Simple and Highly Efficient Method for the Deprotection of Allyl Ethers Using...

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2008 Deprotection O 0345 Simple and Highly Efficient Method for the Deprotection of Allyl Ethers Using Dimethylsulfoxide—Sodium Iodide. — A novel and effective method for the deally- lation of a variety of allyl ethers and N-allyl compounds that is compatible with various active functional groups, is developed. Methyl, benzyl, and tert-butyl ethers are quire stable under these conditions. Moreover, the DMSO-NaI reagent employed hydrolyzes 2-O-acetamidopyridines (VI). — (NAGARAJU, M.; KRISHNAIAH*, A.; MEREYALA, H. B.; Synth. Commun. 37 (2007) 15, 2467-2472; Org. Chem. Div. II, Indian Inst. Chem. Technol., Hyderabad 500 007, India; Eng.) — R. Langenstrassen 52- 053

Transcript of Simple and Highly Efficient Method for the Deprotection of Allyl Ethers Using...

2008

DeprotectionO 0345 Simple and Highly Efficient Method for the Deprotection of Allyl Ethers Using

Dimethylsulfoxide—Sodium Iodide. — A novel and effective method for the deally-lation of a variety of allyl ethers and N-allyl compounds that is compatible with various active functional groups, is developed. Methyl, benzyl, and tert-butyl ethers are quire stable under these conditions. Moreover, the DMSO-NaI reagent employed hydrolyzes 2-O-acetamidopyridines (VI). — (NAGARAJU, M.; KRISHNAIAH*, A.; MEREYALA, H. B.; Synth. Commun. 37 (2007) 15, 2467-2472; Org. Chem. Div. II, Indian Inst. Chem. Technol., Hyderabad 500 007, India; Eng.) — R. Langenstrassen

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