Second Lecture a Janusry 27 2011

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    16 weeks two lectures per week

    one lab per week as listed in syllabus

    Test every third week at the end of the Friday class.

    There will be a total of5 tests.

    The lowest score will be dropped unless a test is

    missed.

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    First week: chapters 1-3

    Second week: chapter 4Third week: chapter 5

    Pay attention to the Learning Outcomes

    highlighted in each chapter.

    Test questions will be multiple choice or short answer

    questions modeled on the questions at the end of

    each chapter.

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    DOMAINS

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    Question

    Hypothesis

    PredictionsExperiments

    Conclusion

    Scientific Method

    Proven hypotheses lead to theories.

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    1858 Hypothesis:

    Natural selection is the mechanism for evolution.

    Individuals possessing attributes that give them an

    advantage in their environment are more likely to

    survive and reproduce.

    Therefore the population gradually changes.

    Decent with modification = evolution

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    Bhor

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    Oxygen oxidizes things, oxygen always gains electrons

    Oxidized molecule looses electrons.

    Oxidation is the loss of electrons.Reduction is the gain of electrons.

    In an oxidation reaction, oxygen itself is reduced.

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    Each period: same # valence electrons in in outermost shell

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    Atomic mass is the sum of the mass ofelectrons, protons and neutrons .

    Isotopes have same number of protonsand electrons but differ in the number

    neutrons.

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    Covalent bonds

    Molecules contain 2 or more atomsjoined by covalent bonds.

    The resulting molecule has no netcharge.

    The octet rule is satisfied, therefore

    there are no unpaired electrons.

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    Structural

    formulaMolecular

    formula

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    Covalent bonds can be polar or non polar

    depending on the individual atoms

    affinity for electrons (electronegativity)

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    The water molecule is polar.

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    Hydrogen bond is a fixed length

    causing ice to be less dense than liqiud.

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    Properties

    ofWater

    mostly

    liquidat earth

    surface

    Can adhere to

    other polarmolecules

    (capillary action)

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    One ml (cc) ofwater

    at 250C and 1 atmosphereweighs 1 gram (g)

    One gram ofhydrogencontains 6.02 X 1023 molecules

    6.02 X 1023 molecules = 1 mole

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    Molecular weight = weight of one mole

    One mole of hydrogen weighs 1 g

    One mole of oxygen weighs 16 g

    Molecular weight of water is

    2 X 1 g + 1 X 16 g = 18 g

    The molecular weight of water is 18 g

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    1 liter = 1000ml = 1000g

    Molecular weight of water is

    18 g/mole

    One liter of water contains

    1000/18

    55 moles of water

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    Water undergoes ionization:

    H2O OH-

    + H+

    At 250C one liter of water contains 10-7

    mole of H+ ions.

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    Acids and Basis

    pH is a measure of the concentration ofhydrogen ions in solution.

    pH is measure of the [H+

    ] in solution.

    pH = -log [H+]

    pH scale is 0 to 14 (acidic to basic)

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    pH = -log [H+]

    0.1 mole H+/liter has a pH = 1

    (-log 10-1 = 1)

    10-14 mole H+/liter has pH = 14

    (-log 10-14 =14)

    pH scale is 0 to 14 (acidic to basic)

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    Buffers stabilize pH.

    At their buffering range they bind excess[H+] as pH decreases and supply [H+] as

    pH increases.

    Dissolved carbon dioxide (carbonic

    acid/bicarbonate)is the key buffer in

    human blood. Its buffering range is from

    pH 4 to 6.

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    Eratosthenes (Er-uh-tos-thuh-neez)