SECTION 6 - Sustainable Fort Rucker · Web view• Flammable/Combustible Warehouses or...

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SECTION 3 HAZARDOUS MATERIALS MANAGEMENT U.S. TEAM Guide, March 2009 A. Applicability This section primarily addresses the proper storage and handling of chemicals and the training, reporting, spill contingency, and response requirements related to hazardous materials. Oil and pesticides are hazardous materials that have additional regulatory requirements that are addressed in separate sections. Radioactive substances and the general category of hazardous wastes also are not included in this section. This section does not focus on individual hazardous chemicals or substances used but deals with the generic requirements and management practices (MP) associated with minimizing impacts on the environment due to spills or releases of hazardous materials because of improper storage and handling. Assessors are required to review state and local regulations and, if applicable, the appropriate Agency Supplement, to perform a comprehensive assessment. Select portions of this section (i.e., Review of Federal Legislation, State and Local Regulations, Key Compliance Requirements, Key Terms and Definitions, Typical Records to Review, Typical Physical Features to Inspect, and the Checklist) have been reviewed by USEPA personnel from the Office of Enforcement and Compliance Assurance (OECA) and USEPA's Office of General Counsel. USEPA's comments and suggestions for changes have been incorporated in this version of the TEAM Guide. USEPA did not review all portions of this section. USEPA also did not review and comment on items pertaining to federal Executive Orders, DOT regulations, OSHA regulations or any other area outside of Title 40 of the Code of Federal Regulations. Portions that have been added or revised as a result of this review are identified as either being reviewed, revised or added in March 2001, for example [Reviewed March 2001]. B. Federal Legislation The Occupational Safety and Health Act (OSHA). This act, last amended in November 1990, 29 U.S. Code (USC) 651-678, is a Federal statute that governs the issues related to occupational safety and health. The purpose and policy of this act are to assure every working man and woman in the nation safe and healthful working condition and to preserve our human resources by, among other things, providing for the development and publication of occupational safety and health standards, providing for an effective enforcement program, and providing for appropriate reporting procedures with respect to 3-1 Hazardous Materials

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SECTION 3

HAZARDOUS MATERIALS MANAGEMENT

U.S. TEAM Guide, March 2009

A. Applicability

This section primarily addresses the proper storage and handling of chemicals and the training, reporting, spill contingency, and response requirements related to hazardous materials. Oil and pesticides are hazardous materials that have additional regulatory requirements that are addressed in separate sections. Radioactive substances and the general category of hazardous wastes also are not included in this section. This section does not focus on individual hazardous chemicals or substances used but deals with the generic requirements and management practices (MP) associated with minimizing impacts on the environment due to spills or releases of hazardous materials because of improper storage and handling.

Assessors are required to review state and local regulations and, if applicable, the appropriate Agency Supplement, to perform a comprehensive assessment.

Select portions of this section (i.e., Review of Federal Legislation, State and Local Regulations, Key Compliance Requirements, Key Terms and Definitions, Typical Records to Review, Typical Physical Features to Inspect, and the Checklist) have been reviewed by USEPA personnel from the Office of Enforcement and Compliance Assurance (OECA) and USEPA's Office of General Counsel. USEPA's comments and suggestions for changes have been incorporated in this version of the TEAM Guide. USEPA did not review all portions of this section. USEPA also did not review and comment on items pertaining to federal Executive Orders, DOT regulations, OSHA regulations or any other area outside of Title 40 of the Code of Federal Regulations. Portions that have been added or revised as a result of this review are identified as either being reviewed, revised or added in March 2001, for example [Reviewed March 2001].

B. Federal Legislation

• The Occupational Safety and Health Act (OSHA). This act, last amended in November 1990, 29 U.S. Code (USC) 651-678, is a Federal statute that governs the issues related to occupational safety and health. The purpose and policy of this act are to assure every working man and woman in the nation safe and healthful working condition and to preserve our human resources by, among other things, providing for the development and publication of occupational safety and health standards, providing for an effective enforcement program, and providing for appropriate reporting procedures with respect to occupational safety and health which procedures will help achieve the objectives of this act and accurately describe the nature of the occupational safety and health (29 USC 651(b)(9)(10)(12)).

• The Hazardous Materials Transportation Act of 1975. This act, as last amended in November 1990, 49 USC 1801-1819, et al, is the federal legislation that governs the transportation of hazardous materials in the nation. The policy of Congress is to improve the regulatory and enforcement authority of the Secretary of Transportation to protect the nation adequately against the risks to life and property that are inherent in the transportation of hazardous materials in commerce (49 USC 1801).

• The Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA). CERCLA, known commonly as Superfund, became law in 1980 and authorizes USEPA to respond to releases or threatened releases of hazardous substances that may endanger public health, welfare, or the environment. The basic purpose of CERCLA is to provide funding and enforcement authority to USEPA for overseeing the clean up of environmental contamination caused by responsible parties. The Superfund Amendments and Reauthorization Act (SARA) of 1986 revised various sections of CERCLA, and created a free-standing law, SARA Title III, also known as the Emergency Planning and Community Right-to-Know Act (EPCRA). The CERCLA hazardous substance release reporting regulations (Section 103; 40 CFR Part 302) direct the person in charge of

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a facility to report to the National Response Center any environmental release of a listed hazardous substance that equals or exceeds a reportable quantity. Reportable quantities are listed in 40 CFR Section 302.4. A release report may trigger a response by USEPA or by one or more federal or state emergency response authorities [Revised March 2001].

• Emergency Planning and Community Right-to-Know Act of 1986 (EPCRA). This act, also known as SARA Title III, was designed to promote emergency planning and preparedness at both the state and local level. It provides citizens, local governments, and local response authorities with information regarding the potential hazards in their community. EPCRA requires the use of emergency planning and designates state and local governments as recipients of information regarding certain chemicals used in the community. EPCRA has four major components [Revised March 2001]:

Emergency planning (Sections 301-303) Emergency release notification (Section 304) Community right-to-know reporting (Sections 311-312) Toxic chemical release reporting (Section 313).

• Pollution Prevention Act of 1990 (PPA). The goals of PPA were the following: preventing or reducing pollution at the source whenever feasible; pollution that cannot be prevented should be recycled in an environmentally safe manner whenever feasible; pollution that cannot be prevented or recycled should be treated in an environmentally safe manner whenever feasible; and disposal or other release into the environment should be employed only as a last resort and conducted in an environmentally safe manner. Section 6607 of the PPA requires owners or operators of facilities who have to file an annual toxic chemical release form (Form R) under EPCRA Section 313 to include a toxic chemical source reduction and recycling report for the preceding calendar year that has been incorporated into the Form R [Added March 2001].

• The Oil Pollution Act of 1990. This law, Public Law (PL) 301-308 (33 USC 2701-2761, et al.), as amended, requires the prevention of oil pollution into navigable waters by tank vessels. This includes the preparation of a response plan, construction of oil carriers with double hulls, and inspection of spill response equipment.

• Executive Order (EO) 12088, Federal Compliance with Pollution Standards. This EO, dated 13 October 1978, requires Federally owned and operated facilities to comply with applicable Federal, state, and local pollution control standards. It makes the head of each executive agency responsible for seeing to it that the agencies, facilities, programs, and activities the agency funds meet applicable Federal, state, and local environmental requirements and for correcting situations that are not in compliance with such requirements. In addition, the EO requires that each agency ensure that sufficient funds for environmental compliance are included in the agency budget.

• Executive Order (EO) 13423, Strengthing Federal Environmental, Energy, and Transportation Management. This EO, dated 24 January 2007, requires Federal agencies to lead by example in advancing the nation’s energy security and environmental performance by achieving goals outlined in the EO. This EO revokes the following EOs [Added July 2007]:

1. Executive Order 13101, Greening the Government Through Waste Prevention, Recycling, and Federal Acquisition of September 14, 1998;

2. Executive Order 13123, Greening the Government Through Efficient Energy Management of June 3, 1999;

3. Executive Order 13134, Developing and Promoting Biobased Products and Bioenergy of August 12, 1999, as amended;

4. Executive Order 13148, Greening the Government through Leadership in Environmental Management of April 21, 2000; and

5. Executive Order 13149, Greening the Government Through Federal Fleet and Transportation Efficiency of April 21, 2000.

• The National Fire Code, Flammable and Combustible Liquids Code, NFPA 30. This code prohibits the storage of Class I and Class II liquids in plastic containers in general-purpose warehousing.

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C. State/Local Regulations

For information on regulations in specific states, see the State Supplements to TEAM Guide.

Hazardous materials may be regulated on the state level as well as local agencies (county/city fire departments) that may require flammable/combustible materials to meet certain storage requirements. Usually, these local ordinances will follow the National Fire Protection Association (NFPA), Fire Protection Guide on Hazardous Materials (Pamphlets 325A, 325M, 49, 491F and 704M).

D. Key Compliance Requirements

• Planning and Documentation - A master listing of hazardous materials storage sites should be maintained. When outside fire protection help is needed, the local fire department should be notified of the types of hazardous chemicals used, the areas where they are use, what they are used for, and the amount used. Material safety data sheet (MSDS) files are required for each hazardous chemical it stores and uses, not including such items as hazardous waste, tobacco, or drugs and cosmetics meant for personal use (29 CFR 1910.1200(b) and 1910.1200(g)).

• Personnel Training - All employees must be provided with written information about hazardous chemicals to which they are exposed. Personnel who work with hazardous materials are required to be trained in the use of and potential hazards of such materials. All employees and supervisors working on sites exposed to hazardous materials or other hazards are required to be trained before engaging in these activities (29 CFR 1910.1200).

• Emergency Response Plans - 40 CFR 355 establishes requirements for a facility to provide information necessary for developing and implementing State and local chemical emergency response plans, and requirements for emergency notification of chemical releases. 40 CFR 355 also lists Extremely Hazardous Substances (EHSs) and Threshold Planning Quantities (TPQs) in Appendices A and B, which are used in determining if a facility are subject to the requirements of 40 CFR 355 [Revised January 2009].

• Community Right-to-Know - 40 CFR 370 establishes reporting requirements for providing the public with important information on the hazardous chemicals in their communities. Reporting raises community awareness of chemical hazards and aids in the development of State and local emergency response plans. The reporting requirements established under this 40 CFR 370 consist of Material Safety Data Sheet (MSDS) reporting and inventory reporting [Revised March 2001, Revised January 2009].

• Toxic Chemical Release Reporting. Section 313 of EPCRA and Section 6607 of the PPA require certain facilities to report to the federal and state governments the annual quantity of toxic chemicals (listed in 40 CFR 372.65) entering each environmental medium, either through normal operations or as the result of an accident, quantities transferred offsite in waste, as well as other information. Facilities subject to this requirement must submit to USEPA and state officials a toxic chemical release form (Form R) for each toxic chemical manufactured, processed, or otherwise used in quantities exceeding minimum threshold values during the preceding calendar year. Facilities that have a “reportable waste quantity” of 500 lb of a listed toxic chemical may take advantage of an alternate threshold of one million pounds. If the facility does not manufacture, process or otherwise use more than one million pounds, it may certify by filing a Form A certification statement rather than a Form R. Releases that must be reported include those to air, water, and land (including land disposal and underground injection). In addition, discharges to a POTW and transfers to off-site locations for treatment, disposal, energy recovery, and recycling must also be reported. Facilities must also report on the quantities of the chemicals treated, recycled, or combusted for energy recovery onsite [Revised March 2001].

Form R/Form A reports must be submitted to both the USEPA and the state on or before July 1. Copies of Form R/Form A reports and related documentation must be kept at the facility for three years after the report is submitted.

The Pollution Prevention Act requires facilities subject to Form R/Form A reporting to also submit information on source reduction.

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• Hazardous Materials Storage - Containers for hazardous chemicals are required to be labeled or tagged with the identity of the substance and appropriate warning markings. Areas where hazardous materials are stored or used are required to be kept free from accumulations of materials that create a hazard, such as leaking containers, or a placement of containers in a manner that would create hazards such as tripping, fire, or pests. Substances that together may create a fire hazard must be separated (29 CFR 1910.176(c), 1910.1200(b), and 1910.1200(f)).

• Hazardous Materials in Laboratories - A chemical hygiene plan that is reviewed annually is required when hazardous chemicals are used in laboratories. Employees are required to be provided with information and training about the hazardous chemicals in their work areas. Records about the exposure of employees are to be kept along with medical records (29 CFR 1910.1450(e), 1910.1450(f), 1910.1450(h), and 1910.1450(j))).

• Storage of Flammable/Combustibles - In general, containers of flammable combustible liquids are to be stored and handled so not to damage the container or label, block exits, or create a fire hazard (29 CFR 1910.106(d)).

• Flammable Combustible Storage Cabinets - Storage cabinets are to be fire resistant and labeled FLAMMABLE - KEEP FIRE AWAY. No more than 60 gal of Class I or Class II liquids and no more than 120 gal of Class III liquids can be stored in a cabinet (29 CFR 1910.106(d)(3)).

• Flammable Combustible Storage Rooms - Storage rooms inside a building are to be fire resistant and have a raised sill or ramp to prevent the flow of spilled material from exiting the room. Ventilation and clear aisles must be provided, and dispensing must be done by an approved pump or self- closing faucet (29 CFR 1910.106(d)(4)).

• Flammable/Combustible Warehouses or Storage Buildings - These structures will have 3 ft wide aisles for access to doors, windows, or standpipe connections. Materials will be stacked using pallets or dunnage when needed for stabilization, and fire protection must be provided (29 CFR 1910.106(d)(5)(iv)).

• Outside Storage of Flammable Combustible Liquids - Containers of flammable/combustible liquids can be stored outside if no more than 1100 gal of liquid are stored adjacent to a building. More than 1100 gal can be stored if there are 10 ft or more between buildings and the nearest flammable container. The storage area must be graded to divert spills or surrounded by a curb (29 CFR 1910.106(d)(6)).

• Storage of Flammable/Combustibles in Industrial Areas - Specific guidelines, requirements, or operating standards apply wherever flammable/combustible materials are stored, dispensed, or used in industrial plants, are in incidental storage, or in use in unit operations. This includes availability of portable fire extinguishers, precautions being taken to prevent ignition, and use of maintenance and operating practices to control leakage and prevent accidental escape of flammable/combustible liquids (29 CFR 1910.106(e)(2) through 1910.106(e)(9)).

• Compressed Gases - Regardless of where the cylinders are stored, NO SMOKING signs should be posted and actions taken to prevent fire. Compressed gases are required to be stored according to the Compressed Gas Association Pamphlet P-1-1965 (29 CFR 1910.101).

• Acid Storage - Bulk storage of acids should be done in buildings that are one story in height with ventilation. Safety equipment and fire protection must be available. The building is labeled NO SMOKING and heated to prevent freezing (MP).

• Hazardous Materials Transportation - The regulations found in Title 49, Subchapter C of the CFR detail requirements for the transportation of hazardous materials, 49 CFR 171.1(b) stipulates that these requirements apply to any person who, under contract with any department, agency, or instrumentality of the executive, legislative, or judicial branch of the Federal Government, transports, or causes to be transported or shipped, a hazardous material or manufactures, fabricates, marks, maintains, reconditions, repairs, or tests a package or container which is represented, marked, certified, or sold by such person as qualified for use in the transportation of a hazardous material is required to comply with all provisions of the Federal hazardous materials transportation law, all orders and regulations issued thereunder, and all other substantive and

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procedural requirements of Federal, State, and local governments and Indian tribes (except any such requirements that have been preempted by the Federal hazardous materials transportation law or any other Federal law), in the same manner and to the same extent as any person engaged in such activities that are in or affect commerce is subject to such provisions, orders, regulations, and requirements [Revised July 2002].

E. Key Compliance Definitions

• Aerosol - a material which is dispensed from its container as a mist, spray, or foam by a propellant under pressure (29 CFR 1910.106(a)(1)).

• Approval - a written authorization, including a competent authority approval, from the Associate Administrator or other designated Department official, to perform a function for which prior authorization by the Associate Administrator is required under 49 CFR 171 through 180 (49 CFR 171.8) [Added April 2005].

• Approved - approval issued or recognized by the Department unless otherwise specifically indicated in 49 CFR

parts 171 through 180 (49 CFR 171.8) [Added April 2005].

• Approved - listed or approved by Underwriters Laboratories, Inc., Factory Mutual Engineering Corporation, The Bureau of Mines, National Institute of Occupational Safety and Health (NIOSH), The American National Standards Institute (ANSI), National Fire Protection Association (NFPA), or other nationally recognized agencies that list, approve, test, or develop specifications for equipment to meet fire protection, health or safety requirements (29 CFR 1910.106(a)(35)).

• Article - a manufactured item which (40 CFR 372.3) [Added March 2001]:1. is formed to a specific shape or design during manufacture;2. has end use functions dependent in whole or in part upon its shape or design during end use;3. does not release a toxic chemical under normal conditions of processing or use of that item at the

facility or establishments.

• Article - a manufactured item other than a fluid or particle (29 CFR 1910.1200(c)): 1. which is formed to a specific shape or design during manufacture; 2. which has end use function(s) dependent in whole or in part upon its shape or design during end use;

and 3. which under normal conditions of use does not release more than very small quantities, e.g., minute or

trace amounts of a hazardous chemical, and does not pose a physical hazard or health risk to employees.

• Barge - any nonself-propelled vessel (46 CFR 90.10-2).

• Barrel - a volume of 42 U.S. gallons (29 CFR 1910.106(a)(33)).

• Basement - a story of a building or structure having one-half or more of its height below ground level and to which access for fire fighting purposes is unduly restricted (29 CFR 1910.106(a)(4)).

• Boiling Point - the temperature at which a liquid starts to boil when at atmospheric pressure (14.7 psia), as determined by ASTM test D-86-72) (29 CFR 1910.106(a)(5)).

• Bulk Packaging - a packaging, other than a vessel or a barge, including a transport vehicle or freight container, in which hazardous materials are loaded with no intermediate form of containment and which has (49 CFR 171.8) [Added April 2005]:

1) A maximum capacity greater than 450 L (119 gal) as a receptacle for a liquid;2) A maximum net mass greater than 400 kg (882 lb) and a maximum capacity greater than 450 L (119 gal)

as a receptacle for a solid; or3) A water capacity greater than 454 kg (1000 lb) as a receptacle for a gas as defined in 49 CFR 173.115.

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• Bulk Plant - that portion of the property where flammable or combustible liquids are received by tank vessel, pipelines, tank car, or tank vehicle and are stored or blended in bulk for the purpose of distributing such liquids by tank vessel, pipeline, car, tank vehicle, or container (29 CFR 1910.106(a)(7)).

• Cargo - on tank vessels this means combustible liquid, flammable liquid, or liquefied flammable gas, unless otherwise stated (46 CFR 30.10-5).

• Cargo Areas - on tank vessels, the part of a vessel that includes the cargo tanks and other tanks into which cargo or cargo vapors are intentionally introduced; holds containing these tanks; all intervening spaces within, between, below, or outboard of these tanks or holds; and the deck areas over the length and beam of the vessel above these tanks, holds, or spaces (46 CFR 30.10-5a).

• Cargo Control Stations - on tank vessels means a location that is manned during cargo transfer operations for the purpose of directing or controlling the loading or unloading of cargo (46 CFR 30.10- 5b).

• Category A Machinery Space - for a tank vessel this means any space and trunks and ducts to such a space that contains (46 CFR 30.10-6a):

1. internal combustion machinery used for main propulsion2. internal combustion machinery used for purposes other than main propulsion where the total aggregate

power is at least 500 brake horsepower3. internal combustion machinery that uses a fuel with a flashpoint of less than 43.3 °C (110 °F), or4. one or more oil-fired boilers or oil-fuel units.

• CERCLA Hazardous Substance - a substance defined in section 101(14) of CERCLA and listed in Table 302.4 of 40 CFR 302) (40 CFR 355.61) [Added March 2001, Revised January 2009].

• Certificated - for tank vessels this applies to a vessel covered by a certificate of inspection issued by the Coast Guard; when applied to personnel employed on tank vessels, the term refers to a certificate of ability issued by the Cost Guard (46 CFR 30.10-7).

• Chemical - any element, chemical compound or mixture of elements and/or compounds (29 CFR 1910.1200(c)).

• Chemical Manufacturer - an employer with a workplace where chemical(s) are produced for use or distribution

(29 CFR 1910.1200(c)). • Chemical Name - the scientific designation of a chemical in accordance with the nomenclature system

developed by the International Union of Pure and Applied Chemistry (IUPAC) or the Chemical Abstracts Service (CAS) rules of nomenclature, or a name which will clearly identify the chemical for the purpose of conducting a hazard evaluation (29 CFR 1910.1200(c)).

• Closed Container - a container so sealed with a lid or other closing device that neither liquid and/or vapor will

escape from it at ordinary temperatures (29 CFR 1910.106(a)(9)).

• Coastwise - this includes all tank vessels and vessels normally navigating the waters of any ocean or the Gulf of Mexico at 20 nautical miles or less offshore (46 CFR 90.10-11).

• Cofferdam - a void or empty space separating two or more compartments for the purpose of isolation or to prevent the contents of one compartment from entering another compartment in the event of the failure of the walls of one to retain their tightness (46 CFR 30.10-13).

• Combustible Liquid - for tank vessels this means any liquid having a flashpoint above 80 °F and include (46 CFR 30.10-15):

1. Grade D, which is any combustible liquid with a flashpoint below 150 °F and above 80 °F2. Grade E, which is any combustible liquid with a flashpoint of 150°F or above.

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• Combustible Liquid - a liquid having a flashpoint at or above 100 °F (37.8 °C). Combustible liquids are categorized as Class II or Class III liquids and are further subdivided as follows (29 CFR 1910.106(a)(18)):

1. Class II liquids are those having a flashpoint at or above 100 °F (37.8 °C) and below 140 °F (60 °C), except any mixture having components with flashpoints of 200 °F (93.3 °C) or higher, the volume of which makes up 99 percent or more of the total volume of the mixture.

2. Class IIIA liquids are those having flashpoints at or above 140 °F (60 °C) and below 200 °F (93.3 °C), except any mixture having components with flashpoints of 200 °F (93.3 °C) or higher, the total volume of which make up 99 percent or more of the total volume of the mixture.

3. Class IIIB liquids are those having flashpoints at or above 200 °F (93.3 °C).

• Combustible Liquid - any liquid having a flashpoint at or above 100 °F (37.8 °C), but below 200 °F (93.3 °C), except any mixture having components with flashpoints of 200 °F (93.3 °C), or higher, the total volume of which make up 99 percent or more of the total volume of the mixture (29 CFR 1910.1200(c)).

• Commerce - trade or transportation in the jurisdiction of the United States within a single state; between a place

in a state and a place outside of the state; or that affects trade or transportation between a place in a state and place outside of the state (49 CFR 171.8) [Added April 2005].

• Common Name - any designation or identification such as code name, code number, trade name, brand name or generic name used to identify a chemical other than by its chemical name (29 CFR 1910.1200(c)).

• Compressed Gas -(29 CFR 1910.1200(c))

1. A gas or mixture of gases having, in a container, an absolute pressure exceeding 40 psi at 70 °F (21.1 °C); or

2. A gas or mixture of gases having, in a container, an absolute pressure exceeding 104 psi at 130 °F (54.4 °C) regardless of the pressure at 70 °F (21.1 °C); or

3. A liquid having a vapor pressure exceeding 40 psi at 100 °F (37.8 °C) as determined by ASTM D-323-72.

• Consignee - the person or place shown on a shipping document, package marking, or other media as the

location to which a carrier is directed to transport a hazardous material (49 CFR 171.8) [Added April 2005].

• Consumer Commodity - a material that is packaged and distributed in a form intended or suitable for sale through retail sales agencies or instrumentalities for consumption by individuals for purposes of personal care or household use. This term also includes drugs and medicines (49 CFR 171.8) [Added April 2005].

• Container - any bag, barrel, bottle, box, can, cylinder, drum, reaction vessel, storage tank, or the like that contains a hazardous chemical. For purposes of this section, pipes or piping systems, and engines, fuel tanks, or other operating systems in a vehicle, are not considered to be containers (29 CFR 1910.1200(c)).

• Continuous - continuous release is a release that occurs without interruption or abatement or that is routine,

anticipated, and intermittent and incidental to normal operations or treatment processes (40 CFR 302.8(b)) [Added April 1999; Reviewed March 2001].

• Control Space - an enclosed space in which is located a ship’s radio, main navigating equipment, or emergency source of power, or in which is located centralized fire recording or fire control equipment, but not including firefighting apparatus that must be located in the cargo area or individual pieces of firefighting equipment (46 CFR 30.10-19a).

• Designated Facility - a hazardous waste treatment, storage, or disposal facility that has been designated on the manifest by the generator (49 CFR 171.8) [Added April 2005].

• Designated Representative - any individual or organization to whom an employee gives written authorization to exercise such employee's rights under this section. A recognized or certified collective bargaining agent shall be treated automatically as a designated representative without regard to written employee authorization (29 CFR 1910.1200(c)).

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• Director - the Director, National Institute for Occupational Safety and Health, U.S. Department of Health and

Human Services, or designee (29 CFR 1910.1200(c)). • Discharge - any release, however caused, from a ship and includes any escape, disposal, spilling, leaking,

pumping, emitting, or emptying (33 CFR 151.05).

• Distributor - a business, other than a chemical manufacturer or importer, which supplies hazardous chemicals to other distributors or to employers (29 CFR 1910.1200(c)).

• Division 6.2 (Infectious Substance) - a material known or reasonably expected to contain a pathogen. A pathogen is a microorganism (including bacteria, viruses, rickettsiae, parasites, fungi) or other agent, such as a proteinaceous infectious particle (prion) that can cause disease in humans or animals. An infectious substance must be assigned the identification number UN 2814, UN 2900, UN 3373, or UN 3291 as appropriate, and must be assigned to one of the following categories (49 CFR 173.134(a)(1)) [Added July 2006]:

1. Category A: An infectious substance in a form capable of causing permanent disability or life-threatening or fatal disease in otherwise healthy humans or animals when exposure to it occurs. An exposure occurs when an infectious substance is released outside of its protective packaging, resulting in physical contact with humans or animals. A Category A infectious substance must be assigned to identification number UN 2814 or UN 2900, as appropriate. Assignment to UN 2814 or UN 2900 must be based on the known medical history or symptoms of the source patient or animal, endemic local conditions, or professional judgment concerning the individual circumstances of the source human or animal.

2. Category B: An infectious substance that is not in a form generally capable of causing permanent disability or life-threatening or fatal disease in otherwise healthy humans or animals when exposure to it occurs. This includes Category B infectious substances transported for diagnostic or investigational purposes. A Category B infectious substance must be described as “Biological substance, Category B” and assigned identification number UN 3373. This does not include regulated medical waste, which must be assigned identification number UN 3291.

• Domestic Wastes - all types of wastes generated in the living spaces on board a ship except victual wastes (33 CFR 151.05).

• Drums, Barrels, or Other Packages - this is interpreted to mean portable tanks having a maximum capacity of 110 gal and Department of Transportation (DOT) specification cylinders having a water capacity of not more than 1000 lb that are actually loaded and discharged from vessels with their content intact (46 CFR 30.01-20(a) and 90.05-30).

• Employee - a worker who may be exposed to hazardous chemicals under normal operating conditions or in foreseeable emergencies. Workers such as office workers or bank tellers who encounter hazardous chemicals only in non-routine, isolated instances are not covered (29 CFR 1910.1200(c)).

• Employer - a person engaged in a business where chemicals are either used, distributed, or are produced for use

or distribution, including a contractor or subcontractor (29 CFR 1910.1200(c)). • Environment - includes water, air, and land and the interrelationship that exists among and between water, air,

and land and all living things (40 CFR 355.61 and 370.66) [Added January 2009].

• Explosive - a chemical that causes a sudden, almost instantaneous release of pressure, gas, and heat when subjected to sudden shock, pressure, or high temperature (29 CFR 1910.1200(c)).

• Exposure or Exposed - that an employee is subjected in the course of employment to a chemical that is a

physical or health hazard, and includes potential (e.g. accidental or possible) exposure. “Subjected” in terms of health hazards includes any route of entry (e.g. inhalation, ingestion, skin contact or absorption.) (29 CFR 1910.1200(c)).

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• Extremely Hazardous Substance - all substances listed in Appendices A and B of 40 CFR 355 (see the column titled Extremely Hazardous Substances in Appendix 3-1) (40 CFR 355.61 and 370.66) [Reviewed March 2001, Citation Revised January 2009].

• Facility - all buildings, equipment, structures, and other stationary items that are located on a single site or on contiguous or adjacent sites and that are owned or operated by the same person (or by any person that controls, is controlled by, or under common control with, such person). Facility includes manmade structures, as well as all natural structures in which chemicals are purposefully placed or removed through human means such that it functions as a containment structure for human use (40 CFR 370.66) [Added March 2001, Revised January 2009].

• Facility - all buildings, equipment, structures, and other stationary items that are located on a single site or on contiguous or adjacent sites and that are owned or operated by the same person (or by any person that controls, is controlled by, or under common control with, such person). Facility includes manmade structures, as well as all natural structures in which chemicals are purposefully placed or removed through human means such that it functions as a containment structure for human use. For purposes of emergency release notification, the term includes motor vehicles, rolling stock, and aircraft (40 CFR 355.61) [Added January 2009].

• Facility - all buildings, equipment, structures, and other stationary items which are located on a single site or on contiguous or adjacent sites and which are owned or operated by the same person (or by any person which controls, is controlled by, or under common control with such person). A facility may contain more than one establishment (40 CFR 372.3) [Added March 2001].

• Fire Area - that portion of a building separated from the remainder by construction having a rated fire resistance of at least 1 h and having all communicating openings properly protected by an assembly having a fire-resistance rating of at least 1 h (29 CFR 1910.106(a)(12)).

• Flammable -a chemical that falls into one of the following categories (29 CFR 1910.1200(c)):1. Aerosol, flammable means an aerosol that, when tested by the method described in 16 CFR 1500.45,

yields a flame projection exceeding 18 in at full valve opening, or a flashback (a flame extending back to the valve) at any degree of valve opening;

2. Gas, flammable means: a. A gas that, at ambient temperature and pressure, forms a flammable mixture with air at a

concentration of thirteen (13) percent by volume or less; orb. A gas that, at ambient temperature and pressure, forms a range of flammable mixtures with air

wider than twelve (12) percent by volume, regardless of the lower limit;3. Liquid, flammable means any liquid having a flashpoint below 100 °F (37.8 °C), except any mixture

having components with flashpoints of 100 °F (37.8 °C) or higher, the total of which make up 99 percent or more of the total volume of the mixture.

4. Solid, flammable means a solid, other than a blasting agent or explosive as defined in 29 CFR 1910.109(a), that is liable to cause fire through friction, absorption of moisture, spontaneous chemical change, or retained heat from manufacturing or processing, or which can be ignited readily and when ignited burns so vigorously and persistently as to create a serious hazard. A chemical shall be considered to be a flammable solid if, when tested by the method described in 16 CFR 1500.44, it ignites and burns with a self-sustained flame at a rate greater than one-tenth of an inch per second along its major axis.

• Flammable Aerosol - an aerosol that is required to be labeled FLAMMABLE under the Federal Hazardous Substance Labeling Act (15 USC 1261). These aerosols are considered Class IA liquids (29 CFR 1910.106(a)(19)).

• Flammable Liquid - a liquid with a flashpoint below 100 F (37.8 C), except any mixture having components with flashpoints of 100 F (37.8 C) or higher, the total of which make up 99 percent or more of the total volume of the mixture. Flammable liquids are categorized as Class I liquids, and are further subdivided as follows (29 CFR 1910.106(a)(19)):

1. Class IA are those that have a flashpoint below 73 F (22.8 C) and boiling point below 100 F (37.8 C).

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2. Class IB are those that have flashpoints below 73 F (22.8 C) and boiling points at or above 100 F (37.8 C).

3. Class IC are those that have flashpoints at or above 73 °F (22.8 C) and below 100 °F (37.8 C).

• Flammable Liquid - any liquid that gives off flammable vapors at or below a temperature of 80 °F (46 CFR 30.10-22).

• Flame Arrester - any device or assembly of a cellular, tubular, pressure, or other type used for preventing the passage of flames into an enclosed space (46 CFR 30.10-23).

• Flashpoint - the minimum temperature at which a liquid gives off vapor in sufficient concentration to form an ignitable mixture with air near the surface of the liquid. Flashpoints are established using several standard, closed-cup test methods (29 CFR 1910.106(a)(14)).

• Flashpoint - the minimum temperature at which a liquid gives off a vapor in sufficient concentration to ignite when tested as follows (29 CFR 1910.1200(c)):

1. Tagliabue Closed Tester (See American National Standard Method of Test for Flash Point by Tag Closed Tester, Z11.24-1979 (ASTM D 56-79)) for liquids with a viscosity of less than 45 Saybolt Universal Seconds (SUS) at 100 °F (37.8 °C), that do not contain suspended solids and do not have a tendency to form a surface film under test; or

2. Pensky-Martens Closed Tester (see American National Standard Method of Test for Flash Point by Pensky-Martens Closed Tester, Z11.7-1979 (ASTM D 93-79)) for liquids with a viscosity equal to or greater than 45 SUS at 100 °F (37.8 °C), or that contain suspended solids, or that have a tendency to form a surface film under test; or

3. Setaflash Closed Tester (see American National Standard Method of Test for Flash Point by Setaflash Closed Tester (ASTM D 3278-78)).

Organic peroxides, which undergo autoaccelerating thermal decomposition, are excluded from any of the flashpoint determination methods specified above.

• Foreseeable Emergency - any potential occurrence such as, but not limited to, equipment failure, rupture of containers, or failure of control equipment which could result in an uncontrolled release of a hazardous chemical into the workplace (29 CFR 1910.1200(c)).

• Fuel Tank - a tank other than a cargo tank, used to transport flammable or combustible liquid, or compressed

gas for the purpose of supplying fuel for propulsion of the transport vehicle to which it is attached, or for the operation of other equipment on the transport vehicle (49 CFR 171.8) [Added April 2005].

• Hazard Category - any of the following (40 CFR 370.66) [Added April 1999; Reviewed March 2001; Citation Revised January 2009]:

1. immediate (acute) health hazard, including highly toxic, toxic, irritant, sensitizer, corrosive, (as defined under 29 CFR 1910.1200) and other hazardous chemicals that cause an adverse effect to a target organ and which effect usually occurs rapidly as a result of short term exposure and is of short duration

2. delayed (chronic) health hazard, including carcinogens (as defined under 29 CFR 1910.1200) and other hazardous chemicals that cause an adverse effect to a target organ and which effect generally occurs as a result of long term exposure and is of long duration

3. fire hazard, including flammable, combustible liquid, pyrophoric, and oxidizer (as defined under 29 CFR 1910.1200)

4. sudden release of pressure, including explosive and compressed gas (as defined under 29 CFR 1910.1200)

5. reactive, including unstable reactive, organic peroxide, and water reactive (as defined under 29 CFR 1910.1200).

• Hazard Class - the category of hazard assigned to a hazardous material under the definitional criteria of 49 CFR

173 and the provisions of the 49 CFR 172.101 table. A material may meet the defining criteria for more than one hazard class but is assigned to only one hazard class (49 CFR 171.8) [Added April 2005].

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• Hazard Warning - any words, pictures, symbols, or combination thereof appearing on a label or other appropriate form of warning which convey the specific physical and health hazard(s), including target organ effects, of the chemical(s) in the container(s). (See the definitions for “physical hazard” and “health hazard” to determine the hazards which must be covered.) (29 CFR 1910.1200(c)),

• Hazardous Chemical - in relationship to laboratories, a chemical for which there is statistically significant evidence based on at least one study conducted in accordance with established scientific principles that acute or chronic health effects may occur in exposed employees (29 CFR 1910.1450(b)).

• Hazardous Chemical - any chemical which is a physical hazard or a health hazard (29 CFR 1910.1200(c)). • Hazardous Chemical - any hazardous chemical as defined under 29 CFR 1910.1200(c), except that this term

does not include (40 CFR 355.61 and 370.66) [Added March 2001; Revised January 2009]:1. Any food, food additive, color additive, drug, or cosmetic regulated by the Food and Drug

Administration.2. Any substance present as a solid in any manufactured item to the extent exposure to the substance does

not occur under normal conditions of use.3. Any substance to the extent it is used:

a. For personal, family, or household purposes, or is present in the same form and concentration as a product packaged for distribution and use by the general public. Present in the same form and concentration as a product packaged for distribution and use by the general public means a substance packaged in a similar manner and present in the same concentration as the substance when packaged for use by the general public, whether or not it is intended for distribution to the general public or used for the same purpose as when it is packaged for use by the general public;

b. In a research laboratory or hospital or other medical facility under the direct supervision of a technically qualified individual; or

c. In routine agricultural operations or is a fertilizer held for sale by a retailer to the ultimate customer.

• Hazardous Material - a substance or material that the Secretary of Transportation has determined is capable of posing an unreasonable risk to health, safety, and property when transported in commerce, and has designated as hazardous under section 5103 of Federal hazardous materials transportation law (49 U.S.C. 5103). The term includes hazardous substances, hazardous wastes, marine pollutants, elevated temperature materials, materials designated as hazardous in the Hazardous Materials Table (see 49 CFR 172.101), and materials that meet the defining criteria for hazard classes and divisions in 49 CFR 173 (49 CFR 171.8) [Added April 2005].

• Hazardous Substance - any substance designated pursuant to 40 CFR 302 [see the column titled Hazardous Substance RQ in Appendix 3-1] (40 CFR 302.3) [Reviewed March 2001].

• Hazardous Substance - for the purposes of this subchapter, means a material, including its mixtures and solutions, that (49 CFR 171.8) [Added April 2005]:

1) Is listed in the appendix A to 49 CFR 172.101 of this subchapter;2) Is in a quantity, in one package, which equals or exceeds the reportable quantity (RQ) listed in the

appendix A to 49 CFR 172.101 of this subchapter; and3) When in a mixture or solution--

a. For radionuclides, conforms to paragraph 7 of the appendix A to 49 CFR 172.101.b. For other than radionuclides, is in a concentration by weight which equals or exceeds the

concentration corresponding to the RQ of the material, as shown in the following table:

RQ pounds (kg) Concentration by weightPercent PPM

5000 (2270)_ 10 10,0001000 (454) 2 20,000100 (45.4) 0.2 2,00010 (4.54) 0.02 2001 (0.454) 0.002 20

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The term does not include petroleum, including crude oil or any fraction thereof which is not otherwise specifically listed or designated as a hazardous substance in appendix A to 49 CFR 172.101 of this subchapter, and the term does not include natural gas, natural gas liquids, liquefied natural gas, or synthetic gas usable for fuel (or mixtures of natural gas and such synthetic gas).

• Hazmat - a hazardous material (49 CFR 171.8) [Added April 2005].

• Hazmat Employee – this term means (49 CFR 171.8) [Added April 2005; Revised January 2006]:1. A person who is:

a. Employed on a full-time, part time, or temporary basis by a hazmat employer and who in the course of such full time, part time or temporary employment directly affects hazardous materials transportation safety;

b. Self-employed (including an owner-operator of a motor vehicle, vessel, or aircraft) transporting hazardous materials in commerce who in the course of such self-employment directly affects hazardous materials transportation safety;

c. A railroad signalman; ord. A railroad maintenance-of-way employee.

2. This term includes an individual, employed on a full time, part time, or temporary basis by a hazmat employer, or who is self-employed, who during the course of employment:a. Loads, unloads, or handles hazardous materials;b. Designs, manufactures, fabricates, inspects, marks, maintains, reconditions, repairs, or tests a

package, container or packaging component that is represented, marked, certified, or sold as qualified for use in transporting hazardous material in commerce.

c. Prepares hazardous materials for transportation;d. Is responsible for safety of transporting hazardous materials;e. Operates a vehicle used to transport hazardous materials.

• Hazmat Employer – this term means (49 CFR 171.8) [Added January 2006]:

1. A person who employs or uses at least one hazmat employee on a full-time, part time, or temporary basis; and who:a. Transports hazardous materials in commerce;b. Causes hazardous materials to be transported in commerce; orc. Designs, manufactures, fabricates, inspects, marks, maintains, reconditions, repairs or tests a

package, container, or packaging component that is represented, marked, certified, or sold by that person as qualified for use in transporting hazardous materials in commerce;

2. A person who is self-employed (including an owner-operator of a motor vehicle, vessel, or aircraft) transporting materials in commerce; and who:a. Transports hazardous materials in commerce;b. Causes hazardous materials to be transported in commerce; orc. Designs, manufactures, fabricates, inspects, marks, maintains, reconditions, repairs or tests a

package, container, or packaging component that is represented, marked, certified, or sold by that person as qualified for use in transporting hazardous materials in commerce; or

3. A department, agency, or instrumentality of the United States Government, or an authority of a State, political subdivision of a State, or an Indian tribe; and who:a. Transports hazardous materials in commerce;b. Causes hazardous materials to be transported in commerce; orc. Designs, manufactures, fabricates, inspects, marks, maintains, reconditions, repairs or tests a

package, container, or packaging component that is represented, marked, certified, or sold by that person as qualified for use in transporting hazardous materials in commerce.

• Health Hazard - a chemical for which there is statistically significant evidence based on at least one study

conducted in accordance with established scientific principles that acute or chronic health effects may occur in exposed employees. The term ``health hazard'' includes chemicals which are carcinogens, toxic or highly toxic agents, reproductive toxins, irritants, corrosives, sensitizers, hepatotoxins, nephrotoxins, neurotoxins, agents which act on the hematopoietic system, and agents which damage the lungs, skin, eyes, or mucous membranes.

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Appendix A provides further definitions and explanations of the scope of health hazards covered by this section, and Appendix B describes the criteria to be used to determine whether or not a chemical is to be considered hazardous for purposes of this standard (29 CFR 1910.1200(c)).

• HMR - the Hazardous Materials Regulations, Parts 171 through 180 of Title 49 (49 CFR 171.8) [Added April

2005].

• Identity - any chemical or common name which is indicated on the material safety data sheet (MSDS) for the chemical. The identity used shall permit cross-references to be made among the required list of hazardous chemicals, the label and the MSDS (29 CFR 1910.1200(c)).

• Immediate Use - that the hazardous chemical will be under the control of and used only by the person who

transfers it from a labeled container and only within the work shift in which it is transferred (29 CFR 1910.1200(c)).

• IM 101 or 102 Portable Tank - a portable tank constructed in accordance with 49 CFR 178.270 through

178.272 and approved under 73.32a (46 CFR 98.30-2(a)).

• Indian Country - Indian country defined in 18 U.S.C. 1151 as (40 CFR 355.61 and 370.66) [Added January 2009]:

1. All land within the limits of any Indian reservation under the jurisdiction of the United States government, notwithstanding the issuance of any patent, and, including rights-of-way running through the reservation;

2. All dependent Indian communities within the borders of the United States whether within the original or subsequently acquired territory thereof, and whether within or without the limits of a State; and

3. All Indian allotments, the Indian titles to which have not been extinguished, including rights-of-way running through the same.

• Indian Tribe or Tribe - those Tribes federally recognized by the Secretary of the Interior (40 CFR 355.61 and

370.66) [Added January 2009].

• Industrial Vessel - every vessel which, by reason of its special outfit, purpose, and design for function, engages in certain industrial ventures. Included in this classification are such vessels as drill rigs, missile range ships, dredges, cable layers, derrick barges, pipe lay barges, and construction and wrecking barges.

• Inflammable or Combustible Liquid Cargo in Bulk - this is interpreted on tank vessels to include such cargo in portable tanks of a capacity more than 110 gal (46 CFR 30.01-20(b)).

• Institutional Occupancy - the occupancy or use of a building or structure or any portion thereof by persons harbored or detained to receive medical, charitable or other care or treatment or by persons involuntarily detained (29 CFR 1910.106(a)(16)).

• Inventory Form - the uniform Tier I and Tier II emergency and hazardous chemical inventory forms published by EPA. These forms can be used for reporting inventory information, as described in 40 CFR 370.40 through 370.45 (40 CFR 370.66) [Added April 1999; Reviewed March 2001; Revised January 2009].

• Keel Laying Date - the date upon which progressive construction identifiable with a specific vessel begins,

including construction of the first module or prefabricated section of the hull that is identifiable with that vessel (46 CFR 30.10-37).

• LEPC - the Local Emergency Planning Committee appointed by the State Emergency Response Commission (40 CFR 355.61) [Added January 2009].

• Label - any written, printed, or graphic material displayed on or affixed to containers of hazardous chemicals (29 CFR 1910.1200(c)).

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• Laboratory - a facility where the laboratory use of hazardous chemicals occurs. It is a workplace where relatively small quantities of hazardous chemicals are used on a nonproduction basis (29 CFR 1910.1450(b)).

• Laboratory Scale - work with substances in which the containers used for reactions, transfers, and other handling of substances are designed to be easily and safely manipulated by one person (29 CFR 1910.1450(b)).

• Laboratory Use of a Hazardous Chemical - handling or use of such chemicals in which all of the following conditions are met (29 CFR 1910.1450(b)):

1. chemical manipulations are carried out on a laboratory scale 2. multiple chemical procedures or chemicals are used 3. the procedures involved are not part of a production process, nor in any way simulate a production

process 4. protective laboratory practices and equipment are available and in common use to minimize the

potential for employee exposure to hazardous chemicals.

• Lightweight - the displacement of a vessel in metric tons without cargo, oil fuel, lubricating oil, ballast water, fresh water, feedwater in tanks, consumable stores, and persons and their effects (46 CFR 30.10-38).

• Liquefied Flammable Gas - any flammable gas having a Reid vapor pressure exceeding 40 lb, which has been liquefied (46 CFR 30.10-39).

• Liquid - any material with a fluidity greater than that of 300 penetration asphalt when tested in accordance with ASTM Test D-5-73. When not otherwise identified, the term liquid will include both flammable and combustible liquid (29 CFR 1910.106(a)(17)).

• Liquid - a material, other than an elevated temperature material, with a melting point or initial melting point of 20 °C (68 °F) or lower at a standard pressure of 101.3 kPa (14.7 psia). A viscous material for which a specific melting point cannot be determined must be subjected to the procedures specified in ASTM D 4359 “Standard Test Method for Determining Whether a Material is Liquid or Solid” (IBR, see 49 CFR 171.7).

• Loading Incidental to Movement - loading by carrier personnel or in the presence of carrier personnel of packaged or containerized hazardous material onto a transport vehicle, aircraft, or vessel for the purpose of transporting it, including the loading, blocking and bracing a hazardous materials package in a freight container or transport vehicle, and segregating a hazardous materials package in a freight container or transport vehicle from incompatible cargo. For a bulk packaging, loading incidental to movement means filling the packaging with a hazardous material for the purpose of transporting it. Loading incidental to movement includes transloading (49 CFR 171.8) [Added April 2005].

• Machinery Space - any space that contains machinery and related equipment including Category A machinery spaces, propelling machinery, boilers, oil fuel units, steam and internal combustion engines, generators and centralized electrical machinery, oil filling stations, refrigeration stabilizing, ventilation, and air-conditioning machinery, and similar spaces and trunks to such spaces (46 CFR 30.10-42).

• Management Practice (MP) - practices that, although not mandated by law, are encouraged to promote safe operating procedures.

• Manufacture - to produce, prepare, import, or compound a toxic chemical. Manufacture also includes coincidental production of a toxic chemical during the manufacture, processing, use, or treatment of another chemical or mixture of chemicals, including a toxic chemical that is separated from that other chemical or mixture of chemicals as a byproduct, and a toxic chemical that remains in that other chemical or mixture as an impurity (>0.1% for carcinogens; otherwise >1%) (40 CFR 372.3) [Added March 2001].

• Marine Pollutant - a material which is listed in appendix B to 49 CFR 172.101 (also see 49 CFR 171.4) and, when in a solution or mixture of one or more marine pollutants, is packaged in a concentration which equals or exceeds (49 CFR 171.8) [Added April 2005]:

1) Ten percent by weight of the solution or mixture for materials listed in the appendix; or

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2) One percent by weight of the solution or mixture for materials that are identified as severe marine pollutants in the appendix.

• Marine Portable Tank (MPT) - a liquid-carrying tank that has a capacity of 110 gal or more, is designed to be

carried on a vessel, can be lifted full or empty onto and off a vessel, can be filled and discharged while on a vessel, is not permanently attached to the vessel, and was inspected by the Coast Guard on or before 30 September 1992 (46 CFR 64.5).

• Marking - a descriptive name, identification number, instructions, cautions, weight, specification, or UN marks, or combinations thereof, required by 49 CFR 171 on outer packagings of hazardous materials (49 CFR 171.8) [Added April 2005].

• Material Safety Data Sheet (MSDS) - written or printed material that contains information on hazardous chemicals such as common name, physical hazards, or health hazards (29 CFR 1910.1200(c)).

• Medium or Media - the environment (i.e., air, water, land) (40 CFR 355.61) [Added January 2009].

• Mixture - any combination of two or more chemicals if the combination is not, in whole or in part, the result of a chemical reaction (29 CFR 1910.1200(c) and 40 CFR 370.66).

• Mixture (EPCRA 311, 312, and 313) - any combination of two or more chemicals, if the combination is not, in

whole or in part, the result of a chemical reaction. However, if the combination was produced by a chemical reaction but could have been produced without a chemical reaction, it is also treated as a mixture. A mixture also includes any combination that consists of a chemical and associated impurities (40 CFR 372.3) [Added March 2001].

• Mixture - for the purposes of 40 CFR 355, a heterogeneous association of substances where the various individual substances retain their identities and can usually be separated by mechanical means. This definition includes, for the purposes of 40 CFR 355, solutions but does not include alloys or amalgams (40 CFR 355.61) [Added April 1999; Reviewed March 2001, Revised January 2009].

• Motor Vehicle - includes a vehicle, machine, tractor, trailer, or semitrailer, or any combination thereof, propelled or drawn by mechanical power and used upon the highways in the transportation of passengers or property. It does not include a vehicle, locomotive, or car operated exclusively on a rail or rails, or a trolley bus operated by electric power derived from a fixed overhead wire, furnishing local passenger transportation similar to street-railway service (49 CFR 171.8) [Added April 2005].

• Movement - the physical transfer of a hazardous material from one geographic location to another by rail car, aircraft, motor vehicle, or vessel (49 CFR 171.8) [Added April 2005].

• New Ship - a ship (33 CFR 151.05):

1. for which the building contract is placed after 31 December 19752. in the absence of a building contract, the keel of which is laid or which is at a similar stage of

construction after 30 June 19763. the delivery of which is after 31 December 19794. that has undergone a major conversion:

a. for which the contract is placed after 31 December 1979b. in the absence of a contract, the construction work of which is begun after 30 June 1975c. that is completed after 31 December 1979.

• Normal Range - the normal range of a release is all releases (in pounds or kilograms) of a hazardous substance reported or occurring over any 24-hour period under normal operating conditions during the preceding year. Only releases that are both continuous and stable in quantity and rate may be included in the normal range (40 CFR 302.8(b)) [Added April 1999; Reviewed March 2001].

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• Office Occupancy - the occupancy or use of a building or structure, or any portion thereof, for the transaction of business, or the rendering or receiving of professional services (29 CFR 1910.106(a)(24)).

• Organic Peroxide - an organic compound that contains the bivalent -O-O-structure and which may be considered to be a structural derivative of hydrogen peroxide where one or both of the hydrogen atoms has been replaced by an organic radical (29 CFR 1910.1200(c)).

• Otherwise Use - any use of a toxic chemical that is not covered by the terms “manufacture” or “process” and includes use of a toxic chemical contained in a mixture, trade name product or waste. Otherwise use of a toxic chemical does not include disposal, stabilization (without subsequent distribution in commerce), or treatment for destruction unless (40 CFR 372.3) [Added March 2001]:

1. the toxic chemical that was disposed, stabilized, or treated for destruction was received from off-site for the purposes of further waste management; or

2. the toxic chemical that was disposed, stabilized, or treated for destruction was manufactured as a result of waste management activities on materials received from off-site for the purposes of further waste management activities. Relabeling or redistributing of the toxic chemical where no repackaging of the toxic chemical occurs does not constitute otherwise use or processing of the toxic chemical.

• Oxidizer - a chemical other than a blasting agent or explosive as defined in 29 CFR 1910.109(a), that initiates or promotes combustion in other materials, thereby causing fire either of itself or through the release of oxygen or other gases (29 CFR 1910.1200(c)).

• Person - an individual, corporation, company, association, firm, partnership, society, joint stock company; or a

government, Indian tribe, or authority of a government or tribe offering a hazardous material for transportation in commerce or transporting a hazardous material to support a commercial enterprise. This term does not include the United States Postal Service or, for purposes of 49 U.S.C. 5123 and 5124, a Department, agency, or instrumentality of the government (49 CFR 171.8) [Added April 2005].

• Person - any individual, trust, firm, joint stock company, corporation (including a government corporation),

partnership, association, State, municipality, commission, political subdivision of a State, or interstate body (40 CFR 355.61 and 370.66) [Added January 2009].

• Person Who Offers or Offeror - any person who does either or both of the following (49 CFR 171.8) [Added October 2005]:

1. Performs, or is responsible for performing, any pre-transportation function required under this subchapter for transportation of the hazardous material in commerce.

2. Tenders or makes the hazardous material available to a carrier for transportation in commerce.A carrier is not an offeror when it performs a function required by this subchapter as a condition of acceptance of a hazardous material for transportation in commerce (e.g., reviewing shipping papers, examining packages to ensure that they are in conformance with this subchapter, or preparing shipping documentation for its own use) or when it transfers a hazardous material to another carrier for continued transportation in commerce without performing a pre-transportation function.

• Physical Hazard - a chemical for which there is scientifically valid evidence that it is a combustible liquid, a compressed gas, explosive, flammable, an organic peroxide, an oxidizer, pyrophoric, unstable (reactive) or water-reactive (29 CFR 1910.1200(c)).

• Portable Tank - see definitions for IM 101 Portable Tank, IM 102 Portable Tank, and Marine Portable Tank.

• Pre-transportation Function - a function specified in the HMR that is required to assure the safe transportation of a hazardous material in commerce, including (49 CFR 171.8) [Revised July 2005]:

1. Determining the hazard class of a hazardous material.2. Selecting a hazardous materials packaging.3. Filling a hazardous materials packaging, including a bulk packaging.4. Securing a closure on a filled or partially filled hazardous materials package or container or on a

package or container containing a residue of a hazardous material.

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5. Marking a package to indicate that it contains a hazardous material.6. Labeling a package to indicate that it contains a hazardous material.7. Preparing a shipping paper.8. Providing and maintaining emergency response information.9. Reviewing a shipping paper to verify compliance with the HMR or international equivalents.10. For each person importing a hazardous material into the United States, providing the shipper with

timely and complete information as to the HMR requirements that will apply to the transportation of the material within the United States.

11. Certifying that a hazardous material is in proper condition for transportation in conformance with the requirements of the HMR.

12. Loading, blocking, and bracing a hazardous materials package in a freight container or transport vehicle.

13. Segregating a hazardous materials package in a freight container or transport vehicle from incompatible cargo.

14. Selecting, providing, or affixing placards for a freight container or transport vehicle to indicate that it contains a hazardous material.

• Pressure Vacuum Relief Valve - any device or assembly of a mechanical, liquid, weight, or other type used for

the automatic regulation of pressure or vacuum in enclosed spaces (46 CFR 30.10-55).

• Private Track or Private Siding - (49 CFR 171.8) [Added April 2005]:1. Track located outside of a carrier's right-of-way, yard, or terminals where the carrier does not own the

rails, ties, roadbed, or right-of-way, or2. Track leased by a railroad to a lessee, where the lease provides for, and actual practice entails, exclusive

use of that trackage by the lessee and/or a general system railroad for purpose of moving only cars shipped to or by the lessee, and where the lessor otherwise exercises no control over or responsibility for the trackage or the cars on the trackage.

• Produce - to manufacture, process, formulate, blend, extract, generate, emit, or repackage (29 CFR 1910.1200(c)).

• Protection for Exposure - adequate fire protection for structures on property adjacent to tanks where there are

employees of the establishment (29 CFR 1910.106(a)(27)).

• Pyrophoric - a chemical that will ignite spontaneously in air at a temperature of 130 °F (54.4 °C) or below (29 CFR 1910.1200(c)).

• Release - any spilling, leaking, pumping, pouring, emitting, emptying, discharging, injecting, escaping,

leaching, dumping, or disposing into the environment (including the abandonment or discarding of barrels, containers, and other closed receptacles) of any hazardous chemical, extremely hazardous substance, or CERCLA hazardous substance (40 CFR 355.61) [Added April 1999; Reviewed March 2001, Citation Revised January 2009].

• Release - any spilling, leaking, pumping, pouring, emitting, emptying, discharging, injecting, escaping,

leaching, dumping, or disposing into the environment (including the abandonment or discarding of barrels, containers, and other closed receptacles) of any toxic chemical (40 CFR 372.3) [Added March 2001].

• Release - any spilling, leaking, pumping, pouring, emitting, emptying, discharging, injecting, escaping, leaching, dumping, or disposing into the environment (including the abandonment or discarding of barrels, containers, and other closed receptacles containing any hazardous substance or pollutant or contaminant), but excludes (40 CFR 302.3) [Added October 2002]:

1. any release which results in exposure to persons solely within a workplace, with respect to such claim which such persons may assert against the employer of such persons;

2. emissions from the engine exhaust of a motor vehicle, rolling stock, aircraft, vessel, or pipeline pumping station engine;

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3. release of source, byproduct, or special nuclear material from a nuclear incident, as those terms are defined in the Atomic Energy Act of 1954, if such release is subject to requirements with respect to financial protection established by the Nuclear Regulatory Commission under section 170 of such Act, or for the purposes of section 103 of CERCLA or any other response action, any release of source, byproduct, or special nuclear material from any processing sites designates under section 102(a)(1) or 302(a) of the Uranium Mill Tailing Radiation Control Act of 1978; and

4. the normal application of fertilizer.

• Reportable Quantity - for any CERCLA hazardous substance, the quantity established in Table 302.4 of 40 CFR 302.4, for such substance. For any extremely hazardous substance (EHS), reportable quantity means the quantity established in Appendices A and B of 40 CFR 355 for such substance. Unless and until superseded by regulations establishing a reportable quantity for newly listed EHSs or CERCLA hazardous substances, a weight of 1 pound shall be the reportable quantity (40 CFR 355.61) [Added April 1999; Reviewed March 2001, Revised January 2009].

• Reportable Quantity (RQ) – that quantity, as set forth in 40 CFR 302, the release of which requires notification pursuant to 40 CFR 302 (40 CFR 302.3) [Added October 2002].

• Responsible Party - someone who can provide additional information on the hazardous chemical and appropriate emergency procedures, if necessary (29 CFR 1910.1200(c)).

• Routine - routine release is a release that occurs during normal operating procedures or processes (40 CFR

302.8(b)) [Added April 1999; Reviewed March 2001].

• SERC - the State Emergency Response Commission for the State in which the facility is located except where the facility is located in Indian Country, in which case, SERC means the Emergency Response Commission for the Tribe under whose jurisdiction the facility is located. In the absence of a SERC for a State or Indian Tribe, the Governor or the chief executive officer of the tribe, respectively, shall be the SERC. Where there is a cooperative agreement between a State and a Tribe, the SERC shall be the entity identified in the agreement (40 CFR 355.61 and 370.66) [Added January 2009].

• Safety Can - an approved container, of not more than 5 gal capacity, having a spring-closing lid, spout cover, and so designed that it will safely relieve internal pressure when subjected to fire exposure (29 CFR 1910.106(a)(29)).

• Select Carcinogens - any substance that meets one of the following criteria (29 CFR 1910.1450(b)):1. it is regulated by OSHA as a carcinogen2. it is listed under the category “known to be carcinogens” in the Annual Report on Carcinogens

published by the National Toxicology Program (NTP)3. it is listed under Group 1 (carcinogenic to humans) by the International Agency for Research on Cancer

Monographs (IARC)4. it is listed in either Group 2A or 2B by IARC or under the category “reasonably anticipated to be

carcinogens” by NTP, and causes statistically significant tumor incidences in experimental animals under specific situations.

• Service Space - spaces that are used for galleys, pantries containing cooking appliances, lockers, storerooms, paint and lamp rooms, and similar spaces that contain highly combustible materials, laundries, garbage and trash disposal and stowage rooms, workshops other than those forming part of the machinery spaces, and similar spaces and trunks to such spaces (46 CFR 30.10-62a).

• Ship - a vessel of any type whatsoever operating in the marine environment (33 CFR 151.05).

• Shipping Paper - a shipping order, bill of lading, manifest or other shipping document serving a similar purpose and containing the information required by 49 CFR 172.202, 172.203 and 172.204 (49 CFR 171.8) [Added April 2005].

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• Special Permit - a document issued by the Associate Administrator under the authority of 49 U.S.C. 5117permitting a person to perform a function that is not otherwise permitted under subchapter A or C of this chapter, or other regulations issued under 49 U.S.C. 5101 et seq. (e.g., Federal Motor Carrier Safety routing requirements). The terms ``special permit'' and ``exemption'' have the same meaning for purposes of subchapter A or C of this chapter or other regulations issued under 49 U.S.C. 5101 through 5127. An exemption issued prior to October 1, 2005 remains valid until it is past its expiration date, terminated by the Associate Administrator, or issued as a special permit, whichever occurs first (49 CFR 171.8) [Added January 2006].

• Specific Chemical Identity - the chemical name, Chemical Abstracts Service (CAS) Registry Number, or any other information that reveals the precise chemical designation of the substance (29 CFR 1910.1200(c)).

• Stable In Quantity and Rate - a release that is stable in quantity and rate is a release that is predictable and

regular in amount and rate of emission (40 CFR 302.8(b)) [Added April 1999; Reviewed March 2001].

• State - any State of the United States, the District of Columbia, the Commonwealth of Puerto Rico, Guam, American Samoa, the United States Virgin Islands, the Northern Mariana Islands, any other territory or possession over which the United States has jurisdiction and Indian Country (40 CFR 355.61 and 370.66) [Added January 2009].

• Statistically Significant Increase - a statistically significant increase in a release is an increase in the quantity of the hazardous substance released above the upper bound of the reported normal range of the release (40 CFR 302.8(b)) [Added April 1999; Reviewed March 2001].

• Storage Incidental to Movement - storage of a transport vehicle, freight container, or package containing a hazardous material by any person between the time that a carrier takes physical possession of the hazardous material for the purpose of transporting it in commerce until the package containing the hazardous material is physically delivered to the destination indicated on a shipping document, package marking, or other medium, or, in the case of a private motor carrier, between the time that a motor vehicle driver takes physical possession of the hazardous material for the purpose of transporting it in commerce until the driver relinquishes possession of the package at its destination and is no longer responsible for performing functions subject to the HMR with respect to that particular package. Storage incidental to movement includes:

1. Storage at the destination shown on a shipping document, including storage at a transloading facility, provided the shipping documentation identifies the shipment as a through-shipment and identifies the final destination or destinations of the hazardous material; and

2. Rail cars containing hazardous materials that are stored on track that does not meet the definition of “private track or siding” in 49 CFR 171.8, even if those cars have been delivered to the destination shown on the shipping document.

Storage incidental to movement does not include storage of a hazardous material at its final destination as shown on a shipping document (49 CFR 171.8) [Revised July 2005].

• Tank Barge - any tank vessel not equipped with means of self-propulsion (46 CFR 30.10-65).

• Tankship - any tank vessel propelled by power or sail (46 CFR 30.10-67).

• Tank Vessel - any vessel especially constructed or converted to carry liquid bulk cargo in tanks (46 CFR 30.10-69).

• Threshold Planning Quantity - for a substance listed in Appendices A and B of 40 CFR 355, the quantity listed in the column “threshold planning quantity” for that substance (40 CFR 355.61 and 370.66) [Added March 2001; Revised January 2009].

• Title III - Title III of the Superfund Amendments and Reauthorization Act of 1986, also titled the Emergency Planning and Community Right-to-Know Act of 1986 (40 CFR 372.3) [Added March 2001].

• Toxic Chemical - a chemical or chemical category listed in 40 CFR 372.65 [see the column titled Toxic Chemicals in Appendix 3-1] (40 CFR 372.3).

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• Transloading - the transfer of a hazardous material by any person from one bulk packaging to another bulk packaging, from a bulk packaging to a non-bulk packaging, or from a non-bulk packaging to a bulk packaging for the purpose of continuing the movement of the hazardous material in commerce (49 CFR 171.8) [Revised July 2005].

• Transportation or Transport - the movement of property and loading, unloading, or storage incidental to that

movement (49 CFR 171.8) [Added April 2005]. • Undeclared Hazardous Material - a hazardous material that is (49 CFR 171.8) [Added April 2004]:

1. subject to any of the hazard communication requirements in subparts C (Shipping Papers), D (Marking), E (Labeling), and F (Placarding) of 49 CFR 172, or an alternative

marking requirement in 49 CFR 173 (such as 49 CFR 173.4(a)(10) and 173.6(c)), and2. offered for transportation in commerce without any clear indication of the presence of the hazardous

material in or on at least one of the following: an accompanying shipping paper, the outer package, the transport vehicle or freight container, or another written statement by the person

offering the hazardous material for transportation.

• Unloading Incidental to Movement - moving a packaged or containerized hazardous material from a transport vehicle, aircraft, or vessel, or for a bulk packaging, emptying a hazardous material from the bulk packaging after the hazardous material has been delivered to the consignee when performed by carrier personnel or in the presence of carrier personnel or, in the case of a private motor carrier, while the driver of the motor vehicle from which the hazardous material is being unloaded immediately after movement is completed is present during the unloading operation. (Emptying a hazardous material from a bulk packaging while the packaging is on board a vessel is subject to separate regulations as delegated by Department of Homeland Security Delegation No. 0170.1 at 2(103).) Unloading incidental to movement includes transloading (49 CFR 171.8) [Revised July 2005].

• Unintentional Release - the escape of a hazardous material from a package on an occasion not anticipated or planned. This includes releases resulting from collision, package failures, human error, criminal activity, negligence, improper packing, or unusual conditions such as the operation of pressure relief devices as a result of over-pressurization, overfill or fire exposure. It does not include releases, such as venting of packages, where allowed, and the operational discharge of contents from packages (49 CFR 171.8) [Added April 2004].

• Unlisted Hazardous Substances - a solid waste, as defined in 40 CFR 261.2, which is not excluded from regulation as a hazardous waste under 40 CFR 261.4(b), is a hazardous substance under section 101(14) of CERCLA if it exhibits any of the characteristics identified in 40 CFR 261.20 through 261.24 (40 CFR 302.4(b)) [Added April 1999; Reviewed March 2001].

• Unstable (Reactive) - a chemical which in the pure state, or as produced or transported, will vigorously polymerize, decompose, condense, or will become self-reactive under conditions of shocks, pressure or temperature (29 CFR 1910.1200(c)).

• Use - to package, handle, react, emit, extract, generate as a byproduct, or transfer (29 CFR 1910.1200(c)). • Vapor Pressure - the pressure, measured in pounds per square inch (absolute) exerted by a volatile liquid (29

CFR 1910.106(a)(30)).

• Water-Reactive - a chemical that reacts with water to release a gas that is either flammable or presents a health hazard (29 CFR 1910.1200(c)).

• Work Area - a room or defined space in a workplace where hazardous chemicals are produced or used, and

where employees are present (29 CFR 1910.1200(c)). • Workplace - an establishment, job site, or project, at one geographical location containing one or more work

areas (29 CFR 1910.1200(c)).

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F. Records To Review

• Hazardous Substance Spill Control and Contingency Plan • Spill records • Emergency plan documents • MSDSs • Inventory records • Hazardous substance release reports • Shipping papers • Training records • Placarding of hazardous materials • Ships log • Certificate of Inspection • Classification Society Certificates • Licenses, documents, and endorsements for crew members • Vessel Response Plan • Hazardous Communication Plan• Chemical Hygiene Plan (labs)

G. Physical Features To Inspect

• Hazardous material storage areas • Shop activities • Shipping and receiving area • Hazardous material transfer areas

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H. Guidance for Hazardous Materials Management Checklist Users

REFER TOCHECKLISTITEMS:

All Federal Facilities HM.1.1.US through HM.1.4.US

Missing, Risk Management, and Positive Checklist Items

HM.2.1.US through HM.2.3.US

Personnel Training HM.10.1.US and HM.10.2.US

Hazardous Materials in Laboratories HM.15.1.US through HM.15.4.US

Releases of Hazardous Materials HM.20.1.US through HM.20.4.US

Emergency Planning HM.25.1.US

Right-to-Know HM.30.1.US through HM.30.3.US

Flammable/Combustible Liquids StorageGeneralIndustrial Areas

HM.35.1.US through HM.35.9.USHM.40.1.US through HM.40.3.US

Compressed Gases Storage HM.45.1.US

Hazardous Materials Transportation HM.50.1.US through HM.50.12.US

Hazardous Material Transfer Operations To or From Vessels

HM.55.1.US through HM.55.4.US

Fixed Facility Transfer Operations for Hazardous Materials

HM.60.1.US through HM.60.3.US

Hazardous Materials Storage on Floating Plants HM.65.1.US through HM.65.3.US

Hazardous Materials on Tank Vessels HM.70.1.US through HM.70.12.US

Hazardous Materials on Cargo andMiscellaneous Vessels

HM.75.1.US

Appendix 3-0, Comparison of 40 CFR 355 Emergency Release Notification Requirements and the Release Notification Requirements of CERCLA as Codified In 40 CFR 302

Appendix 3-0a, Community Right-To-Know Reporting of Mixtures

Appendix 3-0b, Codes for Tier I and Tier II Inventory Reporting

Appendix 3-1, Combined List of Chemicals Covered in Title III of SARA

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Appendix 3-1a, Lower Thresholds for Chemicals of Special Concern

Appendix 3-2, Maximum Allowable Capacity of Containers and Portable Tanks

Appendix 3-3, Storage in Inside Rooms

Appendix 3-4, Flammable Combustible Materials Storage.

Appendix 3-5, Hazardous Materials/Hazardous Waste Storage Incompatibility Chart.

Appendix 3-6, Placarding Guidelines.

Appendix 3-7, List of Flammable and Combustible Bulk Liquid Cargoes.

Appendix 3-8, Classes of Vessels.

Select portions of this section (i.e., Review of Federal Legislation, State and Local Regulations, Key Compliance Requirements, Key Terms and Definitions, Typical Records to Review, Typical Physical Features to Inspect, and the Checklist) have been reviewed by USEPA personnel from the Office of Enforcement and Compliance Assurance (OECA) and USEPA's Office of General Counsel. USEPA's comments and suggestions for changes have been incorporated in this version of the TEAM Guide. USEPA did not review all portions of this section. USEPA also did not review and comment on items pertaining to federal Executive Orders, DOT regulations, OSHA regulations or any other area outside of Title 40 of the Code of Federal Regulations. Portions that have been added or revised as a result of this review are identified as either being reviewed, revised or added in March 2001, for example [Reviewed March 2001].

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COMPLIANCE CATEGORYHAZARDOUS MATERIALS MANAGEMENT

U.S. TEAM Guide

REGULATORYREQUIREMENTS

REVIEWER CHECKSMarch 2009

HM.1

ALL FEDERAL FACILITIES

HM.1.1.US. The current status of any ongoing or unresolved consent orders, compliance agreements, notices of violation (NOVs), interagency agreements, or equivalent state enforcement actions is required to be examined (a finding under this checklist item will have the enforcement action/ identifying information as the citation).

Determine if noncompliance issues have been resolved by reviewing a copy of the previous report, consent orders, compliance agreements, NOVs, interagency agreements, or equivalent state enforcement actions.

HM.1.2.US. A MSDS is required to be on file for each hazardous chemical stored and used (29 CFR 1910.1200(b)(3)(ii), 1910.1200(b)(4)(ii), 1910.1200(b)(6), 1910.1200(g)(1), and 1910.1200(g)(8)).

Verify that an MSDS is on file and readily accessible to workers on all shifts in the workplace for each hazardous material stored or used.

(NOTE: These requirements do not apply to: hazardous waste tobacco or tobacco products wood or wood products articles that are defined as a manufactured item other than a fluid or

particle which under normal conditions of use does not release more than very small amounts of a hazardous chemical and does not pose a physical hazard or health risk to personnel and that:

is formed to a specific shape or design during manufacture has end use functions dependent in whole or in part upon its shape or

design during end use food or alcoholic beverages that are sold, used, or prepared in a retail

establishment and foods intended for consumption by personnel any drug as that term is defined in the Federal Food, Drug, and Cosmetic

Act when it is in its solid, final form for direct administration cosmetics that are packaged for sale or intended for personal use any consumer product or hazardous substance as defined in the Consumer

Product Safety Act and the Federal Hazardous Substances Act for which the facility can demonstrate that it is used in the workplace in the same manner as normal consumer use, and which use results in a duration and frequency of exposure not greater than exposure experienced by consumers

ionizing and nonionizing radiation biological hazards.)

3-24Hazardous Materials

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COMPLIANCE CATEGORYHAZARDOUS MATERIALS MANAGEMENT

U.S. TEAM Guide

REGULATORYREQUIREMENTS

REVIEWER CHECKSMarch 2009

(NOTE: This requirement also applies to work operations where employees handle packaged chemical products or substances.)

HM.1.3.US. Containers of hazardous chemicals in the workplace are required to be labeled, tagged, or marked with specific information (29 CFR 1910.1200(b)(3)(i), 1910.1200(b)(4)(i), 1910.1200(b)(5), and 1910.1200(f)(5) through 1910.1200(f)(7)).

Verify that all containers of hazardous chemicals in the workplace are labeled with the following information:

identity of the hazardous chemical (same as MSDS) appropriate hazard warnings.

(NOTE: Signs, placards, process sheets, batch tickets, operating procedures, or other written materials may be used instead of attached labels to identify stationary process containers as long as the alternate method identifies the containers to which it is applicable.)

(NOTE: Portable containers into which hazardous chemicals are transferred from labeled containers and which are intended only for the immediate use of the employee who performs the transfer are not required to be marked.)

(NOTE: These requirements do not apply to: any pesticide as such term is defined in the Federal Insecticide, Fungicide,

and Rodenticide Act (FIFRA), when subject to the labeling requirements of that act and regulations issued under that act

any chemical substance or mixture as defined by the Toxic Substances Control Act (TSCA) when subject to the labeling requirements of TSCA

any food, food additive, color additive, drug, cosmetic, or medical or veterinary device as defined in the Federal Food, Drug, and Cosmetic Act

any distilled spirits, wine, or malt beverage intended for nonindustrial use as defined in the Federal Alcohol Administration Act

any consumer product or hazardous substance as defined in the Consumer Product Safety Act and the Federal Hazardous Substances Act when subject to a consumer product safety standard or labeling requirement under those acts

agricultural or vegetable seed treated with pesticides and labeled in accordance with the Federal Seed Act.)

(NOTE: These requirements do not apply to: hazardous waste tobacco or tobacco products wood or wood products articles that are defined as a manufactured item other than a fluid or

particle which under normal conditions of use does not release more than very small amounts of a hazardous chemical and does not pose a physical hazard or health risk to personnel and that:

is formed to a specific shape or design during manufacture has end use functions dependent in whole or in part upon its shape or

design during end use food or alcoholic beverages which are sold, used, or prepared in a retail

3-25Hazardous Materials

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COMPLIANCE CATEGORYHAZARDOUS MATERIALS MANAGEMENT

U.S. TEAM Guide

REGULATORYREQUIREMENTS

REVIEWER CHECKSMarch 2009

establishment and foods intended for consumption by personnel any drug as that term is defined in the Federal Food, Drug, and Cosmetic

Act when it is in its solid, final form for direct administration cosmetics that are packaged for sale or intended for personal use any consumer product or hazardous substance as defined in the Consumer

Product Safety Act and the Federal Hazardous Substances Act in which the facility can demonstrate that it is used in the workplace in the same manner as normal consumer use, and which use results in a duration and frequency of exposure not greater than exposure experienced by consumers

ionizing and nonionizing radiation biological hazards.)

(NOTE: This requirement also applies to work operations where employees handle packaged chemical products or substances.)

HM.1.4.US. Specific housekeeping requirements must be met in areas where hazardous materials are stored (29 CFR 1910.176(c)).

Verify that areas where hazardous materials are stored and/or used are free from accumulations of materials that create a hazard from tripping, fire, explosion, or pest harborage.

(NOTE: The following are suggested housekeeping practices: drums/containers are not leaking and are tightly sealed drip pans and/or absorbent material are placed under containers dispensing areas are located away from catch basins and storm drains.)

3-26Hazardous Materials

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3-27Hazardous Materials

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COMPLIANCE CATEGORYHAZARDOUS MATERIALS MANAGEMENT

U.S. TEAM Guide

REGULATORYREQUIREMENTS

REVIEWER CHECKSMarch 2009

HM.2

MISSING, RISK MANAGEMENT, AND POSITIVE CHECKLIST ITEMS

HM.2.1.US. Facilities are required to comply with all applicable Federal regulatory requirements not contained in this checklist (a finding under this checklist item will have the citation of the applied regulation as a basis of finding).

Determine if any new regulations have been issued since the finalization of the guide.

Determine if the facility has activities or facilities that are regulated but not addressed in this checklist.

Verify that the facility is in compliance with all applicable and newly issued regulations.

HM.2.2.US. Risk management techniques should be promoted in environmental efforts (MP) [Added April 2002].

Determine if risk management techniques are promoted in environmental efforts.

HM.2.3.US. Facilities should go above and beyond statutory and regulatory compliance (MP) [Added April 2002].

Determine if the facility has gone above and beyond simply complying with environmental requirements.

3-28Hazardous Materials

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3-29Hazardous Materials

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COMPLIANCE CATEGORYHAZARDOUS MATERIALS MANAGEMENT

U.S. TEAM Guide

REGULATORYREQUIREMENTS

REVIEWER CHECKSMarch 2009

HM.10

PERSONNEL TRAINING

HM.10.1.US. A written hazard communication program is required that is designed to provide all employees with information about the hazardous chemicals to which they are exposed (29 CFR 1910.1200(b)(1) and 1910.1200(e)(1)) [Revised February 1995].

Verify that there is a written hazard communication program which contains the following:

how general training will be done to inform employees of issues such as MSDSs and hazardous materials labels and other warning signs

a list of the hazardous chemicals known to be present (can be done for the entire workplace or individual work areas)

how training will be done the methods used to inform the employees of the hazards associated with

nonroutine tasks and the hazards associated with chemicals contained in unlabeled pipes in their work areas.

Verify that, if employees from more than one employer may be exposed (for example, employees of a construction contractor working onsite), the hazard communication program also addresses what will be done to:

provide the other employees onsite with access to MSDSs for each hazardous chemical the other employer’s employees may be exposed to while working

inform the other employers of the labeling system used in the workplace inform the other employers of any precautionary measures that need to be

taken to protect employees during the workplace’s normal operating conditions and in foreseeable emergencies.

(NOTE: This requirement also applies to work operations where employees handle packaged chemical products or substances.)

(NOTE: These requirements do not apply to: hazardous waste tobacco or tobacco products wood or wood products articles that are defined as a manufactured item other than a fluid or

particle which under normal conditions of use does not release more than very small amounts of a hazardous chemical and does not pose a physical hazard or health risk to personnel and that:

is formed to a specific shape or design during manufacture has end use functions dependent in whole or in part upon its shape or

design during end use food or alcoholic beverages that are sold, used, or prepared in a retail

establishment and foods intended for consumption by personnel any drug as that term is defined in the Federal Food, Drug, and Cosmetic

Act when it is in its solid, final form for direct administration cosmetics that are packaged for sale or intended for personal use

3-30Hazardous Materials

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COMPLIANCE CATEGORYHAZARDOUS MATERIALS MANAGEMENT

U.S. TEAM Guide

REGULATORYREQUIREMENTS

REVIEWER CHECKSMarch 2009

any consumer product or hazardous substance as defined in the Consumer Product Safety Act and the Federal Hazardous Substances Act in which the facility can demonstrate that it is used in the workplace in the same manner as normal consumer use, and which use results in a duration and frequency of exposure not greater than exposure experienced by consumers

ionizing and nonionizing radiation biological hazards.)

HM.10.2.US. Personnel working with hazardous materials are required to be trained in their use and the potential hazards of such materials (29 CFR 1910.1200(b)(3)(iii), 1910.1200(b)(4)(iii), 1910.1200(b)(6), and 1910.1200(h)).

Verify that employees are provided with information and trained on hazardous chemicals in their workplace at the time of initial assignment and whenever a new hazard is introduced into the workplace.

Verify that employees are informed of the following:

any operations in their work areas in which hazardous chemicals are present

the location and availability of the written hazard communication program, including the required lists of hazardous chemicals and MSDSs.

Verify that training includes:

methods and observations to use to detect a release the physical and health hazards of the chemicals in the work areas protective measures and procedures to use the details of the hazard communication program, including an explanation

of the labeling system, MSDSs, and how employees can obtain and use the appropriate hazard information.

(NOTE: These requirements also apply, as necessary for protection in event of a spill or leak, to work operations in which employees only handle packaged chemical products or substances.)

(NOTE: These requirements do not apply to: hazardous waste tobacco or tobacco products wood or wood products articles that are defined as a manufactured item other than a fluid or

particle, which under normal conditions of use does not release more than very small amounts of a hazardous chemical and does not pose a physical hazard or health risk to personnel and that:

is formed to a specific shape or design during manufacture has end use functions dependent in whole or in part upon its shape or

design during end use food or alcoholic beverages that are sold, used, or prepared in a retail

establishment and foods intended for consumption by personnel any drug as that term is defined in the Federal Food, Drug, and Cosmetic

Act when it is in its solid, final form for direct administration cosmetics that are packaged for sale or intended for personal use

3-31Hazardous Materials

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COMPLIANCE CATEGORYHAZARDOUS MATERIALS MANAGEMENT

U.S. TEAM Guide

REGULATORYREQUIREMENTS

REVIEWER CHECKSMarch 2009

any consumer product or hazardous substance as defined in the Consumer Product Safety Act and the Federal Hazardous Substances Act in which the facility can demonstrate that it is used in the workplace in the same manner as normal consumer use, and which use results in a duration and frequency of exposure not greater than exposure experienced by consumers

ionizing and nonionizing radiation biological hazards.)

3-32Hazardous Materials

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3-33Hazardous Materials

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COMPLIANCE CATEGORYHAZARDOUS MATERIALS MANAGEMENT

U.S. TEAM Guide

REGULATORYREQUIREMENTS

REVIEWER CHECKSMarch 2009

HM.15

HAZARDOUS MATERIALS IN LABORATORIES

HM.15.1.US. A Chemical Hygiene Plan is required when engaged in the laboratory use of hazardous chemicals (see definitions) (29 CFR 1910.1450(e)).

(NOTE: The requirements for hazardous materials in laboratories do not apply to:

uses of hazardous chemicals that do not meet the definition of laboratory use

laboratory uses of hazardous chemicals that provide no potential for exposure such as:

commercially prepared kits such as pregnancy tests in which all the reagents needed to conduct the test are contained in the kit

procedures using chemically impregnated test media such as Dip-and- Read tests.)

Verify that a written Chemical Hygiene Plan exists and is:

capable of protecting employees from health hazards associated with hazardous chemicals in the laboratory

capable of keeping exposure to regulated substances below required limits.

Verify that the plan is readily available to employees and employee representatives.

Verify that the plan includes the following elements and indicates specific measures to be taken when laboratory work involves the use of hazardous chemicals:

standard operating procedures relevant to safety and health considerations to be followed

criteria that will be used to determine and implement control measures to reduce employee exposure to hazardous chemicals, including the engineering controls, the use of personal protective equipment, and hygiene practices

a requirement that fume hoods and other protective equipment are functioning properly and specific measures are taken to ensure proper and adequate performance of the equipment

provisions for employee information and training circumstances and situations that require prior approval from a designated

individual provisions for medical consultations and medical exams designation of individuals responsible for the implementation of the plan assignment of a Chemical Hygiene Officer and, if appropriate,

establishment of a Chemical Hygiene Committee provisions for additional employee protection when working with

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particularly hazardous substances, including select carcinogens, reproductive toxins, and substances that have a high degree of acute toxicity. Provisions might include:

establishment of a designated area use of containment devices such as fume hoods or glove boxes procedures for safe removal of contaminated waste decontamination procedures.

Verify that the plan is reviewed annually and updated as needed.

HM.15.2.US. Employees engaged in the laboratory use of hazardous chemicals (see definitions) are required to be provided with information and training concerning the hazards of the chemicals in their work areas (29 CFR 1910.1450(f)).

(NOTE: The requirements for hazardous materials in laboratories do not apply to:

uses of hazardous chemicals that do not meet the definition of laboratory use

laboratory uses of hazardous chemicals that provide no potential for exposure such as:

commercially prepared kits such as pregnancy tests in which all the reagents needed to conduct the test are contained in the kit

procedures using chemically impregnated test media such as Dip-and- Read tests.)

Verify that information about the hazards of the chemicals in the work area is provided at the time of initial employment and prior to assignment involving new exposure risks.

(NOTE: The frequency of refresher training is to be determined by the facility.)

Verify that employees are informed of:

the requirements to be trained and informed the location and availability of the Chemical Hygiene Plan the permissible exposure limits for OSHA regulated substances or

recommended exposure levels for other hazardous chemicals where there is no OSHA limit

signs and symptoms associated with exposure the location and known availability of known reference material such as

MSDSs.

Verify that training includes:

methods and observations that may be used to detect the presence of or release of a hazardous chemical

the physical and health hazards of chemicals in the work area the measures employees can take to protect themselves applicable details of the Chemical Hygiene Plan.

HM.15.3.US. Specific (NOTE: The requirements for hazardous materials in laboratories do not apply

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handling and operating procedures must be followed when engaged in the laboratory use of hazardous chemicals (see definitions) (29 CFR 1910.1450(h)).

to: uses of hazardous chemicals that do not meet the definition of laboratory

use laboratory uses of hazardous chemicals that provide no potential for

exposure such as: commercially prepared kits such as pregnancy tests in which all the

reagents needed to conduct the test are contained in the kit procedures using chemically impregnated test media such as Dip-and-

Read tests.)

Verify that labels on incoming containers of hazardous chemicals are not removed or defaced.

Verify that MSDSs are maintained and readily accessible to lab employees.

Verify that, if developing chemical substances, a determination is made as to whether or not it is a hazardous chemical, if the composition of the chemical is known and the chemical is produced only for use by the laboratory.

Verify that, if developing a chemical substance as a byproduct and the composition is not known, it is assumed to be hazardous.

Verify that, if the chemical substance is produced for another user outside of the lab, the lab meets the standards outlined in 29 CFR 1910.1200 (see checklist items HM.1.4.US. HM.1.5.US., HM.10.1.US., and HM.10.2.US.).

HM.15.4.US. Specific records are required when engaged in the laboratory use of hazardous chemicals (see definitions) (29 CFR 1910.1450(j)).

Verify that records of monitoring for employee exposure are maintained along with any medical records or test results.

(NOTE: The requirements for hazardous materials in laboratories do not apply to:

uses of hazardous chemicals that do not meet the definition of laboratory use

laboratory uses of hazardous chemicals that provide no potential for exposure such as:

commercially prepared kits such as pregnancy tests in which all the reagents needed to conduct the test are contained in the kit

procedures using chemically impregnated test media such as Dip-and- Read tests.)

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3-37Hazardous Materials

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HM.20

RELEASES OF HAZARDOUS MATERIALS

HM.20.1.US. Absorbent materials should be available for spill and/or release cleanup in areas where hazardous materials are used or stored (MP).

Verify that absorbent materials are available for spill cleanup.

HM.20.2.US. Releases in excess of or equal to the RQ of listed and unlisted hazardous substances shall be reported to the NRC immediately (40 CFR 302.1 through 302.6) [Revised April 1999; Reviewed March 2001; Revised October 2006].

Verify that a release (other than a Federally permitted release or application of a pesticide) of a hazardous substance from a vessel, an offshore facility, or an onshore facility is reported to the NRC immediately after the release is identified.

(NOTE: See Appendix 3-1 for the RQ of listed hazardous substances. The RQ of an unlisted hazardous substance (see definitions) is 100 lb, except for those unlisted hazardous wastes that exhibit extraction procedure (EP) toxicity identified in 40 CFR 261.24. Unlisted hazardous wastes that exhibit EP toxicity have the RQs listed in Appendix 3-1 for the contaminant on which the characteristic of EP toxicity is based. The RQ applies to the waste itself, not merely to the toxic contaminant. If an unlisted hazardous waste exhibits EP toxicity on the basis of more than one contaminant, the RQ for that waste shall be the lowest of the RQ listed in Appendix 3-1 for those contaminants. If an unlisted hazardous waste exhibits the characteristic of EP toxicity and one or more of the other characteristics referenced in 40 CFR 302.4(b), the RQ for that waste is the lowest of the applicable reportable quantities.)

Verify that, if mixtures or solutions of hazardous substances are released, except for radionuclides, it is reported when either of the following occur:

the quantity of all hazardous constituents of the mixture or solution is known and a reportable quantity or more of any hazardous constituent is released

the quantity of one or more of the hazardous constituents of the mixture or solution is unknown and the total amount of the mixture or solution released equals or exceeds the reportable quantity for the hazardous constituent with the lowest RQ.

(NOTE: Radionuclides are subject to these notification requirements only in the following circumstances:

if the identity and quantity (in curies) of each radionuclide in a released mixture or solution is known, the ratio between the quantity released (in curies) and the RQ for the radionuclide must be determined for each

3-38Hazardous Materials

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radionuclide (NOTE: The only such releases notification requirements are those in which the sum of the ratios for the radionuclides in the mixture or solution released is =/> 1.)

if the identity of each radionuclide in a released mixture or solution is known but the quantity released (in curies) of one or more of the radionuclides is unknown, the only such releases subject to notification requirements are those in which the total quantity (in curies) of the mixture or solution released is =/> the lowest RQ of any individual radionuclide in the mixture or solution

if the identity of one or more radionuclides in a released mixture or solution is unknown (or if the identity of a radionuclide released by itself is unknown), the only such releases subject to notification requirements are those in which the total quantity (in curies) released is equal to or greater than either one curie or the lowest RQ of any known individual radionuclide in the mixture or solution, whichever is lower.)

(NOTE: The following categories of releases are exempt from the notification requirements:

releases of those radionuclides that occur naturally in the soil from land holdings such as parks, golf courses, or other large tracts of land

releases of naturally occurring radionuclides from land disturbance activities, including farming, construction, and land disturbance incidental to extraction during mining activities, except that which occurs at uranium, phosphate, tin, zircon, hafnium, vanadium, monazite, and rare earth mines. Land disturbance incidental to extraction includes: land clearing; overburden removal and stockpiling; excavating, handling, transporting, and storing ores and other raw materials; and replacing materials in mined-out areas as long as such materials have not been beneficiated or processed and do not contain elevated radionuclide concentrations (greater than 7.6 pCi/g of Uranium-238, 6.8 pCi/g of Thorium-232, or 8.4 pCi/g of Radium-226)

releases of radionuclides from the dumping and transportation of coal and coal ash (including fly ash, bottom ash, and boiler slags), including the dumping and land spreading operations that occur during coal ash uses

releases of radionuclides from piles of coal and coal ash, including fly ash, bottom ash, and boiler slags

releases in amounts less than 1,000 lb/24 h of nitrogen oxide to the air which are the result of combustion and combustion-related activities

releases in amounts less than 1,000 lb/24 h of nitrogen dioxide to the air which are the result of combustion and combustion-related activities.)

(NOTE: Except for releases of radionuclides, notification of the release of an RQ of solid particles of antimony, arsenic, beryllium, cadmium, chromium, copper, lead, nickel, selenium, silver, thallium, or zinc is not required if the mean diameter of the particles released is larger than 100 micrometers (0.004 in.).)

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HM.20.3.US. Specific notification requirements are required to be met for releases of hazardous substances that are continuous and stable in quantity and rate (40 CFR 302.8) [Revised April 1999; Revised March 2001].

Determine if there are any releases that are continuous and stable in quantity and rate.

Verify that the following notifications have been given:

initial telephone notification initial written notification within 30 days of the initial telephone

notification follow-up notification within 30 days of the first anniversary date of the

initial written notification notification of changes in:

the composition or source of the release information submitted in the initial written notification

the follow-up notification required on the first anniversary date of the initial written notification of when there is an increase in the quantity of the hazardous substances in any 24-h period that represents a statistically significant increase.

Verify that, prior to making an initial telephone notification of a continuous release, the person in charge of a facility or vessel establishes a sound basis for qualifying the release for reporting by one of the following:

using release data, engineering estimates, knowledge of operating procedures, or best professional judgment to establish the continuity and stability of the release

reporting the release to the NRC for a period sufficient to establish the continuity and stability of the release, or, when a basis has been established to qualify the release for reduced reporting, initial notification to the NRC is made by telephone.

Verify that the notification is identified as an initial continuous release notification report and includes the following information:

the name and location of the facility or vessel the name and identity of the hazardous substance being released.

Verify that initial written notification of a continuous release is made to the appropriate USEPA Regional Office for the geographical area where the releasing facility or vessel is located and occurs within 30 days of the initial telephone notification to the NRC.

Verify that the initial written notification includes, for each release for which reduced reporting as a continuous release is claimed, the following information:

the name of the facility or vessel; the location, including the latitude and longitude; the case number assigned by the NRC or the USEPA; the Dun and Bradstreet number of the facility, if available; the port of registration of the vessel; the name and telephone number of the person in charge of the facility or vessel

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the population density within a 1-mi radius of the facility or vessel, described in terms of the following ranges: 0-50 persons, 51-100 persons, 101-500 persons, 501-1,000 persons, more than 1,000 persons

the identity and location of sensitive populations and ecosystems within a 1-mi radius of the facility or vessel (e.g., elementary schools, hospitals, retirement communities, or wetlands)

for each hazardous substance release claimed to qualify for reporting under CERCLA section 103(f)(2), the following information:

the name/identity of the hazardous substance; the CAS Registry Number for the substance (if available); and, if the substance being released is a mixture, the components of the mixture and their approximate concentrations and quantities, by weight

the upper and lower bounds of the normal range of the release (in pounds or kilograms) over the previous year

the source(s) of the release (e.g., valves, pump seals, storage tank vents, stacks). If the release is from a stack, the stack height (in feet or meters)

the frequency of the release and the fraction of the release from each release source and the specific period over which it occurs

a brief statement describing the basis for stating that the release is continuous and stable in quantity and rate

an estimate of the total annual amount that was released in the previous year (in pounds or kilograms)

the environmental medium affected by the release, such as the name of the surface water body; the stream order or average flowrate (in cubic feet/second) and designated use; the surface area (in acres) and average depth (in feet or meters) of the lake; the location of public water supply wells within 2 mi if on or underground

a signed statement that the hazardous substance release described is continuous and stable in quantity and rate and that all reported information is accurate and current to the best knowledge of the person in charge.

Verify that, within 30 days of the first anniversary date of the initial written notification, each hazardous substance release reported is evaluated to verify and update the information submitted in the initial written notification.

Verify that the followup notification contains all the information required in the initial notification, plus notification of changes in the release not otherwise reported.

(NOTE: Instead of the initial written report or follow-up report, a copy of the Toxic Release Inventory (TRI) form submitted under SARA Title III section 313 for the previous 1 July may be used if the following information is added:

the population density within a 1 mi radius of the facility or vessel described in terms of the following ranges: 0-50 persons, 51-100 persons, 101-500 persons, 501-1,000 persons, more than 1,000 persons

the identify and location of sensitive populations and ecosystems within a 1-mi radius of the facility or vessel (e.g., elementary schools, hospitals,

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retirement communities, or wetlands) the following information for each hazardous substance release that

qualifies for reporting under CERCLA section 103(f)(2): the upper and lower bounds of the normal range of the release over

the previous year the frequency of the release and the fraction of the release from each

release source and the specific period over which it occurs a brief statement describing the basis for stating that the release is

continuous and stable in quantity and rate a signed statement that the release is continuous and stable in quantity

and rate and that all reported information is accurate and current to the best knowledge of the person in charge.)

(NOTE: If there is a change in any information submitted in the initial written notification or the followup notification other than a change in the source, composition, or quantity of the release, the person in charge of the facility or vessel shall provide written notification of the change to the USEPA Region for the geographical area where the facility or vessel is located, within 30 days of determining that the information submitted previously is no longer valid. Notification shall include the reason for the change, and the basis for stating that the release is continuous and stable under the changed conditions. Notification of changes shall include the case number assigned by the NRC or the USEPA and also the signed certification statement.)

Verify that notification of a statistically significant increase in a release is made to the NRC as soon as there is knowledge of the release.

(NOTE: A determination of whether an increase is a “statistically significant increase” shall be made based upon calculations or estimation procedures that will identify releases that exceed the upper bound of the reported normal range.)

Verify that each hazardous substance release is evaluated annually to determine if changes have occurred in the information submitted in the initial written notification, the followup notification, and/or in a previous change notification.

(NOTE: Where necessary to satisfy the requirements of this section, the person in charge may rely on recent release data, engineering estimates, the operating history of the facility or vessel, or other relevant information to support notification. All supporting documents, materials, and other information shall be kept on file at the facility, or in the case of a vessel, at an office within the United States in either a port of call, a place of regular berthing, or the headquarters of the business operating the vessel.)

Verify that supporting materials are kept on file for a period of 1 yr and that they substantiate the reported normal range of releases, the basis for stating that the release is continuous and stable in quantity and rate, and the other information in the initial written report, the followup report, and the annual evaluations.

(NOTE: Multiple concurrent releases of the same substance occurring at various

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locations with respect to contiguous plants or installations upon contiguous grounds that are under common ownership or control may be considered separately or added together in determining whether such releases constitute a continuous or a statistically significant release; whichever approach is elected for purposes of determining whether a release is continuous also must be used to determine a statistically significant increase in the release.)

HM.20.4.US. When there is a release of an RQ of any extremely hazardous substance (EHS) or CERCLA hazardous substance, emergency release notification is required (40 CFR 355.30, 355.31, 355.32, 355.33, 355.41, 355.42, 355.43, 355.40, 355.60 and Appendix A) [Revised April 1999; Revised July 2000; Reviewed March 2001; Revised October 2006; Citation Revised January 2007; Revised January 2009)

(NOTE: The emergency release notification requirements of 40 CFR 355 are in addition to the release notification requirements of CERCLA. If the facility has a release of a CERCLA hazardous substance, the facility must comply with the emergency release notification requirements of 40 CFR 355 and the release notification requirements of CERCLA section 103, codified at 40 CFR 302 [see checklist items HM.20.2.US and HM.20.3.US]. See Appendix 3-0 for a chart comparing the emergency release notification requirements of 40 CFR 355 and CERCLA)

Verify that, if there is a release of a reportable quantity (RQ) of an EHS or CERCLA hazardous substance within any 24-h period, the emergency release notification requirements are triggered.

(NOTE: RQs for EHSs are listed in Appendix 3-1. The EPA's October 2006 Consolidated List of Chemicals Subject to the Emergency Planning and Community Right-to-Know Act (EPCRA) and Section 112(r) of the Clean Air Act is online and searchable at http://yosemite.epa.gov/oswer/lol.nsf/homepage.) Verify that an immediate, oral, notification is made, and as soon as practicable thereafter a written follow-up emergency notification (or notifications, as more information becomes available).

Verify that the immediate notification includes as much of the following information known at the time:

the chemical name or identity of any substance involved in the release indicate whether the substance is an EHS provide an estimate of the quantity of any such substance that was

released into the environment state the time and duration of the release the medium or media into which the release occurred any known or anticipated acute or chronic health risks associated with the

emergency and, where appropriate, advice regarding medical attention necessary for exposed individuals

proper precautions to take as a result of the release, including evacuation (unless such information is readily available to the community emergency coordinator pursuant to the emergency plan)

the name and telephone number of the individual (or individuals) to be contacted for further information.

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(NOTE: The retrieval of the above information for immediate notification should not cause a delay in the notification on the emergency response.)

Verify that, except for releases that occur during transportation or from storage incident to transportation, the facility provides a written follow-up emergency notice (or notices, as more information becomes available), as soon as practicable after the release.

Verify that, in the written follow-up emergency notice, the facility provides and updates the information required in the immediate notification and includes additional information with respect to all of the following:

actions taken to respond and contain the release any known or anticipated acute or chronic health risks associated with the

release where appropriate, advice regarding medical attention necessary for

exposed individuals.

(NOTE: The facility is not required to submit a written follow-up notification for a release that occurred during transportation or from storage incident to transportation. For a release that occurs during transportation or from storage incident to transportation, the facility may meet the emergency notification requirements by notifying the 911 operator (or in the absence of a 911 emergency telephone number, the operator) of the immediate notification information listed above. )

Verify that the immediate emergency release notification information and the written follow-up are provided to:

the community emergency coordinator for the LEPC of any area likely to be affected by the release (if there is no LEPC, notify the relevant local emergency response personnel)

the SERC of any State likely to be affected by the release.

(NOTE: If the release of an EHS or CERCLA hazardous substance is continuous and stable in quantity and rate at the facility as defined in 40 CFR 302.8(b) [see checklist item HM.20.3.US], then the release qualifies for reduced reporting requirements. Under reduced reporting requirements, the facility does not need to provide the immediate or the followup notifications. However, in addition to the notifications required under 40 CFR 302.8 [see checklist item HM.20.3.US] , the facility must make all of the following notifications to the community emergency coordinator for the LEPC for any area likely to be affected by the release and to the SERC of any State likely to be affected by the release:

initial notifications as specified in 40 CFR 302.8(d) and 302.8(e) notification of a “statistically significant increase,” defined in 40 CFR

302.8(b) as any increase above the upper bound of the reported normal range

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notification of a “new release” as specified in 40 CFR 302.8(g)(1) notification of a change in the normal range of the release as specified

under 40 CFR 302.8(g)(2).)

(NOTE: Emergency release notification is not required for any of the following types of releases of EHSs or CERCLA hazardous substances that occur at a facility:

any release that results in exposure to persons solely within the boundaries of your facility

any release that is a federally permitted release as defined in section 101(10) of CERCLA

any release of a pesticide product that is exempt from reporting under section 103(e) of CERCLA

any release that does not meet the definition of release under section 101(22) of CERCLA and is therefore exempt from CERCLA section 103(a) reporting

any radionuclide release that occurs: naturally in soil from land holdings such as parks, golf courses, or

other large tracts of land naturally from land disturbance activities, including farming,

construction, and land disturbance incidental to extraction during mining activities, except that which occurs at uranium, phosphate, tin, zircon, hafnium, vanadium, monazite, and rare earth mines

from the dumping and transportation of coal and coal ash (including fly ash, bottom ash, and boiler slags), including the dumping and land spreading operations that occur during coal ash uses

from piles of coal and coal ash, including fly ash, bottom ash, and boiler slags

any release less than 1,000 pounds per 24 h of nitrogen oxide or nitrogen dioxide to the air which is the result of combustion and combustion related activities.)

(NOTE: Land disturbance incidental to extraction includes: land clearing; overburden removal and stockpiling; excavating, handling, transporting, and storing ores and other raw (not beneficiated or processed) materials; and replacing in mined-out areas coal ash, earthen materials from farming or construction, or overburden or other raw materials generated from the exempted mining activities.)

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HM.25

EMERGENCY PLANNING

HM.25.1.US. When extremely hazardous substances (EHS) are present in amounts equal to or greater than their threshold planning quantity (TPQ) or the facility has been designated for emergency planning purposes, specific emergency planning procedures are required to be followed (40 CFR 355.10, 355.11, 355.13, 355.14, 355.15, 355.16, 355.20 and 355.21) [Revised April 1999; Revised July 2000; Reviewed March 2001; Citation Revised January 2007; Citation Revised July 2007; Revised January 2009].

(NOTE: This checklist item applies if the facility meets either of the following two conditions:

any EHS is present at the facility in an amount equal to or greater than its TPQ [See Appendix 3-1, plus, the EPA's October 2006 Consolidated List of Chemicals Subject to the Emergency Planning and Community Right-to-Know Act (EPCRA) and Section 112(r) of the Clean Air Act is online and searchable at http://yosemite.epa.gov/oswer/lol.nsf/homepage]

the facility has been designated for emergency planning purposes, after public notice and opportunity for comment, by one of the following three entities: the State Emergency Response Commission (SERC) the Governor of the State in which your facility is located the Chief Executive Officer of the Tribe for the Indian Tribe under

whose jurisdiction the facility is located.If a facility is designated for emergency planning purposes, substances that are not EHSs at this facility may become subject to the emergency planning requirements.)

Verify that the SERC and the LEPC are notified that the facility is subject to emergency planning requirements for EHSs within 60 days after the facility first becomes subject to EHS emergency planning requirements.

Verify that the facility designates a representative who will participate in the local emergency planning process as a facility emergency response coordinator.

Verify that the facility notifies the LEPC (or the SERC if there is no LEPC, or the Governor if there is no SERC) who the facility emergency response coordinator is within 60 days after the facility first becomes subject to EHS emergency planning requirements.

Verify that, if no LEPC exists for the facility at the time the facility is required to provide emergency planning notification and identification of the emergency response coordinator, the facility reports to the LEPC within 30 days after an LEPC is established for the emergency planning district in which the facility is located.

Verify that the facility notifies the LEPC of any changes occurring at the facility that may be relevant to emergency planning within 30 days of the change.

(NOTE: The facility must provide to the LEPC any information necessary for developing and implementing the local emergency plan upon the request of the LEPC.)

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(NOTE: EPA does not require any specific format. EPA recommends that the facility submits the required information in writing in order to insure appropriate documentation. The SERC or LEPC may request that information be submitted in a specific format.)

(NOTE: If an EHS is present in a mixture in a particular container, determine the quantity (in pounds) of the EHS in that container by multiplying the concentration of the EHS (in weight percent) by the weight (in pounds) of the mixture in the container. If the concentration of an EHS is less than or equal to one percent in the mixture, the facility does not have to count that EHS.)

(NOTE: You must aggregate (i.e., add together) the amounts of each EHS at the facility to determine if a TPQ is present. This means that, for a particular EHS, the facility must determine the total amount present at any one time at the facility by adding together the quantity of pure EHS and the quantity contained in all mixtures, regardless of location, number of containers, or method of storage. The facility does not have to count an EHS in a mixture if the concentration of that EHS is less than or equal to one percent.)

(NOTE: EHSs that are in solid form are subject to one of two different TPQs (for example, TPQs may be listed as 500/10,000 pounds), both of which are listed in Appendix 3-1 [EPA's October 2006 Consolidated List of Chemicals Subject to the Emergency Planning and Community Right-to-Know Act (EPCRA) and Section 112(r) of the Clean Air Act is online and searchable at http://yosemite.epa.gov/oswer/lol.nsf/homepage]. Here is how to determine which of the two listed TPQs must be used for an EHS present at the facility in solid form:

use the lower TPQ from Appendix 3-1 if the solid meets one of the following: is in powdered form and has a particle size less than 100 microns is in solution is in molten form meets the criteria for a National Fire Protection Association (NFPA)

rating of 2, 3 or 4 for reactivity. if the solid does not meet one of the above criteria, then the TPQ is

10,000 pounds. For the three forms of solids use the following instructions to determine the quantity of EHS present:

solid in powdered form with a particle size less than 100 microns: multiply the weight percent of solid with a particle size less than 100 microns in a particular container by the total weight of solid in the container

solid in solution: multiply the weight percent of solid in solution in a particular container by the total weight of solution in the container

solid in molten form: multiply the weight of solid in molten form by 0.3.)

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HM.30

RIGHT-TO-KNOW

HM.30.1.US. Facilities are required to report certain hazardous chemicals when they are present in amounts above the regulatory threshold levels (40 CFR 370.10, 370.12, 370.13, 370.14, 370.30, 370.31, 370.32, 370.33, and 370.60) [Revised April 1999; Revised July 2000; Revised March 2001; Citation Revised January 2007; Citation Revised July 2007; Revised January 2009].

Verify that the facility reports any hazardous chemical for which they are required to prepare or have available an MSDS under OSHA Hazard Communication Standard that is present at the facility in amounts equal to or above the applicable threshold levels (see NOTE below) by either:

submitting an MSDS for each hazardous chemical present at the facility that meets or exceeds its applicable threshold level

submitting a list of all hazardous chemicals present at the facility at or above the applicable threshold levels with the hazardous chemicals grouped by Hazard Category and the list contains the chemical or common name of each hazardous chemical as provided on the MSDS.

Verify that, while MSDS reporting is a one-time requirement, the information is updated in all of the following ways:

submitting a revised MSDS after discovering significant new information concerning a hazardous chemical for which an MSDS was submitted

submitting an MSDS, or a list, for any new hazardous chemical for which the facility become subject to these reporting requirements

submitting, as requested by the LEPC, an MSDS for any hazardous chemical present at the facility which you have not already submitted a MSDS.

Verify that the MSDS or list (new or revised) are submitted to the LEPC, the SERC, and the fire department with jurisdiction over the facility within 3 mo after first becoming subject to the reporting requirements.

Verify that , for a mixture containing a hazardous chemical, the table in Appendix 3-0a is used to determine if a reporting threshold is equaled or exceeded, and to determine how to report.

Verify that, for each specific mixture, the reporting option used is consistent for both MSDS and inventory reporting, unless it is not possible to do so.

(NOTE: This means that if the facility reports on a specific mixture as a whole for MSDS reporting, report on that mixture as a whole for inventory reporting too (unless it is not possible).)

(NOTE: To determine the quantity of an EHS or a non-EHS hazardous chemical component present in a mixture, multiply the concentration of the hazardous chemical component (in weight percent) by the weight of the mixture (in pounds). It is not necessary to count a hazardous chemical present in a mixture if the concentration is less than or equal to 1%, or less than or equal to 0.1% for

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a carcinogenic chemical.)

(NOTE: The EPA has not issued a list of hazardous chemicals subject to this reporting requirement. A substance is a hazardous chemical if it is required to have an MSDS and meets the definition of hazardous chemical under the OSHA regulations found at 29 CFR 1910.1200(c). See checklist item HM.1.2.US for more detailed information on MSDS requirements.)

(NOTE: The threshold levels for reporting are as follows: a hazardous chemical that is an Extremely Hazardous Substance (EHS) is

present at the facility at any one time in an amount equal to or greater than 500 lbs (227 kg--approximately 55 gal) or the Threshold Planning Quantity (TPQ), whichever is lower (EHSs and their TPQs are listed in Appendices A and B of 40 CFR 355)

a hazardous chemical that is not an EHS is present at the facility at any one time in an amount equal to or greater than the threshold level for that hazardous chemical and the threshold level for hazardous chemicals that do not meet the following criteria is 10,000 lbs (or 4,540 kg): for gasoline at a retail gas station, the threshold level is 75,000 gal

(approximately 283,900 L) for diesel fuel at a retail gas station the threshold level is 100,000 gal

(approximately 378,500 L).

(NOTE: A retail gas station means a retail facility engaged in selling gasoline and/or diesel fuel principally to the public, for motor vehicle use on land.)

(NOTE: The threshold levels at retail gas stations include all grades of gasoline or diesel combined as applicable. The threshold levels at retail gas stations also only apply for gasoline or diesel that was in tank(s) entirely underground and was in compliance at all times during the preceding calendar year with all applicable UST requirements at 40 CFR 280 or requirements of the EPA-approved state UST program)

Verify that, regardless of the threshold levels of hazardous chemicals at the facility, if the LEPC requests that the facility submit an MSDS for a hazardous chemical, the facility submits the MSDS within 30 days of the request.

Verify that, regardless of the threshold levels of hazardous chemicals at the facility, if the LEPC, SERC, or the fire department with jurisdiction over the facility requests that the facility submits Tier II information, the facility submits the Tier II Information.

(NOTE: In general, facilities are not required to report substances for which they are not required to have an MSDS under the OSHA regulations, or that are excluded from the definition of hazardous chemical under EPCRA section 311(e). Each of the following substances are excluded under EPCRA section 311(e):

any food, food additive, color additive, drug, or cosmetic regulated by the

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Food and Drug Administration any substance present as a solid in any manufactured item to the extent

exposure to the substance does not occur under normal conditions of use any substance to the extent it is used:

for personal, family, or household purposes, or is present in the same form and concentration as a product packaged for distribution and use by the general public

in a research laboratory or hospital or other medical facility under the direct supervision of a technically qualified individual

in routine agricultural operations or is a fertilizer held for sale by a retailer to the ultimate customer.)

(NOTE: “Present in the same form and concentration as a product packaged for distribution and use by the general public” means a substance packaged in a similar manner and present in the same concentration as the substance when packaged for use by the general public, whether or not it is intended for distribution to the general public or used for the same purpose as when it is packaged for use by the general public.)

(NOTE: Any person may obtain an MSDS for a specific facility by writing to the LEPC and asking for it. If the LEPC has the MSDS, it must provide it to the person making the request. If the LEPC does not have the MSDS, it must request the MSDS from the facility's owner or operator.)

HM.30.2.US. When applicable, inventory information (Tier I and Tier II inventory forms) must be submitted annually by March 1 (40 CFR 370.10, 370.40, 370.41, 370.42, 370.44, 370.45, and 370.61) [Revised April 1999; Revised March 2001; Citation Revised January 2007; Citation Revised July 2007; Revised January 2009].

Verify that the facilities which are required to report any hazardous chemical for which they are required to prepare or have available an MSDS under OSHA Hazard Communication Standard that is present at the facility in amounts equal to or above the applicable threshold levels (see checklist item HM.30.1.US) submit inventory information by March 1 of every year to the SERC, LEPC, and fire department with jurisdiction over the facility.

Verify that the inventory information addresses any hazardous chemical present at the facility at any time during the previous calendar year in an amount equal to or in excess of its threshold level.

(NOTE: Tier I information is the minimum information that must be reported to be in compliance with the inventory reporting requirements.)

Verify that, if the facility is reporting Tier I information, the facility reports aggregate information on hazardous chemicals by hazard categories.

(NOTE: There are two health hazard categories and three physical hazard categories for purposes of reporting, see the definitions.)

(NOTE: EPA publishes Tier I and Tier II Inventory Forms that provide uniform formats for reporting the Tier I and Tier II information. You may use a State or local format for reporting inventory information if the State or local format

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contains at least the required Tier I information. EPA's Tier I and Tier II forms are available at http://www.epa.gov/emergencies.) Verify that Tier I information includes all of the following:

certification by the owner or operator or the officially designated representative of the owner or operator that all information included in the Tier I submission is true, accurate, and complete as follows: “I certify under penalty of law that I have personally examined and

am familiar with the information and that based on my inquiry of those individuals responsible for obtaining the information, I believe that the submitted information is true, accurate, and complete''

the certification is accompanied by the owner/operators’ full name, official title, original signature, date signed, and total number of pages in the submission including all attachments

the owner/operators’ signature or signature stamp, the date the certification was signed, and the total number of pages in the submission on all other pages

the calendar year for the reporting period the complete name (and company identifier where appropriate) and

address of the facility, including the full street address or state road, the city, county, State and zip code

the North American Industry Classification System (NAICS) code for the facility

the Dun & Bradstreet number of the facility the owner's or operator's full name, mailing address, and phone number the name, title, and phone number(s) of at least one local individual or

office that can act as a referral if emergency responders need assistance in responding to a chemical accident at the facility

an emergency phone number where emergency information will be available 24 h a day, every day

an indication whether the information being reported is identical to that submitted the previous year

an estimate (in ranges) of the maximum amount of hazardous chemicals in each hazard category present at the facility at any time during the preceding calendar year using codes that correspond to different ranges

an estimate (in ranges) of the average daily amount of hazardous chemicals in each hazard category present at the facility during the preceding calendar year using codes that correspond to different ranges

the maximum number of days that any single hazardous chemical within each hazard category was present at the facility during the reporting period

the general location of hazardous chemicals in each hazard category within the facility, listing the locations of all applicable chemicals, or submit a site plan and list the site coordinates to indicate the locations of the chemicals.

(NOTE: For information on weight range codes, storage type codes, and storage

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condition codes, see Appendix 3-0b)

(NOTE: The facility may choose to report the Tier II information for any hazardous chemical at the facility.)

Verify that Tier II information is submitted to the SERC, LEPC, or fire department having jurisdiction over the facility within 30 days after a request from the SERC, LEPC, or the fire department.

Verify that if the facility is reporting Tier II information, it must include:

certification by the owner or operator or the officially designated representative of the owner or operator that all information included in the Tier II submission is true, accurate, and complete as follows: “I certify under penalty of law that I have personally examined and

am familiar with the information and that based on my inquiry of those individuals responsible for obtaining the information, I believe that the submitted information is true, accurate, and complete”

the certification is accompanied by the owner/operators’ full name, official title, original signature, date signed, and total number of pages in the submission including all Confidential and Non-Confidential Information Sheets and all attachments

the owner/operators’ signature or signature stamp, the date the certification was signed, and the total number of pages in the submission on all other pages

the calendar year for the reporting period the complete name (and company identifier where appropriate) and

address of the facility, including the full street address or state road, the city, county, State and zip code

the North American Industry Classification System (NAICS) code for the facility

the Dun & Bradstreet number of the facility the owner's or operator's full name, mailing address, and phone number the name, title, and phone number(s) of at least one local individual or

office that can act as a referral if emergency responders need assistance in responding to a chemical accident at the facility

an emergency phone number where emergency information will be available 24 h a day, every day

an indication whether the information being reported is identical to that submitted the previous year

for each hazardous chemical that the facility are required to report, the following: the chemical name or the common name of the chemical as provided

on the MSDS and its Chemical Abstract Service (CAS) registry number (NOTE: If the name is being withheld in accordance with trade secret criteria, provide the generic class or category that is structurally descriptive of the chemical and indicate that the name is withheld because of trade secrecy

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indicate whether the chemical is: pure or mixture; solid, liquid, or gas; and whether the chemical is or contains an EHS

if the chemical is a mixture containing an EHS, provide the chemical name of each EHS in the mixture

indicate which hazard categories apply to the chemical (see definitions)

provide an estimate (in ranges) of the maximum amount of the hazardous chemical present at the facility on any single day during the preceding calendar year using codes that correspond to different ranges

provide an estimate (in ranges) of the average daily amount of the hazardous chemical present at the facility during the preceding calendar year using codes that correspond to different ranges

the maximum number of days that the hazardous chemical was present at the facility during the preceding calendar year

a brief description of the precise location of the hazardous chemical at the facility or attach a site plan that notes locations, coordinates or a list of site coordinate abbreviations where hazardous chemicals are located

a brief description of the manner of storage of the hazardous chemical, including container type, temperature and pressure, a description of dikes and other safeguard measures for each location listed including codes that correspond to different storage types and temperature and pressure conditions.

(NOTE: The threshold levels for reporting are as follows: a hazardous chemical that is an Extremely Hazardous Substance (EHS) is

present at the facility at any one time in an amount equal to or greater than 500 lbs (227 kg--approximately 55 gal) or the Threshold Planning Quantity (TPQ), whichever is lower (EHSs and their TPQs are listed in Appendices A and B of 40 CFR 355)

a hazardous chemical that is not an EHS is present at the facility at any one time in an amount equal to or greater than the threshold level for that hazardous chemical and the threshold level for hazardous chemicals that do not meet the following criteria is 10,000 lbs (or 4,540 kg): for gasoline at a retail gas station, the threshold level is 75,000 gal

(approximately 283,900 L) for diesel fuel at a retail gas station the threshold level is 100,000 gal

(approximately 378,500 L). (NOTE: Under EPCRA section 324, the facility may choose to withhold from disclosure to the public the location information for a specific chemical. If the facility chooses to withhold the location information from disclosure to the public, the facility must clearly indicate that the information is “confidential” and provide the confidential location information on a separate sheet from the other Tier II information (which will be disclosed to the public), and attach the Confidential Location Information Sheet to the other Tier II information. If the specific location for which you are reporting storage conditions is a

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“confidential” location, then the facility must report the storage conditions on a separate Confidential Location Information Sheet.)

(NOTE: Any person may request Tier II information for a specific facility by writing to the SERC or the LEPC and asking for such information. If the SERC or LEPC has the Tier II information, the SERC or LEPC must provide it to the person making the request. If the SERC or LEPC does not have the Tier II information, it must request it from the facility owner or operator in either of the following cases:

the person making the request is a State or local official acting in his or her official capacity

the request is for hazardous chemicals in amounts greater than 10,000 lb stored at the facility at any time during the previous calendar year.

If the SERC or LEPC does not have the Tier II information, it may request it from the facility owner or operator when neither of the above 2 conditions is met, but the person's request includes a general statement of need. A SERC or LEPC must respond to a request for Tier II information under this section within 45 days of receiving such a request.)

HM.30.3.US. Facilities that manufacture, process, or otherwise use a toxic chemical (see Appendix 3-1) in excess of applicable threshold quantities and that have 10 or more employees are subject to certain reporting and recordkeeping requirements (40 CFR 372.10(a), 372.10(c), 372.10(d), 372.22 through 372.38; Instructions for Implementing EO 13423, Section VII, paragraph C) [Revised January 2000; Revised July 2000; Revised March 2001; Citation Revised January 2007; Revised April 2007; Citation Revised July 2007; Revised July 2008].

(NOTE: Federal agencies are required to comply with these provisions without regard to the Standard Industrial Classification (SIC) or North American Industrial Classification System (NAICS) delineations.)

(NOTE: These reporting and recordkeeping requirements apply to facilities that meet all of the following criteria for a calendar year:

the facility has ten or more full-time employees the facility is in a Standard Industrial Classification (SIC) (as in effect on

January 1, 1987) major group or industry code listed in 40 CFR 372.23(a) [see text], for which the corresponding North American Industry Classification System (NAICS) (as in effect on January 1, 2007, for reporting year 2008 and thereafter) subsector and industry codes are listed in 40 CFR 372.23(b) and 372.23(c) [see text] by virtue of the fact that it meets one of the following criteria: the facility is an establishment with a primary SIC major group or

industry code in the above list the facility is a multi-establishment complex where all establishments

have primary SIC major group or industry codes in the above list the facility is a multi-establishment complex in which one of the

following is true: the sum of the value of services provided and/or products shipped and/or produced from those establishments that have primary SIC major group or industry codes in the above list is greater than 50 percent of the total value of all services provided and/or products shipped from and/or produced by all establishments at the facility one establishment having a primary SIC major group or industry code in the above list contributes more in terms of value of services provided and/or products shipped from and/or

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produced at the facility than any other establishment within the facility

the facility manufactured (including imported), processed, or otherwise used a toxic chemical in excess of an applicable threshold quantity of that chemical.)

(NOTE: The following are the threshold levels for a facility that is manufacturing (including importing), processing, or otherwise using a toxic chemical:

has manufactured or processed 25,000 lb/yr of toxic chemicals, except for persistent bioaccumulative toxic (PBT) chemicals

has otherwise used over 10,000 lb of toxic chemicals in other ways during the year, except for PBT chemicals

for the chemicals listed in Appendix 3-1a, the amounts indicated in the appendix.)

(NOTE: Articles containing toxic chemicals are not included in calculations of total toxic chemical present. See 40 CFR 372.30(b)(3) for procedure to determine whether an excess has occurred.)

Verify that a completed USEPA Form R, (USEPA Form 9350-1) is submitted annually to the USEPA and state on or before 1 July of the next year for each toxic chemical known by the facility owner or operator to be manufactured (including imported) or otherwise used and exceeding threshold levels in one calendar year.

Verify that USEPA Form R Schedule 1 (EPA Form 9350-3) is submitted for dioxin and dioxin-like compounds category.

(NOTE: A copy of Form R is available at http://www.epa.gov/tri/report.htm.)

(NOTE: The owner or operator of a facility regulated under 40 CFR 372 is required to complete and submit USEPA Form R, as described above, for a toxic chemical that is present as a component of a mixture or trade name product which the owner or operator receives from another person, if that chemical is imported, processed, or otherwise used by the owner or operator in excess of an applicable threshold quantity at the facility as part of that mixture or trade name product.)

(NOTE: The owner or operator or a facility at which a toxic chemical was manufactured (including imported), processed or otherwise used in excess of an applicable threshold quantity may submit a separate Form R for each establishment or for each group of establishments within the facility to report the activities involving the toxic chemical at each establishment or group of establishments, provided that activities involving the toxic chemical at all the establishments within the covered facility are reported. See 40 CFR 372.30(c) for instruction and procedures regarding alternatives for reporting when the facility consists of more than one establishment.)

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(NOTE: A facility may apply an alternate threshold of 1 million pounds per year to that chemical if it is calculated that the facility would have

no more than 2,000 lb of total on-site and off-site disposal or other releases (including disposal or other releases that resulted from catastrophic events)

an annual reportable amount of that toxic chemical not exceeding 5,000 lb for the combined total quantities released at the facility; disposed within the facility; treated for destruction at the facility; recovered at the facility as a result of recycling operations; combusted for the purpose of energy recovery at the facility; transferred from the facility to off-site locations for the purpose of

recycling, energy recovery, treatment, and/or disposal; and managed as a result of remedial actions, catastrophic events, or one-time events not associated with production processes during the reporting year..)

For chemical of special concern (see Appendix 3-1a) the facility may apply an alternate threshold of 1 million lb/yr to that chemical if the owner or operator calculates that the facility would have:

zero on-site and off-site disposal or other releases (including disposal or other releases that resulted from catastrophic events)

an “Annual Reportable Amount of a Chemical of Special Concern” not exceeding 500 lb.

The “Annual Reportable Amount of a Chemical of Special Concern: is the combined total of:

quantities treated for destruction at the facility quantities recovered at the facility as a result of recycling operations quantities combusted for the purpose of energy recovery at the facility quantities transferred from the facility to off-site locations for the purpose

of recycling, energy recovery, and/or treatment quantities managed through recycling, energy recovery, or treatment for

destruction that were the result of remedial actions, catastrophic events, or one-time events not associated with production processes during the reporting year.)

Verify that, if a facility uses the alternate reporting threshold, the facility owner or operator submits the required certification statement that contains the following information instead of the USEPA Form R:

reporting year an indication of whether the chemical identified is being claimed as trade

secret chemical name and CAS number (if applicable) of the chemical, or the

category name signature of a senior management official certifying the following:

pursuant to 40 CFR 372.27, “I hereby certify that to the best of my knowledge and belief for the toxic chemical listed in this statement, the annual reportable amount, as defined in 40 CFR 372.27(a), did not exceed 500 lb for this reporting year and that the chemical was manufactured, or processed, or otherwise used in an amount not exceeding 1 million pounds

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during this reporting year” date signed facility name and address mailing address of the facility if different than the above toxic chemical release inventory facility identification number if known name and telephone number of a technical contact the four-digit SIC codes for the facility or establishments in the facility latitude and longitude coordinates for the facility Dun and Bradstreet number of the facility USEPA identification number(s) (RCRA) I.D. Number(s) of the facility facility NPDES permit number(s) underground Injection Well Code (UIC) I.D. Number(s) of the facility name of the facility's parent company parent company's Dun and Bradstreet Number.

Verify that, when more than one threshold applies to facility activities, the facility reports if it exceeds any applicable threshold and reports on all activities at the facility involving the chemical unless otherwise exempted.

Verify that, when a facility manufactures, processes, or otherwise uses more than one member of a chemical category listed in 40 CFR 372.65(c), the facility reports if it exceeds any applicable threshold for the total volume of all the members of the category involved in the applicable activity and the report covers all activities at the facility involving members of the category.

(NOTE: A facility may process or otherwise use a toxic chemical in a recycle/reuse operation. To determine whether the facility has processed or used more than an applicable threshold of the chemical, the owner or operator of the facility counts the amount of the chemical added to the recycle/reuse operation during the calendar year. In particular, if the facility starts up such an operation during a calendar year, or in the event that the contents of the whole recycle/reuse operation are replaced in a calendar year, the facility also counts the amount of the chemical placed into the system at these times.)

(NOTE: The following exemptions apply: if a toxic chemical is present in a mixture of chemicals at a covered facility

and the toxic chemical is in a concentration in the mixture which is below 1 percent of the mixture, or 0.1 percent of the mixture in the case of a toxic chemical which is a carcinogen, the quantity of the toxic chemical present in such mixture does not have to be considered when determining whether an applicable threshold has been met or determining the amount of release to be reported under. This exemption applies whether the person received the mixture from another person or the person produced the mixture, either by mixing the chemicals involved or by causing a chemical reaction that resulted in the creation of the toxic chemical in the mixture. However, this exemption applies only to the quantity of the toxic chemical present in the mixture. If the toxic chemical is also manufactured (including imported), processed, or otherwise used at the covered facility other than as part of the

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mixture or in a mixture at higher concentrations, in excess of an applicable threshold quantity, the facility is required to report. This exemption does not apply to the chemicals listed in Appendix 3-1a

if a toxic chemical is present in an article at a covered facility, the quantity of the toxic chemical present in such article does not have to be considered when determining whether an applicable threshold has been met or determining the amount of release to be reported. This exemption applies whether the facility received the article from another facility or produced the article. However, this exemption applies only to the quantity of the toxic chemical present in the article. If the toxic chemical is manufactured (including imported), processed, or otherwise used at the covered facility other than as part of the article, in excess of an applicable threshold quantity, reporting is required. If a release of a toxic chemical occurs as a result of the processing or use of an item at the facility, that item does not meet the definition of “article”

if a toxic chemical is used at a covered facility for one of the following purposes, it is not required to consider the quantity of the toxic chemical used for such purpose when determining whether an applicable threshold has been met under or determining the amount of releases to be reported. However, this exemption only applies to the quantity of the toxic chemical used for the purpose described in the following list. If the toxic chemical is also manufactured (including imported), processed, or otherwise used at the covered facility other than as listed, in excess of an applicable threshold quantity, reporting is required. The list includes:

use as a structural component of the facility use of products for routine janitorial or facility grounds maintenance personal use by employees or other persons at the facility of foods,

drugs, cosmetics, or other personal items containing toxic chemicals, including supplies of such products within the facility such as in a facility-operated cafeteria, store, or infirmary

use of products containing toxic chemicals for the purpose of maintaining motor vehicles operated by the facility

use of toxic chemicals present in process water and non-contact cooling water as drawn from the environment or from municipal sources

toxic chemicals present in air used either as compressed air or as part of combustion.

if a toxic chemical is manufactured, processed, or used in a laboratory at a covered facility under the supervision of a technically qualified individual, the laboratory is not required to consider the quantity so manufactured, processed, or used when determining whether an applicable threshold has been met or determining the amount of release to be reported.)

Verify that the following records are kept 3 yr from the date of the submission of USEPA Form R:

a copy of each Form R report submitted all supporting materials and documentation used by the person to make the

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compliance determination that the facility or establishments is a covered facility

documentation supporting the submitted report, including: documentation supporting any determination that a claimed allowable

exemption under 40 CFR 372.38 applies data supporting the determination of whether a threshold applies for

each toxic chemical documentation supporting the calculations of the quantity of each

toxic chemical released to the environment or transferred to an offsite location

documentation supporting the use indications and quantity onsite reporting for each toxic chemical, including dates of manufacturing, processing, or use

documentation supporting the basis of estimate used in developing any release or offsite transfer estimates for each toxic chemical

receipts or manifests associated with the transfer of each toxic chemical in waste to offsite locations

documentation supporting reported waste treatment methods, estimates of treatment efficiencies, ranges of influent concentration to such treatment, the sequential nature of treatment steps, if applicable, and the actual operating data, if applicable, to support the waste treatment efficiency estimate for each toxic chemical.

Verify that the following records are maintained for 3 yr at the facility to which the report applies or from which supplier notification was provided:

all supporting materials and documentation used to determine if supplier notification is required

all supporting materials and documentation used in developing each required supplier notification and a copy of each notification.

Verify that, if it has been determined the alternate threshold may be applied, the following records are kept for 3 yr from the date of submission of the required certification statement:

a copy of each certification statement submitted all supporting materials and documentation used to make the compliance

determination that the facility or establishment is eligible to apply the alternate threshold

documentation supporting the certification statement submitted, including: data supporting the determination of whether the alternate threshold

applies for each toxic chemical documentation supporting the calculation of annual reportable

amount, for each toxic chemical, including documentation supporting the calculations and the calculations of each data element combined for the annual reportable amount

receipts or manifests associated with the transfer of each chemical in waste to offsite locations.

3-60Hazardous Materials

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3-61Hazardous Materials

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3-62Hazardous Materials

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FLAMMABLE/ COMBUSTIBLE LIQUIDS STORAGE

HM.35General

HM.35.1.US. Specific management practices should be considered when storing and handling flammable/combustible materials (MP) [Revised April 1995].

Verify that the following management practices are followed:

items are not stored against pipes or coils producing heat paint drums that are stored horizontally are rolled a half turn every 90 days containers of paint are palletized prior to storage aerosol containers are stored in well-ventilated areas.

HM.35.2.US. Drums and other containers of less than 60 gal individual capacity and portable tanks less than 660 gal individual capacity, used to store flammable or combustible materials, are required to meet specific standards (29 CFR 1910.106(d)(1) and 1910.106(d)(2)).

Verify that flammable and combustible liquid containers meet the constraints out lined in Appendix 3-2, except that glass or plastic containers of no more than 1 gal capacity may be used for a Class IA or IB flammable liquid if:

the liquid would be rendered unfit for its intended use by contact with metal or would excessively corrode a metal container

the user’s process either would require more than 1 pt of a Class IA liquid or more than 1 qt of a Class IB liquid of a single assay lot to be used at one time, or would require the maintenance of an analytical standard liquid of a quality that is not met by the specified standards of the liquids available, and the quantity of the analytical standard liquid required to be used in any one control process exceeds one-sixteenth the capacity of the container allowed under Appendix 3-2 for the class of liquid.

Verify that each portable tank has one or more devices installed in the top with sufficient emergency venting capacity to limit internal pressure under fire exposure conditions to 10 psig or 30 percent of the bursting pressure of the tank, whichever is greater.

(NOTE: These standards do not apply to: storage of containers in service stations Class I or Class II liquids in the fuel tanks of a motor vehicle, aircraft, boat,

or portable or stationary engine flammable or combustible paints, oils, varnishes, or similar mixtures used

for painting or maintenance when not kept for a period in excess of 30 days beverages when packaged in individual containers not greater than 1 gal.)

(NOTE: The requirements pertaining to the handling, storage, and use of flammable/ combustible liquids with a flashpoint below 200 °F outlined through 29 CFR 1910.106 (checklist items HM.35.2.US through HM.40.3.US.) do not apply to the following (29 CFR 1910.106(j)):

bulk transportation of flammable/combustible liquids

3-63Hazardous Materials

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storage, handling, and use of fuel oil tanks and containers connected with oil burning equipment

storage of flammable and combustible liquids on farms liquids without a flashpoint that may be flammable under some conditions,

such as halogenated hydrocarbons and mixtures containing halogenated hydrocarbons

mists, sprays, or foams, except in flammable aerosols the following facilities when they meet NFPA standards:

drycleaning plants manufacture of organic coatings solvent extraction plants stationary combustion engines and gas turbines.)

HM.35.3.US. Flammable or combustible liquids shall not be stored in ways that limit the use of exits, stairways, or areas normally used for the safe egress of people (29 CFR 1910.106(d)(5)(i)).

Verify that exits or common traffic routes are not blocked.

(NOTE: These standards do not apply to: storage of containers in service stations Class I or Class II liquids in the fuel tanks of a motor vehicle, aircraft, boat,

or portable or stationary engine flammable or combustible paints, oils, varnishes, or similar mixtures used

for painting or maintenance when not kept for a period in excess of 30 days beverages when packaged in individual containers not greater than 1 gal.)

(NOTE: The requirements pertaining to the handling, storage, and use of flammable/ combustible liquids with a flashpoint below 200 °F outlined through 29 CFR 1910.106 (checklist items HM.35.2.US. through HM.40.3.US.) do not apply to the following (29 CFR 1910.106(j)):

bulk transportation of flammable/combustible liquids storage, handling, and use of fuel oil tanks and containers connected with

oil burning equipment storage of flammable and combustible liquids on farms liquids without a flashpoint that may be flammable under some conditions,

such as halogenated hydrocarbons and mixtures containing halogenated hydrocarbons

mists, sprays, or foams, except in flammable aerosols the following facilities when they meet NFPA standards:

drycleaning plants manufacture of organic coatings solvent extraction plants stationary combustion engines and gas turbines.)

HM.35.4.US. Storage cabinets used for the storage of flammable/combustible liquids must meet specific requirements (29 CFR 1910.106(d)(3)) [Revised April 1995].

Verify that storage cabinets meet the following:

no more than 60 gal of Class I or Class II liquids nor any more than 120 gal of Class III liquids are stored in the cabinet

the cabinets are fire-resistant cabinets are conspicuously labeled FLAMMABLE--Keep Fire Away.

3-64Hazardous Materials

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Verify that metal cabinets are constructed as follows:

the bottom, top, door, and sides are at least number 18 gage sheet iron and double walled with 1.5 in. air space

joints are riveted, welded, or made tight by an equally effective means the door has a three point lock the door sill is raised at least 2 in. above the bottom of the cabinet.

Verify that wooden cabinets are constructed as follows:

the bottoms, sides, and top are an approved grade of plywood at least 1-in. thick which will not break down or delaminate under fire conditions

all joints are rabbeted and fastened in two directions with flathead woodscrews

there is a rabbeted overlap of at least 1 in. if more than one door is used hinges are mounted so that they will not lose their holding capacity due to

loosening or burning out of the screws when subjected to the fire test.

(NOTE: The requirements pertaining to the handling, storage, and use of flammable/ combustible liquids with a flashpoint below 200 °F outlined through 29 CFR 1910.106 (checklist items HM.35.2.US. through HM.40.3.US.) do not apply to the following (29 CFR 1910.106(j)):

bulk transportation of flammable/combustible liquids storage, handling, and use of fuel oil tanks and containers connected with

oil burning equipment storage of flammable and combustible liquids on farms liquids without a flashpoint that may be flammable under some conditions,

such as halogenated hydrocarbons and mixtures containing halogenated hydrocarbons

mists, sprays, or foams, except in flammable aerosols the following facilities when they meet NFPA standards:

drycleaning plants manufacture of organic coatings solvent extraction plants stationary combustion engines and gas turbines.)

HM.35.5.US. Storage cabinets used for the storage of flammable/combustible liquids should meet specific requirements (MP) [Revised May 1996].

Verify that storage cabinets meet the following:

materials within the cabinet are orderly no containers within the cabinet are open.

HM.35.6.US. Flammable/ combustible storage rooms inside of buildings must meet certain specifications (29 CFR 1910.106(d)(4)) [Revised April 1995].

Verify that flammable/combustible storage rooms meet the following:

the walls meet fire resistance test NFPA 251-1969 a 4 in. raised sill or ramp is provided to adjacent rooms or buildings, or the

floor of the storage area is 4 in. lower than the surrounding floors an open-grated trench that drains to a safe area is in the building if a sill or

3-65Hazardous Materials

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ramp is not present liquid tight wall/floor joints exist wood shelving is at least 1-in. thick. self-closing fire doors exist (NFPA 80) the electrical wiring and equipment meet NFPA 70 requirements the storage in the rooms meet the requirements in Appendix 3-3 there is either gravity or a mechanical exhaust ventilation system the exhaust system provides for six changes of air in the room per hour mechanical exhaust systems are controlled by a switch outside the door for gravity ventilation, the fresh air intake and exhaust outlets are on

exterior walls there is one clear aisle at least 3-ft wide containers over 30 gal capacity are not stacked one upon the other dispensing is done by an approved pump or self-closing faucet.

(NOTE: The requirements pertaining to the handling, storage, and use of flammable/ combustible liquids with a flashpoint below 200 °F outlined through 29 CFR 1910.106 (checklist items HM.35.2.US. through HM.40.3.US.) do not apply to the following (29 CFR 1910.106(j)):

bulk transportation of flammable/combustible liquids storage, handling, and use of fuel oil tanks and containers connected with

oil burning equipment storage of flammable and combustible liquids on farms liquids without a flashpoint that may be flammable under some conditions,

such as halogenated hydrocarbons and mixtures containing halogenated hydrocarbons

mists, sprays, or foams, except in flammable aerosols the following facilities when they meet NFPA standards:

drycleaning plants manufacture of organic coatings solvent extraction plants stationary combustion engines and gas turbines.)

HM.35.7.US. The storage of flammable or combustible liquids in warehouses or storage buildings will meet specific requirements (29 CFR 1910.106(d)(5)(vi)) [Revised December 1997].

Verify that the following requirements are met:

if the storage area is located 50 ft or less from a building or line of adjoining property that may be built upon, the exposing wall is a blank wall having a fire-resistance rating of at least 2 h

the storage arrangements outlined in Appendix 3-4 are met containers are separated by pallets or dunnage when necessary to provide

stability and prevent excess stress on container walls portable tanks that are stored over one tier high are designed to nest

securely no pile is closer than 3 ft to the nearest beam, chord, girder, or other

obstruction piles are 3 ft below sprinkler deflectors or discharge points of water spray aisles are at least 3-ft wide when necessary for access to doors, windows,

or standpipe connections.

3-66Hazardous Materials

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(NOTE: The requirements pertaining to the handling, storage, and use of flammable/ combustible liquids with a flashpoint below 200 °F outlined through 29 CFR 1910.106 (checklist items HM.35.2.US. through HM.40.3.US.) do not apply to the following (29 CFR 1910.106(j)):

bulk transportation of flammable/combustible liquids storage, handling, and use of fuel oil tanks and containers connected with

oil burning equipment storage of flammable and combustible liquids on farms liquids without a flashpoint that may be flammable under some conditions,

such as halogenated hydrocarbons and mixtures containing halogenated hydrocarbons

mists, sprays, or foams, except in flammable aerosols the following facilities when they meet NFPA standards:

drycleaning plants manufacture of organic coatings solvent extraction plants stationary combustion engines and gas turbines.)

HM.35.8.US. Flammable/ combustible materials stored outside of buildings must meet certain storage and handling criteria (29 CFR 1910.106(d)(6)) [Revised April 1995].

Verify that outdoor flammable/combustible storage meets the following:

no more than 1100 gal of flammable/combustible liquids is stored adjacent to buildings located on the same premises unless 10 ft or more exists between buildings and the nearest flammable container

the storage area is graded to divert spills or is surrounded by a curb at least 6-in. high

when curbs are used, there is a provision for draining of accumulated water and the drains terminate in a safe location and are accessible to operate when fire conditions exist

the storage area is protected against tampering and kept free of waste and other combustible materials

all containers bear contents, labels, and hazard markings total quantity and arrangement of liquids outside a building complies with

the requirements in Appendix 3-4.

(NOTE: These standards do not apply to: storage of containers in service stations Class I or Class II liquids in the fuel tanks of a motor vehicle, aircraft, boat,

or portable or stationary engine flammable or combustible paints, oils, varnishes, or similar mixtures used

for painting or maintenance when not kept for a period in excess of 30 days beverages when packaged in containers not greater than 1 gal.)

(NOTE: The requirements pertaining to the handling, storage, and use of flammable/ combustible liquids with a flashpoint below 200 °F outlined through 29 CFR 1910.106 (checklist items HM.35.2.US. through HM.40.3.US.) do not apply to the following (29 CFR 1910.106(j)):

bulk transportation of flammable/combustible liquids

3-67Hazardous Materials

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storage, handling, and use of fuel oil tanks and containers connected with oil burning equipment

storage of flammable and combustible liquids on farms liquids without a flashpoint that may be flammable under some conditions,

such as halogenated hydrocarbons and mixtures containing halogenated hydrocarbons

mists, sprays, or foams, except in flammable aerosols the following facilities when they meet NFPA standards:

drycleaning plants manufacture of organic coatings solvent extraction plants stationary combustion engines and gas turbines.)

HM.35.9.US. Areas where flammable/combustibles are stored must meet certain fire protection standards (29 CFR 1910.106(d)(7)) [Revised April 1995; Revised April 2005].

Verify that all flammable/combustible storage locations meet the following:

a suitable fire control device is available at locations where flammables or combustibles are stored

at least one 12-B rated portable fire extinguisher is located outside and within 10 ft of a door opening into any room for storage

at least one 12-B rated portable fire extinguisher is located within 10 to 25 ft of any Class I or Class II liquid storage area outside of a storage room, but inside a building

fire extinguishing sprinklers or systems meet the standards in 29 CFR 1910.159

no smoking or open flame is permitted within 50 ft and signs are posted no water-reactive materials are stored in the same room with

flammable/combustible liquids. (NOTE: These standards do not apply to:

storage of containers in service stations Class I or Class II liquids in the fuel tanks of a motor vehicle, aircraft, boat,

or portable or stationary engine flammable or combustible paints, oils, varnishes, or similar mixtures used

for painting or maintenance when not kept for a period in excess of 30 days.)

(NOTE: The requirements pertaining to the handling, storage, and use of flammable/ combustible liquids with a flashpoint below 200 °F outlined through 29 CFR 1910.106 (checklist items HM.35.2.US through HM.40.3.US.) do not apply to the following (29 CFR 1910.106(j)):

bulk transportation of flammable/combustible liquids storage, handling, and use of fuel oil tanks and containers connected with

oil burning equipment storage of flammable and combustible liquids on farms liquids without a flashpoint that may be flammable under some conditions,

such as halogenated hydrocarbons and mixtures containing halogenated hydrocarbons

mists, sprays, or foams, except in flammable aerosols the following facilities when they meet NFPA standards:

3-68Hazardous Materials

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drycleaning plants manufacture of organic coatings solvent extraction plants stationary combustion engines and gas turbines.)

3-69Hazardous Materials

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3-70Hazardous Materials

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FLAMMABLE/ COMBUSTIBLE LIQUIDS STORAGE

HM.40 Industrial Areas

HM.40.1.US. Areas where flammable/combustible materials are stored, dispensed, or used in industrial plants will meet specific guidelines (29 CFR 1910.106(e)(4) through 1910.106(e)(6), 1910.106(e)(8), and 1910.106(e)(9)) [Revised April 1995].

(NOTE: Checklist items HM.40.1.US. through HM.40.3.US. pertain to industrial areas in which the use of flammable or combustible liquid is incidental to the principal business or where flammable or combustible liquids are handled or used only in unit physical operations such as drying, evaporating, filtering, distillation, and similar operations that do not involve chemical reactions.)

Verify that the following provisions are met:

portable fire extinguishers and fire control equipment are in place in quantity and type as needed for the hazards of operation and storage at the site

water is available in a volume and adequate pressure to supply fire protection systems as needed depending on the hazards of the operation, dispensing, and storage

when indicated by special hazards of operation, flammable or combustible liquids, processing equipment, major piping, or supporting steel is protected by a water spray system, deluge system, approved fire resistant coatings, insulation, or a combination of these

adequate precautions are taken to prevent sources of ignition at the site Class I liquids are not dispensed into containers unless nozzles and

containers are electrically interconnected operations such as welding and cutting for repairs to equipment are done

under the supervision of an individual in responsible charge maintenance and operating practices control leakage and prevent the

accidental escape of flammable or combustible liquids: adequate aisles shall be maintained combustible waste material and residues are kept to a minimum,

stored in covered metal containers, and disposed of daily the grounds area around the buildings and unit operating areas are

kept free of weeds, trash or other unnecessary combustibles tank vehicle and tank car loading or unloading facilities are separated from

aboveground tanks, warehouses, and other plant buildings or nearest line of adjoining property by a distance of 25 ft for Class I liquids and 15 ft for Class II and III liquids.

Verify that plant fire facilities are maintained and periodically inspected and tested to ensure they are in satisfactory working condition.

HM.40.2.US. Incidental (NOTE: Checklist items HM.40.1.US. through HM.40.3.US. pertain to

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storage of flammable/ combustible liquids in industrial areas must conform to certain requirements (29 CFR 1910.106(e)(2)).

industrial areas in which the use of flammable or combustible liquid is incidental to the principal business or where flammable or combustible liquids are handled or used only in unit physical operations such as drying, evaporating, filtering, distillation, and similar operations that do not involve chemical reactions.)

Verify that flammable and combustible liquids are stored in closed containers.

Verify that the storage areas meet the requirements outlined in 29 CFR 1910.106(d)(3) through 1910.106(d)(4) as listed in checklist items HM.35.4.US. and HM.35.6.US. except that:

the quantity of liquid that is located outside of an inside storage room or storage cabinet in a building or in any one fire area of a building does not exceed:

25 gal of Class IA liquids in containers 120 gal of Class IB, IC, II, or III liquids in containers 660 gal of Class IB, IC, II, or III liquids in a single portable tank

where large quantities of flammable or combustible liquids are needed, storage may be in tanks.

Verify that areas in which flammable/combustible liquids are transferred from one container to another container are separated from other operations in the building by an adequate distance or by fire-resistant construction.

Verify that adequate drainage or other means is provided to contain spills, and adequate natural or mechanical ventilation is present.

Verify that the following practices are observed at the point of final use:

flammable liquids are kept in covered containers when not actually in use where flammable/combustible liquids are used or handled, means are

provided to dispose promptly and safely of spills and leaks Class I liquids are only used when there are no open flames or other

sources of ignition flammable/combustible liquids are drawn from or transferred into vessels,

containers, or portable tanks within a building only through a closed piping system, from safety cans, by means of a device drawing through the top, or from a container or portable tanks by gravity through an approved self closing valve.

(NOTE: Transferring flammable/combustible liquids by means of air pressure on the container or portable tank is prohibited.)

HM.40.3.US. Those areas in which flammable/combustible liquids are used in unit operations such as mixing,

(NOTE: Checklist items HM.40.1.US. through HM.40.3.US. pertain to industrial areas in which the use of flammable or combustible liquid is incidental to the principal business or where flammable or combustible liquids are handled or used only in unit physical operations such as drying, evaporating, filtering,

3-72Hazardous Materials

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drying, evaporating, filtering, or distillation are required to meet specific operating standards (29 CFR 1910.106(e)(3)).

distillation, and similar operations that do not involve chemical reactions.)

Verify that the following parameters are met:

areas are located so that each building or unit of equipment is accessible from at least one side for fire fighting

areas in which unstable liquids are handled or small scale unit chemical processes are carried on shall be separated from the remainder of the area by a fire wall of 2 h minimum fire resistance rating

emergency drainage systems direct leakage and fire protection water to a safe location

emergency drainage systems, if connected to public sewers or discharged into public waterways, are equipped with traps or a separator

when Class I liquids are being used, ventilation is provided at a rate of not less than 1 ft3/min/ft2 of solid floor area through either natural or mechanical means

equipment is designed to limit flammable vapor-air mixtures.

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3-74Hazardous Materials

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HM.45

COMPRESSED GASES STORAGE

HM.45.1.US. The in-plant storage, handling, and utilization of all compressed gases in cylinders, portable tanks, rail tankers, or motor vehicles must be done according to the Compressed Gas Association Pamphlet P-1-1-1965 (29 CFR 1910.101(b)) [Revised Citation October 2003].

Verify that the markings on the container are legible and none removed or defaced.

Verify that no part of the cylinder has been modified, tampered with, obstructed, removed, or repaired by the user.

Verify that the color of the container is not the only means of identifying the contents of the container.

Verify that containers are not:

placed anywhere they might become part of an electrical current grounded or used for grounding exposed to temperature extremes rolled in the horizontal position or dragged.

Verify that compressed gas storage areas meet the following:

they are posted NO SMOKING there is adequate spacing or segregation by partition so that containers are

grouped together by the hazard class of the gas it is designed so that temperatures will not exceed 125 oF cylinders are secured to prevent falling.

Verify that storage areas for flammable compressed gases meet the following:

acetylene containers are stored valve end up (the container may be stored as much as 45 degrees from the vertical)

portable fire extinguishers are available that are either of the CO2 type or dry chemical type

the area is well ventilated heat is by indirect means such as steam or hot water.

Verify that, when flammable compressed gases are stored in a separate room without other occupancy:

the walls, partitions, and ceiling are continuous from floor to ceiling and securely anchored

at least one wall is an exterior wall windows in partitions are wired glass in metal frames with a fixed sash openings to other parts of the building are protected by a self-closing fire

door with a resistance of at least 1 h.

3-75Hazardous Materials

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Verify that flammable compressed gas cylinders stored inside a building with other occupancy are kept at least 20 ft from flammable liquids, highly combustible materials, and oxidizers.

(NOTE: Most common storage problem is that acetylene (a flammable) and oxygen (an oxidizer) are stored side by side.)

(NOTE: Instead of 20 ft, a non-combustible barrier at least 5 ft high having a fire resistance rating of at least one half hour can be used.)

(NOTE: Flammable compressed gases include the following: acetylene; allene; butadiene; butane; 1-butene; 2-butene; 1-chloro-1, 1-difluoroethane; chlorotrifluoroethylene; chloropropane; deuterium; 1,1-difluoroethane; dimethylether; ethane; ethylacetylene; ethylene; hydrogen; liquid hydrogen; isobutane; isbutylene; liquefied petroleum gas; methane; methyl acetylene; methyl acetylene-propadiene mix (MAPP); methyl chloride; methyl fluoride; methyl vinyl ether; natural gas; propane; propylene; trifluoroethane; vinyl bromide; vinyl chloride; vinyl fluoride.)

(NOTE: Oxidizing gases include the following: compressed air; fluorine; nitrous oxide; liquid nitrous oxide; oxygen; liquid oxygen.)

3-76Hazardous Materials

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HM.50

HAZARDOUS MATERIALSTRANSPORTATION

HM.50.1.US. Shipping papers for hazardous materials are required to indicate the proper shipping name, hazard class, identification number, packing group, and quantities of materials (49 CFR 171.1(b) and 172.201) [Revised July 2002; Revised January 2003; Revised July 2005; Revised January 2006].

Verify that the proper information is displayed on the shipping papers for the hazardous material.

Verify that, when a description of hazardous material is required to be included on a shipping paper, that description conforms to the following requirements:

when a hazardous material and a material not subject to the requirements of this subchapter are described on the same shipping paper, the required hazardous material description entries meet one of the following:

must be entered first must be entered in a color that clearly contrasts with any description

on the shipping paper of a material not subject to the requirements of this subchapter, except that a description on a reproduction of a shipping paper may be highlighted, rather than printed, in a contrasting color

must be identified by the entry of an “X” placed before the proper shipping name in a column captioned ``HM'' (NOTE: The “X” may be replaced by “RQ,” if appropriate.)

the required shipping description on a shipping paper and all copies used for transportation purposes, are legible and printed (manually or mechanically) in English

unless it is specifically authorized or required, the required shipping description does not contain any code or abbreviation.

(NOTE: A shipping paper may contain additional information concerning the material provided the information is not inconsistent with the required description. Unless otherwise permitted or required, additional information must be placed after the basic description.) (NOTE: A shipping paper may consist of more than one page, if each page is consecutively numbered and the first page bears a notation specifying the total number of pages included in the shipping paper. For example, “Page 1 of 4 pages.”)

Verify that a shipping paper contains an emergency response telephone number.

Verify, to the extent feasible, each person who provides a shipping paper retains a copy of the shipping paper, or an electronic image thereof, that is accessible at or through its principal place of business and makes the shipping paper available, upon request, to an authorized official of a Federal, State, or local government agency at reasonable times and locations.

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Verify that each person who provides a shipping paper:

retains a copy of the shipping paper, or an electronic image, that is accessible at or through its principal place of business

makes the shipping paper available, upon request, to an authorized official of a Federal, State, or local government agency at reasonable times and locations

retains shipping paper copies for hazardous waste for 3 yr after the material is accepted by the initial carrier

retains shipping paper copies for hazardous materials for 2 yr after the material is accepted by the initial carrier.

Verify that each shipping paper copy includes the date of acceptance by the initial carrier, except that, for rail, vessel, or air shipments, the date on the shipment waybill, airbill, or bill of lading may be used in place of the date of acceptance by the initial carrier.

(NOTE: A motor carrier using a shipping paper without change for multiple shipments of one or more hazardous materials having the same shipping name and identification number may retain a single copy of the shipping paper, instead of a copy for each shipment made, if the carrier also retains a record of each shipment made, to include shipping name, identification number, quantity transported, and date of shipment.)

(NOTE: The regulations found in Title 49, Subchapter C of the CFR detail requirements for the transportation of hazardous materials. 49 CFR 171.1(b) stipulates that these requirements apply to each person who offers a hazardous material for transportation in commerce, causes a hazardous material to be transported in commerce, or transports a hazardous material in commerce and who performs or is responsible for performing a pre-transportation function, including each person performing pre-transportation functions under contract with any department, agency, or instrumentality of the executive, legislative, or judicial branch of the Federal government. Pre-transportation functions include, but are not limited to, the following:

determining the hazard class of a hazardous material selecting a hazardous materials packaging filling a hazardous materials packaging, including a bulk packaging securing a closure on a filled or partially filled hazardous materials package

or container or on a package or container containing a residue of a hazardous material

marking a package to indicate that it contains a hazardous material labeling a package to indicate that it contains a hazardous material preparing a shipping paper providing and maintaining emergency response information reviewing a shipping paper to verify compliance with the HMR or

international equivalents

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for each person importing a hazardous material into the U. S., providing the shipper with timely and complete information as to the HMR requirements that will apply to the transportation of the material within the United States

certifying that a hazardous material is in proper condition for transportation in conformance with the requirements of the HMR

loading, blocking, and bracing a hazardous materials package in a freight container or transport vehicle

segregating a hazardous materials package in a freight container or transport vehicle from incompatible cargo

selecting, providing, or affixing placards for a freight container or transport vehicle to indicate that it contains a hazardous material.)

HM.50.2.US. Each package or container, shall be marked in accordance with specific marking requirements (49 CFR 171.1(b), 172.301 and 172.302) [Revised July 2002; Revised April 2005; Revised January 2006; Revised July 2006].

(NOTE: See HM.50.1.US for information on the applicability of these Title 49 requirements.)

Verify that nonbulk packaging is marked with the proper shipping name and identification number (preceded by “UN” or “NA,” as appropriate).

(NOTE: Identification numbers are not required on non-bulk packagings that contain only ORM-D materials or limited quantities, except for limited quantities marked in accordance with the marking requirements in 49 CFR 172.315.)

(NOTE: The proper shipping name for a hazardous waste is not required to include the word “waste” if the package bears the EPA marking prescribed by 40 CFR 262.32.)

Verify that a transport vehicle or freight container containing only a single hazardous material in non-bulk packages is marked, on each side and each end with the identification number specified for the hazardous material subject to the following provisions and limitations:

each package is marked with the same proper shipping name and identification number

the aggregate gross weight of the hazardous material is 4,000 kg (8,820 lb) or more

all of the hazardous material is loaded at one loading facility the transport vehicle or freight container contains no other material,

hazardous or otherwise the identification number marking requirement of this paragraph does not

apply to Class 1, Class 7, or to non-bulk packagings for which identification numbers are not required.

Verify that each non-bulk packaging containing hazardous materials subject to the provisions of 49 CFR 172.203(k) are marked with the technical name in parentheses in association with the proper shipping name in accordance with the requirements and exceptions specified for display of technical descriptions on shipping papers in 49 CFR 172.203(k).

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(NOTE: A technical name should not be marked on the outer package of a Division 6.2 material (see definitions).)

Verify that the outside of each non-bulk package authorized by a special permit is plainly and durably marked “DOT-SP” followed by the special permit number assigned.

(NOTE: Packages authorized by an exemption issued prior to 1 October 2007, may be plainly and durably marked “DOT-E” in lieu of “DOT-SP” followed by the number assigned as specified in the most recent version of that exemption.)

Verify that each person who offers for transportation a hazardous material in a non-bulk package marks that package with the name and address of the consignor or consignee except when the package is one of the following:

transported by highway only and will not be transferred from one motor carrier to another

part of a carload lot, truckload lot or freight container load, and the entire contents of the rail car, truck or freight container are shipped from one consignor to one consignee.

Verify that no person offers for transportation or transport a hazardous material in a bulk packaging unless the packaging is marked as required by 49 CFR 172.332 with the identification number specified for the material in the 49 CFR 172.101 table and the marking meets one of the following:

on each side and each end, if the packaging has a capacity of 3,785 L (1,000 gal) or more

on two opposing sides, if the packaging has a capacity of less than 3,785 L (1,000 gal)

for cylinders permanently installed on a tube trailer motor vehicle, on each side and each end of the motor vehicle.

Verify that markings on bulk packagings:

have a width of at least 6.0 mm (0.24 in) and a height of at least 100 mm (3.9 in) for rail cars

have a width of at least 4.0 mm (0.16 in) and a height of at least 25 mm (one in) for portable tanks with capacities of less than 3,785 L (1,000 gal) and IBCs

have a width of at least 6.0 mm (0.24 in) and a height of at least 50 mm (2.0 in) for cargo tanks and other bulk packagings.

Verify that the outside of each bulk package authorized by a special permit is plainly and durably marked “DOT-SP” followed by the special permit number assigned.

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(NOTE: Packages authorized by an exemption issued prior to 1 October 2007, may be plainly and durably marked “DOT-E” in lieu of “DOT-SP” followed by the number assigned as specified in the most recent version of that exemption.)

Verify that, each bulk packaging marked with a proper shipping name, common name or identification number as required remains marked when it is emptied unless it is one of the following:

sufficiently cleaned of residue and purged of vapors to remove any potential hazard

refilled, with a material requiring different markings or no markings, to such an extent that any residue remaining in the packaging is no longer hazardous.

(NOTE: Additional requirements for marking portable tanks, cargo tanks, tank cars, multi-unit tank car tanks, and other bulk packagings are prescribed in 49 CFR 172.326, 172.328, 172.330, and 172.331.)

HM.50.3.US. Vehicles transporting hazardous materials on public roads are required to be properly placarded (49 CFR 171.1(b), and 172.500 through 172.558) [Revised July 2002; Revised April 2005].

(NOTE: See HM.50.1.US for information on the applicability of these Title 49 requirements.)

Determine if facility vehicles are used to transport hazardous materials on public roads.

Verify that no person affixes or displays on a packaging, freight container, unit load device, motor vehicle or rail car any placard described in 49 CFR, Subpart F unless:

the material being offered or transported is a hazardous material the placard represents a hazard of the hazardous material being offered or

transported any placarding conforms to the requirements of 49 CFR, Subpart F.

Verify that no person affixes or displays on a packaging, freight container, unit load device, motor vehicle or rail car any sign, advertisement, slogan (such as “Drive Safely'”, or device that, by its color, design, shape or content, could be confused with any required placard.

(NOTE: The restrictions about what can be affixed or displayed do not apply to: a bulk packaging, freight container, unit load device, transport vehicle or

rail car which is placarded in conformance with TDG Regulations, the IMDG Code or the UN Recommendations

the display of a BIOHAZARD marking, a “HOT” marking, or an identification number on a white square-on-point.)

(NOTE: Placards may be displayed for a hazardous material, even when not required, if the placarding otherwise conforms to the regulatory requirements.

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Verify that proper DOT placards, as described in 49 CFR 172.504 through 172.558, are affixed to vehicles being used to transport hazardous materials offsite.

(NOTE: Observe, if practical, the placarding of vehicles used to transport hazardous materials.)

(NOTE: See Appendix 3-6 for sample wording of placards.)

(NOTE: This requirement does not apply to: infectious substances hazardous materials classed as ORM-D hazardous materials authorized to be offered for transportation as limited

quantities when identified as such on shipping papers hazardous materials which are packaged as small quantities combustible liquids in nonbulk packaging.)

HM.50.4.US. The transportation of hazardous materials between buildings onsite should be accomplished in accordance with good management practices to help ensure against spills, releases, and accidents (MP).

Verify that procedures exist to manage movement of hazardous materials between buildings onsite.

Verify that drivers are trained in spill control procedures.

Verify that provisions have been made for securing hazardous materials in vehicles when transporting.

HM.50.5.US. A facility that offers for transport, accepts for transport, transfers, or otherwise handles a hazardous material must have emergency response information available (49 CFR 171.1(b), 172.600 through 172.605) [Revised July 2002; Revised April 2005].

(NOTE: See HM.50.1.US for information on the applicability of these Title 49 requirements.)

(NOTE: This checklist item applies to persons who offer for transportation, accept for transportation, transfer or otherwise handle hazardous materials during transportation.)

Verify that no person offers for transportation, accepts for transportation, transfers, stores or otherwise handles during transportation a hazardous material unless:

emergency response information is immediately available for use at all times the hazardous material is present

emergency response information, including the emergency response telephone number, is immediately available to any person who, as a representative of a Federal, State or local government agency, responds to an incident involving a hazardous material, or is conducting an investigation which involves a hazardous material.

(NOTE: The requirements of this checklist item do not apply to hazardous

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material which is excepted from the shipping paper requirements or a material properly classified as an ORM-D.)

(NOTE: the term ``emergency response information'' means information that can be used in the mitigation of an incident involving hazardous materials.)

Verify that emergency response information contains, at a minimum, the following information:

the basic description and technical name of the hazardous material as required by 49 CFR 172.202 and 172.203(k), the ICAO Technical Instructions, the IMDG Code, or the TDG Regulations, as appropriate

immediate hazards to health risks of fire or explosion immediate precautions to be taken in the event of an accident or incident immediate methods for handling fires initial methods for handling spills or leaks in the absence of fire preliminary first aid measures.

Verify that the information required for a hazardous material is:

printed legibly in English available for use away from the package containing the hazardous material presented on a shipping paper presented in a document, other than a shipping paper, that includes both the

basic description and technical name of the hazardous material as required by 49 CFR 172.202 and 172.203(k), the ICAO Technical Instructions, the IMDG Code, or the TDG Regulations, as appropriate, and the emergency response information required by this subpart (e.g., a material safety data sheet)

related to the information on a shipping paper, a written notification to pilot-in-command, or a dangerous cargo manifest, in a separate document

(e.g., an emergency response guidance document), in a manner that cross-references the description of the hazardous material on the shipping paper with the emergency response information contained in the document.

Verify that each carrier who transports a hazardous material maintains the required information in the same manner as prescribed for shipping papers, except that the information is maintained in the same manner aboard aircraft as the notification of pilot-in-command, and aboard vessels in the same manner as the dangerous cargo manifest.

Verify that the emergency response information is immediately accessible to train crew personnel, drivers of motor vehicles, flight crew members, and bridge personnel on vessels for use in the event of incidents involving hazardous materials.

Verify that each operator of a facility where a hazardous material is received,

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stored or handled during transportation, maintains the required information whenever the hazardous material is present.

Verify that the emergency response information is in a location that is immediately accessible to facility personnel in the event of an incident involving the hazardous material.

Verify that a person who offers a hazardous material for transportation provides an emergency response telephone number, including the area code or international access code, for use in the event of an emergency involving the hazardous material.

Verify that the telephone number is:

monitored at all times the hazardous material is in transportation, including storage incidental to transportation

the number of a person who is either knowledgeable of the hazardous material being shipped and has comprehensive emergency response and incident mitigation information for that material, or has immediate access to a person who possesses such knowledge and information

entered on a shipping paper according to one of the following: immediately following the description of the hazardous

material entered once on the shipping paper in a clearly visible

location (NOTE: This provision may be used only if the telephone number applies to each hazardous material entered on the shipping paper, and if it is indicated that the telephone number is for emergency response information (for example: “EMERGENCY CONTACT: * * *).

Verify that the telephone numbers also include the number of the person offering the hazardous material for transportation or the number of an agency or organization capable of, and accepting responsibility for, providing the detailed information concerning the hazardous material.

Verify that a person offering a hazardous material for transportation who lists the telephone number of an agency or organization ensures that agency or organization has received current information on the material before it is offered for transportation.

(NOTE: The requirements pertaining to emergency telephone numbers do not apply to:

hazardous materials that are offered for transportation under the provisions applicable to limited quantities

materials properly described under the following shipping names: battery powered equipment battery powered vehicle carbon dioxide, solid

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castor bean castor flake castor meal castor pomace consumer commodity dry ice engines, internal combustion fish meal, stabilized fish scrap, stabilized refrigerating machine vehicle, flammable gas powered vehicle, flammable liquid powered wheelchair, electric.

HM.50.6.US. Spills, leaks, and other incidents occurring during hazardous material transportation require immediate notification in specific circumstances (49 CFR 171.1(b) and 171.15) [Revised June 1997; Revised July 2002; Revised April 2004; Revised April 2005].

(NOTE: See HM.50.1.US for information on the applicability of these Title 49 requirements.)

Verify that, as soon as practical but no later than 12 h after the occurrence of any incident, each person in physical possession of the hazardous material provides notice by telephone to the National Response Center (NRC) on 800-424-8802 (toll free) or 202-267-2675 (toll call).

(NOTE: Notice involving an infectious substance (etiologic agent) may be given to the Director, Centers for Disease Control and Prevention, U.S. Public Health Service, Atlanta, GA, 800-232-0124 (toll free), in place of notice to the NRC.)

Verify that each notice includes the following information:

name of reporter name and address of person represented by reporter phone number where reporter can be contacted; date, time, and location of incident the extent of injury, if any class or division, proper shipping name, and quantity of hazardous

materials involved, if such information is available type of incident and nature of hazardous material involvement and whether

a continuing danger to life exists at the scene.

Verify that a telephone report is done whenever any of the following occurs during the course of transportation in commerce (including loading, unloading, and temporary storage):

as a direct result of a hazardous material: a person is killed a person receives an injury requiring admittance to a

hospital the general public is evacuated for one hour or more

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a major transportation artery or facility is closed or shut down for one hour or more

the operational flight pattern or routine of an aircraft is altered

fire, breakage, spillage, or suspected radioactive contamination occurs involving a radioactive material

fire, breakage, spillage, or suspected contamination occurs involving an infectious substance other than a diagnostic specimen or regulated medical waste

a release of a marine pollutant occurs in a quantity exceeding 450 L (119 gal) for a liquid or 400 kg (882 lb) for a solid

a situation exists of such a nature (e.g., a continuing danger to life exists at the scene of the incident) that, in the judgment of the person in possession of the hazardous material, it should be reported to the NRC even though it does not meet the usual reporting criteria.

Verify that each person making a telephone report also makes the written report required by 49 CFR 171.16 (see checklist item HM.50.7.US).

(NOTE: Under 40 CFR 302.6, EPA requires persons in charge of facilities (including transport vehicles, vessels, and aircraft) to report any release of a hazardous substance in a quantity equal to or greater than its reportable quantity, as soon as that person has knowledge of the release, to DOT's National Response Center at [toll free] 800-424-8802 or [toll] 202-267-2675.)

HM.50.7.US. Written hazardous materials incident reports are required to be submitted to the DOT of each hazardous material incident within 30 days of the incident (49 CFR 171.1(b) and 171.16) [Revised June 1997; Revised July 2002; Revised April 2004; Revised April 2005].

(NOTE: See HM.50.1.US for information on the applicability of these Title 49 requirements.)

Verify that each person in physical possession of a hazardous material at the time that any of the following incidents occurs during transportation (including loading, unloading, and temporary storage) submits a Hazardous Materials Incident Report on DOT Form F 5800.1(01/2004) within 30 days of discovery of the incident:

any of the circumstances set forth in 49 CFR 171.15(b) (see checklist item HM.50.6.US)

an unintentional release of a hazardous material or the discharge of any quantity of hazardous waste;

a specification cargo tank with a capacity of 1,000 gal or greater containing any hazardous material suffers structural damage to the lading retention system or damage that requires repair to a system intended to protect the lading retention system, even if there is no release of hazardous material

an undeclared hazardous material is discovered.

Verify that each person reporting:

submits a written Hazardous Materials Incident Report to the Information

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Systems Manager, DHM-63, Research and Special Programs Administration, Department of Transportation, Washington, DC 20590-0001, or an electronic Hazardous Material Incident Report to the Information System Manager, DHM-63, Research and Special Programs Administration, Department of Transportation, Washington, DC 20590-0001 at http://hazmat.dot.gov

submits a written or electronic copy of the Hazardous Materials Incident Report to the FAA Security Field Office nearest the location of the incident for an incident involving travel by aircraft

retains a written or electronic copy of the Hazardous Materials Incident Report for a period of 2 yr at the reporting person's principal place of business.

Verify that, if the written or electronic Hazardous Materials Incident Report is maintained at other than the reporting person's principal place of business, the report is made available at the reporting person's principal place of business within 24 h of a request for the report by an authorized representative or special agent of the DOT.

Verify that a Hazardous Materials Incident Report (HMIR) is updated within 1 yr of the date of occurrence of the incident whenever:

a death results from injury caused by a hazardous material there was a misidentification of the hazardous material or package

information on a prior incident report damage, loss or related cost that was not known when the initial incident

report was filed becomes known damage, loss, or related cost changes by $25,000 or more, or 10% of the

prior total estimate, whichever is greater.

(NOTE: Unless a telephone report is required under the provisions of 49 CFR 171.15 [see checklist item HM.50.6.US], the requirements of this checklist item do not apply to the following incidents:

a release of a minimal amount of material from: a vent, for materials for which venting is authorized the routine operation of a seal, pump, compressor, or valve connection or disconnection of loading or unloading lines,

provided that the release does not result in property damage an unintentional release of hazardous material when:

the material is properly classed as: ORM-D or a Packing Group III material in Class or Division 3, 4, 5, 6.1, 8, or 9

each package has a capacity of less than 20 L [5.2 gal] for liquids or less than 30 kg (66 lb) for solids

the total aggregate release is less than 20 L [5.2 gal] for liquids or less than 30 kg (66 lb) for solids

the material is not: offered for transportation or transported by aircraft; a hazardous waste; or an undeclared hazardous material.

an undeclared hazardous material discovered in an air passenger's checked

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or carry-on baggage during the airport screening process. )

HM.50.8.US. Employees involved in the transportation of hazardous materials re required to be trained according to specific requirements (49 CFR 171.1(b), 172.700 through 172.702, 172.704, and 173.1(b)) [Revised July 2002; Revised October 2003; Revised July 2004; Revised April 2005; Revised January 2006].

(NOTE: See HM.50.1.US for information on the applicability of these Title 49 requirements.)

(NOTE: Training means a systematic program that ensures a hazmat employee has familiarity with the general provisions for transporting hazardous materials, is able to recognize and identify hazardous materials, has knowledge of specific requirements applicable to functions performed by the employee, and has knowledge of emergency response information, self-protection measures and accident prevention methods and procedures. Additional training requirements for the individual modes of transportation are prescribed in 49 CFR 174, 175, 176, and 177.)

(NOTE: For motor vehicle drivers, however, a State may impose more stringent training requirements only if those requirements:

do not conflict with the training requirements in this subpart and in 49 CFR 177

apply only to drivers domiciled in that State.)

Verify that hazardous material employee training includes the following:

general awareness/familiarization training designed to provide familiarity with the packaging, labeling, and shipping requirements, and to enable the employee to recognize and identify hazardous materials consistent with the hazard communication standards

function-specific training concerning requirements of 40 CFR 172, or exemptions or special permits issued under 40 CFR 172, subchapter A, that are specifically applicable to the functions the employee performs

emergency response information required by 40 CFR 172, subpart G measures to protect the employee from the hazards associated with

hazardous materials to which they may be exposed in the work place, including specific measures the hazmat employer has implemented to protect employees from exposure

methods and procedures for avoiding accidents, such as the proper procedures for handling packages containing hazardous materials.

training that provides an awareness of security risks associated with hazardous materials transportation and methods designed to enhance transportation security and a component covering how to recognize and respond to possible security threats (NOTE New hazmat employees must receive the security awareness training within 90 days after employment)

hazmat employee of a person required to have a security plan is trained concerning the security plan and its implementation, including company security objectives, specific security procedures, employee responsibilities, actions to take in the event of a security breach, and the organizational security structure.

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(NOTE: Training conducted by employers to comply with the hazard communication programs required by OSHA or the EPA, or training conducted by employers to comply with security training programs required by other Federal or international agencies, may be used to satisfy the hazardous materials training requirements to the extent that such training addresses the training components specified above.)

(NOTE: A new hazmat employee, or a hazmat employee who changes job functions may perform those functions prior to the completion of training provided:

the employee performs those functions under the direct supervision of a properly trained and knowledgeable hazmat employee

the training is completed within 90 days after employment or a change in job function.

Verify that a hazmat employee receives the required training at least once every 3 yr.

(NOTE: Relevant training received from a previous employer or other source may be used to satisfy these training requirements provided a current record of training is obtained from hazmat employees' previous employer.)

Verify that a record of current training, inclusive of the preceding 3 yr, is created and retained by each hazmat employer for as long as that employee is employed by that employer as a hazmat employee and for 90 days thereafter.

Verify that the records include:

the hazmat employee's name the most recent training completion date of the hazmat employee's training a description, copy, or the location of the training materials the name and address of the person providing the training certification that the hazmat employee has been trained and tested, as

required.

(NOTE: A hazmat employee who repairs, modifies, reconditions, or tests packagings as qualified for use in the transportation of hazardous materials, and who does not perform any other function is not subject to the safety training requirement.)

(NOTE: It is the responsibility of each hazmat employer transporting hazardous materials to ensure that each hazmat employee is trained in accordance with the regulatory requirements. It is the duty of each person who offers hazardous materials for transportation to instruct each of his officers, agents, and employees having any responsibility for preparing hazardous materials for shipment.)

HM.50.9.US. Employees that (NOTE: See HM.50.1.US for information on the applicability of these Title 49

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operate motor vehicles transporting hazardous materials must be appropriately trained (49 CFR 171.1(b), 177.816(a), and 177.816(c)) [Revised July 2002].

requirements.)

(NOTE: This requirement may be met by compliance with the current requirements for a commercial driver’s license (CDL) with a tank vehicle or hazardous materials endorsement.)

Verify that the motor carrier does not transport (or cause to be transported) a hazardous material unless each hazardous materials employee who will operate a motor vehicle has been trained in the following:

the applicable requirements prescribed in 49 CFR 390 through 397 the procedures necessary for the safe operation of that vehicle.

Verify that each driver receives driver training that includes the following subjects:

pretrip safety inspection use of vehicle controls and equipment, including operation of emergency

equipment procedures for maneuvering tunnels, bridges, and railroad crossings requirements pertaining to attendance of vehicles, parking, smoking,

routing, and incident reports loading and unloading of materials, including load securement, package

handling methods, and compatibility and segregation of cargo in a mixed load

operation of the vehicle, including turning, backing, braking, parking, and handling

vehicle characteristics, including those that affect vehicle stability, such as the following:

effects of braking and curves effects of speed on vehicle control dangers associated with maneuvering through curves dangers associated with weather or road conditions that a driver may

experience high center of gravity.

HM.50.10.US. Employees who operate cargo tanks or vehicles with portable tanks having a capacity of 1000 gal or more of hazardous materials must be appropriately trained (49 CFR 171.1(b), 177.816(b) through 177.816(d)) [Revised July 2002; Citation Revised January 2005].

(NOTE: See HM.50.1.US for information on the applicability of these Title 49 requirements.)

(NOTE: This requirement may be met by compliance with the current requirements for a CDL with a tank vehicle or hazardous materials endorsements.)

Verify that each hazardous materials employee who operates a cargo tank or vehicle with a portable tank with a capacity of 1000 gal or more receives training applicable to the requirements of 49 CFR 171 through 177.

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Verify that each employee has the appropriate state-issued CDL.

Verify that each employee receives specialized training which includes the following subjects:

operation of emergency control features of the cargo tank and portable tank retest and inspection requirements for cargo tanks loading and unloading procedures the properties and hazards of the material transported special vehicle handling characteristics, including the following:

high center of gravity fluid load subject to surge effects of fluid-load surge on braking characteristic differences in stability among baffled, unbaffled, and

multi-compartmented tanks effects of partial loads on vehicle stability.

HM.50.11.US. Checklist item deleted [Deleted October 2003].

(NOTE: This checklist item was consolidated with HM.50.8.US)

HM.50.12.US. Checklist item deleted [Deleted October 2003].

(NOTE: This checklist item was consolidated with HM.50.8.US)

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HAZARDOUS MATERIAL TRANSFER OPERATIONS TO OR FROM VESSELS

HM.55Fixed Facility Transfer Operations

HM.55.1.US. Transfer operations are required to be done according to specific parameters (33 CFR 156.100 and 156.120).

(NOTE: A transfer is considered to begin when the person in charge on the transfer ring vessel or facility and the person in charge on the receiving facility or vessel first meet to begin completing the declaration of inspection.)

Verify that transfer operations are not conducted unless:

the moorings are strong enough to hold during expected conditions and long enough to allow for adjustments

transfer hoses and loading arms are long enough to allow the vessel to move without straining hoses

each hose is supported to prevent kinks or other damage to the hose and strain on its coupling

each part of the transfer system is aligned to allow the flow of hazardous material

parts of the transfer system not needed for the transfer are shutoff or securely blanked

the end of each hose and loading arm that is not connected for the transfer is blanked off

the transfer system is attached to a fixed connection on the vessel and the facility except that, when a vessel is receiving fuel, an automatic back pressure shut off nozzle may be used

each overboard discharge or sea suction valve that is connected to the vessel’s transfer or cargo tank system is sealed or lashed in the closed position, except when in use

transfer hoses have no unrepaired loose covers, kinks, bulges, soft spots, or any other defect that would permit the discharge of material

discharge containment equipment is readily accessible drains and scuppers are closed by mechanical means connections in the transfer system are leak free communications are operable emergency means of shutdown are in place and operable .required personnel are on duty necessary lighting is provided smoking is not permitted except in designated smoking areas welding, hot work operations and smoking is prohibited on vessels during

the transfer of flammable or combustible materials.

(NOTE: These requirements apply to the transfer of hazardous materials on the

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navigable waters or contiguous zone of the United States to, from, or within each vessel with a capacity of 250 bbl [approx. 10,500 gal] or more.)

HM.55.2.US. In specific cases of discharges, transfer operations of hazardous materials must be stopped (33 CFR 156.100 and 156.125).

Verify that transfer operations of hazardous materials are stopped when there is a discharge:

in the transfer operation work area into the water or upon adjacent shoreline in the transfer area.

Verify that, prior to restarting the transfer, the discharge is contained and cleaned up.

(NOTE: These requirements apply to the transfer of hazardous materials on the navigable waters or contiguous zone of the United States to, from, or within each vessel with a capacity of 250 bbl [approx. 10,500 gal] or more.)

HM.55.3.US. Hazardous materials must not be transferred unless the declaration of inspection form has been filled out and signed (33 CFR 156.100 and 156.150).

Verify that this form has been signed prior to transfer.

Verify that a copy of the form is retained on board the vessel or at the facility for at least 1 mo from the date of signature.

(NOTE: These requirements apply to the transfer of hazardous materials on the navigable waters or contiguous zone of the United States to, from, or within each vessel with a capacity of 250 bbl [approx. 10,500 gal] or more.)

HM.55.4.US. Coast Guard approval is required before specific substances can be placed on board a vessel as ship’s stores (46 CFR 147.40).

Verify that approval was received for the presence of the following items on board:

Class A poisons Class A explosives flammable gases, other than those discussed in other checklist items forbidden materials listed in 49 CFR 172.101.

(NOTE: These provisions apply to the following: passenger vessels small passenger vessels steam vessels tank vessels.)

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HM.60

FIXED FACILITY TRANSFER OPERATIONS FOR HAZARDOUS MATERIALS

HM.60.1.US. A fixed facility that is capable of transferring hazardous material, in bulk, to or from a vessel with a capacity of 250 bbl or more is required to have an Operations Manual (33 CFR 154.100(a) and 154.300 through 154.325) [Revised May 1997].

Determine if the facility is capable of transferring hazardous materials, in bulk, to or from a vessel with a total capacity, from a combination of all bulk products carried, of 250 bbl [approx. 10,500 gal] or more.

Verify that the facility has an operations manual that:

describes how the facility is meeting applicable operating and equipment requirements

describes the responsibilities of personnel in conducting transfer operations includes translations into a language or languages understood by all

designated persons in charge of transfer operations employed by the facility.

Verify that the manual is current and readily available for examination by the Captain of the Port (COTP).

Verify that a sufficient number of copies of the manual, including necessary translation, are readily available for facility personnel in charge while conducting a transfer operation.

Verify that the manual contains the following specific information:

the geographic location of the facility a physical description of the facility, including a plan or plans, maps,

drawings, aerial photographs or diagrams showing the boundaries of the facility subject to Coast Guard jurisdiction, mooring areas, transfer locations, control stations, wharves, the extent and scope of piping, and locations of safety equipment

for mobile facilities, a physical description of the facility the hours of operation the sizes, types, and number of vessels that the facility can transfer oil or

hazardous materials to or from simultaneously the following cargo information:

generic or chemical name a description of the appearance of the cargo the hazards involved in handling the cargo instruction for safe handling procedures to follow in the event of a spill or leak a list of fire-fighting procedures and extinguishing agents effective

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with fires involving the cargo a description of the odor of the cargo and the name of the cargo as

listed in appendix II of annex II of MARPOL 731.78, table 30.26-1 of 40 CFR 30.25-1, table 151.05 of 46 CFR 151-1, or table 1 of 46 CFR 153

the minimum number of persons on duty during transfer operations the names and telephone numbers of the qualified individual and the title

and/or position and telephone number of the Coast Guard, state, local, and other personnel who may be called in an emergency the duties of the watchman for unmanned vessels moored at the facility

a description of the required communication systems the location and facilities of each personnel shelter a description and instructions for the use of drip and discharge collection

and vessel slop reception facilities a description and location of each emergency shutdown system quantities, types, and locations of monitoring devices, fire extinguishing

equipment, containment equipment quantities, type, location, instruction for use, and time limits for gaining

access to containment equipment maximum allowable working pressure of each loading arm, transfer pipe

system, and hose assembly which is required to be tested, including the maximum relief valve setting for each transfer system

statements explaining that each hazardous materials transfer hose is marked with either the name of each product which may be transferred through the hose or with letters, numbers, symbols, color codes or other system acceptable to the COTP representing such products and the location in the Operations Manual where a chart or a list of symbols utilized is located and a list of the compatible products which may be transferred through the house can be found for consultation before each transfer

a description of tank cleaning or stripping operations for facilities that conduct those activities.

Verify that the following procedures are outlined in the manual:

transferring oil or hazardous materials operating each loading arm completion of pumping emergencies reporting and initial containment of hazardous materials discharges.

Verify that the manual contains a brief summary of applicable Federal, state, and local hazardous material pollution laws and regulations and a description of the training program for persons in charge.

Verify that the manual has been marked "Examined by the Coast Guard".

HM.60.2.US. Equipment Verify that each mechanical loading arm used for transferring hazardous

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used at a fixed facility that is capable of transferring hazardous material, in bulk, to or from a vessel with a capacity of 250 bbl or more is required to meet specific standards in order to prevent environmental pollution (33 CFR 154.100(a) and 154.500 through 154.510).

material has a means of being drained or closed before being disconnected after transfer operations are complete.

HM.60.3.US. A fixed facility that is capable of transferring hazardous material, in bulk, to or from a vessel with a capacity of 250 bbl or more is required to have discharge containment equipment and means to remove spilled materials (33 CFR 154.100(a) and 154.530 through 154.550) [Revised May 1997].

Verify that fixed catchments, curbing, or other fixed means are in place to contain hazardous material discharge in at least:

under each hose connection that will be coupled or uncoupled as part of this transfer operation during coupling, uncoupling, and transfer

each hose connection manifold area each hose handling and loading arm area (that area on that facility that is

within the area traversed by the free end of the hose or loading arm when moved away from its normal stowed or idle position into a position for connection).

(NOTE: Fixed or portable containment may be used to meet the requirements of containment under hose connections during coupling and uncoupling.)

Verify that the fixed catchments, curbing, or other fixed means have a capacity of at least:

2 bbl [approx. 84 gal] if it serves one or more hoses of 6 in. inside diameter or smaller, or loading arms of 6 in nominal pipe size diameter or smaller

3 bbl [approx. 126 gal] if it serves one or more hoses with an inside diameter of more than 6 in. but less than 12 in., or loading arms with nominal pipe size diameter of more than 6 in but less than 12 in.

4 bbl [approx. 168 gal] if it serves one or more hoses of 12 in. inside diameter or larger, or loading arms of 12 in. nominal pipe size diameter or larger.

(NOTE: The requirement for 2 bbl [approx. 84 gal] capacity may be met by using portable means of not less than 1/2 bbl [approx. 21 gal] capacity for part or all of the facility if the COTP has found that fixed means to contain hazardous materials discharges are not feasible.)

Verify that the facility has a means to safely and quickly remove discharged hazardous material from the containment area within 1 hr of completion of the transfer, without discharging the hazardous material into the water.

Verify that the facility has a means to safely and quickly remove discharged hazardous material from the containment area within 1 hr of completion of the

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transfer, without discharging the hazardous material into the water.

Verify that the facility has ready access to enough containment material and equipment to contain any hazardous material discharged on the water from the operations of that facility.

(NOTE: These requirements apply to each ship that is operated under the authority of the United States; however, provisions for exemptions of public vessels exist under certain circumstances.)

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HM.65

STORAGE OF HAZARDOUS MATERIALS ON FLOATING PLANTS

HM.65.1.US. Ships are required to meet specific restrictions as to where hazardous materials can be carried on board (33 CFR 155.100 and 155.470).

Verify that ships of 400 gross tons and above for which the building contract was in place after 1 January 1982 (or if there is no building contract, the keel was laid or is in a similar state of construction after 1 July 1982) do not carry hazardous materials in the forepeak tank or a tank forward of the collision bulkhead.

Verify that self-propelled ships of 300 gross tons and above, to which the above paragraph does not apply, do not carry hazardous materials in any space forward of a collision bulkhead, except when one of the following is met:

for a ship constructed after 30 June 1974, fuel oil for use on the ship is carried in tanks forward of a collision bulkhead, and the tanks are at least 24 in. inboard of the hull structure

for ships constructed before 1 July 1974, fuel oil for use on the ship is carried in tanks forward of a collision bulkhead if the tanks were designated, installed, or constructed for fuel oil carriage before 1 July 1974.

HM.65.2.US. Stowage and handling of flammable and combustible liquids, excluding liquids used as fuel for cooking, heating, and lighting but including gasoline and diesel oil, are required to be stored according to specific requirements (46 CFR 147.45).

Verify that no flammable/combustible liquids are stowed in any accommodation, control, or service space other than a paint locker.

Verify that no more than 19 L (5 gal) of flammable liquids are stowed in any machinery space and that they are stowed in containers of 3.8 L (1 gal) or less.

Verify that no more than 208 L (55 gal) of combustible liquids are stowed in any machinery space.

Verify that an aggregate of more than 7.6 L (2 gal) of flammable or combustible liquids is stowed in a paint locker that is marked with a warning sign indicating flammable or combustible liquid storage.

Verify that flammable and combustible liquids used as fuel for portable auxiliary equipment are stored in one of the following:

integral tanks that form part of the vessel’s structure an independent tank meeting the design requirements found in 46 CFR

58.50 a container meeting the requirements found in 49 CFR 143.119 for the

storage of flammable or combustible liquids a portable outboard fuel tank meeting the specification of ABYC H-25-81

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or one identified by the Underwriters Laboratories (UL) as meeting the specification of UL 1185

a portable safety container identified by UL as meeting the specifications of UL 39 or UL 1313

a portable safety container identified by UL as meeting the requirements of UL 1314.

Verify that each portable container of flammable or combustible liquid used for portable auxiliary equipment is stowed in a paint locker or an open location designated by the master of the vessel.

Verify that fuel tanks for portable auxiliary equipment using flammable/ combustible liquids are refilled on a vessel according to the following:

appropriate containers are used that have a capacity not exceeding 6 gal portable outboard containers or portable outboard fuel tanks are refilled

from a larger container of flammable or combustible liquid on the weather deck of the vessel if:

a drip pan of adequate size is used to collect drippings at least one Coast Guard approved Type B, Size I fire extinguisher is

within 3 m (9.75 ft), of the refilling location.

(NOTE: These provisions apply to the following: passenger vessels small passenger vessels steam vessels tank vessels.)

HM.65.3.US. Cylinders of compressed gas are required to be stowed according to specific parameters (46 CFR 147.60(b)).

Verify that cylinders are always secured and, when not in use, stored in a rack in an upright position with the valve protection cap in place.

Verify that lockers for storing compressed gas cylinders are vented to the open air near the top and bottom.

Verify that cylinders are protected from all sources of heat that may cause the cylinders’ temperatures to rise higher than 130 degrees F.

(NOTE: These provisions apply to the following: passenger vessels small passenger vessels steam vessels tank vessels.)

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HM.70

HAZARDOUS MATERIALS ON TANK VESSELS

HM.70.1.US. Only certificated vessels can carry the flammable or combustible cargos listed in Appendix 3-7, including a mixture of two or more listed cargos, when they are transported in bulk (46 CFR 30.25-1).

Determine if any vessels are carrying items listed in Appendix 3-7 in bulk.

Verify that the vessel is certificated.

(NOTE: These requirements apply to all U.S. flag vessels indicated in column 3 of Appendix 3-8, except:

any vessel operating exclusively on inland waters that are NOT navigable waters of the United States

any vessel that is laid up, dismantled, and out of commission any vessel that has its title vested in the United States and is used for public

purposes.)

HM.70.2.US. A method for determining the level of the liquid in a cargo tank, without opening ullage holes, cargo hatches, or Butterworth plates, is required to exist on all tankships that are certified to carry Grade A liquids and that had conversion or construction started after 1 July 1951 (46 CFR 32.20-20).

Determine when tankships were constructed or converted and what kind of cargo they carry.

Verify that a method of measuring without opening ullage holes, cargo hatches, or Butterworth plates exists.

(NOTE: Ullage holes fitted with sounding pipes tightly secured to the underside of tank tops, open at the bottom, and extending to within 18 in. or less of the bottom of the tank will be considered as complying with these provisions.)

(NOTE: These requirements apply to all U.S. flag vessels indicated in column 3 of Appendix 3-8, except:

any vessel operating exclusively on inland waters that are NOT navigable waters of the United States

any vessel that is laid up, dismantled, and out of commission any vessel that has its title vested in the United States and is used for public

purposes.)

HM.70.3.US. Paint rooms are required to be wholly and tightly lined with metal (46 CFR 32.85).

Verify that paint rooms are wholly and tightly lined with metal.

(NOTE: These requirements apply to all U.S. flag vessels indicated in column 3 of Appendix 3-8, except:

any vessel operating exclusively on inland waters that are NOT navigable waters of the United States

any vessel that is laid up, dismantled, and out of commission any vessel that has its title vested in the United States and is used for public

purposes.)

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HM.70.4.US. A CO2 or water spray system is required to be installed in all lamp and paint lockers and similar spaces (46 CFR 34.05-5(a)(3)) [Revised June 1997].

Verify that vessels are equipped with a CO2 or water spray system.

(NOTE: These requirements apply to all U.S. flag vessels indicated in column 3 of Appendix 3-8, except:

any vessel operating exclusively on inland waters that are not navigable waters of the United States

any vessel that is laid up, dismantled, and out of commission any vessel that has its title vested in the United States and is used for public

purposes.)

HM.70.5.US. The installation of magnesium sacrificial anodes in cargo tanks used for the carriage of flammable or combustible liquids is forbidden (46 CFR 35.01-25).

Verify that cargo tanks carrying flammable or combustible liquids are not equipped with magnesium sacrificial anodes.

(NOTE: A sacrificial anode using an aluminum alloy is permitted in cargo tanks under the following circumstances:

the maximum allowable energy that can be developed by a falling anode is 200 ft-lb

no anode is installed more than 6 ft above the bottom of the tank each anode has at least two welded or bolted connections to the supporting

structure the plans for the system were submitted for approval.)

(NOTE: These requirements apply to all U.S. flag vessels indicated in column 3 of Appendix 3-8, except:

any vessel operating exclusively on inland waters that are not navigable waters of the United States

any vessel that is laid up, dismantled, and out of commission any vessel that has its title vested in the United States and is used for public

purposes.)

HM.70.6.US. Open hopper type barges that do not meet the requirements in 46 CFR 32.63 concerning hull and cargo tank construction, and that are carrying cargos as listed in Appendix 3-8, are required to display additional placards or signs in four different locations (46 CFR 35.01-45(a) and 35.01-45(d)).

Determine what cargo the barge is carrying.

Verify that placards indicating the hazards being carried are mounted:

approximately amidships on each side near the centerline of each end, facing outboard.

(NOTE: These requirements only apply if carrying cargos listed in Appendix 3-8, which are defined as:

flammable liquids with a Reid vapor pressure exceeding 25 psia, in independent tanks

liquefied flammable gases.)

(NOTE: These requirements apply to all U.S. flag vessels indicated in column 3 of Appendix 3-8, except:

any vessel operating exclusively on inland waters that are not navigable

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waters of the United States any vessel that is laid up, dismantled, and out of commission any vessel that has its title vested in the United States and is used for public

purposes.)

HM.70.7.US. Manned tank barges and tankships authorized to carry Grade A, B, C, or D liquids at any temperature or Grade E liquids at elevated temperatures are required to be provided with a combustible gas indicator (46 CFR 35.30-15).

Determine if the vessels meet the listed description.

Verify that vessels are equipped with a combustible gas indicator.

(NOTE: These requirements apply to all U.S. flag vessels indicated in column 3 of Appendix 3-8, except:

any vessel operating exclusively on inland waters that are not navigable waters of the United States

any vessel that is laid up, dismantled, and out of commission any vessel that has its title vested in the United States and is used for public

purposes.)

HM.70.8.US. Where Grades A, B, C, and D liquid cargos are involved, power driven or manually operated spark producing devices must not be used in bulk cargo tanks, fuel oil tanks, cargo pumprooms, or enclosed spaces immediately above or adjacent to bulk cargo tanks unless specific conditions are met (46 CFR 35.30-35).

Verify that the following conditions are met prior to use:

the compartment itself is gas free the compartments adjacent and the compartments diagonally adjacent are

either gas free, inerted, filled with water, contain Grade E liquid and are closed and secure, or are spaces in which flammable vapors and gases normally are not expected to accumulate

all other compartments of the vessel in which flammable vapors and gases may normally be expected to accumulate are closed and secured.

(NOTE: These restrictions do not apply to the use of small hand tools in these locations.)

(NOTE: These requirements apply to all U.S. flag vessels indicated in column 3 of Appendix 3-8, except:

any vessel operating exclusively on inland waters that are not navigable waters of the United States

any vessel that is laid up, dismantled, and out of commission any vessel that has its title vested in the United States and is used for public

purposes.)

HM.70.9.US. Flammable liquids and gases, other than diesel fuel, that are going to be used as fuel for approved equipment are required to be stowed according to specific parameters (46 CFR 35.30-40).

Verify that stowage is in containers approved by the DOT and ASME or in a portable container approved by a recognized testing laboratory.

Verify that the content is marked on the containers and the containers are labeled according to DOT flammability labeling requirements.

Verify that containers are stowed on or above the weather deck.

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(NOTE: Approved containers of 5 gal or less may be stowed below the weather deck in a paint or lamp locker.)

(NOTE: These requirements apply to all U.S. flag vessels indicated in column 3 of Appendix 3-8, except:

any vessel operating exclusively on inland waters that are not navigable waters of the United States

any vessel that is laid up, dismantled, and out of commission any vessel that has its title vested in the United States and is used for public

purposes.)

HM.70.10.US. Tankships and tank barges, in service on all waters, that transport liquefied or compressed flammable gases are required to meet specific standards (46 CFR 30.01-5(d), 38.01-1, and 38.01-2).

Verify that the transportation of liquefied or compressed flammable gases on deck is done according to the requirements found in 49 CFR 171 through 179.

Verify that, when liquefied or compressed gases are being transported below decks in DOT cylinders, DOT specification portable tanks, or other approved portable tanks, the following requirements are met:

cargo has an efficient means of ventilation, is protected from artificial heat, and is readily accessible from hatches

containers are stored so that the safety relief device is in communication with the vapor space of the container

containers are stored, dunnaged, and secured to prevent movement in any direction

containers are not overstowed in the same dry cargo space with other liquefied flammable gas containers or other cargos

containers are protected from damage from other cargo, ship’s stores, or equipment

cylinders have valves protected portable tanks have valves protected by a housing the following are not stored in the same hold or compartment with

liquefied flammable gas containers: Class A, B, or C explosives flammable solids oxidizing materials corrosive liquids poisonous articles cotton and similar fibrous materials.

(NOTE: These requirements apply to all U.S. flag vessels indicated in column 3 of Appendix 3-8, except:

any vessel operating exclusively on inland waters that are not navigable waters of the United States

any vessel that is laid up, dismantled, and out of commission any vessel that has its title vested in the United States and is used for public

purposes.)

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HM.70.11.US. Tanks are required to be inspected on a periodic basis (46 CFR 38.35-1 and 38.25- 10).

Verify that each tank has an internal inspection:

10 yr after the last internal inspection if the tank is a pressure vessel type cargo tank on an unmanned barge carrying cargo at temperatures of –67 degrees F (-55 degrees C) or warmer

8 yr after the last internal inspection for all other tanks.

Verify that an external inspection of unlagged tanks and the visible parts of lagged tanks is done at each inspection for certification and at other times as needed.

Verify that cargo tank safety relief valves are inspected at least once every 2 yr.

HM.70.12.US. Pressure vessel and nonpressure vessel-type cargo tanks that have passed tests and inspection are required to be marked (46 CFR 38.05-5(a)).

Verify that tanks are marked to indicate appropriate tests and inspections have been completed.

(NOTE: For nonpressure vessel-type tanks, omit the Coast Guard number and pressure vessel class.)

Verify that markings are permanent and legible.

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HM.75

HAZARDOUS MATERIALS ON CARGO AND MISCELLANEOUS VESSELS

HM.75.1.US. Paint lockers are required to be constructed of steel and wholly lined with metal (46 CFR 92.05-10).

Verify that paint lockers are metal.

(NOTE: These regulations apply to all U.S. flag vessels indicated in column 5 of Appendix 3-8, except:

any vessel operating exclusively on inland waters that are not navigable waters of the United States

any vessel that is laid up, dismantled, and out of commission any vessel that has its title vested in the United States and is not used for

public purposes, except for vessels of the U.S. Maritime Administration.)

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Appendix 3-0

Comparison of 40 CFR 355 Emergency Release Notification Requirements and the Release Notification Requirements of CERCLA as Codified In 40 CFR 302

(40 CFR 355.60)[Added January 2009)

If a reportable quantity of a substance is released within a 24-h

period at your facility

And if the release is reportable under EPCRA Section 304, you

must

And if the release is reportable under CERCLA Section 103, you

must

a. And the substance is on BOTH the list of EHSs (Appendices A and B of 40 CFR 355) AND the list of CERCLA Hazardous Substances (40 CFR 302.4).

Notify the LEPC and the SERC in accordance with 40 CFR 355.40 through 355.43 (except for a release during transportation or from storage incident to transportation; see 40 CFR 355.42(b) (see checklist item HM.20.4.US).

Comply with the release notification requirementws of CERCLA Section 103 and its implementing regulations (40 CFR 302, [see checklist items HM.230.2.US and HM.230.3.US]). Call the NRC at 800-424-8802.

b. And the substance is on the list of CERCLA Hazardous Substances (40 CFR 302.4) and not on the list of EHSs (Appendices A and B of 40 CFR 355).

Notify the LEPC and the SERC in accordance with 40 CFR 355.40 through 355.43 (except for a release during transportation or from storage incident to transportation; see 40 CFR 355.42(b) (see checklist item HM.20.4.US).

Comply with the release notification requirements of CERCLA Section 103 and its implementing regulations (40 CFR 302). Call the NRC at 800-424-8802.

c. And the substance is on the list of EHSs (Appendices A and B of 40 CFR 355) and not the list of CERCLA Hazardous Substances (40 CFR 302.4).

Notify the LEPC and the SERC in accordance with 40 CFR 355.40 through 355.43 (except for a release during transportation or from storage incident to transportation; see 40 CFR 355.42(b) (see checklist item HM.20.4.US).

NOTE: This table only applies to reportable releases, not to exempt releases.

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Appendix 3-0a

Community Right-To-Know Reporting of Mixtures (40 CFR 370.14)

[Added January 2009]

If your mixture contains a hazardous chemical:

To determine if the threshold level for that hazardous chemical is equaled or exceeded you must:

If the threshold level for the hazardous chemical is exceeded

than the facility must:

1. That is an EHS Determine the total quantity of the EHS present throughout the facility at any one time, by adding together the quantity present as a component in all mixtures and all other quantities of the EHS (the facility must include the quantity present in a mixture even if they are also counting the quantity of that particular mixture toward the threshold level for that mixture).

Report the EHS component– submit an MSDS for the

EHS (or include the EHS on the list of chemicals submitted in lieu of the MSDSs), as provided under 40 CFR 370.30, and submit Tier I (or Tier II) information for the EHS as provided under 40 CFR 370.40 or report the mixture itself

– submit an MSDS for the mixture (or include the mixture on the list of chemicals submitted in lieu of the MSDSs), as provided under 40 CFR 370.30, and submit Tier I (or Tier II) information for the mixture, as provided under 40 CFR 370.40. If the facility reports the mixture itself, then provide the total quantity of that mixture.

2. That is not an EHS Determine either: – The total quantity of the

hazardous chemical present throughout the facility at any one time by adding together the quantity present as a component in all mixtures and all other quantities of the hazardous chemical (the facility will include the quantity present in a mixture even if the facility is also applying that particular mixture as a whole toward the threshold level for that mixture) or

Report the non-EHS hazardous chemical component

– submit an MSDS for the non-EHS hazardous chemical (or include the non-EHS on the list of chemicals submitted in lieu of the MSDSs), as provided under 40 CFR 370.30, and submit Tier I (or Tier II) information for the non-EHS chemical as provided under 40 CFR 370.40 or report the mixture itself

– submit an MSDS for the mixture (or include the mixture on the list of

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– the total quantity of that mixture present throughout the facility at any one time.

chemicals submitted in lieu of MSDSs), as provided under 40 CFR 370.30, and submit Tier I (or Tier II) information for the mixture, as provided under 40 CFR 370.40. If the facility reports the mixture itself, then provide the total quantity of that mixture.

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Appendix 3-0b

Codes for Tier I and Tier II Inventory Reporting(40 CFR 370.43)

[Added January 2009]

Weight Range Codes. Except as provided at the bottom of this Appendix, facilities must use the following codes to report the maximum amount and average daily amount when reporting Tier I or Tier II information:

Range CodesWeight Range in Pounds

From To

01 0 9902 100 99903 1,000 9,99904 10,000 99,99905 100,000 999,99906 1,000,000 9,999,99907 10,000,000 49,999,99908 50,000,000 99,999,99909 100,000,000 499,999,99910 500,000,000 999,999,99911 1 billion More than 1 billion

NOTE: To convert gas or liquid volume to weight in pounds, multiply by an appropriate density factor.

Storage Type Codes. Except as provided at the bottom of this Appendix, facilities must use the following codes to report storage types when they are reporting Tier II information:

Codes Types of Storage

A Aboveground tankB Belowground tankC Tank inside buildingD Steel DrumE Plastic or non-metallic drumF CanG CarboyH SiloI Fiber drumJ BagK BoxL CylinderM Glass bottle or jugsN Plastic bottles of jugsO Tote binP Tank WagonQ Rail carR Other

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Storage Condition Codes. Except as provided at the bottom of this Appendix, facilities must use the following codes to report storage conditions when they are reporting Tier II information:

Codes Storage ConditionPressure Conditions

1 Ambient Pressure2 Greater than ambient pressure3 Less than ambient pressure

Temperature Conditions

4 Ambient temperature5 Greater than ambient temperature6 Less than ambient temperature but

not cryogenic7 Cryogenic conditions

(NOTE: The SERC or LEPC may provide other range codes for reporting maximum amounts and average daily amounts, or may require reporting of specific amounts. The facility may use their SERC's or LEPC's range codes (or specific amounts) provided the ranges are not broader than the ranges above. The SERC or LEPC may also provide other codes for storage types or conditions. The facility may use those codes provided their SERC's or LEPC's storage types and conditions codes specify the same or more detailed information as the codes listed above.)

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3-114Hazardous Materials

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Appendix 3-1

Consolidated List of Chemicals Covered in Title III of SARA[Revised July 2003; Revised January 2005; Revised July 2005; Revised October 2006]

(NOTE: This list is constantly changing and the Federal Register should be consulted for the most up-to-date information.)

This consolidated chemical list includes chemicals subject to reporting requirements under Title III of SARA. This consolidated chemical list does not contain all chemicals that are subject to reporting requirements in Sections 311 and 312 of SARA Title III. These hazardous chemicals, for which MSDSs must be developed under the Occupational Safety and Health Act, Hazard Communication Standards, are identified by broad criteria rather than enumeration. There are over 50,000 such substances that meet the criteria. The consolidated list has been prepared to help determine whether there is a need to submit reports under Section 304 or 313 of Title III and, for a specific chemical, what reports need to be submitted.

The list includes chemicals under the four following Federal statutory provisions:

1. SARA Section 302 Extremely Hazardous Substances - the presence of which, in sufficient quantities, requires certain emergency planning activities to be conducted. Releases of these substances are also subject to reporting under Section 304 of Title III. The final rule listing the extremely hazardous substances and their threshold planning quantities (TPQ) is found in 40 CFR 355.

2. CERCLA Hazardous Substances (RQ) Chemicals - releases of which are subject to reporting under the CERCLA or Superfund of 1980. Such releases are also subject to reporting under Section 304 of Title III. CERCLA hazardous substances, and their RQs, are listed in 40 CFR 302, Table 302.4.

3. SARA Section 313 Toxic Chemicals - emissions or releases of which must be reported annually as part of SARA Title III’s community right-to-know provisions. A list of these toxic chemicals is found in 40 CFR 372.65.

4. RCRA Hazardous Wastes - from the "P" and "U" lists (40 CFR 261.33) of specific chemicals. RCRA hazardous wastes from the "F" and "K" lists are not included here; such waste streams are also CERCLA hazardous substances. This listing is provided as an indicator that you may already have data on a specific chemical that can be used for Title III reporting purposes.

There are four columns in the consolidated list corresponding to these four statutory provisions. If a chemical is listed as an extremely hazardous substance under Section 302, its TPQ is given in the extremely hazardous substance column. Similarly, the CERCLA RQ is given for those chemicals that are listed as hazardous substances. A key to the symbols used in Section 302 and CERCLA columns precedes the list. An "X" in the column for 40 CFR 372.65(f) indicates that the chemical is subject to reporting under Section 313.

The letter-and-digit code in the column for 40 CFR 261.33 is the chemical’s RCRA hazardous waste code. A blank in any of these columns indicates that the chemical is not subject to the corresponding statutory authorities.

The Chemical Abstract Service (CAS) registry number is provided for each chemical on the list.

Key to Symbols in the Consolidated Chemical List

# Indicates that the RQ is subject to change when an assessment of potential carcinogenicity and/or chronic toxicity is completed; until then, the statutory RQ applies.

## Indicates that an adjusted RQ has been proposed, but a final judgment has not been made.

+ USEPA has proposed to adjust the RQ for radionuclides by establishing RQs in units of Curies; until then, the 1 lb RQ applies.

* Indicates that the chemical is proposed for deletion from the list of extremely hazardous substances.

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** Indicates that no RQ is assigned to this generic or broad class.

(NOTE: These abbreviations are used below: Haz Sub (hazardous substances), Mat (materials).)

CONSOLIDATED CHEMICAL LISTThis is an alphabetical listing of the consolidated list of chemicals. Numbered chemicals are listed first.Chemical Name Extremely

Haz Substances

40 CFR 355 (lb)

FINAL RQ

Haz Sub RQ 40 CFR 302.4

(lb)

Toxic Chemicals 40 CFR 372.65(a)

RCRA Waste NO

Haz Mat which are

RCRA wastes

CAS No.

Abamectin (Avermectin B1)

x 71751-41-2

Acenaphthene 100 83-32-9Acenaphthylene 5000 208-96-8Acephate (Acetylphos

phoramidothioic acid O,S-dimethyl ester

x 30560-19-1

Acetaldehyde 1000 x U001 75-07-0Acetaldehyde, chloro- 1000 P023 107-20-0Acetaldehyde, trichloro- 5000 U034 75-87-6Acetamide 100 x 60-35-5Acetamide-N-(4-ethox

yphenyl)-100 U187 62-44-2

Acetamide,N-(aminothi-oxomethyl)-

1000 P002 591-08-2

Acetamide, N-9H-fluoren-2-yl-

1 U005 53-96-3

Acetamide, 2-fluoro 100 PO57 640-19-7Acetic acid 5000 64-19-7Acetic acid (2,4-dichlo

rophenoxy)- salts and esters

100 U240 94-75-7

Acetic acid, ethyl ester 5000 U112 141-78-6Acetic acid, fluoro,

sodium salt10/10,000 10 P058 62-74-8

Acetic acid, lead(2+) salt

10 U144 301-04-2

Acetic acid, thallium(1+) salt

100 U214 563-68-8

Acetic acid, (2,4,5-trichlorophenoxy)

1000 See F027 93-76-5

Acetic anhydride 5000 108-24-7Acetone 5000 U002 67-64-1Acetone cyanohydrin 1000 10 P069 75-86-5Acetone thiosemicarba

zide1000/ 10,000 1752-30-3

Acetonitrile 5000 x U003 75-05-8Acetophenone 5000 x U004 98-86-22-Acetylaminofluorene 1 x U005 53-96-3Acetyl bromide 5000 506-96-7Acetyl chloride 5000 U006 75-36-51-Acetyl-2-thiourea 1000 P002 591-08-2Acifluorfen, sodium salt x 62476-59-9Acrolein 500 1 x P003 107-02-8Acrylamide 1000/ 10,000 5000 x U007 79-06-1

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Chemical Name Extremely Haz Substances

40 CFR 355 (lb)

FINAL RQ

Haz Sub RQ 40 CFR 302.4

(lb)

Toxic Chemicals 40 CFR 372.65(a)

RCRA Waste NO

Haz Mat which are

RCRA wastes

CAS No.

Acrylic acid 5000 x U008 79-10-7Acrylonitrile 10,000 100 x U009 107-13-1Acrylyl chloride 100 814-68-6Adiponitrile 1000 1000 111-69-3Alachlor x 15972-60-8Aldicarb 100/10,000 1 x P070 116-06-3Aldicarb sulfone 1## P203 1646-88-4Aldrin 500/10,000 1 x P004 309-00-2d-trans-Allethrin [d-

trans-Chrysan themic aacid of d- allethrone0]

x

28057-48-9

Allyl alcohol 1000 100 x P005 107-18-6Allylamine 500 500 x 107-11-9Allyl chloride 1000 x 107-05-1alpha-Hexachlorocy

clohexanex 319-84-6

Aluminum (fume or dust)

x 7429-90-5

Aluminum oxide (fibrous forms)

x 1344-28-1

Aluminum phosphide 500 100 x P006 20859-73-8Aluminum sulfate 5000 10043-01-3Ametryn x 834-12-82-Aminoanthraquinone x 117-79-34-Aminoazobenzene x 60-09-34-Aminobiphenyl 1 x 92-67-1Aminopterin 500/10,000 500 54-62-64-Aminopyridine 500/10,000 1000 P008 504-24-5Amiton 500 500 78-53-5Amiton oxalate 100/10,000 100 3734-97-2Amitraz x 33689-61-1Amitrole 10 x U011 61-82-5Ammonia 500 100 x 7664-41-7Ammonium acetate 5000 631-61-8Ammonium benzoate 5000 1863-63-4Ammonium bicarbon

ate5000 1066-33-7

Ammonium bichromate 10 7789-09-5Ammonium bifluoride 100 1341-49-7Ammonium bisulfite 5000 10192-30-0Ammonium carbamate 5000 1111-78-0Ammonium carbonate 5000 506-87-6Ammonium chloride 5000 12125-02-9Ammonium chromate 10 7788-98-9Ammonium

citrate,dibasic5000 3012-65-5

Ammonium fluoborate 5000 13826-83-0Ammonium fluoride 100 12125-01-8Ammonium hydroxide 1000 336-21-6Ammonium oxalate 5000 5972-73-6Ammonium oxalate 5000 6009-70-7Ammonium oxalate 5000 14258-49-2Ammonium picrate 10 P009 131-74-8

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Chemical Name Extremely Haz Substances

40 CFR 355 (lb)

FINAL RQ

Haz Sub RQ 40 CFR 302.4

(lb)

Toxic Chemicals 40 CFR 372.65(a)

RCRA Waste NO

Haz Mat which are

RCRA wastes

CAS No.

Ammonium silicofluoride

1000 16919-19-0

Ammonium sulfamate 5000 7773-06-0Ammonium sulfide 100 12135-76-1Ammonium sulfite 5000 10196-04-0Ammonium tartrate 5000 14307-43-8Ammonium tartrate 5000 3164-29-2Ammonium thiocyanate 5000 1762-95-4Ammonium vanadate 1000 P119 7803-55-6Amphetamine 1000 1000 300-62-9Amyl acetate 5000 628-63-7iso-Amyl acetate 5000 123-92-2sec-Amyl acetate 5000 626-38-0tert-Amyl acetate 5000 625-16-1Analine,2,4,6-trime

thyl-500 500 88-05-1

Anilazine x 101-05-3Aniline 1000 5000 x U012 62-53-3o-Anisidine 100 x 90-04-0p-Anisidine x 104-94-9o-Anisidine

hydrochloridex 134-29-2

Anthracene 5000 x 120-12-71,Amino-2-methyl-

anthraquinonex 82-28-0

Antimony 5000 x 7440-36-0Antimony pentachloride 1000 7647-18-9Antimony pentafluoride 500 500 7783-70-2Antimony potassium

tartrate100 28300-74-5

Antimony tribromide 1000 7789-61-9Antimony trichloride 1000 10025-91-9Antimony trifluoride 1000 7783-56-4Antimony trioxide 1000 1309-64-4Antimycin A 1000/ 10,000 1000 1397-94-0ANTU 500/10,000 100 86-88-4Aroclor 1016 1 12674-11-2Aroclor 1221 1 11104-28-2Aroclor 1232 1 11141-16-5Aroclor 1242 1 53469-21-9Aroclor 1248 1 12672-29-6Aroclor 1254 1 11097-69-1Aroclor 1260 1 11096-82-5Arsenic 1 x 7440-38-2Arsenic acid 1 P010 1327-52-2Arsenic acid 1 P010 7778-39-4Arsenic disulfide 1 1303-32-8Arsenous oxide 100/10,000 1 1327-53-3Arsenic pentoxide 100/10,000 1 P011 1303-28-2Arsenic trioxide 100/10,000 1 P012 1327-53-3Arsenic trisulfide 1 1303-33-9Arsenous trichloride 500 1 7784-34-1Arsine 100 100 7784-42-1Arsine, diethyl- 1 P038 692-42-2

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Chemical Name Extremely Haz Substances

40 CFR 355 (lb)

FINAL RQ

Haz Sub RQ 40 CFR 302.4

(lb)

Toxic Chemicals 40 CFR 372.65(a)

RCRA Waste NO

Haz Mat which are

RCRA wastes

CAS No.

Asbestos 1 x 1332-21-4Atrazine x 1912-24-9AuramineCI Solvent Yellow 34

100 x U014 492-80-8

Azaserine 1 U015 115-02-6Azinophos-ethyl 100/10,000 100 2642-71-9Azinophos-methyl 10/10,000 1 86-50-0Aziridine 1 151-56-4Aziridine, 2-methyl 1 75-55-8Barban 1## U280 101-27-9Barium and compounds x 7440-39-3Barium cyanide 10 P013 542-62-1Benfluralin x 1861-40-1Benomyl 1## x U271 17804-35-2Benzamide x 55-21-0Benzamide, 3,5-

Dichloro-N-(1,1-dimethyl-2-propynyl)

5000 U192 23950-58-5

Benzanthracene,7,12- dimethyl-

1 U094 57-97-6

Benz[c]acridine 100 U016 225-51-4Benz[a]anthracene 10 U018 56-55-3Benzenamine,2-methyl 100 95-53-4Benzenamine,2-methyl

5-nitro-100 U181 99-55-8

Benzenamine,2- methyl, hydrochlo ride

100 x U222 636-21-5

Benzenamine,3-(triflu oro-methyl)-

500 500 98-16-8

Benzenamine-4-chloro 1000 P024 106-47-8Benzenamine,4-chloro-

2-methyl-hydrochloride

100 U049 3165-93-3

Benzenenamine, 4- methyl

100 U353 106-49-0

Benzenamine,4-nitro- 5000 P077 100-01-6Benzenamine, 4,4’-

methylenebis-2- chloro

10 x U158 101-14-4

Benzenamine,NN-dim ethyl-4-phenylazo

10 x U093 60-11-7

Benzene 10 x U019 71-43-2Benzeneacetic acid, 4-

chloro-a-(4-chlo rophenyl)-a- hydroxy-, ethyl ester

10 510-15-6

Benzeneamine 5000 63-53-3Benzene,1-bromo-4-

phenoxy-100 U030 101-55-3

Benzenebutanoic acid,4-[bis(2- chloroethyl)amino]

10 U035 305-03-3

Benzene, chloro- 100 x U037 108-90-7Benzene, chloromethyl- 100 100-44-7

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Chemical Name Extremely Haz Substances

40 CFR 355 (lb)

FINAL RQ

Haz Sub RQ 40 CFR 302.4

(lb)

Toxic Chemicals 40 CFR 372.65(a)

RCRA Waste NO

Haz Mat which are

RCRA wastes

CAS No.

Benzenediamine, ar- methyl

10 95-80-7

1,2-Benzenedicarboxy lic acid,[bis(2-ethyl hexyl)]ester

100 x U028 117-81-7

1,2-Benzenedicarboxy lic acid, diethyl ester (diethyl phthlate)

5000 x U088 84-66-2

1,2-Benzenedicarboxy lic acid, dibutyl ester

100 54-74-2

Benzene,1,2-dichloro 100 x U070 95-50-1Benzene,1,3-dichloro 100 x U071 541-73-1Benzene,1,4-dichloro 100 x U072 106-46-7Benzene,

(dichloromethyl)-500 5000 x U017 98-87-3

Benzene,1,3-diisocy- anatomethyl

100 x U223 26471-62-5

Benzene, dimethyl- 100 x U239 1330-20-71,3-Benzenediol 5000 U201 108-46-31,2-Benzenediol,4-[1-

hydroxy-2-(methy lamino) ethyl]-

1000 P042 51-43-4

Benzene, hexachloro- 10 x U127 118-74-1Benzene, hexahydro-

(cyclohexane)1000 x U056 110-82-7

Benzene, methyl-(tou lene)

1000 x U220 108-88-3

Benzene,1-methyl-2,4- dinitro-

10 x U105 121-14-2

Benzene,2-methyl-1,3- dinitro-

100 x U106 606-20-2

Benzene,1-methyl ethyl- (Cumene)

5000 x U055 98-82-8

Benzene, nitro 1000 98-95-3Benzene, pentachloro- 10 U183 608-93-5Benzene, pentachloro

nitro-100 x U185 82-68-8

Benzenesulfonyl chloride

100 U020 98-09-9

Benzene,1,2,4,5-tetra chloro-

5000 U207 95-94-3

Benzene, 1,1-(2,2,2- trichloroethylidene) bis(4-methoxy

1 72-43-5

Benzene,1,3,5-trinitro- 10 U234 99-35-4Benzidine 1 x U021 92-87-51,2-Benzisothiazolin-

3(2H) one,1,1-diox ide

100 x U202 81-07-2

1,3-Benzodioxole,5-)1- 1 propenyl

100 x U141 120-58-1

1,3-Benzodioxole, 5-) 2,propenyl

100 x U203 94-59-7

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Chemical Name Extremely Haz Substances

40 CFR 355 (lb)

FINAL RQ

Haz Sub RQ 40 CFR 302.4

(lb)

Toxic Chemicals 40 CFR 372.65(a)

RCRA Waste NO

Haz Mat which are

RCRA wastes

CAS No.

1,3-Benzodioxole, 5- propyl

10 U090 94-58-6

1,3-Benzodixol-4-ol,2,2-dimethyl-, (Bendiocarb phenol)

1## U364 22961-82-6

1,3-Benziodioxol-4-ol, 2,2-dimethyl-, methyl carbamate (Bendiocarb)

1## x U278 22781-23-3

Benzo[b]fluoranthene 1 205-99-2Benzo[k]fluoranthene 5000 207-08-9Benzo[jk]fluorene 100 U120 206-44-0Benzoic acid 5000 65-85-0Benzoic acid, 2-

hydroxy-, compd. With (3aS-, cis)-1,2,3,3a,8,8a- hexahydro-1,3a,8- trimethylpyrrolo [2,3- b]indol-5-yl methylcarbamate ester (Physostigmine, salicylate) (1:1)

100/10,000 1## P188 57-64-7

Benzonitrile 5000 100-47-0Benzoyl peroxide x 94-36-0Benzo[ghi]perylene 5000 x 191-24-2Benzo[a]pyrene 1 U022 50-32-8p-Benzoquinone 10 106-51-4p-Benzoquinone 10 x U197 106-51-41,2-Benzphenanthrene 100 U050 218-01-9Benzotrichloride 100 10 x U023 98-07-7Benzoyl chloride 500 100 x 98-88-4Benzyl chloride 500 100 x P028 100-44-7Benzyl cyanide 500 500 140-29-4Beryllium chloride 1 7787-47-5Beryllium fluoride 1 7787-49-7Beryllium nitrate 1 13597-99-4Beryllium nitrate 1 7787-55-5Beryllium powder 10 x P015 7440-41-7alpha-BHC 10 319-84-6beta-BHC 1 319-85-7Delta-BHC 1 319-86-8Biphenyl 100 x 92-52-4(1,1’-Biphenyl)-

4,4’diamine, 3,3’dimethoxy-

100 x U091 119-90-4

(1,1’-Biphenyl)- 4,4’diamine, 3,3’dimethyl-

10 x U095 119-93-7

Bis(2-chloroethoxy) methane

1000 x U024 111-91-1

Bis(2-chloroisopropyl) ether

1000 x U027 108-60-1

Bis(chloromethyl )ether 100 10 542-88-1

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Chemical Name Extremely Haz Substances

40 CFR 355 (lb)

FINAL RQ

Haz Sub RQ 40 CFR 302.4

(lb)

Toxic Chemicals 40 CFR 372.65(a)

RCRA Waste NO

Haz Mat which are

RCRA wastes

CAS No.

Bis(chloromethyl)ketone

10/10,000 10 534-07-6

Bis(2-ethylhexyl)adi pate

x 103-23-1

Bis(tributylin) oxide x 56-35-9Boron trichloride 500 500 x 10294-34-5Boron trifluoride

compound with methyl ether (1:1)

1000 1000 353-42-4

Boron trifluoride 500 500 x 7637-07-2Bromadiolone 100/10,000 100 18772-56-7Bromacil x 314-40-9Bromacil, lithium salt x 53404-19-6Bromine 500 500 x 7726-95-62-Bromo-2-nitropropane

–1,3-diol (Bronopol)x 52-51-7

Bromochlorodifluo romethan (Halon 1211)

x 353-59-3

Bromotrifluorometh- ane (Halon 1301)

x 75-63-8

Bromoxynil x 1689-84-5Bromoxynil octanoate x 1689-88-21,3-Butadiene x 106-99-01,3-Butadiene,

1,1,2,3,4,4-hexachloro-

1 x U128 87-68-3

2-Butanone (Methyl ethyl ketone)

5000 U159 78-93-3

2-Butanone peroxide 10 U160 1338-23-42-Butene, 1,4-dichloro x 764-41-0Butyl acetate 5000 123-86-4iso-Butyl acetate 5000 110-19-0sec-Butyl acetate 5000 105-46-4tert-Butyl acetate 5000 540-88-5Butyl acrylate x 141-32-2sec-Butyl alcohol x 78-92-2tert-Butyl alcohol x 75-65-0Butyl benzyl Phthalate 100 85-68-7sec-Butylamine 1000 13952-84-6sec-Butylamine 1000 513-49-5tert-Butylamine 1000 75-64-9Butylamine 1000 109-73-9iso-Butylamine 1000 78-81-91,2-Butylene oxide x 106-88-7Butyraldehyde x 123-72-8Butyric acid 5000 107-92-6iso-Butyric acid 5000 79-31-2CI Acid Green 3 x 4680-78-8CI Acid Red 114 x 6459-94-5CI Basic Green 4 x 569-64-2CI Basic Red 1 x 989-38-8CI Direct Black 38 x 1937-37-7CI Direct Blue 6 x 2602-46-2

3-122Hazardous Materials

Page 123: SECTION 6 - Sustainable Fort Rucker · Web view• Flammable/Combustible Warehouses or Storage Buildings - These structures will have 3 ft wide aisles for access to doors, windows,

Chemical Name Extremely Haz Substances

40 CFR 355 (lb)

FINAL RQ

Haz Sub RQ 40 CFR 302.4

(lb)

Toxic Chemicals 40 CFR 372.65(a)

RCRA Waste NO

Haz Mat which are

RCRA wastes

CAS No.

CI Direct Blue 218 x 28407-37-6CI Direct Brown 95 x 16071-86-6CI Disperse Yellow 3 x 2832-40-8CI Food Red 15 x 81-88-9CI Food Red 5 x 3761-53-3CI Solvent Orange 7 x 3118-97-6CI Solvent Yellow 14 x 824-07-0CI Solvent Yellow 3 x 97-56-3CI Vat Yellow 4 x 128-66-5Cacodylic acid 1 U136 75-60-5Cadmium 10 x 7440-43-9Cadmium acetate 10 543-90-8Cadmium bromide 10 7789-42-6Cadmium chloride 10 10108-64-2Cadmium oxide 100/10,000 100 1306-19-0Cadmium stearate 1000/ 10,000 1000 2223-93-0Calcium arsenate 500/10,000 1 7778-44-1Calcium arsenite 1 52740-16-6Calcium carbide 10 75-20-7Calcium chromate 10 U032 13765-19-0Calcium cyanamide 1000 x 156-62-7Calcium cyanide 10 P021 592-01-8Calcium dodecylben

zene sulfonate1000 26264-06-2

Calcium hypochlorite 10 7778-54-3Camphechlor 500/10,000 1 8001-35-2Cantharidin 100/10,000 100 56-25-7Caprolactam 5000 105-60-2Captan 10 x 133-06-2Carbachol chloride 500/10,000 500 51-83-2Carbamic acid, ethyl

ester100 x U238 51-79-6

Carbamic acid, methyl- nitroso-,ethyl ester

1 U178 615-53-2

Carbamic acid, methyl- o- (((2,4-dimethyl- 1,3 dithiolan-2-y

100/10,000 1## P185 26419-73-8

Carbamic chloride, dimethyl-

1 x U097 79-44-7

Carbaryl 100 x 63-25-2Carbendazim 1## U372 10605-21-7Carbofuran 10/10,000 10 x 1563-66-2Carbofuran phenol 1## U367 1563-38-8Carbon disulfide 10,000 100 x P022 75-15-0Carbon oxyfluoride 1000 U033 353-50-4Carbon tetrachloride 10 x U211 56-23-5Carbonic dichoride 10 75-44-5Carbonyl sulfide 100 x 463-58-1Carbophenothion 500 500 786-19-6Carbosulfan 1## P189 55285-14-8Carboxin x 5234-68-4Catechol 100 x 120-80-9Chinomethionat x 2349-01-2Chloramben 100 x 133-90-4

3-123Hazardous Materials

Page 124: SECTION 6 - Sustainable Fort Rucker · Web view• Flammable/Combustible Warehouses or Storage Buildings - These structures will have 3 ft wide aisles for access to doors, windows,

Chemical Name Extremely Haz Substances

40 CFR 355 (lb)

FINAL RQ

Haz Sub RQ 40 CFR 302.4

(lb)

Toxic Chemicals 40 CFR 372.65(a)

RCRA Waste NO

Haz Mat which are

RCRA wastes

CAS No.

Chlordane 1000 1 x U036 57-74-9Chlorendic acid x 115-28-6Chlorfenvinfos 500 500 470-90-6Chlorinated camphene 1 8001-35-2Chlorinated fluorocar

bon(Freon 113)x 76-13-1

Chlorine 100 10 x 7782-50-5Chlorine cyanide 10 P033 506-77-4Chlorine dioxide x 10049-04-4Chlorinuron ethyl x 90982-32-4Chlormephos 500 500 24934-91-6Chlormequat chloride 100/10,000 100 999-81-5Chlornaphazine 100 U026 494-03-11-Chloro-1,1-

difluoroethane (HCFC 142(b))

x 75-68-3

1-Chloro-2,3- epoxypropane

100 106-89-8

2-Chloro-1,1,1-trifluoro-ethane (HCFC 133a)

x 75-88-7

Chloroacetaldehyde 1000 P023 107-20-0Chloroacetic acid 100/10,000 100 x 79-11-82-Chloroacetophenone x 532-27-43-chloroacetophenone 100 532-27-4p-Chloroaniline x 106-47-8Chlorobenzene 100 108-90-7Chlorobenzilate 10 x U038 510-15-6Chlorodibromomethane 100 124-48-1Chlorodifluoromethane

(HCFC-22)x 75-45-6

Chloroethane 100 x 75-00-3Chloroethanol 500 500 107-07-3Chloroethyl chlorofor

mate1000 1000 627-11-2

2-Chloroethyl vinyl ether

1000 U042 110-75-8

Chloroform 10,000 10 x U044 67-66-34-Chloro-m-cresol 5000 U039 59-50-7Chloromethane 100 74-87-3Chloromethyl ether 100 10 542-88-1Chloromethyl methyl

ether100 10 x U046 107-30-2

p-Chloro-o-toluidine x 95-69-2(Mono)chloropenta-

fluoroethane (CFC 115)

x 76-15-3

Chlorophacinone 100/10,000 100 3691-35-82-Chlorophenol 100 U048 95-57-84-Chlorophenyl phenyl

ether5000 7005-72-3

p-Chlorophenyl isocy anate

x 104-12-1

Chloropicrin x 76-06-2

3-124Hazardous Materials

Page 125: SECTION 6 - Sustainable Fort Rucker · Web view• Flammable/Combustible Warehouses or Storage Buildings - These structures will have 3 ft wide aisles for access to doors, windows,

Chemical Name Extremely Haz Substances

40 CFR 355 (lb)

FINAL RQ

Haz Sub RQ 40 CFR 302.4

(lb)

Toxic Chemicals 40 CFR 372.65(a)

RCRA Waste NO

Haz Mat which are

RCRA wastes

CAS No.

Chloroprene 100 x 126-99-83-Chloropropionitrile x 542-76-7Chlorotetrafluoroethane x 63938-10-3Chlorothalonil x 1897-45-6Chlorortrifluo

romethane (CFC 13)x 75-72-9

Chloroxuron 500/10,000 500 1982-47-4Chlorpyrifos 1 2921-88-2Chlorpyrifos methyl x 5598-72-3Chlorsulfonic acid 1000 7790-94-5Chlorsulfuron x 64902-72-3Chlorthiophos 500 500 21923-23-9Chromic acetate 1000 1066-30-4Chromic acid 10 11115-74-5Chromic acid 10 7738-94-5Chromic chloride 1/10,000 1 10025-73-7Chromic sulfate 1000 10101-53-8Chromium 5000 x 7440-47-3Chromous chloride 1000 10049-05-5Cobalt x 7440-50-8Cobalt,((2,2’-1,2-

ethanediylbis (ni-trilomethyli dyne))bis(6)

100/10,000 100 62207-76-5

Cobalt carbonyl 10/10,000 10 10210-68-1Cobaltous bromide 1000 7789-43-7Cobaltous formate 1000 544-18-3Cobaltous sulfamate 1000 14017-41-5Colchicine 10/10,000 10 64-86-8Copper 5000 x 7440-50-8Copper cyanide 10 P029 544-92-3Coumaphos 100/10,000 10 56-72-4Coumatetralyl 500/10,000 500 5836-29-3p-Cresidine x 120-71-8Cresol(s) (mixed iso

mers)100 x U052 1319-77-3

m-Cresol 100 x U052 108-39-4o-Cresol 1000/ 10,000 100 x U052 95-48-7p-Cresol 100 x U052 106-44-5Creosote 1 x U051 8001-58-9Cresylic acid (isomers

and mixtures)100 1319-77-3

m-Cresylic acid 100 108-39-4o-Cresylic acid 100 95-48-7p-Cresylic acid 100 106-44-5Crimidine 100/10,000 100 535-89-7Crotonaldehyde,(E)- 1000 100 U053 123-73-9Crotonaldehyde 1000 100 x U053 4170-30-3Cumene 5000 98-82-8Cumene hyroperoxide x 80-15-9Cupferron x 135-20-6Cupric acetate 100 142-71-2Cupric chloride 10 7447-39-4Cupric nitrate 100 3251-23-8

3-125Hazardous Materials

Page 126: SECTION 6 - Sustainable Fort Rucker · Web view• Flammable/Combustible Warehouses or Storage Buildings - These structures will have 3 ft wide aisles for access to doors, windows,

Chemical Name Extremely Haz Substances

40 CFR 355 (lb)

FINAL RQ

Haz Sub RQ 40 CFR 302.4

(lb)

Toxic Chemicals 40 CFR 372.65(a)

RCRA Waste NO

Haz Mat which are

RCRA wastes

CAS No.

Cupric oxalate 100 5893-66-3Cupric sulfate 10 7758-98-7Cupric sulfate

ammoniated100 10380-29-7

Cupric tartrate 100 815-82-7Cyanazine x 21725-46-2Cyanides (soluble cya

nide salts10 P030 57-12-5

Cyanogen 100 P031 460-19-5Cyanogen bromide 500/10,000 1000 U246 506-68-3Cyanogen iodide 1000/ 10,000 1000 506-78-5Cyanophos 1000 1000 2636-26-2Cyanuric fluoride 100 100 675-14-9Cycloate x U386 1134-23-22,5-Cyclohexadiene-

1,4-dione10 106-51-4

Cyclohexane, 1,2,3,4,5,6- hexachloro-,

1 58-89-9

Cyclohexanol x 108-93-0Cyclohexanone 5000 U057 108-94-1Cycloheximide 100/10,000 100 66-81-92-Cyclohexl-4,6-dini

trophenoll100 P034 131-89-5

Cyclohexylamine 10,000 10,000 108-91-81,3-Cyclopentadiene,

1,2,3,4,5,6- hexachloro

1 77-47-4

Cyclophosphamide 10 U058 50-18-0Cyfluthrin x 68359-37-5Cyhalothrin x 68085-85-82,4,-D8 x 94-82-62,4-D acid 100 x U240 94-75-72,4-D 2-ethyhexyl ester x 1928-43-42,4-D 2-ethyl-4-meth

ylpentyl esterx 53404-37-8

2,4,-D Butoxyethyl ester

x 1929-73-3

2,4-D Butyl ester x 94-80-42,4-D chlorocrotyl ester 2971-38-22,4-D esters 100 x 94-11-12,4-D esters 100 94-79-12,4-D esters 100 94-80-42,4-D esters 100 1320-18-92,4-D esters 100 1928-38-72,4-D esters 100 2971-38-22,4-D esters 100 53467-11-12,4-D esters 100 1928-61-62,4-D esters 100 1929-73-32,4-D esters 100 25168-26-7Daunomycin 10 U059 20830-81-3Dazomet x U366 533-74-4Dazomet, sodium salt x 53404-60-7DDD 1 U060 72-54-8

3-126Hazardous Materials

Page 127: SECTION 6 - Sustainable Fort Rucker · Web view• Flammable/Combustible Warehouses or Storage Buildings - These structures will have 3 ft wide aisles for access to doors, windows,

Chemical Name Extremely Haz Substances

40 CFR 355 (lb)

FINAL RQ

Haz Sub RQ 40 CFR 302.4

(lb)

Toxic Chemicals 40 CFR 372.65(a)

RCRA Waste NO

Haz Mat which are

RCRA wastes

CAS No.

DDE 5000 1 72-55-94,4,-DDE 1 72-55-9DDT 1 U061 50-29-3Decaborane(14) 500/10,000 500 17702-41-9Decabromodiphenyl

oxidex 1163-19-5

DEHP 100 117-81-7Demeton 500 500 8065-48-3Demeton-S-methyl 500 500 919-86-8Desmmedipham x 13684-56-5Dialifor 100/10,000 100 10311-84-9Diallate 100 x U062 2303-16-42,4-Diaminoanisole

sulfatex 39156-41-7

4,4’-Diaminodiphenyl ether

x 101-80-4

2,4-Diaminosole x 615-41-7Diaminotoluene (mixed

isomers)10 x U221 25376-45-8

Diaminotoluene(mixed isomers)

10 496-72-0

2,4-Diaminotoluene 10 U221 823-40-53,4-Diaminotoluene 10 x U221 95-80-7Diazinon 1 x 333-41-5Diazomethane 100 x 334-88-3Dibenz[a,h] anthracene 1 U063 53-70-3Dibenzofuran 100 x 132-64-9Dibenz(a)lpyrene 10 U064 189-55-9Diborane 100 100 19287-45-7Dibromotetrafluor-

ethane (Halon 2402x 124-73-2

Dibutyl phthalate 10 x U069 84-74-2Dicamba 1000 x 1918-00-9Dichlone 1 117-80-61,2-Dichloro-1,1-diflu

oroethane (HCFC- 132b)

x

1,2-Dichloro-1,1-difluoroethane (HCFC-132b)

x 1649-08-7

1,4-Dichloro- 2 butene 1 U074 764-41-02,2-Dichloro-1,1,1-tri-

fluoroethane (HCFC 123)

x 306-83-2

Dichloran x 99-30-9p-Dichlorobenzene 100 106-46-71,4,-Dichlorobenzene 100 106-46-7Dichlorobenzene

(mixed isomers)100 x 25321-22-6

3,3-Dichlorobenzidine x 91-94-13,3-Dichlorobenzidine

dihydrochloridex 612-83-9

3-127Hazardous Materials

Page 128: SECTION 6 - Sustainable Fort Rucker · Web view• Flammable/Combustible Warehouses or Storage Buildings - These structures will have 3 ft wide aisles for access to doors, windows,

Chemical Name Extremely Haz Substances

40 CFR 355 (lb)

FINAL RQ

Haz Sub RQ 40 CFR 302.4

(lb)

Toxic Chemicals 40 CFR 372.65(a)

RCRA Waste NO

Haz Mat which are

RCRA wastes

CAS No.

3,3-Dichlorobenzidine sulfate

x 64969-34-2

Dichlorobromomethane 5000 x 75-27-4Dichlorodifluoro-

methane(CFC-12)5000 x U075 75-71-8

1,1-Dichloroethane 1000 U076 75-34-31,2-Dichloroethane 100 x U077 107-06-21,1-Dichloroethylene 100 x U078 75-35-41,2-Dichloroethylene x 540-59-0Dichloroethyl ether 10,000 10 x U025 111-44-41,2-trans-

Dichloroethylene1000 U079 156-60-5

Dichlorofluoromethane (HCFC-21)

x 75-43-4

Dichloromethane 1000 75-02-2Dichloromethyl ether 100 10 x P016 542-88-1Dichloromethyl- phe

nylsilane1000 1000 149-74-6

Dichloropentafluoro propane

x 127564-92- 5

Dichlorophene x 97-23-42,4-Dichlorophenol 100 x U081 120-83-22,6-Dichlorophenol 100 U082 87-65-0Dichloropropane 1000 26638-19-7Dichloropropane- 100 8003-19-81,2-Dichloropropane 1000 x U083 78-87-5Dichloropropene 100 26952-23-81,3,-Dichloropropene 100 542-75-62,3-Dichloropropene 100 x 78-88-62,2-Dichloropropionic

acid5000 75-99-0

1,3-Dichloropropylene 100 x U084 542-75-6Dichlorotetrafluoro-

ethane (CFC-114)x 76-14-2

Dichlorotrifluoroethane x 34077-87-7Dichloro-1,1,2-trifluo

roethanex 90454-18-5

Dichlorvos 1000 10 x 62-73-7Dicholobenil 100 1194-65-6Dicofol x 115-32-2Dicrotophos 100 100 141-66-2Dicyclofop methyl x 51338-27-3Dicyclopenbtadiene xDieldrin 1 P037 60-57-1Diepoxybutane 500 10 x U085 1464-53-5Diethanolamine 100 x 111-42-2Diethatyl ethyl x 38727-55-8Diethylamine 100 109-89-7N,N-Diethylaniline 1000 91-66-7Diethyl chlorophos

phate500 500 814-49-3

Diethyl-p-nitrophe nylphosphate

100 P041 311-45-5

Diethyl sulfate 10 x 64-67-5

3-128Hazardous Materials

Page 129: SECTION 6 - Sustainable Fort Rucker · Web view• Flammable/Combustible Warehouses or Storage Buildings - These structures will have 3 ft wide aisles for access to doors, windows,

Chemical Name Extremely Haz Substances

40 CFR 355 (lb)

FINAL RQ

Haz Sub RQ 40 CFR 302.4

(lb)

Toxic Chemicals 40 CFR 372.65(a)

RCRA Waste NO

Haz Mat which are

RCRA wastes

CAS No.

3.3.-Dimethylbenzidine 10 119-93-7Diethylcarbamazine

citrate100/10,000 1642-54-2

1,4-Diethylene dioxide (1,4-Dioxane)

100 x U108 123-91-1

N,N’-Diethylhydrazine 10 U086 1615-80-1O,O-Diethyl S-methyl

dithiophosphate5000 U087 3288-58-2

Diethylhexylphthalate 100Diethylene glycol,

dicarbamate1## U395 5952-26-1

1,4-Diethyleneoxide 100 123-91-1Diethylstilbestrol 1 U089 56-53-1Diflubenzuron x 35367-38-5Digitoxin 100/10,000 1000 71-63-6Diglycidyl ether 1000 1000 2238-07-5Diglycidyl resorcinol

etherx 101-90-6

Digoxin 10/10,000 10 20830-75-5Dihydrosafrole x 94-58-6Diisopropylfluorophosp

hate100 100 P043 55-91-4

Dimefox 500 599 115-26-4Dimethipin x 55290-64-7Dimethoate 500/10,000 10 x P044 60-51-53.3-

Dimethoxybenzidine100 119-90-4

3,3-Dimethoxybenzidine dihydrochloride

x 612-82-8

3,3-Dimethoxybenzidine dihydrochloride

x 20325-40-0

3,3-Dimethoxybenzidine dihydrofluoride

x 41756-75-0

3.3-Dimethoxybenzidine hydrochloride

x 111984-09- 9

Dimethylamine 1000 x U092 124-40-3Dimethylamine dicamba x 2330-66-5Dimethyl aminoa zobenzene

10 60-11-7

N,N-Dimethylaniline 100 121-69-7Dimethylcarbamoyl

chloride1 79-44-7

Dimethyl chlorothio phosphate

x 2524-03-0

Dimethyldichlorosilane 500 500 x 75-78-5Dimethylformamide 100 68-12-2N-N’-

Dimethylformamidex 68-12-2

Dimethylhydrazine 1000 10 x U098 57-14-71,1,-Dimethylhydrazine 10 57-14-7

3-129Hazardous Materials

Page 130: SECTION 6 - Sustainable Fort Rucker · Web view• Flammable/Combustible Warehouses or Storage Buildings - These structures will have 3 ft wide aisles for access to doors, windows,

Chemical Name Extremely Haz Substances

40 CFR 355 (lb)

FINAL RQ

Haz Sub RQ 40 CFR 302.4

(lb)

Toxic Chemicals 40 CFR 372.65(a)

RCRA Waste NO

Haz Mat which are

RCRA wastes

CAS No.

1,2-Dimethylhydrazine 1 U099 540-73-8alpha,alpha-Dimethyl

phenethylamine5000 P046 122-09-8

2,4-Dimethylphenol 100 x U101 105-67-92,6-Dimethylphenol x 576-26-1Dimethyl phosphoro-

chloridothioate500 500 2524-03-0

Dimethyl phthalate 5000 x U102 131-11-3Dimethyl-p-phenyl-

enediamine10/10,000 99-98-9

Dimethyl sulfate 500 100 x U103 77-78-1Dimetilan 500/10,000 1 P191 644-64-4Di-n-butyl phthalate 10 84-74-2Dinitrobenzene (mixed) 100 25154-54-5o-Dinitrobenzene 100 x 528-29-0p-Dinitrobenzene 100 x 100-25-4Dinitrocresol 10/10,000 10 534-52-14,6-Dinitro-o-cresol and

salts10 534-52-1

Dinitrophenol 10 25550-58-72,4-Dinitrophenol 10 x P048 51-28-5Dinitrotoulene 10/10,000 10 x P047 534-52-13,4-Dinitrotoluene 10 610-39-9Dinitrotoluene (mixed

isomers)10 x 25321-14-6

2,4-Dinitrotoluene 10 121-14-2Di-(2-

ethylhexyl)phthlate (DEHP)

x 177-81-7

Dinocap x 39300-45-3Di-n-octyl phthalate 5000 x U107 117-84-0Dinoseb 100/10,000 1000 x P020 88-85-7Dinoterb 500/10,000 500 1420-07-1Di-n-propylnitro

samine(N-Nitrosodi- n-propylamine)

10 x U111 621-64-7

1,4,-Dioxane 100 123-91-1Dioxathion 500 500 78-34-2Diphacinone 10/10,000 10 82-66-6Diphenamid x 957-51-7Diphenylamine x 122-39-4Diphosphoramide,

octamethyl-100 100 P085 152-16-9

1,2-Diphenylhydrazine 10 x U109 122-66-7Dipotassium enfothal x 2164-07-0Dipropyl isocinchomer

onatex 136-45-8

Dipropylamine 5000 U110 142-84-7Diquat 1000 85-00-7Diquat 1000 2764-72-9Disodium cyanodithio

imidocarbonatex 138-93-2

Disulfoton 500 1 P039 298-04-4Dithiazinine iodide 500/10,000 500 514-73-8

3-130Hazardous Materials

Page 131: SECTION 6 - Sustainable Fort Rucker · Web view• Flammable/Combustible Warehouses or Storage Buildings - These structures will have 3 ft wide aisles for access to doors, windows,

Chemical Name Extremely Haz Substances

40 CFR 355 (lb)

FINAL RQ

Haz Sub RQ 40 CFR 302.4

(lb)

Toxic Chemicals 40 CFR 372.65(a)

RCRA Waste NO

Haz Mat which are

RCRA wastes

CAS No.

Dithiobiuret 100/10,000 100 P049 541-53-72,4-Dithiobiuret x 541-53-7Diuron 100 x 330-54-1Dodecylbenzene

sulfonic acid1000 27176-87-0

Dodine x 2439-10-32,4-DP x 120-36-5Emetine,dihyrochloride 1/10,000 1 316-42-7Endosulfan 10/10,000 1 P050 115-29-7alpha-Endosulfan 1 959-98-8Endosulfan sulfate 1 1031-07-8Endothall 1000 P088 145-73-3Endothion 500/10,000 500 2778-04-3Endrin 500/10,000 1 P051 72-20-8Endrin aldehyde 1 7421-93-4Epichlorohydrin 1000 100 x U041 106-89-8EPN 100/10,000 100 2104-64-51,2-Epoxybutane 100 106-88-7Ergocalciferol 1000/ 10,000 1000 50-14-6Ergotamine tartrate 500/10,000 500 379-79-3Ethanal 1000 75-07-0Ethanamine,N-ethyl-N-

nitroso-1 x U174 55-18-5

Ethanimidothioci acid 1## U394 30558-43-1Ethane,1,2-dibromo- 1 x U067 106-93-4Ethane, 1,1-dichloro 1000 75-34-3Ethane, 11,2-dichloro 100 107-06-2Ethane, hexachloro 100 x U131 67-72-1Ethane,1,1’-oxybis- 100 U117 60-29-7Ethane,1,1’-oxybis(2-

chloro-10 111-44-4

Ethanesulfonyl chlo ride, 2-chloro-

500 500 1622-32-8

Ethane,1,1,1,2-tetra chloro-

100 U208 630-20-6

Ethane,1,1,2,2-tetra chloro-

100 x U209 79-34-5

Ethanethioamide 10 x U218 62-55-5Ethane, 1,1,1-trichloro 1000 71-55-6Ethane,1,1,2-trichloro 100 x U227 79-00-5Ethanol,1,2-dichloro-

acetate1000 1000 10140-87-1

Ethanol,2,2’-(nitroso imino) bis-

1 U173 1116-54-7

Ethanone, 1-phenyl 5000 98-86-2Ethene, 1,1-dichloro 100 75-35-4Ethene, chloro- 1 x U043 75-01-4Ethene, tetrachloro 100 x U210 127-18-4Ethene, trichloro 100 79-01-6Ethion 1000 10 563-12-2Ethoprophos 1000 1000 x 13194-48-42-Ethoxyethanol 100 x 110-80-5Ethyl acrylate 1000 x U113 140-88-5Ethyl carbamate 100 51-79-6

3-131Hazardous Materials

Page 132: SECTION 6 - Sustainable Fort Rucker · Web view• Flammable/Combustible Warehouses or Storage Buildings - These structures will have 3 ft wide aisles for access to doors, windows,

Chemical Name Extremely Haz Substances

40 CFR 355 (lb)

FINAL RQ

Haz Sub RQ 40 CFR 302.4

(lb)

Toxic Chemicals 40 CFR 372.65(a)

RCRA Waste NO

Haz Mat which are

RCRA wastes

CAS No.

Ethylbenzene 1000 x 100-41-4Ethylbis(2-chloroet

hyl)amine500 500 538-07-8

Ethyl chloride 100 75-00-3Ethyl chloroformate x 541-41-3Ethyl dipropylthiocar

bamate (EPTC)x U390 759-94-4

Ethylene x 74-85-1Ethylenebisdithiocar

bamic- acid, salts & esters/

5000 U114 111-54-6

Ethylenediamine 10,000 5000 107-15-3Ethylenediamine tetra-

acetic acid (EDTA)5000 60-00-4

Ethylene dibromide 1 106-93-4Ethylene dichloride 100 107-06-2Ethylene Fluorohydrin 10 10 371-62-0Ethylene glycol 5000 x 107-21-1Ethyleneimine 500 1 x P054 151-56-4Ethylene oxide 1000 10 x U115 75-21-8Ethylenethiocyanate 10,000 10,000 542-90-5Ethylene thiourea 10 x U116 96-45-7Ethylidene dichloride 1000 x 75-34-3Ethyl methacrylate 1000 U118 97-63-2Ethyl methanesulfonate 1 U119 62-50-0Famphur 1000 x P097 52-85-7Fenamiphos 10/10,000 10 22224-92-6Fenarimol x 60100-88-9Fenbutatin oxide x 13356-08-6Fenitrothion 500 122-14-5Fenoxaprop ethyl x 66441-23-4Fenoxycarb x 72490-01-8Fenpropathrin x 39515-41-8Fensulfothion 500 500 115-90-2Fenthion 55-38-9Fenvalerate x 51630-58-1Ferbam x U396 14484--64- 1Ferric ammonium

citrate1000 1185-57-5

Ferric ammonium oxalate

1000 2944-67-4

Ferric ammonium oxalate

1000 55488-87-4

Ferric chloride 1000 7705-08-0Ferric fluoride 100 7783-50-8Ferric nitrate 1000 10421-48-4Ferric sulfate 1000 10028-22-5Ferrous ammonium

sulfate1000 10045-89-3

Ferrous chloride 100 7758-94-3Ferrous sulfate 1000 7720-78-7Ferrous sulfate 1000 7782-63-0Florouracil 500/10,000 51-21-8Fluenetil 100/10,000 100 4301-50-2

3-132Hazardous Materials

Page 133: SECTION 6 - Sustainable Fort Rucker · Web view• Flammable/Combustible Warehouses or Storage Buildings - These structures will have 3 ft wide aisles for access to doors, windows,

Chemical Name Extremely Haz Substances

40 CFR 355 (lb)

FINAL RQ

Haz Sub RQ 40 CFR 302.4

(lb)

Toxic Chemicals 40 CFR 372.65(a)

RCRA Waste NO

Haz Mat which are

RCRA wastes

CAS No.

Fluometuron x 2164-17-2Fluorene 5000 86-73-7Fluorine 500 10 x P056 7782-41-4Fluoroacetamide 100/10,000 100 P057 640-19-7Fluoroacetic acid 10/10,000 10 144-49-0Fluoroacetyl chloride 10 10 359-06-81,1-Dichloro-1-fluoro

ethane (HCFC-141b)x 1717-80-6

1,1,1,2-Tetrachloro-2- fluoroethane (HCFC- 121a)

x 354-11-0

1,1,2,2-Tetrachloro-1- fluoroethane (HCFC 121)

x 354-14-3

Fluorouracil 500/10,000 100 x 51-21-8Fluvalinate x 69409-94-5Folpet x 133-07-3Fomesafen x 72178-02-0Fonofos 500 500 944-22-9Formaldehyde 500 100 x U122 50-00-0Formaldehyde cyano

hydrin1000 1000 107-16-4

Formetanate hydro chloride

500/10,000 1## P198 23422-53-9

Formic acid 5000 x U123 64-18-6Formothion 100 100 2540-82-1Formparanate 100/10,000 1## P197 17702-57-7Fosthietan 500 500 21548-32-3Fuazifop-butyl x 69806-50-4Fuberidazole 100/10,000 100 3878-19-1Fulminic acid, mercu

ry(II) salt10 P065 628-86-4

Fumaric acid 5000 110-17-8Furan 500 100 U124 110-00-92-Furancarboxaldehyde 5000 U125 98-01-12,5-Furandione 5000 x U147 108-31-6Furan, tetrahydro- 1000 U213 109-99-9Gallium trichloride 500/10,000 500 13450-90-3D-Glucopyranose,2-

deoxy-2-(3-methyl- 3-ni-trosoureido)-

1 U206 18883-66-4

Glycidylaldehyde 10 U126 765-33-4Guanidine,N-nitroso-N methyl-N’-nitro

10 U163 70-25-7

Heptachlor 1 x P059 76-44-8Heptachlor epoxide 1 1024-57-3Hexachlorobenzene 10 118-74-1Hexachlorobutadiene 1 87-68-3Hexachlorocyclohex ane 1 58-89-9Hexachlorocyclopenta

diene100 10 x U130 77-47-4

Hexachloroethane 100 67-72-1Hexachloronaphthalene x 1335-87-1Hexachlorophene 100 x U132 70-30-4

3-133Hazardous Materials

Page 134: SECTION 6 - Sustainable Fort Rucker · Web view• Flammable/Combustible Warehouses or Storage Buildings - These structures will have 3 ft wide aisles for access to doors, windows,

Chemical Name Extremely Haz Substances

40 CFR 355 (lb)

FINAL RQ

Haz Sub RQ 40 CFR 302.4

(lb)

Toxic Chemicals 40 CFR 372.65(a)

RCRA Waste NO

Haz Mat which are

RCRA wastes

CAS No.

Hexachloropropene 1000 U234 1888-71-7Hexaethyl tetraphos

phate100 P062 757-58-4

Hexamethyleme-1,6- diisocyante

100 822-06-0

Hexamethylenedi amine, N,N’-dibutyl-

500 4835-11-4

Hexamethylphosphora mide

1 x 680-31-9

Hexane 5000 x 110-54-3Hexazinone x 51235-04-2Hexone 5000 108-10-1Hydramethylnon x 67485-29-4Hydrazine 1000 1 x U133 302-01-2Hydrazine, 11,1-dime

thyl-10 57-14-7

Hydrazine, 1,2-diphe nyl-

10 122-66-7

Hydrazine. methy; 10 60-34-4Hydrazine sulfate x 10034-93-2Hydrochloric acid 5000 7647-01-0Hydrocyanic acid 100 10 x P063 74-90-8Hydrofluoric acid 100 7664-39-3Hydrogen fluoride 100 100 x U134 7664-39-3Hydrogen chloride (gas

only)1000 500 x 7647-01-0

Hydrogen perioxide (conc > 52%)

1000 1000 7722-84-1

Hydrogen phosphide 100 7803-51-2Hydrogen selenide 10 10 7783-07-5Hydrogen sulfide 500 100 U135 7783-06-4Hydroquinone 500/10,000 100 x 123-31-9Imazalil x 35554-44-02-imidazolidinethione 10 96-45-7Indeno(1,2,3-cd)pyrene 100 U137 193-39-53-Iodo-2-propynyl

butylcarbamatex U375 55406-53-6

Iron, pentacarbonyl- 100 100 x 13463-40- 06

Isobenzan 100/10,000 100 297-78-91,3-Isobenzofurandione 5000 x U190 85-44-9Isobutyl alcohol 5000 U140 78-83-1Isobutyraldehyde x 78-84-2Isobutyronitrile 1000 1000 78-82-0Isocyanic acid,3,4-

dichlorophenyl ester500/10,000 500 102-36-3

Isodrin 100/10,000 1 x P060 465-73-6Isofenphos x 25311-71-1Isoflurophate 100 100 56-91-4Isomethane 100 74-88-4Isophorone 5000 78-59-1Isophorone diisocyan

ate500 100 4098-71-9

Isoprene 100 78-79-5

3-134Hazardous Materials

Page 135: SECTION 6 - Sustainable Fort Rucker · Web view• Flammable/Combustible Warehouses or Storage Buildings - These structures will have 3 ft wide aisles for access to doors, windows,

Chemical Name Extremely Haz Substances

40 CFR 355 (lb)

FINAL RQ

Haz Sub RQ 40 CFR 302.4

(lb)

Toxic Chemicals 40 CFR 372.65(a)

RCRA Waste NO

Haz Mat which are

RCRA wastes

CAS No.

Isopropanolamine dode-cyclbenzene sulfonate

1000 42504-46-1

Isopropyl alcohol (mfg- strong acid processes)

x 67-63-0

Isopropyl chlorofor mate

1000 1000 108-23-6

4,4’-Isopropylidene diphenol

x 80-05-7

Isopropylmethylpyra zolyl dimethylcar bamate

500 1## P192 119-38-0

Kepone 1 U142 143-50-0Lactofen x 77501-63-4Lactonitrile 1000 1000 78-97-7Lasiocarpine 10 U143 303-34-4Lead 10 x 7439-92-1Lead arsenate 1 10102-48-4Lead arsenate 1 7645-25-2Lead arsenate 1 7784-40-9Lead chloride 10 7758-95-4Lead fluoborate 10 13814-96-5Lead fluoride 10 7783-46-2Lead iodide 10 10101-63-0Lead nitrate 10 10099-74-8Lead phosphate 10 U145 7446-27-7Lead stearate 10 1072-35-1Lead stearate 10 52652-59-2Lead stearate 10 7428-48-0Lead stearate 10 56189-09-4Lead subacetate 10 U146 1335-32-6Lead sulfate 10 15739-80-7Lead sulfate 10 7446-14-2Lead sulfide 10 1314-87-0Lead thiocyanate 10 592-87-0Leptophos 500/10,000 500 21609-90-5Lewisite 10 10 541-25-3Lindane 1000/ 10,000 1 x U129 58-89-9Linuron x 330-55-2Lithium carbonate x 554-13-2Lithium chromate 10 14307-35-8Lithium hydride 100 100 7580-67-8m-Nitrotoluene 1000 99-08-1Malathion 100 x 121-75-5Maleic acid 5000 110-16-7Maleic anhydride 5000 108-31-6Maleic, hydrazide 5000 U148 123-33-1Malononitrile 500/10,000 1000 x U149 109-77-3Maneb x 12427-38-2Manganese x 7439-96-5Manganese dimeth

yldithiocarbamate1## P196 15339-36-3

3-135Hazardous Materials

Page 136: SECTION 6 - Sustainable Fort Rucker · Web view• Flammable/Combustible Warehouses or Storage Buildings - These structures will have 3 ft wide aisles for access to doors, windows,

Chemical Name Extremely Haz Substances

40 CFR 355 (lb)

FINAL RQ

Haz Sub RQ 40 CFR 302.4

(lb)

Toxic Chemicals 40 CFR 372.65(a)

RCRA Waste NO

Haz Mat which are

RCRA wastes

CAS No.

Manganese, tricarbo nyl methylcyclopen tadienyl

100 100 12108-13-3

1-(3-Chloroallyl)-3,5,7- triaza-1-azoniaada mantane chloride

x4080-31-3

MDI 5000 101-68-8Mechlorethamine 10 10 x 51-75-2Mecoprop x 93-65-2MEK 5000 78-93-3Melphalan 1 U150 148-82-3Mephosfolan 500 500 950-10-72-

Mercaptobenzothiazole

x 149-30-4

Mercuric acetate 500/10,000 500 1600-27-7Mercuric chloride 500/10,000 500 7487-94-7Mercuric cyanide 1 592-04-1Mercuric nitrate 10 10045-94-0Mercuric oxide 500/10,000 500 21908-53-2Mercuric sulfate 10 7783-35-9Mercuric thiocyanate 10 592-85-8Mercurous nitrate 10 7782-86-7Mercurous nitrate 10 10415-75-5Mercury 1 x U151 7439-97-6Merphos x 150-50-5Methacrolein diacetate 1000 1000 10476-95-6Methacrylic anhydride 500 500 760-93-0Methacryloyl chloride 100 100 920-46-7Methacrylonitrile 500 1000 x U152 126-98-7Methacryloyloxyethyl

isocyanate100 100 30674-80-7

Methamidophos 100/10,000 100 10265-92-6Metham sodium 1## x U384 137-42-8Methanamine, N-

methyl-N-nitro10 62-75-9

Methane, bromo 1000 74-83-9Methane, chloro 100 x U045 74-87-3Methane,

chloromethoxy10 107-30-2

Methane, dibromo- 1000 x U068 74-95-3Methane, dichloro- 1000 x U080 75-09-2Methaneiodd 100 x U138 74-88-4Methane, oxybis(chloro 10 542-88-1Methanesulfanyl

chloride, trichloro500 100 x P118 594-42-3

Methanesulfonyl fluoride

1000 1000 558-25-8

Methane, tetrachloro 10 58-23-5Methane, tribromo 100 75-25-2Methane, trichloro 10 67-66-3Methane, trichloroflu

oro- (CFC-11)5000 U121 75-69-4

3-136Hazardous Materials

Page 137: SECTION 6 - Sustainable Fort Rucker · Web view• Flammable/Combustible Warehouses or Storage Buildings - These structures will have 3 ft wide aisles for access to doors, windows,

Chemical Name Extremely Haz Substances

40 CFR 355 (lb)

FINAL RQ

Haz Sub RQ 40 CFR 302.4

(lb)

Toxic Chemicals 40 CFR 372.65(a)

RCRA Waste NO

Haz Mat which are

RCRA wastes

CAS No.

4,7-Methano-1H- Indene, 1,4,5,6,7,8,8- hep tachloro-3a,4,7,7a- tetrahydro

1 57-75-9

4,7-Methano-1H- Indene, 1,2,4,5,6,7,8,8- octachloro- 2,3,3a,4,7,7a- hexahydro

5000 57-74-9

Methanol 5000 x U154 67-56-1Methapyrilene 5000 U155 91-80-5Methazole x 20354-26-1Methidathion 500/10,000 500 950-37-8Methiocarb 500/10,000 10 x 2032-65-7Methomyl 500/10,000 100 P066 16752-77-5Methoxone x 94-74-6Methoxone sodium salt x 3653-48-3Methoxychlor 1 x 72-43-52-Methoxyethanol x 109-86-4Methoxyethylmercuri

cacetate500/10,000 500 151-38-2

Methyl acrylate x 96-33-3Methyl alcohol 5000 67-56-12-Methyl azidine 1 75-55-8Methyl bromide 1000 1000 x U029 74-83-91-Methylbutadiene 100 U186 504-60-9Methyl Chloride 100 74-87-3Methyl 2-chloroacry

late500 500 80-63-7

Methyl chlorocarbonate x 79-22-1Methyl chloroform 1000 x U226 71-55-6Methyl chloroformate

(Methylchlorocarbonate)

500 1000 U156 79-22-1

4,4’-Methylenebis(2- chloroaniline)

10 101-14-4

4,4’-Methylenedi aniline

10 x 101-77-9

4,4’-Methylene bis(N,N-di-

methyl) benzenamine

x 101-61-1

Methylene-bis-(phenyl iso-cyanate)(MBI)

x 101-68-8

Methylene chloride 1000 75-09-2Methylene diphenyl

diisocyanate5000 101-68-8

Methyl ethyl ketone 5000 78-93-3Methyl hydrazine 500 10 x P068 60-34-4Methyl iodide 100 74-88-4Methyl isobutyl ketone 5000 x U161 108-10-1Methyl isocyanate 500 10 x P064 624-83-9Methyl isothiocyanate 500 500 x 556-61-12-Methyllactonitrile x 75-86-5

3-137Hazardous Materials

Page 138: SECTION 6 - Sustainable Fort Rucker · Web view• Flammable/Combustible Warehouses or Storage Buildings - These structures will have 3 ft wide aisles for access to doors, windows,

Chemical Name Extremely Haz Substances

40 CFR 355 (lb)

FINAL RQ

Haz Sub RQ 40 CFR 302.4

(lb)

Toxic Chemicals 40 CFR 372.65(a)

RCRA Waste NO

Haz Mat which are

RCRA wastes

CAS No.

Methyl mercaptan 500 100 U153 74-93-1Methylmercuric dicy-

anamide500/10,000 500 502-39-6

Methyl methacrylate 1000 x U162 80-62-6N-Methylolacrylamide x 924-42-5Methyl parathion x 298-00-04-Methyl-2-pentanone 5000 108-10-1Methyl phenkapton 500 500 3735-23-7Methyl phosphonic

dichloride100 100 676-97-1

2-Methylpyridine x 109-06-8N-Methyl-2-pyrroli

donex 873-50-4

Methyl tert-butyl ether 1000 x 1634-04-4Methyl thiocyanate 10,000 10,000 556-64-9Methylthiouracil 10 U164 56-04-2Methyltrichlorosilane 500 500 x 75-79-6Methyl vinyl ketone 10 10 78-94-4Metiram x 9006-42-2Metolcarb 100/10,000 1## P190 1129-41-5Metribuzin x 21087-64-9Mevinphos 500 10 x 7786-34-7Mexacarbate 500/10,000 1000 315-18-4Michler’s ketone x 90-94-8Mitomycin C 500/10,000 10 U010 50-07-7Molinate x U365 2212-67-1Molybdenum trioxide x 1313-27-5Moncrotophos 10/10,000 10 6923-22-4Monoethylamine 100 75-04-7Monomethylamine 100 74-89-5Monuron x 150-68-5Muscimol 500/10,000 1000 P007 2763-96-4Mustard gas 500 500 x 505-60-2Myclobutanil x 88671-89-0Nabam x 142-59-6Naled 10 x 300-76-5Naphthalene 100 x U165 91-20-31-Naphthalamine 100 x U167 134-32-72-Naphthylamine 10 x U168 91-59-81,4-Naphthalenedione 5000 U166 130-15-4Naphthenic acid 100 1338-24-5Nickel 100 x 7440-02-0Nickel ammonium sul

fate100 15699-18-0

Nickel carbonyl 1 10 P073 13463-39-3Nickel chloride 100 37211-05-5Nickel chloride 100 7718-54-9Nickel cyanide 10 P074 557-19-7Nickel hydroxide 10 12054-48-7Nickel nitrate 100 14216-75-2Nickel sulfate 100 7786-81-4Nicotine 100 100 P075 54-11-5Nicotine sulfate 100/10,000 100 65-30-5Nitrapyrin x 1929-82-4

3-138Hazardous Materials

Page 139: SECTION 6 - Sustainable Fort Rucker · Web view• Flammable/Combustible Warehouses or Storage Buildings - These structures will have 3 ft wide aisles for access to doors, windows,

Chemical Name Extremely Haz Substances

40 CFR 355 (lb)

FINAL RQ

Haz Sub RQ 40 CFR 302.4

(lb)

Toxic Chemicals 40 CFR 372.65(a)

RCRA Waste NO

Haz Mat which are

RCRA wastes

CAS No.

Nitric acid 1000 1000 x 7697-37-2Nitric oxide 100 10 P076 10102-43-9Nitrilotriacetic acid x 139-13-9p-Nitroaaniline x 100-01-6Nitrobenzene 10,000 1000 x U169 98-95-34-Nitrobiphenyl 10 x 92-93-3Nitrocyclohexane 500 500 1122-60-7Nitrogen x 1836-75-5Nitrogen dioxide 100 10 P078 10102-44-0Nitrogen dioxide 10 P078 10544-72-6Nitroglycerine 10 x P081 55-63-05-Nitro-o-anisidine x 99-59-25-Nitro-o-toluidine x 99-55-6Nitrophenol (mixed) 100 25154-55-6m-Nitrophenol 100 554-84-7o-Nitrophenol 100 x 88-75-5p-Nitrophenol 100 x U170 100-02-74-Nitrophenol 100 100-02-72-Nitropropane 10 x U171 79-46-9Nitrosodimethylamine 1000 10 x P082 62-75-9N-Nitroso-N-ethylurea 1 x 759-73-9N-Nitroso-N-methy

lurea1 x 684-93-5

N-Nitrosodimethy lamine

10 62-75-9

N-Nitrosodipheny lamine

100 x 86-30-6

p-Nitrosodipheny lamine

x 156-10-5

N-Nitrosomethylviny lamine

10 x 4549-40-0

N-Nitrosomorpholine 1 x 59-89-2N-Nitrosonornicotine x 16543-55-8N-Nitrosopiperidine 10 x U179 100-75-4N-Nitrosopyrrolidine 1 U180 930-55-2Nitrotoluene 1000 1321-12-6o-Nitrotoluene 1000 88-72-2p-Nitrotoluene 1000 99-99-0Norbormide 100/10,000 100 991-42-4Norflurazon x 27314--13- 2Octachloronaphthalene x 2234-13-1Octachlorostyrene x 29082-74-4Oryzalin x 19044-88-3Osmium tetroxide 1000 x P087 20816-12-0Ouabain 100/10,000 100 630-60-4Oxamyl 100/10,000 1## P194 23135-22-01,2-Oxathiolane,2,2-

dioxide10 x U193 1120-71-4

Oxetane,3,3- bis(chlo romethyl)-

500 500 78-71-7

Oxirane 10 75-21-8Oxirane, (chlorome

thyl)100 106-89-8

Oxydemeton methyl x 301-12-2

3-139Hazardous Materials

Page 140: SECTION 6 - Sustainable Fort Rucker · Web view• Flammable/Combustible Warehouses or Storage Buildings - These structures will have 3 ft wide aisles for access to doors, windows,

Chemical Name Extremely Haz Substances

40 CFR 355 (lb)

FINAL RQ

Haz Sub RQ 40 CFR 302.4

(lb)

Toxic Chemicals 40 CFR 372.65(a)

RCRA Waste NO

Haz Mat which are

RCRA wastes

CAS No.

Oxydiazon x 19666-30-9Oxydisulfoton 500 500 2497-07-6Oxyfluorfen x 42874-03-3Ozone 100 100 x 10028-15-6Paraformaldehyde 1000 30525-89-4Paraldehyde 1000 x 123-63-7Paraquat dichloride 10/10,000 10 x 1910-42-5Paraquat methosulfate 10/10,000 10 2074-50-2Parathion 100 10 x P089 56-38-2Parathion, methyl 100/10,000 100 P071 298-00-0Paris green (Cuprie

acetoarsenite)500/10,000 1 12002-03-8

PCNB 100 82-68-8Pebulate x U391 1114-71-2Pendimethalin x 40487-42-1Pentaborane 500 500 19624-22-7Pentachlorobenzene x 608-93-5Pentachloroethane 10 x U184 76-01-7Pentachloronitroben

zene100 82-68-8

Pentachlorophenol 10 x U242 87-86-5Pentadecyclamine 100/10,000 100 2570-26-51,1-Dichloro-1,2,2,3,3-

pentafluoropropane (HCFC-225cc)

x 13474-88-9

1,1-Dichloro-1,2,3,3,3- pentafluoropropane (HCFC-225ab)

x 111512-56- 2

1,2-dichloro-1,1,2,3,3- pentafluoropropane (HCFC-225bb)

x 422-44-6

1,2-Dichloro1,1,3,3,3- pentafluoropropane (HCFC-225da)

x 431-86-7

1,3-Dichloro-1,1,2,2,3- pentafluoropropane (HCFC-225cb

x 507-55-1

1,3-Dichloro-1,1,2,3,3- pentafluoropropane (HCFC-225ea)

x 136013-79- 1

2,2-Dichloro-1,1,1,3,3- pentafluoropropane (HCFC-225aa)

x 128903-21- 9

2,3-Dichloro-1,1,1,2,3- pentafluoropropane (HCFC-225ba)

x 128903-21- 9

3,3-dichloro-1,1,1,2,2- pentafluoropropane (HCFC-25ca)

x 422-56-0

Pentobarbital sodium x 57-33-0Peracetic acid 500 500 x 79-121-0Perchloroethylene 10 127-18-4Perchloromethyl

mrcaptan100 100 594-42-3

3-140Hazardous Materials

Page 141: SECTION 6 - Sustainable Fort Rucker · Web view• Flammable/Combustible Warehouses or Storage Buildings - These structures will have 3 ft wide aisles for access to doors, windows,

Chemical Name Extremely Haz Substances

40 CFR 355 (lb)

FINAL RQ

Haz Sub RQ 40 CFR 302.4

(lb)

Toxic Chemicals 40 CFR 372.65(a)

RCRA Waste NO

Haz Mat which are

RCRA wastes

CAS No.

Permethrin x 52645-53-1Phenanthrene 5000 x 85-01-8Phenol 500/10,000 1000 x U188 108-95-2Phenol,2,2’-thio bis (4-

chloro-6-methyl100/10,000 100 4418-66-0

Phenol,2,3,4,6-tetra chloro

10 U212 58-90-2

Phenol,2,4,5-trichloro 10 x U230 95-95-4Phenol,2,4,6-trichloro 10 x U231 88-06-2Phenol,3-(1-methyl

ethyl), methylcar bamate

500/10,000 1## P202 64-00-6

Phenol, methyl 100 1319-77-3Phenothrin x 26002-80-2Phenoxarsine,10,10’-

oxydi-500/10,000 500 58-36-6

Phenyl dichloroarsine 500 1 P036 696-28-6p-Phenylenediamine 5000 x 106-50-31,2-Phenylenediamine x 95-54-51,2-Phenylenediamine

dihydrochloridex 615-28-1

1,3-Phenylenediamine x 108-45-21,4-Phenylenediamine

dihydrochloridex 624-18-0

Phenylhydrazine hydrochloride

1000/ 10,000 1000 59-88-1

Phenylmercury acetate 500/10,000 100 P092 62-38-42-Phenylphenol x 90-43-7Phenylsilatrane 100/10,000 100 2097-19-0Phenylthiourea 100/10,000 100 P093 103-85-5Phenytoin x 57-41-0Phorate 10 10 P094 298-02-2Phosacetim 100/10,000 100 4104-14-7Phosfolan 100/10,000 100 947-02-4Phosgene 10 10 x P095 75-44-5Phosmet 10 732-11-6Phosphamidon 100 100 13171-21-6Phosphine 500 100 x P096 7803-51-2Phosphonothioic acid

methyl-O-(4-nitro phenyl)O-phenyl ester

500 500 2665-30-7

Phosphonothioic acid, methyl-O-ethyl-O- (4-(meth ylthio)phenyk Ester

500 500 2703-13-1

Phosphonothioic acid, methyl-,s-(2-(bis(1- methylethyl)amino Ethyl o-Ethyl Ester

100 100 50782-69-9

Phosphoric acid 5000 7664-38-2Phosphoric acid,

dimethyl 4-(meth ylthio)phenyl ester

500 500 3254-63-5

3-141Hazardous Materials

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Chemical Name Extremely Haz Substances

40 CFR 355 (lb)

FINAL RQ

Haz Sub RQ 40 CFR 302.4

(lb)

Toxic Chemicals 40 CFR 372.65(a)

RCRA Waste NO

Haz Mat which are

RCRA wastes

CAS No.

Phosphorothioc acid, O,O-diethyl, O- pyrazinyl ester

20 56-38-2

Phosphorothioc acid, O,O-diethyl, O- (40nitrophenyl) ester

500 100 P040 297-97-2

Phosphorothioic acid, O,O-dimethyl-S-(2-

methylthio)ethyl est

500 500 2587-90-8

Phosphorus 100 1 x 7723-14-0Phosphorus oxychlo

ride500 1000 10025-87-3

Phosphorus pentachlo ride

500 500 10026-13-8

Phosphorus pentasul fide

100 U189 1314-80-3

Phosphorus pentoxide 10 1314-56-3Phosphorus trichloride 1000 1000 7719-12-2Phthalic anhydride 5000 85-44-9Physostigmine 100/10,000 1## P204 57-47-6Picloram x 1918-02-1Picric acid x 88-89-12-Picoline 5000 U191 109-06-8Picrotoxin 500/10,000 500 124-87-8Piperidine 1000 1000 110-89-4Piperonyl butoxide x 51-03-6Pirimifos-ethyl 1000 1000 23505-41-1Piriimiphos methyl x 29232-93-7Polychlorinated biphe

nyls1 x 1336-36-3

Potassium arsenate 1 7784-41-0Potassium arsenite 500/10,000 1 10124-50-2Potassium bichromate 10 7778-50-9Potassium bromate x 7758-01-2Potassium chromate 10 7789-00-6Potassium cyanide 100 10 P098 151-50-8Potassium dimeth

yldithioccarbamatex U383 128-03-0

Potassium hydroxide 1000 1310-58-3Potassium n-meth

yldithiocarbamatex U377 137-41-7

Potassium permangan ate

100 7722-64-7

Potassium silver cyanide

500 1 P099 506-61-6

Profenofos x 41198-08-7Promecarb 500/10,000 1## P201 2631-37-0Prometryn x 7287-19-6Pronamide x 23950-58-5Propachlor x 1918-16-71-Propanamine 5000 U194 107-10-83-Chloro-1,1,1-

trifluoro-propane (HCFC- 253fb)

x460-35-5

3-142Hazardous Materials

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Chemical Name Extremely Haz Substances

40 CFR 355 (lb)

FINAL RQ

Haz Sub RQ 40 CFR 302.4

(lb)

Toxic Chemicals 40 CFR 372.65(a)

RCRA Waste NO

Haz Mat which are

RCRA wastes

CAS No.

1,2-Dibromo-3-chloro propane

1 x U066 96-12-8

1-Bromo-1-(bromomethyl)-1,3- propanedicarbonitril

x 35691-65-7

Propanil x 709-98-81-Propanol,2,3-

dibromo-phosphate (3:1)

10 x U235 126-72-7

Propargite 10 x 2312-35-8Propargyl alcohol 1000 x P102 107-19-7Propargyl bromide 10 10 106-96-71-Propene, 1,3-dichloro 100 542-76-63-Chloro-2-methyl-1-

propenex 563-47-3

2-propenal 1 106-02-82-Propenamide 5000 79-06-1Propenenitrile 500 10 P101 107-12-0Propenenitrile,3-

chloro-1000 1000 P027 542-76-7

2-Propenenitrile 100 107-13-12-Propenoic acid 5000 79-10-72-Propenoic acid, ethyl

ester1000 140-88-5

2-Propenoic acid, 2- methyl-, methyl ester

1000 80-62-6

Propfamphos x 31218-83-4Propham 1## U373 122-42-9Propiconazole x 60207-90-1Propiolactone,beta- 500 10 x 57-57-8Propionaldehyde 1000 x 123-38-6Propionic acid 5000 79-09-4Propionic acid,2-(2,4,5-

trichlorophenoxy)-100 U233 93-72-1

Propionic anhydride 5000 123-62-62,2-Dibromo-3-nitrilo

propionamidex 10222-01-2

Propiophenone,4’- amino-

100/10,000 70-69-9

Propoxur 100 x 114-26-1Propyl chloroformate 500 500 109-61-5Propylene Dichloride 1000 78-87-5Propyleneimine 10,000 1 x P067 75-55-81,2-Propylenimie 1 75-55-82,4-D propylene glycol

butyl ether esterx 1320-18-9

Propylene oxide 10,000 100 x 75-56-9Propylene (Propene) x 115-07-1Prosulfocarb 1## U387 52888-80-9Prothoate 100/10,000 100 2275-18-5Pyrene 1000/ 10,000 5000 129-00-0Pyrethrins 1 121-21-1Pyrethrins 1 121-29-9Pyrethrins 1 8003-34-7

3-143Hazardous Materials

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Chemical Name Extremely Haz Substances

40 CFR 355 (lb)

FINAL RQ

Haz Sub RQ 40 CFR 302.4

(lb)

Toxic Chemicals 40 CFR 372.65(a)

RCRA Waste NO

Haz Mat which are

RCRA wastes

CAS No.

Pyridine 1000 x U196 110-86-1Pyridine,2-methyl-5-

vinyl-500 500 140-76-1

Pyridine,4-nitro-1- oxide

500/10,000 500 1124-33-0

Pyriminil 100/10,000 100 53558-25-1Quinoline 5000 x 91-22-5Quinone 10 106-51-4Quintobenzene 100 82-68-86Quizalofop-ethyl x 76578-14-8Reserpine 5000 U200 50-55-5Resmethrin x 10453-86-8Salcomine 500/10,000 500 14167-18-1Sarin 10 10 107-44-8Selenium 100 x 7782-49-2Selenium dioxide 10 U204 7446-08-4Selenium disulfide 10 U205 7448-56-4Selenium oxychloride 500 500 7791-23-3Selenious acid 1000/ 10,000 10 U204 7783-00-8Selenouree 1000 P103 630-10-4Semicarbazide hydro

chloride1000/ 10,000 1000 563-41-7

Sethoxydim x 74051-80-2Silane,(4-aminobutyl)

diethoxymethyl-1000 3037-72-7

Silver 1000 x 7440-22-4Silver cyanide 1 P104 506-64-9Silver nitrate 1 7761-88-8Simazine x 122-34-9Sodium 10 7440-23-5Sodium arsenate 1000/ 10,000 1 7631-89-2Sodium arsenite 500/10,000 1 7784-46-5Sodium azide (Na(N3)) 500 1000 x P105 26628-22-8Sodium bichromate 10 10588-01-9Sodium bifluoride 100 1333-83-1Sodium bisulfite 5000 7631-90-5Sodium cacodylate 100/10,000 100 124-65-2Sodium chromate 10 7775-11-3Sodium cyanide

(Na(CN))100 10 P106 143-33-9

Sodium dicamba x 1982-69-0Sodium dimethyldithio

carbamatex U382 128-04-1

Sodium dodecylben zene sulfonate

1000 25155-30-0

Sodium fluoride 1000 7681-49-4Sodium fluoroacetate 10/10,000 10 x P058 62-74-8Sodium hydrosulfide 5000 16721-80-5Sodium hydroxide 1000 1310-73-2Sodium hypochlorite 100 10022-70-5Sodium hypochlorite 100 7681-52-9Sodium methylate 1000 124-41-4Sodium nitrite 100 x 7632-00-0

3-144Hazardous Materials

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Chemical Name Extremely Haz Substances

40 CFR 355 (lb)

FINAL RQ

Haz Sub RQ 40 CFR 302.4

(lb)

Toxic Chemicals 40 CFR 372.65(a)

RCRA Waste NO

Haz Mat which are

RCRA wastes

CAS No.

Sodium pentachlo rophenate

x 131-52-2

Sodium o-phenylphe noxide

x 132-27-4

Sodium phos- phate, dibasic

5000 10039-32-4

Sodium phos- phate,dibasic

5000 10140-65-5

Sodium phos- phate,dibasic

5000 7558-79-4

Sodium phosphate, tribasic

5000 10101-89-0

Sodium phosphate, tribasic

5000 10124-56-8

Sodium phosphate, tribasic

5000 10361-89-4

Sodium phosphate, tribasic

5000 7601-54-9

Sodium phosphate, tribasic

5000 7758-29-4

Sodium phosphate, tribasic

5000 7785-84-4

2,4-D sodium salt x 2702-72-9Sodium selenate 100/10,000 100 13410-01-0Sodium selenite 100/10,000 100 10102-18-8Sodium selenite 100 7782-82-3Sodium tellurite 500/10,000 500 10102-20-2Strannane,acetoxy-

triphenyl-500/10,000 500 900-95-8

Strontium chromate 10 7789-06-2Strychnine 100/10,000 10 P108 57-24-9Strychnine, sulfate 100/10,000 10 60-41-3Styrene 1000 x 100-42-5Styrene oxide 100 x 96-09-3Sulfotep 500 100 P109 3689-24-5Sulfoxide,3-chloropro

pyl octyl500 500 3569-57-1

Sulfur dioxide 500 500 7446-09-5Sulfur monochloride 1000 12771-08-3Sulfur tetrafluoride 100 100 7783-60-0Sulfur trioxide 100 100 7446-11-9Sulfuric acid (acid

aerosols including mists, vapors,gas, fog, and airborne forms of any particle size

1000 1000 x 7664-93-9

Sulfuric acid 1000 8014-95-7Sulfuric acid, dimethyl

ester1000 100 77-78-1

Sulfurayl fluoride x 2699-79-8Sulprrofos x 35400-43-22,4,5-T 1000 U232 93-76-52,4,5-T amines 5000 2008-46-0

3-145Hazardous Materials

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Chemical Name Extremely Haz Substances

40 CFR 355 (lb)

FINAL RQ

Haz Sub RQ 40 CFR 302.4

(lb)

Toxic Chemicals 40 CFR 372.65(a)

RCRA Waste NO

Haz Mat which are

RCRA wastes

CAS No.

2,4,5-T amines 5000 1319-72-82,4,5-T amines 5000 3813-14-72,4,5-T amines 5000 6369-96-62,4,5-T amines 5000 6369-97-72,4,5-T esters 1000 93-79-82,4,5-T esters 1000 1928-47-82,4,5-T esters 1000 2545-59-72,4,5-T esters 1000 61792-07-22,4,5-T esters 1000 25168-15-42,4,5-T salts 1000 13560-99-1Tabun 10 10 77-81-6TCDD 1 1746-01-6Tebuthiuron x 34014-18-1Tellurium 500/10,000 13494-80-9Tellurium hexafluoride 100 100 7783-80-4Temephos x 3383-96-8Terbacil x 5902-51-2Terbufos 100 100 13071-79-9Tetrabromobisphenol A x 79-94-71,1,1,2-

Tetrachloroethanex 630-20-6

1,1,2,2-Tetrachloroethane

100 79-34-5

Tetrachloroethene 100 127-18-4Tetrahloroethylene 100 127-18-92,3,7,8-Tetrachlorod

ibenzo p-dioxin (TCDD)

1 1746-01-6

Tetrachlorvinphos x 961-11-5Tetracycline

hydrochloridex 64-75-5

Tetraethyldithiopyr phosphate

100 10 P111 107-49-3

Tetraethyllead 100 10 P110 78-00-2Tetraethyltin 100 100 597-64-81-Chloro-1,1,2,2-

tetrafluoroethane (HCFC-124a)

x 354-256

2-Chloro-1,1,2,2-tet rafluoroethane (HCFC 124)

x 2837-89-0

Tetramethrin x 7696-12-0Tetramethyl Lead 100 100 75-74-1Tetranitromethane 500 10 P112 509-14-8Thallic oxide 100 P113 1314-32-5Thallium 1000 x 7440-28-0Thallium(1) carbonate 100/10,000 100 U215 6533-73-9Thallium(I)nitrate 100 U217 10102-45-1Thallium(I)selenide 1000 P114 12039-52-0Thallium (I)sulfate 100/10,000 100 P115 10031-59-1Thallous chloride 100/10,000 100 U216 7791-73-9Thallous malonate 100/10,000 100 2757-18-8Thallous sulfate 100/10,000 100 P115 7446-18-6Thiabendazole x 140-79-8

3-146Hazardous Materials

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Chemical Name Extremely Haz Substances

40 CFR 355 (lb)

FINAL RQ

Haz Sub RQ 40 CFR 302.4

(lb)

Toxic Chemicals 40 CFR 372.65(a)

RCRA Waste NO

Haz Mat which are

RCRA wastes

CAS No.

Thiobencarb x 28249-77-6Thiocarbazide 1000/ 10,000 1000 2231-57-44,4’-Thiodianiline 6-

dinitrophenollx 139-65-1

Thiodicarb 1# x U410 59669-26-0Thiofanox 100/10,000 100 P045 39196-18-4Thionazin 500 100 297-97-2Thiophanate ethyl x 23564-06-9Thiophanate-methyl 1## x U409 23564-05-8Thiophenol 500 100 P014 108-98-5Thiosemicarbazide 100/10,000 100 x P116 79-19-6Thiourea 10 x 62-56-6Thiourea,(2-

chlorophenyl)-100/10,000 100 P026 5344-82-1

Thiourea, (2- methylphenyl)-

500/10,000 500 614-78-8

Thiram 10 x U244 137-26-8Thorium dioxide x 1314-20-1Titanium dioxide x 13463-67-7Titanium tetrachloride 100 1000 x 7550-45-0Toluene 1000 108-88-3Toluenediamine 10 95-80-72,4-Toluene diamine 10 95-80-72,4-Toluene diisocyan

ate100 91-08-7

Toluene2,4-diisocyan ate

500 100 x 584-84-9

Toluene2,6-diisocyan ate

100 100 x 91-08-7

Toluenediisocyanate 100 584-84-9o-Toluidine 100 95-53-4o-Toluidine 100 x U328 95-53-4Toxaphene(Camphe

clor)1 x P123 8001-35-2

2,4,5-TP acid esters 100 32534-95-5trans 1,1-dichloro

butene500 110-57-6

trans-1,4-Dichloro-2- butene

500 500 x 110-57-6

trans-1,3-Dichloropro pene

x 10061-02-6

Triadimefon x 43121-43-3Triallate 1## x U389 2303-17-5Triamiphos 500/10,000 500 1031-47-6Triaziquone x 68-76-8Triazofos 500 500 24017-47-8Tribenuron methyl x 101200-48-

02,4,6-Tribromophenol 100 U408 118-79-6Tributyltin fluoride x 1982-10-4Tributultin methacry

latex 2155-70-6

S,S,S-Tributyltrithio phosphate

x 78-48-8

3-147Hazardous Materials

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Chemical Name Extremely Haz Substances

40 CFR 355 (lb)

FINAL RQ

Haz Sub RQ 40 CFR 302.4

(lb)

Toxic Chemicals 40 CFR 372.65(a)

RCRA Waste NO

Haz Mat which are

RCRA wastes

CAS No.

1,2,4-Trichlorobenzene 100 120-82-1Trichloroacetyl

chloride500 500 x 76-02-8

Trichloro(chlorome thyl) silane

100 100 1558-25-4

Trichloro(dichloro- phenyl) silane

500 500 27137-85-5

1,1,1-Trichloroethane 1000 71-55-61,1,2-Trichloroethane 100 79-00-5Trichloroethene 100 79-01-6Trichloroethylene 100 x U228 79-01-6Trichloroethylsilane 500 500 115-21-9Trichlorofon 100 x 52-68-6Trichloronate 500 500 327-98-0Trichlorophenol 10 25167-82-22,3,4-Trichlorophenol 10 x 15950-66-02,3,5-Trichlorophenol 10 933-78-82,3,6-Trichlorophenol 10 933-75-52,4,5-Trichlorophenol 10 95-95-42,4,6-Trichlorophenol 10 88-06-23,4,5-Trichlorophenol 10 609-19-8Trichlorophenylsilane 500 500 98-13-51,2,3-Trichloropropane x 96-18-4Triclopyr, triethylam

monium saltx 57213-69-1

Triethanolamine dode-cylbenzene sulfonate

1000 27323-41-7

Triethoxysilane 500 500 998-30-1Triethylamine 5000 x 121-44-81,1-Dichloro-1,2,2-trif

luoroethane (HCFC- 123b)

x 812-04-4

1,2-Dichloro-1,1,2-trif luoroethane (HCFC- 123a)

x 354-23-4

Trifluralin 10 x 1582-09-8Triforine x 26644-46-2Trimethylamine 100 75-50-3Trimethylchlorosilane 1000 1000 x 75-77-4Trimethylolpropane

phosphite100/10,000 100 824-11-3

2,3,4-Trimethylpentane 1000 540-64-12,3,5-Trimethylphenyl

methylcarbamatex 2655-15-4

Trimethyltin chloride 500/10,000 500 1066-45-1Triphenyltin chloride 500/10,000 500 x 639-58-7Triphenyltin hydroxide x 76-87-9Tris(2-chloroethyl)

amine100 100 555-77-1

Trypan blue 10 x U236 72-57-1Uracil,5-[bis(2-chloro

ethyl)amino]-10 U237 66-75-1

Uranyl acetate 100 541-09-3Uranyl nitrate 100 10102-06-4

3-148Hazardous Materials

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Chemical Name Extremely Haz Substances

40 CFR 355 (lb)

FINAL RQ

Haz Sub RQ 40 CFR 302.4

(lb)

Toxic Chemicals 40 CFR 372.65(a)

RCRA Waste NO

Haz Mat which are

RCRA wastes

CAS No.

Uranyl nitrate 100 36478-76-9Urea, N-methyl -N-

nitroso1

Urethane 100 51-79-6Valinomycin 1000/ 10,000 1000 2001-95-8Vanadium(fume or

dust)x (except when contined in an

alloy)

7440-62-2

Vanadium pentoxide 100/10,000 1000 P120 1314-62-1Vanadyl sulfate 1000 27774-13-6Vinclozolin x 50471-44-8Vinyl acetate, monomer 1000 5000 x 108-05-4Vinyl bromide 100 x 593-60-2Vinylidienechloride 100 75-35-4Warfarin 500/10,000 100 P001 81-81-2Warfarin sodium 100/10,000 100 129-06-6Xylene 100 1330-20-7m-Xylene 1000 108-38-3o-Xylene 1000 95-47-6p-Xylene 100 106-42-3Xylene dichloride 100/10,000 100 28347-13-9Xylene, isomers and

mixture100 1330-20-7

Xylene, mixed 100 1330-20-7Xylenol 1000 1300-71-62,6-Xylidine x 87-62-7Zinc 1000 x 7440-66-6Zinc acetate 1000 557-34-6Zinc ammonium

chloride1000 52628-25-8

Zinc ammonium chloride

1000 14639-97-5

Zinc ammonium chloride

1000 14639-98-6

Zinc borate 1000 1332-07-6Zinc bromide 1000 7699-45-8Zinc carbonate 1000 3486-35-9Zinc chloride 1000 7646-85-7Zinc cyanide 10 P121 557-21-1Zinc, dichloro(4,4-dimethyl-5(((methylamino)carbnyl)oxy)imino)Pentane-nitrile)-,(T-4)

100/10,000 100 58270-08-9

Zinc fluoride 1000 7783-49-5Zinc formate 1000 557-41-5Zinc hydrosulfite 1000 7779-86-4Zinc nitrate 1000 7779-88-6Zinc phenolsulfonate 5000 127-82-2Zinc phosphide 500 100 P122 1314-84-7Zinc silicofluoride 5000 16871-71-9Zinc sulfate 1000 7733-02-0Zineb x 12122-67-7Ziram 1## P205 137-30-4

3-149Hazardous Materials

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Chemical Name Extremely Haz Substances

40 CFR 355 (lb)

FINAL RQ

Haz Sub RQ 40 CFR 302.4

(lb)

Toxic Chemicals 40 CFR 372.65(a)

RCRA Waste NO

Haz Mat which are

RCRA wastes

CAS No.

Zirconium nitrate 5000 13746-89-9Zirconium potassiumfluoride

1000 16923-95-8

Zirconium sulfate 5000 14644-61-2Zirconium tetrachloride 5000 10026-11-6

3-150Hazardous Materials

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Appendix 3-1a

Lower Thresholds for Chemicals of Special Concern(40 CFR 372.28)

[Added January 2000; Revised January 2001]

Chemical Listing in Alphabetic Order.

Chemical Name CAS NO. Reporting Threshold

Aldrin 00309-00-2 100Benzo(g,h,i)perylene 00191-24-2 10Chlordane 00057-74-9 10Heptachlor 00076-44-8 10Hexachlorobenzene 00118-74-1 10Isodrin 00465-73-6 10Lead (this lower threshold does not apply to lead when contained in a stainless steel, brass or bronze alloy)

7439-92-1 100

Mercury 07439-97-6 10Methoxychlor 00072-43-5 100Octachlorostyrene 29082-74-4 10Pendimethalin 40487-42-1 100Pentachlorobenzene 00608-93-5 10Polychlorinated biphenyl (PCBs) 01336-36-3 10Tetrabromobisphenol A 00079-94-7 100Toxaphene 08001-35-2 10Trifluralin 01582-09-8 100

Chemical Categories in Alphabetic Order

Category name Reporting threshold

Dioxin and dioxin-like compounds (Manufacturing; and the processing orotherwise use of dioxin and dioxin-like compounds if the dioxin and dioxin-like compounds are present as contaminants in a chemical and if they were created during the manufacturing of that chemical) (This category includes only those chemicals listed below).

1,2,3,4,6,7,8-Heptachlorodibenzofuran 1,2,3,4,7,8,9-Heptachlorodibenzofuran 1,2,3,4,7,8-Hexachlorodibenzofuran 1,2,3,6,7,8-Hexachlorodibenzofuran 1,2,3,7,8,9-Hexachlorodibenzofuran 2,3,4,6,7,8-Hexachlorodibenzofuran 1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin 1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin 1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin

0.1 grams

3-151Hazardous Materials

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Category name Reporting threshold

1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin 1,2,3,4,6,7,8,9-Octachlorodibenzofuran 1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin 1,2,3,7,8-Pentachlorodibenzofuran 2,3,4,7,8-Pentachlorodibenzofuran 1,2,3,7,8-Pentachlorodibenzo-p-dioxin 2,3,7,8-Tetrachlorodibenzofuran 2,3,7,8 Tetrachlorodibenzo-p-dioxin Lead Compounds

100

Mercury compounds 10

Polycyclic aromatic compounds (PACs) (This 100 category includes only those chemicals listed below).

Benz(a)anthracene Benzo(b)fluoranthene Benzo(j)fluoranthene Benzo(k)fluoranthene Benzo(j,k)fluorene Benzo(r,s,t)pentaphene Benzo(a)phenanthrene Benzo(a)pyrene Dibenz(a,h)acridine Dibenz(a,j)acridine Dibenzo(a,h)anthracene 7H-Dibenzo(c,g)carbazole Dibenzo(a,e)fluoranthene Dibenzo(a,e)pyrene Dibenzo(a,h)pyrene Dibenzo(a,l)pyrene 7,12-Dimethylbenz(a)anthracene Indeno[1,2,3-cd]pyrene 3-Methylcholanthrene 5-Methylchrysene 1-Nitropyrene

100

3-152Hazardous Materials

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Appendix 3-2

Maximum Allowable Capacity of Containers and Portable Tanks (29 CFR 1910.106(d)(2), Table H-12)

Container Type Flammable Liquids Combustible LiquidsClass IA Class IB Class IC Class II Class III

Glass or approved plastic

1 pt 1 qt 1 gal 1 gal 1 gal

Metal (other than DOT drums)

1 gal 5 gal 5 gal 5 gal 5 gal

Safety cans 2 gal 5 gal 5 gal 5 gal 5 gal

Metal drums (DOT specifications)

60 gal 60 gal

60 gal

60 gal 60 gal

Approved portable tanks 660 gal 660 gal 660 gal 660 gal 660 gal

3-153Hazardous Materials

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3-154Hazardous Materials

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Appendix 3-3

Storage in Inside Rooms (29 CFR 1910.106(d)(4), Table H-13)

Fire Protection Provided1

Fire Resistance (hours)

Maximum Size Total Allowable Quantities ((gal/ft2) floor area)

Yes 2 500 ft2 10 No 2 500 ft2 5 Yes 1 150 ft2 4 No 1 150 ft2 2

1Fire protection system will be sprinkler, water spray, or other approved method.

3-155Hazardous Materials

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3-156Hazardous Materials

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Appendix 3-4

Flammable/Combustible Materials Storage (29 CFR 1910.106(d)(5) and 1910.106(d)(6), Tables H-14 through H-17)

[Revised January 2008]

Indoor Container Storage

Class Liquid Storage Level Protected Storage Maximum per Pile

Unprotected Storage Maximums per Pile

A Ground and upper floors

Basement

2750 gal (50, 55-gal drums))

Not permitted

600 gal (12, 55-gal drums)

Not permitted

B Ground and upper floors

Basement

5500 gal (100, 55-gal drums)

Not permitted

1375 gal (25, 55-gal drums)

Not permitted

C Ground and upper floors

Basement

16,500 gal (300, 55-gal drums)

Not permitted

4125 gal (25, 55-gal drums)

Not permitted

II Ground and upper floors

Basement

16,500 gal (300, 55-gal drums)

5500 gal (100, 55-gal drums)

4125 gal (75, 55-gal drums)

Not permitted

III Ground and upper floors

Basement

55,000 gal (1000, 55-gal drums)

8250 gal (450, 55-gal drums)

13,750 gal (250, 55-gal drums)

Not permitted

NOTE 1: When two or more classes of materials are stored in a single pile, the maximum gallonage permitted in that pile will be the smallest of the two or more separate maximum gallonages.

NOTE 2: Aisles will be provided so that no container is more than 12 ft from an aisle. Main aisles will be at least 3 ft wide and side aisles at least 4 ft wide.

NOTE 3: Each pile shall be separated from the others by at least 4 ft .

3-157Hazardous Materials

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Outdoor Container Storage

1Class

2Maximum per pile

(gal)

3Distance between piles

(ft)

4Distance to property line that can be built

upon (ft)

5Distance to street, alley or public way

(ft)IA 1100 5 20 10 IB 2200 5 20 10 IC 4400 5 20 10 II 8800 5 10 5III 22,000 5 10 5

NOTE 1: When two or more classes of materials are stored in a single pile, the maximum gallonage permitted in that pile will be the smallest of the two or more separate gallonages.

NOTE 2: Within 200 ft of each container, there will be a 12 ft wide access way to permit approach of fire control apparatus.

NOTE 3: The distances listed apply to properties that have protection for exposures as defined. If there are exposures and such protection for exposures does not exist, the distances in column 4 will need to be doubled.

NOTE 4: When total quantity stored does not exceed 50 percent of maximum per pile, the distance in columns 4 and 5 may be reduced 50 percent, but not less than 3 ft.

Indoor Portable Tank Storage

Class Liquid Storage Level Protected Storage Maximum per Pile (gal)

Unprotected Storage Maximums per Pile (gal)

IA Ground and upper floors

Basement

Not permitted

Not permitted

Not permitted

Not permitted

IB Ground and upper floors

Basement

20,000

Not permitted

2000

Not permitted

IC Ground and upper floors

Basement

40,000

Not permitted

5500

Not permitted

II Ground and upper floors

Basement

40,000

20,000

5500

Not permitted

III Ground and upper floors

Basement

60,000

20,000

22,000

Not permitted

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NOTE 1: When one or more classes of materials are stored in a single pile, the maximum gallonage permitted in that pile will be the smallest of the two or more separate maximum gallonages.

NOTE 2: Aisles will be provided so that no container is more than 12 ft from an aisle. Main aisles will be at least 3 ft wide and side aisles at least 4 ft wide.

NOTE 3: Each pile shall be separated from each other by at least 4 ft.

Outdoor Portable Tank Storage

1Class

2Maximum per pile (gal)

3Distance between piles

(ft)

4Distance to property line that can be built

upon (ft)

5Distance to street,

alley, or public way (ft)

IA 2200 5 20 10 IB 4400 5 20 10 IC 8800 5 20 10 II 17,600 5 10 5 III 44,000 5 10 5

NOTE 1: When two or more classes of materials are stored in a single pile, the maximum gallonage permitted in that pile will be the smallest of the two or more separate gallonages.

NOTE 2: Within 200 ft of each container, there will be a 12 ft wide access way to permit approach of fire control apparatus.

NOTE 3: The distances listed apply to properties that have protection for exposures as defined. If there are exposures, and such protection for exposures does not exist, the distances in column 4 will be doubled.

NOTE 4: When total quantity stored does not exceed 50 percent of maximum per pile, the distance in columns 4 and 5 may be reduced 50 percent, but not less than 3 ft.

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Appendix 3-5Hazardous Materials/Hazardous Waste Storage Incompatibility Chart

Substances in bold have detailed example lists on the next page. If the material contains: It may not be stored with any of the following:

Acid (pH below 2.0) Caustics (pH above 12.5)Reactive MetalsAlcoholWaterAldehydesHalogenated, Nitrated, or Unsaturated HydrocarbonsReactive Organic Compounds and SolventsSpent Cyanide and Sulfide SolutionsOxidizers

Caustic (pH above 12.5) Acid (pH below 2.0)Reactive MetalsAlcoholWaterAldehydesHalogenated, Nitrated, or Unsaturated HydrocarbonsReactive Organic Compounds and Solvents

Reactive Metals CausticsAcidsAlcoholAldehydesHalogenated, Nitrated, or Unsaturated HydrocarbonsReactive Organic Compounds and SolventsOxidizers

Reactive Organic Compounds and Solvents CausticsAcidsReactive Metals

Spent Cyanide and Sulfide Solutions AcidsOxidizers Acetic or Other Organic Acids

Concentrated Mineral AcidsReactive MetalsReactive Organic Compounds and SolventsIgnitable [Flammable/Combustible] Wastes*

* “Ignitable” in this context refers to substances with a flashpoint below 140× oF, and includes:Combustible substances, with a flashpoint below 140× oFFlammable substances, with a flashpoint below 100× oF.

Some Deadly Combinations

Acids + Oil or Grease = Fire Flammable Liquids + Hydrogen Peroxide = Fire/Explosion

Acids + Caustics = Heat/Spattering Aluminum Powder + Ammonium Nitrate = Explosion

Caustics + Epoxies = Extreme Heats Sodium Cyanide + Sulfuric Acid = Lethal Hydrogen Cyanide

Chlorine Gas + Acetylene = Explosion Ammonia + Bleach = Noxious Fumes

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In general: Reactives must be segregated from IgnitablesAcids must be segregated from CausticsCorrosives should be segregated from FlammablesOxidizers should be segregated from EVERYTHINGMany Corrosives are “Water Reactive”Most Organic Reactives must be segregated from Inorganic Reactives (metals)

Ignitables(Flammables/Combustibles)

CorrosivesAcids Caustics

Carburetor CleanersEngine CleanersEpoxy, Resins, Adhesives, and Rubber CementsFinishesFuelsLacquersPaintsPaint ThinnersPaint WastesPesticides that contain Solvents (such as Methyl Alcohol, Ethyl

Alcohol, Isopropyl Alcohol, Toluene, Xylene).Petroleum Solvents (Drycleaning Fluid)Solvents:AcetoneBenzeneCarbon Tetrachloride (Carbon Tet)Ethanol (Ethyl Alcohol)Ethyl BenzeneIsopropanol (Isopropyl Alcohol)Kerosene (Fuel Oil #1)Methanol (Wood Alcohol)Methyl Ethyl Ketone (MEK)Petroleum Distillates Tetrahydrofuran (THF)Toluene (Methacide, Methylbenzene, Methylbenzol, Phenylmethane,

Toluol, Antisal 1A)White Spirits (White Spirits, Mineral Spirits, Naptha)Xylene (Xylol)StainsStripping AgentsVarsolWaste FuelsWaste InkWax RemoversWood Cleaners

Battery AcidsDegreasers and Engine CleanersEtching FluidsHydrobromic AcidHydrochloric Acid (Muriatic

Acid)Nitric Acid (<40%) (Aquafortis)Phosphoric AcidRust Removers Sulfuric Acid (Oil of Vitriol)

___________________________Reactive Metals

___________________________

Lithium (Batteries)AluminumBerylliumCalciumMagnesiumSodiumZinc Powder

Acetylene SludgeAlkaline Battery AcidsAlkaline CleanersAlkaline DegreasersAlkaline Etching FluidsLime and WaterLime WastewaterPotassium Hydroxide (Caustic

Potash)Rust RemoversSodium Hydroxide (Caustic

Soda, Soda Lye)

___________________________Reactive Organic Compounds

and Solutions___________________________

AlcoholsAldehydesChromic Acids (from chrome

plating, copper stripping and aluminum anodizing)

Cyanides (from electroplating operations)

Hypochlorides (from water treatment plants, swimming pools, sanitizing operations)

Organic Peroxides (including Hydrogen Peroxide)

PerchloratesPermanganatesSulfides

OxidizersChlorine GasNitric Acid (>40%), aka Red

Fuming NitricNitrates (Sodium Nitrate,

Ammonium Nitrate)PerchloratesPerchloric AcidPerioxidesCalcium Hypochlorite (>60%)

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Appendix 3-6

Placarding Guidelines(49 CFR 172.504)

[Revised October 2001]

Each bulk packaging, freight container, unit load device, transport vehicle or rail car containing any quantity of a hazardous material must be placarded on each side and each end with the type of placards specified in the following tables:

Table 1

Category of material (Hazard class or division number and

additional description, as appropriate)

Placard NamePlacard Design Section Reference

(49 CFR)

1.1 2 EXPLOSIVES 1.1 172.5221.22 EXPLOSIVES 1.2 172.5221.32 EXPLOSIVES 1.3 172.5222.3 POISON GAS 172.5404.3 DANGEROUS WHEN WET 172.5485.2 (Organic peroxide, Type B, liquid or solid, temperature controlled).

ORGANIC PEROXIDE 172.552

6.1 (inhalation hazard, Zone A or B).

POISON INHALATION HAZARD 172.555

7 (Radioactive Yellow III label only).

RADIOACTIVE 1 172.556

1 RADIOACTIVE placard also required for exclusive use shipments of low specific activity material and surface contaminated objects transported in accordance with 49 CFR 173.427(a). 2 When more than one division placard is required for Class 1 materials on a transport vehicle, rail car, freight container or unit load device, only the placard representing the lowest division number must be displayed.

Table 2 1

Category of material (Hazard class or division number and

additional description, as appropriate)

Placard NamePlacard Design Section Reference

(49 CFR)

1.42,6 EXPLOSIVES 1.4 172.5231.52 EXPLOSIVES 1.5 172.5241.62 EXPLOSIVES 1.6 172.5252.1 FLAMMABLE GAS 172.5322.2 3 NON-FLAMMABLE GAS 172.5283 4 FLAMMABLE 172.542Combustible liquid COMBUSTIBLE 172.544

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Table 2 1

Category of material (Hazard class or division number and

additional description, as appropriate)

Placard NamePlacard Design Section Reference

(49 CFR)

4.1 FLAMMABLE SOLID 172.5464.2 SPONTANEOUSLY COMBUSTIBLE 172.5475.15 OXIDIZER 172.5505.2 (Other than organic peroxide, Type B, liquid or solid, temperature controlled).

ORGANIC PEROXIDE 172.552

6.1 (other than inhalation hazard, Zone A or B).

POISON 172.554

6.2 None8 CORROSIVE 172.5589 Class 9 (see 49 CFR 172.504(f)(9)). 172.560ORM-D None 1 A freight container, unit load device, transport vehicle, or rail car which contains non-bulk packages with two or more categories of hazardous materials that require different placards specified in Table 2 may be placarded with a DANGEROUS placard instead of the separate placarding specified for each of the materials. However, when 1,000 kg (2,205 pounds) aggregate gross weight or more of one category of material is loaded therein at one loading facility on a freight container, unit load device, transport vehicle, or rail car, the placard specified in Table 2 for that category must be applied.

When hazardous materials covered by Table 2 are transported by highway or rail, placards are not required on the following, with the exception of bulk packagings and hazardous materials subject to 49 CFR 172.505:A transport vehicle or freight container which contains less than 454 kg (1001 pounds) aggregate gross weight of hazardous materials covered by Table 2; orA rail car loaded with transport vehicles or freight containers, none of which is required to be placarded.

The exception for Table 2 placarding do not prohibit the display of placards in the manner prescribed, if not otherwise prohibited (see 49 CFR172.502), on transport vehicles or freight containers which are not required to be placarded.

A non-bulk packaging that contains only the residue of a hazardous material covered by Table 2 of need not be included in determining placarding requirements.

2 When more than one division placard is required for Class 1 materials on a transport vehicle, rail car, freight container or unit load device, only the placard representing the lowest division number must be displayed.

3 A NON-FLAMMABLE GAS placard is not required on a transport vehicle which contains non-flammable gas if the transport vehicle also contains flammable gas or oxygen and it is placarded with FLAMMABLE GAS or OXYGEN placards, as required.

4 A FLAMMABLE placard may be used in place of a COMBUSTIBLE placard on--A cargo tank or portable tank.A compartmented tank car which contains both flammable and combustible liquids.

5 OXIDIZER placards are not required for Division 5.1 materials on freight containers, unit load devices, transport vehicles or rail cars which also contain Division 1.1 or 1.2 materials and which are placarded with

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EXPLOSIVES 1.1 or 1.2 placards, as required. For transportation by transport vehicle or rail car only, an OXIDIZER placard is not required for Division 5.1 materials on a transport vehicle, rail car or freight container which also contains Division 1.5 explosives and is placarded with EXPLOSIVES 1.5 placards, as required. 6 The EXPLOSIVE 1.4 placard is not required for those Division 1.4 Compatibility Group S (1.4S) materials that are not required to be labeled 1.4S.

Additional Information

For domestic transportation of oxygen, compressed or oxygen, refrigerated liquid, the OXYGEN placard in 49 CFR.172.530 may be used in place of a NON-FLAMMABLE GAS placard. For domestic transportation, a POISON INHALATION HAZARD placard is not required on a transport vehicle or freight container that is already placarded with the POISON GAS placard. For domestic transportation, a Class 9 placard is not required. A bulk packaging containing a Class 9 material must be marked with the appropriate identification number displayed on a Class 9 placard, an orange panel or a white-square-on-point display configuration.

For Division 6.1, PG III materials, a POISON placard may be modified to display the text ``PG III'' below the mid line of the placard.

For domestic transportation, a POISON placard is not required on a transport vehicle or freight container required to display a POISON INHALATION HAZARD or POISON GAS placard.

For shipments of Class 1 (explosive) materials by aircraft or vessel, the applicable compatibility group letter must be displayed on the placards..

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Appendix 3-7

List of Flammable and Combustible Bulk Liquid Cargoes (46 CFR 30.25-1)

Cargoes Pollution CategoryAcetone IIIAcetophenone *DAcetyl tributyl citrate #Acrylonitrile-Styrene copolymer dispersion in Polyether polyol [D]Alcohols (C13 and above) IIIAlcoholic beverages, n.o.s. IIIAlcohol(C6 - C17)(secondary) poly(3-6)ethoxylates AAlcohol(C6 - C17)(secondary) poly(7-12)ethoxylates BAlcohol(C12 - C15) poly(1-3)ethoxylates AAlcohol(C12 - C15) poly(3-11)ethoxylates AAlkenylsuccinic acid #Alkenylsuccinic anhydride #Alkyl(C9 - C17) benzenes DAlkylbenzensulfonic acid (4% or less) #Alkyl phthalates (n-) see individual phthalates #Alkyl succinate formaldehyde hydr- oxyamino condensate (3.2% or less) #Aminoethyldiethanolamine, Aminoethylethanolamine solution IIIAmyl acetate (iso-, n-) CAmyl alcohol (iso-, n-, sec-, primary) DAmyl alcohol (tert-) IIIAmylene see Pentene (all isomers) CAmyl methyl ketone see Methyl amyl ketone CAmyl tallate #Asphalt IAsphalt blending stocks:Roofers flux Straight run residue

II

Behenyl alcohol IIIBenzene tricarboxilic acid tricotyl ester IIIBenzyl alcohol CBicyclic terpenel polyamine amide salt #Brake fluid base mixtures (containing Poly(2-8)alkylene(C2-C3) glycols, Polyalkylene(C2-C10) glycol monoalkyl(C1-C4) ethers, and their borate esters)

D

Butane LFGButene see ButyleneButene oligomer BButyl acetate ( (iso-, n-) CButyl acetate (sec-) DButyl alcohol (iso-, n-, sec-, tert-) IIIButyl benzyl phthalate AButylene LFGButylene glycol D1,3-Butylene glycol see Butylene glycol DButylene polyglycol see Butylene glycol *Diso-Butyl formate Dn-Butyl formate *DButyl heptyl ketone [C]Butyl methyl ketone see Methyl butyl ketone DButyl stearate III

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Cargoes Pollution CategoryButyl toluene *AButyrolactone (gamma) DCalcium alkylphenate #Calcium alkyl salicylate CCalcium amino nonyl phenolate #Calcium carboxylate #Caprolactam solutions DCarbon black base #Cetyl alcohol (Hexadecanol) see Alcohols (C13 and above) *IIICetyl-Stearyl alcohol IIICleaning spirit (unleaded) #Coal tar ACumene BCycloaliphatic resins #Cyclohexane CCyclohexanol C1,3-Cyclopentadiene dimer (molten) BCyclopentadiene polymers see 1,3-Cyclopentadiene dimer (molten) @BCymene (para-) CDecahydronaphthalene DDecaldehyde (iso-) @CDecaldehyde (n-) *BDecane DDecene BDecyl alcohol (all isomers) BDecyclobenzene (n-) DDetergent alkylate #Diacetone alcohol DDialkyl(C10 - C14) benzenes [D]Dialkyl(C7- C13) phthalates DDibutyl carbinol #Dibutyl phthalate (ortho-) ADicyclopentadiene see 1,3-Clyclopentadiene dimer (molten) BDiethylbenzene CDiethylene glycol IIIDiethylene glycol butyl ether IIIDiethylene glycol butyl ether acetate DDiethylene glycol dibutyl ether DDiethylene glycol diethyl ether IIIDiethylene glycol ethyl ether IIIDiethylene glycol ethyl ether acetate DDiethylene glycol methyl ether CDiethylene glycol methyl ether acetate DDiethylene glycol phenyl ether #Diethylene glycol phthalate [D]Di-(2-ethylhexyl)adipate DDi-(2-ethylhexyl)phthalate DDiethyl phthalate CDiglycidyl ether of Bisphenol A BDiheptyl phthalate IIIDihexyl phthalate IIIDiisobutylcarbinol *CDiisobutylene BDiisobutyl ketone DDiisobutyl phthalate B

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Cargoes Pollution CategoryDiisodecyl phthalate DDiisononyl adipate DDiisononyl phthalate DDiisooctyl phthalate IIIDiisopropylbenzene (all isomers) ADiisopropyl naphalene DDimethyl adipate BDimethylbenzene see Xylenes CDimethyl glutarate CDimethyl phthalate CDimethyl polysiloxane [III]2,2-Dimethylpropane-1,3-diol DDimethyl succinate CDinonyl phthalate DDi(octylphenyl)amine #Dioctyl phthalate IIIDipentene CDiphenyl ADiphenyl,Diphenyl ether mixture ADiphenyl ether ADiphenyl ether, Biphenyl phenyl ether mixtures ADipropylene glycol IIIDipropylene glycol dibenzoate [D]Dipropylene glycol methyl ether DDistillates:

Flashed feed stocksStraight run

II

Ditridecyl phthalate DDiundecyl phthalate DDodecane (all isomers) IIIDodecanol BDodecene (all isomers) BDodecylbenzene IIIDodecyl phenol ADrilling mud (low toxicity) (if flammable or combustible) [III]Epoxylated linear alcohols, C11 - C15 #Ethane LFG2-Ethoxyethanol D2-Ethoxyethyl acetate CEthoxylated alcohols, C11 - C15 see the Alcohol polyethoxylates A/BEthoxy triglycol (crude) DEthyl acetate DEthyl acetoacetate DEthyl alcohol IIIEthyl amyl ketone CEthylbenzene CEthyl butanol @DEthyl butyrate CEthyl cyclohexane CEthylene LFGEthylene carbonate IIIEthylene glycol DEthylene glycol acetate DEthylene glycol butyl ether IIIEthylene glycol butyl ether acetate C

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Cargoes Pollution CategoryEthylene glycol tert-butyl ether IIIEthylene glycol diacetate CEthylene glycol dibutyl ether [D]Ethylene glycol ethyl ether see 2-Ethoxyethanol DEthylene glycol ethyl ether acetate see 2-Ethoxyethyl acetate CEthylene glycol isopropyl ether DEthylene glycol methyl butyl ether DEthylene glycol methyl ether DEthylene glycol methyl ether acetate DEthylene glycol phenyl ether DEthylene glycol phenyl ether, Diethylene glycol phenyl ether mixture DEthylene-Propylene copolymer (in liquid mixtures) [III]Ethyl-3-ethoxypropionate [C]2-2Ethylhexaldehyde see Octyl aldehydes @B2-2Ethylhexanoic acid D2-Ethylhexanol see Octanol (all isomers) @CEthylhexoic acid see 2-Ethylhexanoic acid DEthyl hexyl phthalate CEthyl hexyl tallate #Ethyl propionate DEthyl toluene BFatty acid (saturated, C13 and above) IIIFatty acid amides #Formamide DFurfuryl alcohol CGas oil, cracked IGasoline blending stocks:

AlkylatesReformates

II

Gasolines:Automotive (containing not over 4.23 grams lead per gallon)Aviation (containing not over 4.86 grams lead per gallon)Casinghead (natural)PolymerStraight run

IIIII

Glycerine IIIGlycerol see Glycerine IIIGlycerol polyakoxylate IIIGlycerol triacetate IIIGlycidyl ester of tertiary carboxilic acid see Glycidyl ester of tridecyl acetic acid *BGlycidyl ester of tridecyl acetic acid BGlycidyl ester of versatic acid see Glycidyl ester of tridecyl acetic acid *BGlycol diacetate see Ethylene glycol diacetate CGlycols, Resins, & Solvents mixture #Glycol tiacetate see Glyceryl triacetate IIIGlyoxal solution (40% or less) DGrease #Heptadecane *IIIHeptane (all isomers) CHeptanoic acid DHeptanol (all isomers) CHeptene (all isomers) CHeptyl acetate BHerbicide (C15 -H22 -NO2- Cl) see Metolachlor *BHexaethylene glycol @III

3-170Hazardous Materials

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Cargoes Pollution CategoryHexamethylene glycol IIIHexamethyleneteraamine solutions DHexane (all isomers) CHexanoic acid DHexanol DHexene (all isomers) CHexyl acetate BHexylene glycol IIIHog grease see Lard *III2-Hydroxy-4-(methylthio)butanoic acid [C]Hydroxy terminated polybutadiene see Polybutadiene, hydroxyl terminated Ispphorone DJet fuels:

JP-1 (kerosene)JP-3JP-4JP-5 (kerosene, heavy) JP-8

IIII*I

Kerosene ILatic acid DLard IIILatex, liqud synthetic including: Styrene-butadiene rubber Carboxylated styrene-butadiene copolymer

IIIIIIIII

Magnesium nonyl phenyl sulfide #Magnesium sulfonate #Maleic anhydride copolymer #2-Mercaptobenzothiazol (in liquid mixtures) #\Methane LFG3-Methoxy-1-butanol III3-Methoxybutyl acetate D1-Methoxy-2-propyl acetate #Methoxy triglycol see Triethylene glycol methyl ether *DMethyl acetate IIIMethyl acetoacetate DMethyl alcohol IIIMethyl amyl acetate CMethyl amyl alcohol CMethyl amyl ketone CMethyl butanol see the Amyl alcohols DMethyl butenol DMethyl butyl ketone DMethyl butynol DMethyl butyrate CMethyl ethyl ketone IIIMethyl formal (dimethyl formal) #Methyl heptyl ketone BMethyl isobutyl carbinol see Methyl amyl alcohol CMethyl isosbutyl ketone D3-Methyl-3-methoxybutanol III3-Methyl-3-methoxybutyl acetate IIIMethyl napthalene AMethyl pentene CN-Methyl-2-pyrrolidone BMethyl tert-butyl ether DMetolachlor *B

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Cargoes Pollution CategoryMineral spirits IMyrcene [B]Naphtha:

Aromatic (having less than 10% benzene)Cracking fractionHeavyParaffinicPetroleumSolventStoddard solventVarnish makers’ and painters’ (75%)

*I*I*I*II*I*I*I

Naphthalene sulfonic acid-formaldehyde copolymer, sodium salt solution DNaphthenic acid ANonane (all isomers) CNonanoic cid (all isomers) DNonoic, Tridecanoic acid mixture *DNonene BNonyl alcohol (all isomers) [C]Nonyl methacrylate monomer DNonyl phenol ANonyl phenol poly(4-12)ethoxylates BNonyl phenol sulfide (90% or less) #Noxious liquid, n.o.s. (17) ("trade name", contains "principal components"), Category (if flammable or combustible) DNon-noxious liquid, n.o.s. (18) ("trade name", contains "principalcomponents"), Appendix III (if flammable or combustible) IIIOctadecene see the Olefin or alpha-Olefin entries *IIIOctadecenoamide solution (Oleamide) [D]Octane (all isomers) DOctanoic acid (all isomers) DOctanol (all isomers) COctene (all isomers) COctyl acetate DOctyl alcohol (iso, n-) see Octanol (all isomers) COctyl aldehydes BOctyl decyl adipate IIIOctyl epoxytallate #Octyl phthalate see Di-(2-ethylhexyl)phthalate *DOil, edible

BabassuBeechnutCastorCocao butterCoconutCod liverCornCottenseedFish, n.o.s.GrapeseedGroundnutHazelnutLard

DDDDDDDDD#DD

*IIIMaize see Corn oilMustard seed

D#

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Cargoes Pollution CategoryNutmeg butterOlivePalmPalm kernelPeanutPoppyRaison seedRapeseedRice branSafflowerSaladSesameSoya beanSunflower see Sunflower seedSunflower seed TicumVegetable, n.o.s.Walnut

DDDDDDDDDDDDDDDDDD

Oil, fuel:No. 1 (kerosene)No. 1-DNo. 2No. 2-DNo. 4No. 5No. 6

IIIIIII

Oil, miscellaneous:AbsorptionAliphaticAnimal, n.o.s.AromaticAviation F2300ClarifiedCoalCoconut oil, esterified see Coconut oil, fatty acid methyl esterCoconut oil, fatty acidCoconut oil fatty acid methyl esterCoconut oil, methyl ester, see Coconut oil, fatty acid methyl esterCottenseed, fatty acid see Cottenseed oil, fatty acidCrotonCrudeDieselGas, low pourGas, low sulfurHeartcut distillateLanolinLinseedLubricatingMineralMineral sealMotorNeatsfootOiticicaPalm oil, fatty acid methyl ester

*I*IDI*II##

[C]D#C#II*I*IIDDII*IIDDD

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Cargoes Pollution CategoryPalm oil, methyl ester see Palm oil, fatty acid methyl esterPenetratingPerillaPilchardPineRangeResidualResinResinous petroleumRoadRosinSealSoapstockSoya bean (epoxidized)SpermSpindleSprayTall Tall, fatty acid

#IDD

[B]*II#*IIBI##DI#BC

Tanner’sTransformerTungTurbineWhaleWhite (mineral)Wood

#IDID*I#

alpha-Olefins (C13 - C18) IIIOlefins (C13 and above, all isomers) IIIOleic Acid DOleyl alcohol (Octadecenol) see Alcohols (C13 and above) *IIIOrganic amine 70 see Aminoethyldiethanolamine, Aminoethyl-ethanolamine solution IIIPalm stearin Dn-Parafins (C10 - C20) IIIPentadecanol, see Alcohols (C13 and above) *IIIPentaethylene glycol see Polyethylene glycols IIIPentaethylenehexamine DPentane (all isomers) CPentanoic acid DPentene (all isomers) CPetrolatum III1-Phenyl-1-xylyl ethane CPhosphosulfurized bicyclic terpene #Phthalate plasticizers see individual phthalate #Pinene BPolyalkenyl succinic anhydride amine #Polyalkylene glycols, Polyalkylene glycol monoalkyl ethers mixtures *DPolyalkylene oxide polyol [C]Polyamine, amide mixture #Polybutadiene, hydroxyl terminated [III]Polybutene IIIPolydimethylsiloxane #Polyethylene glycol IIIPolyethylene glycol dimethyl ether IIIPolyglycerol [III]

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Cargoes Pollution CategoryPolyisobutylene see Polybutene [III]Polymerized esters #Poly(20)oxyethylene sorbitan monooleate [B]Polypropylene [III]Polypropylene gycol DPolypropylene gycol methyl ether IIIPolysiloxane IIIPoolystyrene dialkyl maleate #Potassium oleate [D]Propane LFGn-Propoxypropanol #Propyl acetate (iso-) IIIPropyl acetate (n-) DPropyl alcohol (iso-) IIIPropyl alcohol (n-) IIIPropylbenzene (iso-) see Cumene BPropylbenzene (n-) Ciso-Propylcyclohexane CPropylene LFGPropylene-butyene copolymer IIIPropylene dimer CPropylene glycol IIIPropylene glycol ethyl ether DPropylene glycol monoalkyl ether DPropylene glycol methyl ether DPropylene polymer (in liquid mixtures) #Propylene tetramer BPropylene trimer BPseudocumene see Trimethylbenzenes BRum see Alcoholic beverages, n.o.s. *IIISodium acetate, glycol, water solutions #Sodium acetate solution [D]Sodium benzoate solution [D]Sodium sulfonate #Stearic acid *IIIStearyl alcohol (Octadecanol) IIISulfolane IIITallow DTallow alcohol see Alcohols (C13 and above) *IIITallow fatty acid DTallow alkyl nitrile #Tetradecanol IIITetradecene see the Olefin, alpha-Olefin entries IIITetracyclobenzene [C]Tetraethylene glycol IIITetrahydroaphthalene CTetrapropylbenzene see Alkyl(C9-C17) benzenes *DToluene CTriarylphosphate ATributyl phosphate BTricresyl phosphate (less that 1% of the ortho isomer) ATridecane IIITridecanoic acid IIITridecanol see Alcohols (C13 and above) IIITridecene III

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Cargoes Pollution CategoryTridecylbenzene [C]Triethylbenzene ATriethylene glycol IIITriethylene glycol butyl ether IIITriethylene glycol butyl ether mixture #Triethylene glycol ethyl ether DTriethylene glycol methyl ether DTriethyl phosphate DTriisocotyl trimellitate #Triisopropanolamine IIITrimethylbenzenes (all isomers) BTrimethyol propane polyethoxylate D2,2,4-Trimethylpentanediol-1,3-diisobutyrate #2,2,4-Trimethyl-3-pentanol-1-isobutyrate #Tripropylene see Propylene trimer *BTripropylene glycol IIITripropylene glycol methyl ether DTrixylenyl phosphate ATurpentine BTurpentine substitute (White spirit) see White spirit (low(15-20%) aromatic) *BUndecenol see Undecyl alcohol BUndecene BUndecyl alcohol BUndecylbenzene [C]Vinyl acetate-fumerate copolymer #Waxes

CandelilaCarnaubaParaffinPetroleum

@*D*DIII#

White spirit see White spirit (low (15-20%) aromatic) *BWhite spirit (low (15-20%) aromatic) BWine see Alcoholic beverages, n.o.s. IIIWool grease #Xylenes (ortho-, meta-, para-) CZinc dialkyldithiophosphate #

Explanation of symbols: As used in this table the following stands for:

Symbol ExplanationA, B, C, D NLS Category of Annex II of MARPOL 73/78.

I Considered an "oil" under Annex I of MARPOL 73/78.

III Appendix III of Annex II (non-NLS cargoes) of MARPOL 73/78.

LFG Liquefied flammable gas.

# No determination of NLS status.

For shipping on an oceangoing vessel, see

46 CFR 153.900(c).

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[] A NLS category in bracket indicates that the product is previously

categorized and that further data are necessary.

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Appendix 3-8

Classes of Vessels(46 CFR 30.01-5(d))

Method of propulsion

Size or other limitations1 under subchapter

Classes of vessels (including motorboats) examined or inspected under various Coast Guard regulations 1

Vessels inspected and certificated Passenger D- Tank Vessels2

Vessels inspected and certificated under either subchapter H- Cargo and Vessel 2,3, 4, 5 or Subchapter T- Small Passenger Vessels2, 3, 4

Vessels inspected and certificated under subchapter I- Uninspected Miscellaneous Vessels2 ,5

Vessels subject to provisions of subchapter C,- Vessels2, 3, 6, 7 8

Column 1 Column 2 Column 3 Column 4 Column 5 Column 6Steam Vessels not over 65 ft in

length.All vessels carrying combustible or flammable liquid cargo in bulk.

All vessels carrying more than 6 passengers.7

All tugboats and towboats. All vessels except those covered by columns 3, 4, 5, and 7.

Vessels over 65 ft in length. All vessels carrying combustible or flammable liquid cargo in bulk.

1. All vessels carrying more than 12 passengers on an international voyage, except yachts.2. All vessels of not over 15 gross tons which carry more than 6 passengers.73. All other vessels carrying passengers,7 except:a. Yachts.b. Documented cargo or tank vessels issued a permit to carry not more than 16 persons in addition to the crew.c. Towing and fishing vessels, in other than ocean and coastwise service, may carry persons on the legitimate business of the vessel, in addition to crew, but not to exceed one for each net ton of the vessel.

All vessels except those covered by columns 3 and 4.

None

Motor Vessels not over 15 gross tons.

Vessels over 15 gross tons except seagoing motor vessels of 300 gross tons and over.

All vessels carrying combustible or flammable liquid cargo in bulk.

All vessels carrying combustible or flammable liquid cargo in bulk.5

All vessels carrying more than 6 passengers.7

1. All vessels carrying more than 12 passengers on an international voyage, except yachts.2. All vessels not over 65 feet in length which carry more than 6 passengers.7

Those vessels carrying dangerous cargoes when required by 46 CFR 98 or 49 CFR 171- 179.All vessels carrying freight for hire except those covered by columns 3 and 4.

All vessels except those covered by columns 3, 4, 5, and 7.

All vessels except those covered by columns 3, 4, 5, and 7.

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Method of propulsion

Size or other limitations1 under subchapter

Classes of vessels (including motorboats) examined or inspected under various Coast Guard regulations 1

Vessels inspected and certificated Passenger D- Tank Vessels2

Vessels inspected and certificated under either subchapter H- Cargo and Vessel 2,3, 4, 5 or Subchapter T- Small Passenger Vessels2, 3, 4

Vessels inspected and certificated under subchapter I- Uninspected Miscellaneous Vessels2 ,5

Vessels subject to provisions of subchapter C,- Vessels2, 3, 6, 7 8

Column 1 Column 2 Column 3 Column 4 Column 5 Column 63. All other vessels of over 65 feet in length carrying passengers for hire except documented cargo or tank vessels issued a permit to carry not more than 16 persons in addition to the crew.

Seagoing motor vessels of 300 gross tons and over.

All vessels carrying combustible or flammable liquid cargo in bulk.5

1. All vessels carrying more than 12 passengers on an international voyage, except yachts.2. All other vessels carrying passengers,7 except:a. Yachts.b. Documented cargo or tank vessels issued a permit to carry not more than 16 persons in addition to the crew.

All vessels except those covered by columns 3 and 4, and those engaged in the fishing, oystering, clamming crabbing, or any other branch of the fishery, kelp, or sponge industry.

All vessels except those covered by columns 3, 4, 5, and 7.

Sail Vessels not over 700 gross tons.

All vessels carrying combustible or liquid cargo in bulk.

All vessels carrying more than 6 passengers.7

Those vessels carrying dangerous cargoes when required by 46 CFR part 98 or 49 CFR 171-179.

None

Vessels over 700 gross tons. All vessels carrying combustible or liquid cargo in bulk.

All vessels carrying passengers for hire.

Those vessels carrying dangerous cargoes when required by 46 CFR part 98 or 146.

None

Non-self-propelled Vessels less than 100 gross tons.

All vessels carrying combustible or liquid cargo in bulk.

Those vessels carrying dangerous cargoes when required by 49 CFR parts 171-179.

Those Vessels carrying dangerous cargoes when required by 46 CFR part 98 or 49 CFR parts 171-179.

All barges carrying passengers except those covered by column 4.

Vessels 100 gross tons or over.

All vessels carrying combustible or flammable liquid cargo in bulk.

All seagoing barges except those covered by columns 3 and 4; and those inland barges carrying dangerous car goes when required by 49 CFR 171- 179.

All seagoing barges except those covered by columns 3 and 4; and those inland barges carrying dangerous cargoes when required by 46 CFR parts 98 or 49 CFR 171-179.

All barges carrying passengers except columns 4 and 7.

1Where length is used in this table it means the length measured from end to end over the deck, excluding sheer. This expression means a straight line measurement of the overall length from the foremost part of the vessel to the aftermost part of the vessel, measured parallel to the centerline. 2Subchapter E (Load Lines), F (Marine Engineering), J (Electrical Engineering), and N (Dangerous Cargoes) of this chapter may also be applicable under certain conditions. The provisions of 49 CFR 171-179 apply whenever hazardous materials are on board vessels (including motorboats), except when specifically exempted by law. 3Public nautical schoolships, other than vessels of the Navy and Coast Guard, shall meet the requirements of 49 CFR 167 of subchapter R (Nautical Schools) of this chapter. Civilian nautical schools, as defined by 46 USC 1331, shall meet the requirements of subchapter H (Passenger Vessels) and part 168 of subchapter R (Nautical Schools) of this chapter. 4Subchapter H (Passenger Vessels) of this chapter covers only those vessels of 100 gross tons or more. Subchapter T (Small Passenger Vessels) of this chapter covers only those vessels of less than 100 gross tons. 5Vessels covered by subchapter H (Passenger Vessels) or I (Cargo and Miscellaneous Vessels) of this chapter, where the principal purpose or use of the vessel is not the carriage of liquid cargo, may be granted a permit to carry a limited amount of flammable or combustible liquid cargo in bulk. The portion of the vessel used for the carriage of the flammable or combustible liquid cargo shall meet the requirements of subchapter D (Tank Vessels) in addition to the requirements of subchapter H (Passenger Vessels) or I (Cargo and Miscellaneous Vessels) of this chapter. 6Any vessel on an international voyage is subject to the requirements of the International Convention for Safety of Life at Sea, 1974.

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7The meaning of the term passenger is as defined in the Act of 10 May 1956 (Section 1, 70 Statute 151; 46 USC 390). On oceanographic vessels, scientific personnel on board shall not be deemed to be passengers or seamen, but for calculations of lifesaving equipment, etc., shall be counted as persons. 8Boilers and machinery are subject to examination on vessels over 40 ft in length.

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