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Transcript of SPSA / SIPR Conference 2010 Remote Chemical Detection by Tunable Lasers : Potential applications in...
![Page 1: SPSA / SIPR Conference 2010 Remote Chemical Detection by Tunable Lasers : Potential applications in Threat Detection and Forensics Dr Graeme Malcolm.](https://reader034.fdocuments.us/reader034/viewer/2022050714/56649cbb5503460f94982e08/html5/thumbnails/1.jpg)
SPSA / SIPR Conference 2010
Remote Chemical Detection by
Tunable Lasers :
Potential applications in Threat
Detection and Forensics
Dr Graeme Malcolm
![Page 2: SPSA / SIPR Conference 2010 Remote Chemical Detection by Tunable Lasers : Potential applications in Threat Detection and Forensics Dr Graeme Malcolm.](https://reader034.fdocuments.us/reader034/viewer/2022050714/56649cbb5503460f94982e08/html5/thumbnails/2.jpg)
Acknowledgements
•Co-authors:• G.T. Maker, B.Miller & G. Robertson,
M Squared Lasers Ltd• M.H. Dunn and D.J.M Stothard,
University of St. Andrews, UK
•Co-workers :• C.R Howle, A McIntosh, L.Lee and C.Dyer• Defence Science and Technology Laboratory (DSTL),
Porton Down, UK
• Work supported by:• DSTL, MoD, Royal Society of Edinburgh, Scottish
Enterprise.
![Page 3: SPSA / SIPR Conference 2010 Remote Chemical Detection by Tunable Lasers : Potential applications in Threat Detection and Forensics Dr Graeme Malcolm.](https://reader034.fdocuments.us/reader034/viewer/2022050714/56649cbb5503460f94982e08/html5/thumbnails/3.jpg)
Overview
•Active IR hyperspectral sensing concept
•Source requirements
•Source & imaging system
•Results
•Threat Detection and Forensic Applications
•Conclusion and Summary
![Page 4: SPSA / SIPR Conference 2010 Remote Chemical Detection by Tunable Lasers : Potential applications in Threat Detection and Forensics Dr Graeme Malcolm.](https://reader034.fdocuments.us/reader034/viewer/2022050714/56649cbb5503460f94982e08/html5/thumbnails/4.jpg)
www.m2lasers.com
Introduction
•Problem: real-time detection & imaging of threat materials at safe distances• CWAs, BWAs, IEDs, TICs• Ideally detect many agents with one device• ‘Safe’ distance typically ten(s) metres
IED ThreatTypical Explosives Mass(TNT Equivalent)
Building Evacuation Distance
Pipe Bomb 2.3 kg (5 lbs) 21 m (70 ft)
Suicide Belt 4.5 kg (10 lbs) 27 m (90 ft)
LPG Tank 9 kg (20 lbs) 48 m (160 ft)
Ref: US Army, National Ground Intelligence Center, IED Safe Standoff Distances
![Page 5: SPSA / SIPR Conference 2010 Remote Chemical Detection by Tunable Lasers : Potential applications in Threat Detection and Forensics Dr Graeme Malcolm.](https://reader034.fdocuments.us/reader034/viewer/2022050714/56649cbb5503460f94982e08/html5/thumbnails/5.jpg)
Stand-off Concept
Confidential - Feb ‘09
•Threat Detection Concept
•M Squared Current Capability •CWA Sensing
![Page 6: SPSA / SIPR Conference 2010 Remote Chemical Detection by Tunable Lasers : Potential applications in Threat Detection and Forensics Dr Graeme Malcolm.](https://reader034.fdocuments.us/reader034/viewer/2022050714/56649cbb5503460f94982e08/html5/thumbnails/6.jpg)
www.m2lasers.com
Application Requirements:IR Threat Signatures
•C C•C N
•C N•C C
•C O
•X-H attached tohetero-atoms
•C-H •Triples•Doubles
•Singles
•N H •O H
•4000 •2000•3000 •1000
•2300 •2100 •1800 •1500•2800•4000 •3200
•cm-1
•5.0•2.5 •10•3.3 •µm
•cm-1
•Typical absorption wavelengths of molecular bonds in common organic molecules
![Page 7: SPSA / SIPR Conference 2010 Remote Chemical Detection by Tunable Lasers : Potential applications in Threat Detection and Forensics Dr Graeme Malcolm.](https://reader034.fdocuments.us/reader034/viewer/2022050714/56649cbb5503460f94982e08/html5/thumbnails/7.jpg)
Active IRHyperspectral Remote Sensing- Concept
•Use strong absorptions of target molecules or compounds in the IR waveband•Illuminate scene with IR light of high spectral purity to coincide with absorption features• Collect back-scattered light
•Target molecule/compound in path of beam will absorb and reduce backscatter• Negative Contrast Imaging
•Tunable IR source• Different absorption features
measured and spectroscopic identification possible
![Page 8: SPSA / SIPR Conference 2010 Remote Chemical Detection by Tunable Lasers : Potential applications in Threat Detection and Forensics Dr Graeme Malcolm.](https://reader034.fdocuments.us/reader034/viewer/2022050714/56649cbb5503460f94982e08/html5/thumbnails/8.jpg)
3.0 3.5
4.0 4.5 5.0
10 -17
10 -18
10 -19
10 -20
10 -21
10 -22
HCN
C2H2
OH
NH3
H2O
BTEX
CH3CI
C2H4
NO2
HCI
CH4
C2H6
H2CO HBr
H2SSO2
CO2
PH3
N2O
OCS
CO
GeH4
HI
C2N2
O3
Wavelength (µm)
Lin
e S
tren
gth
(cm
/mole
cu
le)
Spectroscopic survey of line strengths of in the 3-5µm infrared region
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Source Requirements
•Sensitivity & specificity require sources with:• High power & brightness (for range, high SNR)• Broad wavelength tuning (cover many species)• Suitable linewidth (selectivity) • High efficiency and compactness (portability)
•Lack of suitable IR illuminators has hindered adoption of active IR hyperspectral sensing
![Page 10: SPSA / SIPR Conference 2010 Remote Chemical Detection by Tunable Lasers : Potential applications in Threat Detection and Forensics Dr Graeme Malcolm.](https://reader034.fdocuments.us/reader034/viewer/2022050714/56649cbb5503460f94982e08/html5/thumbnails/10.jpg)
Novel IR Illuminator - Firefly-IR
•OPO = broad tuning, dual NIR & MWIR outputs•Intracavity OPO = high efficiency•Integrated pump = compact•Designed for field use:• Maintenance-free design• Instrument Control by Ethernet• InvarianT™
alignment-free mounts
36 x 21 x 7cm (L x W X H)
![Page 11: SPSA / SIPR Conference 2010 Remote Chemical Detection by Tunable Lasers : Potential applications in Threat Detection and Forensics Dr Graeme Malcolm.](https://reader034.fdocuments.us/reader034/viewer/2022050714/56649cbb5503460f94982e08/html5/thumbnails/11.jpg)
Firefly-IR:Performance Characteristics
•Tuning ranges:• 1.4 - 1.8 µm (>300 mW)• 2.8 - 4.6 µm (>120 mW)•Pulse repetition rate:• Up to 300 kHz•Pulse width:• < 10 ns (FWHM)•Linewidth:• < 6 cm-1 (no étalons)• < 2 cm-1 (signal étalon)
Pump
Signal
Idler
QS Nd:YV04 pump
PPLN
(Optional étalons)
M2 < 1.4 at 3.3µm
Typical Tuning Curve - MWIR Output, Broadband
![Page 12: SPSA / SIPR Conference 2010 Remote Chemical Detection by Tunable Lasers : Potential applications in Threat Detection and Forensics Dr Graeme Malcolm.](https://reader034.fdocuments.us/reader034/viewer/2022050714/56649cbb5503460f94982e08/html5/thumbnails/12.jpg)
Firefly-IR + Scanner:Imaging
From Firefly-IR
MCT Detector
CaF2 Lens
Galvanometermirror
Raster :
Backscatter Absorption Gas Imaging for Gases
Active Reflectance / Absorption Imaging of Liquids/Solids
![Page 13: SPSA / SIPR Conference 2010 Remote Chemical Detection by Tunable Lasers : Potential applications in Threat Detection and Forensics Dr Graeme Malcolm.](https://reader034.fdocuments.us/reader034/viewer/2022050714/56649cbb5503460f94982e08/html5/thumbnails/13.jpg)
Video-Rate Imaging of Gases
Normal video:gas is invisible
What Firefly saw – methane gas
![Page 14: SPSA / SIPR Conference 2010 Remote Chemical Detection by Tunable Lasers : Potential applications in Threat Detection and Forensics Dr Graeme Malcolm.](https://reader034.fdocuments.us/reader034/viewer/2022050714/56649cbb5503460f94982e08/html5/thumbnails/14.jpg)
Firefly-IR + Scanner:Imaging Applications
Demonstration of gas imaging and false colour concentration measurement with Firefly-IR using differential absorption
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Firefly-IR + Scanner:Concentration Resolution & range
•Sensitive CH4 monitoring
• Detection to <35 ppm.m• Real-time imaging
![Page 16: SPSA / SIPR Conference 2010 Remote Chemical Detection by Tunable Lasers : Potential applications in Threat Detection and Forensics Dr Graeme Malcolm.](https://reader034.fdocuments.us/reader034/viewer/2022050714/56649cbb5503460f94982e08/html5/thumbnails/16.jpg)
Identification of Liquids
Spectral fingerprinting of liquids : various mineral oils
![Page 17: SPSA / SIPR Conference 2010 Remote Chemical Detection by Tunable Lasers : Potential applications in Threat Detection and Forensics Dr Graeme Malcolm.](https://reader034.fdocuments.us/reader034/viewer/2022050714/56649cbb5503460f94982e08/html5/thumbnails/17.jpg)
Identification of Liquids II
•Spectroscopic & spatial negative contrast imaging of mineral oils – with differential analysis
Z ~1.2 m
![Page 18: SPSA / SIPR Conference 2010 Remote Chemical Detection by Tunable Lasers : Potential applications in Threat Detection and Forensics Dr Graeme Malcolm.](https://reader034.fdocuments.us/reader034/viewer/2022050714/56649cbb5503460f94982e08/html5/thumbnails/18.jpg)
www.m2lasers.com
Imaging Threat Simulants:
Forensics : Attempted to remove CWA simulant but still detectable
•Z ~1.2 m
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Applications in Threat Detection / Forensics•Identifying threats• Security & venue protection• Counter Terrorism screening
•Decontamination• Identifying effective decontamination requirements
•Triage• Understanding nature of attack substance
•Forensic Investigation• Ability to investigate a scene remotely and chemically map
evidence.
![Page 20: SPSA / SIPR Conference 2010 Remote Chemical Detection by Tunable Lasers : Potential applications in Threat Detection and Forensics Dr Graeme Malcolm.](https://reader034.fdocuments.us/reader034/viewer/2022050714/56649cbb5503460f94982e08/html5/thumbnails/20.jpg)
THz Imaging for Drug Detection
•THz Spectral Fingerprinting
•The Importance of Terahertz:
•New spectroscopic area important for molecular identification
•Like X-rays but non-ionising – not dangerous
•Drug detection and Identification
•Leveraging pharmaceuticals Leveraging pharmaceuticals non-destructive testing / analysisnon-destructive testing / analysis
•Ecstasy
•Aspirin
•Meth
•
![Page 21: SPSA / SIPR Conference 2010 Remote Chemical Detection by Tunable Lasers : Potential applications in Threat Detection and Forensics Dr Graeme Malcolm.](https://reader034.fdocuments.us/reader034/viewer/2022050714/56649cbb5503460f94982e08/html5/thumbnails/21.jpg)
Summary
•Demonstrated active IR spatial/spectral detection of gases and liquids
• Gases down to 10ppm.m at >10m
• Liquids down to 20ul at 10m
• Solids down to ng of residue
•Novel laser sources provides newcapabilities for threat agent imaging with potential applications in:
• Detection of CWAs and Explosive Materials
• Counter-terrorism and forensic investigation
• Drug detection and analysis