Sparks CH301 ELECTRONS and BONDING WRAP …sparks.cm.utexas.edu/courses/pdf/Slides/Atomic...
Transcript of Sparks CH301 ELECTRONS and BONDING WRAP …sparks.cm.utexas.edu/courses/pdf/Slides/Atomic...
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Sparks
CH301
ELECTRONS and BONDING WRAP
UNIT 2 Day 9
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Important Information
EXAM THURSDAY 7PM – 9PM
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QUIZ: CLICKER QUESTION
Which of the of following is the electronic configuration for K and K+ , respectively? a)1s22s22p63s23p64s1 ; 1s22s22p63s23p64s1
a)1s22s22p63s23p64s1 ; 1s12s22p63s23p64s1
a)1s22s22p63s23p64s1 ; 1s22s22p63s23p6
a)1s22s22p63s23p64s1 ; 1s22s22p63s23p64s2
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Relate electron configuration to periodic table
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QUIZ: CLICKER QUESTION
A laser pulse shines for 10 s delivering a total energy of 4 mJ of 633 nm light. Another laser delivers the same amount of energy with a wavelength of 408 nm. Which laser is delivering more photons to the sample? A) RED Laser B) BLUE Laser C) BOTH ARE THE SAME D) NOT ENOUGH INFORMATION
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QUIZ: CLICKER QUESTION
Each of these lasers shines on calcium ( = 2.90 eV). What will happen when a 10 s pulse of red laser shines on calcium? a) NOTHING b) Electrons will be ejected c) Electrons will be ejected, but fewer than for the
blue laser What will happen when a 10 s pulse of the blue laser shines on calcium? a) NOTHING b) Electrons will be ejected c) Electrons will be ejected, but there will be fewer
than for the red laser
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2. Please explain the change in effective nuclear charge, Zeff , as you move across a row in the periodic table from left to right. Indicate how this change in Zeff affects the ionization energy and the atomic radii of the atoms as you move across a row. Use the elements calcium and selenium as specific examples predicting which would have the smaller atomic nucleus and why.
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EXPLANATION SPACE
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QUIZ: CLICKER QUESTION
Please write out the electron configuration for Germanium, Ge,
using the noble gas short hand method
a) [Ar]3s23p64s23d104p2 b) [Ar] 4s24p2
c) [Ar] 4s23d104p2
d) [Kr] 4s23d104p2
e) [Kr] 4s24p4
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QUIZ: CLICKER QUESTION
Given that the correct electron configuration for Germanium, Ge is: [Ar] 4s23d104p2
Which of the following sets of quantum numbers will not be
an allowed set for an electron in the ground state of Ge? a) 1,0,0,½ b) 4,1,0,½ c) 3,1,1,½ d) 4,2,-2,½ e) 4,1,-1,-½
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QUIZ: CLICKER QUESTION
Please draw the Lewis structure for the molecule, oxalate ion, C2O4
2-.
The formal charge for each atom in the structure is correct in which diagram?
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QUIZ: CLICKER QUESTION
The concept of electronegativity refers to:
a)The notion that metals tend to lose electrons to form cations.
b)The notion that nonmetals have a greater affinity for electrons, so will tend to form anions to achieve a noble gas type electron configuration.
c)The notion that within the context of a covalent bond, an atom which has a stronger affinity for electrons will attract the shared pair to a greater extent.
d)The notion that covalent compounds share their bonding pairs electrons equally between atoms producing pure covalent or non polar type bonds.
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CH302 Vanden Bout/LaBrake Fall 2012
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What have we learned?
Electromagnetic radiation interacts with matter.
Understanding EM radiation, helps to understand matter on
the micro-scale. The physical model of the behavior of teeny
tiny things is quite complicated and difficult to understand.
The number of protons and the number and arrangement of
electrons is important for predicting the chemical
properties of the elements. You can abbreviate complicated
electron configurations using a series of numbers and letters.
The periodic table is your friend.
You can name compounds. You can understand the structure
of ionic compounds. You can predict basic bonding in
molecules using Lewis structures.