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Slaughterhouses RestaurantsWaste disposal units
( container parks)
FOGRA
Meat and bonemealRecycled FA
± 80 T.Animal fat
± 50 T.
DEMETER (NL)
VERKEST19/4
20/4
FEEDMILL
COMPANIES
Second contamination Rendac (Rendering of animals)
Aveve
TRANSPORT COMPANY VILLE DE COURTRAI N.V.
Annex 1
WAYS OF CONTAMINATION
19/1/99 FOGRA DE BRABANDER28.680 kg GR.REC.(très contaminées)
20/1/99 VERKEST TANK 127.200 KG
HUYS VOEDERS NV
ChargementFOGRA : 28.040 kg GR.AN.
VERKEST : - 2/3 Tank 1B+ 2/3 Tank 1
21/1/99 ALIMEX (FRANCE)22/1/99 FOGRA VERKEST (GR.AN.)25/1/99 FOGRA VERKEST (GR.AN.)26/1/99 FOGRA HUYS (GR.AN +GR.REC.)
VERKEST (1+1B) DE
Annex 1
PCB Dioxins
(µg/g fat) (pg/g fat)
453,000 11163,000
6,600 120,450
3,000 61,630
6,500 165,980
6,100 111,430
5,630 108,390
10,300 214,130
336,000 4970,000
0,830 20,080
332,000 6141,000
15,000 301,370
11,00 266,18
3,40 72,97
220,00 5915,00 Log PCBs (µg/g fat)L
og
dio
xin
s (p
g/g
fat)
0 1 2 3-0.50
1
2
3
4
5
Results:r2 = 0.994p < 0.0001Log dioxins = 0.974 x Log PCB + 1.344n = 13
Dioxins and PCBs infeedstuff
Annex 2
PCB Dioxins
(µg/g fat) (pg/g fat)
38,890 713,060
15,938 265,700
0,093 1,400
0,440 6,680
0,380 12,150
4,600 64,310
0,080 2,100
0,110 1,620
0,406 12,000
0,770 19,000
0,850 19,580
0,07 6,04
0,09 1,68
0,12 2,14
0,11 0,90
4,38 54,18
0,05 3,87
0,07 2,23
2,65 67,78
3,93 71,65
0,06 2,43
0,08 2,08
0,13 2,02
0,09 1,85
0,05 0,94
Log PCBs (µg/g fat)
Lo
g d
ioxi
ns
(pg
/g f
at)
-2 -1 0 1 2-1
0
1
2
3
4
Results:r2 = 0.930p < 0.0001Log dioxins = 0.913 x Log PCB + 1.30n = 25
Dioxins and PCBs ineggs
Annex 2
PCB Dioxins
(µg/g fat) (pg/g fat)
44,146 775,110
51,059 2513,000
0,515 14,000
2,721 132,620
5,237 54,380
47,101 965,350
7,602 132,420
6,908 156,500
22,637 463,280
0,159 5,830
0,471 15,800
Log PCBs (µg/g fat)L
og
dio
xin
s (p
g/g
fat
)-1 0 1 2
0
1
2
3
4
Resultsr2 = 0.944p < 0.0001Log dioxins = 0.932 x Log PCB + 1.45n = 11
Dioxins and PCBs inchicken
Annex 2
PCB Dioxins
(µg/g fat) (pg/g fat)
0,014 1,350
0,053 2,080
0,011 0,880
0,024 2,100
0,018 0,800
0,022 3,250
0,015 1,620
0,018 1,730
0,010 0,830
0,028 1,430
0,160 0,650
0,136 2,600
0,028 1,390
0,048 2,500
0,122 2,310
0,144 4,310
0,117 1,890
0,134 2,130
0,101 2,560
0,111 3,000
0,122 4,070
0,058 1,138
0,015 2,070
0,034 1,970
0,019 2,650
0,014 2,290
0,030 1,650
0,013 1,100
0,015 1,460
0,024 2,510
0,018 0,990
0,016 1,230
0,041 2,760
0,019 1,770
0,031 2,470
0,030 2,160
Log PCBs (µg/g fat)Lo
g di
oxi
ns
(pg/
g fa
t)
-2.5 -2.0 -1.5 -1.0 -0.5-0.5
0.0
0.5
1.0
Results:r2 = 0.38p < 0.0001Log dioxins = 0.311 x Log PCB + 0.73n = 35
Dioxins and PCBs inmilk
Annex 2
PCB Dioxins
(µg/g fat) (pg/g fat)
0,225 5,300
1,024 9,500
0,597 13,200
0,598 8,000
Log PCBs (µg/g fat)L
og
dio
xin
s (p
g/g
fat
)-0.75 -0.50 -0.25 0.00 0.25
0.0
0.5
1.0
1.5
2.0
Results:r2 = 0.528p = 0.2733, not significantLog dioxins = 0.437x Log PCB + 1.05n = 4
Dioxins and PCBs inbeef
Annex 3
PCB Dioxins PCB Dioxins
(µg/g fat) (pg/g fat) (µg/g fat) (pg/g fat)
0,23 0,45 0,426 0,97
0,48 1,80 1,05 2,7
0,30 5,50 0,555 0,504
0,29 2,00 1,901 2,2
0,23 0,55 14 2,64
0,44 2,20 0,222 1,9
0,43 2,80 0,755 5,4
0,24 3,20 1,356 5,5
0,75 11,70 2,36 2,1
0,43 3,20 17,954 64
25,47 2,70 3,268 15
4,70 9,80 0,36 1,11
0,61 9,75 0,229 0,92
0,76 2,40 0,491 3,1
0,25 1,60 0,294 1,6
0,24 0,15 0,297 3,4
4,47 4,50 0,244 0,685
0,23 1,27 0,456 2,9
0,37 5,13 0,415 2,1
0,37 1,10 0,277 0,15
0,60 2,10 0,322 2,9
0,49 2,00 0,475 3,1
0,26 3,00 0,356 0,718
0,23 1,50 0,28 1,3
0,74 3,00 0,308 0,35
0,367 2,8
0,381 3
4,285 0,82
0,777 3,1
0,519 3,4
0,612 2,8
0,284 1,2
0,205 0,956
0,38 2,1
0,408 3,2
0,26 0,99
0,37 1,4
0,278 1,2
3,936 3,32
0,894 6,6
2,24 2,8
9,247 20,6
0,463 1,3
0,468 1,9
0,512 1,9
0,207 1,36
0,346 1
2,099 3
2,327 3,2
0,244 1,154
Log PCBs (µg/g fat)Lo
g di
oxin
s (p
g/g
fat)
-1.0 -0.5 0.0 0.5 1.0 1.5-1.5
-1.0
-0.5
0.0
0.5
1.0
1.5
2.0
Results:r2 = 0.305p < 0.0001Log dioxins = 0.478 x Log PCB + 0.431n = 75
Dioxins and PCBs inpigs
Annex 3
-5
0
5
10
15
20
25
30
35
40
28 52 101 118 138 153 180
Congeneres
%
73% 1260/ 27% 1254 µ (feedstuff, 3-9-99) µ+1,96*s µ-1,96*s
Annex 4
ALL RESULTS PCB (results in the central database until 20/10/1999)Type of sample % Negative % Positive number of results negative positive limit (µg/kg)
unknown 99 1 101 100 1 200waste 97 3 471 456 15 1000butter 0 0 54 54 0 200eggs 92 8 1154 1063 91 200foodstuff 98 2 6368 6244 124 200milk 99 1 962 950 12 100fat/other 100 0 121 121 0 200fat-pigs 89 11 16724 14856 1868 200fat-poultry 96 4 4296 4112 184 200fat-cattle 99 1 4108 4055 53 200fat-animal not known 100 0 3694 3684 10 200Total 38053 35695 2358
Type of sample > 200 µg/kg 200 - 500 µg/kg 500 - 1000 µg/kg 1000 - 5000 µg/kg > 5000 µg/kgunknown 1 0 0 1 0butter 0 0 0 0 0eggs 91 40 29 14 8foodstuff 124 60 30 30 4fat/other 0 0 0 0 0fat-pigs 1868 786 425 594 63fat-poultry 184 83 53 30 18fat-cattle 53 33 13 7 0fat-animal not known 10 5 0 5 0
Type of sample > 100 µg/kg 100 - 200 µg/kg > 200 µg/kgmilk 12 8 4
Type of sample > 1000 µg/kg 1000 - 5000 µg/kg > 5000 µg/kgwaste 15 11 4
Annex 5
ALL RESULTS PCB (results in the central database until 20/10/1999)
Type of sample % Negative % Positive number of results negative positive limit (µg/kg)feedstuff 98 2 1244 1213 31 1000ingredients feedstuff 100 0 539 538 1 1000fat for feedstuff 95 6 1177 1118 68 1000Total 2960 2869 100
Type of sample > 200 µg/kg 200 - 500 µg/kg 500-1000 µg/kgfeedstuff 59 37 22ingredients feedstuff 35 13 22fat for feedstuff 33 15 18
Annex 5
Number of negative results PCB (results in the central database until 20/10/1999)
0
2000
4000
6000
8000
10000
12000
14000
16000
Nu
mb
er
of
sa
mp
les
Negative samples 100 456 54 1063 6244 950 121 14856 4112 4055 3684
unknow n w aste butter eggs foodstuff milk fat/other fat-pigs fat-poultry fat-cattlefat-animal not
know n
Annex 5
Number of negative results PCB (results in the central database until 20/10/1999)
0
200
400
600
800
1000
1200
1400
Nu
mb
er
of
sa
mp
les
Negative samples 1213 538 1118
feedstuff ingredients feedstuff fat for feedstuff
Annex 5
Number of positive results PCB (results in the central database until 20/10/1999)
0
200
400
600
800
1000
1200
1400
1600
1800
Nu
mb
er o
f sa
mp
les
Positive samples 1 15 0 91 124 12 0 1868 184 53 10
unknow n w aste butter eggs foodstuff milk fat/other fat-pigs fat-poultry fat-cattlefat-animal not
know n
Annex 5
Number of positive results PCB (results in the central database until 20/10/1999)
0
10
20
30
40
50
60
70
Nu
mb
er o
f sa
mp
les
Positive samples 31 1 68
feedstuff ingredients feedstuff fat for feedstuff
Annex 5
% Negative-Positive Results PCB related to exportDate of entry results:04/08/99 - 20/10/99
0
10
20
30
40
50
60
70
80
90
100
Nu
mb
er o
f sa
mp
les
%
Negative 99,1 99,3 97,9 99,1 100,0 99,6 100,0
Positive 0,9 0,7 2,1 0,9 0,0 0,4 0,0
Pigs Poultry Eggs Bovine Veal Animal fat Feedstuff
Annex 5
% Negative-Positive Results (results in the central database until 20/10/1999)
0
10
20
30
40
50
60
70
80
90
100
Nu
mb
er o
f sa
mp
les
%
Negative 98 100 95
Positive 2 0 6
feedstuff ingredients feedstuff fat for feedstuff
Annex 5
ALL RESULTS PCB RELATED TO EXPORT (date of entry results: between 04/08/99 - 20/10/1999)
Type of sample % negative % positive number of results negative positive limit (µg/kg)Pigs 99,1 0,9 8550 8471 79 200Poultry 99,3 0,7 1314 1305 9 200Eggs 97,9 2,1 485 475 10 200Bovine 99,1 0,9 2882 2856 26 200Veal 100,0 0,0 286 286 0 200Animal fat 99,6 0,4 1394 1388 6 200Feedstuff 100,0 0,0 319 319 0 1000Total 15230 15100 130
Type of sample > 200 µg/kg 200 - 500 µg/kg 500 - 1000 µg/kg 1000 - 5000 µg/kg > 5000 µg/kgPigs 79 60 11 8 0Poultry 9 8 0 0 1Eggs 10 7 2 1 0Bovine 26 17 7 2 0Veal 0 0 0 0 0Animal fat 6 3 2 1 0
Type of sample > 1000 µg/kg 1000 - 5000 µg/kg > 5000 µg/kgFeedstuff 0 0 0
Annex 5
Number of negative results PCB related to export
0
1000
2000
3000
4000
5000
6000
7000
Nu
mb
er
of
sa
mp
les
negative samples 8471 1305 475 2856 286 1388 319
Pigs Poultry Eggs Bovine Veal Animal fat Feedstuff
Annex 5
Number of positive results PCB related to export
0
10
20
30
40
50
60
70
Nu
mb
er o
f sa
mp
les
Positive samples 79 9 10 26 0 6 0
Pigs Poultry Eggs Bovine Veal Animal fat Feedstuff
Annex 5
% Negative-Positive Results PCB related to export
0
10
20
30
40
50
60
70
80
90
100
Nu
mb
er o
f sa
mp
les
%
Negative 99,1 99,3 97,9 99,1 100,0 99,6 100,0
Positive 0,9 0,7 2,1 0,9 0,0 0,4 0,0
Pigs Poultry Eggs Bovine Veal Animal fat Feedstuff
Annex 5
NEGATIVE RESULT POSITIVE RESULT"EXPORT"-samples 15100 130"SANITARY"-samples 13082 2135"CERTIFICATION"-samples 3737 29
0
2000
4000
6000
8000
10000
12000
14000
16000
NEGATIVE RESULT 15100 13082 3737
POSITIVE RESULT 130 2135 29
"EXPORT"-samples "SANITARY"-samples"CERTIFICATION"-
samples
Annex 5
Management of the Belgian Dioxin Crisis
Federal Government
Task Force Governmental CoordinationCrisis CentreGeneral Coordination
Agriculture & Public HealthCrisis cell
Laboratories - ResultsGeert De Poorter
Sanitary InquiriesAlbert Vandersanden (DG 4)Gilbert Houins (DG 4)L. Hallet (DG 5)
Validation CommissionRelease Commission
Noel Vanginderachter (DG 5)Jean-Pierre Vermeersch (DG 5)Guy Temmerman (AEWI)Roger Francaux (IVK)
Regional Government
Annex 6
Entity ChartGovernmental coordination Crisis
Centre
Governmental Coordination Crisis Centre
Civil ProtectionMinistry of Agriculture
Ministry of HealthRegional Authorities
Flanders, Wallonia, Brussels
Provincial Authorities
Private Companies(Rendac, Indaver)
Aminal, Ovam, GANEnvironmental Police
Annex 6
CoordinationGeert De Poorter
LaboratoriesHedwig Beernaert
Sampling distributionBruno Buts
AnalysisAnneke De Cock
InvoicesGeert De Poorter
Export-certificationPierre Joye
Sanitary analysisSabien De Mont
Herd certification analysisSabien De Mont
Pierre Joye
Entity chart
“Laboratories-Results”
Annex 6
Entity Chart “sanitary Inquiries”
Sanitary Inquiries
DG4Feedstuff(feedmill control)
DG5Dairy products,(breeding)eggs and live stock(Farm control, packing station,egg products companies)
Food Inspection ServiceFoodstuff (other thanMeat and Fish)(Food industry and Retail
Veterinary InspectionInstituteMeat and Fish(Slaughterhouses and cutting plants)
Certificates
Destruction of contaminatedanimals and products
Epidemiological inquiryand tracing
Annex 6
SubentityLABORATORIES
LABORATORIES
Formal recognition Accreditation Quality Assurance Normalisation
Federal Ministryof Agriculture
Federal Ministryof Health
PCB and dioxin Protocol Method ValidationInternal QualityControlEuropean Assessement
EU-154
Proficiency TestingReference Materials
Beltest
Annex 6
Subentity ANALYSIS
Analysis
Sanitary analysisExport cerification
analysisHerd certification
analysis
Negative results Positive results
Milk:100(PCB),5 (dioxin)Animal fat and eggs: 200 (PCB), 5(dioxin)
Feed: 1000(PCB), 20(dioxin)Sanitary Inquiries
Annex 6
LAB RESULTS POS. RES. NEG. RES. % POS % NEGENVIROTOX 3811 253 3558 6,6 93,4EURACETA 209 0 209 0,0 100,0ECCA 3392 122 3270 3,6 96,4RIC 2250 121 2129 5,4 94,6CHEMIPHAR 1507 27 1480 1,8 98,2COPIN GEMBLOUX 1046 67 979 6,4 93,6PROV.INST.HYG.ANTW. 1709 50 1659 2,9 97,1CER-MARLOIE 566 10 556 1,8 98,2CCL-NED 52 0 52 0,0 100,0CREPIN-ROUEN 90 2 88 2,2 97,8DEP.ZEEVISSERIJ 253 66 187 26,1 73,9DEP.KWAL.MELLE 264 22 242 8,3 91,7ERC 211 16 195 7,6 92,4HAASE-ASCHOFF-GE 11 0 11 0,0 100,0LAB.ANAL.ALIM.FAC.MED.VET 4 0 4 0,0 100,0LABO MUNIC ROUEN 47 0 47 0,0 100,0LABO VAN VOOREN 4243 127 4116 3,0 97,0LARECO 2253 40 2213 1,8 98,2LISEC 707 111 596 15,7 84,3LOVAP 5140 229 4911 4,5 95,5MASTERLAB 127 1 126 0,8 99,2PROV.CENT.MILIEUOND. 256 29 227 11,3 88,7RIKILT 59 16 43 27,1 72,9ROLT 2012 533 1479 26,5 73,5SERVACO 1981 248 1733 12,5 87,5SGS AGRILAB 4097 379 3718 9,3 90,7TNO-NED 58 0 58 0,0 100,0TOX.CENTR.UNIV.ANTW. 1680 116 1564 6,9 93,1VITO 757 118 639 15,6 84,4WIV-LOUIS PASTEUR 1348 104 1244 7,7 92,3ISSP 33 4 29 12,1 87,9VERWEY-NED 4 0 4 0,0 100,0INSTITUT KUHLMAN 10 0 10 0,0 100,0B.E.A.G.X.-GEMBLOUX 4 0 4 0,0 100,0CLO OOSTENDE 2 0 2 0,0 100,0LUFA-ITL 1 0 1 0,0 100,0MAGHUIN-ROGISTER 78 1 77 1,3 98,7RIVM-NED 1 0 1 0,0 100,0PIVH 22 0 22 0,0 100,0TOTAL 40295 2812 37483 7,0 93,0
Approximative PCB-capacity of the Belgian Labs dioxin-crisis 1999
0
1000
2000
3000
4000
5000
6000
June
4
June
6
June
9
June
23
end o
f July
Augus
t 23
Septe
mbe
r 27
Octobe
r
0
5
10
15
20
25
30
CAPACITY
LABORATORIES
Dioxine/PCB-gehalte Destructievet Rendac (Produktie week 5 t.e.m. 13)
0
500
1000
1500
2000
2500
3000
3500
5 6 7 8 9 10 11 12 13
week
µg
/kg
vet
0
5
10
15
20
25
30
35
40
45
50
pg
TE
Q/g
vet
PCB Dioxine
Dioxine geanalyseerd in SGS-AGRILABPCB geanalyseerd in CCL (Centraal Cooperatief Labo - Nederland)
Week Dioxine PCBpg TEQ/g vet µg/kg vet
5 8,3 5506 35,1 25407 45,1 30808 34 22809 37 245010 33 229011 16,7 111012 10,8 66013 11 680
DIOXINS ANALYSIS TIME OF THE LABORATORY VITO
0
10
20
30
40
50
60
70
80
90
100
3/06
/1999
4/06
/1999
9/06
/1999
14/06
/199
9
16/06
/199
9
16/06
/199
9
1/07
/1999
6/07
/1999
6/07
/1999
10/07
/199
9
13/07
/199
9
13/07
/199
9
13/07
/199
9
14/07
/199
9
14/07
/199
9
26/07
/199
9
9/08
/1999
9/08
/1999
10/08
/199
9
11/08
/199
9
11/08
/199
9
11/08
/199
9
23/08
/199
9
24/08
/199
9
26/08
/199
9
1/09
/1999
3/09
/1999
6/09
/1999
20/09
/199
9
DATE ON WHICH THE SAMPLES WERE RECEIVED BY VITO
AN
AL
YS
IS T
IME
(D
AY
S)
DAYS
MEAN