Test - 5 (Code-C) (Answers) All India Aakash Test Series for JEE … · 2020. 2. 3. · All India...

20
Test - 5 (Code-C) (Answers) All India Aakash Test Series for JEE (Main)-2021 All India Aakash Test Series for JEE (Main)-2021 Test Date : 02/02/2020 ANSWERS Aakash Educational Services Limited - Regd. Office : Aakash Tower, 8, Pusa Road, New Delhi-110005 Ph.011-47623456 TEST-5 - Code-C 1/10 PHYSICS CHEMISTRY MATHEMATICS 1. (3) 2. (1) 3. (2) 4. (3) 5. (3) 6. (4) 7. (2) 8. (1) 9. (2) 10. (1) 11. (2) 12. (4) 13. (1) 14. (4) 15. (4) 16. (3) 17. (3) 18. (1) 19. (4) 20. (2) 21. (24) 22. (04) 23. (25) 24. (31) 25. (07) 26. (2) 27. (1) 28. (2) 29. (3) 30. (3) 31. (4) 32. (3) 33. (2) 34. (2) 35. (1) 36. (3) 37. (2) 38. (3) 39. (3) 40. (1) 41. (2) 42. (4) 43. (1) 44. (3) 45. (1) 46. (02) 47. (06) 48. (06) 49. (60) 50. (56) 51. (3) 52. (3) 53. (3) 54. (3) 55. (2) 56. (4) 57. (4) 58. (1) 59. (2) 60. (1) 61. (3) 62. (3) 63. (4) 64. (2) 65. (1) 66. (3) 67. (4) 68. (4) 69. (3) 70. (3) 71. (65) 72. (09) 73. (61) 74. (10) 75. (36)

Transcript of Test - 5 (Code-C) (Answers) All India Aakash Test Series for JEE … · 2020. 2. 3. · All India...

  • Test - 5 (Code-C) (Answers) All India Aakash Test Series for JEE (Main)-2021

    All India Aakash Test Series for JEE (Main)-2021

    Test Date : 02/02/2020

    ANSWERS

    Aakash Educational Services Limited - Regd. Office : Aakash Tower, 8, Pusa Road, New Delhi-110005 Ph.011-47623456

    TEST-5 - Code-C

    1/10

    PHYSICS CHEMISTRY MATHEMATICS

    1. (3)

    2. (1)

    3. (2)

    4. (3)

    5. (3)

    6. (4)

    7. (2)

    8. (1)

    9. (2)

    10. (1)

    11. (2)

    12. (4)

    13. (1)

    14. (4)

    15. (4)

    16. (3)

    17. (3)

    18. (1)

    19. (4)

    20. (2)

    21. (24)

    22. (04)

    23. (25)

    24. (31)

    25. (07)

    26. (2)

    27. (1)

    28. (2)

    29. (3)

    30. (3)

    31. (4)

    32. (3)

    33. (2)

    34. (2)

    35. (1)

    36. (3)

    37. (2)

    38. (3)

    39. (3)

    40. (1)

    41. (2)

    42. (4)

    43. (1)

    44. (3)

    45. (1)

    46. (02)

    47. (06)

    48. (06)

    49. (60)

    50. (56)

    51. (3)

    52. (3)

    53. (3)

    54. (3)

    55. (2)

    56. (4)

    57. (4)

    58. (1)

    59. (2)

    60. (1)

    61. (3)

    62. (3)

    63. (4)

    64. (2)

    65. (1)

    66. (3)

    67. (4)

    68. (4)

    69. (3)

    70. (3)

    71. (65)

    72. (09)

    73. (61)

    74. (10)

    75. (36)

  • All India Aakash Test Series for JEE (Main)-2021 Test - 5 (Code-C) (Hints & Solutions)

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    HINTS & SOLUTIONS

    PART - A (PHYSICS)

    1. Answer (3)

    Hint: Let R = thermal resistance of each rod

    of y

    then 2R = thermal resistance of each rod of x.

    Sol.:

    1 16A BT T T RI = − =

    2 14B ET T T RI = − =

    1 12

    3 3100 60 C

    2 5

    TT

    T

    = = =

    2 40 = T C

    60 60 20 C= − = − = B A B B CT T T T T

    TC = 40°C

    2. Answer (1)

    Hint: 140 z = 100°C

    Sol.: 14 7

    1 C10 5

    z = =

    1 1 14200

    4200 J kg J kg7

    5

    ws k

    z

    − − −= =

    = 3000 J kg–1 z–1

    3. Answer (2)

    Hint: 2

    12

    mlI =

    Sol.: 2

    2I l

    TI l

    = =

    4. Answer (3)

    Hint: V = VT

    Sol.: 1 dV

    V dT =

    3nRT

    PV nRT KV

    = =

    ln( ) 3 ln ln ln+ = +nR T K V

    3 1 dV

    T V dT= =

    5. Answer (3)

    Hint: W = Area under P-V graph

    Sol.: In general W may be positive or

    negative.

    6. Answer (4)

    Hint: dT dt

    H KA aATdx dx

    = − = −

    Sol.: 0

    0

    2 20 0

    4 0

    16

    2

    T l

    T

    T THdx HlTdT

    aA aA

    − −= − =

    2

    015

    2

    TaAH

    l=

    2 2 2

    0 016 15

    2 2 2

    T T TaA l

    l aA

    − −=

    2

    2 2 00

    1516

    2

    TT T= −

    2

    017

    2

    T=

    017

    2T T=

    7. Answer (2)

    Hint: PV = RT

    Sol.: 22 2

    Constant ConstantP

    PVP V

    = =

    3

    2 2 1 2

    R R RC = − =

    02

    RQ C T T = =

    8. Answer (1)

    Hint: dQ = nCdT

    Sol.: dQ = nCvdT + PdV

    PdV = nTdT

    nRT

    dV n TdTV

    =

  • Test - 5 (Code-C) (Hints & Solutions) All India Aakash Test Series for JEE (Main)-2021

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    dV dT

    V R

    =

    ln lnT

    k VR

    + =

    =

    T

    RkV e

    Constant

    =

    T

    RVe

    9. Answer (2)

    Hint: 4 4[ ]sP A T T= −

    Sol.: P = 5 × 10–4 × 6.0 × 10–8 [6004 – 3004]

    = 3 × 10–11 × 108 [1296 – 81] = 3 × 10–3 ×

    1215 W

    = 3.645 W

    10. Answer (1)

    Hint: dQ = nCdT

    Sol.: nCdT = nCvdT + nVdT

    PdV = nVdT

    nRT

    PV nRT PV

    = =

    dV

    nRT n VdTV

    =

    2

    =

    dT RdV

    T V

    1

    ln( )

    = −

    kT RV

    R

    VkT e−

    =

    constant =

    R

    VTe

    11. Answer (2)

    Hint: U = nCvT

    Sol.: 15

    2i

    RU n T=

    1 2 25 3

    ( ) 2 2 22 2

    = − + fR R

    U n n T n T

    1 2 2( )5 6n n RT n RT= − +

    1 12 2

    5 5

    2 2

    = − = + = +

    f i

    n RT nU U U n RT n RT

    12. Answer (4)

    Hint: The decrease in the KE due to ordered

    motion is equal to increase in internal

    energy.

    Sol.: 2

    2 21 1

    2 2 4

    = − =

    VU nm V nmV

    1

    v

    RnC T n T= =

    2( 1)

    4

    − =

    mVT

    R

    13. Answer (1)

    Hint: p = nRT

    Sol.: 1 1 1 2

    2 2 1 2

    p n m M

    p n M m= =

    2 1 2

    1 2 1

    4 2

    3 3

    M M

    M M

    = =

    1

    2

    1

    2

    M

    M=

    14. Answer (4)

    Hint: TV = constant PV2 = constant

    Sol.: 22 2

    k kP

    v m = =

    15. Answer (4)

    Hint: SlopeP

    V

    = −

    Sol.:

    12 22 1

    2

    f

    f

    f f f

    + + = = = +

    16. Answer (3)

    Hint: dp = –gdh

    Sol.: nRT mRT RT

    PV MV M

    = = =

    RdT dT Mg

    gdhM dh R

    −= − =

    dT Mg

    dh R=

  • All India Aakash Test Series for JEE (Main)-2021 Test - 5 (Code-C) (Hints & Solutions)

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    17. Answer (3)

    Hint: A = A0[1 + T]

    Sol.: 3 5[1 ] 1 12 2

    = + + = +

    A lb T T lb T

    5

    2 =

    18. Answer (1)

    Hint: =

    FLY

    A L

    Sol.: L F F

    T Y TL A T AY

    = = =

    19. Answer (4)

    Hint: extracted

    Wn

    Q=

    Sol.: 0 02W PV=

    0 0 0 033

    2 2AB

    P V P Vn RQ

    nR= =

    0 0 0 045

    102

    BC

    P Vn RQ P V

    nR= =

    0 0

    0 0

    2 42 100%

    23 23

    P Vn

    P V= =

    20. Answer (2)

    Hint: 2Q

    W =

    Sol.: 2 2

    1 2 1 2

    279 93

    24 8

    Q T

    Q Q T T = = = =

    − −

    = 11.6

    21. Answer (24)

    Hint: 21

    0.6 1002

    m

    Sol.: 20.6

    1002

    ms T m =

    0.3 104

    24 C125

    T

    = =

    22. Answer (04)

    Hint: isothermal isothermalQ W =

    Sol.: ln = CBCB

    VQ nRT

    V

    23. Answer (25)

    Hint: Maximum temperature is attained in

    process AB

    Sol.: 0

    0

    = − +P

    P V CV

    00 0 00

    4 5= − + =P

    P V C C PV

    0 00

    5P

    P V PV

    = − +

    20 00

    5P

    PV RT V P V RTV

    = − + =

    0 000

    2 55 0

    2

    P VV P V

    V− + = =

    2

    0 0 0 0max

    0

    25 251

    4 2

    = − +

    P V P VT

    R V

    0 025

    4

    P V

    R=

    24. Answer (31)

    Hint: Q = nCPT

    Sol.: 5

    1252

    RT=

    125 2

    3 6 K5 25

    = =

    T

    25. Answer (07)

    Hint: 5

    2

    RU n T =

    Sol.: 7

    2

    RQ n T =

    W = nRT

  • Test - 5 (Code-C) (Hints & Solutions) All India Aakash Test Series for JEE (Main)-2021

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    PART - B (CHEMISTRY)

    26. Answer (2)

    Hint :

    possible tautomers

    Sol. : A is poly hydroxy aromatic compound.

    B is poly keto non-aromatic compound

    27. Answer (1)

    Hint :

    Sol. : Acidic strength order is Hb > Ha > Hc

    28. Answer (2)

    Hint :

    According to lowest sum rule correct path

    of numbering is given above

    Sol. : Correct IUPAC name is

    4-Amino-4-hydroxy oct-2-en-5-yne-1,

    8-dioic acid.

    29. Answer (3)

    Hint : To show geometrical isomerism molecule

    must have a group which can be oriented

    in different spatial arrangements.

    Sol. :

    Two geometrical isomers

    30. Answer (3)

    Hint : Alcohols and ethers are functional

    isomers

    Sol. :

    and CH3CH2 – O – CH3

    are the two compounds which have same

    molecular formula with different functional

    groups.

    31. Answer (4)

    Hint & Sol. :

    1, 2 and 3 are conjugated system.

    32. Answer (3)

    Hint : Energy of structure I and V and II and IV

    are same

    Sol. : III is least stable

    33. Answer (2)

    Hint : Lesser is the double bond character

    lower would be the energy required for

    rotation.

    Sol. : Both ring becomes aromatic after

    dissociation of -bond hence have least

    double bond order.

    34. Answer (2)

    Hint : Greater the electron density on nitrogen

    greater will be the basic strength

  • All India Aakash Test Series for JEE (Main)-2021 Test - 5 (Code-C) (Hints & Solutions)

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    Sol. :

    Lone pair of nitrogen is in conjugation

    with benzene rings

    35. Answer (1)

    Hint & Sol. :

    Hyperconjugation participate with in

    toluene and increases the resonance

    energy.

    36. Answer (3)

    Hint : Greater the stability of conjugate base

    lesser will be strength of conjugate base

    Sol. :

    Most stable conjugate base due to

    identical resonating structure.

    37. Answer (2)

    Hint : The species which have complete octet

    cannot act as an electrophile.

    Sol. : NH3 has lone pair of electron.

    38. Answer (3)

    Hint : Negative charge on more electronegative

    atom is more stable.

    Sol. :

    Negative charge on N is more stable than

    at carbon.

    39. Answer (3)

    Hint :

    Sol. : Lesser the charge density on cation

    greater will be the stability.

    40. Answer (1)

    Hint : Dipole moment is a vector quantity and to

    calculate the net dipole moment, vector

    sum formula can be used.

    Sol. : Dipole moment would be maximum when

    the angle between the two vectors is

    180°.

    41. Answer (2)

    Hint & Sol. :

    2 46Fe CN [Fe(CN) ]

    + − −+ ⎯⎯→

    Some of the Fe2+ is converted into Fe3+

    when heated with conc. H2SO4

    3 4

    6 4 6 3Prussian blue

    Fe [Fe(CN) ] Fe [Fe(CN) ]+ −+ ⎯⎯→

    42. Answer (4)

    Hint & Sol. :

    S2– + Pb2+ ⎯⎯→ PbS black ppt.

    43. Answer (1)

    Hint : Equivalent of BaSO4 = Equivalents of S

    in organic compound

    Sol. : 0.9625 g of BaSO4 contains

    = 32 0.9625

    g233

    of sulphur

    % of sulphur = 32 0.9625 100

    233 0.314

    42%

    44. Answer (3)

    Hint : In compound P the degree of

    unsaturation is 2 where as in Q is 4.

    Sol. : Both have 4 primary carbon atoms.

    45. Answer (1)

    Hint : Consider the involvement of lone pair in

    resonance.

    Sol. :

  • Test - 5 (Code-C) (Hints & Solutions) All India Aakash Test Series for JEE (Main)-2021

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    46. Answer (02)

    Hint : To show geometrical isomerism along a

    C=C, both C-atom should posses

    different groups

    Sol. :

    47. Answer (06)

    Hint : Except 3-chlorocyclopropene all have

    DBE 3.

    Sol. : DBE = 2.

    48. Answer (06)

    Hint : Check all the possibilities

    Sol. :

    49. Answer (60)

    Hint : Let the given compound is CxHy

    x y 2 2 2

    4.4g2g

    C H O CO H O+ ⎯⎯→ +

    Sol. : 4.4 g of CO2 1.2 g of C

    Composition of C = 1.2

    1002

    = 60%

    50. Answer (56)

    Hint : Equivalents of H2SO4 acid = eq. of NH3 +

    eq. of NaOH

    Sol. : 100 × 0.25 × 2 = eq. of NH3 + 60 × 0.5

    eq. of NH3 = 20 m eq. = 20 m moles

    % of N = 314 20 10 100

    56%0.5

    − =

    PART - C (MATHEMATICS)

    51. Answer (3)

    Hint: Use chain rule.

    Sol.: y = f(x3)

    3 2( ) 3= dy

    f x xdx

    6 2 13 6 3 9 3 9== + = =xx x

    52. Answer (3)

    Hint: Use binomial theorem.

    Sol.: 5

    01 5

    5(1 )5 ... 5 4

    += + + +

    CxC C

    x x

    5

    41 2 5

    (1 ) 15 5 ... 5

    + = + + + +

    C C C

    5(1 ) 1+ −

    53. Answer (3)

    Hint: Make truth table.

    Sol.:

    54. Answer (3)

    Hint: Express equation as factors.

    Sol.: P i(2i) = –2

    z4 + 5z3 + 18z2 – 4z2 + 5 = (z – z1)

    (z – z2) (z – z3) (z – z4)

    16 – 40 + 72 – 16 + 5 = (–2 – z1)

    (–2 – z2) (–2 – z3) (–2 – z4)

    37 = ((PA) (PC))2

  • All India Aakash Test Series for JEE (Main)-2021 Test - 5 (Code-C) (Hints & Solutions)

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    55. Answer (2)

    Hint: G.P of infinite series.

    Sol.: 1

    11 2 1

    12 12

    =

    = = −

    rr

    56. Answer (4)

    Hint: Section formula.

    Sol.:

    9 10 4

    6 3 41 3

    += = − = −

    +

    4(1) 1( 3)

    133 131 1

    3

    z− + −

    −= = =

    −−

    57. Answer (4)

    Hint: Rationalise.

    Sol.:

    2 2

    2 21

    (2 3 4) ( 6 2)lim

    ( 1)( 2 3 4 6 2)→

    + + − + +

    − + + + + +x

    x x x x

    x x x x x

    1

    ( 2)( 1) 1lim

    ( 1)(3 3) 6x

    x x

    x→

    − −= −

    − +

    58. Answer (1)

    Hint: Locus.

    Sol.: |z1| = |z2| = |z1 – z2|

    2 21 2 1 2z z z z+ =

    1 2

    2 1

    1z z

    z z+ =

    59. Answer (2)

    Hint: Condition of line intersection.

    Sol.: z lies on line or segment joining z1 & z2

    and also on line or segment joining 1z

    and z2. Hence only 1 possible solution.

    60. Answer (1)

    Hint: Chain rule.

    Sol.: f(x) = f(2 – x)

    f (x) = –f (2 – x)

    f (x) + f (2 – x) = 0

    Put x = 3 f (3) + f (–1) = 0

    61. Answer (3)

    Hint: Negation of statement.

    Sol.: ~( (~ )) ~(~ )→ = q q p q q p

    ( ~ ) ~q q p q p= =

    62. Answer (3)

    Hint: Truth table.

    Sol.:

    63. Answer (4)

    Hint: 1 form.

    Sol.:

    1 1 1 1

    2 3 5 7 4lim 2

    4→

    + + + −

    x x x x

    xx

    e

    ( ) ( ) ( ) ( )1 1 1 12 1 3 1 5 1 7 1lim

    12

    − + − + − + −

    x x x x

    x

    xe

    1ln(2 3 5 7)

    2 210e

    =

    64. Answer (2)

    Hint: Create Indeterminacy.

    Sol.: 2 2 ( ) (1 )

    lim 31x

    x ax b a x b

    x→

    − + + + −=

    a = 1 and b – a = 3 b = 2

  • Test - 5 (Code-C) (Hints & Solutions) All India Aakash Test Series for JEE (Main)-2021

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    65. Answer (1)

    Hint: Locus is a straight line.

    Sol.: 1

    | 1|2021

    z z− = −

    Locus

    11

    101120212 2021

    x+

    = = =

    66. Answer (3)

    Hint: Section formula.

    Sol.: Let B divides AC in ratio : 1, then for

    y-coordinates

    ( 2) 1(4)

    21

    − +=

    +

    –2 + 4 = 2 + 2

    1

    4 22

    = =

    5(1) ( )

    61

    a+ =

    +

    5 9 82

    aa+ = =

    67. Answer (4)

    Hint: Locus based.

    Sol.: 21

    (3 ) (4 )2

    + − −k i i

    21

    1 22

    i − +

    5 5

    ,2 2

    k

    68. Answer (4)

    Hint: 1 2 1 2 1 22 2 2 2 2 21 1 1 2 2 2

    cosa a b b c c

    a b c a b c

    + + =

    + + + +

    Sol.: For perpendicular lines

    2( 6) 5( ) 6( 1) 0 − + + − =

    3 26 11 6 0 1, 2, 3 − + − = =

    69. Answer (3)

    Hint: Put z = x + iy

    Sol.: 2 2 2 4x iy x y i+ − + = − −

    24 and 16 2y x x= + − + = −

    2 24 4 16x x x+ + = +

    x = 3

    14

    3 4 Arg( ) tan3

    z i z −

    = + =

    70. Answer (3)

    Hint: Check L.H.L. and R.H.L.

    Sol.: R.H.L. = e–1 and L.H.L. = 1

    Limit does not exist

    71. Answer (65)

    Hint: | x | < a –a < x < a

    Sol.: | | 13 2z −

    2 | | 13 2z− −

    11 | | 15z

    72. Answer (09)

    Hint: 0

    form0

    Sol.:

    23

    3

    2

    3

    2 3

    1 1tan

    3 7

    1

    1lim

    7 81

    →−

    + + − = =

    + +

    x

    xxx x

    xL

    xx x

    22

    1

    L=

    73. Answer (61)

    Hint: u

    v rule of differentiation

  • All India Aakash Test Series for JEE (Main)-2021 Test - 5 (Code-C) (Hints & Solutions)

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    Sol.: 22

    ( )( 1) (3 1)

    xf x

    x x= −

    + −

    2

    2 2

    2 (3 2 )( )

    ( 1) (3 1)

    x xf x

    x x

    − − = −

    + −

    2 8 50 72 122

    (2)9 25 225 225

    f− − −

    = − − = =

    74. Answer (10)

    Hint: Locus based

    Sol.: |z – 4| = |z – 8| x = 6

    and 3|z – 12| = 5|z – 8i|

    9(x2 + y2 – 24x + 144) = 25(x2 + y2 – 16y

    + 64)

    y = 8, 17

    | z |min = 10

    75. Answer (36)

    Hint: V = abc

    Sol.: a = 3 b = 6 c = 2

    V = abc = 3 6 2 = 36

  • Test - 5 (Code-D) (Answers) All India Aakash Test Series for JEE (Main)-2021

    All India Aakash Test Series for JEE (Main)-2021

    Test Date : 02/02/2020

    ANSWERS

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    TEST-5 - Code-D

    1/10

    PHYSICS CHEMISTRY MATHEMATICS

    1. (2)

    2. (4)

    3. (1)

    4. (3)

    5. (3)

    6. (4)

    7. (4)

    8. (1)

    9. (4)

    10. (2)

    11. (1)

    12. (2)

    13. (1)

    14. (2)

    15. (4)

    16. (3)

    17. (3)

    18. (2)

    19. (1)

    20. (3)

    21. (07)

    22. (31)

    23. (25)

    24. (04)

    25. (24)

    26. (1)

    27. (3)

    28. (1)

    29. (4)

    30. (2)

    31. (1)

    32. (3)

    33. (3)

    34. (2)

    35. (3)

    36. (1)

    37. (2)

    38. (2)

    39. (3)

    40. (4)

    41. (3)

    42. (3)

    43. (2)

    44. (1)

    45. (2)

    46. (56)

    47. (60)

    48. (06)

    49. (06)

    50. (02)

    51. (3)

    52. (3)

    53. (4)

    54. (4)

    55. (3)

    56. (1)

    57. (2)

    58. (4)

    59. (3)

    60. (3)

    61. (1)

    62. (2)

    63. (1)

    64. (4)

    65. (4)

    66. (2)

    67. (3)

    68. (3)

    69. (3)

    70. (3)

    71. (36)

    72. (10)

    73. (61)

    74. (09)

    75. (65)

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    HINTS & SOLUTIONS

    PART - A (PHYSICS)

    1. Answer (2)

    Hint: 2Q

    W =

    Sol.: 2 2

    1 2 1 2

    279 93

    24 8

    Q T

    Q Q T T = = = =

    − −

    = 11.6

    2. Answer (4)

    Hint: extracted

    Wn

    Q=

    Sol.: 0 02W PV=

    0 0 0 033

    2 2AB

    P V P Vn RQ

    nR= =

    0 0 0 045

    102

    BC

    P Vn RQ P V

    nR= =

    0 0

    0 0

    2 42 100%

    23 23

    P Vn

    P V= =

    3. Answer (1)

    Hint: =

    FLY

    A L

    Sol.: L F F

    T Y TL A T AY

    = = =

    4. Answer (3)

    Hint: A = A0[1 + T]

    Sol.: 3 5[1 ] 1 12 2

    = + + = +

    A lb T T lb T

    5

    2 =

    5. Answer (3)

    Hint: dp = –gdh

    Sol.: nRT mRT RT

    PV MV M

    = = =

    RdT dT Mg

    gdhM dh R

    −= − =

    dT Mg

    dh R=

    6. Answer (4)

    Hint: SlopeP

    V

    = −

    Sol.:

    12 22 1

    2

    f

    f

    f f f

    + + = = = +

    7. Answer (4)

    Hint: TV = constant PV2 = constant

    Sol.: 2

    2 2

    k kP

    v m = =

    8. Answer (1)

    Hint: p = nRT

    Sol.: 1 1 1 2

    2 2 1 2

    p n m M

    p n M m= =

    2 1 2

    1 2 1

    4 2

    3 3

    M M

    M M

    = =

    1

    2

    1

    2

    M

    M=

    9. Answer (4)

    Hint: The decrease in the KE due to ordered

    motion is equal to increase in internal

    energy.

    Sol.: 2

    2 21 1

    2 2 4

    = − =

    VU nm V nmV

    1

    v

    RnC T n T= =

    2( 1)

    4

    − =

    mVT

    R

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    10. Answer (2)

    Hint: U = nCvT

    Sol.: 15

    2i

    RU n T=

    1 2 25 3

    ( ) 2 2 22 2

    = − + fR R

    U n n T n T

    1 2 2( )5 6n n RT n RT= − +

    1 12 2

    5 5

    2 2

    = − = + = +

    f i

    n RT nU U U n RT n RT

    11. Answer (1)

    Hint: dQ = nCdT

    Sol.: nCdT = nCvdT + nVdT

    PdV = nVdT

    nRT

    PV nRT PV

    = =

    dV

    nRT n VdTV

    =

    2

    =

    dT RdV

    T V

    1

    ln( )

    = −

    kT RV

    R

    VkT e−

    =

    constant =

    R

    VTe

    12. Answer (2)

    Hint: 4 4[ ]sP A T T= −

    Sol.: P = 5 × 10–4 × 6.0 × 10–8 [6004 – 3004]

    = 3 × 10–11 × 108 [1296 – 81] = 3 × 10–3 ×

    1215 W

    = 3.645 W

    13. Answer (1)

    Hint: dQ = nCdT

    Sol.: dQ = nCvdT + PdV

    PdV = nTdT

    nRT

    dV n TdTV

    =

    dV dT

    V R

    =

    ln lnT

    k VR

    + =

    =

    T

    RkV e

    Constant

    =

    T

    RVe

    14. Answer (2)

    Hint: PV = RT

    Sol.: 22 2

    Constant ConstantP

    PVP V

    = =

    3

    2 2 1 2

    R R RC = − =

    02

    RQ C T T = =

    15. Answer (4)

    Hint: dT dt

    H KA aATdx dx

    = − = −

    Sol.: 0

    0

    2 20 0

    4 0

    16

    2

    T l

    T

    T THdx HlTdT

    aA aA

    − −= − =

    2

    015

    2

    TaAH

    l=

    2 2 2

    0 016 15

    2 2 2

    T T TaA l

    l aA

    − −=

    2

    2 2 00

    1516

    2

    TT T= −

    2

    017

    2

    T=

    017

    2T T=

    16. Answer (3)

    Hint: W = Area under P-V graph

    Sol.: In general W may be positive or

    negative.

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    17. Answer (3)

    Hint: V = VT

    Sol.: 1 dV

    V dT =

    3nRT

    PV nRT KV

    = =

    ln( ) 3 ln ln ln+ = +nR T K V

    3 1 dV

    T V dT= =

    18. Answer (2)

    Hint: 2

    12

    mlI =

    Sol.: 2

    2I l

    TI l

    = =

    19. Answer (1)

    Hint: 140 z = 100°C

    Sol.: 14 7

    1 C10 5

    z = =

    1 1 14200

    4200 J kg J kg7

    5

    ws k

    z

    − − −= =

    = 3000 J kg–1 z–1

    20. Answer (3)

    Hint: Let R = thermal resistance of each rod

    of y

    then 2R = thermal resistance of each rod of x.

    Sol.:

    1 16A BT T T RI = − =

    2 14B ET T T RI = − =

    1 12

    3 3100 60 C

    2 5

    TT

    T

    = = =

    2 40 = T C

    60 60 20 C= − = − = B A B B CT T T T T

    TC = 40°C

    21. Answer (07)

    Hint: 5

    2

    RU n T =

    Sol.: 7

    2

    RQ n T =

    W = nRT

    22. Answer (31)

    Hint: Q = nCPT

    Sol.: 5

    1252

    RT=

    125 2

    3 6 K5 25

    = =

    T

    23. Answer (25)

    Hint: Maximum temperature is attained in

    process AB

    Sol.: 0

    0

    = − +P

    P V CV

    00 0 00

    4 5= − + =P

    P V C C PV

    0 00

    5P

    P V PV

    = − +

    20

    00

    5P

    PV RT V P V RTV

    = − + =

    0 000

    2 55 0

    2

    P VV P V

    V− + = =

    2

    0 0 0 0max

    0

    25 251

    4 2

    = − +

    P V P VT

    R V

    0 025

    4

    P V

    R=

    24. Answer (04)

    Hint: isothermal isothermalQ W =

    Sol.: ln = CBCB

    VQ nRT

    V

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    25. Answer (24)

    Hint: 21

    0.6 1002

    m

    Sol.: 20.6

    1002

    ms T m =

    0.3 104

    24 C125

    T

    = =

    PART - B (CHEMISTRY)

    26. Answer (1)

    Hint : Consider the involvement of lone pair in

    resonance.

    Sol. :

    27. Answer (3)

    Hint : In compound P the degree of

    unsaturation is 2 where as in Q is 4.

    Sol. : Both have 4 primary carbon atoms.

    28. Answer (1)

    Hint : Equivalent of BaSO4 = Equivalents of S

    in organic compound

    Sol. : 0.9625 g of BaSO4 contains

    = 32 0.9625

    g233

    of sulphur

    % of sulphur = 32 0.9625 100

    233 0.314

    42%

    29. Answer (4)

    Hint & Sol. :

    S2– + Pb2+ ⎯⎯→ PbS black ppt.

    30. Answer (2)

    Hint & Sol. :

    2 46Fe CN [Fe(CN) ]

    + − −+ ⎯⎯→

    Some of the Fe2+ is converted into Fe3+

    when heated with conc. H2SO4

    3 4

    6 4 6 3Prussian blue

    Fe [Fe(CN) ] Fe [Fe(CN) ]+ −+ ⎯⎯→

    31. Answer (1)

    Hint : Dipole moment is a vector quantity and to

    calculate the net dipole moment, vector

    sum formula can be used.

    Sol. : Dipole moment would be maximum when

    the angle between the two vectors is

    180°.

    32. Answer (3)

    Hint :

    Sol. : Lesser the charge density on cation

    greater will be the stability.

    33. Answer (3)

    Hint : Negative charge on more electronegative

    atom is more stable.

    Sol. :

    Negative charge on N is more stable than

    at carbon.

    34. Answer (2)

    Hint : The species which have complete octet

    cannot act as an electrophile.

    Sol. : NH3 has lone pair of electron.

    35. Answer (3)

    Hint : Greater the stability of conjugate base

    lesser will be strength of conjugate base

    Sol. :

    Most stable conjugate base due to

    identical resonating structure.

    36. Answer (1)

    Hint & Sol. :

    Hyperconjugation participate with in

    toluene and increases the resonance

    energy.

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    37. Answer (2)

    Hint : Greater the electron density on

    nitrogen greater will be the basic

    strength

    Sol. :

    Lone pair of nitrogen is in conjugation

    with benzene rings

    38. Answer (2)

    Hint : Lesser is the double bond character

    lower would be the energy required

    for rotation.

    Sol. : Both ring becomes aromatic after

    dissociation of -bond hence have

    least double bond order.

    39. Answer (3)

    Hint : Energy of structure I and V and II and

    IV are same

    Sol. : III is least stable

    40. Answer (4)

    Hint & Sol. :

    1, 2 and 3 are conjugated system.

    41. Answer (3)

    Hint : Alcohols and ethers are functional

    isomers

    Sol. :

    and CH3CH2 – O – CH3

    are the two compounds which have

    same molecular formula with different

    functional groups.

    42. Answer (3)

    Hint : To show geometrical isomerism molecule

    must have a group which can be oriented

    in different spatial arrangements.

    Sol. :

    Two geometrical isomers

    43. Answer (2)

    Hint :

    According to lowest sum rule correct path

    of numbering is given above

    Sol. : Correct IUPAC name is

    4-Amino-4-hydroxy oct-2-en-5-yne-1,

    8-dioic acid.

    44. Answer (1)

    Hint :

    Sol. : Acidic strength order is Hb > Ha > Hc

    45. Answer (2)

    Hint :

    possible tautomers

    Sol. : A is poly hydroxy aromatic compound.

    B is poly keto non-aromatic compound

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    46. Answer (56)

    Hint : Equivalents of H2SO4 acid = eq. of NH3 +

    eq. of NaOH

    Sol. : 100 × 0.25 × 2 = eq. of NH3 + 60 × 0.5

    eq. of NH3 = 20 m eq. = 20 m moles

    % of N = 314 20 10 100

    56%0.5

    − =

    47. Answer (60)

    Hint : Let the given compound is CxHy

    x y 2 2 2

    4.4g2g

    C H O CO H O+ ⎯⎯→ +

    Sol. : 4.4 g of CO2 1.2 g of C

    Composition of C = 1.2

    1002

    = 60%

    48. Answer (06)

    Hint : Check all the possibilities

    Sol. :

    49. Answer (06)

    Hint : Except 3-chlorocyclopropene all have

    DBE 3.

    Sol. : DBE = 2.

    50. Answer (02)

    Hint : To show geometrical isomerism along a

    C=C, both C-atom should posses

    different groups

    Sol. :

    PART - C (MATHEMATICS)

    51. Answer (3)

    Hint: Check L.H.L. and R.H.L.

    Sol.: R.H.L. = e–1 and L.H.L. = 1

    Limit does not exist

    52. Answer (3)

    Hint: Put z = x + iy

    Sol.: 2 2 2 4x iy x y i+ − + = − −

    24 and 16 2y x x= + − + = −

    2 24 4 16x x x+ + = +

    x = 3

    14

    3 4 Arg( ) tan3

    z i z −

    = + =

    53. Answer (4)

    Hint: 1 2 1 2 1 22 2 2 2 2 21 1 1 2 2 2

    cosa a b b c c

    a b c a b c

    + + =

    + + + +

    Sol.: For perpendicular lines

    2( 6) 5( ) 6( 1) 0 − + + − =

    3 26 11 6 0 1, 2, 3 − + − = =

    54. Answer (4)

    Hint: Locus based.

    Sol.: 21

    (3 ) (4 )2

    + − −k i i

    21

    1 22

    i − +

    5 5

    ,2 2

    k

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    55. Answer (3)

    Hint: Section formula.

    Sol.: Let B divides AC in ratio : 1, then for

    y-coordinates

    ( 2) 1(4)

    21

    − +=

    +

    –2 + 4 = 2 + 2

    1

    4 22

    = =

    5(1) ( )

    61

    a+ =

    +

    5 9 82

    aa+ = =

    56. Answer (1)

    Hint: Locus is a straight line.

    Sol.: 1

    | 1|2021

    z z− = −

    Locus

    11

    101120212 2021

    x+

    = = =

    57. Answer (2)

    Hint: Create Indeterminacy.

    Sol.: 2 2 ( ) (1 )

    lim 31x

    x ax b a x b

    x→

    − + + + −=

    a = 1 and b – a = 3 b = 2

    58. Answer (4)

    Hint: 1 form.

    Sol.:

    1 1 1 1

    2 3 5 7 4lim 2

    4→

    + + + −

    x x x x

    xx

    e

    ( ) ( ) ( ) ( )1 1 1 12 1 3 1 5 1 7 1lim

    12

    − + − + − + −

    x x x x

    x

    xe

    1ln(2 3 5 7)

    2 210e

    =

    59. Answer (3)

    Hint: Truth table.

    Sol.:

    60. Answer (3)

    Hint: Negation of statement.

    Sol.: ~( (~ )) ~(~ )→ = q q p q q p

    ( ~ ) ~q q p q p= =

    61. Answer (1)

    Hint: Chain rule.

    Sol.: f(x) = f(2 – x)

    f (x) = –f (2 – x)

    f (x) + f (2 – x) = 0

    Put x = 3 f (3) + f (–1) = 0

    62. Answer (2)

    Hint: Condition of line intersection.

    Sol.: z lies on line or segment joining z1 & z2

    and also on line or segment joining 1z

    and z2. Hence only 1 possible solution.

    63. Answer (1)

    Hint: Locus.

    Sol.: |z1| = |z2| = |z1 – z2|

    2 21 2 1 2z z z z+ =

    1 2

    2 1

    1z z

    z z+ =

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    64. Answer (4)

    Hint: Rationalise.

    Sol.:

    2 2

    2 21

    (2 3 4) ( 6 2)lim

    ( 1)( 2 3 4 6 2)→

    + + − + +

    − + + + + +x

    x x x x

    x x x x x

    1

    ( 2)( 1) 1lim

    ( 1)(3 3) 6x

    x x

    x→

    − −= −

    − +

    65. Answer (4)

    Hint: Section formula.

    Sol.:

    9 10 4

    6 3 41 3

    += = − = −

    +

    4(1) 1( 3)

    133 131 1

    3

    z− + −

    −= = =

    −−

    66. Answer (2)

    Hint: G.P of infinite series.

    Sol.: 1

    11 2 1

    12 12

    =

    = = −

    rr

    67. Answer (3)

    Hint: Express equation as factors.

    Sol.: P i(2i) = –2

    z4 + 5z3 + 18z2 – 4z2 + 5 = (z – z1)

    (z – z2) (z – z3) (z – z4)

    16 – 40 + 72 – 16 + 5 = (–2 – z1)

    (–2 – z2) (–2 – z3) (–2 – z4)

    37 = ((PA) (PC))2

    68. Answer (3)

    Hint: Make truth table.

    Sol.:

    69. Answer (3)

    Hint: Use binomial theorem.

    Sol.: 5

    01 5

    5(1 )5 ... 5 4

    += + + +

    CxC C

    x x

    5

    41 2 5

    (1 ) 15 5 ... 5

    + = + + + +

    C C C

    5(1 ) 1+ −

    70. Answer (3)

    Hint: Use chain rule.

    Sol.: y = f(x3)

    3 2( ) 3= dy

    f x xdx

    6 2 13 6 3 9 3 9== + = =xx x

    71. Answer (36)

    Hint: V = abc

    Sol.: a = 3 b = 6 c = 2

    V = abc = 3 6 2 = 36

    72. Answer (10)

    Hint: Locus based

    Sol.: |z – 4| = |z – 8| x = 6

    and 3|z – 12| = 5|z – 8i|

    9(x2 + y2 – 24x + 144) = 25(x2 + y2 – 16y

    + 64)

    y = 8, 17

    | z |min = 10

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    73. Answer (61)

    Hint: u

    v rule of differentiation

    Sol.: 22

    ( )( 1) (3 1)

    xf x

    x x= −

    + −

    2

    2 2

    2 (3 2 )( )

    ( 1) (3 1)

    x xf x

    x x

    − − = −

    + −

    2 8 50 72 122

    (2)9 25 225 225

    f− − −

    = − − = =

    74. Answer (09)

    Hint: 0

    form0

    Sol.:

    23

    3

    2

    3

    2 3

    1 1tan

    3 7

    1

    1lim

    7 81

    →−

    + + − = =

    + +

    x

    xxx x

    xL

    xx x

    22

    1

    L=

    75. Answer (65)

    Hint: | x | < a –a < x < a

    Sol.: | | 13 2z −

    2 | | 13 2z− −

    11 | | 15z

    AIATS_JEE(M)2021_Test-5_(Code-C)_02-02-2020_SolAIATS_JEE(M)2021_Test-5_(Code-D)_02-02-2020_Sol