SGS - Big Fireworks · Sep.28. 2012 Oct.10. 2012 Sep.28•Oct.12, 2012 Safety Data ... results...

SGS SDS Report No. SHATY1217126101

Date: Oct. 17, 2012 of 1

XIAMEN LONG AFTERGLOW CO.,LTD NO. 1043, TONG JI ZHONG ROAD, TONG AN DISTRICT, XIAMEN. CHINA

Summary

SHTY120900016574 liquid in glow stick and glow cup Activatror See Section 3 Composition/information on ingredients on the SDS report Sep.28. 2012 Oct.10. 2012 Sep.28•Oct.12, 2012

Safety Data Sheet (SDS) for the sample with submitted composition.

As per request, the contents and formats of the SDS are prepared in accordance with European Commission Directives 67/548/EEC, 1999/45/EC, Regulation (EC) No 1907/2006, Regulation (EC) No 1272/2008 and Regulation (EU) No 453/2010, and is provided per attached.

SGS Ref. No. Sample Name End Uses Composition/Ingredient of sample (as per client submission) Job Receiving Date Last Information Date SDS Preparation Period

Service Requested

Signed for and on behalf of SGS-CSTC Chemical Laboratory

Lindy Liu Lab Manager

This document is issued by the Company subject to its General Conditions of Senn. printed overload. avedebre on request or accessible at hfivnorwegs.comnorms and conditions. Otto ant,for electronic formal documentesublect to Terms end Conditions ter Electronic Documents at woreregs.comftermets4ocienenthite. Attenlion is drawn to ma Imitation of

kepi*,f ■ .-7 ,.< 7i"?4 andjunsdtption Issues defined therein. Any holder of this d000n►nt Is advised that trrVirmation contarned hereon reflects the Company's findings at Me time of ea the limits of Client's inenuchons, it any. The Comparry's sole niniponsibifity Ste its Client and this dominant does not exonerate parties to • transaction fr ''...".4 xercising aft t s and obligations under the transaction documents. This document cannot be reproduced except in futiwithout prior written approval of Ina Company

• unaulitOrt/Ori an tt . forgery Of falsification of the content or appearance of this document Is unlawful and offenders may be prosecuted to Ito fullest extant of the law ass oSa. late

8

results shown In this test report refer only In the samples} tested

A -.

3''Buldrspia88311shinRoadX0`00attl5toriteiCreas 200233 1M(88-21)81402553 I EE(05-21)64953679 ensw.cn.sgs.corn

'1'131 • • *ZIZ din$13043416 OW 200233 HL :(813-21)61402594 (ES-21)54500353 e SgectensOlVs -ccm

Member of the SGS Group (SGS SA)

GUIS07

Page 1/9

Safety data sheet Regulation(EC) No. 1907/2006, 1272/2008

Printing date 10.10.2012

Revision: 10.10.2012

I Identification of the substance/mixture and of the company/undertaking

• Product identifier Trade name: liquid in glow stick and glow cup

• Article number: Data not available • Registration number: Data not available • Relevant identified uses of the substance or mixture and uses advised against • Application of the substance/ the preparation: Activatror

• Details of the supplier of the safety data sheet • Manufacturer/Supplier: XIAMEN LONG AVIERGLOW CO.,L•D NO. 1043, TONG JI ZHONG ROAD, TONG AN DISTRICT, XIAMEN, CHINA Tel: 0086-592-3675699 Fax: 0086-592-3675400

• Only Representative / other EU contact point Buyer is not located in European Union. European Union Member State contact not available.

• Further information obtainable front: XIAMEN LONG AFTERGLOW CO.,LTD • Emergency telephone number:

Yolanda flu Tel: 0086-592-3675699

• Email: yolandaUglo-novelty.com • Reference number: SHTY 120900016574; SHATY 1217126101

2 Hazards identification

Classification of the substance or mixture • Classification according to Regulation (EC) No 1272/2008

GHS07

STO• SE 3 11335+11336 May calm respiratory irritation. May cause drowsiness or dizziness.

• Classification according to Directive 67/548/EEC or Directive 1999/45/EC Not applicable.

• Label elements • Labelling according to Regulation (EC) No 1272/2008

The product is classified and labelled according to Regulation (EC) No 1272/2(108. • Hazard pictograms

• Signal word Warning

• Hazard-determining components of labelling: Not applicable • Hazard statements H335+H336 May cause respiratory irritation. May cause drowsiness or dizziness.

• Precautionary statements P101 If medical advice is needed, have product container or label at hand. P102 Keep out of reach of children. P103 Read label before use. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for

breathing. P312 Call a POISON CENTER or doctor/physician if you feel unwell. P405 Store locked up. P403+P233 Store in a well-ventilated place. Keep container tightly closed. P501 Dispose of contents/container in accordance with local/regional/national/international

regulations. (Contd. on page 2)

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Trade name: liquid in glow stick and glow cup

(Contd. of page I)

• Additional information: Important! This product contains substance that is of restricted use under Annex XVII of Regulation (EC) No. 1907/2006. For details, please refer to Section 15 and 16 of this Safety Date Sheet.

• Other hazards Not applicable • Results of PRT and vPvB assessment • PET: Not applicable • vPvB: Not applicable

3 Composition/information on ingredients

• Chemical characterization: Mixtures • Description: Mixture of the substances listed below with nonhazardous additions. For the wording of the listed risk phrases refer to section 16.

• Dangerous components:

CAS: 131-11-3 EINECS: 205-011-6

dimethyl phthalate

0 STOT SE 3, H335+11336

89,5%

CAS: 112-34-5 EINECS: 203-961-6 Index number: 603-096-00-8

2-(2-butoxyethoxy)ethanol

Xi R36 •<> Eye Irrit. 2, 11319

7,0%

CAS: 7722-84-1 EINECS: 231-765-0 Index number: 008-003-00-9

hydrogen peroxide solution 112C R35; Xn R20/22; re, 0 R8 R5 0 Ox. Lig. 1, 11271; > Skin Corr. 1A, 1 -1314; Q Acute lax. 4, H302; Acute lax, 4, H332

1,2%

Non-dangerous component:

CAS: 7732-18-5 EINECS: 231-791-2

water 2,3%

• Remark: 2-(2-butoxyethoxy)ethanol (CAS No.112-34-5) Synonym: butoxydiglycol

4 First aid measures

• Description of first aid measures • After inhalation: Supply fresh air; consult doctor in case of complaints. • After skin contact: Immediately wash with water and soap and rinse thoroughly. • After eye contact: Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.

• After swallowing: Rinse out mouth with water. Never give anything by mouth to an unconscious person. Do not induce vomiting; call for medical help immediately.

• Information for doctor: • Most important symptoms and effects, both acute and delayed No further relevant information available. • Indication of any immediate medical attention and special treatment needed No further relevant information available.

5 Firefighting measures

• Extinguishing media • Suitable extinguishing agents: CO , powder or water spray. Fight larger fires with water spray or alcohol resistant foam.

• Special hazards arising from the substance or mixture No further relevant information available. (Contd. on page 3)

411

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(Contd. of page 2)

• Advice for firefighters • Protective equipment:

Wear fully protective suit.

Wear self-contained respiratory protective device. • _______ _

6 Accidental release measures

• Personal precautions, protective equipment and emergency procedures

Wear protective equipment. Keep unprotected persons away.

Ensure adequate ventilation Keep away from ignition sources. Use respiratory protective device against the effects of fumes/dust/aerosol.

Avoid breathing vapors, mist or gas.

Avoid contact with eyes.

Avoid contact with skin.

• Environmental precautions: Do not allow to enter sewers/ surface or ground water.

. Methods and material for containment and cleaning up:

Absorb with liquid-binding material (sand, diatomite, acid hinders, universal hinders, sawdust).

Dispose contaminated material as waste according to item 13.

• Reference to other sections See Section 7 for information on safe handling.

See Section 8 for information on personal protection equipment.

See Section 13 for disposal information.

7 Handling and storage

• Handling: • Precautions for safe handling

Ensure good ventilation/exhaustion at the workplace. Keep receptacles tightly sealed. Keep away from heat and direct sunlight. Prevent formation of aerosols. Avoid ingestion and inhalation. Avoid contact with skin and eyes.

• Information about fire - and explosion protection: Normal measures for preventive fire protection.

• Storage: • Conditions for safe storage, including any incompatibilities: • Requirements to be nzet by storerooms and receptacles:

Store in a cool location.

Store only in the original receptacle.

• Information about storage in one common storage facility: Store away from foodstuffs. Store away from flammable substances.

• Further information about storage conditions: Store in cool, dry conditions in well sealed receptacles.

• Specific end use(s) No further relevant information available.

1

8 Exposure controhlpersonal protection

• Additional information about design of technical facilities: No further data: see item 7.

• Control parameters

- Ingredients with limit values that require monitoring at the workplace:

131-11-3 dimethyl phthalate

WEL (Great Britain) Short-term value: 10 mg/m' Long-term value: 5 mg/m'

(Contd. on page 4) G

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(Contd. of page D

WI

VME (France) 5 mg/m 3

112-34-5 2-(2-butoxyethoxy)ethattol

10ELV (EU) —

AGW (Germany)

WEL (Great Britain)

VME (France)

Short-term value: 101,2 mg/nt 3, 15 ppm Long-term value: 67,5 mg/m 3, 10 ppm

67 mg/m-1, 10 ppm 1,5(1):EU, Dl-G, Y, 11

Short-term value: 101,2 mg/m 3, 15 ppm Long-term value: 67,5 mg/m3, 10 ppm

Short-term value: 101,2 mg/m 3, 15 ppm

Long-term value: 67,5 mg/m3, 10 ppm

7722-84-1 hydrogen

MAK (Germany)

WEL (Great Britain)

VME (France)

peroxide solution

0,71 mg/m3, 0,5 ppm

Short-term value: 2,8 mg/m 3, 2 ppm Long-term value: 1,4 mg/m3, 1 ppm

1,5 mg/m3, 1 ppm

• DNELs: Data not available • PNECs: Data not available

• Additional information: The lists valid during the making were used as basis.

• Exposure controls • Based on composition shown in Section 3, the following messures are suggested for occupational safety measure:

• Personal protective equipment: • General protective and hygienic measures: Wash hands before breaks and at the end of work.

• Respiratory protection: Suitable respiratory protective device recommended. • Protection of hands:

re' 7

7 Protective gloves IIP

The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Due to missing tests no recommendation to the glove material can he given for the product/ the preparation/ the chemical mixture. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation

• Material of gloves: 1he selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application.

• Penetration tune of glove material: The exact break through time has to be found out by the manufacturer of the protective gloves and has to he observed.

• Eye protection:

Tightly sealed goggles

(Contd. on page 5)

10 Stability and reactivity

• Reactivity No decomposition if used according to specification. • Chemical stability Stable under recommended storage conditions. • Possibility of hazardous reactions No dangerous reactions known. • Conditions to avoid No further relevant information available. • Incompatible materials: No further relevant information available. • Hazardous decomposition products: No dangerous decomposition products known.

Page 5/9





(Contd. of page 4)

9 Physical and chemical properties

• Information on basic physical and chemical properties • General Information • Appearance:

Form: Liquid Colour: Transparent

• Odour: Odourless • Odour threshold: Data not available.

• pH-value: Data not available.

• Change in condition Melting point/Melting range: Data not available. Boiling point/Boiling range: Data not available

• Freezing point: Data not available

• Flash point: Data not available

• Flammability (solid, gaseous): Data not available

• Auto-Ignition temperature: Data not available

• Decomposition temperature: Date not available.

• Self-igniting: Product is not selfigniting.

• Explosive properties: Product does not present an explosion hazard.

• Explosion limits: Lower: Data not available. Upper: Data not available.

• Oxidizing properties Data not available.

• Vapour pressure: Data not available.

• Density: Data nut available. • Relative density Data not available. • Vapour density Data not available. • Evaporation rate Data not available. - _ • Solubility in / Miscibility with

water: Data not available

• Partition coefficient (n-octanoUwater): Data not available.

• Viscosity: Dynamic: Data not available. Kinematic: Data not available.

• Other information No further relevant information available.

(Contd. on page 6)

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(Contd. of page 5)

I I Toxicological in Proration

• Information on toxicological effects • Acute toxicity:

• LOILC50 values relevant for classification:

131-11-3 dimethyl phthalate

Oral

Dermal

L1)50

LD50

6800 mg/kg (rat)

>23800 mg/kg (rabbit)

112-34-5 2-(2-butoxyethoxy)ethanol

[5 6 6 0 mg/kg (rat)

2700 mg/kg (rabbit)

Oral

Dermal

LD50

1, 1)50

7722-84-1 hydrogen peroxide solution

Oral

Dermal

lnhalative

LD50

LD50

LC50/4 h

376 mg/kg (rat)

3000 mg/kg (rat)

2 mg/1 (rat)

Primary irritant effect: • on the skin: Irritating effect possible.

• on the eye: Irritating effect possible. • Sensitization: Sensitization possible.

• Toxicokinetics, metabolism and distribution No further relevant information available.

• Acute effects (acute toxicity, irritation and corrosivity) No further relevant information available.

• Repeated dose toxicity No further relevant information available.

• CMR effects (carcinogenity, mutagenicity and toxicity for reproduction) No further relevant information available

12 Ecological information

• Toxicity • Aquatic toxicity: No further relevant information available. • Persistence and degradability No further relevant information available. • Behaviour in environmental systems: • Bioaccumulative potential No further relevant information available.

• Mobility in soil No further relevant information available. • Additional ecological information: • General notes:

Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water

Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage

system. • Results of PBT and vPvB assessment • PBT: Not applicable. • vPvB: Not applicable. • Other adverse effects No further relevant information available.

13 Disposal considerations

• Waste treatment methods • Recommendation Must not he disposed together with household garbage. Do not allow product to reach sewage system.

(Contd. on pagc 1)

ttl-

15 Regulatory information

• Safety, health and environmental regulations/legislation specific for the substance or mixture MAK (German Maximum Workplace Concerntration) 7722-84-1Ihydrogen peroxide solution

• National regulations:

Waterhazard class: Water hazard class I (Self-assessment): slightly hazardous for water. • Other regulations, limitations and prohibitive regulations

14

• SVHC Candidate List of REACH Regulation Annex XIV Authorisation (18/6/2012) None of the ingredients is listed.

REACH Regulation Annex XVII Restriction(15/5/2012) 112-34-5 2-(2-butoxyethoxy)ethanol

7722-84-1 hydrogen peroxide solution

• REACH Regulation Annex XIV Authorization List(14/2/2012) None of the ingredients is listed.

• Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

16 Other information

• Recommended restriction of use REACH Regulation (EC) No 1907/2006 Annex XVII-3: Liquid substances or mixtures, which are regarded as dangerous according to the definitions in Directive 67/548/EEC and Directive I 999/45/EC. 2-(2-butoxyethoxy)ethanol (CAS No.112-34-5); hydrogen peroxide solution (7722-84-1)

1. Shall not be used in: - ornamental articles intended to produce light or colour effects by means of different phases, for example in

(Contd. on page 8) -FX

14 Transport information

• UN-Number • ADR, IMDG, IATA Not applicable

Not applicable • UN proper shipping name • ADR, IMDG, IATA

• Transport hazard class(es)

• ADR, IMDG, IATA • Class

• Packing group • ADR, IMDG, IATA

Not applicable

Not applicable

• Environmental hazards • Marine pollutant: No

• Special precautions for user Not applicable.

• Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable.

• UN "Model Regulation": -

Page 7/9



Revision: /0.10.2012


(Contd. of page 6)

• Uncleaned packaging: • Recommendation: Disposal must be made according to official regulations.

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Printing date 10.10.2012 Revision: 10.10.2012


(Contd. of page 7)

ornamental lamps and ashtrays, - tricks and jokes, - games for one or more participants, or any article intended to be used as such, even with ornamental aspects, 2. Articles not complying with paragraph 1 shall not he placed on the market. 3. Shall not be placed on the market if they contain a colouring agent, unless required for fiscal reasons, or perfume, or both, if they: - can be used as fuel in decorative oil lamps for supply to the general public, and, - present an aspiration hazard and are labelled with R65 or 11304, 4. Decorative oil lamps for supply to the general public shall not be placed on the market unless they conform to the European Standard on Decorative oil lamps (EN 14059) adopted by the European Committee for Standardisation (CEN). 5. Without prejudice to the implementation of other Community provisions relating to the classification, packaging and labelling of dangerous substances and mixtures, suppliers shall ensure, before the placing on the market, that the following requirements are met: (a) lamp oils, labelled with R65 or 11304, intended for supply to the general public are visibly, legibly and indelibly marked as follows: "Keep lamps filled with this liquid out of the reach of children": and, by 1 December 2010, "Just a sip of lamp oil - or even sucking the wick of lamps - may lead to life- threatening lung damage' : (b) grill lighter fluids, labelled with R65 or H304, intended for supply to the general public are legibly and indelibly marked by 1 December 2010 as follows: "Just a sip of grill lighter may lead to life threatening lung damage' ; (c) lamp oils and grill lighters, labelled with R65 or H304, intended for supply to the general public are packaged in black opaque containers not exceeding 1 litre by 1 December 2010. 6. No later than 1 June 2014, the Commission shall request the European Chemicals Agency to prepare a dossier, in accordance with Article 69 of the present Regulation with a view to ban, if appropriate, grill lighter fluids and fuel for decorative lamps, labelled R65 or 11304, intended for supply to the general public. 7. Natural or legal persons placing on the market for the first time lamp oils and grill lighter fluids, labelled with R65 or H304, shall by 1 December 2011, and annually thereafter, provide data on alternatives to lamp oils and grill lighter fluids labelled R65 or H304 to the competent authority in the Member State concerned. Member States shall make those data available to the Commission.'

REACH Regulation (EC) No 1907/2006 Annex XVII-55: 2-(2-butoxyethoxy)ethanol (DECBE) CAS No 112-34-5 EC No 203-961-6

1. Shall not be placed on the market for the first time after 27 June 2010, for supply to the general public, as a constituent of spray paints or spray cleaners in aerosol dispensers in concentrations equal to or greater than 3 * by weight. 2. Spray paints and spray cleaners in aerosol dispensers containing DEGUE and not confirming to paragraph 1 shall not be placed on the market for supply to the general public after 27 December 2010. 3. Without prejudice to other Community legislation concerning the classification, packaging and labelling of substances and mixtures, suppliers shall ensure before the placing on the market that paints other than spray paints containing DECIIE in concentrations equal to or greater than 3 % by weight of that are placed on the market for supply to the general public are visibly, legibly and indelibly marked by 27 December 2010 as follows: 'Do not use in paint spraying equipment' .

• Relevant phrases 11271 May cause fire or explosion; strong oxidiser. H302 Harmful if swallowed. 11314 Causes severe skin burns and eye damage. H319 Causes serious eye irritation. H332 Harmful if inhaled. H335 May cause respiratory irritation. H336 May cause drowsiness or dizziness.

R2022 Harmful by inhalation and if swallowed. 835 Causes severe burns.

(Contd. on page 9)

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Printing date 10.10.2012 Revision: 10.10.2012


(Contd. of page 8)

R36 Irritating to eyes. 85 Heating may cause an explosion. R8 Contact with combustible material may cause fire.

The contents and format of this MSDS/SDS are in accordance with REGULATION (EC) No 1272/2008, REGULATION (EC) No 1907/2006, Regulation (EU) No 453/2010 and EU C'ommission Directive 1999/45/ EC, 67/548/EEC'.

DISCLAIMER OF LIABILITY The information in this MSDS/SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS/SDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS/SDS information may not be applicable.

• Abbreviations and acronyms: ADR: Accord europeen sur le transport des merchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) 1MDG: International Maritime Code for Dangerous Goods 1ATA: International Air Transport Association GIIS: Globally Harmonized System of Classification and (Abetting of Chemicals !WE!.: Derived No-Effect Level (REACH) PNEC: Predicted No-Effect Concentration (REACH) LC'50: Lethal concentration, 50 percent U)50: Lethal dose, 50 percent

End of document

SGS - Big Fireworks · Sep.28. 2012 Oct.10. 2012 Sep.28•Oct.12, 2012 Safety Data ... results...

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