Sikafast-3121 - Part a (Cartridge)

8/20/2019 Sikafast-3121 - Part a (Cartridge)

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Safety Data Sheet

SikaFast®‐3121 (drum/pail) Part A

Revision Date 04/24/2015 Print Date 04/24/2015

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1. Identification

Product name : SikaFast®‐3121 (drum/pail) Part A

Supplier : Sika Corporation

Address : 201 Polito AvenueLyndhurst, NJ 07071USAwww.sikausa.com

Telephone : (201) 933-8800

Telefax : (201) 804-1076

Emergency telephone : CHEMTREC: 800-424-9300INTERNATIONAL: [email protected]

Recommended use of thechemical and restrictions onuse

: For further information, refer to the product technical datasheet.

2. Hazards identification

GHS Classifi cation

Flammable liquids, Category 2 H225: Highly flammable liquid and vapor.

Skin irritation, Category 2 H315: Causes skin irritation.Eye irritation, Category 2A H319: Causes serious eye irritation.Skin sensitization, Category 1 H317: May cause an allergic skin reaction.Specific target organ systemic toxicity -single exposure, Category 3, Respiratorysystem

H335: May cause respiratory irritation.

Specific target organ systemic toxicity -repeated exposure, Category 2

H373: May cause damage to organs throughprolonged or repeated exposure.

GHS Label element

Hazard pictograms :

Signal Word : Danger

Hazard Statements : H225 Highly flammable liquid and vapor.H315 Causes skin irritation.H317 May cause an allergic skin reaction.H319 Causes serious eye irritation.H335 May cause respiratory irritation.H373 May cause damage to organs through prolonged orrepeated exposure.

Precautionary Statements : Prevention:


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P210 Keep away from heat/sparks/open flames/hot surfaces. -No smoking.P233 Keep container tightly closed.

P240 Ground/bond container and receiving equipment.P241 Use explosion-proof electrical/ ventilating/ lighting/equipment.P242 Use only non-sparking tools.P243 Take precautionary measures against static discharge.P260 Do not breathe dust/ fume/ gas/ mist/ vapors/ spray.P264 Wash skin thoroughly after handling.P271 Use only outdoors or in a well-ventilated area.P272 Contaminated work clothing must not be allowed out ofthe workplace.P280 Wear protective gloves/ eye protection/ face protection.Response:P303 + P361 + P353 IF ON SKIN (or hair): Take offimmediately all contaminated clothing. Rinse skin with

water/shower.P304 + P340 IF INHALED: Remove person to fresh air andkeep comfortable for breathing.P305 + P351 + P338 IF IN EYES: Rinse cautiously with waterfor several minutes. Remove contact lenses, if present andeasy to do. Continue rinsing.P314 Get medical advice/ attention if you feel unwell.P333 + P313 If skin irritation or rash occurs: Get medicaladvice/ attention.P337 + P313 If eye irritation persists: Get medical advice/attention.P362 Take off contaminated clothing and wash before reuse.P370 + P378 In case of fire: Use dry sand, dry chemical oralcohol-resistant foam to extinguish.Storage:P403 + P233 Store in a well-ventilated place. Keep containertightly closed.P403 + P235 Store in a well-ventilated place. Keep cool.P405 Store locked up.Disposal:P501 Dispose of contents/ container to an approved wastedisposal plant.

Warning : Reports have associated repeated and prolonged exposure tosome of the chemicals in this product with permanentbrain,liver, kidney and nervous system damage. Intentionalmisuse by deliberate concentration and inhalation of vaporsmay be harmful or fatal.

See Section 11 for more detailed information on health effects and symptoms.There are no hazards not otherwise classified that have been identified during the classificationprocess.There are no ingredients with unknown acute toxicity used in a mixture at a concentration >= 1%.

3. Composition/information on ingredients

Hazardous ingredients


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Chemical Name CAS-No. Concentration (%)

methyl methacrylate 80-62-6 >= 50 - = 2 - = 1 - = 1 -


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5. Fire-fighting measures

Suitable extinguishing media : Alcohol-resistant foamCarbon dioxide (CO2)Dry chemical

Unsuitable extinguishingmedia

: WaterHigh volume water jet

Specific hazards during firefighting

: Do not use a solid water stream as it may scatter and spreadfire.

Specific extinguishingmethods

: Use water spray to cool unopened containers.Collect contaminated fire extinguishing water separately. Thismust not be discharged into drains.Fire residues and contaminated fire extinguishing water mustbe disposed of in accordance with local regulations.

Special protective equipmentfor fire-fighters

: In the event of fire, wear self-contained breathing apparatus.

6. Accidental release measures

Personal precautions,protective equipment andemergency procedures

: Use personal protective equipment.Remove all sources of ignition.Deny access to unprotected persons.

Beware of vapors accumulating to form explosiveconcentrations. Vapors can accumulate in low areas.

Environmental precautions : Prevent product from entering drains.If the product contaminates rivers and lakes or drains informrespective authorities.Local authorities should be advised if significant spillagescannot be contained.

Methods and materials forcontainment and cleaning up

: Soak up with inert absorbent material (e.g. sand, silica gel,acid binder, universal binder, sawdust).

7. Handling and s torage

Advice on safe handling : Do not breathe vapors or spray mist. Avoid exceeding the given occupational exposure limits (seesection 8).Do not get in eyes, on skin, or on clothing.For personal protection see section 8.Persons with a history of skin sensitization problems orasthma, allergies, chronic or recurrent respiratory diseaseshould not be employed in any process in which this mixture isbeing used.Smoking, eating and drinking should be prohibited in the


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application area.Take precautionary measures against static discharge.Open drum carefully as content may be under pressure.

Take necessary action to avoid static electricity discharge(which might cause ignition of organic vapors).Follow standard hygiene measures when handling chemicalproducts.

Conditions for safe storage : Store in original container.Store in cool place.Keep in a well-ventilated place.Observe label precautions.Store in accordance with local regulations.

Materials to avoid : No data available

8. Exposure controls/personal protection

Component CAS-No. Basis ** Value Exposure limit(s)* /Form of exposure

methyl methacrylate 80-62-6 ACGIH TWA 50 ppm

ACGIH STEL 100 ppm

OSHA Z-1 TWA 100 ppm 410 mg/m3

OSHA P0 TWA 100 ppm 410 mg/m3

Talc 14807-96-6 OSHA P0 TWA 2 mg/m3 Respirable fraction

ACGIH TWA 0.1 fibre/cm3

ACGIH TWA 2 mg/m3 Respirable fraction

OSHA Z-3 TWA 20 Million particlesper cubic foot Dust

OSHA P0 TWA 2 mg/m3 respirable dustfraction


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*The above mentioned values are in accordance with the legislation in effect at the date of the

release of this safety data sheet.

**Basis ACGIH. Threshold Limit Values (TLV)OSHA P0. Table Z-1, Limit for Air Contaminat (1989 Vacated Values)OSHA P1. Permissible Exposure Limits (PEL), Table Z-1, Limit for Air ContaminantOSHA P2. Permissible Exposure Limits (PEL), Table Z-2OSHA Z3. Table Z-3, Mineral Dust

Engineering measures : Use of adequate ventilation should be sufficient to controlworker exposure to airborne contaminants. If the use of thisproduct generates dust, fumes, gas, vapor or mist, useprocess enclosures, local exhaust ventilation or other

engineering controls to keep worker exposure below anyrecommended or statutory limits.The engineering controls also need to keep gas, vapor or dustconcentrations below any lower explosive limits.

Personal protective equipment

Respiratory protection : Use a properly fitted NIOSH approved air-purifying or air-fedrespirator complying with an approved standard if a riskassessment indicates this is necessary.

The filter class for the respirator must be suitable for themaximum expected contaminant concentration(gas/vapor/aerosol/particulates) that may arise when handlingthe product. If this concentration is exceeded, self-contained

breathing apparatus must be used.

Hand protectionRemarks : Chemical-resistant, impervious gloves complying with an

approved standard should be worn at all times when handlingchemical products if a risk assessment indicates this isnecessary.

Eye protection : Safety eyewear complying with an approved standard shouldbe used when a risk assessment indicates this is necessary.

Skin and body protection : Choose body protection in relation to its type, to theconcentration and amount of dangerous substances, and tothe specific work-place.

Hygiene measures : Avoid contact with skin, eyes and clothing.Wash hands before breaks and immediately after handling theproduct.Remove respiratory and skin/eye protection only after vaporshave been cleared from the area.Remove contaminated clothing and protective equipmentbefore entering eating areas.Wash thoroughly after handling.


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9. Physical and chemical properties

Appearance : paste

Color : various

Odor : characteristic

Odor Threshold : No data available

Flash point : 50 °F (10 °C)

Ignition temperature : No data available

Decomposition temperature : No data available

Lower explosion limit (Vol%) : No data available

Upper explosion limit (Vol%) : No data available

Flammability (solid, gas) : No data available

Oxidizing properties : No data available

Autoignition temperature : No data available

pH : No data available

Melting point/range /Freezing point

: No data available

Boiling point/boiling range : No data available

Vapor pressure : No data available

Density : ca.0.96 g/cm3at 73 °F (23 °C)

Water solubility : Note: insoluble

Partition coefficient: n-octanol/water

: No data available

Viscosity, dynamic : No data available

Viscosity, kinematic : > 20.5 mm2/s

at 104 °F (40 °C)

Relative vapor density : No data available

Evaporation rate : No data available

Burning rate

Volatile organic compounds(VOC) content

: No data available

: 18 g/l Part A + SikaFast®‐3081 N Part B Combined.


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10. Stability and reactivity

Reactivity : No dangerous reaction known under conditions of normal use.

Chemical stability : The product is chemically stable.

Possibility of hazardousreactions

: Stable under recommended storage conditions.

Vapors may form explosive mixture with air.

Conditions to avoid : Heat, flames and sparks.

Incompatible materials : No data available

11. Toxicological information

Not classified based on available information.

Skin corrosion/irritation

Causes skin irritation.

Serious eye damage/eye irr itation

Causes serious eye irritation.

Respiratory o r skin sensitization

Skin sensitization: May cause an allergic skin reaction.Respiratory sensitization: Not classified based on available information.

Germ cell mutagenicity


Carcinogenicity

Not classified based on available information.IARC Not applicable

NTP Not applicable

Reproducti ve toxicity


STOT-single exposure

May cause respiratory irritation.

STOT-repeated exposureMay cause damage to organs through prolonged or repeated exposure.Reports have associated repeated and prolonged exposure to some of the chemicals in thisproduct with permanent brain,liver, kidney and nervous system damage. Intentional misuse bydeliberate concentration and inhalation of vapors may be harmful or fatal.Once sensitized, a severe allergic reaction may occur when subsequently exposed to very lowlevels.

Aspirat ion toxic ity



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12. Ecological information

Other information Do not empty into drains; dispose of this material and itscontainer in a safe way. Avoid dispersal of spilled material and runoff and contactwith soil, waterways, drains and sewers.

13. Disposal considerations

Disposal methods

Waste from residues : Disposal of this product, solutions and any by-products shouldat all times comply with the requirements of environmentalprotection and waste disposal legislation and any regional

local authority requirements.

Contaminated packaging : Empty containers should be taken to an approved wastehandling site for recycling or disposal.

14. Transport information

DOTUN number 1133Description of the goods AdhesivesClass 3

Packing group IILabels 3Emergency ResponseGuidebook Number

128

IATAUN number 1133Description of the goods AdhesivesClass 3Packing group IILabels 3Packing instruction (cargoaircraft)

364

Packing instruction(passenger aircraft)

353

Packing instruction(passenger aircraft)

Y341

IMDGUN number 1133Description of the goods ADHESIVESClass 3Packing group IILabels 3EmS Number 1 F-E


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EmS Number 2 S-D

Marine pollutant no

DOT: For Limited Quantity exceptions reference 49 CFR 173.150 (b)IMDG: For Limited Quantity special provisions reference IMDG Code Chapter 3.4

Special precautions for userNo data available

Transport in bu lk according to Annex II of MARPOL 73/78 and the IBC CodeNot applicable

15. Regulatory information

TSCA lis t : All chemical substances in this product are either listed on theTSCA Inventory or are in compliance with a TSCA Inventoryexemption.

EPCRA - Emergency Planning and Community Right-to-Know

CERCLA Reportable Quantit y

This material does not contain any components with a CERCLA RQ.

SARA304 Reportable Quantity

This material does not contain any components with a section 304 EHS RQ.

SARA 311/312 Hazards : Fire Hazard Acute Health HazardChronic Health Hazard

SARA 302 : No chemicals in this material are subject to the reportingrequirements of SARA Title III, Section 302.

SARA 313 : The following components are subject to reporting levelsestablished by SARA Title III, Section 313:methyl methacrylate 80-62-6 53.00 %

Clean Air Act

Ozone-DepletionPotential

This product neither contains, nor was manufactured with aClass I or Class II ODS as defined by the U.S. Clean Air ActSection 602 (40 CFR 82, Subpt. A, App.A + B).

The following chemical(s) are listed as HAP under the U.S. Clean Air Act, Section 12 (40 CFR61):

methyl methacrylate 80-62-6 53.00 %This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for Accidental Release Prevention (40 CFR 68.130, Subpart F).


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California Prop 65 WARNING! This product contains a chemical known in theState of California to cause cancer.

16. Other information

HMIS Classif ication

Caution: HMIS® rating is based on a 0-4 rating scale, with 0 representing minimal hazards orrisks, and 4 representing significant hazards or risks. Although HMIS® rating is not requiredon SDSs under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS® ratingis to be used with a fully implemented HMIS® program. HMIS® is a registered mark of theNational Paint & Coatings Association (NPCA). Please note HMIS® attempts to convey fullhealth warning information to all employees.

Notes to ReaderThe information contained in this Safety Data Sheet applies only to the actual SikaCorporation ("Sika") product identified and described herein. This information is not intendedto address, nor does it address the use or application of the identified Sika product incombination with any other material, product or process. All of the information set forth hereinis based on technical data regarding the identified product that Sika believes to be reliable asof the date hereof. Prior to each use of any Sika product, the user must always read andfollow the warnings and instructions on the product's current Product Data Sheet, productlabel and Safety Data Sheet for each Sika product, which are available at web site and/ortelephone number listed in Section 1 of this SDS.

SIKA MAKES NO WARRANTIES EXPRESS OR IMPLIED AND ASSUMES NO LIABILITY ARISING FROM THIS INFORMATION OR ITS USE. SIKA SHALL NOT BE LIABLE UNDER ANY LEGAL THEORY FOR SPECIAL OR CONSEQUENTIAL DAMAGES AND SHALL NOTBE RESPONSIBLE FOR THE USE OF THIS PRODUCT IN A MANNER TO INFRINGE ON ANY PATENT OR ANY OTHER INTELLECTUAL PROPERTY RIGHTS HELD BY OTHERS.

All sales of Sika products are subject to its current terms and conditions of sale available atwww.sikausa.com or 201-933-8800.

Revision Date 04/24/2015

Material number: 189319

Physical Hazard

Flammability

Personal Protection

Health 2*

3

0

X

Sikafast-3121 - Part a (Cartridge)

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