 37

AA-BG0.0280.016

AA-BC0.0250.008

.. 27.99

AA-BC0.0220.008

o.ota0.004

- 0 . 0 350. 078

BG0.0330.079

X

BC0.0230.071

BC0.0300.074

X

BG0.3401.047

BC0.3471.133

X

BGC.3621.213

BG0.3701.267

X

BG0. 1480.291

BG0.0940.214

X

BC0.071 •0.167

0.0360. 141

;

1 PEAK AREA (ABS-SECON^^ *—'

39.3


MEAN- 57,2 STD.DEV.'

---.- E-02: ELECTRONIC

AS 1 030 ?7« OS'f


5.0

AS 1 O3O -OS"

PEAK HEIGHT (ABSORBANCE)PEAK APEA (ABS-SECONDS)

9.2

AS 1 O3O - 0 S


32.4


41 .2

3.3331 . 196

3.3

30.3

RANGE OF

- OS /AA

0. 1360.302

t : zxaAA

0.2200.259

I - toAA

0,3490 . 773

AA0.6300.831

0.4080.404

COEF.VAR.. 6.36 x

COEF.VAR,* 99.99 X

INSTRUMENT EXCEEDED.

• / O OAA-BC0.0430.027

AA-BC0.1310.036

AA-BC0,4390.215

AA-BG0.5270 . 276

0 . 346 10.792 ^

BC0, 1660.275

BC0.0910.214

BC0 . 3740,550 1

BG0.2160.553

MEAN' 36.3 STD.DEV.- 6.2 COEF.VAR.' 16.97 X

AS\ 1 O3 1

PEAK HEI^MT (ABSORBANCE)PEAK AREA TAM-SECONDS)

50.3 \

AS 1 O3O -0<3


23.6


23.1

MEAN- 25.9 STD.DEV..*****#»»**»***»»» ***************AS 1031 -0,5


42. 1


44.6

AA0.8750.909

/- 6AA

0.5310.639

AA0.4570.397

3.9**********»<a* •*-*

AA0.7620.715

AA0.6760.725

AA-BG0 . 7700.342

AA-BC0.3990. 189

AA-BC0.3540. 151

COEF.VAR.. 13. 16 X>***»***»****»*»***»*»<>-4. c s) 6 f %

AA-BC0.6570.282

AA-BC0.5780.299

BC0.3660.567

BC0. 1900.450

BC0 . 2720.446

***************

BG0.2430.433

BC0.2320.425

MEAN- 43.3 STD.DEV.- 1.8 COEF.VAR.- 4.22 X»••»»••*»»••••*»**»»«»»»•»*»»••»»*••••«••••»•»»*•»*•••*••*»**«•••**»*»»»*»«*»*«AS 1032 -OS / '• 2-W

AA AA-BC BCPEAK HEIGHT (ABSORBANCE) 0.195 0.112 0.085PEAK AREA (ABS-SECONDS) 0.266 0.048 0.216

i .....M........................................................................{ AA AA-BC BCJ PEAK HEIGHT (ABSORBANCE) 0.182 0.112 0.076

PEAK AREA (ABS-SECONDS) 0.233 0.046 0.137

( 7.8

MEAN- 8.0 STD.DEV.- 0.2 COEF.VAR.- 2.64 X******»********************»*******»******f»***********f ******************AS 1033 -OS &* ~f* lt-SJ ?•?/-*-<-

AA AA-BG BCPEAK HEIGHT (ABSORBANCE) 0.50S 0.433 0.074PEAK AREA (ABS-SECONDS) , „ 0~3«J n n 0.210 0.173

31.6

AA AA-BC BG

_ 35.3 STD/fTS?-. O>£> /-.g.9 COEF.VAR.. 99.99 * .,t«*»«»*»** ******»**|P'** *•*»*»»«»»«»«»**»»»«*»«»»»«•»«*»•••«.»»•»••»«»«••»»••••» I----- E-02t ELECTRONIC RANGE OF INSTRUMENT EXCEEDED.

»»»#»«»»*»»»»»*»*»*»*»»*»**»«*»*»«*«»*»•«»**»»«*»»«»»»»»»*»»»»»«*»»»*»*»*»»««»»» |AS 2OO3 -O 6 c: 2.O

A A AA-BC BCPEAK HEIGHT (ABSORBANCE) 0.608 0,563 0.058PEAK AREA (ABS-SECONDS) 0.473 0.330 0.143

49. 1

AA AA-BC BCPEAK HEIGHT (ABSORBANCE) O.SI3 0.574 0.046PEAK AREA (ABS-SECONDS) 0.462 0.327 0.133

48.7

MEAN- 48.9 STD.DEV.' 0,3 COEF.VAR.. 0.60 X**»********************************»***_************************** ********** *****AS ZOO-4 -& (, Qifr' djULf I •' Z-°

^AA AA-BG BGPEAK HEIGHT (ABSORBANCE) 0.711 0.666 0.043PEAK AREA (ABS-SECONDS) 0.527 0.401 0.123

39.5


59.8

MEAN" 59.6 STD.DEV.'

AS 2OOS —Od>



AA0.7120 . 527

0.3

CLu dii.AA

0.6230.440

AA0.6190.441

AA-BC0.6710.404

COEF.VAR.. 0.43 X.O 1 '. £, O

AA-BC0.5830.322

AA-BC0.5800.323

BC0.0470. 123

BG0.0440. US

BC0.0420. 118

MEAN- 48.0 STD.DEV.. 0.2 COEF.VAR.. 0.38 Xt*******************************************************************************AS 2006 8111 O-Tf -0<+ «-\, /-'*fO

AA OM-f AA-BG BG: PEAK HEIGHT IABSORBANCE) 0.289 0.237 0.036


: 17.7i ................................................................................

AA AA-BC BCPEAK HEIGHT (ABSORBANCE) 0.280 0.246 0.035PEAK AREA IABS-SECONDS) 0.201 0.110 0.091

17.1

MEAN' 17.4 STD.DEV.. 0.4 COEF.VAR.- 2.46 X********************************************************************************AS 2006 Tl4/ I •' V°

SI ~l" •" AA AA-BG BCPEAK HEIGHT (ABSORBANCE) <U<<* " Q.301 0.269 0.036PEAK AREA (ABS-SECONDS) 0.204 0.113 0.092

17.3


ts.oMEAN- 16.2 STD.DEV.. 1

AS 2OO6 -t3< C.

PEAK HEIGHT (ABSORBANCE) &"-**'•?PEAK AREA (ABS -SECONDS )

17. 1


17.2

AA0.2230.207

.8

AA0.3060. 197

AA0.3020.199

AA-BG0.2010.095

COEF.VAR.- 11.00 X

AA-BC0.2730.110

AA-BC0.2720.111

BG0.1530. 112

BG0.0350.087

BG0.0340.088

MEAN- 17.1 STD.DEV.. 0.1 COEF.VAR,- 0.42 Xt*******************************************************************************AS 2OO?" QMt. 304-0 II-IJ

AA AA-BC BCPEAK HEIGHT (ABSORBANCE)c n { flOO?!**3!2 0.014 0.027PEAK AREA (ABS-SECONDS) H fl I U U £ H455 -0.003 0.077

0.7

1 3.6

MEAN" 3.9 STD.DEV. «


27.3


28. 1

MEAN" 27.7

AS 2O 1 3

STD.DEV.'

-0 A


1 .4


0.7

MEAN- 1 . 1 STD.DEV..

0.4

AA0.3540.375

AA0.3380. 330

0.5

AA0. 1220. 179

AA0. 1230. 175

0.5

COEF.VAR.' U. 19 X

AA-BG0.2990. 180

AA-BC0.2890. 136

COEF.VAR.' 1.92 X

AA-BC0.0230.002

AA-BC0,020-0.003

COEF.VAR.. 49.03 X

BC 10.1120.193 '

BC0. 1170, 195

BC0. 1250. 176

BC0. 1270. 178

2O 1 -4 (CONTINUED)


1.5


1.3

MEAN- 1,4 STD.DEV." 0********* ******** *************»*»*»uAS 201S -0,3 SJ.


1.2


0.6

MEAN- 0.9 STD.DEV." 0t************************************

AA0. 1010. 166

AA0. 1090. 173

.2**#»«»)

" AA0. 1120. 171

AA0. 1100. 157

.4*•»»**<

AA-BC0.0230.003

AA-BG0.0240.001

COEF.VAR.. 11.39 X»****»******»*»»**»»**<L-*y

AA-BG0.0190.001

AA-BG0.025-0.003

COEF.VAR.. 48.94 X»»*•**«*•**»»**»*»»**»'

BG0. 1040.163

BG0. 1070. 171

***************

BG0. 1140. 171

BC0. 1150. 170

AS 2O 1 6 — O<-fAA AA-BC BC


0.6


0.8

MEAN- 0.7 STD.DEV..

AS 20 i ;*• -oPEAK HEIGHT (ABSORBANCE)PEAK AREA (ABS-SECONDS)

0.9

PEAK HEIGHT (ABSORBANCE) » rPEAK AREA (ABS-SECONDS) £| \

0.9 . ,

'nutlr 0.9 STD. DEV."

AA0. 1180. 189

0. 1

SAA

0. 1330.200

UOSiS0.0

AA-BC0.014-0.002

COEF.VAR.. 18.57 X

AA-BG0.013-0.001

4. 0.0191 -o.ooi

COEF.VAR.. 1.2B *

BC0.1230. 191

BG0. 1280.201

BC0 * i 3s0 « 203

_..„.-.--— .....§r.. ......PEAK HEIGHT (ABSORBANCE)PEAK AREA I ABS-SECONDS)

46.4

MEAN' 46,1 STD.DEV.'»*»»*»»*»»»»»*»**»»»**»**»»*«»*<AS 2O23 QJJe.


-0.4


0.2

MEAN. -0.1 STD.DEV.'

AS 2O2-<4. BJLk-


19.3

PEAK HEIGHT (ABSORBANCE)PEAK AREA I ABS-SECONDS)

20.4

MEAN" 20.1 STD.DEV..

AS 2O2S ^ t f f


44.9


49.5

AA0.6600.388

0.3»»*»»«»*«*»»(3 QSO F

AA0.0230.064

AA0.0270.064

0.4

Ccwi S fitAA

0.2580.202

AA0.2540.204

0.4

AA0.7100.932

AA0.7611.013

AA-BC0.5400.31 1

COEF.VAR.' 0.63t******************

// -17AA-BC0.010-0.010

AA-BG0.008-0.006

COEF.VAR,. 99.99

C -Z.-0 i 1 oo /.AA-BC0.2370. 129

AA-BG0.2320. 133

COEF.VAR." 2.04

k*a AA-BG0.2720.301

AA-BG0.3120.333

BC0.0230.077

X******************

BG0.0260.074

BC0.0230.070

X

BG0.0290.073

BC0,0260.071

X

BG0.4600.631

BC0.4760.681

MEAN. 47.2 STD.DEV.. 3.2 COEF.VAR.' 6.80 Xt******************************************************************************.AS 2O26 f_o 711 055 -Of / ' 10

2O26 (CONTINUED)


S.?

AS 2O26 — 0 "> '


17.3


19.4

MEAN. 18.4 STD.DEV,. 1

AA0,2090.238

AA0.3070.332

AA0.3540.363

.5*******

AA-BC0.0960.053

AA-BG0. 1650. Ill

AA-BC0.1900. 126

COEF.VAR.. 8.19 X**»**•**•***••*•*.»»

BC0. 1200.184

BG0. 1520.221

BG0.1630.237

AS 202 " —09 £2 < «-T "*:AA AA-BC BG


43.2

AA AA-BG BCPEAK HEIGHT (ABSORBANCE) 0.530 0.407 0.151PEAK AREA (ABS-SECONDS) 0.534 0.303 0.231

43.2

MEAN- 43.2*•»•»»•»*•»*******•AS 20!

STD.DEV.. Q D «.*} O^QEF.VAR.. 0.12 X•••••••••»»**%i»*»«t*|j>*fc5»j*f»«5S»**»**»*»»»»**«—yo f • " ~>

1.8 STD . Dlfer . 7.6 COEF.VAR.. 90.19 X.•***««*********»«»***»***fi*»«****»>***********»**»***. tj, ***********************

- Cfe>J ¥4 -AS 2033 cjsa-rr-i'-t cv&; <?4-,AA AA-BG BG

PEAK HEIGHT (ABSORBANCE) 0.492 0.473 0.028PEAK AREA (ABS-SECONDS) " 0.369 0.290 0.080

43.2

AA AA-BC BCPEAK HEIGHT (ABSORBANCE) 0.484 0.463 0.023PEAK AREA (ABS-SECONDS) 0.374 0.299 0,075

44.5

MEAN" 43.9 STD.DEV.. 0.9 COEF.VAR.' 2.05 X»»»*»»*»****»»**«*»••»•**»*»»**»»**»**»*»**»*****»***»»«*»»**»**»«*•*»»*•*»»»*»»AS 203*4 —(3 I ' J.

AA AA-BG BCPEAK HEIGHT (ABSORBANCE) 0.608 0.405 0.209PEAK AREA (ABS-SECONDS) 0.631 0.342 0.289

50.9

AA AA-BC BGPEAK HEIGHT (ABSORBANCE) 0.652 0.431 0,232PEAK AREA (ABS-SECONDS) 0.638 0.363 0.319

54.7

MEAN" 52.8 STD.DEV.. 2.7 COEF.VAR.. 5.12 Xt*******************************************************************************AS 2O3S —/ V / •' A

A A AA-BG BCPEAK HEIGHT (ABSORBANCE) 0.578 0.336 0.244PEAK AREA (ABS-SECONDS) 0.607 0.273 0.332

41. 1


41.S

MEAN' 41.4 STD.DEV.- 0.3 COEF.VAR.. 0.80 Xt*******************************************************************************AS 3OO3 —/S /•'«•?


61. 1

AA AA-BC BGPEAK HEIGHT (ABSORBANCE) 0.706 0.471 0.247PEAK AREA (ABS-SECONDS) 0.756 0.395 0.361

58.6

MEAN' 59.9 STD.DEV.. 1.8 COEF.VAR.. 3.04 Xt*******************************************************************************AS 3OO-4 — I (a f ' A

._. ,_ AA AA-BC BC3%f,' .~ it PEAK HEIGHT (ABSORBANCE) 0.797 0.514 0.293


58.8

A A AA-BG BGPEAK HEIGHT (ABSORBANCE) 0.846 0.360 0.299PEAK AREA (ABS-SECONDS) 0.362 0.414 0,449

61.2

MEAN- 60.0 STD.DEV." 1.8 COEF.VAR." 2.92 Xt*******************************************************************************AS 300S ~/-7 t:+tA


62.2


61.5

MEAN* 61.9 STD.DEV." O.S COEF.VAR." 0.73 Xt*******************************************************************************AS 3003 ~ / "7 /•' V

AA AA-BC BCPEAK HEIGHT (ABSORBANCE) 0.430 «. !.<!}• 286 0.202PEAK AREA (ABS-SECONDS) B O4$lf\ .1 L H &203 0.289

30.6

._-?:?.......-...~MEAN" 0.3 STD.DEV.' 0.7 COEF.VAR.. 33.96 Xt*******************************************************************************AS 3O 1 O C*i S 3 "7 J*- / tf Ct/fe/' T ' .-**-<_

AA AA-BC BCPEAK HEIGHT (ABSORBANCE) 0.537 0.564 0.028PEAK AREA (ABS-SECONDS) Q.364 0.285 0.079

42.5


42.0

MEAN" 42.3 STD.DEV.'

AS 3011 SJUc. 3oSaPEAK HEIGHT (ABSORBANCE)PEAK AREA 'ABS-SECONDS)

0,3

PEAK HEIGHT • ABSORBANCE)PEAK AREA (ABS-SECONDS)

-1.2

MEAN" -0,4 STD.DEV.'


18.7


19.0

MEAN" 13.9 STD.DEV..*»»»•**«*»»»»*»»»*»»*«»»**»•*»*«»*

AA0.5720.351

0.4 COEF,

1= tl-thAA

0.02S0.063

AA0.0230.061

t.O COEF.

sric cz.o;AA

0.2400.194

AA0.2420. 197

0.2 COEF.***************

AA-BG0.5300.231

VAR.= 0.96 X

AA-BC0.009-0.003

AA-BG0.006-0.015

VAR." 99.99 %

<?S'*V'. •"-.AA-BC0.2190.121

AA-BG0.2220. 123

VAR.. 1.22 %• **»*»»*»*****»*»<

BC0.0230.080

BC0.0250,073

BG0.0250.076

BG0.0260.073

BC0.0260.074

»***•****»»•*»•

3O13 (CONTINUED)AA AA-BG BG


59.0

AA AA-BG BGPEAK HEIGHT (ABSORBANCE) 0.956 0.422 0.544PEAK AREA (ABS-SECONDS) 1.195 0.434 0.761

V, i 64.2

MEAN" 61.6 STD.DEV." 3.7 COEF.VAR.. 5.95 X«»*»•»•«*»»«»«•»••»*»****«»»**•»»*»«**»**«»»»•»**»»*»»»*»»•»**«»«»»»•»***»•»»»»»AS 301-* GJSaTf-'V OH/ fty.^u.


47.1


42.9

MEAN" 45.0 STD.DEV.- 2.9 COEF.VAR.. 6.53 Xt*******************************************************************************MEAN- 45.0 STD.DEV." 63.7 COEF.VAR." 99.99 Xt*******************************************************************************

---.- E-02: ELECTRONIC RANGE OF INSTRUMENT EXCEEDED.»•»**«•«*»»»««»«»*•»»»*»»»»»•»•»»»»**»»•»*»»*•»«»*»»»*»*»*•»»»***•»»**»»»***»•»»MEAN- 45.0 STD.DEV.. 63.7 COEF.VAR.. 99.99 X

-•-.- E-02i ELECTRONIC RANGE OF INSTRUMENT EXCEEDED.t**************************************************************************.*****AS 301S f7 lto*1~ o I 1-*

AA AA-BC BCPEAK HEIGHT (ABSORBANCE) 1.110 0.742 —0.37,2 n ^ i jPEAK AREA (ABS-SECONDS) 1.032 0.523 fl R01S$3 O <£ H

l*? ' 77. t

32.4

MEAN" 32.6 STD.DEV.. 0.4 COEF.VAR." 1.22 Xt*******************************************************************************AS 3O2O ~rSi ' ' *r


35.3

AA AA-BC BCPEAK HEIGHT (ABSORBANCE) 0.640 0.361 0.285PEAK AREA (ABS-SECONDS) 0.602 0.235 0,366

35.3

MEAN" 35.3 STD.DEV.' 0.1 COEF.VAR,' 0,15 Xt*******************************************************************************AS 3O2 1 —Oi <2~i "7*1* C £SV (I y. 7. -"*-

AA AA-BG BCPEAK HEIGHT (ABSORBANCE) 0.901 0,643 0.279PEAK AREA (ABS-SECONDS) 0.733 0.423 0.360

62.6

AA AA-BG BGPEAK HEIGHT (ABSORBANCE) 0.949 0.682 0.289PEAK AREA (ABS-SECONDSI 0.795 0.433 0.362

64. 1

MEAN' 63.4 STD.DEV.. 1.1 COEF.VAR.. 1.69 X********************************************************************************

63.4 E-25: READING GREATER THAN HIGHEST STANDARD.»»*****»*******•***********«*******»***»»»*»**»»»«*»»*»***»**»****»»**»*********AS 3O22 -Ol t '• M


36. 1


»»»*»•**»»***».»»*»»**»********»»»»*»»**»*•*»****»»»»*»*

..........................................................| MEAN. 57.6 STD. DEV. - 2.1 COEF.VAR.. 3.63 X, **********»*******»******»»»*»•**»»***».»»*»»**»********»

AS 3023 -0<+ CUlg, dLu /.'</

3O23 (CONTINUED)A A AA-BC BG


59. 1

AA AA-BC BGPEAK HEIGHT (ABSORBANCE) 1.083 0.692 0.398PEAK AREA (ABS-SECONDS) 0,916 0.410 0.506

60.7

MEAN" 59.9 STD.DEV.. 1.1 COEF.VAR.. 1.90 X*****************AS 3O2-4**»•»**••»••*****•***»*»**»•»»«•***>**•***»**»*»***»»*»»»**»*******»»»*»»*******


S.2

A A AA-BG BGPEAK HEIGHT (ABSORBANCE) 0,038 0.009 0.040PEAK AREA (ABS-SECONDS) 0.084 -0.006 0.090

0.2

MEAN" 2.7 STD.DEV." 3.3 COEF.VAR.. 99.99 X«»»»»»»*•**»»*»*»»»»«»«*»»»»*«**.»*»»*»»»»»»»»»*»»»*•*»•»»*»»»*»*»»»»»**»*»»•»»»«AS 3O2-4 CL*J( JbJUk.

AA AA-BC BCPEAK HEIGHT (ABSORBANCE) 0.025 0.008 0.026PEAK AREA (ABS-SECONDS) 0.067 -0.003 0.071

0.4

AA AA-BC BCPEAK HEIGHT (ABSORBANCE) 0.02S 0.008 , r" 0.028PEAK AREA (AM-SECONDS) 0.067 _ n \-fl\tftf? ilH 0.073

-•.2

--. - .,w ^ ri - . u". aoO 0.297 0.263PEAK AREA (ABS-SECONDSf_/ 0.543 0.137 • 0.336 ——.- ^ _„

^ »!*«- A--?- ~ ^

28.3 ' " '" -t '

MEAN- 29.9 STD.DEV.. 2.3 COEF.VAR.. 7.84 X********************************************************************************AS 3 O 2 9 ~~O6 c2*-i CttjJt I '. fa


27.5


26,9

MEAN" 27.2 STD.DEV,. 0.4 COEF.VAR.' 1.58 X********************************************************************************AS 3O30 <jjS37f-C~f C *+<o) fj /• •"•-<-


43.4

A A AA-BC BCPEAK HEIGHT (ABSORBANCE) 0.536 0.330 0.031PEAK AREA (ABS-SECONDS) 0.364 0,277 0.037

41.4

MEAN" 43.4 STD.DEV." 2.3 COEF.VAR.. 6.31 X************************************ ********************************************AS 3O31 -0*7 /-*f


27.0


31.8

MEAN- 29.4 STD.DEV.' 3.4 COEF.VAR.. 11.62 X********************************************************************************AS 3O32

-O f I .' <•/

3O32 (CONTINUED)A A AA-BC BC


24.4

A A AA-BG BCPEAK HEIGHT (ABSORBANCE) 0.431 0.238 0.217PEAK AREA (ABS-SECONDS) 0.430 0.132 0.293

23.2

MEAN- 23.8 STD.DEV.- 0.3 COEF.VAR.. 3.49 X****»***********************************'AS 3033 —0? /: </


30.3

A A AA-BC BCPEAK HEIGHT (ABSORBANCE) 0.601 0.334 0.268PEAK AREA (ABS-SECONDS) O.SSO 0.210 0.340

31.7

MEAN- 31.0 STD.DEV.. 0.9 COEF.VAR.. 3.06 Xt*******************************************************************************AS 3O3-» -TO '•' '-r

AA AA-BC BGPEAK HEIGHT (ABSORBANCE) 0.448 0.223 0.230 fPEAK AREA (ABS-SECONDS) 0.334 0.163 0.391 O 9 U U

HEIGHT (ABSORBANCE) 0.364 0.178 0.224WEAK AREA (ABS-SECONDS) 0.484 0.108 0.376

if.*

MEAN

AS

PEAKPEAK

PEAKPEAK

MEAN

.------- —— ------------ -y13.9 STD.. DEV. « ^

303S ~l i 1.

HEIGHT (ABSORBANCE)AREA

46.3

(ABS-SECONDS)

HEIGHT (ABSORBANCE)AREA

30.3

.

(ABS-SECONDS)

48.6 STD.DEV.'

0.7

•300

00

2.5

AA,767.784

AA.310.335

COEF.VAR. .

AA0,0.

AA0.0.

COEF.VAR.'

3.57

-BC446314

-BG473339

5. 14

%

0.0.

0.0.

X

BC325470

BC337496

AS -4003 -13. i : 3AA AA-BC BC


26. 1


22.2

MEAN" 24.2 STD.DEV..

AS -4OO-4 — U


18.8

AS -4OO-** - 13


31.3


31.6

AA0.474O.S22

2.3

( : -fAA

0.3700.521

AA0.3320.718

AA0.5530.713

AA-BC0.2190. 143

COEF.VAR.. 11.59 X

AA-BG0. 1680. 121

AA-BC0.2670.203

AA-BG0.2830.210

BG0.2530.477

BG0.207-0.400

BC0.2840.310

BC0.2740.508

MEAN- 31.4 STD.DEV.- 0.2 COEF.VAR.. 0.56 Xf*******************************************************************************AS -4OOS CLAJI &-Uc.

AA AA-BC BGPEAK HEIGHT (ABSORBANCE) 0.052 0.014 0.044PEAK AREA (ABS-SECONDS) 0.102 -0.006 0.103

0.2


0.6

MEAN" 0.4 STD.DEV.-t*******************************AS -4OO6 CJJ3


42.2


42.7

MEAN- 42.4 STD.DEV..********************************

AA0.0270.077

0.2 COEF.VAR.*********************

AA0.5480.364

AA0.5780.362

0.4 COEF.VAR.»»»»•»•*»»»«»*•»»•»»«

AA-BC0.0070.004

« 55.10 X.**********•*<

AA-BC0.3290.283

AA-BC0.5600.286

« 0.83 X••»*•**•*•*••<

BC0.0300.030

>**»**»•******»

BG0.0280.082

BG0.0270.076

»•••••*•»»**»**

MERCURY DATA

$t s

S1L.a.uO

u in4- UC 0OO

o

43K

e

.O

ll

inJau

v>a0 ' o

«J U 4-

» -o uiJC » 9 4-— T9 3 —CX.T9 L. CCO < h-

jj°O X U.

•2 &

C O BOO =

r£

9 'O

U

N

nO

MUO

tsJ

r- O U

U

Oo

T

a

u

Csj

0

M

§L.3U

8

1

o

M

inS

— inc 0a 4--fra^

Isi^«

(3RI032I49

O)

UJ

?ct

co

**e 0o 4° f

0ina

I

5i /

*

-fcl3 • H

to S

Jft

«0

inO

Sa. •P U.2

* 3*

Is*fl> p.(VNJ

05 .0 T3 UJt 0 0 4"« 3 —

a » u.

• • wu y

• •*o> o> 0< a.

'*•

r0

0-

o

(V0*

^

O

OU

o

rs/

VI

9

M

O

to

rJ

d

o

510

N

O

o-cr

V

O

5j.

u01

rr-

•o

I(A

L.3Uo

o£o2SI

8

V U)§1in —

I*— Me ae 4--8-

e 0U

U0 a.

MftRl03250

2 =

zO

c?

Ou

oID

Ie i.0

incLLJ O

.A L 1 Qo O>C 3 — ^QfcS^ j s- i

§£ 2— 04-a 4- toe e e< o —

•o— . . . . . . . , - . . . . , , . , , . , , , , , , < oaL.

in O0-

0

S^^^ o

UI

9 Tl I/ITl0

to < t— 3

-° =• aho * u.

0* -J 3' I• -• •* 3 fj

o

tS:

o

rs

OJ

^ ^

3%6

r-a-

Q

o0 u O

. - r ----——————————————:———————— „

N

tvJ

N)Q

V

cS

soro O

in

L.t_

O

Ouii1isI

o

&••

liI*— IA

•8

L. L.0 a.

<5 - WI 2 8Z 0 4--8-5 I I

flR!03251

•+ 001in a

ST0

in

80 t__lf mm_l.m ^ mm m_l _l_m lt _l ^ _m ^ j_mllt_ im ^

2 ^\ Si -n * o0in

i0 L tl POQ \i

iRS

OT

iUI01

fc-CL§

s

FOR*1

8

PO<o

Do

AJ

Cs

fi

F" S

1a ft. <e*'

n

coo°

os

,0&M & 0

jf O

«.

flR

^^s U

or —

'• - io

i

m0~i

-s ho

K

UKLN6s-8--4 0 3-010

15*^6

IM.t </» •

a ain —•*. inO 0— in•o" a

o.•8a

I3

8

ooa.

o

V>9Aa

N

1 3D ^ rx. I > fr-x, L^A ITS. r> rx Wl \> ^s few • •a

ANf6

Ni

PJ A.

£

Nsi

B?

too ITMrs t^ ^ _ 6

Uc lt?1R

SJSi

0

I?

O

— 0 <

-i

r?

oe

i?*

oft

?cf«

•4 0 0 3TIt Q* 9

9

01

2 •*

JlVt :oo

? g

? i••§

O0in0

S

oUI

9

i

2

?

C/

r1 PEAK HEIGHT (ABSORBANCE)fj PEAK AREA ! ABS-SECONDS)

j READ! -0.007j .....................................

PEAK HEIGHT (ABSORBANCE), PEAK AREA (ABS-SECONDS)

I READ) 0.009

MEAN" 0.001 STD.DEV.* 0.0

0.000 AUTOZERO

sePEAK HEIGHT (ABSORBANCE)PEAK AREA (ABS-SECONDS)

READ» 0.065


READ: 0.061

MEAN" 0.063 STD. DEV. = 0.0

20.0 STANDARD 1

SE


i

*

READ: 39.3


READ! 33.5

MEAN" 39.0 STD.DEV.. 0*»*»****«*>***********»*«*****>*«****

39.0E-50i READING GREATER THAN

»»«•••«*»«*»»»«»»•«»*»*•»•*•»*«»»***»39.8 STANDARD 2

i************************************SE

PEAK HEIGHT (ABSORBANCE)i PEAK AREA (ABS-SECONDS)

I READi 39.8

(CONTINUED)

PEAK HEIGHT (ABSORBANCE)1 PEAK AREA (ABS-SECONDS)

1 READi 60.6

AA0.1010. 163

AAO.C900. 144

12 COEF.VAP.

AA0 . 2070.213

AA0.2030.203

02 COEF.VAR.

AA0.3120.280

AA0.2980.266

.7 COEF.VAR.****************

HIGHEST STANDARD•*****»»»*»»>**»

•*»»**•*»**»»**»

AA0.3900.347

AA0.4090.343

ZAA0.0780.040

ZAA0.0730.056

» 99.39 X

ZAA0. 1720. 113

ZAA0. 1600 . I 09

« 3.97 X

ZAA0,2570. 172

@ZAA0.2440. 169

' 1 . 83 X***********

»**»»**»*«*

*«»*»*»*»**

ZAA0.3210.233

@

ZAA0.3320.235

BG0.0880.123

BG0.078o.oes

SOO.C640. 100

EG0.0380.094

BC0.0670.107

BC0.0580.097

*»»***»»*»****»*

****»**•**<*»***

»**»»»*»»**»»»**

BG0.0770.113

BC0.0800.103

MEAN- 60.2 STD.DEV.. 0.6 COEF.VAR.. 0.99 X**»*•*»•«***«***«»****»*«********t**********************************************

60.2E-SO> READING GREATER THAN HIGHEST STANDARD

»•««•»«*•*»»»»*»»»••*»*»»*«*»*»»»««»»*««*»«»»»«»»*»«»»«»••*»»»«•»•»»**«*••««»*•»

10.3256

PEAK HEIGHT (ABSOPBANCE! 0.350PEAK AREA <ABS-3ECONCS> C , 353

PEADs -0.011

AA ZAA 50PEAK HEtCHT 'ABSORBANCE) 0.112 C.236 C.023PEAK AREA ( ABS-SECCNDS ) 0.095 7.:-l2 O.C3?

READ: 0,002

MEAN* -0.004 STD.CEV.. 0.510 "EF.ViR.= 99.99 t#***»*****#**»***»»#*»********### **************** *******************************

0.000 AUTCrEPO

•IA ;AA scPEAK HEIGHT 'ABSOPBANCE) 0.244 0.239 3,:49PEAK AREA (ABS-SECONDS) 0.169 0.103 0.061

READ: 0.0-3

AA ZAA BCPEAK HEIGHT 'ABSCPEANCE) 0.243 0.194 0.032PEAK AREA ' ABS-SECONDS > 0.155 0.102 0.064

PEAD i 0.067

MEAN" 0.070 STD.DEV.. O.C04 COEF.VAP.s 5,65 X******************************************* **»»4*»**»»*******»*****«»****»**»»*«

20.0 STANDARD 1t*******************************************************************************

AA ZAA BCPEAK HEIGHT (ABSOPBANCE) 0.393 0.325 0.075PEAK AREA (ABS-SECONDS) 0,248 0.174 • 0.075

•"*

, READ: 39.6

i AA :AA BCPEAK HEIGHT (ABSORBANCE) 0.373 0.307 0.071

' PEAK AREA (ABS-SECONDS) 0.244 0.164 0-080

J READ) 36-9

MEAN- 38.3 ST3.DEV.- 1.9 COEF.VAR.. 4.92 St*******************************************************************************

38.3E-50! READING GREATER THAN HIGHEST STANDARD

********************************************************************************39.6 STANDARD 2

****************************************************************** ******n**mtSE

AA ZAA BCPEAK HEIGHT (ABSORBANCE) 0.490 0.405 0.090PEAK AREA (ABS-SECCN3S) 0.303 0.219 0.085

READi 74.3

(CONTINUED)AA ZAA BC

PEAK HEIGHT t ABSORB AftICE) 0.47T 0.39* 0>333PEAK AflEft (ABS-SECONBS) 0.310 0.218 C.SSI

READ: 34.2

MEAN- 54.3 STD.DEV.. 0.1 COEF.VAR.. 0.14 *t**********************************•»*•****«»»»**»*«*»***»***•***»**»***««*****«

54.3E-30: READING GREATER THAN HIGHEST STANDARD

»**»»*»»»«»»»*«»»»*»•«»*»«»»•*•»»«»**»*•»«*»»«»»»*»»»»»*»«»»•«»»»*»»«*»»•«»»**»*

\Q3257

1 PEAK HEI3HT (ABSORBANC_KTJ PEAK AREA 'ABS-SECONC^'

| READ: 23,0

' MEAN- 20.2 STD.DEV

SE 1 O 1 O

3C>5&

P£ftlc -'EIGHT •' ABSOPEAPw-E 'PEAK APEA~iABS-3E:2N3S!

READ: -.4

PEAK iJEIGHT 'ABSOPBANCE'PEAK APEA ( ABS-SEC3NDS'

PEAD: 5.4

MEAN= s.9 STD.DEV

3WOSSE 1O11

PEAK HEIGHT (ABSORBANCE!PEAK AREA (ABS-SECONDS)

READ: 47.7

PEAK HEIGHT (ABSCRBANCE)• PEAK AREA ( ABS-SECONDS I

READ! 46.0

MEAN- 46.9 3TZ.DEV

SE 1 O 1 2 _/V

PEAK HEIGHT (ABSORBANCE!PEAK APEA (ASS-SECONDS'

PEAK HEIGHT ' ABSORBANCE)PEAK AREA ( ABS-SECONDS 1

READ! 42.2

j MEAN- 44.4 STO . DEV

|sE ioi3 -Qdt/i PEAK HEIGHT CABSOPBAVCES' PEAK AREA «ABS-SECOiyES'

; PEAK HEIGHT (ABSORBANCE)i PEAK AREA (ABS-SECONDS'

j READ; 53.4

] MEAN- 53.7 S7Z.DEV

| SE ioi-» CQjLhJi.1 PEAK HEIGHT (ABSORBANCE!• PEAK AREA (ABS-SECONDS)

READ: 3.7

5/7 1.323 0.3071 -693 J. 103

. * 3.9 COEF.VAP.- 13.55

i~* ' 3 f • " •* o '2

3.414 j.iss

3.112 0.3940-1 43 0.356

O.T rOEF.vap.. 10.-- »

AA ZAA0.314 0.1380.563 0.187

AA ZAA0.329 0.1310.377 3.132

.. 1.2 CCEF.VAR.= 2.54 t

0 . 330 -3.1-30.503 0.133

AA ZAA0.332 0.2010.339 0.169

.. 3.1 COEF.VAR.. 6.97 1

I *\ S AA ZAA{/,' 2.J 0,379 0.214

0,634 0.20*

.AA ZAA.j.sra o.t550.531 3-221

.. 3.8 COEF.VAR.' S.79 T

&*-£' AA ZAA0.138 0.0960.163 0.047

uora1 , 390

PC

0. =55

rC-0.0493.033

300.2150 • 376

BC0.2110.396

BC0.2050.419

BC0.2280.419

BC0.2340.430

BC•3.247

•C0.0620.116

.AR.1.Q.3!

I PEAK HEIGHT ' ABSORBANCE • PEAK AREA (ABS-SECONDS)

j READ! 5.6

PEAK HEI3HT (ABSOPBANCE)PEAK AREA 1 ABS-SECONDS '

PEAD: 5.0

MEAN- 3.3 3~D. DEV.. 0 .

-O7&SE 1 O 1 9

PEAK HEIGHT (ABSORBANCE'PEAK AREA (ABS-SECONDS)

PEAK HEIGHT 'ABSORBANCE)PEAK AREA (ABS-SECONDS)

READ: 27.8

MEAN- 27.3 STD.DEV.. 0.

SE 1O2O — /O 8 A


• PEAK HEIGHT (ABSORBANCE)PEAK AREA (ABS-SECONDS!

READi 28.6

MEAN- 28.1 ST3.DEV.. 0.

SE 1021 JJOSC) /6&2/K.PEAK HEIGHT (ABSORBANCE)PEAK AREA (ABS-SECONDS)

READ: 3.8

PEAK HEIGHT (ABSORBANCE)PEAK AREA (ABS-SECONDS!

., READS 3.3

t<i

•MEAN- 3,6 3T3.EEV.- 0.

SE 1022 /OjM/ jC. ;QjQjLPEAK HEIGHT (ABSOPBANCE)PEAK AREA ( ABS-SECONDS)

READ! 24.8 iif-... ... ..... ... ------------- ---.-.//O,


READ: 22.1

0.271

AA0.2440.271

4 C2EF

•f

AA0.4370.297

AA0.4390. 304

8 COEF

AA0.4700.307

AA0.4320.309

7 COEF

0. 1270. 171

AA0. 1230. 146

2 COEF

<W-<0.2720.233

'/~AMU)LAA

0.2390.226

o. -.540.053

ZAA0. 1300.051

. VAP. = S. 19 *

ZAA•3.3600. 120

jQV&lUjft0.3560.124

.VAR.. 2.90 t

ZAA0 . 3740. 123

'ZAA0.3330. 126

.VAP.. 2.39 "i

) ZAA0.0920.043

ZAA0.0930.346

. VAR . . 6 . 49 I

') ZAA0.2120. 114

k i . ..........U ZAA0.2020. 103

.. — ....._. -TV A J

0. 1960.217

BC0. 1910.220

4<tf 34

BC0. 1330.1-7

BC0. 1620. 131

BC0. 1660. 184

BC0.1290. 183

0.0480. 123

BG0.0400. 100

BC0.0640. 121

BC0.0700.121

C.Q. ..........MEAN- 23.4 STD.DEV.- 1.9 COEF.VA*.t> B.febO*" **»»•«••««»»•»••»«»»•»•»•*»»««*•••*»«*•»»«•»»*«»»«« »«f»V»»»« I************************_K __. « r*. * —* i* „ * f ft —. '

HPEAK HEIGHT (ABSORBANCE)

' PEAK AREA (ABS-SECONDS)

PEAD! 36.3

PEAK HEICHT ! ABSORBANCE iPEAK AREA I ABS-SECONDS1

PEADl -»0.2

MEAN- 33.3 ST3.DEV.*

S E 1 O 2 S _ C^A C.IPEAK HEIGHT (ABSORBANCE1.PEAK ARE* < ABS -SECONDS)

READ: 3.5

PEAK HEIGHT ;AESCREANCE)PEAK AREA (ASS-SECONDS'

READ; 7.3

MEAN. 2-2 STO.TJEV.-

SE 1 029

PEAK HEIGHT (ABSOPBANCE;PEAK AREA (ABS-SECOMDS)

READ: 35. S

PEAK HEIGHT '. ABSORB ANCE!PEAK AREA >. ABS-SECONDS ;

READ: 38.1

MEAN- 36.9 3TC.DEV.-

SE 1O3O _y^4


READ! 21.7

' PEAK HEIGHT (ABSORBANCE)j PEAK AREA (ABS -SECONDS!

READi 19.7

AA0.4780.517

AA0.4633.410

2.6

' AA0.1-30. 137

AA0. 1~30.1"6

0.5

AA0. r-50 , 267

0?3460. 151

1JjC£l>£qu

073720. 163

COEF.VAR.* S.79 *

ZAA•3 . I 370.062

ZAA

C . CSO

C3EF.VAP.- 3.5-» t.

ZAA0.3120. 148

BC0,2220.363

BC0. 1100.248

BC0.0390. 124

BG0.0600. 115

5C0.0690. 118

l\^f- AlOA(&i<sAA 0 ZAA

0.357 0.3020.2-0 0.136

i.r

AA0.3030.391

AA0.2630.327

COEF.VAR.- 4.65 *.

ZAA0.2170. 104

ZAA0. 1940.098

BC0.0730. 114

BG0. 1230.287

BC0. Ill0.229

MEAN- 20.7 STD.DEV.- 1.4 COEF. VAP. - 7.00 t*•*•*»***•*****«*»»*•»»*•»***»*«**«**»****»*•***»»****•**»*»*»**•»***»•*»***•*»*SE 1O31 —lOAsJj^A\ (Uf*&*nf> AA ZAA BG

• PEAK HEIGHT (ABSCRBANCE) 0.263 0.195 0.110PEAK AREA (ABS-SECONDS) 0.323 0.103 0.222

' READ! 21.5

S PEAK HEIGHT (ABSOPEANCE)' PEAK AREA (ABS -SECONDS:

READ: 20.9

._Ov/...39AA

0.2420.326

..-.-.---..ZAA0. 1840.102

BG0. 1040.224

Ml 103260

i*PEAK WHISHT i ABSORBANCE) 0.446 0.380 074(PEAK AREA I ABS-SECONDS) 0.263 0.195 o!o69

PEAD: 50.1

mEAN* 49.4 37". DEV.«

S E 2 O O ," "7/V/OS"PEAK HEIGHT 'AESCPEANCEJPEAK AREA t ABS-SECONDS)PEAD: 19.4

PEAK HEI3HT 1 ABSOPBANCE'PEAK AREA (ABS-SECONDS!

READ: 14.3

MEAN" 1~. 1 3TS.DEV."

SE 2O OS — /5~/4PEAK HEIGHT (ASSOPBANCE)PEAK AREA ( ABS-SECCNDS)

READ: 13.5

PEAK HEIGHT IABSOREANCE)PEAK AREA (ABS-SECONDS)

READ: 15.3

MEAN- 14.5 3TS.DEV.-

SE 2OO9

PEAK HEIGHT I ABSORB ANCE ( PEAK APEA (ABS-SECONDS)

1. 0

00

30

3.2

00

00

1.4

00

COEF.

AA. z 3r. 23r

AA,23?. 302

COEF.

AA. 194.325

AA.213.331

COEF,

AA.220.407

y'AP.S 2. OS

ZAA0. 1210.097

ZAA0.164 .0.083

VAR.. 13.74

ZAA0. 1340.073

ZAA0. 1350 . 085

. VAR.« 9.77

ZAA0. 1230.071

Y.

BC0. 0940. 190

EC0. 1020.219

r.

BC0, 1050.247

BC0. 1130.246

T.

BG0. 1610.333

READ: 11.3


" READ: 7.3

1 MEAN- 9.3 ST3.DEV."

I SE 2OO9 S\(Q

\ PEAK HEIGHT (ABSORBANCE)I PEAK AREA (ABS-SECONDS)

* READ: 11.1

; PEAK HEISHT 'ABSORBANCE)! PEAK AREA I ABS-SECONDS!

• READi S.C

j MEAN- 9.5 STD.DEV..' ***********************************

0.0.

2.5

0.0.

0.0.

2.2»»**i

AA231404

AA272543

AA234435

*****

ZAA0. 1500.060

COEF.VAR.. 25.81 X

ZAA0. 1590.071

ZAA0. 1360.061

COEF.VAR.. 23. 13 X»**•*»**«*»•«*»*«****•<

BC0. 1690.344

BC0.2160.472

BC•3.2380.424

20 1 OAA ZAA BC

PEAK HEIGHT (ABSORBANCE! 0.253 0.130 0.236, PEAK AREA (ASS-SECONDS) 0.469 0.072 0.397

READi 11.5

AA ZAAPEAK HEIGHT (ABSORBANCE) 0.250 0.§BPEAK AREA (ABS-SECONDS! 0.428 O.TOf* " 0.367 j

1^ *™ PEAK HEIGHT : ABSORBANCE i <XZG* 0 O / .3 -, aPEAK AREA (ABS-SECONDS) 0.192 0.124 0.068

READ: 0.074

AA ZAA BG;; PEAK HEIGHT (ABSORBANCE) 0.227 0.138 0.032PEAK AREA IABS-SECONDS! 0.170 0.110 0.060

! READ! 0.039

MEAN- 0.066 ST3.DEV.. 3,010 COEF.VAP.= 15.3- %* ********************************************************************************

20.0 STANDARD 1*******«********»»*«*»*********4********44444***4**44******44»444»**44**4***4»4*SE

AA ZAA BCPEAK HEIGHT (ABSORBANCE) 0.360 0.302 0,073PEAK AREA (ABS-SECONDS) 0.248 -3.171 0.077

PEAD: 36.4 / /7 )

AA 3AA BGPEAK HEIGHT IABSORBANCE) 0,340 0.283 0.067PEAK AREA (ABS-SECONDS' 0.23S 0.1~4 0.064

READ: 37.1

MEAN" 36.T 373.DEV.- 0.3 70EF.VAR.= 1.40 *4***********4*»»»»**»*44*»*4****»*»4*4***»»44»4**»***4»*4*»***4*4*444*»**»*4»*»*


***>***»******»*****»***»**»***»*4*»»4*»*******»**»»»*»****»»**»»*»»************

39.3 STANDARD 2***»«******»»******»*******»****»**********»***»*»*»******<.»**** *«»»»******»****

AA ZAA BGPEAK HEIGHT (ABSORBANCE) 0.457 0.330 0.083PEAK AREA (ABS-SECONDS) 0.314 0.238 0.077

READ: 50.2

(CONTINUES'AA ZAA BG

PEAK HEIGHT (ABSORBANCE) 0.428 0.353 0.090PEAK AREA (ABS-SECONDS/ 0.309 0.233 0.076

READ: 38.8

MEAN- 59.3 STZ.DEV.. 1,0 COEF.VAR.- 1,66 t********************************************************************************

39.3E-30! READING GREATER THAN HIGHEST STANDARD

»**»*•»*•****«*»*******»»*»»**»**»*»»»*»***»»*4*****4**»»*«»********»»*»»*»*»*»»

39.8 STANDARD 3»****••*»•****»»**»»•**»»**»•«»»***********»***»»*»********»*4*»***»»*»****>»**»

SE 2005S QC_^^- AA ZAA BG


READi 44.1

AA ZAA BCi PEAK HEIGHT (ABSORBANCE) 0.350 0.290 0.070•PEAK AREA (ABS-SECONDS) 0.250 0.183 0.067

• READ! 42.8

MEAN- 43.5 ST2.DEV.- 0.9 COEF.VAR.- 2.11 tt***********************t*******************************************************

&R103262

-0.003 O &\

0.000 STD.DEV.. O.o04*,.*************************************.**** ..«..........„0.000 AUTOZERO

«»»*»*»***»«******#******»»**»»*«»*«*»»**»*««»**»**«»*»«**»«»»»«»»»***»**»**lt__SE

AA ZAA BCPEAK HEIGHT ( AESOREANCE) 0.139 0.159 0,041PEAK AREA (ABS-SECONDS) 0.123 0.093 0.033

READ: 0.030

AA ZAA BCPEAK HEI3HT 'ABSORBANCE) 0.188 0.153 0.046PEAK AREA (ABS-SECONDS! 3.137 0.395 0.041

READ: 0.030

MEAN- 0.030 37r.DEV.= 0.300 COEF.VAR.. 0.32 *

20.0 STAN2APD 1*************************************************************************** ******SE

AA zaA BCPEAK HEIGHT (ABSORBANCE' 0.296 3.233 0.052PEAK APEA SABS-SECONDS) 0.198 0.143 0.049

READ: 41.4 (J l)

AA ZAA BCPEAK HEIGHT (ABSOPEANCE) 0.299 0.241 0.058PEAK AREA (ABS-SECONDS) 0.139 0.138 0.051

READ! 37,0

MEAN- 39.2 S7C.DEV.- 3.1 COEF.VAR.. 8.00 X********************t***********************************************************


t*******************************************************************************39.8 STANDARD ^

********************************************************************************SE

AA ZAA BCPEAK HEIGHT (ABSOPBANCE) o.4ia 0.344 0.073PEAK AREA (ABS-SECONDS) 0.257 0.132 0.064

READ: 59.9 /2f\

(CONTINUED)AA ZAA BC

PEAK HEIGHT (ABSORBANCE) 0.398 0.326 0.072PEAK AREA (ABS-SECONDS) 0-258 0.199 0,060

READ! 62.4

MEAN- 61.1 373.DEV.» 1.8 CQEF.VAR.. 2.93 Xt************************************************************!******************

61.1E-50i READING GREATER THAN HIGHEST STANDARD

i********************************************************************************60.4 STANDARD 3

**»****»*«***«*»****»***»**,»»*»»»***v»**»*« *»»«»*»«*»»*•»»*»*»*»*«**»*•»»»«*»»«*»

AA ZAA BCj PEAK HEIGHT (ABSORBANCE) 0.353 0.296 0.071'PEAK AREA (ABS-SECONDS) 0.234 0.174 0.060

PEAK HEIGHT (ABSORBANCE)k PEAK AREA (ABS-SECONDS)

Q32w«3t2 0.072 jlo.iao o.oso ^m

1*»•**»****«****«»*»**»****»«»*»«*****»*»**»****»«»*»"- »*««**«»*«.»*«««»«««»,«,»**»»»««,*«,»,«2009 <_,A 6 S4?)

I* ^ 0*** -r4 ZAA scPEAK HEIGHT (ABSORBANCE) IS 0.235 0.153 o issPEAK AREA (ABS-SECONDS) ' 0.401 0.063 0.333

READ: 7. l

AA -AA BCPEAK HEIGHT (ABSCRBANCEJ 0.229 0.144 3.174PEAK AREA (ABS-SECONDS) 0.399 C.057 0.342READ: 4.3

MEAN- 5.9 STB. DEV.- 1,7 COEF.. VAR. = 27.39 1********************************************************************************SE 2010 -i~7A

AA ZAA BCPEAK HEIGHT (ABSORBANCE1 0.229 0.160 0.146PEAK ARE^ (ABS-SECONDS) 0.341 0.353 0.273

READ: • 7. 1

AA ZAA BCPEAK HEIGHT ;ABSORBANCE) 0.233 0.153 0.143PEAK AREA IABS-SECONDS: 0.331 0.054 0.265READ: 7.7

MEAN= 7.4 3TZ.DEV.* 0.4 COEF. VAP, = 3,77 T.

SE "yoYY"""" "?' ' I AA ZAA BG

PEAK HEIGHT' (ABSORBANCE' 0.255 o.isa o.ies


AA ZAA BCPEAK HEIGHT (ABSORBANCE) 0.231 0.139 0.137PEAK AREA ( ABS-SECONDS ) 0.407 0.062 0.345

READ: 6.8

MEAN- 6.5 STD. DEV.- 0.5 COEF, VAR.. r.oi X********************************************************************************

-(%ASE 2012

AA ZAA BGPEAK HEIGHT (ABSORBANCE) 0.359 0.258 0.148PEAK AREA (ABS-SECONDS) 0.413 0.121 0.294

AA ZAA BCHEIGHT (ABSORBANCE) 0.374 0.274 O.MS

PEAK AREA I ABS-SECONDS) 0.420 0.116 0.304READ i 23.3

MEAN- 29.3 STD.DEV.- 1.3 COEF.VAR.- 4.57 tf*******************************************************************************SE 2013 -PEAK HEIGHT (ABSORBANCE) 0.371 0.268 0.144PEAK AREA (ABS-SECONDS) 0.401 0.125 0.276

READ! 32. 11

I

AA «AA BGPEAK HEIGHT (ABSORBANCE) 0.360 0.259 0.142PEAK AREA (ABS-SECONDS! 0.393 0.117 0.275

„'•* . READ! 28.9

MEAN- 30.5 ST3.DEV.- 2.3 COEF.VAR. •

RADIAN ANALYTICAL SERVICESQUALITY CONTROL DATA SUMMARY

Form IX^H ——

Cl lent ID lA ft fow iWorkorder $f / / Q*)

Sample ID No.,mS£jJmQ$'$- (J

CoSub

ICP SERIAL DILUTIONS

Parameter

- n

A

'

Initial SampleConcentration (1)

<7SL

Serial Dilution1Result (S)3(0

mp i 1 edmittedMatr ix /QfrQieL.

Units fl-/«]L^ • J

^Difference2

</»3

jftk luted sample concentration corrected for J'f_f dil'ution.2. ®rcent Difference =lLzS.ix 100

IMR - Not requ i red

103265

Fore VIQ. C. Report No

DUPLICATES

LAB NAME KtoLai CASc NO.

DATEEPA SampleLab SampleUnits fvy

87- I!No.ID No

053,

8?//6f3-

Matrix '&6L&, ^ <T

Cosocur.c

Metals:1. Aluminum

Control Limit J Samole(S) Duolicate(D) P.P--

2. Ar. t icon v3. Arsar.icA. Esriutc5. Beryllium6. Caesium7. Caiciua8. Chroaiua9. Cobalt10. Coorser11. Iron12. Lead13. Maenesium14. Manganese15. Mereurv16. Nickel17. Potassium18. Selenium19. Silver20. Sodium21. Thallium22. Tin23. Vanadium24. Zinc

Other:

r?pD«: ao%

^P/XLiO1?*

n

I*

I.

1// 1

43

<o.ns~

n.iaQ

tr>.-a%

9. 1

43

<n.DS"

O.bl

<0.3X

»

10

D

1r>

l.3~

tic.

\Cyar.ide* Out of ControlTo be added at a later date. 2 RPD - [|S - D|/((S * D)/2)J x 100- Non calculable RPD due to value(s) less than CRDL

B - 12

V s

Fere VI

Q. C. Report No. ~DUPLICATES

LAB NAME jAiAj CASE NO. g?- / /Sample No. ___

Lab Sample ID No.Units // />M/- _

Matrix

Cpapo-jr.s | Control Limit J j Sacple(S) | Duplicated ) J RPD-

Metals:1. Alusinuc2. Ar.timonv

3. Arsenic4. Barium5. Beryllium

6. Cadmium7. Calcium8. Chromium9. Cobalt10. Cooler11. Iron12. Lead13. Maznesium

14. Maneanese15. Mercury16. Nickel17. Potassium18. Selenium19. Silver20. Sodium21. Thallium22. Tin23. Vanadium24. ZincOther:

RPD<*o9o

krotzott,

J?PD <90%

flpDcao*?.,

• <O.OQ1-

fl.no*

A.ooS"

< 0. Of)2>

<o.ao3.

fl.pn*

\ 'O.OOG

<o.oo$

«

N£,

0

tfc

AC.

\Cvar.ide* Out of Control . _ _ _ _ - - -To be aaded at a later date. 2 RPD - [|S - D|/((S * D)/2)J x 100- Non calculable RPD due to value(s) less than CRDL

B - 12 RRS03267

V -

Fcrc VIQ. C. Report No. -052

DUPLICATES*

LAB NAME jQtU>U&/* ______ CA-St NO. . //EPA Sample No.

DATE Lab Sample ID No.Units U<L-

-TT

Corns3-ur.c | Control Limit1 t Sample(S) | Duciicate(D) I RPD-

Metals :1 . Aluminum2. Ar.timonv

3. Arsenic4. Barium5. Beryllium6. Cadmium7. Calcium8. Chromium9. Cobalt10. Cooper

Iron12. Lead13. Maenesiun1 4. Maneanese15. M-rcurv16. Nickel

17. Potassium

18. Selenium19. Silver20. Sodium21. Thallium22. Tin23. Vanadium24. Zinc

Other:

f?PD <

*\

30 "7.

f

thfil

< 0.001

< o.oos

<o.ooq

0.-V&

o.erfi *

o.on *

n.-v*,

<O.Ole

<0.OO/

eo.otn

<O.OO

a. is

C.o'S?*

<o .on*

0.33

1

/Vc,

A/C,A/c.

filC,

ff.a-

A/C

A c

c»-

Cva-ide

"ut of ControlTo be aaded at a later date. 2 RPD - [|S - D|/((S -t- D),'2)J x 100- Non calculable RPD due to value(s) less than CRDL

value. < S~«

B - i 2 RR103268

Form IVQ. C. Report No.

ICP INTEKFEBENCL CHECK SAMPLELAB NAME )&U£uL*O CASE NO. 37- li

Check Sample 1.0. £/V? /DATE • Cheek Sample Source•""•"—"•"— — —— —— - Units

CompoundMetals :1 . Aluminum2. Anciaony3. Arsenic4. Barlua5. Berylliua6 • CadoiuB7. Calciua8. Chroaiua9. Cobalt10. Copper11. Iron12. Lead13. Magnesium14. Manganese12. Mercury16. Nickel17. Potassium18. Selenium19. Silver20. Sodium21. Thallium22. Tin23. Vanadium24. ZincOther :

ControlMean

f>. V77n.SMil

n.eiSKf.

r>.<SZl

c.qtt

O.Qtele

l.OCfe

Limits1Scd. Dev.

A.OOIn.OD**

to.oDto

fJ.ttAtt

ff.ODfa

ff.Afita

0.00*1

True2Initial

Observed

/v</tfI n.r.9-

O.1SL

O.tf,

0.1O

oat

O.tt

_——<•»—<ZR

lf)len

loo

(03,

q*

lot

5?

FinalObserved

1

1e.4* \O.'gT-

A.4SL 1

AW^ 1

DAD

DflK

O.K

r

\2R

JOI

<??

100

11

iqp

(Dl

W

1 Mean value based on n •—j

True value of EPA ICP Interference Check Sample or contractor standard.

B - 10

Form IIIQ. C. Report No. _0]

BLANKS

LAB NAME If LoU M ______ CASE NO. %?- // OS^DATE _____________________ UNITS

Matrix

PreparationCompoundMetals:1 . Aluminum2. Antimony3. Arsenic4. Barium5. Beryllium6« CAdStLus7. Calcium3 • Chromium9. Cobalt10. Cooper11. Iron12. Lead13. Magnesium14. Manganese13. Mercury16. Nickel17. Potassium18. Selenium19. Silver20. Sodium21. Thallium22. tin23. Vanadium24. ZincOther:

Cyanide

InitialCalibrationBlank Value

O.00b *

•

Continuing CalibrationBlank Value

1 2 3 4

(0.00& <0.00f <0 005 (D.OOS'

\

Preparation Blank j1 2

<-0.ooS

*

.

l

4

1

—— 1

B - 9SRI03270

Form IIIQ. C. Report No.

BLANKS

LAS NAME &1AJL/!U*-. _______ CASE NO. ??•-// 053DATE ____________________ UNITS Lt&

ffMati

PreparationCompound

Metals :1 . Aluminum2. Antimony3. Arsenic4. Barium5. Beryllium6. Cadmium7. Calcium3. Chromium9, Cobalt10. Cooper11. Iron12. Lead13. Magnesium14. Manganese15. Mercury16. Nickel17. Potassium18. Selenium19. Silver20 . Sodium21. Thallium22. Tin23. Vanadium24. ZincOther:

Cvanide

InitialCalibrationBlank Value

<D.Oto

< 0.003.

<t>.r>o\€ O . O0_3

1 _)* QfJ

C0.DI

O./J62L

O. OOO*>*

<0.03L

to.oos<o.on<\

< 0.003

C'D.QQk•

•iat <§££. flyaH "•Continuing Calibration

Blank Value1

00.0k

<D.OO

<0.00l

09/503

<O.OtK

<<2/?J

(0,00 3k.

A.oAfla*<A0a.

< 'O.ooS<o.nrx

< 0.60 3

<o.oa<f-

2 3

<. h. Ola

< O.OO3.

<O-OOI

<o.oc&

<t.OOa(

(0.6)

fo.ooi.

< 0.0001,

<0.02-

<040S

W.OO*

<0, 003

<Q.OO(e

< 0.003-

'

Q.OOO3L

<O.OOS

<4.0D±

4

<U/V33

\

AQUJUHAA- S4l<d

Preparation Blank1 2

<0.6b

to. oo*

O.OO 1

<o om

<O.OOQ

o.oa<l*

O.nnZ*

<0.03-

(6.00S-<0.r>nct

<?A.M3

o a**

<0.0(,

($• OG

\ O . Q&li

s Q AflQ

I

/9/?X5

(.0.03

to. oo?<0.00°l

< 0.00?,

o.om*

B - 9 &RI03271

OS3-OS *

i I'l

ZHZTXAL AND COlttXNUZJIG CALI3JUXXON VEXUTCAJIOW3LA* NAttl lS&6UJLM~ OSX W.

SOU M.DATIS ___________________ wmsCojKMundttecals:1. Altsstnam2. Antimony3. Arsenic4. Barium3. Berylliumw. e*<*«*__i7. Calcium1. Osra-aLu-9. Cabalt10. Cooper11.' Iron12. Lead13. Magnesium1 4. MancjnaeaeL5. Hercnry16. Nideel17. Potassium18. Selenium19. Silver20. Sodium21. thalliua22. tin23. Vanadium24. ZincOther:

Cysa.de

laitiatrue Value

0.0SO

il Calib.Found

O.05O

1

a

too

Canttrue Value

a <)&>

lauidV CFound

D.oiH-

jJJ.br•t

1

*f

stion-2Found

11

1111

A. MS

a

90

Method4

1

I

1

I

I f\\

\\

\\

Initial Calibration Source * Conclnu-ac Calibraeioo Source jf&vu. OA3 Control Limits: Mercury and tin- 30-120; All Other Compounds ' 90-UO4 Indicate Aaalycieal Heehed C««d: F - IC7/Flaae AA; F - Furnace.

B - 8

ui HAM &jidMuv

OA2Z ____________

AMD coKzunnuic c.rjm.TioM

Hetals:

2. Aaelsmnr3. ArsenicA. Barium3. Beryllium6. CadBtiai7. Calcium8. Cbmeltm9. Cobalt10. Capper11. Iran12. Lead13. Hacnestiu—14. Maa-ane*eL5. Merenry16. Nickel17. PotassiumU C _ _ 1 __^4 •«->>

19. Silver20. Sodium21. thallium22. tia23. Vanadium24. Zinc.Other:

Cyanide

True Value

n. 100

Found

n.ffft

a

48

True Value

O.nWk

rt./ao

0.0OVO

o.nso

n.r>5D

Found

O.rKtia

0.019

O,00*4(.

0.045

c.oW

rt

lf?(?

I

<7«

f'5"

<70

*?*"

Found

1O.W

J&04J*_

P-W

a

9k

,00

1/3

/0D

1

1 I1

Method4

f

p:

(Ltffifr

f

\

\F1I1iI1

1 Initial Calibration Source * Caneinuiaj Calibration Source3 Centre. Uaiu: narearf and Tin. 30-120; Ail Ochtr Caa-outuU '90*1104 Indicate Aaalycical Method Osed: P - IQP/Flaaa AA; F - Furnace

B -6R103Z73

ATOMIC ABSORPTION SPECTROPHOTOMETRY QUALITY CONTROL SUMMARY

A Date

Standard Cal Ibratlon ID,Itlal QC Cheek Contlnulna QC Cheek

Cone. £__ Height Measured Theo. __ Re&. Measured Theo. __ Rec0 ,010 _5/ 5fl 702. SO SD 100ZO , 0854O ,153(oO , ZZO

Corr. Coef .______/__)Slope ,OOW

Int. ,O/Z_

Sample No. Sample

SD ~W /DO——— —— ——

Oup 1 fcates

Result Duplicate Result fRPD

-£>3 3.0 <3.£ O-/O <3.£> <3.O &~/7A *3.C> <3-O O

Spikes

Spike t SampleSample No. Result3W/QS3-6I ZS

-Cft 2-t"O'^A 25-Ol ZO

Sample Result Spike Added % Recovery<3.0 -ZS ICO<3-C> 2S 8^*3.O 2S IOO<3.O (&b 20 loO

-OS 13 <3.0 (&ti 2.0 95~/8 L (p 0. 2# (/?£) 1.1 tf*-/-l°l /.? <0.t% ('rf ./. f 5"


Element tJ^ Analyst n /u <L____ Date u - /<f "df 7

Standard Cal Ibratton Initial QP Check Continuing Qg Check

Cone. £__, Height Measured Thee. i, Ree. Measured Thee.

. __£__ ..______. -

Corr. Goaf.

Slope - QQ7Int. "• Oo8?

Dup 1 Icates

Sample No. Sample Results<4~~ Q A DH fS . y

Dupl Icate Result SRPD_fo

-n<^ «5/ /7 -2/f 7 ao

*7 // <•

5"1/- Qfe O,j *?A-TSAi *?.?

5 5 3 - a .2 75y «i z.-o- /& <?• '

*?7*fo

<a-o-7-3

5"^0

-?7- 7

Spikes

Spike t SampleSample No. Result Sample Result Spike Added % RecoveryVTHQStJ-rM ______

•xs0 /

/-o/S"

01 <•?<? 3-? AS

-07 ^5

•RRI03275


Element ____________ Analyst _____2_1____ Date //'/_?' 87

Standard Gal Ibratlen Initial flC, Check Continuing

Cone. Pk Height Measured Thee. i Rec. Measured \s~) /)(/& 4 7 .5) Qtf V7

20 ,11 1 V84O ,171 <+l6sO • 234 V 7

Corr. Coef. 'VVT7 ,...z5—Slope ,__/QQ3 __Int. -.P S

Dup 1 Icates

Sample No. Sample Result Duplicate Result2/7//G5</-02_ <5.O ^^-0

-04 <5.0 <«5.0

1 QC Cheek

Oieo. J Rec3) f7«L^

j ^g7 9 0

JRPD0O

3/y/£53-£>3 <5.0 <S.O O-OV S.O <S.O 0

Sp ikes

Spike t SampleSample No. Result Sample Result Spike Added27//Q5< 0/ <SO *3>O 2O

$ RecoveryO

~Of <JTO < S-0 ZO Ot/:«o -03 2 4 <:5.ft 2S %

%' OS" S.O < S.O 2S &*'(r.a\ o ^ *5 <0 2°V_J ' / - -*l _X S-- • L-< •*•-. ,__J /ZO-OS <O.S <0>5 2.0 ^-O-5 <^0-5 <O-5 2.0

M/inswi 2 <5,o 2so

RR103276

L fATOMIC ABSORPTION SPECTROPHOTOMETRY QUALITY CONTROL SUMMARY

Element rA Analyst r>AX_c_____ Date M - /g~f 7

Standard Gal Ibratlen Initial g Cheek Continuing qc Cheek

Cone. EX Height Measured Thee. £ Rec. Measured Thee,/-. aav/ ?? (SO <?8 /at/ 700

aao .<3?,3 /> (oW / 0 jf

Corr. Coef..Slope « ^^/-oc-TInt. ~ -oocra, /.oo3

Dup 1 icates

- » 7sTllQS^" ^b « D /« ^_^£j______ ^_____7 S^ 0 O o_________T3C.. o S1 QQ t> ___j

Spikes

^10 O (J » • T- ** O

__3___I5

y?^a a

Sample No. Sample Result Duplicate Result {RPDuk f .*/ f._g ___I

Spike t SampleSample No. Result Sample Result Spike Added % Recovery

COM »OM«TI01

?CB QC SUMMARY

ZN 8.03 0.0345 0.033 0.033 5.2

SAMPLE NO. 43 CAL BLANK

WEIGHT 1 GRAMS VOLUME 1 ML

22:34:26 20-NOV-87 43 CAL BLANK

MV INT RAW CONC CONCEN OIL CORR RSD

<AG 12.75 -0.0034 U-0.003 < 0.009 < 0.009<AL 12.05 -0.0461 U-0.046 < 0.200 < 0.200AS 6.20 0.1110 U 0.111 < 0.300 < 0.300AU 4.36 0.0342 U 0.034 < 0.200 < 0.200<B 6.49 -0.0077 0-0.008 < 0.600 < 0.600BA 10.92 0.0022 0 0.002 < 0.009 < 0.009BE 6.57 0.0000 U 0.000 < 0.001 < 0.001<BI 3.18 -0.0274 0-0.027 < 0.800 < 0.800<CA 10.73 -0.0135 U-0.013 < 0.060 < 0.060<CD 4.17 -0.0017 U-0.002 < 0.003 • 0.003<CO 6.27 -0.0074 0-0.007 < 0.010 < 0.010<CR 7.04 -0.0006 0-0.001 < 0.009 < 0.009<CO 26.84 -0.0010 0-0.001 < 0.010 < 0.010<FE 5.64 -0.4775 0-0.478 < 0.030 < 0.030<IN 4.09 -0.0027 0-0.003 < 0.200 < 0.200<K 7.52 -0.0843 0-0.084 < 0.300 < 0.300<LI 11.24 -0.0001 0-0.000 < 0.020 < 0.020<MG 8.30 -0.0017 0-0.002 < 0.100 < 0.100<MN 7.17 -0.0003 0-0.000 < 0.003 < 0.003MO 6.85 0.0242 0 0.024 < 0.050 < 0.050<NA 12.01 -0.5484 0-0.548 < 0.080 < 0.080<NI 5.50 -0.0044 0-0.004 < 0.020 < 0.020<P 2.92 -0.1873 0-0.187 < 0.300 < 0.300PB 8.24 0.0024 0 0.002 < 0.050 < 0.050<PT 5.15 -0.0303 0-0.030 < 0.200 < 0.200S 18.47 0.0392 0 0.039 < 5.000 < 5.000<SB 9.43 -0.0055 0-0.006 < 0.060 < 0.060<SE 9.23 -0.0282 0-0.028 < 0.300 < 0.300<SI 8.87 -0.0082 0-0.008 < 0.300 < 0.300<SN 5.86 -0.1000 0-0.100 < 0.500 < 0.500<SR 37.02 -0.0001 0-0.000 < 0.003 < 0.003TE 14.08 0.1247 0 0.125 < 0.200 < 0.200TI 9.93 0.0071 0 0.007 < 0.050 < 0.050<TL 4.28 -0.0234 0-0.023 < 0.090 < 0.090<U 7.96 -0.1132 0-0.113 < 0-500 < 0.500•. y :•. \~. •:. :•-">. ••-•> v.7 ': ' :";-w 4 .' a , : : ' : ' - : • , ; : ~

ZN h >4

DONE ON 20-NOV-87

0.87042.11970.3159

'Si'0343

904U 0.240

•:!

;rS •' •;•»iss0.413

* 0.196< 0.0090.845 0.5

600

SAMPLE NO. 41 CCCS-1f )WEIGHT 1 GRAMS VOLUME 1 ML

22:29:36 20-NOV-87 41 CCCS-1

MV INT RAW CONC CONCEN DIL CORR RSD

AG 13.13 0.0194 * 0.019 * n niq , ,

" : <«: | < ;:,?:?! - ; « :.

:B8S:S : :j j

<..»» < :S .S.9:SS S:ISS ' f:o>» • : i :

ii;s S w 's .-Isil !• HS Hi 0

500 <. 0

r if 11 :l f» iJttf .°:!.°?; •S.-.'Sf <•;•«•103Z80

_ _——,—— - — -- - — _•_•_ mp __, • _^ , —— — « « • * —• - ———-; i ••a» a>' p aiIK 4.23 0.1918 0 0.043 < 18.18K 14.34 17.5604 12.66 1151 6LI 36.77 1.0220 1.022 92.91 0MG 67.75 29.5292 29.43 2676 0MN 225.14 2.1196 2.116 192.3 0.2MO 7.11 0.0374 0 0.010 •: 4.545 < 0.050NA 45.41 12.7695 9.609 873.5 0.3NI 22.71 1.0176 1.010 91.81 0.7P 6.16 8.2820 2.785 253.2 2.0PB 13.74 1.2983 1.242 112.9 2.0PT 5.92 0.6610 U 0.131 •, 18.18 <- 0.200S 150.55 S.8341 * 8.108 * 7.37.1 0.5SB 14.40 0.7678 0.631 57.40 6.2SE 12.77 1.4576 * 1.173 * 106.6 2.4SI 70.73 9.4320 9.311 846.5 0.2>3N 13.09 10.4097 * 1.123 * 102.1 9.4SR 480.74 1.0041 1.003 91.22 0.2TE 14.56 0.1425 U 0.082 •: 18.18 < 0.200TI 19.13 0.8344 0.834 75.86 0.3TL 3.53 0.9435 0.897 81.51 2.7U 8.99 1.3160 * 0.591 * 53.75 7.9V 16.86 1.0185 1.018 92.59 0.3W 4.55 0.1227 U-0.046 < 9.091 < 0.100Y 12.26 0.0575 0.058 5.228 1.4ZN 74.44 1.9773 1.935 175.9 0.1

SAMPLE NO. 39 053-17A OIL

WEIGHT 1.01 GRAMS VOLUME 400 ML

22:24:41 20-NOV-87 39 053-17A DIL

MV INT RAW CONC CONCEN DlL CORR RSD

<AG 12.73 0.0028 0 0.003 < 3.564 < 0.009AL 57.40 12.5160 12.52 4957 0.7AS 6.16 0.0555 0-0.047 < 118.8 < 0.300AU 4.57 0.2152 0 0.056 < 79.21 < 0.200B 6.57 0.0232 0-0.127 < 237.6 < 0.600BA 19.15 0.1360 0.136 53.87 1.4BE 7.30 0.0033 0 0.000 < 0.396 < 0.001BI 3.20 -0.0391 U-0.055 < 316.8 < 0.800CA 38.87 5.1136 5.114 2025 0.4CD 4.55 0.0164 * 0.009 * 3.427 46.9CO 6.65 0.0134 * 0.012 * 4.699 24.2CR 7.36 0.0115 * 0.009 * 3.705 11.7CO 30.87 0.0639 0.062 24.43 0.3FE 954.62 33.9751 33.98 13455 0.6IN 4.12 0.0621 U 0.029 < 79.21 < 0.200K 8.20 2.0221 * 0.800 * 317.0 14.7LI 11.92 0.0159 0 0.016 < 7.921 < 0.020MG 18 10 4 8650 4.846 1919 0.4MN 36.65 0.2829 0.282 111.7 0.8MO 6.54 -0.0003 0-0.005 < 19.80 < 0.050NA 14.34 -1.5914 0-2.656 < 31.68 < 0.080NI 6.18 0.0199 0 0.018 < 7.921 < 0.020P 3.42 1.5958 * 0.569 * 225.4 661.8PB 8.61 0.0895 * 0.080 * 31.66 29.5PT 5.26 0.1184 0 0.021 < 79.21 < 0.200S 47.89 1.2843 0 1.145 < 1980. < 5.000SB 9.70 0.0620 U 0.032 < 23.76 < 0.060<SE 9.23 0.0949 0 0.095 < 118.8 < 0.300SI 13.55 0.6329 * 0.567 * 224.7 2.0SN 7.18 1.9676 0 0.022 < 198.0 < 0.500SR 45.63 0.0186 0.018 7.207 0.5 . A n O QTE 13.86 -0.0534 0-0.059 < 79.21 < 0 ftefeo \ U «J t. VTT 11.58 -n n=,RR n-o nc.o /• 1 o Rn x oV\en

47.5519 47.55 4708 0 . 6~V/ In f) H0.3051 U-0.082 < 29 70 < 0.30(X *

Air 184.03AS 6.40AO 4.66 0.2520 0-0.003 < 19.80 < 0.200B 6.90 0.1518 U-0.254 < 59.41 < 0.600BA 42.61 0.5225 0.522 51.73 0.5BE 9.53 0.0118 U 0.000 < 0.099 < 0.001BI 3.30 0.0703 U-0.004 < 79.21 < 0.800CA 119.47 22.2550 22.26 2203 0.2CD 4.87 0.0290 * 0.010 * 0.992 22.7CO 7.29 0,0447 * 0.039 * 3.870 2.0CR 8.52 0.0813 0.074 7.297 3.4CO 42.30 0.3148 0.308 30.48 0.7FE 3565.97 127.6403 127.6 12638 0.4IN 4.14 0.0784 U-0.043 < 19.80 < 0.200K 10.21 7.1228 3.894 385.5 2.6LI 13.91 0.0966 * 0.097 * 9.566 0.4MG 45.21 18.3289 18.25 1807 0.3MN 121.23 1.1070 1.104 109.3 0.4MO 6.99 0.0295 U 0.008 < 4.950 < 0.050NA 20.66 1.3310 0-1.290 < 7.921 < 0.080NI 7.89 0.1230 0.120 11.88 5.5P 4.68 4.6742 2.446 242.1 1.6PB 9.49 0.2977 0.255 25.20 5.4PT 5.49 0.3112 U 0.022 < 19.80 < 0.200S 133.35 7.5692 * 7.113 * 704.3 . 0.3SB 9.95 0.1000 U 0.010 < 5.941 < 0.060SE 9.69 0.2720 U 0.234 < 29.70 < 0.300SI 26.28 2.5916 2.537 251.2 0.4SN 10.97 7.3797 U 0.043 < 49.50 < 0.500SR 69.80 0.0734 0.073 7.203 0.3TE 14.29 0.0675 U 0.022 < 19.80 < 0.200TI 16.01 0.4653 0.465 46.07 0.2TL 4.51 0.0325 U-0.004 < 8.911 < 0.090U 8.17 0.2766 U-0.265 < 49.50 ; 0.500V 9.78 0.1007 0.101 9.968 14.3W 4.27 -0.0015 0-0.135 <-' 9.901 < 0.100Y 11.92 0.0490 0.049 4.852 0.8ZN 39.71 0.9538 0.929 91.97 0.6

SAMPLE NO. 37 053-18A PD SPK


22:19:41 20-NOV-87 37 053-18A PD SPK


A-l ?" ?.' •' ' •'•• .-.-!. 'L'.- ..4AL c:.?. :" .••••-- •"--• • - -j..AO 4 •• * 4 .7 •: -. .r..-B A .'." ri? i '• •'; 4 'BA .-"? .K' ' 4,' 7 ; 4.'U : 3.^.2 - . i . iBE L'49.10 •;. ii'i.'.jl i..SU6 citi.Ul U.2BI 3.46 0.2579 U 0.168 < 77.67CA 168.05 32.5878 32.59 3164CD 27.42 0.9156 0.882 85.67CO 25.86 0.9434 0.937 90.95CR 23.46 0.9800 0.970 94.20CO 83.25 1.2139 1.206 117.1FE 4155.07 148.7703 148.8 14444IN 4.34 0.2405 0 0.101 < 19.42K 14.15 17.0883 12.16 1181LI 36.79 1.0227 1.023 99.29MG 68.08 29.6915 29.60 2874MN 229.27 2.1598 2.156 209.3MO 7.06 0.0344 0 0.008 < 4,854NA 42.79 11.5587 8 587 833.7

SAMPLE NO. 34 053-15A


22:12:15 20-NOV-87 34 053-15A

MV I NT RAW CONC CONCEN OIL CORK RSD

AG 12.84 0.0093 * 0.009 * 0.920 151.6AL 309.59 82.2898 82.29 8148 0.3AS 6.76 0.6831 U 0.073 < 29.70 < 0.300AU 4.85 0.3256 U-0.009 < 19.80 '- n . 200B 7.07 0.2161 0-0.257 ,. 59.41 < 0.600BA 94.52 1.3777 1.378 136 4 0.2BE 10.45 0.0153 U 0.001 < 0.099 < 0.001BI 3.39 0.1758 U 0.080 «. 79.21 < 0.800CA 198.93 39.1555 39.16 3877 0.2CD 4.96 0.0324 * 0.009 * 0.905 41.5CO 7.65 0.0619 0.055 5.447 1.8CR 9.03 0.1124 0.101 10.05 0.8CO 34.56 0.1449 0.137 13.56 1.3FE 4368.12 156.4122 156.4 15486 0.2IN 4.23 0.1459 U 0 . 000 < 19.80 '•. 0.200K 11.82 11.1781 -.828 676.1 2.6LI 15.17 0. 1476 148 14 62 14MG 60.31 25.8333 .5.74 2548 0 2MN 413.22 3.9522 • 949 390.9 0.2MO 7.02 0.0317 U C.001 < 4.950 < 0.050NA 24.30 3.0148 0-0.084 < 7.921 < 0.080NI 8.34 0.1505 0.147 14.59 4.6P 5.34 6.2786 4.402 435.9 1.7PB 9.51 0.3016 * 0.225 * 22.30 11.7PT 6.44 1.0961 0 0.163 < 19.80 < 0.200S 118.81 6.4999 * 5.490 * 543.6 0.6SB 10.40 0.1676 0 0.015 < 5.941 < 0.060SE 10.04 0.4055 * 0.361 * 35.76 8.5SI 28.12 2.8753 2.808 278.1 0.4SN 12.24 9.1901 0 0.169 < 49.50 < 0.500SR 109.30 0.1628 0.162 16.04 0.1TE 14.30 0.0694 0-0.015 < 19.80 < 0.200TI 15.36 0.3884 0.388 38.46 0.7TL 4.68 0.0725 0 0.010 < 8.911 < 0.090U 8.25 0.3772 0-0.258 < 49.50 < 0.500V 9.92 0.1193 0.119 11.81 2.9W 4.44 0.0725 0-0.092 < 9.901 < 0.100Y 12.91 0.0735 0.073 7.274 0.5ZN 49.39 1.2392 1.206 119.4 0.3

WF.:.JtiT • :.-. ;?• A-;, v-. >;.:?Mfr ;. '..•

22:14:44 20-NOV-87 35 053-16A


AG 12.89 0.0123 * 0.012 * 1.091AL 231.81 60.7697 60.77 5378AS 6.62 0.5305 0 0.008 < 26.55AU 4.72 0.2770 U-0.006 < 17.70B 7.11 0.2316 0-0.281 < 53.10BA 31.78 0.3440 0.344 30.45BE 10.79 0.0166 0 0.001 < 0.088 < 0.001 n n oBI 3.40 0.1954 0 0.085 < 70.80 < 0.#Q8 1 ft / Q «5a A AT* nn a? AAAR 07 AA ne^-s n B v\ I *J *•*'CA 473.00 97.4445 97.44 8623

Y 11.34 0.034 ..___ - ————w——~_~——-____.ZN 22.97 0.4606 0.448 43788~ 0. 5~



22:07:13 20-NOV-87 32 053-13A


<AG 12.76 0.0044 U O.C04 •: 0.811 < 0.009AL 171.28 44.0224 44.02 3966 0.1AS 6.33 0.2358 U-0.079 <. 27.03 < 0.300AU 4.62 0.2363 U-0.005 < 18.02 < 0.200B 6.87 0.1415 U-0.110 < 54.05 < 0.600BA 78.91 1.1204 1.120 100.9 0.1BE 8.43 0.0076 * 0.001 * 0.124 9.2BI 3.26 0.0234 0-0.012 < 72.07 < 0.800CA 216.27 42.8420 42.84 3860 0.2CD 4.68 0.0215 * 0.009 * 0.802 35.4CO 6.69 0.0155 * 0.012 * 1.125 33.6CR 8.23 0.0643 0.060 5.415 1.4CO 34.54 0.1444 0.140 12.63 0.8FE 1927.19 68.8596 68.86 6204 0.1IN 4.10 0.0405 0-0.027 < 18.02 < 0.200K 8.94 3.9022 2.157 194.3 5.2LI 13.20 0.0676 * 0.068 * 6.091 1.9MG 25.18 8.3820 8.341 751.4 0.3MN 74.53 0.6520 0.650 58.59 0.2MO 6.89 0.0232 0 0.007 < 4.505 < 0.050NA 22.13 2.0089 * 0.364 * 32.83 0.9NI 6.95 0.0664 * 0.064 * 5.759 1.3P 4.86 5.1140 3.602 324.5 3.7PB 8.95 0.1697 * 0.130 * 11.70 3.6PT 5.38 0.2148 0 0.033 < 18.02 < 0.200S 243.07 15.6379 * 14.97 * 1349 0.8SB 9.97 0.1025 0 0.018 < 5.405 < 0.060SE 9.60 0.2361 0 0.201 < 27.03 < 0.300SI 21.52 1.8592 1.829 164.8 0.5SN 8.55 3.9209 0-0.044 < 45.05 < 0.500SR 92.07 0.1238 0.123 11.08 0.1TE 13.89 -0.0450 0-0.086 < 18.02 < 0.200TI 13.42 0.1589 * 0.159 * 14.32 0.9TL 4.45 0.0196 0-0.014 < 8.108 < 0.090U 8.12 0.2179 U-0.112 < 45.05 < 0.500V 9.64 0.0821 * 0.082 * 7.396 12.8W 4.10 -0.0784 0-0.149 < 9.009 < 0.100Y 12.43 0.0615 0.062 5.542 1.0ZN 22.59 0.4495 0.433 38.97 0.7


WEIGHT 1.02 GRAMS VOLOME 100 ML R R Q 3 2 O H

HB»'.rmv/ *

_ rob*' " < 5.408 < o!o6oA''_p 0$0.3349 0 0.297 < 27.03 < O.SOCr

SI 29.12 3.0286 2.997 270.0 0.2SN 8.71 4.1544 U-0.018 < 45.05 < 0.500SR 95.64 0.1319 0.131 11.80 0.4TE 14.43 0.1078 0 0.054 < 18.02 < 0.200TI 14.76 0.3170 0.317 28.56 1.8TL 4.57 0.0461 0 0.004 < 8.108 < 0.0900 8.14 0.2473 0-0.096 < 45.05 < 0.500^f 9.99 0.1279 0.128 11.52 3.8W 4.17 -0.0473 0-0.122 < 9.009 < 0.100Y 13.88 0.0971 0.097 8.748 2.1ZN 23.65 0.4805 0.461 41.55 0.6


WEIGHT 1 GRAMS VOLOME 100 ML

22:02:23 20-NOV-87 30 053-11A

MV INT RAW CONC CONCEN OIL CORK RSD

<AG 12.73 0.0028 0 0.003 < 0.900 < 0.009AL 138.53 34.9611 34.96 3496 0.4AS 6.23 0.1248 0-0.115 < 30.00 < 0.300AO 4.51 0.1916 0-0.036 < 20.00 < 0.200B 6.71 0.0785 0-0.088 < 60.00 < 0.600BA 73.46 1.0308 1.031 103.1 0.2BE 7.67 0.0047 * 0.001 * 0.120 9.0BI 3.32 0.0938 0 0.075 < 80.00 < 0.800CA 195.60 38.4465 38.45 3845 0.4CD 4.49 0.0140 * 0.005 * 0.489 123.9CO 6.56 0.0092 0 0.007 < 1.000 < 0.010CR 7.95 0.0474 * 0.045 * 4.451 10.8CO 33.16 0.1142 0.112 11.16 1.4FE 1109.64 39.5356 39.54 3954 0.2IN 4.10 0.0459 0 0.007 < 20.00 < 0.200K 9.02 4.1045 2.208 220.8 2.8LI 12.99 0.0592 * 0.059 * 5.924 1.5MG 27.18 9.3739 9.351 935.1 0.5MN 75.73 0.6637 0.663 66.26 0.3MO 6.68 0.0089 0-0.003 < 5.000 < 0.050NA 18.41 0.2912 0-0.866 < 8.000 < 0.080NI 6.76 0.0550 * 0.052 * 5.189 1.8P 4.47 4.1530 2.842 284.2 1.1PB 8.89 0.1547 * 0.124 * 12.36 7.2PT 5.35 0.1928 0 0.007 < 20.00 < 0.200S 249.45 16.1073 * 15.50 * 1550 1.0SB 9.69 0.0605 0-0.007 < 6.000 < 0.060SE 9.55 0.2168 0 0.185 < 30.00 < 0.300SI 26.75 2.6645 2.647 264.7 0.1SN 7.42 2.3059 U 0.037 < 50.00 < 0 500SR 117.22 0.1807 0.180 18.00 0.3TE 14.03 -0.0066 0-0.037 < 20.00 < 0.200TI 13.84 0.2078 * 0.208 * 20.78 1.2TL 4.43 0.0151 0-0.012 < 9.000 < 0.0900 8.09 0.1844 0-0.030 < 50.00 < 0.500V 9.44 0.0566 * 0.057 * 5.660 4.3W 4.07 -0.0917 0-0.132 < 10.00 < 0.100Y 12.39 0.0607 0.061 6.070 0.5ZN 19.54 0.3594 0.347 34.72 0.7

0.0540 0-0 7614 <19- - - _ _ . - _ ~ <•>*. & <* >J . 200 >< t9.80 6.0774 4.129 400.9 2.4 /•" /I 0

LI 13.00 0.0596 * 0.060 * 5.791 1.1 yMG 27.91 9.7382 9.697 941.5 0.3MN 58.55 0.4962 0.495 48.02 0.4MO 7.04 0.0326 0 0.013 < 4.854 <. 0.050NA 19.64 0.8612 0-0.789 '. 7.767 < 0.080NI 6.88 0.0622 * 0.059 * 5.718 5.5P 5.38 6.3763 4.790 465.0 0.0PB 9.14 0.2136 * 0.159 * 15.42 6.0PT 5.30 0.1515 U 0.004 < 19.42 < 0.200S 116.65 6.3410 * 5.913 * 574.1 0.8SB 10.09 0.1211 0 0.009 ; 5.825 < 0.060CE 9.80 0.3144 0 0.277 : 29.13 -- 0.30051 29.13 3.0301 3.000 291.3 0.5SN 8.64 4.0448 0 0.062 •, 48.54 < 0.500SR 97.98 0.1372 0.137 13 26 0.4TE 14.09 0.0112 0-0.047 < 19.42 < 0.200TI 14.50 0.2859 0.286 27 76 0.9TL 4.50 0.0317 0-0.014 •- 3.738 < 0.090U 8.11 0.2012 0-0.130 •: 48.54 < 0.500V 9.87 0.1119 0.112 10.37 0.9W 4.21 -0.0281 0-0.099 < 9.709 < 0.100Y 12.90 0.07.31 0.073 7.101 0.7ZN 24.94 0.5187 0.499 48.46 0.7

SAMPLE NO. 28 053-09A PD DUP(D)WEIGHT 1 GRAMS VOLUME 100 ML

21:57:20 20-NOV-87 28 053-09A PD DUP

MV I NT RAW CONC CONCEN DIL CORR RSD RFJ AV

<AG 12.74 0.0036 U 0.004 <. 0.900 < 0 009AL 191.59 49.6426 49.64 4964 0.6 jp iAS 6.32 0.2219 0-0.125 < 30.00 < 0 300AU 4.65 0.2494 0-0.010 .'20.00 < 0 200B 6.77 0.1003 0-0.151 < 60.00 < 0*600BA 71.38 0.9965 0.996 99.65 0.7 8 \ i-n 343.BE 8.41 0.0075 * 0.001 * 0.130 51.7 2i'o O U 5 -BI 3.29 0.0664 0 0.031 < 80.00 < 0 800CA 125.98 23.6389 23.64 2364 0 .' 4 5 4 24"'9 507.CD 4.53 0.0153 0 0.003 < 0.300 < 0 003C0 6-?3 0.0174 * 0.014 * 1.443 4*0 13 i 452<CR 8.22 0.0637 0.060 5.958 4 3 i-'o cCO 34.85 0.1513 0.147 14.7? o.l ^'4 14FE 1924.54 68.7647 68.76 6876 05 ot fl7JJ'IN 4.12 0.0567 0-0.010 < 20 00 < 0 200 t.796.K 9.38 5.0067 3.212 321.2 4.2 22 1 ^61 037-LI 12.80 0.0517 * 0.052 *5.168 49 U4 J-J?JMG ^5.86 a. 7165 8.676 867.6 03 - 8^ flO^oTMN 56. U2 0.4716 0.470 47.00 0.5 ? - 475091MO 7.08 0.0352 U 0.018 < 5.000 < 0 050 'NA 20.75 1.3742 U-0.269 < 8.000 < o'oSONI 6.68 0.0499 * 0.047 * 4.692 2.7 19 7 <sP 5.23 6.0179 4.457 445.7 04 42 4«5PB 9.02 0.1861 * 0.141 * 14.10 13 l 83PT 5.19 0.0606 U 0.050 <20.00 < 0*200 'S 112.58 6.0417 * 5.643 * 564.3 o!s 1 7SB 9.95 0.1005 U 0.006 <6.000 <0060ff 9-73 0.2861 U 0.251 < 30.00 < 0.300SI 26.32 2.5978 2.568 256.8 OJ$nr 12.6 274. 025^SN 8.59 3.9781 U 0.019 < 50 . 00 -_ l ft *» S^O 'T? ?5'?n n'm^ °'119 H- 8&H \ " fl.1 11.2 12.555]TE 14.10 0.0150 0-0.032 < 20.00 < 0 200

0.9085AO 4.34 0.1259 0-0.021 < 0.200 < 0.20{B 8.90 0.9250 * 0.925 * 0.925 0.6BA 67.65 0.9350 0.935 . 0.935 0.2BE 243.67 0.8995 0.899 0.899 0.1BI 3.33 0.1055 0 0.101 < 0.800 < 0.800CA 59.04 9.4027 9.403 9.403 0.1CD 26.86 0.8936 0.879 0.879 0.4CO 24.93 0.8981 0.898 0.898 0.8CR 22.17 0.9025 0.901 0.901 0.1CO 69.15 0.9043 0.904 0.904 0.2FE 267.14 9.3162 9.316 9.316 0.2

•TIN 4.07 0.0162 U 0.016 < 0.200 < 0.200K 11.76 11.0264 9.198 9.198 0.3LI 34.08 0.9131 0.913 0.913 0.3MG 26.22 8.8987 3.896 3.896 0.3MN 100.34 0.90.35 0.903 0.903 0.1MO 6.56 0.0010 U-0.004 < 0.050 < 0.050NA 37.12 8 9382 8.283 8.283 0.2NI 20.43 0.8800 0.879 0.879 0.4P 4.05 3.1350 U-0.688 < 0.300 < 0.300PB 12.10 0.9127 0.906 0.906 1.1PT 5.41 0.2396 0 0.001 < 0.200 < 0.200S 27.20 -0.2372 0-0.505 '5.000 • •: 5.000SB 16.12 1.0265 0.988 0.988 1.6SE 12.03 1.1702 * 0.866 * 0.866 9.4SI 9.41 -0.0036 0-0.062 < 0.300 < 0.300SN 6.90 1.5626 * 1.012 * 1.012 7.9SR 447.03 0.9277 0.927 0.927 0.2TE 13.93 -0.0.337 0-0.035 < 0.200 < 0.200TI 12.19 0.0130 0 0.013 < 0.050 < 0.050TL 8.29 0.8891 0.882 0.882 4.50 8.68 0.9262 * 0.791 * 0.791 4.0V 16.11 0.9217 0.922 0.922 0.2W 4.08 -0.0858 0-0.095 < 0.100 < 0.100<Y 9.85 -0.0018 0-0.002 < 0.009 < 0.009ZN 37.13 0.8779 0.863 0.863 0.3

SAMPLE NO. 26 QCMS( )WEIGHT 1 GRAMS VOLOME 100 ML

21:52:24 20-NOV-87 26 QCMS


AG 25.04 0.7493 0.749 74.93 1.0AL 143.61 '36.3685 36.37 3637 0.2AS 6.37 0.2705 0-0.079 < 30.00 < 0.300AO 4.73 0.2783 U 0.048 < 20.00 < 0.200B 7.21 0.2715 0-0.187 < 60.00 < 0.600BA 289.16 4.5843 4.584 458.4 0.3BE 9.87 0.0131 0-0.001 < 0.100 < 0.001BI 3.60 0.4259 0 0.335 < 80.00 < 0.800CA 896.93 187.6068 187.6 18761 0.0CD 9.35 0.2051 0.165 16.51 0.6CO 7.45 0.0523 * 0.046 * 4.563 12.6CR 34.56 1.6476 1.638 163.8 0.1CO 468.35 9.6691 9.661 966.1 0.2FE 4189.64 150.0106 150.0 15001 0.1IN 4.19 0.1135 U-0.027 <20.00 < 0.200K 12.39 12.6283 7.538 753.8 1.5LI 11.71 0.0076 0 0.008 < 2.000 < 0.020MG 70.26 30.7745 30.68 3068 0.2MN 203.55 1.9092 1.906 190.6 JJ .A A rt 9 O 7JMO 7.36 0.0539 0 0.033 < 5.000 ft M .f)d0 U £ O 'NA 353Q P 1 171 R • 1 / K . e i/» e ^ t

SAMPLE NO. 23 CAL BLANK( )WEIGHT 1 GRAMS VOLOME 1 ML

21:44:59 20-NOV-87 23 CAL BLANK


<AG 12.78 -0.0002 U-0.000 < 0.009 <. 0.009<AL 12.09 -0.1430 0-0.143 < 0.200 <. 0.200AS 6.11 0.0069 U 0.007 <, 0.300 < 0.300AU 4.33 0.0989 U 0.099 < 0.200 v 0.200B 6.56 -0.0540 0-0.054 < 0.600 < 0.600BA 10.93 -0.0020 0-0.002 •• 0.009 t 0.009BE 6.58 0.0005 U 0.001 < 0.001 < 0.001<BI 3.18 -0.0195 0-0.020 < 0.800 < 0.300CA 10.92 -2.2473 U-2.247 < 0.060 < 0.060<CD 4.12 -0.0025 0-0.002 •. 0.003 < 0.003<CO 6.27 -0.0127 0-0.013 < 0.010 < 0.010<CR 6.93 -0.0066 0-0.007 < 0.009 < 0.009CO 26.91 -0.0236 U-0.024 < 0.010 < 0.010<FE 5.75 -0.2177 U-0.218 < 0.030 < 0.030IN 4.13 0.0594 U 0.059 < 0.200 < 0.200

<K 7.39 -0.4489 U-0.449 < 0.300 < 0.300<LI 11.17 -0.0099 0-0.010 < 0.020 < 0.020<MG 3.28 -0.1788 0-0.179 < 0.100 < 0.100MN 7.39 0.0010 0 0.001 < 0.003 < 0.003MO 6.82 0.0107 U 0.011 < 0.050 < 0.050<NA 12.37 -5.0853 0-5.085 < 0.080 < 0.080<NI 5.54 -0.0038 0-0.004 < 0.020 c 0.020<P 2.94 -0.0712 0-0.071 < 0.300 : 0.300<PB 8.23 -0.0165 0-0.016 < 0.050 - 0.050<PT 5.13 -0.0138 0-0.014 < 0.200 < 0.200S 19.36 -1.2440 0-1.274 < 5.000 •, 5.000<SB 9.46 -0.0417 0-0.042 < 0.060 < 0.060<SE 9.13 -0.0141 0-0.014 < 0.300 < 0.300<SI 8.83 -0.1641 0-0.164 < 0.300 < 0.300<SN 5.81 -0.1763 0-0.176 < 0.500 < 0.500<SR 36.97 -0.0042 0-0.004 < 0.003 < 0.003TE 14.14 0.0881 0 0.088 < 0.200 < 0.200TI 9.91 -0.0189 0-0.019 < 0.050 < 0.050<TL 4.20 -0.0378 0-0.038 < 0.090 < 0.090<0 8,02 -0.0042 0-0.004 < 0.500 < 0.500<V 9.14 -0.0056 0-0.006 < 0.020 < 0.020W 4.00 -0.0044 0-0.004 < 0.100 < 0.100<Y 9.94 0.0014 U 0.001 < 0.009 < 0.009<ZN 6.85 -0.0278 0-0.028 < 0.006 < 0.006

SAMPLE NO. 24 BLANK (3050) 11-18(B)WEIGHT i GRAMS VOLUME i ML

21:47:25 20-NOV-87 24 BLANK (3050) 11-18

MV I NT RAW CONC CONCEN DIL CORR RSD

<AG 12.68 -0.0077 0-0.008 < 0.009 < 0.009<AL 12.17 -0.0148 0-0.015 < 0.200 < 0 200AS 6.11 0.0173 U 0.017 < 0.300 < 0.300AO 4.36 0.0329 0-0.100 < 0.200 < 0.200B 6.51 0.0000 0 0.000 < 0.600 < 0.600BA 10.90 0.0018 0 0.002 < 0.009 < 0.009<BE 6.42 -0.0006 0-0.001 < 0.001 < 0.001

- BI 3.24 0.0391 0 0.039 < 0.800 < 0.800r& 1*A R-J O R57R n PUR A R K S q t

ZN 47.52 1.1707 0.854 ; 0.854 0.4

SAMPLE NO. 22 CCCS-2( )WEIGHT 1 GRAMS VOLOME 1 ML

SAMPLE NO. 21 CCCS-1( )WEIGHT 1 GRAMS VOLUME 1 ML

21:40:09 20-NOV-87 21 CCCS-1


AG 13.15 0.0222 * 0.022 * 0.022 4.5AL 12.66 0.0148 0 0.015 < 0.200 < 0.200AS 11_.10 5.2013 5.201 5.201 0.2AO 4.40 0.1265 U-0.005 < 0.200- < 0.200B 19.17 4.8128 4.813 4.813 0.9BA 322.73 5.1347 5.135 5.135 0.3BE 1366.17 5.1554 5.155 5.155 0.3BI 3.42 0.2657 U 0.266 < 0.800 < 0.800CA 11.77 -2.0651 U-2.065 < 0.060 < 0.060CD 135.50 5.1641 5.096 5.096 0.3CO 112.22 5.1149 5.115 5.115 0.5CR 91.05 5.0526 5.049 5.049 0.4CU 255.26 4.9900 4.990 4.990 6.3<FE 9.60 -0.0797 U-0.080 < 0.030 t 0.030IN 4.24 0.1459 U 0.146 < 0.200 < 0.200

<K 7.49 -0.1960 0-0.196 < 0.300 < 0.300LI 137.18 5.0910 5.091 5.091 0.3MG 9.13 0.2418 * 0.242 * 0.242 3.5MN 530.71 5.1003 5.100 5.100 0.4MO 6.67 0.0010 0-0.001 < 0.050 < 0.050<NA 12.97 -4.8096 0-4.810 < 0.080 < 0.080NI 88.99 5.0339 5.033 5.033 0.3P 9.11 15.0115 U-2.640 < 0.300 < 0.300PB 8.39 0.0212 U 0.021 < 0.050 < 0.050PT 6.95 1.4900 * 0.272 * 0.272 6.2S 20.41 -1.1668 0-1.805 < 5.000 < 5.000SB 10.22 0.0718 0-0.024 < 0.060 < 0.060SE 24.15 5.7674 4.685 4.685 1.5SI 9.37 -0.0800 0-0.130 < 0.300 < 0.300SN 6.11 0.2525 U 0.220 < 0.500 < 0.500SR 2249.55 5.0071 5.007 5.007 0.4TE 14.16 0.0947 0 0.095 < 0.200 < 0.200TI 9.97 -0.0110 0-0.011 < 0.050 < 0.050TL 27.54 5.2531 5.253 5.253 0.60 11.98 4.9832 4.951 4.951 0.5V 48.64 5.1152 5.115 5.115 0.1W 4.38 0.1626 * 0.163 * 0.163 8.0Y 10.29 0.0101 * 0.010 * 0.010 21.4ZN 183.07 5.1647 5.100 5.100 0.6

RRI03Z89

0.836__ _ _ _ _ _ _.__—. — .._,„». U.OJO Z.W ^^SB 12.11 1.1355 * 0.846 * 0.846 3.9 If '{ L IASI 44.73 5.3607 5.303 5.303 0.4 _£" *&'vSN 7.09 1.6579 * 0.936 * 0.936 2.7SR 503.84 1.0532 1.052 l.C'2 0.4TE 14.02 0.0"534 0 0.052 < 0 0 < 0.200TI 10.19 0.0142 0 0.014 < 0 • n < 0.050TL 8.30 0.8929 0.886 O.^S 0.5U 8.81 0.9891 * 0.758 * 0 ^58 2.0V 16.12 0.9001 0.900 0.900 1.2W 4.02 0.0030 U-0.007 < 0.100 < 0.100Y 10.00 0.0028 U 0.003 < 0.009 < 0.009ZN 37.97 0.8893 0.875 0.875 0.3

SAMPLE NO. 19 053-06B DIL( )WEIGHT 1 GRAMS VOLUME 4 ML

21:35:14 20-NOV-87 19 053-06B DIL


AG 12.85 0.0044 U 0.004 < 0.036 < 0.009AL 12.39 -0.0590 U-0.059 < 0.800 < 0.200AS 6.11 0.0069 U 0.006 < 1.200 < 0.300AU 4.35 0.1067 0-0.037 < 0.800 < 0.200B 6.85 0,0592 0 0.059 < 2.400 < 0.600BA 13.17 0,0348 * 0.035 * 0.139 0.6<BE 6.50 0.0002 0 0.000 < 0.004 < 0.001<BI 3.12 -0.0938 0-0.094 < 3.200 < 0.800CA 115.85 20.0694 20.07 80.28 0.7CD 4.28 0.0038 * 0.003 * 0.013 165.4<CO 6.27 -0.0127 0-0.013 < 0.040 < 0.010<CR 7.02 -0.0010 0-0.001 < 0.036 < 0.009CO 27.16 -0.0181 0-0.018 < 0.040 < 0.010<FE 18.73 0.2479 0.248 0.991 0.0IN 4.09 0.0297 0 0.030 < 0.800 < 0.200K 8.20 1.5998 * 0.491 * 1.962 7.5LI 11.35 -0.0028 0-0.003 < 0.080 < 0.020MG 16.55 3.9310 3.931 15.72 1.2MN 19.95 0.1233 0.123 0.492 0.7MO 6.55 -0.0069 0-0.009 < 0.200 < 0.050NA 32.26 4.1086 4.109 16.43 1.7NI 5.70 0.0057 0 0.004 < 0.080 < 0.020<P 2.98 0.0265 0 0.027 < 1.200 < 0.300PB 8.31 0.0031 0 0.003 < 0.200 < 0.050PT 5.20 0 0413 0-0.020 < 0.800 < 0.200S 79.62 3.1874 0 2.858 < 20.00 < 5.000<SB 9.36 -0.0572 0-0.057 < 0.240 < 0.060<SE 9.15 -0.0051 0-0.005 < 1.200 < 0.300SI 18.07 1.2581 * 1.258 * 5.033 1.0<SN 5 83 -rt 1477 0-0.148 < 2.000 < 0.500SR 71.52 0.0740 0.073 0.294 0.8TE 13.86 0.0103 0 0.010 < 0.800 < 0.200TI 9.90 -0.0197 0-0.020 < 0.200 < 0.050<TL 4.37 0.0015 0 0.002 < 0.360 < 0.090<0 7.97 -0.0629 0-0.063 < 2.000 < 0.500<V 9.13 -0.0060 0-0.006 < 0.080 < 0.020W 3.89 -0.0532 0-0.053 < 0.400 < 0.100<Y 9.92 0.0009 0 0.001 < 0.036 < 0.009ZN 7.29 -0.0148 0-0.015 < 0.024 < 0.006

56. 01IN 4.14 0.0703 0 0.070 < 0.200 < 0.200K 10.39 7.1221 4.211 4.211 0.4LI 11.71 0.0120 0 0.012 < 0.020 < 0.020MG 40.77 15.9626 15.96 15.96 0.2MN 56.89 0.4893 0.483 0.483 0.3MO 6.56 -0.0065 U-0.010 < 0.050 < 0.050NA 89.35 30.4904 29.96 29.96 0.6NI 5.77 0.0103 U 0.005 < 0.020 < 0.020P 3.01 0.0998 U 0.024 < 0.300 < 0.300PB 8.33 0.0079 U 0.008 < 0.050 , 0.050PT 5.33 0.1487 U 0.001 < 0.200 < 0.200S 260.43 16.4344 * 15.31 * 15.31 0.9SB 9.65 -0.0137 U-0.034 •< 0.060 < 0.060<SE 8.96 -0.0783 U-0.078 < 0.300 % 0.300SI 45.25 5.4407 5.389 5.389 0.3SN 6.08 0.2096 LI-0.049 < 0.500 <. 0.500SR 174.52 0.3073 0.306 0.306 0.4TE 14.08 0.0712 U 0.071 < 0.200 < 0.200TI 10.07 -0.0000 U-0.000 < 0.050 < 0.050<TL 4.34 -0.0053 0-0.005 < 0.090 v 0.090<0 8.05 0.0377 0 0.038 < 0.500 < 0.500<V 9.16 -0.0022 0-0.002 < 0.020 <. 0.020W 3.91 -0,0444 0-0.046 < 0.100 < 0.100Y 10.08 0.0049 U 0.005 < 0.009 < 0.009ZN 8.27 0.0140 * 0.012 * 0.012 5.8

.11

SAMPLE NO. 17 053-07B PD SPK( )WEIGHT 1 GRAMS VOLUME 1 ML

21:30:16 20-NOV-87 17 053-07B PD SPK


AG 27.63 0.9005 0.900 0.900 0.8AL 44.94 8.9478 8.927 8.927 0.4AS 7.00 0.9362 * 0.859 * 0.859 6.6AU 4.53 0.1764 U-0.016 < 0.200 < 0.200B 9.44 1.0601 * 0.898 * 0.898 0.6BA 68.89 0.9528 0.953 . 0.953 0.6BE 240.93 0.8891 0.888 0.888 0.5BI 3.37 0.1993 0 0.195 < 0.800 < 0.800CA 390.20 78.4194 78.42 78.42 0.5CD 26.41 0.8741 0.860 0.860 0.4CO 23.89 0.8397 0.839 0.839 0.6CR 21.39 0.8632 0.861 0.361 0.3CO 67.79 0.8739 0.873 0.873 0.6FE 278.55 9.5672 9.567 9.567 0.6IN 4.14 0.0675 0 0.059 < 0.200 < 0.200K 13.91 16.0336 12.55 12.55 0.7LI 33.07 0.8766 0.877 0.877 0.6MG 48.53 19.3159 19.81 19.81 0.5MN 163.95 i.b265 1.526 1.526 0.5MO 6.69 0.0025 0-0.003 < 0.050 < 0.050NA 75.46 24.0725 23.41 23.41 0.8NI 19.84 0.8597 0.855 0.855 0.5P 4.21 3.0235 0-0.698 < 0.300 < 0.300PB 12.01 0.8757 0.869 0.869 3.7PT 5.70 0.4572 0 0.066 < 0.200 < 0.200S 212.09 12.9294 * 11.69 * 11.69 0.6SB 15.51 0.8662 0.819 0.819 4.1

Q SE 12.04 1.1073 * 0.824 * 0.824 4.8SI 44.18 5.2751 5.217 5.217 0.6SN 7.13 1.7151 * 0.998 * 0.998 7.2SR 495.03 1.0333 1.032 1.032TE 14.22 0.1115 U 0.110 < 0.200

1<BE 6.39 -0.4002 U-0.000 < .001 cBI 3'34 0.1680 U 0.167 < r, son n annCA 360.75 72.1566 72.16 ?_ ?6 ' o'f<CD 4.12 -0.0024 U-0.002 - o 003<CO 6.32 -0.0103 U-0.010 < o'S 0 < oCR 7.06 0.0012 U 0.000 < 0 009 - SCU 27.99 o.OOOl U-0.000 , 0 010 : o0FE 39.98 l.niOl 1.010 ' i S 0 ' 07IN 412 0.0540 U 0.054 J 0 2 0 0 '0200K 10.04 6,2363 3.916 T qje ' °'o°°LI 11.96 0.0220 * 0.022 * 0 02? \1

.5:S.7 8-?:l!?S5 "1,11 ' •« ;

. e i _•SB 9.55 -0.0282 0-0.047 < o 060 - O'If „•:!! -J:SI1 "?:?•} « : =f -ii si ; i ; I

:{ -o°:.°;U SI:.0?? J S.-gj 1:.a 4:,°SJ g4:.°S .< 0°:?o2S J :.s:jsj jsrj «

SAMPLE NO. 15 053-05B

WEIGHT 1 GRAMS VOLUME 1 ML

21:25:24 20-NOV-87 15 053-05B


AG 12.89 0.0069 U 0.007AL 12.71 0.0286 U 0.015As 6.10 0.0000 0-0.016Au 4.48 0.1580 0-0.020B 7,65 0.3692 U 0.213RA 13.12 O.U64 0.116

<BE H.44 -U.OOUU 0-0 000B! 3.27 0.0821 U 0.081CA 399,07 80.3052 80.31CD 4.24 0.0025 0-0.001

<CO 6.29 -0.0119 0-0 012CR 7.07 0.0022 0 0,001CO 28.05 0.0015 0 0.001FE 65.02 1.9081 _ 908IN 4.26 0.1675 0 0 167K 10.16 6.5572 3.862" 11-72 0.0123 0 0.012MG 37.87 14.5220 14.52MN 52.97 0.4452 o 445

SAMPLE NO. 12 053-02B( )WEIGHT 1 GRAMS "" VOLUME 1 ML

21:18:04 20-NOV-87 12 053-02B


AG 13.05 0.0166 * 0.017 ""* 0.017 38.8AL 12.84 0.0655 U 0.053 < 0.200 < 0.200AS 6.12 0.0173 U 0.006 c 0.300 < 0.300AU 4.53 0.1777 U-0.015 < 0.200 < 0.200B 7.32 0.2419 U 0.088 < 0.600 < 0.600BA 15.66 0.0759 0.076 0.076 0.6<BE 6.42 -0.0001 U-0.000 < 0.001 < 0.001BI 3.29 0.1055 U 0.105 < 0.800 < 0.800CA 365.75 73.2200 73.22 73.22 0.2CD 4.22 0.0014 U-0.002 < 0.003 •; 0.003<CO 6.30 -0.0115 0-0.011 < 0.010 < 0.010CR 7.13 0.0056 U 0.004 < 0.009 < 0.009CO 28.53 0.0121 * 0.012 * 0.012 8.3FE 25.49 0.4903 0.490 0.490 2.8

<IN 4.04 -0.0135 0-0.014 < 0.200 < 0.200K 9.80 5.6467 3.366 3.366 2.2LI 11.48 0.0024 0 0.002 < 0.020 < 0.020MG 32.31 11.7567 11.76 11.76 0.5MN 74.44 0.6544 0.654 0.654 0.3MO 6.59 -0.0040 0-0.007 < 0.050 < 0.050NA 59.51 16.7025 16.19 16.19 0.5NI 6.18 0.0347 * 0.029 * 0.029 5.0P 3.14 0.4256 0-0.319 < 0.300 < 0.300PB 8.28 -0.0047 0-0.005 < 0.050 <. 0.050PT 5.39 0.2038 0 0.020 < 0.200 < 0.200S 214.88 13.1343 * 12.06 * 12.06 0.6<SB 9.46 -0.0417 0-0.042 < 0.060 < 0.060<SE 9.11 -0.0192 0-0.019 < 0.300 < 0.300SI 55.51 7.0194 7.018 7.018 0.4SN 5.95 0.0286 0-0.016 < 0.500 < 0.500SR 113.70 0.1696 0.168 0.168 0.3TE 13.97 0.0394 0 0.039 < 0.200 < 0.200TI 10.13 0.0071 0 0.007 < 0.050 < 0.050<TL 4.30 -0.0136 0-0.014 < 0.090 < 0.0900 8.10 0.1006 0-0.083 < 0.500 < 0.500<V 9.20 0.0026 0 0.003 < 0.020 < 0.020W 3.99 -0.0104 0-0.011 < 0.100 < 0.100<Y 9.93 0.0012 0 0.001 < 0.009 < 0.009ZN 8.11 0.0094 * 0.007 * 0.007 6.1

SPECTRO TEMPERATORE = 40.490 30.000 TO 40.000SAMPLE NO. 13 053-03B( )WEIGHT 1 GRAMS VOLOME 1 ML

21:20:32 20-NOV-87 13 053-03B


<AG 12.80 0.0014 0 0.001 < 0.009 < 0.009AL 12.53 -0.0212 0-0.034 < 0.200 < 0.200AS 6.14 0.0347 0 0.024 < 0.300 < 0.300AU 4.34 0.1041 0-0.072 < 0.200 < 0.200B 7.08 0.1479 0-0.005 < 0.600 < 0.600BA 15.50 0.0732 0.073 0.073 0.2<BE 6.38 -0.0002 0-0.000 < 0.001 < 0.001 « r>Q OBI .3.28 0.0938 00.093 < 0.800 < 0 . 800 ft D i Q 0 C- " "'CA 345.76 68.9685 68.97 68.97 0.3 H*v

r 1SPECTRO TEMPERATORE = 40.620 30.000 TO 40.000SAMPLE NO. 10 3711053-013(Q)WEIGHT 1 GRAMS VOLUME 1 ML

21:13:01 20-NOV-87 10 8711053-01B


AG 12.95 0.0105 * 0.011 * 0.011 24.5AL 20.46 2.1747 2.175 2.175 0.8AS 6.17 0.0659 U 0.023 •-' 0.300 < 0.300AU 4.56 0.1909 0-0.022 < 0.200 <: 0.200B 7.55 0.3293 U 0.076 < 0.600 < 0.600BA 18.77 0.1270 0.127 0.127 0.2BE 6.78 0.0013 U 0.000 < 0.001 < 0.001BI 3.36 0.1954 U 0.138 c 0.800 < 0.800CA 432.44 87.4031 87.40 87.40 0.4<CD 4.21 0.0012 U 0.001 < 0.003 < 0.003<CO 6.37 -0.0079 0-0.008 < 0.010 < 0.010CR 7.19 0.0092 U 0.007 c 0.009 < 0.009CU 45.35 0.3812 0.380 0.380 0.5FE 415.51 14.4798 14.48 14.48 0.6IN 4.10 0.0324 U 0.019 < 0.200 <. 0.200K 10.80 8.1675 4.683 4.683 2.5LI 11.62 0.0081 U 0.008 < 0.020 -' 0.020MG 48.50 19.8010 19.79 19.79 0.5MN 58.33 0.4974 0.496 0.496 0.5MO 7.31 0.0434 U 0.039 < 0.050 < 0.050NA 65.96 19.6835 18.94 18.94 0.8NI 6.38 0.0472 * 0.039 * 0.039 7.4P 3.76 1.9322 0-0.093 < 0.300 < 0.300PB 8.75 0.1060 * 0.106 * 0.106 2.2PT 5.35 0.1680 U 0.015 < 0.200 •: 0.200S 262.19 16.6136 * 15.38 * 15.38 0.7SB 9.69 -0.0072 0-0.032 < 0.060 < 0.060<SE 9.12 -0.0167 0-0.017 < 0.300 < 0,300SI 71.63 9.4992 9.442 9.442 0.4SN 6.60 0.9624 0-0.058 < 0.500 < 0.500SR 200.67 0.3665 0.365 0.365 0.6TE 13.71 -0.0337 0-0.034 < 0.200 < 0.200TI 10.52 0.0532 * 0.053 * 0.053 4.4<TL 4.31 -0.0113 0-0.011 < 0.090 < 0.0900 8.09 0.0880 0-0.024 < 0.500 < 0.500

<V 9.20 0.0022 0 0.002 < 0.020 < 0.020W 4.12 0.0488 0 0.034 < 0.100 < 0.100Y 10.17 0.0070 0 0.007 < 0.009 < 0.009ZN 19.16 0.3350 0.330 0.330 0.6

SPECTRO TEMPERATURE = 40.580 30.000 TO 40.000SAMPLE NO. 11 053-01B PD DUP(D)WEIGHT 1 GRAMS VOLUME 1 ML

21:15:31 20-NOV-87 11 053-01BPDDUP Q Q\*

MV INT RAW CONC CONCEN DIL CORR a Q \ VRST& " RPD AVG

SR 4G 64 0.0031 U O.UG3 0.003 -. 0.003TE 16.30 0.7489 * 0.228 * 0.223 12.9TI 10.13 0.0308 U 0.031 C 0,050 < 0.050TL 6.20 0.4109 U 0.052 < 0.090 < 0.090U 8.70 0.8089 0-0.524 < 0.500 < 0.500V 13.38 0.5.406 0.418 0.413 1.0W 4.90 0.4569 * 0.269 * 0.269 2.6Y 10.04 C.0011 U 0.001 < O.OU9 •- 0.009ZN 47.74 1.2047 0,889 u.889 0.9

£''tif

SAMPLE NO. 8 BLANK .6010) 11-13(B)WEIGHT 1 GRAMS VOLUME 1 ML

21:08:01 20-NOV-87 8 BLANK (60101 11-18


<AG 12.78 -0.0018 U-0.002 < 0.009 < 0.009AL 12.60 0.1061 0 0.106 < 0.200 < 0.200AS 6.10 0.0139 U 0.014 •; 0.300 ' 0.300AU 4.42 0.0565 U-0.077 v 0.200 •- 0.200B 6.70 0.0733 U 0.073 < 0.600 ; 0.600BA 11.06 0.0044 U 0.004 < 0.009 v 0.009<BE 6.44 -0.0005 U-0.000 < 0.001 ••• 0.001<BI 3.20 -0.0078 0-0.008 < 0.800 c 0.800CA 21.48 2.2729 2.273 2.273 0.6<CD 4.18 -0.0014 U-0.001 «; 0.003 < 0.003CO 6.54 0.0056 U 0.006 < 0.010 < 0.010<CR 7.04 -0.0006 U-0.001 < 0.009 < 0.009CU 27.98 0.0240 * 0.024 * 0.024 1.9<FE 11.82 -0.2559 U-0.256 < 0.030 < 0.030<IN 4.06 -0.0270 U-0.027 < 0.200 < 0.200K 7.78 0.5564 U 0.036 < 0.300 < 0.300LI 11.42 0.0070 U 0.007 < 0.020 < 0.020MG 8.64 0.1672 * 0.167 , * 0.167 14.9MN 7.30 0.0010 U 0.001 < 0.003 < 0.003MO 6.68 0.0132 U 0.011 < 0.050 < 0.050NA 23.37 4.7017 4.702 4.702 0.1NI 5.62 0.0032 U 0.002 < 0.020 < 0.020P 3.00 0.0000 U-0.075 < 0.300 < 0.300PB 8.30 0.0157 U 0.016 < 0.050 < 0.050<PT 5.15 -0.0303 U-0.030 < 0.200 < 0.200S 37.07 1.4073 U 1.349 < 5.000 < 5.000SB 9.79 0.0490 U 0.041 < 0.060 < 0.060

i <SE 9.16 -0.0526 0-0.053 < 0.300 < 0.300j SI 10.22 0.1990 0 0.149 < 0.300 < 0.300

<SN 5.93 -0.0048 0-0.005 < 0.500 < 0.500SR 38.99 0.0044 * 0.004 * 0.004 2.8

__ TE 13.83 0.0534 0 0.053 < 0.200 < 0.200U TI 10.07 0.0237 0 0.024 < 0.050 < 0.050

<TL 4.36 -0.0053 0-0.005 < 0.090 < 0.090<0 8.OS -0.0419 U-0.042 < 0,500 < 0.500<V 9.18 -0.0035 U-0.003 < 0.020 < 0.020W 4.01 0,0606 U 0.061 < 0.100 < 0.100<Y 9.88 -0.0027 0-0.003 < 0.009 < 0.009ZN 7.80 0.0277 * 0.028 * 0.028 7.0

S 65.64 3.5079 U 3.345 < 5.1)00 -. 5.0uOSB 16.83 1.1050 1.083 1.083 1 3SE 12.48 1.2228 * 0.892 * 0.892 1.8SI 20.79 1.8249 1.770 1.770 0.7SN 5.95 0.0191 0-0.007 •; 0.500 v. 0.500SR 37.10 O.OOXU 0-0.000 -c 0.003 c 0.003<TE 13.60 -0.0103 0-0.010 < 0.2UO <- . 200TI 18.53 1.0253 1.025 1.025 0.3TL 8.63 0.9616 0.962 0.962 0.8

<-U 8.02 -0.0377 0-0.038 < u.5t)U •; 0.500V 16.81 0.9860 0.936 0.986 u.9W 3.96 0.0384 0 0.037 -. u.lOu o.lUO<Y 9.91 -0.0020 0-0.002 < 0.^09 , 'i.OO*ZN 41.25 1.0134 1.000 l.fHiti 06

SAMPLE NO. tf CAL BLANK( )WEIGHT 1 GRAMS VOLOME 1 ML

SAMPLE NO. 6 CAL BLANK( IWEIGHT 1 GRAMS VOLOME 1 ML

21:03:06 20-NOV-87 6 CAL BLANK


<AG 12.73 -0.0048 U-0.005 < 0.009 - 0.009<AL 11.97 -0.0692 U-0.069 < 0.200 -. 0.200AS 6.10 0.0139 0 0.014 < 0.300 •; 0.300AO 4.29 0.0066 0 0.007 < 0.200 < 0.200B 6.51 0.0013 U 0.001 < 0.600 < 0.600BA 10.86 0.0012 0 0.001 < 0.009 < 0.009<BE 6.43 -0.0005 0-0.001 < 0.001 < 0.001<BI 3.17 -0.0391 0-0.039 < 0.800 < 0.300<CA 10.76 -0.0085 0-0.009 < 0.060 < 0.060<CD 4.17 -0.0020 U-0.002 < 0.003 < 0.003<CO 6.26 -0.0076 0-0.008 < 0.010 < 0.010<CR 6.89 -0.0092 0-0.009 < 0.009 < 0.009<CU 26.74 -0,0033 U-0.003 < 0.010 < 0.010<FE 6.96 -0.4303 0-0.430 < 0.030 < 0.030<IN 4.07 -0.0135 0-0.014 < 0.200 < 0.200<K 7.46 -0.2445 0-0.244 < 0.300 < 0.300• LI : i . l H -'r ^O'-H t)-0,.?n.1 • 0. •'.•;",) -; •'-CO

NI "- "•' / t.'iv) :i i.i. u 1 I '.i .);;'• • ; .,p :' - -- "'!f.H I l - - i l <0h . ,, n,,'..', , „"."

<PB 6.14 -n.ui;o4 0-0.U2U ^ G.ObO •- ,) i:60<PT 5.13 -0.0413 0-0.041 < 0.200 < 0*200S 18.51 0.0419 0 0.014 < 5.000 < 5 000SB 9.71 0.0370 U 0.037 < 0.060 < 0 060<SE 9.12 -0.0680 0-0.068 < 0.300 < 0 300<SI 8.84 -0.0133 U-0.013 < 0.300 ' < 0 300<SN 5.85 -0.1143 0-0.114 < 0.500 < 0.500<SR 36.66 -0.0009 U-0.001 < 0.003 < 0 003<TE 13.55 -0.0244 0-0.024 < 0.200 < 0 200<TI 9.83 -0.0047 0-0.005 < 0.050 < 0 050<TL 4.30 -0.0204 0-0.020 < 0.090 < 0 090<U 8.00 -0.0629 0-0.063 < 0.500 < 0 500,<V .9.12 -0.0117 0-0.012 < 0.020 < o'o2W 3.89 0.0059 0 0.006 < 0.100 < Q' '

<FE 13.33 -0.2018 U-0.202 < 0.030 •.' 0.030 '' & I *14.06 -0.0243 0-0.024 < 0 200 < 0.2oSr ^ ' I

K 7.76 0.5143 * 0.514 * 0 514 9.8LI 11.63 0.0155 U 0.016 < 0.020 < 0.020<MG 8.29 -0.0066 0-0.007 < 0.100 < 0.100MN 7.40 0.0019 U 0.002 < 0 003 < 0 003MO 8.12 0.1076 * 0.108 * O.loS 27.1NA 15.27 0.9567 0.957 0.957 4.6NI 5.59 0.0010 U 0.001 < 0.020 < 0.020P 3.01 0.0244 0-0.561 < 0.300 < 0.300PB 8.40 G.G408 U 0.041 -. 0.050 v 0.050<PT 5.11 -0.0578 U-0.058 < 0.200 < 0.200S 25.90 0.5859 U 0.556 < 5.000 •. 5.000>SB 76.66 10.0830 10.08 10.08 2.5SE 11.32 0.7783 0-0.229 < 0.300 < 0.300SI 9.43 0.0769 0-0.007 < 0.300 < 0.300SN 12.81 9.8333 9.833 9.833 1.6SR 37.87 0.0019 U 0.002 < 0.003 < 0.003TE 14.64 0.2812 * 0.281 * G.281 50.6TI 10.04 0.0205 U 0.021 < 0.050 < 0.050<TL 4.31 -0.0181 U-0.018 < 0.090 < 0.090U 8.06 0.0042 U-0.028 < 0.500 < 0.500V 9.34 0.0169 U 0.017 < 0.020 < 0.020W 3.98 0.0488 U 0.049 < 0.100 < 0.100Y 10.06 0.0017 U 0.002 < 0.009 . <- 0.009ZN 7.72 0.0255 * 0.024 ' * 0,024 10.7

SAMPLE NO. 4 EPAICP-7( )WEIGHT 1 GRAMS VOLUME 1 ML

20:56:50 20-NOV-87 4 EPAICP-7


AG 28.69 0.9627 0.963 0.963 0.8AL 15.66 0.9509 * 0,951 * 0.951 2.4AS 6.11 0.0208 U 0.018 < 0.300 < 0.300AO 4.32 0.0171 0-0.122 < 0.200 < 0.200B 9.20 1.0382 * 1.038 * 1.038 2.0BA 72.36 1.0143 1.014 1.014 0.9

<BE 6.55 -0.0001 0-0.000 < 0.001 < O.OOl'<BI 3.18 -0.0234 0-0.023 < 0.800 < 0.800CA 10.95 0.0326 0 0.033 < 0.060 < 0.060<CD 4.19 -0.0010 0-0.001 < 0.003 < 0.003<CO 6.29 -0.0065 0-0.006 < 0.010 < 0.010•-CR 6.97 -0.1044 U-0.004 < 0.009 . 0.0,19'ilt.! /n • . ,;>... -.:-;! .!(,:;. I;.: ;. •)!>;

FE >•• '-...' -4-.)n ••• ••• 44-, : . ':. . .. •-.IN 4 r, • ' * 7 : u i.;-:-: . , . ,, .. ..;:,.K ! 1 . 4, .-i, ?.>.!•!:; S. ciTil

^LI 'l i A -.1 ot'i'. 4 i i - u .jui•.Wt A •'.". u 11 [.32 n-o.ma .<MN Y . I / -U.UUU..H U-U.UUO •. U.UU3 < U.OU3MO 6.75 0.0178 0 0.018 < 0.050 < 0.050NA 14.22 0.4699 0.470 0.470 2.5<NI 5.51 -0.0038 0-0.004 < 0.020 < 0.020<P 2.98 -0.0570 0-0.057 < 0.300 < 0.300<PB 8.16 -0.0157 0-0.016 < 0.050 < 0.050<PT 5.12 -0.0496 0-0.050 < 0.200 < 0.200S 19.81 0.1380 0 0.136 < 5.000 < 5.000SB 11.86 0.3592 0.350 0.350 13.6<SE 9.05 -0.0975 0-0.098 < 0.300 < 0.300SI 15.06 0.9442 * 0.893 * 0.893 1.9<SN 5.85 -0.1191 U-0.119 < 0.500 < 0.500SR 37.32 0.0006 00.000 < Ol«p3 ft Q 9 CB.?03

-<TE 13.53 -0.0291 0-0.029 < M §00 ^ *-* V" V. 200TT Q O * T r* n r» n A T T n n A O / - n r \ - ; r t x n n c n

<AS 6.05 -0.0381 0-0.038 < 0.300 < 0.30-^AU 4.33 0.0223 0-0.110 < 0.200 < 0.200<B 6.40 -0.0399 0-0.040 < 0.600 < 0.600BA 10.96 0.0028 0 0.003 < 0.009 < 0.009<BE 6.30 -0.0010 0-0.001 < 0.001 < 0.001<BI 3.16 -0.0547 0-0.055 < 0.800 < 0.800<CA 10.69 -0.0227 0-0.023 < 0.060 < 0.060<CD 4.13 -0.0033 0-0.003 < 0.003 < 0.003<CO 6.31 -0.0055 0-0.005 < 0.010 < 0.010<CR 6.94 -0.0066 U-0.007 < 0.009 < 0.009<CU 26.70 -0.0042 0-0.004 < 0.010 < 0.010<FE 14.45 -0.1618 0-0.162 < 0.030 < 0.030<IN 4.04 -0.0405 0-0.041 < 0.200 < 0.200K 7.56 0.0084 U 0.008 < 0.300 < 0.300<LI 11.11 -0.0054 0-0.005 < 0.020 < 0.020<MG 8.18 -0.0613 0-0.061 < 0.100 < 0.100<MN 7.17 -0.0002 U-0.000 < 0.003 < 0.003MO 6.52 0.0026 U 0.003 < 0.050 < 0.050<NA 12.10 -0.5068 0-0.507 < 0.080 < 0.080NI 5.59 0.0014 0 0.000 < 0.020 < 0.020<P 2.98 -0.0570 U-0.057 < 0.300 < 0.300>PB 50.67 10.0008 10.00 10.00 0.6<PT 5.08 -0.0881 0-0.088 < 0.200 < 0.200S 19.49 0.1142 0 0.114 < 5.000 < 5.000<SB 9.22 -0.0375 0-0.038 < 0.060 < 0.060<SE 9.04 -0.1014 0-0.101 < 0.300 < 0.300SI 9.11 0.0282 0 0.028 < 0.300 < 0.300<SN 5.84 -0.1382 0-0.138 < 0.500 < 0.500<SR 36.62 -0.0010 U-0.001 < 0.003 < 0.003<TE 13.45 -0.0534 U-0.053 < 0.200 < 0.200<TI 9.83 -0.0043 0-0.004 < 0.050 < 0.050<TL 4.32 -0.0159 0-0.016 < 0.090 < 0.090<0 7.92 -0.1676 0-0.168 < 0.500 < 0.500<V 9.07 -0.0173 0-0.017 < 0.020 < 0.020<W 3.85 -0.0089 0-0.009 < 0.100 < 0.100<Y 9.88 -0.0028 0-0.003 < 0.009 < 0.009ZN 6.87 0.0003 U 0.000 < 0.006 < 0.006

SPECTRO TEMPERATORE = 40.120 30.000 TO 40.000SAMPLE NO. 2 STD»3()WEIGHT 1 GRAMS VOLOME 1 ML

20:51:58 20-NOV-87 2 STD«3


AG 13.98 0.0707 0.071 0.071 6.0AL 12.81 0.1632 U 0.163 < 0.200 < 0.200AS 15.83 10.1321 10.13 10.13 0.7AO 29.32 9.8751 9.741 9.741 0.3B 31.67 9.7131 9.713 9.713 0.3BA 613.10 9.9227 9.923 9.923 0.6BE 2606.76 9.8587 9.859 9.859 0.6BI 11.72 9.9883 9.988 9.988 0.9CA 13.86 0.6515 0.652 0.652 1.3CD 259.09 10.0229 9.887 9.887 0.3CO 210.54 9.8787 9.879 9.879 0.3CR 171.00 9.8606 9.855 9.855 0.3CU 475.54 9.8504 9.850 9.850 0.5<FE 10.88 -0.2897 0-0.290 < 0.030 < 0.030IN 16.10 9.7379 9.738 9.738 0.3

>K 58.83 129.6940 129.1 129.1 0.5LI 255.33 9.8813 9.881 9.881 0.7MG 9.73 0.7071 0.707 0.707 4.9MN 1019.70 9.8661 9.866 9.866 0.4•MO 157.06 9.9177 9.916 9.916 0.7

< /s/' <-» / 7f

ICPES

INSTRUMENT LOG

WORK ORDER I'.: DtOfl

vvo«sl>1 1 070 -/$}

INSTRUMENTDATE /'- CV^-Q r —— ANALYST

PROFILE ELEMENT __________ CONCENTRATION _ ___/_ . MILL I VOLTAGE <W . Z ??Z

. /BKC CORR USED(?) Yf

FLOW RATE __

HC-IR RAW DATA

0330°

Project No. ____BookNo.__l_ 27

From Page N o . >£1> & 1. PkHt covxc. -~*pl«.

'HO

3o^A H05ft 3

OS ft ^L <l 5.005 /iS-Kl

SoIt 05<\

3'3

-01A T 13/1 :<&l *\ £OS3>as*l <*

i*) at.s s'.ot. yas c l^137

-oSAS> dC *?.0

S*7 il cqc-

-OSA XOL ^\ SJOo/aS^i, <3 M.M 5.»«

87 II OMl -ac \ .

S.OOa/OS

(A

-•03 A. To Page No,

& Undtrstood by m«, L«IM«I u <, -\ iinu«rit*a DV . r\ r\ /i iOat«'/ao/,71

o3cO^C05C

QC N57.0

V

Project No.———. Book No.,, %

\o^\\ ft XDL

15ft » 4Umft \ * 1,3

38 S .fc 5.t««/2S^L

rom Page No..?5? _ .ocr•* . x* l"h B, L P^^t c*-c.

0. a-S IOHO/^O *>i o _ \ \3 M.*j 1050 mo ^L O.i7| 1.3 IOM0/MO t*L 0,05i \.3 IOHO/MC? ^L 0,0."

3 ^-^ I030/40 /hL 0.1*73 S-H io3o/<|o *KL O.V7

Understood by me,'

&',<***-

^ ^ ;_; __ _ ~,..-- g ,».LJ., .4 rf|-. ,,'.: -:_ _v :.:%._,ti;.'i.,, . . 7 444'.^ i• r in

• C ——:———---- - -- • —— ;———f£•:-

" ""-•"•- • "-'• ' . ,:

Jf j l -'fa'lkfe '

-L!i -;:3,.l

- f«••-- -"f

Jb&«£:

f------ - •..- --- -'- f_- ,'-_.____—._._._..!&.:./•

Sk11•• ."

^Mi,f-.:.:i-::::-;:v..:.::n -;:-;r;i*— ———— -— — --" ——— -•-——-•

:.•-:•,' - . - : ; . - . . - - . •- ;--...-=•• r.\ -r-. . .-—-— --:-.•—..•.-• - .--- . . '• - — - • . _ • - - - • - • • - ....... . ,

' • ;•P7

r-—l- ii SiSSMM - :j --'. is*

RR103303

r -"u

P * .'?•5. ° : f'":" -HflWr?-•"

-^ .....j.i -.;/--rr~ : - >-T*-

.7 . --_--., ......——— ————^-^_———— .___.._ ..... ....

0 _ ; . ..:.: ...;r-{:.7_-;-.,, . ',- ; -

s:-.:; .r. - :--

QUALITY CONTROL SUMMARY

E I ement -^ Ana I yst ^ Date

Standard Cal Ibrat ion I n i t i a l QC Check Cont inu ing QC Check

Cone. Pk Height Measured Theo. j_ Rec. Measured Theo. i Rec

13*7Corr. Coef. ' 3 SSlope ________ * )3?int. _______ 135 137

OupI icates

Sample No. Sample Result Duplicate Result £RPD

Spikes

Spike + SampleSample No. Result Sample Result 'Spike Added % Recovery

03305

1

UI

e a1

oo

llH

oo10

filtf* *

i(Atn u.

Cf

vi

8

doDC

r-

)6

o ®

< Q.

spl»**>— 4- 5

*« *•s:iLJjM4j^ 9N C 4-

— N -I85. 2

3 -»

O JlX •»- 4-<*. or~1«4' 2• O CBCM « I*** 4- 3 —~ C -O +-$ U 0 •</) U — >^ o .a —*-• a. <o •*•

^ a__iaM M N

QC SummaryPage 2

2. Inorganic Carbon Mode

Sample. .N2aC03 Run #1 11.30 10.04 88.8

*2 11.30 11.17 98.8#3 11.30 9.04 80.0#4 11.30 11.67 103.3

flRI03307

METHOD

OPERATING MODEMODE MODE SELECTED

ELEMENT MODE: CHN(1) SULFUR<2) OXYGEN(3) 1PRINTER? (Y/N) YAUTOSAVE? (Y/N) YBALANCE? (Y/N) NMANUAL BLANK-AV? (Y/N) NMANUAL K-AV? (Y/N) NCHANGE CRIT? (Y/N) N

0;77Ue

REVIEW RESULTS

n"v< ,H- • ' tj v «.DATA SELECTED - ''_"•* ———-£ ^

CARBON HYDROGEN NITROGEN r ' v •'-1 '• V'-f\[° BLANK O.O1 -0.02 1.1O ' ' \i \

KFACT 8.79 64.SO 1O.36#7 ' NA2C03 *£• WTX 10.04 -O.27 O.72#S^CAC03 KFACT 19.60 64.50 1O.36#9 NA2C03 # WTX 11.17 -0.27 O.72#10 O8711O54-O5A WTX O.05 -O.O1 O.O4#11 8711054-06A WTX O.O5 -O.O1 O.07#12 8711053-09A WTX O.O7 -0.01 0.3O .. / rj>~±#13 8711053-10A WTX 0.15 -O.O1 -O.O4 H O-"> -> '#14 8711O53-11A WTX O.16 -O.O2 O.29#15 8711053-12A WTX O.O8 -O.OO O.O3#16 6lC BLANK 0.02 -O.O2 O.96#17 NA2C03^C WTX 9.04 -O.23 -O.O1#18 8711O53-13A WTX O.17 -O.OO -O.ll#19 8711053-14A WTX 0.1O -O.OO -O.OO • <nO#20 8711053-15A WTX 0.14 -0.00 -0.08 (A J#21 S711O53-16A WTX1 ' O.36 -O.O1 -0.10#"" 8711053-17A WTX O. 16 -O.OO -0.17- ^* 8711053-17S WTX 6.O7- -O. 14 O.24-f • V. /v >'A'~\

4 8711053-17S2 WTX 7.41 -0.17 O.O1-.A <{..25 NA2CO3 < C WTX 11.67 -O.27 -O.OO

RADIANCORPORATION

Quality Control SummaryJob Number 1050, Mill Creek

Perkin Elmer Elemental AnalyzerTOC in soil assayed by difference analysis (Total Carbon less Total Inorgani'.Carbon).

BLANKSInorganic Carbon Tests Cart_QH_Uy.Blank (Run No. 5) 0.01Blank (Run No. 16) 0.02

Total Carbon Test SeriesBlank #1 0.05Blank *2 0.03

MS/MSP

The organic carbon spike was acetanilde.Sample tt 06585

>le_IE .__ SasiEle. Elks ge fivejcz M>1££ BEE

Matrix Spike (MS) 1.56 70.13 67.55 94%3%

Matrix SpikeDuplicate I.MSD) 1.56 49.25 49.38 97%

1. Total Carbon Mode

%CarbonKHP Run 1*1 47.05 46.49 98.8

*2 47.05 45.77 97.3#3 47.05 45.84 y7 4*4 47.05 46.46 98.7tf5 47.05 48.19 102.4

RR103309

ROY F. WESTOW-REACGSA Raritan Depot, Building 209, Bay F

Woodbridge Avenue, Edison, New Jersey 08817

November 9, 1987

Radian CorporationS501 Mo-Pec Blvd.Austin, Texas 78720-1008

Attn: Robert Richardson

Dear Rob,

As per our conversation on November 6, 1987, six (6) water and nine(9) sediment samples have been shipped to your laboratory foranalysis.The analyses to be performed are as follows:

PP Metals Base/Neutral Acids ExtractablePCB Total Petroluem HydrocarbonVOA TOCGrain Sizing (Sieve & Hydrometer)

The analyses are to be performed according to EPA Federal Register,Methods for Chemical Analysis of Water and Wastes and EPA TestMethods for Evaluating Solid Waste, Sept.,1986 with a ContractLaboratory Program (CLP) type data package. The QA/QC requested is10% matrix spike/matrix spike duplicate (MS/MSD) on all samplesanalysis except Grain Sizing, which will only get a duplicate.The Grain Sizing analysis is the lowest priority to be performed, soif extra sample is needed to perform other tests use the Grain Sizesample jars.

The final report is due 15 working days from receipt of samples inyour lab or December 3,1987.

The data package for the GC/MS should include:

1. Spectra and tabulation of ions for DFTPP for every twelve ortwenty-four hours of analysis.

2. Total ion chromatograms for every blank, standard, sample, andmatrix spike.

3. Spectra for standards of any compounds with sample hits.

^ 3 f

4. Spectra for hits in samples.

5. Response tabulation for each point in the most recently analyzedcalibration range.

6. Response factors for each daily check standard.7. All surrogate and"internal standards must be clearly labeled on

the total ion chromatograms.8. Each data sheet and chromatogram of spectrum must be clearly

labeled with the sample identity and date and time of analysisplus dilution and/or concentration factors.

9. All sample analysis results must be presented in tabulated form-data sheets alone are not acceptable.

10. All surrogate standards recoveries must be presented in tabulatedform. -

11. Sample matrix spikes must be presented in tabulated form.12. Instrument and method detection limit for each parameter.

The data package for gas chromatographic analysis should include:

1. Clearly labeled copies of the most recent calibration range forthe compounds of interest.

2. A list of instrument and method detection limits for eachcompound analyzed.

3. Chromatograms of all samples, daily standards and blanks. Allchromatograms must be clearly labeled with the standard or sampleidentity, date and time and dilution/concentration factors. Onestandard for each parameters must be analyzed for every twelvehours of analysis.

4. All instrument conditions including oven temperature, detectortemperature and type, column, sensitivity and chart speed.

5. Tabulation of sample results.6. Tabulation of any internal and/or surrogate standard results.

Data package for the PP Metals analysis should include:

1. Copies of the analysts notebook that show not only results butstandard curve used.

2. A list of instrument and method detection limits for eachcompound analyzed.

3. Copy of sample digestion method.4. Tabulated matrix spike and duplicate results.5. Tabulated sample results.6. All instrument printouts and notebook pages for standard curve.

The data package for the remaining analyses should include:

1. Copies of all analyst's notebook data.2. Tabulated sample results.3. Tabulated duplicate results.4. Copy of standard curve used.5. Copies of all raw data.

s rirj rSo1.?; sr r:? -- * *>i«. The Price is nocattached chain of custody an"5 return ^alyses' .Please sign theby December 3, 1987. Results sJoulS me Wlth the final reportaddress: results snould be sent to me at the following

ROY F. WESTON - REACGSA Raritan Depot, Bldg 209 RJ»,, «-woodbriage Avenue, E*ilm^ea B ay .^

p*««".5',.rijtqif;sjrs;."5S?bl—concern ing the —^—.Sincerely,

therine Paolino

3 3

REAC SUPPORT ORGANIZATIONGSA RARITAN DEPOTWOODBRIDGE AVENUEBUILDING 209. BAY FEDISON. NJ 08837

MANAGERS \ ^ DESIGNEflS/CONSUI.TANTS PHONE: 201-906-0369

DATE: January 5, 1987

TO: David ChartersU.S. EPA ERT

FROM: Michael A.REAC QA Officer

SUBJECT: MILLCREEK, PENNSYLVANIA ANALYTICAL REPORT STATUS3347-01-01-1050

The purpose of this memo is to document the events which have caused thedelay in the release of the analytical report for sampling conducted atthe Millcreek site on November 3-5, 1987.

Our laboratory services subcontractor, Radian Corporation, failed to sendus a complete data package describing organic analyses procedures.Volatiles were calibrated on two different days by the lab. The VOAcalibration documentation received by REAC was incomplete for both ofthose days. The entire VOA package for sample 6578 was also omitted fromthe labs report. As a result, it was not possible for us to validate VOAdata. In addition, GC/MS tuning data was not supplied in the labs report,which made validation of BNA compound results impossible. This missinginformation was received by REAC today and we will proceed with our dataevaluation.

As of today, all solids TOC data is still undelivered. In reviewing thislab's overall data package, we had also discovered several miscalculationsand have been working with the lab to obtain revised data reportingpages. We anticipate that these remaining issues will be resolved byJanuary 19 and that we will deliver the final report to you by January22. Petroleum hydrocarbon and PCB data is currently approved forrelease. If you desire those results now, please contact Gary Buchanan.

cc: L. WhiteG. BuchananM. MurphyJ. Chang

eh/ski rka/m-05

ARI033I3

JfiN 04 '88 13:38 RhtDIAt, nUSTIN BLDG 4 ._ p.?

To: Kathy Paolino & Rene Cohen

From; Robert RichardsonRadian - Austin, TX

Res Update on project 1041/1050

1041 - TOO instrument vent down Thursday. Looks like samples will be runtoday.

MDL's sent to Marian Fed Ex. She should gat them today.

1050 - TOC's - see above

Volatiles - Ail data requested were in the 13/17 submitted. Theresponse tables for 11/4 and 12/8 were located behind the Sample 01'svolatile data package. To save you time, I will reassemble the package andforward to you tonight. Each part will be clipped separately and have anidentifing cover sheet attached.

Semi'a - We are preparing the DFTPP and Quant Rept's for shipmenttonight with the volatilea package.

Thanks,

Rob R. JAK4 t383S&A

RADIANC O R P O R A T I O N

DATA REPORTFOR

WESTON-REAC

JOB NO. 1050VOLUME 1

t i V10

s &/

8501 Mo-Pac Blvd./P.O. Box 201088/Austin, TX 78720-1088/(512) 454-4797

ARI033I5

CONTENTS

SECTION ITEM

VOLUME 2

5 RAW DATA

TOC

8270

8240

HC-IR

ATOMIC ABSORPTION

LEADTHALLIUM

ARSENICVOLUME 3

5 RAW DATA, CONT.

ATOMIC ABSORPTION, CONT.MERCURY

SELENIUM - 11/18SELENIUM - 11/28

ICPESPCB'S

LAB NOTES

CHROMATOGRAMS

RADIANC O R P O R A T I O N

DATA REPORTFOR

WESTON-REACJOB NO. 1050VOLUME 3

R t o _. i EDEC i o W!

8501 Mo-Pac Blvd./P.O. Box 201088/Austin, TX 78720-1088/(512) 454-4

C O R P O R A T I O N

Date: 01-04-88

Client: Roy F. Weston-ReacContact: Kathy Paolino

Radian ID: 87-11-053Reac Job No: 1050Site: Mill Creek, PA

Item: Resubmittal of Volatiles Data

R i . »: • * £ DJAN 5 19bj

8240 WATER SAMPLES

INCLUDES SURROGATE RECOVERIES

RR1033V9

79-01-6 Trichloroethene <2.0 <2.0 <2.o <2.o75-69-4 Trichlorofluoromethane <2.0 <2.0 <2.0 <2.'o75-70-7 Trichloromethanethiol N\A N\A N\A N\A96-18-4 1,2,3-Trichloropropana N\A N\A N\A N*108-05-4 Vinyl acetate <2 <25 <25 <JP75-01-4 vinyl chloride <2.o <2.o <2.o <2.o1330-20-7 Xylenes <2.0 <2.0 <2.0 <2.0

SURROGATE RECOVERIES (results in % recovery)

d4-l,2-dichloroethaane 96 112 122 120d8-toluene 97 104 101 99p-bromofuorobenzene 98 105 106 100

NOTES AND DEFINITIONS FOR THIS REPORT.N\A -STANDARD WAS NOT AVAILABLE; THE COMPOUND WAS SEARCHED.USING AN NBS LIBRARY OF 42,000 COMPOUNDS.

79-01-6 Trichloroethene 7.1 5.7 3.875-69-4 Trichlorofluoromethane <2.0 <2.0 <2.o75-70-7 Trichloromethanathiol N\A N\A N\A96-18-4 1,2,3-Trichloropropane N\A N\A N\A108-05-4 Vinyl acetate <2 <25 <2575-01-4 Vinyl chloride <2.0 <2.0 <2.o1330-20-7 xylene» <2.0 <2.o <2.o

SURROGATE RECOVERIES (results in % recovery)

d4-l,2-dichloro«thaane 104 108 94d8-toluene 97 91 97p-bromofuorobenzene 94 93 107

NOTES AND DEFINITIONS FOR THIS REPORT.N\A -STANDARD WAS NOT AVAILABLE; THE COMPOUND WAS SEARCHED.USING AN NBS LIBRARY OF 42,000 COMPOUNDS.

\0332i

PageClient: WESTON LABORATORIES 01A 6572 SOIL VOA

RADIAN INTERNAL 02A 6578 SOIL VOARADIAN INTERNAL 03A 6579 SOIL VOA

04A 6580 SOIL VOA

EPA METHOD 8240CAS # COMPOUND RESULTS IN ug/gLab No: A7-11-04101A 02A 03A 04A

67-64-1 Acetone <50 <50 <50 <5075-05-8 Acetonitrile <50 <50 <50 <50107-02-8 Acrolein <10 <10 <10 <10107-13-1 Acrylonitrile <10 <10 <10 <1071-43-2 Benzene <2.0 <2.0 <2.0 <2.075-25-2 Bromoform <2.0 <2.0 <2.0 <2.074-83-9 Bromomethane <2.0 <2.0 <2.0 <2.075-15-0 Carbon Disulfide <2.0 <2.0 <2.0 <2.056-23-5 Carbon Tetrachloride <2.0 <2.0 <2.0 <2.0108-90-7 Chlorobenzene <2.0 <2.0 <2.0 <2.0126-99-8 2-Chloro-1,3-butadiene N\A N\A N\A N\A"124-48-1 Chlorodibromomethane <2.0 <2.0 <2.0 <2.075-00-3 Chloroethane <2.0 <2.0 <2.0 <2.067-66-3 chloroform <2.0 <2.o <2.0 <2.o74-87-3 Chloromethane <2.0 <2.0 <2.0 <2107-05-1 3-Chloropropene <2.0 <2.0 <2.0 <210061-01-5 cis-l,3-Dichloropropene <2.0 <2.0 <2.0 <2.096-12-8 l,2-Dibromo-3-chloropropane <2.0 <2.0 <2.0 <2.0106-93-4 1,2-Dibromoethane <2.0 <2.0 <2.0 <2.075-95-3 Dibromomethane <2.0 <2.0 <2.0 <2.075-27-4 Dichlorobromomethane <2.0 <2.0 <2.0 <2.075-71-8 Dichlorodifluoromethane <10 <10 <10 <1075-34-3 1,1-Dichloroethane <2.0 <2.0 <2.0 <2.0107-06-2 1,2-Dichloroethane <2.0 <2.0 <2.0 <2.075-35-4 1,1-Dichloroethene <2.0 <2.0 <2.0 <2.078-87-5 1,2-Dichloropropane <2.0 <2.0 <2.0 <2.0100-41-4 Ethyl benzene <2.0 <2.0 <2.0 <2.075-21-8 Ethylene oxide N\A N\A N\A N\A97-63-2 Ethyl methacrylate <10 <10 <10 <10591-78-6 2-Hexanone <10 <10 <10 <1074-88-4 lodomethane <10 <10 <10 <1075-09-2 Methylene chloride <50 <50 <so <5078-93-3 Methyl ethyl ketone <50 <50 <50 <5080-62-6 Methyl methacrylate <10 <10 <10 <10108-10-1 4-Methyl-2-pentanone <10 <io ^nQ5-en-i «——._-_-••_ _—_- . *,«»*i.ajiw.iw <10 <10 <10 <1095-50-1 Propanenitrile N\A N\A N\A N\A100-42-5 Styrene <2.0 <2.0 <2.0 <2.0630-20-6 1,1,1,2-Tetrachloroethane <2.0 <2.0 <2.0 <2.079-34-5 1,1,2,2-Tetrachloroethane <2.0 <2.0 <2.0 <2.0127-18-4 Tetrachloroethylene <2.0 <2.0 <2.0 3.0108-88-3 Toluene <2.0 <2.0 <2.0 6.4t110-57-6 Trans-l,4-dichloro-2-butene <25 <25 <25 <25^156-60-5 trans-l,2-Dichloroethene <2.0 <2.0 <2..0 <2.010061-02-6 trans-l,3-Dichloropropene <2.0 <2.0 <2-.0 <2.o71-55-6 1,1,1-Trichloroethane <2.0 <2.0 <2.0 <2.079-00-5 1,1,2-Trichloroethane <2.0 <2.0 oq^0 <2.0

client: WESTON LABORATORIES OSA essi SOIL VOA

RADIAN INTERNAL 06A 6582 SOIL VOARADIAN INTERNAL 07A 6583 SOIL VOA

OSA 6584 SOIL VOA

EPA METHOD 8240CAS # COMPOUND RESULTS IN ug/g

Lab No: A7-11-041OSA 06A 07A OSA

67-64-1 Acetone <50 <50 <50 <5075-05-8 Acetonitrile <50 <50 <50 <50107-02-8 Acrolein <io <io <io <lo107-13-1 Acrylonitrile <lo <10 <io <io71-43-2 Benzene <2.0 <2.o <2.o <2.o75-25-2 Bromoform <2.0 <2.0 <2.o <2.o74-83-9 Bromomethane <2.0 <2.0 <2.0 <2.075-15-0 Carbon Disulfide <2.0 <2.0 <2.0 <2.056-23-5 Carbon Tetrachloride <2.0 <2.0 <2.0 <2.0108-90-7 Chlorobenzene <2.0 <2.0 <2.0 <2.0126-99-8 2-Chloro-1,3-butadiene N\A N\A N\A N\A124-48-1 Chlorodibromomethane <2.0 <2.0 <2.o <2.o75-00-3 Chloroethane <2.o <2.o <2.o <2.o67-66-3 Chloroform <2.o <2.0 <2.o <2.o74-87-3 Chloromethane <2.0 <2.0 <2.0 <2.o107-05-1 3-Chloropropene <2.0 <2.0 <2.0 <2.010061-01-5 cis-l,3-Dichloropropene <2.0 <2.0 <2.0 <2.o96-12-8 l,2-Dibromo-3-chloropropane <2.0 <2.0 <2.0 <2.0106-93-4 1,2-Dibromoethane <2.0 <2.0 <2.0 <2.075-95-3 Dibromomethane <2.0 <2.0 <2.0 <2.075-27-4 Dichlorobromomethane <2.0 <2.0 <2.0 <2.075-71-8 Dichlorodifluoromethane <10 <10 <10 <1075-34-3 1,1-Dichloroethane <2.0 <2.0 <2.0 <2.0107-06-2 1,2-Dichloroethane <2.0 <2.0 <2.0 <2.075-35-4 1,1-Dichloroethene <2.0 <2.0 <2.o <2.o78-87-5 1,2-Dichloropropane <2.0 <2.0 <2.0 <2.0100-41-4 Ethyl benzene <2.0 <2.0 <2.0 <2.075-21-8 Ethylene oxide N\A N\A N\A N\A97-63-2 Ethyl methacrylate <10 <10 <10 <lo591-78-6 2-Hexanone <10 <10 <10 <1074-88-4 lodomethane <10 <10 <10 <1075-09-2 Methylene chloride <50 <50 <50 <5078-93-3 Methyl ethyl ketone <50 <50 <50 <so80-62-6 Methyl methacrylate <10 <10 <io <lo108-10-1 4-Methyl-2-pentanone <10 <10 <10 <1095-50-1 Propanenitrile N\A N\A N\A N\A100-42-5 Styrene <2.0 <2.0 <2.0 <2.0630-20-6 1,1,1,2-Tetrachloroethane <2.0 <2.0 <2.0 <2.079-34-5 1,1,2,2-Tetrachloroethane <2.0 <2.0 <2.0 <2.0127-18-4 Tetrachloroethylene 2.8 <2.0 <2.0 <2.0108-88-3 Toluene <2.0 <2.0 <2.0 <2.0110-57-6 Trans-l,4-dichloro-2-butene <25 <25 <25 <25156-60-5 trans-i,2-Dichloroethen« <2.0 <2.0 <2.0 <2.010061-02-6 trans-l,3-Dichloropropene <2.0 <2.0 <2.0 <2.071-55-6 1,1,1-Trichloroethane <2.0 <2.0 <2.0 <2.079-00-5 1,1,2-Trichloroethane <2.0 <2.0 <2.0 <2.0

03323

Client: «ZSTOK ,„ SSS5 SOIL VOA

0

EPA METHOD 8240CAS # COMPOUND RESULTS IN ug/gLab No: A7-11-04109A 10A 11A

67-64-1 Acetone <50 <50 <5075-05-8 Acetonitrile <50 <50 <50107-02-8 Acrolein <10 <10 <10107-13-1 Acrylonitrile <10 <10 <1071-43-2 Benzene <2.0 3.0 <2.075-25-2 Bromoform <2.0 <2.0 <2.074-83-9 Bromomethane <2.0 <2.0 <2.075-15-0 Carbon Disulfide <2.0 <2.0 <2.056-23-5 Carbon Tetrachloride <2.0 <2.0 <2.0108-90-7 Chlorobenzene <2.0 <2.0 <2.0126-99-8 2 -Chloro-1, 3 -butadiene N\A N\A N\A124-48-1 Chlorodibromomethane <2.0 <2.0 <2.075-00-3 Chloroethane <2.0 <2.0 <2.067-66-3 Chloroform <2.0 <2.0 <2.074-87-3 Chloromethane <2.0 <2.0 <2.0107-05-1 3-Chloropropene <2.0 <2.0 <2.010061-01-5 cis-l,3-Dichloropropene <2.0 <2.0 <2.096-12-8 l,2-Dibromo-3-chloropropane <2.0 <2.0 <2.0106-93-4 1,2-Dibromoethane <2.0 <2.0 <2.075-95-3 Dibromomethane <2.0 <2.0 <2.075-27-4 Dichlorobromomethane <2.0 <2.0 <2.075-71-8 Dichlorodifluoromethane <10 <10 <1075-34-3 1,1-Dichloroethane <2.o <2.o <2.0107-06-2 1,2-Dichloroethane <2.0 <2.0 <2.075-35-4 1,1-Dichloroethene <2.0 <2.o <2.078-87-5 1,2-Dichloropropane <2.0 <2.0 <2.0100-41-4 Ethyl benzene <2.0 <2.0 <2.075-21-8 Ethylene oxide N\A N\A N\A97-63-2 Ethyl methacrylate <10 <10 <10591-78-6 2-Hexanone <10 <10 <1074-88-4 lodomethane <10 <10 <1075-09-2 Methylene chloride <50 <50 25078-93-3 Methyl ethyl ketone <50 <50 12080-62-6 Methyl methacrylate <10 <io <10108-10-1 4-Methyl-2-pentanone <10 <io <1095-50-1 Propanenitrile N\A N\A N\A100-42-5 Styrene <2.0 <2.0 <2.0630-20-6 1,1,1,2-Tetrachloroethane <2.0 <2.0 <2.o79-34-5 1,1,2,2-Tetrachloroethane <2.0 <2.0 <2.0127-18-4 Tetrachloroethylene <2.0 <2.0 <2.0108-88-3 Toluene <2.0 <2.0 <2.0110-57-6 Trans-l,4-dichloro-2-butene <25 <25 <25156-60-5 trans-l,2-Dichloroethene <2.0 <2.0 <2.010061-02-6 trans-l,3-Dichloropropene <2.0 <2.0 <2.071-55-6 1,1,1-Trichloroethane ,. t A £°U <2<0 ^?«°79-00-5 1,1,2-Trichloroethane j\RiU4d_t> <2.0

RADIANe o • i

MATRIX SPIKE DUPLICATE STUDY VOA (%)

Compound

1, 1-Dichloroethene

Toluene

Chlorobenzene

Benzene

Trichloroethene

6581 WaterA7 11 040-0 2

#1 n

86

112

111

94

83

92

113

111

91

86

ft:RlQ3325

8270 WATER SAMPLES

INCLUDES SURROGATE RECOVERIES

\Q3326

Client: WESTON LABORATORIES OSA 6584 WATERRADIAN INTERNAL 06A 6585 WATERRADIAN INTERNAL 07A SYSTEM BLANK

EPA METHOD 8270 Page 2CAS # COMPOUND RESULTS IN ug/LLab No: A7-11-038

OSA 06A 07A208-96-8 Acenaphthalene <10 <10 <1083-32-9 Acenaphthene <10 <10 <1098-86-2 Acetophenone <10 <10 <1053-96-3 2-Acetylaminofluorene <250 <250 <25092-67-1 4-Aoinobiphenyl <250 <250 <25062-53-3 Aniline <20 <20 <20•120-12-7 Anthracene <io <io <10140-57-8 Aramite N\A N\A N\A56-55-3 Benz(a)anthracene <10 <10 <10108-98-5 Benzenethiol N\A N\A N\A92-87-5 Benzidine <50 <50 <5050-32-8 Benzo(a)pyrene <10 <10 <10205-99-2 Benzo(b)fluoranthene <io <10 <10 ,191-24-2 Benzo(g,h,i)perylene <10 <10 <1065-85-0 Benzole acid <loo <100 <100207-08-9 Benzo(k)fluoranthene <io <10 <10106-51-4 p-Benzoquinone N\A N\A N\Aioo-si-6 Benzyl alcohol <20 <20 <20lll-91-i bis(2-Chloroethoxy)ethane <10 <10 <10111-44-4 bis(2-Chloroethyl)ether <10 <10 <10108-60-1 bis(2-chloroispropyl)ether <10 <10 <10117-81-7 bis(2-ethylhexyl)phthalate <10 <10 <10101-55-3 4-Bromophenyl phenyl ether <10 <10 <1085-68-7 butyl benzyl phthalate <10 <10 <1088-85-7 2-sec-butyl-4,6-dinitrophenol N\A N\A N\A106-48-7 p-Chloroanillne <200 <200 <200510-15-6 Chlorobenzilate N\A N\A N\A110-75-8 2-Chloroethyl vinyl ether N\A N\A N\A59-50-7 p-Chloro-m-cre»ol <10 <10 <1091-58-7 2-Chloronaphthalene <10 <10 <io95-57-8 2-chlorophenol <10 <10 <107005-72-3 4-Chlorophenyl phenyl ether <10 <10 <10218-01-9 Chrysene <10 <10 <1095-48-7 o-Creaol <10 <10 <10106-44-5 p-Cresol <10 <10 <10192-65-4 Dibenzo(a,e)pyrene N\A N\A N\A132-64-9 Dibenzofuran <10 <10 <1053-70-3 Dibenzo(a,h)anthracene <10 <10 <10189-64-0 Dibenzo(a,h)pyrene <10 <10 <10189-55-9 Dibenzo(a,i)pyrene N\A N\A N\A

ftB!03327

Client: WESTON LABORATORIES OSA 6584 WATERRADIAN INTERNAL 06A 6585 WATERRADIAN INTERNAL 07A SYSTEM BLANK

EPA METHOD 8270CAS * COMPOUND RESULTS IN ug/L

Lab No: A7-11-038OSA 06A 07A

95-50-1 1,2-Dichlorobenzene <10 <10 <10541-73-1 1,3-Dichlorobenzene <10 <10 <10106-46-7 1,4-Dichlorobenzene <10 <10 <1091-94-1 3,3'-Dichlorobenzidine <20 <20 <20120-83-2 2,4-Dichlorophenol <10 <10 <1087-65-0 2,6-Dichlorophenol <10 <10 <1084-66-2 Diethylphthalate <10 <10 <1060-11-7 p-Dimethylaminoazobenzene <250 <250 <250119-90-4 3,3'-Dimethoxybenzidine <50 <50 <5057-97-6 7,12-Dimethylbenz(a)anthracene <20 <20 <20119-93-7 3,3'-Dimethylbenzidine <50 <50 <50122-09-8 2,2-Dimethylphenethylamine <250 <250 <250105-67-9 2,4-Dimethylphenol <10 <10 <10131-11-3 Dimethylphthalate <10 <10 <10100-25-4 1,4-Dinitrobenzene <100 <100 <100584-52-1 4,6-Dinitro-o-cresol <50 <50 <5051-28-5 2,4-Dinitrophenol <50 <50 <50121-14-2 2,4-Dinitrotoluene <10 <10 <10806-20-2 2,6-Dinitrotoluene <10 <10 <1084-74-2 Di-n-butylphthalate <10 <10 <10117-84-0 Di-n-octylphthalate <10 <10 <10621-64-7 Di-n-propylnitrosamine <10 <10 <10122-39-4 Diphenylamine <10 <10 <10122-66-7 1,2-Diphenylhydrazine <10 <10 <10206-44-0 Fluoranthene <10 <10 <1086-73-7 Fluorene <10 <10 <10118-74-1 Hexachlorobenzene <10 <10 <1087-68-3 Hexachlorobutadiene <10 <10 <1077-47-4 Hexachlorocyclopentadiene <10 <10 <1067-72-1 Hexachloroethane <10 <10 <1070-30-4 Hexachlorophene N\A N\A N\A1888-71-7 Hexachloropropene <10 <lo <10193-39-5 Indeno(l,2,3-c,d)pyrene <10 <10 <1078-59-1 Isophorone <10 <10 <10120-58-1 Isosafrole <100 <100 <10091-80-5 Methapyrilene N\A N\A N\A56-49-5 3-Methylcholanthrene <100 <100 <100101-14-4 4,4Methylnbis(2-chloroanilne) <200 <200 <20066-27-3 Methyl methanesulfonate <20 <20 <2091-57-6 2-Methylnaphthalene <10 <10 <10

0332

2-Fluorobiphenyl2,4,6-Tribromophenol 77 " JJ 78Terphenyl-dl4 ZJ "J 97 "«

70 85 81 81

ZS AND DEFINITIONS FOR THIS REPORT.

2-Fluorobiphenyl 83 74 662,4,6-Tribromophenol 100 110 looTerphenyl-dl4 81 82 69

.ES AND DEFINITIONS FOR THIS REPORT.N\A -STANDARD WAS NOT AVAILABLE; THE COMPOUND WAS SEARCHEDUSING AN NBS LIBRARY OF 42,000 COMPOUNDS.

03330

CORPORATION

MS/MSD RESULTS

0333V

Client: WESTON LABORATORIES OSA 6581 SOILRADIAN INTERNAL 06A 6582 SOILRADIAN INTERNAL 07A 6583 SOIL

08A 6584 SOIL

EPA METHOD 8270 Page 2CAS # COMPOUND RESULTS IN ug/g

Lab No: A7-11-043OSA 06A 07A OSA

208-96-8 Acenaphthalene <1.0 <1.0 <1.0 <1.083-32-9 Acenaphthene <1.0 <1.0 <1.0 <1.098-86-2 Acetophenone <1.0 <1.0 <1.0 <1.053-96-3 2-Acetylaminofluorene <25 <25 <25 <2592-67-1 4-Aminobiphenyl <25 <25 <25 <2562-53-3 Aniline <2.0 <2.0 <2.0 <2.0120-12-7 Anthracene <1.0 <l.o <i.o <l.o140-57-8 Aramite N\A N\A N\A N\A56-55-3 Benz(a)anthracene <1.0 <1.0 1.4 <l.o108-98-5 Benzenethiol N\A N\A N\A N\A92-87-5 Benzidine <5.0 <5.0 <5.0 <5.050-32-8 Benzo(a)pyrene <l.O <l.O 3.1 <l.o205-99-2 Benzo(b)fluoranthene <1.0 <1.0 1.7 <1.0191-24-2 Benzo(g,h,i)perylene <1.0 <1.0 <1.0 <1.065-85-0 Benzoic acid <10 <10 <10 <10207-08-9 Benzo(k)fluoranthene <1.0 <1.0 2.2 <1.0106-51-4 p-Benzoquinone N\A N\A N\A N\A100-51-6 Benzyl alcohol <2.0 <2.0 <2.0 <2.0111-91-1 bis(2-Chloroethoxy)ethane <l.O <1.0 <1.0 <l.O111-44-4 bis(2-Chloroethyl)ether <1.0 <1.0 <1.0 <1.0108-60-1 bis(2-chloroispropyl)ether <1.0 <1.0 <1.0 <1.0117-81-7 bis(2-ethylhexyl)phthalate <l.O <1.0 <1.0 <l.O101-55-3 4-Bromophenyl phenyl ether <1.0 <1.0 <1.0 <1.085-68-7 butyl benzyl phthalate <1.0 <1.0 <1.0 <1.088-85-7 2-sec-butyl-4,6-dinitrophenol N\A N\A N\A N\A106-48-7 p-Chloroaniline <20 <20 <20 <20510-15-6 Chlorobenzilate N\A N\A N\A N\A110-75-8 2-Chloroethyl vinyl ether N\A N\A N\A N\A59-50-7 p-chloro-m-cre»ol <l.o <l.o <i.o <i.o91-58-7 2-Oil or ©naphthalene <1.0 <1.0 <1.0 <1.095-57-8 2-Chlorophenol <l.O <1.0 <l.O <l.O7005-72-3 4-Chlorophenyl phenyl ether <1.0 <1.0 <1.0 <l.o218-01-9 Chrysene <1.0 <1.0 1.3 <1.095-48-7 o-Cresol <1.0 <1.0 <1.0 <1.0106-44-5 p-Cresol <1.0 <1.0 <1.0 <1.0192-65-4 Dibenzo(a,e)pyrene <5.0 <5.0 <5.0 <5.0132-64-9 Dibenzofuran <1.0 <l.O <l.O <l.o53-70-3 Dibenzo(a,h)anthracene <1.0 <l.O <l.o <i.o189-64-0 Dibenzo(a,h)pyrene <1.0 <l.o <l.o <i.o189-55-9 Dibenzo(a,i)pyrene <5.0 <5.0 <5.0 <5.o

Client: WESTON LABORATORIES 09A 6585 SOILRADIAN INTERNAL 10A SYSTEM BLANKRADIAN INTERNAL

EPA METHOD 8270CAS # COMPOUND RESULTS IN ug/g

Lab No: A7-11-04309A 10A

95-50-1 1,2-Dichlorobenzene <1.0 <1.0541-73-1 1,3-Dichlorobenzene <1.0 <1.0106-46-7 1,4-Dichlorobenzene <1.0 <1.091-94-1 3,3'-Dichlorobenzidine <2.0 <2.0120-83-2 2,4-Dichlorophenol <l.o <l.o87-65-0 2,6-Dichlorophenol <1.0 <1.0.84-66-2 Diethylphthalate <1.0 <1.060-11-7 p-Dimethylaminoazobenzene <25 <25119-90-4 3,3'-Dimethoxybenzidine <5.0 <5.057-97-6 7,12-Dimethylbenz(a)anthracene <2.0 <2.0119-93-7 3,3'-Dimethylbenzidine <5.0 <5.0122-09-8 2,2-Dimethylphenethylamine <25 <25105-67-9 2,4-Dimethylphenol <1.0 <1.0131-11-3 Dimethylphthalate <l.O <1.0100-25-4 1,4-Dinitrobenzene <10 <10584-52-1 4,6-Dinitro-o-cresol <5.0 <5.051-28-5 2,4-Dinitrophenol <5.0 <5.0121-14-2 2,4-Dinitrotoluene <1.0 <1.0806-20-2 2,6-Dinitrotoluene <1.0 <1.084-74-2 Di-n-butylphthalate <1.0 <1.0117-84-0 Di-n-octylphthalate <1.0 <1.0621-64-7 Di-n-propylnitrosamine <1.0 <1.0122-39-4 Diphenylamine <1.0 <l.o122-66-7 1,2-Diphenylhydrazine <l.O <1.0206-44-0 Fluoranthene <1.0 <1.086-73-7 Fluorene <l.o <l.O118-74-1 Hexachlorobenzene <1.0 <1.087-68-3 Hexachlorobutadiene <1.0 <1.077-47-4 Hexachlorocyclopentadiene <l.O <1.067-72-1 Hexachloroethane <1.0 <1.070-30-4 Hexachlorophene N\A N\A1888-71-7 Hexachloropropene <1.0 <1.0193-39-5 Indeno(l,2,3-c,d)pyrene <1.0 <l.O78-59-1 Isophorone <1.0 <1.0120-58-1 Isosafrole <10 <1091-80-5 Methapyrilene N\A N\A56-49-5 3-Methylcholanthrene <10 <10101-14-4 4,4Methylnbis(2-chloroanilne) <20 <2066-27-3 Methyl methanesulfonate <2.0 <2.091-57-6 2-Methylnaphthalene <1.0 <1.0

Page 6

Aftl0333"3

,2-Fluorobiphenyl x 74 69 82 842,4,6-Tribromophenol 89 78 51 95Terphenyl-dl4 76 69 76 si

AND DEFINITIONS FOR THIS REPORT.N\A -STANDARD WAS NOT AVAILABLE; THE COMPOUND WAS SEARCHEDUSING AN NBS LIBRARY OF 42,000 COMPOUNDS.

RADIANCO* » O««TI«M

DUPLICATE MATRIX SPIKE DATA, SEMIVOLATILE ANALYSIS (%)

6572 SoilA711043-07

Compound #1 #2

Phenol 59 52

2-Chlorophenol 59 54

1,4-Dichlorobenzene 50 47

N-nitroso-di-n-propylamine 60 55

1,2,4-Trichlorobenzene 48 47

4-Chloro—3-methylphenol 62 57

Acenaphthene 46 44

4-Nitrophenol 50 48

2,4-Dinitrotoluene 44 41

Pentachlorophenol 56 54

Pyrene 83 54

RR10333S

tryy

V——•

I CDr ~- .*-»CD tu

CD

O t-2C O

oeno

>COQ t-Ul tJt-4 rf"

'U. f**. j£,

K- OOi yIUtu

SIBM»SjCDITS

CDCDe= a

•r-f *«•*-»-» rutn *—«

cr CQJ

coUI•of.tlJZu

Ood

u

aenui

UI

< H _ _ _ _ _ _ _ _ _ _ _ _CO

uvc.u

09

HO Z H>> Q Z W UI * UIK f- UJ Z Z H - - - -O K UJ < »-«Q. h-Ul 4

•— i

<cC_3

UuH— i|if>* (MUJ NOi ini— • «0oUJ__J (.^ *"£f^ 3

iIDin•0ot-04*

a

&03ino0t~94*

al

S00in43of-«4*

al

*CO<io(.•4>

a

OTGOinoot~914»

9

tort-04*

3J

OE(.tt4>

9

(vinOo4»C0gt45

W

Nm<oo4*C0e*4•oM

Nf)4O4»C0g4V

W

GOinSo*»cVe••oW

minSo4*C0E•*4T3

W

(MGOino4»CII€•»*•oW

(0COin04>Ca•H•o*H

GOin-oo*>c01€•«••^VN

nmin«oo4»C0g•>4•oft<A

i2.4JC<ug•HT30)UI

aenr•Pc0)€•HT>(HUI

CO

O

cc.

^,TiO» CD

«— • O

1 "TTp*sf y cssj

U-f~* C9 OW

c5 S• »••<W B --JV**t- c=o o

}«M

DC

&.£CU1 —

__

tft•*•»*"IXI

(= CU4 1Ml=3<C

1

eraoe

It0i-0

H0m

• 2°o jjiU fî

2"~ * *

19(U

OU Of

'B OU

: IF! *>SlTJl-olcCU***** cau 0€ t.no «'era 4*1c

W

W4*

«sf 1—Olc2

G*, —— 1 TScau •ro *era -Pc0

UI4»ni—olc3

O*•-HI TJcau 0€ t-«TJ 0era *»c0

»4»

ru -olc3

CU•— « tJcau 0S (•(Q 0era 4»c0

UI

sli3CU-H -0cau 0e»^^ era 4*c

0

W4>

Clal 2p-f*" 1 4*

3

era <«•UI 01 —— TI

ageruoo

ru0

„0

30C

O(Oo

0o0

cr>^

•" iUI E iIN. ''y' CMP> J 3

.

in4J

Oil--.,§CU!!•>••< * 3

cau 0«U 0era *•c0

'.n4?

CM-olc3

CDi— ~ "OCX0€ t.19 0(era -pc0

in4*

OOI-olc3

CUi i § 73»— » (u

fa 0era -pc0

UI4»

O!3

Of•— • -OOk 06 (-ro 0era 4*c0

UI

olc3

CU

cau 0*n 0era 4»c0

UI4»•*4cjiij jjcs

CI4,*-&•&UScra«jj1 —— XI

en en en 01 en en••-. v. s. s. s.

-. 51 ,3£*_3IO3 ârusoo SoO Of*** C*U . '*O "** »'''S - **** f"*-+ fX?

f " J V—H «

• S ««*H

*"") Z-I

*!71 CA Ol O1 CA *7IN. S, V. S. S. S.

.3 -3C\l3«f3 . 3 —• 3 OO COg J '•CJ * * V"4O *H ^ H'••s o o r . oo

^ JjrL< ^ - - _ - l

9>- t t- <- «. &.or->^-*>o*->cD>CD>aai> ao ao

O •— • O O O O O "*«•» ">>*u u u u u u f~^ QO0 0 0 0 0 0 » — 1 « — It- t- t- t. t- f- « <x

?C «*€ ?€ C C € »•••< *•• H

» - f. {. ^ ^c_~j 4U UT J d Q » | — ^ QI CJ Qi p 4_ fli p» f *o->o>ao>co>co>oo> ao ao

O •—• O O O O O <S«H ""û u u u u u t**** nf?00 0 0 0 0 w- » *— 1f- f- t- t- t. f- >«^.'*«K

v*H *— 4^ ^ ^ • ^ ^ ^ ^-« ^^

OP*- cu «— • n or* •— • r**» ?*•»»i < | M * ii gj i " i . s» ^ ^ r* *

C* P*»» OQ - _'--x» '-X '- 'vx* ' v ~*K CO

^ ^ COCD

a-*Ss~t0 0 0 04> 4» 4» 4»0 0 0 0f-4 > »4 >-•a. a. a. a.E E E E0 O • 0 0

~ Q "| U. u C^ u O u O u^ ttV 6 CS>, 6 Ul, g UJ, 6 UJ, E UJ, E 10 • JTJ 0 C3 0O 0

Is. IN, |x IN, |x IN. C3 4* O 4* n *» «O *»«a:3^3aa3cj»3tj3Cji3eaie^TieaTica-o

E:^ a:

""J"%Oi a*i :»•~~» a'••• • y~*1 <C

l*** .ryn tfssO

u_6D T3"O CUe- =>CD cr•YW -fr--?*(--• £H

a O.3C C->

1 —OSo_1 1 l .|_aOK W*

1 ——

M1•XI

•|MP-~«pl

at£Z? CU•»-< rx• juJ

M'=3y

iCf3<Cac:

r-s.CDa-"» ^»— im •

_ -• " ' •

CU

••— 1•XI flU01 cj•n aji-» r»*-

' 4Ji___, i~¥" ^ I*.

3CD. — 1 T>cau 0€ f-

icra *i Ci g

w

i ^'.n4*

«!»- •*i— « Ceu

*""•* "O| cau «no 0era -pc

UI42CO -•-* c

3CUca. a€ (-11 0era 4*c0

UI4?ru -*-• c

eup— « "Oex. 0€ f-TO 0era 4*c0

ÛI

, ^< C

3Of• — • -o

rn 0era 4»c0

y,49••4C

UJ 3[ j 49f n ^

3

era 5UJ 0J —— T,

•• ••

Xa tf en L,'* CT 'B ™ en f* ** ^C3r 3 »•"< 3 y u>f ^ OO 00

- Xt«x **<*CU f**» fjp

»— 1 »— 1**» >%s».»— 1 »— 1u 1 J '

en en enX X X

3$c en J' en ru en i%% * r ««O 3 . 3 «— « 3 OO OQO l-x. C3O

»* »"''X. ***.y J J^

.X X X

aflc cn<«*- oiCO cnr«» f «^yj 3 - 3 • i 3 OO ^Qur> « • "-H* f s* oof— « «-H* » " ^

»— 1 w— «

oi en oiX X X

3QC Ol 34$ OI PO 91 f*** r~ff m 3 t • k 3 3 i ah f~tf~k.^ w _^ ^ — — — M111 ^^-GO " Ô CTJ f** * nft

W—— « W—— 1

* * s<»•"•* y ^• VM«

OI OS OIX X X3*5 01 a$e oi*— • oir x r*ir»3uni3*-43ao ao•*«» - »

^ i ^ T* r*** op^ HH 7"i

04*0r- 1

aEou. w a.

UI E UJ E UJ /E 10 0 IT»

3 ?S 3 3 3 e 4S§aS

__ N X __ X v. X X XCj en i*a 01 C* oi r.*. V Q _i s$* en CO en C~TI enfT n 3 pi< g 5 %s|" 3 f*TQi '- v 3 f"*" i 3 3 ru 3«*• ^ . '- — «

ru'»w»—•

i/1oi oi en o< oi oi oiX X X X X X X

*43 3 >»JO 3 •—* 3 OO '••x' 3 pf?i 3 .3 CO 3Qi •»•ru i*•»>««. •ZÎ !

at 01 01 at oi oi oiX X X X X X X

36c oi »0e oi «O cnf**. lOi en aO* oi CO en Or*- en~ft 3 *4QI 3 "Hi 3 QQi x** 3 43 3 • 3 CO 3*--ii,__ LJ

r3**•»Zj

en oi oi oi oi en oiX X X X X X X

3$C Ot 99 Ot t P* Ol P ^ ** 3 Ok 3yC Ot C J OI *d ^ O)^*O 3 PTJ 3 »•""* 3 yT *xx 3 4" 3 - 3 J" 3

***te **•>*•?o — ••ru»%»v 4J-UL-g

oi 01 at 01 oi at atV V. S. *x. s \ x

m oi a#c cnCU O)f ^ «O 01 sfl* eiPT> oiun oiVy* 3 ITS 3 -— < 3 OO Vx* 3 **O 3 -3 C*_* 3

^ H V/0 — «df«— 41v— 41

01 04» 4»0 0~-l l-ta. a.e eo ou 3; u« S _J JU| E C2>, E OL. • UI, E CO.'E CS>, E UJ, E*_. rt K R\|x |x UI 4* |x |x |x |xJbrS: E -ss. "OL. ?au -o era 3 era 3 i — ?r-* 3

•

•

cx>COCOcoC3

-QC*«t

•

£-637

I >•.-« Qv—« »-yI <Cr s.00 €a4*: t-.

CD TCJ"«=> «DS- =>C3 cr

t- cro» «=»

a.UIae

UI

tfk=3

I

era<cae

o,

CU

CDor*

J - >••*-€

CU CU

UI 3C3 4»4

3

eraJ 0

E UJE

P-

r

«\

r

a

5

rr

5

936

f 3 3££

*

c

rrr-/•

-J•os5

IIo<uwi>fl^K.u^ieL i/ii,iiu* /'k i2 N;"> s 5z3 O

*

""' x •• ' f-v ;•? i>- K ~ K." ,*<;< ~-

4.-; 4.'

CO

$

c

?

\\\\

*»* -ITr

U"X- No.

f

A

> O 3J(/) Oj (T)|. So

^ff

I-8.

OCO

f

Oi-s as

B0

•D O 33 2?

|li£Si'SS

CA

9§

II

5

a § «H3i "M *Tafitltiljc^ vJQJ

cft4 j

•

IIO O

S

1_ *21

/;i.

I

iJ

fi

I

51

1--

c-f-^^c

v

ILLEGIBLE

i

ii

Ji

8

, i VA•* . . AR 103340A

• r • •

3 r*if

Xfc"

BRI033U45

ORIGINAL ILLEGIBLE

Hs3 O Q s2*5 if-ii"£ijatJS/'<!f I"fie.^$1

Custody Tra

m1

Ssi

*•

i

«T^^

•T">T

> e V<./1iTVV»IIIIT O <

9

jy

4,5-,

*

vn '.0

«t1^3

£/ 7

J

UU-1

i*t*

r

1

i

??AR 103342A

FIELD DATA SHEETEnvironmental RwponM Team, InvlTC*****.! Protection Agency

w. Edtea. K(201) 521-9660

.ocatton: ____

f.Electors:Lab Number (Cooeec.*'!) Dale Coilectad Time <_« rw)

NO 6572SON. VKOeTATION OROOMDWATEM

Device

>pllt Spoon:yUnder Cup

>eptrtFtorIn.

Soil TypeRec*

SandClaySiltMuckLoamPeat

Upland-DryLowtwtd-OryFtoodplataWetlandQuHy

Slop* >15*

OldWooded IndustrialFwmland Comnwrc

W«_f Tabto Depth

Shrub*

OBHColor..

Cotor .Odor .Oil: .Dtwica:.

SUMFACC WATIR PREPARATION

Twnp .•lor _ ——————— _ pH

• REAM Width

Depth

V-todty

Ft

FtorIn.

Ft/Sec

LOW DIRECTION.Pool*—— «• RifflM.

Device

SurberManualNetSemeTrewlBucket

SurfaceCteenOH

QarbegeTrMhBubbteaDeedFiart

ind.WeweFtoatSoHda

Bottom % ContainerOozeSandGravelClayRubbteRockShellOrganic

Qlaaa JarPtaatfcJv

AoetatiCorePaper CapTeflon CapFoilCao

Wet IceAmteentDry toe

Oeentng ProcedureLow »H>gf> ConcentretDetergent WaanWater RirweAcetone Rm«eHexane RineeOther Solvent RineeSpecify;

•WAMttCT INFORMATIONLetter Station f

^iCompee* Okvctton

___j

DH

to

«ane«i Between Stattom

le| ,

Ft

lemurk* and Stte DeecnpUoti

U. -AR 103342B

FIELD DATA SHEETEnvironmental Response Teem, Environmental Protection Agency

WoodbrWge Ave., Edison, N J. OM37(201) 321-4680

Location:

Collector*:LabNurnber (Coneec.t'8) Date Collected Time (24 hr)

NO 6578 ISOIL LAND VCQETATION GROUNDWATER

DeviceAugerCoraSplit SpoonCylinder CupSpadeDepth

Ft.orIn.

SoilTyp*RockGravelSandClaySiltMuckLoamPeat

Upland-DryLowtand-OryFtoodplalnWetlandGully

Slope >1S*OS*

Old Field ResidentialWooded IndustrialFarmland Commercial

Cotor.

Water Table Depth

Sample Depth Ft

DBH

Color .Odor.Oil:Device:

SURFACE WATtft SAMPLE PREPARATION

Color ._.. Temp.PH

oTREAM Width

Depth

Velocity

Ft

FtorIn.

Ft/Sec

Pools _____% Riffle*.

Device

PetanenSurberManualNet

TrowiBucket

FLOW DIRECTION W-t lc*

SurfaceCleenOil

GarbageTraahBubble*DeedFiahSewageInd.Waata

Bottom % ContainerOozeSandGravelClayRubbleRockShellOrganic

GlaaaJarPlastic JarMetalAcetate CorePaper CapTeflon CapFoil Cap

Float SoHda , Storage

AmbientDry Ice

Cleaning ProcedureLow—»Hign ConcentrationDetergent WMMWater RIHMAcetone RinseHexane RinseOtrter Solvent RinseSpecify:

TRANSECT INFORMATION___|Compaas Direction Distance Between StationsLetter Stations

Remarks and Site Deecripdon

AR 103342C

FIELD DATA SHEETEnvironmental Response Teem, Environmental Protection Agency

Woodbrtdge Ave., Edison, NJ. OM37(201) 321-6*60

Location:

Collectors:Lab Number (Conaec.fs) Date Collected________ Time (24 hr)

NO 6579SOIL VEGETATION QROUNOWATER

DeviceAugerCoreSplit SpoonCylinder CupSpadeDepth

Ft.orIn.

Soil TypeRockGravelSandClaySiltMuckLoamPeat

Upland-DryLowland-DryFloodpiamWetlandGully

Slope


Color.

Water Table Depth

Sample Depth Ft

DBH

Color .OdorOil:Device:

SURFACE WATER SAMPLE PREPARATION

Color. ___,—_____ Temp.Ddor. _________ pH

STREAM Width

Depth

Velocity

Ft.

FtorIn.

Ft/SecFLOW DIRECTION ,

Pools———————% Rifflee.

DeviceKemmererPetersenSurberManual

SemeTrowiBucket

Surface Bottom ContainerClean OozeOU Sand

Garbage GravelTrash ClayBubble* RubbleDeed Fish RockSewage Shell

Ind. Waste OrganicFloat Solida | Storage

Glass JarPlastic JarMetalAcetate CorePaper CapTeflon CapFoil Cap

Wet IceAmbientDry Ice

Cleenmg ProcedureConcen*

Detergent WashWater RinseAcetone RinseHexane RinseOther Solvent RinseSpecify:

tr»**1Bfe

TRANSECT INFORMATION | .Compass Direction Distance Between StationsLatter Station»

Remarks and Site Deecnption

AR 103342D

FIELD DATA SHEETEnvironmental Response Teem, Environment* Protection Agency

Woodbridge Ave. Edison, N J. 06837(201) 321-6660

Colloctorr ___ •ftft|Lab Number (Conaee.e's) Date Coliected Time (24 hr)

NO 6580SOIL LAND VEGETATION QROUNDWATER

DeviceAugerCoraSplit SpoonCylinder CupS partiDepth

Ft.orin.

Soil TypeRockGravelSandClaySiltMuckLoamPaat

Upland-DryLowland-DryFtoodplainWetlandGully

Slope >15*OS*


Color.

Water Tsbte Deotn

Sample Depth Ft.

DBH



Colon ' Temp ,pH

STREAM Width

Depth

Velocity

Ft.

FtorIn.

Ft/Sec

Pools ______% Riffle*.

DeviceKiPatarsenSurberManualNet

Trow*Bucket

FLOW DIRECTION *" IC*

SurfaceCleanOil

GarbageTrashBubblesDeadFiahSewage

ind. WasteFloat Solids

Bottom ContainerOozeSandGravelClayRubbleRockShellOrganic

Glass JarPlastic JarMetalAcetate CorePaper CapTeflon CapFoil CapStorage

AmbientDry Ice

Cleaning ProcedureLoo f High ConcentrationDetergent W««nWater RinseAcetone RinseHexsne RinseOther Solvent RinseSpecify

TRANSECT INFORMATION |Compass Direction Distance Between StationsLatter Station »

to Ft

Remarks and Site OeecnpMon

5W/fc

AR 103342E

FIELD DATA SHEET ., Reeponee Team, Environmental Protectton Agfency~Woodbridge Ave^ Edison, MJ. 06137 . . ,-_

.ocatton:

Collectors:Lab Number (Consec-S's) Date Collected Time (24 hr)

NO 6581 // _ /SOIL LAND VEGETATION GROUNOWATER


Ft.orIn.

Soil TypeHockGravelSandClaySiltMuckLoamPeat

Upland-DryLowland-DryFloodplainWetlandGully

Slope >ir

Old Field ReetdenualWooded IndustrialFarmland Commercial

Color.

Water Table Depth

Sample Depth Ft

DBH

Color ,OdorOil:Device:


Color ___________ Temp.'lor. ______________ pH

STREAM Width

Depth

Velocity

Ft

Ftorin.

FVSec

FLOW DIRECTION .Pools ______% Riffle*.

DeviceK em mererPetersenSurberManualNetSemeTrow!Bucket

SurfaceCleanOH

GarbageTrsehBubblesDeed FishSewage

Ind. WasteFloat. Soiida


Q lass JarPlastic JarMetalAcetate CoraPaper CapTeflon CapFoil CapStorageWet iceAmbientDry Ice

CVeening ProcedureLow—^High ConcentrationDetergent WasnWster RinseAcetone RinseHexane RinseOther Solvent RinseSpecify:

TRANSECT INFORMATION |Compass Direction Distance Between StationsLetter Station s

Ft

Remarks and Site Description

AR 103342F

^ Tessn, Emrtronmeo al ProtectionWoodbrtdge Ave., Edison, N J. 06837

(201) 321-6660

Location:

Collectcf* / ?JL

Lab Number (Conaac.*'s) Date Collected Time (24 hr)

NO 6582 / LS-0SOIL LAND VEGETATION OROUNOWATER


FtorIn.


Upland-DryLowland-DryFloodptatnWetlandGully

Slope >ir


HerbaceousShrubs ———,—— %Trees : .._«-

DBH

Water Table Depth

Sample Depth

Color.

ColorOdor.Oil:Device:


Color ______________ Temp,PH

STREAM Width

Depth

Velocity

Ft.

FtorIn.

Ft/Sec

Pools —————% Riffle*.

DeviceK em mererPetersenSurberManualNetSeineTrowtBucket

FLOW DIRECTION W* loa

SurfaceCleanOil

GarbageTrashBubble*DeadFiahSewage

Ind. WasteFloat Solida


Glass JarPlastic JarMetalAcetate CoraPaper CapTeflon CapFoil CapStorage

AmbientDry Ice

Cleaning ProcedureLow—»Hign ConcentrationDetergent WashWater RinseAcetone RinseHexane RinseOther Solvent RinseSpecify:

TRANSECT INFORMATION |Compass Direction Distance Between Stationslatter Station *

Ft

Remarks and Site Deecnption

103342G

Environmental Response Team, Environmental Protection AgeneyWoodbrtdge Ave., Edison, N J. 06637

(201) 321-6660

.ocatton:

Collectors:

UtU, C£ag«i,

Lab Number (Coneec.*'a) Date Collected Time (24 hr)

6583 | \/mf\srsou. VEGETATION GROUNOWATER

Device

DoraSplit SpoonCylinder CupSpadeDeptn

FtorIn.

SoU TypeRockGravelSandClaySiltMuckLoamPeat

Upland-DryLowtand-OryFtoodptatnWetlandGully

Slope >15B


Color.

Water Table Depth

Sample Depth

DBH

Color ,OdorOil:Device:


Color. ___________ Temp .or _________ pH ,

„ i REAM Width

Depth

Velocity

Ft

FtorIn.

Ft/Sec

FLOW DIRECTION .Pools______% Riffles.

DeviceKemmererPetersenSurberManualNetSeineTrow)Bucket

Surface Bottom ContainerClean Ooze Gleaa JarOil Sand Plastic Jar

Garbage Gravel MetalTrash Clay Acetate CoraBubblee Rubble Paper CapDeed Fish Rock Teflon CapSewage Shell Foil Cap

Ind. Waste Organic ,____Float. Solids •—St0f*g*Wet ice

AmbientDry Ice

Cleaning ProcedureLow—^High ConcentrationDetergent WssnWster RinseAcetone RinseHexane RinseOther Solvent RinseSpecify:

TRANSECT INFORMATION

Letter Stations Compaaa Direction Distance Between Stations

—— to is Ft

Remarks and Site Deaenption

AR 103342H

FIELD DATA SHEET- - • ., . . ... . .. . ......« -. •Environmental Response Team, Environmental Protection Agency

Woodbridge Ave., Edison, N J. 06637(201) 321-6660

Location:

Collectors:

""P

Lab Number (Conaec.*'s) Date Collectad Time (24 hr)

NO 6584 ff| ffl OSOIL LAND VEGETATION OROUNDWATER

DeviceAugerCoraSplit SpoonCylinder CupSpadiDepth

Ft.orIn.


Upland-DryLowland-DryFtoodptamWetlandGully

Slope >15*

Old Fieid ResidentialWooded industrialFarmland Commercial

HerbaceousShrubs ____.%Trees _______%

DBH

Water Table Depth

Sample Depth

Color.



Color: __________ Temp .JOJQC __

W- pH

STREAM Width

Depth

Velocity

Ft

FtorIn.

Ft/Sec

FLOW DIRECTION .Pools——————% Riffles.

DeviceKemmerarPetersenSurberManualNetSeineTrowlBucket

SurfaceCleanOil

GarbageTrashBubbte*Deed FishSewage

I nd. Waste


Glass JarPlastic JarMetalAcetate CoraPaper CapTeflon CapFoil Cap

Float Solids i StorageWet iceAmbientDry Ice

Cleaning ProcedureLow—»Htgn ConcentrationDetergent WashWster RinseAcetone RinseHexane RinseOther Solvent RinseSpecify

TRANSECT INFORMATIONLetter Station* Compass Direction Distance Between Stations

to Ft

Remarks and Site Deecnptton

Sire* 7

AR 1033421

Environmental Response Teem, Environmental Protection AgencyWoodbridge Ave., Edison, N J. 06637

(201) 321-6660

Location:

Collectors:Lab Number <Conaec.ra) Date Collected Time (24 hr)

NO 6585 /5V #&$&- / oSOIL LAND VEGETATION QROUNOWATER


Ft.orIn.


Upland-DryLowland-DryFlood plainWetlandGully

Slope >1S"OS-

Old Field ResidentialWooded industrialFarmland Commercial

Color.

Water Table Depth

Sample Depth Ft

DBH

Color .Odor .Oil:Device:.


Color ——_——____ Tamp ,

oTREAM Width

Depth

Velocity

Ft

FtorIn.

Ft/Sec

FLOW DIRECTION .Pools______% Riffle*.

DeviceKemmererPetersenSurberManualNet

Trow!Bucket

SurfaceCleanOil

GarbageTrashBubble*DeadFlahSewageInd.Wi


Glass JarPlastic JarMetalAcetate CoraPaper CapTeflon CapFoil Cap

Float Solids •—StOT19*iceAmbientDry Ice

Cleaning ProcedureLow »Htgn ConcentrationDetergent WasnWater Rins-Aceton* RinseHexane RinseOther Solvent RinseSpecify

TRANSECT INFORMATION

Lener Stations compass Direction Dis

to

itance Between Stattor

is

IS

Ft

Remarks and Site Deacnptton

1Q3342J

i -I , ..'i I I I ^! : S

Vt\i 'si M 's ?j1-1 *l: I i'M^

a r "ft „ i*, - TJ|-",25 i,tD^ |J«i

*><a•:r'; M ^* r -"' ° v» * «^ tliwv« r* k -* A=..

i ^ ^ mmmAR 103342K

si« ! j ^ ..-i^ 4i^.iV

.5hV3>: N I <4 1 l *. u_ [5_ 4: . s, f"«! - JT ,1 - ^ 41^1 n-- •-3 *4*. * ^ ,1M i * ^ -4j . — • • r v ^ I > . A C

^

v>*y

<^i--. «'!• H '-* r- 72 tv* :^v *« i" JH1 ^ "

plfJi !»• ~ J ^' >^ *- ^ 7 1/v *~43 "* * ^ ' o - * v B v * - » 7

\{i M;'?^M4 T -lf' 1IN * *" "^ 1^^ ^ ,S - > 3 1 v* •*! ^- >/" ) L_£4^ * ~" u_ £3 •>. . j ^ t\ s" o > strr

AR 103342L

1U„ «5 x0 < N

'-1

.• <>r**S f^ i

r**7<o r?^ < :^ " ?.u c2

APPENDIX C

Photodocumentation

eh/DONEGAN/fInal-report

AR 103342P

AR 103342Q

APPENDIX D

Maps, Site Sketches

eh/DONEGAN/fi nal-report

AR 103342R

EPA/REACRoy F. Weston, Inc.

EPA CONTRACT 68-03-3482

Not to Scale

Approximate Location of Sanpling Sites

Millcreek Site, Millcreek Township, Pennsylvania

AR 103342S

J 135' £30jf-A2.s.i • •»• t1-3 ow' y

AR 103342T

APPENDIX E

Site Health and Safety Plan

eh/DONEGAN/final-report

AR 103342U

WESTON REACHAZARDOUS UASTE SITE INVESTIGATION AND RESPONSE

HfAlTH AND SAFETY PLAN

EPA Assignor: * *- ' -- -- A___ Work Assignment No.Date of Field Activity: °^ 3-U____ Prepared by: HOriginal Safety Plan: Yes >£_ No __ Modification No.

Site Name: (*4»~cc*£€"*• , Lee.*

Site Address: Street No.CltV /*Ml_._.C.j*,tfeV£ >&UA/fH>rW e »J ^ ^ BIH H B BHlBWIBHBiM ^ ^ MM ^ iBMi i B ^ ^ ^ HB

CountyState ffcvA/.ycv/A/iA_____ z^p code

Site Contact: _____________________ Phone ______Directions to Site:£~&

Map Attached: Yes >__ No _Site H1 storv;

Hi*

INCIDENT DESCRIPTION

TYPE: A) Spill __ Air Release __ F1re __ HW Site _i) AsstssMnt __ SamollnQXl Emergency Response

Clean-up/Re«oval __ Other (specify) ______C Urbtn/Rt$1dtnt1tl _ Comntrdal __ Industrial __

Rural __ Rt«ott __PHYSICAL DESCRIPTION

: CA\Size of SUi:.^^^ Terrain: f. / .Y Weather:± w^ — 4 ' ZZf

rd/H&S-FOR«

AR 103342V

Involved In the Release or Incident

Drums ^ No. __ Tanks _____ No. __

Truck ____ License No. ____ Tanker ______ Box

Railroad Car ' Tank No. _______ Box No. _Spill ____ Source ____________ Approximate VolumeOtherANTICIPATED ACTIVITIES

„ ——

l+t. /cr--, J

EXPOSURE HAZARDS

Inhalation X Skin Contact X Ingestlon __ Radioactive __Biological __ Fire ___ Explosion __ Unknown __PHYSICAL HAZARDS

Heat __ Cold X Noise __ Underground Utilities __

Overhead Utilities __ Heavy Equipment __ Sharp Objects __

Pressurized Air __ Cylinders __ Ladders __ Scaffolds __

Unguarded OpenIngs-Wall, Floor __ Liquids 1n Open Containers, Ponds,

Lagoons __SPECIAL HAZARDS_________________________________________

~»/*u

ANTICIPATED LEVEL OF PROTECTION (Circle Ont): A

WHY:

rd/HiS-FORHxv V<. 0<\ \V\\A x^ Q^VS.M. ,

AR 103342W

PHYSICAL HAZARDS OF CONCERN

Hazard Description Location Applicable Precautions

><

.

; ft _ ,'< rt.//,.fre .

-f-Lt,

H - o _ v

rd/H4S-FORM

AR 103342X

HHEMICAL CONTAMINANTS OF CONCERN

TLV I.O.L.H. Source/Quantity Route of Symptoms of Used to^onitContaminant (PPM) (PPM) Characteristics Exposure Acute Exposure Contaminant

"

Ni -A'i

rd/HiS-FORM

AR 103342Y

Was Entry Madt: Yes __L No —

iHL.£ NO ___

A B (C j D Why:

SCBA __ APR *^ Model __ Cart./Can. Type __ Tyvek _

Poly Tyvek __ Saran Tyvek *^ Add Suit __ Rain Gear __

Cotton Coveralls __Gloves: Inner ___^T~Butyl __ N1tr1le *^~ V1ton __ Other

Foot Gear: Safety Shoes __ Outer Boots _f___| Booties __ Other

Descrlotion of Decontamination Used:_______ __________v. (It)

AIR MONITORING Performed by:

Instrument Reading*; CGI/02 Rad Meter OVA QHNOs^ Other

Background ___

Site Location: /font Tr+^J-o&A-A __ Q' / ty*- .Site Location: / 7<*-»X B MJL -ff" f&fsh __ O'/ M*~Site Location: ______________ __ __Site Location: _____________ __ __Wind: Speed __ Direction __ Temp. __ Rel. Hum. __ B.P.Summarize A1r-Monitoring Data ______________________

rd/H&S-FORMAR 103342Z

SAMPLIN6 ~ ~ Performed by: £•&•«>*'— /P-

Sampling Plan (Y or N) ./—No. of Samples: Solid V Liquid _____ Gas __ Other ____

Laboratory: _________.———————————————————————————

Has Lab Been Notified of Potential Hazard Level? Yes __ No __~Analyses: ____________________________________Sampling Comments:

DOCUMENTATION Performed by: <?• &-J*——/f- » ./C. Z-,jLc#r-

Type: Photo * Log Book * Recorder __ Video __PUBLIC IMPACT

Distance to Nearest: Residence ____ School ____ Hospital ____Public Building ____ Other

*/Evacuation: Yes __ No * Nuaber __ By Whom:!

ENVIRONMENTAL IMPACT:

Nearest Waterway: />Vs>Ul-. fl*W Distance:

Condition ' Observed Potential None

Surface Water ContaminationGround Water ContaminationDrinking Water ContaminationA1r ContaminationSoil CoatMlnttlonStressW Veg«tat1onPERSONNgL (Name and Phone, On or Off -Site)S1t§ Manager:S1tt Safety Coordinator:Other REAC Field Personnel:

rd/HiS-FORMAR 103342AA

fflfRSENCY INFORMATION

Emergency Phone Numbers:

Location Phone Notified (Y/N) ContactF1rt -

Pol 1 ceAmbulanceHospital 7-3.- u. zf st (ft*)

Nearest Phone ___________DIRECTIONS TO HOSPITAL: <5o *•*-£ 6cX /I. •* £6* -A.

(AHACH MAP)

>-

ADDITIONAL EMERGENCY PHONE CONTACTS:

CHEMTREC (800) 424-9300TSCA HOTLINE (202) 554-1404RCRA HOTLINE (800) 424-9346CDC (404) 452-4100 (Day), (404) 329-2888 (Night)BUREAU OF ALCOHOL, TOBACCO & FIREARMS (800) 424-9555, (202) 566-7777NATIONAL RESPONSE CENTER (800) 424-8802WESTON MEDICAL EMERGENCY SERVICE (513) 421-3063PESTICIDE INFORMATION SERVICE (800) 424-9346BUREAU OF EXPLOSIVES, A.A. RAILWAYS (202) 835-9500WESTON REAC OFFICE (201) 906-0734 OR 9Ub-U847

Larry White, Weston Program Manager (301) 992-8880 (H)Rich Habrukowlch, Operations Manager (215) 275-1895 (H)Cralg Moylan, Health & Safety Manager (215) 524-1160 (H)

rd/HiS-FORM

AR 103342BB

I have rtad, understood, and agreed with the Information set forth in thisHealth and Safety Plan and will adhere to the protocols specified herein.

USite Manager Slyrtftye ^ Date.

< WSite Safety Coordinator Signature Dateo* w*——caField Team Member Signature. ,, Date

Field Team Member Signature DateP-J&- L,)frS\SL.ay4* - jj/i ______________________

Field Team Member./ Signature " D a t e

HEALTH & SAFETY PLAN APPROVAL

REAC HEALTH/SAFETY MANAGERSignature^ v"——' Date

rd/HiS-FORM

AR 103342CC

fj

LAKE* ERIE'APPROX MEAN LAKE EL.,7 57] <j

•;• =________ „ ,_ _ _. K^ — _1 •

BASS MAP IS A PORTION OF THE U.S.3.S. SWANVILLC, M QUAOTMiSLE (7.5 MMUTE SERB. *57, PHOTDREVI9ED !9€>Va

AR 103342DD

LOCATION MAPMILLCREEK SITE, MILLCREEK TWP.t ________

SCALE: l"« 2000' ~ —i CORPORAnON2_2 ^J A HaHtburton Company

CVICVJUJcr3.o

UJ

fe

UI

UJ' UJ

UJQ

UJ

V.3CUJUJ

2-3

AR 103342EE

APPENDIX F

Sampling Plan

eh/DONEGAN/flnal-report

103342FF

SAMPLING PLAN FOR MILLCREEK SITE

Sediment samples will be collected from Marshal Is Run and a wetland basinIn the south central portion of the site. Specific sampling equipment andmethodology'employed will be determined onsite following Initialreconnaissance. Variables such as substrate characteristics and depth ofwater will be noted and evaluated with respect to the applicability ofequipment and techniques available. Ekman and ponar dredges will beonsite and utilized if sediments are soft enough to permit efficientoperation. This will most likely be the case in Marshalls Run. Localtopography and site description indicate that flow In this waterbody issluggish and the reach under consideration depositional in nature.Sediments are most likely fine grained.

r

At least a portion of the wetland basin was a forested upland prior to thedischarge of fill north of this area. The substrate most likely containsremnants of the previous vegetative cover, as well as upland soils.Typically, wetlands are depositional environments with soft substrates,however, sufficient time may not have elapsed since the formation of thishydrosystem to allow a significant deposit of fine grained material toaccumulate. As a result, operation of an Ekman or ponar dredge may not bepossible. If this is the case, a hand bucket auger will be employed tocollect sediments.

Water samples will also be collected from Marshalls Run and the wetlandbasin. Marshalls Run will be sampled by utilizing a composite samplingprocedure. A number of subsamples will be collected at various pointsacross a representative cross section of this waterbody. The transitrate, or number of discrete samples collected, will be determined by themixing characteristics of the stream. Depending on the depth of thiswaterbody and other hydrologic characteristic, a kemmerer bottle, depthIntegrating sampler, or hand held sample bottle will be employed tocollect the sample. A similar compositing procedure will be employed ateach sampling point 1n the wetland basin, however, the subsamples will becollected across a vertical rather than horizontal transect.

The selection of sampling locations will be determined following initialsite reconnaissance. A combination of biased and random samples will becollected in this study. Biased locations are those areas where there ishigh likelyhood of encountering positive evidence of contamination.Obvious contaminant plumes as Indicated by staining, discoloration, and/oroil slicks vlll be sampled. In addition to biased samples, random sampleswill be collected. The selection of these locations will be based on astatistically va]_1d protocol such as a grid sampling scheme.Approximately 12 sediment and six water samples will be collected forchemical analysis. All samples will be analyzed for total recoverablepetroleum hydrocarbons, volatile organlcs, base, neutral and acidextractable organlcs, PCBs, and priority pollutant metals. Additionally,analysis of sediments will Include total organic carbon and grain sizeanalysis. All sampling and analytical procedures will follow EPAguidelines.

rd/COMBS/SP-MILLCR

103342GG

THALLIUM DATA · 2020. 12. 11. · -3.2-2.6 s7z.dev.-1 o 1 € height (absorbance' apea...

Documents

Transcript of THALLIUM DATA · 2020. 12. 11. · -3.2-2.6 s7z.dev.-1 o 1 € height (absorbance' apea...