Second Lecture a Janusry 27 2011
Transcript of Second Lecture a Janusry 27 2011
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16 weeks two lectures per week
one lab per week as listed in syllabus
Test every third week at the end of the Friday class.
There will be a total of5 tests.
The lowest score will be dropped unless a test is
missed.
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First week: chapters 1-3
Second week: chapter 4Third week: chapter 5
Pay attention to the Learning Outcomes
highlighted in each chapter.
Test questions will be multiple choice or short answer
questions modeled on the questions at the end of
each chapter.
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DOMAINS
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Question
Hypothesis
PredictionsExperiments
Conclusion
Scientific Method
Proven hypotheses lead to theories.
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1858 Hypothesis:
Natural selection is the mechanism for evolution.
Individuals possessing attributes that give them an
advantage in their environment are more likely to
survive and reproduce.
Therefore the population gradually changes.
Decent with modification = evolution
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Bhor
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Oxygen oxidizes things, oxygen always gains electrons
Oxidized molecule looses electrons.
Oxidation is the loss of electrons.Reduction is the gain of electrons.
In an oxidation reaction, oxygen itself is reduced.
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Each period: same # valence electrons in in outermost shell
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Atomic mass is the sum of the mass ofelectrons, protons and neutrons .
Isotopes have same number of protonsand electrons but differ in the number
neutrons.
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Covalent bonds
Molecules contain 2 or more atomsjoined by covalent bonds.
The resulting molecule has no netcharge.
The octet rule is satisfied, therefore
there are no unpaired electrons.
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Structural
formulaMolecular
formula
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Covalent bonds can be polar or non polar
depending on the individual atoms
affinity for electrons (electronegativity)
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The water molecule is polar.
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Hydrogen bond is a fixed length
causing ice to be less dense than liqiud.
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Properties
ofWater
mostly
liquidat earth
surface
Can adhere to
other polarmolecules
(capillary action)
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One ml (cc) ofwater
at 250C and 1 atmosphereweighs 1 gram (g)
One gram ofhydrogencontains 6.02 X 1023 molecules
6.02 X 1023 molecules = 1 mole
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Molecular weight = weight of one mole
One mole of hydrogen weighs 1 g
One mole of oxygen weighs 16 g
Molecular weight of water is
2 X 1 g + 1 X 16 g = 18 g
The molecular weight of water is 18 g
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1 liter = 1000ml = 1000g
Molecular weight of water is
18 g/mole
One liter of water contains
1000/18
55 moles of water
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Water undergoes ionization:
H2O OH-
+ H+
At 250C one liter of water contains 10-7
mole of H+ ions.
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Acids and Basis
pH is a measure of the concentration ofhydrogen ions in solution.
pH is measure of the [H+
] in solution.
pH = -log [H+]
pH scale is 0 to 14 (acidic to basic)
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pH = -log [H+]
0.1 mole H+/liter has a pH = 1
(-log 10-1 = 1)
10-14 mole H+/liter has pH = 14
(-log 10-14 =14)
pH scale is 0 to 14 (acidic to basic)
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Buffers stabilize pH.
At their buffering range they bind excess[H+] as pH decreases and supply [H+] as
pH increases.
Dissolved carbon dioxide (carbonic
acid/bicarbonate)is the key buffer in
human blood. Its buffering range is from
pH 4 to 6.
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Eratosthenes (Er-uh-tos-thuh-neez)