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Solid state physics for Nano - Uni Siegen · Analysator pre-mirror Monochro-mator Slits 4 f Storage...
Transcript of Solid state physics for Nano - Uni Siegen · Analysator pre-mirror Monochro-mator Slits 4 f Storage...
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Solid state physics for Nano
Lecture 2: X-ray diffraction
Prof. Dr. U. Pietsch
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The mean aim of Max von Laue (1912)X-rays are electromagnetic wave with wave length much smaller
than wave length of visible light. X-rays are diffracted a crystal lattice
1914
Nobelpreis fürPhysik
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Original experiment von Laue, Friedrich und Knipping
X-ray tube
Photographic film
CollimatorCrystal
Ausgestellt im Deutschen Museum in München
20.April 1913
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Photographic film
Erster Kristall
Cu2SO4 ⋅ 5 H2O
First Laue Experiment
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1912: Begin of modern Crystallography
X-rays are electromagnetic waves of very short wavelength ( ~ 1 Å = 10-10 m).
Crystals are periodic structures in 3D : interatomic distances are of similar order of magnitude as
x-ray wave length
X-ray diffraction is a method to determine the geometric structure of solids !
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Erklärung durch Interferenz am 3D Gitter
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Explanation of Laue pattern
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recip. lattice vector
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𝑎 = 𝑏 = 𝑐
sin2
sin²²²
2
sin4²²²
2
d
lkh
a
a
lkh
=
++=
=++
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Alternative description of Laue-pattern by W.H.Bragg und W.L.Bragg
Interference at dense backed
„lattice planes“
N=2dsinQ
Bragg equation
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Reciprocal space, Ewald construction
,....0*,0*
2*
2*
2*
==
=
=
=
cbba
cc
bb
aa
)(*
)(*
)(*
cba
bac
cba
acb
cba
cba
=
=
=
*)**(2 lckbhaGK ++==
)(
2
2
hkldG
kk fi
=
==
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Setup of modern diffraction experiment
Qi
Slits
Detector
AbsorberboxSample
Analysator
pre-mirror
Monochro-
mator
Slits
Qf
Storage
ring
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X-ray tube and tube spectrum
E = h v = e U
min= h c / e Uamin = 12.4/Ua Brems-
strahlung
Characteristicradiation
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ESRF
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Generation of Synchrotron radiation
Electron circulates with relatvististic energy in orbit of storage ring with orbitfrequency w= 106 Hz → Ee = 5 GeV
²1
²
²
²1
² 00
ß
cm
c
v
cmEe
−=
−
=
Ee is much larger compared to rest mass energy mc², g = 5GeV/ 0.511 GeV≈ 104
²1
1
² ßcm
E
o
e
−==g
value 1/g is the vertical open angle Using g one can estimate the electron velocity
92/1 10*61²2
11]
²
11[ −−=−−=
ggß cv 910*61 −−
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Generation of Synchrotron radiationSupposing the circulating electron emits a photon at point A of orbit. M Elektron proceeds to point C via B on orbit. At point C it emits a secondphoton. For the electron the length
AC (electron) = v* dt .
For the photon emitted in A reaches this distance is
AC(photon = c *dt
The spatial distance between both waves : (c-v) dt
An observer at point C the light pulse has a length
´²)1(´)(
dtc
dtvct −=
−=
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Generation of Synchrotron radiation
Considering the opening angle a = 1/g due to electron orbit
´²2
)²(1´)]
2
²1)(
²2
11(1[´)cos1( dtdtdtt
g
aga
ga
+−−−=−=
For a =0 ´10´
²2
1 8dtdtt −=g
Dilatation of time a consequences for spectral distribution of photon emission
Orbit time of electron along AC differs from time of photon
sTphotont
sTelectront
18
10
10³2
11
²2
1)(
101
2
1)´(
−
−
==
==
wggwg
gwg
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Generation of Synchrotron radiation
Inverse pulse length determines the spectral with of light emission
The emission spectrum has a critical wave length given by
This is x-ray range. In energy :
Hzc1810³
2
3= wgw
mc
c
10
18
8
1010
10 −===
)()(*655.0³2
3 2 TBGeVEec = wgw
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Generation of Synchrotron radiation
Bending radius R of electron orbit is
Emission power is
For ESRF, E=6GeV, B=0.8T → R= 24.8m
Bmv Re=g)(
)(*3.3
² TB
GeVE
eB
mc
mc
E
eB
mcR ee ===
g
)()()²()(*266.1)( 2 mAImRTBGeVEkWP e a=
WmAmradmTGeVkWP e 3.7100*05.08.24)²(8.0)(6*266.1)(2 =+=
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wc
Bend magnet spectrum
ESRF
Well predictable
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Kinematic X-ray scattering
Dipole scattering of x-ray wave by an electron: Electron excites dipole radiation
+==
2
²cos1
²
1
²
²² 2
Rmc
eEEI o
Superposition of dipole radiation generated by two electrons at positions X1 and X2
)])(2
[exp(1
²
²210 XXti
Xmc
eEE −−=
w
For n electrons
])[2
exp(][2exp(1
²
²00 SS
Rti
Rmc
eEE
n
−−=
Stotal scattering amplitude of one atom : → atomic form factor
)(2
0SSkk if −=−
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Kinematic X-ray scattering
Form factor f[(s-s0)/] result fromquantun mechanical calculationsf(0) = Z ; f[(s-s0)/] decays continuoslyas function of (s-s0)/
])[2
exp(][2exp(1
²
²00 SS
Rti
Rmc
eEE
n
−−=
Scattering by all electrons of one atom : → atomic formfactor
−
=−n
dVrss
iSSrie
][2exp()])(
2[exp(* 00
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Kinematic X-ray scattering
Scattering by two atoms :
Debye´sche Streugleichung Debye equation
)])([2exp(]([2exp(]))(
[2exp(][2exp( 02
21
20
21 SSR
iffR
tiRSSR
tifR
tifE
−++=−−
−+−
Scattering by many disordered atoms :
)](2
cos[2* 0212
2
2
1
* SSffffEEI
−++=
nm
nm
mn
nmkr
krffI
)sin(
,
=
2)sin(]][
2exp 0 =→→− k
kr
krrSS
i
nm
nm
nm
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Kinematic X-ray scattering
Scattering by „small“ crystal: rnm= Rnm+rn distances between unit cells → shapefactor, distances betwen atoms within one unit cell→ structure factor
Summation over all unit cells→ N1a1 , N2a2 , N3a3
332211 amamamRnm ++=
])[(2
exp()2exp()exp( 3322110 amamamSSiR
itifE n ++−−
w
2|| =K
²²*
)sin(
)sin(
)sin(
)sin(
)sin(
)sin(²
321
3321
221
2221
121
1121
SFEEI
Ka
KaN
Ka
KaN
Ka
KaNFE
=
if kkK −=
FWHM
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Kinematic X-ray scattering
I 0 only in near vicinity of the peak maxima
lKa
kKa
hKa
2
2
2
3
2
1
=
=
=h,k,l integer
FWHM of a Bragg peak can be approximated
Q=
Q=
Q=Q
cos
94.0
cos
94.0
cos
/)(ln2)2(
LNaNa
sB
FWHM B(2Q) is inversely proportional to crystal size L
kax =2
1)/)²(exp(²
)²(sin
)²(sin)( xNN
x
xNxI −
Q= cos2
1Bk
2
1)²cos)²
2(
²
²²(exp(² =Q−
BaNN
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Structure factor F
))(exp(1
i
n
i
i krifF −= =
czbyaxr iiii ++=
))*)(**(2exp(1
czbyaxlckbhaifF iii
n
i
i ++++−= =
))(2exp(1
iii
n
i
i lzkyhxifF ++−= =
*)**(2 lckbhak ++=
Examples→
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bcc- structure: xyz = 000, ½ ½ ½
))(exp(1( lkhifF ++−+=
F= 2f if h+k+l = even;F= 0 if h+k+l odd
fcc- structure: xyz = 000, ½ ½ 0, ½ 0 ½ , 0 ½ ½
))(exp()(exp()(exp(1( lkilhikhifF +−++−++−+=
F= 4f if h,k,l all are even or odd;F= 0 if h,k,l are mixed
hcp- structure: xyz = 000, 1/3 2/3 ½
))2/3/)2((2exp(1( lkhifF ++−+=
F= 2f if h+2k =3n, l even;F= √3f if h+2k= 3n+1, l oddF= 0 if h+2k= 3n+1 l even
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Extinktion rules
Not all combinations of h,k,l are „allowed“ , Bragg peak intensity can bevanishing due to crystal (point group ) symmetry
In fcc system, only reflections appear with h²+k²+l² = 2,4,8,11,12….
= 111, 200, 220, 311, 222,…..
In NaCl 111, 311….. Are weak reflectons220, 400….. Are strong reflections
In ZnSe 220, 400…….strong111, 311…….middle200, 222…….weka
Structure (point group) identification considering extinktionrules and Bragg peak intensities
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Powder diffraction pattern from CdSe Nanowires
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Debye-Waller Factor
)exp()exp())(exp( rikikrrrik =+
)²2
1exp(...²
2
11)exp( xxxiix −=+−+=
)2exp()²²2
1exp()exp( Mrkrik −=−
²
²sin²²162
uM =
)2exp()( MFTF −=
Due to thermal atom oscillations
X-ray intensity becomes damped, Bragg peaks exit
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Data evaluation
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Electron charge density distribution fromx-ray diffraction data
Electronic charge densityof silicon
Valence charge density difference charge density(bonding charges)
U.Pietschphys.stat.sol.(b) 137, 441,(1986)
−−= dkikrkFr )exp()()(
− − −
−=h
h
k
k
l
l
ii HrHFV
r );2exp()(2
)( )(1
hkla
H =
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Electron density distribution of GaAs fromx-ray diffraction data
Valence charge densitydifference charge density(bonding charges)
Ga As
Ga
As