Søren Flensborg Iversen -...

FEEDING THE WORLD REDUCING OUR DEPENDENCE

ON FOSSIL FUELS

KEEPING PEOPLE AND

THE ENVIRONMENT SAFE

1 © E.I. du Pont de Nemours and Company

Søren Flensborg Iversen Salgs – og Udviklingsansvarlig

DuPont Performance Polymers

En ny æra af plastmaterialer

DuPont Segments,

Businesses and Core Markets

12/3/2014 DuPont Today 2014

DuPont Industrial Biosciences

Core Markets: Industrial Enzymes | BioBased Materials

DuPont Performance Chemicals Titanium Technologies | Chemicals &

Fluoroproducts

Core Markets: Industrials & Chemicals | Construction |

Specialties | Plastics | Transportation

DuPont Agriculture DuPont Pioneer | Crop Protection

Core Markets: Seeds | Agricultural Chemicals

DuPont Safety & Protection Protection Technologies | Building

Innovations | Sustainable Solutions

Core Markets: Industrial | Construction | Military & Law

Enforcement | Transportation | Consumer

DuPont Performance Materials Performance Polymers | Packaging &

Industrial Polymers

Core Markets: Transportation | Industrial | Packaging |

Electrical/Electronics

DuPont Nutrition & Health

Core Markets: Food & Nutrition Products

DuPont Electronics &

Communications

Core Markets: Photovoltaics | Consumer Electronics |

Advanced Printing | Displays

2

DuPont Strategy

Building three world-leading, closely related strategic ‘pillars’:

Driving three critical cross-company ‘enablers’ to maximize results:

innovation, geographic expansion, productivity

Ag & Nutrition Seeds

Traits

Crop Protection

Specialty Food Ingredients

Bio-based Industrials

Biofuels

Biomaterials

Biochemicals

Enzymes

Advanced Materials

Electronic Materials

Protective Solutions

Alternative Energy

Advanced Polymers

Advanced Processes

Use LCA techniques along the product development stages

© E.I. du Pont de Nemours and Company 5

Vision of the development of sustainable solutions

Low footprint Processing

Eco-Design Inclusive

Sustainability Renewable Materials

Enhance customers’ product performance,

improve sustainability and reduce total downstream system cost

•Develop, manufacture and sell Performance Polymers derived from renewable resources

•Value Proposition: - Performance equal or better than fossil incumbent

- Significant footprint improvement

- 20% up to 100% by weight renewable content

- Cost / performance ratio

DuPont Renewably-Sourced Performance Polymers

DuPont™ Performance Polymers Worldwide

• Products

– Zytel® Nylon and Zytel® HTN

– Zytel® RS Renewably Sourced Polyamides

– Delrin® Acetal

– Vespel® Polyimide

– Tynex® Filaments

– Rynite® PET

– Crastin® PBT

– Sorona ® EP Renewably Sourced

– Hytrel® TPC-ET

– Hytrel ® RS Renewably Sourced

High

Performance

Engineering

Polymers

Engineering

Polymers

Standard

polymers

AMORPHOUS SEMI-CRYSTALLINE

PES

PEI

PSU

PAR

PEK

PC

MPPO

SMA ABS PMMA

PS SAN PVC

PP LDPE

HDPE

PPS

PI

PET PBT

PA POM

TPC-ET

HTN Zytel®

RS HTN

Sorona® EP

Zytel® RS

Hytrel® RS

DuPont

Renewably Sourced™

LCP

PA66+

Inclusive Sustainability © E.I. du Pont de Nemours and Company

Properties similar to PBT

37% renewably-sourced Sorona® provides freedom from petroleum dependency - PDO component is Bio- PDO, derived from corn.

Bio-PDO Requires 40% less energy than petrochemical based PDO

HOC

CC

OH C

O

OHC

HO

O+ 1,3-Propanediol

(PDO)

Terephthalic Acid

Polytrimethylene terephthalate

OC

CC

O

O

C

O

CO

CC

C

O

OC

O

DuPont™ Sorona® polymer

© E.I. du Pont de Nemours and Company

PTT polyester similar to PBT in performance and price.

• Better surface appearance, UV resistance.

• Stronger and stiffer than PBT.

• Lower shrink vs PBT, less warpage.

• Improved hydrolysis resistance and laser weldability. Slightly

better electrical properties

DuPont™ Sorona® polymer

2012-08-02 © E.I. du Pont de Nemours and Company 10

Description/Application

Air conditioning register blade

End-user

Toyota Motors

Benefit gained from this development

Cost reduction by eliminating painting process compared with glass reinforced PBT, former material

Design freedom because of higher mechanical property than glass reinforced PBT

Material chosen and Why

Sorona® 2045G, 45% glass filled grade was chosen because of its excellent combination of good appearance and mechanical property. It is also bio-based material.

Sorona® 2045G GF45%-PBT

Tensile strength MPa 170 160

Tensile modulus MPa 15,500 14,500

Mechanical property

45% glass filled Sorona®EP

Sorona®2045G

SORONA ® EP – cell phone covers

Covers for iphone

- SORONA® EP combines

dimensional stability and

scratch resistance

- Excellent surface finish

- Easy sublimation printing on

demand

- Min 20 up to 37% by weight

renewable content in

SORONA® EP

Taber Scratch result after AOA aging

0

2

4

6

8

10

0 8 16 32 64

AOA aging time / hours

Fo

rce

/ N

Sorona NC010 Sorona Red

Sorona Silver ABS

PC/ABS

O

OO

OO

O

HO

O

O

OO

O

O

OH

O

YZ

Ether

HARD SEGMENTS SOFT SEGMENTS

Hytrel® RS uses soft segment based on renewable source

The bio renewable content varies Shore D hardness

The basis is non-food biosource

The bio-soft segment is chemically similar to fossil based soft

segment

• DuPont™ Hytrel® polymer

Air duct applications operate with

design elongation < 50%

Stress versus Strain at different temperatures

Injection molded ISO 5A bars @ 50 mm/min


Current grade portfolio

• Base Polymers ranging from 40 Shore D to

63 Shore D:

– Hytrel® RS 40F3 NC010

(40D, high flow for injection moulding, >50% renewable content )

– Hytrel® RS 40F5 NC010 (40D, for injection moulding and extrusion, >50% renewable content )

– Hytrel® RS 40F2 NC010 ( 40D, low melting point, >38% renewable content )

– Hytrel® RS 55F5 NC010 ( 55D polymer, >30% renewable content )

– Hytrel® RS 63F5 NC010 ( 63D polymer, >22% renewable content )

DUPONT CONFIDENTIAL

Generation by Knoll®


High performance polyamides that provide high

flexibility, toughness and thermal properties with

superior chemical and hydrolysis resistance.

The product line includes unreinforced and glass

reinforced grades of Polyamide 10.10 and 6.10 with a

renewably sourced content of up to 100%, derived

from castor oil.

Provides lower cost options vs. Polyamide-11 and 12.

Radiator end-tanks

Fluid management Electronic housings

DuPont Zytel® RS High performance Nylon

Industrial

ZYTEL® RS Fischer UX-green

Key Benefits Zytel® RS

Min 50% renewable content by weight

Easy Processing

High stiffness and toughness

Similar and better load bearing

Long term properties


Renewable ZYTEL ® RS HTN

Hand Held Device

Inclusive Sustainability


Thinner-Lighter-Renewable

ZYTEL® RS HTN - Very high stiffness and strength for

metal replacement

- Flow ability for thinnest wall sections

allows sleek, light designs that

improve performance

- Part weight reduction supports the

footprint reduction

- Min 20 up to 100% renewable content

by weight in ZYTEL® RS

Thinner Lighter

Aesthetical Innovative

Hand Held Device

20

ZYTEL ® RS – Long Chain LCPA

Hose & Tube

ZYTEL® RS LCPA portfolio for extrusion

- Continued development of the broadest range

of renewably sourced Polyamides

- Commercial Success with ZYTEL RS in Fiat

diesel-fuel lines

- New DuPont™ Zytel® RS LC4000 (PA610)

and Zytel® LC7000 (PA612).

- Chemically modified long chain polyamides

with improved hydrolysis and chemical

resistance

- Min 20 up to 100% renewable content by

weight in ZYTEL® RS




Life Cycle Analysis and Carbon Sequestration

CO2

CO

N2O CH4

CO2

recycling

Cradle-to-Gate GHG

Emissions

DuPont Renewably Sourced Materials

visit www.renewable.dupont.com

FEEDING THE WORLD REDUCING OUR DEPENDENCE

ON FOSSIL FUELS

KEEPING PEOPLE AND

THE ENVIRONMENT SAFE

25 © E.I. du Pont de Nemours and Company

Thank you.

Søren Flensborg Iversen

Renewably Sourced Performance Polymers

[email protected]

+45/51430444

mailto:[email protected]

Søren Flensborg Iversen -...

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