SDMS DocID 2121999 · International Enterprises Corp. building (Coyne Building), which is located...

52
Fw: Coyne Info Robert]' Kelly to; Sally Pascal SDMS DocID 2121999 , V y 01/05/2010 12:37 PM Print out attachments for me Robert F. Kelly OSC, Region III 1650 Arch Street, 8th Floor, Mail Code 3HS32 Philadelphia, PA 19103 215-814-3268 (voice)' 215-814-3254 FAX email: [email protected] 'J From: "Fisher, Thomas A" [[email protected]] Sent: 01/05/2010 10:46 AM EST To: Robert] Kelly Cc: "Sizemore, Joe N^! <[email protected]>;/Zeto, Michael A" <[email protected]> Subject: FW: Coyne InFo~ Bob,' There is a lot more info in the file, but I believe the attached is a good overview of what is going on.... Basically there are two issues. One, is the groundwater contamination in monitoring well numbers. Two, is the contamination found offsite at the park. Let us know what you think and or need. Thanks. Assistant Chief Inspector Environmental Enforcement WV DEP 601 57th Street SE Charleston, WV 25304 • 304T926-0499 ext. 1279 / % From: Sizemore, Joe M Sent: Tuesday, January 05, 2010 9:38 AM To: Fisher, Thomas A Cc: Zeto, Michael A Subject: Coyne Info . Tom. Attached are the following documents: Trends of results from Monitoring Well #5 from the past several years - Recent Indoor Air Quality Monitoring Reports completed for Wayne County EDA Recent Groundwater Investigation completed form Wayne County EDA that~ AR100278

Transcript of SDMS DocID 2121999 · International Enterprises Corp. building (Coyne Building), which is located...

Page 1: SDMS DocID 2121999 · International Enterprises Corp. building (Coyne Building), which is located at 1111 Vernon Street, Westmoreland District, Wayne County, West Virginia. The following

Fw Coyne Info Robert] Kelly to Sally Pascal

SDMS DocID 2121999 V y

01052010 1237 PM

Print out attachments for me

Robert F Kelly OSC Region III 1650 Arch Street 8th Floor Mail Code 3HS32 Philadelphia PA 19103 215-814-3268 (voice) 215-814-3254 FAX email kellyrobertjepagov

J

From Fisher Thomas A [ThomasAFisherwvgov] Sent 01052010 1046 AM EST To Robert] Kelly Cc Sizemore Joe N ltJoeMSizemorewvgovgtZeto Michael A ltMichaeIAZetowvgovgt Subject FW Coyne InFo~

Bob There is a lot more info in the file but I believe the attached is a good overview of what is going on Basically there are two issues One is the groundwater contamination in monitoring well numbers Two is the contamination found offsite at the park Let us know what you think and or need Thanks

Assistant Chief Inspector Environmental Enforcement WV DEP 601 57th Street SE Charleston WV 25304 bull 304T926-0499 ext 1279

From Sizemore Joe M Sent Tuesday January 05 2010 938 AM To Fisher Thomas A Cc Zeto Michael A Subject Coyne Info

Tom Attached are the following documents bull Trends of results from Monitoring Well 5 from the past several years -bull Recent Indoor Air Quality Monitoring Reports completed for Wayne County EDA bull Recent Groundwater Investigation completed form Wayne County EDA that~

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shows contamination on the adjacent property bull The Consent Order

Let me know if Bob needs additional information to get started Thanks Joe

[ABhil Iiutii KWt1 [bullbull^tettl

MW-5 data trendspdf 04-08-0408 Groundwater Sampling Letter Reportpdf Coyne VI Memo_09-08-08pdf Order No HW-011-99pdf

AR100280

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1 2 4 bull 5

TCE 307 - 309

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17

PCE 3 01-3 09

003

0005

Cis 12 DCE 301 - 309

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CIVIL bull ENVIRONMENTAL AND GEOTECHNICAL ENGINEERING

4980 Teays Valley Road Scott Depot WV 25560 Phone 3047550721 Fax 3047551880 TRIAD ENGINEERING INC

October 24 2008

Mr Robert Trocin Wayne County Economic Development Authority PO Box 519 Wayne VVest Virginia 25570

Subject Groundwater Assessment Former Coyne International Enterprises Corp Building Westmoreland District Wayne County West Virginia

Dear Mr Trocin

On behalf of the Wayne County Economic Development Authority (WCEDA) Triad

Engineering Inc conducted a focused groundwater assessment at the former Coyne

International Enterprises Corp building (Coyne Building) which is located at 1111 Vernon

Street Westmoreland District Wayne County West Virginia The following summarizes

field activities and analytical results of this assessment Figure 1 Site Location Map

illustrates the location of the site

On October 32008 five temporary groundwater hionitoring points were installed using a

direct-push technology sampling unit A groundwater sample was collected from each

monitoring point and analyzed by a WVDEP certified laboratory for VOC as per United

States Environmental Protection Agency (USEPA) method SW-8260B Three monitoring

points were installed in the area of groundwater monitoring well MW-5 between the Coyne

Building and the CSX Transportation inc rail line and two monitoring points were installed

to the immediate north of the CSX Transportation Inc rail line Groundwater was

encountered at a depth of approximately 30-feet below ground surface (bgs) Figure 2

Sample Location Map illustrates the locationof the groundwater monitoringpoints and

physical features located within the sample area

WWWTRIADENGCOM

Practical Engineering and Science Solutions Since 1975

AR100282

Wayne County Economic Development Authority Groundwater Assessment Coyne TextileServices Building Westmoreland District Wayne County West Virginia October 24 2008 -

Page 2

FIGURE 1 SITE LOCATION MAP Huntington WVa USGS 75-minute Topographic Quadrangle

1985

Laboratory analytical results were compared to the applicable WVDEP groundwater

maximum contaminant level (MCL) or de mnms values listed in Table 60-3 effective June

26 2008 Concentrations of VOC which exceeded the de minimis values were identified in

5 of 5 groundwater samples collected Tetrachloroethene (PERC) was detected in each of

the groundwater samples at concentrations which exceeded the de minimis values

Triehloroethene was detected in samples collected from GP-1 GP-3 and GP-5 at

concentrations which exceeded the de minimis values Cis-12-Dichloroethene was detected

in samples collected from GP-1 and GP-3 at concentrations which exceeded the de minimis

values Vinyl Chloride was detected in each sample except GP-5 at concentrations which

exceeded the de minimis values A summary of laboratory analytical reports is provided in

Table 1 Laboratory Analytical Summary-Groundwater and copies of the Laboratory

Analytical Reports are included as Attachmenf 1

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(9

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P B B K ftVENIjEl

WEST MORELAND PARK

TENNIS BASKETBALL COURTS

GP-5 GP-4

9-inn i in iMMIMII I IMMII I I I I I I I IMI I I I I I IMI I I IMMII I I I I I I I I IMMII I I I I I IMI I I I I I I I I I I I IMI I I I I I I I I I I IMMII I I IMIMIMII I I I I I I I I I IMI I I I I I I I IMI I I I

CSX RAILROAD GP-2 GP-1 GP-3 I I I I I I I IMI I I IMMI I IMI I I I I I IMIMI I I IMI I I I I I I I I in i l lMI IMIMI I I I I IMMI I I I I I Jd I I IMj r i i y i l lMMI I I IMI I I I I I I I I in i l l l l l l lM l l l l l l l i n i l l l l l l l l ijj^lll^flH|t

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ACCESS ROAD

BUILDING

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LEGEND

CW SAMPLE LOCAT10

MONITORING WELL

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WCEDA VRP GROUNDWATER SAMPLINGS HUNTINGTON WEST VIRGINIA

F I G U R E tslD

Cad Files04-08-p408-1dgn 6122009 24625 PM

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Wayne County Economic Development Authority Page 3 Groundwater Assessment Coyne Textile Services Building Westmoreland District Wayne County West Virginia October 24 2008 _ bull ^

We appreciate the opportijnity to assist you with this project If you have any questions or r

need additional information please feel free to contact us

Sincerely TRIAD ENGINEERING INC

Matthew C Wright

Project Geologist

JohnM Meeks PG LRS

Project Manager

end

^

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Table 1 Laboratory Analytical Summary - Groundvvater WCEDA Vernon street

Huntington Wayne County West Virginia

COPC

Acetone Benzene Bromobenzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone sec-Butylbenzene n-Butyibenzene tert-Butylbenzene Carbon disulfide Carbon Tetrachloride Chlorobenzene Chlorodibromorriethane Ghloroethane Chlbroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene 12-Dibromo-3-chloropropane 12-Dlbronnoethane (EDB) DIbromomethane 14-Dichlorobenzene 13-Dictilorobenzene 12-Dictilorobenzene Dichlorodifluoromethane 11-Dlchloroethane 12-Dichloroethane cis-12-Dichloroethene

MCL ugL

5500 5

NV NV NV 85 87

700 61 61 61

1000 5

100 NV 39

bull 017 190 NV NV 02

005 NV

750 600 600 390 910

5 70

GP-1 ugL ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND

ND ND ND ND ND ND ND ND ND ND ND ND 112 ND

5210

GP-2 ugL ND ND ND

ND ND ND ND ND ND ND ND ND ND ND ND ND ND

062 J ND ND ND

ND ND ND ND ND ND ND ND

379

GP-3 ^ ugL

ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND

065 J ND 184 ND( ND ND ND

ND ND ND ND ND ND ND

12500

GP-4 ugL ND ND ND ND ND

- ND ND ND ND ND ND ND ND ND ND ND ND ND

ND ND ND ND ND ND ND ND ND ND ND 132

GP-5 ugL ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND

ND ND ND ND ND ND ND ND ND ND ND ND 59

Notes - Bold Indicates COPCs detected at concentrations greater than the MCL bull(60CSR3 Table 60-3B July 2008)

NAME - J indicates analyte detected at levels less than the reporting limit and greater than

or equal to the MDL value is estimated -NV indicates no value has been established

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Table 1 Laboratory Analytical Summary - Groundwater (Continued) WCEDA Vernon street

Huntington Wayiie County West Virginia

COPC

11-Dichloroethene trans-12-Dichloroethene 13-Dichloropropane 12-Dichloropropane 22-Dichloropropane cis-13-Dichloropropene trans-13rDichloropropene 11-Dichloropropene Ethylbenzene Hexachlorobutadiene 2-Hexanone Isopropylbenzene p-lsopropyltoluene Methyl tert-Butyl Ether Methylene Chloride 4-Methyl-2-pentanone Naphthalene n-Propylbenzene Styrene 1112-Tetrachloroethane 1122-Tetrachloroethane Tetrachloroethene Toluene 123-Trichlorobenzene 124-Trichlorobenzene 112-Trichloroethane 111-Trlchloroethane Triehloroethene Trichlorofluoromethane 123-Trichloropropane 135-Trimethylbenzene 124-Trimethylbenzene Vinyl chloride Xylenes total s

MCL ugL

91 100 04

5 NV NV NV NV

700 086

NV NV

NV 028

5 NV 62 NV 100

043 0055

5 1000

NV 70

5 20

5 1300

0034 120 120

2 10000

GP-1 ugL 964 458 ND ND

ND ND ND ND

052 J ND ND ND ND ND ND ND ND ND ND ND ND

14700 065 J ND ND ND ND

2850 ND

ND ND ND 116 146 J

GP-2 ugL ND ND ND ND ND ND ND- ND ND ND ND ND -ND ND ND ND ND ND ND ND ND

603 ND ND ND ND ND

079 J ND ND ND ND 242 ND

GP-3 ugL 346 865 ND ND

bull ND ND ND-ND

055 J ND ND ND ND ND ND ND ND ND ND ND ND

13900 159 ND ND ND ND

4870 ND ND ND ND 708 149 J

GP-4 ugL ND ND ND ND ND ND ND ND ND ND ND

ND 177 ND ND ND ND ND ND ND ND

583 ND ND ND ND ND

082 J ND ND ND ND

227 ND bull

GP-5 ugL ND ND ND ND ND

ND ND ND ND ND ND ND ND

ND ND ND ND ND ND ND ND 133 ND ND ND ND ND

574 ND ND

ND ND 122 ND

Notes - Bold indicates COPCs detected at concentrations greater than the MCL

(60CSR3 Table 60-3B July 2008) - ND indicates non-detected at concentrations greater than the MCL - J indicates analyte detected at levels less than the reporting limit and greater than

or equal to the MDL value is estimated - NV indicates no value has been established

AR100287

Risk-Based Rerfiedies

R B R Consulting Inc 650 Shady Drive Beaver Falls PA 15010

Phone724-846-4096 Fax 724-846-6974

MEMORANDUM

TO John Meeks Triad Engineering Inc

FROM Bruce Fishman

DATE September 82009

SUBJECT Evaluation of Potential Risks Associated with Vapor Intrijsion to Indoor Air Coyne Textile Services Facility - Huntington West Virginia

bull V bull bull bull

This memorandum presents a risk evaluation for potential risks associated with vapor intrusion to indoor air at the Coyne Textile Services Facility located in Huntington West Virginia (site) This evaluation was conducted according to West Virginia Department of Environmental Protection (WVDEP) and United States Environmental Protection Agency (USEPA) methodologies

DATA INCLUDED 1N THE EVALUATION

This evaluation includes three subslab vapor samples (VP-01 VP-02 and VP-03) collected from immediately beneath the floor of the existing site building Table 1 lists the subslab vapor samples included in this risk assessment Samples were analyzed for volatile organic compounds (VOCs) by USEPA Method TO-15 Complete analytical data for these samples are provided in Table A-1 of Appendix A

The analytical results of the subslab vapor samples were compared to the target shallow soil gas comparison values presented in Table 2c of the USEPA vapor intrusion guidance document (2002a) These companson values are generic soil gas screening values that are protective of indoor air for residential land uses and represent concentrations in-sliallow soil gas based on a target risk level of 1 x 10reg andor a hazard index of 1 The comparison is presented in Table 2

As indicated in Table 2 the following constituents are identified as contaminants of concern (COC) for the vapor intrusion to indoor air pathway 124-trimethylbenzene 12-dichloroethene (cis) chloroform methylene chloride tetrachloroethene and triehloroethene

ESTIMATION OF INDOOR AIR CONCENTRATIONS

The concentrations of COC in indoor air associated with vapor intrusion from subslab vapor were estimated using methodologies outlined in the Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings (USEPA 2004) A transport factor (TF) is required that will relate the

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Risk-Based Remedies

R B R Consulting Inc

constituent concentration in subslab vapor to the concentration in indoor air The TF is dependent on the diffusion coefficient and other properties that will affect the transfer of constituents into air such as distance from the source to tlie breathing zone soil properties and building properties A site-specific building size of 84000 square feet (Dolphin 2000) and a soil type of sandy loam were used in the calculation of TF The TF is determined using calculationsbased on the Johnson and Ettinger (1991) vapor intrusion model Details of the TF calculations are provided in Appendix B

Subslab vapor concentrations are converted to indoor air concentration by applying the TF as follows

Cja ^ Csubslab X I r

The TF for each COC along with the resulting concentrations of COC in indoor air are presented in Tables

EXPOSURE EVALUATION

Noncarcinogenic health effects are evaluated by calculating the average dose of a constituent over the course of the exposure period This dose is termed the Average Daily Dose (ADD) Potential carcinogenic health effects are evaluated in terms of an individuals theoretical increased risk of developing cancer over a lifetime Although the duration of exposure to a constituent release generally does not last for an entire lifetime constituent intake for carcinogens is estimated as the average dose over a human lifetime (70 years) This lifetime dose applies specifically to the evaluation of carcinogenic effects and is termed tine Lifetime Average Daily Dose (LADD) In a risk assessment the calculated ADD or LADD are estimated quantitatively using assurnptions about the duration frequency and magnitude of exposure experienced by each potential receptor and assumptions about the constituent properties that influence absorption

The quantitative estimation of constituent intake involves the incorporation of numerical assumptions for a variety of exposure parahneters Exposure assumptions used in these intake calculations are based on WVDEP (2001) or USEPA (1989 2002b) recommended values The factors and equation for inhalation of vplatiles is presented in Table 4 and described below

bull Inhalation Rate and Exposure Time WVDEP (2001) and USEPA (2002b) guidance recommend that an inhalation rate of 20 m day be used for workers For an exposure time of 8 hours (a typical workday) this results in an inhalation rate of 25 m hour

bull Exposure Frequency and Duration Default exposure factors for indoor workers are provided by WVDEP (2001) Exposure frequency for the worker is 5 days per week for 50 weeks a year or 250 days per year The exposure duration for these workers is 25 years which is the 95th percentile value ai cording to the Bureau of Labor Statistics (USEPA 1989)

bull Body Weight The default value for average body weight of an adult is 70 kg based on WVDEP (2001) and USEPA guidance (1989 2002b)

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Risk-Based Remedies

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bull Averaging Time As described above the doses for noncarcinogenic health effects are averaged oyer the specific period of exposure for a given receptor Noncarcinogenic

averaging times are therefore calculated by multiplying the exposure duration for the receptor by 365 daysyear Carcinogenic health effects are calculated over a lifetime exposure so the value recommended by WVDEP (2001) and USEPA (2002b) for average lifetime 70 years was used for exposure duration The resulting carcinogenic averaging time is 25550 days

TOXICITY VALUES

Noncarcinogenic responses are evaluated numerically using parameters known as the hazard quotient (HQ) and hazard index (HI) the HQ is obtained by dividing the ADD for a constituent by the reference dose (RfD) Each dose calculation with a specific combination of constituent receptor and exposure pathway will have a distinct ADD and calculated HQ HQs associated with all constituents for a particular pathway are summed to yield the HI

In order to estimate the theoretical excess lifetime cancer risk the LADD of a constituent is multiplied by the cancer slope factor (CSF) For each pathway this calculation is carried out for each applicable constituent and the risks are summed to obtain the total potential risk due to that pathway

Toxicity values for each constituent are presented in Table 5 the toxicity values were obtained from the following sources

bull Integrated Risk Information System (IRIS) on-line database provided by USEPA (2009)

bull The USEPAs Provisional Peer-Reviewed Toxicity Values (PPRTV) as presented in the USEPA Regional Screening Tables (ORNL 2009)

bull Provisional value from the National Center for Environmental Assessnient (as per WVDEP)

bull The Agency for Toxic Substances and Disease Registrys (ATSDR) Minimal Risk Levels (MRLs ATSDR 2009) and

bull Value cited by USEPA Region 3 attributed to other sources (as per WVDEP)

RISK CHARACTERIZATION

Potential noncarcinogenic effects associated with exposure to COC at the site are estimated by comparing calculated intakes with the contaminant-specific RfDs The total HI was calculated by summing the individual HQs An HI value equal to or less than 1 indicates thatthelikelihopd of ah adverse noncancer effect would be negligible (USEPA 1989) An HI greater than 1 indicates that additional evaluation of the case is warranted

Theoretical excess lifetime cancer risks associated with exposure to COC from the site were calculated by comparing estimated intakes to constituent-specific CSFs Summed theoretical

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Risk-Based Remedies

R B R Consulting Inc

excess risks are calculated by combining constituent-specific risks The results may be compared with target benchrharks for acceptable risk Various demarcations of acceptable risk have been established by regulatory agencies WDEP (2001) presents a target cancer risk of 1 x 10 for nonresidential scenarios USEPA (1991) considers potential cancer risks in the range of 1 x 10reg to 1 X 10 to be acceptable

Constituent-specific results for the indoor worker are presented in Table 6 For the indoor worker exposed to COC in indoor air (vapor intrusion from subslab vapor) the total HI is 00081 and the potential cumulative cancer risk is 497 X 10reg

These results meet both WVDEP and USEPA benchmarks indicating that the site poses negligible potential for human health risk for indoor workers

CONCLUSIONS

The results of this focused risk evaluation indicate that potential risks associated with vapor intrusion exposure of indoor workers to constituents that may volatilize from subslab vapor are within the acceptable benchmarks established by WVDEP and USEPA No further evaluation of the vapor intrusion pathway is warranted for the site

REFERENCES

Agency for Toxic Substances and Disease Registry (ATSDR 2009) Minimal Risk Levels (MRLs) Available at httpvtfwwatsdrcdcqovmrisindexhtml

Dolphin Environmental LLC (Dolphin 2000) Site Characterization Report Mach 14 2000

Johnson PC and RA Ettinger (1991) Heuristic model for predicting the intrusion rate of contaminant vapors into buildings Environ Sci Technology 25 1445-1452

Oak Ridge National Laboratory (ORNL 2009) Regional Screening Levels for Chemical Contaminants at Superfund Sites April 15 2009 Available online httpwwwepagovreg3hwmdriskhumanrb-concentration_tableindexhtm

United States Environmental Protection Agency (USEPA 1989) Risk Assessment Guidance for Superfund Volume I PartA Human Health Evaluation Manual EPA5401-89002

United States Environmental Protection Agency (USEPA 1991) Risk Assessment Guidance for Superfund Volume I Part B Development of Risk-Based Remediation Goals Office of Emergency and Remedial Response OSWER Directive 92857-018

United States Environmental Protection Agency (USEPA 2002a) Draft Guidance for Evaluating the Vapor Intrusion to Indoor Air Pathway from Groundwater and Soils Office of Solid Waste and Emergency Response Pub No 92856-10 December 2002

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Risk-Based Remedies

R B R Consul t ing Inc

United States Environmental Protection Agency (USEPA 2002b) Supplemental Guidance for Calculating Soil Screening Levels for Superfund Sites Office of Solid Waste and Emergency Response December

United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004

United States Environmental Protection Agency (USEPA 2009) Integrated Risk Information System (IRIS) On-line database wwwepaqoviris

West Virginia Department of Environmental Protection (WVDEP 2001) West Virginia Voluntary Remediation and Redevelopment Act-Guidance Manual Version 21 March 13

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AR100292

TABLES

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TABLE 1 SUBSLAB VAPOR SAMPLES INCLUDED IN THE RISK ASSESSMENT

Coyne text i le Services Facility - Huntington West Virginia

Medium

Subslab Vapor

Sample Identification

bull VP-01

VP-02

VP-03

Sample Date

8132009

8132009

8132009

Coyne VIMemo Tables_09-08-09xls 982009

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TABLE 2 IDENTIFICATION OF CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR

Coyne Textile Services Facility - Huntington West Virginia

mdash

Const i tuent

Volati le Organics

111-Trichlor6ethane

1122-Tetrachloroethane

112-Trichloro-122-trifluoroethane

112-Trichloroethane

11-Dichloroethane

11-Dichloroethene

124-Trichlorobenzene

124-Trimethylbenzene

12-Dibromoethane

12-Dichlor6benzene

12-Dichloroethane

12-Dichloroethene (cis)

12-pichloroethene (trans)

12-Dichloropropane

12-Dichlorotetraf1uoroethane

135-Trimethylbenzene

13-Butadiene

13-Dichlorobenzene

13-Hexachlorobutadiene

14-Dichlorpbenzene

224-trimethylpentane

2-Chlorotoluene

4-Ethyltoluene

Acetone

Allyl Chloride

Benzene

Bromodichloromethane

Bromoform

Bromomethane

Carbon disulfide bull

Carbon tetrachloride

ChJorobenzene

Chloroethane

Frequency of Detection

0 3

0 3

0 3

bull 0 3

0 3

0 3

0 3

1 3

0 3 bull

0 3

b 3 bull

2 3

0 3

bull 0 3

0 3

0 3

0 3 bull

0 3

0 3

0 3

0 3

0 3

0 17

3 3

0 3

P 3

- 0 3

0 3

0 3

0 3

0 3

0 3

0 3

Min imum Detected

Concentrat ion

(ugm^)

ND

ND

ND

ND

ND

- ND

N D

197

ND bull

ND

ND

369

ND

bull~ ND

ND

ND

ND

ND

ND

bull ND

ND

ND

ND

796

ND

ND

ND-

ND

ND

ND

ND

ND

ND

Maximum

Detected Concentrat ion

(ugm3)

ND

ND

ND

ND

ND

ND

ND

197

ND

ND

ND

mdash 6030

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

1880

ND-

ND

ND

ND

ND

ND

ND

ND

ND

Sample wi th Maximum Detect

ND

ND

ND

ND

ND

ND

- ND

VP-03 -

ND

ND

ND

VP-03

ND

bullND

ND

ND

ND

ND

ND

ND

ND

ND

ND

VP-02

ND

ND bull

ND

ND

ND bull

bull ND

ND

ND

ND

Min imum Detection

Limit (ugm3)

22

28

31

22

16

16

30

20

31

24

16

bull 16

16

19

28

20

89

24 bull

43

24

bull 19

2 1

20

--^ 13

13

27

41

16

13

25

18

11

Maximum Detection

Limit (ugm3)

218

275

307

218

162

159

297

197

307

240

162

- 16

159

185

280

197

89

240

427

240

187

207

197

--125

128

268

414

155

125

252

184

106

Vapor Intrusion Corhparison

V a l u e

(ugm)

22000

042

300000

15

bull 5000

2000

2000

60

011

2000

094

350

700

40

NA

60

0087

1100

11

8000

NA

NA

NA

3500

NA

31

14

22

50

7000

16

bull 600

100000

Chemical of Concern

No

No

No

No

No

No

No

YES

No

No

No

YES

No

No

No

N o bull

bullNo

No

No

No

No

No

No

N o

No

No

No

N o

No

No

No

No

No

Comment

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent notdetected

fflaximCimTdeteetlSffieedsTcomDarisonivalues

Constituent not detected

Constituent not detected

Constituent not detected

Maximum detect exceeds comparison value

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Maximum detect below comparison value

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detectedl

Constituent not detected

Constituent not detected

CoyneVI Memo Tables_09-08-09xls 982009

AR100295

TABLE 2

IDENTIFICATION OF CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR

Coyne Textile Services Facility - Huntington West Virginia

Const i tuent

Volati le Organics

Chloroform -

Chloromethane

13-Dichloropropene (cis)

Cyclohexarie^

Dibrcimochloromethane

DichlonDdifluoromethane

Ethylbenzene

Methyl ethyl ketone

Methyl isobutyl ketone

Methyl tert-butyl ether

Methylene chloride

n-Heptane

n-Hexane

Styrene

Tert-butyl alcohol

Tetrachloroethene

Toluene

13-Dichloropropene(trans)

Triehloroethene

Trichlorofluoromethane

Vinyl bromide

Vinyl chloride

Xylene (0)

Xylenes (mampp)

Frequency of Detection

1 3

0 3

0 3

1 3

0 3

0 3

0 -3

1 3

0 3

0 3

2 3

0 3

3 3

0 3

0 3

3 3

1 3

- 0 3

3 3

P 3

0 3

0 3

1 3

1 3

Min imum Detected

Concentrat ion

(ugm)

5910

ND

ND

52

ND

ND

ND

23

ND

ND

1160

ND

1 4 4

ND

ND

11200

18

ND

91

ND

ND

ND

208

387

Maximuri i Detected

Concentrat ion (ugmS)

bull

5910

ND

ND

52

bull ND

ND

ND

23

ND

ND

1520

ND

183

ND

ND

149000

18

ND

7820

ND

bullND

ND

208

387

Sample vyith Max imum Detect

VP-02

ND

ND

VP-01

bull ND

ND

ND

VP-01

ND

ND

VP-02

ND

VP-02

ND

ND

VP-02

VP-01

ND

VP-03

ND

ND

ND

VP-03

VP-03

Min imum Detection

Limit (ugm3)

20

83

18

138

34

bull 20

17

118

16

14

14

16

- -17

12

--151

18

--23

18

10

1 7 bull

1 7 bull

Maximum Detection

Limit (ugm3)

195

83

182

138

341

198

174

118

164

144

14

164

170

121 -

--151

182

225

175

102

bull 174

174

Vapor Intrusion Compar ison

V a l u e

(ugm)

11

24

NA

2000

1

2000

22

10000

800

30000

52

NA

2000

10000

NA

81

4000

NA

022

7000

NA

28

70000

70000

Chemical o f Concern

YES

No

No

No

No bull

No

No bull

No bull=

No

No

YES

No

No

No

No

YES

No

No

YES

N o

No

No

No

No

Comment

Maximum detect exceeds comparison value

Constituent not detected

Constituent not detected

Maximum detect below comparison value

Constituent not detected

Constituent not detected

Constituent not detected

Maximum detect below comparison value

Constituent not detected

Constituent not detected

Maximum detect exceeds comparison value

Constituent not detected bull

Maximum detect below comparison value

Constituent not detected

Constituent not detected

Maximum detect exceeds comparison value

Maximum detect below comparison value

Constituent not detected

Maximum detect exceeds comparison value

Constituent not detected

Constituent not detected

Constituent not detected bull

Maximum detect below comparison value

Maximum detect below comparison value

Notes

ND - Not Detected

NA - Not Available

- - Constituent detected in every sample detection limit not presented

Values in bold indicate detection limit exceeds comparison values

Target shallow soil gas comparison values corresponding to indoor air concentrations where the soil gas to indoor air attenuation factor = 01 and the target cancer risk is set to ip (presented in Table 2c of USEPA 2002a)

Comparison value for cyclohexane is based on the comparison value for hexane

Coyne VI Memo Tables_09-08-09xls 982009

AR100296

TABLES

EXPOSURE POINT CONCENTRATIONS FOR CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR

Coyne Textile Services Facility - Huntington West Virginia

Chemical of Concern

VolatileOrganics

i24-Trimethylbenzene

12-Dichloroethene (cis)

Chloroform

Methylene chloride

Tetrachloroethene Triehloroethene

Subslab Vapor Source

Concentration (mgm^)

0197

603

591

152

149 782

Transport

Factor^ (unitless)

108E-05

108E-05

108E-05

108E-05

108E-05 108E-05

EPC in

Indoor Air (mgm^)

213E-06

651 E-05

638E-05

164E-05

161E-03 844E-05

Notes

^ Subslab vapor source concentration is based on the maximum detected concentration of samples

VP-01-02 and-03 (see Table 2) -

^ Details of the transport factor calculations are presented in Appendix B

^ Exposure Point Concentration (EPC) in inidoor air is calculated as the subslab vapor concentration TF

Coyne VI Memo Tables_09-08-09xls 982009

AR100297

TABLE 4

FACTORS USED IN DOSE CALCULATIONS INHALATION OF VOLATILE EMISSIONS

Coyne Textile Services Facility - Huntington West Virginia

Symbol

CA

IRA

ET

EF

ED-

BW

AT

Exposure Factor

Constituent Concentration in Air

Inhalation Rate

Exposure Time

Exposure Frequency

Exposure Duration

Body Weight

Averaging Time

Indoor Worker

Constituent-Specific See Table 3

25 m hour

8 hrday

250 daysyear

25 years

bull 70 kg

9125 days (NC)

25550 days (C)

Total Dose = CA x IR^ x ET x EF x ED x 1BW x 1AT

(NC) - Non-carcinogenic Averaging Time

(C) - Carcinogenic Averaging Time

Coyne VI Memo Tables_09-08-09xls 982009

AR100298

TABLES TOXICITY VALUES FOR CHEMICALS OF CONCERN

Coyne Textile Services Facility - Huntington West Virginia

Chemical of Concern

Volatile Organics

124-Trimethylbenzene

12-Dichloroethene (cis)

Chloroform

Methylene chloride

tetrachloroethene

Triehloroethene

Target Organ Critical Effect

blood

bullblood

liver

liver

liver CMS

liver kidney fetus CNS

Chroniclnhalation Reference Dose

(mgkg-day)

200E-03 P

1 OOE-02 R

140E-02 E

286E-01 M

771 E-02 M

1OOE-02 E

Inhalation Cancer ^ Slope Factor

(mgkg-day)^

NA

NA

805E-02 1

165E-03 1

200E-02 0

400E-01 E

(I) - Integrated Risk Information System (IRIS USEPA 2009)

(P) - Provisional Peer-Reviewed Toxicity Value (PPRTV) as presented in USEPA Regional Screening Tables (ORNL 2009)

(R) - Calculated assuming route-to-route extrapolation as per WVDEP

(E)-Provisional value from the National Center for Environmental Assessment (as per WVDEP)

(M)-Chronic Minimal Risk Level (MRL ATSDR 2009)

(0) - Value cited by USEPA Region 3 attributed to other sources (as per WVDEP)

Coyne VI Memo Tables_09-08-09xls 982009

AR100299

TABLE 6

NONCANCER HAZARD INDEX AND POTENTIAL CANCER RISK FOR AN INDOOR WORKER

Coyne Textile Services Facility - Huntington West Virginia

bull

Constituent

Volatile Organics

124-Trinnethylbehzene

12-Dichlorpethene (cis)

Chloroform

Methylene chloride

Tetrachloroethene Triehloroethene

EPC in Indoor Air

(mgm)

213E-06

651 E-05

- 638E-05

164E-05

161 E-03

844E-05

Intake (ADD)

(mgkg-d)

416E-07

127E-05

125E-05

321 E-06

315E-04 l65E-05

RfDi

(mgkg-d)

200E-03

1OOE-02

140E-02

286E-01

771 E-02 1 OOE-02

Hazard

Quotient

208E-04

127E-03

892E-04

112E-05

408E-03 165E-03

Intake (LADD)

(mgkg-d)

) 149E-07

455E-06 bull 446E-06

115E-06

112E-04 590E-06

CSFi

(mgkg-d)

NA

NA

805E-02

165E-03

200E-02

400E-01

Potential

Cancer Risk

NA

NA

359E-07

189E-09

225E-06 236E-06

Total Hazard Index

00081 Total

Cancer Risk 497E-06

Total Blood HI = Total Liver HI =

Total Central Nervous System HI = Total Kidney HI =

Total Fetal HI =

bull 00015 00066 00057 00017 00017

Notes NA = Toxicity values are not available for this endpoint or exposure pathway

Coyne VI Memo Tables_09-08-09xls 982009

AR100300

APPENDIX A

SUBSLAB VAPOR ANALYTICAL DATA

AR100301

Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility Huntington West Virginia

Sample

Consti tuent

Volatile Organics (ugm) 111-Trlchloroethane 1122-Tetrachloroethane 112-Trichloro-122-trifluoroethane 112-Trichloroethane 11-Dichioroethane 11-Dichloroethene 124-Trichloroberi2ene 124-Trimethylbenzene 12-Dibromoethane 12-Dichloroben2ene 12-Dichloroethane 12-Dichloroethene-(cis) -12-Dichloroethene (trans) 12-Dichloropropane 12-Dichlorotetrafluoroethane 135-Trimethylbenzene 13-Butadiene 13-Dichlorobenzene 13-Hexachlorobutadiene 14-Dichlorobenzene 224-trimethVlpentane 2-Chlorotoluene 4-Ethyltoluene Acetone Allyl Chloride Benzene Bromodichloromethane Bromoform Bromomethane Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 13-Dichloropropene (cis) Cyclohexane Dibromochloromethane

Identif ication Sample Date

CAS No

71-55-6 79-34-5 76-13-1 79-00-5 75-34-3 75-35-4 120-82-1 95-63-6 106-93-4 95-50-1 107-06-2 156-59-2 156-60-5 78-87-5 76-14-2 108-67-8 106-99^0 541-73-1 87-68-3 106-46-7 540-84r1 95-49-8

622-96-8 67-64-1 107-05-1 71-43-2 75-27-4 75-252 74-83-9 75-15-0 56-23-5 108-90-7 75-00-3 67-66-3 74-87-3

10061-01-5 110-82-7 124-48-1

lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt

lt lt lt lt lt lt lt lt lt lt lt lt

lt

VP-01 8132009

22 28 31 22 16 16 30 20 31 24 16 16 16 19 28 20 89 24 43 24

1 9 21 20 796 13 13 27 41 16 13 25 18 11 20 83 18 52 34

lt lt lt lt lt lt lt lt lt lt lt

lt lt lt lt lt lt lt lt lt lt lt

lt lt lt lt lt lt lt lt lt

lt lt lt lt

VP-02 8132009

218 2 7 5 307 218 162 159 297

bull 197 307 240 162 369 159 185 280 197 89

240 427 240 187 207 197

1880 125 128 268 414 155 125 252 184 106

5910 83 182 138 341

lt lt lt lt lt lt lt

lt lt lt

lt lt lt lt lt lt lt bull

lt lt lt lt

lt lt lt lt lt lt lt lt lt lt lt lt lt lt

VP-03 8132009

218 275 307 218

bull 162 159 297 197 307 240 162

6030 159 185 280 197 89

240 427 240 187 207 197

1750 125 128 268 414 155 125 252 184 106 195 83 182 138 341

Appx A SG Dataxis Page 1 of 2 982009

AR100302

Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility bull Huntington West Virginia

Consti tuent

Volatile Organics (ugm^) Dichlorodifluoromethane Ethylbenzene Methyl ethyl ketone Methyl Isobutyl ketone Methyl tert-butyl ether Methylene chloride n-Heptane jn-Hexane Styrene Tert-butyl alcohol Tetrachloroethene iToluene 13-Dichloropropene (trans) Triehloroethene Trichlorofluoromethane Vinyl bromide Vinyl chloride Xylene (o) Xylenes (mampp)

Sample Identif ication Sample Date

CAS No

75-71-8 100-41-4 78-93-3 108-10-1

1634-04-4 75-09-2

142-82-5 bull 110-54-3

100-42-5 75-65-0 127-18-4 108-88-3

10061-02-6 79-01-6 75-69-4 593-60-2 75-01-4 95-47-6

179601-23-1

lt lt

lt lt lt lt

lt lt

lt

lt lt lt lt lt

VP01 8132009

20 17 23 16 14 14 16

173 17 12 bull

11200 18 18 91 23 18 10 17 17

lt lt lt lt lt

lt

lt lt

lt lt

lt lt lt lt lt

VP-02 8132009

198 174 118 164 144

1520 164 -183 170 121

149000 151 182

2360 225 175 102 174 174

VP-03 8132009

lt 198 lt 174 lt 118 lt 164 lt 144

1160 lt 164

144 lt 170 ltbull 121

90500 lt 151 lt 182

7820 lt 225 lt 175 lt 102

208 387

Appx A SG Dataxis Page 2 of 2 982009

AR100303

APPENDIX B

CALCULATION OF TRANSPORT FACTORS USED TO ESTIMATE INDOOR AIR CONCENTRATIONS

AR100304

APPENDIX B

Calculation of Transport Factors Used to Estimate Indoor Air Concentrations

This appendix presents the methodology for calculating transport factors that are used to convert subslab

vapor concentrations to concentrations in indoor air 124-Trimethylbenzene 12-dichloroethene (cis)

chloroform methylene chloride tetrachloroethene and triehloroethene were identified as contaminants of

concern (COC) for potential vapor intrusion from subslab vapor associated with the Coyne Textile

Services Facility located in Huntington West Virginia (site) In this appendix the transport factors are

calculated to estimate the concentrations of COC in indoor air of the existing plant building located at the

site ~

Transport Factor for Indoor Air

The concentration of a constituent in indoor air (da) is proportional to the concentration of the constituent

in the subslab vapors immediately beneath the building foundation (ie subslab vapor concentration or

Csubsiab) The following equation is used to calculate da from Csubsiab

^ wja ~ ^subslab X I r

where

Cia = concentration of constituent in indoor air (mgm^) -

Csubsiab^ concentration of constituent in subslab vapors (mgm^) and

TF = transport factor from subslab vapors to indoor air

The transport factor (TF) is an infinite source attenuation coefficient andcan be calculated based on a

model developed by Johnson and Ettinger (1991) t he equation for calculating TF is as follows

(Deff X A B ) ( Q B X L T ) X expKQso i l X Lcrabk)(Dcrack X Acrack)]

exp[ (Qsoi l X Lcrack)(Dcrack X Acrack)] + (Deff X A B ) ( Q B X L T ) + (Deff X AB)(Qsoi l X L j ) X (exp [ (Qso i l X Lcrack)(Dcrack X Acrack)] - 1)

where

Deff = effective diffusion coefficient for vadose zone soil (cm^sec)

AB = area of enclosed space below grade (cm^)

QB = building ventilation rate (cm^sec)

LT = distance from contaminant source to building foundation (cm)

Qsoii = volumetric flow rate of vapors into the building (cm^sec)

Lcrack = foundatlon thickness (cm)

Dcrack = vapor diffusion coefficient through crack (cm^sec) and

Acrack = area of cracks through which vapors can pass (cm^)

AR100305

To solve this equation the USEPAs SG-ADV spreadsheet Version 31 most recently updated in

February 2004 was implemented A combination of site-specific factors and default values from the

Users Guide for Evaluating Subsurface Vapor Intrusion Into Buildings (USEPA 2004) were used as input

values in the model All input values are defined below and presented in Tables B-1-A through B-6-A

bull The initial subslab vapor concentration (Csubsiab) is the maximum detected concentration(in units

of ugm ) of samples VP-01 VP-02 and VP-03 that was presented in Table 3 of the report

bull The depth below grade to the bottom of the enclosed space floor (Lp) is set to 15 cm the default

value provided by USEPA (2004) for a slab-on-grade structure

bull The vapor sampling depth below grade (Lg) is a site-specific value The vapor samples were

collected from immediately beneath the building floor therefore Lj has been set to 15 cm

bull The average soilgroundwater temperature (Ts) is set to 125degC the average value for West

Virginia as estimated frorri Figure 8 of the vapor intrusion users guide (USEPA 2004)

bull The soil type used to estimate vapor permeability is assumed to be sandy loam (SL) The

associated soil properties for a sandy loam soil type are as follows the soil dry bulk density (Pb) is

162 gcm the total porosity (n) is 0387 (cm^-aircm^) and the water-filled porosity (nw) is 0103

(cm -HzOcm )

bull The floor thickness (Lcrack) is set to the USEPA (2004) default value of 10 cm

bull The soil-building pressure differential (AP) is set to the USEPA (2004) default value of 40 gcm-s^

bull The building dimensions are siterspecific based on the existing plant building located at the site

The existing structure is approximately 84000 square feet (Dolphin 2000) therefore the

dimensions are set to 8839 cm (290 feet) length by 8839 cm (290 feet) The USEPA (2004)

default value of 244 cm vyas used for the height

bull Thefloor-wall seam crack width (w) is set to the USEPA (2004)-default value of 01 cm

bull The indoor air exchange rate (ER) is set to 083hour This is the value provided by ASTM (2002)

for commercial and industrial buildings

AR100306

Tables B-1-B through B-6-B present the constituent-specific properties for COC that were used in the TF

calculations Tables B-1-C through B-6-C present the intermediate calculations used to determine the

indoor air attenuation coefficients (ie the transport factors) The shaded boxes in Tables B-1-C through

B-6-C also present the resulting TF values that are applied to the concentrations of COC in subslab

vapor and the estimated indoor air concentrations

References

American Society for Testing and Materials (ASTM 2002) Standard Guide for Risk-Based Corrective Action Applied at Petroleum Release Sites ASTM E-1739-95 (Reapproved 2002)

Johnson PC and RA Ettinger (1991) Heuristic model for predicting the intrusion r-ate of contaminant vapors into buildings Environ Sci Technolpgy 25 1445-1452

Dolphin Environmental LLC (Dolphin 2000) Site Characterization Report Mach 14 2000

United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004

AR100307

APPENDIX B-1-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV Nersion31 0204

Reset to Defaults

ENTER -

Chemical CAS No

(numbers only

no dasties)

95636

ENTER Soil gas

cone

Cg (ngm)

Soil Gas Concentration Data ENTER

Soil gas

OR cone

bull - c bull (PPmv)

197E+02

Chemical

124-Trimethylbenzene

MORE ENTER Depth

below grade to bottom

of enclosed space floor

U bull (cm)

ENTER

Soil gas sampling

depth below grade

U (cm) bull

ENTER

Average soil

temperature Ts

CO

1 15 1 1 5 bull125

ENTER ENTER ENTER Totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hft ha he

(cm) (cm) (cm)

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estirnate OR permeability | soil vapor

permeability) k v bull

(cm)

SL 1 1

MORE ENTER

stratum A SCS

soil type

Lookup Soil Parameters

ENTER stratum A soil dry

bulk density P

(gcm)

ENTER Stratum A soil total porosity

(unitless)

ENTER bull stratum A soil water-filled

porosity

(cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

nlaquo

(unitless)

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gchi-s^)

ENTER Enclosed

space floor

length bull LB

(cm)

ENTER Enclosed

space floor

width WB

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

bull Floor-wall seam crack

width w

(cm)

bullENTER

Indoor air exchange

rate ER

(1h) bull

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bidg OR

Leave blank to caicuij

(Lm)

Appx B-1 124-TMBxls 1 of 3 982009

AR100308

APPENDIX B-1-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of ^ bull law constant law constant vaporization at Normal

Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temperature boiling point point temperature weight

D bull Dbdquo H T R bull AHbdquo TB Tc IVIW

Unit risk Reference

factor cone URF RfC

(cms) (cmls) (atm-mmol) CO (calmol) (degK) (degK) (gmol) bull (ugm)- (mgm)

1 606E-02 1 792E-06 1 bull 614E-C3 1 25 1 9369 1 44230 | 64917 1 12020 1 OOE+00 1 60E-03 1

Appx B-1 124-TMBxls 2 of 3 982009

AR100309

APPENDIX B-1-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

(sec)

Source-building

separation

LT bull

(cm) bull

Stratum A soil

air-filled porosity

Q A

Stratum B soil

air-filled porosity

(cmcm) (cmcm)

Stratum C soil air-filled porosity

(cmcm)

Stratum A effective total fluid

saturation

Se

(cmcm)

Stratum A soil

bullintrinsic permeability

^ (cm)

stratum A Stratum A Floor- soil soli wall BIdg

relative air effective vapor seam Soil bull ventilation permeability permeability perimeter gas rate-

kfg ky Xgrack c o n e - QbuHdinpound

(cm) - (cm) (cm) (ngm) (cms)

946E+08 1 0284 0284 0284 0184 596E-09 0901 537E-09 35357 I 197E+02 | 439E+06 |

Area of enclosed

space below grade

As (cm)

Crack-to-total area ratio

1 bull

(unitless)

Crack depth

below grade

Zcfack

(cm)

Enthalpy of vaporization at

ave soil temperature

AHvjs

(calmol) bull

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law constant at

ave soil bull temperature

bull HTS

(unitless)

Vapor bull viscosity at

ave soil temperature

HTS

(gcm-s)

Stratum A

effective diffusion

coefficient

D (cms)

Stratum-B

effective diffusion coefficient

DB (cms)

Stratum C effective diffusion

coefficient

D-c (cms)

Total - overall effective diffusion

coefficient

D ^ (cms)

Diffusion path

length

L-

(cm)

I 787E+07 I 449E-05 | 15 | 11661 260E-03 111E-01 176E-04 I 612E-03 j OOOE+00 | OOOE+00 | 612E-03 j

bull Convection path

length

Lp

(cm)

Source vapor cone

^source

(ngm)

Crack radius

Tcfack

(cm)

Average vapor

flow rate into bIdg

Qsoii

(cms)

Crack effective diffusion

coefficient pcrack

(cms)

Area of CTack

Acack

(cm)

Exponent of equivalent foundation

Peclet number

exp(Pe)

(unitless)

bull bull - bull bull bull bull

1 15 1 197E+02 1 010 1 474E+01 612E-03 bull 354E-t-03 1 336E+09

Infinite source Indoor

~ attenuation coefficient

a

(unitless)

108E-05

Infinite source

btJbldgjJSv-L ^Ppncji3i-

virhpbiiilding bullbull ^lHltti^m)ilg

213E-03

Unit risk

factor

URF

(ngm)-

Reference cone

RfC (mgm)

NA 60E-03 1

I END

Appx B-1 124-TMBxls 3 of 3 982009

AR100310

APPENDIX B-2-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV Nersion31 020^

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

156592

Soil Gas Concentration Data ENTER

Soil gas

cone OR c

(ngm) bull

ENTER Soil bull-gas

cone

c (ppmv)

603E+03 1

Chemical

cis-12-Dichloroethylene

MORE ENTER Depth

below grade to bottom

of enclosed space floor

LF

(cm)

ENTER

Soil gas sampling

depth below grade

U (cm)

ENTER

Average soil

temperature bull Ts

(degC)

1 15 1 bull 15 125

ENTER ENTER ENTER Totalsmust add ijp tb value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hA hB he

bull (cm) (cm) (cm)

15 1 1

ENTER Soil

straturh A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estimate OR permeability | soil vapor

permeability) kv

(cm)

SL 1 |

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

P (gcm)

ENTER Stratum A soil total porosity

bull n

(unitless)

ENTER Stratum A

soil water-filled porosity

(cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

ENTER Stratum B

soil water-filled porosity

ENTER Stratum C

SCS soil type

(unitless) (cmcm)

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure differential

AP

(gcm-s)

ENTER Enclosed bull

space floor

length

LB (cm)

ENTER Enclosed

space floor

width WB

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER

Average vapor flow rate into bIdg

OR Leave blank to calculi

Qsoil

(Lm)

Appx B-2 cis-12-DCExls 1 of 3 982009

AR100311

APPENDIX B-2-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Diffusivity in air

Da

(cms)

Diffusivity in water

Dw (cms)

Henrys law constant at reference temperature

H

(atm-mmoi)

Henrys law constant

reference temperature

bull T R

CC)

Enthalpy of vaporization at

the normal boiling point

AHbdquob

(calmol)

Normal boiling point

TB

(degK)

Critical temperature

Tc (degK)

Molecular weight

MW

(gmol)

Unit risk

factor URF

(ngm)

Reference cone

RfC (mgm)

1 736E-02 1 113E-05 1 407E-03 j 1 25 1 bull 7192 1 33365 1 54400 1 9694 1 OOE+00 j 35E-02 1

Appx B-2 cis-12-DCExls 2 of 3 982009

AR100312

APPENDIX B-2-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

stratum A Stratum B Stratum C Source- soil soil soil

Exposure building air-filled air-filled air-filled

duration separation porosity porosity porosity

T LT ea e^ bull e= (sec) (cm) (cmcm) (cmcm) (cmcm)

I 946E+08n^

Stratum A Stratum A Stratum A Stratum A Floor-effective soil soil soil wall total fluid intrinsic relative air effective vapor seam

saturation permeability permeability permeability perimeter

Ste kj krg ky Acrack

(cmcm) (cm) (cm) (cm) (cm)

Soil gas

cone (ngm)

I 0284 I 0284~ 0284 0184 I 596E-09 | 090T 537E-09 35357 603E+03

BIdg ventilation

rate

JbulldinE

(cms)

439E+06

Area of enclosed

space below grade

AB

(cm)

Crack-to-total

area ratio

n (unitless)

Crack depth below grade

Zltiack (cm)

Erithalpy of vaporization at

ave soil temperature

AHvTs (calmol)

Henryslaw constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law constant at

ave soil temperature

HTS

(unitless) bull

Vapor viscosity at

ave soil bull temperature

HTS

bull (gcm-s)

Stratum A

effective bull diffusion

coefficient

D^A-(cms)

Stratum B

effective bull diffusion

coefficient

D=B

(cms)

Stratum C

effective diffusion bull

coefficient

D=e (cms)

Total overall

effective diffusion

coefficient

DT

(cms)

Diffusion path

length

Ld

(cm)

I 787E+07 I bull449E-05 | 15 bull7709 230E-03 982E-02 176E-04 | 743E-03 | OOOE+00 | OOOE+00 | 743E-03 |

bull bull bull -

Convecfion path -bull

length

Lp (cm)

Source vapor cone

-source

(Mgm)

Crack radius

fcrack

(cm)

Average vapor

flow rate into bIdg

Qaoil bull

(cms)

Crack effective diffusion

coefficient pcack

(cms)

Area of crack

crack

(cm)-

Exponent of equivalent foundation

Peclet number

exp(Pef)

(unitless)

bull

1 15 -1 603E+03 1 010 1 474E+01 743E-03 354E+03 1 697E+07

Infinite source Indoor

attenuation coefficient

poundbullbullbull C t

pound(unitless)

bullsiilaquogt j ii08E-05

Infinite [ source

bIdg cone

Cbujidjng

(pgm)

651 E-02 iKrt

Unit risk

factor

URF

(ngm)-

Reference cone

RfC

(mgm)

NA 35E-02 1

I END I

Appx B-2 cis-12-DCExls 3o f3 982009

AR100313

APPENDIX B-3-A DATA ENTRY SHEET

Coyne Texti le Services - Hunt ington West Virginia

SG-ADV Version 31 0204

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

67663

Soil Gas Concentration Data ENTER ENTER

Soil Soil gas gas

cone OR cone c C

(^gm) (ppmv)

591 E+03

bull

Chemical

Chloroform

MORE ENTER Depth

below grade tb bottom

of enclosed space floor

bull LF

(cm)

ENTER

Soil gas sampling depth

below grade

(cm)

ENTER

Average soil

temperature-Ts

CO bull

1 15 1 15 1 125

ENTER ENTER ENTER Totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

IIA hs he (cm) (cm) (cm)

1 5 bull 1 1

ENTER ENTER Soil - bull

stratum A User-defined SCS stratum A

soil type bull soil vapor (used to estimate OR permeability

soil vapor k

bull permeability) (cm) 1

SL 1 1 bull

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A soil dry

bulk density

Pb (gcm)

ENTER Stratum A soil total porosity

nV (unitless)

ENTER Stratum A

-soilwater-filled bullporosity

Sraquo (cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

(unitless)

ENTER Stratum B

soil water-filled porosity

bull ebdquo=

(cmcm) bull

ENTER Straturri C

SCS bull soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

- c rack

(cm)

ENTER

Soil-bldg pressure

differential AP^

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor

width bull W B

(cm)

ENTER

Enclosed space

height HB

(cm)

ENTER

bull Floor-wall^ seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bidg OR

Leave blank to calculi

Qsoil bull

(Lm)

I -I

Appx B-3 Chloroformxls 1 of 3 982009

AR100314

APPENDIX B-3-B CHEMICALPROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Diffusivity in air

D (cms)

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffijsivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature

Dbdquo H TR A H bdquo TB Tc

(cm s) (atm-m mol) ro (calmol) (degK) (degK)

Molecular weight

MW

(gmol)

Unit risk

factor URF

(ngm)-

Reference cone

RfC

(mgm)

104E-01 100E-05 I 366E-03 25 6988 33432 53640 11938 I 23E-05 | OOE+00

Appx B-3 Chloroformxls 2 of 3 982009

AR100315

APPENDIX B-3-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure

duration

(sec)

Source-

building

separation

LT

(cm)

Stratum A

soil

air-filled

porosity

Sa

( cm cm )

Stratum B

soil

air-filled

porosity

( cm cm )

Stratum C

soil

air-filled

porosity

( c m c m )

Stratum A

effective

total fluid

saturation

( c m c m )

Stratum A

soil

intrinsic

penmeability

k

(cm )

Stratum A

- soil

relative air

permeabil i ty

(cm )

Stratum A

soil

effective vapor

permeability

kv

(cm )

Floor-

wall

seam

perimeter

gtcrack

(cm)

Soil gas

cone

(ngm)

BIdg

venfilation

rate

^buildlriE

(cms)

I 9 4 6 E + 0 8 ~ T I 0284 T 596E-09 I 0-901 I 537E-09 | 35357 | 591 E+03 j 439E+06 | 1 0 284 0284 0184

Area of

enclosed

space

below

grade

A B

( c m )

Crack-

to-total

area

ratio

n

(unitless)

Crack

depth

bull below

grade

^crack

(cm)

Enthalpy of

vaporization at

ave soil

temperature

AHTs bull

(calmol)

Henry s law

constant at

ave soil

temperature

HTS

(a tm-m mol j

Henrys law

constant at

ave soil

bull temperature

HTS

(unitless) bull

Vapor

viscosity at

ave soil-

temperature

^HTS

(gcm-s)

Stratum

A

effective

diffusion

coefficient

(cm s)

Stratum

B

effective

difftjsion

coefficient

D B

(cms) bull

S t ra tum

C

effective

diffusion

coefficient

Dc

(cm s)

Total

overall

effective

bull diffusion

coefficient

D T

(cm s)

Diffi jsion

path

length

Ld

(cm)

I 787E+07 I 449E-05 j - bull 15 7528 210E-03 896E-02 176E-04 I 105E-02 | OOOE+00 | OOOE+00 | 105E-02

Convection

path length

Lp

(cm)

Source

vapor

cone -

^source

- (ngm)

Crack

radius

Tcrack

(cm)

Average

vapor

flow rate

into bidg

Qsoil

(cms)

Crack

effective

diffusion

coefficient Qcrack

bull (cms)

Area of crack

Acrack

(cm)

Exponent of

equivalent

foundation

Peclet number

exp(Pe)

(unitless)

V bull bull

1 15 1 591 E+03 1 010 1 474E+01 105E-02 354E+03 1 355E+05

Infinite

source

indoor

attenuation

coefficient

d

(unitless)

bull 108E-05

Infinite

source

bIdg

cone

^ b u i l d i n g

i (^gm)

bull bull

i 638E-02 -

Unit

risk bull factor

URF

(ngmY

Reference

cone

RfC

(mgm)

~ 23E-05 NA 1

I END

Appx B-3 Chloroform xls 3 of 3 982009

AR100316

APPENDIX B-4-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ersion 31-020^

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

nodashes)

bull 75092

ENTER Soil gas

cone

c (ngm)

Soil Gas Concentration Data ENTER

Soil gas bull

OR cone

bull C

(ppmv)

152E+03

bull bull

Chemical

Methylene chloride

MORE

MORE 4gt

ENTER Depth

below grade to bottom

of enclosed space floor

LF -

(cm)

ENTER

Soil gas sampling depth

below grade

bull U

(cm)

ENTER

Average soil

temperature

Ts bull CC)

bull bull bull bull

1 15 1 15 125

ENTER Totals

Thickness of soil

stratum A h

(cm)

ENTER ENTER must add up to value of Ls (cell F24

Thickness Thickness of soil of soil

stratum B stratum C (Enter value or 0) (Enter value or 0)

he he bull

(cm) bull (cm) -

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(usedto estimate OR perrrieability | soil vapor

permeability)

k bull

(cm)

SL 1 bull 1

ENTER Stratum A

SCS soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

Pb (gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Stratum A

soil water-filled porosity

9w (cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

Pb^

(gcm)

ENTER Stratum B soil total porosity

n^

(unitless)

ENTER Stratum B

soil water-filled porosity

(crhcm)

ENTER Stratum C

SCS soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE 4gt

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

bull Soil-bldg pressure

differential AP^

(gcm-s)

ENTER Enclosed

space floor

length LB

(cm)

ENTER Enclosed

space floor

width bull W B

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width

w

(cm)

ENTER

Indoor air exchange

rate

ER (1h)

ENTER Average vapor

flow rate into bidg OR

Leave blank to calculc

Qsoil

(Lm)

10 40 8839 8839 244 01 083

Appx B-4 MCxIs 1 of 3 982009

AR100317

Diffijsivity in air

D

APPENDIX B-4-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffusivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature

Pw H TR AHt TB TC

Molecular weight

MW

Unit risk

factor URF

Reference cone

RfC

(cms) (cms) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) bull (ngm)- (mgm)

bull bull

1 101E-01 1 117E-05 1 218E-03 1 25 | 6706 1 31300 1 51000 1 8493 1 47E-07 1 30E+00 1

Appx B-4 MCxIs 2 of 3 982009

AR100318

APPENDIX B-4-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

T

(sec)

Source- -building

separation

LT

(cm)

Stratum A soil

air-filled porosity

e a bull

(cmcm)

Stratum B soil

bullair-filled porosity bull

ea^ (cmcm)

Stratum C soil

air-filled porosity

ea= (cmcmj

Stratum A effective total fluid

saturation

Sc bull

(cmcm)

Stratum A soil

intrinsic pemneability

ki (cm)

Stratum A soil

relative air permeability

^ ^ g

(cm)

stratumA bull soil effective vapor permeability

K (cm)

Floor-wall

seam perimeter

Xcrack

(cm)

Soil gas

cone (ngm)

BIdg ventilation

rate

Qbuildinc

(cms)

1 946E+08

Area of -enclosed

space below

bull grade

AB

(cm)

1

Crack-to-total

area rafio

Tl

(unitless)

0284 1

Crack depth below grade

Zcrack

(cm)

0284 1

bull Enthalpy of vaporization at

ave soil temperature

AHTs (calmol)

0284

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

0184

Henrys law constant at ave soil

temperature

HTS

bull (unitless)

1 596E-09

Vapor viscosity at

ave soil temperature

Mrs (gcm-s)

0901

Stratum A

effective diffusion

coefficient

D (cms)

537E-09

Stratum B

effective diffusion

coefficient

D-B (cms)

35357 1

Stratum C -

effective diffusion

coefficient

D-c ^ (cms)

152E+03

Total bull overall

bull effective diffusion

coefficient

D ^

(cms)

440E+06 1

Difftjsion path

length

Ld (cm)

1 787E+07

Convection path

length

Lp (cm)

4 49E-05

Source vapor cone

Csource

(ngm)

15 1

Crack radius

Tcrack

(cm)

7007 bull 1

Average vapor

flow rate intobldg

Qsoil

(cms)

130E-03

Crack effective diffusion

coefficient pcrack

(cms)-

555E-02

bull ^

Area of crack

Acrack

(cm) bull

1 176E-04

Exponent of equivalent foundation

Peclet number

exp(Pe)

(unitless) bull

bull bull

1 15

1 END

152E+03 010 1 474E+01 1 102E-02 354E+03 1 519E+05

102E-02

Infinite source

indoor ^attenuation coefficient

bull a

(unitless)

aiii08E-05

0 OOE+00

bull

Infinite bull source

bIdg ^ cone

^bu i l d i ng

(MQm)

164E-02

OOOE+00 1

Unit risk

factor

URF

(ngm)-

47E-07 1

102E-02 j

Reference cone

RfC

(mgm)

30E+00 j

1 1

Appx B-4 MCxIs 3 of 3 982009

AR100319

APPENDIX B-5-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ^erslon 31 0204

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

127184

Soil Gas Concentration Data ENTER ^ ENTER

Soil -Soi l bull gas gas

cone OR cone Cg C bull

(tgm) (ppmv)

149E+05 1

Chemical

bull Tetrachlbroethylene

MORE 4

ENTER Depth

below grade to bottom

ofenclosecJ space floor

LF

(cm)

ENTER

Soil gas bull sampling

depth below grade

u bull (cm)

ENTER

Average bullsoil

temperature - Ts

ro 1 1 5 1 15 1 125 bull

ENTER ENTER ENTER totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hft bull he bull he

(cm) (cm) (cm)

bull 1 5 1 - 1

ENTER ENTER Soil

stratum A User^defined bull SCS bull stratum A soil type soil vapor

(used to estimate OR perrrieability soil vapor K bull

permeability) (cm) 1

SL 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

Pb

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Sitratum A

soil water-filled bull porosity

(cmcm)

ENTER Stratum B

SCS soiltype

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

Pb^

(gcm)

ENTER Stratum B soil total porosity

Ajnitless^

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS soil type

LookupSoil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

VS

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor width

W B

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width

w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

ENTER Average vapor

flow rate into bidg OR

Leave blank to calcul

bull Qsoil

(Lm)

10 40 8839 8839 244 01 083

Appx B-5 PCExIS 1 of 3 982009

AR100320

APPENDIX B-5-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal Unit

Diffusivity Diffusivity at reference reference the riormal boiling Critical Molecular risk Reference in air in water temperature temperature boiling point point teriiperature weight factor cone

Da Dbdquo H TR AHb TB Tc MW URF RfC

(cms) (cnis) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) (^gm)- (mgm)

1 720E-02 1 820E-06 1 184E-02 1 25 1 8288 1 39440 1 62020 1 16583 1 59E-06 1 60E-01 1

J

AppxB-5PCExls 2 of 3 - 982009

AR100321

APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

T

(sec)

Source-building

separation

LT

bull (cm)

Stratum A soil

air-filled porosity

Oa (cmcm)

Stratum B - soil air-filled porosity

ea (cmcm)

Stratum C soil

air-filled porosity

ea= - (cmcm)

Stratum A effective total fluid

saturation

sbdquo (cmcm)

Stratum A soil

intrinsic permeability

ki (cm)

Stratum A soil

relative air permeability

- ^ g

(cm)

Stratum A soil

effective vapor permeability

kv (cm)

Floor-wall

seam perimeter

^crack

(cm)

Soil gas

cone

(ngm)

BIdg venfilation

rate

Qbuildins

bull (cms)

bull bull

1 946E+08

Area of enclosed

space below grade

AB

(cm)

1

bullCrack-to-total

area ratio

1 (unitless)

0284 1

Crack bull depth below grade

Zcrack

(cm) -

0284 1

Enthalpy of vaporization at bull

ave soil temperature

bull A H V TS

(calmol)

0284

Henrys law constant at

ave soil temperature

HTS (atm-mmol)

0184

-Henrys law constant at

ave soil temperature

HTS

(unitless)

1 596E-09

Vapor viscosity at

ave soil temperature

HTS

(gcm-s)

0901

Stratum A

effective diffusion

coefficient bull D = bull

(cms)

537E-09

Stratum B

effective diffusion

coefficient

D--B (cms)

35357 1

Stratum C

effective diffusion bull

coefficient

D-c (crris)

149E+05

Total overall

effective bulldiffusion coefficient

DT

(cms)

440E+06 1

Difftjsion path

length

U (cm)

1 787E+07

Convection path

length

bull Lp

(cm)

4 49E-05

Source vapor cone

^source

(ngm)

15 1

Crack radius

Tcrack

(cm)

9528 1

Average vapor

flow rate intobldg

Qsoil (cms)

908E-03

Crack effective diffusion

coefficient pcrack

bull ( c m s ) bull

387E-01

Area of crack

Abdquoack (cm)

1 176E-04

Exponent of equivalent foundafion

Peclet number

exp(Pe)

(unitless)

bull

1 15-

1 END

149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08

727E-03

Infinite source indoor

attenuation coefficient

a

(unitless)

108E-05

OOOE+00

Infinite source

bIdg cone

Cburldtng

(Mgm)

161 E+00

OOOE+00 1

Unit risk

factor

URF

(ugm)-

59E-06 1

727E-03

Reference cone

RfC (mgm)

60E-01

1 1

Appx B-5 PCExls 3 of 3 982009

AR100322

APPENDIX B-6-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ersion31 0204

Reset to Defaults

t

Soil Gas Concentration Data ENTER

Chemical CAS No

(numbers only

no dashes)

79016

ENTER ENTER Soil Soil gas gas

cone OR cone C C -

bull (ngm) (ppmv)

782E+03

Chemical

Trichloroethylene

MORE ENTER Depth

below grade to bottom-

of enclosed space floor

LF

(cm)

ENTER

Soil gas sarnpling

depth below grade

U (cm)

ENTER

Average soil

temperature Ts

(degC)

1 15 1 15 t 125

ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e

(cm) (cm) (cm)

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estimate OR permeability soil vapor

permeability)

k (cm)

bull S L 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil bull-Parameters

ENTER Stratum A

soil dry bulk density

P b -

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Stratum A bull

soilwaterrfilled porosity

(cmcm) bull

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

bull P ^ (gcm)

ENTER Stratum B soil total

porosity

nlaquo

(unitless) -

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS bull soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor

width W B

(cm)

ENTER

Enclosed space height

H B bull

( c m ) bull

ENTER

Floor-wall seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bIdg OR

Leave blank to calculc

Qsoil

(Lm) -

Appx B-6 TCExIs 1 of 3 982009

A

AR100323

APPENDIX B-6-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight

Da Dbdquo H TR AH^b TB TC MW

Unit risk Reference

factor cone URF RfC

(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)

1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1

Appx B-6 TCExIs 2 of 3 982009

AR100324

APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

(sec)

Source-building

separation LT

(cm)

Stratum A soil

air-filled porosity

bull ea (cmcm)

Stratum B Soil

air-fllled porosity

e^ bull (cmcm)

Stratum C soil

air-filled porosity

(cmcm)

StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air

saturation permeability permeability

S|e k krg (cmcm) (cm) (cm)

Stratum A Floor-soil wall BIdg

effective vapor seam Soil ventilafion permeability perimeter gas rate

k^ bull Xack c o n e Qbuildins

(cm) (cm) (ngm) (cms)

946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |

Area of enclosed

space below grade

AB

(cm)

Ciack- to-total

area ratio

1 (unitless)

Crack depth below grade

Zcrack

(cm)

Enthalpy of vaporization at

ave soil temperature

A H J S

(calmol)

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law bull constant at

ave soil temperature

HTS

(unitless)

Vapor viscosity at

ave soil temperature

|JTS

(gcm^s)

Stratum A

effective diffusion

coefficient

(cms)

Stratum B

effective -diffusion

coefficient

D=B (cms)

Stratum ^ C effective diffusion

coefficient

D=c (cms)

Total overall

effective diffusion

coefficient

DT

(cms)

I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03

Diffusion path

length

Li (cm) bull

Convection bull path

length

Lp

(cm)

Source vapor cone bull

^source

(ngm)

Crack radius

rcrack

(cm)

Average vapor

- flow rate intobldg

Qsoil

(cms)

Crack effective diffusion

bull coefficient Qcrack

(cms)

Area of crack

^crack

(cm)

Exponent of equivalent foundation

Peclet bull number

exp(Pe)

(unitless)

bull bull

1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07

Infinite source Indoor

attenuation coefficient

a

(unitless)

108E-05

Infinite source

bIdg concgt

^building

(ngm)

844E-02

Unit risk

factor

URF

(ngm)-

Reference cone

RfC

(mgm)

1 1E-04 1 40E-02 1

END

Appx B-6 TCExIs 3 of 3 982009

AR100325

Office of Waste Management 1356 Hansford Street

Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256

West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director

ORDER

ISSUED UNDER THE

HAZARDOUS WASTE MANAGEMENT ACT

CHAPTER 22 ARTICLE 18

OF THE WEST VIRGINIA CODE^ AS AMENDED

y Order Number HW-011-80

To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704

ATTEMTION MREDARMON

Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull

AR100326

ViWJ011-laquo9 PageNunil)er2

BASIS FOR ORDER

As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following

A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^

B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator

C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities

0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94

^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement

P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following

1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater

2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was

^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment

CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable

CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order

AR100327

H W - 0 1 1 - 9 9 Page Number 3

REQUIREMENTS OF ORDER

Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows

1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^

2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore

remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling

GENERAL PROVaiONS

1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order

2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order

3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order

Effective Date

Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief

Wt T 1 V Oflice of Waste Management

AR100328

^ ^ S I S

^wmmmmamn

AR100329

Page 2: SDMS DocID 2121999 · International Enterprises Corp. building (Coyne Building), which is located at 1111 Vernon Street, Westmoreland District, Wayne County, West Virginia. The following

AR100279

shows contamination on the adjacent property bull The Consent Order

Let me know if Bob needs additional information to get started Thanks Joe

[ABhil Iiutii KWt1 [bullbull^tettl

MW-5 data trendspdf 04-08-0408 Groundwater Sampling Letter Reportpdf Coyne VI Memo_09-08-08pdf Order No HW-011-99pdf

AR100280

n nnp

n n n i -

n nnt^ -

n nnt -

n nriA -

0003 -

n nn

n nni -

n -

^ ^ bull

1 2 4 bull 5

TCE 307 - 309

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17

PCE 3 01-3 09

003

0005

Cis 12 DCE 301 - 309

AR100281

CIVIL bull ENVIRONMENTAL AND GEOTECHNICAL ENGINEERING

4980 Teays Valley Road Scott Depot WV 25560 Phone 3047550721 Fax 3047551880 TRIAD ENGINEERING INC

October 24 2008

Mr Robert Trocin Wayne County Economic Development Authority PO Box 519 Wayne VVest Virginia 25570

Subject Groundwater Assessment Former Coyne International Enterprises Corp Building Westmoreland District Wayne County West Virginia

Dear Mr Trocin

On behalf of the Wayne County Economic Development Authority (WCEDA) Triad

Engineering Inc conducted a focused groundwater assessment at the former Coyne

International Enterprises Corp building (Coyne Building) which is located at 1111 Vernon

Street Westmoreland District Wayne County West Virginia The following summarizes

field activities and analytical results of this assessment Figure 1 Site Location Map

illustrates the location of the site

On October 32008 five temporary groundwater hionitoring points were installed using a

direct-push technology sampling unit A groundwater sample was collected from each

monitoring point and analyzed by a WVDEP certified laboratory for VOC as per United

States Environmental Protection Agency (USEPA) method SW-8260B Three monitoring

points were installed in the area of groundwater monitoring well MW-5 between the Coyne

Building and the CSX Transportation inc rail line and two monitoring points were installed

to the immediate north of the CSX Transportation Inc rail line Groundwater was

encountered at a depth of approximately 30-feet below ground surface (bgs) Figure 2

Sample Location Map illustrates the locationof the groundwater monitoringpoints and

physical features located within the sample area

WWWTRIADENGCOM

Practical Engineering and Science Solutions Since 1975

AR100282

Wayne County Economic Development Authority Groundwater Assessment Coyne TextileServices Building Westmoreland District Wayne County West Virginia October 24 2008 -

Page 2

FIGURE 1 SITE LOCATION MAP Huntington WVa USGS 75-minute Topographic Quadrangle

1985

Laboratory analytical results were compared to the applicable WVDEP groundwater

maximum contaminant level (MCL) or de mnms values listed in Table 60-3 effective June

26 2008 Concentrations of VOC which exceeded the de minimis values were identified in

5 of 5 groundwater samples collected Tetrachloroethene (PERC) was detected in each of

the groundwater samples at concentrations which exceeded the de minimis values

Triehloroethene was detected in samples collected from GP-1 GP-3 and GP-5 at

concentrations which exceeded the de minimis values Cis-12-Dichloroethene was detected

in samples collected from GP-1 and GP-3 at concentrations which exceeded the de minimis

values Vinyl Chloride was detected in each sample except GP-5 at concentrations which

exceeded the de minimis values A summary of laboratory analytical reports is provided in

Table 1 Laboratory Analytical Summary-Groundwater and copies of the Laboratory

Analytical Reports are included as Attachmenf 1

AR100283

(9

00 S

P B B K ftVENIjEl

WEST MORELAND PARK

TENNIS BASKETBALL COURTS

GP-5 GP-4

9-inn i in iMMIMII I IMMII I I I I I I I IMI I I I I I IMI I I IMMII I I I I I I I I IMMII I I I I I IMI I I I I I I I I I I I IMI I I I I I I I I I I IMMII I I IMIMIMII I I I I I I I I I IMI I I I I I I I IMI I I I

CSX RAILROAD GP-2 GP-1 GP-3 I I I I I I I IMI I I IMMI I IMI I I I I I IMIMI I I IMI I I I I I I I I in i l lMI IMIMI I I I I IMMI I I I I I Jd I I IMj r i i y i l lMMI I I IMI I I I I I I I I in i l l l l l l lM l l l l l l l i n i l l l l l l l l ijj^lll^flH|t

bull

ACCESS ROAD

BUILDING

- bull

G P X ^

MM ^

MW

4-

bull ^

LEGEND

CW SAMPLE LOCAT10

MONITORING WELL

gtl

n

PARK ING

SCALE 1 r bull

WCEDA VRP GROUNDWATER SAMPLINGS HUNTINGTON WEST VIRGINIA

F I G U R E tslD

Cad Files04-08-p408-1dgn 6122009 24625 PM

- AR100284

Wayne County Economic Development Authority Page 3 Groundwater Assessment Coyne Textile Services Building Westmoreland District Wayne County West Virginia October 24 2008 _ bull ^

We appreciate the opportijnity to assist you with this project If you have any questions or r

need additional information please feel free to contact us

Sincerely TRIAD ENGINEERING INC

Matthew C Wright

Project Geologist

JohnM Meeks PG LRS

Project Manager

end

^

AR100285

Table 1 Laboratory Analytical Summary - Groundvvater WCEDA Vernon street

Huntington Wayne County West Virginia

COPC

Acetone Benzene Bromobenzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone sec-Butylbenzene n-Butyibenzene tert-Butylbenzene Carbon disulfide Carbon Tetrachloride Chlorobenzene Chlorodibromorriethane Ghloroethane Chlbroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene 12-Dibromo-3-chloropropane 12-Dlbronnoethane (EDB) DIbromomethane 14-Dichlorobenzene 13-Dictilorobenzene 12-Dictilorobenzene Dichlorodifluoromethane 11-Dlchloroethane 12-Dichloroethane cis-12-Dichloroethene

MCL ugL

5500 5

NV NV NV 85 87

700 61 61 61

1000 5

100 NV 39

bull 017 190 NV NV 02

005 NV

750 600 600 390 910

5 70

GP-1 ugL ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND

ND ND ND ND ND ND ND ND ND ND ND ND 112 ND

5210

GP-2 ugL ND ND ND

ND ND ND ND ND ND ND ND ND ND ND ND ND ND

062 J ND ND ND

ND ND ND ND ND ND ND ND

379

GP-3 ^ ugL

ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND

065 J ND 184 ND( ND ND ND

ND ND ND ND ND ND ND

12500

GP-4 ugL ND ND ND ND ND

- ND ND ND ND ND ND ND ND ND ND ND ND ND

ND ND ND ND ND ND ND ND ND ND ND 132

GP-5 ugL ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND

ND ND ND ND ND ND ND ND ND ND ND ND 59

Notes - Bold Indicates COPCs detected at concentrations greater than the MCL bull(60CSR3 Table 60-3B July 2008)

NAME - J indicates analyte detected at levels less than the reporting limit and greater than

or equal to the MDL value is estimated -NV indicates no value has been established

AR100286

Table 1 Laboratory Analytical Summary - Groundwater (Continued) WCEDA Vernon street

Huntington Wayiie County West Virginia

COPC

11-Dichloroethene trans-12-Dichloroethene 13-Dichloropropane 12-Dichloropropane 22-Dichloropropane cis-13-Dichloropropene trans-13rDichloropropene 11-Dichloropropene Ethylbenzene Hexachlorobutadiene 2-Hexanone Isopropylbenzene p-lsopropyltoluene Methyl tert-Butyl Ether Methylene Chloride 4-Methyl-2-pentanone Naphthalene n-Propylbenzene Styrene 1112-Tetrachloroethane 1122-Tetrachloroethane Tetrachloroethene Toluene 123-Trichlorobenzene 124-Trichlorobenzene 112-Trichloroethane 111-Trlchloroethane Triehloroethene Trichlorofluoromethane 123-Trichloropropane 135-Trimethylbenzene 124-Trimethylbenzene Vinyl chloride Xylenes total s

MCL ugL

91 100 04

5 NV NV NV NV

700 086

NV NV

NV 028

5 NV 62 NV 100

043 0055

5 1000

NV 70

5 20

5 1300

0034 120 120

2 10000

GP-1 ugL 964 458 ND ND

ND ND ND ND

052 J ND ND ND ND ND ND ND ND ND ND ND ND

14700 065 J ND ND ND ND

2850 ND

ND ND ND 116 146 J

GP-2 ugL ND ND ND ND ND ND ND- ND ND ND ND ND -ND ND ND ND ND ND ND ND ND

603 ND ND ND ND ND

079 J ND ND ND ND 242 ND

GP-3 ugL 346 865 ND ND

bull ND ND ND-ND

055 J ND ND ND ND ND ND ND ND ND ND ND ND

13900 159 ND ND ND ND

4870 ND ND ND ND 708 149 J

GP-4 ugL ND ND ND ND ND ND ND ND ND ND ND

ND 177 ND ND ND ND ND ND ND ND

583 ND ND ND ND ND

082 J ND ND ND ND

227 ND bull

GP-5 ugL ND ND ND ND ND

ND ND ND ND ND ND ND ND

ND ND ND ND ND ND ND ND 133 ND ND ND ND ND

574 ND ND

ND ND 122 ND

Notes - Bold indicates COPCs detected at concentrations greater than the MCL

(60CSR3 Table 60-3B July 2008) - ND indicates non-detected at concentrations greater than the MCL - J indicates analyte detected at levels less than the reporting limit and greater than

or equal to the MDL value is estimated - NV indicates no value has been established

AR100287

Risk-Based Rerfiedies

R B R Consulting Inc 650 Shady Drive Beaver Falls PA 15010

Phone724-846-4096 Fax 724-846-6974

MEMORANDUM

TO John Meeks Triad Engineering Inc

FROM Bruce Fishman

DATE September 82009

SUBJECT Evaluation of Potential Risks Associated with Vapor Intrijsion to Indoor Air Coyne Textile Services Facility - Huntington West Virginia

bull V bull bull bull

This memorandum presents a risk evaluation for potential risks associated with vapor intrusion to indoor air at the Coyne Textile Services Facility located in Huntington West Virginia (site) This evaluation was conducted according to West Virginia Department of Environmental Protection (WVDEP) and United States Environmental Protection Agency (USEPA) methodologies

DATA INCLUDED 1N THE EVALUATION

This evaluation includes three subslab vapor samples (VP-01 VP-02 and VP-03) collected from immediately beneath the floor of the existing site building Table 1 lists the subslab vapor samples included in this risk assessment Samples were analyzed for volatile organic compounds (VOCs) by USEPA Method TO-15 Complete analytical data for these samples are provided in Table A-1 of Appendix A

The analytical results of the subslab vapor samples were compared to the target shallow soil gas comparison values presented in Table 2c of the USEPA vapor intrusion guidance document (2002a) These companson values are generic soil gas screening values that are protective of indoor air for residential land uses and represent concentrations in-sliallow soil gas based on a target risk level of 1 x 10reg andor a hazard index of 1 The comparison is presented in Table 2

As indicated in Table 2 the following constituents are identified as contaminants of concern (COC) for the vapor intrusion to indoor air pathway 124-trimethylbenzene 12-dichloroethene (cis) chloroform methylene chloride tetrachloroethene and triehloroethene

ESTIMATION OF INDOOR AIR CONCENTRATIONS

The concentrations of COC in indoor air associated with vapor intrusion from subslab vapor were estimated using methodologies outlined in the Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings (USEPA 2004) A transport factor (TF) is required that will relate the

Page 1 of 5 -

AR100288

Risk-Based Remedies

R B R Consulting Inc

constituent concentration in subslab vapor to the concentration in indoor air The TF is dependent on the diffusion coefficient and other properties that will affect the transfer of constituents into air such as distance from the source to tlie breathing zone soil properties and building properties A site-specific building size of 84000 square feet (Dolphin 2000) and a soil type of sandy loam were used in the calculation of TF The TF is determined using calculationsbased on the Johnson and Ettinger (1991) vapor intrusion model Details of the TF calculations are provided in Appendix B

Subslab vapor concentrations are converted to indoor air concentration by applying the TF as follows

Cja ^ Csubslab X I r

The TF for each COC along with the resulting concentrations of COC in indoor air are presented in Tables

EXPOSURE EVALUATION

Noncarcinogenic health effects are evaluated by calculating the average dose of a constituent over the course of the exposure period This dose is termed the Average Daily Dose (ADD) Potential carcinogenic health effects are evaluated in terms of an individuals theoretical increased risk of developing cancer over a lifetime Although the duration of exposure to a constituent release generally does not last for an entire lifetime constituent intake for carcinogens is estimated as the average dose over a human lifetime (70 years) This lifetime dose applies specifically to the evaluation of carcinogenic effects and is termed tine Lifetime Average Daily Dose (LADD) In a risk assessment the calculated ADD or LADD are estimated quantitatively using assurnptions about the duration frequency and magnitude of exposure experienced by each potential receptor and assumptions about the constituent properties that influence absorption

The quantitative estimation of constituent intake involves the incorporation of numerical assumptions for a variety of exposure parahneters Exposure assumptions used in these intake calculations are based on WVDEP (2001) or USEPA (1989 2002b) recommended values The factors and equation for inhalation of vplatiles is presented in Table 4 and described below

bull Inhalation Rate and Exposure Time WVDEP (2001) and USEPA (2002b) guidance recommend that an inhalation rate of 20 m day be used for workers For an exposure time of 8 hours (a typical workday) this results in an inhalation rate of 25 m hour

bull Exposure Frequency and Duration Default exposure factors for indoor workers are provided by WVDEP (2001) Exposure frequency for the worker is 5 days per week for 50 weeks a year or 250 days per year The exposure duration for these workers is 25 years which is the 95th percentile value ai cording to the Bureau of Labor Statistics (USEPA 1989)

bull Body Weight The default value for average body weight of an adult is 70 kg based on WVDEP (2001) and USEPA guidance (1989 2002b)

Page 2 of 5

AR100289

Risk-Based Remedies

R B R Consulting Inc

bull Averaging Time As described above the doses for noncarcinogenic health effects are averaged oyer the specific period of exposure for a given receptor Noncarcinogenic

averaging times are therefore calculated by multiplying the exposure duration for the receptor by 365 daysyear Carcinogenic health effects are calculated over a lifetime exposure so the value recommended by WVDEP (2001) and USEPA (2002b) for average lifetime 70 years was used for exposure duration The resulting carcinogenic averaging time is 25550 days

TOXICITY VALUES

Noncarcinogenic responses are evaluated numerically using parameters known as the hazard quotient (HQ) and hazard index (HI) the HQ is obtained by dividing the ADD for a constituent by the reference dose (RfD) Each dose calculation with a specific combination of constituent receptor and exposure pathway will have a distinct ADD and calculated HQ HQs associated with all constituents for a particular pathway are summed to yield the HI

In order to estimate the theoretical excess lifetime cancer risk the LADD of a constituent is multiplied by the cancer slope factor (CSF) For each pathway this calculation is carried out for each applicable constituent and the risks are summed to obtain the total potential risk due to that pathway

Toxicity values for each constituent are presented in Table 5 the toxicity values were obtained from the following sources

bull Integrated Risk Information System (IRIS) on-line database provided by USEPA (2009)

bull The USEPAs Provisional Peer-Reviewed Toxicity Values (PPRTV) as presented in the USEPA Regional Screening Tables (ORNL 2009)

bull Provisional value from the National Center for Environmental Assessnient (as per WVDEP)

bull The Agency for Toxic Substances and Disease Registrys (ATSDR) Minimal Risk Levels (MRLs ATSDR 2009) and

bull Value cited by USEPA Region 3 attributed to other sources (as per WVDEP)

RISK CHARACTERIZATION

Potential noncarcinogenic effects associated with exposure to COC at the site are estimated by comparing calculated intakes with the contaminant-specific RfDs The total HI was calculated by summing the individual HQs An HI value equal to or less than 1 indicates thatthelikelihopd of ah adverse noncancer effect would be negligible (USEPA 1989) An HI greater than 1 indicates that additional evaluation of the case is warranted

Theoretical excess lifetime cancer risks associated with exposure to COC from the site were calculated by comparing estimated intakes to constituent-specific CSFs Summed theoretical

Page 3 of 5

AR100290

Risk-Based Remedies

R B R Consulting Inc

excess risks are calculated by combining constituent-specific risks The results may be compared with target benchrharks for acceptable risk Various demarcations of acceptable risk have been established by regulatory agencies WDEP (2001) presents a target cancer risk of 1 x 10 for nonresidential scenarios USEPA (1991) considers potential cancer risks in the range of 1 x 10reg to 1 X 10 to be acceptable

Constituent-specific results for the indoor worker are presented in Table 6 For the indoor worker exposed to COC in indoor air (vapor intrusion from subslab vapor) the total HI is 00081 and the potential cumulative cancer risk is 497 X 10reg

These results meet both WVDEP and USEPA benchmarks indicating that the site poses negligible potential for human health risk for indoor workers

CONCLUSIONS

The results of this focused risk evaluation indicate that potential risks associated with vapor intrusion exposure of indoor workers to constituents that may volatilize from subslab vapor are within the acceptable benchmarks established by WVDEP and USEPA No further evaluation of the vapor intrusion pathway is warranted for the site

REFERENCES

Agency for Toxic Substances and Disease Registry (ATSDR 2009) Minimal Risk Levels (MRLs) Available at httpvtfwwatsdrcdcqovmrisindexhtml

Dolphin Environmental LLC (Dolphin 2000) Site Characterization Report Mach 14 2000

Johnson PC and RA Ettinger (1991) Heuristic model for predicting the intrusion rate of contaminant vapors into buildings Environ Sci Technology 25 1445-1452

Oak Ridge National Laboratory (ORNL 2009) Regional Screening Levels for Chemical Contaminants at Superfund Sites April 15 2009 Available online httpwwwepagovreg3hwmdriskhumanrb-concentration_tableindexhtm

United States Environmental Protection Agency (USEPA 1989) Risk Assessment Guidance for Superfund Volume I PartA Human Health Evaluation Manual EPA5401-89002

United States Environmental Protection Agency (USEPA 1991) Risk Assessment Guidance for Superfund Volume I Part B Development of Risk-Based Remediation Goals Office of Emergency and Remedial Response OSWER Directive 92857-018

United States Environmental Protection Agency (USEPA 2002a) Draft Guidance for Evaluating the Vapor Intrusion to Indoor Air Pathway from Groundwater and Soils Office of Solid Waste and Emergency Response Pub No 92856-10 December 2002

Page 4 of 5

AR100291

Risk-Based Remedies

R B R Consul t ing Inc

United States Environmental Protection Agency (USEPA 2002b) Supplemental Guidance for Calculating Soil Screening Levels for Superfund Sites Office of Solid Waste and Emergency Response December

United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004

United States Environmental Protection Agency (USEPA 2009) Integrated Risk Information System (IRIS) On-line database wwwepaqoviris

West Virginia Department of Environmental Protection (WVDEP 2001) West Virginia Voluntary Remediation and Redevelopment Act-Guidance Manual Version 21 March 13

Page 5 of 5

AR100292

TABLES

AR100293

TABLE 1 SUBSLAB VAPOR SAMPLES INCLUDED IN THE RISK ASSESSMENT

Coyne text i le Services Facility - Huntington West Virginia

Medium

Subslab Vapor

Sample Identification

bull VP-01

VP-02

VP-03

Sample Date

8132009

8132009

8132009

Coyne VIMemo Tables_09-08-09xls 982009

AR100294

TABLE 2 IDENTIFICATION OF CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR

Coyne Textile Services Facility - Huntington West Virginia

mdash

Const i tuent

Volati le Organics

111-Trichlor6ethane

1122-Tetrachloroethane

112-Trichloro-122-trifluoroethane

112-Trichloroethane

11-Dichloroethane

11-Dichloroethene

124-Trichlorobenzene

124-Trimethylbenzene

12-Dibromoethane

12-Dichlor6benzene

12-Dichloroethane

12-Dichloroethene (cis)

12-pichloroethene (trans)

12-Dichloropropane

12-Dichlorotetraf1uoroethane

135-Trimethylbenzene

13-Butadiene

13-Dichlorobenzene

13-Hexachlorobutadiene

14-Dichlorpbenzene

224-trimethylpentane

2-Chlorotoluene

4-Ethyltoluene

Acetone

Allyl Chloride

Benzene

Bromodichloromethane

Bromoform

Bromomethane

Carbon disulfide bull

Carbon tetrachloride

ChJorobenzene

Chloroethane

Frequency of Detection

0 3

0 3

0 3

bull 0 3

0 3

0 3

0 3

1 3

0 3 bull

0 3

b 3 bull

2 3

0 3

bull 0 3

0 3

0 3

0 3 bull

0 3

0 3

0 3

0 3

0 3

0 17

3 3

0 3

P 3

- 0 3

0 3

0 3

0 3

0 3

0 3

0 3

Min imum Detected

Concentrat ion

(ugm^)

ND

ND

ND

ND

ND

- ND

N D

197

ND bull

ND

ND

369

ND

bull~ ND

ND

ND

ND

ND

ND

bull ND

ND

ND

ND

796

ND

ND

ND-

ND

ND

ND

ND

ND

ND

Maximum

Detected Concentrat ion

(ugm3)

ND

ND

ND

ND

ND

ND

ND

197

ND

ND

ND

mdash 6030

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

1880

ND-

ND

ND

ND

ND

ND

ND

ND

ND

Sample wi th Maximum Detect

ND

ND

ND

ND

ND

ND

- ND

VP-03 -

ND

ND

ND

VP-03

ND

bullND

ND

ND

ND

ND

ND

ND

ND

ND

ND

VP-02

ND

ND bull

ND

ND

ND bull

bull ND

ND

ND

ND

Min imum Detection

Limit (ugm3)

22

28

31

22

16

16

30

20

31

24

16

bull 16

16

19

28

20

89

24 bull

43

24

bull 19

2 1

20

--^ 13

13

27

41

16

13

25

18

11

Maximum Detection

Limit (ugm3)

218

275

307

218

162

159

297

197

307

240

162

- 16

159

185

280

197

89

240

427

240

187

207

197

--125

128

268

414

155

125

252

184

106

Vapor Intrusion Corhparison

V a l u e

(ugm)

22000

042

300000

15

bull 5000

2000

2000

60

011

2000

094

350

700

40

NA

60

0087

1100

11

8000

NA

NA

NA

3500

NA

31

14

22

50

7000

16

bull 600

100000

Chemical of Concern

No

No

No

No

No

No

No

YES

No

No

No

YES

No

No

No

N o bull

bullNo

No

No

No

No

No

No

N o

No

No

No

N o

No

No

No

No

No

Comment

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent notdetected

fflaximCimTdeteetlSffieedsTcomDarisonivalues

Constituent not detected

Constituent not detected

Constituent not detected

Maximum detect exceeds comparison value

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Maximum detect below comparison value

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detectedl

Constituent not detected

Constituent not detected

CoyneVI Memo Tables_09-08-09xls 982009

AR100295

TABLE 2

IDENTIFICATION OF CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR

Coyne Textile Services Facility - Huntington West Virginia

Const i tuent

Volati le Organics

Chloroform -

Chloromethane

13-Dichloropropene (cis)

Cyclohexarie^

Dibrcimochloromethane

DichlonDdifluoromethane

Ethylbenzene

Methyl ethyl ketone

Methyl isobutyl ketone

Methyl tert-butyl ether

Methylene chloride

n-Heptane

n-Hexane

Styrene

Tert-butyl alcohol

Tetrachloroethene

Toluene

13-Dichloropropene(trans)

Triehloroethene

Trichlorofluoromethane

Vinyl bromide

Vinyl chloride

Xylene (0)

Xylenes (mampp)

Frequency of Detection

1 3

0 3

0 3

1 3

0 3

0 3

0 -3

1 3

0 3

0 3

2 3

0 3

3 3

0 3

0 3

3 3

1 3

- 0 3

3 3

P 3

0 3

0 3

1 3

1 3

Min imum Detected

Concentrat ion

(ugm)

5910

ND

ND

52

ND

ND

ND

23

ND

ND

1160

ND

1 4 4

ND

ND

11200

18

ND

91

ND

ND

ND

208

387

Maximuri i Detected

Concentrat ion (ugmS)

bull

5910

ND

ND

52

bull ND

ND

ND

23

ND

ND

1520

ND

183

ND

ND

149000

18

ND

7820

ND

bullND

ND

208

387

Sample vyith Max imum Detect

VP-02

ND

ND

VP-01

bull ND

ND

ND

VP-01

ND

ND

VP-02

ND

VP-02

ND

ND

VP-02

VP-01

ND

VP-03

ND

ND

ND

VP-03

VP-03

Min imum Detection

Limit (ugm3)

20

83

18

138

34

bull 20

17

118

16

14

14

16

- -17

12

--151

18

--23

18

10

1 7 bull

1 7 bull

Maximum Detection

Limit (ugm3)

195

83

182

138

341

198

174

118

164

144

14

164

170

121 -

--151

182

225

175

102

bull 174

174

Vapor Intrusion Compar ison

V a l u e

(ugm)

11

24

NA

2000

1

2000

22

10000

800

30000

52

NA

2000

10000

NA

81

4000

NA

022

7000

NA

28

70000

70000

Chemical o f Concern

YES

No

No

No

No bull

No

No bull

No bull=

No

No

YES

No

No

No

No

YES

No

No

YES

N o

No

No

No

No

Comment

Maximum detect exceeds comparison value

Constituent not detected

Constituent not detected

Maximum detect below comparison value

Constituent not detected

Constituent not detected

Constituent not detected

Maximum detect below comparison value

Constituent not detected

Constituent not detected

Maximum detect exceeds comparison value

Constituent not detected bull

Maximum detect below comparison value

Constituent not detected

Constituent not detected

Maximum detect exceeds comparison value

Maximum detect below comparison value

Constituent not detected

Maximum detect exceeds comparison value

Constituent not detected

Constituent not detected

Constituent not detected bull

Maximum detect below comparison value

Maximum detect below comparison value

Notes

ND - Not Detected

NA - Not Available

- - Constituent detected in every sample detection limit not presented

Values in bold indicate detection limit exceeds comparison values

Target shallow soil gas comparison values corresponding to indoor air concentrations where the soil gas to indoor air attenuation factor = 01 and the target cancer risk is set to ip (presented in Table 2c of USEPA 2002a)

Comparison value for cyclohexane is based on the comparison value for hexane

Coyne VI Memo Tables_09-08-09xls 982009

AR100296

TABLES

EXPOSURE POINT CONCENTRATIONS FOR CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR

Coyne Textile Services Facility - Huntington West Virginia

Chemical of Concern

VolatileOrganics

i24-Trimethylbenzene

12-Dichloroethene (cis)

Chloroform

Methylene chloride

Tetrachloroethene Triehloroethene

Subslab Vapor Source

Concentration (mgm^)

0197

603

591

152

149 782

Transport

Factor^ (unitless)

108E-05

108E-05

108E-05

108E-05

108E-05 108E-05

EPC in

Indoor Air (mgm^)

213E-06

651 E-05

638E-05

164E-05

161E-03 844E-05

Notes

^ Subslab vapor source concentration is based on the maximum detected concentration of samples

VP-01-02 and-03 (see Table 2) -

^ Details of the transport factor calculations are presented in Appendix B

^ Exposure Point Concentration (EPC) in inidoor air is calculated as the subslab vapor concentration TF

Coyne VI Memo Tables_09-08-09xls 982009

AR100297

TABLE 4

FACTORS USED IN DOSE CALCULATIONS INHALATION OF VOLATILE EMISSIONS

Coyne Textile Services Facility - Huntington West Virginia

Symbol

CA

IRA

ET

EF

ED-

BW

AT

Exposure Factor

Constituent Concentration in Air

Inhalation Rate

Exposure Time

Exposure Frequency

Exposure Duration

Body Weight

Averaging Time

Indoor Worker

Constituent-Specific See Table 3

25 m hour

8 hrday

250 daysyear

25 years

bull 70 kg

9125 days (NC)

25550 days (C)

Total Dose = CA x IR^ x ET x EF x ED x 1BW x 1AT

(NC) - Non-carcinogenic Averaging Time

(C) - Carcinogenic Averaging Time

Coyne VI Memo Tables_09-08-09xls 982009

AR100298

TABLES TOXICITY VALUES FOR CHEMICALS OF CONCERN

Coyne Textile Services Facility - Huntington West Virginia

Chemical of Concern

Volatile Organics

124-Trimethylbenzene

12-Dichloroethene (cis)

Chloroform

Methylene chloride

tetrachloroethene

Triehloroethene

Target Organ Critical Effect

blood

bullblood

liver

liver

liver CMS

liver kidney fetus CNS

Chroniclnhalation Reference Dose

(mgkg-day)

200E-03 P

1 OOE-02 R

140E-02 E

286E-01 M

771 E-02 M

1OOE-02 E

Inhalation Cancer ^ Slope Factor

(mgkg-day)^

NA

NA

805E-02 1

165E-03 1

200E-02 0

400E-01 E

(I) - Integrated Risk Information System (IRIS USEPA 2009)

(P) - Provisional Peer-Reviewed Toxicity Value (PPRTV) as presented in USEPA Regional Screening Tables (ORNL 2009)

(R) - Calculated assuming route-to-route extrapolation as per WVDEP

(E)-Provisional value from the National Center for Environmental Assessment (as per WVDEP)

(M)-Chronic Minimal Risk Level (MRL ATSDR 2009)

(0) - Value cited by USEPA Region 3 attributed to other sources (as per WVDEP)

Coyne VI Memo Tables_09-08-09xls 982009

AR100299

TABLE 6

NONCANCER HAZARD INDEX AND POTENTIAL CANCER RISK FOR AN INDOOR WORKER

Coyne Textile Services Facility - Huntington West Virginia

bull

Constituent

Volatile Organics

124-Trinnethylbehzene

12-Dichlorpethene (cis)

Chloroform

Methylene chloride

Tetrachloroethene Triehloroethene

EPC in Indoor Air

(mgm)

213E-06

651 E-05

- 638E-05

164E-05

161 E-03

844E-05

Intake (ADD)

(mgkg-d)

416E-07

127E-05

125E-05

321 E-06

315E-04 l65E-05

RfDi

(mgkg-d)

200E-03

1OOE-02

140E-02

286E-01

771 E-02 1 OOE-02

Hazard

Quotient

208E-04

127E-03

892E-04

112E-05

408E-03 165E-03

Intake (LADD)

(mgkg-d)

) 149E-07

455E-06 bull 446E-06

115E-06

112E-04 590E-06

CSFi

(mgkg-d)

NA

NA

805E-02

165E-03

200E-02

400E-01

Potential

Cancer Risk

NA

NA

359E-07

189E-09

225E-06 236E-06

Total Hazard Index

00081 Total

Cancer Risk 497E-06

Total Blood HI = Total Liver HI =

Total Central Nervous System HI = Total Kidney HI =

Total Fetal HI =

bull 00015 00066 00057 00017 00017

Notes NA = Toxicity values are not available for this endpoint or exposure pathway

Coyne VI Memo Tables_09-08-09xls 982009

AR100300

APPENDIX A

SUBSLAB VAPOR ANALYTICAL DATA

AR100301

Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility Huntington West Virginia

Sample

Consti tuent

Volatile Organics (ugm) 111-Trlchloroethane 1122-Tetrachloroethane 112-Trichloro-122-trifluoroethane 112-Trichloroethane 11-Dichioroethane 11-Dichloroethene 124-Trichloroberi2ene 124-Trimethylbenzene 12-Dibromoethane 12-Dichloroben2ene 12-Dichloroethane 12-Dichloroethene-(cis) -12-Dichloroethene (trans) 12-Dichloropropane 12-Dichlorotetrafluoroethane 135-Trimethylbenzene 13-Butadiene 13-Dichlorobenzene 13-Hexachlorobutadiene 14-Dichlorobenzene 224-trimethVlpentane 2-Chlorotoluene 4-Ethyltoluene Acetone Allyl Chloride Benzene Bromodichloromethane Bromoform Bromomethane Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 13-Dichloropropene (cis) Cyclohexane Dibromochloromethane

Identif ication Sample Date

CAS No

71-55-6 79-34-5 76-13-1 79-00-5 75-34-3 75-35-4 120-82-1 95-63-6 106-93-4 95-50-1 107-06-2 156-59-2 156-60-5 78-87-5 76-14-2 108-67-8 106-99^0 541-73-1 87-68-3 106-46-7 540-84r1 95-49-8

622-96-8 67-64-1 107-05-1 71-43-2 75-27-4 75-252 74-83-9 75-15-0 56-23-5 108-90-7 75-00-3 67-66-3 74-87-3

10061-01-5 110-82-7 124-48-1

lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt

lt lt lt lt lt lt lt lt lt lt lt lt

lt

VP-01 8132009

22 28 31 22 16 16 30 20 31 24 16 16 16 19 28 20 89 24 43 24

1 9 21 20 796 13 13 27 41 16 13 25 18 11 20 83 18 52 34

lt lt lt lt lt lt lt lt lt lt lt

lt lt lt lt lt lt lt lt lt lt lt

lt lt lt lt lt lt lt lt lt

lt lt lt lt

VP-02 8132009

218 2 7 5 307 218 162 159 297

bull 197 307 240 162 369 159 185 280 197 89

240 427 240 187 207 197

1880 125 128 268 414 155 125 252 184 106

5910 83 182 138 341

lt lt lt lt lt lt lt

lt lt lt

lt lt lt lt lt lt lt bull

lt lt lt lt

lt lt lt lt lt lt lt lt lt lt lt lt lt lt

VP-03 8132009

218 275 307 218

bull 162 159 297 197 307 240 162

6030 159 185 280 197 89

240 427 240 187 207 197

1750 125 128 268 414 155 125 252 184 106 195 83 182 138 341

Appx A SG Dataxis Page 1 of 2 982009

AR100302

Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility bull Huntington West Virginia

Consti tuent

Volatile Organics (ugm^) Dichlorodifluoromethane Ethylbenzene Methyl ethyl ketone Methyl Isobutyl ketone Methyl tert-butyl ether Methylene chloride n-Heptane jn-Hexane Styrene Tert-butyl alcohol Tetrachloroethene iToluene 13-Dichloropropene (trans) Triehloroethene Trichlorofluoromethane Vinyl bromide Vinyl chloride Xylene (o) Xylenes (mampp)

Sample Identif ication Sample Date

CAS No

75-71-8 100-41-4 78-93-3 108-10-1

1634-04-4 75-09-2

142-82-5 bull 110-54-3

100-42-5 75-65-0 127-18-4 108-88-3

10061-02-6 79-01-6 75-69-4 593-60-2 75-01-4 95-47-6

179601-23-1

lt lt

lt lt lt lt

lt lt

lt

lt lt lt lt lt

VP01 8132009

20 17 23 16 14 14 16

173 17 12 bull

11200 18 18 91 23 18 10 17 17

lt lt lt lt lt

lt

lt lt

lt lt

lt lt lt lt lt

VP-02 8132009

198 174 118 164 144

1520 164 -183 170 121

149000 151 182

2360 225 175 102 174 174

VP-03 8132009

lt 198 lt 174 lt 118 lt 164 lt 144

1160 lt 164

144 lt 170 ltbull 121

90500 lt 151 lt 182

7820 lt 225 lt 175 lt 102

208 387

Appx A SG Dataxis Page 2 of 2 982009

AR100303

APPENDIX B

CALCULATION OF TRANSPORT FACTORS USED TO ESTIMATE INDOOR AIR CONCENTRATIONS

AR100304

APPENDIX B

Calculation of Transport Factors Used to Estimate Indoor Air Concentrations

This appendix presents the methodology for calculating transport factors that are used to convert subslab

vapor concentrations to concentrations in indoor air 124-Trimethylbenzene 12-dichloroethene (cis)

chloroform methylene chloride tetrachloroethene and triehloroethene were identified as contaminants of

concern (COC) for potential vapor intrusion from subslab vapor associated with the Coyne Textile

Services Facility located in Huntington West Virginia (site) In this appendix the transport factors are

calculated to estimate the concentrations of COC in indoor air of the existing plant building located at the

site ~

Transport Factor for Indoor Air

The concentration of a constituent in indoor air (da) is proportional to the concentration of the constituent

in the subslab vapors immediately beneath the building foundation (ie subslab vapor concentration or

Csubsiab) The following equation is used to calculate da from Csubsiab

^ wja ~ ^subslab X I r

where

Cia = concentration of constituent in indoor air (mgm^) -

Csubsiab^ concentration of constituent in subslab vapors (mgm^) and

TF = transport factor from subslab vapors to indoor air

The transport factor (TF) is an infinite source attenuation coefficient andcan be calculated based on a

model developed by Johnson and Ettinger (1991) t he equation for calculating TF is as follows

(Deff X A B ) ( Q B X L T ) X expKQso i l X Lcrabk)(Dcrack X Acrack)]

exp[ (Qsoi l X Lcrack)(Dcrack X Acrack)] + (Deff X A B ) ( Q B X L T ) + (Deff X AB)(Qsoi l X L j ) X (exp [ (Qso i l X Lcrack)(Dcrack X Acrack)] - 1)

where

Deff = effective diffusion coefficient for vadose zone soil (cm^sec)

AB = area of enclosed space below grade (cm^)

QB = building ventilation rate (cm^sec)

LT = distance from contaminant source to building foundation (cm)

Qsoii = volumetric flow rate of vapors into the building (cm^sec)

Lcrack = foundatlon thickness (cm)

Dcrack = vapor diffusion coefficient through crack (cm^sec) and

Acrack = area of cracks through which vapors can pass (cm^)

AR100305

To solve this equation the USEPAs SG-ADV spreadsheet Version 31 most recently updated in

February 2004 was implemented A combination of site-specific factors and default values from the

Users Guide for Evaluating Subsurface Vapor Intrusion Into Buildings (USEPA 2004) were used as input

values in the model All input values are defined below and presented in Tables B-1-A through B-6-A

bull The initial subslab vapor concentration (Csubsiab) is the maximum detected concentration(in units

of ugm ) of samples VP-01 VP-02 and VP-03 that was presented in Table 3 of the report

bull The depth below grade to the bottom of the enclosed space floor (Lp) is set to 15 cm the default

value provided by USEPA (2004) for a slab-on-grade structure

bull The vapor sampling depth below grade (Lg) is a site-specific value The vapor samples were

collected from immediately beneath the building floor therefore Lj has been set to 15 cm

bull The average soilgroundwater temperature (Ts) is set to 125degC the average value for West

Virginia as estimated frorri Figure 8 of the vapor intrusion users guide (USEPA 2004)

bull The soil type used to estimate vapor permeability is assumed to be sandy loam (SL) The

associated soil properties for a sandy loam soil type are as follows the soil dry bulk density (Pb) is

162 gcm the total porosity (n) is 0387 (cm^-aircm^) and the water-filled porosity (nw) is 0103

(cm -HzOcm )

bull The floor thickness (Lcrack) is set to the USEPA (2004) default value of 10 cm

bull The soil-building pressure differential (AP) is set to the USEPA (2004) default value of 40 gcm-s^

bull The building dimensions are siterspecific based on the existing plant building located at the site

The existing structure is approximately 84000 square feet (Dolphin 2000) therefore the

dimensions are set to 8839 cm (290 feet) length by 8839 cm (290 feet) The USEPA (2004)

default value of 244 cm vyas used for the height

bull Thefloor-wall seam crack width (w) is set to the USEPA (2004)-default value of 01 cm

bull The indoor air exchange rate (ER) is set to 083hour This is the value provided by ASTM (2002)

for commercial and industrial buildings

AR100306

Tables B-1-B through B-6-B present the constituent-specific properties for COC that were used in the TF

calculations Tables B-1-C through B-6-C present the intermediate calculations used to determine the

indoor air attenuation coefficients (ie the transport factors) The shaded boxes in Tables B-1-C through

B-6-C also present the resulting TF values that are applied to the concentrations of COC in subslab

vapor and the estimated indoor air concentrations

References

American Society for Testing and Materials (ASTM 2002) Standard Guide for Risk-Based Corrective Action Applied at Petroleum Release Sites ASTM E-1739-95 (Reapproved 2002)

Johnson PC and RA Ettinger (1991) Heuristic model for predicting the intrusion r-ate of contaminant vapors into buildings Environ Sci Technolpgy 25 1445-1452

Dolphin Environmental LLC (Dolphin 2000) Site Characterization Report Mach 14 2000

United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004

AR100307

APPENDIX B-1-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV Nersion31 0204

Reset to Defaults

ENTER -

Chemical CAS No

(numbers only

no dasties)

95636

ENTER Soil gas

cone

Cg (ngm)

Soil Gas Concentration Data ENTER

Soil gas

OR cone

bull - c bull (PPmv)

197E+02

Chemical

124-Trimethylbenzene

MORE ENTER Depth

below grade to bottom

of enclosed space floor

U bull (cm)

ENTER

Soil gas sampling

depth below grade

U (cm) bull

ENTER

Average soil

temperature Ts

CO

1 15 1 1 5 bull125

ENTER ENTER ENTER Totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hft ha he

(cm) (cm) (cm)

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estirnate OR permeability | soil vapor

permeability) k v bull

(cm)

SL 1 1

MORE ENTER

stratum A SCS

soil type

Lookup Soil Parameters

ENTER stratum A soil dry

bulk density P

(gcm)

ENTER Stratum A soil total porosity

(unitless)

ENTER bull stratum A soil water-filled

porosity

(cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

nlaquo

(unitless)

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gchi-s^)

ENTER Enclosed

space floor

length bull LB

(cm)

ENTER Enclosed

space floor

width WB

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

bull Floor-wall seam crack

width w

(cm)

bullENTER

Indoor air exchange

rate ER

(1h) bull

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bidg OR

Leave blank to caicuij

(Lm)

Appx B-1 124-TMBxls 1 of 3 982009

AR100308

APPENDIX B-1-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of ^ bull law constant law constant vaporization at Normal

Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temperature boiling point point temperature weight

D bull Dbdquo H T R bull AHbdquo TB Tc IVIW

Unit risk Reference

factor cone URF RfC

(cms) (cmls) (atm-mmol) CO (calmol) (degK) (degK) (gmol) bull (ugm)- (mgm)

1 606E-02 1 792E-06 1 bull 614E-C3 1 25 1 9369 1 44230 | 64917 1 12020 1 OOE+00 1 60E-03 1

Appx B-1 124-TMBxls 2 of 3 982009

AR100309

APPENDIX B-1-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

(sec)

Source-building

separation

LT bull

(cm) bull

Stratum A soil

air-filled porosity

Q A

Stratum B soil

air-filled porosity

(cmcm) (cmcm)

Stratum C soil air-filled porosity

(cmcm)

Stratum A effective total fluid

saturation

Se

(cmcm)

Stratum A soil

bullintrinsic permeability

^ (cm)

stratum A Stratum A Floor- soil soli wall BIdg

relative air effective vapor seam Soil bull ventilation permeability permeability perimeter gas rate-

kfg ky Xgrack c o n e - QbuHdinpound

(cm) - (cm) (cm) (ngm) (cms)

946E+08 1 0284 0284 0284 0184 596E-09 0901 537E-09 35357 I 197E+02 | 439E+06 |

Area of enclosed

space below grade

As (cm)

Crack-to-total area ratio

1 bull

(unitless)

Crack depth

below grade

Zcfack

(cm)

Enthalpy of vaporization at

ave soil temperature

AHvjs

(calmol) bull

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law constant at

ave soil bull temperature

bull HTS

(unitless)

Vapor bull viscosity at

ave soil temperature

HTS

(gcm-s)

Stratum A

effective diffusion

coefficient

D (cms)

Stratum-B

effective diffusion coefficient

DB (cms)

Stratum C effective diffusion

coefficient

D-c (cms)

Total - overall effective diffusion

coefficient

D ^ (cms)

Diffusion path

length

L-

(cm)

I 787E+07 I 449E-05 | 15 | 11661 260E-03 111E-01 176E-04 I 612E-03 j OOOE+00 | OOOE+00 | 612E-03 j

bull Convection path

length

Lp

(cm)

Source vapor cone

^source

(ngm)

Crack radius

Tcfack

(cm)

Average vapor

flow rate into bIdg

Qsoii

(cms)

Crack effective diffusion

coefficient pcrack

(cms)

Area of CTack

Acack

(cm)

Exponent of equivalent foundation

Peclet number

exp(Pe)

(unitless)

bull bull - bull bull bull bull

1 15 1 197E+02 1 010 1 474E+01 612E-03 bull 354E-t-03 1 336E+09

Infinite source Indoor

~ attenuation coefficient

a

(unitless)

108E-05

Infinite source

btJbldgjJSv-L ^Ppncji3i-

virhpbiiilding bullbull ^lHltti^m)ilg

213E-03

Unit risk

factor

URF

(ngm)-

Reference cone

RfC (mgm)

NA 60E-03 1

I END

Appx B-1 124-TMBxls 3 of 3 982009

AR100310

APPENDIX B-2-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV Nersion31 020^

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

156592

Soil Gas Concentration Data ENTER

Soil gas

cone OR c

(ngm) bull

ENTER Soil bull-gas

cone

c (ppmv)

603E+03 1

Chemical

cis-12-Dichloroethylene

MORE ENTER Depth

below grade to bottom

of enclosed space floor

LF

(cm)

ENTER

Soil gas sampling

depth below grade

U (cm)

ENTER

Average soil

temperature bull Ts

(degC)

1 15 1 bull 15 125

ENTER ENTER ENTER Totalsmust add ijp tb value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hA hB he

bull (cm) (cm) (cm)

15 1 1

ENTER Soil

straturh A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estimate OR permeability | soil vapor

permeability) kv

(cm)

SL 1 |

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

P (gcm)

ENTER Stratum A soil total porosity

bull n

(unitless)

ENTER Stratum A

soil water-filled porosity

(cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

ENTER Stratum B

soil water-filled porosity

ENTER Stratum C

SCS soil type

(unitless) (cmcm)

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure differential

AP

(gcm-s)

ENTER Enclosed bull

space floor

length

LB (cm)

ENTER Enclosed

space floor

width WB

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER

Average vapor flow rate into bIdg

OR Leave blank to calculi

Qsoil

(Lm)

Appx B-2 cis-12-DCExls 1 of 3 982009

AR100311

APPENDIX B-2-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Diffusivity in air

Da

(cms)

Diffusivity in water

Dw (cms)

Henrys law constant at reference temperature

H

(atm-mmoi)

Henrys law constant

reference temperature

bull T R

CC)

Enthalpy of vaporization at

the normal boiling point

AHbdquob

(calmol)

Normal boiling point

TB

(degK)

Critical temperature

Tc (degK)

Molecular weight

MW

(gmol)

Unit risk

factor URF

(ngm)

Reference cone

RfC (mgm)

1 736E-02 1 113E-05 1 407E-03 j 1 25 1 bull 7192 1 33365 1 54400 1 9694 1 OOE+00 j 35E-02 1

Appx B-2 cis-12-DCExls 2 of 3 982009

AR100312

APPENDIX B-2-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

stratum A Stratum B Stratum C Source- soil soil soil

Exposure building air-filled air-filled air-filled

duration separation porosity porosity porosity

T LT ea e^ bull e= (sec) (cm) (cmcm) (cmcm) (cmcm)

I 946E+08n^

Stratum A Stratum A Stratum A Stratum A Floor-effective soil soil soil wall total fluid intrinsic relative air effective vapor seam

saturation permeability permeability permeability perimeter

Ste kj krg ky Acrack

(cmcm) (cm) (cm) (cm) (cm)

Soil gas

cone (ngm)

I 0284 I 0284~ 0284 0184 I 596E-09 | 090T 537E-09 35357 603E+03

BIdg ventilation

rate

JbulldinE

(cms)

439E+06

Area of enclosed

space below grade

AB

(cm)

Crack-to-total

area ratio

n (unitless)

Crack depth below grade

Zltiack (cm)

Erithalpy of vaporization at

ave soil temperature

AHvTs (calmol)

Henryslaw constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law constant at

ave soil temperature

HTS

(unitless) bull

Vapor viscosity at

ave soil bull temperature

HTS

bull (gcm-s)

Stratum A

effective bull diffusion

coefficient

D^A-(cms)

Stratum B

effective bull diffusion

coefficient

D=B

(cms)

Stratum C

effective diffusion bull

coefficient

D=e (cms)

Total overall

effective diffusion

coefficient

DT

(cms)

Diffusion path

length

Ld

(cm)

I 787E+07 I bull449E-05 | 15 bull7709 230E-03 982E-02 176E-04 | 743E-03 | OOOE+00 | OOOE+00 | 743E-03 |

bull bull bull -

Convecfion path -bull

length

Lp (cm)

Source vapor cone

-source

(Mgm)

Crack radius

fcrack

(cm)

Average vapor

flow rate into bIdg

Qaoil bull

(cms)

Crack effective diffusion

coefficient pcack

(cms)

Area of crack

crack

(cm)-

Exponent of equivalent foundation

Peclet number

exp(Pef)

(unitless)

bull

1 15 -1 603E+03 1 010 1 474E+01 743E-03 354E+03 1 697E+07

Infinite source Indoor

attenuation coefficient

poundbullbullbull C t

pound(unitless)

bullsiilaquogt j ii08E-05

Infinite [ source

bIdg cone

Cbujidjng

(pgm)

651 E-02 iKrt

Unit risk

factor

URF

(ngm)-

Reference cone

RfC

(mgm)

NA 35E-02 1

I END I

Appx B-2 cis-12-DCExls 3o f3 982009

AR100313

APPENDIX B-3-A DATA ENTRY SHEET

Coyne Texti le Services - Hunt ington West Virginia

SG-ADV Version 31 0204

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

67663

Soil Gas Concentration Data ENTER ENTER

Soil Soil gas gas

cone OR cone c C

(^gm) (ppmv)

591 E+03

bull

Chemical

Chloroform

MORE ENTER Depth

below grade tb bottom

of enclosed space floor

bull LF

(cm)

ENTER

Soil gas sampling depth

below grade

(cm)

ENTER

Average soil

temperature-Ts

CO bull

1 15 1 15 1 125

ENTER ENTER ENTER Totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

IIA hs he (cm) (cm) (cm)

1 5 bull 1 1

ENTER ENTER Soil - bull

stratum A User-defined SCS stratum A

soil type bull soil vapor (used to estimate OR permeability

soil vapor k

bull permeability) (cm) 1

SL 1 1 bull

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A soil dry

bulk density

Pb (gcm)

ENTER Stratum A soil total porosity

nV (unitless)

ENTER Stratum A

-soilwater-filled bullporosity

Sraquo (cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

(unitless)

ENTER Stratum B

soil water-filled porosity

bull ebdquo=

(cmcm) bull

ENTER Straturri C

SCS bull soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

- c rack

(cm)

ENTER

Soil-bldg pressure

differential AP^

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor

width bull W B

(cm)

ENTER

Enclosed space

height HB

(cm)

ENTER

bull Floor-wall^ seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bidg OR

Leave blank to calculi

Qsoil bull

(Lm)

I -I

Appx B-3 Chloroformxls 1 of 3 982009

AR100314

APPENDIX B-3-B CHEMICALPROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Diffusivity in air

D (cms)

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffijsivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature

Dbdquo H TR A H bdquo TB Tc

(cm s) (atm-m mol) ro (calmol) (degK) (degK)

Molecular weight

MW

(gmol)

Unit risk

factor URF

(ngm)-

Reference cone

RfC

(mgm)

104E-01 100E-05 I 366E-03 25 6988 33432 53640 11938 I 23E-05 | OOE+00

Appx B-3 Chloroformxls 2 of 3 982009

AR100315

APPENDIX B-3-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure

duration

(sec)

Source-

building

separation

LT

(cm)

Stratum A

soil

air-filled

porosity

Sa

( cm cm )

Stratum B

soil

air-filled

porosity

( cm cm )

Stratum C

soil

air-filled

porosity

( c m c m )

Stratum A

effective

total fluid

saturation

( c m c m )

Stratum A

soil

intrinsic

penmeability

k

(cm )

Stratum A

- soil

relative air

permeabil i ty

(cm )

Stratum A

soil

effective vapor

permeability

kv

(cm )

Floor-

wall

seam

perimeter

gtcrack

(cm)

Soil gas

cone

(ngm)

BIdg

venfilation

rate

^buildlriE

(cms)

I 9 4 6 E + 0 8 ~ T I 0284 T 596E-09 I 0-901 I 537E-09 | 35357 | 591 E+03 j 439E+06 | 1 0 284 0284 0184

Area of

enclosed

space

below

grade

A B

( c m )

Crack-

to-total

area

ratio

n

(unitless)

Crack

depth

bull below

grade

^crack

(cm)

Enthalpy of

vaporization at

ave soil

temperature

AHTs bull

(calmol)

Henry s law

constant at

ave soil

temperature

HTS

(a tm-m mol j

Henrys law

constant at

ave soil

bull temperature

HTS

(unitless) bull

Vapor

viscosity at

ave soil-

temperature

^HTS

(gcm-s)

Stratum

A

effective

diffusion

coefficient

(cm s)

Stratum

B

effective

difftjsion

coefficient

D B

(cms) bull

S t ra tum

C

effective

diffusion

coefficient

Dc

(cm s)

Total

overall

effective

bull diffusion

coefficient

D T

(cm s)

Diffi jsion

path

length

Ld

(cm)

I 787E+07 I 449E-05 j - bull 15 7528 210E-03 896E-02 176E-04 I 105E-02 | OOOE+00 | OOOE+00 | 105E-02

Convection

path length

Lp

(cm)

Source

vapor

cone -

^source

- (ngm)

Crack

radius

Tcrack

(cm)

Average

vapor

flow rate

into bidg

Qsoil

(cms)

Crack

effective

diffusion

coefficient Qcrack

bull (cms)

Area of crack

Acrack

(cm)

Exponent of

equivalent

foundation

Peclet number

exp(Pe)

(unitless)

V bull bull

1 15 1 591 E+03 1 010 1 474E+01 105E-02 354E+03 1 355E+05

Infinite

source

indoor

attenuation

coefficient

d

(unitless)

bull 108E-05

Infinite

source

bIdg

cone

^ b u i l d i n g

i (^gm)

bull bull

i 638E-02 -

Unit

risk bull factor

URF

(ngmY

Reference

cone

RfC

(mgm)

~ 23E-05 NA 1

I END

Appx B-3 Chloroform xls 3 of 3 982009

AR100316

APPENDIX B-4-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ersion 31-020^

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

nodashes)

bull 75092

ENTER Soil gas

cone

c (ngm)

Soil Gas Concentration Data ENTER

Soil gas bull

OR cone

bull C

(ppmv)

152E+03

bull bull

Chemical

Methylene chloride

MORE

MORE 4gt

ENTER Depth

below grade to bottom

of enclosed space floor

LF -

(cm)

ENTER

Soil gas sampling depth

below grade

bull U

(cm)

ENTER

Average soil

temperature

Ts bull CC)

bull bull bull bull

1 15 1 15 125

ENTER Totals

Thickness of soil

stratum A h

(cm)

ENTER ENTER must add up to value of Ls (cell F24

Thickness Thickness of soil of soil

stratum B stratum C (Enter value or 0) (Enter value or 0)

he he bull

(cm) bull (cm) -

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(usedto estimate OR perrrieability | soil vapor

permeability)

k bull

(cm)

SL 1 bull 1

ENTER Stratum A

SCS soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

Pb (gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Stratum A

soil water-filled porosity

9w (cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

Pb^

(gcm)

ENTER Stratum B soil total porosity

n^

(unitless)

ENTER Stratum B

soil water-filled porosity

(crhcm)

ENTER Stratum C

SCS soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE 4gt

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

bull Soil-bldg pressure

differential AP^

(gcm-s)

ENTER Enclosed

space floor

length LB

(cm)

ENTER Enclosed

space floor

width bull W B

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width

w

(cm)

ENTER

Indoor air exchange

rate

ER (1h)

ENTER Average vapor

flow rate into bidg OR

Leave blank to calculc

Qsoil

(Lm)

10 40 8839 8839 244 01 083

Appx B-4 MCxIs 1 of 3 982009

AR100317

Diffijsivity in air

D

APPENDIX B-4-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffusivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature

Pw H TR AHt TB TC

Molecular weight

MW

Unit risk

factor URF

Reference cone

RfC

(cms) (cms) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) bull (ngm)- (mgm)

bull bull

1 101E-01 1 117E-05 1 218E-03 1 25 | 6706 1 31300 1 51000 1 8493 1 47E-07 1 30E+00 1

Appx B-4 MCxIs 2 of 3 982009

AR100318

APPENDIX B-4-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

T

(sec)

Source- -building

separation

LT

(cm)

Stratum A soil

air-filled porosity

e a bull

(cmcm)

Stratum B soil

bullair-filled porosity bull

ea^ (cmcm)

Stratum C soil

air-filled porosity

ea= (cmcmj

Stratum A effective total fluid

saturation

Sc bull

(cmcm)

Stratum A soil

intrinsic pemneability

ki (cm)

Stratum A soil

relative air permeability

^ ^ g

(cm)

stratumA bull soil effective vapor permeability

K (cm)

Floor-wall

seam perimeter

Xcrack

(cm)

Soil gas

cone (ngm)

BIdg ventilation

rate

Qbuildinc

(cms)

1 946E+08

Area of -enclosed

space below

bull grade

AB

(cm)

1

Crack-to-total

area rafio

Tl

(unitless)

0284 1

Crack depth below grade

Zcrack

(cm)

0284 1

bull Enthalpy of vaporization at

ave soil temperature

AHTs (calmol)

0284

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

0184

Henrys law constant at ave soil

temperature

HTS

bull (unitless)

1 596E-09

Vapor viscosity at

ave soil temperature

Mrs (gcm-s)

0901

Stratum A

effective diffusion

coefficient

D (cms)

537E-09

Stratum B

effective diffusion

coefficient

D-B (cms)

35357 1

Stratum C -

effective diffusion

coefficient

D-c ^ (cms)

152E+03

Total bull overall

bull effective diffusion

coefficient

D ^

(cms)

440E+06 1

Difftjsion path

length

Ld (cm)

1 787E+07

Convection path

length

Lp (cm)

4 49E-05

Source vapor cone

Csource

(ngm)

15 1

Crack radius

Tcrack

(cm)

7007 bull 1

Average vapor

flow rate intobldg

Qsoil

(cms)

130E-03

Crack effective diffusion

coefficient pcrack

(cms)-

555E-02

bull ^

Area of crack

Acrack

(cm) bull

1 176E-04

Exponent of equivalent foundation

Peclet number

exp(Pe)

(unitless) bull

bull bull

1 15

1 END

152E+03 010 1 474E+01 1 102E-02 354E+03 1 519E+05

102E-02

Infinite source

indoor ^attenuation coefficient

bull a

(unitless)

aiii08E-05

0 OOE+00

bull

Infinite bull source

bIdg ^ cone

^bu i l d i ng

(MQm)

164E-02

OOOE+00 1

Unit risk

factor

URF

(ngm)-

47E-07 1

102E-02 j

Reference cone

RfC

(mgm)

30E+00 j

1 1

Appx B-4 MCxIs 3 of 3 982009

AR100319

APPENDIX B-5-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ^erslon 31 0204

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

127184

Soil Gas Concentration Data ENTER ^ ENTER

Soil -Soi l bull gas gas

cone OR cone Cg C bull

(tgm) (ppmv)

149E+05 1

Chemical

bull Tetrachlbroethylene

MORE 4

ENTER Depth

below grade to bottom

ofenclosecJ space floor

LF

(cm)

ENTER

Soil gas bull sampling

depth below grade

u bull (cm)

ENTER

Average bullsoil

temperature - Ts

ro 1 1 5 1 15 1 125 bull

ENTER ENTER ENTER totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hft bull he bull he

(cm) (cm) (cm)

bull 1 5 1 - 1

ENTER ENTER Soil

stratum A User^defined bull SCS bull stratum A soil type soil vapor

(used to estimate OR perrrieability soil vapor K bull

permeability) (cm) 1

SL 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

Pb

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Sitratum A

soil water-filled bull porosity

(cmcm)

ENTER Stratum B

SCS soiltype

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

Pb^

(gcm)

ENTER Stratum B soil total porosity

Ajnitless^

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS soil type

LookupSoil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

VS

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor width

W B

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width

w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

ENTER Average vapor

flow rate into bidg OR

Leave blank to calcul

bull Qsoil

(Lm)

10 40 8839 8839 244 01 083

Appx B-5 PCExIS 1 of 3 982009

AR100320

APPENDIX B-5-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal Unit

Diffusivity Diffusivity at reference reference the riormal boiling Critical Molecular risk Reference in air in water temperature temperature boiling point point teriiperature weight factor cone

Da Dbdquo H TR AHb TB Tc MW URF RfC

(cms) (cnis) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) (^gm)- (mgm)

1 720E-02 1 820E-06 1 184E-02 1 25 1 8288 1 39440 1 62020 1 16583 1 59E-06 1 60E-01 1

J

AppxB-5PCExls 2 of 3 - 982009

AR100321

APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

T

(sec)

Source-building

separation

LT

bull (cm)

Stratum A soil

air-filled porosity

Oa (cmcm)

Stratum B - soil air-filled porosity

ea (cmcm)

Stratum C soil

air-filled porosity

ea= - (cmcm)

Stratum A effective total fluid

saturation

sbdquo (cmcm)

Stratum A soil

intrinsic permeability

ki (cm)

Stratum A soil

relative air permeability

- ^ g

(cm)

Stratum A soil

effective vapor permeability

kv (cm)

Floor-wall

seam perimeter

^crack

(cm)

Soil gas

cone

(ngm)

BIdg venfilation

rate

Qbuildins

bull (cms)

bull bull

1 946E+08

Area of enclosed

space below grade

AB

(cm)

1

bullCrack-to-total

area ratio

1 (unitless)

0284 1

Crack bull depth below grade

Zcrack

(cm) -

0284 1

Enthalpy of vaporization at bull

ave soil temperature

bull A H V TS

(calmol)

0284

Henrys law constant at

ave soil temperature

HTS (atm-mmol)

0184

-Henrys law constant at

ave soil temperature

HTS

(unitless)

1 596E-09

Vapor viscosity at

ave soil temperature

HTS

(gcm-s)

0901

Stratum A

effective diffusion

coefficient bull D = bull

(cms)

537E-09

Stratum B

effective diffusion

coefficient

D--B (cms)

35357 1

Stratum C

effective diffusion bull

coefficient

D-c (crris)

149E+05

Total overall

effective bulldiffusion coefficient

DT

(cms)

440E+06 1

Difftjsion path

length

U (cm)

1 787E+07

Convection path

length

bull Lp

(cm)

4 49E-05

Source vapor cone

^source

(ngm)

15 1

Crack radius

Tcrack

(cm)

9528 1

Average vapor

flow rate intobldg

Qsoil (cms)

908E-03

Crack effective diffusion

coefficient pcrack

bull ( c m s ) bull

387E-01

Area of crack

Abdquoack (cm)

1 176E-04

Exponent of equivalent foundafion

Peclet number

exp(Pe)

(unitless)

bull

1 15-

1 END

149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08

727E-03

Infinite source indoor

attenuation coefficient

a

(unitless)

108E-05

OOOE+00

Infinite source

bIdg cone

Cburldtng

(Mgm)

161 E+00

OOOE+00 1

Unit risk

factor

URF

(ugm)-

59E-06 1

727E-03

Reference cone

RfC (mgm)

60E-01

1 1

Appx B-5 PCExls 3 of 3 982009

AR100322

APPENDIX B-6-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ersion31 0204

Reset to Defaults

t

Soil Gas Concentration Data ENTER

Chemical CAS No

(numbers only

no dashes)

79016

ENTER ENTER Soil Soil gas gas

cone OR cone C C -

bull (ngm) (ppmv)

782E+03

Chemical

Trichloroethylene

MORE ENTER Depth

below grade to bottom-

of enclosed space floor

LF

(cm)

ENTER

Soil gas sarnpling

depth below grade

U (cm)

ENTER

Average soil

temperature Ts

(degC)

1 15 1 15 t 125

ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e

(cm) (cm) (cm)

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estimate OR permeability soil vapor

permeability)

k (cm)

bull S L 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil bull-Parameters

ENTER Stratum A

soil dry bulk density

P b -

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Stratum A bull

soilwaterrfilled porosity

(cmcm) bull

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

bull P ^ (gcm)

ENTER Stratum B soil total

porosity

nlaquo

(unitless) -

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS bull soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor

width W B

(cm)

ENTER

Enclosed space height

H B bull

( c m ) bull

ENTER

Floor-wall seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bIdg OR

Leave blank to calculc

Qsoil

(Lm) -

Appx B-6 TCExIs 1 of 3 982009

A

AR100323

APPENDIX B-6-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight

Da Dbdquo H TR AH^b TB TC MW

Unit risk Reference

factor cone URF RfC

(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)

1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1

Appx B-6 TCExIs 2 of 3 982009

AR100324

APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

(sec)

Source-building

separation LT

(cm)

Stratum A soil

air-filled porosity

bull ea (cmcm)

Stratum B Soil

air-fllled porosity

e^ bull (cmcm)

Stratum C soil

air-filled porosity

(cmcm)

StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air

saturation permeability permeability

S|e k krg (cmcm) (cm) (cm)

Stratum A Floor-soil wall BIdg

effective vapor seam Soil ventilafion permeability perimeter gas rate

k^ bull Xack c o n e Qbuildins

(cm) (cm) (ngm) (cms)

946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |

Area of enclosed

space below grade

AB

(cm)

Ciack- to-total

area ratio

1 (unitless)

Crack depth below grade

Zcrack

(cm)

Enthalpy of vaporization at

ave soil temperature

A H J S

(calmol)

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law bull constant at

ave soil temperature

HTS

(unitless)

Vapor viscosity at

ave soil temperature

|JTS

(gcm^s)

Stratum A

effective diffusion

coefficient

(cms)

Stratum B

effective -diffusion

coefficient

D=B (cms)

Stratum ^ C effective diffusion

coefficient

D=c (cms)

Total overall

effective diffusion

coefficient

DT

(cms)

I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03

Diffusion path

length

Li (cm) bull

Convection bull path

length

Lp

(cm)

Source vapor cone bull

^source

(ngm)

Crack radius

rcrack

(cm)

Average vapor

- flow rate intobldg

Qsoil

(cms)

Crack effective diffusion

bull coefficient Qcrack

(cms)

Area of crack

^crack

(cm)

Exponent of equivalent foundation

Peclet bull number

exp(Pe)

(unitless)

bull bull

1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07

Infinite source Indoor

attenuation coefficient

a

(unitless)

108E-05

Infinite source

bIdg concgt

^building

(ngm)

844E-02

Unit risk

factor

URF

(ngm)-

Reference cone

RfC

(mgm)

1 1E-04 1 40E-02 1

END

Appx B-6 TCExIs 3 of 3 982009

AR100325

Office of Waste Management 1356 Hansford Street

Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256

West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director

ORDER

ISSUED UNDER THE

HAZARDOUS WASTE MANAGEMENT ACT

CHAPTER 22 ARTICLE 18

OF THE WEST VIRGINIA CODE^ AS AMENDED

y Order Number HW-011-80

To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704

ATTEMTION MREDARMON

Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull

AR100326

ViWJ011-laquo9 PageNunil)er2

BASIS FOR ORDER

As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following

A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^

B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator

C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities

0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94

^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement

P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following

1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater

2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was

^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment

CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable

CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order

AR100327

H W - 0 1 1 - 9 9 Page Number 3

REQUIREMENTS OF ORDER

Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows

1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^

2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore

remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling

GENERAL PROVaiONS

1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order

2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order

3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order

Effective Date

Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief

Wt T 1 V Oflice of Waste Management

AR100328

^ ^ S I S

^wmmmmamn

AR100329

Page 3: SDMS DocID 2121999 · International Enterprises Corp. building (Coyne Building), which is located at 1111 Vernon Street, Westmoreland District, Wayne County, West Virginia. The following

shows contamination on the adjacent property bull The Consent Order

Let me know if Bob needs additional information to get started Thanks Joe

[ABhil Iiutii KWt1 [bullbull^tettl

MW-5 data trendspdf 04-08-0408 Groundwater Sampling Letter Reportpdf Coyne VI Memo_09-08-08pdf Order No HW-011-99pdf

AR100280

n nnp

n n n i -

n nnt^ -

n nnt -

n nriA -

0003 -

n nn

n nni -

n -

^ ^ bull

1 2 4 bull 5

TCE 307 - 309

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17

PCE 3 01-3 09

003

0005

Cis 12 DCE 301 - 309

AR100281

CIVIL bull ENVIRONMENTAL AND GEOTECHNICAL ENGINEERING

4980 Teays Valley Road Scott Depot WV 25560 Phone 3047550721 Fax 3047551880 TRIAD ENGINEERING INC

October 24 2008

Mr Robert Trocin Wayne County Economic Development Authority PO Box 519 Wayne VVest Virginia 25570

Subject Groundwater Assessment Former Coyne International Enterprises Corp Building Westmoreland District Wayne County West Virginia

Dear Mr Trocin

On behalf of the Wayne County Economic Development Authority (WCEDA) Triad

Engineering Inc conducted a focused groundwater assessment at the former Coyne

International Enterprises Corp building (Coyne Building) which is located at 1111 Vernon

Street Westmoreland District Wayne County West Virginia The following summarizes

field activities and analytical results of this assessment Figure 1 Site Location Map

illustrates the location of the site

On October 32008 five temporary groundwater hionitoring points were installed using a

direct-push technology sampling unit A groundwater sample was collected from each

monitoring point and analyzed by a WVDEP certified laboratory for VOC as per United

States Environmental Protection Agency (USEPA) method SW-8260B Three monitoring

points were installed in the area of groundwater monitoring well MW-5 between the Coyne

Building and the CSX Transportation inc rail line and two monitoring points were installed

to the immediate north of the CSX Transportation Inc rail line Groundwater was

encountered at a depth of approximately 30-feet below ground surface (bgs) Figure 2

Sample Location Map illustrates the locationof the groundwater monitoringpoints and

physical features located within the sample area

WWWTRIADENGCOM

Practical Engineering and Science Solutions Since 1975

AR100282

Wayne County Economic Development Authority Groundwater Assessment Coyne TextileServices Building Westmoreland District Wayne County West Virginia October 24 2008 -

Page 2

FIGURE 1 SITE LOCATION MAP Huntington WVa USGS 75-minute Topographic Quadrangle

1985

Laboratory analytical results were compared to the applicable WVDEP groundwater

maximum contaminant level (MCL) or de mnms values listed in Table 60-3 effective June

26 2008 Concentrations of VOC which exceeded the de minimis values were identified in

5 of 5 groundwater samples collected Tetrachloroethene (PERC) was detected in each of

the groundwater samples at concentrations which exceeded the de minimis values

Triehloroethene was detected in samples collected from GP-1 GP-3 and GP-5 at

concentrations which exceeded the de minimis values Cis-12-Dichloroethene was detected

in samples collected from GP-1 and GP-3 at concentrations which exceeded the de minimis

values Vinyl Chloride was detected in each sample except GP-5 at concentrations which

exceeded the de minimis values A summary of laboratory analytical reports is provided in

Table 1 Laboratory Analytical Summary-Groundwater and copies of the Laboratory

Analytical Reports are included as Attachmenf 1

AR100283

(9

00 S

P B B K ftVENIjEl

WEST MORELAND PARK

TENNIS BASKETBALL COURTS

GP-5 GP-4

9-inn i in iMMIMII I IMMII I I I I I I I IMI I I I I I IMI I I IMMII I I I I I I I I IMMII I I I I I IMI I I I I I I I I I I I IMI I I I I I I I I I I IMMII I I IMIMIMII I I I I I I I I I IMI I I I I I I I IMI I I I

CSX RAILROAD GP-2 GP-1 GP-3 I I I I I I I IMI I I IMMI I IMI I I I I I IMIMI I I IMI I I I I I I I I in i l lMI IMIMI I I I I IMMI I I I I I Jd I I IMj r i i y i l lMMI I I IMI I I I I I I I I in i l l l l l l lM l l l l l l l i n i l l l l l l l l ijj^lll^flH|t

bull

ACCESS ROAD

BUILDING

- bull

G P X ^

MM ^

MW

4-

bull ^

LEGEND

CW SAMPLE LOCAT10

MONITORING WELL

gtl

n

PARK ING

SCALE 1 r bull

WCEDA VRP GROUNDWATER SAMPLINGS HUNTINGTON WEST VIRGINIA

F I G U R E tslD

Cad Files04-08-p408-1dgn 6122009 24625 PM

- AR100284

Wayne County Economic Development Authority Page 3 Groundwater Assessment Coyne Textile Services Building Westmoreland District Wayne County West Virginia October 24 2008 _ bull ^

We appreciate the opportijnity to assist you with this project If you have any questions or r

need additional information please feel free to contact us

Sincerely TRIAD ENGINEERING INC

Matthew C Wright

Project Geologist

JohnM Meeks PG LRS

Project Manager

end

^

AR100285

Table 1 Laboratory Analytical Summary - Groundvvater WCEDA Vernon street

Huntington Wayne County West Virginia

COPC

Acetone Benzene Bromobenzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone sec-Butylbenzene n-Butyibenzene tert-Butylbenzene Carbon disulfide Carbon Tetrachloride Chlorobenzene Chlorodibromorriethane Ghloroethane Chlbroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene 12-Dibromo-3-chloropropane 12-Dlbronnoethane (EDB) DIbromomethane 14-Dichlorobenzene 13-Dictilorobenzene 12-Dictilorobenzene Dichlorodifluoromethane 11-Dlchloroethane 12-Dichloroethane cis-12-Dichloroethene

MCL ugL

5500 5

NV NV NV 85 87

700 61 61 61

1000 5

100 NV 39

bull 017 190 NV NV 02

005 NV

750 600 600 390 910

5 70

GP-1 ugL ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND

ND ND ND ND ND ND ND ND ND ND ND ND 112 ND

5210

GP-2 ugL ND ND ND

ND ND ND ND ND ND ND ND ND ND ND ND ND ND

062 J ND ND ND

ND ND ND ND ND ND ND ND

379

GP-3 ^ ugL

ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND

065 J ND 184 ND( ND ND ND

ND ND ND ND ND ND ND

12500

GP-4 ugL ND ND ND ND ND

- ND ND ND ND ND ND ND ND ND ND ND ND ND

ND ND ND ND ND ND ND ND ND ND ND 132

GP-5 ugL ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND

ND ND ND ND ND ND ND ND ND ND ND ND 59

Notes - Bold Indicates COPCs detected at concentrations greater than the MCL bull(60CSR3 Table 60-3B July 2008)

NAME - J indicates analyte detected at levels less than the reporting limit and greater than

or equal to the MDL value is estimated -NV indicates no value has been established

AR100286

Table 1 Laboratory Analytical Summary - Groundwater (Continued) WCEDA Vernon street

Huntington Wayiie County West Virginia

COPC

11-Dichloroethene trans-12-Dichloroethene 13-Dichloropropane 12-Dichloropropane 22-Dichloropropane cis-13-Dichloropropene trans-13rDichloropropene 11-Dichloropropene Ethylbenzene Hexachlorobutadiene 2-Hexanone Isopropylbenzene p-lsopropyltoluene Methyl tert-Butyl Ether Methylene Chloride 4-Methyl-2-pentanone Naphthalene n-Propylbenzene Styrene 1112-Tetrachloroethane 1122-Tetrachloroethane Tetrachloroethene Toluene 123-Trichlorobenzene 124-Trichlorobenzene 112-Trichloroethane 111-Trlchloroethane Triehloroethene Trichlorofluoromethane 123-Trichloropropane 135-Trimethylbenzene 124-Trimethylbenzene Vinyl chloride Xylenes total s

MCL ugL

91 100 04

5 NV NV NV NV

700 086

NV NV

NV 028

5 NV 62 NV 100

043 0055

5 1000

NV 70

5 20

5 1300

0034 120 120

2 10000

GP-1 ugL 964 458 ND ND

ND ND ND ND

052 J ND ND ND ND ND ND ND ND ND ND ND ND

14700 065 J ND ND ND ND

2850 ND

ND ND ND 116 146 J

GP-2 ugL ND ND ND ND ND ND ND- ND ND ND ND ND -ND ND ND ND ND ND ND ND ND

603 ND ND ND ND ND

079 J ND ND ND ND 242 ND

GP-3 ugL 346 865 ND ND

bull ND ND ND-ND

055 J ND ND ND ND ND ND ND ND ND ND ND ND

13900 159 ND ND ND ND

4870 ND ND ND ND 708 149 J

GP-4 ugL ND ND ND ND ND ND ND ND ND ND ND

ND 177 ND ND ND ND ND ND ND ND

583 ND ND ND ND ND

082 J ND ND ND ND

227 ND bull

GP-5 ugL ND ND ND ND ND

ND ND ND ND ND ND ND ND

ND ND ND ND ND ND ND ND 133 ND ND ND ND ND

574 ND ND

ND ND 122 ND

Notes - Bold indicates COPCs detected at concentrations greater than the MCL

(60CSR3 Table 60-3B July 2008) - ND indicates non-detected at concentrations greater than the MCL - J indicates analyte detected at levels less than the reporting limit and greater than

or equal to the MDL value is estimated - NV indicates no value has been established

AR100287

Risk-Based Rerfiedies

R B R Consulting Inc 650 Shady Drive Beaver Falls PA 15010

Phone724-846-4096 Fax 724-846-6974

MEMORANDUM

TO John Meeks Triad Engineering Inc

FROM Bruce Fishman

DATE September 82009

SUBJECT Evaluation of Potential Risks Associated with Vapor Intrijsion to Indoor Air Coyne Textile Services Facility - Huntington West Virginia

bull V bull bull bull

This memorandum presents a risk evaluation for potential risks associated with vapor intrusion to indoor air at the Coyne Textile Services Facility located in Huntington West Virginia (site) This evaluation was conducted according to West Virginia Department of Environmental Protection (WVDEP) and United States Environmental Protection Agency (USEPA) methodologies

DATA INCLUDED 1N THE EVALUATION

This evaluation includes three subslab vapor samples (VP-01 VP-02 and VP-03) collected from immediately beneath the floor of the existing site building Table 1 lists the subslab vapor samples included in this risk assessment Samples were analyzed for volatile organic compounds (VOCs) by USEPA Method TO-15 Complete analytical data for these samples are provided in Table A-1 of Appendix A

The analytical results of the subslab vapor samples were compared to the target shallow soil gas comparison values presented in Table 2c of the USEPA vapor intrusion guidance document (2002a) These companson values are generic soil gas screening values that are protective of indoor air for residential land uses and represent concentrations in-sliallow soil gas based on a target risk level of 1 x 10reg andor a hazard index of 1 The comparison is presented in Table 2

As indicated in Table 2 the following constituents are identified as contaminants of concern (COC) for the vapor intrusion to indoor air pathway 124-trimethylbenzene 12-dichloroethene (cis) chloroform methylene chloride tetrachloroethene and triehloroethene

ESTIMATION OF INDOOR AIR CONCENTRATIONS

The concentrations of COC in indoor air associated with vapor intrusion from subslab vapor were estimated using methodologies outlined in the Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings (USEPA 2004) A transport factor (TF) is required that will relate the

Page 1 of 5 -

AR100288

Risk-Based Remedies

R B R Consulting Inc

constituent concentration in subslab vapor to the concentration in indoor air The TF is dependent on the diffusion coefficient and other properties that will affect the transfer of constituents into air such as distance from the source to tlie breathing zone soil properties and building properties A site-specific building size of 84000 square feet (Dolphin 2000) and a soil type of sandy loam were used in the calculation of TF The TF is determined using calculationsbased on the Johnson and Ettinger (1991) vapor intrusion model Details of the TF calculations are provided in Appendix B

Subslab vapor concentrations are converted to indoor air concentration by applying the TF as follows

Cja ^ Csubslab X I r

The TF for each COC along with the resulting concentrations of COC in indoor air are presented in Tables

EXPOSURE EVALUATION

Noncarcinogenic health effects are evaluated by calculating the average dose of a constituent over the course of the exposure period This dose is termed the Average Daily Dose (ADD) Potential carcinogenic health effects are evaluated in terms of an individuals theoretical increased risk of developing cancer over a lifetime Although the duration of exposure to a constituent release generally does not last for an entire lifetime constituent intake for carcinogens is estimated as the average dose over a human lifetime (70 years) This lifetime dose applies specifically to the evaluation of carcinogenic effects and is termed tine Lifetime Average Daily Dose (LADD) In a risk assessment the calculated ADD or LADD are estimated quantitatively using assurnptions about the duration frequency and magnitude of exposure experienced by each potential receptor and assumptions about the constituent properties that influence absorption

The quantitative estimation of constituent intake involves the incorporation of numerical assumptions for a variety of exposure parahneters Exposure assumptions used in these intake calculations are based on WVDEP (2001) or USEPA (1989 2002b) recommended values The factors and equation for inhalation of vplatiles is presented in Table 4 and described below

bull Inhalation Rate and Exposure Time WVDEP (2001) and USEPA (2002b) guidance recommend that an inhalation rate of 20 m day be used for workers For an exposure time of 8 hours (a typical workday) this results in an inhalation rate of 25 m hour

bull Exposure Frequency and Duration Default exposure factors for indoor workers are provided by WVDEP (2001) Exposure frequency for the worker is 5 days per week for 50 weeks a year or 250 days per year The exposure duration for these workers is 25 years which is the 95th percentile value ai cording to the Bureau of Labor Statistics (USEPA 1989)

bull Body Weight The default value for average body weight of an adult is 70 kg based on WVDEP (2001) and USEPA guidance (1989 2002b)

Page 2 of 5

AR100289

Risk-Based Remedies

R B R Consulting Inc

bull Averaging Time As described above the doses for noncarcinogenic health effects are averaged oyer the specific period of exposure for a given receptor Noncarcinogenic

averaging times are therefore calculated by multiplying the exposure duration for the receptor by 365 daysyear Carcinogenic health effects are calculated over a lifetime exposure so the value recommended by WVDEP (2001) and USEPA (2002b) for average lifetime 70 years was used for exposure duration The resulting carcinogenic averaging time is 25550 days

TOXICITY VALUES

Noncarcinogenic responses are evaluated numerically using parameters known as the hazard quotient (HQ) and hazard index (HI) the HQ is obtained by dividing the ADD for a constituent by the reference dose (RfD) Each dose calculation with a specific combination of constituent receptor and exposure pathway will have a distinct ADD and calculated HQ HQs associated with all constituents for a particular pathway are summed to yield the HI

In order to estimate the theoretical excess lifetime cancer risk the LADD of a constituent is multiplied by the cancer slope factor (CSF) For each pathway this calculation is carried out for each applicable constituent and the risks are summed to obtain the total potential risk due to that pathway

Toxicity values for each constituent are presented in Table 5 the toxicity values were obtained from the following sources

bull Integrated Risk Information System (IRIS) on-line database provided by USEPA (2009)

bull The USEPAs Provisional Peer-Reviewed Toxicity Values (PPRTV) as presented in the USEPA Regional Screening Tables (ORNL 2009)

bull Provisional value from the National Center for Environmental Assessnient (as per WVDEP)

bull The Agency for Toxic Substances and Disease Registrys (ATSDR) Minimal Risk Levels (MRLs ATSDR 2009) and

bull Value cited by USEPA Region 3 attributed to other sources (as per WVDEP)

RISK CHARACTERIZATION

Potential noncarcinogenic effects associated with exposure to COC at the site are estimated by comparing calculated intakes with the contaminant-specific RfDs The total HI was calculated by summing the individual HQs An HI value equal to or less than 1 indicates thatthelikelihopd of ah adverse noncancer effect would be negligible (USEPA 1989) An HI greater than 1 indicates that additional evaluation of the case is warranted

Theoretical excess lifetime cancer risks associated with exposure to COC from the site were calculated by comparing estimated intakes to constituent-specific CSFs Summed theoretical

Page 3 of 5

AR100290

Risk-Based Remedies

R B R Consulting Inc

excess risks are calculated by combining constituent-specific risks The results may be compared with target benchrharks for acceptable risk Various demarcations of acceptable risk have been established by regulatory agencies WDEP (2001) presents a target cancer risk of 1 x 10 for nonresidential scenarios USEPA (1991) considers potential cancer risks in the range of 1 x 10reg to 1 X 10 to be acceptable

Constituent-specific results for the indoor worker are presented in Table 6 For the indoor worker exposed to COC in indoor air (vapor intrusion from subslab vapor) the total HI is 00081 and the potential cumulative cancer risk is 497 X 10reg

These results meet both WVDEP and USEPA benchmarks indicating that the site poses negligible potential for human health risk for indoor workers

CONCLUSIONS

The results of this focused risk evaluation indicate that potential risks associated with vapor intrusion exposure of indoor workers to constituents that may volatilize from subslab vapor are within the acceptable benchmarks established by WVDEP and USEPA No further evaluation of the vapor intrusion pathway is warranted for the site

REFERENCES

Agency for Toxic Substances and Disease Registry (ATSDR 2009) Minimal Risk Levels (MRLs) Available at httpvtfwwatsdrcdcqovmrisindexhtml

Dolphin Environmental LLC (Dolphin 2000) Site Characterization Report Mach 14 2000

Johnson PC and RA Ettinger (1991) Heuristic model for predicting the intrusion rate of contaminant vapors into buildings Environ Sci Technology 25 1445-1452

Oak Ridge National Laboratory (ORNL 2009) Regional Screening Levels for Chemical Contaminants at Superfund Sites April 15 2009 Available online httpwwwepagovreg3hwmdriskhumanrb-concentration_tableindexhtm

United States Environmental Protection Agency (USEPA 1989) Risk Assessment Guidance for Superfund Volume I PartA Human Health Evaluation Manual EPA5401-89002

United States Environmental Protection Agency (USEPA 1991) Risk Assessment Guidance for Superfund Volume I Part B Development of Risk-Based Remediation Goals Office of Emergency and Remedial Response OSWER Directive 92857-018

United States Environmental Protection Agency (USEPA 2002a) Draft Guidance for Evaluating the Vapor Intrusion to Indoor Air Pathway from Groundwater and Soils Office of Solid Waste and Emergency Response Pub No 92856-10 December 2002

Page 4 of 5

AR100291

Risk-Based Remedies

R B R Consul t ing Inc

United States Environmental Protection Agency (USEPA 2002b) Supplemental Guidance for Calculating Soil Screening Levels for Superfund Sites Office of Solid Waste and Emergency Response December

United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004

United States Environmental Protection Agency (USEPA 2009) Integrated Risk Information System (IRIS) On-line database wwwepaqoviris

West Virginia Department of Environmental Protection (WVDEP 2001) West Virginia Voluntary Remediation and Redevelopment Act-Guidance Manual Version 21 March 13

Page 5 of 5

AR100292

TABLES

AR100293

TABLE 1 SUBSLAB VAPOR SAMPLES INCLUDED IN THE RISK ASSESSMENT

Coyne text i le Services Facility - Huntington West Virginia

Medium

Subslab Vapor

Sample Identification

bull VP-01

VP-02

VP-03

Sample Date

8132009

8132009

8132009

Coyne VIMemo Tables_09-08-09xls 982009

AR100294

TABLE 2 IDENTIFICATION OF CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR

Coyne Textile Services Facility - Huntington West Virginia

mdash

Const i tuent

Volati le Organics

111-Trichlor6ethane

1122-Tetrachloroethane

112-Trichloro-122-trifluoroethane

112-Trichloroethane

11-Dichloroethane

11-Dichloroethene

124-Trichlorobenzene

124-Trimethylbenzene

12-Dibromoethane

12-Dichlor6benzene

12-Dichloroethane

12-Dichloroethene (cis)

12-pichloroethene (trans)

12-Dichloropropane

12-Dichlorotetraf1uoroethane

135-Trimethylbenzene

13-Butadiene

13-Dichlorobenzene

13-Hexachlorobutadiene

14-Dichlorpbenzene

224-trimethylpentane

2-Chlorotoluene

4-Ethyltoluene

Acetone

Allyl Chloride

Benzene

Bromodichloromethane

Bromoform

Bromomethane

Carbon disulfide bull

Carbon tetrachloride

ChJorobenzene

Chloroethane

Frequency of Detection

0 3

0 3

0 3

bull 0 3

0 3

0 3

0 3

1 3

0 3 bull

0 3

b 3 bull

2 3

0 3

bull 0 3

0 3

0 3

0 3 bull

0 3

0 3

0 3

0 3

0 3

0 17

3 3

0 3

P 3

- 0 3

0 3

0 3

0 3

0 3

0 3

0 3

Min imum Detected

Concentrat ion

(ugm^)

ND

ND

ND

ND

ND

- ND

N D

197

ND bull

ND

ND

369

ND

bull~ ND

ND

ND

ND

ND

ND

bull ND

ND

ND

ND

796

ND

ND

ND-

ND

ND

ND

ND

ND

ND

Maximum

Detected Concentrat ion

(ugm3)

ND

ND

ND

ND

ND

ND

ND

197

ND

ND

ND

mdash 6030

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

1880

ND-

ND

ND

ND

ND

ND

ND

ND

ND

Sample wi th Maximum Detect

ND

ND

ND

ND

ND

ND

- ND

VP-03 -

ND

ND

ND

VP-03

ND

bullND

ND

ND

ND

ND

ND

ND

ND

ND

ND

VP-02

ND

ND bull

ND

ND

ND bull

bull ND

ND

ND

ND

Min imum Detection

Limit (ugm3)

22

28

31

22

16

16

30

20

31

24

16

bull 16

16

19

28

20

89

24 bull

43

24

bull 19

2 1

20

--^ 13

13

27

41

16

13

25

18

11

Maximum Detection

Limit (ugm3)

218

275

307

218

162

159

297

197

307

240

162

- 16

159

185

280

197

89

240

427

240

187

207

197

--125

128

268

414

155

125

252

184

106

Vapor Intrusion Corhparison

V a l u e

(ugm)

22000

042

300000

15

bull 5000

2000

2000

60

011

2000

094

350

700

40

NA

60

0087

1100

11

8000

NA

NA

NA

3500

NA

31

14

22

50

7000

16

bull 600

100000

Chemical of Concern

No

No

No

No

No

No

No

YES

No

No

No

YES

No

No

No

N o bull

bullNo

No

No

No

No

No

No

N o

No

No

No

N o

No

No

No

No

No

Comment

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent notdetected

fflaximCimTdeteetlSffieedsTcomDarisonivalues

Constituent not detected

Constituent not detected

Constituent not detected

Maximum detect exceeds comparison value

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Maximum detect below comparison value

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detectedl

Constituent not detected

Constituent not detected

CoyneVI Memo Tables_09-08-09xls 982009

AR100295

TABLE 2

IDENTIFICATION OF CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR

Coyne Textile Services Facility - Huntington West Virginia

Const i tuent

Volati le Organics

Chloroform -

Chloromethane

13-Dichloropropene (cis)

Cyclohexarie^

Dibrcimochloromethane

DichlonDdifluoromethane

Ethylbenzene

Methyl ethyl ketone

Methyl isobutyl ketone

Methyl tert-butyl ether

Methylene chloride

n-Heptane

n-Hexane

Styrene

Tert-butyl alcohol

Tetrachloroethene

Toluene

13-Dichloropropene(trans)

Triehloroethene

Trichlorofluoromethane

Vinyl bromide

Vinyl chloride

Xylene (0)

Xylenes (mampp)

Frequency of Detection

1 3

0 3

0 3

1 3

0 3

0 3

0 -3

1 3

0 3

0 3

2 3

0 3

3 3

0 3

0 3

3 3

1 3

- 0 3

3 3

P 3

0 3

0 3

1 3

1 3

Min imum Detected

Concentrat ion

(ugm)

5910

ND

ND

52

ND

ND

ND

23

ND

ND

1160

ND

1 4 4

ND

ND

11200

18

ND

91

ND

ND

ND

208

387

Maximuri i Detected

Concentrat ion (ugmS)

bull

5910

ND

ND

52

bull ND

ND

ND

23

ND

ND

1520

ND

183

ND

ND

149000

18

ND

7820

ND

bullND

ND

208

387

Sample vyith Max imum Detect

VP-02

ND

ND

VP-01

bull ND

ND

ND

VP-01

ND

ND

VP-02

ND

VP-02

ND

ND

VP-02

VP-01

ND

VP-03

ND

ND

ND

VP-03

VP-03

Min imum Detection

Limit (ugm3)

20

83

18

138

34

bull 20

17

118

16

14

14

16

- -17

12

--151

18

--23

18

10

1 7 bull

1 7 bull

Maximum Detection

Limit (ugm3)

195

83

182

138

341

198

174

118

164

144

14

164

170

121 -

--151

182

225

175

102

bull 174

174

Vapor Intrusion Compar ison

V a l u e

(ugm)

11

24

NA

2000

1

2000

22

10000

800

30000

52

NA

2000

10000

NA

81

4000

NA

022

7000

NA

28

70000

70000

Chemical o f Concern

YES

No

No

No

No bull

No

No bull

No bull=

No

No

YES

No

No

No

No

YES

No

No

YES

N o

No

No

No

No

Comment

Maximum detect exceeds comparison value

Constituent not detected

Constituent not detected

Maximum detect below comparison value

Constituent not detected

Constituent not detected

Constituent not detected

Maximum detect below comparison value

Constituent not detected

Constituent not detected

Maximum detect exceeds comparison value

Constituent not detected bull

Maximum detect below comparison value

Constituent not detected

Constituent not detected

Maximum detect exceeds comparison value

Maximum detect below comparison value

Constituent not detected

Maximum detect exceeds comparison value

Constituent not detected

Constituent not detected

Constituent not detected bull

Maximum detect below comparison value

Maximum detect below comparison value

Notes

ND - Not Detected

NA - Not Available

- - Constituent detected in every sample detection limit not presented

Values in bold indicate detection limit exceeds comparison values

Target shallow soil gas comparison values corresponding to indoor air concentrations where the soil gas to indoor air attenuation factor = 01 and the target cancer risk is set to ip (presented in Table 2c of USEPA 2002a)

Comparison value for cyclohexane is based on the comparison value for hexane

Coyne VI Memo Tables_09-08-09xls 982009

AR100296

TABLES

EXPOSURE POINT CONCENTRATIONS FOR CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR

Coyne Textile Services Facility - Huntington West Virginia

Chemical of Concern

VolatileOrganics

i24-Trimethylbenzene

12-Dichloroethene (cis)

Chloroform

Methylene chloride

Tetrachloroethene Triehloroethene

Subslab Vapor Source

Concentration (mgm^)

0197

603

591

152

149 782

Transport

Factor^ (unitless)

108E-05

108E-05

108E-05

108E-05

108E-05 108E-05

EPC in

Indoor Air (mgm^)

213E-06

651 E-05

638E-05

164E-05

161E-03 844E-05

Notes

^ Subslab vapor source concentration is based on the maximum detected concentration of samples

VP-01-02 and-03 (see Table 2) -

^ Details of the transport factor calculations are presented in Appendix B

^ Exposure Point Concentration (EPC) in inidoor air is calculated as the subslab vapor concentration TF

Coyne VI Memo Tables_09-08-09xls 982009

AR100297

TABLE 4

FACTORS USED IN DOSE CALCULATIONS INHALATION OF VOLATILE EMISSIONS

Coyne Textile Services Facility - Huntington West Virginia

Symbol

CA

IRA

ET

EF

ED-

BW

AT

Exposure Factor

Constituent Concentration in Air

Inhalation Rate

Exposure Time

Exposure Frequency

Exposure Duration

Body Weight

Averaging Time

Indoor Worker

Constituent-Specific See Table 3

25 m hour

8 hrday

250 daysyear

25 years

bull 70 kg

9125 days (NC)

25550 days (C)

Total Dose = CA x IR^ x ET x EF x ED x 1BW x 1AT

(NC) - Non-carcinogenic Averaging Time

(C) - Carcinogenic Averaging Time

Coyne VI Memo Tables_09-08-09xls 982009

AR100298

TABLES TOXICITY VALUES FOR CHEMICALS OF CONCERN

Coyne Textile Services Facility - Huntington West Virginia

Chemical of Concern

Volatile Organics

124-Trimethylbenzene

12-Dichloroethene (cis)

Chloroform

Methylene chloride

tetrachloroethene

Triehloroethene

Target Organ Critical Effect

blood

bullblood

liver

liver

liver CMS

liver kidney fetus CNS

Chroniclnhalation Reference Dose

(mgkg-day)

200E-03 P

1 OOE-02 R

140E-02 E

286E-01 M

771 E-02 M

1OOE-02 E

Inhalation Cancer ^ Slope Factor

(mgkg-day)^

NA

NA

805E-02 1

165E-03 1

200E-02 0

400E-01 E

(I) - Integrated Risk Information System (IRIS USEPA 2009)

(P) - Provisional Peer-Reviewed Toxicity Value (PPRTV) as presented in USEPA Regional Screening Tables (ORNL 2009)

(R) - Calculated assuming route-to-route extrapolation as per WVDEP

(E)-Provisional value from the National Center for Environmental Assessment (as per WVDEP)

(M)-Chronic Minimal Risk Level (MRL ATSDR 2009)

(0) - Value cited by USEPA Region 3 attributed to other sources (as per WVDEP)

Coyne VI Memo Tables_09-08-09xls 982009

AR100299

TABLE 6

NONCANCER HAZARD INDEX AND POTENTIAL CANCER RISK FOR AN INDOOR WORKER

Coyne Textile Services Facility - Huntington West Virginia

bull

Constituent

Volatile Organics

124-Trinnethylbehzene

12-Dichlorpethene (cis)

Chloroform

Methylene chloride

Tetrachloroethene Triehloroethene

EPC in Indoor Air

(mgm)

213E-06

651 E-05

- 638E-05

164E-05

161 E-03

844E-05

Intake (ADD)

(mgkg-d)

416E-07

127E-05

125E-05

321 E-06

315E-04 l65E-05

RfDi

(mgkg-d)

200E-03

1OOE-02

140E-02

286E-01

771 E-02 1 OOE-02

Hazard

Quotient

208E-04

127E-03

892E-04

112E-05

408E-03 165E-03

Intake (LADD)

(mgkg-d)

) 149E-07

455E-06 bull 446E-06

115E-06

112E-04 590E-06

CSFi

(mgkg-d)

NA

NA

805E-02

165E-03

200E-02

400E-01

Potential

Cancer Risk

NA

NA

359E-07

189E-09

225E-06 236E-06

Total Hazard Index

00081 Total

Cancer Risk 497E-06

Total Blood HI = Total Liver HI =

Total Central Nervous System HI = Total Kidney HI =

Total Fetal HI =

bull 00015 00066 00057 00017 00017

Notes NA = Toxicity values are not available for this endpoint or exposure pathway

Coyne VI Memo Tables_09-08-09xls 982009

AR100300

APPENDIX A

SUBSLAB VAPOR ANALYTICAL DATA

AR100301

Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility Huntington West Virginia

Sample

Consti tuent

Volatile Organics (ugm) 111-Trlchloroethane 1122-Tetrachloroethane 112-Trichloro-122-trifluoroethane 112-Trichloroethane 11-Dichioroethane 11-Dichloroethene 124-Trichloroberi2ene 124-Trimethylbenzene 12-Dibromoethane 12-Dichloroben2ene 12-Dichloroethane 12-Dichloroethene-(cis) -12-Dichloroethene (trans) 12-Dichloropropane 12-Dichlorotetrafluoroethane 135-Trimethylbenzene 13-Butadiene 13-Dichlorobenzene 13-Hexachlorobutadiene 14-Dichlorobenzene 224-trimethVlpentane 2-Chlorotoluene 4-Ethyltoluene Acetone Allyl Chloride Benzene Bromodichloromethane Bromoform Bromomethane Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 13-Dichloropropene (cis) Cyclohexane Dibromochloromethane

Identif ication Sample Date

CAS No

71-55-6 79-34-5 76-13-1 79-00-5 75-34-3 75-35-4 120-82-1 95-63-6 106-93-4 95-50-1 107-06-2 156-59-2 156-60-5 78-87-5 76-14-2 108-67-8 106-99^0 541-73-1 87-68-3 106-46-7 540-84r1 95-49-8

622-96-8 67-64-1 107-05-1 71-43-2 75-27-4 75-252 74-83-9 75-15-0 56-23-5 108-90-7 75-00-3 67-66-3 74-87-3

10061-01-5 110-82-7 124-48-1

lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt

lt lt lt lt lt lt lt lt lt lt lt lt

lt

VP-01 8132009

22 28 31 22 16 16 30 20 31 24 16 16 16 19 28 20 89 24 43 24

1 9 21 20 796 13 13 27 41 16 13 25 18 11 20 83 18 52 34

lt lt lt lt lt lt lt lt lt lt lt

lt lt lt lt lt lt lt lt lt lt lt

lt lt lt lt lt lt lt lt lt

lt lt lt lt

VP-02 8132009

218 2 7 5 307 218 162 159 297

bull 197 307 240 162 369 159 185 280 197 89

240 427 240 187 207 197

1880 125 128 268 414 155 125 252 184 106

5910 83 182 138 341

lt lt lt lt lt lt lt

lt lt lt

lt lt lt lt lt lt lt bull

lt lt lt lt

lt lt lt lt lt lt lt lt lt lt lt lt lt lt

VP-03 8132009

218 275 307 218

bull 162 159 297 197 307 240 162

6030 159 185 280 197 89

240 427 240 187 207 197

1750 125 128 268 414 155 125 252 184 106 195 83 182 138 341

Appx A SG Dataxis Page 1 of 2 982009

AR100302

Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility bull Huntington West Virginia

Consti tuent

Volatile Organics (ugm^) Dichlorodifluoromethane Ethylbenzene Methyl ethyl ketone Methyl Isobutyl ketone Methyl tert-butyl ether Methylene chloride n-Heptane jn-Hexane Styrene Tert-butyl alcohol Tetrachloroethene iToluene 13-Dichloropropene (trans) Triehloroethene Trichlorofluoromethane Vinyl bromide Vinyl chloride Xylene (o) Xylenes (mampp)

Sample Identif ication Sample Date

CAS No

75-71-8 100-41-4 78-93-3 108-10-1

1634-04-4 75-09-2

142-82-5 bull 110-54-3

100-42-5 75-65-0 127-18-4 108-88-3

10061-02-6 79-01-6 75-69-4 593-60-2 75-01-4 95-47-6

179601-23-1

lt lt

lt lt lt lt

lt lt

lt

lt lt lt lt lt

VP01 8132009

20 17 23 16 14 14 16

173 17 12 bull

11200 18 18 91 23 18 10 17 17

lt lt lt lt lt

lt

lt lt

lt lt

lt lt lt lt lt

VP-02 8132009

198 174 118 164 144

1520 164 -183 170 121

149000 151 182

2360 225 175 102 174 174

VP-03 8132009

lt 198 lt 174 lt 118 lt 164 lt 144

1160 lt 164

144 lt 170 ltbull 121

90500 lt 151 lt 182

7820 lt 225 lt 175 lt 102

208 387

Appx A SG Dataxis Page 2 of 2 982009

AR100303

APPENDIX B

CALCULATION OF TRANSPORT FACTORS USED TO ESTIMATE INDOOR AIR CONCENTRATIONS

AR100304

APPENDIX B

Calculation of Transport Factors Used to Estimate Indoor Air Concentrations

This appendix presents the methodology for calculating transport factors that are used to convert subslab

vapor concentrations to concentrations in indoor air 124-Trimethylbenzene 12-dichloroethene (cis)

chloroform methylene chloride tetrachloroethene and triehloroethene were identified as contaminants of

concern (COC) for potential vapor intrusion from subslab vapor associated with the Coyne Textile

Services Facility located in Huntington West Virginia (site) In this appendix the transport factors are

calculated to estimate the concentrations of COC in indoor air of the existing plant building located at the

site ~

Transport Factor for Indoor Air

The concentration of a constituent in indoor air (da) is proportional to the concentration of the constituent

in the subslab vapors immediately beneath the building foundation (ie subslab vapor concentration or

Csubsiab) The following equation is used to calculate da from Csubsiab

^ wja ~ ^subslab X I r

where

Cia = concentration of constituent in indoor air (mgm^) -

Csubsiab^ concentration of constituent in subslab vapors (mgm^) and

TF = transport factor from subslab vapors to indoor air

The transport factor (TF) is an infinite source attenuation coefficient andcan be calculated based on a

model developed by Johnson and Ettinger (1991) t he equation for calculating TF is as follows

(Deff X A B ) ( Q B X L T ) X expKQso i l X Lcrabk)(Dcrack X Acrack)]

exp[ (Qsoi l X Lcrack)(Dcrack X Acrack)] + (Deff X A B ) ( Q B X L T ) + (Deff X AB)(Qsoi l X L j ) X (exp [ (Qso i l X Lcrack)(Dcrack X Acrack)] - 1)

where

Deff = effective diffusion coefficient for vadose zone soil (cm^sec)

AB = area of enclosed space below grade (cm^)

QB = building ventilation rate (cm^sec)

LT = distance from contaminant source to building foundation (cm)

Qsoii = volumetric flow rate of vapors into the building (cm^sec)

Lcrack = foundatlon thickness (cm)

Dcrack = vapor diffusion coefficient through crack (cm^sec) and

Acrack = area of cracks through which vapors can pass (cm^)

AR100305

To solve this equation the USEPAs SG-ADV spreadsheet Version 31 most recently updated in

February 2004 was implemented A combination of site-specific factors and default values from the

Users Guide for Evaluating Subsurface Vapor Intrusion Into Buildings (USEPA 2004) were used as input

values in the model All input values are defined below and presented in Tables B-1-A through B-6-A

bull The initial subslab vapor concentration (Csubsiab) is the maximum detected concentration(in units

of ugm ) of samples VP-01 VP-02 and VP-03 that was presented in Table 3 of the report

bull The depth below grade to the bottom of the enclosed space floor (Lp) is set to 15 cm the default

value provided by USEPA (2004) for a slab-on-grade structure

bull The vapor sampling depth below grade (Lg) is a site-specific value The vapor samples were

collected from immediately beneath the building floor therefore Lj has been set to 15 cm

bull The average soilgroundwater temperature (Ts) is set to 125degC the average value for West

Virginia as estimated frorri Figure 8 of the vapor intrusion users guide (USEPA 2004)

bull The soil type used to estimate vapor permeability is assumed to be sandy loam (SL) The

associated soil properties for a sandy loam soil type are as follows the soil dry bulk density (Pb) is

162 gcm the total porosity (n) is 0387 (cm^-aircm^) and the water-filled porosity (nw) is 0103

(cm -HzOcm )

bull The floor thickness (Lcrack) is set to the USEPA (2004) default value of 10 cm

bull The soil-building pressure differential (AP) is set to the USEPA (2004) default value of 40 gcm-s^

bull The building dimensions are siterspecific based on the existing plant building located at the site

The existing structure is approximately 84000 square feet (Dolphin 2000) therefore the

dimensions are set to 8839 cm (290 feet) length by 8839 cm (290 feet) The USEPA (2004)

default value of 244 cm vyas used for the height

bull Thefloor-wall seam crack width (w) is set to the USEPA (2004)-default value of 01 cm

bull The indoor air exchange rate (ER) is set to 083hour This is the value provided by ASTM (2002)

for commercial and industrial buildings

AR100306

Tables B-1-B through B-6-B present the constituent-specific properties for COC that were used in the TF

calculations Tables B-1-C through B-6-C present the intermediate calculations used to determine the

indoor air attenuation coefficients (ie the transport factors) The shaded boxes in Tables B-1-C through

B-6-C also present the resulting TF values that are applied to the concentrations of COC in subslab

vapor and the estimated indoor air concentrations

References

American Society for Testing and Materials (ASTM 2002) Standard Guide for Risk-Based Corrective Action Applied at Petroleum Release Sites ASTM E-1739-95 (Reapproved 2002)

Johnson PC and RA Ettinger (1991) Heuristic model for predicting the intrusion r-ate of contaminant vapors into buildings Environ Sci Technolpgy 25 1445-1452

Dolphin Environmental LLC (Dolphin 2000) Site Characterization Report Mach 14 2000

United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004

AR100307

APPENDIX B-1-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV Nersion31 0204

Reset to Defaults

ENTER -

Chemical CAS No

(numbers only

no dasties)

95636

ENTER Soil gas

cone

Cg (ngm)

Soil Gas Concentration Data ENTER

Soil gas

OR cone

bull - c bull (PPmv)

197E+02

Chemical

124-Trimethylbenzene

MORE ENTER Depth

below grade to bottom

of enclosed space floor

U bull (cm)

ENTER

Soil gas sampling

depth below grade

U (cm) bull

ENTER

Average soil

temperature Ts

CO

1 15 1 1 5 bull125

ENTER ENTER ENTER Totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hft ha he

(cm) (cm) (cm)

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estirnate OR permeability | soil vapor

permeability) k v bull

(cm)

SL 1 1

MORE ENTER

stratum A SCS

soil type

Lookup Soil Parameters

ENTER stratum A soil dry

bulk density P

(gcm)

ENTER Stratum A soil total porosity

(unitless)

ENTER bull stratum A soil water-filled

porosity

(cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

nlaquo

(unitless)

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gchi-s^)

ENTER Enclosed

space floor

length bull LB

(cm)

ENTER Enclosed

space floor

width WB

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

bull Floor-wall seam crack

width w

(cm)

bullENTER

Indoor air exchange

rate ER

(1h) bull

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bidg OR

Leave blank to caicuij

(Lm)

Appx B-1 124-TMBxls 1 of 3 982009

AR100308

APPENDIX B-1-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of ^ bull law constant law constant vaporization at Normal

Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temperature boiling point point temperature weight

D bull Dbdquo H T R bull AHbdquo TB Tc IVIW

Unit risk Reference

factor cone URF RfC

(cms) (cmls) (atm-mmol) CO (calmol) (degK) (degK) (gmol) bull (ugm)- (mgm)

1 606E-02 1 792E-06 1 bull 614E-C3 1 25 1 9369 1 44230 | 64917 1 12020 1 OOE+00 1 60E-03 1

Appx B-1 124-TMBxls 2 of 3 982009

AR100309

APPENDIX B-1-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

(sec)

Source-building

separation

LT bull

(cm) bull

Stratum A soil

air-filled porosity

Q A

Stratum B soil

air-filled porosity

(cmcm) (cmcm)

Stratum C soil air-filled porosity

(cmcm)

Stratum A effective total fluid

saturation

Se

(cmcm)

Stratum A soil

bullintrinsic permeability

^ (cm)

stratum A Stratum A Floor- soil soli wall BIdg

relative air effective vapor seam Soil bull ventilation permeability permeability perimeter gas rate-

kfg ky Xgrack c o n e - QbuHdinpound

(cm) - (cm) (cm) (ngm) (cms)

946E+08 1 0284 0284 0284 0184 596E-09 0901 537E-09 35357 I 197E+02 | 439E+06 |

Area of enclosed

space below grade

As (cm)

Crack-to-total area ratio

1 bull

(unitless)

Crack depth

below grade

Zcfack

(cm)

Enthalpy of vaporization at

ave soil temperature

AHvjs

(calmol) bull

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law constant at

ave soil bull temperature

bull HTS

(unitless)

Vapor bull viscosity at

ave soil temperature

HTS

(gcm-s)

Stratum A

effective diffusion

coefficient

D (cms)

Stratum-B

effective diffusion coefficient

DB (cms)

Stratum C effective diffusion

coefficient

D-c (cms)

Total - overall effective diffusion

coefficient

D ^ (cms)

Diffusion path

length

L-

(cm)

I 787E+07 I 449E-05 | 15 | 11661 260E-03 111E-01 176E-04 I 612E-03 j OOOE+00 | OOOE+00 | 612E-03 j

bull Convection path

length

Lp

(cm)

Source vapor cone

^source

(ngm)

Crack radius

Tcfack

(cm)

Average vapor

flow rate into bIdg

Qsoii

(cms)

Crack effective diffusion

coefficient pcrack

(cms)

Area of CTack

Acack

(cm)

Exponent of equivalent foundation

Peclet number

exp(Pe)

(unitless)

bull bull - bull bull bull bull

1 15 1 197E+02 1 010 1 474E+01 612E-03 bull 354E-t-03 1 336E+09

Infinite source Indoor

~ attenuation coefficient

a

(unitless)

108E-05

Infinite source

btJbldgjJSv-L ^Ppncji3i-

virhpbiiilding bullbull ^lHltti^m)ilg

213E-03

Unit risk

factor

URF

(ngm)-

Reference cone

RfC (mgm)

NA 60E-03 1

I END

Appx B-1 124-TMBxls 3 of 3 982009

AR100310

APPENDIX B-2-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV Nersion31 020^

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

156592

Soil Gas Concentration Data ENTER

Soil gas

cone OR c

(ngm) bull

ENTER Soil bull-gas

cone

c (ppmv)

603E+03 1

Chemical

cis-12-Dichloroethylene

MORE ENTER Depth

below grade to bottom

of enclosed space floor

LF

(cm)

ENTER

Soil gas sampling

depth below grade

U (cm)

ENTER

Average soil

temperature bull Ts

(degC)

1 15 1 bull 15 125

ENTER ENTER ENTER Totalsmust add ijp tb value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hA hB he

bull (cm) (cm) (cm)

15 1 1

ENTER Soil

straturh A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estimate OR permeability | soil vapor

permeability) kv

(cm)

SL 1 |

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

P (gcm)

ENTER Stratum A soil total porosity

bull n

(unitless)

ENTER Stratum A

soil water-filled porosity

(cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

ENTER Stratum B

soil water-filled porosity

ENTER Stratum C

SCS soil type

(unitless) (cmcm)

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure differential

AP

(gcm-s)

ENTER Enclosed bull

space floor

length

LB (cm)

ENTER Enclosed

space floor

width WB

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER

Average vapor flow rate into bIdg

OR Leave blank to calculi

Qsoil

(Lm)

Appx B-2 cis-12-DCExls 1 of 3 982009

AR100311

APPENDIX B-2-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Diffusivity in air

Da

(cms)

Diffusivity in water

Dw (cms)

Henrys law constant at reference temperature

H

(atm-mmoi)

Henrys law constant

reference temperature

bull T R

CC)

Enthalpy of vaporization at

the normal boiling point

AHbdquob

(calmol)

Normal boiling point

TB

(degK)

Critical temperature

Tc (degK)

Molecular weight

MW

(gmol)

Unit risk

factor URF

(ngm)

Reference cone

RfC (mgm)

1 736E-02 1 113E-05 1 407E-03 j 1 25 1 bull 7192 1 33365 1 54400 1 9694 1 OOE+00 j 35E-02 1

Appx B-2 cis-12-DCExls 2 of 3 982009

AR100312

APPENDIX B-2-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

stratum A Stratum B Stratum C Source- soil soil soil

Exposure building air-filled air-filled air-filled

duration separation porosity porosity porosity

T LT ea e^ bull e= (sec) (cm) (cmcm) (cmcm) (cmcm)

I 946E+08n^

Stratum A Stratum A Stratum A Stratum A Floor-effective soil soil soil wall total fluid intrinsic relative air effective vapor seam

saturation permeability permeability permeability perimeter

Ste kj krg ky Acrack

(cmcm) (cm) (cm) (cm) (cm)

Soil gas

cone (ngm)

I 0284 I 0284~ 0284 0184 I 596E-09 | 090T 537E-09 35357 603E+03

BIdg ventilation

rate

JbulldinE

(cms)

439E+06

Area of enclosed

space below grade

AB

(cm)

Crack-to-total

area ratio

n (unitless)

Crack depth below grade

Zltiack (cm)

Erithalpy of vaporization at

ave soil temperature

AHvTs (calmol)

Henryslaw constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law constant at

ave soil temperature

HTS

(unitless) bull

Vapor viscosity at

ave soil bull temperature

HTS

bull (gcm-s)

Stratum A

effective bull diffusion

coefficient

D^A-(cms)

Stratum B

effective bull diffusion

coefficient

D=B

(cms)

Stratum C

effective diffusion bull

coefficient

D=e (cms)

Total overall

effective diffusion

coefficient

DT

(cms)

Diffusion path

length

Ld

(cm)

I 787E+07 I bull449E-05 | 15 bull7709 230E-03 982E-02 176E-04 | 743E-03 | OOOE+00 | OOOE+00 | 743E-03 |

bull bull bull -

Convecfion path -bull

length

Lp (cm)

Source vapor cone

-source

(Mgm)

Crack radius

fcrack

(cm)

Average vapor

flow rate into bIdg

Qaoil bull

(cms)

Crack effective diffusion

coefficient pcack

(cms)

Area of crack

crack

(cm)-

Exponent of equivalent foundation

Peclet number

exp(Pef)

(unitless)

bull

1 15 -1 603E+03 1 010 1 474E+01 743E-03 354E+03 1 697E+07

Infinite source Indoor

attenuation coefficient

poundbullbullbull C t

pound(unitless)

bullsiilaquogt j ii08E-05

Infinite [ source

bIdg cone

Cbujidjng

(pgm)

651 E-02 iKrt

Unit risk

factor

URF

(ngm)-

Reference cone

RfC

(mgm)

NA 35E-02 1

I END I

Appx B-2 cis-12-DCExls 3o f3 982009

AR100313

APPENDIX B-3-A DATA ENTRY SHEET

Coyne Texti le Services - Hunt ington West Virginia

SG-ADV Version 31 0204

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

67663

Soil Gas Concentration Data ENTER ENTER

Soil Soil gas gas

cone OR cone c C

(^gm) (ppmv)

591 E+03

bull

Chemical

Chloroform

MORE ENTER Depth

below grade tb bottom

of enclosed space floor

bull LF

(cm)

ENTER

Soil gas sampling depth

below grade

(cm)

ENTER

Average soil

temperature-Ts

CO bull

1 15 1 15 1 125

ENTER ENTER ENTER Totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

IIA hs he (cm) (cm) (cm)

1 5 bull 1 1

ENTER ENTER Soil - bull

stratum A User-defined SCS stratum A

soil type bull soil vapor (used to estimate OR permeability

soil vapor k

bull permeability) (cm) 1

SL 1 1 bull

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A soil dry

bulk density

Pb (gcm)

ENTER Stratum A soil total porosity

nV (unitless)

ENTER Stratum A

-soilwater-filled bullporosity

Sraquo (cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

(unitless)

ENTER Stratum B

soil water-filled porosity

bull ebdquo=

(cmcm) bull

ENTER Straturri C

SCS bull soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

- c rack

(cm)

ENTER

Soil-bldg pressure

differential AP^

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor

width bull W B

(cm)

ENTER

Enclosed space

height HB

(cm)

ENTER

bull Floor-wall^ seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bidg OR

Leave blank to calculi

Qsoil bull

(Lm)

I -I

Appx B-3 Chloroformxls 1 of 3 982009

AR100314

APPENDIX B-3-B CHEMICALPROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Diffusivity in air

D (cms)

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffijsivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature

Dbdquo H TR A H bdquo TB Tc

(cm s) (atm-m mol) ro (calmol) (degK) (degK)

Molecular weight

MW

(gmol)

Unit risk

factor URF

(ngm)-

Reference cone

RfC

(mgm)

104E-01 100E-05 I 366E-03 25 6988 33432 53640 11938 I 23E-05 | OOE+00

Appx B-3 Chloroformxls 2 of 3 982009

AR100315

APPENDIX B-3-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure

duration

(sec)

Source-

building

separation

LT

(cm)

Stratum A

soil

air-filled

porosity

Sa

( cm cm )

Stratum B

soil

air-filled

porosity

( cm cm )

Stratum C

soil

air-filled

porosity

( c m c m )

Stratum A

effective

total fluid

saturation

( c m c m )

Stratum A

soil

intrinsic

penmeability

k

(cm )

Stratum A

- soil

relative air

permeabil i ty

(cm )

Stratum A

soil

effective vapor

permeability

kv

(cm )

Floor-

wall

seam

perimeter

gtcrack

(cm)

Soil gas

cone

(ngm)

BIdg

venfilation

rate

^buildlriE

(cms)

I 9 4 6 E + 0 8 ~ T I 0284 T 596E-09 I 0-901 I 537E-09 | 35357 | 591 E+03 j 439E+06 | 1 0 284 0284 0184

Area of

enclosed

space

below

grade

A B

( c m )

Crack-

to-total

area

ratio

n

(unitless)

Crack

depth

bull below

grade

^crack

(cm)

Enthalpy of

vaporization at

ave soil

temperature

AHTs bull

(calmol)

Henry s law

constant at

ave soil

temperature

HTS

(a tm-m mol j

Henrys law

constant at

ave soil

bull temperature

HTS

(unitless) bull

Vapor

viscosity at

ave soil-

temperature

^HTS

(gcm-s)

Stratum

A

effective

diffusion

coefficient

(cm s)

Stratum

B

effective

difftjsion

coefficient

D B

(cms) bull

S t ra tum

C

effective

diffusion

coefficient

Dc

(cm s)

Total

overall

effective

bull diffusion

coefficient

D T

(cm s)

Diffi jsion

path

length

Ld

(cm)

I 787E+07 I 449E-05 j - bull 15 7528 210E-03 896E-02 176E-04 I 105E-02 | OOOE+00 | OOOE+00 | 105E-02

Convection

path length

Lp

(cm)

Source

vapor

cone -

^source

- (ngm)

Crack

radius

Tcrack

(cm)

Average

vapor

flow rate

into bidg

Qsoil

(cms)

Crack

effective

diffusion

coefficient Qcrack

bull (cms)

Area of crack

Acrack

(cm)

Exponent of

equivalent

foundation

Peclet number

exp(Pe)

(unitless)

V bull bull

1 15 1 591 E+03 1 010 1 474E+01 105E-02 354E+03 1 355E+05

Infinite

source

indoor

attenuation

coefficient

d

(unitless)

bull 108E-05

Infinite

source

bIdg

cone

^ b u i l d i n g

i (^gm)

bull bull

i 638E-02 -

Unit

risk bull factor

URF

(ngmY

Reference

cone

RfC

(mgm)

~ 23E-05 NA 1

I END

Appx B-3 Chloroform xls 3 of 3 982009

AR100316

APPENDIX B-4-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ersion 31-020^

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

nodashes)

bull 75092

ENTER Soil gas

cone

c (ngm)

Soil Gas Concentration Data ENTER

Soil gas bull

OR cone

bull C

(ppmv)

152E+03

bull bull

Chemical

Methylene chloride

MORE

MORE 4gt

ENTER Depth

below grade to bottom

of enclosed space floor

LF -

(cm)

ENTER

Soil gas sampling depth

below grade

bull U

(cm)

ENTER

Average soil

temperature

Ts bull CC)

bull bull bull bull

1 15 1 15 125

ENTER Totals

Thickness of soil

stratum A h

(cm)

ENTER ENTER must add up to value of Ls (cell F24

Thickness Thickness of soil of soil

stratum B stratum C (Enter value or 0) (Enter value or 0)

he he bull

(cm) bull (cm) -

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(usedto estimate OR perrrieability | soil vapor

permeability)

k bull

(cm)

SL 1 bull 1

ENTER Stratum A

SCS soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

Pb (gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Stratum A

soil water-filled porosity

9w (cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

Pb^

(gcm)

ENTER Stratum B soil total porosity

n^

(unitless)

ENTER Stratum B

soil water-filled porosity

(crhcm)

ENTER Stratum C

SCS soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE 4gt

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

bull Soil-bldg pressure

differential AP^

(gcm-s)

ENTER Enclosed

space floor

length LB

(cm)

ENTER Enclosed

space floor

width bull W B

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width

w

(cm)

ENTER

Indoor air exchange

rate

ER (1h)

ENTER Average vapor

flow rate into bidg OR

Leave blank to calculc

Qsoil

(Lm)

10 40 8839 8839 244 01 083

Appx B-4 MCxIs 1 of 3 982009

AR100317

Diffijsivity in air

D

APPENDIX B-4-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffusivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature

Pw H TR AHt TB TC

Molecular weight

MW

Unit risk

factor URF

Reference cone

RfC

(cms) (cms) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) bull (ngm)- (mgm)

bull bull

1 101E-01 1 117E-05 1 218E-03 1 25 | 6706 1 31300 1 51000 1 8493 1 47E-07 1 30E+00 1

Appx B-4 MCxIs 2 of 3 982009

AR100318

APPENDIX B-4-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

T

(sec)

Source- -building

separation

LT

(cm)

Stratum A soil

air-filled porosity

e a bull

(cmcm)

Stratum B soil

bullair-filled porosity bull

ea^ (cmcm)

Stratum C soil

air-filled porosity

ea= (cmcmj

Stratum A effective total fluid

saturation

Sc bull

(cmcm)

Stratum A soil

intrinsic pemneability

ki (cm)

Stratum A soil

relative air permeability

^ ^ g

(cm)

stratumA bull soil effective vapor permeability

K (cm)

Floor-wall

seam perimeter

Xcrack

(cm)

Soil gas

cone (ngm)

BIdg ventilation

rate

Qbuildinc

(cms)

1 946E+08

Area of -enclosed

space below

bull grade

AB

(cm)

1

Crack-to-total

area rafio

Tl

(unitless)

0284 1

Crack depth below grade

Zcrack

(cm)

0284 1

bull Enthalpy of vaporization at

ave soil temperature

AHTs (calmol)

0284

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

0184

Henrys law constant at ave soil

temperature

HTS

bull (unitless)

1 596E-09

Vapor viscosity at

ave soil temperature

Mrs (gcm-s)

0901

Stratum A

effective diffusion

coefficient

D (cms)

537E-09

Stratum B

effective diffusion

coefficient

D-B (cms)

35357 1

Stratum C -

effective diffusion

coefficient

D-c ^ (cms)

152E+03

Total bull overall

bull effective diffusion

coefficient

D ^

(cms)

440E+06 1

Difftjsion path

length

Ld (cm)

1 787E+07

Convection path

length

Lp (cm)

4 49E-05

Source vapor cone

Csource

(ngm)

15 1

Crack radius

Tcrack

(cm)

7007 bull 1

Average vapor

flow rate intobldg

Qsoil

(cms)

130E-03

Crack effective diffusion

coefficient pcrack

(cms)-

555E-02

bull ^

Area of crack

Acrack

(cm) bull

1 176E-04

Exponent of equivalent foundation

Peclet number

exp(Pe)

(unitless) bull

bull bull

1 15

1 END

152E+03 010 1 474E+01 1 102E-02 354E+03 1 519E+05

102E-02

Infinite source

indoor ^attenuation coefficient

bull a

(unitless)

aiii08E-05

0 OOE+00

bull

Infinite bull source

bIdg ^ cone

^bu i l d i ng

(MQm)

164E-02

OOOE+00 1

Unit risk

factor

URF

(ngm)-

47E-07 1

102E-02 j

Reference cone

RfC

(mgm)

30E+00 j

1 1

Appx B-4 MCxIs 3 of 3 982009

AR100319

APPENDIX B-5-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ^erslon 31 0204

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

127184

Soil Gas Concentration Data ENTER ^ ENTER

Soil -Soi l bull gas gas

cone OR cone Cg C bull

(tgm) (ppmv)

149E+05 1

Chemical

bull Tetrachlbroethylene

MORE 4

ENTER Depth

below grade to bottom

ofenclosecJ space floor

LF

(cm)

ENTER

Soil gas bull sampling

depth below grade

u bull (cm)

ENTER

Average bullsoil

temperature - Ts

ro 1 1 5 1 15 1 125 bull

ENTER ENTER ENTER totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hft bull he bull he

(cm) (cm) (cm)

bull 1 5 1 - 1

ENTER ENTER Soil

stratum A User^defined bull SCS bull stratum A soil type soil vapor

(used to estimate OR perrrieability soil vapor K bull

permeability) (cm) 1

SL 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

Pb

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Sitratum A

soil water-filled bull porosity

(cmcm)

ENTER Stratum B

SCS soiltype

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

Pb^

(gcm)

ENTER Stratum B soil total porosity

Ajnitless^

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS soil type

LookupSoil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

VS

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor width

W B

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width

w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

ENTER Average vapor

flow rate into bidg OR

Leave blank to calcul

bull Qsoil

(Lm)

10 40 8839 8839 244 01 083

Appx B-5 PCExIS 1 of 3 982009

AR100320

APPENDIX B-5-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal Unit

Diffusivity Diffusivity at reference reference the riormal boiling Critical Molecular risk Reference in air in water temperature temperature boiling point point teriiperature weight factor cone

Da Dbdquo H TR AHb TB Tc MW URF RfC

(cms) (cnis) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) (^gm)- (mgm)

1 720E-02 1 820E-06 1 184E-02 1 25 1 8288 1 39440 1 62020 1 16583 1 59E-06 1 60E-01 1

J

AppxB-5PCExls 2 of 3 - 982009

AR100321

APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

T

(sec)

Source-building

separation

LT

bull (cm)

Stratum A soil

air-filled porosity

Oa (cmcm)

Stratum B - soil air-filled porosity

ea (cmcm)

Stratum C soil

air-filled porosity

ea= - (cmcm)

Stratum A effective total fluid

saturation

sbdquo (cmcm)

Stratum A soil

intrinsic permeability

ki (cm)

Stratum A soil

relative air permeability

- ^ g

(cm)

Stratum A soil

effective vapor permeability

kv (cm)

Floor-wall

seam perimeter

^crack

(cm)

Soil gas

cone

(ngm)

BIdg venfilation

rate

Qbuildins

bull (cms)

bull bull

1 946E+08

Area of enclosed

space below grade

AB

(cm)

1

bullCrack-to-total

area ratio

1 (unitless)

0284 1

Crack bull depth below grade

Zcrack

(cm) -

0284 1

Enthalpy of vaporization at bull

ave soil temperature

bull A H V TS

(calmol)

0284

Henrys law constant at

ave soil temperature

HTS (atm-mmol)

0184

-Henrys law constant at

ave soil temperature

HTS

(unitless)

1 596E-09

Vapor viscosity at

ave soil temperature

HTS

(gcm-s)

0901

Stratum A

effective diffusion

coefficient bull D = bull

(cms)

537E-09

Stratum B

effective diffusion

coefficient

D--B (cms)

35357 1

Stratum C

effective diffusion bull

coefficient

D-c (crris)

149E+05

Total overall

effective bulldiffusion coefficient

DT

(cms)

440E+06 1

Difftjsion path

length

U (cm)

1 787E+07

Convection path

length

bull Lp

(cm)

4 49E-05

Source vapor cone

^source

(ngm)

15 1

Crack radius

Tcrack

(cm)

9528 1

Average vapor

flow rate intobldg

Qsoil (cms)

908E-03

Crack effective diffusion

coefficient pcrack

bull ( c m s ) bull

387E-01

Area of crack

Abdquoack (cm)

1 176E-04

Exponent of equivalent foundafion

Peclet number

exp(Pe)

(unitless)

bull

1 15-

1 END

149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08

727E-03

Infinite source indoor

attenuation coefficient

a

(unitless)

108E-05

OOOE+00

Infinite source

bIdg cone

Cburldtng

(Mgm)

161 E+00

OOOE+00 1

Unit risk

factor

URF

(ugm)-

59E-06 1

727E-03

Reference cone

RfC (mgm)

60E-01

1 1

Appx B-5 PCExls 3 of 3 982009

AR100322

APPENDIX B-6-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ersion31 0204

Reset to Defaults

t

Soil Gas Concentration Data ENTER

Chemical CAS No

(numbers only

no dashes)

79016

ENTER ENTER Soil Soil gas gas

cone OR cone C C -

bull (ngm) (ppmv)

782E+03

Chemical

Trichloroethylene

MORE ENTER Depth

below grade to bottom-

of enclosed space floor

LF

(cm)

ENTER

Soil gas sarnpling

depth below grade

U (cm)

ENTER

Average soil

temperature Ts

(degC)

1 15 1 15 t 125

ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e

(cm) (cm) (cm)

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estimate OR permeability soil vapor

permeability)

k (cm)

bull S L 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil bull-Parameters

ENTER Stratum A

soil dry bulk density

P b -

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Stratum A bull

soilwaterrfilled porosity

(cmcm) bull

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

bull P ^ (gcm)

ENTER Stratum B soil total

porosity

nlaquo

(unitless) -

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS bull soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor

width W B

(cm)

ENTER

Enclosed space height

H B bull

( c m ) bull

ENTER

Floor-wall seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bIdg OR

Leave blank to calculc

Qsoil

(Lm) -

Appx B-6 TCExIs 1 of 3 982009

A

AR100323

APPENDIX B-6-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight

Da Dbdquo H TR AH^b TB TC MW

Unit risk Reference

factor cone URF RfC

(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)

1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1

Appx B-6 TCExIs 2 of 3 982009

AR100324

APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

(sec)

Source-building

separation LT

(cm)

Stratum A soil

air-filled porosity

bull ea (cmcm)

Stratum B Soil

air-fllled porosity

e^ bull (cmcm)

Stratum C soil

air-filled porosity

(cmcm)

StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air

saturation permeability permeability

S|e k krg (cmcm) (cm) (cm)

Stratum A Floor-soil wall BIdg

effective vapor seam Soil ventilafion permeability perimeter gas rate

k^ bull Xack c o n e Qbuildins

(cm) (cm) (ngm) (cms)

946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |

Area of enclosed

space below grade

AB

(cm)

Ciack- to-total

area ratio

1 (unitless)

Crack depth below grade

Zcrack

(cm)

Enthalpy of vaporization at

ave soil temperature

A H J S

(calmol)

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law bull constant at

ave soil temperature

HTS

(unitless)

Vapor viscosity at

ave soil temperature

|JTS

(gcm^s)

Stratum A

effective diffusion

coefficient

(cms)

Stratum B

effective -diffusion

coefficient

D=B (cms)

Stratum ^ C effective diffusion

coefficient

D=c (cms)

Total overall

effective diffusion

coefficient

DT

(cms)

I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03

Diffusion path

length

Li (cm) bull

Convection bull path

length

Lp

(cm)

Source vapor cone bull

^source

(ngm)

Crack radius

rcrack

(cm)

Average vapor

- flow rate intobldg

Qsoil

(cms)

Crack effective diffusion

bull coefficient Qcrack

(cms)

Area of crack

^crack

(cm)

Exponent of equivalent foundation

Peclet bull number

exp(Pe)

(unitless)

bull bull

1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07

Infinite source Indoor

attenuation coefficient

a

(unitless)

108E-05

Infinite source

bIdg concgt

^building

(ngm)

844E-02

Unit risk

factor

URF

(ngm)-

Reference cone

RfC

(mgm)

1 1E-04 1 40E-02 1

END

Appx B-6 TCExIs 3 of 3 982009

AR100325

Office of Waste Management 1356 Hansford Street

Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256

West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director

ORDER

ISSUED UNDER THE

HAZARDOUS WASTE MANAGEMENT ACT

CHAPTER 22 ARTICLE 18

OF THE WEST VIRGINIA CODE^ AS AMENDED

y Order Number HW-011-80

To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704

ATTEMTION MREDARMON

Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull

AR100326

ViWJ011-laquo9 PageNunil)er2

BASIS FOR ORDER

As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following

A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^

B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator

C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities

0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94

^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement

P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following

1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater

2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was

^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment

CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable

CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order

AR100327

H W - 0 1 1 - 9 9 Page Number 3

REQUIREMENTS OF ORDER

Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows

1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^

2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore

remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling

GENERAL PROVaiONS

1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order

2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order

3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order

Effective Date

Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief

Wt T 1 V Oflice of Waste Management

AR100328

^ ^ S I S

^wmmmmamn

AR100329

Page 4: SDMS DocID 2121999 · International Enterprises Corp. building (Coyne Building), which is located at 1111 Vernon Street, Westmoreland District, Wayne County, West Virginia. The following

n nnp

n n n i -

n nnt^ -

n nnt -

n nriA -

0003 -

n nn

n nni -

n -

^ ^ bull

1 2 4 bull 5

TCE 307 - 309

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17

PCE 3 01-3 09

003

0005

Cis 12 DCE 301 - 309

AR100281

CIVIL bull ENVIRONMENTAL AND GEOTECHNICAL ENGINEERING

4980 Teays Valley Road Scott Depot WV 25560 Phone 3047550721 Fax 3047551880 TRIAD ENGINEERING INC

October 24 2008

Mr Robert Trocin Wayne County Economic Development Authority PO Box 519 Wayne VVest Virginia 25570

Subject Groundwater Assessment Former Coyne International Enterprises Corp Building Westmoreland District Wayne County West Virginia

Dear Mr Trocin

On behalf of the Wayne County Economic Development Authority (WCEDA) Triad

Engineering Inc conducted a focused groundwater assessment at the former Coyne

International Enterprises Corp building (Coyne Building) which is located at 1111 Vernon

Street Westmoreland District Wayne County West Virginia The following summarizes

field activities and analytical results of this assessment Figure 1 Site Location Map

illustrates the location of the site

On October 32008 five temporary groundwater hionitoring points were installed using a

direct-push technology sampling unit A groundwater sample was collected from each

monitoring point and analyzed by a WVDEP certified laboratory for VOC as per United

States Environmental Protection Agency (USEPA) method SW-8260B Three monitoring

points were installed in the area of groundwater monitoring well MW-5 between the Coyne

Building and the CSX Transportation inc rail line and two monitoring points were installed

to the immediate north of the CSX Transportation Inc rail line Groundwater was

encountered at a depth of approximately 30-feet below ground surface (bgs) Figure 2

Sample Location Map illustrates the locationof the groundwater monitoringpoints and

physical features located within the sample area

WWWTRIADENGCOM

Practical Engineering and Science Solutions Since 1975

AR100282

Wayne County Economic Development Authority Groundwater Assessment Coyne TextileServices Building Westmoreland District Wayne County West Virginia October 24 2008 -

Page 2

FIGURE 1 SITE LOCATION MAP Huntington WVa USGS 75-minute Topographic Quadrangle

1985

Laboratory analytical results were compared to the applicable WVDEP groundwater

maximum contaminant level (MCL) or de mnms values listed in Table 60-3 effective June

26 2008 Concentrations of VOC which exceeded the de minimis values were identified in

5 of 5 groundwater samples collected Tetrachloroethene (PERC) was detected in each of

the groundwater samples at concentrations which exceeded the de minimis values

Triehloroethene was detected in samples collected from GP-1 GP-3 and GP-5 at

concentrations which exceeded the de minimis values Cis-12-Dichloroethene was detected

in samples collected from GP-1 and GP-3 at concentrations which exceeded the de minimis

values Vinyl Chloride was detected in each sample except GP-5 at concentrations which

exceeded the de minimis values A summary of laboratory analytical reports is provided in

Table 1 Laboratory Analytical Summary-Groundwater and copies of the Laboratory

Analytical Reports are included as Attachmenf 1

AR100283

(9

00 S

P B B K ftVENIjEl

WEST MORELAND PARK

TENNIS BASKETBALL COURTS

GP-5 GP-4

9-inn i in iMMIMII I IMMII I I I I I I I IMI I I I I I IMI I I IMMII I I I I I I I I IMMII I I I I I IMI I I I I I I I I I I I IMI I I I I I I I I I I IMMII I I IMIMIMII I I I I I I I I I IMI I I I I I I I IMI I I I

CSX RAILROAD GP-2 GP-1 GP-3 I I I I I I I IMI I I IMMI I IMI I I I I I IMIMI I I IMI I I I I I I I I in i l lMI IMIMI I I I I IMMI I I I I I Jd I I IMj r i i y i l lMMI I I IMI I I I I I I I I in i l l l l l l lM l l l l l l l i n i l l l l l l l l ijj^lll^flH|t

bull

ACCESS ROAD

BUILDING

- bull

G P X ^

MM ^

MW

4-

bull ^

LEGEND

CW SAMPLE LOCAT10

MONITORING WELL

gtl

n

PARK ING

SCALE 1 r bull

WCEDA VRP GROUNDWATER SAMPLINGS HUNTINGTON WEST VIRGINIA

F I G U R E tslD

Cad Files04-08-p408-1dgn 6122009 24625 PM

- AR100284

Wayne County Economic Development Authority Page 3 Groundwater Assessment Coyne Textile Services Building Westmoreland District Wayne County West Virginia October 24 2008 _ bull ^

We appreciate the opportijnity to assist you with this project If you have any questions or r

need additional information please feel free to contact us

Sincerely TRIAD ENGINEERING INC

Matthew C Wright

Project Geologist

JohnM Meeks PG LRS

Project Manager

end

^

AR100285

Table 1 Laboratory Analytical Summary - Groundvvater WCEDA Vernon street

Huntington Wayne County West Virginia

COPC

Acetone Benzene Bromobenzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone sec-Butylbenzene n-Butyibenzene tert-Butylbenzene Carbon disulfide Carbon Tetrachloride Chlorobenzene Chlorodibromorriethane Ghloroethane Chlbroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene 12-Dibromo-3-chloropropane 12-Dlbronnoethane (EDB) DIbromomethane 14-Dichlorobenzene 13-Dictilorobenzene 12-Dictilorobenzene Dichlorodifluoromethane 11-Dlchloroethane 12-Dichloroethane cis-12-Dichloroethene

MCL ugL

5500 5

NV NV NV 85 87

700 61 61 61

1000 5

100 NV 39

bull 017 190 NV NV 02

005 NV

750 600 600 390 910

5 70

GP-1 ugL ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND

ND ND ND ND ND ND ND ND ND ND ND ND 112 ND

5210

GP-2 ugL ND ND ND

ND ND ND ND ND ND ND ND ND ND ND ND ND ND

062 J ND ND ND

ND ND ND ND ND ND ND ND

379

GP-3 ^ ugL

ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND

065 J ND 184 ND( ND ND ND

ND ND ND ND ND ND ND

12500

GP-4 ugL ND ND ND ND ND

- ND ND ND ND ND ND ND ND ND ND ND ND ND

ND ND ND ND ND ND ND ND ND ND ND 132

GP-5 ugL ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND

ND ND ND ND ND ND ND ND ND ND ND ND 59

Notes - Bold Indicates COPCs detected at concentrations greater than the MCL bull(60CSR3 Table 60-3B July 2008)

NAME - J indicates analyte detected at levels less than the reporting limit and greater than

or equal to the MDL value is estimated -NV indicates no value has been established

AR100286

Table 1 Laboratory Analytical Summary - Groundwater (Continued) WCEDA Vernon street

Huntington Wayiie County West Virginia

COPC

11-Dichloroethene trans-12-Dichloroethene 13-Dichloropropane 12-Dichloropropane 22-Dichloropropane cis-13-Dichloropropene trans-13rDichloropropene 11-Dichloropropene Ethylbenzene Hexachlorobutadiene 2-Hexanone Isopropylbenzene p-lsopropyltoluene Methyl tert-Butyl Ether Methylene Chloride 4-Methyl-2-pentanone Naphthalene n-Propylbenzene Styrene 1112-Tetrachloroethane 1122-Tetrachloroethane Tetrachloroethene Toluene 123-Trichlorobenzene 124-Trichlorobenzene 112-Trichloroethane 111-Trlchloroethane Triehloroethene Trichlorofluoromethane 123-Trichloropropane 135-Trimethylbenzene 124-Trimethylbenzene Vinyl chloride Xylenes total s

MCL ugL

91 100 04

5 NV NV NV NV

700 086

NV NV

NV 028

5 NV 62 NV 100

043 0055

5 1000

NV 70

5 20

5 1300

0034 120 120

2 10000

GP-1 ugL 964 458 ND ND

ND ND ND ND

052 J ND ND ND ND ND ND ND ND ND ND ND ND

14700 065 J ND ND ND ND

2850 ND

ND ND ND 116 146 J

GP-2 ugL ND ND ND ND ND ND ND- ND ND ND ND ND -ND ND ND ND ND ND ND ND ND

603 ND ND ND ND ND

079 J ND ND ND ND 242 ND

GP-3 ugL 346 865 ND ND

bull ND ND ND-ND

055 J ND ND ND ND ND ND ND ND ND ND ND ND

13900 159 ND ND ND ND

4870 ND ND ND ND 708 149 J

GP-4 ugL ND ND ND ND ND ND ND ND ND ND ND

ND 177 ND ND ND ND ND ND ND ND

583 ND ND ND ND ND

082 J ND ND ND ND

227 ND bull

GP-5 ugL ND ND ND ND ND

ND ND ND ND ND ND ND ND

ND ND ND ND ND ND ND ND 133 ND ND ND ND ND

574 ND ND

ND ND 122 ND

Notes - Bold indicates COPCs detected at concentrations greater than the MCL

(60CSR3 Table 60-3B July 2008) - ND indicates non-detected at concentrations greater than the MCL - J indicates analyte detected at levels less than the reporting limit and greater than

or equal to the MDL value is estimated - NV indicates no value has been established

AR100287

Risk-Based Rerfiedies

R B R Consulting Inc 650 Shady Drive Beaver Falls PA 15010

Phone724-846-4096 Fax 724-846-6974

MEMORANDUM

TO John Meeks Triad Engineering Inc

FROM Bruce Fishman

DATE September 82009

SUBJECT Evaluation of Potential Risks Associated with Vapor Intrijsion to Indoor Air Coyne Textile Services Facility - Huntington West Virginia

bull V bull bull bull

This memorandum presents a risk evaluation for potential risks associated with vapor intrusion to indoor air at the Coyne Textile Services Facility located in Huntington West Virginia (site) This evaluation was conducted according to West Virginia Department of Environmental Protection (WVDEP) and United States Environmental Protection Agency (USEPA) methodologies

DATA INCLUDED 1N THE EVALUATION

This evaluation includes three subslab vapor samples (VP-01 VP-02 and VP-03) collected from immediately beneath the floor of the existing site building Table 1 lists the subslab vapor samples included in this risk assessment Samples were analyzed for volatile organic compounds (VOCs) by USEPA Method TO-15 Complete analytical data for these samples are provided in Table A-1 of Appendix A

The analytical results of the subslab vapor samples were compared to the target shallow soil gas comparison values presented in Table 2c of the USEPA vapor intrusion guidance document (2002a) These companson values are generic soil gas screening values that are protective of indoor air for residential land uses and represent concentrations in-sliallow soil gas based on a target risk level of 1 x 10reg andor a hazard index of 1 The comparison is presented in Table 2

As indicated in Table 2 the following constituents are identified as contaminants of concern (COC) for the vapor intrusion to indoor air pathway 124-trimethylbenzene 12-dichloroethene (cis) chloroform methylene chloride tetrachloroethene and triehloroethene

ESTIMATION OF INDOOR AIR CONCENTRATIONS

The concentrations of COC in indoor air associated with vapor intrusion from subslab vapor were estimated using methodologies outlined in the Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings (USEPA 2004) A transport factor (TF) is required that will relate the

Page 1 of 5 -

AR100288

Risk-Based Remedies

R B R Consulting Inc

constituent concentration in subslab vapor to the concentration in indoor air The TF is dependent on the diffusion coefficient and other properties that will affect the transfer of constituents into air such as distance from the source to tlie breathing zone soil properties and building properties A site-specific building size of 84000 square feet (Dolphin 2000) and a soil type of sandy loam were used in the calculation of TF The TF is determined using calculationsbased on the Johnson and Ettinger (1991) vapor intrusion model Details of the TF calculations are provided in Appendix B

Subslab vapor concentrations are converted to indoor air concentration by applying the TF as follows

Cja ^ Csubslab X I r

The TF for each COC along with the resulting concentrations of COC in indoor air are presented in Tables

EXPOSURE EVALUATION

Noncarcinogenic health effects are evaluated by calculating the average dose of a constituent over the course of the exposure period This dose is termed the Average Daily Dose (ADD) Potential carcinogenic health effects are evaluated in terms of an individuals theoretical increased risk of developing cancer over a lifetime Although the duration of exposure to a constituent release generally does not last for an entire lifetime constituent intake for carcinogens is estimated as the average dose over a human lifetime (70 years) This lifetime dose applies specifically to the evaluation of carcinogenic effects and is termed tine Lifetime Average Daily Dose (LADD) In a risk assessment the calculated ADD or LADD are estimated quantitatively using assurnptions about the duration frequency and magnitude of exposure experienced by each potential receptor and assumptions about the constituent properties that influence absorption

The quantitative estimation of constituent intake involves the incorporation of numerical assumptions for a variety of exposure parahneters Exposure assumptions used in these intake calculations are based on WVDEP (2001) or USEPA (1989 2002b) recommended values The factors and equation for inhalation of vplatiles is presented in Table 4 and described below

bull Inhalation Rate and Exposure Time WVDEP (2001) and USEPA (2002b) guidance recommend that an inhalation rate of 20 m day be used for workers For an exposure time of 8 hours (a typical workday) this results in an inhalation rate of 25 m hour

bull Exposure Frequency and Duration Default exposure factors for indoor workers are provided by WVDEP (2001) Exposure frequency for the worker is 5 days per week for 50 weeks a year or 250 days per year The exposure duration for these workers is 25 years which is the 95th percentile value ai cording to the Bureau of Labor Statistics (USEPA 1989)

bull Body Weight The default value for average body weight of an adult is 70 kg based on WVDEP (2001) and USEPA guidance (1989 2002b)

Page 2 of 5

AR100289

Risk-Based Remedies

R B R Consulting Inc

bull Averaging Time As described above the doses for noncarcinogenic health effects are averaged oyer the specific period of exposure for a given receptor Noncarcinogenic

averaging times are therefore calculated by multiplying the exposure duration for the receptor by 365 daysyear Carcinogenic health effects are calculated over a lifetime exposure so the value recommended by WVDEP (2001) and USEPA (2002b) for average lifetime 70 years was used for exposure duration The resulting carcinogenic averaging time is 25550 days

TOXICITY VALUES

Noncarcinogenic responses are evaluated numerically using parameters known as the hazard quotient (HQ) and hazard index (HI) the HQ is obtained by dividing the ADD for a constituent by the reference dose (RfD) Each dose calculation with a specific combination of constituent receptor and exposure pathway will have a distinct ADD and calculated HQ HQs associated with all constituents for a particular pathway are summed to yield the HI

In order to estimate the theoretical excess lifetime cancer risk the LADD of a constituent is multiplied by the cancer slope factor (CSF) For each pathway this calculation is carried out for each applicable constituent and the risks are summed to obtain the total potential risk due to that pathway

Toxicity values for each constituent are presented in Table 5 the toxicity values were obtained from the following sources

bull Integrated Risk Information System (IRIS) on-line database provided by USEPA (2009)

bull The USEPAs Provisional Peer-Reviewed Toxicity Values (PPRTV) as presented in the USEPA Regional Screening Tables (ORNL 2009)

bull Provisional value from the National Center for Environmental Assessnient (as per WVDEP)

bull The Agency for Toxic Substances and Disease Registrys (ATSDR) Minimal Risk Levels (MRLs ATSDR 2009) and

bull Value cited by USEPA Region 3 attributed to other sources (as per WVDEP)

RISK CHARACTERIZATION

Potential noncarcinogenic effects associated with exposure to COC at the site are estimated by comparing calculated intakes with the contaminant-specific RfDs The total HI was calculated by summing the individual HQs An HI value equal to or less than 1 indicates thatthelikelihopd of ah adverse noncancer effect would be negligible (USEPA 1989) An HI greater than 1 indicates that additional evaluation of the case is warranted

Theoretical excess lifetime cancer risks associated with exposure to COC from the site were calculated by comparing estimated intakes to constituent-specific CSFs Summed theoretical

Page 3 of 5

AR100290

Risk-Based Remedies

R B R Consulting Inc

excess risks are calculated by combining constituent-specific risks The results may be compared with target benchrharks for acceptable risk Various demarcations of acceptable risk have been established by regulatory agencies WDEP (2001) presents a target cancer risk of 1 x 10 for nonresidential scenarios USEPA (1991) considers potential cancer risks in the range of 1 x 10reg to 1 X 10 to be acceptable

Constituent-specific results for the indoor worker are presented in Table 6 For the indoor worker exposed to COC in indoor air (vapor intrusion from subslab vapor) the total HI is 00081 and the potential cumulative cancer risk is 497 X 10reg

These results meet both WVDEP and USEPA benchmarks indicating that the site poses negligible potential for human health risk for indoor workers

CONCLUSIONS

The results of this focused risk evaluation indicate that potential risks associated with vapor intrusion exposure of indoor workers to constituents that may volatilize from subslab vapor are within the acceptable benchmarks established by WVDEP and USEPA No further evaluation of the vapor intrusion pathway is warranted for the site

REFERENCES

Agency for Toxic Substances and Disease Registry (ATSDR 2009) Minimal Risk Levels (MRLs) Available at httpvtfwwatsdrcdcqovmrisindexhtml

Dolphin Environmental LLC (Dolphin 2000) Site Characterization Report Mach 14 2000

Johnson PC and RA Ettinger (1991) Heuristic model for predicting the intrusion rate of contaminant vapors into buildings Environ Sci Technology 25 1445-1452

Oak Ridge National Laboratory (ORNL 2009) Regional Screening Levels for Chemical Contaminants at Superfund Sites April 15 2009 Available online httpwwwepagovreg3hwmdriskhumanrb-concentration_tableindexhtm

United States Environmental Protection Agency (USEPA 1989) Risk Assessment Guidance for Superfund Volume I PartA Human Health Evaluation Manual EPA5401-89002

United States Environmental Protection Agency (USEPA 1991) Risk Assessment Guidance for Superfund Volume I Part B Development of Risk-Based Remediation Goals Office of Emergency and Remedial Response OSWER Directive 92857-018

United States Environmental Protection Agency (USEPA 2002a) Draft Guidance for Evaluating the Vapor Intrusion to Indoor Air Pathway from Groundwater and Soils Office of Solid Waste and Emergency Response Pub No 92856-10 December 2002

Page 4 of 5

AR100291

Risk-Based Remedies

R B R Consul t ing Inc

United States Environmental Protection Agency (USEPA 2002b) Supplemental Guidance for Calculating Soil Screening Levels for Superfund Sites Office of Solid Waste and Emergency Response December

United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004

United States Environmental Protection Agency (USEPA 2009) Integrated Risk Information System (IRIS) On-line database wwwepaqoviris

West Virginia Department of Environmental Protection (WVDEP 2001) West Virginia Voluntary Remediation and Redevelopment Act-Guidance Manual Version 21 March 13

Page 5 of 5

AR100292

TABLES

AR100293

TABLE 1 SUBSLAB VAPOR SAMPLES INCLUDED IN THE RISK ASSESSMENT

Coyne text i le Services Facility - Huntington West Virginia

Medium

Subslab Vapor

Sample Identification

bull VP-01

VP-02

VP-03

Sample Date

8132009

8132009

8132009

Coyne VIMemo Tables_09-08-09xls 982009

AR100294

TABLE 2 IDENTIFICATION OF CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR

Coyne Textile Services Facility - Huntington West Virginia

mdash

Const i tuent

Volati le Organics

111-Trichlor6ethane

1122-Tetrachloroethane

112-Trichloro-122-trifluoroethane

112-Trichloroethane

11-Dichloroethane

11-Dichloroethene

124-Trichlorobenzene

124-Trimethylbenzene

12-Dibromoethane

12-Dichlor6benzene

12-Dichloroethane

12-Dichloroethene (cis)

12-pichloroethene (trans)

12-Dichloropropane

12-Dichlorotetraf1uoroethane

135-Trimethylbenzene

13-Butadiene

13-Dichlorobenzene

13-Hexachlorobutadiene

14-Dichlorpbenzene

224-trimethylpentane

2-Chlorotoluene

4-Ethyltoluene

Acetone

Allyl Chloride

Benzene

Bromodichloromethane

Bromoform

Bromomethane

Carbon disulfide bull

Carbon tetrachloride

ChJorobenzene

Chloroethane

Frequency of Detection

0 3

0 3

0 3

bull 0 3

0 3

0 3

0 3

1 3

0 3 bull

0 3

b 3 bull

2 3

0 3

bull 0 3

0 3

0 3

0 3 bull

0 3

0 3

0 3

0 3

0 3

0 17

3 3

0 3

P 3

- 0 3

0 3

0 3

0 3

0 3

0 3

0 3

Min imum Detected

Concentrat ion

(ugm^)

ND

ND

ND

ND

ND

- ND

N D

197

ND bull

ND

ND

369

ND

bull~ ND

ND

ND

ND

ND

ND

bull ND

ND

ND

ND

796

ND

ND

ND-

ND

ND

ND

ND

ND

ND

Maximum

Detected Concentrat ion

(ugm3)

ND

ND

ND

ND

ND

ND

ND

197

ND

ND

ND

mdash 6030

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

1880

ND-

ND

ND

ND

ND

ND

ND

ND

ND

Sample wi th Maximum Detect

ND

ND

ND

ND

ND

ND

- ND

VP-03 -

ND

ND

ND

VP-03

ND

bullND

ND

ND

ND

ND

ND

ND

ND

ND

ND

VP-02

ND

ND bull

ND

ND

ND bull

bull ND

ND

ND

ND

Min imum Detection

Limit (ugm3)

22

28

31

22

16

16

30

20

31

24

16

bull 16

16

19

28

20

89

24 bull

43

24

bull 19

2 1

20

--^ 13

13

27

41

16

13

25

18

11

Maximum Detection

Limit (ugm3)

218

275

307

218

162

159

297

197

307

240

162

- 16

159

185

280

197

89

240

427

240

187

207

197

--125

128

268

414

155

125

252

184

106

Vapor Intrusion Corhparison

V a l u e

(ugm)

22000

042

300000

15

bull 5000

2000

2000

60

011

2000

094

350

700

40

NA

60

0087

1100

11

8000

NA

NA

NA

3500

NA

31

14

22

50

7000

16

bull 600

100000

Chemical of Concern

No

No

No

No

No

No

No

YES

No

No

No

YES

No

No

No

N o bull

bullNo

No

No

No

No

No

No

N o

No

No

No

N o

No

No

No

No

No

Comment

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent notdetected

fflaximCimTdeteetlSffieedsTcomDarisonivalues

Constituent not detected

Constituent not detected

Constituent not detected

Maximum detect exceeds comparison value

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Maximum detect below comparison value

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detectedl

Constituent not detected

Constituent not detected

CoyneVI Memo Tables_09-08-09xls 982009

AR100295

TABLE 2

IDENTIFICATION OF CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR

Coyne Textile Services Facility - Huntington West Virginia

Const i tuent

Volati le Organics

Chloroform -

Chloromethane

13-Dichloropropene (cis)

Cyclohexarie^

Dibrcimochloromethane

DichlonDdifluoromethane

Ethylbenzene

Methyl ethyl ketone

Methyl isobutyl ketone

Methyl tert-butyl ether

Methylene chloride

n-Heptane

n-Hexane

Styrene

Tert-butyl alcohol

Tetrachloroethene

Toluene

13-Dichloropropene(trans)

Triehloroethene

Trichlorofluoromethane

Vinyl bromide

Vinyl chloride

Xylene (0)

Xylenes (mampp)

Frequency of Detection

1 3

0 3

0 3

1 3

0 3

0 3

0 -3

1 3

0 3

0 3

2 3

0 3

3 3

0 3

0 3

3 3

1 3

- 0 3

3 3

P 3

0 3

0 3

1 3

1 3

Min imum Detected

Concentrat ion

(ugm)

5910

ND

ND

52

ND

ND

ND

23

ND

ND

1160

ND

1 4 4

ND

ND

11200

18

ND

91

ND

ND

ND

208

387

Maximuri i Detected

Concentrat ion (ugmS)

bull

5910

ND

ND

52

bull ND

ND

ND

23

ND

ND

1520

ND

183

ND

ND

149000

18

ND

7820

ND

bullND

ND

208

387

Sample vyith Max imum Detect

VP-02

ND

ND

VP-01

bull ND

ND

ND

VP-01

ND

ND

VP-02

ND

VP-02

ND

ND

VP-02

VP-01

ND

VP-03

ND

ND

ND

VP-03

VP-03

Min imum Detection

Limit (ugm3)

20

83

18

138

34

bull 20

17

118

16

14

14

16

- -17

12

--151

18

--23

18

10

1 7 bull

1 7 bull

Maximum Detection

Limit (ugm3)

195

83

182

138

341

198

174

118

164

144

14

164

170

121 -

--151

182

225

175

102

bull 174

174

Vapor Intrusion Compar ison

V a l u e

(ugm)

11

24

NA

2000

1

2000

22

10000

800

30000

52

NA

2000

10000

NA

81

4000

NA

022

7000

NA

28

70000

70000

Chemical o f Concern

YES

No

No

No

No bull

No

No bull

No bull=

No

No

YES

No

No

No

No

YES

No

No

YES

N o

No

No

No

No

Comment

Maximum detect exceeds comparison value

Constituent not detected

Constituent not detected

Maximum detect below comparison value

Constituent not detected

Constituent not detected

Constituent not detected

Maximum detect below comparison value

Constituent not detected

Constituent not detected

Maximum detect exceeds comparison value

Constituent not detected bull

Maximum detect below comparison value

Constituent not detected

Constituent not detected

Maximum detect exceeds comparison value

Maximum detect below comparison value

Constituent not detected

Maximum detect exceeds comparison value

Constituent not detected

Constituent not detected

Constituent not detected bull

Maximum detect below comparison value

Maximum detect below comparison value

Notes

ND - Not Detected

NA - Not Available

- - Constituent detected in every sample detection limit not presented

Values in bold indicate detection limit exceeds comparison values

Target shallow soil gas comparison values corresponding to indoor air concentrations where the soil gas to indoor air attenuation factor = 01 and the target cancer risk is set to ip (presented in Table 2c of USEPA 2002a)

Comparison value for cyclohexane is based on the comparison value for hexane

Coyne VI Memo Tables_09-08-09xls 982009

AR100296

TABLES

EXPOSURE POINT CONCENTRATIONS FOR CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR

Coyne Textile Services Facility - Huntington West Virginia

Chemical of Concern

VolatileOrganics

i24-Trimethylbenzene

12-Dichloroethene (cis)

Chloroform

Methylene chloride

Tetrachloroethene Triehloroethene

Subslab Vapor Source

Concentration (mgm^)

0197

603

591

152

149 782

Transport

Factor^ (unitless)

108E-05

108E-05

108E-05

108E-05

108E-05 108E-05

EPC in

Indoor Air (mgm^)

213E-06

651 E-05

638E-05

164E-05

161E-03 844E-05

Notes

^ Subslab vapor source concentration is based on the maximum detected concentration of samples

VP-01-02 and-03 (see Table 2) -

^ Details of the transport factor calculations are presented in Appendix B

^ Exposure Point Concentration (EPC) in inidoor air is calculated as the subslab vapor concentration TF

Coyne VI Memo Tables_09-08-09xls 982009

AR100297

TABLE 4

FACTORS USED IN DOSE CALCULATIONS INHALATION OF VOLATILE EMISSIONS

Coyne Textile Services Facility - Huntington West Virginia

Symbol

CA

IRA

ET

EF

ED-

BW

AT

Exposure Factor

Constituent Concentration in Air

Inhalation Rate

Exposure Time

Exposure Frequency

Exposure Duration

Body Weight

Averaging Time

Indoor Worker

Constituent-Specific See Table 3

25 m hour

8 hrday

250 daysyear

25 years

bull 70 kg

9125 days (NC)

25550 days (C)

Total Dose = CA x IR^ x ET x EF x ED x 1BW x 1AT

(NC) - Non-carcinogenic Averaging Time

(C) - Carcinogenic Averaging Time

Coyne VI Memo Tables_09-08-09xls 982009

AR100298

TABLES TOXICITY VALUES FOR CHEMICALS OF CONCERN

Coyne Textile Services Facility - Huntington West Virginia

Chemical of Concern

Volatile Organics

124-Trimethylbenzene

12-Dichloroethene (cis)

Chloroform

Methylene chloride

tetrachloroethene

Triehloroethene

Target Organ Critical Effect

blood

bullblood

liver

liver

liver CMS

liver kidney fetus CNS

Chroniclnhalation Reference Dose

(mgkg-day)

200E-03 P

1 OOE-02 R

140E-02 E

286E-01 M

771 E-02 M

1OOE-02 E

Inhalation Cancer ^ Slope Factor

(mgkg-day)^

NA

NA

805E-02 1

165E-03 1

200E-02 0

400E-01 E

(I) - Integrated Risk Information System (IRIS USEPA 2009)

(P) - Provisional Peer-Reviewed Toxicity Value (PPRTV) as presented in USEPA Regional Screening Tables (ORNL 2009)

(R) - Calculated assuming route-to-route extrapolation as per WVDEP

(E)-Provisional value from the National Center for Environmental Assessment (as per WVDEP)

(M)-Chronic Minimal Risk Level (MRL ATSDR 2009)

(0) - Value cited by USEPA Region 3 attributed to other sources (as per WVDEP)

Coyne VI Memo Tables_09-08-09xls 982009

AR100299

TABLE 6

NONCANCER HAZARD INDEX AND POTENTIAL CANCER RISK FOR AN INDOOR WORKER

Coyne Textile Services Facility - Huntington West Virginia

bull

Constituent

Volatile Organics

124-Trinnethylbehzene

12-Dichlorpethene (cis)

Chloroform

Methylene chloride

Tetrachloroethene Triehloroethene

EPC in Indoor Air

(mgm)

213E-06

651 E-05

- 638E-05

164E-05

161 E-03

844E-05

Intake (ADD)

(mgkg-d)

416E-07

127E-05

125E-05

321 E-06

315E-04 l65E-05

RfDi

(mgkg-d)

200E-03

1OOE-02

140E-02

286E-01

771 E-02 1 OOE-02

Hazard

Quotient

208E-04

127E-03

892E-04

112E-05

408E-03 165E-03

Intake (LADD)

(mgkg-d)

) 149E-07

455E-06 bull 446E-06

115E-06

112E-04 590E-06

CSFi

(mgkg-d)

NA

NA

805E-02

165E-03

200E-02

400E-01

Potential

Cancer Risk

NA

NA

359E-07

189E-09

225E-06 236E-06

Total Hazard Index

00081 Total

Cancer Risk 497E-06

Total Blood HI = Total Liver HI =

Total Central Nervous System HI = Total Kidney HI =

Total Fetal HI =

bull 00015 00066 00057 00017 00017

Notes NA = Toxicity values are not available for this endpoint or exposure pathway

Coyne VI Memo Tables_09-08-09xls 982009

AR100300

APPENDIX A

SUBSLAB VAPOR ANALYTICAL DATA

AR100301

Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility Huntington West Virginia

Sample

Consti tuent

Volatile Organics (ugm) 111-Trlchloroethane 1122-Tetrachloroethane 112-Trichloro-122-trifluoroethane 112-Trichloroethane 11-Dichioroethane 11-Dichloroethene 124-Trichloroberi2ene 124-Trimethylbenzene 12-Dibromoethane 12-Dichloroben2ene 12-Dichloroethane 12-Dichloroethene-(cis) -12-Dichloroethene (trans) 12-Dichloropropane 12-Dichlorotetrafluoroethane 135-Trimethylbenzene 13-Butadiene 13-Dichlorobenzene 13-Hexachlorobutadiene 14-Dichlorobenzene 224-trimethVlpentane 2-Chlorotoluene 4-Ethyltoluene Acetone Allyl Chloride Benzene Bromodichloromethane Bromoform Bromomethane Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 13-Dichloropropene (cis) Cyclohexane Dibromochloromethane

Identif ication Sample Date

CAS No

71-55-6 79-34-5 76-13-1 79-00-5 75-34-3 75-35-4 120-82-1 95-63-6 106-93-4 95-50-1 107-06-2 156-59-2 156-60-5 78-87-5 76-14-2 108-67-8 106-99^0 541-73-1 87-68-3 106-46-7 540-84r1 95-49-8

622-96-8 67-64-1 107-05-1 71-43-2 75-27-4 75-252 74-83-9 75-15-0 56-23-5 108-90-7 75-00-3 67-66-3 74-87-3

10061-01-5 110-82-7 124-48-1

lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt

lt lt lt lt lt lt lt lt lt lt lt lt

lt

VP-01 8132009

22 28 31 22 16 16 30 20 31 24 16 16 16 19 28 20 89 24 43 24

1 9 21 20 796 13 13 27 41 16 13 25 18 11 20 83 18 52 34

lt lt lt lt lt lt lt lt lt lt lt

lt lt lt lt lt lt lt lt lt lt lt

lt lt lt lt lt lt lt lt lt

lt lt lt lt

VP-02 8132009

218 2 7 5 307 218 162 159 297

bull 197 307 240 162 369 159 185 280 197 89

240 427 240 187 207 197

1880 125 128 268 414 155 125 252 184 106

5910 83 182 138 341

lt lt lt lt lt lt lt

lt lt lt

lt lt lt lt lt lt lt bull

lt lt lt lt

lt lt lt lt lt lt lt lt lt lt lt lt lt lt

VP-03 8132009

218 275 307 218

bull 162 159 297 197 307 240 162

6030 159 185 280 197 89

240 427 240 187 207 197

1750 125 128 268 414 155 125 252 184 106 195 83 182 138 341

Appx A SG Dataxis Page 1 of 2 982009

AR100302

Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility bull Huntington West Virginia

Consti tuent

Volatile Organics (ugm^) Dichlorodifluoromethane Ethylbenzene Methyl ethyl ketone Methyl Isobutyl ketone Methyl tert-butyl ether Methylene chloride n-Heptane jn-Hexane Styrene Tert-butyl alcohol Tetrachloroethene iToluene 13-Dichloropropene (trans) Triehloroethene Trichlorofluoromethane Vinyl bromide Vinyl chloride Xylene (o) Xylenes (mampp)

Sample Identif ication Sample Date

CAS No

75-71-8 100-41-4 78-93-3 108-10-1

1634-04-4 75-09-2

142-82-5 bull 110-54-3

100-42-5 75-65-0 127-18-4 108-88-3

10061-02-6 79-01-6 75-69-4 593-60-2 75-01-4 95-47-6

179601-23-1

lt lt

lt lt lt lt

lt lt

lt

lt lt lt lt lt

VP01 8132009

20 17 23 16 14 14 16

173 17 12 bull

11200 18 18 91 23 18 10 17 17

lt lt lt lt lt

lt

lt lt

lt lt

lt lt lt lt lt

VP-02 8132009

198 174 118 164 144

1520 164 -183 170 121

149000 151 182

2360 225 175 102 174 174

VP-03 8132009

lt 198 lt 174 lt 118 lt 164 lt 144

1160 lt 164

144 lt 170 ltbull 121

90500 lt 151 lt 182

7820 lt 225 lt 175 lt 102

208 387

Appx A SG Dataxis Page 2 of 2 982009

AR100303

APPENDIX B

CALCULATION OF TRANSPORT FACTORS USED TO ESTIMATE INDOOR AIR CONCENTRATIONS

AR100304

APPENDIX B

Calculation of Transport Factors Used to Estimate Indoor Air Concentrations

This appendix presents the methodology for calculating transport factors that are used to convert subslab

vapor concentrations to concentrations in indoor air 124-Trimethylbenzene 12-dichloroethene (cis)

chloroform methylene chloride tetrachloroethene and triehloroethene were identified as contaminants of

concern (COC) for potential vapor intrusion from subslab vapor associated with the Coyne Textile

Services Facility located in Huntington West Virginia (site) In this appendix the transport factors are

calculated to estimate the concentrations of COC in indoor air of the existing plant building located at the

site ~

Transport Factor for Indoor Air

The concentration of a constituent in indoor air (da) is proportional to the concentration of the constituent

in the subslab vapors immediately beneath the building foundation (ie subslab vapor concentration or

Csubsiab) The following equation is used to calculate da from Csubsiab

^ wja ~ ^subslab X I r

where

Cia = concentration of constituent in indoor air (mgm^) -

Csubsiab^ concentration of constituent in subslab vapors (mgm^) and

TF = transport factor from subslab vapors to indoor air

The transport factor (TF) is an infinite source attenuation coefficient andcan be calculated based on a

model developed by Johnson and Ettinger (1991) t he equation for calculating TF is as follows

(Deff X A B ) ( Q B X L T ) X expKQso i l X Lcrabk)(Dcrack X Acrack)]

exp[ (Qsoi l X Lcrack)(Dcrack X Acrack)] + (Deff X A B ) ( Q B X L T ) + (Deff X AB)(Qsoi l X L j ) X (exp [ (Qso i l X Lcrack)(Dcrack X Acrack)] - 1)

where

Deff = effective diffusion coefficient for vadose zone soil (cm^sec)

AB = area of enclosed space below grade (cm^)

QB = building ventilation rate (cm^sec)

LT = distance from contaminant source to building foundation (cm)

Qsoii = volumetric flow rate of vapors into the building (cm^sec)

Lcrack = foundatlon thickness (cm)

Dcrack = vapor diffusion coefficient through crack (cm^sec) and

Acrack = area of cracks through which vapors can pass (cm^)

AR100305

To solve this equation the USEPAs SG-ADV spreadsheet Version 31 most recently updated in

February 2004 was implemented A combination of site-specific factors and default values from the

Users Guide for Evaluating Subsurface Vapor Intrusion Into Buildings (USEPA 2004) were used as input

values in the model All input values are defined below and presented in Tables B-1-A through B-6-A

bull The initial subslab vapor concentration (Csubsiab) is the maximum detected concentration(in units

of ugm ) of samples VP-01 VP-02 and VP-03 that was presented in Table 3 of the report

bull The depth below grade to the bottom of the enclosed space floor (Lp) is set to 15 cm the default

value provided by USEPA (2004) for a slab-on-grade structure

bull The vapor sampling depth below grade (Lg) is a site-specific value The vapor samples were

collected from immediately beneath the building floor therefore Lj has been set to 15 cm

bull The average soilgroundwater temperature (Ts) is set to 125degC the average value for West

Virginia as estimated frorri Figure 8 of the vapor intrusion users guide (USEPA 2004)

bull The soil type used to estimate vapor permeability is assumed to be sandy loam (SL) The

associated soil properties for a sandy loam soil type are as follows the soil dry bulk density (Pb) is

162 gcm the total porosity (n) is 0387 (cm^-aircm^) and the water-filled porosity (nw) is 0103

(cm -HzOcm )

bull The floor thickness (Lcrack) is set to the USEPA (2004) default value of 10 cm

bull The soil-building pressure differential (AP) is set to the USEPA (2004) default value of 40 gcm-s^

bull The building dimensions are siterspecific based on the existing plant building located at the site

The existing structure is approximately 84000 square feet (Dolphin 2000) therefore the

dimensions are set to 8839 cm (290 feet) length by 8839 cm (290 feet) The USEPA (2004)

default value of 244 cm vyas used for the height

bull Thefloor-wall seam crack width (w) is set to the USEPA (2004)-default value of 01 cm

bull The indoor air exchange rate (ER) is set to 083hour This is the value provided by ASTM (2002)

for commercial and industrial buildings

AR100306

Tables B-1-B through B-6-B present the constituent-specific properties for COC that were used in the TF

calculations Tables B-1-C through B-6-C present the intermediate calculations used to determine the

indoor air attenuation coefficients (ie the transport factors) The shaded boxes in Tables B-1-C through

B-6-C also present the resulting TF values that are applied to the concentrations of COC in subslab

vapor and the estimated indoor air concentrations

References

American Society for Testing and Materials (ASTM 2002) Standard Guide for Risk-Based Corrective Action Applied at Petroleum Release Sites ASTM E-1739-95 (Reapproved 2002)

Johnson PC and RA Ettinger (1991) Heuristic model for predicting the intrusion r-ate of contaminant vapors into buildings Environ Sci Technolpgy 25 1445-1452

Dolphin Environmental LLC (Dolphin 2000) Site Characterization Report Mach 14 2000

United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004

AR100307

APPENDIX B-1-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV Nersion31 0204

Reset to Defaults

ENTER -

Chemical CAS No

(numbers only

no dasties)

95636

ENTER Soil gas

cone

Cg (ngm)

Soil Gas Concentration Data ENTER

Soil gas

OR cone

bull - c bull (PPmv)

197E+02

Chemical

124-Trimethylbenzene

MORE ENTER Depth

below grade to bottom

of enclosed space floor

U bull (cm)

ENTER

Soil gas sampling

depth below grade

U (cm) bull

ENTER

Average soil

temperature Ts

CO

1 15 1 1 5 bull125

ENTER ENTER ENTER Totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hft ha he

(cm) (cm) (cm)

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estirnate OR permeability | soil vapor

permeability) k v bull

(cm)

SL 1 1

MORE ENTER

stratum A SCS

soil type

Lookup Soil Parameters

ENTER stratum A soil dry

bulk density P

(gcm)

ENTER Stratum A soil total porosity

(unitless)

ENTER bull stratum A soil water-filled

porosity

(cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

nlaquo

(unitless)

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gchi-s^)

ENTER Enclosed

space floor

length bull LB

(cm)

ENTER Enclosed

space floor

width WB

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

bull Floor-wall seam crack

width w

(cm)

bullENTER

Indoor air exchange

rate ER

(1h) bull

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bidg OR

Leave blank to caicuij

(Lm)

Appx B-1 124-TMBxls 1 of 3 982009

AR100308

APPENDIX B-1-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of ^ bull law constant law constant vaporization at Normal

Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temperature boiling point point temperature weight

D bull Dbdquo H T R bull AHbdquo TB Tc IVIW

Unit risk Reference

factor cone URF RfC

(cms) (cmls) (atm-mmol) CO (calmol) (degK) (degK) (gmol) bull (ugm)- (mgm)

1 606E-02 1 792E-06 1 bull 614E-C3 1 25 1 9369 1 44230 | 64917 1 12020 1 OOE+00 1 60E-03 1

Appx B-1 124-TMBxls 2 of 3 982009

AR100309

APPENDIX B-1-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

(sec)

Source-building

separation

LT bull

(cm) bull

Stratum A soil

air-filled porosity

Q A

Stratum B soil

air-filled porosity

(cmcm) (cmcm)

Stratum C soil air-filled porosity

(cmcm)

Stratum A effective total fluid

saturation

Se

(cmcm)

Stratum A soil

bullintrinsic permeability

^ (cm)

stratum A Stratum A Floor- soil soli wall BIdg

relative air effective vapor seam Soil bull ventilation permeability permeability perimeter gas rate-

kfg ky Xgrack c o n e - QbuHdinpound

(cm) - (cm) (cm) (ngm) (cms)

946E+08 1 0284 0284 0284 0184 596E-09 0901 537E-09 35357 I 197E+02 | 439E+06 |

Area of enclosed

space below grade

As (cm)

Crack-to-total area ratio

1 bull

(unitless)

Crack depth

below grade

Zcfack

(cm)

Enthalpy of vaporization at

ave soil temperature

AHvjs

(calmol) bull

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law constant at

ave soil bull temperature

bull HTS

(unitless)

Vapor bull viscosity at

ave soil temperature

HTS

(gcm-s)

Stratum A

effective diffusion

coefficient

D (cms)

Stratum-B

effective diffusion coefficient

DB (cms)

Stratum C effective diffusion

coefficient

D-c (cms)

Total - overall effective diffusion

coefficient

D ^ (cms)

Diffusion path

length

L-

(cm)

I 787E+07 I 449E-05 | 15 | 11661 260E-03 111E-01 176E-04 I 612E-03 j OOOE+00 | OOOE+00 | 612E-03 j

bull Convection path

length

Lp

(cm)

Source vapor cone

^source

(ngm)

Crack radius

Tcfack

(cm)

Average vapor

flow rate into bIdg

Qsoii

(cms)

Crack effective diffusion

coefficient pcrack

(cms)

Area of CTack

Acack

(cm)

Exponent of equivalent foundation

Peclet number

exp(Pe)

(unitless)

bull bull - bull bull bull bull

1 15 1 197E+02 1 010 1 474E+01 612E-03 bull 354E-t-03 1 336E+09

Infinite source Indoor

~ attenuation coefficient

a

(unitless)

108E-05

Infinite source

btJbldgjJSv-L ^Ppncji3i-

virhpbiiilding bullbull ^lHltti^m)ilg

213E-03

Unit risk

factor

URF

(ngm)-

Reference cone

RfC (mgm)

NA 60E-03 1

I END

Appx B-1 124-TMBxls 3 of 3 982009

AR100310

APPENDIX B-2-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV Nersion31 020^

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

156592

Soil Gas Concentration Data ENTER

Soil gas

cone OR c

(ngm) bull

ENTER Soil bull-gas

cone

c (ppmv)

603E+03 1

Chemical

cis-12-Dichloroethylene

MORE ENTER Depth

below grade to bottom

of enclosed space floor

LF

(cm)

ENTER

Soil gas sampling

depth below grade

U (cm)

ENTER

Average soil

temperature bull Ts

(degC)

1 15 1 bull 15 125

ENTER ENTER ENTER Totalsmust add ijp tb value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hA hB he

bull (cm) (cm) (cm)

15 1 1

ENTER Soil

straturh A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estimate OR permeability | soil vapor

permeability) kv

(cm)

SL 1 |

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

P (gcm)

ENTER Stratum A soil total porosity

bull n

(unitless)

ENTER Stratum A

soil water-filled porosity

(cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

ENTER Stratum B

soil water-filled porosity

ENTER Stratum C

SCS soil type

(unitless) (cmcm)

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure differential

AP

(gcm-s)

ENTER Enclosed bull

space floor

length

LB (cm)

ENTER Enclosed

space floor

width WB

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER

Average vapor flow rate into bIdg

OR Leave blank to calculi

Qsoil

(Lm)

Appx B-2 cis-12-DCExls 1 of 3 982009

AR100311

APPENDIX B-2-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Diffusivity in air

Da

(cms)

Diffusivity in water

Dw (cms)

Henrys law constant at reference temperature

H

(atm-mmoi)

Henrys law constant

reference temperature

bull T R

CC)

Enthalpy of vaporization at

the normal boiling point

AHbdquob

(calmol)

Normal boiling point

TB

(degK)

Critical temperature

Tc (degK)

Molecular weight

MW

(gmol)

Unit risk

factor URF

(ngm)

Reference cone

RfC (mgm)

1 736E-02 1 113E-05 1 407E-03 j 1 25 1 bull 7192 1 33365 1 54400 1 9694 1 OOE+00 j 35E-02 1

Appx B-2 cis-12-DCExls 2 of 3 982009

AR100312

APPENDIX B-2-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

stratum A Stratum B Stratum C Source- soil soil soil

Exposure building air-filled air-filled air-filled

duration separation porosity porosity porosity

T LT ea e^ bull e= (sec) (cm) (cmcm) (cmcm) (cmcm)

I 946E+08n^

Stratum A Stratum A Stratum A Stratum A Floor-effective soil soil soil wall total fluid intrinsic relative air effective vapor seam

saturation permeability permeability permeability perimeter

Ste kj krg ky Acrack

(cmcm) (cm) (cm) (cm) (cm)

Soil gas

cone (ngm)

I 0284 I 0284~ 0284 0184 I 596E-09 | 090T 537E-09 35357 603E+03

BIdg ventilation

rate

JbulldinE

(cms)

439E+06

Area of enclosed

space below grade

AB

(cm)

Crack-to-total

area ratio

n (unitless)

Crack depth below grade

Zltiack (cm)

Erithalpy of vaporization at

ave soil temperature

AHvTs (calmol)

Henryslaw constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law constant at

ave soil temperature

HTS

(unitless) bull

Vapor viscosity at

ave soil bull temperature

HTS

bull (gcm-s)

Stratum A

effective bull diffusion

coefficient

D^A-(cms)

Stratum B

effective bull diffusion

coefficient

D=B

(cms)

Stratum C

effective diffusion bull

coefficient

D=e (cms)

Total overall

effective diffusion

coefficient

DT

(cms)

Diffusion path

length

Ld

(cm)

I 787E+07 I bull449E-05 | 15 bull7709 230E-03 982E-02 176E-04 | 743E-03 | OOOE+00 | OOOE+00 | 743E-03 |

bull bull bull -

Convecfion path -bull

length

Lp (cm)

Source vapor cone

-source

(Mgm)

Crack radius

fcrack

(cm)

Average vapor

flow rate into bIdg

Qaoil bull

(cms)

Crack effective diffusion

coefficient pcack

(cms)

Area of crack

crack

(cm)-

Exponent of equivalent foundation

Peclet number

exp(Pef)

(unitless)

bull

1 15 -1 603E+03 1 010 1 474E+01 743E-03 354E+03 1 697E+07

Infinite source Indoor

attenuation coefficient

poundbullbullbull C t

pound(unitless)

bullsiilaquogt j ii08E-05

Infinite [ source

bIdg cone

Cbujidjng

(pgm)

651 E-02 iKrt

Unit risk

factor

URF

(ngm)-

Reference cone

RfC

(mgm)

NA 35E-02 1

I END I

Appx B-2 cis-12-DCExls 3o f3 982009

AR100313

APPENDIX B-3-A DATA ENTRY SHEET

Coyne Texti le Services - Hunt ington West Virginia

SG-ADV Version 31 0204

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

67663

Soil Gas Concentration Data ENTER ENTER

Soil Soil gas gas

cone OR cone c C

(^gm) (ppmv)

591 E+03

bull

Chemical

Chloroform

MORE ENTER Depth

below grade tb bottom

of enclosed space floor

bull LF

(cm)

ENTER

Soil gas sampling depth

below grade

(cm)

ENTER

Average soil

temperature-Ts

CO bull

1 15 1 15 1 125

ENTER ENTER ENTER Totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

IIA hs he (cm) (cm) (cm)

1 5 bull 1 1

ENTER ENTER Soil - bull

stratum A User-defined SCS stratum A

soil type bull soil vapor (used to estimate OR permeability

soil vapor k

bull permeability) (cm) 1

SL 1 1 bull

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A soil dry

bulk density

Pb (gcm)

ENTER Stratum A soil total porosity

nV (unitless)

ENTER Stratum A

-soilwater-filled bullporosity

Sraquo (cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

(unitless)

ENTER Stratum B

soil water-filled porosity

bull ebdquo=

(cmcm) bull

ENTER Straturri C

SCS bull soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

- c rack

(cm)

ENTER

Soil-bldg pressure

differential AP^

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor

width bull W B

(cm)

ENTER

Enclosed space

height HB

(cm)

ENTER

bull Floor-wall^ seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bidg OR

Leave blank to calculi

Qsoil bull

(Lm)

I -I

Appx B-3 Chloroformxls 1 of 3 982009

AR100314

APPENDIX B-3-B CHEMICALPROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Diffusivity in air

D (cms)

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffijsivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature

Dbdquo H TR A H bdquo TB Tc

(cm s) (atm-m mol) ro (calmol) (degK) (degK)

Molecular weight

MW

(gmol)

Unit risk

factor URF

(ngm)-

Reference cone

RfC

(mgm)

104E-01 100E-05 I 366E-03 25 6988 33432 53640 11938 I 23E-05 | OOE+00

Appx B-3 Chloroformxls 2 of 3 982009

AR100315

APPENDIX B-3-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure

duration

(sec)

Source-

building

separation

LT

(cm)

Stratum A

soil

air-filled

porosity

Sa

( cm cm )

Stratum B

soil

air-filled

porosity

( cm cm )

Stratum C

soil

air-filled

porosity

( c m c m )

Stratum A

effective

total fluid

saturation

( c m c m )

Stratum A

soil

intrinsic

penmeability

k

(cm )

Stratum A

- soil

relative air

permeabil i ty

(cm )

Stratum A

soil

effective vapor

permeability

kv

(cm )

Floor-

wall

seam

perimeter

gtcrack

(cm)

Soil gas

cone

(ngm)

BIdg

venfilation

rate

^buildlriE

(cms)

I 9 4 6 E + 0 8 ~ T I 0284 T 596E-09 I 0-901 I 537E-09 | 35357 | 591 E+03 j 439E+06 | 1 0 284 0284 0184

Area of

enclosed

space

below

grade

A B

( c m )

Crack-

to-total

area

ratio

n

(unitless)

Crack

depth

bull below

grade

^crack

(cm)

Enthalpy of

vaporization at

ave soil

temperature

AHTs bull

(calmol)

Henry s law

constant at

ave soil

temperature

HTS

(a tm-m mol j

Henrys law

constant at

ave soil

bull temperature

HTS

(unitless) bull

Vapor

viscosity at

ave soil-

temperature

^HTS

(gcm-s)

Stratum

A

effective

diffusion

coefficient

(cm s)

Stratum

B

effective

difftjsion

coefficient

D B

(cms) bull

S t ra tum

C

effective

diffusion

coefficient

Dc

(cm s)

Total

overall

effective

bull diffusion

coefficient

D T

(cm s)

Diffi jsion

path

length

Ld

(cm)

I 787E+07 I 449E-05 j - bull 15 7528 210E-03 896E-02 176E-04 I 105E-02 | OOOE+00 | OOOE+00 | 105E-02

Convection

path length

Lp

(cm)

Source

vapor

cone -

^source

- (ngm)

Crack

radius

Tcrack

(cm)

Average

vapor

flow rate

into bidg

Qsoil

(cms)

Crack

effective

diffusion

coefficient Qcrack

bull (cms)

Area of crack

Acrack

(cm)

Exponent of

equivalent

foundation

Peclet number

exp(Pe)

(unitless)

V bull bull

1 15 1 591 E+03 1 010 1 474E+01 105E-02 354E+03 1 355E+05

Infinite

source

indoor

attenuation

coefficient

d

(unitless)

bull 108E-05

Infinite

source

bIdg

cone

^ b u i l d i n g

i (^gm)

bull bull

i 638E-02 -

Unit

risk bull factor

URF

(ngmY

Reference

cone

RfC

(mgm)

~ 23E-05 NA 1

I END

Appx B-3 Chloroform xls 3 of 3 982009

AR100316

APPENDIX B-4-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ersion 31-020^

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

nodashes)

bull 75092

ENTER Soil gas

cone

c (ngm)

Soil Gas Concentration Data ENTER

Soil gas bull

OR cone

bull C

(ppmv)

152E+03

bull bull

Chemical

Methylene chloride

MORE

MORE 4gt

ENTER Depth

below grade to bottom

of enclosed space floor

LF -

(cm)

ENTER

Soil gas sampling depth

below grade

bull U

(cm)

ENTER

Average soil

temperature

Ts bull CC)

bull bull bull bull

1 15 1 15 125

ENTER Totals

Thickness of soil

stratum A h

(cm)

ENTER ENTER must add up to value of Ls (cell F24

Thickness Thickness of soil of soil

stratum B stratum C (Enter value or 0) (Enter value or 0)

he he bull

(cm) bull (cm) -

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(usedto estimate OR perrrieability | soil vapor

permeability)

k bull

(cm)

SL 1 bull 1

ENTER Stratum A

SCS soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

Pb (gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Stratum A

soil water-filled porosity

9w (cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

Pb^

(gcm)

ENTER Stratum B soil total porosity

n^

(unitless)

ENTER Stratum B

soil water-filled porosity

(crhcm)

ENTER Stratum C

SCS soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE 4gt

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

bull Soil-bldg pressure

differential AP^

(gcm-s)

ENTER Enclosed

space floor

length LB

(cm)

ENTER Enclosed

space floor

width bull W B

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width

w

(cm)

ENTER

Indoor air exchange

rate

ER (1h)

ENTER Average vapor

flow rate into bidg OR

Leave blank to calculc

Qsoil

(Lm)

10 40 8839 8839 244 01 083

Appx B-4 MCxIs 1 of 3 982009

AR100317

Diffijsivity in air

D

APPENDIX B-4-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffusivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature

Pw H TR AHt TB TC

Molecular weight

MW

Unit risk

factor URF

Reference cone

RfC

(cms) (cms) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) bull (ngm)- (mgm)

bull bull

1 101E-01 1 117E-05 1 218E-03 1 25 | 6706 1 31300 1 51000 1 8493 1 47E-07 1 30E+00 1

Appx B-4 MCxIs 2 of 3 982009

AR100318

APPENDIX B-4-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

T

(sec)

Source- -building

separation

LT

(cm)

Stratum A soil

air-filled porosity

e a bull

(cmcm)

Stratum B soil

bullair-filled porosity bull

ea^ (cmcm)

Stratum C soil

air-filled porosity

ea= (cmcmj

Stratum A effective total fluid

saturation

Sc bull

(cmcm)

Stratum A soil

intrinsic pemneability

ki (cm)

Stratum A soil

relative air permeability

^ ^ g

(cm)

stratumA bull soil effective vapor permeability

K (cm)

Floor-wall

seam perimeter

Xcrack

(cm)

Soil gas

cone (ngm)

BIdg ventilation

rate

Qbuildinc

(cms)

1 946E+08

Area of -enclosed

space below

bull grade

AB

(cm)

1

Crack-to-total

area rafio

Tl

(unitless)

0284 1

Crack depth below grade

Zcrack

(cm)

0284 1

bull Enthalpy of vaporization at

ave soil temperature

AHTs (calmol)

0284

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

0184

Henrys law constant at ave soil

temperature

HTS

bull (unitless)

1 596E-09

Vapor viscosity at

ave soil temperature

Mrs (gcm-s)

0901

Stratum A

effective diffusion

coefficient

D (cms)

537E-09

Stratum B

effective diffusion

coefficient

D-B (cms)

35357 1

Stratum C -

effective diffusion

coefficient

D-c ^ (cms)

152E+03

Total bull overall

bull effective diffusion

coefficient

D ^

(cms)

440E+06 1

Difftjsion path

length

Ld (cm)

1 787E+07

Convection path

length

Lp (cm)

4 49E-05

Source vapor cone

Csource

(ngm)

15 1

Crack radius

Tcrack

(cm)

7007 bull 1

Average vapor

flow rate intobldg

Qsoil

(cms)

130E-03

Crack effective diffusion

coefficient pcrack

(cms)-

555E-02

bull ^

Area of crack

Acrack

(cm) bull

1 176E-04

Exponent of equivalent foundation

Peclet number

exp(Pe)

(unitless) bull

bull bull

1 15

1 END

152E+03 010 1 474E+01 1 102E-02 354E+03 1 519E+05

102E-02

Infinite source

indoor ^attenuation coefficient

bull a

(unitless)

aiii08E-05

0 OOE+00

bull

Infinite bull source

bIdg ^ cone

^bu i l d i ng

(MQm)

164E-02

OOOE+00 1

Unit risk

factor

URF

(ngm)-

47E-07 1

102E-02 j

Reference cone

RfC

(mgm)

30E+00 j

1 1

Appx B-4 MCxIs 3 of 3 982009

AR100319

APPENDIX B-5-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ^erslon 31 0204

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

127184

Soil Gas Concentration Data ENTER ^ ENTER

Soil -Soi l bull gas gas

cone OR cone Cg C bull

(tgm) (ppmv)

149E+05 1

Chemical

bull Tetrachlbroethylene

MORE 4

ENTER Depth

below grade to bottom

ofenclosecJ space floor

LF

(cm)

ENTER

Soil gas bull sampling

depth below grade

u bull (cm)

ENTER

Average bullsoil

temperature - Ts

ro 1 1 5 1 15 1 125 bull

ENTER ENTER ENTER totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hft bull he bull he

(cm) (cm) (cm)

bull 1 5 1 - 1

ENTER ENTER Soil

stratum A User^defined bull SCS bull stratum A soil type soil vapor

(used to estimate OR perrrieability soil vapor K bull

permeability) (cm) 1

SL 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

Pb

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Sitratum A

soil water-filled bull porosity

(cmcm)

ENTER Stratum B

SCS soiltype

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

Pb^

(gcm)

ENTER Stratum B soil total porosity

Ajnitless^

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS soil type

LookupSoil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

VS

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor width

W B

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width

w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

ENTER Average vapor

flow rate into bidg OR

Leave blank to calcul

bull Qsoil

(Lm)

10 40 8839 8839 244 01 083

Appx B-5 PCExIS 1 of 3 982009

AR100320

APPENDIX B-5-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal Unit

Diffusivity Diffusivity at reference reference the riormal boiling Critical Molecular risk Reference in air in water temperature temperature boiling point point teriiperature weight factor cone

Da Dbdquo H TR AHb TB Tc MW URF RfC

(cms) (cnis) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) (^gm)- (mgm)

1 720E-02 1 820E-06 1 184E-02 1 25 1 8288 1 39440 1 62020 1 16583 1 59E-06 1 60E-01 1

J

AppxB-5PCExls 2 of 3 - 982009

AR100321

APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

T

(sec)

Source-building

separation

LT

bull (cm)

Stratum A soil

air-filled porosity

Oa (cmcm)

Stratum B - soil air-filled porosity

ea (cmcm)

Stratum C soil

air-filled porosity

ea= - (cmcm)

Stratum A effective total fluid

saturation

sbdquo (cmcm)

Stratum A soil

intrinsic permeability

ki (cm)

Stratum A soil

relative air permeability

- ^ g

(cm)

Stratum A soil

effective vapor permeability

kv (cm)

Floor-wall

seam perimeter

^crack

(cm)

Soil gas

cone

(ngm)

BIdg venfilation

rate

Qbuildins

bull (cms)

bull bull

1 946E+08

Area of enclosed

space below grade

AB

(cm)

1

bullCrack-to-total

area ratio

1 (unitless)

0284 1

Crack bull depth below grade

Zcrack

(cm) -

0284 1

Enthalpy of vaporization at bull

ave soil temperature

bull A H V TS

(calmol)

0284

Henrys law constant at

ave soil temperature

HTS (atm-mmol)

0184

-Henrys law constant at

ave soil temperature

HTS

(unitless)

1 596E-09

Vapor viscosity at

ave soil temperature

HTS

(gcm-s)

0901

Stratum A

effective diffusion

coefficient bull D = bull

(cms)

537E-09

Stratum B

effective diffusion

coefficient

D--B (cms)

35357 1

Stratum C

effective diffusion bull

coefficient

D-c (crris)

149E+05

Total overall

effective bulldiffusion coefficient

DT

(cms)

440E+06 1

Difftjsion path

length

U (cm)

1 787E+07

Convection path

length

bull Lp

(cm)

4 49E-05

Source vapor cone

^source

(ngm)

15 1

Crack radius

Tcrack

(cm)

9528 1

Average vapor

flow rate intobldg

Qsoil (cms)

908E-03

Crack effective diffusion

coefficient pcrack

bull ( c m s ) bull

387E-01

Area of crack

Abdquoack (cm)

1 176E-04

Exponent of equivalent foundafion

Peclet number

exp(Pe)

(unitless)

bull

1 15-

1 END

149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08

727E-03

Infinite source indoor

attenuation coefficient

a

(unitless)

108E-05

OOOE+00

Infinite source

bIdg cone

Cburldtng

(Mgm)

161 E+00

OOOE+00 1

Unit risk

factor

URF

(ugm)-

59E-06 1

727E-03

Reference cone

RfC (mgm)

60E-01

1 1

Appx B-5 PCExls 3 of 3 982009

AR100322

APPENDIX B-6-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ersion31 0204

Reset to Defaults

t

Soil Gas Concentration Data ENTER

Chemical CAS No

(numbers only

no dashes)

79016

ENTER ENTER Soil Soil gas gas

cone OR cone C C -

bull (ngm) (ppmv)

782E+03

Chemical

Trichloroethylene

MORE ENTER Depth

below grade to bottom-

of enclosed space floor

LF

(cm)

ENTER

Soil gas sarnpling

depth below grade

U (cm)

ENTER

Average soil

temperature Ts

(degC)

1 15 1 15 t 125

ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e

(cm) (cm) (cm)

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estimate OR permeability soil vapor

permeability)

k (cm)

bull S L 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil bull-Parameters

ENTER Stratum A

soil dry bulk density

P b -

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Stratum A bull

soilwaterrfilled porosity

(cmcm) bull

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

bull P ^ (gcm)

ENTER Stratum B soil total

porosity

nlaquo

(unitless) -

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS bull soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor

width W B

(cm)

ENTER

Enclosed space height

H B bull

( c m ) bull

ENTER

Floor-wall seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bIdg OR

Leave blank to calculc

Qsoil

(Lm) -

Appx B-6 TCExIs 1 of 3 982009

A

AR100323

APPENDIX B-6-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight

Da Dbdquo H TR AH^b TB TC MW

Unit risk Reference

factor cone URF RfC

(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)

1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1

Appx B-6 TCExIs 2 of 3 982009

AR100324

APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

(sec)

Source-building

separation LT

(cm)

Stratum A soil

air-filled porosity

bull ea (cmcm)

Stratum B Soil

air-fllled porosity

e^ bull (cmcm)

Stratum C soil

air-filled porosity

(cmcm)

StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air

saturation permeability permeability

S|e k krg (cmcm) (cm) (cm)

Stratum A Floor-soil wall BIdg

effective vapor seam Soil ventilafion permeability perimeter gas rate

k^ bull Xack c o n e Qbuildins

(cm) (cm) (ngm) (cms)

946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |

Area of enclosed

space below grade

AB

(cm)

Ciack- to-total

area ratio

1 (unitless)

Crack depth below grade

Zcrack

(cm)

Enthalpy of vaporization at

ave soil temperature

A H J S

(calmol)

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law bull constant at

ave soil temperature

HTS

(unitless)

Vapor viscosity at

ave soil temperature

|JTS

(gcm^s)

Stratum A

effective diffusion

coefficient

(cms)

Stratum B

effective -diffusion

coefficient

D=B (cms)

Stratum ^ C effective diffusion

coefficient

D=c (cms)

Total overall

effective diffusion

coefficient

DT

(cms)

I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03

Diffusion path

length

Li (cm) bull

Convection bull path

length

Lp

(cm)

Source vapor cone bull

^source

(ngm)

Crack radius

rcrack

(cm)

Average vapor

- flow rate intobldg

Qsoil

(cms)

Crack effective diffusion

bull coefficient Qcrack

(cms)

Area of crack

^crack

(cm)

Exponent of equivalent foundation

Peclet bull number

exp(Pe)

(unitless)

bull bull

1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07

Infinite source Indoor

attenuation coefficient

a

(unitless)

108E-05

Infinite source

bIdg concgt

^building

(ngm)

844E-02

Unit risk

factor

URF

(ngm)-

Reference cone

RfC

(mgm)

1 1E-04 1 40E-02 1

END

Appx B-6 TCExIs 3 of 3 982009

AR100325

Office of Waste Management 1356 Hansford Street

Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256

West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director

ORDER

ISSUED UNDER THE

HAZARDOUS WASTE MANAGEMENT ACT

CHAPTER 22 ARTICLE 18

OF THE WEST VIRGINIA CODE^ AS AMENDED

y Order Number HW-011-80

To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704

ATTEMTION MREDARMON

Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull

AR100326

ViWJ011-laquo9 PageNunil)er2

BASIS FOR ORDER

As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following

A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^

B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator

C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities

0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94

^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement

P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following

1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater

2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was

^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment

CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable

CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order

AR100327

H W - 0 1 1 - 9 9 Page Number 3

REQUIREMENTS OF ORDER

Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows

1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^

2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore

remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling

GENERAL PROVaiONS

1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order

2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order

3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order

Effective Date

Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief

Wt T 1 V Oflice of Waste Management

AR100328

^ ^ S I S

^wmmmmamn

AR100329

Page 5: SDMS DocID 2121999 · International Enterprises Corp. building (Coyne Building), which is located at 1111 Vernon Street, Westmoreland District, Wayne County, West Virginia. The following

CIVIL bull ENVIRONMENTAL AND GEOTECHNICAL ENGINEERING

4980 Teays Valley Road Scott Depot WV 25560 Phone 3047550721 Fax 3047551880 TRIAD ENGINEERING INC

October 24 2008

Mr Robert Trocin Wayne County Economic Development Authority PO Box 519 Wayne VVest Virginia 25570

Subject Groundwater Assessment Former Coyne International Enterprises Corp Building Westmoreland District Wayne County West Virginia

Dear Mr Trocin

On behalf of the Wayne County Economic Development Authority (WCEDA) Triad

Engineering Inc conducted a focused groundwater assessment at the former Coyne

International Enterprises Corp building (Coyne Building) which is located at 1111 Vernon

Street Westmoreland District Wayne County West Virginia The following summarizes

field activities and analytical results of this assessment Figure 1 Site Location Map

illustrates the location of the site

On October 32008 five temporary groundwater hionitoring points were installed using a

direct-push technology sampling unit A groundwater sample was collected from each

monitoring point and analyzed by a WVDEP certified laboratory for VOC as per United

States Environmental Protection Agency (USEPA) method SW-8260B Three monitoring

points were installed in the area of groundwater monitoring well MW-5 between the Coyne

Building and the CSX Transportation inc rail line and two monitoring points were installed

to the immediate north of the CSX Transportation Inc rail line Groundwater was

encountered at a depth of approximately 30-feet below ground surface (bgs) Figure 2

Sample Location Map illustrates the locationof the groundwater monitoringpoints and

physical features located within the sample area

WWWTRIADENGCOM

Practical Engineering and Science Solutions Since 1975

AR100282

Wayne County Economic Development Authority Groundwater Assessment Coyne TextileServices Building Westmoreland District Wayne County West Virginia October 24 2008 -

Page 2

FIGURE 1 SITE LOCATION MAP Huntington WVa USGS 75-minute Topographic Quadrangle

1985

Laboratory analytical results were compared to the applicable WVDEP groundwater

maximum contaminant level (MCL) or de mnms values listed in Table 60-3 effective June

26 2008 Concentrations of VOC which exceeded the de minimis values were identified in

5 of 5 groundwater samples collected Tetrachloroethene (PERC) was detected in each of

the groundwater samples at concentrations which exceeded the de minimis values

Triehloroethene was detected in samples collected from GP-1 GP-3 and GP-5 at

concentrations which exceeded the de minimis values Cis-12-Dichloroethene was detected

in samples collected from GP-1 and GP-3 at concentrations which exceeded the de minimis

values Vinyl Chloride was detected in each sample except GP-5 at concentrations which

exceeded the de minimis values A summary of laboratory analytical reports is provided in

Table 1 Laboratory Analytical Summary-Groundwater and copies of the Laboratory

Analytical Reports are included as Attachmenf 1

AR100283

(9

00 S

P B B K ftVENIjEl

WEST MORELAND PARK

TENNIS BASKETBALL COURTS

GP-5 GP-4

9-inn i in iMMIMII I IMMII I I I I I I I IMI I I I I I IMI I I IMMII I I I I I I I I IMMII I I I I I IMI I I I I I I I I I I I IMI I I I I I I I I I I IMMII I I IMIMIMII I I I I I I I I I IMI I I I I I I I IMI I I I

CSX RAILROAD GP-2 GP-1 GP-3 I I I I I I I IMI I I IMMI I IMI I I I I I IMIMI I I IMI I I I I I I I I in i l lMI IMIMI I I I I IMMI I I I I I Jd I I IMj r i i y i l lMMI I I IMI I I I I I I I I in i l l l l l l lM l l l l l l l i n i l l l l l l l l ijj^lll^flH|t

bull

ACCESS ROAD

BUILDING

- bull

G P X ^

MM ^

MW

4-

bull ^

LEGEND

CW SAMPLE LOCAT10

MONITORING WELL

gtl

n

PARK ING

SCALE 1 r bull

WCEDA VRP GROUNDWATER SAMPLINGS HUNTINGTON WEST VIRGINIA

F I G U R E tslD

Cad Files04-08-p408-1dgn 6122009 24625 PM

- AR100284

Wayne County Economic Development Authority Page 3 Groundwater Assessment Coyne Textile Services Building Westmoreland District Wayne County West Virginia October 24 2008 _ bull ^

We appreciate the opportijnity to assist you with this project If you have any questions or r

need additional information please feel free to contact us

Sincerely TRIAD ENGINEERING INC

Matthew C Wright

Project Geologist

JohnM Meeks PG LRS

Project Manager

end

^

AR100285

Table 1 Laboratory Analytical Summary - Groundvvater WCEDA Vernon street

Huntington Wayne County West Virginia

COPC

Acetone Benzene Bromobenzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone sec-Butylbenzene n-Butyibenzene tert-Butylbenzene Carbon disulfide Carbon Tetrachloride Chlorobenzene Chlorodibromorriethane Ghloroethane Chlbroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene 12-Dibromo-3-chloropropane 12-Dlbronnoethane (EDB) DIbromomethane 14-Dichlorobenzene 13-Dictilorobenzene 12-Dictilorobenzene Dichlorodifluoromethane 11-Dlchloroethane 12-Dichloroethane cis-12-Dichloroethene

MCL ugL

5500 5

NV NV NV 85 87

700 61 61 61

1000 5

100 NV 39

bull 017 190 NV NV 02

005 NV

750 600 600 390 910

5 70

GP-1 ugL ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND

ND ND ND ND ND ND ND ND ND ND ND ND 112 ND

5210

GP-2 ugL ND ND ND

ND ND ND ND ND ND ND ND ND ND ND ND ND ND

062 J ND ND ND

ND ND ND ND ND ND ND ND

379

GP-3 ^ ugL

ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND

065 J ND 184 ND( ND ND ND

ND ND ND ND ND ND ND

12500

GP-4 ugL ND ND ND ND ND

- ND ND ND ND ND ND ND ND ND ND ND ND ND

ND ND ND ND ND ND ND ND ND ND ND 132

GP-5 ugL ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND

ND ND ND ND ND ND ND ND ND ND ND ND 59

Notes - Bold Indicates COPCs detected at concentrations greater than the MCL bull(60CSR3 Table 60-3B July 2008)

NAME - J indicates analyte detected at levels less than the reporting limit and greater than

or equal to the MDL value is estimated -NV indicates no value has been established

AR100286

Table 1 Laboratory Analytical Summary - Groundwater (Continued) WCEDA Vernon street

Huntington Wayiie County West Virginia

COPC

11-Dichloroethene trans-12-Dichloroethene 13-Dichloropropane 12-Dichloropropane 22-Dichloropropane cis-13-Dichloropropene trans-13rDichloropropene 11-Dichloropropene Ethylbenzene Hexachlorobutadiene 2-Hexanone Isopropylbenzene p-lsopropyltoluene Methyl tert-Butyl Ether Methylene Chloride 4-Methyl-2-pentanone Naphthalene n-Propylbenzene Styrene 1112-Tetrachloroethane 1122-Tetrachloroethane Tetrachloroethene Toluene 123-Trichlorobenzene 124-Trichlorobenzene 112-Trichloroethane 111-Trlchloroethane Triehloroethene Trichlorofluoromethane 123-Trichloropropane 135-Trimethylbenzene 124-Trimethylbenzene Vinyl chloride Xylenes total s

MCL ugL

91 100 04

5 NV NV NV NV

700 086

NV NV

NV 028

5 NV 62 NV 100

043 0055

5 1000

NV 70

5 20

5 1300

0034 120 120

2 10000

GP-1 ugL 964 458 ND ND

ND ND ND ND

052 J ND ND ND ND ND ND ND ND ND ND ND ND

14700 065 J ND ND ND ND

2850 ND

ND ND ND 116 146 J

GP-2 ugL ND ND ND ND ND ND ND- ND ND ND ND ND -ND ND ND ND ND ND ND ND ND

603 ND ND ND ND ND

079 J ND ND ND ND 242 ND

GP-3 ugL 346 865 ND ND

bull ND ND ND-ND

055 J ND ND ND ND ND ND ND ND ND ND ND ND

13900 159 ND ND ND ND

4870 ND ND ND ND 708 149 J

GP-4 ugL ND ND ND ND ND ND ND ND ND ND ND

ND 177 ND ND ND ND ND ND ND ND

583 ND ND ND ND ND

082 J ND ND ND ND

227 ND bull

GP-5 ugL ND ND ND ND ND

ND ND ND ND ND ND ND ND

ND ND ND ND ND ND ND ND 133 ND ND ND ND ND

574 ND ND

ND ND 122 ND

Notes - Bold indicates COPCs detected at concentrations greater than the MCL

(60CSR3 Table 60-3B July 2008) - ND indicates non-detected at concentrations greater than the MCL - J indicates analyte detected at levels less than the reporting limit and greater than

or equal to the MDL value is estimated - NV indicates no value has been established

AR100287

Risk-Based Rerfiedies

R B R Consulting Inc 650 Shady Drive Beaver Falls PA 15010

Phone724-846-4096 Fax 724-846-6974

MEMORANDUM

TO John Meeks Triad Engineering Inc

FROM Bruce Fishman

DATE September 82009

SUBJECT Evaluation of Potential Risks Associated with Vapor Intrijsion to Indoor Air Coyne Textile Services Facility - Huntington West Virginia

bull V bull bull bull

This memorandum presents a risk evaluation for potential risks associated with vapor intrusion to indoor air at the Coyne Textile Services Facility located in Huntington West Virginia (site) This evaluation was conducted according to West Virginia Department of Environmental Protection (WVDEP) and United States Environmental Protection Agency (USEPA) methodologies

DATA INCLUDED 1N THE EVALUATION

This evaluation includes three subslab vapor samples (VP-01 VP-02 and VP-03) collected from immediately beneath the floor of the existing site building Table 1 lists the subslab vapor samples included in this risk assessment Samples were analyzed for volatile organic compounds (VOCs) by USEPA Method TO-15 Complete analytical data for these samples are provided in Table A-1 of Appendix A

The analytical results of the subslab vapor samples were compared to the target shallow soil gas comparison values presented in Table 2c of the USEPA vapor intrusion guidance document (2002a) These companson values are generic soil gas screening values that are protective of indoor air for residential land uses and represent concentrations in-sliallow soil gas based on a target risk level of 1 x 10reg andor a hazard index of 1 The comparison is presented in Table 2

As indicated in Table 2 the following constituents are identified as contaminants of concern (COC) for the vapor intrusion to indoor air pathway 124-trimethylbenzene 12-dichloroethene (cis) chloroform methylene chloride tetrachloroethene and triehloroethene

ESTIMATION OF INDOOR AIR CONCENTRATIONS

The concentrations of COC in indoor air associated with vapor intrusion from subslab vapor were estimated using methodologies outlined in the Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings (USEPA 2004) A transport factor (TF) is required that will relate the

Page 1 of 5 -

AR100288

Risk-Based Remedies

R B R Consulting Inc

constituent concentration in subslab vapor to the concentration in indoor air The TF is dependent on the diffusion coefficient and other properties that will affect the transfer of constituents into air such as distance from the source to tlie breathing zone soil properties and building properties A site-specific building size of 84000 square feet (Dolphin 2000) and a soil type of sandy loam were used in the calculation of TF The TF is determined using calculationsbased on the Johnson and Ettinger (1991) vapor intrusion model Details of the TF calculations are provided in Appendix B

Subslab vapor concentrations are converted to indoor air concentration by applying the TF as follows

Cja ^ Csubslab X I r

The TF for each COC along with the resulting concentrations of COC in indoor air are presented in Tables

EXPOSURE EVALUATION

Noncarcinogenic health effects are evaluated by calculating the average dose of a constituent over the course of the exposure period This dose is termed the Average Daily Dose (ADD) Potential carcinogenic health effects are evaluated in terms of an individuals theoretical increased risk of developing cancer over a lifetime Although the duration of exposure to a constituent release generally does not last for an entire lifetime constituent intake for carcinogens is estimated as the average dose over a human lifetime (70 years) This lifetime dose applies specifically to the evaluation of carcinogenic effects and is termed tine Lifetime Average Daily Dose (LADD) In a risk assessment the calculated ADD or LADD are estimated quantitatively using assurnptions about the duration frequency and magnitude of exposure experienced by each potential receptor and assumptions about the constituent properties that influence absorption

The quantitative estimation of constituent intake involves the incorporation of numerical assumptions for a variety of exposure parahneters Exposure assumptions used in these intake calculations are based on WVDEP (2001) or USEPA (1989 2002b) recommended values The factors and equation for inhalation of vplatiles is presented in Table 4 and described below

bull Inhalation Rate and Exposure Time WVDEP (2001) and USEPA (2002b) guidance recommend that an inhalation rate of 20 m day be used for workers For an exposure time of 8 hours (a typical workday) this results in an inhalation rate of 25 m hour

bull Exposure Frequency and Duration Default exposure factors for indoor workers are provided by WVDEP (2001) Exposure frequency for the worker is 5 days per week for 50 weeks a year or 250 days per year The exposure duration for these workers is 25 years which is the 95th percentile value ai cording to the Bureau of Labor Statistics (USEPA 1989)

bull Body Weight The default value for average body weight of an adult is 70 kg based on WVDEP (2001) and USEPA guidance (1989 2002b)

Page 2 of 5

AR100289

Risk-Based Remedies

R B R Consulting Inc

bull Averaging Time As described above the doses for noncarcinogenic health effects are averaged oyer the specific period of exposure for a given receptor Noncarcinogenic

averaging times are therefore calculated by multiplying the exposure duration for the receptor by 365 daysyear Carcinogenic health effects are calculated over a lifetime exposure so the value recommended by WVDEP (2001) and USEPA (2002b) for average lifetime 70 years was used for exposure duration The resulting carcinogenic averaging time is 25550 days

TOXICITY VALUES

Noncarcinogenic responses are evaluated numerically using parameters known as the hazard quotient (HQ) and hazard index (HI) the HQ is obtained by dividing the ADD for a constituent by the reference dose (RfD) Each dose calculation with a specific combination of constituent receptor and exposure pathway will have a distinct ADD and calculated HQ HQs associated with all constituents for a particular pathway are summed to yield the HI

In order to estimate the theoretical excess lifetime cancer risk the LADD of a constituent is multiplied by the cancer slope factor (CSF) For each pathway this calculation is carried out for each applicable constituent and the risks are summed to obtain the total potential risk due to that pathway

Toxicity values for each constituent are presented in Table 5 the toxicity values were obtained from the following sources

bull Integrated Risk Information System (IRIS) on-line database provided by USEPA (2009)

bull The USEPAs Provisional Peer-Reviewed Toxicity Values (PPRTV) as presented in the USEPA Regional Screening Tables (ORNL 2009)

bull Provisional value from the National Center for Environmental Assessnient (as per WVDEP)

bull The Agency for Toxic Substances and Disease Registrys (ATSDR) Minimal Risk Levels (MRLs ATSDR 2009) and

bull Value cited by USEPA Region 3 attributed to other sources (as per WVDEP)

RISK CHARACTERIZATION

Potential noncarcinogenic effects associated with exposure to COC at the site are estimated by comparing calculated intakes with the contaminant-specific RfDs The total HI was calculated by summing the individual HQs An HI value equal to or less than 1 indicates thatthelikelihopd of ah adverse noncancer effect would be negligible (USEPA 1989) An HI greater than 1 indicates that additional evaluation of the case is warranted

Theoretical excess lifetime cancer risks associated with exposure to COC from the site were calculated by comparing estimated intakes to constituent-specific CSFs Summed theoretical

Page 3 of 5

AR100290

Risk-Based Remedies

R B R Consulting Inc

excess risks are calculated by combining constituent-specific risks The results may be compared with target benchrharks for acceptable risk Various demarcations of acceptable risk have been established by regulatory agencies WDEP (2001) presents a target cancer risk of 1 x 10 for nonresidential scenarios USEPA (1991) considers potential cancer risks in the range of 1 x 10reg to 1 X 10 to be acceptable

Constituent-specific results for the indoor worker are presented in Table 6 For the indoor worker exposed to COC in indoor air (vapor intrusion from subslab vapor) the total HI is 00081 and the potential cumulative cancer risk is 497 X 10reg

These results meet both WVDEP and USEPA benchmarks indicating that the site poses negligible potential for human health risk for indoor workers

CONCLUSIONS

The results of this focused risk evaluation indicate that potential risks associated with vapor intrusion exposure of indoor workers to constituents that may volatilize from subslab vapor are within the acceptable benchmarks established by WVDEP and USEPA No further evaluation of the vapor intrusion pathway is warranted for the site

REFERENCES

Agency for Toxic Substances and Disease Registry (ATSDR 2009) Minimal Risk Levels (MRLs) Available at httpvtfwwatsdrcdcqovmrisindexhtml

Dolphin Environmental LLC (Dolphin 2000) Site Characterization Report Mach 14 2000

Johnson PC and RA Ettinger (1991) Heuristic model for predicting the intrusion rate of contaminant vapors into buildings Environ Sci Technology 25 1445-1452

Oak Ridge National Laboratory (ORNL 2009) Regional Screening Levels for Chemical Contaminants at Superfund Sites April 15 2009 Available online httpwwwepagovreg3hwmdriskhumanrb-concentration_tableindexhtm

United States Environmental Protection Agency (USEPA 1989) Risk Assessment Guidance for Superfund Volume I PartA Human Health Evaluation Manual EPA5401-89002

United States Environmental Protection Agency (USEPA 1991) Risk Assessment Guidance for Superfund Volume I Part B Development of Risk-Based Remediation Goals Office of Emergency and Remedial Response OSWER Directive 92857-018

United States Environmental Protection Agency (USEPA 2002a) Draft Guidance for Evaluating the Vapor Intrusion to Indoor Air Pathway from Groundwater and Soils Office of Solid Waste and Emergency Response Pub No 92856-10 December 2002

Page 4 of 5

AR100291

Risk-Based Remedies

R B R Consul t ing Inc

United States Environmental Protection Agency (USEPA 2002b) Supplemental Guidance for Calculating Soil Screening Levels for Superfund Sites Office of Solid Waste and Emergency Response December

United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004

United States Environmental Protection Agency (USEPA 2009) Integrated Risk Information System (IRIS) On-line database wwwepaqoviris

West Virginia Department of Environmental Protection (WVDEP 2001) West Virginia Voluntary Remediation and Redevelopment Act-Guidance Manual Version 21 March 13

Page 5 of 5

AR100292

TABLES

AR100293

TABLE 1 SUBSLAB VAPOR SAMPLES INCLUDED IN THE RISK ASSESSMENT

Coyne text i le Services Facility - Huntington West Virginia

Medium

Subslab Vapor

Sample Identification

bull VP-01

VP-02

VP-03

Sample Date

8132009

8132009

8132009

Coyne VIMemo Tables_09-08-09xls 982009

AR100294

TABLE 2 IDENTIFICATION OF CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR

Coyne Textile Services Facility - Huntington West Virginia

mdash

Const i tuent

Volati le Organics

111-Trichlor6ethane

1122-Tetrachloroethane

112-Trichloro-122-trifluoroethane

112-Trichloroethane

11-Dichloroethane

11-Dichloroethene

124-Trichlorobenzene

124-Trimethylbenzene

12-Dibromoethane

12-Dichlor6benzene

12-Dichloroethane

12-Dichloroethene (cis)

12-pichloroethene (trans)

12-Dichloropropane

12-Dichlorotetraf1uoroethane

135-Trimethylbenzene

13-Butadiene

13-Dichlorobenzene

13-Hexachlorobutadiene

14-Dichlorpbenzene

224-trimethylpentane

2-Chlorotoluene

4-Ethyltoluene

Acetone

Allyl Chloride

Benzene

Bromodichloromethane

Bromoform

Bromomethane

Carbon disulfide bull

Carbon tetrachloride

ChJorobenzene

Chloroethane

Frequency of Detection

0 3

0 3

0 3

bull 0 3

0 3

0 3

0 3

1 3

0 3 bull

0 3

b 3 bull

2 3

0 3

bull 0 3

0 3

0 3

0 3 bull

0 3

0 3

0 3

0 3

0 3

0 17

3 3

0 3

P 3

- 0 3

0 3

0 3

0 3

0 3

0 3

0 3

Min imum Detected

Concentrat ion

(ugm^)

ND

ND

ND

ND

ND

- ND

N D

197

ND bull

ND

ND

369

ND

bull~ ND

ND

ND

ND

ND

ND

bull ND

ND

ND

ND

796

ND

ND

ND-

ND

ND

ND

ND

ND

ND

Maximum

Detected Concentrat ion

(ugm3)

ND

ND

ND

ND

ND

ND

ND

197

ND

ND

ND

mdash 6030

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

1880

ND-

ND

ND

ND

ND

ND

ND

ND

ND

Sample wi th Maximum Detect

ND

ND

ND

ND

ND

ND

- ND

VP-03 -

ND

ND

ND

VP-03

ND

bullND

ND

ND

ND

ND

ND

ND

ND

ND

ND

VP-02

ND

ND bull

ND

ND

ND bull

bull ND

ND

ND

ND

Min imum Detection

Limit (ugm3)

22

28

31

22

16

16

30

20

31

24

16

bull 16

16

19

28

20

89

24 bull

43

24

bull 19

2 1

20

--^ 13

13

27

41

16

13

25

18

11

Maximum Detection

Limit (ugm3)

218

275

307

218

162

159

297

197

307

240

162

- 16

159

185

280

197

89

240

427

240

187

207

197

--125

128

268

414

155

125

252

184

106

Vapor Intrusion Corhparison

V a l u e

(ugm)

22000

042

300000

15

bull 5000

2000

2000

60

011

2000

094

350

700

40

NA

60

0087

1100

11

8000

NA

NA

NA

3500

NA

31

14

22

50

7000

16

bull 600

100000

Chemical of Concern

No

No

No

No

No

No

No

YES

No

No

No

YES

No

No

No

N o bull

bullNo

No

No

No

No

No

No

N o

No

No

No

N o

No

No

No

No

No

Comment

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent notdetected

fflaximCimTdeteetlSffieedsTcomDarisonivalues

Constituent not detected

Constituent not detected

Constituent not detected

Maximum detect exceeds comparison value

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Maximum detect below comparison value

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detectedl

Constituent not detected

Constituent not detected

CoyneVI Memo Tables_09-08-09xls 982009

AR100295

TABLE 2

IDENTIFICATION OF CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR

Coyne Textile Services Facility - Huntington West Virginia

Const i tuent

Volati le Organics

Chloroform -

Chloromethane

13-Dichloropropene (cis)

Cyclohexarie^

Dibrcimochloromethane

DichlonDdifluoromethane

Ethylbenzene

Methyl ethyl ketone

Methyl isobutyl ketone

Methyl tert-butyl ether

Methylene chloride

n-Heptane

n-Hexane

Styrene

Tert-butyl alcohol

Tetrachloroethene

Toluene

13-Dichloropropene(trans)

Triehloroethene

Trichlorofluoromethane

Vinyl bromide

Vinyl chloride

Xylene (0)

Xylenes (mampp)

Frequency of Detection

1 3

0 3

0 3

1 3

0 3

0 3

0 -3

1 3

0 3

0 3

2 3

0 3

3 3

0 3

0 3

3 3

1 3

- 0 3

3 3

P 3

0 3

0 3

1 3

1 3

Min imum Detected

Concentrat ion

(ugm)

5910

ND

ND

52

ND

ND

ND

23

ND

ND

1160

ND

1 4 4

ND

ND

11200

18

ND

91

ND

ND

ND

208

387

Maximuri i Detected

Concentrat ion (ugmS)

bull

5910

ND

ND

52

bull ND

ND

ND

23

ND

ND

1520

ND

183

ND

ND

149000

18

ND

7820

ND

bullND

ND

208

387

Sample vyith Max imum Detect

VP-02

ND

ND

VP-01

bull ND

ND

ND

VP-01

ND

ND

VP-02

ND

VP-02

ND

ND

VP-02

VP-01

ND

VP-03

ND

ND

ND

VP-03

VP-03

Min imum Detection

Limit (ugm3)

20

83

18

138

34

bull 20

17

118

16

14

14

16

- -17

12

--151

18

--23

18

10

1 7 bull

1 7 bull

Maximum Detection

Limit (ugm3)

195

83

182

138

341

198

174

118

164

144

14

164

170

121 -

--151

182

225

175

102

bull 174

174

Vapor Intrusion Compar ison

V a l u e

(ugm)

11

24

NA

2000

1

2000

22

10000

800

30000

52

NA

2000

10000

NA

81

4000

NA

022

7000

NA

28

70000

70000

Chemical o f Concern

YES

No

No

No

No bull

No

No bull

No bull=

No

No

YES

No

No

No

No

YES

No

No

YES

N o

No

No

No

No

Comment

Maximum detect exceeds comparison value

Constituent not detected

Constituent not detected

Maximum detect below comparison value

Constituent not detected

Constituent not detected

Constituent not detected

Maximum detect below comparison value

Constituent not detected

Constituent not detected

Maximum detect exceeds comparison value

Constituent not detected bull

Maximum detect below comparison value

Constituent not detected

Constituent not detected

Maximum detect exceeds comparison value

Maximum detect below comparison value

Constituent not detected

Maximum detect exceeds comparison value

Constituent not detected

Constituent not detected

Constituent not detected bull

Maximum detect below comparison value

Maximum detect below comparison value

Notes

ND - Not Detected

NA - Not Available

- - Constituent detected in every sample detection limit not presented

Values in bold indicate detection limit exceeds comparison values

Target shallow soil gas comparison values corresponding to indoor air concentrations where the soil gas to indoor air attenuation factor = 01 and the target cancer risk is set to ip (presented in Table 2c of USEPA 2002a)

Comparison value for cyclohexane is based on the comparison value for hexane

Coyne VI Memo Tables_09-08-09xls 982009

AR100296

TABLES

EXPOSURE POINT CONCENTRATIONS FOR CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR

Coyne Textile Services Facility - Huntington West Virginia

Chemical of Concern

VolatileOrganics

i24-Trimethylbenzene

12-Dichloroethene (cis)

Chloroform

Methylene chloride

Tetrachloroethene Triehloroethene

Subslab Vapor Source

Concentration (mgm^)

0197

603

591

152

149 782

Transport

Factor^ (unitless)

108E-05

108E-05

108E-05

108E-05

108E-05 108E-05

EPC in

Indoor Air (mgm^)

213E-06

651 E-05

638E-05

164E-05

161E-03 844E-05

Notes

^ Subslab vapor source concentration is based on the maximum detected concentration of samples

VP-01-02 and-03 (see Table 2) -

^ Details of the transport factor calculations are presented in Appendix B

^ Exposure Point Concentration (EPC) in inidoor air is calculated as the subslab vapor concentration TF

Coyne VI Memo Tables_09-08-09xls 982009

AR100297

TABLE 4

FACTORS USED IN DOSE CALCULATIONS INHALATION OF VOLATILE EMISSIONS

Coyne Textile Services Facility - Huntington West Virginia

Symbol

CA

IRA

ET

EF

ED-

BW

AT

Exposure Factor

Constituent Concentration in Air

Inhalation Rate

Exposure Time

Exposure Frequency

Exposure Duration

Body Weight

Averaging Time

Indoor Worker

Constituent-Specific See Table 3

25 m hour

8 hrday

250 daysyear

25 years

bull 70 kg

9125 days (NC)

25550 days (C)

Total Dose = CA x IR^ x ET x EF x ED x 1BW x 1AT

(NC) - Non-carcinogenic Averaging Time

(C) - Carcinogenic Averaging Time

Coyne VI Memo Tables_09-08-09xls 982009

AR100298

TABLES TOXICITY VALUES FOR CHEMICALS OF CONCERN

Coyne Textile Services Facility - Huntington West Virginia

Chemical of Concern

Volatile Organics

124-Trimethylbenzene

12-Dichloroethene (cis)

Chloroform

Methylene chloride

tetrachloroethene

Triehloroethene

Target Organ Critical Effect

blood

bullblood

liver

liver

liver CMS

liver kidney fetus CNS

Chroniclnhalation Reference Dose

(mgkg-day)

200E-03 P

1 OOE-02 R

140E-02 E

286E-01 M

771 E-02 M

1OOE-02 E

Inhalation Cancer ^ Slope Factor

(mgkg-day)^

NA

NA

805E-02 1

165E-03 1

200E-02 0

400E-01 E

(I) - Integrated Risk Information System (IRIS USEPA 2009)

(P) - Provisional Peer-Reviewed Toxicity Value (PPRTV) as presented in USEPA Regional Screening Tables (ORNL 2009)

(R) - Calculated assuming route-to-route extrapolation as per WVDEP

(E)-Provisional value from the National Center for Environmental Assessment (as per WVDEP)

(M)-Chronic Minimal Risk Level (MRL ATSDR 2009)

(0) - Value cited by USEPA Region 3 attributed to other sources (as per WVDEP)

Coyne VI Memo Tables_09-08-09xls 982009

AR100299

TABLE 6

NONCANCER HAZARD INDEX AND POTENTIAL CANCER RISK FOR AN INDOOR WORKER

Coyne Textile Services Facility - Huntington West Virginia

bull

Constituent

Volatile Organics

124-Trinnethylbehzene

12-Dichlorpethene (cis)

Chloroform

Methylene chloride

Tetrachloroethene Triehloroethene

EPC in Indoor Air

(mgm)

213E-06

651 E-05

- 638E-05

164E-05

161 E-03

844E-05

Intake (ADD)

(mgkg-d)

416E-07

127E-05

125E-05

321 E-06

315E-04 l65E-05

RfDi

(mgkg-d)

200E-03

1OOE-02

140E-02

286E-01

771 E-02 1 OOE-02

Hazard

Quotient

208E-04

127E-03

892E-04

112E-05

408E-03 165E-03

Intake (LADD)

(mgkg-d)

) 149E-07

455E-06 bull 446E-06

115E-06

112E-04 590E-06

CSFi

(mgkg-d)

NA

NA

805E-02

165E-03

200E-02

400E-01

Potential

Cancer Risk

NA

NA

359E-07

189E-09

225E-06 236E-06

Total Hazard Index

00081 Total

Cancer Risk 497E-06

Total Blood HI = Total Liver HI =

Total Central Nervous System HI = Total Kidney HI =

Total Fetal HI =

bull 00015 00066 00057 00017 00017

Notes NA = Toxicity values are not available for this endpoint or exposure pathway

Coyne VI Memo Tables_09-08-09xls 982009

AR100300

APPENDIX A

SUBSLAB VAPOR ANALYTICAL DATA

AR100301

Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility Huntington West Virginia

Sample

Consti tuent

Volatile Organics (ugm) 111-Trlchloroethane 1122-Tetrachloroethane 112-Trichloro-122-trifluoroethane 112-Trichloroethane 11-Dichioroethane 11-Dichloroethene 124-Trichloroberi2ene 124-Trimethylbenzene 12-Dibromoethane 12-Dichloroben2ene 12-Dichloroethane 12-Dichloroethene-(cis) -12-Dichloroethene (trans) 12-Dichloropropane 12-Dichlorotetrafluoroethane 135-Trimethylbenzene 13-Butadiene 13-Dichlorobenzene 13-Hexachlorobutadiene 14-Dichlorobenzene 224-trimethVlpentane 2-Chlorotoluene 4-Ethyltoluene Acetone Allyl Chloride Benzene Bromodichloromethane Bromoform Bromomethane Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 13-Dichloropropene (cis) Cyclohexane Dibromochloromethane

Identif ication Sample Date

CAS No

71-55-6 79-34-5 76-13-1 79-00-5 75-34-3 75-35-4 120-82-1 95-63-6 106-93-4 95-50-1 107-06-2 156-59-2 156-60-5 78-87-5 76-14-2 108-67-8 106-99^0 541-73-1 87-68-3 106-46-7 540-84r1 95-49-8

622-96-8 67-64-1 107-05-1 71-43-2 75-27-4 75-252 74-83-9 75-15-0 56-23-5 108-90-7 75-00-3 67-66-3 74-87-3

10061-01-5 110-82-7 124-48-1

lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt

lt lt lt lt lt lt lt lt lt lt lt lt

lt

VP-01 8132009

22 28 31 22 16 16 30 20 31 24 16 16 16 19 28 20 89 24 43 24

1 9 21 20 796 13 13 27 41 16 13 25 18 11 20 83 18 52 34

lt lt lt lt lt lt lt lt lt lt lt

lt lt lt lt lt lt lt lt lt lt lt

lt lt lt lt lt lt lt lt lt

lt lt lt lt

VP-02 8132009

218 2 7 5 307 218 162 159 297

bull 197 307 240 162 369 159 185 280 197 89

240 427 240 187 207 197

1880 125 128 268 414 155 125 252 184 106

5910 83 182 138 341

lt lt lt lt lt lt lt

lt lt lt

lt lt lt lt lt lt lt bull

lt lt lt lt

lt lt lt lt lt lt lt lt lt lt lt lt lt lt

VP-03 8132009

218 275 307 218

bull 162 159 297 197 307 240 162

6030 159 185 280 197 89

240 427 240 187 207 197

1750 125 128 268 414 155 125 252 184 106 195 83 182 138 341

Appx A SG Dataxis Page 1 of 2 982009

AR100302

Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility bull Huntington West Virginia

Consti tuent

Volatile Organics (ugm^) Dichlorodifluoromethane Ethylbenzene Methyl ethyl ketone Methyl Isobutyl ketone Methyl tert-butyl ether Methylene chloride n-Heptane jn-Hexane Styrene Tert-butyl alcohol Tetrachloroethene iToluene 13-Dichloropropene (trans) Triehloroethene Trichlorofluoromethane Vinyl bromide Vinyl chloride Xylene (o) Xylenes (mampp)

Sample Identif ication Sample Date

CAS No

75-71-8 100-41-4 78-93-3 108-10-1

1634-04-4 75-09-2

142-82-5 bull 110-54-3

100-42-5 75-65-0 127-18-4 108-88-3

10061-02-6 79-01-6 75-69-4 593-60-2 75-01-4 95-47-6

179601-23-1

lt lt

lt lt lt lt

lt lt

lt

lt lt lt lt lt

VP01 8132009

20 17 23 16 14 14 16

173 17 12 bull

11200 18 18 91 23 18 10 17 17

lt lt lt lt lt

lt

lt lt

lt lt

lt lt lt lt lt

VP-02 8132009

198 174 118 164 144

1520 164 -183 170 121

149000 151 182

2360 225 175 102 174 174

VP-03 8132009

lt 198 lt 174 lt 118 lt 164 lt 144

1160 lt 164

144 lt 170 ltbull 121

90500 lt 151 lt 182

7820 lt 225 lt 175 lt 102

208 387

Appx A SG Dataxis Page 2 of 2 982009

AR100303

APPENDIX B

CALCULATION OF TRANSPORT FACTORS USED TO ESTIMATE INDOOR AIR CONCENTRATIONS

AR100304

APPENDIX B

Calculation of Transport Factors Used to Estimate Indoor Air Concentrations

This appendix presents the methodology for calculating transport factors that are used to convert subslab

vapor concentrations to concentrations in indoor air 124-Trimethylbenzene 12-dichloroethene (cis)

chloroform methylene chloride tetrachloroethene and triehloroethene were identified as contaminants of

concern (COC) for potential vapor intrusion from subslab vapor associated with the Coyne Textile

Services Facility located in Huntington West Virginia (site) In this appendix the transport factors are

calculated to estimate the concentrations of COC in indoor air of the existing plant building located at the

site ~

Transport Factor for Indoor Air

The concentration of a constituent in indoor air (da) is proportional to the concentration of the constituent

in the subslab vapors immediately beneath the building foundation (ie subslab vapor concentration or

Csubsiab) The following equation is used to calculate da from Csubsiab

^ wja ~ ^subslab X I r

where

Cia = concentration of constituent in indoor air (mgm^) -

Csubsiab^ concentration of constituent in subslab vapors (mgm^) and

TF = transport factor from subslab vapors to indoor air

The transport factor (TF) is an infinite source attenuation coefficient andcan be calculated based on a

model developed by Johnson and Ettinger (1991) t he equation for calculating TF is as follows

(Deff X A B ) ( Q B X L T ) X expKQso i l X Lcrabk)(Dcrack X Acrack)]

exp[ (Qsoi l X Lcrack)(Dcrack X Acrack)] + (Deff X A B ) ( Q B X L T ) + (Deff X AB)(Qsoi l X L j ) X (exp [ (Qso i l X Lcrack)(Dcrack X Acrack)] - 1)

where

Deff = effective diffusion coefficient for vadose zone soil (cm^sec)

AB = area of enclosed space below grade (cm^)

QB = building ventilation rate (cm^sec)

LT = distance from contaminant source to building foundation (cm)

Qsoii = volumetric flow rate of vapors into the building (cm^sec)

Lcrack = foundatlon thickness (cm)

Dcrack = vapor diffusion coefficient through crack (cm^sec) and

Acrack = area of cracks through which vapors can pass (cm^)

AR100305

To solve this equation the USEPAs SG-ADV spreadsheet Version 31 most recently updated in

February 2004 was implemented A combination of site-specific factors and default values from the

Users Guide for Evaluating Subsurface Vapor Intrusion Into Buildings (USEPA 2004) were used as input

values in the model All input values are defined below and presented in Tables B-1-A through B-6-A

bull The initial subslab vapor concentration (Csubsiab) is the maximum detected concentration(in units

of ugm ) of samples VP-01 VP-02 and VP-03 that was presented in Table 3 of the report

bull The depth below grade to the bottom of the enclosed space floor (Lp) is set to 15 cm the default

value provided by USEPA (2004) for a slab-on-grade structure

bull The vapor sampling depth below grade (Lg) is a site-specific value The vapor samples were

collected from immediately beneath the building floor therefore Lj has been set to 15 cm

bull The average soilgroundwater temperature (Ts) is set to 125degC the average value for West

Virginia as estimated frorri Figure 8 of the vapor intrusion users guide (USEPA 2004)

bull The soil type used to estimate vapor permeability is assumed to be sandy loam (SL) The

associated soil properties for a sandy loam soil type are as follows the soil dry bulk density (Pb) is

162 gcm the total porosity (n) is 0387 (cm^-aircm^) and the water-filled porosity (nw) is 0103

(cm -HzOcm )

bull The floor thickness (Lcrack) is set to the USEPA (2004) default value of 10 cm

bull The soil-building pressure differential (AP) is set to the USEPA (2004) default value of 40 gcm-s^

bull The building dimensions are siterspecific based on the existing plant building located at the site

The existing structure is approximately 84000 square feet (Dolphin 2000) therefore the

dimensions are set to 8839 cm (290 feet) length by 8839 cm (290 feet) The USEPA (2004)

default value of 244 cm vyas used for the height

bull Thefloor-wall seam crack width (w) is set to the USEPA (2004)-default value of 01 cm

bull The indoor air exchange rate (ER) is set to 083hour This is the value provided by ASTM (2002)

for commercial and industrial buildings

AR100306

Tables B-1-B through B-6-B present the constituent-specific properties for COC that were used in the TF

calculations Tables B-1-C through B-6-C present the intermediate calculations used to determine the

indoor air attenuation coefficients (ie the transport factors) The shaded boxes in Tables B-1-C through

B-6-C also present the resulting TF values that are applied to the concentrations of COC in subslab

vapor and the estimated indoor air concentrations

References

American Society for Testing and Materials (ASTM 2002) Standard Guide for Risk-Based Corrective Action Applied at Petroleum Release Sites ASTM E-1739-95 (Reapproved 2002)

Johnson PC and RA Ettinger (1991) Heuristic model for predicting the intrusion r-ate of contaminant vapors into buildings Environ Sci Technolpgy 25 1445-1452

Dolphin Environmental LLC (Dolphin 2000) Site Characterization Report Mach 14 2000

United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004

AR100307

APPENDIX B-1-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV Nersion31 0204

Reset to Defaults

ENTER -

Chemical CAS No

(numbers only

no dasties)

95636

ENTER Soil gas

cone

Cg (ngm)

Soil Gas Concentration Data ENTER

Soil gas

OR cone

bull - c bull (PPmv)

197E+02

Chemical

124-Trimethylbenzene

MORE ENTER Depth

below grade to bottom

of enclosed space floor

U bull (cm)

ENTER

Soil gas sampling

depth below grade

U (cm) bull

ENTER

Average soil

temperature Ts

CO

1 15 1 1 5 bull125

ENTER ENTER ENTER Totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hft ha he

(cm) (cm) (cm)

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estirnate OR permeability | soil vapor

permeability) k v bull

(cm)

SL 1 1

MORE ENTER

stratum A SCS

soil type

Lookup Soil Parameters

ENTER stratum A soil dry

bulk density P

(gcm)

ENTER Stratum A soil total porosity

(unitless)

ENTER bull stratum A soil water-filled

porosity

(cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

nlaquo

(unitless)

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gchi-s^)

ENTER Enclosed

space floor

length bull LB

(cm)

ENTER Enclosed

space floor

width WB

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

bull Floor-wall seam crack

width w

(cm)

bullENTER

Indoor air exchange

rate ER

(1h) bull

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bidg OR

Leave blank to caicuij

(Lm)

Appx B-1 124-TMBxls 1 of 3 982009

AR100308

APPENDIX B-1-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of ^ bull law constant law constant vaporization at Normal

Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temperature boiling point point temperature weight

D bull Dbdquo H T R bull AHbdquo TB Tc IVIW

Unit risk Reference

factor cone URF RfC

(cms) (cmls) (atm-mmol) CO (calmol) (degK) (degK) (gmol) bull (ugm)- (mgm)

1 606E-02 1 792E-06 1 bull 614E-C3 1 25 1 9369 1 44230 | 64917 1 12020 1 OOE+00 1 60E-03 1

Appx B-1 124-TMBxls 2 of 3 982009

AR100309

APPENDIX B-1-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

(sec)

Source-building

separation

LT bull

(cm) bull

Stratum A soil

air-filled porosity

Q A

Stratum B soil

air-filled porosity

(cmcm) (cmcm)

Stratum C soil air-filled porosity

(cmcm)

Stratum A effective total fluid

saturation

Se

(cmcm)

Stratum A soil

bullintrinsic permeability

^ (cm)

stratum A Stratum A Floor- soil soli wall BIdg

relative air effective vapor seam Soil bull ventilation permeability permeability perimeter gas rate-

kfg ky Xgrack c o n e - QbuHdinpound

(cm) - (cm) (cm) (ngm) (cms)

946E+08 1 0284 0284 0284 0184 596E-09 0901 537E-09 35357 I 197E+02 | 439E+06 |

Area of enclosed

space below grade

As (cm)

Crack-to-total area ratio

1 bull

(unitless)

Crack depth

below grade

Zcfack

(cm)

Enthalpy of vaporization at

ave soil temperature

AHvjs

(calmol) bull

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law constant at

ave soil bull temperature

bull HTS

(unitless)

Vapor bull viscosity at

ave soil temperature

HTS

(gcm-s)

Stratum A

effective diffusion

coefficient

D (cms)

Stratum-B

effective diffusion coefficient

DB (cms)

Stratum C effective diffusion

coefficient

D-c (cms)

Total - overall effective diffusion

coefficient

D ^ (cms)

Diffusion path

length

L-

(cm)

I 787E+07 I 449E-05 | 15 | 11661 260E-03 111E-01 176E-04 I 612E-03 j OOOE+00 | OOOE+00 | 612E-03 j

bull Convection path

length

Lp

(cm)

Source vapor cone

^source

(ngm)

Crack radius

Tcfack

(cm)

Average vapor

flow rate into bIdg

Qsoii

(cms)

Crack effective diffusion

coefficient pcrack

(cms)

Area of CTack

Acack

(cm)

Exponent of equivalent foundation

Peclet number

exp(Pe)

(unitless)

bull bull - bull bull bull bull

1 15 1 197E+02 1 010 1 474E+01 612E-03 bull 354E-t-03 1 336E+09

Infinite source Indoor

~ attenuation coefficient

a

(unitless)

108E-05

Infinite source

btJbldgjJSv-L ^Ppncji3i-

virhpbiiilding bullbull ^lHltti^m)ilg

213E-03

Unit risk

factor

URF

(ngm)-

Reference cone

RfC (mgm)

NA 60E-03 1

I END

Appx B-1 124-TMBxls 3 of 3 982009

AR100310

APPENDIX B-2-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV Nersion31 020^

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

156592

Soil Gas Concentration Data ENTER

Soil gas

cone OR c

(ngm) bull

ENTER Soil bull-gas

cone

c (ppmv)

603E+03 1

Chemical

cis-12-Dichloroethylene

MORE ENTER Depth

below grade to bottom

of enclosed space floor

LF

(cm)

ENTER

Soil gas sampling

depth below grade

U (cm)

ENTER

Average soil

temperature bull Ts

(degC)

1 15 1 bull 15 125

ENTER ENTER ENTER Totalsmust add ijp tb value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hA hB he

bull (cm) (cm) (cm)

15 1 1

ENTER Soil

straturh A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estimate OR permeability | soil vapor

permeability) kv

(cm)

SL 1 |

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

P (gcm)

ENTER Stratum A soil total porosity

bull n

(unitless)

ENTER Stratum A

soil water-filled porosity

(cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

ENTER Stratum B

soil water-filled porosity

ENTER Stratum C

SCS soil type

(unitless) (cmcm)

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure differential

AP

(gcm-s)

ENTER Enclosed bull

space floor

length

LB (cm)

ENTER Enclosed

space floor

width WB

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER

Average vapor flow rate into bIdg

OR Leave blank to calculi

Qsoil

(Lm)

Appx B-2 cis-12-DCExls 1 of 3 982009

AR100311

APPENDIX B-2-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Diffusivity in air

Da

(cms)

Diffusivity in water

Dw (cms)

Henrys law constant at reference temperature

H

(atm-mmoi)

Henrys law constant

reference temperature

bull T R

CC)

Enthalpy of vaporization at

the normal boiling point

AHbdquob

(calmol)

Normal boiling point

TB

(degK)

Critical temperature

Tc (degK)

Molecular weight

MW

(gmol)

Unit risk

factor URF

(ngm)

Reference cone

RfC (mgm)

1 736E-02 1 113E-05 1 407E-03 j 1 25 1 bull 7192 1 33365 1 54400 1 9694 1 OOE+00 j 35E-02 1

Appx B-2 cis-12-DCExls 2 of 3 982009

AR100312

APPENDIX B-2-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

stratum A Stratum B Stratum C Source- soil soil soil

Exposure building air-filled air-filled air-filled

duration separation porosity porosity porosity

T LT ea e^ bull e= (sec) (cm) (cmcm) (cmcm) (cmcm)

I 946E+08n^

Stratum A Stratum A Stratum A Stratum A Floor-effective soil soil soil wall total fluid intrinsic relative air effective vapor seam

saturation permeability permeability permeability perimeter

Ste kj krg ky Acrack

(cmcm) (cm) (cm) (cm) (cm)

Soil gas

cone (ngm)

I 0284 I 0284~ 0284 0184 I 596E-09 | 090T 537E-09 35357 603E+03

BIdg ventilation

rate

JbulldinE

(cms)

439E+06

Area of enclosed

space below grade

AB

(cm)

Crack-to-total

area ratio

n (unitless)

Crack depth below grade

Zltiack (cm)

Erithalpy of vaporization at

ave soil temperature

AHvTs (calmol)

Henryslaw constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law constant at

ave soil temperature

HTS

(unitless) bull

Vapor viscosity at

ave soil bull temperature

HTS

bull (gcm-s)

Stratum A

effective bull diffusion

coefficient

D^A-(cms)

Stratum B

effective bull diffusion

coefficient

D=B

(cms)

Stratum C

effective diffusion bull

coefficient

D=e (cms)

Total overall

effective diffusion

coefficient

DT

(cms)

Diffusion path

length

Ld

(cm)

I 787E+07 I bull449E-05 | 15 bull7709 230E-03 982E-02 176E-04 | 743E-03 | OOOE+00 | OOOE+00 | 743E-03 |

bull bull bull -

Convecfion path -bull

length

Lp (cm)

Source vapor cone

-source

(Mgm)

Crack radius

fcrack

(cm)

Average vapor

flow rate into bIdg

Qaoil bull

(cms)

Crack effective diffusion

coefficient pcack

(cms)

Area of crack

crack

(cm)-

Exponent of equivalent foundation

Peclet number

exp(Pef)

(unitless)

bull

1 15 -1 603E+03 1 010 1 474E+01 743E-03 354E+03 1 697E+07

Infinite source Indoor

attenuation coefficient

poundbullbullbull C t

pound(unitless)

bullsiilaquogt j ii08E-05

Infinite [ source

bIdg cone

Cbujidjng

(pgm)

651 E-02 iKrt

Unit risk

factor

URF

(ngm)-

Reference cone

RfC

(mgm)

NA 35E-02 1

I END I

Appx B-2 cis-12-DCExls 3o f3 982009

AR100313

APPENDIX B-3-A DATA ENTRY SHEET

Coyne Texti le Services - Hunt ington West Virginia

SG-ADV Version 31 0204

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

67663

Soil Gas Concentration Data ENTER ENTER

Soil Soil gas gas

cone OR cone c C

(^gm) (ppmv)

591 E+03

bull

Chemical

Chloroform

MORE ENTER Depth

below grade tb bottom

of enclosed space floor

bull LF

(cm)

ENTER

Soil gas sampling depth

below grade

(cm)

ENTER

Average soil

temperature-Ts

CO bull

1 15 1 15 1 125

ENTER ENTER ENTER Totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

IIA hs he (cm) (cm) (cm)

1 5 bull 1 1

ENTER ENTER Soil - bull

stratum A User-defined SCS stratum A

soil type bull soil vapor (used to estimate OR permeability

soil vapor k

bull permeability) (cm) 1

SL 1 1 bull

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A soil dry

bulk density

Pb (gcm)

ENTER Stratum A soil total porosity

nV (unitless)

ENTER Stratum A

-soilwater-filled bullporosity

Sraquo (cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

(unitless)

ENTER Stratum B

soil water-filled porosity

bull ebdquo=

(cmcm) bull

ENTER Straturri C

SCS bull soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

- c rack

(cm)

ENTER

Soil-bldg pressure

differential AP^

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor

width bull W B

(cm)

ENTER

Enclosed space

height HB

(cm)

ENTER

bull Floor-wall^ seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bidg OR

Leave blank to calculi

Qsoil bull

(Lm)

I -I

Appx B-3 Chloroformxls 1 of 3 982009

AR100314

APPENDIX B-3-B CHEMICALPROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Diffusivity in air

D (cms)

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffijsivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature

Dbdquo H TR A H bdquo TB Tc

(cm s) (atm-m mol) ro (calmol) (degK) (degK)

Molecular weight

MW

(gmol)

Unit risk

factor URF

(ngm)-

Reference cone

RfC

(mgm)

104E-01 100E-05 I 366E-03 25 6988 33432 53640 11938 I 23E-05 | OOE+00

Appx B-3 Chloroformxls 2 of 3 982009

AR100315

APPENDIX B-3-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure

duration

(sec)

Source-

building

separation

LT

(cm)

Stratum A

soil

air-filled

porosity

Sa

( cm cm )

Stratum B

soil

air-filled

porosity

( cm cm )

Stratum C

soil

air-filled

porosity

( c m c m )

Stratum A

effective

total fluid

saturation

( c m c m )

Stratum A

soil

intrinsic

penmeability

k

(cm )

Stratum A

- soil

relative air

permeabil i ty

(cm )

Stratum A

soil

effective vapor

permeability

kv

(cm )

Floor-

wall

seam

perimeter

gtcrack

(cm)

Soil gas

cone

(ngm)

BIdg

venfilation

rate

^buildlriE

(cms)

I 9 4 6 E + 0 8 ~ T I 0284 T 596E-09 I 0-901 I 537E-09 | 35357 | 591 E+03 j 439E+06 | 1 0 284 0284 0184

Area of

enclosed

space

below

grade

A B

( c m )

Crack-

to-total

area

ratio

n

(unitless)

Crack

depth

bull below

grade

^crack

(cm)

Enthalpy of

vaporization at

ave soil

temperature

AHTs bull

(calmol)

Henry s law

constant at

ave soil

temperature

HTS

(a tm-m mol j

Henrys law

constant at

ave soil

bull temperature

HTS

(unitless) bull

Vapor

viscosity at

ave soil-

temperature

^HTS

(gcm-s)

Stratum

A

effective

diffusion

coefficient

(cm s)

Stratum

B

effective

difftjsion

coefficient

D B

(cms) bull

S t ra tum

C

effective

diffusion

coefficient

Dc

(cm s)

Total

overall

effective

bull diffusion

coefficient

D T

(cm s)

Diffi jsion

path

length

Ld

(cm)

I 787E+07 I 449E-05 j - bull 15 7528 210E-03 896E-02 176E-04 I 105E-02 | OOOE+00 | OOOE+00 | 105E-02

Convection

path length

Lp

(cm)

Source

vapor

cone -

^source

- (ngm)

Crack

radius

Tcrack

(cm)

Average

vapor

flow rate

into bidg

Qsoil

(cms)

Crack

effective

diffusion

coefficient Qcrack

bull (cms)

Area of crack

Acrack

(cm)

Exponent of

equivalent

foundation

Peclet number

exp(Pe)

(unitless)

V bull bull

1 15 1 591 E+03 1 010 1 474E+01 105E-02 354E+03 1 355E+05

Infinite

source

indoor

attenuation

coefficient

d

(unitless)

bull 108E-05

Infinite

source

bIdg

cone

^ b u i l d i n g

i (^gm)

bull bull

i 638E-02 -

Unit

risk bull factor

URF

(ngmY

Reference

cone

RfC

(mgm)

~ 23E-05 NA 1

I END

Appx B-3 Chloroform xls 3 of 3 982009

AR100316

APPENDIX B-4-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ersion 31-020^

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

nodashes)

bull 75092

ENTER Soil gas

cone

c (ngm)

Soil Gas Concentration Data ENTER

Soil gas bull

OR cone

bull C

(ppmv)

152E+03

bull bull

Chemical

Methylene chloride

MORE

MORE 4gt

ENTER Depth

below grade to bottom

of enclosed space floor

LF -

(cm)

ENTER

Soil gas sampling depth

below grade

bull U

(cm)

ENTER

Average soil

temperature

Ts bull CC)

bull bull bull bull

1 15 1 15 125

ENTER Totals

Thickness of soil

stratum A h

(cm)

ENTER ENTER must add up to value of Ls (cell F24

Thickness Thickness of soil of soil

stratum B stratum C (Enter value or 0) (Enter value or 0)

he he bull

(cm) bull (cm) -

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(usedto estimate OR perrrieability | soil vapor

permeability)

k bull

(cm)

SL 1 bull 1

ENTER Stratum A

SCS soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

Pb (gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Stratum A

soil water-filled porosity

9w (cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

Pb^

(gcm)

ENTER Stratum B soil total porosity

n^

(unitless)

ENTER Stratum B

soil water-filled porosity

(crhcm)

ENTER Stratum C

SCS soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE 4gt

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

bull Soil-bldg pressure

differential AP^

(gcm-s)

ENTER Enclosed

space floor

length LB

(cm)

ENTER Enclosed

space floor

width bull W B

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width

w

(cm)

ENTER

Indoor air exchange

rate

ER (1h)

ENTER Average vapor

flow rate into bidg OR

Leave blank to calculc

Qsoil

(Lm)

10 40 8839 8839 244 01 083

Appx B-4 MCxIs 1 of 3 982009

AR100317

Diffijsivity in air

D

APPENDIX B-4-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffusivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature

Pw H TR AHt TB TC

Molecular weight

MW

Unit risk

factor URF

Reference cone

RfC

(cms) (cms) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) bull (ngm)- (mgm)

bull bull

1 101E-01 1 117E-05 1 218E-03 1 25 | 6706 1 31300 1 51000 1 8493 1 47E-07 1 30E+00 1

Appx B-4 MCxIs 2 of 3 982009

AR100318

APPENDIX B-4-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

T

(sec)

Source- -building

separation

LT

(cm)

Stratum A soil

air-filled porosity

e a bull

(cmcm)

Stratum B soil

bullair-filled porosity bull

ea^ (cmcm)

Stratum C soil

air-filled porosity

ea= (cmcmj

Stratum A effective total fluid

saturation

Sc bull

(cmcm)

Stratum A soil

intrinsic pemneability

ki (cm)

Stratum A soil

relative air permeability

^ ^ g

(cm)

stratumA bull soil effective vapor permeability

K (cm)

Floor-wall

seam perimeter

Xcrack

(cm)

Soil gas

cone (ngm)

BIdg ventilation

rate

Qbuildinc

(cms)

1 946E+08

Area of -enclosed

space below

bull grade

AB

(cm)

1

Crack-to-total

area rafio

Tl

(unitless)

0284 1

Crack depth below grade

Zcrack

(cm)

0284 1

bull Enthalpy of vaporization at

ave soil temperature

AHTs (calmol)

0284

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

0184

Henrys law constant at ave soil

temperature

HTS

bull (unitless)

1 596E-09

Vapor viscosity at

ave soil temperature

Mrs (gcm-s)

0901

Stratum A

effective diffusion

coefficient

D (cms)

537E-09

Stratum B

effective diffusion

coefficient

D-B (cms)

35357 1

Stratum C -

effective diffusion

coefficient

D-c ^ (cms)

152E+03

Total bull overall

bull effective diffusion

coefficient

D ^

(cms)

440E+06 1

Difftjsion path

length

Ld (cm)

1 787E+07

Convection path

length

Lp (cm)

4 49E-05

Source vapor cone

Csource

(ngm)

15 1

Crack radius

Tcrack

(cm)

7007 bull 1

Average vapor

flow rate intobldg

Qsoil

(cms)

130E-03

Crack effective diffusion

coefficient pcrack

(cms)-

555E-02

bull ^

Area of crack

Acrack

(cm) bull

1 176E-04

Exponent of equivalent foundation

Peclet number

exp(Pe)

(unitless) bull

bull bull

1 15

1 END

152E+03 010 1 474E+01 1 102E-02 354E+03 1 519E+05

102E-02

Infinite source

indoor ^attenuation coefficient

bull a

(unitless)

aiii08E-05

0 OOE+00

bull

Infinite bull source

bIdg ^ cone

^bu i l d i ng

(MQm)

164E-02

OOOE+00 1

Unit risk

factor

URF

(ngm)-

47E-07 1

102E-02 j

Reference cone

RfC

(mgm)

30E+00 j

1 1

Appx B-4 MCxIs 3 of 3 982009

AR100319

APPENDIX B-5-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ^erslon 31 0204

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

127184

Soil Gas Concentration Data ENTER ^ ENTER

Soil -Soi l bull gas gas

cone OR cone Cg C bull

(tgm) (ppmv)

149E+05 1

Chemical

bull Tetrachlbroethylene

MORE 4

ENTER Depth

below grade to bottom

ofenclosecJ space floor

LF

(cm)

ENTER

Soil gas bull sampling

depth below grade

u bull (cm)

ENTER

Average bullsoil

temperature - Ts

ro 1 1 5 1 15 1 125 bull

ENTER ENTER ENTER totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hft bull he bull he

(cm) (cm) (cm)

bull 1 5 1 - 1

ENTER ENTER Soil

stratum A User^defined bull SCS bull stratum A soil type soil vapor

(used to estimate OR perrrieability soil vapor K bull

permeability) (cm) 1

SL 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

Pb

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Sitratum A

soil water-filled bull porosity

(cmcm)

ENTER Stratum B

SCS soiltype

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

Pb^

(gcm)

ENTER Stratum B soil total porosity

Ajnitless^

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS soil type

LookupSoil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

VS

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor width

W B

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width

w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

ENTER Average vapor

flow rate into bidg OR

Leave blank to calcul

bull Qsoil

(Lm)

10 40 8839 8839 244 01 083

Appx B-5 PCExIS 1 of 3 982009

AR100320

APPENDIX B-5-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal Unit

Diffusivity Diffusivity at reference reference the riormal boiling Critical Molecular risk Reference in air in water temperature temperature boiling point point teriiperature weight factor cone

Da Dbdquo H TR AHb TB Tc MW URF RfC

(cms) (cnis) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) (^gm)- (mgm)

1 720E-02 1 820E-06 1 184E-02 1 25 1 8288 1 39440 1 62020 1 16583 1 59E-06 1 60E-01 1

J

AppxB-5PCExls 2 of 3 - 982009

AR100321

APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

T

(sec)

Source-building

separation

LT

bull (cm)

Stratum A soil

air-filled porosity

Oa (cmcm)

Stratum B - soil air-filled porosity

ea (cmcm)

Stratum C soil

air-filled porosity

ea= - (cmcm)

Stratum A effective total fluid

saturation

sbdquo (cmcm)

Stratum A soil

intrinsic permeability

ki (cm)

Stratum A soil

relative air permeability

- ^ g

(cm)

Stratum A soil

effective vapor permeability

kv (cm)

Floor-wall

seam perimeter

^crack

(cm)

Soil gas

cone

(ngm)

BIdg venfilation

rate

Qbuildins

bull (cms)

bull bull

1 946E+08

Area of enclosed

space below grade

AB

(cm)

1

bullCrack-to-total

area ratio

1 (unitless)

0284 1

Crack bull depth below grade

Zcrack

(cm) -

0284 1

Enthalpy of vaporization at bull

ave soil temperature

bull A H V TS

(calmol)

0284

Henrys law constant at

ave soil temperature

HTS (atm-mmol)

0184

-Henrys law constant at

ave soil temperature

HTS

(unitless)

1 596E-09

Vapor viscosity at

ave soil temperature

HTS

(gcm-s)

0901

Stratum A

effective diffusion

coefficient bull D = bull

(cms)

537E-09

Stratum B

effective diffusion

coefficient

D--B (cms)

35357 1

Stratum C

effective diffusion bull

coefficient

D-c (crris)

149E+05

Total overall

effective bulldiffusion coefficient

DT

(cms)

440E+06 1

Difftjsion path

length

U (cm)

1 787E+07

Convection path

length

bull Lp

(cm)

4 49E-05

Source vapor cone

^source

(ngm)

15 1

Crack radius

Tcrack

(cm)

9528 1

Average vapor

flow rate intobldg

Qsoil (cms)

908E-03

Crack effective diffusion

coefficient pcrack

bull ( c m s ) bull

387E-01

Area of crack

Abdquoack (cm)

1 176E-04

Exponent of equivalent foundafion

Peclet number

exp(Pe)

(unitless)

bull

1 15-

1 END

149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08

727E-03

Infinite source indoor

attenuation coefficient

a

(unitless)

108E-05

OOOE+00

Infinite source

bIdg cone

Cburldtng

(Mgm)

161 E+00

OOOE+00 1

Unit risk

factor

URF

(ugm)-

59E-06 1

727E-03

Reference cone

RfC (mgm)

60E-01

1 1

Appx B-5 PCExls 3 of 3 982009

AR100322

APPENDIX B-6-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ersion31 0204

Reset to Defaults

t

Soil Gas Concentration Data ENTER

Chemical CAS No

(numbers only

no dashes)

79016

ENTER ENTER Soil Soil gas gas

cone OR cone C C -

bull (ngm) (ppmv)

782E+03

Chemical

Trichloroethylene

MORE ENTER Depth

below grade to bottom-

of enclosed space floor

LF

(cm)

ENTER

Soil gas sarnpling

depth below grade

U (cm)

ENTER

Average soil

temperature Ts

(degC)

1 15 1 15 t 125

ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e

(cm) (cm) (cm)

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estimate OR permeability soil vapor

permeability)

k (cm)

bull S L 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil bull-Parameters

ENTER Stratum A

soil dry bulk density

P b -

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Stratum A bull

soilwaterrfilled porosity

(cmcm) bull

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

bull P ^ (gcm)

ENTER Stratum B soil total

porosity

nlaquo

(unitless) -

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS bull soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor

width W B

(cm)

ENTER

Enclosed space height

H B bull

( c m ) bull

ENTER

Floor-wall seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bIdg OR

Leave blank to calculc

Qsoil

(Lm) -

Appx B-6 TCExIs 1 of 3 982009

A

AR100323

APPENDIX B-6-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight

Da Dbdquo H TR AH^b TB TC MW

Unit risk Reference

factor cone URF RfC

(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)

1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1

Appx B-6 TCExIs 2 of 3 982009

AR100324

APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

(sec)

Source-building

separation LT

(cm)

Stratum A soil

air-filled porosity

bull ea (cmcm)

Stratum B Soil

air-fllled porosity

e^ bull (cmcm)

Stratum C soil

air-filled porosity

(cmcm)

StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air

saturation permeability permeability

S|e k krg (cmcm) (cm) (cm)

Stratum A Floor-soil wall BIdg

effective vapor seam Soil ventilafion permeability perimeter gas rate

k^ bull Xack c o n e Qbuildins

(cm) (cm) (ngm) (cms)

946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |

Area of enclosed

space below grade

AB

(cm)

Ciack- to-total

area ratio

1 (unitless)

Crack depth below grade

Zcrack

(cm)

Enthalpy of vaporization at

ave soil temperature

A H J S

(calmol)

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law bull constant at

ave soil temperature

HTS

(unitless)

Vapor viscosity at

ave soil temperature

|JTS

(gcm^s)

Stratum A

effective diffusion

coefficient

(cms)

Stratum B

effective -diffusion

coefficient

D=B (cms)

Stratum ^ C effective diffusion

coefficient

D=c (cms)

Total overall

effective diffusion

coefficient

DT

(cms)

I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03

Diffusion path

length

Li (cm) bull

Convection bull path

length

Lp

(cm)

Source vapor cone bull

^source

(ngm)

Crack radius

rcrack

(cm)

Average vapor

- flow rate intobldg

Qsoil

(cms)

Crack effective diffusion

bull coefficient Qcrack

(cms)

Area of crack

^crack

(cm)

Exponent of equivalent foundation

Peclet bull number

exp(Pe)

(unitless)

bull bull

1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07

Infinite source Indoor

attenuation coefficient

a

(unitless)

108E-05

Infinite source

bIdg concgt

^building

(ngm)

844E-02

Unit risk

factor

URF

(ngm)-

Reference cone

RfC

(mgm)

1 1E-04 1 40E-02 1

END

Appx B-6 TCExIs 3 of 3 982009

AR100325

Office of Waste Management 1356 Hansford Street

Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256

West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director

ORDER

ISSUED UNDER THE

HAZARDOUS WASTE MANAGEMENT ACT

CHAPTER 22 ARTICLE 18

OF THE WEST VIRGINIA CODE^ AS AMENDED

y Order Number HW-011-80

To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704

ATTEMTION MREDARMON

Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull

AR100326

ViWJ011-laquo9 PageNunil)er2

BASIS FOR ORDER

As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following

A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^

B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator

C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities

0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94

^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement

P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following

1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater

2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was

^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment

CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable

CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order

AR100327

H W - 0 1 1 - 9 9 Page Number 3

REQUIREMENTS OF ORDER

Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows

1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^

2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore

remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling

GENERAL PROVaiONS

1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order

2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order

3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order

Effective Date

Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief

Wt T 1 V Oflice of Waste Management

AR100328

^ ^ S I S

^wmmmmamn

AR100329

Page 6: SDMS DocID 2121999 · International Enterprises Corp. building (Coyne Building), which is located at 1111 Vernon Street, Westmoreland District, Wayne County, West Virginia. The following

Wayne County Economic Development Authority Groundwater Assessment Coyne TextileServices Building Westmoreland District Wayne County West Virginia October 24 2008 -

Page 2

FIGURE 1 SITE LOCATION MAP Huntington WVa USGS 75-minute Topographic Quadrangle

1985

Laboratory analytical results were compared to the applicable WVDEP groundwater

maximum contaminant level (MCL) or de mnms values listed in Table 60-3 effective June

26 2008 Concentrations of VOC which exceeded the de minimis values were identified in

5 of 5 groundwater samples collected Tetrachloroethene (PERC) was detected in each of

the groundwater samples at concentrations which exceeded the de minimis values

Triehloroethene was detected in samples collected from GP-1 GP-3 and GP-5 at

concentrations which exceeded the de minimis values Cis-12-Dichloroethene was detected

in samples collected from GP-1 and GP-3 at concentrations which exceeded the de minimis

values Vinyl Chloride was detected in each sample except GP-5 at concentrations which

exceeded the de minimis values A summary of laboratory analytical reports is provided in

Table 1 Laboratory Analytical Summary-Groundwater and copies of the Laboratory

Analytical Reports are included as Attachmenf 1

AR100283

(9

00 S

P B B K ftVENIjEl

WEST MORELAND PARK

TENNIS BASKETBALL COURTS

GP-5 GP-4

9-inn i in iMMIMII I IMMII I I I I I I I IMI I I I I I IMI I I IMMII I I I I I I I I IMMII I I I I I IMI I I I I I I I I I I I IMI I I I I I I I I I I IMMII I I IMIMIMII I I I I I I I I I IMI I I I I I I I IMI I I I

CSX RAILROAD GP-2 GP-1 GP-3 I I I I I I I IMI I I IMMI I IMI I I I I I IMIMI I I IMI I I I I I I I I in i l lMI IMIMI I I I I IMMI I I I I I Jd I I IMj r i i y i l lMMI I I IMI I I I I I I I I in i l l l l l l lM l l l l l l l i n i l l l l l l l l ijj^lll^flH|t

bull

ACCESS ROAD

BUILDING

- bull

G P X ^

MM ^

MW

4-

bull ^

LEGEND

CW SAMPLE LOCAT10

MONITORING WELL

gtl

n

PARK ING

SCALE 1 r bull

WCEDA VRP GROUNDWATER SAMPLINGS HUNTINGTON WEST VIRGINIA

F I G U R E tslD

Cad Files04-08-p408-1dgn 6122009 24625 PM

- AR100284

Wayne County Economic Development Authority Page 3 Groundwater Assessment Coyne Textile Services Building Westmoreland District Wayne County West Virginia October 24 2008 _ bull ^

We appreciate the opportijnity to assist you with this project If you have any questions or r

need additional information please feel free to contact us

Sincerely TRIAD ENGINEERING INC

Matthew C Wright

Project Geologist

JohnM Meeks PG LRS

Project Manager

end

^

AR100285

Table 1 Laboratory Analytical Summary - Groundvvater WCEDA Vernon street

Huntington Wayne County West Virginia

COPC

Acetone Benzene Bromobenzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone sec-Butylbenzene n-Butyibenzene tert-Butylbenzene Carbon disulfide Carbon Tetrachloride Chlorobenzene Chlorodibromorriethane Ghloroethane Chlbroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene 12-Dibromo-3-chloropropane 12-Dlbronnoethane (EDB) DIbromomethane 14-Dichlorobenzene 13-Dictilorobenzene 12-Dictilorobenzene Dichlorodifluoromethane 11-Dlchloroethane 12-Dichloroethane cis-12-Dichloroethene

MCL ugL

5500 5

NV NV NV 85 87

700 61 61 61

1000 5

100 NV 39

bull 017 190 NV NV 02

005 NV

750 600 600 390 910

5 70

GP-1 ugL ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND

ND ND ND ND ND ND ND ND ND ND ND ND 112 ND

5210

GP-2 ugL ND ND ND

ND ND ND ND ND ND ND ND ND ND ND ND ND ND

062 J ND ND ND

ND ND ND ND ND ND ND ND

379

GP-3 ^ ugL

ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND

065 J ND 184 ND( ND ND ND

ND ND ND ND ND ND ND

12500

GP-4 ugL ND ND ND ND ND

- ND ND ND ND ND ND ND ND ND ND ND ND ND

ND ND ND ND ND ND ND ND ND ND ND 132

GP-5 ugL ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND

ND ND ND ND ND ND ND ND ND ND ND ND 59

Notes - Bold Indicates COPCs detected at concentrations greater than the MCL bull(60CSR3 Table 60-3B July 2008)

NAME - J indicates analyte detected at levels less than the reporting limit and greater than

or equal to the MDL value is estimated -NV indicates no value has been established

AR100286

Table 1 Laboratory Analytical Summary - Groundwater (Continued) WCEDA Vernon street

Huntington Wayiie County West Virginia

COPC

11-Dichloroethene trans-12-Dichloroethene 13-Dichloropropane 12-Dichloropropane 22-Dichloropropane cis-13-Dichloropropene trans-13rDichloropropene 11-Dichloropropene Ethylbenzene Hexachlorobutadiene 2-Hexanone Isopropylbenzene p-lsopropyltoluene Methyl tert-Butyl Ether Methylene Chloride 4-Methyl-2-pentanone Naphthalene n-Propylbenzene Styrene 1112-Tetrachloroethane 1122-Tetrachloroethane Tetrachloroethene Toluene 123-Trichlorobenzene 124-Trichlorobenzene 112-Trichloroethane 111-Trlchloroethane Triehloroethene Trichlorofluoromethane 123-Trichloropropane 135-Trimethylbenzene 124-Trimethylbenzene Vinyl chloride Xylenes total s

MCL ugL

91 100 04

5 NV NV NV NV

700 086

NV NV

NV 028

5 NV 62 NV 100

043 0055

5 1000

NV 70

5 20

5 1300

0034 120 120

2 10000

GP-1 ugL 964 458 ND ND

ND ND ND ND

052 J ND ND ND ND ND ND ND ND ND ND ND ND

14700 065 J ND ND ND ND

2850 ND

ND ND ND 116 146 J

GP-2 ugL ND ND ND ND ND ND ND- ND ND ND ND ND -ND ND ND ND ND ND ND ND ND

603 ND ND ND ND ND

079 J ND ND ND ND 242 ND

GP-3 ugL 346 865 ND ND

bull ND ND ND-ND

055 J ND ND ND ND ND ND ND ND ND ND ND ND

13900 159 ND ND ND ND

4870 ND ND ND ND 708 149 J

GP-4 ugL ND ND ND ND ND ND ND ND ND ND ND

ND 177 ND ND ND ND ND ND ND ND

583 ND ND ND ND ND

082 J ND ND ND ND

227 ND bull

GP-5 ugL ND ND ND ND ND

ND ND ND ND ND ND ND ND

ND ND ND ND ND ND ND ND 133 ND ND ND ND ND

574 ND ND

ND ND 122 ND

Notes - Bold indicates COPCs detected at concentrations greater than the MCL

(60CSR3 Table 60-3B July 2008) - ND indicates non-detected at concentrations greater than the MCL - J indicates analyte detected at levels less than the reporting limit and greater than

or equal to the MDL value is estimated - NV indicates no value has been established

AR100287

Risk-Based Rerfiedies

R B R Consulting Inc 650 Shady Drive Beaver Falls PA 15010

Phone724-846-4096 Fax 724-846-6974

MEMORANDUM

TO John Meeks Triad Engineering Inc

FROM Bruce Fishman

DATE September 82009

SUBJECT Evaluation of Potential Risks Associated with Vapor Intrijsion to Indoor Air Coyne Textile Services Facility - Huntington West Virginia

bull V bull bull bull

This memorandum presents a risk evaluation for potential risks associated with vapor intrusion to indoor air at the Coyne Textile Services Facility located in Huntington West Virginia (site) This evaluation was conducted according to West Virginia Department of Environmental Protection (WVDEP) and United States Environmental Protection Agency (USEPA) methodologies

DATA INCLUDED 1N THE EVALUATION

This evaluation includes three subslab vapor samples (VP-01 VP-02 and VP-03) collected from immediately beneath the floor of the existing site building Table 1 lists the subslab vapor samples included in this risk assessment Samples were analyzed for volatile organic compounds (VOCs) by USEPA Method TO-15 Complete analytical data for these samples are provided in Table A-1 of Appendix A

The analytical results of the subslab vapor samples were compared to the target shallow soil gas comparison values presented in Table 2c of the USEPA vapor intrusion guidance document (2002a) These companson values are generic soil gas screening values that are protective of indoor air for residential land uses and represent concentrations in-sliallow soil gas based on a target risk level of 1 x 10reg andor a hazard index of 1 The comparison is presented in Table 2

As indicated in Table 2 the following constituents are identified as contaminants of concern (COC) for the vapor intrusion to indoor air pathway 124-trimethylbenzene 12-dichloroethene (cis) chloroform methylene chloride tetrachloroethene and triehloroethene

ESTIMATION OF INDOOR AIR CONCENTRATIONS

The concentrations of COC in indoor air associated with vapor intrusion from subslab vapor were estimated using methodologies outlined in the Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings (USEPA 2004) A transport factor (TF) is required that will relate the

Page 1 of 5 -

AR100288

Risk-Based Remedies

R B R Consulting Inc

constituent concentration in subslab vapor to the concentration in indoor air The TF is dependent on the diffusion coefficient and other properties that will affect the transfer of constituents into air such as distance from the source to tlie breathing zone soil properties and building properties A site-specific building size of 84000 square feet (Dolphin 2000) and a soil type of sandy loam were used in the calculation of TF The TF is determined using calculationsbased on the Johnson and Ettinger (1991) vapor intrusion model Details of the TF calculations are provided in Appendix B

Subslab vapor concentrations are converted to indoor air concentration by applying the TF as follows

Cja ^ Csubslab X I r

The TF for each COC along with the resulting concentrations of COC in indoor air are presented in Tables

EXPOSURE EVALUATION

Noncarcinogenic health effects are evaluated by calculating the average dose of a constituent over the course of the exposure period This dose is termed the Average Daily Dose (ADD) Potential carcinogenic health effects are evaluated in terms of an individuals theoretical increased risk of developing cancer over a lifetime Although the duration of exposure to a constituent release generally does not last for an entire lifetime constituent intake for carcinogens is estimated as the average dose over a human lifetime (70 years) This lifetime dose applies specifically to the evaluation of carcinogenic effects and is termed tine Lifetime Average Daily Dose (LADD) In a risk assessment the calculated ADD or LADD are estimated quantitatively using assurnptions about the duration frequency and magnitude of exposure experienced by each potential receptor and assumptions about the constituent properties that influence absorption

The quantitative estimation of constituent intake involves the incorporation of numerical assumptions for a variety of exposure parahneters Exposure assumptions used in these intake calculations are based on WVDEP (2001) or USEPA (1989 2002b) recommended values The factors and equation for inhalation of vplatiles is presented in Table 4 and described below

bull Inhalation Rate and Exposure Time WVDEP (2001) and USEPA (2002b) guidance recommend that an inhalation rate of 20 m day be used for workers For an exposure time of 8 hours (a typical workday) this results in an inhalation rate of 25 m hour

bull Exposure Frequency and Duration Default exposure factors for indoor workers are provided by WVDEP (2001) Exposure frequency for the worker is 5 days per week for 50 weeks a year or 250 days per year The exposure duration for these workers is 25 years which is the 95th percentile value ai cording to the Bureau of Labor Statistics (USEPA 1989)

bull Body Weight The default value for average body weight of an adult is 70 kg based on WVDEP (2001) and USEPA guidance (1989 2002b)

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bull Averaging Time As described above the doses for noncarcinogenic health effects are averaged oyer the specific period of exposure for a given receptor Noncarcinogenic

averaging times are therefore calculated by multiplying the exposure duration for the receptor by 365 daysyear Carcinogenic health effects are calculated over a lifetime exposure so the value recommended by WVDEP (2001) and USEPA (2002b) for average lifetime 70 years was used for exposure duration The resulting carcinogenic averaging time is 25550 days

TOXICITY VALUES

Noncarcinogenic responses are evaluated numerically using parameters known as the hazard quotient (HQ) and hazard index (HI) the HQ is obtained by dividing the ADD for a constituent by the reference dose (RfD) Each dose calculation with a specific combination of constituent receptor and exposure pathway will have a distinct ADD and calculated HQ HQs associated with all constituents for a particular pathway are summed to yield the HI

In order to estimate the theoretical excess lifetime cancer risk the LADD of a constituent is multiplied by the cancer slope factor (CSF) For each pathway this calculation is carried out for each applicable constituent and the risks are summed to obtain the total potential risk due to that pathway

Toxicity values for each constituent are presented in Table 5 the toxicity values were obtained from the following sources

bull Integrated Risk Information System (IRIS) on-line database provided by USEPA (2009)

bull The USEPAs Provisional Peer-Reviewed Toxicity Values (PPRTV) as presented in the USEPA Regional Screening Tables (ORNL 2009)

bull Provisional value from the National Center for Environmental Assessnient (as per WVDEP)

bull The Agency for Toxic Substances and Disease Registrys (ATSDR) Minimal Risk Levels (MRLs ATSDR 2009) and

bull Value cited by USEPA Region 3 attributed to other sources (as per WVDEP)

RISK CHARACTERIZATION

Potential noncarcinogenic effects associated with exposure to COC at the site are estimated by comparing calculated intakes with the contaminant-specific RfDs The total HI was calculated by summing the individual HQs An HI value equal to or less than 1 indicates thatthelikelihopd of ah adverse noncancer effect would be negligible (USEPA 1989) An HI greater than 1 indicates that additional evaluation of the case is warranted

Theoretical excess lifetime cancer risks associated with exposure to COC from the site were calculated by comparing estimated intakes to constituent-specific CSFs Summed theoretical

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excess risks are calculated by combining constituent-specific risks The results may be compared with target benchrharks for acceptable risk Various demarcations of acceptable risk have been established by regulatory agencies WDEP (2001) presents a target cancer risk of 1 x 10 for nonresidential scenarios USEPA (1991) considers potential cancer risks in the range of 1 x 10reg to 1 X 10 to be acceptable

Constituent-specific results for the indoor worker are presented in Table 6 For the indoor worker exposed to COC in indoor air (vapor intrusion from subslab vapor) the total HI is 00081 and the potential cumulative cancer risk is 497 X 10reg

These results meet both WVDEP and USEPA benchmarks indicating that the site poses negligible potential for human health risk for indoor workers

CONCLUSIONS

The results of this focused risk evaluation indicate that potential risks associated with vapor intrusion exposure of indoor workers to constituents that may volatilize from subslab vapor are within the acceptable benchmarks established by WVDEP and USEPA No further evaluation of the vapor intrusion pathway is warranted for the site

REFERENCES

Agency for Toxic Substances and Disease Registry (ATSDR 2009) Minimal Risk Levels (MRLs) Available at httpvtfwwatsdrcdcqovmrisindexhtml

Dolphin Environmental LLC (Dolphin 2000) Site Characterization Report Mach 14 2000

Johnson PC and RA Ettinger (1991) Heuristic model for predicting the intrusion rate of contaminant vapors into buildings Environ Sci Technology 25 1445-1452

Oak Ridge National Laboratory (ORNL 2009) Regional Screening Levels for Chemical Contaminants at Superfund Sites April 15 2009 Available online httpwwwepagovreg3hwmdriskhumanrb-concentration_tableindexhtm

United States Environmental Protection Agency (USEPA 1989) Risk Assessment Guidance for Superfund Volume I PartA Human Health Evaluation Manual EPA5401-89002

United States Environmental Protection Agency (USEPA 1991) Risk Assessment Guidance for Superfund Volume I Part B Development of Risk-Based Remediation Goals Office of Emergency and Remedial Response OSWER Directive 92857-018

United States Environmental Protection Agency (USEPA 2002a) Draft Guidance for Evaluating the Vapor Intrusion to Indoor Air Pathway from Groundwater and Soils Office of Solid Waste and Emergency Response Pub No 92856-10 December 2002

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United States Environmental Protection Agency (USEPA 2002b) Supplemental Guidance for Calculating Soil Screening Levels for Superfund Sites Office of Solid Waste and Emergency Response December

United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004

United States Environmental Protection Agency (USEPA 2009) Integrated Risk Information System (IRIS) On-line database wwwepaqoviris

West Virginia Department of Environmental Protection (WVDEP 2001) West Virginia Voluntary Remediation and Redevelopment Act-Guidance Manual Version 21 March 13

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AR100292

TABLES

AR100293

TABLE 1 SUBSLAB VAPOR SAMPLES INCLUDED IN THE RISK ASSESSMENT

Coyne text i le Services Facility - Huntington West Virginia

Medium

Subslab Vapor

Sample Identification

bull VP-01

VP-02

VP-03

Sample Date

8132009

8132009

8132009

Coyne VIMemo Tables_09-08-09xls 982009

AR100294

TABLE 2 IDENTIFICATION OF CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR

Coyne Textile Services Facility - Huntington West Virginia

mdash

Const i tuent

Volati le Organics

111-Trichlor6ethane

1122-Tetrachloroethane

112-Trichloro-122-trifluoroethane

112-Trichloroethane

11-Dichloroethane

11-Dichloroethene

124-Trichlorobenzene

124-Trimethylbenzene

12-Dibromoethane

12-Dichlor6benzene

12-Dichloroethane

12-Dichloroethene (cis)

12-pichloroethene (trans)

12-Dichloropropane

12-Dichlorotetraf1uoroethane

135-Trimethylbenzene

13-Butadiene

13-Dichlorobenzene

13-Hexachlorobutadiene

14-Dichlorpbenzene

224-trimethylpentane

2-Chlorotoluene

4-Ethyltoluene

Acetone

Allyl Chloride

Benzene

Bromodichloromethane

Bromoform

Bromomethane

Carbon disulfide bull

Carbon tetrachloride

ChJorobenzene

Chloroethane

Frequency of Detection

0 3

0 3

0 3

bull 0 3

0 3

0 3

0 3

1 3

0 3 bull

0 3

b 3 bull

2 3

0 3

bull 0 3

0 3

0 3

0 3 bull

0 3

0 3

0 3

0 3

0 3

0 17

3 3

0 3

P 3

- 0 3

0 3

0 3

0 3

0 3

0 3

0 3

Min imum Detected

Concentrat ion

(ugm^)

ND

ND

ND

ND

ND

- ND

N D

197

ND bull

ND

ND

369

ND

bull~ ND

ND

ND

ND

ND

ND

bull ND

ND

ND

ND

796

ND

ND

ND-

ND

ND

ND

ND

ND

ND

Maximum

Detected Concentrat ion

(ugm3)

ND

ND

ND

ND

ND

ND

ND

197

ND

ND

ND

mdash 6030

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

1880

ND-

ND

ND

ND

ND

ND

ND

ND

ND

Sample wi th Maximum Detect

ND

ND

ND

ND

ND

ND

- ND

VP-03 -

ND

ND

ND

VP-03

ND

bullND

ND

ND

ND

ND

ND

ND

ND

ND

ND

VP-02

ND

ND bull

ND

ND

ND bull

bull ND

ND

ND

ND

Min imum Detection

Limit (ugm3)

22

28

31

22

16

16

30

20

31

24

16

bull 16

16

19

28

20

89

24 bull

43

24

bull 19

2 1

20

--^ 13

13

27

41

16

13

25

18

11

Maximum Detection

Limit (ugm3)

218

275

307

218

162

159

297

197

307

240

162

- 16

159

185

280

197

89

240

427

240

187

207

197

--125

128

268

414

155

125

252

184

106

Vapor Intrusion Corhparison

V a l u e

(ugm)

22000

042

300000

15

bull 5000

2000

2000

60

011

2000

094

350

700

40

NA

60

0087

1100

11

8000

NA

NA

NA

3500

NA

31

14

22

50

7000

16

bull 600

100000

Chemical of Concern

No

No

No

No

No

No

No

YES

No

No

No

YES

No

No

No

N o bull

bullNo

No

No

No

No

No

No

N o

No

No

No

N o

No

No

No

No

No

Comment

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent notdetected

fflaximCimTdeteetlSffieedsTcomDarisonivalues

Constituent not detected

Constituent not detected

Constituent not detected

Maximum detect exceeds comparison value

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Maximum detect below comparison value

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detectedl

Constituent not detected

Constituent not detected

CoyneVI Memo Tables_09-08-09xls 982009

AR100295

TABLE 2

IDENTIFICATION OF CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR

Coyne Textile Services Facility - Huntington West Virginia

Const i tuent

Volati le Organics

Chloroform -

Chloromethane

13-Dichloropropene (cis)

Cyclohexarie^

Dibrcimochloromethane

DichlonDdifluoromethane

Ethylbenzene

Methyl ethyl ketone

Methyl isobutyl ketone

Methyl tert-butyl ether

Methylene chloride

n-Heptane

n-Hexane

Styrene

Tert-butyl alcohol

Tetrachloroethene

Toluene

13-Dichloropropene(trans)

Triehloroethene

Trichlorofluoromethane

Vinyl bromide

Vinyl chloride

Xylene (0)

Xylenes (mampp)

Frequency of Detection

1 3

0 3

0 3

1 3

0 3

0 3

0 -3

1 3

0 3

0 3

2 3

0 3

3 3

0 3

0 3

3 3

1 3

- 0 3

3 3

P 3

0 3

0 3

1 3

1 3

Min imum Detected

Concentrat ion

(ugm)

5910

ND

ND

52

ND

ND

ND

23

ND

ND

1160

ND

1 4 4

ND

ND

11200

18

ND

91

ND

ND

ND

208

387

Maximuri i Detected

Concentrat ion (ugmS)

bull

5910

ND

ND

52

bull ND

ND

ND

23

ND

ND

1520

ND

183

ND

ND

149000

18

ND

7820

ND

bullND

ND

208

387

Sample vyith Max imum Detect

VP-02

ND

ND

VP-01

bull ND

ND

ND

VP-01

ND

ND

VP-02

ND

VP-02

ND

ND

VP-02

VP-01

ND

VP-03

ND

ND

ND

VP-03

VP-03

Min imum Detection

Limit (ugm3)

20

83

18

138

34

bull 20

17

118

16

14

14

16

- -17

12

--151

18

--23

18

10

1 7 bull

1 7 bull

Maximum Detection

Limit (ugm3)

195

83

182

138

341

198

174

118

164

144

14

164

170

121 -

--151

182

225

175

102

bull 174

174

Vapor Intrusion Compar ison

V a l u e

(ugm)

11

24

NA

2000

1

2000

22

10000

800

30000

52

NA

2000

10000

NA

81

4000

NA

022

7000

NA

28

70000

70000

Chemical o f Concern

YES

No

No

No

No bull

No

No bull

No bull=

No

No

YES

No

No

No

No

YES

No

No

YES

N o

No

No

No

No

Comment

Maximum detect exceeds comparison value

Constituent not detected

Constituent not detected

Maximum detect below comparison value

Constituent not detected

Constituent not detected

Constituent not detected

Maximum detect below comparison value

Constituent not detected

Constituent not detected

Maximum detect exceeds comparison value

Constituent not detected bull

Maximum detect below comparison value

Constituent not detected

Constituent not detected

Maximum detect exceeds comparison value

Maximum detect below comparison value

Constituent not detected

Maximum detect exceeds comparison value

Constituent not detected

Constituent not detected

Constituent not detected bull

Maximum detect below comparison value

Maximum detect below comparison value

Notes

ND - Not Detected

NA - Not Available

- - Constituent detected in every sample detection limit not presented

Values in bold indicate detection limit exceeds comparison values

Target shallow soil gas comparison values corresponding to indoor air concentrations where the soil gas to indoor air attenuation factor = 01 and the target cancer risk is set to ip (presented in Table 2c of USEPA 2002a)

Comparison value for cyclohexane is based on the comparison value for hexane

Coyne VI Memo Tables_09-08-09xls 982009

AR100296

TABLES

EXPOSURE POINT CONCENTRATIONS FOR CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR

Coyne Textile Services Facility - Huntington West Virginia

Chemical of Concern

VolatileOrganics

i24-Trimethylbenzene

12-Dichloroethene (cis)

Chloroform

Methylene chloride

Tetrachloroethene Triehloroethene

Subslab Vapor Source

Concentration (mgm^)

0197

603

591

152

149 782

Transport

Factor^ (unitless)

108E-05

108E-05

108E-05

108E-05

108E-05 108E-05

EPC in

Indoor Air (mgm^)

213E-06

651 E-05

638E-05

164E-05

161E-03 844E-05

Notes

^ Subslab vapor source concentration is based on the maximum detected concentration of samples

VP-01-02 and-03 (see Table 2) -

^ Details of the transport factor calculations are presented in Appendix B

^ Exposure Point Concentration (EPC) in inidoor air is calculated as the subslab vapor concentration TF

Coyne VI Memo Tables_09-08-09xls 982009

AR100297

TABLE 4

FACTORS USED IN DOSE CALCULATIONS INHALATION OF VOLATILE EMISSIONS

Coyne Textile Services Facility - Huntington West Virginia

Symbol

CA

IRA

ET

EF

ED-

BW

AT

Exposure Factor

Constituent Concentration in Air

Inhalation Rate

Exposure Time

Exposure Frequency

Exposure Duration

Body Weight

Averaging Time

Indoor Worker

Constituent-Specific See Table 3

25 m hour

8 hrday

250 daysyear

25 years

bull 70 kg

9125 days (NC)

25550 days (C)

Total Dose = CA x IR^ x ET x EF x ED x 1BW x 1AT

(NC) - Non-carcinogenic Averaging Time

(C) - Carcinogenic Averaging Time

Coyne VI Memo Tables_09-08-09xls 982009

AR100298

TABLES TOXICITY VALUES FOR CHEMICALS OF CONCERN

Coyne Textile Services Facility - Huntington West Virginia

Chemical of Concern

Volatile Organics

124-Trimethylbenzene

12-Dichloroethene (cis)

Chloroform

Methylene chloride

tetrachloroethene

Triehloroethene

Target Organ Critical Effect

blood

bullblood

liver

liver

liver CMS

liver kidney fetus CNS

Chroniclnhalation Reference Dose

(mgkg-day)

200E-03 P

1 OOE-02 R

140E-02 E

286E-01 M

771 E-02 M

1OOE-02 E

Inhalation Cancer ^ Slope Factor

(mgkg-day)^

NA

NA

805E-02 1

165E-03 1

200E-02 0

400E-01 E

(I) - Integrated Risk Information System (IRIS USEPA 2009)

(P) - Provisional Peer-Reviewed Toxicity Value (PPRTV) as presented in USEPA Regional Screening Tables (ORNL 2009)

(R) - Calculated assuming route-to-route extrapolation as per WVDEP

(E)-Provisional value from the National Center for Environmental Assessment (as per WVDEP)

(M)-Chronic Minimal Risk Level (MRL ATSDR 2009)

(0) - Value cited by USEPA Region 3 attributed to other sources (as per WVDEP)

Coyne VI Memo Tables_09-08-09xls 982009

AR100299

TABLE 6

NONCANCER HAZARD INDEX AND POTENTIAL CANCER RISK FOR AN INDOOR WORKER

Coyne Textile Services Facility - Huntington West Virginia

bull

Constituent

Volatile Organics

124-Trinnethylbehzene

12-Dichlorpethene (cis)

Chloroform

Methylene chloride

Tetrachloroethene Triehloroethene

EPC in Indoor Air

(mgm)

213E-06

651 E-05

- 638E-05

164E-05

161 E-03

844E-05

Intake (ADD)

(mgkg-d)

416E-07

127E-05

125E-05

321 E-06

315E-04 l65E-05

RfDi

(mgkg-d)

200E-03

1OOE-02

140E-02

286E-01

771 E-02 1 OOE-02

Hazard

Quotient

208E-04

127E-03

892E-04

112E-05

408E-03 165E-03

Intake (LADD)

(mgkg-d)

) 149E-07

455E-06 bull 446E-06

115E-06

112E-04 590E-06

CSFi

(mgkg-d)

NA

NA

805E-02

165E-03

200E-02

400E-01

Potential

Cancer Risk

NA

NA

359E-07

189E-09

225E-06 236E-06

Total Hazard Index

00081 Total

Cancer Risk 497E-06

Total Blood HI = Total Liver HI =

Total Central Nervous System HI = Total Kidney HI =

Total Fetal HI =

bull 00015 00066 00057 00017 00017

Notes NA = Toxicity values are not available for this endpoint or exposure pathway

Coyne VI Memo Tables_09-08-09xls 982009

AR100300

APPENDIX A

SUBSLAB VAPOR ANALYTICAL DATA

AR100301

Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility Huntington West Virginia

Sample

Consti tuent

Volatile Organics (ugm) 111-Trlchloroethane 1122-Tetrachloroethane 112-Trichloro-122-trifluoroethane 112-Trichloroethane 11-Dichioroethane 11-Dichloroethene 124-Trichloroberi2ene 124-Trimethylbenzene 12-Dibromoethane 12-Dichloroben2ene 12-Dichloroethane 12-Dichloroethene-(cis) -12-Dichloroethene (trans) 12-Dichloropropane 12-Dichlorotetrafluoroethane 135-Trimethylbenzene 13-Butadiene 13-Dichlorobenzene 13-Hexachlorobutadiene 14-Dichlorobenzene 224-trimethVlpentane 2-Chlorotoluene 4-Ethyltoluene Acetone Allyl Chloride Benzene Bromodichloromethane Bromoform Bromomethane Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 13-Dichloropropene (cis) Cyclohexane Dibromochloromethane

Identif ication Sample Date

CAS No

71-55-6 79-34-5 76-13-1 79-00-5 75-34-3 75-35-4 120-82-1 95-63-6 106-93-4 95-50-1 107-06-2 156-59-2 156-60-5 78-87-5 76-14-2 108-67-8 106-99^0 541-73-1 87-68-3 106-46-7 540-84r1 95-49-8

622-96-8 67-64-1 107-05-1 71-43-2 75-27-4 75-252 74-83-9 75-15-0 56-23-5 108-90-7 75-00-3 67-66-3 74-87-3

10061-01-5 110-82-7 124-48-1

lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt

lt lt lt lt lt lt lt lt lt lt lt lt

lt

VP-01 8132009

22 28 31 22 16 16 30 20 31 24 16 16 16 19 28 20 89 24 43 24

1 9 21 20 796 13 13 27 41 16 13 25 18 11 20 83 18 52 34

lt lt lt lt lt lt lt lt lt lt lt

lt lt lt lt lt lt lt lt lt lt lt

lt lt lt lt lt lt lt lt lt

lt lt lt lt

VP-02 8132009

218 2 7 5 307 218 162 159 297

bull 197 307 240 162 369 159 185 280 197 89

240 427 240 187 207 197

1880 125 128 268 414 155 125 252 184 106

5910 83 182 138 341

lt lt lt lt lt lt lt

lt lt lt

lt lt lt lt lt lt lt bull

lt lt lt lt

lt lt lt lt lt lt lt lt lt lt lt lt lt lt

VP-03 8132009

218 275 307 218

bull 162 159 297 197 307 240 162

6030 159 185 280 197 89

240 427 240 187 207 197

1750 125 128 268 414 155 125 252 184 106 195 83 182 138 341

Appx A SG Dataxis Page 1 of 2 982009

AR100302

Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility bull Huntington West Virginia

Consti tuent

Volatile Organics (ugm^) Dichlorodifluoromethane Ethylbenzene Methyl ethyl ketone Methyl Isobutyl ketone Methyl tert-butyl ether Methylene chloride n-Heptane jn-Hexane Styrene Tert-butyl alcohol Tetrachloroethene iToluene 13-Dichloropropene (trans) Triehloroethene Trichlorofluoromethane Vinyl bromide Vinyl chloride Xylene (o) Xylenes (mampp)

Sample Identif ication Sample Date

CAS No

75-71-8 100-41-4 78-93-3 108-10-1

1634-04-4 75-09-2

142-82-5 bull 110-54-3

100-42-5 75-65-0 127-18-4 108-88-3

10061-02-6 79-01-6 75-69-4 593-60-2 75-01-4 95-47-6

179601-23-1

lt lt

lt lt lt lt

lt lt

lt

lt lt lt lt lt

VP01 8132009

20 17 23 16 14 14 16

173 17 12 bull

11200 18 18 91 23 18 10 17 17

lt lt lt lt lt

lt

lt lt

lt lt

lt lt lt lt lt

VP-02 8132009

198 174 118 164 144

1520 164 -183 170 121

149000 151 182

2360 225 175 102 174 174

VP-03 8132009

lt 198 lt 174 lt 118 lt 164 lt 144

1160 lt 164

144 lt 170 ltbull 121

90500 lt 151 lt 182

7820 lt 225 lt 175 lt 102

208 387

Appx A SG Dataxis Page 2 of 2 982009

AR100303

APPENDIX B

CALCULATION OF TRANSPORT FACTORS USED TO ESTIMATE INDOOR AIR CONCENTRATIONS

AR100304

APPENDIX B

Calculation of Transport Factors Used to Estimate Indoor Air Concentrations

This appendix presents the methodology for calculating transport factors that are used to convert subslab

vapor concentrations to concentrations in indoor air 124-Trimethylbenzene 12-dichloroethene (cis)

chloroform methylene chloride tetrachloroethene and triehloroethene were identified as contaminants of

concern (COC) for potential vapor intrusion from subslab vapor associated with the Coyne Textile

Services Facility located in Huntington West Virginia (site) In this appendix the transport factors are

calculated to estimate the concentrations of COC in indoor air of the existing plant building located at the

site ~

Transport Factor for Indoor Air

The concentration of a constituent in indoor air (da) is proportional to the concentration of the constituent

in the subslab vapors immediately beneath the building foundation (ie subslab vapor concentration or

Csubsiab) The following equation is used to calculate da from Csubsiab

^ wja ~ ^subslab X I r

where

Cia = concentration of constituent in indoor air (mgm^) -

Csubsiab^ concentration of constituent in subslab vapors (mgm^) and

TF = transport factor from subslab vapors to indoor air

The transport factor (TF) is an infinite source attenuation coefficient andcan be calculated based on a

model developed by Johnson and Ettinger (1991) t he equation for calculating TF is as follows

(Deff X A B ) ( Q B X L T ) X expKQso i l X Lcrabk)(Dcrack X Acrack)]

exp[ (Qsoi l X Lcrack)(Dcrack X Acrack)] + (Deff X A B ) ( Q B X L T ) + (Deff X AB)(Qsoi l X L j ) X (exp [ (Qso i l X Lcrack)(Dcrack X Acrack)] - 1)

where

Deff = effective diffusion coefficient for vadose zone soil (cm^sec)

AB = area of enclosed space below grade (cm^)

QB = building ventilation rate (cm^sec)

LT = distance from contaminant source to building foundation (cm)

Qsoii = volumetric flow rate of vapors into the building (cm^sec)

Lcrack = foundatlon thickness (cm)

Dcrack = vapor diffusion coefficient through crack (cm^sec) and

Acrack = area of cracks through which vapors can pass (cm^)

AR100305

To solve this equation the USEPAs SG-ADV spreadsheet Version 31 most recently updated in

February 2004 was implemented A combination of site-specific factors and default values from the

Users Guide for Evaluating Subsurface Vapor Intrusion Into Buildings (USEPA 2004) were used as input

values in the model All input values are defined below and presented in Tables B-1-A through B-6-A

bull The initial subslab vapor concentration (Csubsiab) is the maximum detected concentration(in units

of ugm ) of samples VP-01 VP-02 and VP-03 that was presented in Table 3 of the report

bull The depth below grade to the bottom of the enclosed space floor (Lp) is set to 15 cm the default

value provided by USEPA (2004) for a slab-on-grade structure

bull The vapor sampling depth below grade (Lg) is a site-specific value The vapor samples were

collected from immediately beneath the building floor therefore Lj has been set to 15 cm

bull The average soilgroundwater temperature (Ts) is set to 125degC the average value for West

Virginia as estimated frorri Figure 8 of the vapor intrusion users guide (USEPA 2004)

bull The soil type used to estimate vapor permeability is assumed to be sandy loam (SL) The

associated soil properties for a sandy loam soil type are as follows the soil dry bulk density (Pb) is

162 gcm the total porosity (n) is 0387 (cm^-aircm^) and the water-filled porosity (nw) is 0103

(cm -HzOcm )

bull The floor thickness (Lcrack) is set to the USEPA (2004) default value of 10 cm

bull The soil-building pressure differential (AP) is set to the USEPA (2004) default value of 40 gcm-s^

bull The building dimensions are siterspecific based on the existing plant building located at the site

The existing structure is approximately 84000 square feet (Dolphin 2000) therefore the

dimensions are set to 8839 cm (290 feet) length by 8839 cm (290 feet) The USEPA (2004)

default value of 244 cm vyas used for the height

bull Thefloor-wall seam crack width (w) is set to the USEPA (2004)-default value of 01 cm

bull The indoor air exchange rate (ER) is set to 083hour This is the value provided by ASTM (2002)

for commercial and industrial buildings

AR100306

Tables B-1-B through B-6-B present the constituent-specific properties for COC that were used in the TF

calculations Tables B-1-C through B-6-C present the intermediate calculations used to determine the

indoor air attenuation coefficients (ie the transport factors) The shaded boxes in Tables B-1-C through

B-6-C also present the resulting TF values that are applied to the concentrations of COC in subslab

vapor and the estimated indoor air concentrations

References

American Society for Testing and Materials (ASTM 2002) Standard Guide for Risk-Based Corrective Action Applied at Petroleum Release Sites ASTM E-1739-95 (Reapproved 2002)

Johnson PC and RA Ettinger (1991) Heuristic model for predicting the intrusion r-ate of contaminant vapors into buildings Environ Sci Technolpgy 25 1445-1452

Dolphin Environmental LLC (Dolphin 2000) Site Characterization Report Mach 14 2000

United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004

AR100307

APPENDIX B-1-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV Nersion31 0204

Reset to Defaults

ENTER -

Chemical CAS No

(numbers only

no dasties)

95636

ENTER Soil gas

cone

Cg (ngm)

Soil Gas Concentration Data ENTER

Soil gas

OR cone

bull - c bull (PPmv)

197E+02

Chemical

124-Trimethylbenzene

MORE ENTER Depth

below grade to bottom

of enclosed space floor

U bull (cm)

ENTER

Soil gas sampling

depth below grade

U (cm) bull

ENTER

Average soil

temperature Ts

CO

1 15 1 1 5 bull125

ENTER ENTER ENTER Totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hft ha he

(cm) (cm) (cm)

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estirnate OR permeability | soil vapor

permeability) k v bull

(cm)

SL 1 1

MORE ENTER

stratum A SCS

soil type

Lookup Soil Parameters

ENTER stratum A soil dry

bulk density P

(gcm)

ENTER Stratum A soil total porosity

(unitless)

ENTER bull stratum A soil water-filled

porosity

(cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

nlaquo

(unitless)

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gchi-s^)

ENTER Enclosed

space floor

length bull LB

(cm)

ENTER Enclosed

space floor

width WB

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

bull Floor-wall seam crack

width w

(cm)

bullENTER

Indoor air exchange

rate ER

(1h) bull

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bidg OR

Leave blank to caicuij

(Lm)

Appx B-1 124-TMBxls 1 of 3 982009

AR100308

APPENDIX B-1-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of ^ bull law constant law constant vaporization at Normal

Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temperature boiling point point temperature weight

D bull Dbdquo H T R bull AHbdquo TB Tc IVIW

Unit risk Reference

factor cone URF RfC

(cms) (cmls) (atm-mmol) CO (calmol) (degK) (degK) (gmol) bull (ugm)- (mgm)

1 606E-02 1 792E-06 1 bull 614E-C3 1 25 1 9369 1 44230 | 64917 1 12020 1 OOE+00 1 60E-03 1

Appx B-1 124-TMBxls 2 of 3 982009

AR100309

APPENDIX B-1-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

(sec)

Source-building

separation

LT bull

(cm) bull

Stratum A soil

air-filled porosity

Q A

Stratum B soil

air-filled porosity

(cmcm) (cmcm)

Stratum C soil air-filled porosity

(cmcm)

Stratum A effective total fluid

saturation

Se

(cmcm)

Stratum A soil

bullintrinsic permeability

^ (cm)

stratum A Stratum A Floor- soil soli wall BIdg

relative air effective vapor seam Soil bull ventilation permeability permeability perimeter gas rate-

kfg ky Xgrack c o n e - QbuHdinpound

(cm) - (cm) (cm) (ngm) (cms)

946E+08 1 0284 0284 0284 0184 596E-09 0901 537E-09 35357 I 197E+02 | 439E+06 |

Area of enclosed

space below grade

As (cm)

Crack-to-total area ratio

1 bull

(unitless)

Crack depth

below grade

Zcfack

(cm)

Enthalpy of vaporization at

ave soil temperature

AHvjs

(calmol) bull

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law constant at

ave soil bull temperature

bull HTS

(unitless)

Vapor bull viscosity at

ave soil temperature

HTS

(gcm-s)

Stratum A

effective diffusion

coefficient

D (cms)

Stratum-B

effective diffusion coefficient

DB (cms)

Stratum C effective diffusion

coefficient

D-c (cms)

Total - overall effective diffusion

coefficient

D ^ (cms)

Diffusion path

length

L-

(cm)

I 787E+07 I 449E-05 | 15 | 11661 260E-03 111E-01 176E-04 I 612E-03 j OOOE+00 | OOOE+00 | 612E-03 j

bull Convection path

length

Lp

(cm)

Source vapor cone

^source

(ngm)

Crack radius

Tcfack

(cm)

Average vapor

flow rate into bIdg

Qsoii

(cms)

Crack effective diffusion

coefficient pcrack

(cms)

Area of CTack

Acack

(cm)

Exponent of equivalent foundation

Peclet number

exp(Pe)

(unitless)

bull bull - bull bull bull bull

1 15 1 197E+02 1 010 1 474E+01 612E-03 bull 354E-t-03 1 336E+09

Infinite source Indoor

~ attenuation coefficient

a

(unitless)

108E-05

Infinite source

btJbldgjJSv-L ^Ppncji3i-

virhpbiiilding bullbull ^lHltti^m)ilg

213E-03

Unit risk

factor

URF

(ngm)-

Reference cone

RfC (mgm)

NA 60E-03 1

I END

Appx B-1 124-TMBxls 3 of 3 982009

AR100310

APPENDIX B-2-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV Nersion31 020^

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

156592

Soil Gas Concentration Data ENTER

Soil gas

cone OR c

(ngm) bull

ENTER Soil bull-gas

cone

c (ppmv)

603E+03 1

Chemical

cis-12-Dichloroethylene

MORE ENTER Depth

below grade to bottom

of enclosed space floor

LF

(cm)

ENTER

Soil gas sampling

depth below grade

U (cm)

ENTER

Average soil

temperature bull Ts

(degC)

1 15 1 bull 15 125

ENTER ENTER ENTER Totalsmust add ijp tb value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hA hB he

bull (cm) (cm) (cm)

15 1 1

ENTER Soil

straturh A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estimate OR permeability | soil vapor

permeability) kv

(cm)

SL 1 |

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

P (gcm)

ENTER Stratum A soil total porosity

bull n

(unitless)

ENTER Stratum A

soil water-filled porosity

(cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

ENTER Stratum B

soil water-filled porosity

ENTER Stratum C

SCS soil type

(unitless) (cmcm)

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure differential

AP

(gcm-s)

ENTER Enclosed bull

space floor

length

LB (cm)

ENTER Enclosed

space floor

width WB

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER

Average vapor flow rate into bIdg

OR Leave blank to calculi

Qsoil

(Lm)

Appx B-2 cis-12-DCExls 1 of 3 982009

AR100311

APPENDIX B-2-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Diffusivity in air

Da

(cms)

Diffusivity in water

Dw (cms)

Henrys law constant at reference temperature

H

(atm-mmoi)

Henrys law constant

reference temperature

bull T R

CC)

Enthalpy of vaporization at

the normal boiling point

AHbdquob

(calmol)

Normal boiling point

TB

(degK)

Critical temperature

Tc (degK)

Molecular weight

MW

(gmol)

Unit risk

factor URF

(ngm)

Reference cone

RfC (mgm)

1 736E-02 1 113E-05 1 407E-03 j 1 25 1 bull 7192 1 33365 1 54400 1 9694 1 OOE+00 j 35E-02 1

Appx B-2 cis-12-DCExls 2 of 3 982009

AR100312

APPENDIX B-2-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

stratum A Stratum B Stratum C Source- soil soil soil

Exposure building air-filled air-filled air-filled

duration separation porosity porosity porosity

T LT ea e^ bull e= (sec) (cm) (cmcm) (cmcm) (cmcm)

I 946E+08n^

Stratum A Stratum A Stratum A Stratum A Floor-effective soil soil soil wall total fluid intrinsic relative air effective vapor seam

saturation permeability permeability permeability perimeter

Ste kj krg ky Acrack

(cmcm) (cm) (cm) (cm) (cm)

Soil gas

cone (ngm)

I 0284 I 0284~ 0284 0184 I 596E-09 | 090T 537E-09 35357 603E+03

BIdg ventilation

rate

JbulldinE

(cms)

439E+06

Area of enclosed

space below grade

AB

(cm)

Crack-to-total

area ratio

n (unitless)

Crack depth below grade

Zltiack (cm)

Erithalpy of vaporization at

ave soil temperature

AHvTs (calmol)

Henryslaw constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law constant at

ave soil temperature

HTS

(unitless) bull

Vapor viscosity at

ave soil bull temperature

HTS

bull (gcm-s)

Stratum A

effective bull diffusion

coefficient

D^A-(cms)

Stratum B

effective bull diffusion

coefficient

D=B

(cms)

Stratum C

effective diffusion bull

coefficient

D=e (cms)

Total overall

effective diffusion

coefficient

DT

(cms)

Diffusion path

length

Ld

(cm)

I 787E+07 I bull449E-05 | 15 bull7709 230E-03 982E-02 176E-04 | 743E-03 | OOOE+00 | OOOE+00 | 743E-03 |

bull bull bull -

Convecfion path -bull

length

Lp (cm)

Source vapor cone

-source

(Mgm)

Crack radius

fcrack

(cm)

Average vapor

flow rate into bIdg

Qaoil bull

(cms)

Crack effective diffusion

coefficient pcack

(cms)

Area of crack

crack

(cm)-

Exponent of equivalent foundation

Peclet number

exp(Pef)

(unitless)

bull

1 15 -1 603E+03 1 010 1 474E+01 743E-03 354E+03 1 697E+07

Infinite source Indoor

attenuation coefficient

poundbullbullbull C t

pound(unitless)

bullsiilaquogt j ii08E-05

Infinite [ source

bIdg cone

Cbujidjng

(pgm)

651 E-02 iKrt

Unit risk

factor

URF

(ngm)-

Reference cone

RfC

(mgm)

NA 35E-02 1

I END I

Appx B-2 cis-12-DCExls 3o f3 982009

AR100313

APPENDIX B-3-A DATA ENTRY SHEET

Coyne Texti le Services - Hunt ington West Virginia

SG-ADV Version 31 0204

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

67663

Soil Gas Concentration Data ENTER ENTER

Soil Soil gas gas

cone OR cone c C

(^gm) (ppmv)

591 E+03

bull

Chemical

Chloroform

MORE ENTER Depth

below grade tb bottom

of enclosed space floor

bull LF

(cm)

ENTER

Soil gas sampling depth

below grade

(cm)

ENTER

Average soil

temperature-Ts

CO bull

1 15 1 15 1 125

ENTER ENTER ENTER Totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

IIA hs he (cm) (cm) (cm)

1 5 bull 1 1

ENTER ENTER Soil - bull

stratum A User-defined SCS stratum A

soil type bull soil vapor (used to estimate OR permeability

soil vapor k

bull permeability) (cm) 1

SL 1 1 bull

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A soil dry

bulk density

Pb (gcm)

ENTER Stratum A soil total porosity

nV (unitless)

ENTER Stratum A

-soilwater-filled bullporosity

Sraquo (cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

(unitless)

ENTER Stratum B

soil water-filled porosity

bull ebdquo=

(cmcm) bull

ENTER Straturri C

SCS bull soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

- c rack

(cm)

ENTER

Soil-bldg pressure

differential AP^

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor

width bull W B

(cm)

ENTER

Enclosed space

height HB

(cm)

ENTER

bull Floor-wall^ seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bidg OR

Leave blank to calculi

Qsoil bull

(Lm)

I -I

Appx B-3 Chloroformxls 1 of 3 982009

AR100314

APPENDIX B-3-B CHEMICALPROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Diffusivity in air

D (cms)

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffijsivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature

Dbdquo H TR A H bdquo TB Tc

(cm s) (atm-m mol) ro (calmol) (degK) (degK)

Molecular weight

MW

(gmol)

Unit risk

factor URF

(ngm)-

Reference cone

RfC

(mgm)

104E-01 100E-05 I 366E-03 25 6988 33432 53640 11938 I 23E-05 | OOE+00

Appx B-3 Chloroformxls 2 of 3 982009

AR100315

APPENDIX B-3-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure

duration

(sec)

Source-

building

separation

LT

(cm)

Stratum A

soil

air-filled

porosity

Sa

( cm cm )

Stratum B

soil

air-filled

porosity

( cm cm )

Stratum C

soil

air-filled

porosity

( c m c m )

Stratum A

effective

total fluid

saturation

( c m c m )

Stratum A

soil

intrinsic

penmeability

k

(cm )

Stratum A

- soil

relative air

permeabil i ty

(cm )

Stratum A

soil

effective vapor

permeability

kv

(cm )

Floor-

wall

seam

perimeter

gtcrack

(cm)

Soil gas

cone

(ngm)

BIdg

venfilation

rate

^buildlriE

(cms)

I 9 4 6 E + 0 8 ~ T I 0284 T 596E-09 I 0-901 I 537E-09 | 35357 | 591 E+03 j 439E+06 | 1 0 284 0284 0184

Area of

enclosed

space

below

grade

A B

( c m )

Crack-

to-total

area

ratio

n

(unitless)

Crack

depth

bull below

grade

^crack

(cm)

Enthalpy of

vaporization at

ave soil

temperature

AHTs bull

(calmol)

Henry s law

constant at

ave soil

temperature

HTS

(a tm-m mol j

Henrys law

constant at

ave soil

bull temperature

HTS

(unitless) bull

Vapor

viscosity at

ave soil-

temperature

^HTS

(gcm-s)

Stratum

A

effective

diffusion

coefficient

(cm s)

Stratum

B

effective

difftjsion

coefficient

D B

(cms) bull

S t ra tum

C

effective

diffusion

coefficient

Dc

(cm s)

Total

overall

effective

bull diffusion

coefficient

D T

(cm s)

Diffi jsion

path

length

Ld

(cm)

I 787E+07 I 449E-05 j - bull 15 7528 210E-03 896E-02 176E-04 I 105E-02 | OOOE+00 | OOOE+00 | 105E-02

Convection

path length

Lp

(cm)

Source

vapor

cone -

^source

- (ngm)

Crack

radius

Tcrack

(cm)

Average

vapor

flow rate

into bidg

Qsoil

(cms)

Crack

effective

diffusion

coefficient Qcrack

bull (cms)

Area of crack

Acrack

(cm)

Exponent of

equivalent

foundation

Peclet number

exp(Pe)

(unitless)

V bull bull

1 15 1 591 E+03 1 010 1 474E+01 105E-02 354E+03 1 355E+05

Infinite

source

indoor

attenuation

coefficient

d

(unitless)

bull 108E-05

Infinite

source

bIdg

cone

^ b u i l d i n g

i (^gm)

bull bull

i 638E-02 -

Unit

risk bull factor

URF

(ngmY

Reference

cone

RfC

(mgm)

~ 23E-05 NA 1

I END

Appx B-3 Chloroform xls 3 of 3 982009

AR100316

APPENDIX B-4-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ersion 31-020^

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

nodashes)

bull 75092

ENTER Soil gas

cone

c (ngm)

Soil Gas Concentration Data ENTER

Soil gas bull

OR cone

bull C

(ppmv)

152E+03

bull bull

Chemical

Methylene chloride

MORE

MORE 4gt

ENTER Depth

below grade to bottom

of enclosed space floor

LF -

(cm)

ENTER

Soil gas sampling depth

below grade

bull U

(cm)

ENTER

Average soil

temperature

Ts bull CC)

bull bull bull bull

1 15 1 15 125

ENTER Totals

Thickness of soil

stratum A h

(cm)

ENTER ENTER must add up to value of Ls (cell F24

Thickness Thickness of soil of soil

stratum B stratum C (Enter value or 0) (Enter value or 0)

he he bull

(cm) bull (cm) -

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(usedto estimate OR perrrieability | soil vapor

permeability)

k bull

(cm)

SL 1 bull 1

ENTER Stratum A

SCS soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

Pb (gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Stratum A

soil water-filled porosity

9w (cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

Pb^

(gcm)

ENTER Stratum B soil total porosity

n^

(unitless)

ENTER Stratum B

soil water-filled porosity

(crhcm)

ENTER Stratum C

SCS soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE 4gt

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

bull Soil-bldg pressure

differential AP^

(gcm-s)

ENTER Enclosed

space floor

length LB

(cm)

ENTER Enclosed

space floor

width bull W B

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width

w

(cm)

ENTER

Indoor air exchange

rate

ER (1h)

ENTER Average vapor

flow rate into bidg OR

Leave blank to calculc

Qsoil

(Lm)

10 40 8839 8839 244 01 083

Appx B-4 MCxIs 1 of 3 982009

AR100317

Diffijsivity in air

D

APPENDIX B-4-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffusivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature

Pw H TR AHt TB TC

Molecular weight

MW

Unit risk

factor URF

Reference cone

RfC

(cms) (cms) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) bull (ngm)- (mgm)

bull bull

1 101E-01 1 117E-05 1 218E-03 1 25 | 6706 1 31300 1 51000 1 8493 1 47E-07 1 30E+00 1

Appx B-4 MCxIs 2 of 3 982009

AR100318

APPENDIX B-4-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

T

(sec)

Source- -building

separation

LT

(cm)

Stratum A soil

air-filled porosity

e a bull

(cmcm)

Stratum B soil

bullair-filled porosity bull

ea^ (cmcm)

Stratum C soil

air-filled porosity

ea= (cmcmj

Stratum A effective total fluid

saturation

Sc bull

(cmcm)

Stratum A soil

intrinsic pemneability

ki (cm)

Stratum A soil

relative air permeability

^ ^ g

(cm)

stratumA bull soil effective vapor permeability

K (cm)

Floor-wall

seam perimeter

Xcrack

(cm)

Soil gas

cone (ngm)

BIdg ventilation

rate

Qbuildinc

(cms)

1 946E+08

Area of -enclosed

space below

bull grade

AB

(cm)

1

Crack-to-total

area rafio

Tl

(unitless)

0284 1

Crack depth below grade

Zcrack

(cm)

0284 1

bull Enthalpy of vaporization at

ave soil temperature

AHTs (calmol)

0284

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

0184

Henrys law constant at ave soil

temperature

HTS

bull (unitless)

1 596E-09

Vapor viscosity at

ave soil temperature

Mrs (gcm-s)

0901

Stratum A

effective diffusion

coefficient

D (cms)

537E-09

Stratum B

effective diffusion

coefficient

D-B (cms)

35357 1

Stratum C -

effective diffusion

coefficient

D-c ^ (cms)

152E+03

Total bull overall

bull effective diffusion

coefficient

D ^

(cms)

440E+06 1

Difftjsion path

length

Ld (cm)

1 787E+07

Convection path

length

Lp (cm)

4 49E-05

Source vapor cone

Csource

(ngm)

15 1

Crack radius

Tcrack

(cm)

7007 bull 1

Average vapor

flow rate intobldg

Qsoil

(cms)

130E-03

Crack effective diffusion

coefficient pcrack

(cms)-

555E-02

bull ^

Area of crack

Acrack

(cm) bull

1 176E-04

Exponent of equivalent foundation

Peclet number

exp(Pe)

(unitless) bull

bull bull

1 15

1 END

152E+03 010 1 474E+01 1 102E-02 354E+03 1 519E+05

102E-02

Infinite source

indoor ^attenuation coefficient

bull a

(unitless)

aiii08E-05

0 OOE+00

bull

Infinite bull source

bIdg ^ cone

^bu i l d i ng

(MQm)

164E-02

OOOE+00 1

Unit risk

factor

URF

(ngm)-

47E-07 1

102E-02 j

Reference cone

RfC

(mgm)

30E+00 j

1 1

Appx B-4 MCxIs 3 of 3 982009

AR100319

APPENDIX B-5-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ^erslon 31 0204

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

127184

Soil Gas Concentration Data ENTER ^ ENTER

Soil -Soi l bull gas gas

cone OR cone Cg C bull

(tgm) (ppmv)

149E+05 1

Chemical

bull Tetrachlbroethylene

MORE 4

ENTER Depth

below grade to bottom

ofenclosecJ space floor

LF

(cm)

ENTER

Soil gas bull sampling

depth below grade

u bull (cm)

ENTER

Average bullsoil

temperature - Ts

ro 1 1 5 1 15 1 125 bull

ENTER ENTER ENTER totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hft bull he bull he

(cm) (cm) (cm)

bull 1 5 1 - 1

ENTER ENTER Soil

stratum A User^defined bull SCS bull stratum A soil type soil vapor

(used to estimate OR perrrieability soil vapor K bull

permeability) (cm) 1

SL 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

Pb

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Sitratum A

soil water-filled bull porosity

(cmcm)

ENTER Stratum B

SCS soiltype

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

Pb^

(gcm)

ENTER Stratum B soil total porosity

Ajnitless^

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS soil type

LookupSoil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

VS

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor width

W B

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width

w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

ENTER Average vapor

flow rate into bidg OR

Leave blank to calcul

bull Qsoil

(Lm)

10 40 8839 8839 244 01 083

Appx B-5 PCExIS 1 of 3 982009

AR100320

APPENDIX B-5-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal Unit

Diffusivity Diffusivity at reference reference the riormal boiling Critical Molecular risk Reference in air in water temperature temperature boiling point point teriiperature weight factor cone

Da Dbdquo H TR AHb TB Tc MW URF RfC

(cms) (cnis) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) (^gm)- (mgm)

1 720E-02 1 820E-06 1 184E-02 1 25 1 8288 1 39440 1 62020 1 16583 1 59E-06 1 60E-01 1

J

AppxB-5PCExls 2 of 3 - 982009

AR100321

APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

T

(sec)

Source-building

separation

LT

bull (cm)

Stratum A soil

air-filled porosity

Oa (cmcm)

Stratum B - soil air-filled porosity

ea (cmcm)

Stratum C soil

air-filled porosity

ea= - (cmcm)

Stratum A effective total fluid

saturation

sbdquo (cmcm)

Stratum A soil

intrinsic permeability

ki (cm)

Stratum A soil

relative air permeability

- ^ g

(cm)

Stratum A soil

effective vapor permeability

kv (cm)

Floor-wall

seam perimeter

^crack

(cm)

Soil gas

cone

(ngm)

BIdg venfilation

rate

Qbuildins

bull (cms)

bull bull

1 946E+08

Area of enclosed

space below grade

AB

(cm)

1

bullCrack-to-total

area ratio

1 (unitless)

0284 1

Crack bull depth below grade

Zcrack

(cm) -

0284 1

Enthalpy of vaporization at bull

ave soil temperature

bull A H V TS

(calmol)

0284

Henrys law constant at

ave soil temperature

HTS (atm-mmol)

0184

-Henrys law constant at

ave soil temperature

HTS

(unitless)

1 596E-09

Vapor viscosity at

ave soil temperature

HTS

(gcm-s)

0901

Stratum A

effective diffusion

coefficient bull D = bull

(cms)

537E-09

Stratum B

effective diffusion

coefficient

D--B (cms)

35357 1

Stratum C

effective diffusion bull

coefficient

D-c (crris)

149E+05

Total overall

effective bulldiffusion coefficient

DT

(cms)

440E+06 1

Difftjsion path

length

U (cm)

1 787E+07

Convection path

length

bull Lp

(cm)

4 49E-05

Source vapor cone

^source

(ngm)

15 1

Crack radius

Tcrack

(cm)

9528 1

Average vapor

flow rate intobldg

Qsoil (cms)

908E-03

Crack effective diffusion

coefficient pcrack

bull ( c m s ) bull

387E-01

Area of crack

Abdquoack (cm)

1 176E-04

Exponent of equivalent foundafion

Peclet number

exp(Pe)

(unitless)

bull

1 15-

1 END

149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08

727E-03

Infinite source indoor

attenuation coefficient

a

(unitless)

108E-05

OOOE+00

Infinite source

bIdg cone

Cburldtng

(Mgm)

161 E+00

OOOE+00 1

Unit risk

factor

URF

(ugm)-

59E-06 1

727E-03

Reference cone

RfC (mgm)

60E-01

1 1

Appx B-5 PCExls 3 of 3 982009

AR100322

APPENDIX B-6-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ersion31 0204

Reset to Defaults

t

Soil Gas Concentration Data ENTER

Chemical CAS No

(numbers only

no dashes)

79016

ENTER ENTER Soil Soil gas gas

cone OR cone C C -

bull (ngm) (ppmv)

782E+03

Chemical

Trichloroethylene

MORE ENTER Depth

below grade to bottom-

of enclosed space floor

LF

(cm)

ENTER

Soil gas sarnpling

depth below grade

U (cm)

ENTER

Average soil

temperature Ts

(degC)

1 15 1 15 t 125

ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e

(cm) (cm) (cm)

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estimate OR permeability soil vapor

permeability)

k (cm)

bull S L 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil bull-Parameters

ENTER Stratum A

soil dry bulk density

P b -

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Stratum A bull

soilwaterrfilled porosity

(cmcm) bull

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

bull P ^ (gcm)

ENTER Stratum B soil total

porosity

nlaquo

(unitless) -

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS bull soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor

width W B

(cm)

ENTER

Enclosed space height

H B bull

( c m ) bull

ENTER

Floor-wall seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bIdg OR

Leave blank to calculc

Qsoil

(Lm) -

Appx B-6 TCExIs 1 of 3 982009

A

AR100323

APPENDIX B-6-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight

Da Dbdquo H TR AH^b TB TC MW

Unit risk Reference

factor cone URF RfC

(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)

1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1

Appx B-6 TCExIs 2 of 3 982009

AR100324

APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

(sec)

Source-building

separation LT

(cm)

Stratum A soil

air-filled porosity

bull ea (cmcm)

Stratum B Soil

air-fllled porosity

e^ bull (cmcm)

Stratum C soil

air-filled porosity

(cmcm)

StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air

saturation permeability permeability

S|e k krg (cmcm) (cm) (cm)

Stratum A Floor-soil wall BIdg

effective vapor seam Soil ventilafion permeability perimeter gas rate

k^ bull Xack c o n e Qbuildins

(cm) (cm) (ngm) (cms)

946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |

Area of enclosed

space below grade

AB

(cm)

Ciack- to-total

area ratio

1 (unitless)

Crack depth below grade

Zcrack

(cm)

Enthalpy of vaporization at

ave soil temperature

A H J S

(calmol)

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law bull constant at

ave soil temperature

HTS

(unitless)

Vapor viscosity at

ave soil temperature

|JTS

(gcm^s)

Stratum A

effective diffusion

coefficient

(cms)

Stratum B

effective -diffusion

coefficient

D=B (cms)

Stratum ^ C effective diffusion

coefficient

D=c (cms)

Total overall

effective diffusion

coefficient

DT

(cms)

I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03

Diffusion path

length

Li (cm) bull

Convection bull path

length

Lp

(cm)

Source vapor cone bull

^source

(ngm)

Crack radius

rcrack

(cm)

Average vapor

- flow rate intobldg

Qsoil

(cms)

Crack effective diffusion

bull coefficient Qcrack

(cms)

Area of crack

^crack

(cm)

Exponent of equivalent foundation

Peclet bull number

exp(Pe)

(unitless)

bull bull

1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07

Infinite source Indoor

attenuation coefficient

a

(unitless)

108E-05

Infinite source

bIdg concgt

^building

(ngm)

844E-02

Unit risk

factor

URF

(ngm)-

Reference cone

RfC

(mgm)

1 1E-04 1 40E-02 1

END

Appx B-6 TCExIs 3 of 3 982009

AR100325

Office of Waste Management 1356 Hansford Street

Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256

West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director

ORDER

ISSUED UNDER THE

HAZARDOUS WASTE MANAGEMENT ACT

CHAPTER 22 ARTICLE 18

OF THE WEST VIRGINIA CODE^ AS AMENDED

y Order Number HW-011-80

To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704

ATTEMTION MREDARMON

Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull

AR100326

ViWJ011-laquo9 PageNunil)er2

BASIS FOR ORDER

As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following

A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^

B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator

C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities

0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94

^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement

P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following

1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater

2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was

^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment

CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable

CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order

AR100327

H W - 0 1 1 - 9 9 Page Number 3

REQUIREMENTS OF ORDER

Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows

1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^

2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore

remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling

GENERAL PROVaiONS

1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order

2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order

3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order

Effective Date

Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief

Wt T 1 V Oflice of Waste Management

AR100328

^ ^ S I S

^wmmmmamn

AR100329

Page 7: SDMS DocID 2121999 · International Enterprises Corp. building (Coyne Building), which is located at 1111 Vernon Street, Westmoreland District, Wayne County, West Virginia. The following

(9

00 S

P B B K ftVENIjEl

WEST MORELAND PARK

TENNIS BASKETBALL COURTS

GP-5 GP-4

9-inn i in iMMIMII I IMMII I I I I I I I IMI I I I I I IMI I I IMMII I I I I I I I I IMMII I I I I I IMI I I I I I I I I I I I IMI I I I I I I I I I I IMMII I I IMIMIMII I I I I I I I I I IMI I I I I I I I IMI I I I

CSX RAILROAD GP-2 GP-1 GP-3 I I I I I I I IMI I I IMMI I IMI I I I I I IMIMI I I IMI I I I I I I I I in i l lMI IMIMI I I I I IMMI I I I I I Jd I I IMj r i i y i l lMMI I I IMI I I I I I I I I in i l l l l l l lM l l l l l l l i n i l l l l l l l l ijj^lll^flH|t

bull

ACCESS ROAD

BUILDING

- bull

G P X ^

MM ^

MW

4-

bull ^

LEGEND

CW SAMPLE LOCAT10

MONITORING WELL

gtl

n

PARK ING

SCALE 1 r bull

WCEDA VRP GROUNDWATER SAMPLINGS HUNTINGTON WEST VIRGINIA

F I G U R E tslD

Cad Files04-08-p408-1dgn 6122009 24625 PM

- AR100284

Wayne County Economic Development Authority Page 3 Groundwater Assessment Coyne Textile Services Building Westmoreland District Wayne County West Virginia October 24 2008 _ bull ^

We appreciate the opportijnity to assist you with this project If you have any questions or r

need additional information please feel free to contact us

Sincerely TRIAD ENGINEERING INC

Matthew C Wright

Project Geologist

JohnM Meeks PG LRS

Project Manager

end

^

AR100285

Table 1 Laboratory Analytical Summary - Groundvvater WCEDA Vernon street

Huntington Wayne County West Virginia

COPC

Acetone Benzene Bromobenzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone sec-Butylbenzene n-Butyibenzene tert-Butylbenzene Carbon disulfide Carbon Tetrachloride Chlorobenzene Chlorodibromorriethane Ghloroethane Chlbroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene 12-Dibromo-3-chloropropane 12-Dlbronnoethane (EDB) DIbromomethane 14-Dichlorobenzene 13-Dictilorobenzene 12-Dictilorobenzene Dichlorodifluoromethane 11-Dlchloroethane 12-Dichloroethane cis-12-Dichloroethene

MCL ugL

5500 5

NV NV NV 85 87

700 61 61 61

1000 5

100 NV 39

bull 017 190 NV NV 02

005 NV

750 600 600 390 910

5 70

GP-1 ugL ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND

ND ND ND ND ND ND ND ND ND ND ND ND 112 ND

5210

GP-2 ugL ND ND ND

ND ND ND ND ND ND ND ND ND ND ND ND ND ND

062 J ND ND ND

ND ND ND ND ND ND ND ND

379

GP-3 ^ ugL

ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND

065 J ND 184 ND( ND ND ND

ND ND ND ND ND ND ND

12500

GP-4 ugL ND ND ND ND ND

- ND ND ND ND ND ND ND ND ND ND ND ND ND

ND ND ND ND ND ND ND ND ND ND ND 132

GP-5 ugL ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND

ND ND ND ND ND ND ND ND ND ND ND ND 59

Notes - Bold Indicates COPCs detected at concentrations greater than the MCL bull(60CSR3 Table 60-3B July 2008)

NAME - J indicates analyte detected at levels less than the reporting limit and greater than

or equal to the MDL value is estimated -NV indicates no value has been established

AR100286

Table 1 Laboratory Analytical Summary - Groundwater (Continued) WCEDA Vernon street

Huntington Wayiie County West Virginia

COPC

11-Dichloroethene trans-12-Dichloroethene 13-Dichloropropane 12-Dichloropropane 22-Dichloropropane cis-13-Dichloropropene trans-13rDichloropropene 11-Dichloropropene Ethylbenzene Hexachlorobutadiene 2-Hexanone Isopropylbenzene p-lsopropyltoluene Methyl tert-Butyl Ether Methylene Chloride 4-Methyl-2-pentanone Naphthalene n-Propylbenzene Styrene 1112-Tetrachloroethane 1122-Tetrachloroethane Tetrachloroethene Toluene 123-Trichlorobenzene 124-Trichlorobenzene 112-Trichloroethane 111-Trlchloroethane Triehloroethene Trichlorofluoromethane 123-Trichloropropane 135-Trimethylbenzene 124-Trimethylbenzene Vinyl chloride Xylenes total s

MCL ugL

91 100 04

5 NV NV NV NV

700 086

NV NV

NV 028

5 NV 62 NV 100

043 0055

5 1000

NV 70

5 20

5 1300

0034 120 120

2 10000

GP-1 ugL 964 458 ND ND

ND ND ND ND

052 J ND ND ND ND ND ND ND ND ND ND ND ND

14700 065 J ND ND ND ND

2850 ND

ND ND ND 116 146 J

GP-2 ugL ND ND ND ND ND ND ND- ND ND ND ND ND -ND ND ND ND ND ND ND ND ND

603 ND ND ND ND ND

079 J ND ND ND ND 242 ND

GP-3 ugL 346 865 ND ND

bull ND ND ND-ND

055 J ND ND ND ND ND ND ND ND ND ND ND ND

13900 159 ND ND ND ND

4870 ND ND ND ND 708 149 J

GP-4 ugL ND ND ND ND ND ND ND ND ND ND ND

ND 177 ND ND ND ND ND ND ND ND

583 ND ND ND ND ND

082 J ND ND ND ND

227 ND bull

GP-5 ugL ND ND ND ND ND

ND ND ND ND ND ND ND ND

ND ND ND ND ND ND ND ND 133 ND ND ND ND ND

574 ND ND

ND ND 122 ND

Notes - Bold indicates COPCs detected at concentrations greater than the MCL

(60CSR3 Table 60-3B July 2008) - ND indicates non-detected at concentrations greater than the MCL - J indicates analyte detected at levels less than the reporting limit and greater than

or equal to the MDL value is estimated - NV indicates no value has been established

AR100287

Risk-Based Rerfiedies

R B R Consulting Inc 650 Shady Drive Beaver Falls PA 15010

Phone724-846-4096 Fax 724-846-6974

MEMORANDUM

TO John Meeks Triad Engineering Inc

FROM Bruce Fishman

DATE September 82009

SUBJECT Evaluation of Potential Risks Associated with Vapor Intrijsion to Indoor Air Coyne Textile Services Facility - Huntington West Virginia

bull V bull bull bull

This memorandum presents a risk evaluation for potential risks associated with vapor intrusion to indoor air at the Coyne Textile Services Facility located in Huntington West Virginia (site) This evaluation was conducted according to West Virginia Department of Environmental Protection (WVDEP) and United States Environmental Protection Agency (USEPA) methodologies

DATA INCLUDED 1N THE EVALUATION

This evaluation includes three subslab vapor samples (VP-01 VP-02 and VP-03) collected from immediately beneath the floor of the existing site building Table 1 lists the subslab vapor samples included in this risk assessment Samples were analyzed for volatile organic compounds (VOCs) by USEPA Method TO-15 Complete analytical data for these samples are provided in Table A-1 of Appendix A

The analytical results of the subslab vapor samples were compared to the target shallow soil gas comparison values presented in Table 2c of the USEPA vapor intrusion guidance document (2002a) These companson values are generic soil gas screening values that are protective of indoor air for residential land uses and represent concentrations in-sliallow soil gas based on a target risk level of 1 x 10reg andor a hazard index of 1 The comparison is presented in Table 2

As indicated in Table 2 the following constituents are identified as contaminants of concern (COC) for the vapor intrusion to indoor air pathway 124-trimethylbenzene 12-dichloroethene (cis) chloroform methylene chloride tetrachloroethene and triehloroethene

ESTIMATION OF INDOOR AIR CONCENTRATIONS

The concentrations of COC in indoor air associated with vapor intrusion from subslab vapor were estimated using methodologies outlined in the Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings (USEPA 2004) A transport factor (TF) is required that will relate the

Page 1 of 5 -

AR100288

Risk-Based Remedies

R B R Consulting Inc

constituent concentration in subslab vapor to the concentration in indoor air The TF is dependent on the diffusion coefficient and other properties that will affect the transfer of constituents into air such as distance from the source to tlie breathing zone soil properties and building properties A site-specific building size of 84000 square feet (Dolphin 2000) and a soil type of sandy loam were used in the calculation of TF The TF is determined using calculationsbased on the Johnson and Ettinger (1991) vapor intrusion model Details of the TF calculations are provided in Appendix B

Subslab vapor concentrations are converted to indoor air concentration by applying the TF as follows

Cja ^ Csubslab X I r

The TF for each COC along with the resulting concentrations of COC in indoor air are presented in Tables

EXPOSURE EVALUATION

Noncarcinogenic health effects are evaluated by calculating the average dose of a constituent over the course of the exposure period This dose is termed the Average Daily Dose (ADD) Potential carcinogenic health effects are evaluated in terms of an individuals theoretical increased risk of developing cancer over a lifetime Although the duration of exposure to a constituent release generally does not last for an entire lifetime constituent intake for carcinogens is estimated as the average dose over a human lifetime (70 years) This lifetime dose applies specifically to the evaluation of carcinogenic effects and is termed tine Lifetime Average Daily Dose (LADD) In a risk assessment the calculated ADD or LADD are estimated quantitatively using assurnptions about the duration frequency and magnitude of exposure experienced by each potential receptor and assumptions about the constituent properties that influence absorption

The quantitative estimation of constituent intake involves the incorporation of numerical assumptions for a variety of exposure parahneters Exposure assumptions used in these intake calculations are based on WVDEP (2001) or USEPA (1989 2002b) recommended values The factors and equation for inhalation of vplatiles is presented in Table 4 and described below

bull Inhalation Rate and Exposure Time WVDEP (2001) and USEPA (2002b) guidance recommend that an inhalation rate of 20 m day be used for workers For an exposure time of 8 hours (a typical workday) this results in an inhalation rate of 25 m hour

bull Exposure Frequency and Duration Default exposure factors for indoor workers are provided by WVDEP (2001) Exposure frequency for the worker is 5 days per week for 50 weeks a year or 250 days per year The exposure duration for these workers is 25 years which is the 95th percentile value ai cording to the Bureau of Labor Statistics (USEPA 1989)

bull Body Weight The default value for average body weight of an adult is 70 kg based on WVDEP (2001) and USEPA guidance (1989 2002b)

Page 2 of 5

AR100289

Risk-Based Remedies

R B R Consulting Inc

bull Averaging Time As described above the doses for noncarcinogenic health effects are averaged oyer the specific period of exposure for a given receptor Noncarcinogenic

averaging times are therefore calculated by multiplying the exposure duration for the receptor by 365 daysyear Carcinogenic health effects are calculated over a lifetime exposure so the value recommended by WVDEP (2001) and USEPA (2002b) for average lifetime 70 years was used for exposure duration The resulting carcinogenic averaging time is 25550 days

TOXICITY VALUES

Noncarcinogenic responses are evaluated numerically using parameters known as the hazard quotient (HQ) and hazard index (HI) the HQ is obtained by dividing the ADD for a constituent by the reference dose (RfD) Each dose calculation with a specific combination of constituent receptor and exposure pathway will have a distinct ADD and calculated HQ HQs associated with all constituents for a particular pathway are summed to yield the HI

In order to estimate the theoretical excess lifetime cancer risk the LADD of a constituent is multiplied by the cancer slope factor (CSF) For each pathway this calculation is carried out for each applicable constituent and the risks are summed to obtain the total potential risk due to that pathway

Toxicity values for each constituent are presented in Table 5 the toxicity values were obtained from the following sources

bull Integrated Risk Information System (IRIS) on-line database provided by USEPA (2009)

bull The USEPAs Provisional Peer-Reviewed Toxicity Values (PPRTV) as presented in the USEPA Regional Screening Tables (ORNL 2009)

bull Provisional value from the National Center for Environmental Assessnient (as per WVDEP)

bull The Agency for Toxic Substances and Disease Registrys (ATSDR) Minimal Risk Levels (MRLs ATSDR 2009) and

bull Value cited by USEPA Region 3 attributed to other sources (as per WVDEP)

RISK CHARACTERIZATION

Potential noncarcinogenic effects associated with exposure to COC at the site are estimated by comparing calculated intakes with the contaminant-specific RfDs The total HI was calculated by summing the individual HQs An HI value equal to or less than 1 indicates thatthelikelihopd of ah adverse noncancer effect would be negligible (USEPA 1989) An HI greater than 1 indicates that additional evaluation of the case is warranted

Theoretical excess lifetime cancer risks associated with exposure to COC from the site were calculated by comparing estimated intakes to constituent-specific CSFs Summed theoretical

Page 3 of 5

AR100290

Risk-Based Remedies

R B R Consulting Inc

excess risks are calculated by combining constituent-specific risks The results may be compared with target benchrharks for acceptable risk Various demarcations of acceptable risk have been established by regulatory agencies WDEP (2001) presents a target cancer risk of 1 x 10 for nonresidential scenarios USEPA (1991) considers potential cancer risks in the range of 1 x 10reg to 1 X 10 to be acceptable

Constituent-specific results for the indoor worker are presented in Table 6 For the indoor worker exposed to COC in indoor air (vapor intrusion from subslab vapor) the total HI is 00081 and the potential cumulative cancer risk is 497 X 10reg

These results meet both WVDEP and USEPA benchmarks indicating that the site poses negligible potential for human health risk for indoor workers

CONCLUSIONS

The results of this focused risk evaluation indicate that potential risks associated with vapor intrusion exposure of indoor workers to constituents that may volatilize from subslab vapor are within the acceptable benchmarks established by WVDEP and USEPA No further evaluation of the vapor intrusion pathway is warranted for the site

REFERENCES

Agency for Toxic Substances and Disease Registry (ATSDR 2009) Minimal Risk Levels (MRLs) Available at httpvtfwwatsdrcdcqovmrisindexhtml

Dolphin Environmental LLC (Dolphin 2000) Site Characterization Report Mach 14 2000

Johnson PC and RA Ettinger (1991) Heuristic model for predicting the intrusion rate of contaminant vapors into buildings Environ Sci Technology 25 1445-1452

Oak Ridge National Laboratory (ORNL 2009) Regional Screening Levels for Chemical Contaminants at Superfund Sites April 15 2009 Available online httpwwwepagovreg3hwmdriskhumanrb-concentration_tableindexhtm

United States Environmental Protection Agency (USEPA 1989) Risk Assessment Guidance for Superfund Volume I PartA Human Health Evaluation Manual EPA5401-89002

United States Environmental Protection Agency (USEPA 1991) Risk Assessment Guidance for Superfund Volume I Part B Development of Risk-Based Remediation Goals Office of Emergency and Remedial Response OSWER Directive 92857-018

United States Environmental Protection Agency (USEPA 2002a) Draft Guidance for Evaluating the Vapor Intrusion to Indoor Air Pathway from Groundwater and Soils Office of Solid Waste and Emergency Response Pub No 92856-10 December 2002

Page 4 of 5

AR100291

Risk-Based Remedies

R B R Consul t ing Inc

United States Environmental Protection Agency (USEPA 2002b) Supplemental Guidance for Calculating Soil Screening Levels for Superfund Sites Office of Solid Waste and Emergency Response December

United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004

United States Environmental Protection Agency (USEPA 2009) Integrated Risk Information System (IRIS) On-line database wwwepaqoviris

West Virginia Department of Environmental Protection (WVDEP 2001) West Virginia Voluntary Remediation and Redevelopment Act-Guidance Manual Version 21 March 13

Page 5 of 5

AR100292

TABLES

AR100293

TABLE 1 SUBSLAB VAPOR SAMPLES INCLUDED IN THE RISK ASSESSMENT

Coyne text i le Services Facility - Huntington West Virginia

Medium

Subslab Vapor

Sample Identification

bull VP-01

VP-02

VP-03

Sample Date

8132009

8132009

8132009

Coyne VIMemo Tables_09-08-09xls 982009

AR100294

TABLE 2 IDENTIFICATION OF CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR

Coyne Textile Services Facility - Huntington West Virginia

mdash

Const i tuent

Volati le Organics

111-Trichlor6ethane

1122-Tetrachloroethane

112-Trichloro-122-trifluoroethane

112-Trichloroethane

11-Dichloroethane

11-Dichloroethene

124-Trichlorobenzene

124-Trimethylbenzene

12-Dibromoethane

12-Dichlor6benzene

12-Dichloroethane

12-Dichloroethene (cis)

12-pichloroethene (trans)

12-Dichloropropane

12-Dichlorotetraf1uoroethane

135-Trimethylbenzene

13-Butadiene

13-Dichlorobenzene

13-Hexachlorobutadiene

14-Dichlorpbenzene

224-trimethylpentane

2-Chlorotoluene

4-Ethyltoluene

Acetone

Allyl Chloride

Benzene

Bromodichloromethane

Bromoform

Bromomethane

Carbon disulfide bull

Carbon tetrachloride

ChJorobenzene

Chloroethane

Frequency of Detection

0 3

0 3

0 3

bull 0 3

0 3

0 3

0 3

1 3

0 3 bull

0 3

b 3 bull

2 3

0 3

bull 0 3

0 3

0 3

0 3 bull

0 3

0 3

0 3

0 3

0 3

0 17

3 3

0 3

P 3

- 0 3

0 3

0 3

0 3

0 3

0 3

0 3

Min imum Detected

Concentrat ion

(ugm^)

ND

ND

ND

ND

ND

- ND

N D

197

ND bull

ND

ND

369

ND

bull~ ND

ND

ND

ND

ND

ND

bull ND

ND

ND

ND

796

ND

ND

ND-

ND

ND

ND

ND

ND

ND

Maximum

Detected Concentrat ion

(ugm3)

ND

ND

ND

ND

ND

ND

ND

197

ND

ND

ND

mdash 6030

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

1880

ND-

ND

ND

ND

ND

ND

ND

ND

ND

Sample wi th Maximum Detect

ND

ND

ND

ND

ND

ND

- ND

VP-03 -

ND

ND

ND

VP-03

ND

bullND

ND

ND

ND

ND

ND

ND

ND

ND

ND

VP-02

ND

ND bull

ND

ND

ND bull

bull ND

ND

ND

ND

Min imum Detection

Limit (ugm3)

22

28

31

22

16

16

30

20

31

24

16

bull 16

16

19

28

20

89

24 bull

43

24

bull 19

2 1

20

--^ 13

13

27

41

16

13

25

18

11

Maximum Detection

Limit (ugm3)

218

275

307

218

162

159

297

197

307

240

162

- 16

159

185

280

197

89

240

427

240

187

207

197

--125

128

268

414

155

125

252

184

106

Vapor Intrusion Corhparison

V a l u e

(ugm)

22000

042

300000

15

bull 5000

2000

2000

60

011

2000

094

350

700

40

NA

60

0087

1100

11

8000

NA

NA

NA

3500

NA

31

14

22

50

7000

16

bull 600

100000

Chemical of Concern

No

No

No

No

No

No

No

YES

No

No

No

YES

No

No

No

N o bull

bullNo

No

No

No

No

No

No

N o

No

No

No

N o

No

No

No

No

No

Comment

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent notdetected

fflaximCimTdeteetlSffieedsTcomDarisonivalues

Constituent not detected

Constituent not detected

Constituent not detected

Maximum detect exceeds comparison value

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Maximum detect below comparison value

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detectedl

Constituent not detected

Constituent not detected

CoyneVI Memo Tables_09-08-09xls 982009

AR100295

TABLE 2

IDENTIFICATION OF CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR

Coyne Textile Services Facility - Huntington West Virginia

Const i tuent

Volati le Organics

Chloroform -

Chloromethane

13-Dichloropropene (cis)

Cyclohexarie^

Dibrcimochloromethane

DichlonDdifluoromethane

Ethylbenzene

Methyl ethyl ketone

Methyl isobutyl ketone

Methyl tert-butyl ether

Methylene chloride

n-Heptane

n-Hexane

Styrene

Tert-butyl alcohol

Tetrachloroethene

Toluene

13-Dichloropropene(trans)

Triehloroethene

Trichlorofluoromethane

Vinyl bromide

Vinyl chloride

Xylene (0)

Xylenes (mampp)

Frequency of Detection

1 3

0 3

0 3

1 3

0 3

0 3

0 -3

1 3

0 3

0 3

2 3

0 3

3 3

0 3

0 3

3 3

1 3

- 0 3

3 3

P 3

0 3

0 3

1 3

1 3

Min imum Detected

Concentrat ion

(ugm)

5910

ND

ND

52

ND

ND

ND

23

ND

ND

1160

ND

1 4 4

ND

ND

11200

18

ND

91

ND

ND

ND

208

387

Maximuri i Detected

Concentrat ion (ugmS)

bull

5910

ND

ND

52

bull ND

ND

ND

23

ND

ND

1520

ND

183

ND

ND

149000

18

ND

7820

ND

bullND

ND

208

387

Sample vyith Max imum Detect

VP-02

ND

ND

VP-01

bull ND

ND

ND

VP-01

ND

ND

VP-02

ND

VP-02

ND

ND

VP-02

VP-01

ND

VP-03

ND

ND

ND

VP-03

VP-03

Min imum Detection

Limit (ugm3)

20

83

18

138

34

bull 20

17

118

16

14

14

16

- -17

12

--151

18

--23

18

10

1 7 bull

1 7 bull

Maximum Detection

Limit (ugm3)

195

83

182

138

341

198

174

118

164

144

14

164

170

121 -

--151

182

225

175

102

bull 174

174

Vapor Intrusion Compar ison

V a l u e

(ugm)

11

24

NA

2000

1

2000

22

10000

800

30000

52

NA

2000

10000

NA

81

4000

NA

022

7000

NA

28

70000

70000

Chemical o f Concern

YES

No

No

No

No bull

No

No bull

No bull=

No

No

YES

No

No

No

No

YES

No

No

YES

N o

No

No

No

No

Comment

Maximum detect exceeds comparison value

Constituent not detected

Constituent not detected

Maximum detect below comparison value

Constituent not detected

Constituent not detected

Constituent not detected

Maximum detect below comparison value

Constituent not detected

Constituent not detected

Maximum detect exceeds comparison value

Constituent not detected bull

Maximum detect below comparison value

Constituent not detected

Constituent not detected

Maximum detect exceeds comparison value

Maximum detect below comparison value

Constituent not detected

Maximum detect exceeds comparison value

Constituent not detected

Constituent not detected

Constituent not detected bull

Maximum detect below comparison value

Maximum detect below comparison value

Notes

ND - Not Detected

NA - Not Available

- - Constituent detected in every sample detection limit not presented

Values in bold indicate detection limit exceeds comparison values

Target shallow soil gas comparison values corresponding to indoor air concentrations where the soil gas to indoor air attenuation factor = 01 and the target cancer risk is set to ip (presented in Table 2c of USEPA 2002a)

Comparison value for cyclohexane is based on the comparison value for hexane

Coyne VI Memo Tables_09-08-09xls 982009

AR100296

TABLES

EXPOSURE POINT CONCENTRATIONS FOR CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR

Coyne Textile Services Facility - Huntington West Virginia

Chemical of Concern

VolatileOrganics

i24-Trimethylbenzene

12-Dichloroethene (cis)

Chloroform

Methylene chloride

Tetrachloroethene Triehloroethene

Subslab Vapor Source

Concentration (mgm^)

0197

603

591

152

149 782

Transport

Factor^ (unitless)

108E-05

108E-05

108E-05

108E-05

108E-05 108E-05

EPC in

Indoor Air (mgm^)

213E-06

651 E-05

638E-05

164E-05

161E-03 844E-05

Notes

^ Subslab vapor source concentration is based on the maximum detected concentration of samples

VP-01-02 and-03 (see Table 2) -

^ Details of the transport factor calculations are presented in Appendix B

^ Exposure Point Concentration (EPC) in inidoor air is calculated as the subslab vapor concentration TF

Coyne VI Memo Tables_09-08-09xls 982009

AR100297

TABLE 4

FACTORS USED IN DOSE CALCULATIONS INHALATION OF VOLATILE EMISSIONS

Coyne Textile Services Facility - Huntington West Virginia

Symbol

CA

IRA

ET

EF

ED-

BW

AT

Exposure Factor

Constituent Concentration in Air

Inhalation Rate

Exposure Time

Exposure Frequency

Exposure Duration

Body Weight

Averaging Time

Indoor Worker

Constituent-Specific See Table 3

25 m hour

8 hrday

250 daysyear

25 years

bull 70 kg

9125 days (NC)

25550 days (C)

Total Dose = CA x IR^ x ET x EF x ED x 1BW x 1AT

(NC) - Non-carcinogenic Averaging Time

(C) - Carcinogenic Averaging Time

Coyne VI Memo Tables_09-08-09xls 982009

AR100298

TABLES TOXICITY VALUES FOR CHEMICALS OF CONCERN

Coyne Textile Services Facility - Huntington West Virginia

Chemical of Concern

Volatile Organics

124-Trimethylbenzene

12-Dichloroethene (cis)

Chloroform

Methylene chloride

tetrachloroethene

Triehloroethene

Target Organ Critical Effect

blood

bullblood

liver

liver

liver CMS

liver kidney fetus CNS

Chroniclnhalation Reference Dose

(mgkg-day)

200E-03 P

1 OOE-02 R

140E-02 E

286E-01 M

771 E-02 M

1OOE-02 E

Inhalation Cancer ^ Slope Factor

(mgkg-day)^

NA

NA

805E-02 1

165E-03 1

200E-02 0

400E-01 E

(I) - Integrated Risk Information System (IRIS USEPA 2009)

(P) - Provisional Peer-Reviewed Toxicity Value (PPRTV) as presented in USEPA Regional Screening Tables (ORNL 2009)

(R) - Calculated assuming route-to-route extrapolation as per WVDEP

(E)-Provisional value from the National Center for Environmental Assessment (as per WVDEP)

(M)-Chronic Minimal Risk Level (MRL ATSDR 2009)

(0) - Value cited by USEPA Region 3 attributed to other sources (as per WVDEP)

Coyne VI Memo Tables_09-08-09xls 982009

AR100299

TABLE 6

NONCANCER HAZARD INDEX AND POTENTIAL CANCER RISK FOR AN INDOOR WORKER

Coyne Textile Services Facility - Huntington West Virginia

bull

Constituent

Volatile Organics

124-Trinnethylbehzene

12-Dichlorpethene (cis)

Chloroform

Methylene chloride

Tetrachloroethene Triehloroethene

EPC in Indoor Air

(mgm)

213E-06

651 E-05

- 638E-05

164E-05

161 E-03

844E-05

Intake (ADD)

(mgkg-d)

416E-07

127E-05

125E-05

321 E-06

315E-04 l65E-05

RfDi

(mgkg-d)

200E-03

1OOE-02

140E-02

286E-01

771 E-02 1 OOE-02

Hazard

Quotient

208E-04

127E-03

892E-04

112E-05

408E-03 165E-03

Intake (LADD)

(mgkg-d)

) 149E-07

455E-06 bull 446E-06

115E-06

112E-04 590E-06

CSFi

(mgkg-d)

NA

NA

805E-02

165E-03

200E-02

400E-01

Potential

Cancer Risk

NA

NA

359E-07

189E-09

225E-06 236E-06

Total Hazard Index

00081 Total

Cancer Risk 497E-06

Total Blood HI = Total Liver HI =

Total Central Nervous System HI = Total Kidney HI =

Total Fetal HI =

bull 00015 00066 00057 00017 00017

Notes NA = Toxicity values are not available for this endpoint or exposure pathway

Coyne VI Memo Tables_09-08-09xls 982009

AR100300

APPENDIX A

SUBSLAB VAPOR ANALYTICAL DATA

AR100301

Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility Huntington West Virginia

Sample

Consti tuent

Volatile Organics (ugm) 111-Trlchloroethane 1122-Tetrachloroethane 112-Trichloro-122-trifluoroethane 112-Trichloroethane 11-Dichioroethane 11-Dichloroethene 124-Trichloroberi2ene 124-Trimethylbenzene 12-Dibromoethane 12-Dichloroben2ene 12-Dichloroethane 12-Dichloroethene-(cis) -12-Dichloroethene (trans) 12-Dichloropropane 12-Dichlorotetrafluoroethane 135-Trimethylbenzene 13-Butadiene 13-Dichlorobenzene 13-Hexachlorobutadiene 14-Dichlorobenzene 224-trimethVlpentane 2-Chlorotoluene 4-Ethyltoluene Acetone Allyl Chloride Benzene Bromodichloromethane Bromoform Bromomethane Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 13-Dichloropropene (cis) Cyclohexane Dibromochloromethane

Identif ication Sample Date

CAS No

71-55-6 79-34-5 76-13-1 79-00-5 75-34-3 75-35-4 120-82-1 95-63-6 106-93-4 95-50-1 107-06-2 156-59-2 156-60-5 78-87-5 76-14-2 108-67-8 106-99^0 541-73-1 87-68-3 106-46-7 540-84r1 95-49-8

622-96-8 67-64-1 107-05-1 71-43-2 75-27-4 75-252 74-83-9 75-15-0 56-23-5 108-90-7 75-00-3 67-66-3 74-87-3

10061-01-5 110-82-7 124-48-1

lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt

lt lt lt lt lt lt lt lt lt lt lt lt

lt

VP-01 8132009

22 28 31 22 16 16 30 20 31 24 16 16 16 19 28 20 89 24 43 24

1 9 21 20 796 13 13 27 41 16 13 25 18 11 20 83 18 52 34

lt lt lt lt lt lt lt lt lt lt lt

lt lt lt lt lt lt lt lt lt lt lt

lt lt lt lt lt lt lt lt lt

lt lt lt lt

VP-02 8132009

218 2 7 5 307 218 162 159 297

bull 197 307 240 162 369 159 185 280 197 89

240 427 240 187 207 197

1880 125 128 268 414 155 125 252 184 106

5910 83 182 138 341

lt lt lt lt lt lt lt

lt lt lt

lt lt lt lt lt lt lt bull

lt lt lt lt

lt lt lt lt lt lt lt lt lt lt lt lt lt lt

VP-03 8132009

218 275 307 218

bull 162 159 297 197 307 240 162

6030 159 185 280 197 89

240 427 240 187 207 197

1750 125 128 268 414 155 125 252 184 106 195 83 182 138 341

Appx A SG Dataxis Page 1 of 2 982009

AR100302

Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility bull Huntington West Virginia

Consti tuent

Volatile Organics (ugm^) Dichlorodifluoromethane Ethylbenzene Methyl ethyl ketone Methyl Isobutyl ketone Methyl tert-butyl ether Methylene chloride n-Heptane jn-Hexane Styrene Tert-butyl alcohol Tetrachloroethene iToluene 13-Dichloropropene (trans) Triehloroethene Trichlorofluoromethane Vinyl bromide Vinyl chloride Xylene (o) Xylenes (mampp)

Sample Identif ication Sample Date

CAS No

75-71-8 100-41-4 78-93-3 108-10-1

1634-04-4 75-09-2

142-82-5 bull 110-54-3

100-42-5 75-65-0 127-18-4 108-88-3

10061-02-6 79-01-6 75-69-4 593-60-2 75-01-4 95-47-6

179601-23-1

lt lt

lt lt lt lt

lt lt

lt

lt lt lt lt lt

VP01 8132009

20 17 23 16 14 14 16

173 17 12 bull

11200 18 18 91 23 18 10 17 17

lt lt lt lt lt

lt

lt lt

lt lt

lt lt lt lt lt

VP-02 8132009

198 174 118 164 144

1520 164 -183 170 121

149000 151 182

2360 225 175 102 174 174

VP-03 8132009

lt 198 lt 174 lt 118 lt 164 lt 144

1160 lt 164

144 lt 170 ltbull 121

90500 lt 151 lt 182

7820 lt 225 lt 175 lt 102

208 387

Appx A SG Dataxis Page 2 of 2 982009

AR100303

APPENDIX B

CALCULATION OF TRANSPORT FACTORS USED TO ESTIMATE INDOOR AIR CONCENTRATIONS

AR100304

APPENDIX B

Calculation of Transport Factors Used to Estimate Indoor Air Concentrations

This appendix presents the methodology for calculating transport factors that are used to convert subslab

vapor concentrations to concentrations in indoor air 124-Trimethylbenzene 12-dichloroethene (cis)

chloroform methylene chloride tetrachloroethene and triehloroethene were identified as contaminants of

concern (COC) for potential vapor intrusion from subslab vapor associated with the Coyne Textile

Services Facility located in Huntington West Virginia (site) In this appendix the transport factors are

calculated to estimate the concentrations of COC in indoor air of the existing plant building located at the

site ~

Transport Factor for Indoor Air

The concentration of a constituent in indoor air (da) is proportional to the concentration of the constituent

in the subslab vapors immediately beneath the building foundation (ie subslab vapor concentration or

Csubsiab) The following equation is used to calculate da from Csubsiab

^ wja ~ ^subslab X I r

where

Cia = concentration of constituent in indoor air (mgm^) -

Csubsiab^ concentration of constituent in subslab vapors (mgm^) and

TF = transport factor from subslab vapors to indoor air

The transport factor (TF) is an infinite source attenuation coefficient andcan be calculated based on a

model developed by Johnson and Ettinger (1991) t he equation for calculating TF is as follows

(Deff X A B ) ( Q B X L T ) X expKQso i l X Lcrabk)(Dcrack X Acrack)]

exp[ (Qsoi l X Lcrack)(Dcrack X Acrack)] + (Deff X A B ) ( Q B X L T ) + (Deff X AB)(Qsoi l X L j ) X (exp [ (Qso i l X Lcrack)(Dcrack X Acrack)] - 1)

where

Deff = effective diffusion coefficient for vadose zone soil (cm^sec)

AB = area of enclosed space below grade (cm^)

QB = building ventilation rate (cm^sec)

LT = distance from contaminant source to building foundation (cm)

Qsoii = volumetric flow rate of vapors into the building (cm^sec)

Lcrack = foundatlon thickness (cm)

Dcrack = vapor diffusion coefficient through crack (cm^sec) and

Acrack = area of cracks through which vapors can pass (cm^)

AR100305

To solve this equation the USEPAs SG-ADV spreadsheet Version 31 most recently updated in

February 2004 was implemented A combination of site-specific factors and default values from the

Users Guide for Evaluating Subsurface Vapor Intrusion Into Buildings (USEPA 2004) were used as input

values in the model All input values are defined below and presented in Tables B-1-A through B-6-A

bull The initial subslab vapor concentration (Csubsiab) is the maximum detected concentration(in units

of ugm ) of samples VP-01 VP-02 and VP-03 that was presented in Table 3 of the report

bull The depth below grade to the bottom of the enclosed space floor (Lp) is set to 15 cm the default

value provided by USEPA (2004) for a slab-on-grade structure

bull The vapor sampling depth below grade (Lg) is a site-specific value The vapor samples were

collected from immediately beneath the building floor therefore Lj has been set to 15 cm

bull The average soilgroundwater temperature (Ts) is set to 125degC the average value for West

Virginia as estimated frorri Figure 8 of the vapor intrusion users guide (USEPA 2004)

bull The soil type used to estimate vapor permeability is assumed to be sandy loam (SL) The

associated soil properties for a sandy loam soil type are as follows the soil dry bulk density (Pb) is

162 gcm the total porosity (n) is 0387 (cm^-aircm^) and the water-filled porosity (nw) is 0103

(cm -HzOcm )

bull The floor thickness (Lcrack) is set to the USEPA (2004) default value of 10 cm

bull The soil-building pressure differential (AP) is set to the USEPA (2004) default value of 40 gcm-s^

bull The building dimensions are siterspecific based on the existing plant building located at the site

The existing structure is approximately 84000 square feet (Dolphin 2000) therefore the

dimensions are set to 8839 cm (290 feet) length by 8839 cm (290 feet) The USEPA (2004)

default value of 244 cm vyas used for the height

bull Thefloor-wall seam crack width (w) is set to the USEPA (2004)-default value of 01 cm

bull The indoor air exchange rate (ER) is set to 083hour This is the value provided by ASTM (2002)

for commercial and industrial buildings

AR100306

Tables B-1-B through B-6-B present the constituent-specific properties for COC that were used in the TF

calculations Tables B-1-C through B-6-C present the intermediate calculations used to determine the

indoor air attenuation coefficients (ie the transport factors) The shaded boxes in Tables B-1-C through

B-6-C also present the resulting TF values that are applied to the concentrations of COC in subslab

vapor and the estimated indoor air concentrations

References

American Society for Testing and Materials (ASTM 2002) Standard Guide for Risk-Based Corrective Action Applied at Petroleum Release Sites ASTM E-1739-95 (Reapproved 2002)

Johnson PC and RA Ettinger (1991) Heuristic model for predicting the intrusion r-ate of contaminant vapors into buildings Environ Sci Technolpgy 25 1445-1452

Dolphin Environmental LLC (Dolphin 2000) Site Characterization Report Mach 14 2000

United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004

AR100307

APPENDIX B-1-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV Nersion31 0204

Reset to Defaults

ENTER -

Chemical CAS No

(numbers only

no dasties)

95636

ENTER Soil gas

cone

Cg (ngm)

Soil Gas Concentration Data ENTER

Soil gas

OR cone

bull - c bull (PPmv)

197E+02

Chemical

124-Trimethylbenzene

MORE ENTER Depth

below grade to bottom

of enclosed space floor

U bull (cm)

ENTER

Soil gas sampling

depth below grade

U (cm) bull

ENTER

Average soil

temperature Ts

CO

1 15 1 1 5 bull125

ENTER ENTER ENTER Totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hft ha he

(cm) (cm) (cm)

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estirnate OR permeability | soil vapor

permeability) k v bull

(cm)

SL 1 1

MORE ENTER

stratum A SCS

soil type

Lookup Soil Parameters

ENTER stratum A soil dry

bulk density P

(gcm)

ENTER Stratum A soil total porosity

(unitless)

ENTER bull stratum A soil water-filled

porosity

(cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

nlaquo

(unitless)

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gchi-s^)

ENTER Enclosed

space floor

length bull LB

(cm)

ENTER Enclosed

space floor

width WB

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

bull Floor-wall seam crack

width w

(cm)

bullENTER

Indoor air exchange

rate ER

(1h) bull

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bidg OR

Leave blank to caicuij

(Lm)

Appx B-1 124-TMBxls 1 of 3 982009

AR100308

APPENDIX B-1-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of ^ bull law constant law constant vaporization at Normal

Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temperature boiling point point temperature weight

D bull Dbdquo H T R bull AHbdquo TB Tc IVIW

Unit risk Reference

factor cone URF RfC

(cms) (cmls) (atm-mmol) CO (calmol) (degK) (degK) (gmol) bull (ugm)- (mgm)

1 606E-02 1 792E-06 1 bull 614E-C3 1 25 1 9369 1 44230 | 64917 1 12020 1 OOE+00 1 60E-03 1

Appx B-1 124-TMBxls 2 of 3 982009

AR100309

APPENDIX B-1-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

(sec)

Source-building

separation

LT bull

(cm) bull

Stratum A soil

air-filled porosity

Q A

Stratum B soil

air-filled porosity

(cmcm) (cmcm)

Stratum C soil air-filled porosity

(cmcm)

Stratum A effective total fluid

saturation

Se

(cmcm)

Stratum A soil

bullintrinsic permeability

^ (cm)

stratum A Stratum A Floor- soil soli wall BIdg

relative air effective vapor seam Soil bull ventilation permeability permeability perimeter gas rate-

kfg ky Xgrack c o n e - QbuHdinpound

(cm) - (cm) (cm) (ngm) (cms)

946E+08 1 0284 0284 0284 0184 596E-09 0901 537E-09 35357 I 197E+02 | 439E+06 |

Area of enclosed

space below grade

As (cm)

Crack-to-total area ratio

1 bull

(unitless)

Crack depth

below grade

Zcfack

(cm)

Enthalpy of vaporization at

ave soil temperature

AHvjs

(calmol) bull

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law constant at

ave soil bull temperature

bull HTS

(unitless)

Vapor bull viscosity at

ave soil temperature

HTS

(gcm-s)

Stratum A

effective diffusion

coefficient

D (cms)

Stratum-B

effective diffusion coefficient

DB (cms)

Stratum C effective diffusion

coefficient

D-c (cms)

Total - overall effective diffusion

coefficient

D ^ (cms)

Diffusion path

length

L-

(cm)

I 787E+07 I 449E-05 | 15 | 11661 260E-03 111E-01 176E-04 I 612E-03 j OOOE+00 | OOOE+00 | 612E-03 j

bull Convection path

length

Lp

(cm)

Source vapor cone

^source

(ngm)

Crack radius

Tcfack

(cm)

Average vapor

flow rate into bIdg

Qsoii

(cms)

Crack effective diffusion

coefficient pcrack

(cms)

Area of CTack

Acack

(cm)

Exponent of equivalent foundation

Peclet number

exp(Pe)

(unitless)

bull bull - bull bull bull bull

1 15 1 197E+02 1 010 1 474E+01 612E-03 bull 354E-t-03 1 336E+09

Infinite source Indoor

~ attenuation coefficient

a

(unitless)

108E-05

Infinite source

btJbldgjJSv-L ^Ppncji3i-

virhpbiiilding bullbull ^lHltti^m)ilg

213E-03

Unit risk

factor

URF

(ngm)-

Reference cone

RfC (mgm)

NA 60E-03 1

I END

Appx B-1 124-TMBxls 3 of 3 982009

AR100310

APPENDIX B-2-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV Nersion31 020^

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

156592

Soil Gas Concentration Data ENTER

Soil gas

cone OR c

(ngm) bull

ENTER Soil bull-gas

cone

c (ppmv)

603E+03 1

Chemical

cis-12-Dichloroethylene

MORE ENTER Depth

below grade to bottom

of enclosed space floor

LF

(cm)

ENTER

Soil gas sampling

depth below grade

U (cm)

ENTER

Average soil

temperature bull Ts

(degC)

1 15 1 bull 15 125

ENTER ENTER ENTER Totalsmust add ijp tb value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hA hB he

bull (cm) (cm) (cm)

15 1 1

ENTER Soil

straturh A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estimate OR permeability | soil vapor

permeability) kv

(cm)

SL 1 |

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

P (gcm)

ENTER Stratum A soil total porosity

bull n

(unitless)

ENTER Stratum A

soil water-filled porosity

(cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

ENTER Stratum B

soil water-filled porosity

ENTER Stratum C

SCS soil type

(unitless) (cmcm)

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure differential

AP

(gcm-s)

ENTER Enclosed bull

space floor

length

LB (cm)

ENTER Enclosed

space floor

width WB

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER

Average vapor flow rate into bIdg

OR Leave blank to calculi

Qsoil

(Lm)

Appx B-2 cis-12-DCExls 1 of 3 982009

AR100311

APPENDIX B-2-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Diffusivity in air

Da

(cms)

Diffusivity in water

Dw (cms)

Henrys law constant at reference temperature

H

(atm-mmoi)

Henrys law constant

reference temperature

bull T R

CC)

Enthalpy of vaporization at

the normal boiling point

AHbdquob

(calmol)

Normal boiling point

TB

(degK)

Critical temperature

Tc (degK)

Molecular weight

MW

(gmol)

Unit risk

factor URF

(ngm)

Reference cone

RfC (mgm)

1 736E-02 1 113E-05 1 407E-03 j 1 25 1 bull 7192 1 33365 1 54400 1 9694 1 OOE+00 j 35E-02 1

Appx B-2 cis-12-DCExls 2 of 3 982009

AR100312

APPENDIX B-2-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

stratum A Stratum B Stratum C Source- soil soil soil

Exposure building air-filled air-filled air-filled

duration separation porosity porosity porosity

T LT ea e^ bull e= (sec) (cm) (cmcm) (cmcm) (cmcm)

I 946E+08n^

Stratum A Stratum A Stratum A Stratum A Floor-effective soil soil soil wall total fluid intrinsic relative air effective vapor seam

saturation permeability permeability permeability perimeter

Ste kj krg ky Acrack

(cmcm) (cm) (cm) (cm) (cm)

Soil gas

cone (ngm)

I 0284 I 0284~ 0284 0184 I 596E-09 | 090T 537E-09 35357 603E+03

BIdg ventilation

rate

JbulldinE

(cms)

439E+06

Area of enclosed

space below grade

AB

(cm)

Crack-to-total

area ratio

n (unitless)

Crack depth below grade

Zltiack (cm)

Erithalpy of vaporization at

ave soil temperature

AHvTs (calmol)

Henryslaw constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law constant at

ave soil temperature

HTS

(unitless) bull

Vapor viscosity at

ave soil bull temperature

HTS

bull (gcm-s)

Stratum A

effective bull diffusion

coefficient

D^A-(cms)

Stratum B

effective bull diffusion

coefficient

D=B

(cms)

Stratum C

effective diffusion bull

coefficient

D=e (cms)

Total overall

effective diffusion

coefficient

DT

(cms)

Diffusion path

length

Ld

(cm)

I 787E+07 I bull449E-05 | 15 bull7709 230E-03 982E-02 176E-04 | 743E-03 | OOOE+00 | OOOE+00 | 743E-03 |

bull bull bull -

Convecfion path -bull

length

Lp (cm)

Source vapor cone

-source

(Mgm)

Crack radius

fcrack

(cm)

Average vapor

flow rate into bIdg

Qaoil bull

(cms)

Crack effective diffusion

coefficient pcack

(cms)

Area of crack

crack

(cm)-

Exponent of equivalent foundation

Peclet number

exp(Pef)

(unitless)

bull

1 15 -1 603E+03 1 010 1 474E+01 743E-03 354E+03 1 697E+07

Infinite source Indoor

attenuation coefficient

poundbullbullbull C t

pound(unitless)

bullsiilaquogt j ii08E-05

Infinite [ source

bIdg cone

Cbujidjng

(pgm)

651 E-02 iKrt

Unit risk

factor

URF

(ngm)-

Reference cone

RfC

(mgm)

NA 35E-02 1

I END I

Appx B-2 cis-12-DCExls 3o f3 982009

AR100313

APPENDIX B-3-A DATA ENTRY SHEET

Coyne Texti le Services - Hunt ington West Virginia

SG-ADV Version 31 0204

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

67663

Soil Gas Concentration Data ENTER ENTER

Soil Soil gas gas

cone OR cone c C

(^gm) (ppmv)

591 E+03

bull

Chemical

Chloroform

MORE ENTER Depth

below grade tb bottom

of enclosed space floor

bull LF

(cm)

ENTER

Soil gas sampling depth

below grade

(cm)

ENTER

Average soil

temperature-Ts

CO bull

1 15 1 15 1 125

ENTER ENTER ENTER Totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

IIA hs he (cm) (cm) (cm)

1 5 bull 1 1

ENTER ENTER Soil - bull

stratum A User-defined SCS stratum A

soil type bull soil vapor (used to estimate OR permeability

soil vapor k

bull permeability) (cm) 1

SL 1 1 bull

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A soil dry

bulk density

Pb (gcm)

ENTER Stratum A soil total porosity

nV (unitless)

ENTER Stratum A

-soilwater-filled bullporosity

Sraquo (cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

(unitless)

ENTER Stratum B

soil water-filled porosity

bull ebdquo=

(cmcm) bull

ENTER Straturri C

SCS bull soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

- c rack

(cm)

ENTER

Soil-bldg pressure

differential AP^

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor

width bull W B

(cm)

ENTER

Enclosed space

height HB

(cm)

ENTER

bull Floor-wall^ seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bidg OR

Leave blank to calculi

Qsoil bull

(Lm)

I -I

Appx B-3 Chloroformxls 1 of 3 982009

AR100314

APPENDIX B-3-B CHEMICALPROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Diffusivity in air

D (cms)

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffijsivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature

Dbdquo H TR A H bdquo TB Tc

(cm s) (atm-m mol) ro (calmol) (degK) (degK)

Molecular weight

MW

(gmol)

Unit risk

factor URF

(ngm)-

Reference cone

RfC

(mgm)

104E-01 100E-05 I 366E-03 25 6988 33432 53640 11938 I 23E-05 | OOE+00

Appx B-3 Chloroformxls 2 of 3 982009

AR100315

APPENDIX B-3-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure

duration

(sec)

Source-

building

separation

LT

(cm)

Stratum A

soil

air-filled

porosity

Sa

( cm cm )

Stratum B

soil

air-filled

porosity

( cm cm )

Stratum C

soil

air-filled

porosity

( c m c m )

Stratum A

effective

total fluid

saturation

( c m c m )

Stratum A

soil

intrinsic

penmeability

k

(cm )

Stratum A

- soil

relative air

permeabil i ty

(cm )

Stratum A

soil

effective vapor

permeability

kv

(cm )

Floor-

wall

seam

perimeter

gtcrack

(cm)

Soil gas

cone

(ngm)

BIdg

venfilation

rate

^buildlriE

(cms)

I 9 4 6 E + 0 8 ~ T I 0284 T 596E-09 I 0-901 I 537E-09 | 35357 | 591 E+03 j 439E+06 | 1 0 284 0284 0184

Area of

enclosed

space

below

grade

A B

( c m )

Crack-

to-total

area

ratio

n

(unitless)

Crack

depth

bull below

grade

^crack

(cm)

Enthalpy of

vaporization at

ave soil

temperature

AHTs bull

(calmol)

Henry s law

constant at

ave soil

temperature

HTS

(a tm-m mol j

Henrys law

constant at

ave soil

bull temperature

HTS

(unitless) bull

Vapor

viscosity at

ave soil-

temperature

^HTS

(gcm-s)

Stratum

A

effective

diffusion

coefficient

(cm s)

Stratum

B

effective

difftjsion

coefficient

D B

(cms) bull

S t ra tum

C

effective

diffusion

coefficient

Dc

(cm s)

Total

overall

effective

bull diffusion

coefficient

D T

(cm s)

Diffi jsion

path

length

Ld

(cm)

I 787E+07 I 449E-05 j - bull 15 7528 210E-03 896E-02 176E-04 I 105E-02 | OOOE+00 | OOOE+00 | 105E-02

Convection

path length

Lp

(cm)

Source

vapor

cone -

^source

- (ngm)

Crack

radius

Tcrack

(cm)

Average

vapor

flow rate

into bidg

Qsoil

(cms)

Crack

effective

diffusion

coefficient Qcrack

bull (cms)

Area of crack

Acrack

(cm)

Exponent of

equivalent

foundation

Peclet number

exp(Pe)

(unitless)

V bull bull

1 15 1 591 E+03 1 010 1 474E+01 105E-02 354E+03 1 355E+05

Infinite

source

indoor

attenuation

coefficient

d

(unitless)

bull 108E-05

Infinite

source

bIdg

cone

^ b u i l d i n g

i (^gm)

bull bull

i 638E-02 -

Unit

risk bull factor

URF

(ngmY

Reference

cone

RfC

(mgm)

~ 23E-05 NA 1

I END

Appx B-3 Chloroform xls 3 of 3 982009

AR100316

APPENDIX B-4-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ersion 31-020^

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

nodashes)

bull 75092

ENTER Soil gas

cone

c (ngm)

Soil Gas Concentration Data ENTER

Soil gas bull

OR cone

bull C

(ppmv)

152E+03

bull bull

Chemical

Methylene chloride

MORE

MORE 4gt

ENTER Depth

below grade to bottom

of enclosed space floor

LF -

(cm)

ENTER

Soil gas sampling depth

below grade

bull U

(cm)

ENTER

Average soil

temperature

Ts bull CC)

bull bull bull bull

1 15 1 15 125

ENTER Totals

Thickness of soil

stratum A h

(cm)

ENTER ENTER must add up to value of Ls (cell F24

Thickness Thickness of soil of soil

stratum B stratum C (Enter value or 0) (Enter value or 0)

he he bull

(cm) bull (cm) -

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(usedto estimate OR perrrieability | soil vapor

permeability)

k bull

(cm)

SL 1 bull 1

ENTER Stratum A

SCS soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

Pb (gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Stratum A

soil water-filled porosity

9w (cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

Pb^

(gcm)

ENTER Stratum B soil total porosity

n^

(unitless)

ENTER Stratum B

soil water-filled porosity

(crhcm)

ENTER Stratum C

SCS soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE 4gt

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

bull Soil-bldg pressure

differential AP^

(gcm-s)

ENTER Enclosed

space floor

length LB

(cm)

ENTER Enclosed

space floor

width bull W B

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width

w

(cm)

ENTER

Indoor air exchange

rate

ER (1h)

ENTER Average vapor

flow rate into bidg OR

Leave blank to calculc

Qsoil

(Lm)

10 40 8839 8839 244 01 083

Appx B-4 MCxIs 1 of 3 982009

AR100317

Diffijsivity in air

D

APPENDIX B-4-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffusivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature

Pw H TR AHt TB TC

Molecular weight

MW

Unit risk

factor URF

Reference cone

RfC

(cms) (cms) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) bull (ngm)- (mgm)

bull bull

1 101E-01 1 117E-05 1 218E-03 1 25 | 6706 1 31300 1 51000 1 8493 1 47E-07 1 30E+00 1

Appx B-4 MCxIs 2 of 3 982009

AR100318

APPENDIX B-4-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

T

(sec)

Source- -building

separation

LT

(cm)

Stratum A soil

air-filled porosity

e a bull

(cmcm)

Stratum B soil

bullair-filled porosity bull

ea^ (cmcm)

Stratum C soil

air-filled porosity

ea= (cmcmj

Stratum A effective total fluid

saturation

Sc bull

(cmcm)

Stratum A soil

intrinsic pemneability

ki (cm)

Stratum A soil

relative air permeability

^ ^ g

(cm)

stratumA bull soil effective vapor permeability

K (cm)

Floor-wall

seam perimeter

Xcrack

(cm)

Soil gas

cone (ngm)

BIdg ventilation

rate

Qbuildinc

(cms)

1 946E+08

Area of -enclosed

space below

bull grade

AB

(cm)

1

Crack-to-total

area rafio

Tl

(unitless)

0284 1

Crack depth below grade

Zcrack

(cm)

0284 1

bull Enthalpy of vaporization at

ave soil temperature

AHTs (calmol)

0284

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

0184

Henrys law constant at ave soil

temperature

HTS

bull (unitless)

1 596E-09

Vapor viscosity at

ave soil temperature

Mrs (gcm-s)

0901

Stratum A

effective diffusion

coefficient

D (cms)

537E-09

Stratum B

effective diffusion

coefficient

D-B (cms)

35357 1

Stratum C -

effective diffusion

coefficient

D-c ^ (cms)

152E+03

Total bull overall

bull effective diffusion

coefficient

D ^

(cms)

440E+06 1

Difftjsion path

length

Ld (cm)

1 787E+07

Convection path

length

Lp (cm)

4 49E-05

Source vapor cone

Csource

(ngm)

15 1

Crack radius

Tcrack

(cm)

7007 bull 1

Average vapor

flow rate intobldg

Qsoil

(cms)

130E-03

Crack effective diffusion

coefficient pcrack

(cms)-

555E-02

bull ^

Area of crack

Acrack

(cm) bull

1 176E-04

Exponent of equivalent foundation

Peclet number

exp(Pe)

(unitless) bull

bull bull

1 15

1 END

152E+03 010 1 474E+01 1 102E-02 354E+03 1 519E+05

102E-02

Infinite source

indoor ^attenuation coefficient

bull a

(unitless)

aiii08E-05

0 OOE+00

bull

Infinite bull source

bIdg ^ cone

^bu i l d i ng

(MQm)

164E-02

OOOE+00 1

Unit risk

factor

URF

(ngm)-

47E-07 1

102E-02 j

Reference cone

RfC

(mgm)

30E+00 j

1 1

Appx B-4 MCxIs 3 of 3 982009

AR100319

APPENDIX B-5-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ^erslon 31 0204

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

127184

Soil Gas Concentration Data ENTER ^ ENTER

Soil -Soi l bull gas gas

cone OR cone Cg C bull

(tgm) (ppmv)

149E+05 1

Chemical

bull Tetrachlbroethylene

MORE 4

ENTER Depth

below grade to bottom

ofenclosecJ space floor

LF

(cm)

ENTER

Soil gas bull sampling

depth below grade

u bull (cm)

ENTER

Average bullsoil

temperature - Ts

ro 1 1 5 1 15 1 125 bull

ENTER ENTER ENTER totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hft bull he bull he

(cm) (cm) (cm)

bull 1 5 1 - 1

ENTER ENTER Soil

stratum A User^defined bull SCS bull stratum A soil type soil vapor

(used to estimate OR perrrieability soil vapor K bull

permeability) (cm) 1

SL 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

Pb

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Sitratum A

soil water-filled bull porosity

(cmcm)

ENTER Stratum B

SCS soiltype

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

Pb^

(gcm)

ENTER Stratum B soil total porosity

Ajnitless^

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS soil type

LookupSoil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

VS

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor width

W B

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width

w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

ENTER Average vapor

flow rate into bidg OR

Leave blank to calcul

bull Qsoil

(Lm)

10 40 8839 8839 244 01 083

Appx B-5 PCExIS 1 of 3 982009

AR100320

APPENDIX B-5-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal Unit

Diffusivity Diffusivity at reference reference the riormal boiling Critical Molecular risk Reference in air in water temperature temperature boiling point point teriiperature weight factor cone

Da Dbdquo H TR AHb TB Tc MW URF RfC

(cms) (cnis) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) (^gm)- (mgm)

1 720E-02 1 820E-06 1 184E-02 1 25 1 8288 1 39440 1 62020 1 16583 1 59E-06 1 60E-01 1

J

AppxB-5PCExls 2 of 3 - 982009

AR100321

APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

T

(sec)

Source-building

separation

LT

bull (cm)

Stratum A soil

air-filled porosity

Oa (cmcm)

Stratum B - soil air-filled porosity

ea (cmcm)

Stratum C soil

air-filled porosity

ea= - (cmcm)

Stratum A effective total fluid

saturation

sbdquo (cmcm)

Stratum A soil

intrinsic permeability

ki (cm)

Stratum A soil

relative air permeability

- ^ g

(cm)

Stratum A soil

effective vapor permeability

kv (cm)

Floor-wall

seam perimeter

^crack

(cm)

Soil gas

cone

(ngm)

BIdg venfilation

rate

Qbuildins

bull (cms)

bull bull

1 946E+08

Area of enclosed

space below grade

AB

(cm)

1

bullCrack-to-total

area ratio

1 (unitless)

0284 1

Crack bull depth below grade

Zcrack

(cm) -

0284 1

Enthalpy of vaporization at bull

ave soil temperature

bull A H V TS

(calmol)

0284

Henrys law constant at

ave soil temperature

HTS (atm-mmol)

0184

-Henrys law constant at

ave soil temperature

HTS

(unitless)

1 596E-09

Vapor viscosity at

ave soil temperature

HTS

(gcm-s)

0901

Stratum A

effective diffusion

coefficient bull D = bull

(cms)

537E-09

Stratum B

effective diffusion

coefficient

D--B (cms)

35357 1

Stratum C

effective diffusion bull

coefficient

D-c (crris)

149E+05

Total overall

effective bulldiffusion coefficient

DT

(cms)

440E+06 1

Difftjsion path

length

U (cm)

1 787E+07

Convection path

length

bull Lp

(cm)

4 49E-05

Source vapor cone

^source

(ngm)

15 1

Crack radius

Tcrack

(cm)

9528 1

Average vapor

flow rate intobldg

Qsoil (cms)

908E-03

Crack effective diffusion

coefficient pcrack

bull ( c m s ) bull

387E-01

Area of crack

Abdquoack (cm)

1 176E-04

Exponent of equivalent foundafion

Peclet number

exp(Pe)

(unitless)

bull

1 15-

1 END

149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08

727E-03

Infinite source indoor

attenuation coefficient

a

(unitless)

108E-05

OOOE+00

Infinite source

bIdg cone

Cburldtng

(Mgm)

161 E+00

OOOE+00 1

Unit risk

factor

URF

(ugm)-

59E-06 1

727E-03

Reference cone

RfC (mgm)

60E-01

1 1

Appx B-5 PCExls 3 of 3 982009

AR100322

APPENDIX B-6-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ersion31 0204

Reset to Defaults

t

Soil Gas Concentration Data ENTER

Chemical CAS No

(numbers only

no dashes)

79016

ENTER ENTER Soil Soil gas gas

cone OR cone C C -

bull (ngm) (ppmv)

782E+03

Chemical

Trichloroethylene

MORE ENTER Depth

below grade to bottom-

of enclosed space floor

LF

(cm)

ENTER

Soil gas sarnpling

depth below grade

U (cm)

ENTER

Average soil

temperature Ts

(degC)

1 15 1 15 t 125

ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e

(cm) (cm) (cm)

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estimate OR permeability soil vapor

permeability)

k (cm)

bull S L 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil bull-Parameters

ENTER Stratum A

soil dry bulk density

P b -

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Stratum A bull

soilwaterrfilled porosity

(cmcm) bull

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

bull P ^ (gcm)

ENTER Stratum B soil total

porosity

nlaquo

(unitless) -

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS bull soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor

width W B

(cm)

ENTER

Enclosed space height

H B bull

( c m ) bull

ENTER

Floor-wall seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bIdg OR

Leave blank to calculc

Qsoil

(Lm) -

Appx B-6 TCExIs 1 of 3 982009

A

AR100323

APPENDIX B-6-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight

Da Dbdquo H TR AH^b TB TC MW

Unit risk Reference

factor cone URF RfC

(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)

1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1

Appx B-6 TCExIs 2 of 3 982009

AR100324

APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

(sec)

Source-building

separation LT

(cm)

Stratum A soil

air-filled porosity

bull ea (cmcm)

Stratum B Soil

air-fllled porosity

e^ bull (cmcm)

Stratum C soil

air-filled porosity

(cmcm)

StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air

saturation permeability permeability

S|e k krg (cmcm) (cm) (cm)

Stratum A Floor-soil wall BIdg

effective vapor seam Soil ventilafion permeability perimeter gas rate

k^ bull Xack c o n e Qbuildins

(cm) (cm) (ngm) (cms)

946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |

Area of enclosed

space below grade

AB

(cm)

Ciack- to-total

area ratio

1 (unitless)

Crack depth below grade

Zcrack

(cm)

Enthalpy of vaporization at

ave soil temperature

A H J S

(calmol)

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law bull constant at

ave soil temperature

HTS

(unitless)

Vapor viscosity at

ave soil temperature

|JTS

(gcm^s)

Stratum A

effective diffusion

coefficient

(cms)

Stratum B

effective -diffusion

coefficient

D=B (cms)

Stratum ^ C effective diffusion

coefficient

D=c (cms)

Total overall

effective diffusion

coefficient

DT

(cms)

I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03

Diffusion path

length

Li (cm) bull

Convection bull path

length

Lp

(cm)

Source vapor cone bull

^source

(ngm)

Crack radius

rcrack

(cm)

Average vapor

- flow rate intobldg

Qsoil

(cms)

Crack effective diffusion

bull coefficient Qcrack

(cms)

Area of crack

^crack

(cm)

Exponent of equivalent foundation

Peclet bull number

exp(Pe)

(unitless)

bull bull

1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07

Infinite source Indoor

attenuation coefficient

a

(unitless)

108E-05

Infinite source

bIdg concgt

^building

(ngm)

844E-02

Unit risk

factor

URF

(ngm)-

Reference cone

RfC

(mgm)

1 1E-04 1 40E-02 1

END

Appx B-6 TCExIs 3 of 3 982009

AR100325

Office of Waste Management 1356 Hansford Street

Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256

West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director

ORDER

ISSUED UNDER THE

HAZARDOUS WASTE MANAGEMENT ACT

CHAPTER 22 ARTICLE 18

OF THE WEST VIRGINIA CODE^ AS AMENDED

y Order Number HW-011-80

To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704

ATTEMTION MREDARMON

Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull

AR100326

ViWJ011-laquo9 PageNunil)er2

BASIS FOR ORDER

As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following

A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^

B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator

C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities

0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94

^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement

P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following

1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater

2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was

^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment

CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable

CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order

AR100327

H W - 0 1 1 - 9 9 Page Number 3

REQUIREMENTS OF ORDER

Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows

1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^

2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore

remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling

GENERAL PROVaiONS

1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order

2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order

3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order

Effective Date

Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief

Wt T 1 V Oflice of Waste Management

AR100328

^ ^ S I S

^wmmmmamn

AR100329

Page 8: SDMS DocID 2121999 · International Enterprises Corp. building (Coyne Building), which is located at 1111 Vernon Street, Westmoreland District, Wayne County, West Virginia. The following

Wayne County Economic Development Authority Page 3 Groundwater Assessment Coyne Textile Services Building Westmoreland District Wayne County West Virginia October 24 2008 _ bull ^

We appreciate the opportijnity to assist you with this project If you have any questions or r

need additional information please feel free to contact us

Sincerely TRIAD ENGINEERING INC

Matthew C Wright

Project Geologist

JohnM Meeks PG LRS

Project Manager

end

^

AR100285

Table 1 Laboratory Analytical Summary - Groundvvater WCEDA Vernon street

Huntington Wayne County West Virginia

COPC

Acetone Benzene Bromobenzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone sec-Butylbenzene n-Butyibenzene tert-Butylbenzene Carbon disulfide Carbon Tetrachloride Chlorobenzene Chlorodibromorriethane Ghloroethane Chlbroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene 12-Dibromo-3-chloropropane 12-Dlbronnoethane (EDB) DIbromomethane 14-Dichlorobenzene 13-Dictilorobenzene 12-Dictilorobenzene Dichlorodifluoromethane 11-Dlchloroethane 12-Dichloroethane cis-12-Dichloroethene

MCL ugL

5500 5

NV NV NV 85 87

700 61 61 61

1000 5

100 NV 39

bull 017 190 NV NV 02

005 NV

750 600 600 390 910

5 70

GP-1 ugL ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND

ND ND ND ND ND ND ND ND ND ND ND ND 112 ND

5210

GP-2 ugL ND ND ND

ND ND ND ND ND ND ND ND ND ND ND ND ND ND

062 J ND ND ND

ND ND ND ND ND ND ND ND

379

GP-3 ^ ugL

ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND

065 J ND 184 ND( ND ND ND

ND ND ND ND ND ND ND

12500

GP-4 ugL ND ND ND ND ND

- ND ND ND ND ND ND ND ND ND ND ND ND ND

ND ND ND ND ND ND ND ND ND ND ND 132

GP-5 ugL ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND

ND ND ND ND ND ND ND ND ND ND ND ND 59

Notes - Bold Indicates COPCs detected at concentrations greater than the MCL bull(60CSR3 Table 60-3B July 2008)

NAME - J indicates analyte detected at levels less than the reporting limit and greater than

or equal to the MDL value is estimated -NV indicates no value has been established

AR100286

Table 1 Laboratory Analytical Summary - Groundwater (Continued) WCEDA Vernon street

Huntington Wayiie County West Virginia

COPC

11-Dichloroethene trans-12-Dichloroethene 13-Dichloropropane 12-Dichloropropane 22-Dichloropropane cis-13-Dichloropropene trans-13rDichloropropene 11-Dichloropropene Ethylbenzene Hexachlorobutadiene 2-Hexanone Isopropylbenzene p-lsopropyltoluene Methyl tert-Butyl Ether Methylene Chloride 4-Methyl-2-pentanone Naphthalene n-Propylbenzene Styrene 1112-Tetrachloroethane 1122-Tetrachloroethane Tetrachloroethene Toluene 123-Trichlorobenzene 124-Trichlorobenzene 112-Trichloroethane 111-Trlchloroethane Triehloroethene Trichlorofluoromethane 123-Trichloropropane 135-Trimethylbenzene 124-Trimethylbenzene Vinyl chloride Xylenes total s

MCL ugL

91 100 04

5 NV NV NV NV

700 086

NV NV

NV 028

5 NV 62 NV 100

043 0055

5 1000

NV 70

5 20

5 1300

0034 120 120

2 10000

GP-1 ugL 964 458 ND ND

ND ND ND ND

052 J ND ND ND ND ND ND ND ND ND ND ND ND

14700 065 J ND ND ND ND

2850 ND

ND ND ND 116 146 J

GP-2 ugL ND ND ND ND ND ND ND- ND ND ND ND ND -ND ND ND ND ND ND ND ND ND

603 ND ND ND ND ND

079 J ND ND ND ND 242 ND

GP-3 ugL 346 865 ND ND

bull ND ND ND-ND

055 J ND ND ND ND ND ND ND ND ND ND ND ND

13900 159 ND ND ND ND

4870 ND ND ND ND 708 149 J

GP-4 ugL ND ND ND ND ND ND ND ND ND ND ND

ND 177 ND ND ND ND ND ND ND ND

583 ND ND ND ND ND

082 J ND ND ND ND

227 ND bull

GP-5 ugL ND ND ND ND ND

ND ND ND ND ND ND ND ND

ND ND ND ND ND ND ND ND 133 ND ND ND ND ND

574 ND ND

ND ND 122 ND

Notes - Bold indicates COPCs detected at concentrations greater than the MCL

(60CSR3 Table 60-3B July 2008) - ND indicates non-detected at concentrations greater than the MCL - J indicates analyte detected at levels less than the reporting limit and greater than

or equal to the MDL value is estimated - NV indicates no value has been established

AR100287

Risk-Based Rerfiedies

R B R Consulting Inc 650 Shady Drive Beaver Falls PA 15010

Phone724-846-4096 Fax 724-846-6974

MEMORANDUM

TO John Meeks Triad Engineering Inc

FROM Bruce Fishman

DATE September 82009

SUBJECT Evaluation of Potential Risks Associated with Vapor Intrijsion to Indoor Air Coyne Textile Services Facility - Huntington West Virginia

bull V bull bull bull

This memorandum presents a risk evaluation for potential risks associated with vapor intrusion to indoor air at the Coyne Textile Services Facility located in Huntington West Virginia (site) This evaluation was conducted according to West Virginia Department of Environmental Protection (WVDEP) and United States Environmental Protection Agency (USEPA) methodologies

DATA INCLUDED 1N THE EVALUATION

This evaluation includes three subslab vapor samples (VP-01 VP-02 and VP-03) collected from immediately beneath the floor of the existing site building Table 1 lists the subslab vapor samples included in this risk assessment Samples were analyzed for volatile organic compounds (VOCs) by USEPA Method TO-15 Complete analytical data for these samples are provided in Table A-1 of Appendix A

The analytical results of the subslab vapor samples were compared to the target shallow soil gas comparison values presented in Table 2c of the USEPA vapor intrusion guidance document (2002a) These companson values are generic soil gas screening values that are protective of indoor air for residential land uses and represent concentrations in-sliallow soil gas based on a target risk level of 1 x 10reg andor a hazard index of 1 The comparison is presented in Table 2

As indicated in Table 2 the following constituents are identified as contaminants of concern (COC) for the vapor intrusion to indoor air pathway 124-trimethylbenzene 12-dichloroethene (cis) chloroform methylene chloride tetrachloroethene and triehloroethene

ESTIMATION OF INDOOR AIR CONCENTRATIONS

The concentrations of COC in indoor air associated with vapor intrusion from subslab vapor were estimated using methodologies outlined in the Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings (USEPA 2004) A transport factor (TF) is required that will relate the

Page 1 of 5 -

AR100288

Risk-Based Remedies

R B R Consulting Inc

constituent concentration in subslab vapor to the concentration in indoor air The TF is dependent on the diffusion coefficient and other properties that will affect the transfer of constituents into air such as distance from the source to tlie breathing zone soil properties and building properties A site-specific building size of 84000 square feet (Dolphin 2000) and a soil type of sandy loam were used in the calculation of TF The TF is determined using calculationsbased on the Johnson and Ettinger (1991) vapor intrusion model Details of the TF calculations are provided in Appendix B

Subslab vapor concentrations are converted to indoor air concentration by applying the TF as follows

Cja ^ Csubslab X I r

The TF for each COC along with the resulting concentrations of COC in indoor air are presented in Tables

EXPOSURE EVALUATION

Noncarcinogenic health effects are evaluated by calculating the average dose of a constituent over the course of the exposure period This dose is termed the Average Daily Dose (ADD) Potential carcinogenic health effects are evaluated in terms of an individuals theoretical increased risk of developing cancer over a lifetime Although the duration of exposure to a constituent release generally does not last for an entire lifetime constituent intake for carcinogens is estimated as the average dose over a human lifetime (70 years) This lifetime dose applies specifically to the evaluation of carcinogenic effects and is termed tine Lifetime Average Daily Dose (LADD) In a risk assessment the calculated ADD or LADD are estimated quantitatively using assurnptions about the duration frequency and magnitude of exposure experienced by each potential receptor and assumptions about the constituent properties that influence absorption

The quantitative estimation of constituent intake involves the incorporation of numerical assumptions for a variety of exposure parahneters Exposure assumptions used in these intake calculations are based on WVDEP (2001) or USEPA (1989 2002b) recommended values The factors and equation for inhalation of vplatiles is presented in Table 4 and described below

bull Inhalation Rate and Exposure Time WVDEP (2001) and USEPA (2002b) guidance recommend that an inhalation rate of 20 m day be used for workers For an exposure time of 8 hours (a typical workday) this results in an inhalation rate of 25 m hour

bull Exposure Frequency and Duration Default exposure factors for indoor workers are provided by WVDEP (2001) Exposure frequency for the worker is 5 days per week for 50 weeks a year or 250 days per year The exposure duration for these workers is 25 years which is the 95th percentile value ai cording to the Bureau of Labor Statistics (USEPA 1989)

bull Body Weight The default value for average body weight of an adult is 70 kg based on WVDEP (2001) and USEPA guidance (1989 2002b)

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Risk-Based Remedies

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bull Averaging Time As described above the doses for noncarcinogenic health effects are averaged oyer the specific period of exposure for a given receptor Noncarcinogenic

averaging times are therefore calculated by multiplying the exposure duration for the receptor by 365 daysyear Carcinogenic health effects are calculated over a lifetime exposure so the value recommended by WVDEP (2001) and USEPA (2002b) for average lifetime 70 years was used for exposure duration The resulting carcinogenic averaging time is 25550 days

TOXICITY VALUES

Noncarcinogenic responses are evaluated numerically using parameters known as the hazard quotient (HQ) and hazard index (HI) the HQ is obtained by dividing the ADD for a constituent by the reference dose (RfD) Each dose calculation with a specific combination of constituent receptor and exposure pathway will have a distinct ADD and calculated HQ HQs associated with all constituents for a particular pathway are summed to yield the HI

In order to estimate the theoretical excess lifetime cancer risk the LADD of a constituent is multiplied by the cancer slope factor (CSF) For each pathway this calculation is carried out for each applicable constituent and the risks are summed to obtain the total potential risk due to that pathway

Toxicity values for each constituent are presented in Table 5 the toxicity values were obtained from the following sources

bull Integrated Risk Information System (IRIS) on-line database provided by USEPA (2009)

bull The USEPAs Provisional Peer-Reviewed Toxicity Values (PPRTV) as presented in the USEPA Regional Screening Tables (ORNL 2009)

bull Provisional value from the National Center for Environmental Assessnient (as per WVDEP)

bull The Agency for Toxic Substances and Disease Registrys (ATSDR) Minimal Risk Levels (MRLs ATSDR 2009) and

bull Value cited by USEPA Region 3 attributed to other sources (as per WVDEP)

RISK CHARACTERIZATION

Potential noncarcinogenic effects associated with exposure to COC at the site are estimated by comparing calculated intakes with the contaminant-specific RfDs The total HI was calculated by summing the individual HQs An HI value equal to or less than 1 indicates thatthelikelihopd of ah adverse noncancer effect would be negligible (USEPA 1989) An HI greater than 1 indicates that additional evaluation of the case is warranted

Theoretical excess lifetime cancer risks associated with exposure to COC from the site were calculated by comparing estimated intakes to constituent-specific CSFs Summed theoretical

Page 3 of 5

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Risk-Based Remedies

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excess risks are calculated by combining constituent-specific risks The results may be compared with target benchrharks for acceptable risk Various demarcations of acceptable risk have been established by regulatory agencies WDEP (2001) presents a target cancer risk of 1 x 10 for nonresidential scenarios USEPA (1991) considers potential cancer risks in the range of 1 x 10reg to 1 X 10 to be acceptable

Constituent-specific results for the indoor worker are presented in Table 6 For the indoor worker exposed to COC in indoor air (vapor intrusion from subslab vapor) the total HI is 00081 and the potential cumulative cancer risk is 497 X 10reg

These results meet both WVDEP and USEPA benchmarks indicating that the site poses negligible potential for human health risk for indoor workers

CONCLUSIONS

The results of this focused risk evaluation indicate that potential risks associated with vapor intrusion exposure of indoor workers to constituents that may volatilize from subslab vapor are within the acceptable benchmarks established by WVDEP and USEPA No further evaluation of the vapor intrusion pathway is warranted for the site

REFERENCES

Agency for Toxic Substances and Disease Registry (ATSDR 2009) Minimal Risk Levels (MRLs) Available at httpvtfwwatsdrcdcqovmrisindexhtml

Dolphin Environmental LLC (Dolphin 2000) Site Characterization Report Mach 14 2000

Johnson PC and RA Ettinger (1991) Heuristic model for predicting the intrusion rate of contaminant vapors into buildings Environ Sci Technology 25 1445-1452

Oak Ridge National Laboratory (ORNL 2009) Regional Screening Levels for Chemical Contaminants at Superfund Sites April 15 2009 Available online httpwwwepagovreg3hwmdriskhumanrb-concentration_tableindexhtm

United States Environmental Protection Agency (USEPA 1989) Risk Assessment Guidance for Superfund Volume I PartA Human Health Evaluation Manual EPA5401-89002

United States Environmental Protection Agency (USEPA 1991) Risk Assessment Guidance for Superfund Volume I Part B Development of Risk-Based Remediation Goals Office of Emergency and Remedial Response OSWER Directive 92857-018

United States Environmental Protection Agency (USEPA 2002a) Draft Guidance for Evaluating the Vapor Intrusion to Indoor Air Pathway from Groundwater and Soils Office of Solid Waste and Emergency Response Pub No 92856-10 December 2002

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United States Environmental Protection Agency (USEPA 2002b) Supplemental Guidance for Calculating Soil Screening Levels for Superfund Sites Office of Solid Waste and Emergency Response December

United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004

United States Environmental Protection Agency (USEPA 2009) Integrated Risk Information System (IRIS) On-line database wwwepaqoviris

West Virginia Department of Environmental Protection (WVDEP 2001) West Virginia Voluntary Remediation and Redevelopment Act-Guidance Manual Version 21 March 13

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AR100292

TABLES

AR100293

TABLE 1 SUBSLAB VAPOR SAMPLES INCLUDED IN THE RISK ASSESSMENT

Coyne text i le Services Facility - Huntington West Virginia

Medium

Subslab Vapor

Sample Identification

bull VP-01

VP-02

VP-03

Sample Date

8132009

8132009

8132009

Coyne VIMemo Tables_09-08-09xls 982009

AR100294

TABLE 2 IDENTIFICATION OF CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR

Coyne Textile Services Facility - Huntington West Virginia

mdash

Const i tuent

Volati le Organics

111-Trichlor6ethane

1122-Tetrachloroethane

112-Trichloro-122-trifluoroethane

112-Trichloroethane

11-Dichloroethane

11-Dichloroethene

124-Trichlorobenzene

124-Trimethylbenzene

12-Dibromoethane

12-Dichlor6benzene

12-Dichloroethane

12-Dichloroethene (cis)

12-pichloroethene (trans)

12-Dichloropropane

12-Dichlorotetraf1uoroethane

135-Trimethylbenzene

13-Butadiene

13-Dichlorobenzene

13-Hexachlorobutadiene

14-Dichlorpbenzene

224-trimethylpentane

2-Chlorotoluene

4-Ethyltoluene

Acetone

Allyl Chloride

Benzene

Bromodichloromethane

Bromoform

Bromomethane

Carbon disulfide bull

Carbon tetrachloride

ChJorobenzene

Chloroethane

Frequency of Detection

0 3

0 3

0 3

bull 0 3

0 3

0 3

0 3

1 3

0 3 bull

0 3

b 3 bull

2 3

0 3

bull 0 3

0 3

0 3

0 3 bull

0 3

0 3

0 3

0 3

0 3

0 17

3 3

0 3

P 3

- 0 3

0 3

0 3

0 3

0 3

0 3

0 3

Min imum Detected

Concentrat ion

(ugm^)

ND

ND

ND

ND

ND

- ND

N D

197

ND bull

ND

ND

369

ND

bull~ ND

ND

ND

ND

ND

ND

bull ND

ND

ND

ND

796

ND

ND

ND-

ND

ND

ND

ND

ND

ND

Maximum

Detected Concentrat ion

(ugm3)

ND

ND

ND

ND

ND

ND

ND

197

ND

ND

ND

mdash 6030

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

1880

ND-

ND

ND

ND

ND

ND

ND

ND

ND

Sample wi th Maximum Detect

ND

ND

ND

ND

ND

ND

- ND

VP-03 -

ND

ND

ND

VP-03

ND

bullND

ND

ND

ND

ND

ND

ND

ND

ND

ND

VP-02

ND

ND bull

ND

ND

ND bull

bull ND

ND

ND

ND

Min imum Detection

Limit (ugm3)

22

28

31

22

16

16

30

20

31

24

16

bull 16

16

19

28

20

89

24 bull

43

24

bull 19

2 1

20

--^ 13

13

27

41

16

13

25

18

11

Maximum Detection

Limit (ugm3)

218

275

307

218

162

159

297

197

307

240

162

- 16

159

185

280

197

89

240

427

240

187

207

197

--125

128

268

414

155

125

252

184

106

Vapor Intrusion Corhparison

V a l u e

(ugm)

22000

042

300000

15

bull 5000

2000

2000

60

011

2000

094

350

700

40

NA

60

0087

1100

11

8000

NA

NA

NA

3500

NA

31

14

22

50

7000

16

bull 600

100000

Chemical of Concern

No

No

No

No

No

No

No

YES

No

No

No

YES

No

No

No

N o bull

bullNo

No

No

No

No

No

No

N o

No

No

No

N o

No

No

No

No

No

Comment

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent notdetected

fflaximCimTdeteetlSffieedsTcomDarisonivalues

Constituent not detected

Constituent not detected

Constituent not detected

Maximum detect exceeds comparison value

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Maximum detect below comparison value

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detectedl

Constituent not detected

Constituent not detected

CoyneVI Memo Tables_09-08-09xls 982009

AR100295

TABLE 2

IDENTIFICATION OF CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR

Coyne Textile Services Facility - Huntington West Virginia

Const i tuent

Volati le Organics

Chloroform -

Chloromethane

13-Dichloropropene (cis)

Cyclohexarie^

Dibrcimochloromethane

DichlonDdifluoromethane

Ethylbenzene

Methyl ethyl ketone

Methyl isobutyl ketone

Methyl tert-butyl ether

Methylene chloride

n-Heptane

n-Hexane

Styrene

Tert-butyl alcohol

Tetrachloroethene

Toluene

13-Dichloropropene(trans)

Triehloroethene

Trichlorofluoromethane

Vinyl bromide

Vinyl chloride

Xylene (0)

Xylenes (mampp)

Frequency of Detection

1 3

0 3

0 3

1 3

0 3

0 3

0 -3

1 3

0 3

0 3

2 3

0 3

3 3

0 3

0 3

3 3

1 3

- 0 3

3 3

P 3

0 3

0 3

1 3

1 3

Min imum Detected

Concentrat ion

(ugm)

5910

ND

ND

52

ND

ND

ND

23

ND

ND

1160

ND

1 4 4

ND

ND

11200

18

ND

91

ND

ND

ND

208

387

Maximuri i Detected

Concentrat ion (ugmS)

bull

5910

ND

ND

52

bull ND

ND

ND

23

ND

ND

1520

ND

183

ND

ND

149000

18

ND

7820

ND

bullND

ND

208

387

Sample vyith Max imum Detect

VP-02

ND

ND

VP-01

bull ND

ND

ND

VP-01

ND

ND

VP-02

ND

VP-02

ND

ND

VP-02

VP-01

ND

VP-03

ND

ND

ND

VP-03

VP-03

Min imum Detection

Limit (ugm3)

20

83

18

138

34

bull 20

17

118

16

14

14

16

- -17

12

--151

18

--23

18

10

1 7 bull

1 7 bull

Maximum Detection

Limit (ugm3)

195

83

182

138

341

198

174

118

164

144

14

164

170

121 -

--151

182

225

175

102

bull 174

174

Vapor Intrusion Compar ison

V a l u e

(ugm)

11

24

NA

2000

1

2000

22

10000

800

30000

52

NA

2000

10000

NA

81

4000

NA

022

7000

NA

28

70000

70000

Chemical o f Concern

YES

No

No

No

No bull

No

No bull

No bull=

No

No

YES

No

No

No

No

YES

No

No

YES

N o

No

No

No

No

Comment

Maximum detect exceeds comparison value

Constituent not detected

Constituent not detected

Maximum detect below comparison value

Constituent not detected

Constituent not detected

Constituent not detected

Maximum detect below comparison value

Constituent not detected

Constituent not detected

Maximum detect exceeds comparison value

Constituent not detected bull

Maximum detect below comparison value

Constituent not detected

Constituent not detected

Maximum detect exceeds comparison value

Maximum detect below comparison value

Constituent not detected

Maximum detect exceeds comparison value

Constituent not detected

Constituent not detected

Constituent not detected bull

Maximum detect below comparison value

Maximum detect below comparison value

Notes

ND - Not Detected

NA - Not Available

- - Constituent detected in every sample detection limit not presented

Values in bold indicate detection limit exceeds comparison values

Target shallow soil gas comparison values corresponding to indoor air concentrations where the soil gas to indoor air attenuation factor = 01 and the target cancer risk is set to ip (presented in Table 2c of USEPA 2002a)

Comparison value for cyclohexane is based on the comparison value for hexane

Coyne VI Memo Tables_09-08-09xls 982009

AR100296

TABLES

EXPOSURE POINT CONCENTRATIONS FOR CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR

Coyne Textile Services Facility - Huntington West Virginia

Chemical of Concern

VolatileOrganics

i24-Trimethylbenzene

12-Dichloroethene (cis)

Chloroform

Methylene chloride

Tetrachloroethene Triehloroethene

Subslab Vapor Source

Concentration (mgm^)

0197

603

591

152

149 782

Transport

Factor^ (unitless)

108E-05

108E-05

108E-05

108E-05

108E-05 108E-05

EPC in

Indoor Air (mgm^)

213E-06

651 E-05

638E-05

164E-05

161E-03 844E-05

Notes

^ Subslab vapor source concentration is based on the maximum detected concentration of samples

VP-01-02 and-03 (see Table 2) -

^ Details of the transport factor calculations are presented in Appendix B

^ Exposure Point Concentration (EPC) in inidoor air is calculated as the subslab vapor concentration TF

Coyne VI Memo Tables_09-08-09xls 982009

AR100297

TABLE 4

FACTORS USED IN DOSE CALCULATIONS INHALATION OF VOLATILE EMISSIONS

Coyne Textile Services Facility - Huntington West Virginia

Symbol

CA

IRA

ET

EF

ED-

BW

AT

Exposure Factor

Constituent Concentration in Air

Inhalation Rate

Exposure Time

Exposure Frequency

Exposure Duration

Body Weight

Averaging Time

Indoor Worker

Constituent-Specific See Table 3

25 m hour

8 hrday

250 daysyear

25 years

bull 70 kg

9125 days (NC)

25550 days (C)

Total Dose = CA x IR^ x ET x EF x ED x 1BW x 1AT

(NC) - Non-carcinogenic Averaging Time

(C) - Carcinogenic Averaging Time

Coyne VI Memo Tables_09-08-09xls 982009

AR100298

TABLES TOXICITY VALUES FOR CHEMICALS OF CONCERN

Coyne Textile Services Facility - Huntington West Virginia

Chemical of Concern

Volatile Organics

124-Trimethylbenzene

12-Dichloroethene (cis)

Chloroform

Methylene chloride

tetrachloroethene

Triehloroethene

Target Organ Critical Effect

blood

bullblood

liver

liver

liver CMS

liver kidney fetus CNS

Chroniclnhalation Reference Dose

(mgkg-day)

200E-03 P

1 OOE-02 R

140E-02 E

286E-01 M

771 E-02 M

1OOE-02 E

Inhalation Cancer ^ Slope Factor

(mgkg-day)^

NA

NA

805E-02 1

165E-03 1

200E-02 0

400E-01 E

(I) - Integrated Risk Information System (IRIS USEPA 2009)

(P) - Provisional Peer-Reviewed Toxicity Value (PPRTV) as presented in USEPA Regional Screening Tables (ORNL 2009)

(R) - Calculated assuming route-to-route extrapolation as per WVDEP

(E)-Provisional value from the National Center for Environmental Assessment (as per WVDEP)

(M)-Chronic Minimal Risk Level (MRL ATSDR 2009)

(0) - Value cited by USEPA Region 3 attributed to other sources (as per WVDEP)

Coyne VI Memo Tables_09-08-09xls 982009

AR100299

TABLE 6

NONCANCER HAZARD INDEX AND POTENTIAL CANCER RISK FOR AN INDOOR WORKER

Coyne Textile Services Facility - Huntington West Virginia

bull

Constituent

Volatile Organics

124-Trinnethylbehzene

12-Dichlorpethene (cis)

Chloroform

Methylene chloride

Tetrachloroethene Triehloroethene

EPC in Indoor Air

(mgm)

213E-06

651 E-05

- 638E-05

164E-05

161 E-03

844E-05

Intake (ADD)

(mgkg-d)

416E-07

127E-05

125E-05

321 E-06

315E-04 l65E-05

RfDi

(mgkg-d)

200E-03

1OOE-02

140E-02

286E-01

771 E-02 1 OOE-02

Hazard

Quotient

208E-04

127E-03

892E-04

112E-05

408E-03 165E-03

Intake (LADD)

(mgkg-d)

) 149E-07

455E-06 bull 446E-06

115E-06

112E-04 590E-06

CSFi

(mgkg-d)

NA

NA

805E-02

165E-03

200E-02

400E-01

Potential

Cancer Risk

NA

NA

359E-07

189E-09

225E-06 236E-06

Total Hazard Index

00081 Total

Cancer Risk 497E-06

Total Blood HI = Total Liver HI =

Total Central Nervous System HI = Total Kidney HI =

Total Fetal HI =

bull 00015 00066 00057 00017 00017

Notes NA = Toxicity values are not available for this endpoint or exposure pathway

Coyne VI Memo Tables_09-08-09xls 982009

AR100300

APPENDIX A

SUBSLAB VAPOR ANALYTICAL DATA

AR100301

Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility Huntington West Virginia

Sample

Consti tuent

Volatile Organics (ugm) 111-Trlchloroethane 1122-Tetrachloroethane 112-Trichloro-122-trifluoroethane 112-Trichloroethane 11-Dichioroethane 11-Dichloroethene 124-Trichloroberi2ene 124-Trimethylbenzene 12-Dibromoethane 12-Dichloroben2ene 12-Dichloroethane 12-Dichloroethene-(cis) -12-Dichloroethene (trans) 12-Dichloropropane 12-Dichlorotetrafluoroethane 135-Trimethylbenzene 13-Butadiene 13-Dichlorobenzene 13-Hexachlorobutadiene 14-Dichlorobenzene 224-trimethVlpentane 2-Chlorotoluene 4-Ethyltoluene Acetone Allyl Chloride Benzene Bromodichloromethane Bromoform Bromomethane Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 13-Dichloropropene (cis) Cyclohexane Dibromochloromethane

Identif ication Sample Date

CAS No

71-55-6 79-34-5 76-13-1 79-00-5 75-34-3 75-35-4 120-82-1 95-63-6 106-93-4 95-50-1 107-06-2 156-59-2 156-60-5 78-87-5 76-14-2 108-67-8 106-99^0 541-73-1 87-68-3 106-46-7 540-84r1 95-49-8

622-96-8 67-64-1 107-05-1 71-43-2 75-27-4 75-252 74-83-9 75-15-0 56-23-5 108-90-7 75-00-3 67-66-3 74-87-3

10061-01-5 110-82-7 124-48-1

lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt

lt lt lt lt lt lt lt lt lt lt lt lt

lt

VP-01 8132009

22 28 31 22 16 16 30 20 31 24 16 16 16 19 28 20 89 24 43 24

1 9 21 20 796 13 13 27 41 16 13 25 18 11 20 83 18 52 34

lt lt lt lt lt lt lt lt lt lt lt

lt lt lt lt lt lt lt lt lt lt lt

lt lt lt lt lt lt lt lt lt

lt lt lt lt

VP-02 8132009

218 2 7 5 307 218 162 159 297

bull 197 307 240 162 369 159 185 280 197 89

240 427 240 187 207 197

1880 125 128 268 414 155 125 252 184 106

5910 83 182 138 341

lt lt lt lt lt lt lt

lt lt lt

lt lt lt lt lt lt lt bull

lt lt lt lt

lt lt lt lt lt lt lt lt lt lt lt lt lt lt

VP-03 8132009

218 275 307 218

bull 162 159 297 197 307 240 162

6030 159 185 280 197 89

240 427 240 187 207 197

1750 125 128 268 414 155 125 252 184 106 195 83 182 138 341

Appx A SG Dataxis Page 1 of 2 982009

AR100302

Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility bull Huntington West Virginia

Consti tuent

Volatile Organics (ugm^) Dichlorodifluoromethane Ethylbenzene Methyl ethyl ketone Methyl Isobutyl ketone Methyl tert-butyl ether Methylene chloride n-Heptane jn-Hexane Styrene Tert-butyl alcohol Tetrachloroethene iToluene 13-Dichloropropene (trans) Triehloroethene Trichlorofluoromethane Vinyl bromide Vinyl chloride Xylene (o) Xylenes (mampp)

Sample Identif ication Sample Date

CAS No

75-71-8 100-41-4 78-93-3 108-10-1

1634-04-4 75-09-2

142-82-5 bull 110-54-3

100-42-5 75-65-0 127-18-4 108-88-3

10061-02-6 79-01-6 75-69-4 593-60-2 75-01-4 95-47-6

179601-23-1

lt lt

lt lt lt lt

lt lt

lt

lt lt lt lt lt

VP01 8132009

20 17 23 16 14 14 16

173 17 12 bull

11200 18 18 91 23 18 10 17 17

lt lt lt lt lt

lt

lt lt

lt lt

lt lt lt lt lt

VP-02 8132009

198 174 118 164 144

1520 164 -183 170 121

149000 151 182

2360 225 175 102 174 174

VP-03 8132009

lt 198 lt 174 lt 118 lt 164 lt 144

1160 lt 164

144 lt 170 ltbull 121

90500 lt 151 lt 182

7820 lt 225 lt 175 lt 102

208 387

Appx A SG Dataxis Page 2 of 2 982009

AR100303

APPENDIX B

CALCULATION OF TRANSPORT FACTORS USED TO ESTIMATE INDOOR AIR CONCENTRATIONS

AR100304

APPENDIX B

Calculation of Transport Factors Used to Estimate Indoor Air Concentrations

This appendix presents the methodology for calculating transport factors that are used to convert subslab

vapor concentrations to concentrations in indoor air 124-Trimethylbenzene 12-dichloroethene (cis)

chloroform methylene chloride tetrachloroethene and triehloroethene were identified as contaminants of

concern (COC) for potential vapor intrusion from subslab vapor associated with the Coyne Textile

Services Facility located in Huntington West Virginia (site) In this appendix the transport factors are

calculated to estimate the concentrations of COC in indoor air of the existing plant building located at the

site ~

Transport Factor for Indoor Air

The concentration of a constituent in indoor air (da) is proportional to the concentration of the constituent

in the subslab vapors immediately beneath the building foundation (ie subslab vapor concentration or

Csubsiab) The following equation is used to calculate da from Csubsiab

^ wja ~ ^subslab X I r

where

Cia = concentration of constituent in indoor air (mgm^) -

Csubsiab^ concentration of constituent in subslab vapors (mgm^) and

TF = transport factor from subslab vapors to indoor air

The transport factor (TF) is an infinite source attenuation coefficient andcan be calculated based on a

model developed by Johnson and Ettinger (1991) t he equation for calculating TF is as follows

(Deff X A B ) ( Q B X L T ) X expKQso i l X Lcrabk)(Dcrack X Acrack)]

exp[ (Qsoi l X Lcrack)(Dcrack X Acrack)] + (Deff X A B ) ( Q B X L T ) + (Deff X AB)(Qsoi l X L j ) X (exp [ (Qso i l X Lcrack)(Dcrack X Acrack)] - 1)

where

Deff = effective diffusion coefficient for vadose zone soil (cm^sec)

AB = area of enclosed space below grade (cm^)

QB = building ventilation rate (cm^sec)

LT = distance from contaminant source to building foundation (cm)

Qsoii = volumetric flow rate of vapors into the building (cm^sec)

Lcrack = foundatlon thickness (cm)

Dcrack = vapor diffusion coefficient through crack (cm^sec) and

Acrack = area of cracks through which vapors can pass (cm^)

AR100305

To solve this equation the USEPAs SG-ADV spreadsheet Version 31 most recently updated in

February 2004 was implemented A combination of site-specific factors and default values from the

Users Guide for Evaluating Subsurface Vapor Intrusion Into Buildings (USEPA 2004) were used as input

values in the model All input values are defined below and presented in Tables B-1-A through B-6-A

bull The initial subslab vapor concentration (Csubsiab) is the maximum detected concentration(in units

of ugm ) of samples VP-01 VP-02 and VP-03 that was presented in Table 3 of the report

bull The depth below grade to the bottom of the enclosed space floor (Lp) is set to 15 cm the default

value provided by USEPA (2004) for a slab-on-grade structure

bull The vapor sampling depth below grade (Lg) is a site-specific value The vapor samples were

collected from immediately beneath the building floor therefore Lj has been set to 15 cm

bull The average soilgroundwater temperature (Ts) is set to 125degC the average value for West

Virginia as estimated frorri Figure 8 of the vapor intrusion users guide (USEPA 2004)

bull The soil type used to estimate vapor permeability is assumed to be sandy loam (SL) The

associated soil properties for a sandy loam soil type are as follows the soil dry bulk density (Pb) is

162 gcm the total porosity (n) is 0387 (cm^-aircm^) and the water-filled porosity (nw) is 0103

(cm -HzOcm )

bull The floor thickness (Lcrack) is set to the USEPA (2004) default value of 10 cm

bull The soil-building pressure differential (AP) is set to the USEPA (2004) default value of 40 gcm-s^

bull The building dimensions are siterspecific based on the existing plant building located at the site

The existing structure is approximately 84000 square feet (Dolphin 2000) therefore the

dimensions are set to 8839 cm (290 feet) length by 8839 cm (290 feet) The USEPA (2004)

default value of 244 cm vyas used for the height

bull Thefloor-wall seam crack width (w) is set to the USEPA (2004)-default value of 01 cm

bull The indoor air exchange rate (ER) is set to 083hour This is the value provided by ASTM (2002)

for commercial and industrial buildings

AR100306

Tables B-1-B through B-6-B present the constituent-specific properties for COC that were used in the TF

calculations Tables B-1-C through B-6-C present the intermediate calculations used to determine the

indoor air attenuation coefficients (ie the transport factors) The shaded boxes in Tables B-1-C through

B-6-C also present the resulting TF values that are applied to the concentrations of COC in subslab

vapor and the estimated indoor air concentrations

References

American Society for Testing and Materials (ASTM 2002) Standard Guide for Risk-Based Corrective Action Applied at Petroleum Release Sites ASTM E-1739-95 (Reapproved 2002)

Johnson PC and RA Ettinger (1991) Heuristic model for predicting the intrusion r-ate of contaminant vapors into buildings Environ Sci Technolpgy 25 1445-1452

Dolphin Environmental LLC (Dolphin 2000) Site Characterization Report Mach 14 2000

United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004

AR100307

APPENDIX B-1-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV Nersion31 0204

Reset to Defaults

ENTER -

Chemical CAS No

(numbers only

no dasties)

95636

ENTER Soil gas

cone

Cg (ngm)

Soil Gas Concentration Data ENTER

Soil gas

OR cone

bull - c bull (PPmv)

197E+02

Chemical

124-Trimethylbenzene

MORE ENTER Depth

below grade to bottom

of enclosed space floor

U bull (cm)

ENTER

Soil gas sampling

depth below grade

U (cm) bull

ENTER

Average soil

temperature Ts

CO

1 15 1 1 5 bull125

ENTER ENTER ENTER Totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hft ha he

(cm) (cm) (cm)

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estirnate OR permeability | soil vapor

permeability) k v bull

(cm)

SL 1 1

MORE ENTER

stratum A SCS

soil type

Lookup Soil Parameters

ENTER stratum A soil dry

bulk density P

(gcm)

ENTER Stratum A soil total porosity

(unitless)

ENTER bull stratum A soil water-filled

porosity

(cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

nlaquo

(unitless)

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gchi-s^)

ENTER Enclosed

space floor

length bull LB

(cm)

ENTER Enclosed

space floor

width WB

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

bull Floor-wall seam crack

width w

(cm)

bullENTER

Indoor air exchange

rate ER

(1h) bull

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bidg OR

Leave blank to caicuij

(Lm)

Appx B-1 124-TMBxls 1 of 3 982009

AR100308

APPENDIX B-1-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of ^ bull law constant law constant vaporization at Normal

Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temperature boiling point point temperature weight

D bull Dbdquo H T R bull AHbdquo TB Tc IVIW

Unit risk Reference

factor cone URF RfC

(cms) (cmls) (atm-mmol) CO (calmol) (degK) (degK) (gmol) bull (ugm)- (mgm)

1 606E-02 1 792E-06 1 bull 614E-C3 1 25 1 9369 1 44230 | 64917 1 12020 1 OOE+00 1 60E-03 1

Appx B-1 124-TMBxls 2 of 3 982009

AR100309

APPENDIX B-1-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

(sec)

Source-building

separation

LT bull

(cm) bull

Stratum A soil

air-filled porosity

Q A

Stratum B soil

air-filled porosity

(cmcm) (cmcm)

Stratum C soil air-filled porosity

(cmcm)

Stratum A effective total fluid

saturation

Se

(cmcm)

Stratum A soil

bullintrinsic permeability

^ (cm)

stratum A Stratum A Floor- soil soli wall BIdg

relative air effective vapor seam Soil bull ventilation permeability permeability perimeter gas rate-

kfg ky Xgrack c o n e - QbuHdinpound

(cm) - (cm) (cm) (ngm) (cms)

946E+08 1 0284 0284 0284 0184 596E-09 0901 537E-09 35357 I 197E+02 | 439E+06 |

Area of enclosed

space below grade

As (cm)

Crack-to-total area ratio

1 bull

(unitless)

Crack depth

below grade

Zcfack

(cm)

Enthalpy of vaporization at

ave soil temperature

AHvjs

(calmol) bull

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law constant at

ave soil bull temperature

bull HTS

(unitless)

Vapor bull viscosity at

ave soil temperature

HTS

(gcm-s)

Stratum A

effective diffusion

coefficient

D (cms)

Stratum-B

effective diffusion coefficient

DB (cms)

Stratum C effective diffusion

coefficient

D-c (cms)

Total - overall effective diffusion

coefficient

D ^ (cms)

Diffusion path

length

L-

(cm)

I 787E+07 I 449E-05 | 15 | 11661 260E-03 111E-01 176E-04 I 612E-03 j OOOE+00 | OOOE+00 | 612E-03 j

bull Convection path

length

Lp

(cm)

Source vapor cone

^source

(ngm)

Crack radius

Tcfack

(cm)

Average vapor

flow rate into bIdg

Qsoii

(cms)

Crack effective diffusion

coefficient pcrack

(cms)

Area of CTack

Acack

(cm)

Exponent of equivalent foundation

Peclet number

exp(Pe)

(unitless)

bull bull - bull bull bull bull

1 15 1 197E+02 1 010 1 474E+01 612E-03 bull 354E-t-03 1 336E+09

Infinite source Indoor

~ attenuation coefficient

a

(unitless)

108E-05

Infinite source

btJbldgjJSv-L ^Ppncji3i-

virhpbiiilding bullbull ^lHltti^m)ilg

213E-03

Unit risk

factor

URF

(ngm)-

Reference cone

RfC (mgm)

NA 60E-03 1

I END

Appx B-1 124-TMBxls 3 of 3 982009

AR100310

APPENDIX B-2-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV Nersion31 020^

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

156592

Soil Gas Concentration Data ENTER

Soil gas

cone OR c

(ngm) bull

ENTER Soil bull-gas

cone

c (ppmv)

603E+03 1

Chemical

cis-12-Dichloroethylene

MORE ENTER Depth

below grade to bottom

of enclosed space floor

LF

(cm)

ENTER

Soil gas sampling

depth below grade

U (cm)

ENTER

Average soil

temperature bull Ts

(degC)

1 15 1 bull 15 125

ENTER ENTER ENTER Totalsmust add ijp tb value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hA hB he

bull (cm) (cm) (cm)

15 1 1

ENTER Soil

straturh A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estimate OR permeability | soil vapor

permeability) kv

(cm)

SL 1 |

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

P (gcm)

ENTER Stratum A soil total porosity

bull n

(unitless)

ENTER Stratum A

soil water-filled porosity

(cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

ENTER Stratum B

soil water-filled porosity

ENTER Stratum C

SCS soil type

(unitless) (cmcm)

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure differential

AP

(gcm-s)

ENTER Enclosed bull

space floor

length

LB (cm)

ENTER Enclosed

space floor

width WB

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER

Average vapor flow rate into bIdg

OR Leave blank to calculi

Qsoil

(Lm)

Appx B-2 cis-12-DCExls 1 of 3 982009

AR100311

APPENDIX B-2-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Diffusivity in air

Da

(cms)

Diffusivity in water

Dw (cms)

Henrys law constant at reference temperature

H

(atm-mmoi)

Henrys law constant

reference temperature

bull T R

CC)

Enthalpy of vaporization at

the normal boiling point

AHbdquob

(calmol)

Normal boiling point

TB

(degK)

Critical temperature

Tc (degK)

Molecular weight

MW

(gmol)

Unit risk

factor URF

(ngm)

Reference cone

RfC (mgm)

1 736E-02 1 113E-05 1 407E-03 j 1 25 1 bull 7192 1 33365 1 54400 1 9694 1 OOE+00 j 35E-02 1

Appx B-2 cis-12-DCExls 2 of 3 982009

AR100312

APPENDIX B-2-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

stratum A Stratum B Stratum C Source- soil soil soil

Exposure building air-filled air-filled air-filled

duration separation porosity porosity porosity

T LT ea e^ bull e= (sec) (cm) (cmcm) (cmcm) (cmcm)

I 946E+08n^

Stratum A Stratum A Stratum A Stratum A Floor-effective soil soil soil wall total fluid intrinsic relative air effective vapor seam

saturation permeability permeability permeability perimeter

Ste kj krg ky Acrack

(cmcm) (cm) (cm) (cm) (cm)

Soil gas

cone (ngm)

I 0284 I 0284~ 0284 0184 I 596E-09 | 090T 537E-09 35357 603E+03

BIdg ventilation

rate

JbulldinE

(cms)

439E+06

Area of enclosed

space below grade

AB

(cm)

Crack-to-total

area ratio

n (unitless)

Crack depth below grade

Zltiack (cm)

Erithalpy of vaporization at

ave soil temperature

AHvTs (calmol)

Henryslaw constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law constant at

ave soil temperature

HTS

(unitless) bull

Vapor viscosity at

ave soil bull temperature

HTS

bull (gcm-s)

Stratum A

effective bull diffusion

coefficient

D^A-(cms)

Stratum B

effective bull diffusion

coefficient

D=B

(cms)

Stratum C

effective diffusion bull

coefficient

D=e (cms)

Total overall

effective diffusion

coefficient

DT

(cms)

Diffusion path

length

Ld

(cm)

I 787E+07 I bull449E-05 | 15 bull7709 230E-03 982E-02 176E-04 | 743E-03 | OOOE+00 | OOOE+00 | 743E-03 |

bull bull bull -

Convecfion path -bull

length

Lp (cm)

Source vapor cone

-source

(Mgm)

Crack radius

fcrack

(cm)

Average vapor

flow rate into bIdg

Qaoil bull

(cms)

Crack effective diffusion

coefficient pcack

(cms)

Area of crack

crack

(cm)-

Exponent of equivalent foundation

Peclet number

exp(Pef)

(unitless)

bull

1 15 -1 603E+03 1 010 1 474E+01 743E-03 354E+03 1 697E+07

Infinite source Indoor

attenuation coefficient

poundbullbullbull C t

pound(unitless)

bullsiilaquogt j ii08E-05

Infinite [ source

bIdg cone

Cbujidjng

(pgm)

651 E-02 iKrt

Unit risk

factor

URF

(ngm)-

Reference cone

RfC

(mgm)

NA 35E-02 1

I END I

Appx B-2 cis-12-DCExls 3o f3 982009

AR100313

APPENDIX B-3-A DATA ENTRY SHEET

Coyne Texti le Services - Hunt ington West Virginia

SG-ADV Version 31 0204

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

67663

Soil Gas Concentration Data ENTER ENTER

Soil Soil gas gas

cone OR cone c C

(^gm) (ppmv)

591 E+03

bull

Chemical

Chloroform

MORE ENTER Depth

below grade tb bottom

of enclosed space floor

bull LF

(cm)

ENTER

Soil gas sampling depth

below grade

(cm)

ENTER

Average soil

temperature-Ts

CO bull

1 15 1 15 1 125

ENTER ENTER ENTER Totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

IIA hs he (cm) (cm) (cm)

1 5 bull 1 1

ENTER ENTER Soil - bull

stratum A User-defined SCS stratum A

soil type bull soil vapor (used to estimate OR permeability

soil vapor k

bull permeability) (cm) 1

SL 1 1 bull

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A soil dry

bulk density

Pb (gcm)

ENTER Stratum A soil total porosity

nV (unitless)

ENTER Stratum A

-soilwater-filled bullporosity

Sraquo (cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

(unitless)

ENTER Stratum B

soil water-filled porosity

bull ebdquo=

(cmcm) bull

ENTER Straturri C

SCS bull soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

- c rack

(cm)

ENTER

Soil-bldg pressure

differential AP^

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor

width bull W B

(cm)

ENTER

Enclosed space

height HB

(cm)

ENTER

bull Floor-wall^ seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bidg OR

Leave blank to calculi

Qsoil bull

(Lm)

I -I

Appx B-3 Chloroformxls 1 of 3 982009

AR100314

APPENDIX B-3-B CHEMICALPROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Diffusivity in air

D (cms)

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffijsivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature

Dbdquo H TR A H bdquo TB Tc

(cm s) (atm-m mol) ro (calmol) (degK) (degK)

Molecular weight

MW

(gmol)

Unit risk

factor URF

(ngm)-

Reference cone

RfC

(mgm)

104E-01 100E-05 I 366E-03 25 6988 33432 53640 11938 I 23E-05 | OOE+00

Appx B-3 Chloroformxls 2 of 3 982009

AR100315

APPENDIX B-3-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure

duration

(sec)

Source-

building

separation

LT

(cm)

Stratum A

soil

air-filled

porosity

Sa

( cm cm )

Stratum B

soil

air-filled

porosity

( cm cm )

Stratum C

soil

air-filled

porosity

( c m c m )

Stratum A

effective

total fluid

saturation

( c m c m )

Stratum A

soil

intrinsic

penmeability

k

(cm )

Stratum A

- soil

relative air

permeabil i ty

(cm )

Stratum A

soil

effective vapor

permeability

kv

(cm )

Floor-

wall

seam

perimeter

gtcrack

(cm)

Soil gas

cone

(ngm)

BIdg

venfilation

rate

^buildlriE

(cms)

I 9 4 6 E + 0 8 ~ T I 0284 T 596E-09 I 0-901 I 537E-09 | 35357 | 591 E+03 j 439E+06 | 1 0 284 0284 0184

Area of

enclosed

space

below

grade

A B

( c m )

Crack-

to-total

area

ratio

n

(unitless)

Crack

depth

bull below

grade

^crack

(cm)

Enthalpy of

vaporization at

ave soil

temperature

AHTs bull

(calmol)

Henry s law

constant at

ave soil

temperature

HTS

(a tm-m mol j

Henrys law

constant at

ave soil

bull temperature

HTS

(unitless) bull

Vapor

viscosity at

ave soil-

temperature

^HTS

(gcm-s)

Stratum

A

effective

diffusion

coefficient

(cm s)

Stratum

B

effective

difftjsion

coefficient

D B

(cms) bull

S t ra tum

C

effective

diffusion

coefficient

Dc

(cm s)

Total

overall

effective

bull diffusion

coefficient

D T

(cm s)

Diffi jsion

path

length

Ld

(cm)

I 787E+07 I 449E-05 j - bull 15 7528 210E-03 896E-02 176E-04 I 105E-02 | OOOE+00 | OOOE+00 | 105E-02

Convection

path length

Lp

(cm)

Source

vapor

cone -

^source

- (ngm)

Crack

radius

Tcrack

(cm)

Average

vapor

flow rate

into bidg

Qsoil

(cms)

Crack

effective

diffusion

coefficient Qcrack

bull (cms)

Area of crack

Acrack

(cm)

Exponent of

equivalent

foundation

Peclet number

exp(Pe)

(unitless)

V bull bull

1 15 1 591 E+03 1 010 1 474E+01 105E-02 354E+03 1 355E+05

Infinite

source

indoor

attenuation

coefficient

d

(unitless)

bull 108E-05

Infinite

source

bIdg

cone

^ b u i l d i n g

i (^gm)

bull bull

i 638E-02 -

Unit

risk bull factor

URF

(ngmY

Reference

cone

RfC

(mgm)

~ 23E-05 NA 1

I END

Appx B-3 Chloroform xls 3 of 3 982009

AR100316

APPENDIX B-4-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ersion 31-020^

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

nodashes)

bull 75092

ENTER Soil gas

cone

c (ngm)

Soil Gas Concentration Data ENTER

Soil gas bull

OR cone

bull C

(ppmv)

152E+03

bull bull

Chemical

Methylene chloride

MORE

MORE 4gt

ENTER Depth

below grade to bottom

of enclosed space floor

LF -

(cm)

ENTER

Soil gas sampling depth

below grade

bull U

(cm)

ENTER

Average soil

temperature

Ts bull CC)

bull bull bull bull

1 15 1 15 125

ENTER Totals

Thickness of soil

stratum A h

(cm)

ENTER ENTER must add up to value of Ls (cell F24

Thickness Thickness of soil of soil

stratum B stratum C (Enter value or 0) (Enter value or 0)

he he bull

(cm) bull (cm) -

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(usedto estimate OR perrrieability | soil vapor

permeability)

k bull

(cm)

SL 1 bull 1

ENTER Stratum A

SCS soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

Pb (gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Stratum A

soil water-filled porosity

9w (cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

Pb^

(gcm)

ENTER Stratum B soil total porosity

n^

(unitless)

ENTER Stratum B

soil water-filled porosity

(crhcm)

ENTER Stratum C

SCS soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE 4gt

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

bull Soil-bldg pressure

differential AP^

(gcm-s)

ENTER Enclosed

space floor

length LB

(cm)

ENTER Enclosed

space floor

width bull W B

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width

w

(cm)

ENTER

Indoor air exchange

rate

ER (1h)

ENTER Average vapor

flow rate into bidg OR

Leave blank to calculc

Qsoil

(Lm)

10 40 8839 8839 244 01 083

Appx B-4 MCxIs 1 of 3 982009

AR100317

Diffijsivity in air

D

APPENDIX B-4-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffusivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature

Pw H TR AHt TB TC

Molecular weight

MW

Unit risk

factor URF

Reference cone

RfC

(cms) (cms) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) bull (ngm)- (mgm)

bull bull

1 101E-01 1 117E-05 1 218E-03 1 25 | 6706 1 31300 1 51000 1 8493 1 47E-07 1 30E+00 1

Appx B-4 MCxIs 2 of 3 982009

AR100318

APPENDIX B-4-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

T

(sec)

Source- -building

separation

LT

(cm)

Stratum A soil

air-filled porosity

e a bull

(cmcm)

Stratum B soil

bullair-filled porosity bull

ea^ (cmcm)

Stratum C soil

air-filled porosity

ea= (cmcmj

Stratum A effective total fluid

saturation

Sc bull

(cmcm)

Stratum A soil

intrinsic pemneability

ki (cm)

Stratum A soil

relative air permeability

^ ^ g

(cm)

stratumA bull soil effective vapor permeability

K (cm)

Floor-wall

seam perimeter

Xcrack

(cm)

Soil gas

cone (ngm)

BIdg ventilation

rate

Qbuildinc

(cms)

1 946E+08

Area of -enclosed

space below

bull grade

AB

(cm)

1

Crack-to-total

area rafio

Tl

(unitless)

0284 1

Crack depth below grade

Zcrack

(cm)

0284 1

bull Enthalpy of vaporization at

ave soil temperature

AHTs (calmol)

0284

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

0184

Henrys law constant at ave soil

temperature

HTS

bull (unitless)

1 596E-09

Vapor viscosity at

ave soil temperature

Mrs (gcm-s)

0901

Stratum A

effective diffusion

coefficient

D (cms)

537E-09

Stratum B

effective diffusion

coefficient

D-B (cms)

35357 1

Stratum C -

effective diffusion

coefficient

D-c ^ (cms)

152E+03

Total bull overall

bull effective diffusion

coefficient

D ^

(cms)

440E+06 1

Difftjsion path

length

Ld (cm)

1 787E+07

Convection path

length

Lp (cm)

4 49E-05

Source vapor cone

Csource

(ngm)

15 1

Crack radius

Tcrack

(cm)

7007 bull 1

Average vapor

flow rate intobldg

Qsoil

(cms)

130E-03

Crack effective diffusion

coefficient pcrack

(cms)-

555E-02

bull ^

Area of crack

Acrack

(cm) bull

1 176E-04

Exponent of equivalent foundation

Peclet number

exp(Pe)

(unitless) bull

bull bull

1 15

1 END

152E+03 010 1 474E+01 1 102E-02 354E+03 1 519E+05

102E-02

Infinite source

indoor ^attenuation coefficient

bull a

(unitless)

aiii08E-05

0 OOE+00

bull

Infinite bull source

bIdg ^ cone

^bu i l d i ng

(MQm)

164E-02

OOOE+00 1

Unit risk

factor

URF

(ngm)-

47E-07 1

102E-02 j

Reference cone

RfC

(mgm)

30E+00 j

1 1

Appx B-4 MCxIs 3 of 3 982009

AR100319

APPENDIX B-5-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ^erslon 31 0204

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

127184

Soil Gas Concentration Data ENTER ^ ENTER

Soil -Soi l bull gas gas

cone OR cone Cg C bull

(tgm) (ppmv)

149E+05 1

Chemical

bull Tetrachlbroethylene

MORE 4

ENTER Depth

below grade to bottom

ofenclosecJ space floor

LF

(cm)

ENTER

Soil gas bull sampling

depth below grade

u bull (cm)

ENTER

Average bullsoil

temperature - Ts

ro 1 1 5 1 15 1 125 bull

ENTER ENTER ENTER totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hft bull he bull he

(cm) (cm) (cm)

bull 1 5 1 - 1

ENTER ENTER Soil

stratum A User^defined bull SCS bull stratum A soil type soil vapor

(used to estimate OR perrrieability soil vapor K bull

permeability) (cm) 1

SL 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

Pb

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Sitratum A

soil water-filled bull porosity

(cmcm)

ENTER Stratum B

SCS soiltype

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

Pb^

(gcm)

ENTER Stratum B soil total porosity

Ajnitless^

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS soil type

LookupSoil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

VS

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor width

W B

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width

w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

ENTER Average vapor

flow rate into bidg OR

Leave blank to calcul

bull Qsoil

(Lm)

10 40 8839 8839 244 01 083

Appx B-5 PCExIS 1 of 3 982009

AR100320

APPENDIX B-5-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal Unit

Diffusivity Diffusivity at reference reference the riormal boiling Critical Molecular risk Reference in air in water temperature temperature boiling point point teriiperature weight factor cone

Da Dbdquo H TR AHb TB Tc MW URF RfC

(cms) (cnis) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) (^gm)- (mgm)

1 720E-02 1 820E-06 1 184E-02 1 25 1 8288 1 39440 1 62020 1 16583 1 59E-06 1 60E-01 1

J

AppxB-5PCExls 2 of 3 - 982009

AR100321

APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

T

(sec)

Source-building

separation

LT

bull (cm)

Stratum A soil

air-filled porosity

Oa (cmcm)

Stratum B - soil air-filled porosity

ea (cmcm)

Stratum C soil

air-filled porosity

ea= - (cmcm)

Stratum A effective total fluid

saturation

sbdquo (cmcm)

Stratum A soil

intrinsic permeability

ki (cm)

Stratum A soil

relative air permeability

- ^ g

(cm)

Stratum A soil

effective vapor permeability

kv (cm)

Floor-wall

seam perimeter

^crack

(cm)

Soil gas

cone

(ngm)

BIdg venfilation

rate

Qbuildins

bull (cms)

bull bull

1 946E+08

Area of enclosed

space below grade

AB

(cm)

1

bullCrack-to-total

area ratio

1 (unitless)

0284 1

Crack bull depth below grade

Zcrack

(cm) -

0284 1

Enthalpy of vaporization at bull

ave soil temperature

bull A H V TS

(calmol)

0284

Henrys law constant at

ave soil temperature

HTS (atm-mmol)

0184

-Henrys law constant at

ave soil temperature

HTS

(unitless)

1 596E-09

Vapor viscosity at

ave soil temperature

HTS

(gcm-s)

0901

Stratum A

effective diffusion

coefficient bull D = bull

(cms)

537E-09

Stratum B

effective diffusion

coefficient

D--B (cms)

35357 1

Stratum C

effective diffusion bull

coefficient

D-c (crris)

149E+05

Total overall

effective bulldiffusion coefficient

DT

(cms)

440E+06 1

Difftjsion path

length

U (cm)

1 787E+07

Convection path

length

bull Lp

(cm)

4 49E-05

Source vapor cone

^source

(ngm)

15 1

Crack radius

Tcrack

(cm)

9528 1

Average vapor

flow rate intobldg

Qsoil (cms)

908E-03

Crack effective diffusion

coefficient pcrack

bull ( c m s ) bull

387E-01

Area of crack

Abdquoack (cm)

1 176E-04

Exponent of equivalent foundafion

Peclet number

exp(Pe)

(unitless)

bull

1 15-

1 END

149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08

727E-03

Infinite source indoor

attenuation coefficient

a

(unitless)

108E-05

OOOE+00

Infinite source

bIdg cone

Cburldtng

(Mgm)

161 E+00

OOOE+00 1

Unit risk

factor

URF

(ugm)-

59E-06 1

727E-03

Reference cone

RfC (mgm)

60E-01

1 1

Appx B-5 PCExls 3 of 3 982009

AR100322

APPENDIX B-6-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ersion31 0204

Reset to Defaults

t

Soil Gas Concentration Data ENTER

Chemical CAS No

(numbers only

no dashes)

79016

ENTER ENTER Soil Soil gas gas

cone OR cone C C -

bull (ngm) (ppmv)

782E+03

Chemical

Trichloroethylene

MORE ENTER Depth

below grade to bottom-

of enclosed space floor

LF

(cm)

ENTER

Soil gas sarnpling

depth below grade

U (cm)

ENTER

Average soil

temperature Ts

(degC)

1 15 1 15 t 125

ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e

(cm) (cm) (cm)

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estimate OR permeability soil vapor

permeability)

k (cm)

bull S L 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil bull-Parameters

ENTER Stratum A

soil dry bulk density

P b -

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Stratum A bull

soilwaterrfilled porosity

(cmcm) bull

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

bull P ^ (gcm)

ENTER Stratum B soil total

porosity

nlaquo

(unitless) -

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS bull soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor

width W B

(cm)

ENTER

Enclosed space height

H B bull

( c m ) bull

ENTER

Floor-wall seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bIdg OR

Leave blank to calculc

Qsoil

(Lm) -

Appx B-6 TCExIs 1 of 3 982009

A

AR100323

APPENDIX B-6-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight

Da Dbdquo H TR AH^b TB TC MW

Unit risk Reference

factor cone URF RfC

(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)

1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1

Appx B-6 TCExIs 2 of 3 982009

AR100324

APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

(sec)

Source-building

separation LT

(cm)

Stratum A soil

air-filled porosity

bull ea (cmcm)

Stratum B Soil

air-fllled porosity

e^ bull (cmcm)

Stratum C soil

air-filled porosity

(cmcm)

StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air

saturation permeability permeability

S|e k krg (cmcm) (cm) (cm)

Stratum A Floor-soil wall BIdg

effective vapor seam Soil ventilafion permeability perimeter gas rate

k^ bull Xack c o n e Qbuildins

(cm) (cm) (ngm) (cms)

946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |

Area of enclosed

space below grade

AB

(cm)

Ciack- to-total

area ratio

1 (unitless)

Crack depth below grade

Zcrack

(cm)

Enthalpy of vaporization at

ave soil temperature

A H J S

(calmol)

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law bull constant at

ave soil temperature

HTS

(unitless)

Vapor viscosity at

ave soil temperature

|JTS

(gcm^s)

Stratum A

effective diffusion

coefficient

(cms)

Stratum B

effective -diffusion

coefficient

D=B (cms)

Stratum ^ C effective diffusion

coefficient

D=c (cms)

Total overall

effective diffusion

coefficient

DT

(cms)

I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03

Diffusion path

length

Li (cm) bull

Convection bull path

length

Lp

(cm)

Source vapor cone bull

^source

(ngm)

Crack radius

rcrack

(cm)

Average vapor

- flow rate intobldg

Qsoil

(cms)

Crack effective diffusion

bull coefficient Qcrack

(cms)

Area of crack

^crack

(cm)

Exponent of equivalent foundation

Peclet bull number

exp(Pe)

(unitless)

bull bull

1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07

Infinite source Indoor

attenuation coefficient

a

(unitless)

108E-05

Infinite source

bIdg concgt

^building

(ngm)

844E-02

Unit risk

factor

URF

(ngm)-

Reference cone

RfC

(mgm)

1 1E-04 1 40E-02 1

END

Appx B-6 TCExIs 3 of 3 982009

AR100325

Office of Waste Management 1356 Hansford Street

Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256

West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director

ORDER

ISSUED UNDER THE

HAZARDOUS WASTE MANAGEMENT ACT

CHAPTER 22 ARTICLE 18

OF THE WEST VIRGINIA CODE^ AS AMENDED

y Order Number HW-011-80

To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704

ATTEMTION MREDARMON

Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull

AR100326

ViWJ011-laquo9 PageNunil)er2

BASIS FOR ORDER

As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following

A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^

B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator

C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities

0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94

^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement

P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following

1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater

2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was

^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment

CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable

CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order

AR100327

H W - 0 1 1 - 9 9 Page Number 3

REQUIREMENTS OF ORDER

Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows

1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^

2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore

remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling

GENERAL PROVaiONS

1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order

2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order

3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order

Effective Date

Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief

Wt T 1 V Oflice of Waste Management

AR100328

^ ^ S I S

^wmmmmamn

AR100329

Page 9: SDMS DocID 2121999 · International Enterprises Corp. building (Coyne Building), which is located at 1111 Vernon Street, Westmoreland District, Wayne County, West Virginia. The following

Table 1 Laboratory Analytical Summary - Groundvvater WCEDA Vernon street

Huntington Wayne County West Virginia

COPC

Acetone Benzene Bromobenzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone sec-Butylbenzene n-Butyibenzene tert-Butylbenzene Carbon disulfide Carbon Tetrachloride Chlorobenzene Chlorodibromorriethane Ghloroethane Chlbroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene 12-Dibromo-3-chloropropane 12-Dlbronnoethane (EDB) DIbromomethane 14-Dichlorobenzene 13-Dictilorobenzene 12-Dictilorobenzene Dichlorodifluoromethane 11-Dlchloroethane 12-Dichloroethane cis-12-Dichloroethene

MCL ugL

5500 5

NV NV NV 85 87

700 61 61 61

1000 5

100 NV 39

bull 017 190 NV NV 02

005 NV

750 600 600 390 910

5 70

GP-1 ugL ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND

ND ND ND ND ND ND ND ND ND ND ND ND 112 ND

5210

GP-2 ugL ND ND ND

ND ND ND ND ND ND ND ND ND ND ND ND ND ND

062 J ND ND ND

ND ND ND ND ND ND ND ND

379

GP-3 ^ ugL

ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND

065 J ND 184 ND( ND ND ND

ND ND ND ND ND ND ND

12500

GP-4 ugL ND ND ND ND ND

- ND ND ND ND ND ND ND ND ND ND ND ND ND

ND ND ND ND ND ND ND ND ND ND ND 132

GP-5 ugL ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND

ND ND ND ND ND ND ND ND ND ND ND ND 59

Notes - Bold Indicates COPCs detected at concentrations greater than the MCL bull(60CSR3 Table 60-3B July 2008)

NAME - J indicates analyte detected at levels less than the reporting limit and greater than

or equal to the MDL value is estimated -NV indicates no value has been established

AR100286

Table 1 Laboratory Analytical Summary - Groundwater (Continued) WCEDA Vernon street

Huntington Wayiie County West Virginia

COPC

11-Dichloroethene trans-12-Dichloroethene 13-Dichloropropane 12-Dichloropropane 22-Dichloropropane cis-13-Dichloropropene trans-13rDichloropropene 11-Dichloropropene Ethylbenzene Hexachlorobutadiene 2-Hexanone Isopropylbenzene p-lsopropyltoluene Methyl tert-Butyl Ether Methylene Chloride 4-Methyl-2-pentanone Naphthalene n-Propylbenzene Styrene 1112-Tetrachloroethane 1122-Tetrachloroethane Tetrachloroethene Toluene 123-Trichlorobenzene 124-Trichlorobenzene 112-Trichloroethane 111-Trlchloroethane Triehloroethene Trichlorofluoromethane 123-Trichloropropane 135-Trimethylbenzene 124-Trimethylbenzene Vinyl chloride Xylenes total s

MCL ugL

91 100 04

5 NV NV NV NV

700 086

NV NV

NV 028

5 NV 62 NV 100

043 0055

5 1000

NV 70

5 20

5 1300

0034 120 120

2 10000

GP-1 ugL 964 458 ND ND

ND ND ND ND

052 J ND ND ND ND ND ND ND ND ND ND ND ND

14700 065 J ND ND ND ND

2850 ND

ND ND ND 116 146 J

GP-2 ugL ND ND ND ND ND ND ND- ND ND ND ND ND -ND ND ND ND ND ND ND ND ND

603 ND ND ND ND ND

079 J ND ND ND ND 242 ND

GP-3 ugL 346 865 ND ND

bull ND ND ND-ND

055 J ND ND ND ND ND ND ND ND ND ND ND ND

13900 159 ND ND ND ND

4870 ND ND ND ND 708 149 J

GP-4 ugL ND ND ND ND ND ND ND ND ND ND ND

ND 177 ND ND ND ND ND ND ND ND

583 ND ND ND ND ND

082 J ND ND ND ND

227 ND bull

GP-5 ugL ND ND ND ND ND

ND ND ND ND ND ND ND ND

ND ND ND ND ND ND ND ND 133 ND ND ND ND ND

574 ND ND

ND ND 122 ND

Notes - Bold indicates COPCs detected at concentrations greater than the MCL

(60CSR3 Table 60-3B July 2008) - ND indicates non-detected at concentrations greater than the MCL - J indicates analyte detected at levels less than the reporting limit and greater than

or equal to the MDL value is estimated - NV indicates no value has been established

AR100287

Risk-Based Rerfiedies

R B R Consulting Inc 650 Shady Drive Beaver Falls PA 15010

Phone724-846-4096 Fax 724-846-6974

MEMORANDUM

TO John Meeks Triad Engineering Inc

FROM Bruce Fishman

DATE September 82009

SUBJECT Evaluation of Potential Risks Associated with Vapor Intrijsion to Indoor Air Coyne Textile Services Facility - Huntington West Virginia

bull V bull bull bull

This memorandum presents a risk evaluation for potential risks associated with vapor intrusion to indoor air at the Coyne Textile Services Facility located in Huntington West Virginia (site) This evaluation was conducted according to West Virginia Department of Environmental Protection (WVDEP) and United States Environmental Protection Agency (USEPA) methodologies

DATA INCLUDED 1N THE EVALUATION

This evaluation includes three subslab vapor samples (VP-01 VP-02 and VP-03) collected from immediately beneath the floor of the existing site building Table 1 lists the subslab vapor samples included in this risk assessment Samples were analyzed for volatile organic compounds (VOCs) by USEPA Method TO-15 Complete analytical data for these samples are provided in Table A-1 of Appendix A

The analytical results of the subslab vapor samples were compared to the target shallow soil gas comparison values presented in Table 2c of the USEPA vapor intrusion guidance document (2002a) These companson values are generic soil gas screening values that are protective of indoor air for residential land uses and represent concentrations in-sliallow soil gas based on a target risk level of 1 x 10reg andor a hazard index of 1 The comparison is presented in Table 2

As indicated in Table 2 the following constituents are identified as contaminants of concern (COC) for the vapor intrusion to indoor air pathway 124-trimethylbenzene 12-dichloroethene (cis) chloroform methylene chloride tetrachloroethene and triehloroethene

ESTIMATION OF INDOOR AIR CONCENTRATIONS

The concentrations of COC in indoor air associated with vapor intrusion from subslab vapor were estimated using methodologies outlined in the Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings (USEPA 2004) A transport factor (TF) is required that will relate the

Page 1 of 5 -

AR100288

Risk-Based Remedies

R B R Consulting Inc

constituent concentration in subslab vapor to the concentration in indoor air The TF is dependent on the diffusion coefficient and other properties that will affect the transfer of constituents into air such as distance from the source to tlie breathing zone soil properties and building properties A site-specific building size of 84000 square feet (Dolphin 2000) and a soil type of sandy loam were used in the calculation of TF The TF is determined using calculationsbased on the Johnson and Ettinger (1991) vapor intrusion model Details of the TF calculations are provided in Appendix B

Subslab vapor concentrations are converted to indoor air concentration by applying the TF as follows

Cja ^ Csubslab X I r

The TF for each COC along with the resulting concentrations of COC in indoor air are presented in Tables

EXPOSURE EVALUATION

Noncarcinogenic health effects are evaluated by calculating the average dose of a constituent over the course of the exposure period This dose is termed the Average Daily Dose (ADD) Potential carcinogenic health effects are evaluated in terms of an individuals theoretical increased risk of developing cancer over a lifetime Although the duration of exposure to a constituent release generally does not last for an entire lifetime constituent intake for carcinogens is estimated as the average dose over a human lifetime (70 years) This lifetime dose applies specifically to the evaluation of carcinogenic effects and is termed tine Lifetime Average Daily Dose (LADD) In a risk assessment the calculated ADD or LADD are estimated quantitatively using assurnptions about the duration frequency and magnitude of exposure experienced by each potential receptor and assumptions about the constituent properties that influence absorption

The quantitative estimation of constituent intake involves the incorporation of numerical assumptions for a variety of exposure parahneters Exposure assumptions used in these intake calculations are based on WVDEP (2001) or USEPA (1989 2002b) recommended values The factors and equation for inhalation of vplatiles is presented in Table 4 and described below

bull Inhalation Rate and Exposure Time WVDEP (2001) and USEPA (2002b) guidance recommend that an inhalation rate of 20 m day be used for workers For an exposure time of 8 hours (a typical workday) this results in an inhalation rate of 25 m hour

bull Exposure Frequency and Duration Default exposure factors for indoor workers are provided by WVDEP (2001) Exposure frequency for the worker is 5 days per week for 50 weeks a year or 250 days per year The exposure duration for these workers is 25 years which is the 95th percentile value ai cording to the Bureau of Labor Statistics (USEPA 1989)

bull Body Weight The default value for average body weight of an adult is 70 kg based on WVDEP (2001) and USEPA guidance (1989 2002b)

Page 2 of 5

AR100289

Risk-Based Remedies

R B R Consulting Inc

bull Averaging Time As described above the doses for noncarcinogenic health effects are averaged oyer the specific period of exposure for a given receptor Noncarcinogenic

averaging times are therefore calculated by multiplying the exposure duration for the receptor by 365 daysyear Carcinogenic health effects are calculated over a lifetime exposure so the value recommended by WVDEP (2001) and USEPA (2002b) for average lifetime 70 years was used for exposure duration The resulting carcinogenic averaging time is 25550 days

TOXICITY VALUES

Noncarcinogenic responses are evaluated numerically using parameters known as the hazard quotient (HQ) and hazard index (HI) the HQ is obtained by dividing the ADD for a constituent by the reference dose (RfD) Each dose calculation with a specific combination of constituent receptor and exposure pathway will have a distinct ADD and calculated HQ HQs associated with all constituents for a particular pathway are summed to yield the HI

In order to estimate the theoretical excess lifetime cancer risk the LADD of a constituent is multiplied by the cancer slope factor (CSF) For each pathway this calculation is carried out for each applicable constituent and the risks are summed to obtain the total potential risk due to that pathway

Toxicity values for each constituent are presented in Table 5 the toxicity values were obtained from the following sources

bull Integrated Risk Information System (IRIS) on-line database provided by USEPA (2009)

bull The USEPAs Provisional Peer-Reviewed Toxicity Values (PPRTV) as presented in the USEPA Regional Screening Tables (ORNL 2009)

bull Provisional value from the National Center for Environmental Assessnient (as per WVDEP)

bull The Agency for Toxic Substances and Disease Registrys (ATSDR) Minimal Risk Levels (MRLs ATSDR 2009) and

bull Value cited by USEPA Region 3 attributed to other sources (as per WVDEP)

RISK CHARACTERIZATION

Potential noncarcinogenic effects associated with exposure to COC at the site are estimated by comparing calculated intakes with the contaminant-specific RfDs The total HI was calculated by summing the individual HQs An HI value equal to or less than 1 indicates thatthelikelihopd of ah adverse noncancer effect would be negligible (USEPA 1989) An HI greater than 1 indicates that additional evaluation of the case is warranted

Theoretical excess lifetime cancer risks associated with exposure to COC from the site were calculated by comparing estimated intakes to constituent-specific CSFs Summed theoretical

Page 3 of 5

AR100290

Risk-Based Remedies

R B R Consulting Inc

excess risks are calculated by combining constituent-specific risks The results may be compared with target benchrharks for acceptable risk Various demarcations of acceptable risk have been established by regulatory agencies WDEP (2001) presents a target cancer risk of 1 x 10 for nonresidential scenarios USEPA (1991) considers potential cancer risks in the range of 1 x 10reg to 1 X 10 to be acceptable

Constituent-specific results for the indoor worker are presented in Table 6 For the indoor worker exposed to COC in indoor air (vapor intrusion from subslab vapor) the total HI is 00081 and the potential cumulative cancer risk is 497 X 10reg

These results meet both WVDEP and USEPA benchmarks indicating that the site poses negligible potential for human health risk for indoor workers

CONCLUSIONS

The results of this focused risk evaluation indicate that potential risks associated with vapor intrusion exposure of indoor workers to constituents that may volatilize from subslab vapor are within the acceptable benchmarks established by WVDEP and USEPA No further evaluation of the vapor intrusion pathway is warranted for the site

REFERENCES

Agency for Toxic Substances and Disease Registry (ATSDR 2009) Minimal Risk Levels (MRLs) Available at httpvtfwwatsdrcdcqovmrisindexhtml

Dolphin Environmental LLC (Dolphin 2000) Site Characterization Report Mach 14 2000

Johnson PC and RA Ettinger (1991) Heuristic model for predicting the intrusion rate of contaminant vapors into buildings Environ Sci Technology 25 1445-1452

Oak Ridge National Laboratory (ORNL 2009) Regional Screening Levels for Chemical Contaminants at Superfund Sites April 15 2009 Available online httpwwwepagovreg3hwmdriskhumanrb-concentration_tableindexhtm

United States Environmental Protection Agency (USEPA 1989) Risk Assessment Guidance for Superfund Volume I PartA Human Health Evaluation Manual EPA5401-89002

United States Environmental Protection Agency (USEPA 1991) Risk Assessment Guidance for Superfund Volume I Part B Development of Risk-Based Remediation Goals Office of Emergency and Remedial Response OSWER Directive 92857-018

United States Environmental Protection Agency (USEPA 2002a) Draft Guidance for Evaluating the Vapor Intrusion to Indoor Air Pathway from Groundwater and Soils Office of Solid Waste and Emergency Response Pub No 92856-10 December 2002

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Risk-Based Remedies

R B R Consul t ing Inc

United States Environmental Protection Agency (USEPA 2002b) Supplemental Guidance for Calculating Soil Screening Levels for Superfund Sites Office of Solid Waste and Emergency Response December

United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004

United States Environmental Protection Agency (USEPA 2009) Integrated Risk Information System (IRIS) On-line database wwwepaqoviris

West Virginia Department of Environmental Protection (WVDEP 2001) West Virginia Voluntary Remediation and Redevelopment Act-Guidance Manual Version 21 March 13

Page 5 of 5

AR100292

TABLES

AR100293

TABLE 1 SUBSLAB VAPOR SAMPLES INCLUDED IN THE RISK ASSESSMENT

Coyne text i le Services Facility - Huntington West Virginia

Medium

Subslab Vapor

Sample Identification

bull VP-01

VP-02

VP-03

Sample Date

8132009

8132009

8132009

Coyne VIMemo Tables_09-08-09xls 982009

AR100294

TABLE 2 IDENTIFICATION OF CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR

Coyne Textile Services Facility - Huntington West Virginia

mdash

Const i tuent

Volati le Organics

111-Trichlor6ethane

1122-Tetrachloroethane

112-Trichloro-122-trifluoroethane

112-Trichloroethane

11-Dichloroethane

11-Dichloroethene

124-Trichlorobenzene

124-Trimethylbenzene

12-Dibromoethane

12-Dichlor6benzene

12-Dichloroethane

12-Dichloroethene (cis)

12-pichloroethene (trans)

12-Dichloropropane

12-Dichlorotetraf1uoroethane

135-Trimethylbenzene

13-Butadiene

13-Dichlorobenzene

13-Hexachlorobutadiene

14-Dichlorpbenzene

224-trimethylpentane

2-Chlorotoluene

4-Ethyltoluene

Acetone

Allyl Chloride

Benzene

Bromodichloromethane

Bromoform

Bromomethane

Carbon disulfide bull

Carbon tetrachloride

ChJorobenzene

Chloroethane

Frequency of Detection

0 3

0 3

0 3

bull 0 3

0 3

0 3

0 3

1 3

0 3 bull

0 3

b 3 bull

2 3

0 3

bull 0 3

0 3

0 3

0 3 bull

0 3

0 3

0 3

0 3

0 3

0 17

3 3

0 3

P 3

- 0 3

0 3

0 3

0 3

0 3

0 3

0 3

Min imum Detected

Concentrat ion

(ugm^)

ND

ND

ND

ND

ND

- ND

N D

197

ND bull

ND

ND

369

ND

bull~ ND

ND

ND

ND

ND

ND

bull ND

ND

ND

ND

796

ND

ND

ND-

ND

ND

ND

ND

ND

ND

Maximum

Detected Concentrat ion

(ugm3)

ND

ND

ND

ND

ND

ND

ND

197

ND

ND

ND

mdash 6030

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

1880

ND-

ND

ND

ND

ND

ND

ND

ND

ND

Sample wi th Maximum Detect

ND

ND

ND

ND

ND

ND

- ND

VP-03 -

ND

ND

ND

VP-03

ND

bullND

ND

ND

ND

ND

ND

ND

ND

ND

ND

VP-02

ND

ND bull

ND

ND

ND bull

bull ND

ND

ND

ND

Min imum Detection

Limit (ugm3)

22

28

31

22

16

16

30

20

31

24

16

bull 16

16

19

28

20

89

24 bull

43

24

bull 19

2 1

20

--^ 13

13

27

41

16

13

25

18

11

Maximum Detection

Limit (ugm3)

218

275

307

218

162

159

297

197

307

240

162

- 16

159

185

280

197

89

240

427

240

187

207

197

--125

128

268

414

155

125

252

184

106

Vapor Intrusion Corhparison

V a l u e

(ugm)

22000

042

300000

15

bull 5000

2000

2000

60

011

2000

094

350

700

40

NA

60

0087

1100

11

8000

NA

NA

NA

3500

NA

31

14

22

50

7000

16

bull 600

100000

Chemical of Concern

No

No

No

No

No

No

No

YES

No

No

No

YES

No

No

No

N o bull

bullNo

No

No

No

No

No

No

N o

No

No

No

N o

No

No

No

No

No

Comment

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent notdetected

fflaximCimTdeteetlSffieedsTcomDarisonivalues

Constituent not detected

Constituent not detected

Constituent not detected

Maximum detect exceeds comparison value

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Maximum detect below comparison value

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detectedl

Constituent not detected

Constituent not detected

CoyneVI Memo Tables_09-08-09xls 982009

AR100295

TABLE 2

IDENTIFICATION OF CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR

Coyne Textile Services Facility - Huntington West Virginia

Const i tuent

Volati le Organics

Chloroform -

Chloromethane

13-Dichloropropene (cis)

Cyclohexarie^

Dibrcimochloromethane

DichlonDdifluoromethane

Ethylbenzene

Methyl ethyl ketone

Methyl isobutyl ketone

Methyl tert-butyl ether

Methylene chloride

n-Heptane

n-Hexane

Styrene

Tert-butyl alcohol

Tetrachloroethene

Toluene

13-Dichloropropene(trans)

Triehloroethene

Trichlorofluoromethane

Vinyl bromide

Vinyl chloride

Xylene (0)

Xylenes (mampp)

Frequency of Detection

1 3

0 3

0 3

1 3

0 3

0 3

0 -3

1 3

0 3

0 3

2 3

0 3

3 3

0 3

0 3

3 3

1 3

- 0 3

3 3

P 3

0 3

0 3

1 3

1 3

Min imum Detected

Concentrat ion

(ugm)

5910

ND

ND

52

ND

ND

ND

23

ND

ND

1160

ND

1 4 4

ND

ND

11200

18

ND

91

ND

ND

ND

208

387

Maximuri i Detected

Concentrat ion (ugmS)

bull

5910

ND

ND

52

bull ND

ND

ND

23

ND

ND

1520

ND

183

ND

ND

149000

18

ND

7820

ND

bullND

ND

208

387

Sample vyith Max imum Detect

VP-02

ND

ND

VP-01

bull ND

ND

ND

VP-01

ND

ND

VP-02

ND

VP-02

ND

ND

VP-02

VP-01

ND

VP-03

ND

ND

ND

VP-03

VP-03

Min imum Detection

Limit (ugm3)

20

83

18

138

34

bull 20

17

118

16

14

14

16

- -17

12

--151

18

--23

18

10

1 7 bull

1 7 bull

Maximum Detection

Limit (ugm3)

195

83

182

138

341

198

174

118

164

144

14

164

170

121 -

--151

182

225

175

102

bull 174

174

Vapor Intrusion Compar ison

V a l u e

(ugm)

11

24

NA

2000

1

2000

22

10000

800

30000

52

NA

2000

10000

NA

81

4000

NA

022

7000

NA

28

70000

70000

Chemical o f Concern

YES

No

No

No

No bull

No

No bull

No bull=

No

No

YES

No

No

No

No

YES

No

No

YES

N o

No

No

No

No

Comment

Maximum detect exceeds comparison value

Constituent not detected

Constituent not detected

Maximum detect below comparison value

Constituent not detected

Constituent not detected

Constituent not detected

Maximum detect below comparison value

Constituent not detected

Constituent not detected

Maximum detect exceeds comparison value

Constituent not detected bull

Maximum detect below comparison value

Constituent not detected

Constituent not detected

Maximum detect exceeds comparison value

Maximum detect below comparison value

Constituent not detected

Maximum detect exceeds comparison value

Constituent not detected

Constituent not detected

Constituent not detected bull

Maximum detect below comparison value

Maximum detect below comparison value

Notes

ND - Not Detected

NA - Not Available

- - Constituent detected in every sample detection limit not presented

Values in bold indicate detection limit exceeds comparison values

Target shallow soil gas comparison values corresponding to indoor air concentrations where the soil gas to indoor air attenuation factor = 01 and the target cancer risk is set to ip (presented in Table 2c of USEPA 2002a)

Comparison value for cyclohexane is based on the comparison value for hexane

Coyne VI Memo Tables_09-08-09xls 982009

AR100296

TABLES

EXPOSURE POINT CONCENTRATIONS FOR CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR

Coyne Textile Services Facility - Huntington West Virginia

Chemical of Concern

VolatileOrganics

i24-Trimethylbenzene

12-Dichloroethene (cis)

Chloroform

Methylene chloride

Tetrachloroethene Triehloroethene

Subslab Vapor Source

Concentration (mgm^)

0197

603

591

152

149 782

Transport

Factor^ (unitless)

108E-05

108E-05

108E-05

108E-05

108E-05 108E-05

EPC in

Indoor Air (mgm^)

213E-06

651 E-05

638E-05

164E-05

161E-03 844E-05

Notes

^ Subslab vapor source concentration is based on the maximum detected concentration of samples

VP-01-02 and-03 (see Table 2) -

^ Details of the transport factor calculations are presented in Appendix B

^ Exposure Point Concentration (EPC) in inidoor air is calculated as the subslab vapor concentration TF

Coyne VI Memo Tables_09-08-09xls 982009

AR100297

TABLE 4

FACTORS USED IN DOSE CALCULATIONS INHALATION OF VOLATILE EMISSIONS

Coyne Textile Services Facility - Huntington West Virginia

Symbol

CA

IRA

ET

EF

ED-

BW

AT

Exposure Factor

Constituent Concentration in Air

Inhalation Rate

Exposure Time

Exposure Frequency

Exposure Duration

Body Weight

Averaging Time

Indoor Worker

Constituent-Specific See Table 3

25 m hour

8 hrday

250 daysyear

25 years

bull 70 kg

9125 days (NC)

25550 days (C)

Total Dose = CA x IR^ x ET x EF x ED x 1BW x 1AT

(NC) - Non-carcinogenic Averaging Time

(C) - Carcinogenic Averaging Time

Coyne VI Memo Tables_09-08-09xls 982009

AR100298

TABLES TOXICITY VALUES FOR CHEMICALS OF CONCERN

Coyne Textile Services Facility - Huntington West Virginia

Chemical of Concern

Volatile Organics

124-Trimethylbenzene

12-Dichloroethene (cis)

Chloroform

Methylene chloride

tetrachloroethene

Triehloroethene

Target Organ Critical Effect

blood

bullblood

liver

liver

liver CMS

liver kidney fetus CNS

Chroniclnhalation Reference Dose

(mgkg-day)

200E-03 P

1 OOE-02 R

140E-02 E

286E-01 M

771 E-02 M

1OOE-02 E

Inhalation Cancer ^ Slope Factor

(mgkg-day)^

NA

NA

805E-02 1

165E-03 1

200E-02 0

400E-01 E

(I) - Integrated Risk Information System (IRIS USEPA 2009)

(P) - Provisional Peer-Reviewed Toxicity Value (PPRTV) as presented in USEPA Regional Screening Tables (ORNL 2009)

(R) - Calculated assuming route-to-route extrapolation as per WVDEP

(E)-Provisional value from the National Center for Environmental Assessment (as per WVDEP)

(M)-Chronic Minimal Risk Level (MRL ATSDR 2009)

(0) - Value cited by USEPA Region 3 attributed to other sources (as per WVDEP)

Coyne VI Memo Tables_09-08-09xls 982009

AR100299

TABLE 6

NONCANCER HAZARD INDEX AND POTENTIAL CANCER RISK FOR AN INDOOR WORKER

Coyne Textile Services Facility - Huntington West Virginia

bull

Constituent

Volatile Organics

124-Trinnethylbehzene

12-Dichlorpethene (cis)

Chloroform

Methylene chloride

Tetrachloroethene Triehloroethene

EPC in Indoor Air

(mgm)

213E-06

651 E-05

- 638E-05

164E-05

161 E-03

844E-05

Intake (ADD)

(mgkg-d)

416E-07

127E-05

125E-05

321 E-06

315E-04 l65E-05

RfDi

(mgkg-d)

200E-03

1OOE-02

140E-02

286E-01

771 E-02 1 OOE-02

Hazard

Quotient

208E-04

127E-03

892E-04

112E-05

408E-03 165E-03

Intake (LADD)

(mgkg-d)

) 149E-07

455E-06 bull 446E-06

115E-06

112E-04 590E-06

CSFi

(mgkg-d)

NA

NA

805E-02

165E-03

200E-02

400E-01

Potential

Cancer Risk

NA

NA

359E-07

189E-09

225E-06 236E-06

Total Hazard Index

00081 Total

Cancer Risk 497E-06

Total Blood HI = Total Liver HI =

Total Central Nervous System HI = Total Kidney HI =

Total Fetal HI =

bull 00015 00066 00057 00017 00017

Notes NA = Toxicity values are not available for this endpoint or exposure pathway

Coyne VI Memo Tables_09-08-09xls 982009

AR100300

APPENDIX A

SUBSLAB VAPOR ANALYTICAL DATA

AR100301

Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility Huntington West Virginia

Sample

Consti tuent

Volatile Organics (ugm) 111-Trlchloroethane 1122-Tetrachloroethane 112-Trichloro-122-trifluoroethane 112-Trichloroethane 11-Dichioroethane 11-Dichloroethene 124-Trichloroberi2ene 124-Trimethylbenzene 12-Dibromoethane 12-Dichloroben2ene 12-Dichloroethane 12-Dichloroethene-(cis) -12-Dichloroethene (trans) 12-Dichloropropane 12-Dichlorotetrafluoroethane 135-Trimethylbenzene 13-Butadiene 13-Dichlorobenzene 13-Hexachlorobutadiene 14-Dichlorobenzene 224-trimethVlpentane 2-Chlorotoluene 4-Ethyltoluene Acetone Allyl Chloride Benzene Bromodichloromethane Bromoform Bromomethane Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 13-Dichloropropene (cis) Cyclohexane Dibromochloromethane

Identif ication Sample Date

CAS No

71-55-6 79-34-5 76-13-1 79-00-5 75-34-3 75-35-4 120-82-1 95-63-6 106-93-4 95-50-1 107-06-2 156-59-2 156-60-5 78-87-5 76-14-2 108-67-8 106-99^0 541-73-1 87-68-3 106-46-7 540-84r1 95-49-8

622-96-8 67-64-1 107-05-1 71-43-2 75-27-4 75-252 74-83-9 75-15-0 56-23-5 108-90-7 75-00-3 67-66-3 74-87-3

10061-01-5 110-82-7 124-48-1

lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt

lt lt lt lt lt lt lt lt lt lt lt lt

lt

VP-01 8132009

22 28 31 22 16 16 30 20 31 24 16 16 16 19 28 20 89 24 43 24

1 9 21 20 796 13 13 27 41 16 13 25 18 11 20 83 18 52 34

lt lt lt lt lt lt lt lt lt lt lt

lt lt lt lt lt lt lt lt lt lt lt

lt lt lt lt lt lt lt lt lt

lt lt lt lt

VP-02 8132009

218 2 7 5 307 218 162 159 297

bull 197 307 240 162 369 159 185 280 197 89

240 427 240 187 207 197

1880 125 128 268 414 155 125 252 184 106

5910 83 182 138 341

lt lt lt lt lt lt lt

lt lt lt

lt lt lt lt lt lt lt bull

lt lt lt lt

lt lt lt lt lt lt lt lt lt lt lt lt lt lt

VP-03 8132009

218 275 307 218

bull 162 159 297 197 307 240 162

6030 159 185 280 197 89

240 427 240 187 207 197

1750 125 128 268 414 155 125 252 184 106 195 83 182 138 341

Appx A SG Dataxis Page 1 of 2 982009

AR100302

Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility bull Huntington West Virginia

Consti tuent

Volatile Organics (ugm^) Dichlorodifluoromethane Ethylbenzene Methyl ethyl ketone Methyl Isobutyl ketone Methyl tert-butyl ether Methylene chloride n-Heptane jn-Hexane Styrene Tert-butyl alcohol Tetrachloroethene iToluene 13-Dichloropropene (trans) Triehloroethene Trichlorofluoromethane Vinyl bromide Vinyl chloride Xylene (o) Xylenes (mampp)

Sample Identif ication Sample Date

CAS No

75-71-8 100-41-4 78-93-3 108-10-1

1634-04-4 75-09-2

142-82-5 bull 110-54-3

100-42-5 75-65-0 127-18-4 108-88-3

10061-02-6 79-01-6 75-69-4 593-60-2 75-01-4 95-47-6

179601-23-1

lt lt

lt lt lt lt

lt lt

lt

lt lt lt lt lt

VP01 8132009

20 17 23 16 14 14 16

173 17 12 bull

11200 18 18 91 23 18 10 17 17

lt lt lt lt lt

lt

lt lt

lt lt

lt lt lt lt lt

VP-02 8132009

198 174 118 164 144

1520 164 -183 170 121

149000 151 182

2360 225 175 102 174 174

VP-03 8132009

lt 198 lt 174 lt 118 lt 164 lt 144

1160 lt 164

144 lt 170 ltbull 121

90500 lt 151 lt 182

7820 lt 225 lt 175 lt 102

208 387

Appx A SG Dataxis Page 2 of 2 982009

AR100303

APPENDIX B

CALCULATION OF TRANSPORT FACTORS USED TO ESTIMATE INDOOR AIR CONCENTRATIONS

AR100304

APPENDIX B

Calculation of Transport Factors Used to Estimate Indoor Air Concentrations

This appendix presents the methodology for calculating transport factors that are used to convert subslab

vapor concentrations to concentrations in indoor air 124-Trimethylbenzene 12-dichloroethene (cis)

chloroform methylene chloride tetrachloroethene and triehloroethene were identified as contaminants of

concern (COC) for potential vapor intrusion from subslab vapor associated with the Coyne Textile

Services Facility located in Huntington West Virginia (site) In this appendix the transport factors are

calculated to estimate the concentrations of COC in indoor air of the existing plant building located at the

site ~

Transport Factor for Indoor Air

The concentration of a constituent in indoor air (da) is proportional to the concentration of the constituent

in the subslab vapors immediately beneath the building foundation (ie subslab vapor concentration or

Csubsiab) The following equation is used to calculate da from Csubsiab

^ wja ~ ^subslab X I r

where

Cia = concentration of constituent in indoor air (mgm^) -

Csubsiab^ concentration of constituent in subslab vapors (mgm^) and

TF = transport factor from subslab vapors to indoor air

The transport factor (TF) is an infinite source attenuation coefficient andcan be calculated based on a

model developed by Johnson and Ettinger (1991) t he equation for calculating TF is as follows

(Deff X A B ) ( Q B X L T ) X expKQso i l X Lcrabk)(Dcrack X Acrack)]

exp[ (Qsoi l X Lcrack)(Dcrack X Acrack)] + (Deff X A B ) ( Q B X L T ) + (Deff X AB)(Qsoi l X L j ) X (exp [ (Qso i l X Lcrack)(Dcrack X Acrack)] - 1)

where

Deff = effective diffusion coefficient for vadose zone soil (cm^sec)

AB = area of enclosed space below grade (cm^)

QB = building ventilation rate (cm^sec)

LT = distance from contaminant source to building foundation (cm)

Qsoii = volumetric flow rate of vapors into the building (cm^sec)

Lcrack = foundatlon thickness (cm)

Dcrack = vapor diffusion coefficient through crack (cm^sec) and

Acrack = area of cracks through which vapors can pass (cm^)

AR100305

To solve this equation the USEPAs SG-ADV spreadsheet Version 31 most recently updated in

February 2004 was implemented A combination of site-specific factors and default values from the

Users Guide for Evaluating Subsurface Vapor Intrusion Into Buildings (USEPA 2004) were used as input

values in the model All input values are defined below and presented in Tables B-1-A through B-6-A

bull The initial subslab vapor concentration (Csubsiab) is the maximum detected concentration(in units

of ugm ) of samples VP-01 VP-02 and VP-03 that was presented in Table 3 of the report

bull The depth below grade to the bottom of the enclosed space floor (Lp) is set to 15 cm the default

value provided by USEPA (2004) for a slab-on-grade structure

bull The vapor sampling depth below grade (Lg) is a site-specific value The vapor samples were

collected from immediately beneath the building floor therefore Lj has been set to 15 cm

bull The average soilgroundwater temperature (Ts) is set to 125degC the average value for West

Virginia as estimated frorri Figure 8 of the vapor intrusion users guide (USEPA 2004)

bull The soil type used to estimate vapor permeability is assumed to be sandy loam (SL) The

associated soil properties for a sandy loam soil type are as follows the soil dry bulk density (Pb) is

162 gcm the total porosity (n) is 0387 (cm^-aircm^) and the water-filled porosity (nw) is 0103

(cm -HzOcm )

bull The floor thickness (Lcrack) is set to the USEPA (2004) default value of 10 cm

bull The soil-building pressure differential (AP) is set to the USEPA (2004) default value of 40 gcm-s^

bull The building dimensions are siterspecific based on the existing plant building located at the site

The existing structure is approximately 84000 square feet (Dolphin 2000) therefore the

dimensions are set to 8839 cm (290 feet) length by 8839 cm (290 feet) The USEPA (2004)

default value of 244 cm vyas used for the height

bull Thefloor-wall seam crack width (w) is set to the USEPA (2004)-default value of 01 cm

bull The indoor air exchange rate (ER) is set to 083hour This is the value provided by ASTM (2002)

for commercial and industrial buildings

AR100306

Tables B-1-B through B-6-B present the constituent-specific properties for COC that were used in the TF

calculations Tables B-1-C through B-6-C present the intermediate calculations used to determine the

indoor air attenuation coefficients (ie the transport factors) The shaded boxes in Tables B-1-C through

B-6-C also present the resulting TF values that are applied to the concentrations of COC in subslab

vapor and the estimated indoor air concentrations

References

American Society for Testing and Materials (ASTM 2002) Standard Guide for Risk-Based Corrective Action Applied at Petroleum Release Sites ASTM E-1739-95 (Reapproved 2002)

Johnson PC and RA Ettinger (1991) Heuristic model for predicting the intrusion r-ate of contaminant vapors into buildings Environ Sci Technolpgy 25 1445-1452

Dolphin Environmental LLC (Dolphin 2000) Site Characterization Report Mach 14 2000

United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004

AR100307

APPENDIX B-1-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV Nersion31 0204

Reset to Defaults

ENTER -

Chemical CAS No

(numbers only

no dasties)

95636

ENTER Soil gas

cone

Cg (ngm)

Soil Gas Concentration Data ENTER

Soil gas

OR cone

bull - c bull (PPmv)

197E+02

Chemical

124-Trimethylbenzene

MORE ENTER Depth

below grade to bottom

of enclosed space floor

U bull (cm)

ENTER

Soil gas sampling

depth below grade

U (cm) bull

ENTER

Average soil

temperature Ts

CO

1 15 1 1 5 bull125

ENTER ENTER ENTER Totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hft ha he

(cm) (cm) (cm)

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estirnate OR permeability | soil vapor

permeability) k v bull

(cm)

SL 1 1

MORE ENTER

stratum A SCS

soil type

Lookup Soil Parameters

ENTER stratum A soil dry

bulk density P

(gcm)

ENTER Stratum A soil total porosity

(unitless)

ENTER bull stratum A soil water-filled

porosity

(cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

nlaquo

(unitless)

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gchi-s^)

ENTER Enclosed

space floor

length bull LB

(cm)

ENTER Enclosed

space floor

width WB

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

bull Floor-wall seam crack

width w

(cm)

bullENTER

Indoor air exchange

rate ER

(1h) bull

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bidg OR

Leave blank to caicuij

(Lm)

Appx B-1 124-TMBxls 1 of 3 982009

AR100308

APPENDIX B-1-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of ^ bull law constant law constant vaporization at Normal

Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temperature boiling point point temperature weight

D bull Dbdquo H T R bull AHbdquo TB Tc IVIW

Unit risk Reference

factor cone URF RfC

(cms) (cmls) (atm-mmol) CO (calmol) (degK) (degK) (gmol) bull (ugm)- (mgm)

1 606E-02 1 792E-06 1 bull 614E-C3 1 25 1 9369 1 44230 | 64917 1 12020 1 OOE+00 1 60E-03 1

Appx B-1 124-TMBxls 2 of 3 982009

AR100309

APPENDIX B-1-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

(sec)

Source-building

separation

LT bull

(cm) bull

Stratum A soil

air-filled porosity

Q A

Stratum B soil

air-filled porosity

(cmcm) (cmcm)

Stratum C soil air-filled porosity

(cmcm)

Stratum A effective total fluid

saturation

Se

(cmcm)

Stratum A soil

bullintrinsic permeability

^ (cm)

stratum A Stratum A Floor- soil soli wall BIdg

relative air effective vapor seam Soil bull ventilation permeability permeability perimeter gas rate-

kfg ky Xgrack c o n e - QbuHdinpound

(cm) - (cm) (cm) (ngm) (cms)

946E+08 1 0284 0284 0284 0184 596E-09 0901 537E-09 35357 I 197E+02 | 439E+06 |

Area of enclosed

space below grade

As (cm)

Crack-to-total area ratio

1 bull

(unitless)

Crack depth

below grade

Zcfack

(cm)

Enthalpy of vaporization at

ave soil temperature

AHvjs

(calmol) bull

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law constant at

ave soil bull temperature

bull HTS

(unitless)

Vapor bull viscosity at

ave soil temperature

HTS

(gcm-s)

Stratum A

effective diffusion

coefficient

D (cms)

Stratum-B

effective diffusion coefficient

DB (cms)

Stratum C effective diffusion

coefficient

D-c (cms)

Total - overall effective diffusion

coefficient

D ^ (cms)

Diffusion path

length

L-

(cm)

I 787E+07 I 449E-05 | 15 | 11661 260E-03 111E-01 176E-04 I 612E-03 j OOOE+00 | OOOE+00 | 612E-03 j

bull Convection path

length

Lp

(cm)

Source vapor cone

^source

(ngm)

Crack radius

Tcfack

(cm)

Average vapor

flow rate into bIdg

Qsoii

(cms)

Crack effective diffusion

coefficient pcrack

(cms)

Area of CTack

Acack

(cm)

Exponent of equivalent foundation

Peclet number

exp(Pe)

(unitless)

bull bull - bull bull bull bull

1 15 1 197E+02 1 010 1 474E+01 612E-03 bull 354E-t-03 1 336E+09

Infinite source Indoor

~ attenuation coefficient

a

(unitless)

108E-05

Infinite source

btJbldgjJSv-L ^Ppncji3i-

virhpbiiilding bullbull ^lHltti^m)ilg

213E-03

Unit risk

factor

URF

(ngm)-

Reference cone

RfC (mgm)

NA 60E-03 1

I END

Appx B-1 124-TMBxls 3 of 3 982009

AR100310

APPENDIX B-2-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV Nersion31 020^

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

156592

Soil Gas Concentration Data ENTER

Soil gas

cone OR c

(ngm) bull

ENTER Soil bull-gas

cone

c (ppmv)

603E+03 1

Chemical

cis-12-Dichloroethylene

MORE ENTER Depth

below grade to bottom

of enclosed space floor

LF

(cm)

ENTER

Soil gas sampling

depth below grade

U (cm)

ENTER

Average soil

temperature bull Ts

(degC)

1 15 1 bull 15 125

ENTER ENTER ENTER Totalsmust add ijp tb value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hA hB he

bull (cm) (cm) (cm)

15 1 1

ENTER Soil

straturh A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estimate OR permeability | soil vapor

permeability) kv

(cm)

SL 1 |

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

P (gcm)

ENTER Stratum A soil total porosity

bull n

(unitless)

ENTER Stratum A

soil water-filled porosity

(cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

ENTER Stratum B

soil water-filled porosity

ENTER Stratum C

SCS soil type

(unitless) (cmcm)

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure differential

AP

(gcm-s)

ENTER Enclosed bull

space floor

length

LB (cm)

ENTER Enclosed

space floor

width WB

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER

Average vapor flow rate into bIdg

OR Leave blank to calculi

Qsoil

(Lm)

Appx B-2 cis-12-DCExls 1 of 3 982009

AR100311

APPENDIX B-2-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Diffusivity in air

Da

(cms)

Diffusivity in water

Dw (cms)

Henrys law constant at reference temperature

H

(atm-mmoi)

Henrys law constant

reference temperature

bull T R

CC)

Enthalpy of vaporization at

the normal boiling point

AHbdquob

(calmol)

Normal boiling point

TB

(degK)

Critical temperature

Tc (degK)

Molecular weight

MW

(gmol)

Unit risk

factor URF

(ngm)

Reference cone

RfC (mgm)

1 736E-02 1 113E-05 1 407E-03 j 1 25 1 bull 7192 1 33365 1 54400 1 9694 1 OOE+00 j 35E-02 1

Appx B-2 cis-12-DCExls 2 of 3 982009

AR100312

APPENDIX B-2-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

stratum A Stratum B Stratum C Source- soil soil soil

Exposure building air-filled air-filled air-filled

duration separation porosity porosity porosity

T LT ea e^ bull e= (sec) (cm) (cmcm) (cmcm) (cmcm)

I 946E+08n^

Stratum A Stratum A Stratum A Stratum A Floor-effective soil soil soil wall total fluid intrinsic relative air effective vapor seam

saturation permeability permeability permeability perimeter

Ste kj krg ky Acrack

(cmcm) (cm) (cm) (cm) (cm)

Soil gas

cone (ngm)

I 0284 I 0284~ 0284 0184 I 596E-09 | 090T 537E-09 35357 603E+03

BIdg ventilation

rate

JbulldinE

(cms)

439E+06

Area of enclosed

space below grade

AB

(cm)

Crack-to-total

area ratio

n (unitless)

Crack depth below grade

Zltiack (cm)

Erithalpy of vaporization at

ave soil temperature

AHvTs (calmol)

Henryslaw constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law constant at

ave soil temperature

HTS

(unitless) bull

Vapor viscosity at

ave soil bull temperature

HTS

bull (gcm-s)

Stratum A

effective bull diffusion

coefficient

D^A-(cms)

Stratum B

effective bull diffusion

coefficient

D=B

(cms)

Stratum C

effective diffusion bull

coefficient

D=e (cms)

Total overall

effective diffusion

coefficient

DT

(cms)

Diffusion path

length

Ld

(cm)

I 787E+07 I bull449E-05 | 15 bull7709 230E-03 982E-02 176E-04 | 743E-03 | OOOE+00 | OOOE+00 | 743E-03 |

bull bull bull -

Convecfion path -bull

length

Lp (cm)

Source vapor cone

-source

(Mgm)

Crack radius

fcrack

(cm)

Average vapor

flow rate into bIdg

Qaoil bull

(cms)

Crack effective diffusion

coefficient pcack

(cms)

Area of crack

crack

(cm)-

Exponent of equivalent foundation

Peclet number

exp(Pef)

(unitless)

bull

1 15 -1 603E+03 1 010 1 474E+01 743E-03 354E+03 1 697E+07

Infinite source Indoor

attenuation coefficient

poundbullbullbull C t

pound(unitless)

bullsiilaquogt j ii08E-05

Infinite [ source

bIdg cone

Cbujidjng

(pgm)

651 E-02 iKrt

Unit risk

factor

URF

(ngm)-

Reference cone

RfC

(mgm)

NA 35E-02 1

I END I

Appx B-2 cis-12-DCExls 3o f3 982009

AR100313

APPENDIX B-3-A DATA ENTRY SHEET

Coyne Texti le Services - Hunt ington West Virginia

SG-ADV Version 31 0204

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

67663

Soil Gas Concentration Data ENTER ENTER

Soil Soil gas gas

cone OR cone c C

(^gm) (ppmv)

591 E+03

bull

Chemical

Chloroform

MORE ENTER Depth

below grade tb bottom

of enclosed space floor

bull LF

(cm)

ENTER

Soil gas sampling depth

below grade

(cm)

ENTER

Average soil

temperature-Ts

CO bull

1 15 1 15 1 125

ENTER ENTER ENTER Totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

IIA hs he (cm) (cm) (cm)

1 5 bull 1 1

ENTER ENTER Soil - bull

stratum A User-defined SCS stratum A

soil type bull soil vapor (used to estimate OR permeability

soil vapor k

bull permeability) (cm) 1

SL 1 1 bull

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A soil dry

bulk density

Pb (gcm)

ENTER Stratum A soil total porosity

nV (unitless)

ENTER Stratum A

-soilwater-filled bullporosity

Sraquo (cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

(unitless)

ENTER Stratum B

soil water-filled porosity

bull ebdquo=

(cmcm) bull

ENTER Straturri C

SCS bull soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

- c rack

(cm)

ENTER

Soil-bldg pressure

differential AP^

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor

width bull W B

(cm)

ENTER

Enclosed space

height HB

(cm)

ENTER

bull Floor-wall^ seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bidg OR

Leave blank to calculi

Qsoil bull

(Lm)

I -I

Appx B-3 Chloroformxls 1 of 3 982009

AR100314

APPENDIX B-3-B CHEMICALPROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Diffusivity in air

D (cms)

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffijsivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature

Dbdquo H TR A H bdquo TB Tc

(cm s) (atm-m mol) ro (calmol) (degK) (degK)

Molecular weight

MW

(gmol)

Unit risk

factor URF

(ngm)-

Reference cone

RfC

(mgm)

104E-01 100E-05 I 366E-03 25 6988 33432 53640 11938 I 23E-05 | OOE+00

Appx B-3 Chloroformxls 2 of 3 982009

AR100315

APPENDIX B-3-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure

duration

(sec)

Source-

building

separation

LT

(cm)

Stratum A

soil

air-filled

porosity

Sa

( cm cm )

Stratum B

soil

air-filled

porosity

( cm cm )

Stratum C

soil

air-filled

porosity

( c m c m )

Stratum A

effective

total fluid

saturation

( c m c m )

Stratum A

soil

intrinsic

penmeability

k

(cm )

Stratum A

- soil

relative air

permeabil i ty

(cm )

Stratum A

soil

effective vapor

permeability

kv

(cm )

Floor-

wall

seam

perimeter

gtcrack

(cm)

Soil gas

cone

(ngm)

BIdg

venfilation

rate

^buildlriE

(cms)

I 9 4 6 E + 0 8 ~ T I 0284 T 596E-09 I 0-901 I 537E-09 | 35357 | 591 E+03 j 439E+06 | 1 0 284 0284 0184

Area of

enclosed

space

below

grade

A B

( c m )

Crack-

to-total

area

ratio

n

(unitless)

Crack

depth

bull below

grade

^crack

(cm)

Enthalpy of

vaporization at

ave soil

temperature

AHTs bull

(calmol)

Henry s law

constant at

ave soil

temperature

HTS

(a tm-m mol j

Henrys law

constant at

ave soil

bull temperature

HTS

(unitless) bull

Vapor

viscosity at

ave soil-

temperature

^HTS

(gcm-s)

Stratum

A

effective

diffusion

coefficient

(cm s)

Stratum

B

effective

difftjsion

coefficient

D B

(cms) bull

S t ra tum

C

effective

diffusion

coefficient

Dc

(cm s)

Total

overall

effective

bull diffusion

coefficient

D T

(cm s)

Diffi jsion

path

length

Ld

(cm)

I 787E+07 I 449E-05 j - bull 15 7528 210E-03 896E-02 176E-04 I 105E-02 | OOOE+00 | OOOE+00 | 105E-02

Convection

path length

Lp

(cm)

Source

vapor

cone -

^source

- (ngm)

Crack

radius

Tcrack

(cm)

Average

vapor

flow rate

into bidg

Qsoil

(cms)

Crack

effective

diffusion

coefficient Qcrack

bull (cms)

Area of crack

Acrack

(cm)

Exponent of

equivalent

foundation

Peclet number

exp(Pe)

(unitless)

V bull bull

1 15 1 591 E+03 1 010 1 474E+01 105E-02 354E+03 1 355E+05

Infinite

source

indoor

attenuation

coefficient

d

(unitless)

bull 108E-05

Infinite

source

bIdg

cone

^ b u i l d i n g

i (^gm)

bull bull

i 638E-02 -

Unit

risk bull factor

URF

(ngmY

Reference

cone

RfC

(mgm)

~ 23E-05 NA 1

I END

Appx B-3 Chloroform xls 3 of 3 982009

AR100316

APPENDIX B-4-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ersion 31-020^

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

nodashes)

bull 75092

ENTER Soil gas

cone

c (ngm)

Soil Gas Concentration Data ENTER

Soil gas bull

OR cone

bull C

(ppmv)

152E+03

bull bull

Chemical

Methylene chloride

MORE

MORE 4gt

ENTER Depth

below grade to bottom

of enclosed space floor

LF -

(cm)

ENTER

Soil gas sampling depth

below grade

bull U

(cm)

ENTER

Average soil

temperature

Ts bull CC)

bull bull bull bull

1 15 1 15 125

ENTER Totals

Thickness of soil

stratum A h

(cm)

ENTER ENTER must add up to value of Ls (cell F24

Thickness Thickness of soil of soil

stratum B stratum C (Enter value or 0) (Enter value or 0)

he he bull

(cm) bull (cm) -

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(usedto estimate OR perrrieability | soil vapor

permeability)

k bull

(cm)

SL 1 bull 1

ENTER Stratum A

SCS soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

Pb (gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Stratum A

soil water-filled porosity

9w (cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

Pb^

(gcm)

ENTER Stratum B soil total porosity

n^

(unitless)

ENTER Stratum B

soil water-filled porosity

(crhcm)

ENTER Stratum C

SCS soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE 4gt

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

bull Soil-bldg pressure

differential AP^

(gcm-s)

ENTER Enclosed

space floor

length LB

(cm)

ENTER Enclosed

space floor

width bull W B

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width

w

(cm)

ENTER

Indoor air exchange

rate

ER (1h)

ENTER Average vapor

flow rate into bidg OR

Leave blank to calculc

Qsoil

(Lm)

10 40 8839 8839 244 01 083

Appx B-4 MCxIs 1 of 3 982009

AR100317

Diffijsivity in air

D

APPENDIX B-4-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffusivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature

Pw H TR AHt TB TC

Molecular weight

MW

Unit risk

factor URF

Reference cone

RfC

(cms) (cms) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) bull (ngm)- (mgm)

bull bull

1 101E-01 1 117E-05 1 218E-03 1 25 | 6706 1 31300 1 51000 1 8493 1 47E-07 1 30E+00 1

Appx B-4 MCxIs 2 of 3 982009

AR100318

APPENDIX B-4-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

T

(sec)

Source- -building

separation

LT

(cm)

Stratum A soil

air-filled porosity

e a bull

(cmcm)

Stratum B soil

bullair-filled porosity bull

ea^ (cmcm)

Stratum C soil

air-filled porosity

ea= (cmcmj

Stratum A effective total fluid

saturation

Sc bull

(cmcm)

Stratum A soil

intrinsic pemneability

ki (cm)

Stratum A soil

relative air permeability

^ ^ g

(cm)

stratumA bull soil effective vapor permeability

K (cm)

Floor-wall

seam perimeter

Xcrack

(cm)

Soil gas

cone (ngm)

BIdg ventilation

rate

Qbuildinc

(cms)

1 946E+08

Area of -enclosed

space below

bull grade

AB

(cm)

1

Crack-to-total

area rafio

Tl

(unitless)

0284 1

Crack depth below grade

Zcrack

(cm)

0284 1

bull Enthalpy of vaporization at

ave soil temperature

AHTs (calmol)

0284

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

0184

Henrys law constant at ave soil

temperature

HTS

bull (unitless)

1 596E-09

Vapor viscosity at

ave soil temperature

Mrs (gcm-s)

0901

Stratum A

effective diffusion

coefficient

D (cms)

537E-09

Stratum B

effective diffusion

coefficient

D-B (cms)

35357 1

Stratum C -

effective diffusion

coefficient

D-c ^ (cms)

152E+03

Total bull overall

bull effective diffusion

coefficient

D ^

(cms)

440E+06 1

Difftjsion path

length

Ld (cm)

1 787E+07

Convection path

length

Lp (cm)

4 49E-05

Source vapor cone

Csource

(ngm)

15 1

Crack radius

Tcrack

(cm)

7007 bull 1

Average vapor

flow rate intobldg

Qsoil

(cms)

130E-03

Crack effective diffusion

coefficient pcrack

(cms)-

555E-02

bull ^

Area of crack

Acrack

(cm) bull

1 176E-04

Exponent of equivalent foundation

Peclet number

exp(Pe)

(unitless) bull

bull bull

1 15

1 END

152E+03 010 1 474E+01 1 102E-02 354E+03 1 519E+05

102E-02

Infinite source

indoor ^attenuation coefficient

bull a

(unitless)

aiii08E-05

0 OOE+00

bull

Infinite bull source

bIdg ^ cone

^bu i l d i ng

(MQm)

164E-02

OOOE+00 1

Unit risk

factor

URF

(ngm)-

47E-07 1

102E-02 j

Reference cone

RfC

(mgm)

30E+00 j

1 1

Appx B-4 MCxIs 3 of 3 982009

AR100319

APPENDIX B-5-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ^erslon 31 0204

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

127184

Soil Gas Concentration Data ENTER ^ ENTER

Soil -Soi l bull gas gas

cone OR cone Cg C bull

(tgm) (ppmv)

149E+05 1

Chemical

bull Tetrachlbroethylene

MORE 4

ENTER Depth

below grade to bottom

ofenclosecJ space floor

LF

(cm)

ENTER

Soil gas bull sampling

depth below grade

u bull (cm)

ENTER

Average bullsoil

temperature - Ts

ro 1 1 5 1 15 1 125 bull

ENTER ENTER ENTER totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hft bull he bull he

(cm) (cm) (cm)

bull 1 5 1 - 1

ENTER ENTER Soil

stratum A User^defined bull SCS bull stratum A soil type soil vapor

(used to estimate OR perrrieability soil vapor K bull

permeability) (cm) 1

SL 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

Pb

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Sitratum A

soil water-filled bull porosity

(cmcm)

ENTER Stratum B

SCS soiltype

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

Pb^

(gcm)

ENTER Stratum B soil total porosity

Ajnitless^

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS soil type

LookupSoil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

VS

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor width

W B

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width

w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

ENTER Average vapor

flow rate into bidg OR

Leave blank to calcul

bull Qsoil

(Lm)

10 40 8839 8839 244 01 083

Appx B-5 PCExIS 1 of 3 982009

AR100320

APPENDIX B-5-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal Unit

Diffusivity Diffusivity at reference reference the riormal boiling Critical Molecular risk Reference in air in water temperature temperature boiling point point teriiperature weight factor cone

Da Dbdquo H TR AHb TB Tc MW URF RfC

(cms) (cnis) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) (^gm)- (mgm)

1 720E-02 1 820E-06 1 184E-02 1 25 1 8288 1 39440 1 62020 1 16583 1 59E-06 1 60E-01 1

J

AppxB-5PCExls 2 of 3 - 982009

AR100321

APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

T

(sec)

Source-building

separation

LT

bull (cm)

Stratum A soil

air-filled porosity

Oa (cmcm)

Stratum B - soil air-filled porosity

ea (cmcm)

Stratum C soil

air-filled porosity

ea= - (cmcm)

Stratum A effective total fluid

saturation

sbdquo (cmcm)

Stratum A soil

intrinsic permeability

ki (cm)

Stratum A soil

relative air permeability

- ^ g

(cm)

Stratum A soil

effective vapor permeability

kv (cm)

Floor-wall

seam perimeter

^crack

(cm)

Soil gas

cone

(ngm)

BIdg venfilation

rate

Qbuildins

bull (cms)

bull bull

1 946E+08

Area of enclosed

space below grade

AB

(cm)

1

bullCrack-to-total

area ratio

1 (unitless)

0284 1

Crack bull depth below grade

Zcrack

(cm) -

0284 1

Enthalpy of vaporization at bull

ave soil temperature

bull A H V TS

(calmol)

0284

Henrys law constant at

ave soil temperature

HTS (atm-mmol)

0184

-Henrys law constant at

ave soil temperature

HTS

(unitless)

1 596E-09

Vapor viscosity at

ave soil temperature

HTS

(gcm-s)

0901

Stratum A

effective diffusion

coefficient bull D = bull

(cms)

537E-09

Stratum B

effective diffusion

coefficient

D--B (cms)

35357 1

Stratum C

effective diffusion bull

coefficient

D-c (crris)

149E+05

Total overall

effective bulldiffusion coefficient

DT

(cms)

440E+06 1

Difftjsion path

length

U (cm)

1 787E+07

Convection path

length

bull Lp

(cm)

4 49E-05

Source vapor cone

^source

(ngm)

15 1

Crack radius

Tcrack

(cm)

9528 1

Average vapor

flow rate intobldg

Qsoil (cms)

908E-03

Crack effective diffusion

coefficient pcrack

bull ( c m s ) bull

387E-01

Area of crack

Abdquoack (cm)

1 176E-04

Exponent of equivalent foundafion

Peclet number

exp(Pe)

(unitless)

bull

1 15-

1 END

149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08

727E-03

Infinite source indoor

attenuation coefficient

a

(unitless)

108E-05

OOOE+00

Infinite source

bIdg cone

Cburldtng

(Mgm)

161 E+00

OOOE+00 1

Unit risk

factor

URF

(ugm)-

59E-06 1

727E-03

Reference cone

RfC (mgm)

60E-01

1 1

Appx B-5 PCExls 3 of 3 982009

AR100322

APPENDIX B-6-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ersion31 0204

Reset to Defaults

t

Soil Gas Concentration Data ENTER

Chemical CAS No

(numbers only

no dashes)

79016

ENTER ENTER Soil Soil gas gas

cone OR cone C C -

bull (ngm) (ppmv)

782E+03

Chemical

Trichloroethylene

MORE ENTER Depth

below grade to bottom-

of enclosed space floor

LF

(cm)

ENTER

Soil gas sarnpling

depth below grade

U (cm)

ENTER

Average soil

temperature Ts

(degC)

1 15 1 15 t 125

ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e

(cm) (cm) (cm)

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estimate OR permeability soil vapor

permeability)

k (cm)

bull S L 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil bull-Parameters

ENTER Stratum A

soil dry bulk density

P b -

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Stratum A bull

soilwaterrfilled porosity

(cmcm) bull

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

bull P ^ (gcm)

ENTER Stratum B soil total

porosity

nlaquo

(unitless) -

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS bull soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor

width W B

(cm)

ENTER

Enclosed space height

H B bull

( c m ) bull

ENTER

Floor-wall seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bIdg OR

Leave blank to calculc

Qsoil

(Lm) -

Appx B-6 TCExIs 1 of 3 982009

A

AR100323

APPENDIX B-6-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight

Da Dbdquo H TR AH^b TB TC MW

Unit risk Reference

factor cone URF RfC

(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)

1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1

Appx B-6 TCExIs 2 of 3 982009

AR100324

APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

(sec)

Source-building

separation LT

(cm)

Stratum A soil

air-filled porosity

bull ea (cmcm)

Stratum B Soil

air-fllled porosity

e^ bull (cmcm)

Stratum C soil

air-filled porosity

(cmcm)

StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air

saturation permeability permeability

S|e k krg (cmcm) (cm) (cm)

Stratum A Floor-soil wall BIdg

effective vapor seam Soil ventilafion permeability perimeter gas rate

k^ bull Xack c o n e Qbuildins

(cm) (cm) (ngm) (cms)

946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |

Area of enclosed

space below grade

AB

(cm)

Ciack- to-total

area ratio

1 (unitless)

Crack depth below grade

Zcrack

(cm)

Enthalpy of vaporization at

ave soil temperature

A H J S

(calmol)

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law bull constant at

ave soil temperature

HTS

(unitless)

Vapor viscosity at

ave soil temperature

|JTS

(gcm^s)

Stratum A

effective diffusion

coefficient

(cms)

Stratum B

effective -diffusion

coefficient

D=B (cms)

Stratum ^ C effective diffusion

coefficient

D=c (cms)

Total overall

effective diffusion

coefficient

DT

(cms)

I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03

Diffusion path

length

Li (cm) bull

Convection bull path

length

Lp

(cm)

Source vapor cone bull

^source

(ngm)

Crack radius

rcrack

(cm)

Average vapor

- flow rate intobldg

Qsoil

(cms)

Crack effective diffusion

bull coefficient Qcrack

(cms)

Area of crack

^crack

(cm)

Exponent of equivalent foundation

Peclet bull number

exp(Pe)

(unitless)

bull bull

1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07

Infinite source Indoor

attenuation coefficient

a

(unitless)

108E-05

Infinite source

bIdg concgt

^building

(ngm)

844E-02

Unit risk

factor

URF

(ngm)-

Reference cone

RfC

(mgm)

1 1E-04 1 40E-02 1

END

Appx B-6 TCExIs 3 of 3 982009

AR100325

Office of Waste Management 1356 Hansford Street

Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256

West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director

ORDER

ISSUED UNDER THE

HAZARDOUS WASTE MANAGEMENT ACT

CHAPTER 22 ARTICLE 18

OF THE WEST VIRGINIA CODE^ AS AMENDED

y Order Number HW-011-80

To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704

ATTEMTION MREDARMON

Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull

AR100326

ViWJ011-laquo9 PageNunil)er2

BASIS FOR ORDER

As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following

A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^

B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator

C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities

0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94

^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement

P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following

1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater

2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was

^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment

CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable

CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order

AR100327

H W - 0 1 1 - 9 9 Page Number 3

REQUIREMENTS OF ORDER

Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows

1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^

2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore

remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling

GENERAL PROVaiONS

1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order

2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order

3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order

Effective Date

Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief

Wt T 1 V Oflice of Waste Management

AR100328

^ ^ S I S

^wmmmmamn

AR100329

Page 10: SDMS DocID 2121999 · International Enterprises Corp. building (Coyne Building), which is located at 1111 Vernon Street, Westmoreland District, Wayne County, West Virginia. The following

Table 1 Laboratory Analytical Summary - Groundwater (Continued) WCEDA Vernon street

Huntington Wayiie County West Virginia

COPC

11-Dichloroethene trans-12-Dichloroethene 13-Dichloropropane 12-Dichloropropane 22-Dichloropropane cis-13-Dichloropropene trans-13rDichloropropene 11-Dichloropropene Ethylbenzene Hexachlorobutadiene 2-Hexanone Isopropylbenzene p-lsopropyltoluene Methyl tert-Butyl Ether Methylene Chloride 4-Methyl-2-pentanone Naphthalene n-Propylbenzene Styrene 1112-Tetrachloroethane 1122-Tetrachloroethane Tetrachloroethene Toluene 123-Trichlorobenzene 124-Trichlorobenzene 112-Trichloroethane 111-Trlchloroethane Triehloroethene Trichlorofluoromethane 123-Trichloropropane 135-Trimethylbenzene 124-Trimethylbenzene Vinyl chloride Xylenes total s

MCL ugL

91 100 04

5 NV NV NV NV

700 086

NV NV

NV 028

5 NV 62 NV 100

043 0055

5 1000

NV 70

5 20

5 1300

0034 120 120

2 10000

GP-1 ugL 964 458 ND ND

ND ND ND ND

052 J ND ND ND ND ND ND ND ND ND ND ND ND

14700 065 J ND ND ND ND

2850 ND

ND ND ND 116 146 J

GP-2 ugL ND ND ND ND ND ND ND- ND ND ND ND ND -ND ND ND ND ND ND ND ND ND

603 ND ND ND ND ND

079 J ND ND ND ND 242 ND

GP-3 ugL 346 865 ND ND

bull ND ND ND-ND

055 J ND ND ND ND ND ND ND ND ND ND ND ND

13900 159 ND ND ND ND

4870 ND ND ND ND 708 149 J

GP-4 ugL ND ND ND ND ND ND ND ND ND ND ND

ND 177 ND ND ND ND ND ND ND ND

583 ND ND ND ND ND

082 J ND ND ND ND

227 ND bull

GP-5 ugL ND ND ND ND ND

ND ND ND ND ND ND ND ND

ND ND ND ND ND ND ND ND 133 ND ND ND ND ND

574 ND ND

ND ND 122 ND

Notes - Bold indicates COPCs detected at concentrations greater than the MCL

(60CSR3 Table 60-3B July 2008) - ND indicates non-detected at concentrations greater than the MCL - J indicates analyte detected at levels less than the reporting limit and greater than

or equal to the MDL value is estimated - NV indicates no value has been established

AR100287

Risk-Based Rerfiedies

R B R Consulting Inc 650 Shady Drive Beaver Falls PA 15010

Phone724-846-4096 Fax 724-846-6974

MEMORANDUM

TO John Meeks Triad Engineering Inc

FROM Bruce Fishman

DATE September 82009

SUBJECT Evaluation of Potential Risks Associated with Vapor Intrijsion to Indoor Air Coyne Textile Services Facility - Huntington West Virginia

bull V bull bull bull

This memorandum presents a risk evaluation for potential risks associated with vapor intrusion to indoor air at the Coyne Textile Services Facility located in Huntington West Virginia (site) This evaluation was conducted according to West Virginia Department of Environmental Protection (WVDEP) and United States Environmental Protection Agency (USEPA) methodologies

DATA INCLUDED 1N THE EVALUATION

This evaluation includes three subslab vapor samples (VP-01 VP-02 and VP-03) collected from immediately beneath the floor of the existing site building Table 1 lists the subslab vapor samples included in this risk assessment Samples were analyzed for volatile organic compounds (VOCs) by USEPA Method TO-15 Complete analytical data for these samples are provided in Table A-1 of Appendix A

The analytical results of the subslab vapor samples were compared to the target shallow soil gas comparison values presented in Table 2c of the USEPA vapor intrusion guidance document (2002a) These companson values are generic soil gas screening values that are protective of indoor air for residential land uses and represent concentrations in-sliallow soil gas based on a target risk level of 1 x 10reg andor a hazard index of 1 The comparison is presented in Table 2

As indicated in Table 2 the following constituents are identified as contaminants of concern (COC) for the vapor intrusion to indoor air pathway 124-trimethylbenzene 12-dichloroethene (cis) chloroform methylene chloride tetrachloroethene and triehloroethene

ESTIMATION OF INDOOR AIR CONCENTRATIONS

The concentrations of COC in indoor air associated with vapor intrusion from subslab vapor were estimated using methodologies outlined in the Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings (USEPA 2004) A transport factor (TF) is required that will relate the

Page 1 of 5 -

AR100288

Risk-Based Remedies

R B R Consulting Inc

constituent concentration in subslab vapor to the concentration in indoor air The TF is dependent on the diffusion coefficient and other properties that will affect the transfer of constituents into air such as distance from the source to tlie breathing zone soil properties and building properties A site-specific building size of 84000 square feet (Dolphin 2000) and a soil type of sandy loam were used in the calculation of TF The TF is determined using calculationsbased on the Johnson and Ettinger (1991) vapor intrusion model Details of the TF calculations are provided in Appendix B

Subslab vapor concentrations are converted to indoor air concentration by applying the TF as follows

Cja ^ Csubslab X I r

The TF for each COC along with the resulting concentrations of COC in indoor air are presented in Tables

EXPOSURE EVALUATION

Noncarcinogenic health effects are evaluated by calculating the average dose of a constituent over the course of the exposure period This dose is termed the Average Daily Dose (ADD) Potential carcinogenic health effects are evaluated in terms of an individuals theoretical increased risk of developing cancer over a lifetime Although the duration of exposure to a constituent release generally does not last for an entire lifetime constituent intake for carcinogens is estimated as the average dose over a human lifetime (70 years) This lifetime dose applies specifically to the evaluation of carcinogenic effects and is termed tine Lifetime Average Daily Dose (LADD) In a risk assessment the calculated ADD or LADD are estimated quantitatively using assurnptions about the duration frequency and magnitude of exposure experienced by each potential receptor and assumptions about the constituent properties that influence absorption

The quantitative estimation of constituent intake involves the incorporation of numerical assumptions for a variety of exposure parahneters Exposure assumptions used in these intake calculations are based on WVDEP (2001) or USEPA (1989 2002b) recommended values The factors and equation for inhalation of vplatiles is presented in Table 4 and described below

bull Inhalation Rate and Exposure Time WVDEP (2001) and USEPA (2002b) guidance recommend that an inhalation rate of 20 m day be used for workers For an exposure time of 8 hours (a typical workday) this results in an inhalation rate of 25 m hour

bull Exposure Frequency and Duration Default exposure factors for indoor workers are provided by WVDEP (2001) Exposure frequency for the worker is 5 days per week for 50 weeks a year or 250 days per year The exposure duration for these workers is 25 years which is the 95th percentile value ai cording to the Bureau of Labor Statistics (USEPA 1989)

bull Body Weight The default value for average body weight of an adult is 70 kg based on WVDEP (2001) and USEPA guidance (1989 2002b)

Page 2 of 5

AR100289

Risk-Based Remedies

R B R Consulting Inc

bull Averaging Time As described above the doses for noncarcinogenic health effects are averaged oyer the specific period of exposure for a given receptor Noncarcinogenic

averaging times are therefore calculated by multiplying the exposure duration for the receptor by 365 daysyear Carcinogenic health effects are calculated over a lifetime exposure so the value recommended by WVDEP (2001) and USEPA (2002b) for average lifetime 70 years was used for exposure duration The resulting carcinogenic averaging time is 25550 days

TOXICITY VALUES

Noncarcinogenic responses are evaluated numerically using parameters known as the hazard quotient (HQ) and hazard index (HI) the HQ is obtained by dividing the ADD for a constituent by the reference dose (RfD) Each dose calculation with a specific combination of constituent receptor and exposure pathway will have a distinct ADD and calculated HQ HQs associated with all constituents for a particular pathway are summed to yield the HI

In order to estimate the theoretical excess lifetime cancer risk the LADD of a constituent is multiplied by the cancer slope factor (CSF) For each pathway this calculation is carried out for each applicable constituent and the risks are summed to obtain the total potential risk due to that pathway

Toxicity values for each constituent are presented in Table 5 the toxicity values were obtained from the following sources

bull Integrated Risk Information System (IRIS) on-line database provided by USEPA (2009)

bull The USEPAs Provisional Peer-Reviewed Toxicity Values (PPRTV) as presented in the USEPA Regional Screening Tables (ORNL 2009)

bull Provisional value from the National Center for Environmental Assessnient (as per WVDEP)

bull The Agency for Toxic Substances and Disease Registrys (ATSDR) Minimal Risk Levels (MRLs ATSDR 2009) and

bull Value cited by USEPA Region 3 attributed to other sources (as per WVDEP)

RISK CHARACTERIZATION

Potential noncarcinogenic effects associated with exposure to COC at the site are estimated by comparing calculated intakes with the contaminant-specific RfDs The total HI was calculated by summing the individual HQs An HI value equal to or less than 1 indicates thatthelikelihopd of ah adverse noncancer effect would be negligible (USEPA 1989) An HI greater than 1 indicates that additional evaluation of the case is warranted

Theoretical excess lifetime cancer risks associated with exposure to COC from the site were calculated by comparing estimated intakes to constituent-specific CSFs Summed theoretical

Page 3 of 5

AR100290

Risk-Based Remedies

R B R Consulting Inc

excess risks are calculated by combining constituent-specific risks The results may be compared with target benchrharks for acceptable risk Various demarcations of acceptable risk have been established by regulatory agencies WDEP (2001) presents a target cancer risk of 1 x 10 for nonresidential scenarios USEPA (1991) considers potential cancer risks in the range of 1 x 10reg to 1 X 10 to be acceptable

Constituent-specific results for the indoor worker are presented in Table 6 For the indoor worker exposed to COC in indoor air (vapor intrusion from subslab vapor) the total HI is 00081 and the potential cumulative cancer risk is 497 X 10reg

These results meet both WVDEP and USEPA benchmarks indicating that the site poses negligible potential for human health risk for indoor workers

CONCLUSIONS

The results of this focused risk evaluation indicate that potential risks associated with vapor intrusion exposure of indoor workers to constituents that may volatilize from subslab vapor are within the acceptable benchmarks established by WVDEP and USEPA No further evaluation of the vapor intrusion pathway is warranted for the site

REFERENCES

Agency for Toxic Substances and Disease Registry (ATSDR 2009) Minimal Risk Levels (MRLs) Available at httpvtfwwatsdrcdcqovmrisindexhtml

Dolphin Environmental LLC (Dolphin 2000) Site Characterization Report Mach 14 2000

Johnson PC and RA Ettinger (1991) Heuristic model for predicting the intrusion rate of contaminant vapors into buildings Environ Sci Technology 25 1445-1452

Oak Ridge National Laboratory (ORNL 2009) Regional Screening Levels for Chemical Contaminants at Superfund Sites April 15 2009 Available online httpwwwepagovreg3hwmdriskhumanrb-concentration_tableindexhtm

United States Environmental Protection Agency (USEPA 1989) Risk Assessment Guidance for Superfund Volume I PartA Human Health Evaluation Manual EPA5401-89002

United States Environmental Protection Agency (USEPA 1991) Risk Assessment Guidance for Superfund Volume I Part B Development of Risk-Based Remediation Goals Office of Emergency and Remedial Response OSWER Directive 92857-018

United States Environmental Protection Agency (USEPA 2002a) Draft Guidance for Evaluating the Vapor Intrusion to Indoor Air Pathway from Groundwater and Soils Office of Solid Waste and Emergency Response Pub No 92856-10 December 2002

Page 4 of 5

AR100291

Risk-Based Remedies

R B R Consul t ing Inc

United States Environmental Protection Agency (USEPA 2002b) Supplemental Guidance for Calculating Soil Screening Levels for Superfund Sites Office of Solid Waste and Emergency Response December

United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004

United States Environmental Protection Agency (USEPA 2009) Integrated Risk Information System (IRIS) On-line database wwwepaqoviris

West Virginia Department of Environmental Protection (WVDEP 2001) West Virginia Voluntary Remediation and Redevelopment Act-Guidance Manual Version 21 March 13

Page 5 of 5

AR100292

TABLES

AR100293

TABLE 1 SUBSLAB VAPOR SAMPLES INCLUDED IN THE RISK ASSESSMENT

Coyne text i le Services Facility - Huntington West Virginia

Medium

Subslab Vapor

Sample Identification

bull VP-01

VP-02

VP-03

Sample Date

8132009

8132009

8132009

Coyne VIMemo Tables_09-08-09xls 982009

AR100294

TABLE 2 IDENTIFICATION OF CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR

Coyne Textile Services Facility - Huntington West Virginia

mdash

Const i tuent

Volati le Organics

111-Trichlor6ethane

1122-Tetrachloroethane

112-Trichloro-122-trifluoroethane

112-Trichloroethane

11-Dichloroethane

11-Dichloroethene

124-Trichlorobenzene

124-Trimethylbenzene

12-Dibromoethane

12-Dichlor6benzene

12-Dichloroethane

12-Dichloroethene (cis)

12-pichloroethene (trans)

12-Dichloropropane

12-Dichlorotetraf1uoroethane

135-Trimethylbenzene

13-Butadiene

13-Dichlorobenzene

13-Hexachlorobutadiene

14-Dichlorpbenzene

224-trimethylpentane

2-Chlorotoluene

4-Ethyltoluene

Acetone

Allyl Chloride

Benzene

Bromodichloromethane

Bromoform

Bromomethane

Carbon disulfide bull

Carbon tetrachloride

ChJorobenzene

Chloroethane

Frequency of Detection

0 3

0 3

0 3

bull 0 3

0 3

0 3

0 3

1 3

0 3 bull

0 3

b 3 bull

2 3

0 3

bull 0 3

0 3

0 3

0 3 bull

0 3

0 3

0 3

0 3

0 3

0 17

3 3

0 3

P 3

- 0 3

0 3

0 3

0 3

0 3

0 3

0 3

Min imum Detected

Concentrat ion

(ugm^)

ND

ND

ND

ND

ND

- ND

N D

197

ND bull

ND

ND

369

ND

bull~ ND

ND

ND

ND

ND

ND

bull ND

ND

ND

ND

796

ND

ND

ND-

ND

ND

ND

ND

ND

ND

Maximum

Detected Concentrat ion

(ugm3)

ND

ND

ND

ND

ND

ND

ND

197

ND

ND

ND

mdash 6030

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

1880

ND-

ND

ND

ND

ND

ND

ND

ND

ND

Sample wi th Maximum Detect

ND

ND

ND

ND

ND

ND

- ND

VP-03 -

ND

ND

ND

VP-03

ND

bullND

ND

ND

ND

ND

ND

ND

ND

ND

ND

VP-02

ND

ND bull

ND

ND

ND bull

bull ND

ND

ND

ND

Min imum Detection

Limit (ugm3)

22

28

31

22

16

16

30

20

31

24

16

bull 16

16

19

28

20

89

24 bull

43

24

bull 19

2 1

20

--^ 13

13

27

41

16

13

25

18

11

Maximum Detection

Limit (ugm3)

218

275

307

218

162

159

297

197

307

240

162

- 16

159

185

280

197

89

240

427

240

187

207

197

--125

128

268

414

155

125

252

184

106

Vapor Intrusion Corhparison

V a l u e

(ugm)

22000

042

300000

15

bull 5000

2000

2000

60

011

2000

094

350

700

40

NA

60

0087

1100

11

8000

NA

NA

NA

3500

NA

31

14

22

50

7000

16

bull 600

100000

Chemical of Concern

No

No

No

No

No

No

No

YES

No

No

No

YES

No

No

No

N o bull

bullNo

No

No

No

No

No

No

N o

No

No

No

N o

No

No

No

No

No

Comment

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent notdetected

fflaximCimTdeteetlSffieedsTcomDarisonivalues

Constituent not detected

Constituent not detected

Constituent not detected

Maximum detect exceeds comparison value

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Maximum detect below comparison value

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detectedl

Constituent not detected

Constituent not detected

CoyneVI Memo Tables_09-08-09xls 982009

AR100295

TABLE 2

IDENTIFICATION OF CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR

Coyne Textile Services Facility - Huntington West Virginia

Const i tuent

Volati le Organics

Chloroform -

Chloromethane

13-Dichloropropene (cis)

Cyclohexarie^

Dibrcimochloromethane

DichlonDdifluoromethane

Ethylbenzene

Methyl ethyl ketone

Methyl isobutyl ketone

Methyl tert-butyl ether

Methylene chloride

n-Heptane

n-Hexane

Styrene

Tert-butyl alcohol

Tetrachloroethene

Toluene

13-Dichloropropene(trans)

Triehloroethene

Trichlorofluoromethane

Vinyl bromide

Vinyl chloride

Xylene (0)

Xylenes (mampp)

Frequency of Detection

1 3

0 3

0 3

1 3

0 3

0 3

0 -3

1 3

0 3

0 3

2 3

0 3

3 3

0 3

0 3

3 3

1 3

- 0 3

3 3

P 3

0 3

0 3

1 3

1 3

Min imum Detected

Concentrat ion

(ugm)

5910

ND

ND

52

ND

ND

ND

23

ND

ND

1160

ND

1 4 4

ND

ND

11200

18

ND

91

ND

ND

ND

208

387

Maximuri i Detected

Concentrat ion (ugmS)

bull

5910

ND

ND

52

bull ND

ND

ND

23

ND

ND

1520

ND

183

ND

ND

149000

18

ND

7820

ND

bullND

ND

208

387

Sample vyith Max imum Detect

VP-02

ND

ND

VP-01

bull ND

ND

ND

VP-01

ND

ND

VP-02

ND

VP-02

ND

ND

VP-02

VP-01

ND

VP-03

ND

ND

ND

VP-03

VP-03

Min imum Detection

Limit (ugm3)

20

83

18

138

34

bull 20

17

118

16

14

14

16

- -17

12

--151

18

--23

18

10

1 7 bull

1 7 bull

Maximum Detection

Limit (ugm3)

195

83

182

138

341

198

174

118

164

144

14

164

170

121 -

--151

182

225

175

102

bull 174

174

Vapor Intrusion Compar ison

V a l u e

(ugm)

11

24

NA

2000

1

2000

22

10000

800

30000

52

NA

2000

10000

NA

81

4000

NA

022

7000

NA

28

70000

70000

Chemical o f Concern

YES

No

No

No

No bull

No

No bull

No bull=

No

No

YES

No

No

No

No

YES

No

No

YES

N o

No

No

No

No

Comment

Maximum detect exceeds comparison value

Constituent not detected

Constituent not detected

Maximum detect below comparison value

Constituent not detected

Constituent not detected

Constituent not detected

Maximum detect below comparison value

Constituent not detected

Constituent not detected

Maximum detect exceeds comparison value

Constituent not detected bull

Maximum detect below comparison value

Constituent not detected

Constituent not detected

Maximum detect exceeds comparison value

Maximum detect below comparison value

Constituent not detected

Maximum detect exceeds comparison value

Constituent not detected

Constituent not detected

Constituent not detected bull

Maximum detect below comparison value

Maximum detect below comparison value

Notes

ND - Not Detected

NA - Not Available

- - Constituent detected in every sample detection limit not presented

Values in bold indicate detection limit exceeds comparison values

Target shallow soil gas comparison values corresponding to indoor air concentrations where the soil gas to indoor air attenuation factor = 01 and the target cancer risk is set to ip (presented in Table 2c of USEPA 2002a)

Comparison value for cyclohexane is based on the comparison value for hexane

Coyne VI Memo Tables_09-08-09xls 982009

AR100296

TABLES

EXPOSURE POINT CONCENTRATIONS FOR CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR

Coyne Textile Services Facility - Huntington West Virginia

Chemical of Concern

VolatileOrganics

i24-Trimethylbenzene

12-Dichloroethene (cis)

Chloroform

Methylene chloride

Tetrachloroethene Triehloroethene

Subslab Vapor Source

Concentration (mgm^)

0197

603

591

152

149 782

Transport

Factor^ (unitless)

108E-05

108E-05

108E-05

108E-05

108E-05 108E-05

EPC in

Indoor Air (mgm^)

213E-06

651 E-05

638E-05

164E-05

161E-03 844E-05

Notes

^ Subslab vapor source concentration is based on the maximum detected concentration of samples

VP-01-02 and-03 (see Table 2) -

^ Details of the transport factor calculations are presented in Appendix B

^ Exposure Point Concentration (EPC) in inidoor air is calculated as the subslab vapor concentration TF

Coyne VI Memo Tables_09-08-09xls 982009

AR100297

TABLE 4

FACTORS USED IN DOSE CALCULATIONS INHALATION OF VOLATILE EMISSIONS

Coyne Textile Services Facility - Huntington West Virginia

Symbol

CA

IRA

ET

EF

ED-

BW

AT

Exposure Factor

Constituent Concentration in Air

Inhalation Rate

Exposure Time

Exposure Frequency

Exposure Duration

Body Weight

Averaging Time

Indoor Worker

Constituent-Specific See Table 3

25 m hour

8 hrday

250 daysyear

25 years

bull 70 kg

9125 days (NC)

25550 days (C)

Total Dose = CA x IR^ x ET x EF x ED x 1BW x 1AT

(NC) - Non-carcinogenic Averaging Time

(C) - Carcinogenic Averaging Time

Coyne VI Memo Tables_09-08-09xls 982009

AR100298

TABLES TOXICITY VALUES FOR CHEMICALS OF CONCERN

Coyne Textile Services Facility - Huntington West Virginia

Chemical of Concern

Volatile Organics

124-Trimethylbenzene

12-Dichloroethene (cis)

Chloroform

Methylene chloride

tetrachloroethene

Triehloroethene

Target Organ Critical Effect

blood

bullblood

liver

liver

liver CMS

liver kidney fetus CNS

Chroniclnhalation Reference Dose

(mgkg-day)

200E-03 P

1 OOE-02 R

140E-02 E

286E-01 M

771 E-02 M

1OOE-02 E

Inhalation Cancer ^ Slope Factor

(mgkg-day)^

NA

NA

805E-02 1

165E-03 1

200E-02 0

400E-01 E

(I) - Integrated Risk Information System (IRIS USEPA 2009)

(P) - Provisional Peer-Reviewed Toxicity Value (PPRTV) as presented in USEPA Regional Screening Tables (ORNL 2009)

(R) - Calculated assuming route-to-route extrapolation as per WVDEP

(E)-Provisional value from the National Center for Environmental Assessment (as per WVDEP)

(M)-Chronic Minimal Risk Level (MRL ATSDR 2009)

(0) - Value cited by USEPA Region 3 attributed to other sources (as per WVDEP)

Coyne VI Memo Tables_09-08-09xls 982009

AR100299

TABLE 6

NONCANCER HAZARD INDEX AND POTENTIAL CANCER RISK FOR AN INDOOR WORKER

Coyne Textile Services Facility - Huntington West Virginia

bull

Constituent

Volatile Organics

124-Trinnethylbehzene

12-Dichlorpethene (cis)

Chloroform

Methylene chloride

Tetrachloroethene Triehloroethene

EPC in Indoor Air

(mgm)

213E-06

651 E-05

- 638E-05

164E-05

161 E-03

844E-05

Intake (ADD)

(mgkg-d)

416E-07

127E-05

125E-05

321 E-06

315E-04 l65E-05

RfDi

(mgkg-d)

200E-03

1OOE-02

140E-02

286E-01

771 E-02 1 OOE-02

Hazard

Quotient

208E-04

127E-03

892E-04

112E-05

408E-03 165E-03

Intake (LADD)

(mgkg-d)

) 149E-07

455E-06 bull 446E-06

115E-06

112E-04 590E-06

CSFi

(mgkg-d)

NA

NA

805E-02

165E-03

200E-02

400E-01

Potential

Cancer Risk

NA

NA

359E-07

189E-09

225E-06 236E-06

Total Hazard Index

00081 Total

Cancer Risk 497E-06

Total Blood HI = Total Liver HI =

Total Central Nervous System HI = Total Kidney HI =

Total Fetal HI =

bull 00015 00066 00057 00017 00017

Notes NA = Toxicity values are not available for this endpoint or exposure pathway

Coyne VI Memo Tables_09-08-09xls 982009

AR100300

APPENDIX A

SUBSLAB VAPOR ANALYTICAL DATA

AR100301

Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility Huntington West Virginia

Sample

Consti tuent

Volatile Organics (ugm) 111-Trlchloroethane 1122-Tetrachloroethane 112-Trichloro-122-trifluoroethane 112-Trichloroethane 11-Dichioroethane 11-Dichloroethene 124-Trichloroberi2ene 124-Trimethylbenzene 12-Dibromoethane 12-Dichloroben2ene 12-Dichloroethane 12-Dichloroethene-(cis) -12-Dichloroethene (trans) 12-Dichloropropane 12-Dichlorotetrafluoroethane 135-Trimethylbenzene 13-Butadiene 13-Dichlorobenzene 13-Hexachlorobutadiene 14-Dichlorobenzene 224-trimethVlpentane 2-Chlorotoluene 4-Ethyltoluene Acetone Allyl Chloride Benzene Bromodichloromethane Bromoform Bromomethane Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 13-Dichloropropene (cis) Cyclohexane Dibromochloromethane

Identif ication Sample Date

CAS No

71-55-6 79-34-5 76-13-1 79-00-5 75-34-3 75-35-4 120-82-1 95-63-6 106-93-4 95-50-1 107-06-2 156-59-2 156-60-5 78-87-5 76-14-2 108-67-8 106-99^0 541-73-1 87-68-3 106-46-7 540-84r1 95-49-8

622-96-8 67-64-1 107-05-1 71-43-2 75-27-4 75-252 74-83-9 75-15-0 56-23-5 108-90-7 75-00-3 67-66-3 74-87-3

10061-01-5 110-82-7 124-48-1

lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt

lt lt lt lt lt lt lt lt lt lt lt lt

lt

VP-01 8132009

22 28 31 22 16 16 30 20 31 24 16 16 16 19 28 20 89 24 43 24

1 9 21 20 796 13 13 27 41 16 13 25 18 11 20 83 18 52 34

lt lt lt lt lt lt lt lt lt lt lt

lt lt lt lt lt lt lt lt lt lt lt

lt lt lt lt lt lt lt lt lt

lt lt lt lt

VP-02 8132009

218 2 7 5 307 218 162 159 297

bull 197 307 240 162 369 159 185 280 197 89

240 427 240 187 207 197

1880 125 128 268 414 155 125 252 184 106

5910 83 182 138 341

lt lt lt lt lt lt lt

lt lt lt

lt lt lt lt lt lt lt bull

lt lt lt lt

lt lt lt lt lt lt lt lt lt lt lt lt lt lt

VP-03 8132009

218 275 307 218

bull 162 159 297 197 307 240 162

6030 159 185 280 197 89

240 427 240 187 207 197

1750 125 128 268 414 155 125 252 184 106 195 83 182 138 341

Appx A SG Dataxis Page 1 of 2 982009

AR100302

Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility bull Huntington West Virginia

Consti tuent

Volatile Organics (ugm^) Dichlorodifluoromethane Ethylbenzene Methyl ethyl ketone Methyl Isobutyl ketone Methyl tert-butyl ether Methylene chloride n-Heptane jn-Hexane Styrene Tert-butyl alcohol Tetrachloroethene iToluene 13-Dichloropropene (trans) Triehloroethene Trichlorofluoromethane Vinyl bromide Vinyl chloride Xylene (o) Xylenes (mampp)

Sample Identif ication Sample Date

CAS No

75-71-8 100-41-4 78-93-3 108-10-1

1634-04-4 75-09-2

142-82-5 bull 110-54-3

100-42-5 75-65-0 127-18-4 108-88-3

10061-02-6 79-01-6 75-69-4 593-60-2 75-01-4 95-47-6

179601-23-1

lt lt

lt lt lt lt

lt lt

lt

lt lt lt lt lt

VP01 8132009

20 17 23 16 14 14 16

173 17 12 bull

11200 18 18 91 23 18 10 17 17

lt lt lt lt lt

lt

lt lt

lt lt

lt lt lt lt lt

VP-02 8132009

198 174 118 164 144

1520 164 -183 170 121

149000 151 182

2360 225 175 102 174 174

VP-03 8132009

lt 198 lt 174 lt 118 lt 164 lt 144

1160 lt 164

144 lt 170 ltbull 121

90500 lt 151 lt 182

7820 lt 225 lt 175 lt 102

208 387

Appx A SG Dataxis Page 2 of 2 982009

AR100303

APPENDIX B

CALCULATION OF TRANSPORT FACTORS USED TO ESTIMATE INDOOR AIR CONCENTRATIONS

AR100304

APPENDIX B

Calculation of Transport Factors Used to Estimate Indoor Air Concentrations

This appendix presents the methodology for calculating transport factors that are used to convert subslab

vapor concentrations to concentrations in indoor air 124-Trimethylbenzene 12-dichloroethene (cis)

chloroform methylene chloride tetrachloroethene and triehloroethene were identified as contaminants of

concern (COC) for potential vapor intrusion from subslab vapor associated with the Coyne Textile

Services Facility located in Huntington West Virginia (site) In this appendix the transport factors are

calculated to estimate the concentrations of COC in indoor air of the existing plant building located at the

site ~

Transport Factor for Indoor Air

The concentration of a constituent in indoor air (da) is proportional to the concentration of the constituent

in the subslab vapors immediately beneath the building foundation (ie subslab vapor concentration or

Csubsiab) The following equation is used to calculate da from Csubsiab

^ wja ~ ^subslab X I r

where

Cia = concentration of constituent in indoor air (mgm^) -

Csubsiab^ concentration of constituent in subslab vapors (mgm^) and

TF = transport factor from subslab vapors to indoor air

The transport factor (TF) is an infinite source attenuation coefficient andcan be calculated based on a

model developed by Johnson and Ettinger (1991) t he equation for calculating TF is as follows

(Deff X A B ) ( Q B X L T ) X expKQso i l X Lcrabk)(Dcrack X Acrack)]

exp[ (Qsoi l X Lcrack)(Dcrack X Acrack)] + (Deff X A B ) ( Q B X L T ) + (Deff X AB)(Qsoi l X L j ) X (exp [ (Qso i l X Lcrack)(Dcrack X Acrack)] - 1)

where

Deff = effective diffusion coefficient for vadose zone soil (cm^sec)

AB = area of enclosed space below grade (cm^)

QB = building ventilation rate (cm^sec)

LT = distance from contaminant source to building foundation (cm)

Qsoii = volumetric flow rate of vapors into the building (cm^sec)

Lcrack = foundatlon thickness (cm)

Dcrack = vapor diffusion coefficient through crack (cm^sec) and

Acrack = area of cracks through which vapors can pass (cm^)

AR100305

To solve this equation the USEPAs SG-ADV spreadsheet Version 31 most recently updated in

February 2004 was implemented A combination of site-specific factors and default values from the

Users Guide for Evaluating Subsurface Vapor Intrusion Into Buildings (USEPA 2004) were used as input

values in the model All input values are defined below and presented in Tables B-1-A through B-6-A

bull The initial subslab vapor concentration (Csubsiab) is the maximum detected concentration(in units

of ugm ) of samples VP-01 VP-02 and VP-03 that was presented in Table 3 of the report

bull The depth below grade to the bottom of the enclosed space floor (Lp) is set to 15 cm the default

value provided by USEPA (2004) for a slab-on-grade structure

bull The vapor sampling depth below grade (Lg) is a site-specific value The vapor samples were

collected from immediately beneath the building floor therefore Lj has been set to 15 cm

bull The average soilgroundwater temperature (Ts) is set to 125degC the average value for West

Virginia as estimated frorri Figure 8 of the vapor intrusion users guide (USEPA 2004)

bull The soil type used to estimate vapor permeability is assumed to be sandy loam (SL) The

associated soil properties for a sandy loam soil type are as follows the soil dry bulk density (Pb) is

162 gcm the total porosity (n) is 0387 (cm^-aircm^) and the water-filled porosity (nw) is 0103

(cm -HzOcm )

bull The floor thickness (Lcrack) is set to the USEPA (2004) default value of 10 cm

bull The soil-building pressure differential (AP) is set to the USEPA (2004) default value of 40 gcm-s^

bull The building dimensions are siterspecific based on the existing plant building located at the site

The existing structure is approximately 84000 square feet (Dolphin 2000) therefore the

dimensions are set to 8839 cm (290 feet) length by 8839 cm (290 feet) The USEPA (2004)

default value of 244 cm vyas used for the height

bull Thefloor-wall seam crack width (w) is set to the USEPA (2004)-default value of 01 cm

bull The indoor air exchange rate (ER) is set to 083hour This is the value provided by ASTM (2002)

for commercial and industrial buildings

AR100306

Tables B-1-B through B-6-B present the constituent-specific properties for COC that were used in the TF

calculations Tables B-1-C through B-6-C present the intermediate calculations used to determine the

indoor air attenuation coefficients (ie the transport factors) The shaded boxes in Tables B-1-C through

B-6-C also present the resulting TF values that are applied to the concentrations of COC in subslab

vapor and the estimated indoor air concentrations

References

American Society for Testing and Materials (ASTM 2002) Standard Guide for Risk-Based Corrective Action Applied at Petroleum Release Sites ASTM E-1739-95 (Reapproved 2002)

Johnson PC and RA Ettinger (1991) Heuristic model for predicting the intrusion r-ate of contaminant vapors into buildings Environ Sci Technolpgy 25 1445-1452

Dolphin Environmental LLC (Dolphin 2000) Site Characterization Report Mach 14 2000

United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004

AR100307

APPENDIX B-1-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV Nersion31 0204

Reset to Defaults

ENTER -

Chemical CAS No

(numbers only

no dasties)

95636

ENTER Soil gas

cone

Cg (ngm)

Soil Gas Concentration Data ENTER

Soil gas

OR cone

bull - c bull (PPmv)

197E+02

Chemical

124-Trimethylbenzene

MORE ENTER Depth

below grade to bottom

of enclosed space floor

U bull (cm)

ENTER

Soil gas sampling

depth below grade

U (cm) bull

ENTER

Average soil

temperature Ts

CO

1 15 1 1 5 bull125

ENTER ENTER ENTER Totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hft ha he

(cm) (cm) (cm)

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estirnate OR permeability | soil vapor

permeability) k v bull

(cm)

SL 1 1

MORE ENTER

stratum A SCS

soil type

Lookup Soil Parameters

ENTER stratum A soil dry

bulk density P

(gcm)

ENTER Stratum A soil total porosity

(unitless)

ENTER bull stratum A soil water-filled

porosity

(cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

nlaquo

(unitless)

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gchi-s^)

ENTER Enclosed

space floor

length bull LB

(cm)

ENTER Enclosed

space floor

width WB

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

bull Floor-wall seam crack

width w

(cm)

bullENTER

Indoor air exchange

rate ER

(1h) bull

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bidg OR

Leave blank to caicuij

(Lm)

Appx B-1 124-TMBxls 1 of 3 982009

AR100308

APPENDIX B-1-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of ^ bull law constant law constant vaporization at Normal

Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temperature boiling point point temperature weight

D bull Dbdquo H T R bull AHbdquo TB Tc IVIW

Unit risk Reference

factor cone URF RfC

(cms) (cmls) (atm-mmol) CO (calmol) (degK) (degK) (gmol) bull (ugm)- (mgm)

1 606E-02 1 792E-06 1 bull 614E-C3 1 25 1 9369 1 44230 | 64917 1 12020 1 OOE+00 1 60E-03 1

Appx B-1 124-TMBxls 2 of 3 982009

AR100309

APPENDIX B-1-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

(sec)

Source-building

separation

LT bull

(cm) bull

Stratum A soil

air-filled porosity

Q A

Stratum B soil

air-filled porosity

(cmcm) (cmcm)

Stratum C soil air-filled porosity

(cmcm)

Stratum A effective total fluid

saturation

Se

(cmcm)

Stratum A soil

bullintrinsic permeability

^ (cm)

stratum A Stratum A Floor- soil soli wall BIdg

relative air effective vapor seam Soil bull ventilation permeability permeability perimeter gas rate-

kfg ky Xgrack c o n e - QbuHdinpound

(cm) - (cm) (cm) (ngm) (cms)

946E+08 1 0284 0284 0284 0184 596E-09 0901 537E-09 35357 I 197E+02 | 439E+06 |

Area of enclosed

space below grade

As (cm)

Crack-to-total area ratio

1 bull

(unitless)

Crack depth

below grade

Zcfack

(cm)

Enthalpy of vaporization at

ave soil temperature

AHvjs

(calmol) bull

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law constant at

ave soil bull temperature

bull HTS

(unitless)

Vapor bull viscosity at

ave soil temperature

HTS

(gcm-s)

Stratum A

effective diffusion

coefficient

D (cms)

Stratum-B

effective diffusion coefficient

DB (cms)

Stratum C effective diffusion

coefficient

D-c (cms)

Total - overall effective diffusion

coefficient

D ^ (cms)

Diffusion path

length

L-

(cm)

I 787E+07 I 449E-05 | 15 | 11661 260E-03 111E-01 176E-04 I 612E-03 j OOOE+00 | OOOE+00 | 612E-03 j

bull Convection path

length

Lp

(cm)

Source vapor cone

^source

(ngm)

Crack radius

Tcfack

(cm)

Average vapor

flow rate into bIdg

Qsoii

(cms)

Crack effective diffusion

coefficient pcrack

(cms)

Area of CTack

Acack

(cm)

Exponent of equivalent foundation

Peclet number

exp(Pe)

(unitless)

bull bull - bull bull bull bull

1 15 1 197E+02 1 010 1 474E+01 612E-03 bull 354E-t-03 1 336E+09

Infinite source Indoor

~ attenuation coefficient

a

(unitless)

108E-05

Infinite source

btJbldgjJSv-L ^Ppncji3i-

virhpbiiilding bullbull ^lHltti^m)ilg

213E-03

Unit risk

factor

URF

(ngm)-

Reference cone

RfC (mgm)

NA 60E-03 1

I END

Appx B-1 124-TMBxls 3 of 3 982009

AR100310

APPENDIX B-2-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV Nersion31 020^

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

156592

Soil Gas Concentration Data ENTER

Soil gas

cone OR c

(ngm) bull

ENTER Soil bull-gas

cone

c (ppmv)

603E+03 1

Chemical

cis-12-Dichloroethylene

MORE ENTER Depth

below grade to bottom

of enclosed space floor

LF

(cm)

ENTER

Soil gas sampling

depth below grade

U (cm)

ENTER

Average soil

temperature bull Ts

(degC)

1 15 1 bull 15 125

ENTER ENTER ENTER Totalsmust add ijp tb value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hA hB he

bull (cm) (cm) (cm)

15 1 1

ENTER Soil

straturh A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estimate OR permeability | soil vapor

permeability) kv

(cm)

SL 1 |

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

P (gcm)

ENTER Stratum A soil total porosity

bull n

(unitless)

ENTER Stratum A

soil water-filled porosity

(cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

ENTER Stratum B

soil water-filled porosity

ENTER Stratum C

SCS soil type

(unitless) (cmcm)

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure differential

AP

(gcm-s)

ENTER Enclosed bull

space floor

length

LB (cm)

ENTER Enclosed

space floor

width WB

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER

Average vapor flow rate into bIdg

OR Leave blank to calculi

Qsoil

(Lm)

Appx B-2 cis-12-DCExls 1 of 3 982009

AR100311

APPENDIX B-2-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Diffusivity in air

Da

(cms)

Diffusivity in water

Dw (cms)

Henrys law constant at reference temperature

H

(atm-mmoi)

Henrys law constant

reference temperature

bull T R

CC)

Enthalpy of vaporization at

the normal boiling point

AHbdquob

(calmol)

Normal boiling point

TB

(degK)

Critical temperature

Tc (degK)

Molecular weight

MW

(gmol)

Unit risk

factor URF

(ngm)

Reference cone

RfC (mgm)

1 736E-02 1 113E-05 1 407E-03 j 1 25 1 bull 7192 1 33365 1 54400 1 9694 1 OOE+00 j 35E-02 1

Appx B-2 cis-12-DCExls 2 of 3 982009

AR100312

APPENDIX B-2-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

stratum A Stratum B Stratum C Source- soil soil soil

Exposure building air-filled air-filled air-filled

duration separation porosity porosity porosity

T LT ea e^ bull e= (sec) (cm) (cmcm) (cmcm) (cmcm)

I 946E+08n^

Stratum A Stratum A Stratum A Stratum A Floor-effective soil soil soil wall total fluid intrinsic relative air effective vapor seam

saturation permeability permeability permeability perimeter

Ste kj krg ky Acrack

(cmcm) (cm) (cm) (cm) (cm)

Soil gas

cone (ngm)

I 0284 I 0284~ 0284 0184 I 596E-09 | 090T 537E-09 35357 603E+03

BIdg ventilation

rate

JbulldinE

(cms)

439E+06

Area of enclosed

space below grade

AB

(cm)

Crack-to-total

area ratio

n (unitless)

Crack depth below grade

Zltiack (cm)

Erithalpy of vaporization at

ave soil temperature

AHvTs (calmol)

Henryslaw constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law constant at

ave soil temperature

HTS

(unitless) bull

Vapor viscosity at

ave soil bull temperature

HTS

bull (gcm-s)

Stratum A

effective bull diffusion

coefficient

D^A-(cms)

Stratum B

effective bull diffusion

coefficient

D=B

(cms)

Stratum C

effective diffusion bull

coefficient

D=e (cms)

Total overall

effective diffusion

coefficient

DT

(cms)

Diffusion path

length

Ld

(cm)

I 787E+07 I bull449E-05 | 15 bull7709 230E-03 982E-02 176E-04 | 743E-03 | OOOE+00 | OOOE+00 | 743E-03 |

bull bull bull -

Convecfion path -bull

length

Lp (cm)

Source vapor cone

-source

(Mgm)

Crack radius

fcrack

(cm)

Average vapor

flow rate into bIdg

Qaoil bull

(cms)

Crack effective diffusion

coefficient pcack

(cms)

Area of crack

crack

(cm)-

Exponent of equivalent foundation

Peclet number

exp(Pef)

(unitless)

bull

1 15 -1 603E+03 1 010 1 474E+01 743E-03 354E+03 1 697E+07

Infinite source Indoor

attenuation coefficient

poundbullbullbull C t

pound(unitless)

bullsiilaquogt j ii08E-05

Infinite [ source

bIdg cone

Cbujidjng

(pgm)

651 E-02 iKrt

Unit risk

factor

URF

(ngm)-

Reference cone

RfC

(mgm)

NA 35E-02 1

I END I

Appx B-2 cis-12-DCExls 3o f3 982009

AR100313

APPENDIX B-3-A DATA ENTRY SHEET

Coyne Texti le Services - Hunt ington West Virginia

SG-ADV Version 31 0204

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

67663

Soil Gas Concentration Data ENTER ENTER

Soil Soil gas gas

cone OR cone c C

(^gm) (ppmv)

591 E+03

bull

Chemical

Chloroform

MORE ENTER Depth

below grade tb bottom

of enclosed space floor

bull LF

(cm)

ENTER

Soil gas sampling depth

below grade

(cm)

ENTER

Average soil

temperature-Ts

CO bull

1 15 1 15 1 125

ENTER ENTER ENTER Totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

IIA hs he (cm) (cm) (cm)

1 5 bull 1 1

ENTER ENTER Soil - bull

stratum A User-defined SCS stratum A

soil type bull soil vapor (used to estimate OR permeability

soil vapor k

bull permeability) (cm) 1

SL 1 1 bull

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A soil dry

bulk density

Pb (gcm)

ENTER Stratum A soil total porosity

nV (unitless)

ENTER Stratum A

-soilwater-filled bullporosity

Sraquo (cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

(unitless)

ENTER Stratum B

soil water-filled porosity

bull ebdquo=

(cmcm) bull

ENTER Straturri C

SCS bull soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

- c rack

(cm)

ENTER

Soil-bldg pressure

differential AP^

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor

width bull W B

(cm)

ENTER

Enclosed space

height HB

(cm)

ENTER

bull Floor-wall^ seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bidg OR

Leave blank to calculi

Qsoil bull

(Lm)

I -I

Appx B-3 Chloroformxls 1 of 3 982009

AR100314

APPENDIX B-3-B CHEMICALPROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Diffusivity in air

D (cms)

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffijsivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature

Dbdquo H TR A H bdquo TB Tc

(cm s) (atm-m mol) ro (calmol) (degK) (degK)

Molecular weight

MW

(gmol)

Unit risk

factor URF

(ngm)-

Reference cone

RfC

(mgm)

104E-01 100E-05 I 366E-03 25 6988 33432 53640 11938 I 23E-05 | OOE+00

Appx B-3 Chloroformxls 2 of 3 982009

AR100315

APPENDIX B-3-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure

duration

(sec)

Source-

building

separation

LT

(cm)

Stratum A

soil

air-filled

porosity

Sa

( cm cm )

Stratum B

soil

air-filled

porosity

( cm cm )

Stratum C

soil

air-filled

porosity

( c m c m )

Stratum A

effective

total fluid

saturation

( c m c m )

Stratum A

soil

intrinsic

penmeability

k

(cm )

Stratum A

- soil

relative air

permeabil i ty

(cm )

Stratum A

soil

effective vapor

permeability

kv

(cm )

Floor-

wall

seam

perimeter

gtcrack

(cm)

Soil gas

cone

(ngm)

BIdg

venfilation

rate

^buildlriE

(cms)

I 9 4 6 E + 0 8 ~ T I 0284 T 596E-09 I 0-901 I 537E-09 | 35357 | 591 E+03 j 439E+06 | 1 0 284 0284 0184

Area of

enclosed

space

below

grade

A B

( c m )

Crack-

to-total

area

ratio

n

(unitless)

Crack

depth

bull below

grade

^crack

(cm)

Enthalpy of

vaporization at

ave soil

temperature

AHTs bull

(calmol)

Henry s law

constant at

ave soil

temperature

HTS

(a tm-m mol j

Henrys law

constant at

ave soil

bull temperature

HTS

(unitless) bull

Vapor

viscosity at

ave soil-

temperature

^HTS

(gcm-s)

Stratum

A

effective

diffusion

coefficient

(cm s)

Stratum

B

effective

difftjsion

coefficient

D B

(cms) bull

S t ra tum

C

effective

diffusion

coefficient

Dc

(cm s)

Total

overall

effective

bull diffusion

coefficient

D T

(cm s)

Diffi jsion

path

length

Ld

(cm)

I 787E+07 I 449E-05 j - bull 15 7528 210E-03 896E-02 176E-04 I 105E-02 | OOOE+00 | OOOE+00 | 105E-02

Convection

path length

Lp

(cm)

Source

vapor

cone -

^source

- (ngm)

Crack

radius

Tcrack

(cm)

Average

vapor

flow rate

into bidg

Qsoil

(cms)

Crack

effective

diffusion

coefficient Qcrack

bull (cms)

Area of crack

Acrack

(cm)

Exponent of

equivalent

foundation

Peclet number

exp(Pe)

(unitless)

V bull bull

1 15 1 591 E+03 1 010 1 474E+01 105E-02 354E+03 1 355E+05

Infinite

source

indoor

attenuation

coefficient

d

(unitless)

bull 108E-05

Infinite

source

bIdg

cone

^ b u i l d i n g

i (^gm)

bull bull

i 638E-02 -

Unit

risk bull factor

URF

(ngmY

Reference

cone

RfC

(mgm)

~ 23E-05 NA 1

I END

Appx B-3 Chloroform xls 3 of 3 982009

AR100316

APPENDIX B-4-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ersion 31-020^

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

nodashes)

bull 75092

ENTER Soil gas

cone

c (ngm)

Soil Gas Concentration Data ENTER

Soil gas bull

OR cone

bull C

(ppmv)

152E+03

bull bull

Chemical

Methylene chloride

MORE

MORE 4gt

ENTER Depth

below grade to bottom

of enclosed space floor

LF -

(cm)

ENTER

Soil gas sampling depth

below grade

bull U

(cm)

ENTER

Average soil

temperature

Ts bull CC)

bull bull bull bull

1 15 1 15 125

ENTER Totals

Thickness of soil

stratum A h

(cm)

ENTER ENTER must add up to value of Ls (cell F24

Thickness Thickness of soil of soil

stratum B stratum C (Enter value or 0) (Enter value or 0)

he he bull

(cm) bull (cm) -

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(usedto estimate OR perrrieability | soil vapor

permeability)

k bull

(cm)

SL 1 bull 1

ENTER Stratum A

SCS soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

Pb (gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Stratum A

soil water-filled porosity

9w (cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

Pb^

(gcm)

ENTER Stratum B soil total porosity

n^

(unitless)

ENTER Stratum B

soil water-filled porosity

(crhcm)

ENTER Stratum C

SCS soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE 4gt

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

bull Soil-bldg pressure

differential AP^

(gcm-s)

ENTER Enclosed

space floor

length LB

(cm)

ENTER Enclosed

space floor

width bull W B

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width

w

(cm)

ENTER

Indoor air exchange

rate

ER (1h)

ENTER Average vapor

flow rate into bidg OR

Leave blank to calculc

Qsoil

(Lm)

10 40 8839 8839 244 01 083

Appx B-4 MCxIs 1 of 3 982009

AR100317

Diffijsivity in air

D

APPENDIX B-4-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffusivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature

Pw H TR AHt TB TC

Molecular weight

MW

Unit risk

factor URF

Reference cone

RfC

(cms) (cms) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) bull (ngm)- (mgm)

bull bull

1 101E-01 1 117E-05 1 218E-03 1 25 | 6706 1 31300 1 51000 1 8493 1 47E-07 1 30E+00 1

Appx B-4 MCxIs 2 of 3 982009

AR100318

APPENDIX B-4-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

T

(sec)

Source- -building

separation

LT

(cm)

Stratum A soil

air-filled porosity

e a bull

(cmcm)

Stratum B soil

bullair-filled porosity bull

ea^ (cmcm)

Stratum C soil

air-filled porosity

ea= (cmcmj

Stratum A effective total fluid

saturation

Sc bull

(cmcm)

Stratum A soil

intrinsic pemneability

ki (cm)

Stratum A soil

relative air permeability

^ ^ g

(cm)

stratumA bull soil effective vapor permeability

K (cm)

Floor-wall

seam perimeter

Xcrack

(cm)

Soil gas

cone (ngm)

BIdg ventilation

rate

Qbuildinc

(cms)

1 946E+08

Area of -enclosed

space below

bull grade

AB

(cm)

1

Crack-to-total

area rafio

Tl

(unitless)

0284 1

Crack depth below grade

Zcrack

(cm)

0284 1

bull Enthalpy of vaporization at

ave soil temperature

AHTs (calmol)

0284

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

0184

Henrys law constant at ave soil

temperature

HTS

bull (unitless)

1 596E-09

Vapor viscosity at

ave soil temperature

Mrs (gcm-s)

0901

Stratum A

effective diffusion

coefficient

D (cms)

537E-09

Stratum B

effective diffusion

coefficient

D-B (cms)

35357 1

Stratum C -

effective diffusion

coefficient

D-c ^ (cms)

152E+03

Total bull overall

bull effective diffusion

coefficient

D ^

(cms)

440E+06 1

Difftjsion path

length

Ld (cm)

1 787E+07

Convection path

length

Lp (cm)

4 49E-05

Source vapor cone

Csource

(ngm)

15 1

Crack radius

Tcrack

(cm)

7007 bull 1

Average vapor

flow rate intobldg

Qsoil

(cms)

130E-03

Crack effective diffusion

coefficient pcrack

(cms)-

555E-02

bull ^

Area of crack

Acrack

(cm) bull

1 176E-04

Exponent of equivalent foundation

Peclet number

exp(Pe)

(unitless) bull

bull bull

1 15

1 END

152E+03 010 1 474E+01 1 102E-02 354E+03 1 519E+05

102E-02

Infinite source

indoor ^attenuation coefficient

bull a

(unitless)

aiii08E-05

0 OOE+00

bull

Infinite bull source

bIdg ^ cone

^bu i l d i ng

(MQm)

164E-02

OOOE+00 1

Unit risk

factor

URF

(ngm)-

47E-07 1

102E-02 j

Reference cone

RfC

(mgm)

30E+00 j

1 1

Appx B-4 MCxIs 3 of 3 982009

AR100319

APPENDIX B-5-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ^erslon 31 0204

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

127184

Soil Gas Concentration Data ENTER ^ ENTER

Soil -Soi l bull gas gas

cone OR cone Cg C bull

(tgm) (ppmv)

149E+05 1

Chemical

bull Tetrachlbroethylene

MORE 4

ENTER Depth

below grade to bottom

ofenclosecJ space floor

LF

(cm)

ENTER

Soil gas bull sampling

depth below grade

u bull (cm)

ENTER

Average bullsoil

temperature - Ts

ro 1 1 5 1 15 1 125 bull

ENTER ENTER ENTER totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hft bull he bull he

(cm) (cm) (cm)

bull 1 5 1 - 1

ENTER ENTER Soil

stratum A User^defined bull SCS bull stratum A soil type soil vapor

(used to estimate OR perrrieability soil vapor K bull

permeability) (cm) 1

SL 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

Pb

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Sitratum A

soil water-filled bull porosity

(cmcm)

ENTER Stratum B

SCS soiltype

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

Pb^

(gcm)

ENTER Stratum B soil total porosity

Ajnitless^

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS soil type

LookupSoil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

VS

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor width

W B

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width

w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

ENTER Average vapor

flow rate into bidg OR

Leave blank to calcul

bull Qsoil

(Lm)

10 40 8839 8839 244 01 083

Appx B-5 PCExIS 1 of 3 982009

AR100320

APPENDIX B-5-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal Unit

Diffusivity Diffusivity at reference reference the riormal boiling Critical Molecular risk Reference in air in water temperature temperature boiling point point teriiperature weight factor cone

Da Dbdquo H TR AHb TB Tc MW URF RfC

(cms) (cnis) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) (^gm)- (mgm)

1 720E-02 1 820E-06 1 184E-02 1 25 1 8288 1 39440 1 62020 1 16583 1 59E-06 1 60E-01 1

J

AppxB-5PCExls 2 of 3 - 982009

AR100321

APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

T

(sec)

Source-building

separation

LT

bull (cm)

Stratum A soil

air-filled porosity

Oa (cmcm)

Stratum B - soil air-filled porosity

ea (cmcm)

Stratum C soil

air-filled porosity

ea= - (cmcm)

Stratum A effective total fluid

saturation

sbdquo (cmcm)

Stratum A soil

intrinsic permeability

ki (cm)

Stratum A soil

relative air permeability

- ^ g

(cm)

Stratum A soil

effective vapor permeability

kv (cm)

Floor-wall

seam perimeter

^crack

(cm)

Soil gas

cone

(ngm)

BIdg venfilation

rate

Qbuildins

bull (cms)

bull bull

1 946E+08

Area of enclosed

space below grade

AB

(cm)

1

bullCrack-to-total

area ratio

1 (unitless)

0284 1

Crack bull depth below grade

Zcrack

(cm) -

0284 1

Enthalpy of vaporization at bull

ave soil temperature

bull A H V TS

(calmol)

0284

Henrys law constant at

ave soil temperature

HTS (atm-mmol)

0184

-Henrys law constant at

ave soil temperature

HTS

(unitless)

1 596E-09

Vapor viscosity at

ave soil temperature

HTS

(gcm-s)

0901

Stratum A

effective diffusion

coefficient bull D = bull

(cms)

537E-09

Stratum B

effective diffusion

coefficient

D--B (cms)

35357 1

Stratum C

effective diffusion bull

coefficient

D-c (crris)

149E+05

Total overall

effective bulldiffusion coefficient

DT

(cms)

440E+06 1

Difftjsion path

length

U (cm)

1 787E+07

Convection path

length

bull Lp

(cm)

4 49E-05

Source vapor cone

^source

(ngm)

15 1

Crack radius

Tcrack

(cm)

9528 1

Average vapor

flow rate intobldg

Qsoil (cms)

908E-03

Crack effective diffusion

coefficient pcrack

bull ( c m s ) bull

387E-01

Area of crack

Abdquoack (cm)

1 176E-04

Exponent of equivalent foundafion

Peclet number

exp(Pe)

(unitless)

bull

1 15-

1 END

149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08

727E-03

Infinite source indoor

attenuation coefficient

a

(unitless)

108E-05

OOOE+00

Infinite source

bIdg cone

Cburldtng

(Mgm)

161 E+00

OOOE+00 1

Unit risk

factor

URF

(ugm)-

59E-06 1

727E-03

Reference cone

RfC (mgm)

60E-01

1 1

Appx B-5 PCExls 3 of 3 982009

AR100322

APPENDIX B-6-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ersion31 0204

Reset to Defaults

t

Soil Gas Concentration Data ENTER

Chemical CAS No

(numbers only

no dashes)

79016

ENTER ENTER Soil Soil gas gas

cone OR cone C C -

bull (ngm) (ppmv)

782E+03

Chemical

Trichloroethylene

MORE ENTER Depth

below grade to bottom-

of enclosed space floor

LF

(cm)

ENTER

Soil gas sarnpling

depth below grade

U (cm)

ENTER

Average soil

temperature Ts

(degC)

1 15 1 15 t 125

ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e

(cm) (cm) (cm)

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estimate OR permeability soil vapor

permeability)

k (cm)

bull S L 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil bull-Parameters

ENTER Stratum A

soil dry bulk density

P b -

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Stratum A bull

soilwaterrfilled porosity

(cmcm) bull

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

bull P ^ (gcm)

ENTER Stratum B soil total

porosity

nlaquo

(unitless) -

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS bull soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor

width W B

(cm)

ENTER

Enclosed space height

H B bull

( c m ) bull

ENTER

Floor-wall seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bIdg OR

Leave blank to calculc

Qsoil

(Lm) -

Appx B-6 TCExIs 1 of 3 982009

A

AR100323

APPENDIX B-6-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight

Da Dbdquo H TR AH^b TB TC MW

Unit risk Reference

factor cone URF RfC

(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)

1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1

Appx B-6 TCExIs 2 of 3 982009

AR100324

APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

(sec)

Source-building

separation LT

(cm)

Stratum A soil

air-filled porosity

bull ea (cmcm)

Stratum B Soil

air-fllled porosity

e^ bull (cmcm)

Stratum C soil

air-filled porosity

(cmcm)

StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air

saturation permeability permeability

S|e k krg (cmcm) (cm) (cm)

Stratum A Floor-soil wall BIdg

effective vapor seam Soil ventilafion permeability perimeter gas rate

k^ bull Xack c o n e Qbuildins

(cm) (cm) (ngm) (cms)

946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |

Area of enclosed

space below grade

AB

(cm)

Ciack- to-total

area ratio

1 (unitless)

Crack depth below grade

Zcrack

(cm)

Enthalpy of vaporization at

ave soil temperature

A H J S

(calmol)

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law bull constant at

ave soil temperature

HTS

(unitless)

Vapor viscosity at

ave soil temperature

|JTS

(gcm^s)

Stratum A

effective diffusion

coefficient

(cms)

Stratum B

effective -diffusion

coefficient

D=B (cms)

Stratum ^ C effective diffusion

coefficient

D=c (cms)

Total overall

effective diffusion

coefficient

DT

(cms)

I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03

Diffusion path

length

Li (cm) bull

Convection bull path

length

Lp

(cm)

Source vapor cone bull

^source

(ngm)

Crack radius

rcrack

(cm)

Average vapor

- flow rate intobldg

Qsoil

(cms)

Crack effective diffusion

bull coefficient Qcrack

(cms)

Area of crack

^crack

(cm)

Exponent of equivalent foundation

Peclet bull number

exp(Pe)

(unitless)

bull bull

1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07

Infinite source Indoor

attenuation coefficient

a

(unitless)

108E-05

Infinite source

bIdg concgt

^building

(ngm)

844E-02

Unit risk

factor

URF

(ngm)-

Reference cone

RfC

(mgm)

1 1E-04 1 40E-02 1

END

Appx B-6 TCExIs 3 of 3 982009

AR100325

Office of Waste Management 1356 Hansford Street

Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256

West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director

ORDER

ISSUED UNDER THE

HAZARDOUS WASTE MANAGEMENT ACT

CHAPTER 22 ARTICLE 18

OF THE WEST VIRGINIA CODE^ AS AMENDED

y Order Number HW-011-80

To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704

ATTEMTION MREDARMON

Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull

AR100326

ViWJ011-laquo9 PageNunil)er2

BASIS FOR ORDER

As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following

A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^

B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator

C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities

0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94

^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement

P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following

1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater

2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was

^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment

CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable

CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order

AR100327

H W - 0 1 1 - 9 9 Page Number 3

REQUIREMENTS OF ORDER

Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows

1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^

2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore

remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling

GENERAL PROVaiONS

1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order

2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order

3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order

Effective Date

Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief

Wt T 1 V Oflice of Waste Management

AR100328

^ ^ S I S

^wmmmmamn

AR100329

Page 11: SDMS DocID 2121999 · International Enterprises Corp. building (Coyne Building), which is located at 1111 Vernon Street, Westmoreland District, Wayne County, West Virginia. The following

Risk-Based Rerfiedies

R B R Consulting Inc 650 Shady Drive Beaver Falls PA 15010

Phone724-846-4096 Fax 724-846-6974

MEMORANDUM

TO John Meeks Triad Engineering Inc

FROM Bruce Fishman

DATE September 82009

SUBJECT Evaluation of Potential Risks Associated with Vapor Intrijsion to Indoor Air Coyne Textile Services Facility - Huntington West Virginia

bull V bull bull bull

This memorandum presents a risk evaluation for potential risks associated with vapor intrusion to indoor air at the Coyne Textile Services Facility located in Huntington West Virginia (site) This evaluation was conducted according to West Virginia Department of Environmental Protection (WVDEP) and United States Environmental Protection Agency (USEPA) methodologies

DATA INCLUDED 1N THE EVALUATION

This evaluation includes three subslab vapor samples (VP-01 VP-02 and VP-03) collected from immediately beneath the floor of the existing site building Table 1 lists the subslab vapor samples included in this risk assessment Samples were analyzed for volatile organic compounds (VOCs) by USEPA Method TO-15 Complete analytical data for these samples are provided in Table A-1 of Appendix A

The analytical results of the subslab vapor samples were compared to the target shallow soil gas comparison values presented in Table 2c of the USEPA vapor intrusion guidance document (2002a) These companson values are generic soil gas screening values that are protective of indoor air for residential land uses and represent concentrations in-sliallow soil gas based on a target risk level of 1 x 10reg andor a hazard index of 1 The comparison is presented in Table 2

As indicated in Table 2 the following constituents are identified as contaminants of concern (COC) for the vapor intrusion to indoor air pathway 124-trimethylbenzene 12-dichloroethene (cis) chloroform methylene chloride tetrachloroethene and triehloroethene

ESTIMATION OF INDOOR AIR CONCENTRATIONS

The concentrations of COC in indoor air associated with vapor intrusion from subslab vapor were estimated using methodologies outlined in the Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings (USEPA 2004) A transport factor (TF) is required that will relate the

Page 1 of 5 -

AR100288

Risk-Based Remedies

R B R Consulting Inc

constituent concentration in subslab vapor to the concentration in indoor air The TF is dependent on the diffusion coefficient and other properties that will affect the transfer of constituents into air such as distance from the source to tlie breathing zone soil properties and building properties A site-specific building size of 84000 square feet (Dolphin 2000) and a soil type of sandy loam were used in the calculation of TF The TF is determined using calculationsbased on the Johnson and Ettinger (1991) vapor intrusion model Details of the TF calculations are provided in Appendix B

Subslab vapor concentrations are converted to indoor air concentration by applying the TF as follows

Cja ^ Csubslab X I r

The TF for each COC along with the resulting concentrations of COC in indoor air are presented in Tables

EXPOSURE EVALUATION

Noncarcinogenic health effects are evaluated by calculating the average dose of a constituent over the course of the exposure period This dose is termed the Average Daily Dose (ADD) Potential carcinogenic health effects are evaluated in terms of an individuals theoretical increased risk of developing cancer over a lifetime Although the duration of exposure to a constituent release generally does not last for an entire lifetime constituent intake for carcinogens is estimated as the average dose over a human lifetime (70 years) This lifetime dose applies specifically to the evaluation of carcinogenic effects and is termed tine Lifetime Average Daily Dose (LADD) In a risk assessment the calculated ADD or LADD are estimated quantitatively using assurnptions about the duration frequency and magnitude of exposure experienced by each potential receptor and assumptions about the constituent properties that influence absorption

The quantitative estimation of constituent intake involves the incorporation of numerical assumptions for a variety of exposure parahneters Exposure assumptions used in these intake calculations are based on WVDEP (2001) or USEPA (1989 2002b) recommended values The factors and equation for inhalation of vplatiles is presented in Table 4 and described below

bull Inhalation Rate and Exposure Time WVDEP (2001) and USEPA (2002b) guidance recommend that an inhalation rate of 20 m day be used for workers For an exposure time of 8 hours (a typical workday) this results in an inhalation rate of 25 m hour

bull Exposure Frequency and Duration Default exposure factors for indoor workers are provided by WVDEP (2001) Exposure frequency for the worker is 5 days per week for 50 weeks a year or 250 days per year The exposure duration for these workers is 25 years which is the 95th percentile value ai cording to the Bureau of Labor Statistics (USEPA 1989)

bull Body Weight The default value for average body weight of an adult is 70 kg based on WVDEP (2001) and USEPA guidance (1989 2002b)

Page 2 of 5

AR100289

Risk-Based Remedies

R B R Consulting Inc

bull Averaging Time As described above the doses for noncarcinogenic health effects are averaged oyer the specific period of exposure for a given receptor Noncarcinogenic

averaging times are therefore calculated by multiplying the exposure duration for the receptor by 365 daysyear Carcinogenic health effects are calculated over a lifetime exposure so the value recommended by WVDEP (2001) and USEPA (2002b) for average lifetime 70 years was used for exposure duration The resulting carcinogenic averaging time is 25550 days

TOXICITY VALUES

Noncarcinogenic responses are evaluated numerically using parameters known as the hazard quotient (HQ) and hazard index (HI) the HQ is obtained by dividing the ADD for a constituent by the reference dose (RfD) Each dose calculation with a specific combination of constituent receptor and exposure pathway will have a distinct ADD and calculated HQ HQs associated with all constituents for a particular pathway are summed to yield the HI

In order to estimate the theoretical excess lifetime cancer risk the LADD of a constituent is multiplied by the cancer slope factor (CSF) For each pathway this calculation is carried out for each applicable constituent and the risks are summed to obtain the total potential risk due to that pathway

Toxicity values for each constituent are presented in Table 5 the toxicity values were obtained from the following sources

bull Integrated Risk Information System (IRIS) on-line database provided by USEPA (2009)

bull The USEPAs Provisional Peer-Reviewed Toxicity Values (PPRTV) as presented in the USEPA Regional Screening Tables (ORNL 2009)

bull Provisional value from the National Center for Environmental Assessnient (as per WVDEP)

bull The Agency for Toxic Substances and Disease Registrys (ATSDR) Minimal Risk Levels (MRLs ATSDR 2009) and

bull Value cited by USEPA Region 3 attributed to other sources (as per WVDEP)

RISK CHARACTERIZATION

Potential noncarcinogenic effects associated with exposure to COC at the site are estimated by comparing calculated intakes with the contaminant-specific RfDs The total HI was calculated by summing the individual HQs An HI value equal to or less than 1 indicates thatthelikelihopd of ah adverse noncancer effect would be negligible (USEPA 1989) An HI greater than 1 indicates that additional evaluation of the case is warranted

Theoretical excess lifetime cancer risks associated with exposure to COC from the site were calculated by comparing estimated intakes to constituent-specific CSFs Summed theoretical

Page 3 of 5

AR100290

Risk-Based Remedies

R B R Consulting Inc

excess risks are calculated by combining constituent-specific risks The results may be compared with target benchrharks for acceptable risk Various demarcations of acceptable risk have been established by regulatory agencies WDEP (2001) presents a target cancer risk of 1 x 10 for nonresidential scenarios USEPA (1991) considers potential cancer risks in the range of 1 x 10reg to 1 X 10 to be acceptable

Constituent-specific results for the indoor worker are presented in Table 6 For the indoor worker exposed to COC in indoor air (vapor intrusion from subslab vapor) the total HI is 00081 and the potential cumulative cancer risk is 497 X 10reg

These results meet both WVDEP and USEPA benchmarks indicating that the site poses negligible potential for human health risk for indoor workers

CONCLUSIONS

The results of this focused risk evaluation indicate that potential risks associated with vapor intrusion exposure of indoor workers to constituents that may volatilize from subslab vapor are within the acceptable benchmarks established by WVDEP and USEPA No further evaluation of the vapor intrusion pathway is warranted for the site

REFERENCES

Agency for Toxic Substances and Disease Registry (ATSDR 2009) Minimal Risk Levels (MRLs) Available at httpvtfwwatsdrcdcqovmrisindexhtml

Dolphin Environmental LLC (Dolphin 2000) Site Characterization Report Mach 14 2000

Johnson PC and RA Ettinger (1991) Heuristic model for predicting the intrusion rate of contaminant vapors into buildings Environ Sci Technology 25 1445-1452

Oak Ridge National Laboratory (ORNL 2009) Regional Screening Levels for Chemical Contaminants at Superfund Sites April 15 2009 Available online httpwwwepagovreg3hwmdriskhumanrb-concentration_tableindexhtm

United States Environmental Protection Agency (USEPA 1989) Risk Assessment Guidance for Superfund Volume I PartA Human Health Evaluation Manual EPA5401-89002

United States Environmental Protection Agency (USEPA 1991) Risk Assessment Guidance for Superfund Volume I Part B Development of Risk-Based Remediation Goals Office of Emergency and Remedial Response OSWER Directive 92857-018

United States Environmental Protection Agency (USEPA 2002a) Draft Guidance for Evaluating the Vapor Intrusion to Indoor Air Pathway from Groundwater and Soils Office of Solid Waste and Emergency Response Pub No 92856-10 December 2002

Page 4 of 5

AR100291

Risk-Based Remedies

R B R Consul t ing Inc

United States Environmental Protection Agency (USEPA 2002b) Supplemental Guidance for Calculating Soil Screening Levels for Superfund Sites Office of Solid Waste and Emergency Response December

United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004

United States Environmental Protection Agency (USEPA 2009) Integrated Risk Information System (IRIS) On-line database wwwepaqoviris

West Virginia Department of Environmental Protection (WVDEP 2001) West Virginia Voluntary Remediation and Redevelopment Act-Guidance Manual Version 21 March 13

Page 5 of 5

AR100292

TABLES

AR100293

TABLE 1 SUBSLAB VAPOR SAMPLES INCLUDED IN THE RISK ASSESSMENT

Coyne text i le Services Facility - Huntington West Virginia

Medium

Subslab Vapor

Sample Identification

bull VP-01

VP-02

VP-03

Sample Date

8132009

8132009

8132009

Coyne VIMemo Tables_09-08-09xls 982009

AR100294

TABLE 2 IDENTIFICATION OF CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR

Coyne Textile Services Facility - Huntington West Virginia

mdash

Const i tuent

Volati le Organics

111-Trichlor6ethane

1122-Tetrachloroethane

112-Trichloro-122-trifluoroethane

112-Trichloroethane

11-Dichloroethane

11-Dichloroethene

124-Trichlorobenzene

124-Trimethylbenzene

12-Dibromoethane

12-Dichlor6benzene

12-Dichloroethane

12-Dichloroethene (cis)

12-pichloroethene (trans)

12-Dichloropropane

12-Dichlorotetraf1uoroethane

135-Trimethylbenzene

13-Butadiene

13-Dichlorobenzene

13-Hexachlorobutadiene

14-Dichlorpbenzene

224-trimethylpentane

2-Chlorotoluene

4-Ethyltoluene

Acetone

Allyl Chloride

Benzene

Bromodichloromethane

Bromoform

Bromomethane

Carbon disulfide bull

Carbon tetrachloride

ChJorobenzene

Chloroethane

Frequency of Detection

0 3

0 3

0 3

bull 0 3

0 3

0 3

0 3

1 3

0 3 bull

0 3

b 3 bull

2 3

0 3

bull 0 3

0 3

0 3

0 3 bull

0 3

0 3

0 3

0 3

0 3

0 17

3 3

0 3

P 3

- 0 3

0 3

0 3

0 3

0 3

0 3

0 3

Min imum Detected

Concentrat ion

(ugm^)

ND

ND

ND

ND

ND

- ND

N D

197

ND bull

ND

ND

369

ND

bull~ ND

ND

ND

ND

ND

ND

bull ND

ND

ND

ND

796

ND

ND

ND-

ND

ND

ND

ND

ND

ND

Maximum

Detected Concentrat ion

(ugm3)

ND

ND

ND

ND

ND

ND

ND

197

ND

ND

ND

mdash 6030

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

1880

ND-

ND

ND

ND

ND

ND

ND

ND

ND

Sample wi th Maximum Detect

ND

ND

ND

ND

ND

ND

- ND

VP-03 -

ND

ND

ND

VP-03

ND

bullND

ND

ND

ND

ND

ND

ND

ND

ND

ND

VP-02

ND

ND bull

ND

ND

ND bull

bull ND

ND

ND

ND

Min imum Detection

Limit (ugm3)

22

28

31

22

16

16

30

20

31

24

16

bull 16

16

19

28

20

89

24 bull

43

24

bull 19

2 1

20

--^ 13

13

27

41

16

13

25

18

11

Maximum Detection

Limit (ugm3)

218

275

307

218

162

159

297

197

307

240

162

- 16

159

185

280

197

89

240

427

240

187

207

197

--125

128

268

414

155

125

252

184

106

Vapor Intrusion Corhparison

V a l u e

(ugm)

22000

042

300000

15

bull 5000

2000

2000

60

011

2000

094

350

700

40

NA

60

0087

1100

11

8000

NA

NA

NA

3500

NA

31

14

22

50

7000

16

bull 600

100000

Chemical of Concern

No

No

No

No

No

No

No

YES

No

No

No

YES

No

No

No

N o bull

bullNo

No

No

No

No

No

No

N o

No

No

No

N o

No

No

No

No

No

Comment

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent notdetected

fflaximCimTdeteetlSffieedsTcomDarisonivalues

Constituent not detected

Constituent not detected

Constituent not detected

Maximum detect exceeds comparison value

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Maximum detect below comparison value

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detectedl

Constituent not detected

Constituent not detected

CoyneVI Memo Tables_09-08-09xls 982009

AR100295

TABLE 2

IDENTIFICATION OF CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR

Coyne Textile Services Facility - Huntington West Virginia

Const i tuent

Volati le Organics

Chloroform -

Chloromethane

13-Dichloropropene (cis)

Cyclohexarie^

Dibrcimochloromethane

DichlonDdifluoromethane

Ethylbenzene

Methyl ethyl ketone

Methyl isobutyl ketone

Methyl tert-butyl ether

Methylene chloride

n-Heptane

n-Hexane

Styrene

Tert-butyl alcohol

Tetrachloroethene

Toluene

13-Dichloropropene(trans)

Triehloroethene

Trichlorofluoromethane

Vinyl bromide

Vinyl chloride

Xylene (0)

Xylenes (mampp)

Frequency of Detection

1 3

0 3

0 3

1 3

0 3

0 3

0 -3

1 3

0 3

0 3

2 3

0 3

3 3

0 3

0 3

3 3

1 3

- 0 3

3 3

P 3

0 3

0 3

1 3

1 3

Min imum Detected

Concentrat ion

(ugm)

5910

ND

ND

52

ND

ND

ND

23

ND

ND

1160

ND

1 4 4

ND

ND

11200

18

ND

91

ND

ND

ND

208

387

Maximuri i Detected

Concentrat ion (ugmS)

bull

5910

ND

ND

52

bull ND

ND

ND

23

ND

ND

1520

ND

183

ND

ND

149000

18

ND

7820

ND

bullND

ND

208

387

Sample vyith Max imum Detect

VP-02

ND

ND

VP-01

bull ND

ND

ND

VP-01

ND

ND

VP-02

ND

VP-02

ND

ND

VP-02

VP-01

ND

VP-03

ND

ND

ND

VP-03

VP-03

Min imum Detection

Limit (ugm3)

20

83

18

138

34

bull 20

17

118

16

14

14

16

- -17

12

--151

18

--23

18

10

1 7 bull

1 7 bull

Maximum Detection

Limit (ugm3)

195

83

182

138

341

198

174

118

164

144

14

164

170

121 -

--151

182

225

175

102

bull 174

174

Vapor Intrusion Compar ison

V a l u e

(ugm)

11

24

NA

2000

1

2000

22

10000

800

30000

52

NA

2000

10000

NA

81

4000

NA

022

7000

NA

28

70000

70000

Chemical o f Concern

YES

No

No

No

No bull

No

No bull

No bull=

No

No

YES

No

No

No

No

YES

No

No

YES

N o

No

No

No

No

Comment

Maximum detect exceeds comparison value

Constituent not detected

Constituent not detected

Maximum detect below comparison value

Constituent not detected

Constituent not detected

Constituent not detected

Maximum detect below comparison value

Constituent not detected

Constituent not detected

Maximum detect exceeds comparison value

Constituent not detected bull

Maximum detect below comparison value

Constituent not detected

Constituent not detected

Maximum detect exceeds comparison value

Maximum detect below comparison value

Constituent not detected

Maximum detect exceeds comparison value

Constituent not detected

Constituent not detected

Constituent not detected bull

Maximum detect below comparison value

Maximum detect below comparison value

Notes

ND - Not Detected

NA - Not Available

- - Constituent detected in every sample detection limit not presented

Values in bold indicate detection limit exceeds comparison values

Target shallow soil gas comparison values corresponding to indoor air concentrations where the soil gas to indoor air attenuation factor = 01 and the target cancer risk is set to ip (presented in Table 2c of USEPA 2002a)

Comparison value for cyclohexane is based on the comparison value for hexane

Coyne VI Memo Tables_09-08-09xls 982009

AR100296

TABLES

EXPOSURE POINT CONCENTRATIONS FOR CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR

Coyne Textile Services Facility - Huntington West Virginia

Chemical of Concern

VolatileOrganics

i24-Trimethylbenzene

12-Dichloroethene (cis)

Chloroform

Methylene chloride

Tetrachloroethene Triehloroethene

Subslab Vapor Source

Concentration (mgm^)

0197

603

591

152

149 782

Transport

Factor^ (unitless)

108E-05

108E-05

108E-05

108E-05

108E-05 108E-05

EPC in

Indoor Air (mgm^)

213E-06

651 E-05

638E-05

164E-05

161E-03 844E-05

Notes

^ Subslab vapor source concentration is based on the maximum detected concentration of samples

VP-01-02 and-03 (see Table 2) -

^ Details of the transport factor calculations are presented in Appendix B

^ Exposure Point Concentration (EPC) in inidoor air is calculated as the subslab vapor concentration TF

Coyne VI Memo Tables_09-08-09xls 982009

AR100297

TABLE 4

FACTORS USED IN DOSE CALCULATIONS INHALATION OF VOLATILE EMISSIONS

Coyne Textile Services Facility - Huntington West Virginia

Symbol

CA

IRA

ET

EF

ED-

BW

AT

Exposure Factor

Constituent Concentration in Air

Inhalation Rate

Exposure Time

Exposure Frequency

Exposure Duration

Body Weight

Averaging Time

Indoor Worker

Constituent-Specific See Table 3

25 m hour

8 hrday

250 daysyear

25 years

bull 70 kg

9125 days (NC)

25550 days (C)

Total Dose = CA x IR^ x ET x EF x ED x 1BW x 1AT

(NC) - Non-carcinogenic Averaging Time

(C) - Carcinogenic Averaging Time

Coyne VI Memo Tables_09-08-09xls 982009

AR100298

TABLES TOXICITY VALUES FOR CHEMICALS OF CONCERN

Coyne Textile Services Facility - Huntington West Virginia

Chemical of Concern

Volatile Organics

124-Trimethylbenzene

12-Dichloroethene (cis)

Chloroform

Methylene chloride

tetrachloroethene

Triehloroethene

Target Organ Critical Effect

blood

bullblood

liver

liver

liver CMS

liver kidney fetus CNS

Chroniclnhalation Reference Dose

(mgkg-day)

200E-03 P

1 OOE-02 R

140E-02 E

286E-01 M

771 E-02 M

1OOE-02 E

Inhalation Cancer ^ Slope Factor

(mgkg-day)^

NA

NA

805E-02 1

165E-03 1

200E-02 0

400E-01 E

(I) - Integrated Risk Information System (IRIS USEPA 2009)

(P) - Provisional Peer-Reviewed Toxicity Value (PPRTV) as presented in USEPA Regional Screening Tables (ORNL 2009)

(R) - Calculated assuming route-to-route extrapolation as per WVDEP

(E)-Provisional value from the National Center for Environmental Assessment (as per WVDEP)

(M)-Chronic Minimal Risk Level (MRL ATSDR 2009)

(0) - Value cited by USEPA Region 3 attributed to other sources (as per WVDEP)

Coyne VI Memo Tables_09-08-09xls 982009

AR100299

TABLE 6

NONCANCER HAZARD INDEX AND POTENTIAL CANCER RISK FOR AN INDOOR WORKER

Coyne Textile Services Facility - Huntington West Virginia

bull

Constituent

Volatile Organics

124-Trinnethylbehzene

12-Dichlorpethene (cis)

Chloroform

Methylene chloride

Tetrachloroethene Triehloroethene

EPC in Indoor Air

(mgm)

213E-06

651 E-05

- 638E-05

164E-05

161 E-03

844E-05

Intake (ADD)

(mgkg-d)

416E-07

127E-05

125E-05

321 E-06

315E-04 l65E-05

RfDi

(mgkg-d)

200E-03

1OOE-02

140E-02

286E-01

771 E-02 1 OOE-02

Hazard

Quotient

208E-04

127E-03

892E-04

112E-05

408E-03 165E-03

Intake (LADD)

(mgkg-d)

) 149E-07

455E-06 bull 446E-06

115E-06

112E-04 590E-06

CSFi

(mgkg-d)

NA

NA

805E-02

165E-03

200E-02

400E-01

Potential

Cancer Risk

NA

NA

359E-07

189E-09

225E-06 236E-06

Total Hazard Index

00081 Total

Cancer Risk 497E-06

Total Blood HI = Total Liver HI =

Total Central Nervous System HI = Total Kidney HI =

Total Fetal HI =

bull 00015 00066 00057 00017 00017

Notes NA = Toxicity values are not available for this endpoint or exposure pathway

Coyne VI Memo Tables_09-08-09xls 982009

AR100300

APPENDIX A

SUBSLAB VAPOR ANALYTICAL DATA

AR100301

Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility Huntington West Virginia

Sample

Consti tuent

Volatile Organics (ugm) 111-Trlchloroethane 1122-Tetrachloroethane 112-Trichloro-122-trifluoroethane 112-Trichloroethane 11-Dichioroethane 11-Dichloroethene 124-Trichloroberi2ene 124-Trimethylbenzene 12-Dibromoethane 12-Dichloroben2ene 12-Dichloroethane 12-Dichloroethene-(cis) -12-Dichloroethene (trans) 12-Dichloropropane 12-Dichlorotetrafluoroethane 135-Trimethylbenzene 13-Butadiene 13-Dichlorobenzene 13-Hexachlorobutadiene 14-Dichlorobenzene 224-trimethVlpentane 2-Chlorotoluene 4-Ethyltoluene Acetone Allyl Chloride Benzene Bromodichloromethane Bromoform Bromomethane Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 13-Dichloropropene (cis) Cyclohexane Dibromochloromethane

Identif ication Sample Date

CAS No

71-55-6 79-34-5 76-13-1 79-00-5 75-34-3 75-35-4 120-82-1 95-63-6 106-93-4 95-50-1 107-06-2 156-59-2 156-60-5 78-87-5 76-14-2 108-67-8 106-99^0 541-73-1 87-68-3 106-46-7 540-84r1 95-49-8

622-96-8 67-64-1 107-05-1 71-43-2 75-27-4 75-252 74-83-9 75-15-0 56-23-5 108-90-7 75-00-3 67-66-3 74-87-3

10061-01-5 110-82-7 124-48-1

lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt

lt lt lt lt lt lt lt lt lt lt lt lt

lt

VP-01 8132009

22 28 31 22 16 16 30 20 31 24 16 16 16 19 28 20 89 24 43 24

1 9 21 20 796 13 13 27 41 16 13 25 18 11 20 83 18 52 34

lt lt lt lt lt lt lt lt lt lt lt

lt lt lt lt lt lt lt lt lt lt lt

lt lt lt lt lt lt lt lt lt

lt lt lt lt

VP-02 8132009

218 2 7 5 307 218 162 159 297

bull 197 307 240 162 369 159 185 280 197 89

240 427 240 187 207 197

1880 125 128 268 414 155 125 252 184 106

5910 83 182 138 341

lt lt lt lt lt lt lt

lt lt lt

lt lt lt lt lt lt lt bull

lt lt lt lt

lt lt lt lt lt lt lt lt lt lt lt lt lt lt

VP-03 8132009

218 275 307 218

bull 162 159 297 197 307 240 162

6030 159 185 280 197 89

240 427 240 187 207 197

1750 125 128 268 414 155 125 252 184 106 195 83 182 138 341

Appx A SG Dataxis Page 1 of 2 982009

AR100302

Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility bull Huntington West Virginia

Consti tuent

Volatile Organics (ugm^) Dichlorodifluoromethane Ethylbenzene Methyl ethyl ketone Methyl Isobutyl ketone Methyl tert-butyl ether Methylene chloride n-Heptane jn-Hexane Styrene Tert-butyl alcohol Tetrachloroethene iToluene 13-Dichloropropene (trans) Triehloroethene Trichlorofluoromethane Vinyl bromide Vinyl chloride Xylene (o) Xylenes (mampp)

Sample Identif ication Sample Date

CAS No

75-71-8 100-41-4 78-93-3 108-10-1

1634-04-4 75-09-2

142-82-5 bull 110-54-3

100-42-5 75-65-0 127-18-4 108-88-3

10061-02-6 79-01-6 75-69-4 593-60-2 75-01-4 95-47-6

179601-23-1

lt lt

lt lt lt lt

lt lt

lt

lt lt lt lt lt

VP01 8132009

20 17 23 16 14 14 16

173 17 12 bull

11200 18 18 91 23 18 10 17 17

lt lt lt lt lt

lt

lt lt

lt lt

lt lt lt lt lt

VP-02 8132009

198 174 118 164 144

1520 164 -183 170 121

149000 151 182

2360 225 175 102 174 174

VP-03 8132009

lt 198 lt 174 lt 118 lt 164 lt 144

1160 lt 164

144 lt 170 ltbull 121

90500 lt 151 lt 182

7820 lt 225 lt 175 lt 102

208 387

Appx A SG Dataxis Page 2 of 2 982009

AR100303

APPENDIX B

CALCULATION OF TRANSPORT FACTORS USED TO ESTIMATE INDOOR AIR CONCENTRATIONS

AR100304

APPENDIX B

Calculation of Transport Factors Used to Estimate Indoor Air Concentrations

This appendix presents the methodology for calculating transport factors that are used to convert subslab

vapor concentrations to concentrations in indoor air 124-Trimethylbenzene 12-dichloroethene (cis)

chloroform methylene chloride tetrachloroethene and triehloroethene were identified as contaminants of

concern (COC) for potential vapor intrusion from subslab vapor associated with the Coyne Textile

Services Facility located in Huntington West Virginia (site) In this appendix the transport factors are

calculated to estimate the concentrations of COC in indoor air of the existing plant building located at the

site ~

Transport Factor for Indoor Air

The concentration of a constituent in indoor air (da) is proportional to the concentration of the constituent

in the subslab vapors immediately beneath the building foundation (ie subslab vapor concentration or

Csubsiab) The following equation is used to calculate da from Csubsiab

^ wja ~ ^subslab X I r

where

Cia = concentration of constituent in indoor air (mgm^) -

Csubsiab^ concentration of constituent in subslab vapors (mgm^) and

TF = transport factor from subslab vapors to indoor air

The transport factor (TF) is an infinite source attenuation coefficient andcan be calculated based on a

model developed by Johnson and Ettinger (1991) t he equation for calculating TF is as follows

(Deff X A B ) ( Q B X L T ) X expKQso i l X Lcrabk)(Dcrack X Acrack)]

exp[ (Qsoi l X Lcrack)(Dcrack X Acrack)] + (Deff X A B ) ( Q B X L T ) + (Deff X AB)(Qsoi l X L j ) X (exp [ (Qso i l X Lcrack)(Dcrack X Acrack)] - 1)

where

Deff = effective diffusion coefficient for vadose zone soil (cm^sec)

AB = area of enclosed space below grade (cm^)

QB = building ventilation rate (cm^sec)

LT = distance from contaminant source to building foundation (cm)

Qsoii = volumetric flow rate of vapors into the building (cm^sec)

Lcrack = foundatlon thickness (cm)

Dcrack = vapor diffusion coefficient through crack (cm^sec) and

Acrack = area of cracks through which vapors can pass (cm^)

AR100305

To solve this equation the USEPAs SG-ADV spreadsheet Version 31 most recently updated in

February 2004 was implemented A combination of site-specific factors and default values from the

Users Guide for Evaluating Subsurface Vapor Intrusion Into Buildings (USEPA 2004) were used as input

values in the model All input values are defined below and presented in Tables B-1-A through B-6-A

bull The initial subslab vapor concentration (Csubsiab) is the maximum detected concentration(in units

of ugm ) of samples VP-01 VP-02 and VP-03 that was presented in Table 3 of the report

bull The depth below grade to the bottom of the enclosed space floor (Lp) is set to 15 cm the default

value provided by USEPA (2004) for a slab-on-grade structure

bull The vapor sampling depth below grade (Lg) is a site-specific value The vapor samples were

collected from immediately beneath the building floor therefore Lj has been set to 15 cm

bull The average soilgroundwater temperature (Ts) is set to 125degC the average value for West

Virginia as estimated frorri Figure 8 of the vapor intrusion users guide (USEPA 2004)

bull The soil type used to estimate vapor permeability is assumed to be sandy loam (SL) The

associated soil properties for a sandy loam soil type are as follows the soil dry bulk density (Pb) is

162 gcm the total porosity (n) is 0387 (cm^-aircm^) and the water-filled porosity (nw) is 0103

(cm -HzOcm )

bull The floor thickness (Lcrack) is set to the USEPA (2004) default value of 10 cm

bull The soil-building pressure differential (AP) is set to the USEPA (2004) default value of 40 gcm-s^

bull The building dimensions are siterspecific based on the existing plant building located at the site

The existing structure is approximately 84000 square feet (Dolphin 2000) therefore the

dimensions are set to 8839 cm (290 feet) length by 8839 cm (290 feet) The USEPA (2004)

default value of 244 cm vyas used for the height

bull Thefloor-wall seam crack width (w) is set to the USEPA (2004)-default value of 01 cm

bull The indoor air exchange rate (ER) is set to 083hour This is the value provided by ASTM (2002)

for commercial and industrial buildings

AR100306

Tables B-1-B through B-6-B present the constituent-specific properties for COC that were used in the TF

calculations Tables B-1-C through B-6-C present the intermediate calculations used to determine the

indoor air attenuation coefficients (ie the transport factors) The shaded boxes in Tables B-1-C through

B-6-C also present the resulting TF values that are applied to the concentrations of COC in subslab

vapor and the estimated indoor air concentrations

References

American Society for Testing and Materials (ASTM 2002) Standard Guide for Risk-Based Corrective Action Applied at Petroleum Release Sites ASTM E-1739-95 (Reapproved 2002)

Johnson PC and RA Ettinger (1991) Heuristic model for predicting the intrusion r-ate of contaminant vapors into buildings Environ Sci Technolpgy 25 1445-1452

Dolphin Environmental LLC (Dolphin 2000) Site Characterization Report Mach 14 2000

United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004

AR100307

APPENDIX B-1-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV Nersion31 0204

Reset to Defaults

ENTER -

Chemical CAS No

(numbers only

no dasties)

95636

ENTER Soil gas

cone

Cg (ngm)

Soil Gas Concentration Data ENTER

Soil gas

OR cone

bull - c bull (PPmv)

197E+02

Chemical

124-Trimethylbenzene

MORE ENTER Depth

below grade to bottom

of enclosed space floor

U bull (cm)

ENTER

Soil gas sampling

depth below grade

U (cm) bull

ENTER

Average soil

temperature Ts

CO

1 15 1 1 5 bull125

ENTER ENTER ENTER Totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hft ha he

(cm) (cm) (cm)

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estirnate OR permeability | soil vapor

permeability) k v bull

(cm)

SL 1 1

MORE ENTER

stratum A SCS

soil type

Lookup Soil Parameters

ENTER stratum A soil dry

bulk density P

(gcm)

ENTER Stratum A soil total porosity

(unitless)

ENTER bull stratum A soil water-filled

porosity

(cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

nlaquo

(unitless)

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gchi-s^)

ENTER Enclosed

space floor

length bull LB

(cm)

ENTER Enclosed

space floor

width WB

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

bull Floor-wall seam crack

width w

(cm)

bullENTER

Indoor air exchange

rate ER

(1h) bull

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bidg OR

Leave blank to caicuij

(Lm)

Appx B-1 124-TMBxls 1 of 3 982009

AR100308

APPENDIX B-1-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of ^ bull law constant law constant vaporization at Normal

Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temperature boiling point point temperature weight

D bull Dbdquo H T R bull AHbdquo TB Tc IVIW

Unit risk Reference

factor cone URF RfC

(cms) (cmls) (atm-mmol) CO (calmol) (degK) (degK) (gmol) bull (ugm)- (mgm)

1 606E-02 1 792E-06 1 bull 614E-C3 1 25 1 9369 1 44230 | 64917 1 12020 1 OOE+00 1 60E-03 1

Appx B-1 124-TMBxls 2 of 3 982009

AR100309

APPENDIX B-1-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

(sec)

Source-building

separation

LT bull

(cm) bull

Stratum A soil

air-filled porosity

Q A

Stratum B soil

air-filled porosity

(cmcm) (cmcm)

Stratum C soil air-filled porosity

(cmcm)

Stratum A effective total fluid

saturation

Se

(cmcm)

Stratum A soil

bullintrinsic permeability

^ (cm)

stratum A Stratum A Floor- soil soli wall BIdg

relative air effective vapor seam Soil bull ventilation permeability permeability perimeter gas rate-

kfg ky Xgrack c o n e - QbuHdinpound

(cm) - (cm) (cm) (ngm) (cms)

946E+08 1 0284 0284 0284 0184 596E-09 0901 537E-09 35357 I 197E+02 | 439E+06 |

Area of enclosed

space below grade

As (cm)

Crack-to-total area ratio

1 bull

(unitless)

Crack depth

below grade

Zcfack

(cm)

Enthalpy of vaporization at

ave soil temperature

AHvjs

(calmol) bull

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law constant at

ave soil bull temperature

bull HTS

(unitless)

Vapor bull viscosity at

ave soil temperature

HTS

(gcm-s)

Stratum A

effective diffusion

coefficient

D (cms)

Stratum-B

effective diffusion coefficient

DB (cms)

Stratum C effective diffusion

coefficient

D-c (cms)

Total - overall effective diffusion

coefficient

D ^ (cms)

Diffusion path

length

L-

(cm)

I 787E+07 I 449E-05 | 15 | 11661 260E-03 111E-01 176E-04 I 612E-03 j OOOE+00 | OOOE+00 | 612E-03 j

bull Convection path

length

Lp

(cm)

Source vapor cone

^source

(ngm)

Crack radius

Tcfack

(cm)

Average vapor

flow rate into bIdg

Qsoii

(cms)

Crack effective diffusion

coefficient pcrack

(cms)

Area of CTack

Acack

(cm)

Exponent of equivalent foundation

Peclet number

exp(Pe)

(unitless)

bull bull - bull bull bull bull

1 15 1 197E+02 1 010 1 474E+01 612E-03 bull 354E-t-03 1 336E+09

Infinite source Indoor

~ attenuation coefficient

a

(unitless)

108E-05

Infinite source

btJbldgjJSv-L ^Ppncji3i-

virhpbiiilding bullbull ^lHltti^m)ilg

213E-03

Unit risk

factor

URF

(ngm)-

Reference cone

RfC (mgm)

NA 60E-03 1

I END

Appx B-1 124-TMBxls 3 of 3 982009

AR100310

APPENDIX B-2-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV Nersion31 020^

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

156592

Soil Gas Concentration Data ENTER

Soil gas

cone OR c

(ngm) bull

ENTER Soil bull-gas

cone

c (ppmv)

603E+03 1

Chemical

cis-12-Dichloroethylene

MORE ENTER Depth

below grade to bottom

of enclosed space floor

LF

(cm)

ENTER

Soil gas sampling

depth below grade

U (cm)

ENTER

Average soil

temperature bull Ts

(degC)

1 15 1 bull 15 125

ENTER ENTER ENTER Totalsmust add ijp tb value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hA hB he

bull (cm) (cm) (cm)

15 1 1

ENTER Soil

straturh A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estimate OR permeability | soil vapor

permeability) kv

(cm)

SL 1 |

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

P (gcm)

ENTER Stratum A soil total porosity

bull n

(unitless)

ENTER Stratum A

soil water-filled porosity

(cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

ENTER Stratum B

soil water-filled porosity

ENTER Stratum C

SCS soil type

(unitless) (cmcm)

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure differential

AP

(gcm-s)

ENTER Enclosed bull

space floor

length

LB (cm)

ENTER Enclosed

space floor

width WB

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER

Average vapor flow rate into bIdg

OR Leave blank to calculi

Qsoil

(Lm)

Appx B-2 cis-12-DCExls 1 of 3 982009

AR100311

APPENDIX B-2-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Diffusivity in air

Da

(cms)

Diffusivity in water

Dw (cms)

Henrys law constant at reference temperature

H

(atm-mmoi)

Henrys law constant

reference temperature

bull T R

CC)

Enthalpy of vaporization at

the normal boiling point

AHbdquob

(calmol)

Normal boiling point

TB

(degK)

Critical temperature

Tc (degK)

Molecular weight

MW

(gmol)

Unit risk

factor URF

(ngm)

Reference cone

RfC (mgm)

1 736E-02 1 113E-05 1 407E-03 j 1 25 1 bull 7192 1 33365 1 54400 1 9694 1 OOE+00 j 35E-02 1

Appx B-2 cis-12-DCExls 2 of 3 982009

AR100312

APPENDIX B-2-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

stratum A Stratum B Stratum C Source- soil soil soil

Exposure building air-filled air-filled air-filled

duration separation porosity porosity porosity

T LT ea e^ bull e= (sec) (cm) (cmcm) (cmcm) (cmcm)

I 946E+08n^

Stratum A Stratum A Stratum A Stratum A Floor-effective soil soil soil wall total fluid intrinsic relative air effective vapor seam

saturation permeability permeability permeability perimeter

Ste kj krg ky Acrack

(cmcm) (cm) (cm) (cm) (cm)

Soil gas

cone (ngm)

I 0284 I 0284~ 0284 0184 I 596E-09 | 090T 537E-09 35357 603E+03

BIdg ventilation

rate

JbulldinE

(cms)

439E+06

Area of enclosed

space below grade

AB

(cm)

Crack-to-total

area ratio

n (unitless)

Crack depth below grade

Zltiack (cm)

Erithalpy of vaporization at

ave soil temperature

AHvTs (calmol)

Henryslaw constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law constant at

ave soil temperature

HTS

(unitless) bull

Vapor viscosity at

ave soil bull temperature

HTS

bull (gcm-s)

Stratum A

effective bull diffusion

coefficient

D^A-(cms)

Stratum B

effective bull diffusion

coefficient

D=B

(cms)

Stratum C

effective diffusion bull

coefficient

D=e (cms)

Total overall

effective diffusion

coefficient

DT

(cms)

Diffusion path

length

Ld

(cm)

I 787E+07 I bull449E-05 | 15 bull7709 230E-03 982E-02 176E-04 | 743E-03 | OOOE+00 | OOOE+00 | 743E-03 |

bull bull bull -

Convecfion path -bull

length

Lp (cm)

Source vapor cone

-source

(Mgm)

Crack radius

fcrack

(cm)

Average vapor

flow rate into bIdg

Qaoil bull

(cms)

Crack effective diffusion

coefficient pcack

(cms)

Area of crack

crack

(cm)-

Exponent of equivalent foundation

Peclet number

exp(Pef)

(unitless)

bull

1 15 -1 603E+03 1 010 1 474E+01 743E-03 354E+03 1 697E+07

Infinite source Indoor

attenuation coefficient

poundbullbullbull C t

pound(unitless)

bullsiilaquogt j ii08E-05

Infinite [ source

bIdg cone

Cbujidjng

(pgm)

651 E-02 iKrt

Unit risk

factor

URF

(ngm)-

Reference cone

RfC

(mgm)

NA 35E-02 1

I END I

Appx B-2 cis-12-DCExls 3o f3 982009

AR100313

APPENDIX B-3-A DATA ENTRY SHEET

Coyne Texti le Services - Hunt ington West Virginia

SG-ADV Version 31 0204

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

67663

Soil Gas Concentration Data ENTER ENTER

Soil Soil gas gas

cone OR cone c C

(^gm) (ppmv)

591 E+03

bull

Chemical

Chloroform

MORE ENTER Depth

below grade tb bottom

of enclosed space floor

bull LF

(cm)

ENTER

Soil gas sampling depth

below grade

(cm)

ENTER

Average soil

temperature-Ts

CO bull

1 15 1 15 1 125

ENTER ENTER ENTER Totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

IIA hs he (cm) (cm) (cm)

1 5 bull 1 1

ENTER ENTER Soil - bull

stratum A User-defined SCS stratum A

soil type bull soil vapor (used to estimate OR permeability

soil vapor k

bull permeability) (cm) 1

SL 1 1 bull

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A soil dry

bulk density

Pb (gcm)

ENTER Stratum A soil total porosity

nV (unitless)

ENTER Stratum A

-soilwater-filled bullporosity

Sraquo (cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

(unitless)

ENTER Stratum B

soil water-filled porosity

bull ebdquo=

(cmcm) bull

ENTER Straturri C

SCS bull soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

- c rack

(cm)

ENTER

Soil-bldg pressure

differential AP^

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor

width bull W B

(cm)

ENTER

Enclosed space

height HB

(cm)

ENTER

bull Floor-wall^ seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bidg OR

Leave blank to calculi

Qsoil bull

(Lm)

I -I

Appx B-3 Chloroformxls 1 of 3 982009

AR100314

APPENDIX B-3-B CHEMICALPROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Diffusivity in air

D (cms)

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffijsivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature

Dbdquo H TR A H bdquo TB Tc

(cm s) (atm-m mol) ro (calmol) (degK) (degK)

Molecular weight

MW

(gmol)

Unit risk

factor URF

(ngm)-

Reference cone

RfC

(mgm)

104E-01 100E-05 I 366E-03 25 6988 33432 53640 11938 I 23E-05 | OOE+00

Appx B-3 Chloroformxls 2 of 3 982009

AR100315

APPENDIX B-3-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure

duration

(sec)

Source-

building

separation

LT

(cm)

Stratum A

soil

air-filled

porosity

Sa

( cm cm )

Stratum B

soil

air-filled

porosity

( cm cm )

Stratum C

soil

air-filled

porosity

( c m c m )

Stratum A

effective

total fluid

saturation

( c m c m )

Stratum A

soil

intrinsic

penmeability

k

(cm )

Stratum A

- soil

relative air

permeabil i ty

(cm )

Stratum A

soil

effective vapor

permeability

kv

(cm )

Floor-

wall

seam

perimeter

gtcrack

(cm)

Soil gas

cone

(ngm)

BIdg

venfilation

rate

^buildlriE

(cms)

I 9 4 6 E + 0 8 ~ T I 0284 T 596E-09 I 0-901 I 537E-09 | 35357 | 591 E+03 j 439E+06 | 1 0 284 0284 0184

Area of

enclosed

space

below

grade

A B

( c m )

Crack-

to-total

area

ratio

n

(unitless)

Crack

depth

bull below

grade

^crack

(cm)

Enthalpy of

vaporization at

ave soil

temperature

AHTs bull

(calmol)

Henry s law

constant at

ave soil

temperature

HTS

(a tm-m mol j

Henrys law

constant at

ave soil

bull temperature

HTS

(unitless) bull

Vapor

viscosity at

ave soil-

temperature

^HTS

(gcm-s)

Stratum

A

effective

diffusion

coefficient

(cm s)

Stratum

B

effective

difftjsion

coefficient

D B

(cms) bull

S t ra tum

C

effective

diffusion

coefficient

Dc

(cm s)

Total

overall

effective

bull diffusion

coefficient

D T

(cm s)

Diffi jsion

path

length

Ld

(cm)

I 787E+07 I 449E-05 j - bull 15 7528 210E-03 896E-02 176E-04 I 105E-02 | OOOE+00 | OOOE+00 | 105E-02

Convection

path length

Lp

(cm)

Source

vapor

cone -

^source

- (ngm)

Crack

radius

Tcrack

(cm)

Average

vapor

flow rate

into bidg

Qsoil

(cms)

Crack

effective

diffusion

coefficient Qcrack

bull (cms)

Area of crack

Acrack

(cm)

Exponent of

equivalent

foundation

Peclet number

exp(Pe)

(unitless)

V bull bull

1 15 1 591 E+03 1 010 1 474E+01 105E-02 354E+03 1 355E+05

Infinite

source

indoor

attenuation

coefficient

d

(unitless)

bull 108E-05

Infinite

source

bIdg

cone

^ b u i l d i n g

i (^gm)

bull bull

i 638E-02 -

Unit

risk bull factor

URF

(ngmY

Reference

cone

RfC

(mgm)

~ 23E-05 NA 1

I END

Appx B-3 Chloroform xls 3 of 3 982009

AR100316

APPENDIX B-4-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ersion 31-020^

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

nodashes)

bull 75092

ENTER Soil gas

cone

c (ngm)

Soil Gas Concentration Data ENTER

Soil gas bull

OR cone

bull C

(ppmv)

152E+03

bull bull

Chemical

Methylene chloride

MORE

MORE 4gt

ENTER Depth

below grade to bottom

of enclosed space floor

LF -

(cm)

ENTER

Soil gas sampling depth

below grade

bull U

(cm)

ENTER

Average soil

temperature

Ts bull CC)

bull bull bull bull

1 15 1 15 125

ENTER Totals

Thickness of soil

stratum A h

(cm)

ENTER ENTER must add up to value of Ls (cell F24

Thickness Thickness of soil of soil

stratum B stratum C (Enter value or 0) (Enter value or 0)

he he bull

(cm) bull (cm) -

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(usedto estimate OR perrrieability | soil vapor

permeability)

k bull

(cm)

SL 1 bull 1

ENTER Stratum A

SCS soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

Pb (gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Stratum A

soil water-filled porosity

9w (cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

Pb^

(gcm)

ENTER Stratum B soil total porosity

n^

(unitless)

ENTER Stratum B

soil water-filled porosity

(crhcm)

ENTER Stratum C

SCS soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE 4gt

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

bull Soil-bldg pressure

differential AP^

(gcm-s)

ENTER Enclosed

space floor

length LB

(cm)

ENTER Enclosed

space floor

width bull W B

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width

w

(cm)

ENTER

Indoor air exchange

rate

ER (1h)

ENTER Average vapor

flow rate into bidg OR

Leave blank to calculc

Qsoil

(Lm)

10 40 8839 8839 244 01 083

Appx B-4 MCxIs 1 of 3 982009

AR100317

Diffijsivity in air

D

APPENDIX B-4-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffusivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature

Pw H TR AHt TB TC

Molecular weight

MW

Unit risk

factor URF

Reference cone

RfC

(cms) (cms) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) bull (ngm)- (mgm)

bull bull

1 101E-01 1 117E-05 1 218E-03 1 25 | 6706 1 31300 1 51000 1 8493 1 47E-07 1 30E+00 1

Appx B-4 MCxIs 2 of 3 982009

AR100318

APPENDIX B-4-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

T

(sec)

Source- -building

separation

LT

(cm)

Stratum A soil

air-filled porosity

e a bull

(cmcm)

Stratum B soil

bullair-filled porosity bull

ea^ (cmcm)

Stratum C soil

air-filled porosity

ea= (cmcmj

Stratum A effective total fluid

saturation

Sc bull

(cmcm)

Stratum A soil

intrinsic pemneability

ki (cm)

Stratum A soil

relative air permeability

^ ^ g

(cm)

stratumA bull soil effective vapor permeability

K (cm)

Floor-wall

seam perimeter

Xcrack

(cm)

Soil gas

cone (ngm)

BIdg ventilation

rate

Qbuildinc

(cms)

1 946E+08

Area of -enclosed

space below

bull grade

AB

(cm)

1

Crack-to-total

area rafio

Tl

(unitless)

0284 1

Crack depth below grade

Zcrack

(cm)

0284 1

bull Enthalpy of vaporization at

ave soil temperature

AHTs (calmol)

0284

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

0184

Henrys law constant at ave soil

temperature

HTS

bull (unitless)

1 596E-09

Vapor viscosity at

ave soil temperature

Mrs (gcm-s)

0901

Stratum A

effective diffusion

coefficient

D (cms)

537E-09

Stratum B

effective diffusion

coefficient

D-B (cms)

35357 1

Stratum C -

effective diffusion

coefficient

D-c ^ (cms)

152E+03

Total bull overall

bull effective diffusion

coefficient

D ^

(cms)

440E+06 1

Difftjsion path

length

Ld (cm)

1 787E+07

Convection path

length

Lp (cm)

4 49E-05

Source vapor cone

Csource

(ngm)

15 1

Crack radius

Tcrack

(cm)

7007 bull 1

Average vapor

flow rate intobldg

Qsoil

(cms)

130E-03

Crack effective diffusion

coefficient pcrack

(cms)-

555E-02

bull ^

Area of crack

Acrack

(cm) bull

1 176E-04

Exponent of equivalent foundation

Peclet number

exp(Pe)

(unitless) bull

bull bull

1 15

1 END

152E+03 010 1 474E+01 1 102E-02 354E+03 1 519E+05

102E-02

Infinite source

indoor ^attenuation coefficient

bull a

(unitless)

aiii08E-05

0 OOE+00

bull

Infinite bull source

bIdg ^ cone

^bu i l d i ng

(MQm)

164E-02

OOOE+00 1

Unit risk

factor

URF

(ngm)-

47E-07 1

102E-02 j

Reference cone

RfC

(mgm)

30E+00 j

1 1

Appx B-4 MCxIs 3 of 3 982009

AR100319

APPENDIX B-5-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ^erslon 31 0204

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

127184

Soil Gas Concentration Data ENTER ^ ENTER

Soil -Soi l bull gas gas

cone OR cone Cg C bull

(tgm) (ppmv)

149E+05 1

Chemical

bull Tetrachlbroethylene

MORE 4

ENTER Depth

below grade to bottom

ofenclosecJ space floor

LF

(cm)

ENTER

Soil gas bull sampling

depth below grade

u bull (cm)

ENTER

Average bullsoil

temperature - Ts

ro 1 1 5 1 15 1 125 bull

ENTER ENTER ENTER totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hft bull he bull he

(cm) (cm) (cm)

bull 1 5 1 - 1

ENTER ENTER Soil

stratum A User^defined bull SCS bull stratum A soil type soil vapor

(used to estimate OR perrrieability soil vapor K bull

permeability) (cm) 1

SL 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

Pb

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Sitratum A

soil water-filled bull porosity

(cmcm)

ENTER Stratum B

SCS soiltype

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

Pb^

(gcm)

ENTER Stratum B soil total porosity

Ajnitless^

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS soil type

LookupSoil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

VS

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor width

W B

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width

w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

ENTER Average vapor

flow rate into bidg OR

Leave blank to calcul

bull Qsoil

(Lm)

10 40 8839 8839 244 01 083

Appx B-5 PCExIS 1 of 3 982009

AR100320

APPENDIX B-5-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal Unit

Diffusivity Diffusivity at reference reference the riormal boiling Critical Molecular risk Reference in air in water temperature temperature boiling point point teriiperature weight factor cone

Da Dbdquo H TR AHb TB Tc MW URF RfC

(cms) (cnis) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) (^gm)- (mgm)

1 720E-02 1 820E-06 1 184E-02 1 25 1 8288 1 39440 1 62020 1 16583 1 59E-06 1 60E-01 1

J

AppxB-5PCExls 2 of 3 - 982009

AR100321

APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

T

(sec)

Source-building

separation

LT

bull (cm)

Stratum A soil

air-filled porosity

Oa (cmcm)

Stratum B - soil air-filled porosity

ea (cmcm)

Stratum C soil

air-filled porosity

ea= - (cmcm)

Stratum A effective total fluid

saturation

sbdquo (cmcm)

Stratum A soil

intrinsic permeability

ki (cm)

Stratum A soil

relative air permeability

- ^ g

(cm)

Stratum A soil

effective vapor permeability

kv (cm)

Floor-wall

seam perimeter

^crack

(cm)

Soil gas

cone

(ngm)

BIdg venfilation

rate

Qbuildins

bull (cms)

bull bull

1 946E+08

Area of enclosed

space below grade

AB

(cm)

1

bullCrack-to-total

area ratio

1 (unitless)

0284 1

Crack bull depth below grade

Zcrack

(cm) -

0284 1

Enthalpy of vaporization at bull

ave soil temperature

bull A H V TS

(calmol)

0284

Henrys law constant at

ave soil temperature

HTS (atm-mmol)

0184

-Henrys law constant at

ave soil temperature

HTS

(unitless)

1 596E-09

Vapor viscosity at

ave soil temperature

HTS

(gcm-s)

0901

Stratum A

effective diffusion

coefficient bull D = bull

(cms)

537E-09

Stratum B

effective diffusion

coefficient

D--B (cms)

35357 1

Stratum C

effective diffusion bull

coefficient

D-c (crris)

149E+05

Total overall

effective bulldiffusion coefficient

DT

(cms)

440E+06 1

Difftjsion path

length

U (cm)

1 787E+07

Convection path

length

bull Lp

(cm)

4 49E-05

Source vapor cone

^source

(ngm)

15 1

Crack radius

Tcrack

(cm)

9528 1

Average vapor

flow rate intobldg

Qsoil (cms)

908E-03

Crack effective diffusion

coefficient pcrack

bull ( c m s ) bull

387E-01

Area of crack

Abdquoack (cm)

1 176E-04

Exponent of equivalent foundafion

Peclet number

exp(Pe)

(unitless)

bull

1 15-

1 END

149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08

727E-03

Infinite source indoor

attenuation coefficient

a

(unitless)

108E-05

OOOE+00

Infinite source

bIdg cone

Cburldtng

(Mgm)

161 E+00

OOOE+00 1

Unit risk

factor

URF

(ugm)-

59E-06 1

727E-03

Reference cone

RfC (mgm)

60E-01

1 1

Appx B-5 PCExls 3 of 3 982009

AR100322

APPENDIX B-6-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ersion31 0204

Reset to Defaults

t

Soil Gas Concentration Data ENTER

Chemical CAS No

(numbers only

no dashes)

79016

ENTER ENTER Soil Soil gas gas

cone OR cone C C -

bull (ngm) (ppmv)

782E+03

Chemical

Trichloroethylene

MORE ENTER Depth

below grade to bottom-

of enclosed space floor

LF

(cm)

ENTER

Soil gas sarnpling

depth below grade

U (cm)

ENTER

Average soil

temperature Ts

(degC)

1 15 1 15 t 125

ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e

(cm) (cm) (cm)

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estimate OR permeability soil vapor

permeability)

k (cm)

bull S L 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil bull-Parameters

ENTER Stratum A

soil dry bulk density

P b -

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Stratum A bull

soilwaterrfilled porosity

(cmcm) bull

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

bull P ^ (gcm)

ENTER Stratum B soil total

porosity

nlaquo

(unitless) -

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS bull soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor

width W B

(cm)

ENTER

Enclosed space height

H B bull

( c m ) bull

ENTER

Floor-wall seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bIdg OR

Leave blank to calculc

Qsoil

(Lm) -

Appx B-6 TCExIs 1 of 3 982009

A

AR100323

APPENDIX B-6-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight

Da Dbdquo H TR AH^b TB TC MW

Unit risk Reference

factor cone URF RfC

(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)

1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1

Appx B-6 TCExIs 2 of 3 982009

AR100324

APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

(sec)

Source-building

separation LT

(cm)

Stratum A soil

air-filled porosity

bull ea (cmcm)

Stratum B Soil

air-fllled porosity

e^ bull (cmcm)

Stratum C soil

air-filled porosity

(cmcm)

StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air

saturation permeability permeability

S|e k krg (cmcm) (cm) (cm)

Stratum A Floor-soil wall BIdg

effective vapor seam Soil ventilafion permeability perimeter gas rate

k^ bull Xack c o n e Qbuildins

(cm) (cm) (ngm) (cms)

946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |

Area of enclosed

space below grade

AB

(cm)

Ciack- to-total

area ratio

1 (unitless)

Crack depth below grade

Zcrack

(cm)

Enthalpy of vaporization at

ave soil temperature

A H J S

(calmol)

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law bull constant at

ave soil temperature

HTS

(unitless)

Vapor viscosity at

ave soil temperature

|JTS

(gcm^s)

Stratum A

effective diffusion

coefficient

(cms)

Stratum B

effective -diffusion

coefficient

D=B (cms)

Stratum ^ C effective diffusion

coefficient

D=c (cms)

Total overall

effective diffusion

coefficient

DT

(cms)

I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03

Diffusion path

length

Li (cm) bull

Convection bull path

length

Lp

(cm)

Source vapor cone bull

^source

(ngm)

Crack radius

rcrack

(cm)

Average vapor

- flow rate intobldg

Qsoil

(cms)

Crack effective diffusion

bull coefficient Qcrack

(cms)

Area of crack

^crack

(cm)

Exponent of equivalent foundation

Peclet bull number

exp(Pe)

(unitless)

bull bull

1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07

Infinite source Indoor

attenuation coefficient

a

(unitless)

108E-05

Infinite source

bIdg concgt

^building

(ngm)

844E-02

Unit risk

factor

URF

(ngm)-

Reference cone

RfC

(mgm)

1 1E-04 1 40E-02 1

END

Appx B-6 TCExIs 3 of 3 982009

AR100325

Office of Waste Management 1356 Hansford Street

Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256

West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director

ORDER

ISSUED UNDER THE

HAZARDOUS WASTE MANAGEMENT ACT

CHAPTER 22 ARTICLE 18

OF THE WEST VIRGINIA CODE^ AS AMENDED

y Order Number HW-011-80

To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704

ATTEMTION MREDARMON

Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull

AR100326

ViWJ011-laquo9 PageNunil)er2

BASIS FOR ORDER

As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following

A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^

B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator

C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities

0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94

^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement

P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following

1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater

2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was

^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment

CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable

CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order

AR100327

H W - 0 1 1 - 9 9 Page Number 3

REQUIREMENTS OF ORDER

Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows

1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^

2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore

remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling

GENERAL PROVaiONS

1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order

2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order

3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order

Effective Date

Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief

Wt T 1 V Oflice of Waste Management

AR100328

^ ^ S I S

^wmmmmamn

AR100329

Page 12: SDMS DocID 2121999 · International Enterprises Corp. building (Coyne Building), which is located at 1111 Vernon Street, Westmoreland District, Wayne County, West Virginia. The following

Risk-Based Remedies

R B R Consulting Inc

constituent concentration in subslab vapor to the concentration in indoor air The TF is dependent on the diffusion coefficient and other properties that will affect the transfer of constituents into air such as distance from the source to tlie breathing zone soil properties and building properties A site-specific building size of 84000 square feet (Dolphin 2000) and a soil type of sandy loam were used in the calculation of TF The TF is determined using calculationsbased on the Johnson and Ettinger (1991) vapor intrusion model Details of the TF calculations are provided in Appendix B

Subslab vapor concentrations are converted to indoor air concentration by applying the TF as follows

Cja ^ Csubslab X I r

The TF for each COC along with the resulting concentrations of COC in indoor air are presented in Tables

EXPOSURE EVALUATION

Noncarcinogenic health effects are evaluated by calculating the average dose of a constituent over the course of the exposure period This dose is termed the Average Daily Dose (ADD) Potential carcinogenic health effects are evaluated in terms of an individuals theoretical increased risk of developing cancer over a lifetime Although the duration of exposure to a constituent release generally does not last for an entire lifetime constituent intake for carcinogens is estimated as the average dose over a human lifetime (70 years) This lifetime dose applies specifically to the evaluation of carcinogenic effects and is termed tine Lifetime Average Daily Dose (LADD) In a risk assessment the calculated ADD or LADD are estimated quantitatively using assurnptions about the duration frequency and magnitude of exposure experienced by each potential receptor and assumptions about the constituent properties that influence absorption

The quantitative estimation of constituent intake involves the incorporation of numerical assumptions for a variety of exposure parahneters Exposure assumptions used in these intake calculations are based on WVDEP (2001) or USEPA (1989 2002b) recommended values The factors and equation for inhalation of vplatiles is presented in Table 4 and described below

bull Inhalation Rate and Exposure Time WVDEP (2001) and USEPA (2002b) guidance recommend that an inhalation rate of 20 m day be used for workers For an exposure time of 8 hours (a typical workday) this results in an inhalation rate of 25 m hour

bull Exposure Frequency and Duration Default exposure factors for indoor workers are provided by WVDEP (2001) Exposure frequency for the worker is 5 days per week for 50 weeks a year or 250 days per year The exposure duration for these workers is 25 years which is the 95th percentile value ai cording to the Bureau of Labor Statistics (USEPA 1989)

bull Body Weight The default value for average body weight of an adult is 70 kg based on WVDEP (2001) and USEPA guidance (1989 2002b)

Page 2 of 5

AR100289

Risk-Based Remedies

R B R Consulting Inc

bull Averaging Time As described above the doses for noncarcinogenic health effects are averaged oyer the specific period of exposure for a given receptor Noncarcinogenic

averaging times are therefore calculated by multiplying the exposure duration for the receptor by 365 daysyear Carcinogenic health effects are calculated over a lifetime exposure so the value recommended by WVDEP (2001) and USEPA (2002b) for average lifetime 70 years was used for exposure duration The resulting carcinogenic averaging time is 25550 days

TOXICITY VALUES

Noncarcinogenic responses are evaluated numerically using parameters known as the hazard quotient (HQ) and hazard index (HI) the HQ is obtained by dividing the ADD for a constituent by the reference dose (RfD) Each dose calculation with a specific combination of constituent receptor and exposure pathway will have a distinct ADD and calculated HQ HQs associated with all constituents for a particular pathway are summed to yield the HI

In order to estimate the theoretical excess lifetime cancer risk the LADD of a constituent is multiplied by the cancer slope factor (CSF) For each pathway this calculation is carried out for each applicable constituent and the risks are summed to obtain the total potential risk due to that pathway

Toxicity values for each constituent are presented in Table 5 the toxicity values were obtained from the following sources

bull Integrated Risk Information System (IRIS) on-line database provided by USEPA (2009)

bull The USEPAs Provisional Peer-Reviewed Toxicity Values (PPRTV) as presented in the USEPA Regional Screening Tables (ORNL 2009)

bull Provisional value from the National Center for Environmental Assessnient (as per WVDEP)

bull The Agency for Toxic Substances and Disease Registrys (ATSDR) Minimal Risk Levels (MRLs ATSDR 2009) and

bull Value cited by USEPA Region 3 attributed to other sources (as per WVDEP)

RISK CHARACTERIZATION

Potential noncarcinogenic effects associated with exposure to COC at the site are estimated by comparing calculated intakes with the contaminant-specific RfDs The total HI was calculated by summing the individual HQs An HI value equal to or less than 1 indicates thatthelikelihopd of ah adverse noncancer effect would be negligible (USEPA 1989) An HI greater than 1 indicates that additional evaluation of the case is warranted

Theoretical excess lifetime cancer risks associated with exposure to COC from the site were calculated by comparing estimated intakes to constituent-specific CSFs Summed theoretical

Page 3 of 5

AR100290

Risk-Based Remedies

R B R Consulting Inc

excess risks are calculated by combining constituent-specific risks The results may be compared with target benchrharks for acceptable risk Various demarcations of acceptable risk have been established by regulatory agencies WDEP (2001) presents a target cancer risk of 1 x 10 for nonresidential scenarios USEPA (1991) considers potential cancer risks in the range of 1 x 10reg to 1 X 10 to be acceptable

Constituent-specific results for the indoor worker are presented in Table 6 For the indoor worker exposed to COC in indoor air (vapor intrusion from subslab vapor) the total HI is 00081 and the potential cumulative cancer risk is 497 X 10reg

These results meet both WVDEP and USEPA benchmarks indicating that the site poses negligible potential for human health risk for indoor workers

CONCLUSIONS

The results of this focused risk evaluation indicate that potential risks associated with vapor intrusion exposure of indoor workers to constituents that may volatilize from subslab vapor are within the acceptable benchmarks established by WVDEP and USEPA No further evaluation of the vapor intrusion pathway is warranted for the site

REFERENCES

Agency for Toxic Substances and Disease Registry (ATSDR 2009) Minimal Risk Levels (MRLs) Available at httpvtfwwatsdrcdcqovmrisindexhtml

Dolphin Environmental LLC (Dolphin 2000) Site Characterization Report Mach 14 2000

Johnson PC and RA Ettinger (1991) Heuristic model for predicting the intrusion rate of contaminant vapors into buildings Environ Sci Technology 25 1445-1452

Oak Ridge National Laboratory (ORNL 2009) Regional Screening Levels for Chemical Contaminants at Superfund Sites April 15 2009 Available online httpwwwepagovreg3hwmdriskhumanrb-concentration_tableindexhtm

United States Environmental Protection Agency (USEPA 1989) Risk Assessment Guidance for Superfund Volume I PartA Human Health Evaluation Manual EPA5401-89002

United States Environmental Protection Agency (USEPA 1991) Risk Assessment Guidance for Superfund Volume I Part B Development of Risk-Based Remediation Goals Office of Emergency and Remedial Response OSWER Directive 92857-018

United States Environmental Protection Agency (USEPA 2002a) Draft Guidance for Evaluating the Vapor Intrusion to Indoor Air Pathway from Groundwater and Soils Office of Solid Waste and Emergency Response Pub No 92856-10 December 2002

Page 4 of 5

AR100291

Risk-Based Remedies

R B R Consul t ing Inc

United States Environmental Protection Agency (USEPA 2002b) Supplemental Guidance for Calculating Soil Screening Levels for Superfund Sites Office of Solid Waste and Emergency Response December

United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004

United States Environmental Protection Agency (USEPA 2009) Integrated Risk Information System (IRIS) On-line database wwwepaqoviris

West Virginia Department of Environmental Protection (WVDEP 2001) West Virginia Voluntary Remediation and Redevelopment Act-Guidance Manual Version 21 March 13

Page 5 of 5

AR100292

TABLES

AR100293

TABLE 1 SUBSLAB VAPOR SAMPLES INCLUDED IN THE RISK ASSESSMENT

Coyne text i le Services Facility - Huntington West Virginia

Medium

Subslab Vapor

Sample Identification

bull VP-01

VP-02

VP-03

Sample Date

8132009

8132009

8132009

Coyne VIMemo Tables_09-08-09xls 982009

AR100294

TABLE 2 IDENTIFICATION OF CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR

Coyne Textile Services Facility - Huntington West Virginia

mdash

Const i tuent

Volati le Organics

111-Trichlor6ethane

1122-Tetrachloroethane

112-Trichloro-122-trifluoroethane

112-Trichloroethane

11-Dichloroethane

11-Dichloroethene

124-Trichlorobenzene

124-Trimethylbenzene

12-Dibromoethane

12-Dichlor6benzene

12-Dichloroethane

12-Dichloroethene (cis)

12-pichloroethene (trans)

12-Dichloropropane

12-Dichlorotetraf1uoroethane

135-Trimethylbenzene

13-Butadiene

13-Dichlorobenzene

13-Hexachlorobutadiene

14-Dichlorpbenzene

224-trimethylpentane

2-Chlorotoluene

4-Ethyltoluene

Acetone

Allyl Chloride

Benzene

Bromodichloromethane

Bromoform

Bromomethane

Carbon disulfide bull

Carbon tetrachloride

ChJorobenzene

Chloroethane

Frequency of Detection

0 3

0 3

0 3

bull 0 3

0 3

0 3

0 3

1 3

0 3 bull

0 3

b 3 bull

2 3

0 3

bull 0 3

0 3

0 3

0 3 bull

0 3

0 3

0 3

0 3

0 3

0 17

3 3

0 3

P 3

- 0 3

0 3

0 3

0 3

0 3

0 3

0 3

Min imum Detected

Concentrat ion

(ugm^)

ND

ND

ND

ND

ND

- ND

N D

197

ND bull

ND

ND

369

ND

bull~ ND

ND

ND

ND

ND

ND

bull ND

ND

ND

ND

796

ND

ND

ND-

ND

ND

ND

ND

ND

ND

Maximum

Detected Concentrat ion

(ugm3)

ND

ND

ND

ND

ND

ND

ND

197

ND

ND

ND

mdash 6030

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

1880

ND-

ND

ND

ND

ND

ND

ND

ND

ND

Sample wi th Maximum Detect

ND

ND

ND

ND

ND

ND

- ND

VP-03 -

ND

ND

ND

VP-03

ND

bullND

ND

ND

ND

ND

ND

ND

ND

ND

ND

VP-02

ND

ND bull

ND

ND

ND bull

bull ND

ND

ND

ND

Min imum Detection

Limit (ugm3)

22

28

31

22

16

16

30

20

31

24

16

bull 16

16

19

28

20

89

24 bull

43

24

bull 19

2 1

20

--^ 13

13

27

41

16

13

25

18

11

Maximum Detection

Limit (ugm3)

218

275

307

218

162

159

297

197

307

240

162

- 16

159

185

280

197

89

240

427

240

187

207

197

--125

128

268

414

155

125

252

184

106

Vapor Intrusion Corhparison

V a l u e

(ugm)

22000

042

300000

15

bull 5000

2000

2000

60

011

2000

094

350

700

40

NA

60

0087

1100

11

8000

NA

NA

NA

3500

NA

31

14

22

50

7000

16

bull 600

100000

Chemical of Concern

No

No

No

No

No

No

No

YES

No

No

No

YES

No

No

No

N o bull

bullNo

No

No

No

No

No

No

N o

No

No

No

N o

No

No

No

No

No

Comment

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent notdetected

fflaximCimTdeteetlSffieedsTcomDarisonivalues

Constituent not detected

Constituent not detected

Constituent not detected

Maximum detect exceeds comparison value

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Maximum detect below comparison value

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detectedl

Constituent not detected

Constituent not detected

CoyneVI Memo Tables_09-08-09xls 982009

AR100295

TABLE 2

IDENTIFICATION OF CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR

Coyne Textile Services Facility - Huntington West Virginia

Const i tuent

Volati le Organics

Chloroform -

Chloromethane

13-Dichloropropene (cis)

Cyclohexarie^

Dibrcimochloromethane

DichlonDdifluoromethane

Ethylbenzene

Methyl ethyl ketone

Methyl isobutyl ketone

Methyl tert-butyl ether

Methylene chloride

n-Heptane

n-Hexane

Styrene

Tert-butyl alcohol

Tetrachloroethene

Toluene

13-Dichloropropene(trans)

Triehloroethene

Trichlorofluoromethane

Vinyl bromide

Vinyl chloride

Xylene (0)

Xylenes (mampp)

Frequency of Detection

1 3

0 3

0 3

1 3

0 3

0 3

0 -3

1 3

0 3

0 3

2 3

0 3

3 3

0 3

0 3

3 3

1 3

- 0 3

3 3

P 3

0 3

0 3

1 3

1 3

Min imum Detected

Concentrat ion

(ugm)

5910

ND

ND

52

ND

ND

ND

23

ND

ND

1160

ND

1 4 4

ND

ND

11200

18

ND

91

ND

ND

ND

208

387

Maximuri i Detected

Concentrat ion (ugmS)

bull

5910

ND

ND

52

bull ND

ND

ND

23

ND

ND

1520

ND

183

ND

ND

149000

18

ND

7820

ND

bullND

ND

208

387

Sample vyith Max imum Detect

VP-02

ND

ND

VP-01

bull ND

ND

ND

VP-01

ND

ND

VP-02

ND

VP-02

ND

ND

VP-02

VP-01

ND

VP-03

ND

ND

ND

VP-03

VP-03

Min imum Detection

Limit (ugm3)

20

83

18

138

34

bull 20

17

118

16

14

14

16

- -17

12

--151

18

--23

18

10

1 7 bull

1 7 bull

Maximum Detection

Limit (ugm3)

195

83

182

138

341

198

174

118

164

144

14

164

170

121 -

--151

182

225

175

102

bull 174

174

Vapor Intrusion Compar ison

V a l u e

(ugm)

11

24

NA

2000

1

2000

22

10000

800

30000

52

NA

2000

10000

NA

81

4000

NA

022

7000

NA

28

70000

70000

Chemical o f Concern

YES

No

No

No

No bull

No

No bull

No bull=

No

No

YES

No

No

No

No

YES

No

No

YES

N o

No

No

No

No

Comment

Maximum detect exceeds comparison value

Constituent not detected

Constituent not detected

Maximum detect below comparison value

Constituent not detected

Constituent not detected

Constituent not detected

Maximum detect below comparison value

Constituent not detected

Constituent not detected

Maximum detect exceeds comparison value

Constituent not detected bull

Maximum detect below comparison value

Constituent not detected

Constituent not detected

Maximum detect exceeds comparison value

Maximum detect below comparison value

Constituent not detected

Maximum detect exceeds comparison value

Constituent not detected

Constituent not detected

Constituent not detected bull

Maximum detect below comparison value

Maximum detect below comparison value

Notes

ND - Not Detected

NA - Not Available

- - Constituent detected in every sample detection limit not presented

Values in bold indicate detection limit exceeds comparison values

Target shallow soil gas comparison values corresponding to indoor air concentrations where the soil gas to indoor air attenuation factor = 01 and the target cancer risk is set to ip (presented in Table 2c of USEPA 2002a)

Comparison value for cyclohexane is based on the comparison value for hexane

Coyne VI Memo Tables_09-08-09xls 982009

AR100296

TABLES

EXPOSURE POINT CONCENTRATIONS FOR CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR

Coyne Textile Services Facility - Huntington West Virginia

Chemical of Concern

VolatileOrganics

i24-Trimethylbenzene

12-Dichloroethene (cis)

Chloroform

Methylene chloride

Tetrachloroethene Triehloroethene

Subslab Vapor Source

Concentration (mgm^)

0197

603

591

152

149 782

Transport

Factor^ (unitless)

108E-05

108E-05

108E-05

108E-05

108E-05 108E-05

EPC in

Indoor Air (mgm^)

213E-06

651 E-05

638E-05

164E-05

161E-03 844E-05

Notes

^ Subslab vapor source concentration is based on the maximum detected concentration of samples

VP-01-02 and-03 (see Table 2) -

^ Details of the transport factor calculations are presented in Appendix B

^ Exposure Point Concentration (EPC) in inidoor air is calculated as the subslab vapor concentration TF

Coyne VI Memo Tables_09-08-09xls 982009

AR100297

TABLE 4

FACTORS USED IN DOSE CALCULATIONS INHALATION OF VOLATILE EMISSIONS

Coyne Textile Services Facility - Huntington West Virginia

Symbol

CA

IRA

ET

EF

ED-

BW

AT

Exposure Factor

Constituent Concentration in Air

Inhalation Rate

Exposure Time

Exposure Frequency

Exposure Duration

Body Weight

Averaging Time

Indoor Worker

Constituent-Specific See Table 3

25 m hour

8 hrday

250 daysyear

25 years

bull 70 kg

9125 days (NC)

25550 days (C)

Total Dose = CA x IR^ x ET x EF x ED x 1BW x 1AT

(NC) - Non-carcinogenic Averaging Time

(C) - Carcinogenic Averaging Time

Coyne VI Memo Tables_09-08-09xls 982009

AR100298

TABLES TOXICITY VALUES FOR CHEMICALS OF CONCERN

Coyne Textile Services Facility - Huntington West Virginia

Chemical of Concern

Volatile Organics

124-Trimethylbenzene

12-Dichloroethene (cis)

Chloroform

Methylene chloride

tetrachloroethene

Triehloroethene

Target Organ Critical Effect

blood

bullblood

liver

liver

liver CMS

liver kidney fetus CNS

Chroniclnhalation Reference Dose

(mgkg-day)

200E-03 P

1 OOE-02 R

140E-02 E

286E-01 M

771 E-02 M

1OOE-02 E

Inhalation Cancer ^ Slope Factor

(mgkg-day)^

NA

NA

805E-02 1

165E-03 1

200E-02 0

400E-01 E

(I) - Integrated Risk Information System (IRIS USEPA 2009)

(P) - Provisional Peer-Reviewed Toxicity Value (PPRTV) as presented in USEPA Regional Screening Tables (ORNL 2009)

(R) - Calculated assuming route-to-route extrapolation as per WVDEP

(E)-Provisional value from the National Center for Environmental Assessment (as per WVDEP)

(M)-Chronic Minimal Risk Level (MRL ATSDR 2009)

(0) - Value cited by USEPA Region 3 attributed to other sources (as per WVDEP)

Coyne VI Memo Tables_09-08-09xls 982009

AR100299

TABLE 6

NONCANCER HAZARD INDEX AND POTENTIAL CANCER RISK FOR AN INDOOR WORKER

Coyne Textile Services Facility - Huntington West Virginia

bull

Constituent

Volatile Organics

124-Trinnethylbehzene

12-Dichlorpethene (cis)

Chloroform

Methylene chloride

Tetrachloroethene Triehloroethene

EPC in Indoor Air

(mgm)

213E-06

651 E-05

- 638E-05

164E-05

161 E-03

844E-05

Intake (ADD)

(mgkg-d)

416E-07

127E-05

125E-05

321 E-06

315E-04 l65E-05

RfDi

(mgkg-d)

200E-03

1OOE-02

140E-02

286E-01

771 E-02 1 OOE-02

Hazard

Quotient

208E-04

127E-03

892E-04

112E-05

408E-03 165E-03

Intake (LADD)

(mgkg-d)

) 149E-07

455E-06 bull 446E-06

115E-06

112E-04 590E-06

CSFi

(mgkg-d)

NA

NA

805E-02

165E-03

200E-02

400E-01

Potential

Cancer Risk

NA

NA

359E-07

189E-09

225E-06 236E-06

Total Hazard Index

00081 Total

Cancer Risk 497E-06

Total Blood HI = Total Liver HI =

Total Central Nervous System HI = Total Kidney HI =

Total Fetal HI =

bull 00015 00066 00057 00017 00017

Notes NA = Toxicity values are not available for this endpoint or exposure pathway

Coyne VI Memo Tables_09-08-09xls 982009

AR100300

APPENDIX A

SUBSLAB VAPOR ANALYTICAL DATA

AR100301

Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility Huntington West Virginia

Sample

Consti tuent

Volatile Organics (ugm) 111-Trlchloroethane 1122-Tetrachloroethane 112-Trichloro-122-trifluoroethane 112-Trichloroethane 11-Dichioroethane 11-Dichloroethene 124-Trichloroberi2ene 124-Trimethylbenzene 12-Dibromoethane 12-Dichloroben2ene 12-Dichloroethane 12-Dichloroethene-(cis) -12-Dichloroethene (trans) 12-Dichloropropane 12-Dichlorotetrafluoroethane 135-Trimethylbenzene 13-Butadiene 13-Dichlorobenzene 13-Hexachlorobutadiene 14-Dichlorobenzene 224-trimethVlpentane 2-Chlorotoluene 4-Ethyltoluene Acetone Allyl Chloride Benzene Bromodichloromethane Bromoform Bromomethane Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 13-Dichloropropene (cis) Cyclohexane Dibromochloromethane

Identif ication Sample Date

CAS No

71-55-6 79-34-5 76-13-1 79-00-5 75-34-3 75-35-4 120-82-1 95-63-6 106-93-4 95-50-1 107-06-2 156-59-2 156-60-5 78-87-5 76-14-2 108-67-8 106-99^0 541-73-1 87-68-3 106-46-7 540-84r1 95-49-8

622-96-8 67-64-1 107-05-1 71-43-2 75-27-4 75-252 74-83-9 75-15-0 56-23-5 108-90-7 75-00-3 67-66-3 74-87-3

10061-01-5 110-82-7 124-48-1

lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt

lt lt lt lt lt lt lt lt lt lt lt lt

lt

VP-01 8132009

22 28 31 22 16 16 30 20 31 24 16 16 16 19 28 20 89 24 43 24

1 9 21 20 796 13 13 27 41 16 13 25 18 11 20 83 18 52 34

lt lt lt lt lt lt lt lt lt lt lt

lt lt lt lt lt lt lt lt lt lt lt

lt lt lt lt lt lt lt lt lt

lt lt lt lt

VP-02 8132009

218 2 7 5 307 218 162 159 297

bull 197 307 240 162 369 159 185 280 197 89

240 427 240 187 207 197

1880 125 128 268 414 155 125 252 184 106

5910 83 182 138 341

lt lt lt lt lt lt lt

lt lt lt

lt lt lt lt lt lt lt bull

lt lt lt lt

lt lt lt lt lt lt lt lt lt lt lt lt lt lt

VP-03 8132009

218 275 307 218

bull 162 159 297 197 307 240 162

6030 159 185 280 197 89

240 427 240 187 207 197

1750 125 128 268 414 155 125 252 184 106 195 83 182 138 341

Appx A SG Dataxis Page 1 of 2 982009

AR100302

Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility bull Huntington West Virginia

Consti tuent

Volatile Organics (ugm^) Dichlorodifluoromethane Ethylbenzene Methyl ethyl ketone Methyl Isobutyl ketone Methyl tert-butyl ether Methylene chloride n-Heptane jn-Hexane Styrene Tert-butyl alcohol Tetrachloroethene iToluene 13-Dichloropropene (trans) Triehloroethene Trichlorofluoromethane Vinyl bromide Vinyl chloride Xylene (o) Xylenes (mampp)

Sample Identif ication Sample Date

CAS No

75-71-8 100-41-4 78-93-3 108-10-1

1634-04-4 75-09-2

142-82-5 bull 110-54-3

100-42-5 75-65-0 127-18-4 108-88-3

10061-02-6 79-01-6 75-69-4 593-60-2 75-01-4 95-47-6

179601-23-1

lt lt

lt lt lt lt

lt lt

lt

lt lt lt lt lt

VP01 8132009

20 17 23 16 14 14 16

173 17 12 bull

11200 18 18 91 23 18 10 17 17

lt lt lt lt lt

lt

lt lt

lt lt

lt lt lt lt lt

VP-02 8132009

198 174 118 164 144

1520 164 -183 170 121

149000 151 182

2360 225 175 102 174 174

VP-03 8132009

lt 198 lt 174 lt 118 lt 164 lt 144

1160 lt 164

144 lt 170 ltbull 121

90500 lt 151 lt 182

7820 lt 225 lt 175 lt 102

208 387

Appx A SG Dataxis Page 2 of 2 982009

AR100303

APPENDIX B

CALCULATION OF TRANSPORT FACTORS USED TO ESTIMATE INDOOR AIR CONCENTRATIONS

AR100304

APPENDIX B

Calculation of Transport Factors Used to Estimate Indoor Air Concentrations

This appendix presents the methodology for calculating transport factors that are used to convert subslab

vapor concentrations to concentrations in indoor air 124-Trimethylbenzene 12-dichloroethene (cis)

chloroform methylene chloride tetrachloroethene and triehloroethene were identified as contaminants of

concern (COC) for potential vapor intrusion from subslab vapor associated with the Coyne Textile

Services Facility located in Huntington West Virginia (site) In this appendix the transport factors are

calculated to estimate the concentrations of COC in indoor air of the existing plant building located at the

site ~

Transport Factor for Indoor Air

The concentration of a constituent in indoor air (da) is proportional to the concentration of the constituent

in the subslab vapors immediately beneath the building foundation (ie subslab vapor concentration or

Csubsiab) The following equation is used to calculate da from Csubsiab

^ wja ~ ^subslab X I r

where

Cia = concentration of constituent in indoor air (mgm^) -

Csubsiab^ concentration of constituent in subslab vapors (mgm^) and

TF = transport factor from subslab vapors to indoor air

The transport factor (TF) is an infinite source attenuation coefficient andcan be calculated based on a

model developed by Johnson and Ettinger (1991) t he equation for calculating TF is as follows

(Deff X A B ) ( Q B X L T ) X expKQso i l X Lcrabk)(Dcrack X Acrack)]

exp[ (Qsoi l X Lcrack)(Dcrack X Acrack)] + (Deff X A B ) ( Q B X L T ) + (Deff X AB)(Qsoi l X L j ) X (exp [ (Qso i l X Lcrack)(Dcrack X Acrack)] - 1)

where

Deff = effective diffusion coefficient for vadose zone soil (cm^sec)

AB = area of enclosed space below grade (cm^)

QB = building ventilation rate (cm^sec)

LT = distance from contaminant source to building foundation (cm)

Qsoii = volumetric flow rate of vapors into the building (cm^sec)

Lcrack = foundatlon thickness (cm)

Dcrack = vapor diffusion coefficient through crack (cm^sec) and

Acrack = area of cracks through which vapors can pass (cm^)

AR100305

To solve this equation the USEPAs SG-ADV spreadsheet Version 31 most recently updated in

February 2004 was implemented A combination of site-specific factors and default values from the

Users Guide for Evaluating Subsurface Vapor Intrusion Into Buildings (USEPA 2004) were used as input

values in the model All input values are defined below and presented in Tables B-1-A through B-6-A

bull The initial subslab vapor concentration (Csubsiab) is the maximum detected concentration(in units

of ugm ) of samples VP-01 VP-02 and VP-03 that was presented in Table 3 of the report

bull The depth below grade to the bottom of the enclosed space floor (Lp) is set to 15 cm the default

value provided by USEPA (2004) for a slab-on-grade structure

bull The vapor sampling depth below grade (Lg) is a site-specific value The vapor samples were

collected from immediately beneath the building floor therefore Lj has been set to 15 cm

bull The average soilgroundwater temperature (Ts) is set to 125degC the average value for West

Virginia as estimated frorri Figure 8 of the vapor intrusion users guide (USEPA 2004)

bull The soil type used to estimate vapor permeability is assumed to be sandy loam (SL) The

associated soil properties for a sandy loam soil type are as follows the soil dry bulk density (Pb) is

162 gcm the total porosity (n) is 0387 (cm^-aircm^) and the water-filled porosity (nw) is 0103

(cm -HzOcm )

bull The floor thickness (Lcrack) is set to the USEPA (2004) default value of 10 cm

bull The soil-building pressure differential (AP) is set to the USEPA (2004) default value of 40 gcm-s^

bull The building dimensions are siterspecific based on the existing plant building located at the site

The existing structure is approximately 84000 square feet (Dolphin 2000) therefore the

dimensions are set to 8839 cm (290 feet) length by 8839 cm (290 feet) The USEPA (2004)

default value of 244 cm vyas used for the height

bull Thefloor-wall seam crack width (w) is set to the USEPA (2004)-default value of 01 cm

bull The indoor air exchange rate (ER) is set to 083hour This is the value provided by ASTM (2002)

for commercial and industrial buildings

AR100306

Tables B-1-B through B-6-B present the constituent-specific properties for COC that were used in the TF

calculations Tables B-1-C through B-6-C present the intermediate calculations used to determine the

indoor air attenuation coefficients (ie the transport factors) The shaded boxes in Tables B-1-C through

B-6-C also present the resulting TF values that are applied to the concentrations of COC in subslab

vapor and the estimated indoor air concentrations

References

American Society for Testing and Materials (ASTM 2002) Standard Guide for Risk-Based Corrective Action Applied at Petroleum Release Sites ASTM E-1739-95 (Reapproved 2002)

Johnson PC and RA Ettinger (1991) Heuristic model for predicting the intrusion r-ate of contaminant vapors into buildings Environ Sci Technolpgy 25 1445-1452

Dolphin Environmental LLC (Dolphin 2000) Site Characterization Report Mach 14 2000

United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004

AR100307

APPENDIX B-1-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV Nersion31 0204

Reset to Defaults

ENTER -

Chemical CAS No

(numbers only

no dasties)

95636

ENTER Soil gas

cone

Cg (ngm)

Soil Gas Concentration Data ENTER

Soil gas

OR cone

bull - c bull (PPmv)

197E+02

Chemical

124-Trimethylbenzene

MORE ENTER Depth

below grade to bottom

of enclosed space floor

U bull (cm)

ENTER

Soil gas sampling

depth below grade

U (cm) bull

ENTER

Average soil

temperature Ts

CO

1 15 1 1 5 bull125

ENTER ENTER ENTER Totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hft ha he

(cm) (cm) (cm)

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estirnate OR permeability | soil vapor

permeability) k v bull

(cm)

SL 1 1

MORE ENTER

stratum A SCS

soil type

Lookup Soil Parameters

ENTER stratum A soil dry

bulk density P

(gcm)

ENTER Stratum A soil total porosity

(unitless)

ENTER bull stratum A soil water-filled

porosity

(cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

nlaquo

(unitless)

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gchi-s^)

ENTER Enclosed

space floor

length bull LB

(cm)

ENTER Enclosed

space floor

width WB

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

bull Floor-wall seam crack

width w

(cm)

bullENTER

Indoor air exchange

rate ER

(1h) bull

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bidg OR

Leave blank to caicuij

(Lm)

Appx B-1 124-TMBxls 1 of 3 982009

AR100308

APPENDIX B-1-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of ^ bull law constant law constant vaporization at Normal

Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temperature boiling point point temperature weight

D bull Dbdquo H T R bull AHbdquo TB Tc IVIW

Unit risk Reference

factor cone URF RfC

(cms) (cmls) (atm-mmol) CO (calmol) (degK) (degK) (gmol) bull (ugm)- (mgm)

1 606E-02 1 792E-06 1 bull 614E-C3 1 25 1 9369 1 44230 | 64917 1 12020 1 OOE+00 1 60E-03 1

Appx B-1 124-TMBxls 2 of 3 982009

AR100309

APPENDIX B-1-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

(sec)

Source-building

separation

LT bull

(cm) bull

Stratum A soil

air-filled porosity

Q A

Stratum B soil

air-filled porosity

(cmcm) (cmcm)

Stratum C soil air-filled porosity

(cmcm)

Stratum A effective total fluid

saturation

Se

(cmcm)

Stratum A soil

bullintrinsic permeability

^ (cm)

stratum A Stratum A Floor- soil soli wall BIdg

relative air effective vapor seam Soil bull ventilation permeability permeability perimeter gas rate-

kfg ky Xgrack c o n e - QbuHdinpound

(cm) - (cm) (cm) (ngm) (cms)

946E+08 1 0284 0284 0284 0184 596E-09 0901 537E-09 35357 I 197E+02 | 439E+06 |

Area of enclosed

space below grade

As (cm)

Crack-to-total area ratio

1 bull

(unitless)

Crack depth

below grade

Zcfack

(cm)

Enthalpy of vaporization at

ave soil temperature

AHvjs

(calmol) bull

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law constant at

ave soil bull temperature

bull HTS

(unitless)

Vapor bull viscosity at

ave soil temperature

HTS

(gcm-s)

Stratum A

effective diffusion

coefficient

D (cms)

Stratum-B

effective diffusion coefficient

DB (cms)

Stratum C effective diffusion

coefficient

D-c (cms)

Total - overall effective diffusion

coefficient

D ^ (cms)

Diffusion path

length

L-

(cm)

I 787E+07 I 449E-05 | 15 | 11661 260E-03 111E-01 176E-04 I 612E-03 j OOOE+00 | OOOE+00 | 612E-03 j

bull Convection path

length

Lp

(cm)

Source vapor cone

^source

(ngm)

Crack radius

Tcfack

(cm)

Average vapor

flow rate into bIdg

Qsoii

(cms)

Crack effective diffusion

coefficient pcrack

(cms)

Area of CTack

Acack

(cm)

Exponent of equivalent foundation

Peclet number

exp(Pe)

(unitless)

bull bull - bull bull bull bull

1 15 1 197E+02 1 010 1 474E+01 612E-03 bull 354E-t-03 1 336E+09

Infinite source Indoor

~ attenuation coefficient

a

(unitless)

108E-05

Infinite source

btJbldgjJSv-L ^Ppncji3i-

virhpbiiilding bullbull ^lHltti^m)ilg

213E-03

Unit risk

factor

URF

(ngm)-

Reference cone

RfC (mgm)

NA 60E-03 1

I END

Appx B-1 124-TMBxls 3 of 3 982009

AR100310

APPENDIX B-2-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV Nersion31 020^

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

156592

Soil Gas Concentration Data ENTER

Soil gas

cone OR c

(ngm) bull

ENTER Soil bull-gas

cone

c (ppmv)

603E+03 1

Chemical

cis-12-Dichloroethylene

MORE ENTER Depth

below grade to bottom

of enclosed space floor

LF

(cm)

ENTER

Soil gas sampling

depth below grade

U (cm)

ENTER

Average soil

temperature bull Ts

(degC)

1 15 1 bull 15 125

ENTER ENTER ENTER Totalsmust add ijp tb value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hA hB he

bull (cm) (cm) (cm)

15 1 1

ENTER Soil

straturh A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estimate OR permeability | soil vapor

permeability) kv

(cm)

SL 1 |

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

P (gcm)

ENTER Stratum A soil total porosity

bull n

(unitless)

ENTER Stratum A

soil water-filled porosity

(cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

ENTER Stratum B

soil water-filled porosity

ENTER Stratum C

SCS soil type

(unitless) (cmcm)

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure differential

AP

(gcm-s)

ENTER Enclosed bull

space floor

length

LB (cm)

ENTER Enclosed

space floor

width WB

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER

Average vapor flow rate into bIdg

OR Leave blank to calculi

Qsoil

(Lm)

Appx B-2 cis-12-DCExls 1 of 3 982009

AR100311

APPENDIX B-2-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Diffusivity in air

Da

(cms)

Diffusivity in water

Dw (cms)

Henrys law constant at reference temperature

H

(atm-mmoi)

Henrys law constant

reference temperature

bull T R

CC)

Enthalpy of vaporization at

the normal boiling point

AHbdquob

(calmol)

Normal boiling point

TB

(degK)

Critical temperature

Tc (degK)

Molecular weight

MW

(gmol)

Unit risk

factor URF

(ngm)

Reference cone

RfC (mgm)

1 736E-02 1 113E-05 1 407E-03 j 1 25 1 bull 7192 1 33365 1 54400 1 9694 1 OOE+00 j 35E-02 1

Appx B-2 cis-12-DCExls 2 of 3 982009

AR100312

APPENDIX B-2-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

stratum A Stratum B Stratum C Source- soil soil soil

Exposure building air-filled air-filled air-filled

duration separation porosity porosity porosity

T LT ea e^ bull e= (sec) (cm) (cmcm) (cmcm) (cmcm)

I 946E+08n^

Stratum A Stratum A Stratum A Stratum A Floor-effective soil soil soil wall total fluid intrinsic relative air effective vapor seam

saturation permeability permeability permeability perimeter

Ste kj krg ky Acrack

(cmcm) (cm) (cm) (cm) (cm)

Soil gas

cone (ngm)

I 0284 I 0284~ 0284 0184 I 596E-09 | 090T 537E-09 35357 603E+03

BIdg ventilation

rate

JbulldinE

(cms)

439E+06

Area of enclosed

space below grade

AB

(cm)

Crack-to-total

area ratio

n (unitless)

Crack depth below grade

Zltiack (cm)

Erithalpy of vaporization at

ave soil temperature

AHvTs (calmol)

Henryslaw constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law constant at

ave soil temperature

HTS

(unitless) bull

Vapor viscosity at

ave soil bull temperature

HTS

bull (gcm-s)

Stratum A

effective bull diffusion

coefficient

D^A-(cms)

Stratum B

effective bull diffusion

coefficient

D=B

(cms)

Stratum C

effective diffusion bull

coefficient

D=e (cms)

Total overall

effective diffusion

coefficient

DT

(cms)

Diffusion path

length

Ld

(cm)

I 787E+07 I bull449E-05 | 15 bull7709 230E-03 982E-02 176E-04 | 743E-03 | OOOE+00 | OOOE+00 | 743E-03 |

bull bull bull -

Convecfion path -bull

length

Lp (cm)

Source vapor cone

-source

(Mgm)

Crack radius

fcrack

(cm)

Average vapor

flow rate into bIdg

Qaoil bull

(cms)

Crack effective diffusion

coefficient pcack

(cms)

Area of crack

crack

(cm)-

Exponent of equivalent foundation

Peclet number

exp(Pef)

(unitless)

bull

1 15 -1 603E+03 1 010 1 474E+01 743E-03 354E+03 1 697E+07

Infinite source Indoor

attenuation coefficient

poundbullbullbull C t

pound(unitless)

bullsiilaquogt j ii08E-05

Infinite [ source

bIdg cone

Cbujidjng

(pgm)

651 E-02 iKrt

Unit risk

factor

URF

(ngm)-

Reference cone

RfC

(mgm)

NA 35E-02 1

I END I

Appx B-2 cis-12-DCExls 3o f3 982009

AR100313

APPENDIX B-3-A DATA ENTRY SHEET

Coyne Texti le Services - Hunt ington West Virginia

SG-ADV Version 31 0204

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

67663

Soil Gas Concentration Data ENTER ENTER

Soil Soil gas gas

cone OR cone c C

(^gm) (ppmv)

591 E+03

bull

Chemical

Chloroform

MORE ENTER Depth

below grade tb bottom

of enclosed space floor

bull LF

(cm)

ENTER

Soil gas sampling depth

below grade

(cm)

ENTER

Average soil

temperature-Ts

CO bull

1 15 1 15 1 125

ENTER ENTER ENTER Totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

IIA hs he (cm) (cm) (cm)

1 5 bull 1 1

ENTER ENTER Soil - bull

stratum A User-defined SCS stratum A

soil type bull soil vapor (used to estimate OR permeability

soil vapor k

bull permeability) (cm) 1

SL 1 1 bull

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A soil dry

bulk density

Pb (gcm)

ENTER Stratum A soil total porosity

nV (unitless)

ENTER Stratum A

-soilwater-filled bullporosity

Sraquo (cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

(unitless)

ENTER Stratum B

soil water-filled porosity

bull ebdquo=

(cmcm) bull

ENTER Straturri C

SCS bull soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

- c rack

(cm)

ENTER

Soil-bldg pressure

differential AP^

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor

width bull W B

(cm)

ENTER

Enclosed space

height HB

(cm)

ENTER

bull Floor-wall^ seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bidg OR

Leave blank to calculi

Qsoil bull

(Lm)

I -I

Appx B-3 Chloroformxls 1 of 3 982009

AR100314

APPENDIX B-3-B CHEMICALPROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Diffusivity in air

D (cms)

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffijsivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature

Dbdquo H TR A H bdquo TB Tc

(cm s) (atm-m mol) ro (calmol) (degK) (degK)

Molecular weight

MW

(gmol)

Unit risk

factor URF

(ngm)-

Reference cone

RfC

(mgm)

104E-01 100E-05 I 366E-03 25 6988 33432 53640 11938 I 23E-05 | OOE+00

Appx B-3 Chloroformxls 2 of 3 982009

AR100315

APPENDIX B-3-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure

duration

(sec)

Source-

building

separation

LT

(cm)

Stratum A

soil

air-filled

porosity

Sa

( cm cm )

Stratum B

soil

air-filled

porosity

( cm cm )

Stratum C

soil

air-filled

porosity

( c m c m )

Stratum A

effective

total fluid

saturation

( c m c m )

Stratum A

soil

intrinsic

penmeability

k

(cm )

Stratum A

- soil

relative air

permeabil i ty

(cm )

Stratum A

soil

effective vapor

permeability

kv

(cm )

Floor-

wall

seam

perimeter

gtcrack

(cm)

Soil gas

cone

(ngm)

BIdg

venfilation

rate

^buildlriE

(cms)

I 9 4 6 E + 0 8 ~ T I 0284 T 596E-09 I 0-901 I 537E-09 | 35357 | 591 E+03 j 439E+06 | 1 0 284 0284 0184

Area of

enclosed

space

below

grade

A B

( c m )

Crack-

to-total

area

ratio

n

(unitless)

Crack

depth

bull below

grade

^crack

(cm)

Enthalpy of

vaporization at

ave soil

temperature

AHTs bull

(calmol)

Henry s law

constant at

ave soil

temperature

HTS

(a tm-m mol j

Henrys law

constant at

ave soil

bull temperature

HTS

(unitless) bull

Vapor

viscosity at

ave soil-

temperature

^HTS

(gcm-s)

Stratum

A

effective

diffusion

coefficient

(cm s)

Stratum

B

effective

difftjsion

coefficient

D B

(cms) bull

S t ra tum

C

effective

diffusion

coefficient

Dc

(cm s)

Total

overall

effective

bull diffusion

coefficient

D T

(cm s)

Diffi jsion

path

length

Ld

(cm)

I 787E+07 I 449E-05 j - bull 15 7528 210E-03 896E-02 176E-04 I 105E-02 | OOOE+00 | OOOE+00 | 105E-02

Convection

path length

Lp

(cm)

Source

vapor

cone -

^source

- (ngm)

Crack

radius

Tcrack

(cm)

Average

vapor

flow rate

into bidg

Qsoil

(cms)

Crack

effective

diffusion

coefficient Qcrack

bull (cms)

Area of crack

Acrack

(cm)

Exponent of

equivalent

foundation

Peclet number

exp(Pe)

(unitless)

V bull bull

1 15 1 591 E+03 1 010 1 474E+01 105E-02 354E+03 1 355E+05

Infinite

source

indoor

attenuation

coefficient

d

(unitless)

bull 108E-05

Infinite

source

bIdg

cone

^ b u i l d i n g

i (^gm)

bull bull

i 638E-02 -

Unit

risk bull factor

URF

(ngmY

Reference

cone

RfC

(mgm)

~ 23E-05 NA 1

I END

Appx B-3 Chloroform xls 3 of 3 982009

AR100316

APPENDIX B-4-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ersion 31-020^

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

nodashes)

bull 75092

ENTER Soil gas

cone

c (ngm)

Soil Gas Concentration Data ENTER

Soil gas bull

OR cone

bull C

(ppmv)

152E+03

bull bull

Chemical

Methylene chloride

MORE

MORE 4gt

ENTER Depth

below grade to bottom

of enclosed space floor

LF -

(cm)

ENTER

Soil gas sampling depth

below grade

bull U

(cm)

ENTER

Average soil

temperature

Ts bull CC)

bull bull bull bull

1 15 1 15 125

ENTER Totals

Thickness of soil

stratum A h

(cm)

ENTER ENTER must add up to value of Ls (cell F24

Thickness Thickness of soil of soil

stratum B stratum C (Enter value or 0) (Enter value or 0)

he he bull

(cm) bull (cm) -

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(usedto estimate OR perrrieability | soil vapor

permeability)

k bull

(cm)

SL 1 bull 1

ENTER Stratum A

SCS soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

Pb (gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Stratum A

soil water-filled porosity

9w (cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

Pb^

(gcm)

ENTER Stratum B soil total porosity

n^

(unitless)

ENTER Stratum B

soil water-filled porosity

(crhcm)

ENTER Stratum C

SCS soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE 4gt

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

bull Soil-bldg pressure

differential AP^

(gcm-s)

ENTER Enclosed

space floor

length LB

(cm)

ENTER Enclosed

space floor

width bull W B

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width

w

(cm)

ENTER

Indoor air exchange

rate

ER (1h)

ENTER Average vapor

flow rate into bidg OR

Leave blank to calculc

Qsoil

(Lm)

10 40 8839 8839 244 01 083

Appx B-4 MCxIs 1 of 3 982009

AR100317

Diffijsivity in air

D

APPENDIX B-4-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffusivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature

Pw H TR AHt TB TC

Molecular weight

MW

Unit risk

factor URF

Reference cone

RfC

(cms) (cms) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) bull (ngm)- (mgm)

bull bull

1 101E-01 1 117E-05 1 218E-03 1 25 | 6706 1 31300 1 51000 1 8493 1 47E-07 1 30E+00 1

Appx B-4 MCxIs 2 of 3 982009

AR100318

APPENDIX B-4-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

T

(sec)

Source- -building

separation

LT

(cm)

Stratum A soil

air-filled porosity

e a bull

(cmcm)

Stratum B soil

bullair-filled porosity bull

ea^ (cmcm)

Stratum C soil

air-filled porosity

ea= (cmcmj

Stratum A effective total fluid

saturation

Sc bull

(cmcm)

Stratum A soil

intrinsic pemneability

ki (cm)

Stratum A soil

relative air permeability

^ ^ g

(cm)

stratumA bull soil effective vapor permeability

K (cm)

Floor-wall

seam perimeter

Xcrack

(cm)

Soil gas

cone (ngm)

BIdg ventilation

rate

Qbuildinc

(cms)

1 946E+08

Area of -enclosed

space below

bull grade

AB

(cm)

1

Crack-to-total

area rafio

Tl

(unitless)

0284 1

Crack depth below grade

Zcrack

(cm)

0284 1

bull Enthalpy of vaporization at

ave soil temperature

AHTs (calmol)

0284

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

0184

Henrys law constant at ave soil

temperature

HTS

bull (unitless)

1 596E-09

Vapor viscosity at

ave soil temperature

Mrs (gcm-s)

0901

Stratum A

effective diffusion

coefficient

D (cms)

537E-09

Stratum B

effective diffusion

coefficient

D-B (cms)

35357 1

Stratum C -

effective diffusion

coefficient

D-c ^ (cms)

152E+03

Total bull overall

bull effective diffusion

coefficient

D ^

(cms)

440E+06 1

Difftjsion path

length

Ld (cm)

1 787E+07

Convection path

length

Lp (cm)

4 49E-05

Source vapor cone

Csource

(ngm)

15 1

Crack radius

Tcrack

(cm)

7007 bull 1

Average vapor

flow rate intobldg

Qsoil

(cms)

130E-03

Crack effective diffusion

coefficient pcrack

(cms)-

555E-02

bull ^

Area of crack

Acrack

(cm) bull

1 176E-04

Exponent of equivalent foundation

Peclet number

exp(Pe)

(unitless) bull

bull bull

1 15

1 END

152E+03 010 1 474E+01 1 102E-02 354E+03 1 519E+05

102E-02

Infinite source

indoor ^attenuation coefficient

bull a

(unitless)

aiii08E-05

0 OOE+00

bull

Infinite bull source

bIdg ^ cone

^bu i l d i ng

(MQm)

164E-02

OOOE+00 1

Unit risk

factor

URF

(ngm)-

47E-07 1

102E-02 j

Reference cone

RfC

(mgm)

30E+00 j

1 1

Appx B-4 MCxIs 3 of 3 982009

AR100319

APPENDIX B-5-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ^erslon 31 0204

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

127184

Soil Gas Concentration Data ENTER ^ ENTER

Soil -Soi l bull gas gas

cone OR cone Cg C bull

(tgm) (ppmv)

149E+05 1

Chemical

bull Tetrachlbroethylene

MORE 4

ENTER Depth

below grade to bottom

ofenclosecJ space floor

LF

(cm)

ENTER

Soil gas bull sampling

depth below grade

u bull (cm)

ENTER

Average bullsoil

temperature - Ts

ro 1 1 5 1 15 1 125 bull

ENTER ENTER ENTER totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hft bull he bull he

(cm) (cm) (cm)

bull 1 5 1 - 1

ENTER ENTER Soil

stratum A User^defined bull SCS bull stratum A soil type soil vapor

(used to estimate OR perrrieability soil vapor K bull

permeability) (cm) 1

SL 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

Pb

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Sitratum A

soil water-filled bull porosity

(cmcm)

ENTER Stratum B

SCS soiltype

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

Pb^

(gcm)

ENTER Stratum B soil total porosity

Ajnitless^

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS soil type

LookupSoil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

VS

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor width

W B

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width

w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

ENTER Average vapor

flow rate into bidg OR

Leave blank to calcul

bull Qsoil

(Lm)

10 40 8839 8839 244 01 083

Appx B-5 PCExIS 1 of 3 982009

AR100320

APPENDIX B-5-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal Unit

Diffusivity Diffusivity at reference reference the riormal boiling Critical Molecular risk Reference in air in water temperature temperature boiling point point teriiperature weight factor cone

Da Dbdquo H TR AHb TB Tc MW URF RfC

(cms) (cnis) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) (^gm)- (mgm)

1 720E-02 1 820E-06 1 184E-02 1 25 1 8288 1 39440 1 62020 1 16583 1 59E-06 1 60E-01 1

J

AppxB-5PCExls 2 of 3 - 982009

AR100321

APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

T

(sec)

Source-building

separation

LT

bull (cm)

Stratum A soil

air-filled porosity

Oa (cmcm)

Stratum B - soil air-filled porosity

ea (cmcm)

Stratum C soil

air-filled porosity

ea= - (cmcm)

Stratum A effective total fluid

saturation

sbdquo (cmcm)

Stratum A soil

intrinsic permeability

ki (cm)

Stratum A soil

relative air permeability

- ^ g

(cm)

Stratum A soil

effective vapor permeability

kv (cm)

Floor-wall

seam perimeter

^crack

(cm)

Soil gas

cone

(ngm)

BIdg venfilation

rate

Qbuildins

bull (cms)

bull bull

1 946E+08

Area of enclosed

space below grade

AB

(cm)

1

bullCrack-to-total

area ratio

1 (unitless)

0284 1

Crack bull depth below grade

Zcrack

(cm) -

0284 1

Enthalpy of vaporization at bull

ave soil temperature

bull A H V TS

(calmol)

0284

Henrys law constant at

ave soil temperature

HTS (atm-mmol)

0184

-Henrys law constant at

ave soil temperature

HTS

(unitless)

1 596E-09

Vapor viscosity at

ave soil temperature

HTS

(gcm-s)

0901

Stratum A

effective diffusion

coefficient bull D = bull

(cms)

537E-09

Stratum B

effective diffusion

coefficient

D--B (cms)

35357 1

Stratum C

effective diffusion bull

coefficient

D-c (crris)

149E+05

Total overall

effective bulldiffusion coefficient

DT

(cms)

440E+06 1

Difftjsion path

length

U (cm)

1 787E+07

Convection path

length

bull Lp

(cm)

4 49E-05

Source vapor cone

^source

(ngm)

15 1

Crack radius

Tcrack

(cm)

9528 1

Average vapor

flow rate intobldg

Qsoil (cms)

908E-03

Crack effective diffusion

coefficient pcrack

bull ( c m s ) bull

387E-01

Area of crack

Abdquoack (cm)

1 176E-04

Exponent of equivalent foundafion

Peclet number

exp(Pe)

(unitless)

bull

1 15-

1 END

149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08

727E-03

Infinite source indoor

attenuation coefficient

a

(unitless)

108E-05

OOOE+00

Infinite source

bIdg cone

Cburldtng

(Mgm)

161 E+00

OOOE+00 1

Unit risk

factor

URF

(ugm)-

59E-06 1

727E-03

Reference cone

RfC (mgm)

60E-01

1 1

Appx B-5 PCExls 3 of 3 982009

AR100322

APPENDIX B-6-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ersion31 0204

Reset to Defaults

t

Soil Gas Concentration Data ENTER

Chemical CAS No

(numbers only

no dashes)

79016

ENTER ENTER Soil Soil gas gas

cone OR cone C C -

bull (ngm) (ppmv)

782E+03

Chemical

Trichloroethylene

MORE ENTER Depth

below grade to bottom-

of enclosed space floor

LF

(cm)

ENTER

Soil gas sarnpling

depth below grade

U (cm)

ENTER

Average soil

temperature Ts

(degC)

1 15 1 15 t 125

ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e

(cm) (cm) (cm)

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estimate OR permeability soil vapor

permeability)

k (cm)

bull S L 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil bull-Parameters

ENTER Stratum A

soil dry bulk density

P b -

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Stratum A bull

soilwaterrfilled porosity

(cmcm) bull

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

bull P ^ (gcm)

ENTER Stratum B soil total

porosity

nlaquo

(unitless) -

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS bull soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor

width W B

(cm)

ENTER

Enclosed space height

H B bull

( c m ) bull

ENTER

Floor-wall seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bIdg OR

Leave blank to calculc

Qsoil

(Lm) -

Appx B-6 TCExIs 1 of 3 982009

A

AR100323

APPENDIX B-6-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight

Da Dbdquo H TR AH^b TB TC MW

Unit risk Reference

factor cone URF RfC

(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)

1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1

Appx B-6 TCExIs 2 of 3 982009

AR100324

APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

(sec)

Source-building

separation LT

(cm)

Stratum A soil

air-filled porosity

bull ea (cmcm)

Stratum B Soil

air-fllled porosity

e^ bull (cmcm)

Stratum C soil

air-filled porosity

(cmcm)

StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air

saturation permeability permeability

S|e k krg (cmcm) (cm) (cm)

Stratum A Floor-soil wall BIdg

effective vapor seam Soil ventilafion permeability perimeter gas rate

k^ bull Xack c o n e Qbuildins

(cm) (cm) (ngm) (cms)

946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |

Area of enclosed

space below grade

AB

(cm)

Ciack- to-total

area ratio

1 (unitless)

Crack depth below grade

Zcrack

(cm)

Enthalpy of vaporization at

ave soil temperature

A H J S

(calmol)

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law bull constant at

ave soil temperature

HTS

(unitless)

Vapor viscosity at

ave soil temperature

|JTS

(gcm^s)

Stratum A

effective diffusion

coefficient

(cms)

Stratum B

effective -diffusion

coefficient

D=B (cms)

Stratum ^ C effective diffusion

coefficient

D=c (cms)

Total overall

effective diffusion

coefficient

DT

(cms)

I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03

Diffusion path

length

Li (cm) bull

Convection bull path

length

Lp

(cm)

Source vapor cone bull

^source

(ngm)

Crack radius

rcrack

(cm)

Average vapor

- flow rate intobldg

Qsoil

(cms)

Crack effective diffusion

bull coefficient Qcrack

(cms)

Area of crack

^crack

(cm)

Exponent of equivalent foundation

Peclet bull number

exp(Pe)

(unitless)

bull bull

1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07

Infinite source Indoor

attenuation coefficient

a

(unitless)

108E-05

Infinite source

bIdg concgt

^building

(ngm)

844E-02

Unit risk

factor

URF

(ngm)-

Reference cone

RfC

(mgm)

1 1E-04 1 40E-02 1

END

Appx B-6 TCExIs 3 of 3 982009

AR100325

Office of Waste Management 1356 Hansford Street

Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256

West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director

ORDER

ISSUED UNDER THE

HAZARDOUS WASTE MANAGEMENT ACT

CHAPTER 22 ARTICLE 18

OF THE WEST VIRGINIA CODE^ AS AMENDED

y Order Number HW-011-80

To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704

ATTEMTION MREDARMON

Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull

AR100326

ViWJ011-laquo9 PageNunil)er2

BASIS FOR ORDER

As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following

A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^

B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator

C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities

0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94

^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement

P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following

1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater

2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was

^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment

CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable

CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order

AR100327

H W - 0 1 1 - 9 9 Page Number 3

REQUIREMENTS OF ORDER

Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows

1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^

2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore

remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling

GENERAL PROVaiONS

1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order

2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order

3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order

Effective Date

Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief

Wt T 1 V Oflice of Waste Management

AR100328

^ ^ S I S

^wmmmmamn

AR100329

Page 13: SDMS DocID 2121999 · International Enterprises Corp. building (Coyne Building), which is located at 1111 Vernon Street, Westmoreland District, Wayne County, West Virginia. The following

Risk-Based Remedies

R B R Consulting Inc

bull Averaging Time As described above the doses for noncarcinogenic health effects are averaged oyer the specific period of exposure for a given receptor Noncarcinogenic

averaging times are therefore calculated by multiplying the exposure duration for the receptor by 365 daysyear Carcinogenic health effects are calculated over a lifetime exposure so the value recommended by WVDEP (2001) and USEPA (2002b) for average lifetime 70 years was used for exposure duration The resulting carcinogenic averaging time is 25550 days

TOXICITY VALUES

Noncarcinogenic responses are evaluated numerically using parameters known as the hazard quotient (HQ) and hazard index (HI) the HQ is obtained by dividing the ADD for a constituent by the reference dose (RfD) Each dose calculation with a specific combination of constituent receptor and exposure pathway will have a distinct ADD and calculated HQ HQs associated with all constituents for a particular pathway are summed to yield the HI

In order to estimate the theoretical excess lifetime cancer risk the LADD of a constituent is multiplied by the cancer slope factor (CSF) For each pathway this calculation is carried out for each applicable constituent and the risks are summed to obtain the total potential risk due to that pathway

Toxicity values for each constituent are presented in Table 5 the toxicity values were obtained from the following sources

bull Integrated Risk Information System (IRIS) on-line database provided by USEPA (2009)

bull The USEPAs Provisional Peer-Reviewed Toxicity Values (PPRTV) as presented in the USEPA Regional Screening Tables (ORNL 2009)

bull Provisional value from the National Center for Environmental Assessnient (as per WVDEP)

bull The Agency for Toxic Substances and Disease Registrys (ATSDR) Minimal Risk Levels (MRLs ATSDR 2009) and

bull Value cited by USEPA Region 3 attributed to other sources (as per WVDEP)

RISK CHARACTERIZATION

Potential noncarcinogenic effects associated with exposure to COC at the site are estimated by comparing calculated intakes with the contaminant-specific RfDs The total HI was calculated by summing the individual HQs An HI value equal to or less than 1 indicates thatthelikelihopd of ah adverse noncancer effect would be negligible (USEPA 1989) An HI greater than 1 indicates that additional evaluation of the case is warranted

Theoretical excess lifetime cancer risks associated with exposure to COC from the site were calculated by comparing estimated intakes to constituent-specific CSFs Summed theoretical

Page 3 of 5

AR100290

Risk-Based Remedies

R B R Consulting Inc

excess risks are calculated by combining constituent-specific risks The results may be compared with target benchrharks for acceptable risk Various demarcations of acceptable risk have been established by regulatory agencies WDEP (2001) presents a target cancer risk of 1 x 10 for nonresidential scenarios USEPA (1991) considers potential cancer risks in the range of 1 x 10reg to 1 X 10 to be acceptable

Constituent-specific results for the indoor worker are presented in Table 6 For the indoor worker exposed to COC in indoor air (vapor intrusion from subslab vapor) the total HI is 00081 and the potential cumulative cancer risk is 497 X 10reg

These results meet both WVDEP and USEPA benchmarks indicating that the site poses negligible potential for human health risk for indoor workers

CONCLUSIONS

The results of this focused risk evaluation indicate that potential risks associated with vapor intrusion exposure of indoor workers to constituents that may volatilize from subslab vapor are within the acceptable benchmarks established by WVDEP and USEPA No further evaluation of the vapor intrusion pathway is warranted for the site

REFERENCES

Agency for Toxic Substances and Disease Registry (ATSDR 2009) Minimal Risk Levels (MRLs) Available at httpvtfwwatsdrcdcqovmrisindexhtml

Dolphin Environmental LLC (Dolphin 2000) Site Characterization Report Mach 14 2000

Johnson PC and RA Ettinger (1991) Heuristic model for predicting the intrusion rate of contaminant vapors into buildings Environ Sci Technology 25 1445-1452

Oak Ridge National Laboratory (ORNL 2009) Regional Screening Levels for Chemical Contaminants at Superfund Sites April 15 2009 Available online httpwwwepagovreg3hwmdriskhumanrb-concentration_tableindexhtm

United States Environmental Protection Agency (USEPA 1989) Risk Assessment Guidance for Superfund Volume I PartA Human Health Evaluation Manual EPA5401-89002

United States Environmental Protection Agency (USEPA 1991) Risk Assessment Guidance for Superfund Volume I Part B Development of Risk-Based Remediation Goals Office of Emergency and Remedial Response OSWER Directive 92857-018

United States Environmental Protection Agency (USEPA 2002a) Draft Guidance for Evaluating the Vapor Intrusion to Indoor Air Pathway from Groundwater and Soils Office of Solid Waste and Emergency Response Pub No 92856-10 December 2002

Page 4 of 5

AR100291

Risk-Based Remedies

R B R Consul t ing Inc

United States Environmental Protection Agency (USEPA 2002b) Supplemental Guidance for Calculating Soil Screening Levels for Superfund Sites Office of Solid Waste and Emergency Response December

United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004

United States Environmental Protection Agency (USEPA 2009) Integrated Risk Information System (IRIS) On-line database wwwepaqoviris

West Virginia Department of Environmental Protection (WVDEP 2001) West Virginia Voluntary Remediation and Redevelopment Act-Guidance Manual Version 21 March 13

Page 5 of 5

AR100292

TABLES

AR100293

TABLE 1 SUBSLAB VAPOR SAMPLES INCLUDED IN THE RISK ASSESSMENT

Coyne text i le Services Facility - Huntington West Virginia

Medium

Subslab Vapor

Sample Identification

bull VP-01

VP-02

VP-03

Sample Date

8132009

8132009

8132009

Coyne VIMemo Tables_09-08-09xls 982009

AR100294

TABLE 2 IDENTIFICATION OF CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR

Coyne Textile Services Facility - Huntington West Virginia

mdash

Const i tuent

Volati le Organics

111-Trichlor6ethane

1122-Tetrachloroethane

112-Trichloro-122-trifluoroethane

112-Trichloroethane

11-Dichloroethane

11-Dichloroethene

124-Trichlorobenzene

124-Trimethylbenzene

12-Dibromoethane

12-Dichlor6benzene

12-Dichloroethane

12-Dichloroethene (cis)

12-pichloroethene (trans)

12-Dichloropropane

12-Dichlorotetraf1uoroethane

135-Trimethylbenzene

13-Butadiene

13-Dichlorobenzene

13-Hexachlorobutadiene

14-Dichlorpbenzene

224-trimethylpentane

2-Chlorotoluene

4-Ethyltoluene

Acetone

Allyl Chloride

Benzene

Bromodichloromethane

Bromoform

Bromomethane

Carbon disulfide bull

Carbon tetrachloride

ChJorobenzene

Chloroethane

Frequency of Detection

0 3

0 3

0 3

bull 0 3

0 3

0 3

0 3

1 3

0 3 bull

0 3

b 3 bull

2 3

0 3

bull 0 3

0 3

0 3

0 3 bull

0 3

0 3

0 3

0 3

0 3

0 17

3 3

0 3

P 3

- 0 3

0 3

0 3

0 3

0 3

0 3

0 3

Min imum Detected

Concentrat ion

(ugm^)

ND

ND

ND

ND

ND

- ND

N D

197

ND bull

ND

ND

369

ND

bull~ ND

ND

ND

ND

ND

ND

bull ND

ND

ND

ND

796

ND

ND

ND-

ND

ND

ND

ND

ND

ND

Maximum

Detected Concentrat ion

(ugm3)

ND

ND

ND

ND

ND

ND

ND

197

ND

ND

ND

mdash 6030

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

1880

ND-

ND

ND

ND

ND

ND

ND

ND

ND

Sample wi th Maximum Detect

ND

ND

ND

ND

ND

ND

- ND

VP-03 -

ND

ND

ND

VP-03

ND

bullND

ND

ND

ND

ND

ND

ND

ND

ND

ND

VP-02

ND

ND bull

ND

ND

ND bull

bull ND

ND

ND

ND

Min imum Detection

Limit (ugm3)

22

28

31

22

16

16

30

20

31

24

16

bull 16

16

19

28

20

89

24 bull

43

24

bull 19

2 1

20

--^ 13

13

27

41

16

13

25

18

11

Maximum Detection

Limit (ugm3)

218

275

307

218

162

159

297

197

307

240

162

- 16

159

185

280

197

89

240

427

240

187

207

197

--125

128

268

414

155

125

252

184

106

Vapor Intrusion Corhparison

V a l u e

(ugm)

22000

042

300000

15

bull 5000

2000

2000

60

011

2000

094

350

700

40

NA

60

0087

1100

11

8000

NA

NA

NA

3500

NA

31

14

22

50

7000

16

bull 600

100000

Chemical of Concern

No

No

No

No

No

No

No

YES

No

No

No

YES

No

No

No

N o bull

bullNo

No

No

No

No

No

No

N o

No

No

No

N o

No

No

No

No

No

Comment

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent notdetected

fflaximCimTdeteetlSffieedsTcomDarisonivalues

Constituent not detected

Constituent not detected

Constituent not detected

Maximum detect exceeds comparison value

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Maximum detect below comparison value

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detectedl

Constituent not detected

Constituent not detected

CoyneVI Memo Tables_09-08-09xls 982009

AR100295

TABLE 2

IDENTIFICATION OF CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR

Coyne Textile Services Facility - Huntington West Virginia

Const i tuent

Volati le Organics

Chloroform -

Chloromethane

13-Dichloropropene (cis)

Cyclohexarie^

Dibrcimochloromethane

DichlonDdifluoromethane

Ethylbenzene

Methyl ethyl ketone

Methyl isobutyl ketone

Methyl tert-butyl ether

Methylene chloride

n-Heptane

n-Hexane

Styrene

Tert-butyl alcohol

Tetrachloroethene

Toluene

13-Dichloropropene(trans)

Triehloroethene

Trichlorofluoromethane

Vinyl bromide

Vinyl chloride

Xylene (0)

Xylenes (mampp)

Frequency of Detection

1 3

0 3

0 3

1 3

0 3

0 3

0 -3

1 3

0 3

0 3

2 3

0 3

3 3

0 3

0 3

3 3

1 3

- 0 3

3 3

P 3

0 3

0 3

1 3

1 3

Min imum Detected

Concentrat ion

(ugm)

5910

ND

ND

52

ND

ND

ND

23

ND

ND

1160

ND

1 4 4

ND

ND

11200

18

ND

91

ND

ND

ND

208

387

Maximuri i Detected

Concentrat ion (ugmS)

bull

5910

ND

ND

52

bull ND

ND

ND

23

ND

ND

1520

ND

183

ND

ND

149000

18

ND

7820

ND

bullND

ND

208

387

Sample vyith Max imum Detect

VP-02

ND

ND

VP-01

bull ND

ND

ND

VP-01

ND

ND

VP-02

ND

VP-02

ND

ND

VP-02

VP-01

ND

VP-03

ND

ND

ND

VP-03

VP-03

Min imum Detection

Limit (ugm3)

20

83

18

138

34

bull 20

17

118

16

14

14

16

- -17

12

--151

18

--23

18

10

1 7 bull

1 7 bull

Maximum Detection

Limit (ugm3)

195

83

182

138

341

198

174

118

164

144

14

164

170

121 -

--151

182

225

175

102

bull 174

174

Vapor Intrusion Compar ison

V a l u e

(ugm)

11

24

NA

2000

1

2000

22

10000

800

30000

52

NA

2000

10000

NA

81

4000

NA

022

7000

NA

28

70000

70000

Chemical o f Concern

YES

No

No

No

No bull

No

No bull

No bull=

No

No

YES

No

No

No

No

YES

No

No

YES

N o

No

No

No

No

Comment

Maximum detect exceeds comparison value

Constituent not detected

Constituent not detected

Maximum detect below comparison value

Constituent not detected

Constituent not detected

Constituent not detected

Maximum detect below comparison value

Constituent not detected

Constituent not detected

Maximum detect exceeds comparison value

Constituent not detected bull

Maximum detect below comparison value

Constituent not detected

Constituent not detected

Maximum detect exceeds comparison value

Maximum detect below comparison value

Constituent not detected

Maximum detect exceeds comparison value

Constituent not detected

Constituent not detected

Constituent not detected bull

Maximum detect below comparison value

Maximum detect below comparison value

Notes

ND - Not Detected

NA - Not Available

- - Constituent detected in every sample detection limit not presented

Values in bold indicate detection limit exceeds comparison values

Target shallow soil gas comparison values corresponding to indoor air concentrations where the soil gas to indoor air attenuation factor = 01 and the target cancer risk is set to ip (presented in Table 2c of USEPA 2002a)

Comparison value for cyclohexane is based on the comparison value for hexane

Coyne VI Memo Tables_09-08-09xls 982009

AR100296

TABLES

EXPOSURE POINT CONCENTRATIONS FOR CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR

Coyne Textile Services Facility - Huntington West Virginia

Chemical of Concern

VolatileOrganics

i24-Trimethylbenzene

12-Dichloroethene (cis)

Chloroform

Methylene chloride

Tetrachloroethene Triehloroethene

Subslab Vapor Source

Concentration (mgm^)

0197

603

591

152

149 782

Transport

Factor^ (unitless)

108E-05

108E-05

108E-05

108E-05

108E-05 108E-05

EPC in

Indoor Air (mgm^)

213E-06

651 E-05

638E-05

164E-05

161E-03 844E-05

Notes

^ Subslab vapor source concentration is based on the maximum detected concentration of samples

VP-01-02 and-03 (see Table 2) -

^ Details of the transport factor calculations are presented in Appendix B

^ Exposure Point Concentration (EPC) in inidoor air is calculated as the subslab vapor concentration TF

Coyne VI Memo Tables_09-08-09xls 982009

AR100297

TABLE 4

FACTORS USED IN DOSE CALCULATIONS INHALATION OF VOLATILE EMISSIONS

Coyne Textile Services Facility - Huntington West Virginia

Symbol

CA

IRA

ET

EF

ED-

BW

AT

Exposure Factor

Constituent Concentration in Air

Inhalation Rate

Exposure Time

Exposure Frequency

Exposure Duration

Body Weight

Averaging Time

Indoor Worker

Constituent-Specific See Table 3

25 m hour

8 hrday

250 daysyear

25 years

bull 70 kg

9125 days (NC)

25550 days (C)

Total Dose = CA x IR^ x ET x EF x ED x 1BW x 1AT

(NC) - Non-carcinogenic Averaging Time

(C) - Carcinogenic Averaging Time

Coyne VI Memo Tables_09-08-09xls 982009

AR100298

TABLES TOXICITY VALUES FOR CHEMICALS OF CONCERN

Coyne Textile Services Facility - Huntington West Virginia

Chemical of Concern

Volatile Organics

124-Trimethylbenzene

12-Dichloroethene (cis)

Chloroform

Methylene chloride

tetrachloroethene

Triehloroethene

Target Organ Critical Effect

blood

bullblood

liver

liver

liver CMS

liver kidney fetus CNS

Chroniclnhalation Reference Dose

(mgkg-day)

200E-03 P

1 OOE-02 R

140E-02 E

286E-01 M

771 E-02 M

1OOE-02 E

Inhalation Cancer ^ Slope Factor

(mgkg-day)^

NA

NA

805E-02 1

165E-03 1

200E-02 0

400E-01 E

(I) - Integrated Risk Information System (IRIS USEPA 2009)

(P) - Provisional Peer-Reviewed Toxicity Value (PPRTV) as presented in USEPA Regional Screening Tables (ORNL 2009)

(R) - Calculated assuming route-to-route extrapolation as per WVDEP

(E)-Provisional value from the National Center for Environmental Assessment (as per WVDEP)

(M)-Chronic Minimal Risk Level (MRL ATSDR 2009)

(0) - Value cited by USEPA Region 3 attributed to other sources (as per WVDEP)

Coyne VI Memo Tables_09-08-09xls 982009

AR100299

TABLE 6

NONCANCER HAZARD INDEX AND POTENTIAL CANCER RISK FOR AN INDOOR WORKER

Coyne Textile Services Facility - Huntington West Virginia

bull

Constituent

Volatile Organics

124-Trinnethylbehzene

12-Dichlorpethene (cis)

Chloroform

Methylene chloride

Tetrachloroethene Triehloroethene

EPC in Indoor Air

(mgm)

213E-06

651 E-05

- 638E-05

164E-05

161 E-03

844E-05

Intake (ADD)

(mgkg-d)

416E-07

127E-05

125E-05

321 E-06

315E-04 l65E-05

RfDi

(mgkg-d)

200E-03

1OOE-02

140E-02

286E-01

771 E-02 1 OOE-02

Hazard

Quotient

208E-04

127E-03

892E-04

112E-05

408E-03 165E-03

Intake (LADD)

(mgkg-d)

) 149E-07

455E-06 bull 446E-06

115E-06

112E-04 590E-06

CSFi

(mgkg-d)

NA

NA

805E-02

165E-03

200E-02

400E-01

Potential

Cancer Risk

NA

NA

359E-07

189E-09

225E-06 236E-06

Total Hazard Index

00081 Total

Cancer Risk 497E-06

Total Blood HI = Total Liver HI =

Total Central Nervous System HI = Total Kidney HI =

Total Fetal HI =

bull 00015 00066 00057 00017 00017

Notes NA = Toxicity values are not available for this endpoint or exposure pathway

Coyne VI Memo Tables_09-08-09xls 982009

AR100300

APPENDIX A

SUBSLAB VAPOR ANALYTICAL DATA

AR100301

Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility Huntington West Virginia

Sample

Consti tuent

Volatile Organics (ugm) 111-Trlchloroethane 1122-Tetrachloroethane 112-Trichloro-122-trifluoroethane 112-Trichloroethane 11-Dichioroethane 11-Dichloroethene 124-Trichloroberi2ene 124-Trimethylbenzene 12-Dibromoethane 12-Dichloroben2ene 12-Dichloroethane 12-Dichloroethene-(cis) -12-Dichloroethene (trans) 12-Dichloropropane 12-Dichlorotetrafluoroethane 135-Trimethylbenzene 13-Butadiene 13-Dichlorobenzene 13-Hexachlorobutadiene 14-Dichlorobenzene 224-trimethVlpentane 2-Chlorotoluene 4-Ethyltoluene Acetone Allyl Chloride Benzene Bromodichloromethane Bromoform Bromomethane Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 13-Dichloropropene (cis) Cyclohexane Dibromochloromethane

Identif ication Sample Date

CAS No

71-55-6 79-34-5 76-13-1 79-00-5 75-34-3 75-35-4 120-82-1 95-63-6 106-93-4 95-50-1 107-06-2 156-59-2 156-60-5 78-87-5 76-14-2 108-67-8 106-99^0 541-73-1 87-68-3 106-46-7 540-84r1 95-49-8

622-96-8 67-64-1 107-05-1 71-43-2 75-27-4 75-252 74-83-9 75-15-0 56-23-5 108-90-7 75-00-3 67-66-3 74-87-3

10061-01-5 110-82-7 124-48-1

lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt

lt lt lt lt lt lt lt lt lt lt lt lt

lt

VP-01 8132009

22 28 31 22 16 16 30 20 31 24 16 16 16 19 28 20 89 24 43 24

1 9 21 20 796 13 13 27 41 16 13 25 18 11 20 83 18 52 34

lt lt lt lt lt lt lt lt lt lt lt

lt lt lt lt lt lt lt lt lt lt lt

lt lt lt lt lt lt lt lt lt

lt lt lt lt

VP-02 8132009

218 2 7 5 307 218 162 159 297

bull 197 307 240 162 369 159 185 280 197 89

240 427 240 187 207 197

1880 125 128 268 414 155 125 252 184 106

5910 83 182 138 341

lt lt lt lt lt lt lt

lt lt lt

lt lt lt lt lt lt lt bull

lt lt lt lt

lt lt lt lt lt lt lt lt lt lt lt lt lt lt

VP-03 8132009

218 275 307 218

bull 162 159 297 197 307 240 162

6030 159 185 280 197 89

240 427 240 187 207 197

1750 125 128 268 414 155 125 252 184 106 195 83 182 138 341

Appx A SG Dataxis Page 1 of 2 982009

AR100302

Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility bull Huntington West Virginia

Consti tuent

Volatile Organics (ugm^) Dichlorodifluoromethane Ethylbenzene Methyl ethyl ketone Methyl Isobutyl ketone Methyl tert-butyl ether Methylene chloride n-Heptane jn-Hexane Styrene Tert-butyl alcohol Tetrachloroethene iToluene 13-Dichloropropene (trans) Triehloroethene Trichlorofluoromethane Vinyl bromide Vinyl chloride Xylene (o) Xylenes (mampp)

Sample Identif ication Sample Date

CAS No

75-71-8 100-41-4 78-93-3 108-10-1

1634-04-4 75-09-2

142-82-5 bull 110-54-3

100-42-5 75-65-0 127-18-4 108-88-3

10061-02-6 79-01-6 75-69-4 593-60-2 75-01-4 95-47-6

179601-23-1

lt lt

lt lt lt lt

lt lt

lt

lt lt lt lt lt

VP01 8132009

20 17 23 16 14 14 16

173 17 12 bull

11200 18 18 91 23 18 10 17 17

lt lt lt lt lt

lt

lt lt

lt lt

lt lt lt lt lt

VP-02 8132009

198 174 118 164 144

1520 164 -183 170 121

149000 151 182

2360 225 175 102 174 174

VP-03 8132009

lt 198 lt 174 lt 118 lt 164 lt 144

1160 lt 164

144 lt 170 ltbull 121

90500 lt 151 lt 182

7820 lt 225 lt 175 lt 102

208 387

Appx A SG Dataxis Page 2 of 2 982009

AR100303

APPENDIX B

CALCULATION OF TRANSPORT FACTORS USED TO ESTIMATE INDOOR AIR CONCENTRATIONS

AR100304

APPENDIX B

Calculation of Transport Factors Used to Estimate Indoor Air Concentrations

This appendix presents the methodology for calculating transport factors that are used to convert subslab

vapor concentrations to concentrations in indoor air 124-Trimethylbenzene 12-dichloroethene (cis)

chloroform methylene chloride tetrachloroethene and triehloroethene were identified as contaminants of

concern (COC) for potential vapor intrusion from subslab vapor associated with the Coyne Textile

Services Facility located in Huntington West Virginia (site) In this appendix the transport factors are

calculated to estimate the concentrations of COC in indoor air of the existing plant building located at the

site ~

Transport Factor for Indoor Air

The concentration of a constituent in indoor air (da) is proportional to the concentration of the constituent

in the subslab vapors immediately beneath the building foundation (ie subslab vapor concentration or

Csubsiab) The following equation is used to calculate da from Csubsiab

^ wja ~ ^subslab X I r

where

Cia = concentration of constituent in indoor air (mgm^) -

Csubsiab^ concentration of constituent in subslab vapors (mgm^) and

TF = transport factor from subslab vapors to indoor air

The transport factor (TF) is an infinite source attenuation coefficient andcan be calculated based on a

model developed by Johnson and Ettinger (1991) t he equation for calculating TF is as follows

(Deff X A B ) ( Q B X L T ) X expKQso i l X Lcrabk)(Dcrack X Acrack)]

exp[ (Qsoi l X Lcrack)(Dcrack X Acrack)] + (Deff X A B ) ( Q B X L T ) + (Deff X AB)(Qsoi l X L j ) X (exp [ (Qso i l X Lcrack)(Dcrack X Acrack)] - 1)

where

Deff = effective diffusion coefficient for vadose zone soil (cm^sec)

AB = area of enclosed space below grade (cm^)

QB = building ventilation rate (cm^sec)

LT = distance from contaminant source to building foundation (cm)

Qsoii = volumetric flow rate of vapors into the building (cm^sec)

Lcrack = foundatlon thickness (cm)

Dcrack = vapor diffusion coefficient through crack (cm^sec) and

Acrack = area of cracks through which vapors can pass (cm^)

AR100305

To solve this equation the USEPAs SG-ADV spreadsheet Version 31 most recently updated in

February 2004 was implemented A combination of site-specific factors and default values from the

Users Guide for Evaluating Subsurface Vapor Intrusion Into Buildings (USEPA 2004) were used as input

values in the model All input values are defined below and presented in Tables B-1-A through B-6-A

bull The initial subslab vapor concentration (Csubsiab) is the maximum detected concentration(in units

of ugm ) of samples VP-01 VP-02 and VP-03 that was presented in Table 3 of the report

bull The depth below grade to the bottom of the enclosed space floor (Lp) is set to 15 cm the default

value provided by USEPA (2004) for a slab-on-grade structure

bull The vapor sampling depth below grade (Lg) is a site-specific value The vapor samples were

collected from immediately beneath the building floor therefore Lj has been set to 15 cm

bull The average soilgroundwater temperature (Ts) is set to 125degC the average value for West

Virginia as estimated frorri Figure 8 of the vapor intrusion users guide (USEPA 2004)

bull The soil type used to estimate vapor permeability is assumed to be sandy loam (SL) The

associated soil properties for a sandy loam soil type are as follows the soil dry bulk density (Pb) is

162 gcm the total porosity (n) is 0387 (cm^-aircm^) and the water-filled porosity (nw) is 0103

(cm -HzOcm )

bull The floor thickness (Lcrack) is set to the USEPA (2004) default value of 10 cm

bull The soil-building pressure differential (AP) is set to the USEPA (2004) default value of 40 gcm-s^

bull The building dimensions are siterspecific based on the existing plant building located at the site

The existing structure is approximately 84000 square feet (Dolphin 2000) therefore the

dimensions are set to 8839 cm (290 feet) length by 8839 cm (290 feet) The USEPA (2004)

default value of 244 cm vyas used for the height

bull Thefloor-wall seam crack width (w) is set to the USEPA (2004)-default value of 01 cm

bull The indoor air exchange rate (ER) is set to 083hour This is the value provided by ASTM (2002)

for commercial and industrial buildings

AR100306

Tables B-1-B through B-6-B present the constituent-specific properties for COC that were used in the TF

calculations Tables B-1-C through B-6-C present the intermediate calculations used to determine the

indoor air attenuation coefficients (ie the transport factors) The shaded boxes in Tables B-1-C through

B-6-C also present the resulting TF values that are applied to the concentrations of COC in subslab

vapor and the estimated indoor air concentrations

References

American Society for Testing and Materials (ASTM 2002) Standard Guide for Risk-Based Corrective Action Applied at Petroleum Release Sites ASTM E-1739-95 (Reapproved 2002)

Johnson PC and RA Ettinger (1991) Heuristic model for predicting the intrusion r-ate of contaminant vapors into buildings Environ Sci Technolpgy 25 1445-1452

Dolphin Environmental LLC (Dolphin 2000) Site Characterization Report Mach 14 2000

United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004

AR100307

APPENDIX B-1-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV Nersion31 0204

Reset to Defaults

ENTER -

Chemical CAS No

(numbers only

no dasties)

95636

ENTER Soil gas

cone

Cg (ngm)

Soil Gas Concentration Data ENTER

Soil gas

OR cone

bull - c bull (PPmv)

197E+02

Chemical

124-Trimethylbenzene

MORE ENTER Depth

below grade to bottom

of enclosed space floor

U bull (cm)

ENTER

Soil gas sampling

depth below grade

U (cm) bull

ENTER

Average soil

temperature Ts

CO

1 15 1 1 5 bull125

ENTER ENTER ENTER Totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hft ha he

(cm) (cm) (cm)

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estirnate OR permeability | soil vapor

permeability) k v bull

(cm)

SL 1 1

MORE ENTER

stratum A SCS

soil type

Lookup Soil Parameters

ENTER stratum A soil dry

bulk density P

(gcm)

ENTER Stratum A soil total porosity

(unitless)

ENTER bull stratum A soil water-filled

porosity

(cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

nlaquo

(unitless)

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gchi-s^)

ENTER Enclosed

space floor

length bull LB

(cm)

ENTER Enclosed

space floor

width WB

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

bull Floor-wall seam crack

width w

(cm)

bullENTER

Indoor air exchange

rate ER

(1h) bull

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bidg OR

Leave blank to caicuij

(Lm)

Appx B-1 124-TMBxls 1 of 3 982009

AR100308

APPENDIX B-1-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of ^ bull law constant law constant vaporization at Normal

Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temperature boiling point point temperature weight

D bull Dbdquo H T R bull AHbdquo TB Tc IVIW

Unit risk Reference

factor cone URF RfC

(cms) (cmls) (atm-mmol) CO (calmol) (degK) (degK) (gmol) bull (ugm)- (mgm)

1 606E-02 1 792E-06 1 bull 614E-C3 1 25 1 9369 1 44230 | 64917 1 12020 1 OOE+00 1 60E-03 1

Appx B-1 124-TMBxls 2 of 3 982009

AR100309

APPENDIX B-1-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

(sec)

Source-building

separation

LT bull

(cm) bull

Stratum A soil

air-filled porosity

Q A

Stratum B soil

air-filled porosity

(cmcm) (cmcm)

Stratum C soil air-filled porosity

(cmcm)

Stratum A effective total fluid

saturation

Se

(cmcm)

Stratum A soil

bullintrinsic permeability

^ (cm)

stratum A Stratum A Floor- soil soli wall BIdg

relative air effective vapor seam Soil bull ventilation permeability permeability perimeter gas rate-

kfg ky Xgrack c o n e - QbuHdinpound

(cm) - (cm) (cm) (ngm) (cms)

946E+08 1 0284 0284 0284 0184 596E-09 0901 537E-09 35357 I 197E+02 | 439E+06 |

Area of enclosed

space below grade

As (cm)

Crack-to-total area ratio

1 bull

(unitless)

Crack depth

below grade

Zcfack

(cm)

Enthalpy of vaporization at

ave soil temperature

AHvjs

(calmol) bull

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law constant at

ave soil bull temperature

bull HTS

(unitless)

Vapor bull viscosity at

ave soil temperature

HTS

(gcm-s)

Stratum A

effective diffusion

coefficient

D (cms)

Stratum-B

effective diffusion coefficient

DB (cms)

Stratum C effective diffusion

coefficient

D-c (cms)

Total - overall effective diffusion

coefficient

D ^ (cms)

Diffusion path

length

L-

(cm)

I 787E+07 I 449E-05 | 15 | 11661 260E-03 111E-01 176E-04 I 612E-03 j OOOE+00 | OOOE+00 | 612E-03 j

bull Convection path

length

Lp

(cm)

Source vapor cone

^source

(ngm)

Crack radius

Tcfack

(cm)

Average vapor

flow rate into bIdg

Qsoii

(cms)

Crack effective diffusion

coefficient pcrack

(cms)

Area of CTack

Acack

(cm)

Exponent of equivalent foundation

Peclet number

exp(Pe)

(unitless)

bull bull - bull bull bull bull

1 15 1 197E+02 1 010 1 474E+01 612E-03 bull 354E-t-03 1 336E+09

Infinite source Indoor

~ attenuation coefficient

a

(unitless)

108E-05

Infinite source

btJbldgjJSv-L ^Ppncji3i-

virhpbiiilding bullbull ^lHltti^m)ilg

213E-03

Unit risk

factor

URF

(ngm)-

Reference cone

RfC (mgm)

NA 60E-03 1

I END

Appx B-1 124-TMBxls 3 of 3 982009

AR100310

APPENDIX B-2-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV Nersion31 020^

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

156592

Soil Gas Concentration Data ENTER

Soil gas

cone OR c

(ngm) bull

ENTER Soil bull-gas

cone

c (ppmv)

603E+03 1

Chemical

cis-12-Dichloroethylene

MORE ENTER Depth

below grade to bottom

of enclosed space floor

LF

(cm)

ENTER

Soil gas sampling

depth below grade

U (cm)

ENTER

Average soil

temperature bull Ts

(degC)

1 15 1 bull 15 125

ENTER ENTER ENTER Totalsmust add ijp tb value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hA hB he

bull (cm) (cm) (cm)

15 1 1

ENTER Soil

straturh A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estimate OR permeability | soil vapor

permeability) kv

(cm)

SL 1 |

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

P (gcm)

ENTER Stratum A soil total porosity

bull n

(unitless)

ENTER Stratum A

soil water-filled porosity

(cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

ENTER Stratum B

soil water-filled porosity

ENTER Stratum C

SCS soil type

(unitless) (cmcm)

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure differential

AP

(gcm-s)

ENTER Enclosed bull

space floor

length

LB (cm)

ENTER Enclosed

space floor

width WB

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER

Average vapor flow rate into bIdg

OR Leave blank to calculi

Qsoil

(Lm)

Appx B-2 cis-12-DCExls 1 of 3 982009

AR100311

APPENDIX B-2-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Diffusivity in air

Da

(cms)

Diffusivity in water

Dw (cms)

Henrys law constant at reference temperature

H

(atm-mmoi)

Henrys law constant

reference temperature

bull T R

CC)

Enthalpy of vaporization at

the normal boiling point

AHbdquob

(calmol)

Normal boiling point

TB

(degK)

Critical temperature

Tc (degK)

Molecular weight

MW

(gmol)

Unit risk

factor URF

(ngm)

Reference cone

RfC (mgm)

1 736E-02 1 113E-05 1 407E-03 j 1 25 1 bull 7192 1 33365 1 54400 1 9694 1 OOE+00 j 35E-02 1

Appx B-2 cis-12-DCExls 2 of 3 982009

AR100312

APPENDIX B-2-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

stratum A Stratum B Stratum C Source- soil soil soil

Exposure building air-filled air-filled air-filled

duration separation porosity porosity porosity

T LT ea e^ bull e= (sec) (cm) (cmcm) (cmcm) (cmcm)

I 946E+08n^

Stratum A Stratum A Stratum A Stratum A Floor-effective soil soil soil wall total fluid intrinsic relative air effective vapor seam

saturation permeability permeability permeability perimeter

Ste kj krg ky Acrack

(cmcm) (cm) (cm) (cm) (cm)

Soil gas

cone (ngm)

I 0284 I 0284~ 0284 0184 I 596E-09 | 090T 537E-09 35357 603E+03

BIdg ventilation

rate

JbulldinE

(cms)

439E+06

Area of enclosed

space below grade

AB

(cm)

Crack-to-total

area ratio

n (unitless)

Crack depth below grade

Zltiack (cm)

Erithalpy of vaporization at

ave soil temperature

AHvTs (calmol)

Henryslaw constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law constant at

ave soil temperature

HTS

(unitless) bull

Vapor viscosity at

ave soil bull temperature

HTS

bull (gcm-s)

Stratum A

effective bull diffusion

coefficient

D^A-(cms)

Stratum B

effective bull diffusion

coefficient

D=B

(cms)

Stratum C

effective diffusion bull

coefficient

D=e (cms)

Total overall

effective diffusion

coefficient

DT

(cms)

Diffusion path

length

Ld

(cm)

I 787E+07 I bull449E-05 | 15 bull7709 230E-03 982E-02 176E-04 | 743E-03 | OOOE+00 | OOOE+00 | 743E-03 |

bull bull bull -

Convecfion path -bull

length

Lp (cm)

Source vapor cone

-source

(Mgm)

Crack radius

fcrack

(cm)

Average vapor

flow rate into bIdg

Qaoil bull

(cms)

Crack effective diffusion

coefficient pcack

(cms)

Area of crack

crack

(cm)-

Exponent of equivalent foundation

Peclet number

exp(Pef)

(unitless)

bull

1 15 -1 603E+03 1 010 1 474E+01 743E-03 354E+03 1 697E+07

Infinite source Indoor

attenuation coefficient

poundbullbullbull C t

pound(unitless)

bullsiilaquogt j ii08E-05

Infinite [ source

bIdg cone

Cbujidjng

(pgm)

651 E-02 iKrt

Unit risk

factor

URF

(ngm)-

Reference cone

RfC

(mgm)

NA 35E-02 1

I END I

Appx B-2 cis-12-DCExls 3o f3 982009

AR100313

APPENDIX B-3-A DATA ENTRY SHEET

Coyne Texti le Services - Hunt ington West Virginia

SG-ADV Version 31 0204

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

67663

Soil Gas Concentration Data ENTER ENTER

Soil Soil gas gas

cone OR cone c C

(^gm) (ppmv)

591 E+03

bull

Chemical

Chloroform

MORE ENTER Depth

below grade tb bottom

of enclosed space floor

bull LF

(cm)

ENTER

Soil gas sampling depth

below grade

(cm)

ENTER

Average soil

temperature-Ts

CO bull

1 15 1 15 1 125

ENTER ENTER ENTER Totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

IIA hs he (cm) (cm) (cm)

1 5 bull 1 1

ENTER ENTER Soil - bull

stratum A User-defined SCS stratum A

soil type bull soil vapor (used to estimate OR permeability

soil vapor k

bull permeability) (cm) 1

SL 1 1 bull

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A soil dry

bulk density

Pb (gcm)

ENTER Stratum A soil total porosity

nV (unitless)

ENTER Stratum A

-soilwater-filled bullporosity

Sraquo (cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

(unitless)

ENTER Stratum B

soil water-filled porosity

bull ebdquo=

(cmcm) bull

ENTER Straturri C

SCS bull soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

- c rack

(cm)

ENTER

Soil-bldg pressure

differential AP^

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor

width bull W B

(cm)

ENTER

Enclosed space

height HB

(cm)

ENTER

bull Floor-wall^ seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bidg OR

Leave blank to calculi

Qsoil bull

(Lm)

I -I

Appx B-3 Chloroformxls 1 of 3 982009

AR100314

APPENDIX B-3-B CHEMICALPROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Diffusivity in air

D (cms)

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffijsivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature

Dbdquo H TR A H bdquo TB Tc

(cm s) (atm-m mol) ro (calmol) (degK) (degK)

Molecular weight

MW

(gmol)

Unit risk

factor URF

(ngm)-

Reference cone

RfC

(mgm)

104E-01 100E-05 I 366E-03 25 6988 33432 53640 11938 I 23E-05 | OOE+00

Appx B-3 Chloroformxls 2 of 3 982009

AR100315

APPENDIX B-3-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure

duration

(sec)

Source-

building

separation

LT

(cm)

Stratum A

soil

air-filled

porosity

Sa

( cm cm )

Stratum B

soil

air-filled

porosity

( cm cm )

Stratum C

soil

air-filled

porosity

( c m c m )

Stratum A

effective

total fluid

saturation

( c m c m )

Stratum A

soil

intrinsic

penmeability

k

(cm )

Stratum A

- soil

relative air

permeabil i ty

(cm )

Stratum A

soil

effective vapor

permeability

kv

(cm )

Floor-

wall

seam

perimeter

gtcrack

(cm)

Soil gas

cone

(ngm)

BIdg

venfilation

rate

^buildlriE

(cms)

I 9 4 6 E + 0 8 ~ T I 0284 T 596E-09 I 0-901 I 537E-09 | 35357 | 591 E+03 j 439E+06 | 1 0 284 0284 0184

Area of

enclosed

space

below

grade

A B

( c m )

Crack-

to-total

area

ratio

n

(unitless)

Crack

depth

bull below

grade

^crack

(cm)

Enthalpy of

vaporization at

ave soil

temperature

AHTs bull

(calmol)

Henry s law

constant at

ave soil

temperature

HTS

(a tm-m mol j

Henrys law

constant at

ave soil

bull temperature

HTS

(unitless) bull

Vapor

viscosity at

ave soil-

temperature

^HTS

(gcm-s)

Stratum

A

effective

diffusion

coefficient

(cm s)

Stratum

B

effective

difftjsion

coefficient

D B

(cms) bull

S t ra tum

C

effective

diffusion

coefficient

Dc

(cm s)

Total

overall

effective

bull diffusion

coefficient

D T

(cm s)

Diffi jsion

path

length

Ld

(cm)

I 787E+07 I 449E-05 j - bull 15 7528 210E-03 896E-02 176E-04 I 105E-02 | OOOE+00 | OOOE+00 | 105E-02

Convection

path length

Lp

(cm)

Source

vapor

cone -

^source

- (ngm)

Crack

radius

Tcrack

(cm)

Average

vapor

flow rate

into bidg

Qsoil

(cms)

Crack

effective

diffusion

coefficient Qcrack

bull (cms)

Area of crack

Acrack

(cm)

Exponent of

equivalent

foundation

Peclet number

exp(Pe)

(unitless)

V bull bull

1 15 1 591 E+03 1 010 1 474E+01 105E-02 354E+03 1 355E+05

Infinite

source

indoor

attenuation

coefficient

d

(unitless)

bull 108E-05

Infinite

source

bIdg

cone

^ b u i l d i n g

i (^gm)

bull bull

i 638E-02 -

Unit

risk bull factor

URF

(ngmY

Reference

cone

RfC

(mgm)

~ 23E-05 NA 1

I END

Appx B-3 Chloroform xls 3 of 3 982009

AR100316

APPENDIX B-4-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ersion 31-020^

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

nodashes)

bull 75092

ENTER Soil gas

cone

c (ngm)

Soil Gas Concentration Data ENTER

Soil gas bull

OR cone

bull C

(ppmv)

152E+03

bull bull

Chemical

Methylene chloride

MORE

MORE 4gt

ENTER Depth

below grade to bottom

of enclosed space floor

LF -

(cm)

ENTER

Soil gas sampling depth

below grade

bull U

(cm)

ENTER

Average soil

temperature

Ts bull CC)

bull bull bull bull

1 15 1 15 125

ENTER Totals

Thickness of soil

stratum A h

(cm)

ENTER ENTER must add up to value of Ls (cell F24

Thickness Thickness of soil of soil

stratum B stratum C (Enter value or 0) (Enter value or 0)

he he bull

(cm) bull (cm) -

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(usedto estimate OR perrrieability | soil vapor

permeability)

k bull

(cm)

SL 1 bull 1

ENTER Stratum A

SCS soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

Pb (gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Stratum A

soil water-filled porosity

9w (cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

Pb^

(gcm)

ENTER Stratum B soil total porosity

n^

(unitless)

ENTER Stratum B

soil water-filled porosity

(crhcm)

ENTER Stratum C

SCS soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE 4gt

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

bull Soil-bldg pressure

differential AP^

(gcm-s)

ENTER Enclosed

space floor

length LB

(cm)

ENTER Enclosed

space floor

width bull W B

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width

w

(cm)

ENTER

Indoor air exchange

rate

ER (1h)

ENTER Average vapor

flow rate into bidg OR

Leave blank to calculc

Qsoil

(Lm)

10 40 8839 8839 244 01 083

Appx B-4 MCxIs 1 of 3 982009

AR100317

Diffijsivity in air

D

APPENDIX B-4-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffusivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature

Pw H TR AHt TB TC

Molecular weight

MW

Unit risk

factor URF

Reference cone

RfC

(cms) (cms) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) bull (ngm)- (mgm)

bull bull

1 101E-01 1 117E-05 1 218E-03 1 25 | 6706 1 31300 1 51000 1 8493 1 47E-07 1 30E+00 1

Appx B-4 MCxIs 2 of 3 982009

AR100318

APPENDIX B-4-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

T

(sec)

Source- -building

separation

LT

(cm)

Stratum A soil

air-filled porosity

e a bull

(cmcm)

Stratum B soil

bullair-filled porosity bull

ea^ (cmcm)

Stratum C soil

air-filled porosity

ea= (cmcmj

Stratum A effective total fluid

saturation

Sc bull

(cmcm)

Stratum A soil

intrinsic pemneability

ki (cm)

Stratum A soil

relative air permeability

^ ^ g

(cm)

stratumA bull soil effective vapor permeability

K (cm)

Floor-wall

seam perimeter

Xcrack

(cm)

Soil gas

cone (ngm)

BIdg ventilation

rate

Qbuildinc

(cms)

1 946E+08

Area of -enclosed

space below

bull grade

AB

(cm)

1

Crack-to-total

area rafio

Tl

(unitless)

0284 1

Crack depth below grade

Zcrack

(cm)

0284 1

bull Enthalpy of vaporization at

ave soil temperature

AHTs (calmol)

0284

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

0184

Henrys law constant at ave soil

temperature

HTS

bull (unitless)

1 596E-09

Vapor viscosity at

ave soil temperature

Mrs (gcm-s)

0901

Stratum A

effective diffusion

coefficient

D (cms)

537E-09

Stratum B

effective diffusion

coefficient

D-B (cms)

35357 1

Stratum C -

effective diffusion

coefficient

D-c ^ (cms)

152E+03

Total bull overall

bull effective diffusion

coefficient

D ^

(cms)

440E+06 1

Difftjsion path

length

Ld (cm)

1 787E+07

Convection path

length

Lp (cm)

4 49E-05

Source vapor cone

Csource

(ngm)

15 1

Crack radius

Tcrack

(cm)

7007 bull 1

Average vapor

flow rate intobldg

Qsoil

(cms)

130E-03

Crack effective diffusion

coefficient pcrack

(cms)-

555E-02

bull ^

Area of crack

Acrack

(cm) bull

1 176E-04

Exponent of equivalent foundation

Peclet number

exp(Pe)

(unitless) bull

bull bull

1 15

1 END

152E+03 010 1 474E+01 1 102E-02 354E+03 1 519E+05

102E-02

Infinite source

indoor ^attenuation coefficient

bull a

(unitless)

aiii08E-05

0 OOE+00

bull

Infinite bull source

bIdg ^ cone

^bu i l d i ng

(MQm)

164E-02

OOOE+00 1

Unit risk

factor

URF

(ngm)-

47E-07 1

102E-02 j

Reference cone

RfC

(mgm)

30E+00 j

1 1

Appx B-4 MCxIs 3 of 3 982009

AR100319

APPENDIX B-5-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ^erslon 31 0204

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

127184

Soil Gas Concentration Data ENTER ^ ENTER

Soil -Soi l bull gas gas

cone OR cone Cg C bull

(tgm) (ppmv)

149E+05 1

Chemical

bull Tetrachlbroethylene

MORE 4

ENTER Depth

below grade to bottom

ofenclosecJ space floor

LF

(cm)

ENTER

Soil gas bull sampling

depth below grade

u bull (cm)

ENTER

Average bullsoil

temperature - Ts

ro 1 1 5 1 15 1 125 bull

ENTER ENTER ENTER totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hft bull he bull he

(cm) (cm) (cm)

bull 1 5 1 - 1

ENTER ENTER Soil

stratum A User^defined bull SCS bull stratum A soil type soil vapor

(used to estimate OR perrrieability soil vapor K bull

permeability) (cm) 1

SL 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

Pb

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Sitratum A

soil water-filled bull porosity

(cmcm)

ENTER Stratum B

SCS soiltype

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

Pb^

(gcm)

ENTER Stratum B soil total porosity

Ajnitless^

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS soil type

LookupSoil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

VS

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor width

W B

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width

w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

ENTER Average vapor

flow rate into bidg OR

Leave blank to calcul

bull Qsoil

(Lm)

10 40 8839 8839 244 01 083

Appx B-5 PCExIS 1 of 3 982009

AR100320

APPENDIX B-5-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal Unit

Diffusivity Diffusivity at reference reference the riormal boiling Critical Molecular risk Reference in air in water temperature temperature boiling point point teriiperature weight factor cone

Da Dbdquo H TR AHb TB Tc MW URF RfC

(cms) (cnis) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) (^gm)- (mgm)

1 720E-02 1 820E-06 1 184E-02 1 25 1 8288 1 39440 1 62020 1 16583 1 59E-06 1 60E-01 1

J

AppxB-5PCExls 2 of 3 - 982009

AR100321

APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

T

(sec)

Source-building

separation

LT

bull (cm)

Stratum A soil

air-filled porosity

Oa (cmcm)

Stratum B - soil air-filled porosity

ea (cmcm)

Stratum C soil

air-filled porosity

ea= - (cmcm)

Stratum A effective total fluid

saturation

sbdquo (cmcm)

Stratum A soil

intrinsic permeability

ki (cm)

Stratum A soil

relative air permeability

- ^ g

(cm)

Stratum A soil

effective vapor permeability

kv (cm)

Floor-wall

seam perimeter

^crack

(cm)

Soil gas

cone

(ngm)

BIdg venfilation

rate

Qbuildins

bull (cms)

bull bull

1 946E+08

Area of enclosed

space below grade

AB

(cm)

1

bullCrack-to-total

area ratio

1 (unitless)

0284 1

Crack bull depth below grade

Zcrack

(cm) -

0284 1

Enthalpy of vaporization at bull

ave soil temperature

bull A H V TS

(calmol)

0284

Henrys law constant at

ave soil temperature

HTS (atm-mmol)

0184

-Henrys law constant at

ave soil temperature

HTS

(unitless)

1 596E-09

Vapor viscosity at

ave soil temperature

HTS

(gcm-s)

0901

Stratum A

effective diffusion

coefficient bull D = bull

(cms)

537E-09

Stratum B

effective diffusion

coefficient

D--B (cms)

35357 1

Stratum C

effective diffusion bull

coefficient

D-c (crris)

149E+05

Total overall

effective bulldiffusion coefficient

DT

(cms)

440E+06 1

Difftjsion path

length

U (cm)

1 787E+07

Convection path

length

bull Lp

(cm)

4 49E-05

Source vapor cone

^source

(ngm)

15 1

Crack radius

Tcrack

(cm)

9528 1

Average vapor

flow rate intobldg

Qsoil (cms)

908E-03

Crack effective diffusion

coefficient pcrack

bull ( c m s ) bull

387E-01

Area of crack

Abdquoack (cm)

1 176E-04

Exponent of equivalent foundafion

Peclet number

exp(Pe)

(unitless)

bull

1 15-

1 END

149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08

727E-03

Infinite source indoor

attenuation coefficient

a

(unitless)

108E-05

OOOE+00

Infinite source

bIdg cone

Cburldtng

(Mgm)

161 E+00

OOOE+00 1

Unit risk

factor

URF

(ugm)-

59E-06 1

727E-03

Reference cone

RfC (mgm)

60E-01

1 1

Appx B-5 PCExls 3 of 3 982009

AR100322

APPENDIX B-6-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ersion31 0204

Reset to Defaults

t

Soil Gas Concentration Data ENTER

Chemical CAS No

(numbers only

no dashes)

79016

ENTER ENTER Soil Soil gas gas

cone OR cone C C -

bull (ngm) (ppmv)

782E+03

Chemical

Trichloroethylene

MORE ENTER Depth

below grade to bottom-

of enclosed space floor

LF

(cm)

ENTER

Soil gas sarnpling

depth below grade

U (cm)

ENTER

Average soil

temperature Ts

(degC)

1 15 1 15 t 125

ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e

(cm) (cm) (cm)

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estimate OR permeability soil vapor

permeability)

k (cm)

bull S L 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil bull-Parameters

ENTER Stratum A

soil dry bulk density

P b -

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Stratum A bull

soilwaterrfilled porosity

(cmcm) bull

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

bull P ^ (gcm)

ENTER Stratum B soil total

porosity

nlaquo

(unitless) -

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS bull soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor

width W B

(cm)

ENTER

Enclosed space height

H B bull

( c m ) bull

ENTER

Floor-wall seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bIdg OR

Leave blank to calculc

Qsoil

(Lm) -

Appx B-6 TCExIs 1 of 3 982009

A

AR100323

APPENDIX B-6-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight

Da Dbdquo H TR AH^b TB TC MW

Unit risk Reference

factor cone URF RfC

(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)

1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1

Appx B-6 TCExIs 2 of 3 982009

AR100324

APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

(sec)

Source-building

separation LT

(cm)

Stratum A soil

air-filled porosity

bull ea (cmcm)

Stratum B Soil

air-fllled porosity

e^ bull (cmcm)

Stratum C soil

air-filled porosity

(cmcm)

StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air

saturation permeability permeability

S|e k krg (cmcm) (cm) (cm)

Stratum A Floor-soil wall BIdg

effective vapor seam Soil ventilafion permeability perimeter gas rate

k^ bull Xack c o n e Qbuildins

(cm) (cm) (ngm) (cms)

946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |

Area of enclosed

space below grade

AB

(cm)

Ciack- to-total

area ratio

1 (unitless)

Crack depth below grade

Zcrack

(cm)

Enthalpy of vaporization at

ave soil temperature

A H J S

(calmol)

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law bull constant at

ave soil temperature

HTS

(unitless)

Vapor viscosity at

ave soil temperature

|JTS

(gcm^s)

Stratum A

effective diffusion

coefficient

(cms)

Stratum B

effective -diffusion

coefficient

D=B (cms)

Stratum ^ C effective diffusion

coefficient

D=c (cms)

Total overall

effective diffusion

coefficient

DT

(cms)

I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03

Diffusion path

length

Li (cm) bull

Convection bull path

length

Lp

(cm)

Source vapor cone bull

^source

(ngm)

Crack radius

rcrack

(cm)

Average vapor

- flow rate intobldg

Qsoil

(cms)

Crack effective diffusion

bull coefficient Qcrack

(cms)

Area of crack

^crack

(cm)

Exponent of equivalent foundation

Peclet bull number

exp(Pe)

(unitless)

bull bull

1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07

Infinite source Indoor

attenuation coefficient

a

(unitless)

108E-05

Infinite source

bIdg concgt

^building

(ngm)

844E-02

Unit risk

factor

URF

(ngm)-

Reference cone

RfC

(mgm)

1 1E-04 1 40E-02 1

END

Appx B-6 TCExIs 3 of 3 982009

AR100325

Office of Waste Management 1356 Hansford Street

Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256

West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director

ORDER

ISSUED UNDER THE

HAZARDOUS WASTE MANAGEMENT ACT

CHAPTER 22 ARTICLE 18

OF THE WEST VIRGINIA CODE^ AS AMENDED

y Order Number HW-011-80

To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704

ATTEMTION MREDARMON

Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull

AR100326

ViWJ011-laquo9 PageNunil)er2

BASIS FOR ORDER

As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following

A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^

B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator

C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities

0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94

^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement

P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following

1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater

2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was

^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment

CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable

CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order

AR100327

H W - 0 1 1 - 9 9 Page Number 3

REQUIREMENTS OF ORDER

Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows

1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^

2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore

remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling

GENERAL PROVaiONS

1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order

2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order

3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order

Effective Date

Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief

Wt T 1 V Oflice of Waste Management

AR100328

^ ^ S I S

^wmmmmamn

AR100329

Page 14: SDMS DocID 2121999 · International Enterprises Corp. building (Coyne Building), which is located at 1111 Vernon Street, Westmoreland District, Wayne County, West Virginia. The following

Risk-Based Remedies

R B R Consulting Inc

excess risks are calculated by combining constituent-specific risks The results may be compared with target benchrharks for acceptable risk Various demarcations of acceptable risk have been established by regulatory agencies WDEP (2001) presents a target cancer risk of 1 x 10 for nonresidential scenarios USEPA (1991) considers potential cancer risks in the range of 1 x 10reg to 1 X 10 to be acceptable

Constituent-specific results for the indoor worker are presented in Table 6 For the indoor worker exposed to COC in indoor air (vapor intrusion from subslab vapor) the total HI is 00081 and the potential cumulative cancer risk is 497 X 10reg

These results meet both WVDEP and USEPA benchmarks indicating that the site poses negligible potential for human health risk for indoor workers

CONCLUSIONS

The results of this focused risk evaluation indicate that potential risks associated with vapor intrusion exposure of indoor workers to constituents that may volatilize from subslab vapor are within the acceptable benchmarks established by WVDEP and USEPA No further evaluation of the vapor intrusion pathway is warranted for the site

REFERENCES

Agency for Toxic Substances and Disease Registry (ATSDR 2009) Minimal Risk Levels (MRLs) Available at httpvtfwwatsdrcdcqovmrisindexhtml

Dolphin Environmental LLC (Dolphin 2000) Site Characterization Report Mach 14 2000

Johnson PC and RA Ettinger (1991) Heuristic model for predicting the intrusion rate of contaminant vapors into buildings Environ Sci Technology 25 1445-1452

Oak Ridge National Laboratory (ORNL 2009) Regional Screening Levels for Chemical Contaminants at Superfund Sites April 15 2009 Available online httpwwwepagovreg3hwmdriskhumanrb-concentration_tableindexhtm

United States Environmental Protection Agency (USEPA 1989) Risk Assessment Guidance for Superfund Volume I PartA Human Health Evaluation Manual EPA5401-89002

United States Environmental Protection Agency (USEPA 1991) Risk Assessment Guidance for Superfund Volume I Part B Development of Risk-Based Remediation Goals Office of Emergency and Remedial Response OSWER Directive 92857-018

United States Environmental Protection Agency (USEPA 2002a) Draft Guidance for Evaluating the Vapor Intrusion to Indoor Air Pathway from Groundwater and Soils Office of Solid Waste and Emergency Response Pub No 92856-10 December 2002

Page 4 of 5

AR100291

Risk-Based Remedies

R B R Consul t ing Inc

United States Environmental Protection Agency (USEPA 2002b) Supplemental Guidance for Calculating Soil Screening Levels for Superfund Sites Office of Solid Waste and Emergency Response December

United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004

United States Environmental Protection Agency (USEPA 2009) Integrated Risk Information System (IRIS) On-line database wwwepaqoviris

West Virginia Department of Environmental Protection (WVDEP 2001) West Virginia Voluntary Remediation and Redevelopment Act-Guidance Manual Version 21 March 13

Page 5 of 5

AR100292

TABLES

AR100293

TABLE 1 SUBSLAB VAPOR SAMPLES INCLUDED IN THE RISK ASSESSMENT

Coyne text i le Services Facility - Huntington West Virginia

Medium

Subslab Vapor

Sample Identification

bull VP-01

VP-02

VP-03

Sample Date

8132009

8132009

8132009

Coyne VIMemo Tables_09-08-09xls 982009

AR100294

TABLE 2 IDENTIFICATION OF CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR

Coyne Textile Services Facility - Huntington West Virginia

mdash

Const i tuent

Volati le Organics

111-Trichlor6ethane

1122-Tetrachloroethane

112-Trichloro-122-trifluoroethane

112-Trichloroethane

11-Dichloroethane

11-Dichloroethene

124-Trichlorobenzene

124-Trimethylbenzene

12-Dibromoethane

12-Dichlor6benzene

12-Dichloroethane

12-Dichloroethene (cis)

12-pichloroethene (trans)

12-Dichloropropane

12-Dichlorotetraf1uoroethane

135-Trimethylbenzene

13-Butadiene

13-Dichlorobenzene

13-Hexachlorobutadiene

14-Dichlorpbenzene

224-trimethylpentane

2-Chlorotoluene

4-Ethyltoluene

Acetone

Allyl Chloride

Benzene

Bromodichloromethane

Bromoform

Bromomethane

Carbon disulfide bull

Carbon tetrachloride

ChJorobenzene

Chloroethane

Frequency of Detection

0 3

0 3

0 3

bull 0 3

0 3

0 3

0 3

1 3

0 3 bull

0 3

b 3 bull

2 3

0 3

bull 0 3

0 3

0 3

0 3 bull

0 3

0 3

0 3

0 3

0 3

0 17

3 3

0 3

P 3

- 0 3

0 3

0 3

0 3

0 3

0 3

0 3

Min imum Detected

Concentrat ion

(ugm^)

ND

ND

ND

ND

ND

- ND

N D

197

ND bull

ND

ND

369

ND

bull~ ND

ND

ND

ND

ND

ND

bull ND

ND

ND

ND

796

ND

ND

ND-

ND

ND

ND

ND

ND

ND

Maximum

Detected Concentrat ion

(ugm3)

ND

ND

ND

ND

ND

ND

ND

197

ND

ND

ND

mdash 6030

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

1880

ND-

ND

ND

ND

ND

ND

ND

ND

ND

Sample wi th Maximum Detect

ND

ND

ND

ND

ND

ND

- ND

VP-03 -

ND

ND

ND

VP-03

ND

bullND

ND

ND

ND

ND

ND

ND

ND

ND

ND

VP-02

ND

ND bull

ND

ND

ND bull

bull ND

ND

ND

ND

Min imum Detection

Limit (ugm3)

22

28

31

22

16

16

30

20

31

24

16

bull 16

16

19

28

20

89

24 bull

43

24

bull 19

2 1

20

--^ 13

13

27

41

16

13

25

18

11

Maximum Detection

Limit (ugm3)

218

275

307

218

162

159

297

197

307

240

162

- 16

159

185

280

197

89

240

427

240

187

207

197

--125

128

268

414

155

125

252

184

106

Vapor Intrusion Corhparison

V a l u e

(ugm)

22000

042

300000

15

bull 5000

2000

2000

60

011

2000

094

350

700

40

NA

60

0087

1100

11

8000

NA

NA

NA

3500

NA

31

14

22

50

7000

16

bull 600

100000

Chemical of Concern

No

No

No

No

No

No

No

YES

No

No

No

YES

No

No

No

N o bull

bullNo

No

No

No

No

No

No

N o

No

No

No

N o

No

No

No

No

No

Comment

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent notdetected

fflaximCimTdeteetlSffieedsTcomDarisonivalues

Constituent not detected

Constituent not detected

Constituent not detected

Maximum detect exceeds comparison value

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Maximum detect below comparison value

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detectedl

Constituent not detected

Constituent not detected

CoyneVI Memo Tables_09-08-09xls 982009

AR100295

TABLE 2

IDENTIFICATION OF CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR

Coyne Textile Services Facility - Huntington West Virginia

Const i tuent

Volati le Organics

Chloroform -

Chloromethane

13-Dichloropropene (cis)

Cyclohexarie^

Dibrcimochloromethane

DichlonDdifluoromethane

Ethylbenzene

Methyl ethyl ketone

Methyl isobutyl ketone

Methyl tert-butyl ether

Methylene chloride

n-Heptane

n-Hexane

Styrene

Tert-butyl alcohol

Tetrachloroethene

Toluene

13-Dichloropropene(trans)

Triehloroethene

Trichlorofluoromethane

Vinyl bromide

Vinyl chloride

Xylene (0)

Xylenes (mampp)

Frequency of Detection

1 3

0 3

0 3

1 3

0 3

0 3

0 -3

1 3

0 3

0 3

2 3

0 3

3 3

0 3

0 3

3 3

1 3

- 0 3

3 3

P 3

0 3

0 3

1 3

1 3

Min imum Detected

Concentrat ion

(ugm)

5910

ND

ND

52

ND

ND

ND

23

ND

ND

1160

ND

1 4 4

ND

ND

11200

18

ND

91

ND

ND

ND

208

387

Maximuri i Detected

Concentrat ion (ugmS)

bull

5910

ND

ND

52

bull ND

ND

ND

23

ND

ND

1520

ND

183

ND

ND

149000

18

ND

7820

ND

bullND

ND

208

387

Sample vyith Max imum Detect

VP-02

ND

ND

VP-01

bull ND

ND

ND

VP-01

ND

ND

VP-02

ND

VP-02

ND

ND

VP-02

VP-01

ND

VP-03

ND

ND

ND

VP-03

VP-03

Min imum Detection

Limit (ugm3)

20

83

18

138

34

bull 20

17

118

16

14

14

16

- -17

12

--151

18

--23

18

10

1 7 bull

1 7 bull

Maximum Detection

Limit (ugm3)

195

83

182

138

341

198

174

118

164

144

14

164

170

121 -

--151

182

225

175

102

bull 174

174

Vapor Intrusion Compar ison

V a l u e

(ugm)

11

24

NA

2000

1

2000

22

10000

800

30000

52

NA

2000

10000

NA

81

4000

NA

022

7000

NA

28

70000

70000

Chemical o f Concern

YES

No

No

No

No bull

No

No bull

No bull=

No

No

YES

No

No

No

No

YES

No

No

YES

N o

No

No

No

No

Comment

Maximum detect exceeds comparison value

Constituent not detected

Constituent not detected

Maximum detect below comparison value

Constituent not detected

Constituent not detected

Constituent not detected

Maximum detect below comparison value

Constituent not detected

Constituent not detected

Maximum detect exceeds comparison value

Constituent not detected bull

Maximum detect below comparison value

Constituent not detected

Constituent not detected

Maximum detect exceeds comparison value

Maximum detect below comparison value

Constituent not detected

Maximum detect exceeds comparison value

Constituent not detected

Constituent not detected

Constituent not detected bull

Maximum detect below comparison value

Maximum detect below comparison value

Notes

ND - Not Detected

NA - Not Available

- - Constituent detected in every sample detection limit not presented

Values in bold indicate detection limit exceeds comparison values

Target shallow soil gas comparison values corresponding to indoor air concentrations where the soil gas to indoor air attenuation factor = 01 and the target cancer risk is set to ip (presented in Table 2c of USEPA 2002a)

Comparison value for cyclohexane is based on the comparison value for hexane

Coyne VI Memo Tables_09-08-09xls 982009

AR100296

TABLES

EXPOSURE POINT CONCENTRATIONS FOR CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR

Coyne Textile Services Facility - Huntington West Virginia

Chemical of Concern

VolatileOrganics

i24-Trimethylbenzene

12-Dichloroethene (cis)

Chloroform

Methylene chloride

Tetrachloroethene Triehloroethene

Subslab Vapor Source

Concentration (mgm^)

0197

603

591

152

149 782

Transport

Factor^ (unitless)

108E-05

108E-05

108E-05

108E-05

108E-05 108E-05

EPC in

Indoor Air (mgm^)

213E-06

651 E-05

638E-05

164E-05

161E-03 844E-05

Notes

^ Subslab vapor source concentration is based on the maximum detected concentration of samples

VP-01-02 and-03 (see Table 2) -

^ Details of the transport factor calculations are presented in Appendix B

^ Exposure Point Concentration (EPC) in inidoor air is calculated as the subslab vapor concentration TF

Coyne VI Memo Tables_09-08-09xls 982009

AR100297

TABLE 4

FACTORS USED IN DOSE CALCULATIONS INHALATION OF VOLATILE EMISSIONS

Coyne Textile Services Facility - Huntington West Virginia

Symbol

CA

IRA

ET

EF

ED-

BW

AT

Exposure Factor

Constituent Concentration in Air

Inhalation Rate

Exposure Time

Exposure Frequency

Exposure Duration

Body Weight

Averaging Time

Indoor Worker

Constituent-Specific See Table 3

25 m hour

8 hrday

250 daysyear

25 years

bull 70 kg

9125 days (NC)

25550 days (C)

Total Dose = CA x IR^ x ET x EF x ED x 1BW x 1AT

(NC) - Non-carcinogenic Averaging Time

(C) - Carcinogenic Averaging Time

Coyne VI Memo Tables_09-08-09xls 982009

AR100298

TABLES TOXICITY VALUES FOR CHEMICALS OF CONCERN

Coyne Textile Services Facility - Huntington West Virginia

Chemical of Concern

Volatile Organics

124-Trimethylbenzene

12-Dichloroethene (cis)

Chloroform

Methylene chloride

tetrachloroethene

Triehloroethene

Target Organ Critical Effect

blood

bullblood

liver

liver

liver CMS

liver kidney fetus CNS

Chroniclnhalation Reference Dose

(mgkg-day)

200E-03 P

1 OOE-02 R

140E-02 E

286E-01 M

771 E-02 M

1OOE-02 E

Inhalation Cancer ^ Slope Factor

(mgkg-day)^

NA

NA

805E-02 1

165E-03 1

200E-02 0

400E-01 E

(I) - Integrated Risk Information System (IRIS USEPA 2009)

(P) - Provisional Peer-Reviewed Toxicity Value (PPRTV) as presented in USEPA Regional Screening Tables (ORNL 2009)

(R) - Calculated assuming route-to-route extrapolation as per WVDEP

(E)-Provisional value from the National Center for Environmental Assessment (as per WVDEP)

(M)-Chronic Minimal Risk Level (MRL ATSDR 2009)

(0) - Value cited by USEPA Region 3 attributed to other sources (as per WVDEP)

Coyne VI Memo Tables_09-08-09xls 982009

AR100299

TABLE 6

NONCANCER HAZARD INDEX AND POTENTIAL CANCER RISK FOR AN INDOOR WORKER

Coyne Textile Services Facility - Huntington West Virginia

bull

Constituent

Volatile Organics

124-Trinnethylbehzene

12-Dichlorpethene (cis)

Chloroform

Methylene chloride

Tetrachloroethene Triehloroethene

EPC in Indoor Air

(mgm)

213E-06

651 E-05

- 638E-05

164E-05

161 E-03

844E-05

Intake (ADD)

(mgkg-d)

416E-07

127E-05

125E-05

321 E-06

315E-04 l65E-05

RfDi

(mgkg-d)

200E-03

1OOE-02

140E-02

286E-01

771 E-02 1 OOE-02

Hazard

Quotient

208E-04

127E-03

892E-04

112E-05

408E-03 165E-03

Intake (LADD)

(mgkg-d)

) 149E-07

455E-06 bull 446E-06

115E-06

112E-04 590E-06

CSFi

(mgkg-d)

NA

NA

805E-02

165E-03

200E-02

400E-01

Potential

Cancer Risk

NA

NA

359E-07

189E-09

225E-06 236E-06

Total Hazard Index

00081 Total

Cancer Risk 497E-06

Total Blood HI = Total Liver HI =

Total Central Nervous System HI = Total Kidney HI =

Total Fetal HI =

bull 00015 00066 00057 00017 00017

Notes NA = Toxicity values are not available for this endpoint or exposure pathway

Coyne VI Memo Tables_09-08-09xls 982009

AR100300

APPENDIX A

SUBSLAB VAPOR ANALYTICAL DATA

AR100301

Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility Huntington West Virginia

Sample

Consti tuent

Volatile Organics (ugm) 111-Trlchloroethane 1122-Tetrachloroethane 112-Trichloro-122-trifluoroethane 112-Trichloroethane 11-Dichioroethane 11-Dichloroethene 124-Trichloroberi2ene 124-Trimethylbenzene 12-Dibromoethane 12-Dichloroben2ene 12-Dichloroethane 12-Dichloroethene-(cis) -12-Dichloroethene (trans) 12-Dichloropropane 12-Dichlorotetrafluoroethane 135-Trimethylbenzene 13-Butadiene 13-Dichlorobenzene 13-Hexachlorobutadiene 14-Dichlorobenzene 224-trimethVlpentane 2-Chlorotoluene 4-Ethyltoluene Acetone Allyl Chloride Benzene Bromodichloromethane Bromoform Bromomethane Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 13-Dichloropropene (cis) Cyclohexane Dibromochloromethane

Identif ication Sample Date

CAS No

71-55-6 79-34-5 76-13-1 79-00-5 75-34-3 75-35-4 120-82-1 95-63-6 106-93-4 95-50-1 107-06-2 156-59-2 156-60-5 78-87-5 76-14-2 108-67-8 106-99^0 541-73-1 87-68-3 106-46-7 540-84r1 95-49-8

622-96-8 67-64-1 107-05-1 71-43-2 75-27-4 75-252 74-83-9 75-15-0 56-23-5 108-90-7 75-00-3 67-66-3 74-87-3

10061-01-5 110-82-7 124-48-1

lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt

lt lt lt lt lt lt lt lt lt lt lt lt

lt

VP-01 8132009

22 28 31 22 16 16 30 20 31 24 16 16 16 19 28 20 89 24 43 24

1 9 21 20 796 13 13 27 41 16 13 25 18 11 20 83 18 52 34

lt lt lt lt lt lt lt lt lt lt lt

lt lt lt lt lt lt lt lt lt lt lt

lt lt lt lt lt lt lt lt lt

lt lt lt lt

VP-02 8132009

218 2 7 5 307 218 162 159 297

bull 197 307 240 162 369 159 185 280 197 89

240 427 240 187 207 197

1880 125 128 268 414 155 125 252 184 106

5910 83 182 138 341

lt lt lt lt lt lt lt

lt lt lt

lt lt lt lt lt lt lt bull

lt lt lt lt

lt lt lt lt lt lt lt lt lt lt lt lt lt lt

VP-03 8132009

218 275 307 218

bull 162 159 297 197 307 240 162

6030 159 185 280 197 89

240 427 240 187 207 197

1750 125 128 268 414 155 125 252 184 106 195 83 182 138 341

Appx A SG Dataxis Page 1 of 2 982009

AR100302

Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility bull Huntington West Virginia

Consti tuent

Volatile Organics (ugm^) Dichlorodifluoromethane Ethylbenzene Methyl ethyl ketone Methyl Isobutyl ketone Methyl tert-butyl ether Methylene chloride n-Heptane jn-Hexane Styrene Tert-butyl alcohol Tetrachloroethene iToluene 13-Dichloropropene (trans) Triehloroethene Trichlorofluoromethane Vinyl bromide Vinyl chloride Xylene (o) Xylenes (mampp)

Sample Identif ication Sample Date

CAS No

75-71-8 100-41-4 78-93-3 108-10-1

1634-04-4 75-09-2

142-82-5 bull 110-54-3

100-42-5 75-65-0 127-18-4 108-88-3

10061-02-6 79-01-6 75-69-4 593-60-2 75-01-4 95-47-6

179601-23-1

lt lt

lt lt lt lt

lt lt

lt

lt lt lt lt lt

VP01 8132009

20 17 23 16 14 14 16

173 17 12 bull

11200 18 18 91 23 18 10 17 17

lt lt lt lt lt

lt

lt lt

lt lt

lt lt lt lt lt

VP-02 8132009

198 174 118 164 144

1520 164 -183 170 121

149000 151 182

2360 225 175 102 174 174

VP-03 8132009

lt 198 lt 174 lt 118 lt 164 lt 144

1160 lt 164

144 lt 170 ltbull 121

90500 lt 151 lt 182

7820 lt 225 lt 175 lt 102

208 387

Appx A SG Dataxis Page 2 of 2 982009

AR100303

APPENDIX B

CALCULATION OF TRANSPORT FACTORS USED TO ESTIMATE INDOOR AIR CONCENTRATIONS

AR100304

APPENDIX B

Calculation of Transport Factors Used to Estimate Indoor Air Concentrations

This appendix presents the methodology for calculating transport factors that are used to convert subslab

vapor concentrations to concentrations in indoor air 124-Trimethylbenzene 12-dichloroethene (cis)

chloroform methylene chloride tetrachloroethene and triehloroethene were identified as contaminants of

concern (COC) for potential vapor intrusion from subslab vapor associated with the Coyne Textile

Services Facility located in Huntington West Virginia (site) In this appendix the transport factors are

calculated to estimate the concentrations of COC in indoor air of the existing plant building located at the

site ~

Transport Factor for Indoor Air

The concentration of a constituent in indoor air (da) is proportional to the concentration of the constituent

in the subslab vapors immediately beneath the building foundation (ie subslab vapor concentration or

Csubsiab) The following equation is used to calculate da from Csubsiab

^ wja ~ ^subslab X I r

where

Cia = concentration of constituent in indoor air (mgm^) -

Csubsiab^ concentration of constituent in subslab vapors (mgm^) and

TF = transport factor from subslab vapors to indoor air

The transport factor (TF) is an infinite source attenuation coefficient andcan be calculated based on a

model developed by Johnson and Ettinger (1991) t he equation for calculating TF is as follows

(Deff X A B ) ( Q B X L T ) X expKQso i l X Lcrabk)(Dcrack X Acrack)]

exp[ (Qsoi l X Lcrack)(Dcrack X Acrack)] + (Deff X A B ) ( Q B X L T ) + (Deff X AB)(Qsoi l X L j ) X (exp [ (Qso i l X Lcrack)(Dcrack X Acrack)] - 1)

where

Deff = effective diffusion coefficient for vadose zone soil (cm^sec)

AB = area of enclosed space below grade (cm^)

QB = building ventilation rate (cm^sec)

LT = distance from contaminant source to building foundation (cm)

Qsoii = volumetric flow rate of vapors into the building (cm^sec)

Lcrack = foundatlon thickness (cm)

Dcrack = vapor diffusion coefficient through crack (cm^sec) and

Acrack = area of cracks through which vapors can pass (cm^)

AR100305

To solve this equation the USEPAs SG-ADV spreadsheet Version 31 most recently updated in

February 2004 was implemented A combination of site-specific factors and default values from the

Users Guide for Evaluating Subsurface Vapor Intrusion Into Buildings (USEPA 2004) were used as input

values in the model All input values are defined below and presented in Tables B-1-A through B-6-A

bull The initial subslab vapor concentration (Csubsiab) is the maximum detected concentration(in units

of ugm ) of samples VP-01 VP-02 and VP-03 that was presented in Table 3 of the report

bull The depth below grade to the bottom of the enclosed space floor (Lp) is set to 15 cm the default

value provided by USEPA (2004) for a slab-on-grade structure

bull The vapor sampling depth below grade (Lg) is a site-specific value The vapor samples were

collected from immediately beneath the building floor therefore Lj has been set to 15 cm

bull The average soilgroundwater temperature (Ts) is set to 125degC the average value for West

Virginia as estimated frorri Figure 8 of the vapor intrusion users guide (USEPA 2004)

bull The soil type used to estimate vapor permeability is assumed to be sandy loam (SL) The

associated soil properties for a sandy loam soil type are as follows the soil dry bulk density (Pb) is

162 gcm the total porosity (n) is 0387 (cm^-aircm^) and the water-filled porosity (nw) is 0103

(cm -HzOcm )

bull The floor thickness (Lcrack) is set to the USEPA (2004) default value of 10 cm

bull The soil-building pressure differential (AP) is set to the USEPA (2004) default value of 40 gcm-s^

bull The building dimensions are siterspecific based on the existing plant building located at the site

The existing structure is approximately 84000 square feet (Dolphin 2000) therefore the

dimensions are set to 8839 cm (290 feet) length by 8839 cm (290 feet) The USEPA (2004)

default value of 244 cm vyas used for the height

bull Thefloor-wall seam crack width (w) is set to the USEPA (2004)-default value of 01 cm

bull The indoor air exchange rate (ER) is set to 083hour This is the value provided by ASTM (2002)

for commercial and industrial buildings

AR100306

Tables B-1-B through B-6-B present the constituent-specific properties for COC that were used in the TF

calculations Tables B-1-C through B-6-C present the intermediate calculations used to determine the

indoor air attenuation coefficients (ie the transport factors) The shaded boxes in Tables B-1-C through

B-6-C also present the resulting TF values that are applied to the concentrations of COC in subslab

vapor and the estimated indoor air concentrations

References

American Society for Testing and Materials (ASTM 2002) Standard Guide for Risk-Based Corrective Action Applied at Petroleum Release Sites ASTM E-1739-95 (Reapproved 2002)

Johnson PC and RA Ettinger (1991) Heuristic model for predicting the intrusion r-ate of contaminant vapors into buildings Environ Sci Technolpgy 25 1445-1452

Dolphin Environmental LLC (Dolphin 2000) Site Characterization Report Mach 14 2000

United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004

AR100307

APPENDIX B-1-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV Nersion31 0204

Reset to Defaults

ENTER -

Chemical CAS No

(numbers only

no dasties)

95636

ENTER Soil gas

cone

Cg (ngm)

Soil Gas Concentration Data ENTER

Soil gas

OR cone

bull - c bull (PPmv)

197E+02

Chemical

124-Trimethylbenzene

MORE ENTER Depth

below grade to bottom

of enclosed space floor

U bull (cm)

ENTER

Soil gas sampling

depth below grade

U (cm) bull

ENTER

Average soil

temperature Ts

CO

1 15 1 1 5 bull125

ENTER ENTER ENTER Totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hft ha he

(cm) (cm) (cm)

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estirnate OR permeability | soil vapor

permeability) k v bull

(cm)

SL 1 1

MORE ENTER

stratum A SCS

soil type

Lookup Soil Parameters

ENTER stratum A soil dry

bulk density P

(gcm)

ENTER Stratum A soil total porosity

(unitless)

ENTER bull stratum A soil water-filled

porosity

(cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

nlaquo

(unitless)

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gchi-s^)

ENTER Enclosed

space floor

length bull LB

(cm)

ENTER Enclosed

space floor

width WB

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

bull Floor-wall seam crack

width w

(cm)

bullENTER

Indoor air exchange

rate ER

(1h) bull

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bidg OR

Leave blank to caicuij

(Lm)

Appx B-1 124-TMBxls 1 of 3 982009

AR100308

APPENDIX B-1-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of ^ bull law constant law constant vaporization at Normal

Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temperature boiling point point temperature weight

D bull Dbdquo H T R bull AHbdquo TB Tc IVIW

Unit risk Reference

factor cone URF RfC

(cms) (cmls) (atm-mmol) CO (calmol) (degK) (degK) (gmol) bull (ugm)- (mgm)

1 606E-02 1 792E-06 1 bull 614E-C3 1 25 1 9369 1 44230 | 64917 1 12020 1 OOE+00 1 60E-03 1

Appx B-1 124-TMBxls 2 of 3 982009

AR100309

APPENDIX B-1-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

(sec)

Source-building

separation

LT bull

(cm) bull

Stratum A soil

air-filled porosity

Q A

Stratum B soil

air-filled porosity

(cmcm) (cmcm)

Stratum C soil air-filled porosity

(cmcm)

Stratum A effective total fluid

saturation

Se

(cmcm)

Stratum A soil

bullintrinsic permeability

^ (cm)

stratum A Stratum A Floor- soil soli wall BIdg

relative air effective vapor seam Soil bull ventilation permeability permeability perimeter gas rate-

kfg ky Xgrack c o n e - QbuHdinpound

(cm) - (cm) (cm) (ngm) (cms)

946E+08 1 0284 0284 0284 0184 596E-09 0901 537E-09 35357 I 197E+02 | 439E+06 |

Area of enclosed

space below grade

As (cm)

Crack-to-total area ratio

1 bull

(unitless)

Crack depth

below grade

Zcfack

(cm)

Enthalpy of vaporization at

ave soil temperature

AHvjs

(calmol) bull

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law constant at

ave soil bull temperature

bull HTS

(unitless)

Vapor bull viscosity at

ave soil temperature

HTS

(gcm-s)

Stratum A

effective diffusion

coefficient

D (cms)

Stratum-B

effective diffusion coefficient

DB (cms)

Stratum C effective diffusion

coefficient

D-c (cms)

Total - overall effective diffusion

coefficient

D ^ (cms)

Diffusion path

length

L-

(cm)

I 787E+07 I 449E-05 | 15 | 11661 260E-03 111E-01 176E-04 I 612E-03 j OOOE+00 | OOOE+00 | 612E-03 j

bull Convection path

length

Lp

(cm)

Source vapor cone

^source

(ngm)

Crack radius

Tcfack

(cm)

Average vapor

flow rate into bIdg

Qsoii

(cms)

Crack effective diffusion

coefficient pcrack

(cms)

Area of CTack

Acack

(cm)

Exponent of equivalent foundation

Peclet number

exp(Pe)

(unitless)

bull bull - bull bull bull bull

1 15 1 197E+02 1 010 1 474E+01 612E-03 bull 354E-t-03 1 336E+09

Infinite source Indoor

~ attenuation coefficient

a

(unitless)

108E-05

Infinite source

btJbldgjJSv-L ^Ppncji3i-

virhpbiiilding bullbull ^lHltti^m)ilg

213E-03

Unit risk

factor

URF

(ngm)-

Reference cone

RfC (mgm)

NA 60E-03 1

I END

Appx B-1 124-TMBxls 3 of 3 982009

AR100310

APPENDIX B-2-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV Nersion31 020^

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

156592

Soil Gas Concentration Data ENTER

Soil gas

cone OR c

(ngm) bull

ENTER Soil bull-gas

cone

c (ppmv)

603E+03 1

Chemical

cis-12-Dichloroethylene

MORE ENTER Depth

below grade to bottom

of enclosed space floor

LF

(cm)

ENTER

Soil gas sampling

depth below grade

U (cm)

ENTER

Average soil

temperature bull Ts

(degC)

1 15 1 bull 15 125

ENTER ENTER ENTER Totalsmust add ijp tb value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hA hB he

bull (cm) (cm) (cm)

15 1 1

ENTER Soil

straturh A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estimate OR permeability | soil vapor

permeability) kv

(cm)

SL 1 |

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

P (gcm)

ENTER Stratum A soil total porosity

bull n

(unitless)

ENTER Stratum A

soil water-filled porosity

(cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

ENTER Stratum B

soil water-filled porosity

ENTER Stratum C

SCS soil type

(unitless) (cmcm)

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure differential

AP

(gcm-s)

ENTER Enclosed bull

space floor

length

LB (cm)

ENTER Enclosed

space floor

width WB

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER

Average vapor flow rate into bIdg

OR Leave blank to calculi

Qsoil

(Lm)

Appx B-2 cis-12-DCExls 1 of 3 982009

AR100311

APPENDIX B-2-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Diffusivity in air

Da

(cms)

Diffusivity in water

Dw (cms)

Henrys law constant at reference temperature

H

(atm-mmoi)

Henrys law constant

reference temperature

bull T R

CC)

Enthalpy of vaporization at

the normal boiling point

AHbdquob

(calmol)

Normal boiling point

TB

(degK)

Critical temperature

Tc (degK)

Molecular weight

MW

(gmol)

Unit risk

factor URF

(ngm)

Reference cone

RfC (mgm)

1 736E-02 1 113E-05 1 407E-03 j 1 25 1 bull 7192 1 33365 1 54400 1 9694 1 OOE+00 j 35E-02 1

Appx B-2 cis-12-DCExls 2 of 3 982009

AR100312

APPENDIX B-2-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

stratum A Stratum B Stratum C Source- soil soil soil

Exposure building air-filled air-filled air-filled

duration separation porosity porosity porosity

T LT ea e^ bull e= (sec) (cm) (cmcm) (cmcm) (cmcm)

I 946E+08n^

Stratum A Stratum A Stratum A Stratum A Floor-effective soil soil soil wall total fluid intrinsic relative air effective vapor seam

saturation permeability permeability permeability perimeter

Ste kj krg ky Acrack

(cmcm) (cm) (cm) (cm) (cm)

Soil gas

cone (ngm)

I 0284 I 0284~ 0284 0184 I 596E-09 | 090T 537E-09 35357 603E+03

BIdg ventilation

rate

JbulldinE

(cms)

439E+06

Area of enclosed

space below grade

AB

(cm)

Crack-to-total

area ratio

n (unitless)

Crack depth below grade

Zltiack (cm)

Erithalpy of vaporization at

ave soil temperature

AHvTs (calmol)

Henryslaw constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law constant at

ave soil temperature

HTS

(unitless) bull

Vapor viscosity at

ave soil bull temperature

HTS

bull (gcm-s)

Stratum A

effective bull diffusion

coefficient

D^A-(cms)

Stratum B

effective bull diffusion

coefficient

D=B

(cms)

Stratum C

effective diffusion bull

coefficient

D=e (cms)

Total overall

effective diffusion

coefficient

DT

(cms)

Diffusion path

length

Ld

(cm)

I 787E+07 I bull449E-05 | 15 bull7709 230E-03 982E-02 176E-04 | 743E-03 | OOOE+00 | OOOE+00 | 743E-03 |

bull bull bull -

Convecfion path -bull

length

Lp (cm)

Source vapor cone

-source

(Mgm)

Crack radius

fcrack

(cm)

Average vapor

flow rate into bIdg

Qaoil bull

(cms)

Crack effective diffusion

coefficient pcack

(cms)

Area of crack

crack

(cm)-

Exponent of equivalent foundation

Peclet number

exp(Pef)

(unitless)

bull

1 15 -1 603E+03 1 010 1 474E+01 743E-03 354E+03 1 697E+07

Infinite source Indoor

attenuation coefficient

poundbullbullbull C t

pound(unitless)

bullsiilaquogt j ii08E-05

Infinite [ source

bIdg cone

Cbujidjng

(pgm)

651 E-02 iKrt

Unit risk

factor

URF

(ngm)-

Reference cone

RfC

(mgm)

NA 35E-02 1

I END I

Appx B-2 cis-12-DCExls 3o f3 982009

AR100313

APPENDIX B-3-A DATA ENTRY SHEET

Coyne Texti le Services - Hunt ington West Virginia

SG-ADV Version 31 0204

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

67663

Soil Gas Concentration Data ENTER ENTER

Soil Soil gas gas

cone OR cone c C

(^gm) (ppmv)

591 E+03

bull

Chemical

Chloroform

MORE ENTER Depth

below grade tb bottom

of enclosed space floor

bull LF

(cm)

ENTER

Soil gas sampling depth

below grade

(cm)

ENTER

Average soil

temperature-Ts

CO bull

1 15 1 15 1 125

ENTER ENTER ENTER Totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

IIA hs he (cm) (cm) (cm)

1 5 bull 1 1

ENTER ENTER Soil - bull

stratum A User-defined SCS stratum A

soil type bull soil vapor (used to estimate OR permeability

soil vapor k

bull permeability) (cm) 1

SL 1 1 bull

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A soil dry

bulk density

Pb (gcm)

ENTER Stratum A soil total porosity

nV (unitless)

ENTER Stratum A

-soilwater-filled bullporosity

Sraquo (cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

(unitless)

ENTER Stratum B

soil water-filled porosity

bull ebdquo=

(cmcm) bull

ENTER Straturri C

SCS bull soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

- c rack

(cm)

ENTER

Soil-bldg pressure

differential AP^

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor

width bull W B

(cm)

ENTER

Enclosed space

height HB

(cm)

ENTER

bull Floor-wall^ seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bidg OR

Leave blank to calculi

Qsoil bull

(Lm)

I -I

Appx B-3 Chloroformxls 1 of 3 982009

AR100314

APPENDIX B-3-B CHEMICALPROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Diffusivity in air

D (cms)

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffijsivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature

Dbdquo H TR A H bdquo TB Tc

(cm s) (atm-m mol) ro (calmol) (degK) (degK)

Molecular weight

MW

(gmol)

Unit risk

factor URF

(ngm)-

Reference cone

RfC

(mgm)

104E-01 100E-05 I 366E-03 25 6988 33432 53640 11938 I 23E-05 | OOE+00

Appx B-3 Chloroformxls 2 of 3 982009

AR100315

APPENDIX B-3-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure

duration

(sec)

Source-

building

separation

LT

(cm)

Stratum A

soil

air-filled

porosity

Sa

( cm cm )

Stratum B

soil

air-filled

porosity

( cm cm )

Stratum C

soil

air-filled

porosity

( c m c m )

Stratum A

effective

total fluid

saturation

( c m c m )

Stratum A

soil

intrinsic

penmeability

k

(cm )

Stratum A

- soil

relative air

permeabil i ty

(cm )

Stratum A

soil

effective vapor

permeability

kv

(cm )

Floor-

wall

seam

perimeter

gtcrack

(cm)

Soil gas

cone

(ngm)

BIdg

venfilation

rate

^buildlriE

(cms)

I 9 4 6 E + 0 8 ~ T I 0284 T 596E-09 I 0-901 I 537E-09 | 35357 | 591 E+03 j 439E+06 | 1 0 284 0284 0184

Area of

enclosed

space

below

grade

A B

( c m )

Crack-

to-total

area

ratio

n

(unitless)

Crack

depth

bull below

grade

^crack

(cm)

Enthalpy of

vaporization at

ave soil

temperature

AHTs bull

(calmol)

Henry s law

constant at

ave soil

temperature

HTS

(a tm-m mol j

Henrys law

constant at

ave soil

bull temperature

HTS

(unitless) bull

Vapor

viscosity at

ave soil-

temperature

^HTS

(gcm-s)

Stratum

A

effective

diffusion

coefficient

(cm s)

Stratum

B

effective

difftjsion

coefficient

D B

(cms) bull

S t ra tum

C

effective

diffusion

coefficient

Dc

(cm s)

Total

overall

effective

bull diffusion

coefficient

D T

(cm s)

Diffi jsion

path

length

Ld

(cm)

I 787E+07 I 449E-05 j - bull 15 7528 210E-03 896E-02 176E-04 I 105E-02 | OOOE+00 | OOOE+00 | 105E-02

Convection

path length

Lp

(cm)

Source

vapor

cone -

^source

- (ngm)

Crack

radius

Tcrack

(cm)

Average

vapor

flow rate

into bidg

Qsoil

(cms)

Crack

effective

diffusion

coefficient Qcrack

bull (cms)

Area of crack

Acrack

(cm)

Exponent of

equivalent

foundation

Peclet number

exp(Pe)

(unitless)

V bull bull

1 15 1 591 E+03 1 010 1 474E+01 105E-02 354E+03 1 355E+05

Infinite

source

indoor

attenuation

coefficient

d

(unitless)

bull 108E-05

Infinite

source

bIdg

cone

^ b u i l d i n g

i (^gm)

bull bull

i 638E-02 -

Unit

risk bull factor

URF

(ngmY

Reference

cone

RfC

(mgm)

~ 23E-05 NA 1

I END

Appx B-3 Chloroform xls 3 of 3 982009

AR100316

APPENDIX B-4-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ersion 31-020^

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

nodashes)

bull 75092

ENTER Soil gas

cone

c (ngm)

Soil Gas Concentration Data ENTER

Soil gas bull

OR cone

bull C

(ppmv)

152E+03

bull bull

Chemical

Methylene chloride

MORE

MORE 4gt

ENTER Depth

below grade to bottom

of enclosed space floor

LF -

(cm)

ENTER

Soil gas sampling depth

below grade

bull U

(cm)

ENTER

Average soil

temperature

Ts bull CC)

bull bull bull bull

1 15 1 15 125

ENTER Totals

Thickness of soil

stratum A h

(cm)

ENTER ENTER must add up to value of Ls (cell F24

Thickness Thickness of soil of soil

stratum B stratum C (Enter value or 0) (Enter value or 0)

he he bull

(cm) bull (cm) -

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(usedto estimate OR perrrieability | soil vapor

permeability)

k bull

(cm)

SL 1 bull 1

ENTER Stratum A

SCS soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

Pb (gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Stratum A

soil water-filled porosity

9w (cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

Pb^

(gcm)

ENTER Stratum B soil total porosity

n^

(unitless)

ENTER Stratum B

soil water-filled porosity

(crhcm)

ENTER Stratum C

SCS soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE 4gt

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

bull Soil-bldg pressure

differential AP^

(gcm-s)

ENTER Enclosed

space floor

length LB

(cm)

ENTER Enclosed

space floor

width bull W B

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width

w

(cm)

ENTER

Indoor air exchange

rate

ER (1h)

ENTER Average vapor

flow rate into bidg OR

Leave blank to calculc

Qsoil

(Lm)

10 40 8839 8839 244 01 083

Appx B-4 MCxIs 1 of 3 982009

AR100317

Diffijsivity in air

D

APPENDIX B-4-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffusivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature

Pw H TR AHt TB TC

Molecular weight

MW

Unit risk

factor URF

Reference cone

RfC

(cms) (cms) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) bull (ngm)- (mgm)

bull bull

1 101E-01 1 117E-05 1 218E-03 1 25 | 6706 1 31300 1 51000 1 8493 1 47E-07 1 30E+00 1

Appx B-4 MCxIs 2 of 3 982009

AR100318

APPENDIX B-4-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

T

(sec)

Source- -building

separation

LT

(cm)

Stratum A soil

air-filled porosity

e a bull

(cmcm)

Stratum B soil

bullair-filled porosity bull

ea^ (cmcm)

Stratum C soil

air-filled porosity

ea= (cmcmj

Stratum A effective total fluid

saturation

Sc bull

(cmcm)

Stratum A soil

intrinsic pemneability

ki (cm)

Stratum A soil

relative air permeability

^ ^ g

(cm)

stratumA bull soil effective vapor permeability

K (cm)

Floor-wall

seam perimeter

Xcrack

(cm)

Soil gas

cone (ngm)

BIdg ventilation

rate

Qbuildinc

(cms)

1 946E+08

Area of -enclosed

space below

bull grade

AB

(cm)

1

Crack-to-total

area rafio

Tl

(unitless)

0284 1

Crack depth below grade

Zcrack

(cm)

0284 1

bull Enthalpy of vaporization at

ave soil temperature

AHTs (calmol)

0284

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

0184

Henrys law constant at ave soil

temperature

HTS

bull (unitless)

1 596E-09

Vapor viscosity at

ave soil temperature

Mrs (gcm-s)

0901

Stratum A

effective diffusion

coefficient

D (cms)

537E-09

Stratum B

effective diffusion

coefficient

D-B (cms)

35357 1

Stratum C -

effective diffusion

coefficient

D-c ^ (cms)

152E+03

Total bull overall

bull effective diffusion

coefficient

D ^

(cms)

440E+06 1

Difftjsion path

length

Ld (cm)

1 787E+07

Convection path

length

Lp (cm)

4 49E-05

Source vapor cone

Csource

(ngm)

15 1

Crack radius

Tcrack

(cm)

7007 bull 1

Average vapor

flow rate intobldg

Qsoil

(cms)

130E-03

Crack effective diffusion

coefficient pcrack

(cms)-

555E-02

bull ^

Area of crack

Acrack

(cm) bull

1 176E-04

Exponent of equivalent foundation

Peclet number

exp(Pe)

(unitless) bull

bull bull

1 15

1 END

152E+03 010 1 474E+01 1 102E-02 354E+03 1 519E+05

102E-02

Infinite source

indoor ^attenuation coefficient

bull a

(unitless)

aiii08E-05

0 OOE+00

bull

Infinite bull source

bIdg ^ cone

^bu i l d i ng

(MQm)

164E-02

OOOE+00 1

Unit risk

factor

URF

(ngm)-

47E-07 1

102E-02 j

Reference cone

RfC

(mgm)

30E+00 j

1 1

Appx B-4 MCxIs 3 of 3 982009

AR100319

APPENDIX B-5-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ^erslon 31 0204

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

127184

Soil Gas Concentration Data ENTER ^ ENTER

Soil -Soi l bull gas gas

cone OR cone Cg C bull

(tgm) (ppmv)

149E+05 1

Chemical

bull Tetrachlbroethylene

MORE 4

ENTER Depth

below grade to bottom

ofenclosecJ space floor

LF

(cm)

ENTER

Soil gas bull sampling

depth below grade

u bull (cm)

ENTER

Average bullsoil

temperature - Ts

ro 1 1 5 1 15 1 125 bull

ENTER ENTER ENTER totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hft bull he bull he

(cm) (cm) (cm)

bull 1 5 1 - 1

ENTER ENTER Soil

stratum A User^defined bull SCS bull stratum A soil type soil vapor

(used to estimate OR perrrieability soil vapor K bull

permeability) (cm) 1

SL 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

Pb

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Sitratum A

soil water-filled bull porosity

(cmcm)

ENTER Stratum B

SCS soiltype

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

Pb^

(gcm)

ENTER Stratum B soil total porosity

Ajnitless^

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS soil type

LookupSoil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

VS

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor width

W B

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width

w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

ENTER Average vapor

flow rate into bidg OR

Leave blank to calcul

bull Qsoil

(Lm)

10 40 8839 8839 244 01 083

Appx B-5 PCExIS 1 of 3 982009

AR100320

APPENDIX B-5-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal Unit

Diffusivity Diffusivity at reference reference the riormal boiling Critical Molecular risk Reference in air in water temperature temperature boiling point point teriiperature weight factor cone

Da Dbdquo H TR AHb TB Tc MW URF RfC

(cms) (cnis) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) (^gm)- (mgm)

1 720E-02 1 820E-06 1 184E-02 1 25 1 8288 1 39440 1 62020 1 16583 1 59E-06 1 60E-01 1

J

AppxB-5PCExls 2 of 3 - 982009

AR100321

APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

T

(sec)

Source-building

separation

LT

bull (cm)

Stratum A soil

air-filled porosity

Oa (cmcm)

Stratum B - soil air-filled porosity

ea (cmcm)

Stratum C soil

air-filled porosity

ea= - (cmcm)

Stratum A effective total fluid

saturation

sbdquo (cmcm)

Stratum A soil

intrinsic permeability

ki (cm)

Stratum A soil

relative air permeability

- ^ g

(cm)

Stratum A soil

effective vapor permeability

kv (cm)

Floor-wall

seam perimeter

^crack

(cm)

Soil gas

cone

(ngm)

BIdg venfilation

rate

Qbuildins

bull (cms)

bull bull

1 946E+08

Area of enclosed

space below grade

AB

(cm)

1

bullCrack-to-total

area ratio

1 (unitless)

0284 1

Crack bull depth below grade

Zcrack

(cm) -

0284 1

Enthalpy of vaporization at bull

ave soil temperature

bull A H V TS

(calmol)

0284

Henrys law constant at

ave soil temperature

HTS (atm-mmol)

0184

-Henrys law constant at

ave soil temperature

HTS

(unitless)

1 596E-09

Vapor viscosity at

ave soil temperature

HTS

(gcm-s)

0901

Stratum A

effective diffusion

coefficient bull D = bull

(cms)

537E-09

Stratum B

effective diffusion

coefficient

D--B (cms)

35357 1

Stratum C

effective diffusion bull

coefficient

D-c (crris)

149E+05

Total overall

effective bulldiffusion coefficient

DT

(cms)

440E+06 1

Difftjsion path

length

U (cm)

1 787E+07

Convection path

length

bull Lp

(cm)

4 49E-05

Source vapor cone

^source

(ngm)

15 1

Crack radius

Tcrack

(cm)

9528 1

Average vapor

flow rate intobldg

Qsoil (cms)

908E-03

Crack effective diffusion

coefficient pcrack

bull ( c m s ) bull

387E-01

Area of crack

Abdquoack (cm)

1 176E-04

Exponent of equivalent foundafion

Peclet number

exp(Pe)

(unitless)

bull

1 15-

1 END

149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08

727E-03

Infinite source indoor

attenuation coefficient

a

(unitless)

108E-05

OOOE+00

Infinite source

bIdg cone

Cburldtng

(Mgm)

161 E+00

OOOE+00 1

Unit risk

factor

URF

(ugm)-

59E-06 1

727E-03

Reference cone

RfC (mgm)

60E-01

1 1

Appx B-5 PCExls 3 of 3 982009

AR100322

APPENDIX B-6-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ersion31 0204

Reset to Defaults

t

Soil Gas Concentration Data ENTER

Chemical CAS No

(numbers only

no dashes)

79016

ENTER ENTER Soil Soil gas gas

cone OR cone C C -

bull (ngm) (ppmv)

782E+03

Chemical

Trichloroethylene

MORE ENTER Depth

below grade to bottom-

of enclosed space floor

LF

(cm)

ENTER

Soil gas sarnpling

depth below grade

U (cm)

ENTER

Average soil

temperature Ts

(degC)

1 15 1 15 t 125

ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e

(cm) (cm) (cm)

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estimate OR permeability soil vapor

permeability)

k (cm)

bull S L 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil bull-Parameters

ENTER Stratum A

soil dry bulk density

P b -

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Stratum A bull

soilwaterrfilled porosity

(cmcm) bull

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

bull P ^ (gcm)

ENTER Stratum B soil total

porosity

nlaquo

(unitless) -

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS bull soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor

width W B

(cm)

ENTER

Enclosed space height

H B bull

( c m ) bull

ENTER

Floor-wall seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bIdg OR

Leave blank to calculc

Qsoil

(Lm) -

Appx B-6 TCExIs 1 of 3 982009

A

AR100323

APPENDIX B-6-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight

Da Dbdquo H TR AH^b TB TC MW

Unit risk Reference

factor cone URF RfC

(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)

1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1

Appx B-6 TCExIs 2 of 3 982009

AR100324

APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

(sec)

Source-building

separation LT

(cm)

Stratum A soil

air-filled porosity

bull ea (cmcm)

Stratum B Soil

air-fllled porosity

e^ bull (cmcm)

Stratum C soil

air-filled porosity

(cmcm)

StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air

saturation permeability permeability

S|e k krg (cmcm) (cm) (cm)

Stratum A Floor-soil wall BIdg

effective vapor seam Soil ventilafion permeability perimeter gas rate

k^ bull Xack c o n e Qbuildins

(cm) (cm) (ngm) (cms)

946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |

Area of enclosed

space below grade

AB

(cm)

Ciack- to-total

area ratio

1 (unitless)

Crack depth below grade

Zcrack

(cm)

Enthalpy of vaporization at

ave soil temperature

A H J S

(calmol)

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law bull constant at

ave soil temperature

HTS

(unitless)

Vapor viscosity at

ave soil temperature

|JTS

(gcm^s)

Stratum A

effective diffusion

coefficient

(cms)

Stratum B

effective -diffusion

coefficient

D=B (cms)

Stratum ^ C effective diffusion

coefficient

D=c (cms)

Total overall

effective diffusion

coefficient

DT

(cms)

I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03

Diffusion path

length

Li (cm) bull

Convection bull path

length

Lp

(cm)

Source vapor cone bull

^source

(ngm)

Crack radius

rcrack

(cm)

Average vapor

- flow rate intobldg

Qsoil

(cms)

Crack effective diffusion

bull coefficient Qcrack

(cms)

Area of crack

^crack

(cm)

Exponent of equivalent foundation

Peclet bull number

exp(Pe)

(unitless)

bull bull

1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07

Infinite source Indoor

attenuation coefficient

a

(unitless)

108E-05

Infinite source

bIdg concgt

^building

(ngm)

844E-02

Unit risk

factor

URF

(ngm)-

Reference cone

RfC

(mgm)

1 1E-04 1 40E-02 1

END

Appx B-6 TCExIs 3 of 3 982009

AR100325

Office of Waste Management 1356 Hansford Street

Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256

West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director

ORDER

ISSUED UNDER THE

HAZARDOUS WASTE MANAGEMENT ACT

CHAPTER 22 ARTICLE 18

OF THE WEST VIRGINIA CODE^ AS AMENDED

y Order Number HW-011-80

To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704

ATTEMTION MREDARMON

Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull

AR100326

ViWJ011-laquo9 PageNunil)er2

BASIS FOR ORDER

As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following

A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^

B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator

C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities

0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94

^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement

P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following

1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater

2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was

^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment

CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable

CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order

AR100327

H W - 0 1 1 - 9 9 Page Number 3

REQUIREMENTS OF ORDER

Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows

1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^

2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore

remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling

GENERAL PROVaiONS

1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order

2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order

3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order

Effective Date

Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief

Wt T 1 V Oflice of Waste Management

AR100328

^ ^ S I S

^wmmmmamn

AR100329

Page 15: SDMS DocID 2121999 · International Enterprises Corp. building (Coyne Building), which is located at 1111 Vernon Street, Westmoreland District, Wayne County, West Virginia. The following

Risk-Based Remedies

R B R Consul t ing Inc

United States Environmental Protection Agency (USEPA 2002b) Supplemental Guidance for Calculating Soil Screening Levels for Superfund Sites Office of Solid Waste and Emergency Response December

United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004

United States Environmental Protection Agency (USEPA 2009) Integrated Risk Information System (IRIS) On-line database wwwepaqoviris

West Virginia Department of Environmental Protection (WVDEP 2001) West Virginia Voluntary Remediation and Redevelopment Act-Guidance Manual Version 21 March 13

Page 5 of 5

AR100292

TABLES

AR100293

TABLE 1 SUBSLAB VAPOR SAMPLES INCLUDED IN THE RISK ASSESSMENT

Coyne text i le Services Facility - Huntington West Virginia

Medium

Subslab Vapor

Sample Identification

bull VP-01

VP-02

VP-03

Sample Date

8132009

8132009

8132009

Coyne VIMemo Tables_09-08-09xls 982009

AR100294

TABLE 2 IDENTIFICATION OF CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR

Coyne Textile Services Facility - Huntington West Virginia

mdash

Const i tuent

Volati le Organics

111-Trichlor6ethane

1122-Tetrachloroethane

112-Trichloro-122-trifluoroethane

112-Trichloroethane

11-Dichloroethane

11-Dichloroethene

124-Trichlorobenzene

124-Trimethylbenzene

12-Dibromoethane

12-Dichlor6benzene

12-Dichloroethane

12-Dichloroethene (cis)

12-pichloroethene (trans)

12-Dichloropropane

12-Dichlorotetraf1uoroethane

135-Trimethylbenzene

13-Butadiene

13-Dichlorobenzene

13-Hexachlorobutadiene

14-Dichlorpbenzene

224-trimethylpentane

2-Chlorotoluene

4-Ethyltoluene

Acetone

Allyl Chloride

Benzene

Bromodichloromethane

Bromoform

Bromomethane

Carbon disulfide bull

Carbon tetrachloride

ChJorobenzene

Chloroethane

Frequency of Detection

0 3

0 3

0 3

bull 0 3

0 3

0 3

0 3

1 3

0 3 bull

0 3

b 3 bull

2 3

0 3

bull 0 3

0 3

0 3

0 3 bull

0 3

0 3

0 3

0 3

0 3

0 17

3 3

0 3

P 3

- 0 3

0 3

0 3

0 3

0 3

0 3

0 3

Min imum Detected

Concentrat ion

(ugm^)

ND

ND

ND

ND

ND

- ND

N D

197

ND bull

ND

ND

369

ND

bull~ ND

ND

ND

ND

ND

ND

bull ND

ND

ND

ND

796

ND

ND

ND-

ND

ND

ND

ND

ND

ND

Maximum

Detected Concentrat ion

(ugm3)

ND

ND

ND

ND

ND

ND

ND

197

ND

ND

ND

mdash 6030

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

1880

ND-

ND

ND

ND

ND

ND

ND

ND

ND

Sample wi th Maximum Detect

ND

ND

ND

ND

ND

ND

- ND

VP-03 -

ND

ND

ND

VP-03

ND

bullND

ND

ND

ND

ND

ND

ND

ND

ND

ND

VP-02

ND

ND bull

ND

ND

ND bull

bull ND

ND

ND

ND

Min imum Detection

Limit (ugm3)

22

28

31

22

16

16

30

20

31

24

16

bull 16

16

19

28

20

89

24 bull

43

24

bull 19

2 1

20

--^ 13

13

27

41

16

13

25

18

11

Maximum Detection

Limit (ugm3)

218

275

307

218

162

159

297

197

307

240

162

- 16

159

185

280

197

89

240

427

240

187

207

197

--125

128

268

414

155

125

252

184

106

Vapor Intrusion Corhparison

V a l u e

(ugm)

22000

042

300000

15

bull 5000

2000

2000

60

011

2000

094

350

700

40

NA

60

0087

1100

11

8000

NA

NA

NA

3500

NA

31

14

22

50

7000

16

bull 600

100000

Chemical of Concern

No

No

No

No

No

No

No

YES

No

No

No

YES

No

No

No

N o bull

bullNo

No

No

No

No

No

No

N o

No

No

No

N o

No

No

No

No

No

Comment

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent notdetected

fflaximCimTdeteetlSffieedsTcomDarisonivalues

Constituent not detected

Constituent not detected

Constituent not detected

Maximum detect exceeds comparison value

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Maximum detect below comparison value

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detectedl

Constituent not detected

Constituent not detected

CoyneVI Memo Tables_09-08-09xls 982009

AR100295

TABLE 2

IDENTIFICATION OF CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR

Coyne Textile Services Facility - Huntington West Virginia

Const i tuent

Volati le Organics

Chloroform -

Chloromethane

13-Dichloropropene (cis)

Cyclohexarie^

Dibrcimochloromethane

DichlonDdifluoromethane

Ethylbenzene

Methyl ethyl ketone

Methyl isobutyl ketone

Methyl tert-butyl ether

Methylene chloride

n-Heptane

n-Hexane

Styrene

Tert-butyl alcohol

Tetrachloroethene

Toluene

13-Dichloropropene(trans)

Triehloroethene

Trichlorofluoromethane

Vinyl bromide

Vinyl chloride

Xylene (0)

Xylenes (mampp)

Frequency of Detection

1 3

0 3

0 3

1 3

0 3

0 3

0 -3

1 3

0 3

0 3

2 3

0 3

3 3

0 3

0 3

3 3

1 3

- 0 3

3 3

P 3

0 3

0 3

1 3

1 3

Min imum Detected

Concentrat ion

(ugm)

5910

ND

ND

52

ND

ND

ND

23

ND

ND

1160

ND

1 4 4

ND

ND

11200

18

ND

91

ND

ND

ND

208

387

Maximuri i Detected

Concentrat ion (ugmS)

bull

5910

ND

ND

52

bull ND

ND

ND

23

ND

ND

1520

ND

183

ND

ND

149000

18

ND

7820

ND

bullND

ND

208

387

Sample vyith Max imum Detect

VP-02

ND

ND

VP-01

bull ND

ND

ND

VP-01

ND

ND

VP-02

ND

VP-02

ND

ND

VP-02

VP-01

ND

VP-03

ND

ND

ND

VP-03

VP-03

Min imum Detection

Limit (ugm3)

20

83

18

138

34

bull 20

17

118

16

14

14

16

- -17

12

--151

18

--23

18

10

1 7 bull

1 7 bull

Maximum Detection

Limit (ugm3)

195

83

182

138

341

198

174

118

164

144

14

164

170

121 -

--151

182

225

175

102

bull 174

174

Vapor Intrusion Compar ison

V a l u e

(ugm)

11

24

NA

2000

1

2000

22

10000

800

30000

52

NA

2000

10000

NA

81

4000

NA

022

7000

NA

28

70000

70000

Chemical o f Concern

YES

No

No

No

No bull

No

No bull

No bull=

No

No

YES

No

No

No

No

YES

No

No

YES

N o

No

No

No

No

Comment

Maximum detect exceeds comparison value

Constituent not detected

Constituent not detected

Maximum detect below comparison value

Constituent not detected

Constituent not detected

Constituent not detected

Maximum detect below comparison value

Constituent not detected

Constituent not detected

Maximum detect exceeds comparison value

Constituent not detected bull

Maximum detect below comparison value

Constituent not detected

Constituent not detected

Maximum detect exceeds comparison value

Maximum detect below comparison value

Constituent not detected

Maximum detect exceeds comparison value

Constituent not detected

Constituent not detected

Constituent not detected bull

Maximum detect below comparison value

Maximum detect below comparison value

Notes

ND - Not Detected

NA - Not Available

- - Constituent detected in every sample detection limit not presented

Values in bold indicate detection limit exceeds comparison values

Target shallow soil gas comparison values corresponding to indoor air concentrations where the soil gas to indoor air attenuation factor = 01 and the target cancer risk is set to ip (presented in Table 2c of USEPA 2002a)

Comparison value for cyclohexane is based on the comparison value for hexane

Coyne VI Memo Tables_09-08-09xls 982009

AR100296

TABLES

EXPOSURE POINT CONCENTRATIONS FOR CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR

Coyne Textile Services Facility - Huntington West Virginia

Chemical of Concern

VolatileOrganics

i24-Trimethylbenzene

12-Dichloroethene (cis)

Chloroform

Methylene chloride

Tetrachloroethene Triehloroethene

Subslab Vapor Source

Concentration (mgm^)

0197

603

591

152

149 782

Transport

Factor^ (unitless)

108E-05

108E-05

108E-05

108E-05

108E-05 108E-05

EPC in

Indoor Air (mgm^)

213E-06

651 E-05

638E-05

164E-05

161E-03 844E-05

Notes

^ Subslab vapor source concentration is based on the maximum detected concentration of samples

VP-01-02 and-03 (see Table 2) -

^ Details of the transport factor calculations are presented in Appendix B

^ Exposure Point Concentration (EPC) in inidoor air is calculated as the subslab vapor concentration TF

Coyne VI Memo Tables_09-08-09xls 982009

AR100297

TABLE 4

FACTORS USED IN DOSE CALCULATIONS INHALATION OF VOLATILE EMISSIONS

Coyne Textile Services Facility - Huntington West Virginia

Symbol

CA

IRA

ET

EF

ED-

BW

AT

Exposure Factor

Constituent Concentration in Air

Inhalation Rate

Exposure Time

Exposure Frequency

Exposure Duration

Body Weight

Averaging Time

Indoor Worker

Constituent-Specific See Table 3

25 m hour

8 hrday

250 daysyear

25 years

bull 70 kg

9125 days (NC)

25550 days (C)

Total Dose = CA x IR^ x ET x EF x ED x 1BW x 1AT

(NC) - Non-carcinogenic Averaging Time

(C) - Carcinogenic Averaging Time

Coyne VI Memo Tables_09-08-09xls 982009

AR100298

TABLES TOXICITY VALUES FOR CHEMICALS OF CONCERN

Coyne Textile Services Facility - Huntington West Virginia

Chemical of Concern

Volatile Organics

124-Trimethylbenzene

12-Dichloroethene (cis)

Chloroform

Methylene chloride

tetrachloroethene

Triehloroethene

Target Organ Critical Effect

blood

bullblood

liver

liver

liver CMS

liver kidney fetus CNS

Chroniclnhalation Reference Dose

(mgkg-day)

200E-03 P

1 OOE-02 R

140E-02 E

286E-01 M

771 E-02 M

1OOE-02 E

Inhalation Cancer ^ Slope Factor

(mgkg-day)^

NA

NA

805E-02 1

165E-03 1

200E-02 0

400E-01 E

(I) - Integrated Risk Information System (IRIS USEPA 2009)

(P) - Provisional Peer-Reviewed Toxicity Value (PPRTV) as presented in USEPA Regional Screening Tables (ORNL 2009)

(R) - Calculated assuming route-to-route extrapolation as per WVDEP

(E)-Provisional value from the National Center for Environmental Assessment (as per WVDEP)

(M)-Chronic Minimal Risk Level (MRL ATSDR 2009)

(0) - Value cited by USEPA Region 3 attributed to other sources (as per WVDEP)

Coyne VI Memo Tables_09-08-09xls 982009

AR100299

TABLE 6

NONCANCER HAZARD INDEX AND POTENTIAL CANCER RISK FOR AN INDOOR WORKER

Coyne Textile Services Facility - Huntington West Virginia

bull

Constituent

Volatile Organics

124-Trinnethylbehzene

12-Dichlorpethene (cis)

Chloroform

Methylene chloride

Tetrachloroethene Triehloroethene

EPC in Indoor Air

(mgm)

213E-06

651 E-05

- 638E-05

164E-05

161 E-03

844E-05

Intake (ADD)

(mgkg-d)

416E-07

127E-05

125E-05

321 E-06

315E-04 l65E-05

RfDi

(mgkg-d)

200E-03

1OOE-02

140E-02

286E-01

771 E-02 1 OOE-02

Hazard

Quotient

208E-04

127E-03

892E-04

112E-05

408E-03 165E-03

Intake (LADD)

(mgkg-d)

) 149E-07

455E-06 bull 446E-06

115E-06

112E-04 590E-06

CSFi

(mgkg-d)

NA

NA

805E-02

165E-03

200E-02

400E-01

Potential

Cancer Risk

NA

NA

359E-07

189E-09

225E-06 236E-06

Total Hazard Index

00081 Total

Cancer Risk 497E-06

Total Blood HI = Total Liver HI =

Total Central Nervous System HI = Total Kidney HI =

Total Fetal HI =

bull 00015 00066 00057 00017 00017

Notes NA = Toxicity values are not available for this endpoint or exposure pathway

Coyne VI Memo Tables_09-08-09xls 982009

AR100300

APPENDIX A

SUBSLAB VAPOR ANALYTICAL DATA

AR100301

Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility Huntington West Virginia

Sample

Consti tuent

Volatile Organics (ugm) 111-Trlchloroethane 1122-Tetrachloroethane 112-Trichloro-122-trifluoroethane 112-Trichloroethane 11-Dichioroethane 11-Dichloroethene 124-Trichloroberi2ene 124-Trimethylbenzene 12-Dibromoethane 12-Dichloroben2ene 12-Dichloroethane 12-Dichloroethene-(cis) -12-Dichloroethene (trans) 12-Dichloropropane 12-Dichlorotetrafluoroethane 135-Trimethylbenzene 13-Butadiene 13-Dichlorobenzene 13-Hexachlorobutadiene 14-Dichlorobenzene 224-trimethVlpentane 2-Chlorotoluene 4-Ethyltoluene Acetone Allyl Chloride Benzene Bromodichloromethane Bromoform Bromomethane Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 13-Dichloropropene (cis) Cyclohexane Dibromochloromethane

Identif ication Sample Date

CAS No

71-55-6 79-34-5 76-13-1 79-00-5 75-34-3 75-35-4 120-82-1 95-63-6 106-93-4 95-50-1 107-06-2 156-59-2 156-60-5 78-87-5 76-14-2 108-67-8 106-99^0 541-73-1 87-68-3 106-46-7 540-84r1 95-49-8

622-96-8 67-64-1 107-05-1 71-43-2 75-27-4 75-252 74-83-9 75-15-0 56-23-5 108-90-7 75-00-3 67-66-3 74-87-3

10061-01-5 110-82-7 124-48-1

lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt

lt lt lt lt lt lt lt lt lt lt lt lt

lt

VP-01 8132009

22 28 31 22 16 16 30 20 31 24 16 16 16 19 28 20 89 24 43 24

1 9 21 20 796 13 13 27 41 16 13 25 18 11 20 83 18 52 34

lt lt lt lt lt lt lt lt lt lt lt

lt lt lt lt lt lt lt lt lt lt lt

lt lt lt lt lt lt lt lt lt

lt lt lt lt

VP-02 8132009

218 2 7 5 307 218 162 159 297

bull 197 307 240 162 369 159 185 280 197 89

240 427 240 187 207 197

1880 125 128 268 414 155 125 252 184 106

5910 83 182 138 341

lt lt lt lt lt lt lt

lt lt lt

lt lt lt lt lt lt lt bull

lt lt lt lt

lt lt lt lt lt lt lt lt lt lt lt lt lt lt

VP-03 8132009

218 275 307 218

bull 162 159 297 197 307 240 162

6030 159 185 280 197 89

240 427 240 187 207 197

1750 125 128 268 414 155 125 252 184 106 195 83 182 138 341

Appx A SG Dataxis Page 1 of 2 982009

AR100302

Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility bull Huntington West Virginia

Consti tuent

Volatile Organics (ugm^) Dichlorodifluoromethane Ethylbenzene Methyl ethyl ketone Methyl Isobutyl ketone Methyl tert-butyl ether Methylene chloride n-Heptane jn-Hexane Styrene Tert-butyl alcohol Tetrachloroethene iToluene 13-Dichloropropene (trans) Triehloroethene Trichlorofluoromethane Vinyl bromide Vinyl chloride Xylene (o) Xylenes (mampp)

Sample Identif ication Sample Date

CAS No

75-71-8 100-41-4 78-93-3 108-10-1

1634-04-4 75-09-2

142-82-5 bull 110-54-3

100-42-5 75-65-0 127-18-4 108-88-3

10061-02-6 79-01-6 75-69-4 593-60-2 75-01-4 95-47-6

179601-23-1

lt lt

lt lt lt lt

lt lt

lt

lt lt lt lt lt

VP01 8132009

20 17 23 16 14 14 16

173 17 12 bull

11200 18 18 91 23 18 10 17 17

lt lt lt lt lt

lt

lt lt

lt lt

lt lt lt lt lt

VP-02 8132009

198 174 118 164 144

1520 164 -183 170 121

149000 151 182

2360 225 175 102 174 174

VP-03 8132009

lt 198 lt 174 lt 118 lt 164 lt 144

1160 lt 164

144 lt 170 ltbull 121

90500 lt 151 lt 182

7820 lt 225 lt 175 lt 102

208 387

Appx A SG Dataxis Page 2 of 2 982009

AR100303

APPENDIX B

CALCULATION OF TRANSPORT FACTORS USED TO ESTIMATE INDOOR AIR CONCENTRATIONS

AR100304

APPENDIX B

Calculation of Transport Factors Used to Estimate Indoor Air Concentrations

This appendix presents the methodology for calculating transport factors that are used to convert subslab

vapor concentrations to concentrations in indoor air 124-Trimethylbenzene 12-dichloroethene (cis)

chloroform methylene chloride tetrachloroethene and triehloroethene were identified as contaminants of

concern (COC) for potential vapor intrusion from subslab vapor associated with the Coyne Textile

Services Facility located in Huntington West Virginia (site) In this appendix the transport factors are

calculated to estimate the concentrations of COC in indoor air of the existing plant building located at the

site ~

Transport Factor for Indoor Air

The concentration of a constituent in indoor air (da) is proportional to the concentration of the constituent

in the subslab vapors immediately beneath the building foundation (ie subslab vapor concentration or

Csubsiab) The following equation is used to calculate da from Csubsiab

^ wja ~ ^subslab X I r

where

Cia = concentration of constituent in indoor air (mgm^) -

Csubsiab^ concentration of constituent in subslab vapors (mgm^) and

TF = transport factor from subslab vapors to indoor air

The transport factor (TF) is an infinite source attenuation coefficient andcan be calculated based on a

model developed by Johnson and Ettinger (1991) t he equation for calculating TF is as follows

(Deff X A B ) ( Q B X L T ) X expKQso i l X Lcrabk)(Dcrack X Acrack)]

exp[ (Qsoi l X Lcrack)(Dcrack X Acrack)] + (Deff X A B ) ( Q B X L T ) + (Deff X AB)(Qsoi l X L j ) X (exp [ (Qso i l X Lcrack)(Dcrack X Acrack)] - 1)

where

Deff = effective diffusion coefficient for vadose zone soil (cm^sec)

AB = area of enclosed space below grade (cm^)

QB = building ventilation rate (cm^sec)

LT = distance from contaminant source to building foundation (cm)

Qsoii = volumetric flow rate of vapors into the building (cm^sec)

Lcrack = foundatlon thickness (cm)

Dcrack = vapor diffusion coefficient through crack (cm^sec) and

Acrack = area of cracks through which vapors can pass (cm^)

AR100305

To solve this equation the USEPAs SG-ADV spreadsheet Version 31 most recently updated in

February 2004 was implemented A combination of site-specific factors and default values from the

Users Guide for Evaluating Subsurface Vapor Intrusion Into Buildings (USEPA 2004) were used as input

values in the model All input values are defined below and presented in Tables B-1-A through B-6-A

bull The initial subslab vapor concentration (Csubsiab) is the maximum detected concentration(in units

of ugm ) of samples VP-01 VP-02 and VP-03 that was presented in Table 3 of the report

bull The depth below grade to the bottom of the enclosed space floor (Lp) is set to 15 cm the default

value provided by USEPA (2004) for a slab-on-grade structure

bull The vapor sampling depth below grade (Lg) is a site-specific value The vapor samples were

collected from immediately beneath the building floor therefore Lj has been set to 15 cm

bull The average soilgroundwater temperature (Ts) is set to 125degC the average value for West

Virginia as estimated frorri Figure 8 of the vapor intrusion users guide (USEPA 2004)

bull The soil type used to estimate vapor permeability is assumed to be sandy loam (SL) The

associated soil properties for a sandy loam soil type are as follows the soil dry bulk density (Pb) is

162 gcm the total porosity (n) is 0387 (cm^-aircm^) and the water-filled porosity (nw) is 0103

(cm -HzOcm )

bull The floor thickness (Lcrack) is set to the USEPA (2004) default value of 10 cm

bull The soil-building pressure differential (AP) is set to the USEPA (2004) default value of 40 gcm-s^

bull The building dimensions are siterspecific based on the existing plant building located at the site

The existing structure is approximately 84000 square feet (Dolphin 2000) therefore the

dimensions are set to 8839 cm (290 feet) length by 8839 cm (290 feet) The USEPA (2004)

default value of 244 cm vyas used for the height

bull Thefloor-wall seam crack width (w) is set to the USEPA (2004)-default value of 01 cm

bull The indoor air exchange rate (ER) is set to 083hour This is the value provided by ASTM (2002)

for commercial and industrial buildings

AR100306

Tables B-1-B through B-6-B present the constituent-specific properties for COC that were used in the TF

calculations Tables B-1-C through B-6-C present the intermediate calculations used to determine the

indoor air attenuation coefficients (ie the transport factors) The shaded boxes in Tables B-1-C through

B-6-C also present the resulting TF values that are applied to the concentrations of COC in subslab

vapor and the estimated indoor air concentrations

References

American Society for Testing and Materials (ASTM 2002) Standard Guide for Risk-Based Corrective Action Applied at Petroleum Release Sites ASTM E-1739-95 (Reapproved 2002)

Johnson PC and RA Ettinger (1991) Heuristic model for predicting the intrusion r-ate of contaminant vapors into buildings Environ Sci Technolpgy 25 1445-1452

Dolphin Environmental LLC (Dolphin 2000) Site Characterization Report Mach 14 2000

United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004

AR100307

APPENDIX B-1-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV Nersion31 0204

Reset to Defaults

ENTER -

Chemical CAS No

(numbers only

no dasties)

95636

ENTER Soil gas

cone

Cg (ngm)

Soil Gas Concentration Data ENTER

Soil gas

OR cone

bull - c bull (PPmv)

197E+02

Chemical

124-Trimethylbenzene

MORE ENTER Depth

below grade to bottom

of enclosed space floor

U bull (cm)

ENTER

Soil gas sampling

depth below grade

U (cm) bull

ENTER

Average soil

temperature Ts

CO

1 15 1 1 5 bull125

ENTER ENTER ENTER Totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hft ha he

(cm) (cm) (cm)

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estirnate OR permeability | soil vapor

permeability) k v bull

(cm)

SL 1 1

MORE ENTER

stratum A SCS

soil type

Lookup Soil Parameters

ENTER stratum A soil dry

bulk density P

(gcm)

ENTER Stratum A soil total porosity

(unitless)

ENTER bull stratum A soil water-filled

porosity

(cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

nlaquo

(unitless)

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gchi-s^)

ENTER Enclosed

space floor

length bull LB

(cm)

ENTER Enclosed

space floor

width WB

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

bull Floor-wall seam crack

width w

(cm)

bullENTER

Indoor air exchange

rate ER

(1h) bull

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bidg OR

Leave blank to caicuij

(Lm)

Appx B-1 124-TMBxls 1 of 3 982009

AR100308

APPENDIX B-1-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of ^ bull law constant law constant vaporization at Normal

Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temperature boiling point point temperature weight

D bull Dbdquo H T R bull AHbdquo TB Tc IVIW

Unit risk Reference

factor cone URF RfC

(cms) (cmls) (atm-mmol) CO (calmol) (degK) (degK) (gmol) bull (ugm)- (mgm)

1 606E-02 1 792E-06 1 bull 614E-C3 1 25 1 9369 1 44230 | 64917 1 12020 1 OOE+00 1 60E-03 1

Appx B-1 124-TMBxls 2 of 3 982009

AR100309

APPENDIX B-1-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

(sec)

Source-building

separation

LT bull

(cm) bull

Stratum A soil

air-filled porosity

Q A

Stratum B soil

air-filled porosity

(cmcm) (cmcm)

Stratum C soil air-filled porosity

(cmcm)

Stratum A effective total fluid

saturation

Se

(cmcm)

Stratum A soil

bullintrinsic permeability

^ (cm)

stratum A Stratum A Floor- soil soli wall BIdg

relative air effective vapor seam Soil bull ventilation permeability permeability perimeter gas rate-

kfg ky Xgrack c o n e - QbuHdinpound

(cm) - (cm) (cm) (ngm) (cms)

946E+08 1 0284 0284 0284 0184 596E-09 0901 537E-09 35357 I 197E+02 | 439E+06 |

Area of enclosed

space below grade

As (cm)

Crack-to-total area ratio

1 bull

(unitless)

Crack depth

below grade

Zcfack

(cm)

Enthalpy of vaporization at

ave soil temperature

AHvjs

(calmol) bull

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law constant at

ave soil bull temperature

bull HTS

(unitless)

Vapor bull viscosity at

ave soil temperature

HTS

(gcm-s)

Stratum A

effective diffusion

coefficient

D (cms)

Stratum-B

effective diffusion coefficient

DB (cms)

Stratum C effective diffusion

coefficient

D-c (cms)

Total - overall effective diffusion

coefficient

D ^ (cms)

Diffusion path

length

L-

(cm)

I 787E+07 I 449E-05 | 15 | 11661 260E-03 111E-01 176E-04 I 612E-03 j OOOE+00 | OOOE+00 | 612E-03 j

bull Convection path

length

Lp

(cm)

Source vapor cone

^source

(ngm)

Crack radius

Tcfack

(cm)

Average vapor

flow rate into bIdg

Qsoii

(cms)

Crack effective diffusion

coefficient pcrack

(cms)

Area of CTack

Acack

(cm)

Exponent of equivalent foundation

Peclet number

exp(Pe)

(unitless)

bull bull - bull bull bull bull

1 15 1 197E+02 1 010 1 474E+01 612E-03 bull 354E-t-03 1 336E+09

Infinite source Indoor

~ attenuation coefficient

a

(unitless)

108E-05

Infinite source

btJbldgjJSv-L ^Ppncji3i-

virhpbiiilding bullbull ^lHltti^m)ilg

213E-03

Unit risk

factor

URF

(ngm)-

Reference cone

RfC (mgm)

NA 60E-03 1

I END

Appx B-1 124-TMBxls 3 of 3 982009

AR100310

APPENDIX B-2-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV Nersion31 020^

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

156592

Soil Gas Concentration Data ENTER

Soil gas

cone OR c

(ngm) bull

ENTER Soil bull-gas

cone

c (ppmv)

603E+03 1

Chemical

cis-12-Dichloroethylene

MORE ENTER Depth

below grade to bottom

of enclosed space floor

LF

(cm)

ENTER

Soil gas sampling

depth below grade

U (cm)

ENTER

Average soil

temperature bull Ts

(degC)

1 15 1 bull 15 125

ENTER ENTER ENTER Totalsmust add ijp tb value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hA hB he

bull (cm) (cm) (cm)

15 1 1

ENTER Soil

straturh A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estimate OR permeability | soil vapor

permeability) kv

(cm)

SL 1 |

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

P (gcm)

ENTER Stratum A soil total porosity

bull n

(unitless)

ENTER Stratum A

soil water-filled porosity

(cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

ENTER Stratum B

soil water-filled porosity

ENTER Stratum C

SCS soil type

(unitless) (cmcm)

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure differential

AP

(gcm-s)

ENTER Enclosed bull

space floor

length

LB (cm)

ENTER Enclosed

space floor

width WB

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER

Average vapor flow rate into bIdg

OR Leave blank to calculi

Qsoil

(Lm)

Appx B-2 cis-12-DCExls 1 of 3 982009

AR100311

APPENDIX B-2-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Diffusivity in air

Da

(cms)

Diffusivity in water

Dw (cms)

Henrys law constant at reference temperature

H

(atm-mmoi)

Henrys law constant

reference temperature

bull T R

CC)

Enthalpy of vaporization at

the normal boiling point

AHbdquob

(calmol)

Normal boiling point

TB

(degK)

Critical temperature

Tc (degK)

Molecular weight

MW

(gmol)

Unit risk

factor URF

(ngm)

Reference cone

RfC (mgm)

1 736E-02 1 113E-05 1 407E-03 j 1 25 1 bull 7192 1 33365 1 54400 1 9694 1 OOE+00 j 35E-02 1

Appx B-2 cis-12-DCExls 2 of 3 982009

AR100312

APPENDIX B-2-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

stratum A Stratum B Stratum C Source- soil soil soil

Exposure building air-filled air-filled air-filled

duration separation porosity porosity porosity

T LT ea e^ bull e= (sec) (cm) (cmcm) (cmcm) (cmcm)

I 946E+08n^

Stratum A Stratum A Stratum A Stratum A Floor-effective soil soil soil wall total fluid intrinsic relative air effective vapor seam

saturation permeability permeability permeability perimeter

Ste kj krg ky Acrack

(cmcm) (cm) (cm) (cm) (cm)

Soil gas

cone (ngm)

I 0284 I 0284~ 0284 0184 I 596E-09 | 090T 537E-09 35357 603E+03

BIdg ventilation

rate

JbulldinE

(cms)

439E+06

Area of enclosed

space below grade

AB

(cm)

Crack-to-total

area ratio

n (unitless)

Crack depth below grade

Zltiack (cm)

Erithalpy of vaporization at

ave soil temperature

AHvTs (calmol)

Henryslaw constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law constant at

ave soil temperature

HTS

(unitless) bull

Vapor viscosity at

ave soil bull temperature

HTS

bull (gcm-s)

Stratum A

effective bull diffusion

coefficient

D^A-(cms)

Stratum B

effective bull diffusion

coefficient

D=B

(cms)

Stratum C

effective diffusion bull

coefficient

D=e (cms)

Total overall

effective diffusion

coefficient

DT

(cms)

Diffusion path

length

Ld

(cm)

I 787E+07 I bull449E-05 | 15 bull7709 230E-03 982E-02 176E-04 | 743E-03 | OOOE+00 | OOOE+00 | 743E-03 |

bull bull bull -

Convecfion path -bull

length

Lp (cm)

Source vapor cone

-source

(Mgm)

Crack radius

fcrack

(cm)

Average vapor

flow rate into bIdg

Qaoil bull

(cms)

Crack effective diffusion

coefficient pcack

(cms)

Area of crack

crack

(cm)-

Exponent of equivalent foundation

Peclet number

exp(Pef)

(unitless)

bull

1 15 -1 603E+03 1 010 1 474E+01 743E-03 354E+03 1 697E+07

Infinite source Indoor

attenuation coefficient

poundbullbullbull C t

pound(unitless)

bullsiilaquogt j ii08E-05

Infinite [ source

bIdg cone

Cbujidjng

(pgm)

651 E-02 iKrt

Unit risk

factor

URF

(ngm)-

Reference cone

RfC

(mgm)

NA 35E-02 1

I END I

Appx B-2 cis-12-DCExls 3o f3 982009

AR100313

APPENDIX B-3-A DATA ENTRY SHEET

Coyne Texti le Services - Hunt ington West Virginia

SG-ADV Version 31 0204

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

67663

Soil Gas Concentration Data ENTER ENTER

Soil Soil gas gas

cone OR cone c C

(^gm) (ppmv)

591 E+03

bull

Chemical

Chloroform

MORE ENTER Depth

below grade tb bottom

of enclosed space floor

bull LF

(cm)

ENTER

Soil gas sampling depth

below grade

(cm)

ENTER

Average soil

temperature-Ts

CO bull

1 15 1 15 1 125

ENTER ENTER ENTER Totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

IIA hs he (cm) (cm) (cm)

1 5 bull 1 1

ENTER ENTER Soil - bull

stratum A User-defined SCS stratum A

soil type bull soil vapor (used to estimate OR permeability

soil vapor k

bull permeability) (cm) 1

SL 1 1 bull

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A soil dry

bulk density

Pb (gcm)

ENTER Stratum A soil total porosity

nV (unitless)

ENTER Stratum A

-soilwater-filled bullporosity

Sraquo (cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

(unitless)

ENTER Stratum B

soil water-filled porosity

bull ebdquo=

(cmcm) bull

ENTER Straturri C

SCS bull soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

- c rack

(cm)

ENTER

Soil-bldg pressure

differential AP^

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor

width bull W B

(cm)

ENTER

Enclosed space

height HB

(cm)

ENTER

bull Floor-wall^ seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bidg OR

Leave blank to calculi

Qsoil bull

(Lm)

I -I

Appx B-3 Chloroformxls 1 of 3 982009

AR100314

APPENDIX B-3-B CHEMICALPROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Diffusivity in air

D (cms)

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffijsivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature

Dbdquo H TR A H bdquo TB Tc

(cm s) (atm-m mol) ro (calmol) (degK) (degK)

Molecular weight

MW

(gmol)

Unit risk

factor URF

(ngm)-

Reference cone

RfC

(mgm)

104E-01 100E-05 I 366E-03 25 6988 33432 53640 11938 I 23E-05 | OOE+00

Appx B-3 Chloroformxls 2 of 3 982009

AR100315

APPENDIX B-3-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure

duration

(sec)

Source-

building

separation

LT

(cm)

Stratum A

soil

air-filled

porosity

Sa

( cm cm )

Stratum B

soil

air-filled

porosity

( cm cm )

Stratum C

soil

air-filled

porosity

( c m c m )

Stratum A

effective

total fluid

saturation

( c m c m )

Stratum A

soil

intrinsic

penmeability

k

(cm )

Stratum A

- soil

relative air

permeabil i ty

(cm )

Stratum A

soil

effective vapor

permeability

kv

(cm )

Floor-

wall

seam

perimeter

gtcrack

(cm)

Soil gas

cone

(ngm)

BIdg

venfilation

rate

^buildlriE

(cms)

I 9 4 6 E + 0 8 ~ T I 0284 T 596E-09 I 0-901 I 537E-09 | 35357 | 591 E+03 j 439E+06 | 1 0 284 0284 0184

Area of

enclosed

space

below

grade

A B

( c m )

Crack-

to-total

area

ratio

n

(unitless)

Crack

depth

bull below

grade

^crack

(cm)

Enthalpy of

vaporization at

ave soil

temperature

AHTs bull

(calmol)

Henry s law

constant at

ave soil

temperature

HTS

(a tm-m mol j

Henrys law

constant at

ave soil

bull temperature

HTS

(unitless) bull

Vapor

viscosity at

ave soil-

temperature

^HTS

(gcm-s)

Stratum

A

effective

diffusion

coefficient

(cm s)

Stratum

B

effective

difftjsion

coefficient

D B

(cms) bull

S t ra tum

C

effective

diffusion

coefficient

Dc

(cm s)

Total

overall

effective

bull diffusion

coefficient

D T

(cm s)

Diffi jsion

path

length

Ld

(cm)

I 787E+07 I 449E-05 j - bull 15 7528 210E-03 896E-02 176E-04 I 105E-02 | OOOE+00 | OOOE+00 | 105E-02

Convection

path length

Lp

(cm)

Source

vapor

cone -

^source

- (ngm)

Crack

radius

Tcrack

(cm)

Average

vapor

flow rate

into bidg

Qsoil

(cms)

Crack

effective

diffusion

coefficient Qcrack

bull (cms)

Area of crack

Acrack

(cm)

Exponent of

equivalent

foundation

Peclet number

exp(Pe)

(unitless)

V bull bull

1 15 1 591 E+03 1 010 1 474E+01 105E-02 354E+03 1 355E+05

Infinite

source

indoor

attenuation

coefficient

d

(unitless)

bull 108E-05

Infinite

source

bIdg

cone

^ b u i l d i n g

i (^gm)

bull bull

i 638E-02 -

Unit

risk bull factor

URF

(ngmY

Reference

cone

RfC

(mgm)

~ 23E-05 NA 1

I END

Appx B-3 Chloroform xls 3 of 3 982009

AR100316

APPENDIX B-4-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ersion 31-020^

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

nodashes)

bull 75092

ENTER Soil gas

cone

c (ngm)

Soil Gas Concentration Data ENTER

Soil gas bull

OR cone

bull C

(ppmv)

152E+03

bull bull

Chemical

Methylene chloride

MORE

MORE 4gt

ENTER Depth

below grade to bottom

of enclosed space floor

LF -

(cm)

ENTER

Soil gas sampling depth

below grade

bull U

(cm)

ENTER

Average soil

temperature

Ts bull CC)

bull bull bull bull

1 15 1 15 125

ENTER Totals

Thickness of soil

stratum A h

(cm)

ENTER ENTER must add up to value of Ls (cell F24

Thickness Thickness of soil of soil

stratum B stratum C (Enter value or 0) (Enter value or 0)

he he bull

(cm) bull (cm) -

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(usedto estimate OR perrrieability | soil vapor

permeability)

k bull

(cm)

SL 1 bull 1

ENTER Stratum A

SCS soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

Pb (gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Stratum A

soil water-filled porosity

9w (cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

Pb^

(gcm)

ENTER Stratum B soil total porosity

n^

(unitless)

ENTER Stratum B

soil water-filled porosity

(crhcm)

ENTER Stratum C

SCS soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE 4gt

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

bull Soil-bldg pressure

differential AP^

(gcm-s)

ENTER Enclosed

space floor

length LB

(cm)

ENTER Enclosed

space floor

width bull W B

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width

w

(cm)

ENTER

Indoor air exchange

rate

ER (1h)

ENTER Average vapor

flow rate into bidg OR

Leave blank to calculc

Qsoil

(Lm)

10 40 8839 8839 244 01 083

Appx B-4 MCxIs 1 of 3 982009

AR100317

Diffijsivity in air

D

APPENDIX B-4-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffusivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature

Pw H TR AHt TB TC

Molecular weight

MW

Unit risk

factor URF

Reference cone

RfC

(cms) (cms) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) bull (ngm)- (mgm)

bull bull

1 101E-01 1 117E-05 1 218E-03 1 25 | 6706 1 31300 1 51000 1 8493 1 47E-07 1 30E+00 1

Appx B-4 MCxIs 2 of 3 982009

AR100318

APPENDIX B-4-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

T

(sec)

Source- -building

separation

LT

(cm)

Stratum A soil

air-filled porosity

e a bull

(cmcm)

Stratum B soil

bullair-filled porosity bull

ea^ (cmcm)

Stratum C soil

air-filled porosity

ea= (cmcmj

Stratum A effective total fluid

saturation

Sc bull

(cmcm)

Stratum A soil

intrinsic pemneability

ki (cm)

Stratum A soil

relative air permeability

^ ^ g

(cm)

stratumA bull soil effective vapor permeability

K (cm)

Floor-wall

seam perimeter

Xcrack

(cm)

Soil gas

cone (ngm)

BIdg ventilation

rate

Qbuildinc

(cms)

1 946E+08

Area of -enclosed

space below

bull grade

AB

(cm)

1

Crack-to-total

area rafio

Tl

(unitless)

0284 1

Crack depth below grade

Zcrack

(cm)

0284 1

bull Enthalpy of vaporization at

ave soil temperature

AHTs (calmol)

0284

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

0184

Henrys law constant at ave soil

temperature

HTS

bull (unitless)

1 596E-09

Vapor viscosity at

ave soil temperature

Mrs (gcm-s)

0901

Stratum A

effective diffusion

coefficient

D (cms)

537E-09

Stratum B

effective diffusion

coefficient

D-B (cms)

35357 1

Stratum C -

effective diffusion

coefficient

D-c ^ (cms)

152E+03

Total bull overall

bull effective diffusion

coefficient

D ^

(cms)

440E+06 1

Difftjsion path

length

Ld (cm)

1 787E+07

Convection path

length

Lp (cm)

4 49E-05

Source vapor cone

Csource

(ngm)

15 1

Crack radius

Tcrack

(cm)

7007 bull 1

Average vapor

flow rate intobldg

Qsoil

(cms)

130E-03

Crack effective diffusion

coefficient pcrack

(cms)-

555E-02

bull ^

Area of crack

Acrack

(cm) bull

1 176E-04

Exponent of equivalent foundation

Peclet number

exp(Pe)

(unitless) bull

bull bull

1 15

1 END

152E+03 010 1 474E+01 1 102E-02 354E+03 1 519E+05

102E-02

Infinite source

indoor ^attenuation coefficient

bull a

(unitless)

aiii08E-05

0 OOE+00

bull

Infinite bull source

bIdg ^ cone

^bu i l d i ng

(MQm)

164E-02

OOOE+00 1

Unit risk

factor

URF

(ngm)-

47E-07 1

102E-02 j

Reference cone

RfC

(mgm)

30E+00 j

1 1

Appx B-4 MCxIs 3 of 3 982009

AR100319

APPENDIX B-5-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ^erslon 31 0204

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

127184

Soil Gas Concentration Data ENTER ^ ENTER

Soil -Soi l bull gas gas

cone OR cone Cg C bull

(tgm) (ppmv)

149E+05 1

Chemical

bull Tetrachlbroethylene

MORE 4

ENTER Depth

below grade to bottom

ofenclosecJ space floor

LF

(cm)

ENTER

Soil gas bull sampling

depth below grade

u bull (cm)

ENTER

Average bullsoil

temperature - Ts

ro 1 1 5 1 15 1 125 bull

ENTER ENTER ENTER totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hft bull he bull he

(cm) (cm) (cm)

bull 1 5 1 - 1

ENTER ENTER Soil

stratum A User^defined bull SCS bull stratum A soil type soil vapor

(used to estimate OR perrrieability soil vapor K bull

permeability) (cm) 1

SL 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

Pb

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Sitratum A

soil water-filled bull porosity

(cmcm)

ENTER Stratum B

SCS soiltype

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

Pb^

(gcm)

ENTER Stratum B soil total porosity

Ajnitless^

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS soil type

LookupSoil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

VS

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor width

W B

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width

w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

ENTER Average vapor

flow rate into bidg OR

Leave blank to calcul

bull Qsoil

(Lm)

10 40 8839 8839 244 01 083

Appx B-5 PCExIS 1 of 3 982009

AR100320

APPENDIX B-5-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal Unit

Diffusivity Diffusivity at reference reference the riormal boiling Critical Molecular risk Reference in air in water temperature temperature boiling point point teriiperature weight factor cone

Da Dbdquo H TR AHb TB Tc MW URF RfC

(cms) (cnis) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) (^gm)- (mgm)

1 720E-02 1 820E-06 1 184E-02 1 25 1 8288 1 39440 1 62020 1 16583 1 59E-06 1 60E-01 1

J

AppxB-5PCExls 2 of 3 - 982009

AR100321

APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

T

(sec)

Source-building

separation

LT

bull (cm)

Stratum A soil

air-filled porosity

Oa (cmcm)

Stratum B - soil air-filled porosity

ea (cmcm)

Stratum C soil

air-filled porosity

ea= - (cmcm)

Stratum A effective total fluid

saturation

sbdquo (cmcm)

Stratum A soil

intrinsic permeability

ki (cm)

Stratum A soil

relative air permeability

- ^ g

(cm)

Stratum A soil

effective vapor permeability

kv (cm)

Floor-wall

seam perimeter

^crack

(cm)

Soil gas

cone

(ngm)

BIdg venfilation

rate

Qbuildins

bull (cms)

bull bull

1 946E+08

Area of enclosed

space below grade

AB

(cm)

1

bullCrack-to-total

area ratio

1 (unitless)

0284 1

Crack bull depth below grade

Zcrack

(cm) -

0284 1

Enthalpy of vaporization at bull

ave soil temperature

bull A H V TS

(calmol)

0284

Henrys law constant at

ave soil temperature

HTS (atm-mmol)

0184

-Henrys law constant at

ave soil temperature

HTS

(unitless)

1 596E-09

Vapor viscosity at

ave soil temperature

HTS

(gcm-s)

0901

Stratum A

effective diffusion

coefficient bull D = bull

(cms)

537E-09

Stratum B

effective diffusion

coefficient

D--B (cms)

35357 1

Stratum C

effective diffusion bull

coefficient

D-c (crris)

149E+05

Total overall

effective bulldiffusion coefficient

DT

(cms)

440E+06 1

Difftjsion path

length

U (cm)

1 787E+07

Convection path

length

bull Lp

(cm)

4 49E-05

Source vapor cone

^source

(ngm)

15 1

Crack radius

Tcrack

(cm)

9528 1

Average vapor

flow rate intobldg

Qsoil (cms)

908E-03

Crack effective diffusion

coefficient pcrack

bull ( c m s ) bull

387E-01

Area of crack

Abdquoack (cm)

1 176E-04

Exponent of equivalent foundafion

Peclet number

exp(Pe)

(unitless)

bull

1 15-

1 END

149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08

727E-03

Infinite source indoor

attenuation coefficient

a

(unitless)

108E-05

OOOE+00

Infinite source

bIdg cone

Cburldtng

(Mgm)

161 E+00

OOOE+00 1

Unit risk

factor

URF

(ugm)-

59E-06 1

727E-03

Reference cone

RfC (mgm)

60E-01

1 1

Appx B-5 PCExls 3 of 3 982009

AR100322

APPENDIX B-6-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ersion31 0204

Reset to Defaults

t

Soil Gas Concentration Data ENTER

Chemical CAS No

(numbers only

no dashes)

79016

ENTER ENTER Soil Soil gas gas

cone OR cone C C -

bull (ngm) (ppmv)

782E+03

Chemical

Trichloroethylene

MORE ENTER Depth

below grade to bottom-

of enclosed space floor

LF

(cm)

ENTER

Soil gas sarnpling

depth below grade

U (cm)

ENTER

Average soil

temperature Ts

(degC)

1 15 1 15 t 125

ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e

(cm) (cm) (cm)

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estimate OR permeability soil vapor

permeability)

k (cm)

bull S L 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil bull-Parameters

ENTER Stratum A

soil dry bulk density

P b -

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Stratum A bull

soilwaterrfilled porosity

(cmcm) bull

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

bull P ^ (gcm)

ENTER Stratum B soil total

porosity

nlaquo

(unitless) -

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS bull soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor

width W B

(cm)

ENTER

Enclosed space height

H B bull

( c m ) bull

ENTER

Floor-wall seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bIdg OR

Leave blank to calculc

Qsoil

(Lm) -

Appx B-6 TCExIs 1 of 3 982009

A

AR100323

APPENDIX B-6-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight

Da Dbdquo H TR AH^b TB TC MW

Unit risk Reference

factor cone URF RfC

(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)

1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1

Appx B-6 TCExIs 2 of 3 982009

AR100324

APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

(sec)

Source-building

separation LT

(cm)

Stratum A soil

air-filled porosity

bull ea (cmcm)

Stratum B Soil

air-fllled porosity

e^ bull (cmcm)

Stratum C soil

air-filled porosity

(cmcm)

StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air

saturation permeability permeability

S|e k krg (cmcm) (cm) (cm)

Stratum A Floor-soil wall BIdg

effective vapor seam Soil ventilafion permeability perimeter gas rate

k^ bull Xack c o n e Qbuildins

(cm) (cm) (ngm) (cms)

946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |

Area of enclosed

space below grade

AB

(cm)

Ciack- to-total

area ratio

1 (unitless)

Crack depth below grade

Zcrack

(cm)

Enthalpy of vaporization at

ave soil temperature

A H J S

(calmol)

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law bull constant at

ave soil temperature

HTS

(unitless)

Vapor viscosity at

ave soil temperature

|JTS

(gcm^s)

Stratum A

effective diffusion

coefficient

(cms)

Stratum B

effective -diffusion

coefficient

D=B (cms)

Stratum ^ C effective diffusion

coefficient

D=c (cms)

Total overall

effective diffusion

coefficient

DT

(cms)

I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03

Diffusion path

length

Li (cm) bull

Convection bull path

length

Lp

(cm)

Source vapor cone bull

^source

(ngm)

Crack radius

rcrack

(cm)

Average vapor

- flow rate intobldg

Qsoil

(cms)

Crack effective diffusion

bull coefficient Qcrack

(cms)

Area of crack

^crack

(cm)

Exponent of equivalent foundation

Peclet bull number

exp(Pe)

(unitless)

bull bull

1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07

Infinite source Indoor

attenuation coefficient

a

(unitless)

108E-05

Infinite source

bIdg concgt

^building

(ngm)

844E-02

Unit risk

factor

URF

(ngm)-

Reference cone

RfC

(mgm)

1 1E-04 1 40E-02 1

END

Appx B-6 TCExIs 3 of 3 982009

AR100325

Office of Waste Management 1356 Hansford Street

Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256

West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director

ORDER

ISSUED UNDER THE

HAZARDOUS WASTE MANAGEMENT ACT

CHAPTER 22 ARTICLE 18

OF THE WEST VIRGINIA CODE^ AS AMENDED

y Order Number HW-011-80

To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704

ATTEMTION MREDARMON

Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull

AR100326

ViWJ011-laquo9 PageNunil)er2

BASIS FOR ORDER

As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following

A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^

B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator

C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities

0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94

^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement

P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following

1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater

2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was

^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment

CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable

CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order

AR100327

H W - 0 1 1 - 9 9 Page Number 3

REQUIREMENTS OF ORDER

Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows

1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^

2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore

remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling

GENERAL PROVaiONS

1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order

2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order

3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order

Effective Date

Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief

Wt T 1 V Oflice of Waste Management

AR100328

^ ^ S I S

^wmmmmamn

AR100329

Page 16: SDMS DocID 2121999 · International Enterprises Corp. building (Coyne Building), which is located at 1111 Vernon Street, Westmoreland District, Wayne County, West Virginia. The following

TABLES

AR100293

TABLE 1 SUBSLAB VAPOR SAMPLES INCLUDED IN THE RISK ASSESSMENT

Coyne text i le Services Facility - Huntington West Virginia

Medium

Subslab Vapor

Sample Identification

bull VP-01

VP-02

VP-03

Sample Date

8132009

8132009

8132009

Coyne VIMemo Tables_09-08-09xls 982009

AR100294

TABLE 2 IDENTIFICATION OF CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR

Coyne Textile Services Facility - Huntington West Virginia

mdash

Const i tuent

Volati le Organics

111-Trichlor6ethane

1122-Tetrachloroethane

112-Trichloro-122-trifluoroethane

112-Trichloroethane

11-Dichloroethane

11-Dichloroethene

124-Trichlorobenzene

124-Trimethylbenzene

12-Dibromoethane

12-Dichlor6benzene

12-Dichloroethane

12-Dichloroethene (cis)

12-pichloroethene (trans)

12-Dichloropropane

12-Dichlorotetraf1uoroethane

135-Trimethylbenzene

13-Butadiene

13-Dichlorobenzene

13-Hexachlorobutadiene

14-Dichlorpbenzene

224-trimethylpentane

2-Chlorotoluene

4-Ethyltoluene

Acetone

Allyl Chloride

Benzene

Bromodichloromethane

Bromoform

Bromomethane

Carbon disulfide bull

Carbon tetrachloride

ChJorobenzene

Chloroethane

Frequency of Detection

0 3

0 3

0 3

bull 0 3

0 3

0 3

0 3

1 3

0 3 bull

0 3

b 3 bull

2 3

0 3

bull 0 3

0 3

0 3

0 3 bull

0 3

0 3

0 3

0 3

0 3

0 17

3 3

0 3

P 3

- 0 3

0 3

0 3

0 3

0 3

0 3

0 3

Min imum Detected

Concentrat ion

(ugm^)

ND

ND

ND

ND

ND

- ND

N D

197

ND bull

ND

ND

369

ND

bull~ ND

ND

ND

ND

ND

ND

bull ND

ND

ND

ND

796

ND

ND

ND-

ND

ND

ND

ND

ND

ND

Maximum

Detected Concentrat ion

(ugm3)

ND

ND

ND

ND

ND

ND

ND

197

ND

ND

ND

mdash 6030

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

1880

ND-

ND

ND

ND

ND

ND

ND

ND

ND

Sample wi th Maximum Detect

ND

ND

ND

ND

ND

ND

- ND

VP-03 -

ND

ND

ND

VP-03

ND

bullND

ND

ND

ND

ND

ND

ND

ND

ND

ND

VP-02

ND

ND bull

ND

ND

ND bull

bull ND

ND

ND

ND

Min imum Detection

Limit (ugm3)

22

28

31

22

16

16

30

20

31

24

16

bull 16

16

19

28

20

89

24 bull

43

24

bull 19

2 1

20

--^ 13

13

27

41

16

13

25

18

11

Maximum Detection

Limit (ugm3)

218

275

307

218

162

159

297

197

307

240

162

- 16

159

185

280

197

89

240

427

240

187

207

197

--125

128

268

414

155

125

252

184

106

Vapor Intrusion Corhparison

V a l u e

(ugm)

22000

042

300000

15

bull 5000

2000

2000

60

011

2000

094

350

700

40

NA

60

0087

1100

11

8000

NA

NA

NA

3500

NA

31

14

22

50

7000

16

bull 600

100000

Chemical of Concern

No

No

No

No

No

No

No

YES

No

No

No

YES

No

No

No

N o bull

bullNo

No

No

No

No

No

No

N o

No

No

No

N o

No

No

No

No

No

Comment

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent notdetected

fflaximCimTdeteetlSffieedsTcomDarisonivalues

Constituent not detected

Constituent not detected

Constituent not detected

Maximum detect exceeds comparison value

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Maximum detect below comparison value

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detectedl

Constituent not detected

Constituent not detected

CoyneVI Memo Tables_09-08-09xls 982009

AR100295

TABLE 2

IDENTIFICATION OF CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR

Coyne Textile Services Facility - Huntington West Virginia

Const i tuent

Volati le Organics

Chloroform -

Chloromethane

13-Dichloropropene (cis)

Cyclohexarie^

Dibrcimochloromethane

DichlonDdifluoromethane

Ethylbenzene

Methyl ethyl ketone

Methyl isobutyl ketone

Methyl tert-butyl ether

Methylene chloride

n-Heptane

n-Hexane

Styrene

Tert-butyl alcohol

Tetrachloroethene

Toluene

13-Dichloropropene(trans)

Triehloroethene

Trichlorofluoromethane

Vinyl bromide

Vinyl chloride

Xylene (0)

Xylenes (mampp)

Frequency of Detection

1 3

0 3

0 3

1 3

0 3

0 3

0 -3

1 3

0 3

0 3

2 3

0 3

3 3

0 3

0 3

3 3

1 3

- 0 3

3 3

P 3

0 3

0 3

1 3

1 3

Min imum Detected

Concentrat ion

(ugm)

5910

ND

ND

52

ND

ND

ND

23

ND

ND

1160

ND

1 4 4

ND

ND

11200

18

ND

91

ND

ND

ND

208

387

Maximuri i Detected

Concentrat ion (ugmS)

bull

5910

ND

ND

52

bull ND

ND

ND

23

ND

ND

1520

ND

183

ND

ND

149000

18

ND

7820

ND

bullND

ND

208

387

Sample vyith Max imum Detect

VP-02

ND

ND

VP-01

bull ND

ND

ND

VP-01

ND

ND

VP-02

ND

VP-02

ND

ND

VP-02

VP-01

ND

VP-03

ND

ND

ND

VP-03

VP-03

Min imum Detection

Limit (ugm3)

20

83

18

138

34

bull 20

17

118

16

14

14

16

- -17

12

--151

18

--23

18

10

1 7 bull

1 7 bull

Maximum Detection

Limit (ugm3)

195

83

182

138

341

198

174

118

164

144

14

164

170

121 -

--151

182

225

175

102

bull 174

174

Vapor Intrusion Compar ison

V a l u e

(ugm)

11

24

NA

2000

1

2000

22

10000

800

30000

52

NA

2000

10000

NA

81

4000

NA

022

7000

NA

28

70000

70000

Chemical o f Concern

YES

No

No

No

No bull

No

No bull

No bull=

No

No

YES

No

No

No

No

YES

No

No

YES

N o

No

No

No

No

Comment

Maximum detect exceeds comparison value

Constituent not detected

Constituent not detected

Maximum detect below comparison value

Constituent not detected

Constituent not detected

Constituent not detected

Maximum detect below comparison value

Constituent not detected

Constituent not detected

Maximum detect exceeds comparison value

Constituent not detected bull

Maximum detect below comparison value

Constituent not detected

Constituent not detected

Maximum detect exceeds comparison value

Maximum detect below comparison value

Constituent not detected

Maximum detect exceeds comparison value

Constituent not detected

Constituent not detected

Constituent not detected bull

Maximum detect below comparison value

Maximum detect below comparison value

Notes

ND - Not Detected

NA - Not Available

- - Constituent detected in every sample detection limit not presented

Values in bold indicate detection limit exceeds comparison values

Target shallow soil gas comparison values corresponding to indoor air concentrations where the soil gas to indoor air attenuation factor = 01 and the target cancer risk is set to ip (presented in Table 2c of USEPA 2002a)

Comparison value for cyclohexane is based on the comparison value for hexane

Coyne VI Memo Tables_09-08-09xls 982009

AR100296

TABLES

EXPOSURE POINT CONCENTRATIONS FOR CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR

Coyne Textile Services Facility - Huntington West Virginia

Chemical of Concern

VolatileOrganics

i24-Trimethylbenzene

12-Dichloroethene (cis)

Chloroform

Methylene chloride

Tetrachloroethene Triehloroethene

Subslab Vapor Source

Concentration (mgm^)

0197

603

591

152

149 782

Transport

Factor^ (unitless)

108E-05

108E-05

108E-05

108E-05

108E-05 108E-05

EPC in

Indoor Air (mgm^)

213E-06

651 E-05

638E-05

164E-05

161E-03 844E-05

Notes

^ Subslab vapor source concentration is based on the maximum detected concentration of samples

VP-01-02 and-03 (see Table 2) -

^ Details of the transport factor calculations are presented in Appendix B

^ Exposure Point Concentration (EPC) in inidoor air is calculated as the subslab vapor concentration TF

Coyne VI Memo Tables_09-08-09xls 982009

AR100297

TABLE 4

FACTORS USED IN DOSE CALCULATIONS INHALATION OF VOLATILE EMISSIONS

Coyne Textile Services Facility - Huntington West Virginia

Symbol

CA

IRA

ET

EF

ED-

BW

AT

Exposure Factor

Constituent Concentration in Air

Inhalation Rate

Exposure Time

Exposure Frequency

Exposure Duration

Body Weight

Averaging Time

Indoor Worker

Constituent-Specific See Table 3

25 m hour

8 hrday

250 daysyear

25 years

bull 70 kg

9125 days (NC)

25550 days (C)

Total Dose = CA x IR^ x ET x EF x ED x 1BW x 1AT

(NC) - Non-carcinogenic Averaging Time

(C) - Carcinogenic Averaging Time

Coyne VI Memo Tables_09-08-09xls 982009

AR100298

TABLES TOXICITY VALUES FOR CHEMICALS OF CONCERN

Coyne Textile Services Facility - Huntington West Virginia

Chemical of Concern

Volatile Organics

124-Trimethylbenzene

12-Dichloroethene (cis)

Chloroform

Methylene chloride

tetrachloroethene

Triehloroethene

Target Organ Critical Effect

blood

bullblood

liver

liver

liver CMS

liver kidney fetus CNS

Chroniclnhalation Reference Dose

(mgkg-day)

200E-03 P

1 OOE-02 R

140E-02 E

286E-01 M

771 E-02 M

1OOE-02 E

Inhalation Cancer ^ Slope Factor

(mgkg-day)^

NA

NA

805E-02 1

165E-03 1

200E-02 0

400E-01 E

(I) - Integrated Risk Information System (IRIS USEPA 2009)

(P) - Provisional Peer-Reviewed Toxicity Value (PPRTV) as presented in USEPA Regional Screening Tables (ORNL 2009)

(R) - Calculated assuming route-to-route extrapolation as per WVDEP

(E)-Provisional value from the National Center for Environmental Assessment (as per WVDEP)

(M)-Chronic Minimal Risk Level (MRL ATSDR 2009)

(0) - Value cited by USEPA Region 3 attributed to other sources (as per WVDEP)

Coyne VI Memo Tables_09-08-09xls 982009

AR100299

TABLE 6

NONCANCER HAZARD INDEX AND POTENTIAL CANCER RISK FOR AN INDOOR WORKER

Coyne Textile Services Facility - Huntington West Virginia

bull

Constituent

Volatile Organics

124-Trinnethylbehzene

12-Dichlorpethene (cis)

Chloroform

Methylene chloride

Tetrachloroethene Triehloroethene

EPC in Indoor Air

(mgm)

213E-06

651 E-05

- 638E-05

164E-05

161 E-03

844E-05

Intake (ADD)

(mgkg-d)

416E-07

127E-05

125E-05

321 E-06

315E-04 l65E-05

RfDi

(mgkg-d)

200E-03

1OOE-02

140E-02

286E-01

771 E-02 1 OOE-02

Hazard

Quotient

208E-04

127E-03

892E-04

112E-05

408E-03 165E-03

Intake (LADD)

(mgkg-d)

) 149E-07

455E-06 bull 446E-06

115E-06

112E-04 590E-06

CSFi

(mgkg-d)

NA

NA

805E-02

165E-03

200E-02

400E-01

Potential

Cancer Risk

NA

NA

359E-07

189E-09

225E-06 236E-06

Total Hazard Index

00081 Total

Cancer Risk 497E-06

Total Blood HI = Total Liver HI =

Total Central Nervous System HI = Total Kidney HI =

Total Fetal HI =

bull 00015 00066 00057 00017 00017

Notes NA = Toxicity values are not available for this endpoint or exposure pathway

Coyne VI Memo Tables_09-08-09xls 982009

AR100300

APPENDIX A

SUBSLAB VAPOR ANALYTICAL DATA

AR100301

Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility Huntington West Virginia

Sample

Consti tuent

Volatile Organics (ugm) 111-Trlchloroethane 1122-Tetrachloroethane 112-Trichloro-122-trifluoroethane 112-Trichloroethane 11-Dichioroethane 11-Dichloroethene 124-Trichloroberi2ene 124-Trimethylbenzene 12-Dibromoethane 12-Dichloroben2ene 12-Dichloroethane 12-Dichloroethene-(cis) -12-Dichloroethene (trans) 12-Dichloropropane 12-Dichlorotetrafluoroethane 135-Trimethylbenzene 13-Butadiene 13-Dichlorobenzene 13-Hexachlorobutadiene 14-Dichlorobenzene 224-trimethVlpentane 2-Chlorotoluene 4-Ethyltoluene Acetone Allyl Chloride Benzene Bromodichloromethane Bromoform Bromomethane Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 13-Dichloropropene (cis) Cyclohexane Dibromochloromethane

Identif ication Sample Date

CAS No

71-55-6 79-34-5 76-13-1 79-00-5 75-34-3 75-35-4 120-82-1 95-63-6 106-93-4 95-50-1 107-06-2 156-59-2 156-60-5 78-87-5 76-14-2 108-67-8 106-99^0 541-73-1 87-68-3 106-46-7 540-84r1 95-49-8

622-96-8 67-64-1 107-05-1 71-43-2 75-27-4 75-252 74-83-9 75-15-0 56-23-5 108-90-7 75-00-3 67-66-3 74-87-3

10061-01-5 110-82-7 124-48-1

lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt

lt lt lt lt lt lt lt lt lt lt lt lt

lt

VP-01 8132009

22 28 31 22 16 16 30 20 31 24 16 16 16 19 28 20 89 24 43 24

1 9 21 20 796 13 13 27 41 16 13 25 18 11 20 83 18 52 34

lt lt lt lt lt lt lt lt lt lt lt

lt lt lt lt lt lt lt lt lt lt lt

lt lt lt lt lt lt lt lt lt

lt lt lt lt

VP-02 8132009

218 2 7 5 307 218 162 159 297

bull 197 307 240 162 369 159 185 280 197 89

240 427 240 187 207 197

1880 125 128 268 414 155 125 252 184 106

5910 83 182 138 341

lt lt lt lt lt lt lt

lt lt lt

lt lt lt lt lt lt lt bull

lt lt lt lt

lt lt lt lt lt lt lt lt lt lt lt lt lt lt

VP-03 8132009

218 275 307 218

bull 162 159 297 197 307 240 162

6030 159 185 280 197 89

240 427 240 187 207 197

1750 125 128 268 414 155 125 252 184 106 195 83 182 138 341

Appx A SG Dataxis Page 1 of 2 982009

AR100302

Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility bull Huntington West Virginia

Consti tuent

Volatile Organics (ugm^) Dichlorodifluoromethane Ethylbenzene Methyl ethyl ketone Methyl Isobutyl ketone Methyl tert-butyl ether Methylene chloride n-Heptane jn-Hexane Styrene Tert-butyl alcohol Tetrachloroethene iToluene 13-Dichloropropene (trans) Triehloroethene Trichlorofluoromethane Vinyl bromide Vinyl chloride Xylene (o) Xylenes (mampp)

Sample Identif ication Sample Date

CAS No

75-71-8 100-41-4 78-93-3 108-10-1

1634-04-4 75-09-2

142-82-5 bull 110-54-3

100-42-5 75-65-0 127-18-4 108-88-3

10061-02-6 79-01-6 75-69-4 593-60-2 75-01-4 95-47-6

179601-23-1

lt lt

lt lt lt lt

lt lt

lt

lt lt lt lt lt

VP01 8132009

20 17 23 16 14 14 16

173 17 12 bull

11200 18 18 91 23 18 10 17 17

lt lt lt lt lt

lt

lt lt

lt lt

lt lt lt lt lt

VP-02 8132009

198 174 118 164 144

1520 164 -183 170 121

149000 151 182

2360 225 175 102 174 174

VP-03 8132009

lt 198 lt 174 lt 118 lt 164 lt 144

1160 lt 164

144 lt 170 ltbull 121

90500 lt 151 lt 182

7820 lt 225 lt 175 lt 102

208 387

Appx A SG Dataxis Page 2 of 2 982009

AR100303

APPENDIX B

CALCULATION OF TRANSPORT FACTORS USED TO ESTIMATE INDOOR AIR CONCENTRATIONS

AR100304

APPENDIX B

Calculation of Transport Factors Used to Estimate Indoor Air Concentrations

This appendix presents the methodology for calculating transport factors that are used to convert subslab

vapor concentrations to concentrations in indoor air 124-Trimethylbenzene 12-dichloroethene (cis)

chloroform methylene chloride tetrachloroethene and triehloroethene were identified as contaminants of

concern (COC) for potential vapor intrusion from subslab vapor associated with the Coyne Textile

Services Facility located in Huntington West Virginia (site) In this appendix the transport factors are

calculated to estimate the concentrations of COC in indoor air of the existing plant building located at the

site ~

Transport Factor for Indoor Air

The concentration of a constituent in indoor air (da) is proportional to the concentration of the constituent

in the subslab vapors immediately beneath the building foundation (ie subslab vapor concentration or

Csubsiab) The following equation is used to calculate da from Csubsiab

^ wja ~ ^subslab X I r

where

Cia = concentration of constituent in indoor air (mgm^) -

Csubsiab^ concentration of constituent in subslab vapors (mgm^) and

TF = transport factor from subslab vapors to indoor air

The transport factor (TF) is an infinite source attenuation coefficient andcan be calculated based on a

model developed by Johnson and Ettinger (1991) t he equation for calculating TF is as follows

(Deff X A B ) ( Q B X L T ) X expKQso i l X Lcrabk)(Dcrack X Acrack)]

exp[ (Qsoi l X Lcrack)(Dcrack X Acrack)] + (Deff X A B ) ( Q B X L T ) + (Deff X AB)(Qsoi l X L j ) X (exp [ (Qso i l X Lcrack)(Dcrack X Acrack)] - 1)

where

Deff = effective diffusion coefficient for vadose zone soil (cm^sec)

AB = area of enclosed space below grade (cm^)

QB = building ventilation rate (cm^sec)

LT = distance from contaminant source to building foundation (cm)

Qsoii = volumetric flow rate of vapors into the building (cm^sec)

Lcrack = foundatlon thickness (cm)

Dcrack = vapor diffusion coefficient through crack (cm^sec) and

Acrack = area of cracks through which vapors can pass (cm^)

AR100305

To solve this equation the USEPAs SG-ADV spreadsheet Version 31 most recently updated in

February 2004 was implemented A combination of site-specific factors and default values from the

Users Guide for Evaluating Subsurface Vapor Intrusion Into Buildings (USEPA 2004) were used as input

values in the model All input values are defined below and presented in Tables B-1-A through B-6-A

bull The initial subslab vapor concentration (Csubsiab) is the maximum detected concentration(in units

of ugm ) of samples VP-01 VP-02 and VP-03 that was presented in Table 3 of the report

bull The depth below grade to the bottom of the enclosed space floor (Lp) is set to 15 cm the default

value provided by USEPA (2004) for a slab-on-grade structure

bull The vapor sampling depth below grade (Lg) is a site-specific value The vapor samples were

collected from immediately beneath the building floor therefore Lj has been set to 15 cm

bull The average soilgroundwater temperature (Ts) is set to 125degC the average value for West

Virginia as estimated frorri Figure 8 of the vapor intrusion users guide (USEPA 2004)

bull The soil type used to estimate vapor permeability is assumed to be sandy loam (SL) The

associated soil properties for a sandy loam soil type are as follows the soil dry bulk density (Pb) is

162 gcm the total porosity (n) is 0387 (cm^-aircm^) and the water-filled porosity (nw) is 0103

(cm -HzOcm )

bull The floor thickness (Lcrack) is set to the USEPA (2004) default value of 10 cm

bull The soil-building pressure differential (AP) is set to the USEPA (2004) default value of 40 gcm-s^

bull The building dimensions are siterspecific based on the existing plant building located at the site

The existing structure is approximately 84000 square feet (Dolphin 2000) therefore the

dimensions are set to 8839 cm (290 feet) length by 8839 cm (290 feet) The USEPA (2004)

default value of 244 cm vyas used for the height

bull Thefloor-wall seam crack width (w) is set to the USEPA (2004)-default value of 01 cm

bull The indoor air exchange rate (ER) is set to 083hour This is the value provided by ASTM (2002)

for commercial and industrial buildings

AR100306

Tables B-1-B through B-6-B present the constituent-specific properties for COC that were used in the TF

calculations Tables B-1-C through B-6-C present the intermediate calculations used to determine the

indoor air attenuation coefficients (ie the transport factors) The shaded boxes in Tables B-1-C through

B-6-C also present the resulting TF values that are applied to the concentrations of COC in subslab

vapor and the estimated indoor air concentrations

References

American Society for Testing and Materials (ASTM 2002) Standard Guide for Risk-Based Corrective Action Applied at Petroleum Release Sites ASTM E-1739-95 (Reapproved 2002)

Johnson PC and RA Ettinger (1991) Heuristic model for predicting the intrusion r-ate of contaminant vapors into buildings Environ Sci Technolpgy 25 1445-1452

Dolphin Environmental LLC (Dolphin 2000) Site Characterization Report Mach 14 2000

United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004

AR100307

APPENDIX B-1-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV Nersion31 0204

Reset to Defaults

ENTER -

Chemical CAS No

(numbers only

no dasties)

95636

ENTER Soil gas

cone

Cg (ngm)

Soil Gas Concentration Data ENTER

Soil gas

OR cone

bull - c bull (PPmv)

197E+02

Chemical

124-Trimethylbenzene

MORE ENTER Depth

below grade to bottom

of enclosed space floor

U bull (cm)

ENTER

Soil gas sampling

depth below grade

U (cm) bull

ENTER

Average soil

temperature Ts

CO

1 15 1 1 5 bull125

ENTER ENTER ENTER Totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hft ha he

(cm) (cm) (cm)

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estirnate OR permeability | soil vapor

permeability) k v bull

(cm)

SL 1 1

MORE ENTER

stratum A SCS

soil type

Lookup Soil Parameters

ENTER stratum A soil dry

bulk density P

(gcm)

ENTER Stratum A soil total porosity

(unitless)

ENTER bull stratum A soil water-filled

porosity

(cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

nlaquo

(unitless)

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gchi-s^)

ENTER Enclosed

space floor

length bull LB

(cm)

ENTER Enclosed

space floor

width WB

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

bull Floor-wall seam crack

width w

(cm)

bullENTER

Indoor air exchange

rate ER

(1h) bull

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bidg OR

Leave blank to caicuij

(Lm)

Appx B-1 124-TMBxls 1 of 3 982009

AR100308

APPENDIX B-1-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of ^ bull law constant law constant vaporization at Normal

Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temperature boiling point point temperature weight

D bull Dbdquo H T R bull AHbdquo TB Tc IVIW

Unit risk Reference

factor cone URF RfC

(cms) (cmls) (atm-mmol) CO (calmol) (degK) (degK) (gmol) bull (ugm)- (mgm)

1 606E-02 1 792E-06 1 bull 614E-C3 1 25 1 9369 1 44230 | 64917 1 12020 1 OOE+00 1 60E-03 1

Appx B-1 124-TMBxls 2 of 3 982009

AR100309

APPENDIX B-1-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

(sec)

Source-building

separation

LT bull

(cm) bull

Stratum A soil

air-filled porosity

Q A

Stratum B soil

air-filled porosity

(cmcm) (cmcm)

Stratum C soil air-filled porosity

(cmcm)

Stratum A effective total fluid

saturation

Se

(cmcm)

Stratum A soil

bullintrinsic permeability

^ (cm)

stratum A Stratum A Floor- soil soli wall BIdg

relative air effective vapor seam Soil bull ventilation permeability permeability perimeter gas rate-

kfg ky Xgrack c o n e - QbuHdinpound

(cm) - (cm) (cm) (ngm) (cms)

946E+08 1 0284 0284 0284 0184 596E-09 0901 537E-09 35357 I 197E+02 | 439E+06 |

Area of enclosed

space below grade

As (cm)

Crack-to-total area ratio

1 bull

(unitless)

Crack depth

below grade

Zcfack

(cm)

Enthalpy of vaporization at

ave soil temperature

AHvjs

(calmol) bull

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law constant at

ave soil bull temperature

bull HTS

(unitless)

Vapor bull viscosity at

ave soil temperature

HTS

(gcm-s)

Stratum A

effective diffusion

coefficient

D (cms)

Stratum-B

effective diffusion coefficient

DB (cms)

Stratum C effective diffusion

coefficient

D-c (cms)

Total - overall effective diffusion

coefficient

D ^ (cms)

Diffusion path

length

L-

(cm)

I 787E+07 I 449E-05 | 15 | 11661 260E-03 111E-01 176E-04 I 612E-03 j OOOE+00 | OOOE+00 | 612E-03 j

bull Convection path

length

Lp

(cm)

Source vapor cone

^source

(ngm)

Crack radius

Tcfack

(cm)

Average vapor

flow rate into bIdg

Qsoii

(cms)

Crack effective diffusion

coefficient pcrack

(cms)

Area of CTack

Acack

(cm)

Exponent of equivalent foundation

Peclet number

exp(Pe)

(unitless)

bull bull - bull bull bull bull

1 15 1 197E+02 1 010 1 474E+01 612E-03 bull 354E-t-03 1 336E+09

Infinite source Indoor

~ attenuation coefficient

a

(unitless)

108E-05

Infinite source

btJbldgjJSv-L ^Ppncji3i-

virhpbiiilding bullbull ^lHltti^m)ilg

213E-03

Unit risk

factor

URF

(ngm)-

Reference cone

RfC (mgm)

NA 60E-03 1

I END

Appx B-1 124-TMBxls 3 of 3 982009

AR100310

APPENDIX B-2-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV Nersion31 020^

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

156592

Soil Gas Concentration Data ENTER

Soil gas

cone OR c

(ngm) bull

ENTER Soil bull-gas

cone

c (ppmv)

603E+03 1

Chemical

cis-12-Dichloroethylene

MORE ENTER Depth

below grade to bottom

of enclosed space floor

LF

(cm)

ENTER

Soil gas sampling

depth below grade

U (cm)

ENTER

Average soil

temperature bull Ts

(degC)

1 15 1 bull 15 125

ENTER ENTER ENTER Totalsmust add ijp tb value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hA hB he

bull (cm) (cm) (cm)

15 1 1

ENTER Soil

straturh A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estimate OR permeability | soil vapor

permeability) kv

(cm)

SL 1 |

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

P (gcm)

ENTER Stratum A soil total porosity

bull n

(unitless)

ENTER Stratum A

soil water-filled porosity

(cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

ENTER Stratum B

soil water-filled porosity

ENTER Stratum C

SCS soil type

(unitless) (cmcm)

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure differential

AP

(gcm-s)

ENTER Enclosed bull

space floor

length

LB (cm)

ENTER Enclosed

space floor

width WB

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER

Average vapor flow rate into bIdg

OR Leave blank to calculi

Qsoil

(Lm)

Appx B-2 cis-12-DCExls 1 of 3 982009

AR100311

APPENDIX B-2-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Diffusivity in air

Da

(cms)

Diffusivity in water

Dw (cms)

Henrys law constant at reference temperature

H

(atm-mmoi)

Henrys law constant

reference temperature

bull T R

CC)

Enthalpy of vaporization at

the normal boiling point

AHbdquob

(calmol)

Normal boiling point

TB

(degK)

Critical temperature

Tc (degK)

Molecular weight

MW

(gmol)

Unit risk

factor URF

(ngm)

Reference cone

RfC (mgm)

1 736E-02 1 113E-05 1 407E-03 j 1 25 1 bull 7192 1 33365 1 54400 1 9694 1 OOE+00 j 35E-02 1

Appx B-2 cis-12-DCExls 2 of 3 982009

AR100312

APPENDIX B-2-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

stratum A Stratum B Stratum C Source- soil soil soil

Exposure building air-filled air-filled air-filled

duration separation porosity porosity porosity

T LT ea e^ bull e= (sec) (cm) (cmcm) (cmcm) (cmcm)

I 946E+08n^

Stratum A Stratum A Stratum A Stratum A Floor-effective soil soil soil wall total fluid intrinsic relative air effective vapor seam

saturation permeability permeability permeability perimeter

Ste kj krg ky Acrack

(cmcm) (cm) (cm) (cm) (cm)

Soil gas

cone (ngm)

I 0284 I 0284~ 0284 0184 I 596E-09 | 090T 537E-09 35357 603E+03

BIdg ventilation

rate

JbulldinE

(cms)

439E+06

Area of enclosed

space below grade

AB

(cm)

Crack-to-total

area ratio

n (unitless)

Crack depth below grade

Zltiack (cm)

Erithalpy of vaporization at

ave soil temperature

AHvTs (calmol)

Henryslaw constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law constant at

ave soil temperature

HTS

(unitless) bull

Vapor viscosity at

ave soil bull temperature

HTS

bull (gcm-s)

Stratum A

effective bull diffusion

coefficient

D^A-(cms)

Stratum B

effective bull diffusion

coefficient

D=B

(cms)

Stratum C

effective diffusion bull

coefficient

D=e (cms)

Total overall

effective diffusion

coefficient

DT

(cms)

Diffusion path

length

Ld

(cm)

I 787E+07 I bull449E-05 | 15 bull7709 230E-03 982E-02 176E-04 | 743E-03 | OOOE+00 | OOOE+00 | 743E-03 |

bull bull bull -

Convecfion path -bull

length

Lp (cm)

Source vapor cone

-source

(Mgm)

Crack radius

fcrack

(cm)

Average vapor

flow rate into bIdg

Qaoil bull

(cms)

Crack effective diffusion

coefficient pcack

(cms)

Area of crack

crack

(cm)-

Exponent of equivalent foundation

Peclet number

exp(Pef)

(unitless)

bull

1 15 -1 603E+03 1 010 1 474E+01 743E-03 354E+03 1 697E+07

Infinite source Indoor

attenuation coefficient

poundbullbullbull C t

pound(unitless)

bullsiilaquogt j ii08E-05

Infinite [ source

bIdg cone

Cbujidjng

(pgm)

651 E-02 iKrt

Unit risk

factor

URF

(ngm)-

Reference cone

RfC

(mgm)

NA 35E-02 1

I END I

Appx B-2 cis-12-DCExls 3o f3 982009

AR100313

APPENDIX B-3-A DATA ENTRY SHEET

Coyne Texti le Services - Hunt ington West Virginia

SG-ADV Version 31 0204

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

67663

Soil Gas Concentration Data ENTER ENTER

Soil Soil gas gas

cone OR cone c C

(^gm) (ppmv)

591 E+03

bull

Chemical

Chloroform

MORE ENTER Depth

below grade tb bottom

of enclosed space floor

bull LF

(cm)

ENTER

Soil gas sampling depth

below grade

(cm)

ENTER

Average soil

temperature-Ts

CO bull

1 15 1 15 1 125

ENTER ENTER ENTER Totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

IIA hs he (cm) (cm) (cm)

1 5 bull 1 1

ENTER ENTER Soil - bull

stratum A User-defined SCS stratum A

soil type bull soil vapor (used to estimate OR permeability

soil vapor k

bull permeability) (cm) 1

SL 1 1 bull

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A soil dry

bulk density

Pb (gcm)

ENTER Stratum A soil total porosity

nV (unitless)

ENTER Stratum A

-soilwater-filled bullporosity

Sraquo (cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

(unitless)

ENTER Stratum B

soil water-filled porosity

bull ebdquo=

(cmcm) bull

ENTER Straturri C

SCS bull soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

- c rack

(cm)

ENTER

Soil-bldg pressure

differential AP^

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor

width bull W B

(cm)

ENTER

Enclosed space

height HB

(cm)

ENTER

bull Floor-wall^ seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bidg OR

Leave blank to calculi

Qsoil bull

(Lm)

I -I

Appx B-3 Chloroformxls 1 of 3 982009

AR100314

APPENDIX B-3-B CHEMICALPROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Diffusivity in air

D (cms)

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffijsivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature

Dbdquo H TR A H bdquo TB Tc

(cm s) (atm-m mol) ro (calmol) (degK) (degK)

Molecular weight

MW

(gmol)

Unit risk

factor URF

(ngm)-

Reference cone

RfC

(mgm)

104E-01 100E-05 I 366E-03 25 6988 33432 53640 11938 I 23E-05 | OOE+00

Appx B-3 Chloroformxls 2 of 3 982009

AR100315

APPENDIX B-3-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure

duration

(sec)

Source-

building

separation

LT

(cm)

Stratum A

soil

air-filled

porosity

Sa

( cm cm )

Stratum B

soil

air-filled

porosity

( cm cm )

Stratum C

soil

air-filled

porosity

( c m c m )

Stratum A

effective

total fluid

saturation

( c m c m )

Stratum A

soil

intrinsic

penmeability

k

(cm )

Stratum A

- soil

relative air

permeabil i ty

(cm )

Stratum A

soil

effective vapor

permeability

kv

(cm )

Floor-

wall

seam

perimeter

gtcrack

(cm)

Soil gas

cone

(ngm)

BIdg

venfilation

rate

^buildlriE

(cms)

I 9 4 6 E + 0 8 ~ T I 0284 T 596E-09 I 0-901 I 537E-09 | 35357 | 591 E+03 j 439E+06 | 1 0 284 0284 0184

Area of

enclosed

space

below

grade

A B

( c m )

Crack-

to-total

area

ratio

n

(unitless)

Crack

depth

bull below

grade

^crack

(cm)

Enthalpy of

vaporization at

ave soil

temperature

AHTs bull

(calmol)

Henry s law

constant at

ave soil

temperature

HTS

(a tm-m mol j

Henrys law

constant at

ave soil

bull temperature

HTS

(unitless) bull

Vapor

viscosity at

ave soil-

temperature

^HTS

(gcm-s)

Stratum

A

effective

diffusion

coefficient

(cm s)

Stratum

B

effective

difftjsion

coefficient

D B

(cms) bull

S t ra tum

C

effective

diffusion

coefficient

Dc

(cm s)

Total

overall

effective

bull diffusion

coefficient

D T

(cm s)

Diffi jsion

path

length

Ld

(cm)

I 787E+07 I 449E-05 j - bull 15 7528 210E-03 896E-02 176E-04 I 105E-02 | OOOE+00 | OOOE+00 | 105E-02

Convection

path length

Lp

(cm)

Source

vapor

cone -

^source

- (ngm)

Crack

radius

Tcrack

(cm)

Average

vapor

flow rate

into bidg

Qsoil

(cms)

Crack

effective

diffusion

coefficient Qcrack

bull (cms)

Area of crack

Acrack

(cm)

Exponent of

equivalent

foundation

Peclet number

exp(Pe)

(unitless)

V bull bull

1 15 1 591 E+03 1 010 1 474E+01 105E-02 354E+03 1 355E+05

Infinite

source

indoor

attenuation

coefficient

d

(unitless)

bull 108E-05

Infinite

source

bIdg

cone

^ b u i l d i n g

i (^gm)

bull bull

i 638E-02 -

Unit

risk bull factor

URF

(ngmY

Reference

cone

RfC

(mgm)

~ 23E-05 NA 1

I END

Appx B-3 Chloroform xls 3 of 3 982009

AR100316

APPENDIX B-4-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ersion 31-020^

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

nodashes)

bull 75092

ENTER Soil gas

cone

c (ngm)

Soil Gas Concentration Data ENTER

Soil gas bull

OR cone

bull C

(ppmv)

152E+03

bull bull

Chemical

Methylene chloride

MORE

MORE 4gt

ENTER Depth

below grade to bottom

of enclosed space floor

LF -

(cm)

ENTER

Soil gas sampling depth

below grade

bull U

(cm)

ENTER

Average soil

temperature

Ts bull CC)

bull bull bull bull

1 15 1 15 125

ENTER Totals

Thickness of soil

stratum A h

(cm)

ENTER ENTER must add up to value of Ls (cell F24

Thickness Thickness of soil of soil

stratum B stratum C (Enter value or 0) (Enter value or 0)

he he bull

(cm) bull (cm) -

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(usedto estimate OR perrrieability | soil vapor

permeability)

k bull

(cm)

SL 1 bull 1

ENTER Stratum A

SCS soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

Pb (gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Stratum A

soil water-filled porosity

9w (cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

Pb^

(gcm)

ENTER Stratum B soil total porosity

n^

(unitless)

ENTER Stratum B

soil water-filled porosity

(crhcm)

ENTER Stratum C

SCS soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE 4gt

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

bull Soil-bldg pressure

differential AP^

(gcm-s)

ENTER Enclosed

space floor

length LB

(cm)

ENTER Enclosed

space floor

width bull W B

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width

w

(cm)

ENTER

Indoor air exchange

rate

ER (1h)

ENTER Average vapor

flow rate into bidg OR

Leave blank to calculc

Qsoil

(Lm)

10 40 8839 8839 244 01 083

Appx B-4 MCxIs 1 of 3 982009

AR100317

Diffijsivity in air

D

APPENDIX B-4-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffusivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature

Pw H TR AHt TB TC

Molecular weight

MW

Unit risk

factor URF

Reference cone

RfC

(cms) (cms) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) bull (ngm)- (mgm)

bull bull

1 101E-01 1 117E-05 1 218E-03 1 25 | 6706 1 31300 1 51000 1 8493 1 47E-07 1 30E+00 1

Appx B-4 MCxIs 2 of 3 982009

AR100318

APPENDIX B-4-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

T

(sec)

Source- -building

separation

LT

(cm)

Stratum A soil

air-filled porosity

e a bull

(cmcm)

Stratum B soil

bullair-filled porosity bull

ea^ (cmcm)

Stratum C soil

air-filled porosity

ea= (cmcmj

Stratum A effective total fluid

saturation

Sc bull

(cmcm)

Stratum A soil

intrinsic pemneability

ki (cm)

Stratum A soil

relative air permeability

^ ^ g

(cm)

stratumA bull soil effective vapor permeability

K (cm)

Floor-wall

seam perimeter

Xcrack

(cm)

Soil gas

cone (ngm)

BIdg ventilation

rate

Qbuildinc

(cms)

1 946E+08

Area of -enclosed

space below

bull grade

AB

(cm)

1

Crack-to-total

area rafio

Tl

(unitless)

0284 1

Crack depth below grade

Zcrack

(cm)

0284 1

bull Enthalpy of vaporization at

ave soil temperature

AHTs (calmol)

0284

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

0184

Henrys law constant at ave soil

temperature

HTS

bull (unitless)

1 596E-09

Vapor viscosity at

ave soil temperature

Mrs (gcm-s)

0901

Stratum A

effective diffusion

coefficient

D (cms)

537E-09

Stratum B

effective diffusion

coefficient

D-B (cms)

35357 1

Stratum C -

effective diffusion

coefficient

D-c ^ (cms)

152E+03

Total bull overall

bull effective diffusion

coefficient

D ^

(cms)

440E+06 1

Difftjsion path

length

Ld (cm)

1 787E+07

Convection path

length

Lp (cm)

4 49E-05

Source vapor cone

Csource

(ngm)

15 1

Crack radius

Tcrack

(cm)

7007 bull 1

Average vapor

flow rate intobldg

Qsoil

(cms)

130E-03

Crack effective diffusion

coefficient pcrack

(cms)-

555E-02

bull ^

Area of crack

Acrack

(cm) bull

1 176E-04

Exponent of equivalent foundation

Peclet number

exp(Pe)

(unitless) bull

bull bull

1 15

1 END

152E+03 010 1 474E+01 1 102E-02 354E+03 1 519E+05

102E-02

Infinite source

indoor ^attenuation coefficient

bull a

(unitless)

aiii08E-05

0 OOE+00

bull

Infinite bull source

bIdg ^ cone

^bu i l d i ng

(MQm)

164E-02

OOOE+00 1

Unit risk

factor

URF

(ngm)-

47E-07 1

102E-02 j

Reference cone

RfC

(mgm)

30E+00 j

1 1

Appx B-4 MCxIs 3 of 3 982009

AR100319

APPENDIX B-5-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ^erslon 31 0204

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

127184

Soil Gas Concentration Data ENTER ^ ENTER

Soil -Soi l bull gas gas

cone OR cone Cg C bull

(tgm) (ppmv)

149E+05 1

Chemical

bull Tetrachlbroethylene

MORE 4

ENTER Depth

below grade to bottom

ofenclosecJ space floor

LF

(cm)

ENTER

Soil gas bull sampling

depth below grade

u bull (cm)

ENTER

Average bullsoil

temperature - Ts

ro 1 1 5 1 15 1 125 bull

ENTER ENTER ENTER totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hft bull he bull he

(cm) (cm) (cm)

bull 1 5 1 - 1

ENTER ENTER Soil

stratum A User^defined bull SCS bull stratum A soil type soil vapor

(used to estimate OR perrrieability soil vapor K bull

permeability) (cm) 1

SL 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

Pb

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Sitratum A

soil water-filled bull porosity

(cmcm)

ENTER Stratum B

SCS soiltype

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

Pb^

(gcm)

ENTER Stratum B soil total porosity

Ajnitless^

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS soil type

LookupSoil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

VS

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor width

W B

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width

w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

ENTER Average vapor

flow rate into bidg OR

Leave blank to calcul

bull Qsoil

(Lm)

10 40 8839 8839 244 01 083

Appx B-5 PCExIS 1 of 3 982009

AR100320

APPENDIX B-5-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal Unit

Diffusivity Diffusivity at reference reference the riormal boiling Critical Molecular risk Reference in air in water temperature temperature boiling point point teriiperature weight factor cone

Da Dbdquo H TR AHb TB Tc MW URF RfC

(cms) (cnis) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) (^gm)- (mgm)

1 720E-02 1 820E-06 1 184E-02 1 25 1 8288 1 39440 1 62020 1 16583 1 59E-06 1 60E-01 1

J

AppxB-5PCExls 2 of 3 - 982009

AR100321

APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

T

(sec)

Source-building

separation

LT

bull (cm)

Stratum A soil

air-filled porosity

Oa (cmcm)

Stratum B - soil air-filled porosity

ea (cmcm)

Stratum C soil

air-filled porosity

ea= - (cmcm)

Stratum A effective total fluid

saturation

sbdquo (cmcm)

Stratum A soil

intrinsic permeability

ki (cm)

Stratum A soil

relative air permeability

- ^ g

(cm)

Stratum A soil

effective vapor permeability

kv (cm)

Floor-wall

seam perimeter

^crack

(cm)

Soil gas

cone

(ngm)

BIdg venfilation

rate

Qbuildins

bull (cms)

bull bull

1 946E+08

Area of enclosed

space below grade

AB

(cm)

1

bullCrack-to-total

area ratio

1 (unitless)

0284 1

Crack bull depth below grade

Zcrack

(cm) -

0284 1

Enthalpy of vaporization at bull

ave soil temperature

bull A H V TS

(calmol)

0284

Henrys law constant at

ave soil temperature

HTS (atm-mmol)

0184

-Henrys law constant at

ave soil temperature

HTS

(unitless)

1 596E-09

Vapor viscosity at

ave soil temperature

HTS

(gcm-s)

0901

Stratum A

effective diffusion

coefficient bull D = bull

(cms)

537E-09

Stratum B

effective diffusion

coefficient

D--B (cms)

35357 1

Stratum C

effective diffusion bull

coefficient

D-c (crris)

149E+05

Total overall

effective bulldiffusion coefficient

DT

(cms)

440E+06 1

Difftjsion path

length

U (cm)

1 787E+07

Convection path

length

bull Lp

(cm)

4 49E-05

Source vapor cone

^source

(ngm)

15 1

Crack radius

Tcrack

(cm)

9528 1

Average vapor

flow rate intobldg

Qsoil (cms)

908E-03

Crack effective diffusion

coefficient pcrack

bull ( c m s ) bull

387E-01

Area of crack

Abdquoack (cm)

1 176E-04

Exponent of equivalent foundafion

Peclet number

exp(Pe)

(unitless)

bull

1 15-

1 END

149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08

727E-03

Infinite source indoor

attenuation coefficient

a

(unitless)

108E-05

OOOE+00

Infinite source

bIdg cone

Cburldtng

(Mgm)

161 E+00

OOOE+00 1

Unit risk

factor

URF

(ugm)-

59E-06 1

727E-03

Reference cone

RfC (mgm)

60E-01

1 1

Appx B-5 PCExls 3 of 3 982009

AR100322

APPENDIX B-6-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ersion31 0204

Reset to Defaults

t

Soil Gas Concentration Data ENTER

Chemical CAS No

(numbers only

no dashes)

79016

ENTER ENTER Soil Soil gas gas

cone OR cone C C -

bull (ngm) (ppmv)

782E+03

Chemical

Trichloroethylene

MORE ENTER Depth

below grade to bottom-

of enclosed space floor

LF

(cm)

ENTER

Soil gas sarnpling

depth below grade

U (cm)

ENTER

Average soil

temperature Ts

(degC)

1 15 1 15 t 125

ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e

(cm) (cm) (cm)

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estimate OR permeability soil vapor

permeability)

k (cm)

bull S L 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil bull-Parameters

ENTER Stratum A

soil dry bulk density

P b -

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Stratum A bull

soilwaterrfilled porosity

(cmcm) bull

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

bull P ^ (gcm)

ENTER Stratum B soil total

porosity

nlaquo

(unitless) -

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS bull soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor

width W B

(cm)

ENTER

Enclosed space height

H B bull

( c m ) bull

ENTER

Floor-wall seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bIdg OR

Leave blank to calculc

Qsoil

(Lm) -

Appx B-6 TCExIs 1 of 3 982009

A

AR100323

APPENDIX B-6-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight

Da Dbdquo H TR AH^b TB TC MW

Unit risk Reference

factor cone URF RfC

(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)

1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1

Appx B-6 TCExIs 2 of 3 982009

AR100324

APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

(sec)

Source-building

separation LT

(cm)

Stratum A soil

air-filled porosity

bull ea (cmcm)

Stratum B Soil

air-fllled porosity

e^ bull (cmcm)

Stratum C soil

air-filled porosity

(cmcm)

StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air

saturation permeability permeability

S|e k krg (cmcm) (cm) (cm)

Stratum A Floor-soil wall BIdg

effective vapor seam Soil ventilafion permeability perimeter gas rate

k^ bull Xack c o n e Qbuildins

(cm) (cm) (ngm) (cms)

946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |

Area of enclosed

space below grade

AB

(cm)

Ciack- to-total

area ratio

1 (unitless)

Crack depth below grade

Zcrack

(cm)

Enthalpy of vaporization at

ave soil temperature

A H J S

(calmol)

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law bull constant at

ave soil temperature

HTS

(unitless)

Vapor viscosity at

ave soil temperature

|JTS

(gcm^s)

Stratum A

effective diffusion

coefficient

(cms)

Stratum B

effective -diffusion

coefficient

D=B (cms)

Stratum ^ C effective diffusion

coefficient

D=c (cms)

Total overall

effective diffusion

coefficient

DT

(cms)

I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03

Diffusion path

length

Li (cm) bull

Convection bull path

length

Lp

(cm)

Source vapor cone bull

^source

(ngm)

Crack radius

rcrack

(cm)

Average vapor

- flow rate intobldg

Qsoil

(cms)

Crack effective diffusion

bull coefficient Qcrack

(cms)

Area of crack

^crack

(cm)

Exponent of equivalent foundation

Peclet bull number

exp(Pe)

(unitless)

bull bull

1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07

Infinite source Indoor

attenuation coefficient

a

(unitless)

108E-05

Infinite source

bIdg concgt

^building

(ngm)

844E-02

Unit risk

factor

URF

(ngm)-

Reference cone

RfC

(mgm)

1 1E-04 1 40E-02 1

END

Appx B-6 TCExIs 3 of 3 982009

AR100325

Office of Waste Management 1356 Hansford Street

Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256

West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director

ORDER

ISSUED UNDER THE

HAZARDOUS WASTE MANAGEMENT ACT

CHAPTER 22 ARTICLE 18

OF THE WEST VIRGINIA CODE^ AS AMENDED

y Order Number HW-011-80

To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704

ATTEMTION MREDARMON

Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull

AR100326

ViWJ011-laquo9 PageNunil)er2

BASIS FOR ORDER

As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following

A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^

B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator

C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities

0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94

^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement

P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following

1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater

2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was

^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment

CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable

CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order

AR100327

H W - 0 1 1 - 9 9 Page Number 3

REQUIREMENTS OF ORDER

Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows

1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^

2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore

remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling

GENERAL PROVaiONS

1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order

2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order

3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order

Effective Date

Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief

Wt T 1 V Oflice of Waste Management

AR100328

^ ^ S I S

^wmmmmamn

AR100329

Page 17: SDMS DocID 2121999 · International Enterprises Corp. building (Coyne Building), which is located at 1111 Vernon Street, Westmoreland District, Wayne County, West Virginia. The following

TABLE 1 SUBSLAB VAPOR SAMPLES INCLUDED IN THE RISK ASSESSMENT

Coyne text i le Services Facility - Huntington West Virginia

Medium

Subslab Vapor

Sample Identification

bull VP-01

VP-02

VP-03

Sample Date

8132009

8132009

8132009

Coyne VIMemo Tables_09-08-09xls 982009

AR100294

TABLE 2 IDENTIFICATION OF CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR

Coyne Textile Services Facility - Huntington West Virginia

mdash

Const i tuent

Volati le Organics

111-Trichlor6ethane

1122-Tetrachloroethane

112-Trichloro-122-trifluoroethane

112-Trichloroethane

11-Dichloroethane

11-Dichloroethene

124-Trichlorobenzene

124-Trimethylbenzene

12-Dibromoethane

12-Dichlor6benzene

12-Dichloroethane

12-Dichloroethene (cis)

12-pichloroethene (trans)

12-Dichloropropane

12-Dichlorotetraf1uoroethane

135-Trimethylbenzene

13-Butadiene

13-Dichlorobenzene

13-Hexachlorobutadiene

14-Dichlorpbenzene

224-trimethylpentane

2-Chlorotoluene

4-Ethyltoluene

Acetone

Allyl Chloride

Benzene

Bromodichloromethane

Bromoform

Bromomethane

Carbon disulfide bull

Carbon tetrachloride

ChJorobenzene

Chloroethane

Frequency of Detection

0 3

0 3

0 3

bull 0 3

0 3

0 3

0 3

1 3

0 3 bull

0 3

b 3 bull

2 3

0 3

bull 0 3

0 3

0 3

0 3 bull

0 3

0 3

0 3

0 3

0 3

0 17

3 3

0 3

P 3

- 0 3

0 3

0 3

0 3

0 3

0 3

0 3

Min imum Detected

Concentrat ion

(ugm^)

ND

ND

ND

ND

ND

- ND

N D

197

ND bull

ND

ND

369

ND

bull~ ND

ND

ND

ND

ND

ND

bull ND

ND

ND

ND

796

ND

ND

ND-

ND

ND

ND

ND

ND

ND

Maximum

Detected Concentrat ion

(ugm3)

ND

ND

ND

ND

ND

ND

ND

197

ND

ND

ND

mdash 6030

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

1880

ND-

ND

ND

ND

ND

ND

ND

ND

ND

Sample wi th Maximum Detect

ND

ND

ND

ND

ND

ND

- ND

VP-03 -

ND

ND

ND

VP-03

ND

bullND

ND

ND

ND

ND

ND

ND

ND

ND

ND

VP-02

ND

ND bull

ND

ND

ND bull

bull ND

ND

ND

ND

Min imum Detection

Limit (ugm3)

22

28

31

22

16

16

30

20

31

24

16

bull 16

16

19

28

20

89

24 bull

43

24

bull 19

2 1

20

--^ 13

13

27

41

16

13

25

18

11

Maximum Detection

Limit (ugm3)

218

275

307

218

162

159

297

197

307

240

162

- 16

159

185

280

197

89

240

427

240

187

207

197

--125

128

268

414

155

125

252

184

106

Vapor Intrusion Corhparison

V a l u e

(ugm)

22000

042

300000

15

bull 5000

2000

2000

60

011

2000

094

350

700

40

NA

60

0087

1100

11

8000

NA

NA

NA

3500

NA

31

14

22

50

7000

16

bull 600

100000

Chemical of Concern

No

No

No

No

No

No

No

YES

No

No

No

YES

No

No

No

N o bull

bullNo

No

No

No

No

No

No

N o

No

No

No

N o

No

No

No

No

No

Comment

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent notdetected

fflaximCimTdeteetlSffieedsTcomDarisonivalues

Constituent not detected

Constituent not detected

Constituent not detected

Maximum detect exceeds comparison value

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Maximum detect below comparison value

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detectedl

Constituent not detected

Constituent not detected

CoyneVI Memo Tables_09-08-09xls 982009

AR100295

TABLE 2

IDENTIFICATION OF CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR

Coyne Textile Services Facility - Huntington West Virginia

Const i tuent

Volati le Organics

Chloroform -

Chloromethane

13-Dichloropropene (cis)

Cyclohexarie^

Dibrcimochloromethane

DichlonDdifluoromethane

Ethylbenzene

Methyl ethyl ketone

Methyl isobutyl ketone

Methyl tert-butyl ether

Methylene chloride

n-Heptane

n-Hexane

Styrene

Tert-butyl alcohol

Tetrachloroethene

Toluene

13-Dichloropropene(trans)

Triehloroethene

Trichlorofluoromethane

Vinyl bromide

Vinyl chloride

Xylene (0)

Xylenes (mampp)

Frequency of Detection

1 3

0 3

0 3

1 3

0 3

0 3

0 -3

1 3

0 3

0 3

2 3

0 3

3 3

0 3

0 3

3 3

1 3

- 0 3

3 3

P 3

0 3

0 3

1 3

1 3

Min imum Detected

Concentrat ion

(ugm)

5910

ND

ND

52

ND

ND

ND

23

ND

ND

1160

ND

1 4 4

ND

ND

11200

18

ND

91

ND

ND

ND

208

387

Maximuri i Detected

Concentrat ion (ugmS)

bull

5910

ND

ND

52

bull ND

ND

ND

23

ND

ND

1520

ND

183

ND

ND

149000

18

ND

7820

ND

bullND

ND

208

387

Sample vyith Max imum Detect

VP-02

ND

ND

VP-01

bull ND

ND

ND

VP-01

ND

ND

VP-02

ND

VP-02

ND

ND

VP-02

VP-01

ND

VP-03

ND

ND

ND

VP-03

VP-03

Min imum Detection

Limit (ugm3)

20

83

18

138

34

bull 20

17

118

16

14

14

16

- -17

12

--151

18

--23

18

10

1 7 bull

1 7 bull

Maximum Detection

Limit (ugm3)

195

83

182

138

341

198

174

118

164

144

14

164

170

121 -

--151

182

225

175

102

bull 174

174

Vapor Intrusion Compar ison

V a l u e

(ugm)

11

24

NA

2000

1

2000

22

10000

800

30000

52

NA

2000

10000

NA

81

4000

NA

022

7000

NA

28

70000

70000

Chemical o f Concern

YES

No

No

No

No bull

No

No bull

No bull=

No

No

YES

No

No

No

No

YES

No

No

YES

N o

No

No

No

No

Comment

Maximum detect exceeds comparison value

Constituent not detected

Constituent not detected

Maximum detect below comparison value

Constituent not detected

Constituent not detected

Constituent not detected

Maximum detect below comparison value

Constituent not detected

Constituent not detected

Maximum detect exceeds comparison value

Constituent not detected bull

Maximum detect below comparison value

Constituent not detected

Constituent not detected

Maximum detect exceeds comparison value

Maximum detect below comparison value

Constituent not detected

Maximum detect exceeds comparison value

Constituent not detected

Constituent not detected

Constituent not detected bull

Maximum detect below comparison value

Maximum detect below comparison value

Notes

ND - Not Detected

NA - Not Available

- - Constituent detected in every sample detection limit not presented

Values in bold indicate detection limit exceeds comparison values

Target shallow soil gas comparison values corresponding to indoor air concentrations where the soil gas to indoor air attenuation factor = 01 and the target cancer risk is set to ip (presented in Table 2c of USEPA 2002a)

Comparison value for cyclohexane is based on the comparison value for hexane

Coyne VI Memo Tables_09-08-09xls 982009

AR100296

TABLES

EXPOSURE POINT CONCENTRATIONS FOR CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR

Coyne Textile Services Facility - Huntington West Virginia

Chemical of Concern

VolatileOrganics

i24-Trimethylbenzene

12-Dichloroethene (cis)

Chloroform

Methylene chloride

Tetrachloroethene Triehloroethene

Subslab Vapor Source

Concentration (mgm^)

0197

603

591

152

149 782

Transport

Factor^ (unitless)

108E-05

108E-05

108E-05

108E-05

108E-05 108E-05

EPC in

Indoor Air (mgm^)

213E-06

651 E-05

638E-05

164E-05

161E-03 844E-05

Notes

^ Subslab vapor source concentration is based on the maximum detected concentration of samples

VP-01-02 and-03 (see Table 2) -

^ Details of the transport factor calculations are presented in Appendix B

^ Exposure Point Concentration (EPC) in inidoor air is calculated as the subslab vapor concentration TF

Coyne VI Memo Tables_09-08-09xls 982009

AR100297

TABLE 4

FACTORS USED IN DOSE CALCULATIONS INHALATION OF VOLATILE EMISSIONS

Coyne Textile Services Facility - Huntington West Virginia

Symbol

CA

IRA

ET

EF

ED-

BW

AT

Exposure Factor

Constituent Concentration in Air

Inhalation Rate

Exposure Time

Exposure Frequency

Exposure Duration

Body Weight

Averaging Time

Indoor Worker

Constituent-Specific See Table 3

25 m hour

8 hrday

250 daysyear

25 years

bull 70 kg

9125 days (NC)

25550 days (C)

Total Dose = CA x IR^ x ET x EF x ED x 1BW x 1AT

(NC) - Non-carcinogenic Averaging Time

(C) - Carcinogenic Averaging Time

Coyne VI Memo Tables_09-08-09xls 982009

AR100298

TABLES TOXICITY VALUES FOR CHEMICALS OF CONCERN

Coyne Textile Services Facility - Huntington West Virginia

Chemical of Concern

Volatile Organics

124-Trimethylbenzene

12-Dichloroethene (cis)

Chloroform

Methylene chloride

tetrachloroethene

Triehloroethene

Target Organ Critical Effect

blood

bullblood

liver

liver

liver CMS

liver kidney fetus CNS

Chroniclnhalation Reference Dose

(mgkg-day)

200E-03 P

1 OOE-02 R

140E-02 E

286E-01 M

771 E-02 M

1OOE-02 E

Inhalation Cancer ^ Slope Factor

(mgkg-day)^

NA

NA

805E-02 1

165E-03 1

200E-02 0

400E-01 E

(I) - Integrated Risk Information System (IRIS USEPA 2009)

(P) - Provisional Peer-Reviewed Toxicity Value (PPRTV) as presented in USEPA Regional Screening Tables (ORNL 2009)

(R) - Calculated assuming route-to-route extrapolation as per WVDEP

(E)-Provisional value from the National Center for Environmental Assessment (as per WVDEP)

(M)-Chronic Minimal Risk Level (MRL ATSDR 2009)

(0) - Value cited by USEPA Region 3 attributed to other sources (as per WVDEP)

Coyne VI Memo Tables_09-08-09xls 982009

AR100299

TABLE 6

NONCANCER HAZARD INDEX AND POTENTIAL CANCER RISK FOR AN INDOOR WORKER

Coyne Textile Services Facility - Huntington West Virginia

bull

Constituent

Volatile Organics

124-Trinnethylbehzene

12-Dichlorpethene (cis)

Chloroform

Methylene chloride

Tetrachloroethene Triehloroethene

EPC in Indoor Air

(mgm)

213E-06

651 E-05

- 638E-05

164E-05

161 E-03

844E-05

Intake (ADD)

(mgkg-d)

416E-07

127E-05

125E-05

321 E-06

315E-04 l65E-05

RfDi

(mgkg-d)

200E-03

1OOE-02

140E-02

286E-01

771 E-02 1 OOE-02

Hazard

Quotient

208E-04

127E-03

892E-04

112E-05

408E-03 165E-03

Intake (LADD)

(mgkg-d)

) 149E-07

455E-06 bull 446E-06

115E-06

112E-04 590E-06

CSFi

(mgkg-d)

NA

NA

805E-02

165E-03

200E-02

400E-01

Potential

Cancer Risk

NA

NA

359E-07

189E-09

225E-06 236E-06

Total Hazard Index

00081 Total

Cancer Risk 497E-06

Total Blood HI = Total Liver HI =

Total Central Nervous System HI = Total Kidney HI =

Total Fetal HI =

bull 00015 00066 00057 00017 00017

Notes NA = Toxicity values are not available for this endpoint or exposure pathway

Coyne VI Memo Tables_09-08-09xls 982009

AR100300

APPENDIX A

SUBSLAB VAPOR ANALYTICAL DATA

AR100301

Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility Huntington West Virginia

Sample

Consti tuent

Volatile Organics (ugm) 111-Trlchloroethane 1122-Tetrachloroethane 112-Trichloro-122-trifluoroethane 112-Trichloroethane 11-Dichioroethane 11-Dichloroethene 124-Trichloroberi2ene 124-Trimethylbenzene 12-Dibromoethane 12-Dichloroben2ene 12-Dichloroethane 12-Dichloroethene-(cis) -12-Dichloroethene (trans) 12-Dichloropropane 12-Dichlorotetrafluoroethane 135-Trimethylbenzene 13-Butadiene 13-Dichlorobenzene 13-Hexachlorobutadiene 14-Dichlorobenzene 224-trimethVlpentane 2-Chlorotoluene 4-Ethyltoluene Acetone Allyl Chloride Benzene Bromodichloromethane Bromoform Bromomethane Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 13-Dichloropropene (cis) Cyclohexane Dibromochloromethane

Identif ication Sample Date

CAS No

71-55-6 79-34-5 76-13-1 79-00-5 75-34-3 75-35-4 120-82-1 95-63-6 106-93-4 95-50-1 107-06-2 156-59-2 156-60-5 78-87-5 76-14-2 108-67-8 106-99^0 541-73-1 87-68-3 106-46-7 540-84r1 95-49-8

622-96-8 67-64-1 107-05-1 71-43-2 75-27-4 75-252 74-83-9 75-15-0 56-23-5 108-90-7 75-00-3 67-66-3 74-87-3

10061-01-5 110-82-7 124-48-1

lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt

lt lt lt lt lt lt lt lt lt lt lt lt

lt

VP-01 8132009

22 28 31 22 16 16 30 20 31 24 16 16 16 19 28 20 89 24 43 24

1 9 21 20 796 13 13 27 41 16 13 25 18 11 20 83 18 52 34

lt lt lt lt lt lt lt lt lt lt lt

lt lt lt lt lt lt lt lt lt lt lt

lt lt lt lt lt lt lt lt lt

lt lt lt lt

VP-02 8132009

218 2 7 5 307 218 162 159 297

bull 197 307 240 162 369 159 185 280 197 89

240 427 240 187 207 197

1880 125 128 268 414 155 125 252 184 106

5910 83 182 138 341

lt lt lt lt lt lt lt

lt lt lt

lt lt lt lt lt lt lt bull

lt lt lt lt

lt lt lt lt lt lt lt lt lt lt lt lt lt lt

VP-03 8132009

218 275 307 218

bull 162 159 297 197 307 240 162

6030 159 185 280 197 89

240 427 240 187 207 197

1750 125 128 268 414 155 125 252 184 106 195 83 182 138 341

Appx A SG Dataxis Page 1 of 2 982009

AR100302

Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility bull Huntington West Virginia

Consti tuent

Volatile Organics (ugm^) Dichlorodifluoromethane Ethylbenzene Methyl ethyl ketone Methyl Isobutyl ketone Methyl tert-butyl ether Methylene chloride n-Heptane jn-Hexane Styrene Tert-butyl alcohol Tetrachloroethene iToluene 13-Dichloropropene (trans) Triehloroethene Trichlorofluoromethane Vinyl bromide Vinyl chloride Xylene (o) Xylenes (mampp)

Sample Identif ication Sample Date

CAS No

75-71-8 100-41-4 78-93-3 108-10-1

1634-04-4 75-09-2

142-82-5 bull 110-54-3

100-42-5 75-65-0 127-18-4 108-88-3

10061-02-6 79-01-6 75-69-4 593-60-2 75-01-4 95-47-6

179601-23-1

lt lt

lt lt lt lt

lt lt

lt

lt lt lt lt lt

VP01 8132009

20 17 23 16 14 14 16

173 17 12 bull

11200 18 18 91 23 18 10 17 17

lt lt lt lt lt

lt

lt lt

lt lt

lt lt lt lt lt

VP-02 8132009

198 174 118 164 144

1520 164 -183 170 121

149000 151 182

2360 225 175 102 174 174

VP-03 8132009

lt 198 lt 174 lt 118 lt 164 lt 144

1160 lt 164

144 lt 170 ltbull 121

90500 lt 151 lt 182

7820 lt 225 lt 175 lt 102

208 387

Appx A SG Dataxis Page 2 of 2 982009

AR100303

APPENDIX B

CALCULATION OF TRANSPORT FACTORS USED TO ESTIMATE INDOOR AIR CONCENTRATIONS

AR100304

APPENDIX B

Calculation of Transport Factors Used to Estimate Indoor Air Concentrations

This appendix presents the methodology for calculating transport factors that are used to convert subslab

vapor concentrations to concentrations in indoor air 124-Trimethylbenzene 12-dichloroethene (cis)

chloroform methylene chloride tetrachloroethene and triehloroethene were identified as contaminants of

concern (COC) for potential vapor intrusion from subslab vapor associated with the Coyne Textile

Services Facility located in Huntington West Virginia (site) In this appendix the transport factors are

calculated to estimate the concentrations of COC in indoor air of the existing plant building located at the

site ~

Transport Factor for Indoor Air

The concentration of a constituent in indoor air (da) is proportional to the concentration of the constituent

in the subslab vapors immediately beneath the building foundation (ie subslab vapor concentration or

Csubsiab) The following equation is used to calculate da from Csubsiab

^ wja ~ ^subslab X I r

where

Cia = concentration of constituent in indoor air (mgm^) -

Csubsiab^ concentration of constituent in subslab vapors (mgm^) and

TF = transport factor from subslab vapors to indoor air

The transport factor (TF) is an infinite source attenuation coefficient andcan be calculated based on a

model developed by Johnson and Ettinger (1991) t he equation for calculating TF is as follows

(Deff X A B ) ( Q B X L T ) X expKQso i l X Lcrabk)(Dcrack X Acrack)]

exp[ (Qsoi l X Lcrack)(Dcrack X Acrack)] + (Deff X A B ) ( Q B X L T ) + (Deff X AB)(Qsoi l X L j ) X (exp [ (Qso i l X Lcrack)(Dcrack X Acrack)] - 1)

where

Deff = effective diffusion coefficient for vadose zone soil (cm^sec)

AB = area of enclosed space below grade (cm^)

QB = building ventilation rate (cm^sec)

LT = distance from contaminant source to building foundation (cm)

Qsoii = volumetric flow rate of vapors into the building (cm^sec)

Lcrack = foundatlon thickness (cm)

Dcrack = vapor diffusion coefficient through crack (cm^sec) and

Acrack = area of cracks through which vapors can pass (cm^)

AR100305

To solve this equation the USEPAs SG-ADV spreadsheet Version 31 most recently updated in

February 2004 was implemented A combination of site-specific factors and default values from the

Users Guide for Evaluating Subsurface Vapor Intrusion Into Buildings (USEPA 2004) were used as input

values in the model All input values are defined below and presented in Tables B-1-A through B-6-A

bull The initial subslab vapor concentration (Csubsiab) is the maximum detected concentration(in units

of ugm ) of samples VP-01 VP-02 and VP-03 that was presented in Table 3 of the report

bull The depth below grade to the bottom of the enclosed space floor (Lp) is set to 15 cm the default

value provided by USEPA (2004) for a slab-on-grade structure

bull The vapor sampling depth below grade (Lg) is a site-specific value The vapor samples were

collected from immediately beneath the building floor therefore Lj has been set to 15 cm

bull The average soilgroundwater temperature (Ts) is set to 125degC the average value for West

Virginia as estimated frorri Figure 8 of the vapor intrusion users guide (USEPA 2004)

bull The soil type used to estimate vapor permeability is assumed to be sandy loam (SL) The

associated soil properties for a sandy loam soil type are as follows the soil dry bulk density (Pb) is

162 gcm the total porosity (n) is 0387 (cm^-aircm^) and the water-filled porosity (nw) is 0103

(cm -HzOcm )

bull The floor thickness (Lcrack) is set to the USEPA (2004) default value of 10 cm

bull The soil-building pressure differential (AP) is set to the USEPA (2004) default value of 40 gcm-s^

bull The building dimensions are siterspecific based on the existing plant building located at the site

The existing structure is approximately 84000 square feet (Dolphin 2000) therefore the

dimensions are set to 8839 cm (290 feet) length by 8839 cm (290 feet) The USEPA (2004)

default value of 244 cm vyas used for the height

bull Thefloor-wall seam crack width (w) is set to the USEPA (2004)-default value of 01 cm

bull The indoor air exchange rate (ER) is set to 083hour This is the value provided by ASTM (2002)

for commercial and industrial buildings

AR100306

Tables B-1-B through B-6-B present the constituent-specific properties for COC that were used in the TF

calculations Tables B-1-C through B-6-C present the intermediate calculations used to determine the

indoor air attenuation coefficients (ie the transport factors) The shaded boxes in Tables B-1-C through

B-6-C also present the resulting TF values that are applied to the concentrations of COC in subslab

vapor and the estimated indoor air concentrations

References

American Society for Testing and Materials (ASTM 2002) Standard Guide for Risk-Based Corrective Action Applied at Petroleum Release Sites ASTM E-1739-95 (Reapproved 2002)

Johnson PC and RA Ettinger (1991) Heuristic model for predicting the intrusion r-ate of contaminant vapors into buildings Environ Sci Technolpgy 25 1445-1452

Dolphin Environmental LLC (Dolphin 2000) Site Characterization Report Mach 14 2000

United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004

AR100307

APPENDIX B-1-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV Nersion31 0204

Reset to Defaults

ENTER -

Chemical CAS No

(numbers only

no dasties)

95636

ENTER Soil gas

cone

Cg (ngm)

Soil Gas Concentration Data ENTER

Soil gas

OR cone

bull - c bull (PPmv)

197E+02

Chemical

124-Trimethylbenzene

MORE ENTER Depth

below grade to bottom

of enclosed space floor

U bull (cm)

ENTER

Soil gas sampling

depth below grade

U (cm) bull

ENTER

Average soil

temperature Ts

CO

1 15 1 1 5 bull125

ENTER ENTER ENTER Totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hft ha he

(cm) (cm) (cm)

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estirnate OR permeability | soil vapor

permeability) k v bull

(cm)

SL 1 1

MORE ENTER

stratum A SCS

soil type

Lookup Soil Parameters

ENTER stratum A soil dry

bulk density P

(gcm)

ENTER Stratum A soil total porosity

(unitless)

ENTER bull stratum A soil water-filled

porosity

(cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

nlaquo

(unitless)

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gchi-s^)

ENTER Enclosed

space floor

length bull LB

(cm)

ENTER Enclosed

space floor

width WB

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

bull Floor-wall seam crack

width w

(cm)

bullENTER

Indoor air exchange

rate ER

(1h) bull

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bidg OR

Leave blank to caicuij

(Lm)

Appx B-1 124-TMBxls 1 of 3 982009

AR100308

APPENDIX B-1-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of ^ bull law constant law constant vaporization at Normal

Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temperature boiling point point temperature weight

D bull Dbdquo H T R bull AHbdquo TB Tc IVIW

Unit risk Reference

factor cone URF RfC

(cms) (cmls) (atm-mmol) CO (calmol) (degK) (degK) (gmol) bull (ugm)- (mgm)

1 606E-02 1 792E-06 1 bull 614E-C3 1 25 1 9369 1 44230 | 64917 1 12020 1 OOE+00 1 60E-03 1

Appx B-1 124-TMBxls 2 of 3 982009

AR100309

APPENDIX B-1-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

(sec)

Source-building

separation

LT bull

(cm) bull

Stratum A soil

air-filled porosity

Q A

Stratum B soil

air-filled porosity

(cmcm) (cmcm)

Stratum C soil air-filled porosity

(cmcm)

Stratum A effective total fluid

saturation

Se

(cmcm)

Stratum A soil

bullintrinsic permeability

^ (cm)

stratum A Stratum A Floor- soil soli wall BIdg

relative air effective vapor seam Soil bull ventilation permeability permeability perimeter gas rate-

kfg ky Xgrack c o n e - QbuHdinpound

(cm) - (cm) (cm) (ngm) (cms)

946E+08 1 0284 0284 0284 0184 596E-09 0901 537E-09 35357 I 197E+02 | 439E+06 |

Area of enclosed

space below grade

As (cm)

Crack-to-total area ratio

1 bull

(unitless)

Crack depth

below grade

Zcfack

(cm)

Enthalpy of vaporization at

ave soil temperature

AHvjs

(calmol) bull

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law constant at

ave soil bull temperature

bull HTS

(unitless)

Vapor bull viscosity at

ave soil temperature

HTS

(gcm-s)

Stratum A

effective diffusion

coefficient

D (cms)

Stratum-B

effective diffusion coefficient

DB (cms)

Stratum C effective diffusion

coefficient

D-c (cms)

Total - overall effective diffusion

coefficient

D ^ (cms)

Diffusion path

length

L-

(cm)

I 787E+07 I 449E-05 | 15 | 11661 260E-03 111E-01 176E-04 I 612E-03 j OOOE+00 | OOOE+00 | 612E-03 j

bull Convection path

length

Lp

(cm)

Source vapor cone

^source

(ngm)

Crack radius

Tcfack

(cm)

Average vapor

flow rate into bIdg

Qsoii

(cms)

Crack effective diffusion

coefficient pcrack

(cms)

Area of CTack

Acack

(cm)

Exponent of equivalent foundation

Peclet number

exp(Pe)

(unitless)

bull bull - bull bull bull bull

1 15 1 197E+02 1 010 1 474E+01 612E-03 bull 354E-t-03 1 336E+09

Infinite source Indoor

~ attenuation coefficient

a

(unitless)

108E-05

Infinite source

btJbldgjJSv-L ^Ppncji3i-

virhpbiiilding bullbull ^lHltti^m)ilg

213E-03

Unit risk

factor

URF

(ngm)-

Reference cone

RfC (mgm)

NA 60E-03 1

I END

Appx B-1 124-TMBxls 3 of 3 982009

AR100310

APPENDIX B-2-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV Nersion31 020^

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

156592

Soil Gas Concentration Data ENTER

Soil gas

cone OR c

(ngm) bull

ENTER Soil bull-gas

cone

c (ppmv)

603E+03 1

Chemical

cis-12-Dichloroethylene

MORE ENTER Depth

below grade to bottom

of enclosed space floor

LF

(cm)

ENTER

Soil gas sampling

depth below grade

U (cm)

ENTER

Average soil

temperature bull Ts

(degC)

1 15 1 bull 15 125

ENTER ENTER ENTER Totalsmust add ijp tb value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hA hB he

bull (cm) (cm) (cm)

15 1 1

ENTER Soil

straturh A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estimate OR permeability | soil vapor

permeability) kv

(cm)

SL 1 |

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

P (gcm)

ENTER Stratum A soil total porosity

bull n

(unitless)

ENTER Stratum A

soil water-filled porosity

(cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

ENTER Stratum B

soil water-filled porosity

ENTER Stratum C

SCS soil type

(unitless) (cmcm)

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure differential

AP

(gcm-s)

ENTER Enclosed bull

space floor

length

LB (cm)

ENTER Enclosed

space floor

width WB

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER

Average vapor flow rate into bIdg

OR Leave blank to calculi

Qsoil

(Lm)

Appx B-2 cis-12-DCExls 1 of 3 982009

AR100311

APPENDIX B-2-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Diffusivity in air

Da

(cms)

Diffusivity in water

Dw (cms)

Henrys law constant at reference temperature

H

(atm-mmoi)

Henrys law constant

reference temperature

bull T R

CC)

Enthalpy of vaporization at

the normal boiling point

AHbdquob

(calmol)

Normal boiling point

TB

(degK)

Critical temperature

Tc (degK)

Molecular weight

MW

(gmol)

Unit risk

factor URF

(ngm)

Reference cone

RfC (mgm)

1 736E-02 1 113E-05 1 407E-03 j 1 25 1 bull 7192 1 33365 1 54400 1 9694 1 OOE+00 j 35E-02 1

Appx B-2 cis-12-DCExls 2 of 3 982009

AR100312

APPENDIX B-2-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

stratum A Stratum B Stratum C Source- soil soil soil

Exposure building air-filled air-filled air-filled

duration separation porosity porosity porosity

T LT ea e^ bull e= (sec) (cm) (cmcm) (cmcm) (cmcm)

I 946E+08n^

Stratum A Stratum A Stratum A Stratum A Floor-effective soil soil soil wall total fluid intrinsic relative air effective vapor seam

saturation permeability permeability permeability perimeter

Ste kj krg ky Acrack

(cmcm) (cm) (cm) (cm) (cm)

Soil gas

cone (ngm)

I 0284 I 0284~ 0284 0184 I 596E-09 | 090T 537E-09 35357 603E+03

BIdg ventilation

rate

JbulldinE

(cms)

439E+06

Area of enclosed

space below grade

AB

(cm)

Crack-to-total

area ratio

n (unitless)

Crack depth below grade

Zltiack (cm)

Erithalpy of vaporization at

ave soil temperature

AHvTs (calmol)

Henryslaw constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law constant at

ave soil temperature

HTS

(unitless) bull

Vapor viscosity at

ave soil bull temperature

HTS

bull (gcm-s)

Stratum A

effective bull diffusion

coefficient

D^A-(cms)

Stratum B

effective bull diffusion

coefficient

D=B

(cms)

Stratum C

effective diffusion bull

coefficient

D=e (cms)

Total overall

effective diffusion

coefficient

DT

(cms)

Diffusion path

length

Ld

(cm)

I 787E+07 I bull449E-05 | 15 bull7709 230E-03 982E-02 176E-04 | 743E-03 | OOOE+00 | OOOE+00 | 743E-03 |

bull bull bull -

Convecfion path -bull

length

Lp (cm)

Source vapor cone

-source

(Mgm)

Crack radius

fcrack

(cm)

Average vapor

flow rate into bIdg

Qaoil bull

(cms)

Crack effective diffusion

coefficient pcack

(cms)

Area of crack

crack

(cm)-

Exponent of equivalent foundation

Peclet number

exp(Pef)

(unitless)

bull

1 15 -1 603E+03 1 010 1 474E+01 743E-03 354E+03 1 697E+07

Infinite source Indoor

attenuation coefficient

poundbullbullbull C t

pound(unitless)

bullsiilaquogt j ii08E-05

Infinite [ source

bIdg cone

Cbujidjng

(pgm)

651 E-02 iKrt

Unit risk

factor

URF

(ngm)-

Reference cone

RfC

(mgm)

NA 35E-02 1

I END I

Appx B-2 cis-12-DCExls 3o f3 982009

AR100313

APPENDIX B-3-A DATA ENTRY SHEET

Coyne Texti le Services - Hunt ington West Virginia

SG-ADV Version 31 0204

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

67663

Soil Gas Concentration Data ENTER ENTER

Soil Soil gas gas

cone OR cone c C

(^gm) (ppmv)

591 E+03

bull

Chemical

Chloroform

MORE ENTER Depth

below grade tb bottom

of enclosed space floor

bull LF

(cm)

ENTER

Soil gas sampling depth

below grade

(cm)

ENTER

Average soil

temperature-Ts

CO bull

1 15 1 15 1 125

ENTER ENTER ENTER Totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

IIA hs he (cm) (cm) (cm)

1 5 bull 1 1

ENTER ENTER Soil - bull

stratum A User-defined SCS stratum A

soil type bull soil vapor (used to estimate OR permeability

soil vapor k

bull permeability) (cm) 1

SL 1 1 bull

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A soil dry

bulk density

Pb (gcm)

ENTER Stratum A soil total porosity

nV (unitless)

ENTER Stratum A

-soilwater-filled bullporosity

Sraquo (cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

(unitless)

ENTER Stratum B

soil water-filled porosity

bull ebdquo=

(cmcm) bull

ENTER Straturri C

SCS bull soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

- c rack

(cm)

ENTER

Soil-bldg pressure

differential AP^

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor

width bull W B

(cm)

ENTER

Enclosed space

height HB

(cm)

ENTER

bull Floor-wall^ seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bidg OR

Leave blank to calculi

Qsoil bull

(Lm)

I -I

Appx B-3 Chloroformxls 1 of 3 982009

AR100314

APPENDIX B-3-B CHEMICALPROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Diffusivity in air

D (cms)

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffijsivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature

Dbdquo H TR A H bdquo TB Tc

(cm s) (atm-m mol) ro (calmol) (degK) (degK)

Molecular weight

MW

(gmol)

Unit risk

factor URF

(ngm)-

Reference cone

RfC

(mgm)

104E-01 100E-05 I 366E-03 25 6988 33432 53640 11938 I 23E-05 | OOE+00

Appx B-3 Chloroformxls 2 of 3 982009

AR100315

APPENDIX B-3-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure

duration

(sec)

Source-

building

separation

LT

(cm)

Stratum A

soil

air-filled

porosity

Sa

( cm cm )

Stratum B

soil

air-filled

porosity

( cm cm )

Stratum C

soil

air-filled

porosity

( c m c m )

Stratum A

effective

total fluid

saturation

( c m c m )

Stratum A

soil

intrinsic

penmeability

k

(cm )

Stratum A

- soil

relative air

permeabil i ty

(cm )

Stratum A

soil

effective vapor

permeability

kv

(cm )

Floor-

wall

seam

perimeter

gtcrack

(cm)

Soil gas

cone

(ngm)

BIdg

venfilation

rate

^buildlriE

(cms)

I 9 4 6 E + 0 8 ~ T I 0284 T 596E-09 I 0-901 I 537E-09 | 35357 | 591 E+03 j 439E+06 | 1 0 284 0284 0184

Area of

enclosed

space

below

grade

A B

( c m )

Crack-

to-total

area

ratio

n

(unitless)

Crack

depth

bull below

grade

^crack

(cm)

Enthalpy of

vaporization at

ave soil

temperature

AHTs bull

(calmol)

Henry s law

constant at

ave soil

temperature

HTS

(a tm-m mol j

Henrys law

constant at

ave soil

bull temperature

HTS

(unitless) bull

Vapor

viscosity at

ave soil-

temperature

^HTS

(gcm-s)

Stratum

A

effective

diffusion

coefficient

(cm s)

Stratum

B

effective

difftjsion

coefficient

D B

(cms) bull

S t ra tum

C

effective

diffusion

coefficient

Dc

(cm s)

Total

overall

effective

bull diffusion

coefficient

D T

(cm s)

Diffi jsion

path

length

Ld

(cm)

I 787E+07 I 449E-05 j - bull 15 7528 210E-03 896E-02 176E-04 I 105E-02 | OOOE+00 | OOOE+00 | 105E-02

Convection

path length

Lp

(cm)

Source

vapor

cone -

^source

- (ngm)

Crack

radius

Tcrack

(cm)

Average

vapor

flow rate

into bidg

Qsoil

(cms)

Crack

effective

diffusion

coefficient Qcrack

bull (cms)

Area of crack

Acrack

(cm)

Exponent of

equivalent

foundation

Peclet number

exp(Pe)

(unitless)

V bull bull

1 15 1 591 E+03 1 010 1 474E+01 105E-02 354E+03 1 355E+05

Infinite

source

indoor

attenuation

coefficient

d

(unitless)

bull 108E-05

Infinite

source

bIdg

cone

^ b u i l d i n g

i (^gm)

bull bull

i 638E-02 -

Unit

risk bull factor

URF

(ngmY

Reference

cone

RfC

(mgm)

~ 23E-05 NA 1

I END

Appx B-3 Chloroform xls 3 of 3 982009

AR100316

APPENDIX B-4-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ersion 31-020^

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

nodashes)

bull 75092

ENTER Soil gas

cone

c (ngm)

Soil Gas Concentration Data ENTER

Soil gas bull

OR cone

bull C

(ppmv)

152E+03

bull bull

Chemical

Methylene chloride

MORE

MORE 4gt

ENTER Depth

below grade to bottom

of enclosed space floor

LF -

(cm)

ENTER

Soil gas sampling depth

below grade

bull U

(cm)

ENTER

Average soil

temperature

Ts bull CC)

bull bull bull bull

1 15 1 15 125

ENTER Totals

Thickness of soil

stratum A h

(cm)

ENTER ENTER must add up to value of Ls (cell F24

Thickness Thickness of soil of soil

stratum B stratum C (Enter value or 0) (Enter value or 0)

he he bull

(cm) bull (cm) -

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(usedto estimate OR perrrieability | soil vapor

permeability)

k bull

(cm)

SL 1 bull 1

ENTER Stratum A

SCS soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

Pb (gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Stratum A

soil water-filled porosity

9w (cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

Pb^

(gcm)

ENTER Stratum B soil total porosity

n^

(unitless)

ENTER Stratum B

soil water-filled porosity

(crhcm)

ENTER Stratum C

SCS soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE 4gt

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

bull Soil-bldg pressure

differential AP^

(gcm-s)

ENTER Enclosed

space floor

length LB

(cm)

ENTER Enclosed

space floor

width bull W B

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width

w

(cm)

ENTER

Indoor air exchange

rate

ER (1h)

ENTER Average vapor

flow rate into bidg OR

Leave blank to calculc

Qsoil

(Lm)

10 40 8839 8839 244 01 083

Appx B-4 MCxIs 1 of 3 982009

AR100317

Diffijsivity in air

D

APPENDIX B-4-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffusivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature

Pw H TR AHt TB TC

Molecular weight

MW

Unit risk

factor URF

Reference cone

RfC

(cms) (cms) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) bull (ngm)- (mgm)

bull bull

1 101E-01 1 117E-05 1 218E-03 1 25 | 6706 1 31300 1 51000 1 8493 1 47E-07 1 30E+00 1

Appx B-4 MCxIs 2 of 3 982009

AR100318

APPENDIX B-4-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

T

(sec)

Source- -building

separation

LT

(cm)

Stratum A soil

air-filled porosity

e a bull

(cmcm)

Stratum B soil

bullair-filled porosity bull

ea^ (cmcm)

Stratum C soil

air-filled porosity

ea= (cmcmj

Stratum A effective total fluid

saturation

Sc bull

(cmcm)

Stratum A soil

intrinsic pemneability

ki (cm)

Stratum A soil

relative air permeability

^ ^ g

(cm)

stratumA bull soil effective vapor permeability

K (cm)

Floor-wall

seam perimeter

Xcrack

(cm)

Soil gas

cone (ngm)

BIdg ventilation

rate

Qbuildinc

(cms)

1 946E+08

Area of -enclosed

space below

bull grade

AB

(cm)

1

Crack-to-total

area rafio

Tl

(unitless)

0284 1

Crack depth below grade

Zcrack

(cm)

0284 1

bull Enthalpy of vaporization at

ave soil temperature

AHTs (calmol)

0284

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

0184

Henrys law constant at ave soil

temperature

HTS

bull (unitless)

1 596E-09

Vapor viscosity at

ave soil temperature

Mrs (gcm-s)

0901

Stratum A

effective diffusion

coefficient

D (cms)

537E-09

Stratum B

effective diffusion

coefficient

D-B (cms)

35357 1

Stratum C -

effective diffusion

coefficient

D-c ^ (cms)

152E+03

Total bull overall

bull effective diffusion

coefficient

D ^

(cms)

440E+06 1

Difftjsion path

length

Ld (cm)

1 787E+07

Convection path

length

Lp (cm)

4 49E-05

Source vapor cone

Csource

(ngm)

15 1

Crack radius

Tcrack

(cm)

7007 bull 1

Average vapor

flow rate intobldg

Qsoil

(cms)

130E-03

Crack effective diffusion

coefficient pcrack

(cms)-

555E-02

bull ^

Area of crack

Acrack

(cm) bull

1 176E-04

Exponent of equivalent foundation

Peclet number

exp(Pe)

(unitless) bull

bull bull

1 15

1 END

152E+03 010 1 474E+01 1 102E-02 354E+03 1 519E+05

102E-02

Infinite source

indoor ^attenuation coefficient

bull a

(unitless)

aiii08E-05

0 OOE+00

bull

Infinite bull source

bIdg ^ cone

^bu i l d i ng

(MQm)

164E-02

OOOE+00 1

Unit risk

factor

URF

(ngm)-

47E-07 1

102E-02 j

Reference cone

RfC

(mgm)

30E+00 j

1 1

Appx B-4 MCxIs 3 of 3 982009

AR100319

APPENDIX B-5-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ^erslon 31 0204

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

127184

Soil Gas Concentration Data ENTER ^ ENTER

Soil -Soi l bull gas gas

cone OR cone Cg C bull

(tgm) (ppmv)

149E+05 1

Chemical

bull Tetrachlbroethylene

MORE 4

ENTER Depth

below grade to bottom

ofenclosecJ space floor

LF

(cm)

ENTER

Soil gas bull sampling

depth below grade

u bull (cm)

ENTER

Average bullsoil

temperature - Ts

ro 1 1 5 1 15 1 125 bull

ENTER ENTER ENTER totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hft bull he bull he

(cm) (cm) (cm)

bull 1 5 1 - 1

ENTER ENTER Soil

stratum A User^defined bull SCS bull stratum A soil type soil vapor

(used to estimate OR perrrieability soil vapor K bull

permeability) (cm) 1

SL 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

Pb

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Sitratum A

soil water-filled bull porosity

(cmcm)

ENTER Stratum B

SCS soiltype

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

Pb^

(gcm)

ENTER Stratum B soil total porosity

Ajnitless^

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS soil type

LookupSoil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

VS

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor width

W B

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width

w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

ENTER Average vapor

flow rate into bidg OR

Leave blank to calcul

bull Qsoil

(Lm)

10 40 8839 8839 244 01 083

Appx B-5 PCExIS 1 of 3 982009

AR100320

APPENDIX B-5-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal Unit

Diffusivity Diffusivity at reference reference the riormal boiling Critical Molecular risk Reference in air in water temperature temperature boiling point point teriiperature weight factor cone

Da Dbdquo H TR AHb TB Tc MW URF RfC

(cms) (cnis) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) (^gm)- (mgm)

1 720E-02 1 820E-06 1 184E-02 1 25 1 8288 1 39440 1 62020 1 16583 1 59E-06 1 60E-01 1

J

AppxB-5PCExls 2 of 3 - 982009

AR100321

APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

T

(sec)

Source-building

separation

LT

bull (cm)

Stratum A soil

air-filled porosity

Oa (cmcm)

Stratum B - soil air-filled porosity

ea (cmcm)

Stratum C soil

air-filled porosity

ea= - (cmcm)

Stratum A effective total fluid

saturation

sbdquo (cmcm)

Stratum A soil

intrinsic permeability

ki (cm)

Stratum A soil

relative air permeability

- ^ g

(cm)

Stratum A soil

effective vapor permeability

kv (cm)

Floor-wall

seam perimeter

^crack

(cm)

Soil gas

cone

(ngm)

BIdg venfilation

rate

Qbuildins

bull (cms)

bull bull

1 946E+08

Area of enclosed

space below grade

AB

(cm)

1

bullCrack-to-total

area ratio

1 (unitless)

0284 1

Crack bull depth below grade

Zcrack

(cm) -

0284 1

Enthalpy of vaporization at bull

ave soil temperature

bull A H V TS

(calmol)

0284

Henrys law constant at

ave soil temperature

HTS (atm-mmol)

0184

-Henrys law constant at

ave soil temperature

HTS

(unitless)

1 596E-09

Vapor viscosity at

ave soil temperature

HTS

(gcm-s)

0901

Stratum A

effective diffusion

coefficient bull D = bull

(cms)

537E-09

Stratum B

effective diffusion

coefficient

D--B (cms)

35357 1

Stratum C

effective diffusion bull

coefficient

D-c (crris)

149E+05

Total overall

effective bulldiffusion coefficient

DT

(cms)

440E+06 1

Difftjsion path

length

U (cm)

1 787E+07

Convection path

length

bull Lp

(cm)

4 49E-05

Source vapor cone

^source

(ngm)

15 1

Crack radius

Tcrack

(cm)

9528 1

Average vapor

flow rate intobldg

Qsoil (cms)

908E-03

Crack effective diffusion

coefficient pcrack

bull ( c m s ) bull

387E-01

Area of crack

Abdquoack (cm)

1 176E-04

Exponent of equivalent foundafion

Peclet number

exp(Pe)

(unitless)

bull

1 15-

1 END

149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08

727E-03

Infinite source indoor

attenuation coefficient

a

(unitless)

108E-05

OOOE+00

Infinite source

bIdg cone

Cburldtng

(Mgm)

161 E+00

OOOE+00 1

Unit risk

factor

URF

(ugm)-

59E-06 1

727E-03

Reference cone

RfC (mgm)

60E-01

1 1

Appx B-5 PCExls 3 of 3 982009

AR100322

APPENDIX B-6-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ersion31 0204

Reset to Defaults

t

Soil Gas Concentration Data ENTER

Chemical CAS No

(numbers only

no dashes)

79016

ENTER ENTER Soil Soil gas gas

cone OR cone C C -

bull (ngm) (ppmv)

782E+03

Chemical

Trichloroethylene

MORE ENTER Depth

below grade to bottom-

of enclosed space floor

LF

(cm)

ENTER

Soil gas sarnpling

depth below grade

U (cm)

ENTER

Average soil

temperature Ts

(degC)

1 15 1 15 t 125

ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e

(cm) (cm) (cm)

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estimate OR permeability soil vapor

permeability)

k (cm)

bull S L 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil bull-Parameters

ENTER Stratum A

soil dry bulk density

P b -

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Stratum A bull

soilwaterrfilled porosity

(cmcm) bull

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

bull P ^ (gcm)

ENTER Stratum B soil total

porosity

nlaquo

(unitless) -

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS bull soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor

width W B

(cm)

ENTER

Enclosed space height

H B bull

( c m ) bull

ENTER

Floor-wall seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bIdg OR

Leave blank to calculc

Qsoil

(Lm) -

Appx B-6 TCExIs 1 of 3 982009

A

AR100323

APPENDIX B-6-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight

Da Dbdquo H TR AH^b TB TC MW

Unit risk Reference

factor cone URF RfC

(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)

1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1

Appx B-6 TCExIs 2 of 3 982009

AR100324

APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

(sec)

Source-building

separation LT

(cm)

Stratum A soil

air-filled porosity

bull ea (cmcm)

Stratum B Soil

air-fllled porosity

e^ bull (cmcm)

Stratum C soil

air-filled porosity

(cmcm)

StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air

saturation permeability permeability

S|e k krg (cmcm) (cm) (cm)

Stratum A Floor-soil wall BIdg

effective vapor seam Soil ventilafion permeability perimeter gas rate

k^ bull Xack c o n e Qbuildins

(cm) (cm) (ngm) (cms)

946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |

Area of enclosed

space below grade

AB

(cm)

Ciack- to-total

area ratio

1 (unitless)

Crack depth below grade

Zcrack

(cm)

Enthalpy of vaporization at

ave soil temperature

A H J S

(calmol)

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law bull constant at

ave soil temperature

HTS

(unitless)

Vapor viscosity at

ave soil temperature

|JTS

(gcm^s)

Stratum A

effective diffusion

coefficient

(cms)

Stratum B

effective -diffusion

coefficient

D=B (cms)

Stratum ^ C effective diffusion

coefficient

D=c (cms)

Total overall

effective diffusion

coefficient

DT

(cms)

I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03

Diffusion path

length

Li (cm) bull

Convection bull path

length

Lp

(cm)

Source vapor cone bull

^source

(ngm)

Crack radius

rcrack

(cm)

Average vapor

- flow rate intobldg

Qsoil

(cms)

Crack effective diffusion

bull coefficient Qcrack

(cms)

Area of crack

^crack

(cm)

Exponent of equivalent foundation

Peclet bull number

exp(Pe)

(unitless)

bull bull

1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07

Infinite source Indoor

attenuation coefficient

a

(unitless)

108E-05

Infinite source

bIdg concgt

^building

(ngm)

844E-02

Unit risk

factor

URF

(ngm)-

Reference cone

RfC

(mgm)

1 1E-04 1 40E-02 1

END

Appx B-6 TCExIs 3 of 3 982009

AR100325

Office of Waste Management 1356 Hansford Street

Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256

West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director

ORDER

ISSUED UNDER THE

HAZARDOUS WASTE MANAGEMENT ACT

CHAPTER 22 ARTICLE 18

OF THE WEST VIRGINIA CODE^ AS AMENDED

y Order Number HW-011-80

To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704

ATTEMTION MREDARMON

Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull

AR100326

ViWJ011-laquo9 PageNunil)er2

BASIS FOR ORDER

As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following

A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^

B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator

C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities

0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94

^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement

P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following

1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater

2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was

^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment

CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable

CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order

AR100327

H W - 0 1 1 - 9 9 Page Number 3

REQUIREMENTS OF ORDER

Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows

1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^

2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore

remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling

GENERAL PROVaiONS

1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order

2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order

3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order

Effective Date

Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief

Wt T 1 V Oflice of Waste Management

AR100328

^ ^ S I S

^wmmmmamn

AR100329

Page 18: SDMS DocID 2121999 · International Enterprises Corp. building (Coyne Building), which is located at 1111 Vernon Street, Westmoreland District, Wayne County, West Virginia. The following

TABLE 2 IDENTIFICATION OF CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR

Coyne Textile Services Facility - Huntington West Virginia

mdash

Const i tuent

Volati le Organics

111-Trichlor6ethane

1122-Tetrachloroethane

112-Trichloro-122-trifluoroethane

112-Trichloroethane

11-Dichloroethane

11-Dichloroethene

124-Trichlorobenzene

124-Trimethylbenzene

12-Dibromoethane

12-Dichlor6benzene

12-Dichloroethane

12-Dichloroethene (cis)

12-pichloroethene (trans)

12-Dichloropropane

12-Dichlorotetraf1uoroethane

135-Trimethylbenzene

13-Butadiene

13-Dichlorobenzene

13-Hexachlorobutadiene

14-Dichlorpbenzene

224-trimethylpentane

2-Chlorotoluene

4-Ethyltoluene

Acetone

Allyl Chloride

Benzene

Bromodichloromethane

Bromoform

Bromomethane

Carbon disulfide bull

Carbon tetrachloride

ChJorobenzene

Chloroethane

Frequency of Detection

0 3

0 3

0 3

bull 0 3

0 3

0 3

0 3

1 3

0 3 bull

0 3

b 3 bull

2 3

0 3

bull 0 3

0 3

0 3

0 3 bull

0 3

0 3

0 3

0 3

0 3

0 17

3 3

0 3

P 3

- 0 3

0 3

0 3

0 3

0 3

0 3

0 3

Min imum Detected

Concentrat ion

(ugm^)

ND

ND

ND

ND

ND

- ND

N D

197

ND bull

ND

ND

369

ND

bull~ ND

ND

ND

ND

ND

ND

bull ND

ND

ND

ND

796

ND

ND

ND-

ND

ND

ND

ND

ND

ND

Maximum

Detected Concentrat ion

(ugm3)

ND

ND

ND

ND

ND

ND

ND

197

ND

ND

ND

mdash 6030

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

1880

ND-

ND

ND

ND

ND

ND

ND

ND

ND

Sample wi th Maximum Detect

ND

ND

ND

ND

ND

ND

- ND

VP-03 -

ND

ND

ND

VP-03

ND

bullND

ND

ND

ND

ND

ND

ND

ND

ND

ND

VP-02

ND

ND bull

ND

ND

ND bull

bull ND

ND

ND

ND

Min imum Detection

Limit (ugm3)

22

28

31

22

16

16

30

20

31

24

16

bull 16

16

19

28

20

89

24 bull

43

24

bull 19

2 1

20

--^ 13

13

27

41

16

13

25

18

11

Maximum Detection

Limit (ugm3)

218

275

307

218

162

159

297

197

307

240

162

- 16

159

185

280

197

89

240

427

240

187

207

197

--125

128

268

414

155

125

252

184

106

Vapor Intrusion Corhparison

V a l u e

(ugm)

22000

042

300000

15

bull 5000

2000

2000

60

011

2000

094

350

700

40

NA

60

0087

1100

11

8000

NA

NA

NA

3500

NA

31

14

22

50

7000

16

bull 600

100000

Chemical of Concern

No

No

No

No

No

No

No

YES

No

No

No

YES

No

No

No

N o bull

bullNo

No

No

No

No

No

No

N o

No

No

No

N o

No

No

No

No

No

Comment

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent notdetected

fflaximCimTdeteetlSffieedsTcomDarisonivalues

Constituent not detected

Constituent not detected

Constituent not detected

Maximum detect exceeds comparison value

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Maximum detect below comparison value

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detected

Constituent not detectedl

Constituent not detected

Constituent not detected

CoyneVI Memo Tables_09-08-09xls 982009

AR100295

TABLE 2

IDENTIFICATION OF CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR

Coyne Textile Services Facility - Huntington West Virginia

Const i tuent

Volati le Organics

Chloroform -

Chloromethane

13-Dichloropropene (cis)

Cyclohexarie^

Dibrcimochloromethane

DichlonDdifluoromethane

Ethylbenzene

Methyl ethyl ketone

Methyl isobutyl ketone

Methyl tert-butyl ether

Methylene chloride

n-Heptane

n-Hexane

Styrene

Tert-butyl alcohol

Tetrachloroethene

Toluene

13-Dichloropropene(trans)

Triehloroethene

Trichlorofluoromethane

Vinyl bromide

Vinyl chloride

Xylene (0)

Xylenes (mampp)

Frequency of Detection

1 3

0 3

0 3

1 3

0 3

0 3

0 -3

1 3

0 3

0 3

2 3

0 3

3 3

0 3

0 3

3 3

1 3

- 0 3

3 3

P 3

0 3

0 3

1 3

1 3

Min imum Detected

Concentrat ion

(ugm)

5910

ND

ND

52

ND

ND

ND

23

ND

ND

1160

ND

1 4 4

ND

ND

11200

18

ND

91

ND

ND

ND

208

387

Maximuri i Detected

Concentrat ion (ugmS)

bull

5910

ND

ND

52

bull ND

ND

ND

23

ND

ND

1520

ND

183

ND

ND

149000

18

ND

7820

ND

bullND

ND

208

387

Sample vyith Max imum Detect

VP-02

ND

ND

VP-01

bull ND

ND

ND

VP-01

ND

ND

VP-02

ND

VP-02

ND

ND

VP-02

VP-01

ND

VP-03

ND

ND

ND

VP-03

VP-03

Min imum Detection

Limit (ugm3)

20

83

18

138

34

bull 20

17

118

16

14

14

16

- -17

12

--151

18

--23

18

10

1 7 bull

1 7 bull

Maximum Detection

Limit (ugm3)

195

83

182

138

341

198

174

118

164

144

14

164

170

121 -

--151

182

225

175

102

bull 174

174

Vapor Intrusion Compar ison

V a l u e

(ugm)

11

24

NA

2000

1

2000

22

10000

800

30000

52

NA

2000

10000

NA

81

4000

NA

022

7000

NA

28

70000

70000

Chemical o f Concern

YES

No

No

No

No bull

No

No bull

No bull=

No

No

YES

No

No

No

No

YES

No

No

YES

N o

No

No

No

No

Comment

Maximum detect exceeds comparison value

Constituent not detected

Constituent not detected

Maximum detect below comparison value

Constituent not detected

Constituent not detected

Constituent not detected

Maximum detect below comparison value

Constituent not detected

Constituent not detected

Maximum detect exceeds comparison value

Constituent not detected bull

Maximum detect below comparison value

Constituent not detected

Constituent not detected

Maximum detect exceeds comparison value

Maximum detect below comparison value

Constituent not detected

Maximum detect exceeds comparison value

Constituent not detected

Constituent not detected

Constituent not detected bull

Maximum detect below comparison value

Maximum detect below comparison value

Notes

ND - Not Detected

NA - Not Available

- - Constituent detected in every sample detection limit not presented

Values in bold indicate detection limit exceeds comparison values

Target shallow soil gas comparison values corresponding to indoor air concentrations where the soil gas to indoor air attenuation factor = 01 and the target cancer risk is set to ip (presented in Table 2c of USEPA 2002a)

Comparison value for cyclohexane is based on the comparison value for hexane

Coyne VI Memo Tables_09-08-09xls 982009

AR100296

TABLES

EXPOSURE POINT CONCENTRATIONS FOR CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR

Coyne Textile Services Facility - Huntington West Virginia

Chemical of Concern

VolatileOrganics

i24-Trimethylbenzene

12-Dichloroethene (cis)

Chloroform

Methylene chloride

Tetrachloroethene Triehloroethene

Subslab Vapor Source

Concentration (mgm^)

0197

603

591

152

149 782

Transport

Factor^ (unitless)

108E-05

108E-05

108E-05

108E-05

108E-05 108E-05

EPC in

Indoor Air (mgm^)

213E-06

651 E-05

638E-05

164E-05

161E-03 844E-05

Notes

^ Subslab vapor source concentration is based on the maximum detected concentration of samples

VP-01-02 and-03 (see Table 2) -

^ Details of the transport factor calculations are presented in Appendix B

^ Exposure Point Concentration (EPC) in inidoor air is calculated as the subslab vapor concentration TF

Coyne VI Memo Tables_09-08-09xls 982009

AR100297

TABLE 4

FACTORS USED IN DOSE CALCULATIONS INHALATION OF VOLATILE EMISSIONS

Coyne Textile Services Facility - Huntington West Virginia

Symbol

CA

IRA

ET

EF

ED-

BW

AT

Exposure Factor

Constituent Concentration in Air

Inhalation Rate

Exposure Time

Exposure Frequency

Exposure Duration

Body Weight

Averaging Time

Indoor Worker

Constituent-Specific See Table 3

25 m hour

8 hrday

250 daysyear

25 years

bull 70 kg

9125 days (NC)

25550 days (C)

Total Dose = CA x IR^ x ET x EF x ED x 1BW x 1AT

(NC) - Non-carcinogenic Averaging Time

(C) - Carcinogenic Averaging Time

Coyne VI Memo Tables_09-08-09xls 982009

AR100298

TABLES TOXICITY VALUES FOR CHEMICALS OF CONCERN

Coyne Textile Services Facility - Huntington West Virginia

Chemical of Concern

Volatile Organics

124-Trimethylbenzene

12-Dichloroethene (cis)

Chloroform

Methylene chloride

tetrachloroethene

Triehloroethene

Target Organ Critical Effect

blood

bullblood

liver

liver

liver CMS

liver kidney fetus CNS

Chroniclnhalation Reference Dose

(mgkg-day)

200E-03 P

1 OOE-02 R

140E-02 E

286E-01 M

771 E-02 M

1OOE-02 E

Inhalation Cancer ^ Slope Factor

(mgkg-day)^

NA

NA

805E-02 1

165E-03 1

200E-02 0

400E-01 E

(I) - Integrated Risk Information System (IRIS USEPA 2009)

(P) - Provisional Peer-Reviewed Toxicity Value (PPRTV) as presented in USEPA Regional Screening Tables (ORNL 2009)

(R) - Calculated assuming route-to-route extrapolation as per WVDEP

(E)-Provisional value from the National Center for Environmental Assessment (as per WVDEP)

(M)-Chronic Minimal Risk Level (MRL ATSDR 2009)

(0) - Value cited by USEPA Region 3 attributed to other sources (as per WVDEP)

Coyne VI Memo Tables_09-08-09xls 982009

AR100299

TABLE 6

NONCANCER HAZARD INDEX AND POTENTIAL CANCER RISK FOR AN INDOOR WORKER

Coyne Textile Services Facility - Huntington West Virginia

bull

Constituent

Volatile Organics

124-Trinnethylbehzene

12-Dichlorpethene (cis)

Chloroform

Methylene chloride

Tetrachloroethene Triehloroethene

EPC in Indoor Air

(mgm)

213E-06

651 E-05

- 638E-05

164E-05

161 E-03

844E-05

Intake (ADD)

(mgkg-d)

416E-07

127E-05

125E-05

321 E-06

315E-04 l65E-05

RfDi

(mgkg-d)

200E-03

1OOE-02

140E-02

286E-01

771 E-02 1 OOE-02

Hazard

Quotient

208E-04

127E-03

892E-04

112E-05

408E-03 165E-03

Intake (LADD)

(mgkg-d)

) 149E-07

455E-06 bull 446E-06

115E-06

112E-04 590E-06

CSFi

(mgkg-d)

NA

NA

805E-02

165E-03

200E-02

400E-01

Potential

Cancer Risk

NA

NA

359E-07

189E-09

225E-06 236E-06

Total Hazard Index

00081 Total

Cancer Risk 497E-06

Total Blood HI = Total Liver HI =

Total Central Nervous System HI = Total Kidney HI =

Total Fetal HI =

bull 00015 00066 00057 00017 00017

Notes NA = Toxicity values are not available for this endpoint or exposure pathway

Coyne VI Memo Tables_09-08-09xls 982009

AR100300

APPENDIX A

SUBSLAB VAPOR ANALYTICAL DATA

AR100301

Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility Huntington West Virginia

Sample

Consti tuent

Volatile Organics (ugm) 111-Trlchloroethane 1122-Tetrachloroethane 112-Trichloro-122-trifluoroethane 112-Trichloroethane 11-Dichioroethane 11-Dichloroethene 124-Trichloroberi2ene 124-Trimethylbenzene 12-Dibromoethane 12-Dichloroben2ene 12-Dichloroethane 12-Dichloroethene-(cis) -12-Dichloroethene (trans) 12-Dichloropropane 12-Dichlorotetrafluoroethane 135-Trimethylbenzene 13-Butadiene 13-Dichlorobenzene 13-Hexachlorobutadiene 14-Dichlorobenzene 224-trimethVlpentane 2-Chlorotoluene 4-Ethyltoluene Acetone Allyl Chloride Benzene Bromodichloromethane Bromoform Bromomethane Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 13-Dichloropropene (cis) Cyclohexane Dibromochloromethane

Identif ication Sample Date

CAS No

71-55-6 79-34-5 76-13-1 79-00-5 75-34-3 75-35-4 120-82-1 95-63-6 106-93-4 95-50-1 107-06-2 156-59-2 156-60-5 78-87-5 76-14-2 108-67-8 106-99^0 541-73-1 87-68-3 106-46-7 540-84r1 95-49-8

622-96-8 67-64-1 107-05-1 71-43-2 75-27-4 75-252 74-83-9 75-15-0 56-23-5 108-90-7 75-00-3 67-66-3 74-87-3

10061-01-5 110-82-7 124-48-1

lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt

lt lt lt lt lt lt lt lt lt lt lt lt

lt

VP-01 8132009

22 28 31 22 16 16 30 20 31 24 16 16 16 19 28 20 89 24 43 24

1 9 21 20 796 13 13 27 41 16 13 25 18 11 20 83 18 52 34

lt lt lt lt lt lt lt lt lt lt lt

lt lt lt lt lt lt lt lt lt lt lt

lt lt lt lt lt lt lt lt lt

lt lt lt lt

VP-02 8132009

218 2 7 5 307 218 162 159 297

bull 197 307 240 162 369 159 185 280 197 89

240 427 240 187 207 197

1880 125 128 268 414 155 125 252 184 106

5910 83 182 138 341

lt lt lt lt lt lt lt

lt lt lt

lt lt lt lt lt lt lt bull

lt lt lt lt

lt lt lt lt lt lt lt lt lt lt lt lt lt lt

VP-03 8132009

218 275 307 218

bull 162 159 297 197 307 240 162

6030 159 185 280 197 89

240 427 240 187 207 197

1750 125 128 268 414 155 125 252 184 106 195 83 182 138 341

Appx A SG Dataxis Page 1 of 2 982009

AR100302

Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility bull Huntington West Virginia

Consti tuent

Volatile Organics (ugm^) Dichlorodifluoromethane Ethylbenzene Methyl ethyl ketone Methyl Isobutyl ketone Methyl tert-butyl ether Methylene chloride n-Heptane jn-Hexane Styrene Tert-butyl alcohol Tetrachloroethene iToluene 13-Dichloropropene (trans) Triehloroethene Trichlorofluoromethane Vinyl bromide Vinyl chloride Xylene (o) Xylenes (mampp)

Sample Identif ication Sample Date

CAS No

75-71-8 100-41-4 78-93-3 108-10-1

1634-04-4 75-09-2

142-82-5 bull 110-54-3

100-42-5 75-65-0 127-18-4 108-88-3

10061-02-6 79-01-6 75-69-4 593-60-2 75-01-4 95-47-6

179601-23-1

lt lt

lt lt lt lt

lt lt

lt

lt lt lt lt lt

VP01 8132009

20 17 23 16 14 14 16

173 17 12 bull

11200 18 18 91 23 18 10 17 17

lt lt lt lt lt

lt

lt lt

lt lt

lt lt lt lt lt

VP-02 8132009

198 174 118 164 144

1520 164 -183 170 121

149000 151 182

2360 225 175 102 174 174

VP-03 8132009

lt 198 lt 174 lt 118 lt 164 lt 144

1160 lt 164

144 lt 170 ltbull 121

90500 lt 151 lt 182

7820 lt 225 lt 175 lt 102

208 387

Appx A SG Dataxis Page 2 of 2 982009

AR100303

APPENDIX B

CALCULATION OF TRANSPORT FACTORS USED TO ESTIMATE INDOOR AIR CONCENTRATIONS

AR100304

APPENDIX B

Calculation of Transport Factors Used to Estimate Indoor Air Concentrations

This appendix presents the methodology for calculating transport factors that are used to convert subslab

vapor concentrations to concentrations in indoor air 124-Trimethylbenzene 12-dichloroethene (cis)

chloroform methylene chloride tetrachloroethene and triehloroethene were identified as contaminants of

concern (COC) for potential vapor intrusion from subslab vapor associated with the Coyne Textile

Services Facility located in Huntington West Virginia (site) In this appendix the transport factors are

calculated to estimate the concentrations of COC in indoor air of the existing plant building located at the

site ~

Transport Factor for Indoor Air

The concentration of a constituent in indoor air (da) is proportional to the concentration of the constituent

in the subslab vapors immediately beneath the building foundation (ie subslab vapor concentration or

Csubsiab) The following equation is used to calculate da from Csubsiab

^ wja ~ ^subslab X I r

where

Cia = concentration of constituent in indoor air (mgm^) -

Csubsiab^ concentration of constituent in subslab vapors (mgm^) and

TF = transport factor from subslab vapors to indoor air

The transport factor (TF) is an infinite source attenuation coefficient andcan be calculated based on a

model developed by Johnson and Ettinger (1991) t he equation for calculating TF is as follows

(Deff X A B ) ( Q B X L T ) X expKQso i l X Lcrabk)(Dcrack X Acrack)]

exp[ (Qsoi l X Lcrack)(Dcrack X Acrack)] + (Deff X A B ) ( Q B X L T ) + (Deff X AB)(Qsoi l X L j ) X (exp [ (Qso i l X Lcrack)(Dcrack X Acrack)] - 1)

where

Deff = effective diffusion coefficient for vadose zone soil (cm^sec)

AB = area of enclosed space below grade (cm^)

QB = building ventilation rate (cm^sec)

LT = distance from contaminant source to building foundation (cm)

Qsoii = volumetric flow rate of vapors into the building (cm^sec)

Lcrack = foundatlon thickness (cm)

Dcrack = vapor diffusion coefficient through crack (cm^sec) and

Acrack = area of cracks through which vapors can pass (cm^)

AR100305

To solve this equation the USEPAs SG-ADV spreadsheet Version 31 most recently updated in

February 2004 was implemented A combination of site-specific factors and default values from the

Users Guide for Evaluating Subsurface Vapor Intrusion Into Buildings (USEPA 2004) were used as input

values in the model All input values are defined below and presented in Tables B-1-A through B-6-A

bull The initial subslab vapor concentration (Csubsiab) is the maximum detected concentration(in units

of ugm ) of samples VP-01 VP-02 and VP-03 that was presented in Table 3 of the report

bull The depth below grade to the bottom of the enclosed space floor (Lp) is set to 15 cm the default

value provided by USEPA (2004) for a slab-on-grade structure

bull The vapor sampling depth below grade (Lg) is a site-specific value The vapor samples were

collected from immediately beneath the building floor therefore Lj has been set to 15 cm

bull The average soilgroundwater temperature (Ts) is set to 125degC the average value for West

Virginia as estimated frorri Figure 8 of the vapor intrusion users guide (USEPA 2004)

bull The soil type used to estimate vapor permeability is assumed to be sandy loam (SL) The

associated soil properties for a sandy loam soil type are as follows the soil dry bulk density (Pb) is

162 gcm the total porosity (n) is 0387 (cm^-aircm^) and the water-filled porosity (nw) is 0103

(cm -HzOcm )

bull The floor thickness (Lcrack) is set to the USEPA (2004) default value of 10 cm

bull The soil-building pressure differential (AP) is set to the USEPA (2004) default value of 40 gcm-s^

bull The building dimensions are siterspecific based on the existing plant building located at the site

The existing structure is approximately 84000 square feet (Dolphin 2000) therefore the

dimensions are set to 8839 cm (290 feet) length by 8839 cm (290 feet) The USEPA (2004)

default value of 244 cm vyas used for the height

bull Thefloor-wall seam crack width (w) is set to the USEPA (2004)-default value of 01 cm

bull The indoor air exchange rate (ER) is set to 083hour This is the value provided by ASTM (2002)

for commercial and industrial buildings

AR100306

Tables B-1-B through B-6-B present the constituent-specific properties for COC that were used in the TF

calculations Tables B-1-C through B-6-C present the intermediate calculations used to determine the

indoor air attenuation coefficients (ie the transport factors) The shaded boxes in Tables B-1-C through

B-6-C also present the resulting TF values that are applied to the concentrations of COC in subslab

vapor and the estimated indoor air concentrations

References

American Society for Testing and Materials (ASTM 2002) Standard Guide for Risk-Based Corrective Action Applied at Petroleum Release Sites ASTM E-1739-95 (Reapproved 2002)

Johnson PC and RA Ettinger (1991) Heuristic model for predicting the intrusion r-ate of contaminant vapors into buildings Environ Sci Technolpgy 25 1445-1452

Dolphin Environmental LLC (Dolphin 2000) Site Characterization Report Mach 14 2000

United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004

AR100307

APPENDIX B-1-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV Nersion31 0204

Reset to Defaults

ENTER -

Chemical CAS No

(numbers only

no dasties)

95636

ENTER Soil gas

cone

Cg (ngm)

Soil Gas Concentration Data ENTER

Soil gas

OR cone

bull - c bull (PPmv)

197E+02

Chemical

124-Trimethylbenzene

MORE ENTER Depth

below grade to bottom

of enclosed space floor

U bull (cm)

ENTER

Soil gas sampling

depth below grade

U (cm) bull

ENTER

Average soil

temperature Ts

CO

1 15 1 1 5 bull125

ENTER ENTER ENTER Totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hft ha he

(cm) (cm) (cm)

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estirnate OR permeability | soil vapor

permeability) k v bull

(cm)

SL 1 1

MORE ENTER

stratum A SCS

soil type

Lookup Soil Parameters

ENTER stratum A soil dry

bulk density P

(gcm)

ENTER Stratum A soil total porosity

(unitless)

ENTER bull stratum A soil water-filled

porosity

(cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

nlaquo

(unitless)

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gchi-s^)

ENTER Enclosed

space floor

length bull LB

(cm)

ENTER Enclosed

space floor

width WB

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

bull Floor-wall seam crack

width w

(cm)

bullENTER

Indoor air exchange

rate ER

(1h) bull

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bidg OR

Leave blank to caicuij

(Lm)

Appx B-1 124-TMBxls 1 of 3 982009

AR100308

APPENDIX B-1-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of ^ bull law constant law constant vaporization at Normal

Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temperature boiling point point temperature weight

D bull Dbdquo H T R bull AHbdquo TB Tc IVIW

Unit risk Reference

factor cone URF RfC

(cms) (cmls) (atm-mmol) CO (calmol) (degK) (degK) (gmol) bull (ugm)- (mgm)

1 606E-02 1 792E-06 1 bull 614E-C3 1 25 1 9369 1 44230 | 64917 1 12020 1 OOE+00 1 60E-03 1

Appx B-1 124-TMBxls 2 of 3 982009

AR100309

APPENDIX B-1-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

(sec)

Source-building

separation

LT bull

(cm) bull

Stratum A soil

air-filled porosity

Q A

Stratum B soil

air-filled porosity

(cmcm) (cmcm)

Stratum C soil air-filled porosity

(cmcm)

Stratum A effective total fluid

saturation

Se

(cmcm)

Stratum A soil

bullintrinsic permeability

^ (cm)

stratum A Stratum A Floor- soil soli wall BIdg

relative air effective vapor seam Soil bull ventilation permeability permeability perimeter gas rate-

kfg ky Xgrack c o n e - QbuHdinpound

(cm) - (cm) (cm) (ngm) (cms)

946E+08 1 0284 0284 0284 0184 596E-09 0901 537E-09 35357 I 197E+02 | 439E+06 |

Area of enclosed

space below grade

As (cm)

Crack-to-total area ratio

1 bull

(unitless)

Crack depth

below grade

Zcfack

(cm)

Enthalpy of vaporization at

ave soil temperature

AHvjs

(calmol) bull

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law constant at

ave soil bull temperature

bull HTS

(unitless)

Vapor bull viscosity at

ave soil temperature

HTS

(gcm-s)

Stratum A

effective diffusion

coefficient

D (cms)

Stratum-B

effective diffusion coefficient

DB (cms)

Stratum C effective diffusion

coefficient

D-c (cms)

Total - overall effective diffusion

coefficient

D ^ (cms)

Diffusion path

length

L-

(cm)

I 787E+07 I 449E-05 | 15 | 11661 260E-03 111E-01 176E-04 I 612E-03 j OOOE+00 | OOOE+00 | 612E-03 j

bull Convection path

length

Lp

(cm)

Source vapor cone

^source

(ngm)

Crack radius

Tcfack

(cm)

Average vapor

flow rate into bIdg

Qsoii

(cms)

Crack effective diffusion

coefficient pcrack

(cms)

Area of CTack

Acack

(cm)

Exponent of equivalent foundation

Peclet number

exp(Pe)

(unitless)

bull bull - bull bull bull bull

1 15 1 197E+02 1 010 1 474E+01 612E-03 bull 354E-t-03 1 336E+09

Infinite source Indoor

~ attenuation coefficient

a

(unitless)

108E-05

Infinite source

btJbldgjJSv-L ^Ppncji3i-

virhpbiiilding bullbull ^lHltti^m)ilg

213E-03

Unit risk

factor

URF

(ngm)-

Reference cone

RfC (mgm)

NA 60E-03 1

I END

Appx B-1 124-TMBxls 3 of 3 982009

AR100310

APPENDIX B-2-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV Nersion31 020^

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

156592

Soil Gas Concentration Data ENTER

Soil gas

cone OR c

(ngm) bull

ENTER Soil bull-gas

cone

c (ppmv)

603E+03 1

Chemical

cis-12-Dichloroethylene

MORE ENTER Depth

below grade to bottom

of enclosed space floor

LF

(cm)

ENTER

Soil gas sampling

depth below grade

U (cm)

ENTER

Average soil

temperature bull Ts

(degC)

1 15 1 bull 15 125

ENTER ENTER ENTER Totalsmust add ijp tb value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hA hB he

bull (cm) (cm) (cm)

15 1 1

ENTER Soil

straturh A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estimate OR permeability | soil vapor

permeability) kv

(cm)

SL 1 |

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

P (gcm)

ENTER Stratum A soil total porosity

bull n

(unitless)

ENTER Stratum A

soil water-filled porosity

(cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

ENTER Stratum B

soil water-filled porosity

ENTER Stratum C

SCS soil type

(unitless) (cmcm)

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure differential

AP

(gcm-s)

ENTER Enclosed bull

space floor

length

LB (cm)

ENTER Enclosed

space floor

width WB

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER

Average vapor flow rate into bIdg

OR Leave blank to calculi

Qsoil

(Lm)

Appx B-2 cis-12-DCExls 1 of 3 982009

AR100311

APPENDIX B-2-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Diffusivity in air

Da

(cms)

Diffusivity in water

Dw (cms)

Henrys law constant at reference temperature

H

(atm-mmoi)

Henrys law constant

reference temperature

bull T R

CC)

Enthalpy of vaporization at

the normal boiling point

AHbdquob

(calmol)

Normal boiling point

TB

(degK)

Critical temperature

Tc (degK)

Molecular weight

MW

(gmol)

Unit risk

factor URF

(ngm)

Reference cone

RfC (mgm)

1 736E-02 1 113E-05 1 407E-03 j 1 25 1 bull 7192 1 33365 1 54400 1 9694 1 OOE+00 j 35E-02 1

Appx B-2 cis-12-DCExls 2 of 3 982009

AR100312

APPENDIX B-2-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

stratum A Stratum B Stratum C Source- soil soil soil

Exposure building air-filled air-filled air-filled

duration separation porosity porosity porosity

T LT ea e^ bull e= (sec) (cm) (cmcm) (cmcm) (cmcm)

I 946E+08n^

Stratum A Stratum A Stratum A Stratum A Floor-effective soil soil soil wall total fluid intrinsic relative air effective vapor seam

saturation permeability permeability permeability perimeter

Ste kj krg ky Acrack

(cmcm) (cm) (cm) (cm) (cm)

Soil gas

cone (ngm)

I 0284 I 0284~ 0284 0184 I 596E-09 | 090T 537E-09 35357 603E+03

BIdg ventilation

rate

JbulldinE

(cms)

439E+06

Area of enclosed

space below grade

AB

(cm)

Crack-to-total

area ratio

n (unitless)

Crack depth below grade

Zltiack (cm)

Erithalpy of vaporization at

ave soil temperature

AHvTs (calmol)

Henryslaw constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law constant at

ave soil temperature

HTS

(unitless) bull

Vapor viscosity at

ave soil bull temperature

HTS

bull (gcm-s)

Stratum A

effective bull diffusion

coefficient

D^A-(cms)

Stratum B

effective bull diffusion

coefficient

D=B

(cms)

Stratum C

effective diffusion bull

coefficient

D=e (cms)

Total overall

effective diffusion

coefficient

DT

(cms)

Diffusion path

length

Ld

(cm)

I 787E+07 I bull449E-05 | 15 bull7709 230E-03 982E-02 176E-04 | 743E-03 | OOOE+00 | OOOE+00 | 743E-03 |

bull bull bull -

Convecfion path -bull

length

Lp (cm)

Source vapor cone

-source

(Mgm)

Crack radius

fcrack

(cm)

Average vapor

flow rate into bIdg

Qaoil bull

(cms)

Crack effective diffusion

coefficient pcack

(cms)

Area of crack

crack

(cm)-

Exponent of equivalent foundation

Peclet number

exp(Pef)

(unitless)

bull

1 15 -1 603E+03 1 010 1 474E+01 743E-03 354E+03 1 697E+07

Infinite source Indoor

attenuation coefficient

poundbullbullbull C t

pound(unitless)

bullsiilaquogt j ii08E-05

Infinite [ source

bIdg cone

Cbujidjng

(pgm)

651 E-02 iKrt

Unit risk

factor

URF

(ngm)-

Reference cone

RfC

(mgm)

NA 35E-02 1

I END I

Appx B-2 cis-12-DCExls 3o f3 982009

AR100313

APPENDIX B-3-A DATA ENTRY SHEET

Coyne Texti le Services - Hunt ington West Virginia

SG-ADV Version 31 0204

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

67663

Soil Gas Concentration Data ENTER ENTER

Soil Soil gas gas

cone OR cone c C

(^gm) (ppmv)

591 E+03

bull

Chemical

Chloroform

MORE ENTER Depth

below grade tb bottom

of enclosed space floor

bull LF

(cm)

ENTER

Soil gas sampling depth

below grade

(cm)

ENTER

Average soil

temperature-Ts

CO bull

1 15 1 15 1 125

ENTER ENTER ENTER Totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

IIA hs he (cm) (cm) (cm)

1 5 bull 1 1

ENTER ENTER Soil - bull

stratum A User-defined SCS stratum A

soil type bull soil vapor (used to estimate OR permeability

soil vapor k

bull permeability) (cm) 1

SL 1 1 bull

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A soil dry

bulk density

Pb (gcm)

ENTER Stratum A soil total porosity

nV (unitless)

ENTER Stratum A

-soilwater-filled bullporosity

Sraquo (cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

(unitless)

ENTER Stratum B

soil water-filled porosity

bull ebdquo=

(cmcm) bull

ENTER Straturri C

SCS bull soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

- c rack

(cm)

ENTER

Soil-bldg pressure

differential AP^

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor

width bull W B

(cm)

ENTER

Enclosed space

height HB

(cm)

ENTER

bull Floor-wall^ seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bidg OR

Leave blank to calculi

Qsoil bull

(Lm)

I -I

Appx B-3 Chloroformxls 1 of 3 982009

AR100314

APPENDIX B-3-B CHEMICALPROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Diffusivity in air

D (cms)

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffijsivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature

Dbdquo H TR A H bdquo TB Tc

(cm s) (atm-m mol) ro (calmol) (degK) (degK)

Molecular weight

MW

(gmol)

Unit risk

factor URF

(ngm)-

Reference cone

RfC

(mgm)

104E-01 100E-05 I 366E-03 25 6988 33432 53640 11938 I 23E-05 | OOE+00

Appx B-3 Chloroformxls 2 of 3 982009

AR100315

APPENDIX B-3-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure

duration

(sec)

Source-

building

separation

LT

(cm)

Stratum A

soil

air-filled

porosity

Sa

( cm cm )

Stratum B

soil

air-filled

porosity

( cm cm )

Stratum C

soil

air-filled

porosity

( c m c m )

Stratum A

effective

total fluid

saturation

( c m c m )

Stratum A

soil

intrinsic

penmeability

k

(cm )

Stratum A

- soil

relative air

permeabil i ty

(cm )

Stratum A

soil

effective vapor

permeability

kv

(cm )

Floor-

wall

seam

perimeter

gtcrack

(cm)

Soil gas

cone

(ngm)

BIdg

venfilation

rate

^buildlriE

(cms)

I 9 4 6 E + 0 8 ~ T I 0284 T 596E-09 I 0-901 I 537E-09 | 35357 | 591 E+03 j 439E+06 | 1 0 284 0284 0184

Area of

enclosed

space

below

grade

A B

( c m )

Crack-

to-total

area

ratio

n

(unitless)

Crack

depth

bull below

grade

^crack

(cm)

Enthalpy of

vaporization at

ave soil

temperature

AHTs bull

(calmol)

Henry s law

constant at

ave soil

temperature

HTS

(a tm-m mol j

Henrys law

constant at

ave soil

bull temperature

HTS

(unitless) bull

Vapor

viscosity at

ave soil-

temperature

^HTS

(gcm-s)

Stratum

A

effective

diffusion

coefficient

(cm s)

Stratum

B

effective

difftjsion

coefficient

D B

(cms) bull

S t ra tum

C

effective

diffusion

coefficient

Dc

(cm s)

Total

overall

effective

bull diffusion

coefficient

D T

(cm s)

Diffi jsion

path

length

Ld

(cm)

I 787E+07 I 449E-05 j - bull 15 7528 210E-03 896E-02 176E-04 I 105E-02 | OOOE+00 | OOOE+00 | 105E-02

Convection

path length

Lp

(cm)

Source

vapor

cone -

^source

- (ngm)

Crack

radius

Tcrack

(cm)

Average

vapor

flow rate

into bidg

Qsoil

(cms)

Crack

effective

diffusion

coefficient Qcrack

bull (cms)

Area of crack

Acrack

(cm)

Exponent of

equivalent

foundation

Peclet number

exp(Pe)

(unitless)

V bull bull

1 15 1 591 E+03 1 010 1 474E+01 105E-02 354E+03 1 355E+05

Infinite

source

indoor

attenuation

coefficient

d

(unitless)

bull 108E-05

Infinite

source

bIdg

cone

^ b u i l d i n g

i (^gm)

bull bull

i 638E-02 -

Unit

risk bull factor

URF

(ngmY

Reference

cone

RfC

(mgm)

~ 23E-05 NA 1

I END

Appx B-3 Chloroform xls 3 of 3 982009

AR100316

APPENDIX B-4-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ersion 31-020^

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

nodashes)

bull 75092

ENTER Soil gas

cone

c (ngm)

Soil Gas Concentration Data ENTER

Soil gas bull

OR cone

bull C

(ppmv)

152E+03

bull bull

Chemical

Methylene chloride

MORE

MORE 4gt

ENTER Depth

below grade to bottom

of enclosed space floor

LF -

(cm)

ENTER

Soil gas sampling depth

below grade

bull U

(cm)

ENTER

Average soil

temperature

Ts bull CC)

bull bull bull bull

1 15 1 15 125

ENTER Totals

Thickness of soil

stratum A h

(cm)

ENTER ENTER must add up to value of Ls (cell F24

Thickness Thickness of soil of soil

stratum B stratum C (Enter value or 0) (Enter value or 0)

he he bull

(cm) bull (cm) -

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(usedto estimate OR perrrieability | soil vapor

permeability)

k bull

(cm)

SL 1 bull 1

ENTER Stratum A

SCS soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

Pb (gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Stratum A

soil water-filled porosity

9w (cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

Pb^

(gcm)

ENTER Stratum B soil total porosity

n^

(unitless)

ENTER Stratum B

soil water-filled porosity

(crhcm)

ENTER Stratum C

SCS soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE 4gt

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

bull Soil-bldg pressure

differential AP^

(gcm-s)

ENTER Enclosed

space floor

length LB

(cm)

ENTER Enclosed

space floor

width bull W B

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width

w

(cm)

ENTER

Indoor air exchange

rate

ER (1h)

ENTER Average vapor

flow rate into bidg OR

Leave blank to calculc

Qsoil

(Lm)

10 40 8839 8839 244 01 083

Appx B-4 MCxIs 1 of 3 982009

AR100317

Diffijsivity in air

D

APPENDIX B-4-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffusivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature

Pw H TR AHt TB TC

Molecular weight

MW

Unit risk

factor URF

Reference cone

RfC

(cms) (cms) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) bull (ngm)- (mgm)

bull bull

1 101E-01 1 117E-05 1 218E-03 1 25 | 6706 1 31300 1 51000 1 8493 1 47E-07 1 30E+00 1

Appx B-4 MCxIs 2 of 3 982009

AR100318

APPENDIX B-4-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

T

(sec)

Source- -building

separation

LT

(cm)

Stratum A soil

air-filled porosity

e a bull

(cmcm)

Stratum B soil

bullair-filled porosity bull

ea^ (cmcm)

Stratum C soil

air-filled porosity

ea= (cmcmj

Stratum A effective total fluid

saturation

Sc bull

(cmcm)

Stratum A soil

intrinsic pemneability

ki (cm)

Stratum A soil

relative air permeability

^ ^ g

(cm)

stratumA bull soil effective vapor permeability

K (cm)

Floor-wall

seam perimeter

Xcrack

(cm)

Soil gas

cone (ngm)

BIdg ventilation

rate

Qbuildinc

(cms)

1 946E+08

Area of -enclosed

space below

bull grade

AB

(cm)

1

Crack-to-total

area rafio

Tl

(unitless)

0284 1

Crack depth below grade

Zcrack

(cm)

0284 1

bull Enthalpy of vaporization at

ave soil temperature

AHTs (calmol)

0284

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

0184

Henrys law constant at ave soil

temperature

HTS

bull (unitless)

1 596E-09

Vapor viscosity at

ave soil temperature

Mrs (gcm-s)

0901

Stratum A

effective diffusion

coefficient

D (cms)

537E-09

Stratum B

effective diffusion

coefficient

D-B (cms)

35357 1

Stratum C -

effective diffusion

coefficient

D-c ^ (cms)

152E+03

Total bull overall

bull effective diffusion

coefficient

D ^

(cms)

440E+06 1

Difftjsion path

length

Ld (cm)

1 787E+07

Convection path

length

Lp (cm)

4 49E-05

Source vapor cone

Csource

(ngm)

15 1

Crack radius

Tcrack

(cm)

7007 bull 1

Average vapor

flow rate intobldg

Qsoil

(cms)

130E-03

Crack effective diffusion

coefficient pcrack

(cms)-

555E-02

bull ^

Area of crack

Acrack

(cm) bull

1 176E-04

Exponent of equivalent foundation

Peclet number

exp(Pe)

(unitless) bull

bull bull

1 15

1 END

152E+03 010 1 474E+01 1 102E-02 354E+03 1 519E+05

102E-02

Infinite source

indoor ^attenuation coefficient

bull a

(unitless)

aiii08E-05

0 OOE+00

bull

Infinite bull source

bIdg ^ cone

^bu i l d i ng

(MQm)

164E-02

OOOE+00 1

Unit risk

factor

URF

(ngm)-

47E-07 1

102E-02 j

Reference cone

RfC

(mgm)

30E+00 j

1 1

Appx B-4 MCxIs 3 of 3 982009

AR100319

APPENDIX B-5-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ^erslon 31 0204

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

127184

Soil Gas Concentration Data ENTER ^ ENTER

Soil -Soi l bull gas gas

cone OR cone Cg C bull

(tgm) (ppmv)

149E+05 1

Chemical

bull Tetrachlbroethylene

MORE 4

ENTER Depth

below grade to bottom

ofenclosecJ space floor

LF

(cm)

ENTER

Soil gas bull sampling

depth below grade

u bull (cm)

ENTER

Average bullsoil

temperature - Ts

ro 1 1 5 1 15 1 125 bull

ENTER ENTER ENTER totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hft bull he bull he

(cm) (cm) (cm)

bull 1 5 1 - 1

ENTER ENTER Soil

stratum A User^defined bull SCS bull stratum A soil type soil vapor

(used to estimate OR perrrieability soil vapor K bull

permeability) (cm) 1

SL 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

Pb

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Sitratum A

soil water-filled bull porosity

(cmcm)

ENTER Stratum B

SCS soiltype

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

Pb^

(gcm)

ENTER Stratum B soil total porosity

Ajnitless^

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS soil type

LookupSoil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

VS

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor width

W B

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width

w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

ENTER Average vapor

flow rate into bidg OR

Leave blank to calcul

bull Qsoil

(Lm)

10 40 8839 8839 244 01 083

Appx B-5 PCExIS 1 of 3 982009

AR100320

APPENDIX B-5-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal Unit

Diffusivity Diffusivity at reference reference the riormal boiling Critical Molecular risk Reference in air in water temperature temperature boiling point point teriiperature weight factor cone

Da Dbdquo H TR AHb TB Tc MW URF RfC

(cms) (cnis) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) (^gm)- (mgm)

1 720E-02 1 820E-06 1 184E-02 1 25 1 8288 1 39440 1 62020 1 16583 1 59E-06 1 60E-01 1

J

AppxB-5PCExls 2 of 3 - 982009

AR100321

APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

T

(sec)

Source-building

separation

LT

bull (cm)

Stratum A soil

air-filled porosity

Oa (cmcm)

Stratum B - soil air-filled porosity

ea (cmcm)

Stratum C soil

air-filled porosity

ea= - (cmcm)

Stratum A effective total fluid

saturation

sbdquo (cmcm)

Stratum A soil

intrinsic permeability

ki (cm)

Stratum A soil

relative air permeability

- ^ g

(cm)

Stratum A soil

effective vapor permeability

kv (cm)

Floor-wall

seam perimeter

^crack

(cm)

Soil gas

cone

(ngm)

BIdg venfilation

rate

Qbuildins

bull (cms)

bull bull

1 946E+08

Area of enclosed

space below grade

AB

(cm)

1

bullCrack-to-total

area ratio

1 (unitless)

0284 1

Crack bull depth below grade

Zcrack

(cm) -

0284 1

Enthalpy of vaporization at bull

ave soil temperature

bull A H V TS

(calmol)

0284

Henrys law constant at

ave soil temperature

HTS (atm-mmol)

0184

-Henrys law constant at

ave soil temperature

HTS

(unitless)

1 596E-09

Vapor viscosity at

ave soil temperature

HTS

(gcm-s)

0901

Stratum A

effective diffusion

coefficient bull D = bull

(cms)

537E-09

Stratum B

effective diffusion

coefficient

D--B (cms)

35357 1

Stratum C

effective diffusion bull

coefficient

D-c (crris)

149E+05

Total overall

effective bulldiffusion coefficient

DT

(cms)

440E+06 1

Difftjsion path

length

U (cm)

1 787E+07

Convection path

length

bull Lp

(cm)

4 49E-05

Source vapor cone

^source

(ngm)

15 1

Crack radius

Tcrack

(cm)

9528 1

Average vapor

flow rate intobldg

Qsoil (cms)

908E-03

Crack effective diffusion

coefficient pcrack

bull ( c m s ) bull

387E-01

Area of crack

Abdquoack (cm)

1 176E-04

Exponent of equivalent foundafion

Peclet number

exp(Pe)

(unitless)

bull

1 15-

1 END

149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08

727E-03

Infinite source indoor

attenuation coefficient

a

(unitless)

108E-05

OOOE+00

Infinite source

bIdg cone

Cburldtng

(Mgm)

161 E+00

OOOE+00 1

Unit risk

factor

URF

(ugm)-

59E-06 1

727E-03

Reference cone

RfC (mgm)

60E-01

1 1

Appx B-5 PCExls 3 of 3 982009

AR100322

APPENDIX B-6-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ersion31 0204

Reset to Defaults

t

Soil Gas Concentration Data ENTER

Chemical CAS No

(numbers only

no dashes)

79016

ENTER ENTER Soil Soil gas gas

cone OR cone C C -

bull (ngm) (ppmv)

782E+03

Chemical

Trichloroethylene

MORE ENTER Depth

below grade to bottom-

of enclosed space floor

LF

(cm)

ENTER

Soil gas sarnpling

depth below grade

U (cm)

ENTER

Average soil

temperature Ts

(degC)

1 15 1 15 t 125

ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e

(cm) (cm) (cm)

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estimate OR permeability soil vapor

permeability)

k (cm)

bull S L 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil bull-Parameters

ENTER Stratum A

soil dry bulk density

P b -

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Stratum A bull

soilwaterrfilled porosity

(cmcm) bull

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

bull P ^ (gcm)

ENTER Stratum B soil total

porosity

nlaquo

(unitless) -

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS bull soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor

width W B

(cm)

ENTER

Enclosed space height

H B bull

( c m ) bull

ENTER

Floor-wall seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bIdg OR

Leave blank to calculc

Qsoil

(Lm) -

Appx B-6 TCExIs 1 of 3 982009

A

AR100323

APPENDIX B-6-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight

Da Dbdquo H TR AH^b TB TC MW

Unit risk Reference

factor cone URF RfC

(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)

1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1

Appx B-6 TCExIs 2 of 3 982009

AR100324

APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

(sec)

Source-building

separation LT

(cm)

Stratum A soil

air-filled porosity

bull ea (cmcm)

Stratum B Soil

air-fllled porosity

e^ bull (cmcm)

Stratum C soil

air-filled porosity

(cmcm)

StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air

saturation permeability permeability

S|e k krg (cmcm) (cm) (cm)

Stratum A Floor-soil wall BIdg

effective vapor seam Soil ventilafion permeability perimeter gas rate

k^ bull Xack c o n e Qbuildins

(cm) (cm) (ngm) (cms)

946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |

Area of enclosed

space below grade

AB

(cm)

Ciack- to-total

area ratio

1 (unitless)

Crack depth below grade

Zcrack

(cm)

Enthalpy of vaporization at

ave soil temperature

A H J S

(calmol)

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law bull constant at

ave soil temperature

HTS

(unitless)

Vapor viscosity at

ave soil temperature

|JTS

(gcm^s)

Stratum A

effective diffusion

coefficient

(cms)

Stratum B

effective -diffusion

coefficient

D=B (cms)

Stratum ^ C effective diffusion

coefficient

D=c (cms)

Total overall

effective diffusion

coefficient

DT

(cms)

I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03

Diffusion path

length

Li (cm) bull

Convection bull path

length

Lp

(cm)

Source vapor cone bull

^source

(ngm)

Crack radius

rcrack

(cm)

Average vapor

- flow rate intobldg

Qsoil

(cms)

Crack effective diffusion

bull coefficient Qcrack

(cms)

Area of crack

^crack

(cm)

Exponent of equivalent foundation

Peclet bull number

exp(Pe)

(unitless)

bull bull

1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07

Infinite source Indoor

attenuation coefficient

a

(unitless)

108E-05

Infinite source

bIdg concgt

^building

(ngm)

844E-02

Unit risk

factor

URF

(ngm)-

Reference cone

RfC

(mgm)

1 1E-04 1 40E-02 1

END

Appx B-6 TCExIs 3 of 3 982009

AR100325

Office of Waste Management 1356 Hansford Street

Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256

West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director

ORDER

ISSUED UNDER THE

HAZARDOUS WASTE MANAGEMENT ACT

CHAPTER 22 ARTICLE 18

OF THE WEST VIRGINIA CODE^ AS AMENDED

y Order Number HW-011-80

To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704

ATTEMTION MREDARMON

Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull

AR100326

ViWJ011-laquo9 PageNunil)er2

BASIS FOR ORDER

As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following

A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^

B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator

C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities

0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94

^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement

P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following

1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater

2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was

^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment

CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable

CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order

AR100327

H W - 0 1 1 - 9 9 Page Number 3

REQUIREMENTS OF ORDER

Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows

1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^

2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore

remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling

GENERAL PROVaiONS

1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order

2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order

3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order

Effective Date

Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief

Wt T 1 V Oflice of Waste Management

AR100328

^ ^ S I S

^wmmmmamn

AR100329

Page 19: SDMS DocID 2121999 · International Enterprises Corp. building (Coyne Building), which is located at 1111 Vernon Street, Westmoreland District, Wayne County, West Virginia. The following

TABLE 2

IDENTIFICATION OF CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR

Coyne Textile Services Facility - Huntington West Virginia

Const i tuent

Volati le Organics

Chloroform -

Chloromethane

13-Dichloropropene (cis)

Cyclohexarie^

Dibrcimochloromethane

DichlonDdifluoromethane

Ethylbenzene

Methyl ethyl ketone

Methyl isobutyl ketone

Methyl tert-butyl ether

Methylene chloride

n-Heptane

n-Hexane

Styrene

Tert-butyl alcohol

Tetrachloroethene

Toluene

13-Dichloropropene(trans)

Triehloroethene

Trichlorofluoromethane

Vinyl bromide

Vinyl chloride

Xylene (0)

Xylenes (mampp)

Frequency of Detection

1 3

0 3

0 3

1 3

0 3

0 3

0 -3

1 3

0 3

0 3

2 3

0 3

3 3

0 3

0 3

3 3

1 3

- 0 3

3 3

P 3

0 3

0 3

1 3

1 3

Min imum Detected

Concentrat ion

(ugm)

5910

ND

ND

52

ND

ND

ND

23

ND

ND

1160

ND

1 4 4

ND

ND

11200

18

ND

91

ND

ND

ND

208

387

Maximuri i Detected

Concentrat ion (ugmS)

bull

5910

ND

ND

52

bull ND

ND

ND

23

ND

ND

1520

ND

183

ND

ND

149000

18

ND

7820

ND

bullND

ND

208

387

Sample vyith Max imum Detect

VP-02

ND

ND

VP-01

bull ND

ND

ND

VP-01

ND

ND

VP-02

ND

VP-02

ND

ND

VP-02

VP-01

ND

VP-03

ND

ND

ND

VP-03

VP-03

Min imum Detection

Limit (ugm3)

20

83

18

138

34

bull 20

17

118

16

14

14

16

- -17

12

--151

18

--23

18

10

1 7 bull

1 7 bull

Maximum Detection

Limit (ugm3)

195

83

182

138

341

198

174

118

164

144

14

164

170

121 -

--151

182

225

175

102

bull 174

174

Vapor Intrusion Compar ison

V a l u e

(ugm)

11

24

NA

2000

1

2000

22

10000

800

30000

52

NA

2000

10000

NA

81

4000

NA

022

7000

NA

28

70000

70000

Chemical o f Concern

YES

No

No

No

No bull

No

No bull

No bull=

No

No

YES

No

No

No

No

YES

No

No

YES

N o

No

No

No

No

Comment

Maximum detect exceeds comparison value

Constituent not detected

Constituent not detected

Maximum detect below comparison value

Constituent not detected

Constituent not detected

Constituent not detected

Maximum detect below comparison value

Constituent not detected

Constituent not detected

Maximum detect exceeds comparison value

Constituent not detected bull

Maximum detect below comparison value

Constituent not detected

Constituent not detected

Maximum detect exceeds comparison value

Maximum detect below comparison value

Constituent not detected

Maximum detect exceeds comparison value

Constituent not detected

Constituent not detected

Constituent not detected bull

Maximum detect below comparison value

Maximum detect below comparison value

Notes

ND - Not Detected

NA - Not Available

- - Constituent detected in every sample detection limit not presented

Values in bold indicate detection limit exceeds comparison values

Target shallow soil gas comparison values corresponding to indoor air concentrations where the soil gas to indoor air attenuation factor = 01 and the target cancer risk is set to ip (presented in Table 2c of USEPA 2002a)

Comparison value for cyclohexane is based on the comparison value for hexane

Coyne VI Memo Tables_09-08-09xls 982009

AR100296

TABLES

EXPOSURE POINT CONCENTRATIONS FOR CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR

Coyne Textile Services Facility - Huntington West Virginia

Chemical of Concern

VolatileOrganics

i24-Trimethylbenzene

12-Dichloroethene (cis)

Chloroform

Methylene chloride

Tetrachloroethene Triehloroethene

Subslab Vapor Source

Concentration (mgm^)

0197

603

591

152

149 782

Transport

Factor^ (unitless)

108E-05

108E-05

108E-05

108E-05

108E-05 108E-05

EPC in

Indoor Air (mgm^)

213E-06

651 E-05

638E-05

164E-05

161E-03 844E-05

Notes

^ Subslab vapor source concentration is based on the maximum detected concentration of samples

VP-01-02 and-03 (see Table 2) -

^ Details of the transport factor calculations are presented in Appendix B

^ Exposure Point Concentration (EPC) in inidoor air is calculated as the subslab vapor concentration TF

Coyne VI Memo Tables_09-08-09xls 982009

AR100297

TABLE 4

FACTORS USED IN DOSE CALCULATIONS INHALATION OF VOLATILE EMISSIONS

Coyne Textile Services Facility - Huntington West Virginia

Symbol

CA

IRA

ET

EF

ED-

BW

AT

Exposure Factor

Constituent Concentration in Air

Inhalation Rate

Exposure Time

Exposure Frequency

Exposure Duration

Body Weight

Averaging Time

Indoor Worker

Constituent-Specific See Table 3

25 m hour

8 hrday

250 daysyear

25 years

bull 70 kg

9125 days (NC)

25550 days (C)

Total Dose = CA x IR^ x ET x EF x ED x 1BW x 1AT

(NC) - Non-carcinogenic Averaging Time

(C) - Carcinogenic Averaging Time

Coyne VI Memo Tables_09-08-09xls 982009

AR100298

TABLES TOXICITY VALUES FOR CHEMICALS OF CONCERN

Coyne Textile Services Facility - Huntington West Virginia

Chemical of Concern

Volatile Organics

124-Trimethylbenzene

12-Dichloroethene (cis)

Chloroform

Methylene chloride

tetrachloroethene

Triehloroethene

Target Organ Critical Effect

blood

bullblood

liver

liver

liver CMS

liver kidney fetus CNS

Chroniclnhalation Reference Dose

(mgkg-day)

200E-03 P

1 OOE-02 R

140E-02 E

286E-01 M

771 E-02 M

1OOE-02 E

Inhalation Cancer ^ Slope Factor

(mgkg-day)^

NA

NA

805E-02 1

165E-03 1

200E-02 0

400E-01 E

(I) - Integrated Risk Information System (IRIS USEPA 2009)

(P) - Provisional Peer-Reviewed Toxicity Value (PPRTV) as presented in USEPA Regional Screening Tables (ORNL 2009)

(R) - Calculated assuming route-to-route extrapolation as per WVDEP

(E)-Provisional value from the National Center for Environmental Assessment (as per WVDEP)

(M)-Chronic Minimal Risk Level (MRL ATSDR 2009)

(0) - Value cited by USEPA Region 3 attributed to other sources (as per WVDEP)

Coyne VI Memo Tables_09-08-09xls 982009

AR100299

TABLE 6

NONCANCER HAZARD INDEX AND POTENTIAL CANCER RISK FOR AN INDOOR WORKER

Coyne Textile Services Facility - Huntington West Virginia

bull

Constituent

Volatile Organics

124-Trinnethylbehzene

12-Dichlorpethene (cis)

Chloroform

Methylene chloride

Tetrachloroethene Triehloroethene

EPC in Indoor Air

(mgm)

213E-06

651 E-05

- 638E-05

164E-05

161 E-03

844E-05

Intake (ADD)

(mgkg-d)

416E-07

127E-05

125E-05

321 E-06

315E-04 l65E-05

RfDi

(mgkg-d)

200E-03

1OOE-02

140E-02

286E-01

771 E-02 1 OOE-02

Hazard

Quotient

208E-04

127E-03

892E-04

112E-05

408E-03 165E-03

Intake (LADD)

(mgkg-d)

) 149E-07

455E-06 bull 446E-06

115E-06

112E-04 590E-06

CSFi

(mgkg-d)

NA

NA

805E-02

165E-03

200E-02

400E-01

Potential

Cancer Risk

NA

NA

359E-07

189E-09

225E-06 236E-06

Total Hazard Index

00081 Total

Cancer Risk 497E-06

Total Blood HI = Total Liver HI =

Total Central Nervous System HI = Total Kidney HI =

Total Fetal HI =

bull 00015 00066 00057 00017 00017

Notes NA = Toxicity values are not available for this endpoint or exposure pathway

Coyne VI Memo Tables_09-08-09xls 982009

AR100300

APPENDIX A

SUBSLAB VAPOR ANALYTICAL DATA

AR100301

Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility Huntington West Virginia

Sample

Consti tuent

Volatile Organics (ugm) 111-Trlchloroethane 1122-Tetrachloroethane 112-Trichloro-122-trifluoroethane 112-Trichloroethane 11-Dichioroethane 11-Dichloroethene 124-Trichloroberi2ene 124-Trimethylbenzene 12-Dibromoethane 12-Dichloroben2ene 12-Dichloroethane 12-Dichloroethene-(cis) -12-Dichloroethene (trans) 12-Dichloropropane 12-Dichlorotetrafluoroethane 135-Trimethylbenzene 13-Butadiene 13-Dichlorobenzene 13-Hexachlorobutadiene 14-Dichlorobenzene 224-trimethVlpentane 2-Chlorotoluene 4-Ethyltoluene Acetone Allyl Chloride Benzene Bromodichloromethane Bromoform Bromomethane Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 13-Dichloropropene (cis) Cyclohexane Dibromochloromethane

Identif ication Sample Date

CAS No

71-55-6 79-34-5 76-13-1 79-00-5 75-34-3 75-35-4 120-82-1 95-63-6 106-93-4 95-50-1 107-06-2 156-59-2 156-60-5 78-87-5 76-14-2 108-67-8 106-99^0 541-73-1 87-68-3 106-46-7 540-84r1 95-49-8

622-96-8 67-64-1 107-05-1 71-43-2 75-27-4 75-252 74-83-9 75-15-0 56-23-5 108-90-7 75-00-3 67-66-3 74-87-3

10061-01-5 110-82-7 124-48-1

lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt

lt lt lt lt lt lt lt lt lt lt lt lt

lt

VP-01 8132009

22 28 31 22 16 16 30 20 31 24 16 16 16 19 28 20 89 24 43 24

1 9 21 20 796 13 13 27 41 16 13 25 18 11 20 83 18 52 34

lt lt lt lt lt lt lt lt lt lt lt

lt lt lt lt lt lt lt lt lt lt lt

lt lt lt lt lt lt lt lt lt

lt lt lt lt

VP-02 8132009

218 2 7 5 307 218 162 159 297

bull 197 307 240 162 369 159 185 280 197 89

240 427 240 187 207 197

1880 125 128 268 414 155 125 252 184 106

5910 83 182 138 341

lt lt lt lt lt lt lt

lt lt lt

lt lt lt lt lt lt lt bull

lt lt lt lt

lt lt lt lt lt lt lt lt lt lt lt lt lt lt

VP-03 8132009

218 275 307 218

bull 162 159 297 197 307 240 162

6030 159 185 280 197 89

240 427 240 187 207 197

1750 125 128 268 414 155 125 252 184 106 195 83 182 138 341

Appx A SG Dataxis Page 1 of 2 982009

AR100302

Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility bull Huntington West Virginia

Consti tuent

Volatile Organics (ugm^) Dichlorodifluoromethane Ethylbenzene Methyl ethyl ketone Methyl Isobutyl ketone Methyl tert-butyl ether Methylene chloride n-Heptane jn-Hexane Styrene Tert-butyl alcohol Tetrachloroethene iToluene 13-Dichloropropene (trans) Triehloroethene Trichlorofluoromethane Vinyl bromide Vinyl chloride Xylene (o) Xylenes (mampp)

Sample Identif ication Sample Date

CAS No

75-71-8 100-41-4 78-93-3 108-10-1

1634-04-4 75-09-2

142-82-5 bull 110-54-3

100-42-5 75-65-0 127-18-4 108-88-3

10061-02-6 79-01-6 75-69-4 593-60-2 75-01-4 95-47-6

179601-23-1

lt lt

lt lt lt lt

lt lt

lt

lt lt lt lt lt

VP01 8132009

20 17 23 16 14 14 16

173 17 12 bull

11200 18 18 91 23 18 10 17 17

lt lt lt lt lt

lt

lt lt

lt lt

lt lt lt lt lt

VP-02 8132009

198 174 118 164 144

1520 164 -183 170 121

149000 151 182

2360 225 175 102 174 174

VP-03 8132009

lt 198 lt 174 lt 118 lt 164 lt 144

1160 lt 164

144 lt 170 ltbull 121

90500 lt 151 lt 182

7820 lt 225 lt 175 lt 102

208 387

Appx A SG Dataxis Page 2 of 2 982009

AR100303

APPENDIX B

CALCULATION OF TRANSPORT FACTORS USED TO ESTIMATE INDOOR AIR CONCENTRATIONS

AR100304

APPENDIX B

Calculation of Transport Factors Used to Estimate Indoor Air Concentrations

This appendix presents the methodology for calculating transport factors that are used to convert subslab

vapor concentrations to concentrations in indoor air 124-Trimethylbenzene 12-dichloroethene (cis)

chloroform methylene chloride tetrachloroethene and triehloroethene were identified as contaminants of

concern (COC) for potential vapor intrusion from subslab vapor associated with the Coyne Textile

Services Facility located in Huntington West Virginia (site) In this appendix the transport factors are

calculated to estimate the concentrations of COC in indoor air of the existing plant building located at the

site ~

Transport Factor for Indoor Air

The concentration of a constituent in indoor air (da) is proportional to the concentration of the constituent

in the subslab vapors immediately beneath the building foundation (ie subslab vapor concentration or

Csubsiab) The following equation is used to calculate da from Csubsiab

^ wja ~ ^subslab X I r

where

Cia = concentration of constituent in indoor air (mgm^) -

Csubsiab^ concentration of constituent in subslab vapors (mgm^) and

TF = transport factor from subslab vapors to indoor air

The transport factor (TF) is an infinite source attenuation coefficient andcan be calculated based on a

model developed by Johnson and Ettinger (1991) t he equation for calculating TF is as follows

(Deff X A B ) ( Q B X L T ) X expKQso i l X Lcrabk)(Dcrack X Acrack)]

exp[ (Qsoi l X Lcrack)(Dcrack X Acrack)] + (Deff X A B ) ( Q B X L T ) + (Deff X AB)(Qsoi l X L j ) X (exp [ (Qso i l X Lcrack)(Dcrack X Acrack)] - 1)

where

Deff = effective diffusion coefficient for vadose zone soil (cm^sec)

AB = area of enclosed space below grade (cm^)

QB = building ventilation rate (cm^sec)

LT = distance from contaminant source to building foundation (cm)

Qsoii = volumetric flow rate of vapors into the building (cm^sec)

Lcrack = foundatlon thickness (cm)

Dcrack = vapor diffusion coefficient through crack (cm^sec) and

Acrack = area of cracks through which vapors can pass (cm^)

AR100305

To solve this equation the USEPAs SG-ADV spreadsheet Version 31 most recently updated in

February 2004 was implemented A combination of site-specific factors and default values from the

Users Guide for Evaluating Subsurface Vapor Intrusion Into Buildings (USEPA 2004) were used as input

values in the model All input values are defined below and presented in Tables B-1-A through B-6-A

bull The initial subslab vapor concentration (Csubsiab) is the maximum detected concentration(in units

of ugm ) of samples VP-01 VP-02 and VP-03 that was presented in Table 3 of the report

bull The depth below grade to the bottom of the enclosed space floor (Lp) is set to 15 cm the default

value provided by USEPA (2004) for a slab-on-grade structure

bull The vapor sampling depth below grade (Lg) is a site-specific value The vapor samples were

collected from immediately beneath the building floor therefore Lj has been set to 15 cm

bull The average soilgroundwater temperature (Ts) is set to 125degC the average value for West

Virginia as estimated frorri Figure 8 of the vapor intrusion users guide (USEPA 2004)

bull The soil type used to estimate vapor permeability is assumed to be sandy loam (SL) The

associated soil properties for a sandy loam soil type are as follows the soil dry bulk density (Pb) is

162 gcm the total porosity (n) is 0387 (cm^-aircm^) and the water-filled porosity (nw) is 0103

(cm -HzOcm )

bull The floor thickness (Lcrack) is set to the USEPA (2004) default value of 10 cm

bull The soil-building pressure differential (AP) is set to the USEPA (2004) default value of 40 gcm-s^

bull The building dimensions are siterspecific based on the existing plant building located at the site

The existing structure is approximately 84000 square feet (Dolphin 2000) therefore the

dimensions are set to 8839 cm (290 feet) length by 8839 cm (290 feet) The USEPA (2004)

default value of 244 cm vyas used for the height

bull Thefloor-wall seam crack width (w) is set to the USEPA (2004)-default value of 01 cm

bull The indoor air exchange rate (ER) is set to 083hour This is the value provided by ASTM (2002)

for commercial and industrial buildings

AR100306

Tables B-1-B through B-6-B present the constituent-specific properties for COC that were used in the TF

calculations Tables B-1-C through B-6-C present the intermediate calculations used to determine the

indoor air attenuation coefficients (ie the transport factors) The shaded boxes in Tables B-1-C through

B-6-C also present the resulting TF values that are applied to the concentrations of COC in subslab

vapor and the estimated indoor air concentrations

References

American Society for Testing and Materials (ASTM 2002) Standard Guide for Risk-Based Corrective Action Applied at Petroleum Release Sites ASTM E-1739-95 (Reapproved 2002)

Johnson PC and RA Ettinger (1991) Heuristic model for predicting the intrusion r-ate of contaminant vapors into buildings Environ Sci Technolpgy 25 1445-1452

Dolphin Environmental LLC (Dolphin 2000) Site Characterization Report Mach 14 2000

United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004

AR100307

APPENDIX B-1-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV Nersion31 0204

Reset to Defaults

ENTER -

Chemical CAS No

(numbers only

no dasties)

95636

ENTER Soil gas

cone

Cg (ngm)

Soil Gas Concentration Data ENTER

Soil gas

OR cone

bull - c bull (PPmv)

197E+02

Chemical

124-Trimethylbenzene

MORE ENTER Depth

below grade to bottom

of enclosed space floor

U bull (cm)

ENTER

Soil gas sampling

depth below grade

U (cm) bull

ENTER

Average soil

temperature Ts

CO

1 15 1 1 5 bull125

ENTER ENTER ENTER Totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hft ha he

(cm) (cm) (cm)

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estirnate OR permeability | soil vapor

permeability) k v bull

(cm)

SL 1 1

MORE ENTER

stratum A SCS

soil type

Lookup Soil Parameters

ENTER stratum A soil dry

bulk density P

(gcm)

ENTER Stratum A soil total porosity

(unitless)

ENTER bull stratum A soil water-filled

porosity

(cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

nlaquo

(unitless)

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gchi-s^)

ENTER Enclosed

space floor

length bull LB

(cm)

ENTER Enclosed

space floor

width WB

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

bull Floor-wall seam crack

width w

(cm)

bullENTER

Indoor air exchange

rate ER

(1h) bull

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bidg OR

Leave blank to caicuij

(Lm)

Appx B-1 124-TMBxls 1 of 3 982009

AR100308

APPENDIX B-1-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of ^ bull law constant law constant vaporization at Normal

Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temperature boiling point point temperature weight

D bull Dbdquo H T R bull AHbdquo TB Tc IVIW

Unit risk Reference

factor cone URF RfC

(cms) (cmls) (atm-mmol) CO (calmol) (degK) (degK) (gmol) bull (ugm)- (mgm)

1 606E-02 1 792E-06 1 bull 614E-C3 1 25 1 9369 1 44230 | 64917 1 12020 1 OOE+00 1 60E-03 1

Appx B-1 124-TMBxls 2 of 3 982009

AR100309

APPENDIX B-1-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

(sec)

Source-building

separation

LT bull

(cm) bull

Stratum A soil

air-filled porosity

Q A

Stratum B soil

air-filled porosity

(cmcm) (cmcm)

Stratum C soil air-filled porosity

(cmcm)

Stratum A effective total fluid

saturation

Se

(cmcm)

Stratum A soil

bullintrinsic permeability

^ (cm)

stratum A Stratum A Floor- soil soli wall BIdg

relative air effective vapor seam Soil bull ventilation permeability permeability perimeter gas rate-

kfg ky Xgrack c o n e - QbuHdinpound

(cm) - (cm) (cm) (ngm) (cms)

946E+08 1 0284 0284 0284 0184 596E-09 0901 537E-09 35357 I 197E+02 | 439E+06 |

Area of enclosed

space below grade

As (cm)

Crack-to-total area ratio

1 bull

(unitless)

Crack depth

below grade

Zcfack

(cm)

Enthalpy of vaporization at

ave soil temperature

AHvjs

(calmol) bull

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law constant at

ave soil bull temperature

bull HTS

(unitless)

Vapor bull viscosity at

ave soil temperature

HTS

(gcm-s)

Stratum A

effective diffusion

coefficient

D (cms)

Stratum-B

effective diffusion coefficient

DB (cms)

Stratum C effective diffusion

coefficient

D-c (cms)

Total - overall effective diffusion

coefficient

D ^ (cms)

Diffusion path

length

L-

(cm)

I 787E+07 I 449E-05 | 15 | 11661 260E-03 111E-01 176E-04 I 612E-03 j OOOE+00 | OOOE+00 | 612E-03 j

bull Convection path

length

Lp

(cm)

Source vapor cone

^source

(ngm)

Crack radius

Tcfack

(cm)

Average vapor

flow rate into bIdg

Qsoii

(cms)

Crack effective diffusion

coefficient pcrack

(cms)

Area of CTack

Acack

(cm)

Exponent of equivalent foundation

Peclet number

exp(Pe)

(unitless)

bull bull - bull bull bull bull

1 15 1 197E+02 1 010 1 474E+01 612E-03 bull 354E-t-03 1 336E+09

Infinite source Indoor

~ attenuation coefficient

a

(unitless)

108E-05

Infinite source

btJbldgjJSv-L ^Ppncji3i-

virhpbiiilding bullbull ^lHltti^m)ilg

213E-03

Unit risk

factor

URF

(ngm)-

Reference cone

RfC (mgm)

NA 60E-03 1

I END

Appx B-1 124-TMBxls 3 of 3 982009

AR100310

APPENDIX B-2-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV Nersion31 020^

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

156592

Soil Gas Concentration Data ENTER

Soil gas

cone OR c

(ngm) bull

ENTER Soil bull-gas

cone

c (ppmv)

603E+03 1

Chemical

cis-12-Dichloroethylene

MORE ENTER Depth

below grade to bottom

of enclosed space floor

LF

(cm)

ENTER

Soil gas sampling

depth below grade

U (cm)

ENTER

Average soil

temperature bull Ts

(degC)

1 15 1 bull 15 125

ENTER ENTER ENTER Totalsmust add ijp tb value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hA hB he

bull (cm) (cm) (cm)

15 1 1

ENTER Soil

straturh A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estimate OR permeability | soil vapor

permeability) kv

(cm)

SL 1 |

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

P (gcm)

ENTER Stratum A soil total porosity

bull n

(unitless)

ENTER Stratum A

soil water-filled porosity

(cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

ENTER Stratum B

soil water-filled porosity

ENTER Stratum C

SCS soil type

(unitless) (cmcm)

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure differential

AP

(gcm-s)

ENTER Enclosed bull

space floor

length

LB (cm)

ENTER Enclosed

space floor

width WB

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER

Average vapor flow rate into bIdg

OR Leave blank to calculi

Qsoil

(Lm)

Appx B-2 cis-12-DCExls 1 of 3 982009

AR100311

APPENDIX B-2-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Diffusivity in air

Da

(cms)

Diffusivity in water

Dw (cms)

Henrys law constant at reference temperature

H

(atm-mmoi)

Henrys law constant

reference temperature

bull T R

CC)

Enthalpy of vaporization at

the normal boiling point

AHbdquob

(calmol)

Normal boiling point

TB

(degK)

Critical temperature

Tc (degK)

Molecular weight

MW

(gmol)

Unit risk

factor URF

(ngm)

Reference cone

RfC (mgm)

1 736E-02 1 113E-05 1 407E-03 j 1 25 1 bull 7192 1 33365 1 54400 1 9694 1 OOE+00 j 35E-02 1

Appx B-2 cis-12-DCExls 2 of 3 982009

AR100312

APPENDIX B-2-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

stratum A Stratum B Stratum C Source- soil soil soil

Exposure building air-filled air-filled air-filled

duration separation porosity porosity porosity

T LT ea e^ bull e= (sec) (cm) (cmcm) (cmcm) (cmcm)

I 946E+08n^

Stratum A Stratum A Stratum A Stratum A Floor-effective soil soil soil wall total fluid intrinsic relative air effective vapor seam

saturation permeability permeability permeability perimeter

Ste kj krg ky Acrack

(cmcm) (cm) (cm) (cm) (cm)

Soil gas

cone (ngm)

I 0284 I 0284~ 0284 0184 I 596E-09 | 090T 537E-09 35357 603E+03

BIdg ventilation

rate

JbulldinE

(cms)

439E+06

Area of enclosed

space below grade

AB

(cm)

Crack-to-total

area ratio

n (unitless)

Crack depth below grade

Zltiack (cm)

Erithalpy of vaporization at

ave soil temperature

AHvTs (calmol)

Henryslaw constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law constant at

ave soil temperature

HTS

(unitless) bull

Vapor viscosity at

ave soil bull temperature

HTS

bull (gcm-s)

Stratum A

effective bull diffusion

coefficient

D^A-(cms)

Stratum B

effective bull diffusion

coefficient

D=B

(cms)

Stratum C

effective diffusion bull

coefficient

D=e (cms)

Total overall

effective diffusion

coefficient

DT

(cms)

Diffusion path

length

Ld

(cm)

I 787E+07 I bull449E-05 | 15 bull7709 230E-03 982E-02 176E-04 | 743E-03 | OOOE+00 | OOOE+00 | 743E-03 |

bull bull bull -

Convecfion path -bull

length

Lp (cm)

Source vapor cone

-source

(Mgm)

Crack radius

fcrack

(cm)

Average vapor

flow rate into bIdg

Qaoil bull

(cms)

Crack effective diffusion

coefficient pcack

(cms)

Area of crack

crack

(cm)-

Exponent of equivalent foundation

Peclet number

exp(Pef)

(unitless)

bull

1 15 -1 603E+03 1 010 1 474E+01 743E-03 354E+03 1 697E+07

Infinite source Indoor

attenuation coefficient

poundbullbullbull C t

pound(unitless)

bullsiilaquogt j ii08E-05

Infinite [ source

bIdg cone

Cbujidjng

(pgm)

651 E-02 iKrt

Unit risk

factor

URF

(ngm)-

Reference cone

RfC

(mgm)

NA 35E-02 1

I END I

Appx B-2 cis-12-DCExls 3o f3 982009

AR100313

APPENDIX B-3-A DATA ENTRY SHEET

Coyne Texti le Services - Hunt ington West Virginia

SG-ADV Version 31 0204

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

67663

Soil Gas Concentration Data ENTER ENTER

Soil Soil gas gas

cone OR cone c C

(^gm) (ppmv)

591 E+03

bull

Chemical

Chloroform

MORE ENTER Depth

below grade tb bottom

of enclosed space floor

bull LF

(cm)

ENTER

Soil gas sampling depth

below grade

(cm)

ENTER

Average soil

temperature-Ts

CO bull

1 15 1 15 1 125

ENTER ENTER ENTER Totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

IIA hs he (cm) (cm) (cm)

1 5 bull 1 1

ENTER ENTER Soil - bull

stratum A User-defined SCS stratum A

soil type bull soil vapor (used to estimate OR permeability

soil vapor k

bull permeability) (cm) 1

SL 1 1 bull

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A soil dry

bulk density

Pb (gcm)

ENTER Stratum A soil total porosity

nV (unitless)

ENTER Stratum A

-soilwater-filled bullporosity

Sraquo (cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

(unitless)

ENTER Stratum B

soil water-filled porosity

bull ebdquo=

(cmcm) bull

ENTER Straturri C

SCS bull soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

- c rack

(cm)

ENTER

Soil-bldg pressure

differential AP^

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor

width bull W B

(cm)

ENTER

Enclosed space

height HB

(cm)

ENTER

bull Floor-wall^ seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bidg OR

Leave blank to calculi

Qsoil bull

(Lm)

I -I

Appx B-3 Chloroformxls 1 of 3 982009

AR100314

APPENDIX B-3-B CHEMICALPROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Diffusivity in air

D (cms)

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffijsivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature

Dbdquo H TR A H bdquo TB Tc

(cm s) (atm-m mol) ro (calmol) (degK) (degK)

Molecular weight

MW

(gmol)

Unit risk

factor URF

(ngm)-

Reference cone

RfC

(mgm)

104E-01 100E-05 I 366E-03 25 6988 33432 53640 11938 I 23E-05 | OOE+00

Appx B-3 Chloroformxls 2 of 3 982009

AR100315

APPENDIX B-3-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure

duration

(sec)

Source-

building

separation

LT

(cm)

Stratum A

soil

air-filled

porosity

Sa

( cm cm )

Stratum B

soil

air-filled

porosity

( cm cm )

Stratum C

soil

air-filled

porosity

( c m c m )

Stratum A

effective

total fluid

saturation

( c m c m )

Stratum A

soil

intrinsic

penmeability

k

(cm )

Stratum A

- soil

relative air

permeabil i ty

(cm )

Stratum A

soil

effective vapor

permeability

kv

(cm )

Floor-

wall

seam

perimeter

gtcrack

(cm)

Soil gas

cone

(ngm)

BIdg

venfilation

rate

^buildlriE

(cms)

I 9 4 6 E + 0 8 ~ T I 0284 T 596E-09 I 0-901 I 537E-09 | 35357 | 591 E+03 j 439E+06 | 1 0 284 0284 0184

Area of

enclosed

space

below

grade

A B

( c m )

Crack-

to-total

area

ratio

n

(unitless)

Crack

depth

bull below

grade

^crack

(cm)

Enthalpy of

vaporization at

ave soil

temperature

AHTs bull

(calmol)

Henry s law

constant at

ave soil

temperature

HTS

(a tm-m mol j

Henrys law

constant at

ave soil

bull temperature

HTS

(unitless) bull

Vapor

viscosity at

ave soil-

temperature

^HTS

(gcm-s)

Stratum

A

effective

diffusion

coefficient

(cm s)

Stratum

B

effective

difftjsion

coefficient

D B

(cms) bull

S t ra tum

C

effective

diffusion

coefficient

Dc

(cm s)

Total

overall

effective

bull diffusion

coefficient

D T

(cm s)

Diffi jsion

path

length

Ld

(cm)

I 787E+07 I 449E-05 j - bull 15 7528 210E-03 896E-02 176E-04 I 105E-02 | OOOE+00 | OOOE+00 | 105E-02

Convection

path length

Lp

(cm)

Source

vapor

cone -

^source

- (ngm)

Crack

radius

Tcrack

(cm)

Average

vapor

flow rate

into bidg

Qsoil

(cms)

Crack

effective

diffusion

coefficient Qcrack

bull (cms)

Area of crack

Acrack

(cm)

Exponent of

equivalent

foundation

Peclet number

exp(Pe)

(unitless)

V bull bull

1 15 1 591 E+03 1 010 1 474E+01 105E-02 354E+03 1 355E+05

Infinite

source

indoor

attenuation

coefficient

d

(unitless)

bull 108E-05

Infinite

source

bIdg

cone

^ b u i l d i n g

i (^gm)

bull bull

i 638E-02 -

Unit

risk bull factor

URF

(ngmY

Reference

cone

RfC

(mgm)

~ 23E-05 NA 1

I END

Appx B-3 Chloroform xls 3 of 3 982009

AR100316

APPENDIX B-4-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ersion 31-020^

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

nodashes)

bull 75092

ENTER Soil gas

cone

c (ngm)

Soil Gas Concentration Data ENTER

Soil gas bull

OR cone

bull C

(ppmv)

152E+03

bull bull

Chemical

Methylene chloride

MORE

MORE 4gt

ENTER Depth

below grade to bottom

of enclosed space floor

LF -

(cm)

ENTER

Soil gas sampling depth

below grade

bull U

(cm)

ENTER

Average soil

temperature

Ts bull CC)

bull bull bull bull

1 15 1 15 125

ENTER Totals

Thickness of soil

stratum A h

(cm)

ENTER ENTER must add up to value of Ls (cell F24

Thickness Thickness of soil of soil

stratum B stratum C (Enter value or 0) (Enter value or 0)

he he bull

(cm) bull (cm) -

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(usedto estimate OR perrrieability | soil vapor

permeability)

k bull

(cm)

SL 1 bull 1

ENTER Stratum A

SCS soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

Pb (gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Stratum A

soil water-filled porosity

9w (cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

Pb^

(gcm)

ENTER Stratum B soil total porosity

n^

(unitless)

ENTER Stratum B

soil water-filled porosity

(crhcm)

ENTER Stratum C

SCS soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE 4gt

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

bull Soil-bldg pressure

differential AP^

(gcm-s)

ENTER Enclosed

space floor

length LB

(cm)

ENTER Enclosed

space floor

width bull W B

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width

w

(cm)

ENTER

Indoor air exchange

rate

ER (1h)

ENTER Average vapor

flow rate into bidg OR

Leave blank to calculc

Qsoil

(Lm)

10 40 8839 8839 244 01 083

Appx B-4 MCxIs 1 of 3 982009

AR100317

Diffijsivity in air

D

APPENDIX B-4-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffusivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature

Pw H TR AHt TB TC

Molecular weight

MW

Unit risk

factor URF

Reference cone

RfC

(cms) (cms) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) bull (ngm)- (mgm)

bull bull

1 101E-01 1 117E-05 1 218E-03 1 25 | 6706 1 31300 1 51000 1 8493 1 47E-07 1 30E+00 1

Appx B-4 MCxIs 2 of 3 982009

AR100318

APPENDIX B-4-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

T

(sec)

Source- -building

separation

LT

(cm)

Stratum A soil

air-filled porosity

e a bull

(cmcm)

Stratum B soil

bullair-filled porosity bull

ea^ (cmcm)

Stratum C soil

air-filled porosity

ea= (cmcmj

Stratum A effective total fluid

saturation

Sc bull

(cmcm)

Stratum A soil

intrinsic pemneability

ki (cm)

Stratum A soil

relative air permeability

^ ^ g

(cm)

stratumA bull soil effective vapor permeability

K (cm)

Floor-wall

seam perimeter

Xcrack

(cm)

Soil gas

cone (ngm)

BIdg ventilation

rate

Qbuildinc

(cms)

1 946E+08

Area of -enclosed

space below

bull grade

AB

(cm)

1

Crack-to-total

area rafio

Tl

(unitless)

0284 1

Crack depth below grade

Zcrack

(cm)

0284 1

bull Enthalpy of vaporization at

ave soil temperature

AHTs (calmol)

0284

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

0184

Henrys law constant at ave soil

temperature

HTS

bull (unitless)

1 596E-09

Vapor viscosity at

ave soil temperature

Mrs (gcm-s)

0901

Stratum A

effective diffusion

coefficient

D (cms)

537E-09

Stratum B

effective diffusion

coefficient

D-B (cms)

35357 1

Stratum C -

effective diffusion

coefficient

D-c ^ (cms)

152E+03

Total bull overall

bull effective diffusion

coefficient

D ^

(cms)

440E+06 1

Difftjsion path

length

Ld (cm)

1 787E+07

Convection path

length

Lp (cm)

4 49E-05

Source vapor cone

Csource

(ngm)

15 1

Crack radius

Tcrack

(cm)

7007 bull 1

Average vapor

flow rate intobldg

Qsoil

(cms)

130E-03

Crack effective diffusion

coefficient pcrack

(cms)-

555E-02

bull ^

Area of crack

Acrack

(cm) bull

1 176E-04

Exponent of equivalent foundation

Peclet number

exp(Pe)

(unitless) bull

bull bull

1 15

1 END

152E+03 010 1 474E+01 1 102E-02 354E+03 1 519E+05

102E-02

Infinite source

indoor ^attenuation coefficient

bull a

(unitless)

aiii08E-05

0 OOE+00

bull

Infinite bull source

bIdg ^ cone

^bu i l d i ng

(MQm)

164E-02

OOOE+00 1

Unit risk

factor

URF

(ngm)-

47E-07 1

102E-02 j

Reference cone

RfC

(mgm)

30E+00 j

1 1

Appx B-4 MCxIs 3 of 3 982009

AR100319

APPENDIX B-5-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ^erslon 31 0204

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

127184

Soil Gas Concentration Data ENTER ^ ENTER

Soil -Soi l bull gas gas

cone OR cone Cg C bull

(tgm) (ppmv)

149E+05 1

Chemical

bull Tetrachlbroethylene

MORE 4

ENTER Depth

below grade to bottom

ofenclosecJ space floor

LF

(cm)

ENTER

Soil gas bull sampling

depth below grade

u bull (cm)

ENTER

Average bullsoil

temperature - Ts

ro 1 1 5 1 15 1 125 bull

ENTER ENTER ENTER totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hft bull he bull he

(cm) (cm) (cm)

bull 1 5 1 - 1

ENTER ENTER Soil

stratum A User^defined bull SCS bull stratum A soil type soil vapor

(used to estimate OR perrrieability soil vapor K bull

permeability) (cm) 1

SL 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

Pb

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Sitratum A

soil water-filled bull porosity

(cmcm)

ENTER Stratum B

SCS soiltype

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

Pb^

(gcm)

ENTER Stratum B soil total porosity

Ajnitless^

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS soil type

LookupSoil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

VS

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor width

W B

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width

w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

ENTER Average vapor

flow rate into bidg OR

Leave blank to calcul

bull Qsoil

(Lm)

10 40 8839 8839 244 01 083

Appx B-5 PCExIS 1 of 3 982009

AR100320

APPENDIX B-5-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal Unit

Diffusivity Diffusivity at reference reference the riormal boiling Critical Molecular risk Reference in air in water temperature temperature boiling point point teriiperature weight factor cone

Da Dbdquo H TR AHb TB Tc MW URF RfC

(cms) (cnis) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) (^gm)- (mgm)

1 720E-02 1 820E-06 1 184E-02 1 25 1 8288 1 39440 1 62020 1 16583 1 59E-06 1 60E-01 1

J

AppxB-5PCExls 2 of 3 - 982009

AR100321

APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

T

(sec)

Source-building

separation

LT

bull (cm)

Stratum A soil

air-filled porosity

Oa (cmcm)

Stratum B - soil air-filled porosity

ea (cmcm)

Stratum C soil

air-filled porosity

ea= - (cmcm)

Stratum A effective total fluid

saturation

sbdquo (cmcm)

Stratum A soil

intrinsic permeability

ki (cm)

Stratum A soil

relative air permeability

- ^ g

(cm)

Stratum A soil

effective vapor permeability

kv (cm)

Floor-wall

seam perimeter

^crack

(cm)

Soil gas

cone

(ngm)

BIdg venfilation

rate

Qbuildins

bull (cms)

bull bull

1 946E+08

Area of enclosed

space below grade

AB

(cm)

1

bullCrack-to-total

area ratio

1 (unitless)

0284 1

Crack bull depth below grade

Zcrack

(cm) -

0284 1

Enthalpy of vaporization at bull

ave soil temperature

bull A H V TS

(calmol)

0284

Henrys law constant at

ave soil temperature

HTS (atm-mmol)

0184

-Henrys law constant at

ave soil temperature

HTS

(unitless)

1 596E-09

Vapor viscosity at

ave soil temperature

HTS

(gcm-s)

0901

Stratum A

effective diffusion

coefficient bull D = bull

(cms)

537E-09

Stratum B

effective diffusion

coefficient

D--B (cms)

35357 1

Stratum C

effective diffusion bull

coefficient

D-c (crris)

149E+05

Total overall

effective bulldiffusion coefficient

DT

(cms)

440E+06 1

Difftjsion path

length

U (cm)

1 787E+07

Convection path

length

bull Lp

(cm)

4 49E-05

Source vapor cone

^source

(ngm)

15 1

Crack radius

Tcrack

(cm)

9528 1

Average vapor

flow rate intobldg

Qsoil (cms)

908E-03

Crack effective diffusion

coefficient pcrack

bull ( c m s ) bull

387E-01

Area of crack

Abdquoack (cm)

1 176E-04

Exponent of equivalent foundafion

Peclet number

exp(Pe)

(unitless)

bull

1 15-

1 END

149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08

727E-03

Infinite source indoor

attenuation coefficient

a

(unitless)

108E-05

OOOE+00

Infinite source

bIdg cone

Cburldtng

(Mgm)

161 E+00

OOOE+00 1

Unit risk

factor

URF

(ugm)-

59E-06 1

727E-03

Reference cone

RfC (mgm)

60E-01

1 1

Appx B-5 PCExls 3 of 3 982009

AR100322

APPENDIX B-6-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ersion31 0204

Reset to Defaults

t

Soil Gas Concentration Data ENTER

Chemical CAS No

(numbers only

no dashes)

79016

ENTER ENTER Soil Soil gas gas

cone OR cone C C -

bull (ngm) (ppmv)

782E+03

Chemical

Trichloroethylene

MORE ENTER Depth

below grade to bottom-

of enclosed space floor

LF

(cm)

ENTER

Soil gas sarnpling

depth below grade

U (cm)

ENTER

Average soil

temperature Ts

(degC)

1 15 1 15 t 125

ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e

(cm) (cm) (cm)

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estimate OR permeability soil vapor

permeability)

k (cm)

bull S L 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil bull-Parameters

ENTER Stratum A

soil dry bulk density

P b -

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Stratum A bull

soilwaterrfilled porosity

(cmcm) bull

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

bull P ^ (gcm)

ENTER Stratum B soil total

porosity

nlaquo

(unitless) -

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS bull soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor

width W B

(cm)

ENTER

Enclosed space height

H B bull

( c m ) bull

ENTER

Floor-wall seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bIdg OR

Leave blank to calculc

Qsoil

(Lm) -

Appx B-6 TCExIs 1 of 3 982009

A

AR100323

APPENDIX B-6-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight

Da Dbdquo H TR AH^b TB TC MW

Unit risk Reference

factor cone URF RfC

(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)

1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1

Appx B-6 TCExIs 2 of 3 982009

AR100324

APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

(sec)

Source-building

separation LT

(cm)

Stratum A soil

air-filled porosity

bull ea (cmcm)

Stratum B Soil

air-fllled porosity

e^ bull (cmcm)

Stratum C soil

air-filled porosity

(cmcm)

StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air

saturation permeability permeability

S|e k krg (cmcm) (cm) (cm)

Stratum A Floor-soil wall BIdg

effective vapor seam Soil ventilafion permeability perimeter gas rate

k^ bull Xack c o n e Qbuildins

(cm) (cm) (ngm) (cms)

946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |

Area of enclosed

space below grade

AB

(cm)

Ciack- to-total

area ratio

1 (unitless)

Crack depth below grade

Zcrack

(cm)

Enthalpy of vaporization at

ave soil temperature

A H J S

(calmol)

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law bull constant at

ave soil temperature

HTS

(unitless)

Vapor viscosity at

ave soil temperature

|JTS

(gcm^s)

Stratum A

effective diffusion

coefficient

(cms)

Stratum B

effective -diffusion

coefficient

D=B (cms)

Stratum ^ C effective diffusion

coefficient

D=c (cms)

Total overall

effective diffusion

coefficient

DT

(cms)

I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03

Diffusion path

length

Li (cm) bull

Convection bull path

length

Lp

(cm)

Source vapor cone bull

^source

(ngm)

Crack radius

rcrack

(cm)

Average vapor

- flow rate intobldg

Qsoil

(cms)

Crack effective diffusion

bull coefficient Qcrack

(cms)

Area of crack

^crack

(cm)

Exponent of equivalent foundation

Peclet bull number

exp(Pe)

(unitless)

bull bull

1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07

Infinite source Indoor

attenuation coefficient

a

(unitless)

108E-05

Infinite source

bIdg concgt

^building

(ngm)

844E-02

Unit risk

factor

URF

(ngm)-

Reference cone

RfC

(mgm)

1 1E-04 1 40E-02 1

END

Appx B-6 TCExIs 3 of 3 982009

AR100325

Office of Waste Management 1356 Hansford Street

Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256

West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director

ORDER

ISSUED UNDER THE

HAZARDOUS WASTE MANAGEMENT ACT

CHAPTER 22 ARTICLE 18

OF THE WEST VIRGINIA CODE^ AS AMENDED

y Order Number HW-011-80

To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704

ATTEMTION MREDARMON

Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull

AR100326

ViWJ011-laquo9 PageNunil)er2

BASIS FOR ORDER

As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following

A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^

B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator

C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities

0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94

^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement

P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following

1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater

2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was

^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment

CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable

CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order

AR100327

H W - 0 1 1 - 9 9 Page Number 3

REQUIREMENTS OF ORDER

Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows

1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^

2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore

remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling

GENERAL PROVaiONS

1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order

2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order

3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order

Effective Date

Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief

Wt T 1 V Oflice of Waste Management

AR100328

^ ^ S I S

^wmmmmamn

AR100329

Page 20: SDMS DocID 2121999 · International Enterprises Corp. building (Coyne Building), which is located at 1111 Vernon Street, Westmoreland District, Wayne County, West Virginia. The following

TABLES

EXPOSURE POINT CONCENTRATIONS FOR CHEMICALS OF CONCERN FOR VAPOR INTRUSION TO INDOOR AIR

Coyne Textile Services Facility - Huntington West Virginia

Chemical of Concern

VolatileOrganics

i24-Trimethylbenzene

12-Dichloroethene (cis)

Chloroform

Methylene chloride

Tetrachloroethene Triehloroethene

Subslab Vapor Source

Concentration (mgm^)

0197

603

591

152

149 782

Transport

Factor^ (unitless)

108E-05

108E-05

108E-05

108E-05

108E-05 108E-05

EPC in

Indoor Air (mgm^)

213E-06

651 E-05

638E-05

164E-05

161E-03 844E-05

Notes

^ Subslab vapor source concentration is based on the maximum detected concentration of samples

VP-01-02 and-03 (see Table 2) -

^ Details of the transport factor calculations are presented in Appendix B

^ Exposure Point Concentration (EPC) in inidoor air is calculated as the subslab vapor concentration TF

Coyne VI Memo Tables_09-08-09xls 982009

AR100297

TABLE 4

FACTORS USED IN DOSE CALCULATIONS INHALATION OF VOLATILE EMISSIONS

Coyne Textile Services Facility - Huntington West Virginia

Symbol

CA

IRA

ET

EF

ED-

BW

AT

Exposure Factor

Constituent Concentration in Air

Inhalation Rate

Exposure Time

Exposure Frequency

Exposure Duration

Body Weight

Averaging Time

Indoor Worker

Constituent-Specific See Table 3

25 m hour

8 hrday

250 daysyear

25 years

bull 70 kg

9125 days (NC)

25550 days (C)

Total Dose = CA x IR^ x ET x EF x ED x 1BW x 1AT

(NC) - Non-carcinogenic Averaging Time

(C) - Carcinogenic Averaging Time

Coyne VI Memo Tables_09-08-09xls 982009

AR100298

TABLES TOXICITY VALUES FOR CHEMICALS OF CONCERN

Coyne Textile Services Facility - Huntington West Virginia

Chemical of Concern

Volatile Organics

124-Trimethylbenzene

12-Dichloroethene (cis)

Chloroform

Methylene chloride

tetrachloroethene

Triehloroethene

Target Organ Critical Effect

blood

bullblood

liver

liver

liver CMS

liver kidney fetus CNS

Chroniclnhalation Reference Dose

(mgkg-day)

200E-03 P

1 OOE-02 R

140E-02 E

286E-01 M

771 E-02 M

1OOE-02 E

Inhalation Cancer ^ Slope Factor

(mgkg-day)^

NA

NA

805E-02 1

165E-03 1

200E-02 0

400E-01 E

(I) - Integrated Risk Information System (IRIS USEPA 2009)

(P) - Provisional Peer-Reviewed Toxicity Value (PPRTV) as presented in USEPA Regional Screening Tables (ORNL 2009)

(R) - Calculated assuming route-to-route extrapolation as per WVDEP

(E)-Provisional value from the National Center for Environmental Assessment (as per WVDEP)

(M)-Chronic Minimal Risk Level (MRL ATSDR 2009)

(0) - Value cited by USEPA Region 3 attributed to other sources (as per WVDEP)

Coyne VI Memo Tables_09-08-09xls 982009

AR100299

TABLE 6

NONCANCER HAZARD INDEX AND POTENTIAL CANCER RISK FOR AN INDOOR WORKER

Coyne Textile Services Facility - Huntington West Virginia

bull

Constituent

Volatile Organics

124-Trinnethylbehzene

12-Dichlorpethene (cis)

Chloroform

Methylene chloride

Tetrachloroethene Triehloroethene

EPC in Indoor Air

(mgm)

213E-06

651 E-05

- 638E-05

164E-05

161 E-03

844E-05

Intake (ADD)

(mgkg-d)

416E-07

127E-05

125E-05

321 E-06

315E-04 l65E-05

RfDi

(mgkg-d)

200E-03

1OOE-02

140E-02

286E-01

771 E-02 1 OOE-02

Hazard

Quotient

208E-04

127E-03

892E-04

112E-05

408E-03 165E-03

Intake (LADD)

(mgkg-d)

) 149E-07

455E-06 bull 446E-06

115E-06

112E-04 590E-06

CSFi

(mgkg-d)

NA

NA

805E-02

165E-03

200E-02

400E-01

Potential

Cancer Risk

NA

NA

359E-07

189E-09

225E-06 236E-06

Total Hazard Index

00081 Total

Cancer Risk 497E-06

Total Blood HI = Total Liver HI =

Total Central Nervous System HI = Total Kidney HI =

Total Fetal HI =

bull 00015 00066 00057 00017 00017

Notes NA = Toxicity values are not available for this endpoint or exposure pathway

Coyne VI Memo Tables_09-08-09xls 982009

AR100300

APPENDIX A

SUBSLAB VAPOR ANALYTICAL DATA

AR100301

Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility Huntington West Virginia

Sample

Consti tuent

Volatile Organics (ugm) 111-Trlchloroethane 1122-Tetrachloroethane 112-Trichloro-122-trifluoroethane 112-Trichloroethane 11-Dichioroethane 11-Dichloroethene 124-Trichloroberi2ene 124-Trimethylbenzene 12-Dibromoethane 12-Dichloroben2ene 12-Dichloroethane 12-Dichloroethene-(cis) -12-Dichloroethene (trans) 12-Dichloropropane 12-Dichlorotetrafluoroethane 135-Trimethylbenzene 13-Butadiene 13-Dichlorobenzene 13-Hexachlorobutadiene 14-Dichlorobenzene 224-trimethVlpentane 2-Chlorotoluene 4-Ethyltoluene Acetone Allyl Chloride Benzene Bromodichloromethane Bromoform Bromomethane Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 13-Dichloropropene (cis) Cyclohexane Dibromochloromethane

Identif ication Sample Date

CAS No

71-55-6 79-34-5 76-13-1 79-00-5 75-34-3 75-35-4 120-82-1 95-63-6 106-93-4 95-50-1 107-06-2 156-59-2 156-60-5 78-87-5 76-14-2 108-67-8 106-99^0 541-73-1 87-68-3 106-46-7 540-84r1 95-49-8

622-96-8 67-64-1 107-05-1 71-43-2 75-27-4 75-252 74-83-9 75-15-0 56-23-5 108-90-7 75-00-3 67-66-3 74-87-3

10061-01-5 110-82-7 124-48-1

lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt

lt lt lt lt lt lt lt lt lt lt lt lt

lt

VP-01 8132009

22 28 31 22 16 16 30 20 31 24 16 16 16 19 28 20 89 24 43 24

1 9 21 20 796 13 13 27 41 16 13 25 18 11 20 83 18 52 34

lt lt lt lt lt lt lt lt lt lt lt

lt lt lt lt lt lt lt lt lt lt lt

lt lt lt lt lt lt lt lt lt

lt lt lt lt

VP-02 8132009

218 2 7 5 307 218 162 159 297

bull 197 307 240 162 369 159 185 280 197 89

240 427 240 187 207 197

1880 125 128 268 414 155 125 252 184 106

5910 83 182 138 341

lt lt lt lt lt lt lt

lt lt lt

lt lt lt lt lt lt lt bull

lt lt lt lt

lt lt lt lt lt lt lt lt lt lt lt lt lt lt

VP-03 8132009

218 275 307 218

bull 162 159 297 197 307 240 162

6030 159 185 280 197 89

240 427 240 187 207 197

1750 125 128 268 414 155 125 252 184 106 195 83 182 138 341

Appx A SG Dataxis Page 1 of 2 982009

AR100302

Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility bull Huntington West Virginia

Consti tuent

Volatile Organics (ugm^) Dichlorodifluoromethane Ethylbenzene Methyl ethyl ketone Methyl Isobutyl ketone Methyl tert-butyl ether Methylene chloride n-Heptane jn-Hexane Styrene Tert-butyl alcohol Tetrachloroethene iToluene 13-Dichloropropene (trans) Triehloroethene Trichlorofluoromethane Vinyl bromide Vinyl chloride Xylene (o) Xylenes (mampp)

Sample Identif ication Sample Date

CAS No

75-71-8 100-41-4 78-93-3 108-10-1

1634-04-4 75-09-2

142-82-5 bull 110-54-3

100-42-5 75-65-0 127-18-4 108-88-3

10061-02-6 79-01-6 75-69-4 593-60-2 75-01-4 95-47-6

179601-23-1

lt lt

lt lt lt lt

lt lt

lt

lt lt lt lt lt

VP01 8132009

20 17 23 16 14 14 16

173 17 12 bull

11200 18 18 91 23 18 10 17 17

lt lt lt lt lt

lt

lt lt

lt lt

lt lt lt lt lt

VP-02 8132009

198 174 118 164 144

1520 164 -183 170 121

149000 151 182

2360 225 175 102 174 174

VP-03 8132009

lt 198 lt 174 lt 118 lt 164 lt 144

1160 lt 164

144 lt 170 ltbull 121

90500 lt 151 lt 182

7820 lt 225 lt 175 lt 102

208 387

Appx A SG Dataxis Page 2 of 2 982009

AR100303

APPENDIX B

CALCULATION OF TRANSPORT FACTORS USED TO ESTIMATE INDOOR AIR CONCENTRATIONS

AR100304

APPENDIX B

Calculation of Transport Factors Used to Estimate Indoor Air Concentrations

This appendix presents the methodology for calculating transport factors that are used to convert subslab

vapor concentrations to concentrations in indoor air 124-Trimethylbenzene 12-dichloroethene (cis)

chloroform methylene chloride tetrachloroethene and triehloroethene were identified as contaminants of

concern (COC) for potential vapor intrusion from subslab vapor associated with the Coyne Textile

Services Facility located in Huntington West Virginia (site) In this appendix the transport factors are

calculated to estimate the concentrations of COC in indoor air of the existing plant building located at the

site ~

Transport Factor for Indoor Air

The concentration of a constituent in indoor air (da) is proportional to the concentration of the constituent

in the subslab vapors immediately beneath the building foundation (ie subslab vapor concentration or

Csubsiab) The following equation is used to calculate da from Csubsiab

^ wja ~ ^subslab X I r

where

Cia = concentration of constituent in indoor air (mgm^) -

Csubsiab^ concentration of constituent in subslab vapors (mgm^) and

TF = transport factor from subslab vapors to indoor air

The transport factor (TF) is an infinite source attenuation coefficient andcan be calculated based on a

model developed by Johnson and Ettinger (1991) t he equation for calculating TF is as follows

(Deff X A B ) ( Q B X L T ) X expKQso i l X Lcrabk)(Dcrack X Acrack)]

exp[ (Qsoi l X Lcrack)(Dcrack X Acrack)] + (Deff X A B ) ( Q B X L T ) + (Deff X AB)(Qsoi l X L j ) X (exp [ (Qso i l X Lcrack)(Dcrack X Acrack)] - 1)

where

Deff = effective diffusion coefficient for vadose zone soil (cm^sec)

AB = area of enclosed space below grade (cm^)

QB = building ventilation rate (cm^sec)

LT = distance from contaminant source to building foundation (cm)

Qsoii = volumetric flow rate of vapors into the building (cm^sec)

Lcrack = foundatlon thickness (cm)

Dcrack = vapor diffusion coefficient through crack (cm^sec) and

Acrack = area of cracks through which vapors can pass (cm^)

AR100305

To solve this equation the USEPAs SG-ADV spreadsheet Version 31 most recently updated in

February 2004 was implemented A combination of site-specific factors and default values from the

Users Guide for Evaluating Subsurface Vapor Intrusion Into Buildings (USEPA 2004) were used as input

values in the model All input values are defined below and presented in Tables B-1-A through B-6-A

bull The initial subslab vapor concentration (Csubsiab) is the maximum detected concentration(in units

of ugm ) of samples VP-01 VP-02 and VP-03 that was presented in Table 3 of the report

bull The depth below grade to the bottom of the enclosed space floor (Lp) is set to 15 cm the default

value provided by USEPA (2004) for a slab-on-grade structure

bull The vapor sampling depth below grade (Lg) is a site-specific value The vapor samples were

collected from immediately beneath the building floor therefore Lj has been set to 15 cm

bull The average soilgroundwater temperature (Ts) is set to 125degC the average value for West

Virginia as estimated frorri Figure 8 of the vapor intrusion users guide (USEPA 2004)

bull The soil type used to estimate vapor permeability is assumed to be sandy loam (SL) The

associated soil properties for a sandy loam soil type are as follows the soil dry bulk density (Pb) is

162 gcm the total porosity (n) is 0387 (cm^-aircm^) and the water-filled porosity (nw) is 0103

(cm -HzOcm )

bull The floor thickness (Lcrack) is set to the USEPA (2004) default value of 10 cm

bull The soil-building pressure differential (AP) is set to the USEPA (2004) default value of 40 gcm-s^

bull The building dimensions are siterspecific based on the existing plant building located at the site

The existing structure is approximately 84000 square feet (Dolphin 2000) therefore the

dimensions are set to 8839 cm (290 feet) length by 8839 cm (290 feet) The USEPA (2004)

default value of 244 cm vyas used for the height

bull Thefloor-wall seam crack width (w) is set to the USEPA (2004)-default value of 01 cm

bull The indoor air exchange rate (ER) is set to 083hour This is the value provided by ASTM (2002)

for commercial and industrial buildings

AR100306

Tables B-1-B through B-6-B present the constituent-specific properties for COC that were used in the TF

calculations Tables B-1-C through B-6-C present the intermediate calculations used to determine the

indoor air attenuation coefficients (ie the transport factors) The shaded boxes in Tables B-1-C through

B-6-C also present the resulting TF values that are applied to the concentrations of COC in subslab

vapor and the estimated indoor air concentrations

References

American Society for Testing and Materials (ASTM 2002) Standard Guide for Risk-Based Corrective Action Applied at Petroleum Release Sites ASTM E-1739-95 (Reapproved 2002)

Johnson PC and RA Ettinger (1991) Heuristic model for predicting the intrusion r-ate of contaminant vapors into buildings Environ Sci Technolpgy 25 1445-1452

Dolphin Environmental LLC (Dolphin 2000) Site Characterization Report Mach 14 2000

United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004

AR100307

APPENDIX B-1-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV Nersion31 0204

Reset to Defaults

ENTER -

Chemical CAS No

(numbers only

no dasties)

95636

ENTER Soil gas

cone

Cg (ngm)

Soil Gas Concentration Data ENTER

Soil gas

OR cone

bull - c bull (PPmv)

197E+02

Chemical

124-Trimethylbenzene

MORE ENTER Depth

below grade to bottom

of enclosed space floor

U bull (cm)

ENTER

Soil gas sampling

depth below grade

U (cm) bull

ENTER

Average soil

temperature Ts

CO

1 15 1 1 5 bull125

ENTER ENTER ENTER Totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hft ha he

(cm) (cm) (cm)

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estirnate OR permeability | soil vapor

permeability) k v bull

(cm)

SL 1 1

MORE ENTER

stratum A SCS

soil type

Lookup Soil Parameters

ENTER stratum A soil dry

bulk density P

(gcm)

ENTER Stratum A soil total porosity

(unitless)

ENTER bull stratum A soil water-filled

porosity

(cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

nlaquo

(unitless)

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gchi-s^)

ENTER Enclosed

space floor

length bull LB

(cm)

ENTER Enclosed

space floor

width WB

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

bull Floor-wall seam crack

width w

(cm)

bullENTER

Indoor air exchange

rate ER

(1h) bull

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bidg OR

Leave blank to caicuij

(Lm)

Appx B-1 124-TMBxls 1 of 3 982009

AR100308

APPENDIX B-1-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of ^ bull law constant law constant vaporization at Normal

Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temperature boiling point point temperature weight

D bull Dbdquo H T R bull AHbdquo TB Tc IVIW

Unit risk Reference

factor cone URF RfC

(cms) (cmls) (atm-mmol) CO (calmol) (degK) (degK) (gmol) bull (ugm)- (mgm)

1 606E-02 1 792E-06 1 bull 614E-C3 1 25 1 9369 1 44230 | 64917 1 12020 1 OOE+00 1 60E-03 1

Appx B-1 124-TMBxls 2 of 3 982009

AR100309

APPENDIX B-1-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

(sec)

Source-building

separation

LT bull

(cm) bull

Stratum A soil

air-filled porosity

Q A

Stratum B soil

air-filled porosity

(cmcm) (cmcm)

Stratum C soil air-filled porosity

(cmcm)

Stratum A effective total fluid

saturation

Se

(cmcm)

Stratum A soil

bullintrinsic permeability

^ (cm)

stratum A Stratum A Floor- soil soli wall BIdg

relative air effective vapor seam Soil bull ventilation permeability permeability perimeter gas rate-

kfg ky Xgrack c o n e - QbuHdinpound

(cm) - (cm) (cm) (ngm) (cms)

946E+08 1 0284 0284 0284 0184 596E-09 0901 537E-09 35357 I 197E+02 | 439E+06 |

Area of enclosed

space below grade

As (cm)

Crack-to-total area ratio

1 bull

(unitless)

Crack depth

below grade

Zcfack

(cm)

Enthalpy of vaporization at

ave soil temperature

AHvjs

(calmol) bull

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law constant at

ave soil bull temperature

bull HTS

(unitless)

Vapor bull viscosity at

ave soil temperature

HTS

(gcm-s)

Stratum A

effective diffusion

coefficient

D (cms)

Stratum-B

effective diffusion coefficient

DB (cms)

Stratum C effective diffusion

coefficient

D-c (cms)

Total - overall effective diffusion

coefficient

D ^ (cms)

Diffusion path

length

L-

(cm)

I 787E+07 I 449E-05 | 15 | 11661 260E-03 111E-01 176E-04 I 612E-03 j OOOE+00 | OOOE+00 | 612E-03 j

bull Convection path

length

Lp

(cm)

Source vapor cone

^source

(ngm)

Crack radius

Tcfack

(cm)

Average vapor

flow rate into bIdg

Qsoii

(cms)

Crack effective diffusion

coefficient pcrack

(cms)

Area of CTack

Acack

(cm)

Exponent of equivalent foundation

Peclet number

exp(Pe)

(unitless)

bull bull - bull bull bull bull

1 15 1 197E+02 1 010 1 474E+01 612E-03 bull 354E-t-03 1 336E+09

Infinite source Indoor

~ attenuation coefficient

a

(unitless)

108E-05

Infinite source

btJbldgjJSv-L ^Ppncji3i-

virhpbiiilding bullbull ^lHltti^m)ilg

213E-03

Unit risk

factor

URF

(ngm)-

Reference cone

RfC (mgm)

NA 60E-03 1

I END

Appx B-1 124-TMBxls 3 of 3 982009

AR100310

APPENDIX B-2-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV Nersion31 020^

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

156592

Soil Gas Concentration Data ENTER

Soil gas

cone OR c

(ngm) bull

ENTER Soil bull-gas

cone

c (ppmv)

603E+03 1

Chemical

cis-12-Dichloroethylene

MORE ENTER Depth

below grade to bottom

of enclosed space floor

LF

(cm)

ENTER

Soil gas sampling

depth below grade

U (cm)

ENTER

Average soil

temperature bull Ts

(degC)

1 15 1 bull 15 125

ENTER ENTER ENTER Totalsmust add ijp tb value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hA hB he

bull (cm) (cm) (cm)

15 1 1

ENTER Soil

straturh A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estimate OR permeability | soil vapor

permeability) kv

(cm)

SL 1 |

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

P (gcm)

ENTER Stratum A soil total porosity

bull n

(unitless)

ENTER Stratum A

soil water-filled porosity

(cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

ENTER Stratum B

soil water-filled porosity

ENTER Stratum C

SCS soil type

(unitless) (cmcm)

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure differential

AP

(gcm-s)

ENTER Enclosed bull

space floor

length

LB (cm)

ENTER Enclosed

space floor

width WB

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER

Average vapor flow rate into bIdg

OR Leave blank to calculi

Qsoil

(Lm)

Appx B-2 cis-12-DCExls 1 of 3 982009

AR100311

APPENDIX B-2-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Diffusivity in air

Da

(cms)

Diffusivity in water

Dw (cms)

Henrys law constant at reference temperature

H

(atm-mmoi)

Henrys law constant

reference temperature

bull T R

CC)

Enthalpy of vaporization at

the normal boiling point

AHbdquob

(calmol)

Normal boiling point

TB

(degK)

Critical temperature

Tc (degK)

Molecular weight

MW

(gmol)

Unit risk

factor URF

(ngm)

Reference cone

RfC (mgm)

1 736E-02 1 113E-05 1 407E-03 j 1 25 1 bull 7192 1 33365 1 54400 1 9694 1 OOE+00 j 35E-02 1

Appx B-2 cis-12-DCExls 2 of 3 982009

AR100312

APPENDIX B-2-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

stratum A Stratum B Stratum C Source- soil soil soil

Exposure building air-filled air-filled air-filled

duration separation porosity porosity porosity

T LT ea e^ bull e= (sec) (cm) (cmcm) (cmcm) (cmcm)

I 946E+08n^

Stratum A Stratum A Stratum A Stratum A Floor-effective soil soil soil wall total fluid intrinsic relative air effective vapor seam

saturation permeability permeability permeability perimeter

Ste kj krg ky Acrack

(cmcm) (cm) (cm) (cm) (cm)

Soil gas

cone (ngm)

I 0284 I 0284~ 0284 0184 I 596E-09 | 090T 537E-09 35357 603E+03

BIdg ventilation

rate

JbulldinE

(cms)

439E+06

Area of enclosed

space below grade

AB

(cm)

Crack-to-total

area ratio

n (unitless)

Crack depth below grade

Zltiack (cm)

Erithalpy of vaporization at

ave soil temperature

AHvTs (calmol)

Henryslaw constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law constant at

ave soil temperature

HTS

(unitless) bull

Vapor viscosity at

ave soil bull temperature

HTS

bull (gcm-s)

Stratum A

effective bull diffusion

coefficient

D^A-(cms)

Stratum B

effective bull diffusion

coefficient

D=B

(cms)

Stratum C

effective diffusion bull

coefficient

D=e (cms)

Total overall

effective diffusion

coefficient

DT

(cms)

Diffusion path

length

Ld

(cm)

I 787E+07 I bull449E-05 | 15 bull7709 230E-03 982E-02 176E-04 | 743E-03 | OOOE+00 | OOOE+00 | 743E-03 |

bull bull bull -

Convecfion path -bull

length

Lp (cm)

Source vapor cone

-source

(Mgm)

Crack radius

fcrack

(cm)

Average vapor

flow rate into bIdg

Qaoil bull

(cms)

Crack effective diffusion

coefficient pcack

(cms)

Area of crack

crack

(cm)-

Exponent of equivalent foundation

Peclet number

exp(Pef)

(unitless)

bull

1 15 -1 603E+03 1 010 1 474E+01 743E-03 354E+03 1 697E+07

Infinite source Indoor

attenuation coefficient

poundbullbullbull C t

pound(unitless)

bullsiilaquogt j ii08E-05

Infinite [ source

bIdg cone

Cbujidjng

(pgm)

651 E-02 iKrt

Unit risk

factor

URF

(ngm)-

Reference cone

RfC

(mgm)

NA 35E-02 1

I END I

Appx B-2 cis-12-DCExls 3o f3 982009

AR100313

APPENDIX B-3-A DATA ENTRY SHEET

Coyne Texti le Services - Hunt ington West Virginia

SG-ADV Version 31 0204

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

67663

Soil Gas Concentration Data ENTER ENTER

Soil Soil gas gas

cone OR cone c C

(^gm) (ppmv)

591 E+03

bull

Chemical

Chloroform

MORE ENTER Depth

below grade tb bottom

of enclosed space floor

bull LF

(cm)

ENTER

Soil gas sampling depth

below grade

(cm)

ENTER

Average soil

temperature-Ts

CO bull

1 15 1 15 1 125

ENTER ENTER ENTER Totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

IIA hs he (cm) (cm) (cm)

1 5 bull 1 1

ENTER ENTER Soil - bull

stratum A User-defined SCS stratum A

soil type bull soil vapor (used to estimate OR permeability

soil vapor k

bull permeability) (cm) 1

SL 1 1 bull

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A soil dry

bulk density

Pb (gcm)

ENTER Stratum A soil total porosity

nV (unitless)

ENTER Stratum A

-soilwater-filled bullporosity

Sraquo (cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

(unitless)

ENTER Stratum B

soil water-filled porosity

bull ebdquo=

(cmcm) bull

ENTER Straturri C

SCS bull soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

- c rack

(cm)

ENTER

Soil-bldg pressure

differential AP^

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor

width bull W B

(cm)

ENTER

Enclosed space

height HB

(cm)

ENTER

bull Floor-wall^ seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bidg OR

Leave blank to calculi

Qsoil bull

(Lm)

I -I

Appx B-3 Chloroformxls 1 of 3 982009

AR100314

APPENDIX B-3-B CHEMICALPROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Diffusivity in air

D (cms)

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffijsivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature

Dbdquo H TR A H bdquo TB Tc

(cm s) (atm-m mol) ro (calmol) (degK) (degK)

Molecular weight

MW

(gmol)

Unit risk

factor URF

(ngm)-

Reference cone

RfC

(mgm)

104E-01 100E-05 I 366E-03 25 6988 33432 53640 11938 I 23E-05 | OOE+00

Appx B-3 Chloroformxls 2 of 3 982009

AR100315

APPENDIX B-3-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure

duration

(sec)

Source-

building

separation

LT

(cm)

Stratum A

soil

air-filled

porosity

Sa

( cm cm )

Stratum B

soil

air-filled

porosity

( cm cm )

Stratum C

soil

air-filled

porosity

( c m c m )

Stratum A

effective

total fluid

saturation

( c m c m )

Stratum A

soil

intrinsic

penmeability

k

(cm )

Stratum A

- soil

relative air

permeabil i ty

(cm )

Stratum A

soil

effective vapor

permeability

kv

(cm )

Floor-

wall

seam

perimeter

gtcrack

(cm)

Soil gas

cone

(ngm)

BIdg

venfilation

rate

^buildlriE

(cms)

I 9 4 6 E + 0 8 ~ T I 0284 T 596E-09 I 0-901 I 537E-09 | 35357 | 591 E+03 j 439E+06 | 1 0 284 0284 0184

Area of

enclosed

space

below

grade

A B

( c m )

Crack-

to-total

area

ratio

n

(unitless)

Crack

depth

bull below

grade

^crack

(cm)

Enthalpy of

vaporization at

ave soil

temperature

AHTs bull

(calmol)

Henry s law

constant at

ave soil

temperature

HTS

(a tm-m mol j

Henrys law

constant at

ave soil

bull temperature

HTS

(unitless) bull

Vapor

viscosity at

ave soil-

temperature

^HTS

(gcm-s)

Stratum

A

effective

diffusion

coefficient

(cm s)

Stratum

B

effective

difftjsion

coefficient

D B

(cms) bull

S t ra tum

C

effective

diffusion

coefficient

Dc

(cm s)

Total

overall

effective

bull diffusion

coefficient

D T

(cm s)

Diffi jsion

path

length

Ld

(cm)

I 787E+07 I 449E-05 j - bull 15 7528 210E-03 896E-02 176E-04 I 105E-02 | OOOE+00 | OOOE+00 | 105E-02

Convection

path length

Lp

(cm)

Source

vapor

cone -

^source

- (ngm)

Crack

radius

Tcrack

(cm)

Average

vapor

flow rate

into bidg

Qsoil

(cms)

Crack

effective

diffusion

coefficient Qcrack

bull (cms)

Area of crack

Acrack

(cm)

Exponent of

equivalent

foundation

Peclet number

exp(Pe)

(unitless)

V bull bull

1 15 1 591 E+03 1 010 1 474E+01 105E-02 354E+03 1 355E+05

Infinite

source

indoor

attenuation

coefficient

d

(unitless)

bull 108E-05

Infinite

source

bIdg

cone

^ b u i l d i n g

i (^gm)

bull bull

i 638E-02 -

Unit

risk bull factor

URF

(ngmY

Reference

cone

RfC

(mgm)

~ 23E-05 NA 1

I END

Appx B-3 Chloroform xls 3 of 3 982009

AR100316

APPENDIX B-4-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ersion 31-020^

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

nodashes)

bull 75092

ENTER Soil gas

cone

c (ngm)

Soil Gas Concentration Data ENTER

Soil gas bull

OR cone

bull C

(ppmv)

152E+03

bull bull

Chemical

Methylene chloride

MORE

MORE 4gt

ENTER Depth

below grade to bottom

of enclosed space floor

LF -

(cm)

ENTER

Soil gas sampling depth

below grade

bull U

(cm)

ENTER

Average soil

temperature

Ts bull CC)

bull bull bull bull

1 15 1 15 125

ENTER Totals

Thickness of soil

stratum A h

(cm)

ENTER ENTER must add up to value of Ls (cell F24

Thickness Thickness of soil of soil

stratum B stratum C (Enter value or 0) (Enter value or 0)

he he bull

(cm) bull (cm) -

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(usedto estimate OR perrrieability | soil vapor

permeability)

k bull

(cm)

SL 1 bull 1

ENTER Stratum A

SCS soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

Pb (gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Stratum A

soil water-filled porosity

9w (cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

Pb^

(gcm)

ENTER Stratum B soil total porosity

n^

(unitless)

ENTER Stratum B

soil water-filled porosity

(crhcm)

ENTER Stratum C

SCS soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE 4gt

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

bull Soil-bldg pressure

differential AP^

(gcm-s)

ENTER Enclosed

space floor

length LB

(cm)

ENTER Enclosed

space floor

width bull W B

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width

w

(cm)

ENTER

Indoor air exchange

rate

ER (1h)

ENTER Average vapor

flow rate into bidg OR

Leave blank to calculc

Qsoil

(Lm)

10 40 8839 8839 244 01 083

Appx B-4 MCxIs 1 of 3 982009

AR100317

Diffijsivity in air

D

APPENDIX B-4-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffusivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature

Pw H TR AHt TB TC

Molecular weight

MW

Unit risk

factor URF

Reference cone

RfC

(cms) (cms) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) bull (ngm)- (mgm)

bull bull

1 101E-01 1 117E-05 1 218E-03 1 25 | 6706 1 31300 1 51000 1 8493 1 47E-07 1 30E+00 1

Appx B-4 MCxIs 2 of 3 982009

AR100318

APPENDIX B-4-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

T

(sec)

Source- -building

separation

LT

(cm)

Stratum A soil

air-filled porosity

e a bull

(cmcm)

Stratum B soil

bullair-filled porosity bull

ea^ (cmcm)

Stratum C soil

air-filled porosity

ea= (cmcmj

Stratum A effective total fluid

saturation

Sc bull

(cmcm)

Stratum A soil

intrinsic pemneability

ki (cm)

Stratum A soil

relative air permeability

^ ^ g

(cm)

stratumA bull soil effective vapor permeability

K (cm)

Floor-wall

seam perimeter

Xcrack

(cm)

Soil gas

cone (ngm)

BIdg ventilation

rate

Qbuildinc

(cms)

1 946E+08

Area of -enclosed

space below

bull grade

AB

(cm)

1

Crack-to-total

area rafio

Tl

(unitless)

0284 1

Crack depth below grade

Zcrack

(cm)

0284 1

bull Enthalpy of vaporization at

ave soil temperature

AHTs (calmol)

0284

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

0184

Henrys law constant at ave soil

temperature

HTS

bull (unitless)

1 596E-09

Vapor viscosity at

ave soil temperature

Mrs (gcm-s)

0901

Stratum A

effective diffusion

coefficient

D (cms)

537E-09

Stratum B

effective diffusion

coefficient

D-B (cms)

35357 1

Stratum C -

effective diffusion

coefficient

D-c ^ (cms)

152E+03

Total bull overall

bull effective diffusion

coefficient

D ^

(cms)

440E+06 1

Difftjsion path

length

Ld (cm)

1 787E+07

Convection path

length

Lp (cm)

4 49E-05

Source vapor cone

Csource

(ngm)

15 1

Crack radius

Tcrack

(cm)

7007 bull 1

Average vapor

flow rate intobldg

Qsoil

(cms)

130E-03

Crack effective diffusion

coefficient pcrack

(cms)-

555E-02

bull ^

Area of crack

Acrack

(cm) bull

1 176E-04

Exponent of equivalent foundation

Peclet number

exp(Pe)

(unitless) bull

bull bull

1 15

1 END

152E+03 010 1 474E+01 1 102E-02 354E+03 1 519E+05

102E-02

Infinite source

indoor ^attenuation coefficient

bull a

(unitless)

aiii08E-05

0 OOE+00

bull

Infinite bull source

bIdg ^ cone

^bu i l d i ng

(MQm)

164E-02

OOOE+00 1

Unit risk

factor

URF

(ngm)-

47E-07 1

102E-02 j

Reference cone

RfC

(mgm)

30E+00 j

1 1

Appx B-4 MCxIs 3 of 3 982009

AR100319

APPENDIX B-5-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ^erslon 31 0204

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

127184

Soil Gas Concentration Data ENTER ^ ENTER

Soil -Soi l bull gas gas

cone OR cone Cg C bull

(tgm) (ppmv)

149E+05 1

Chemical

bull Tetrachlbroethylene

MORE 4

ENTER Depth

below grade to bottom

ofenclosecJ space floor

LF

(cm)

ENTER

Soil gas bull sampling

depth below grade

u bull (cm)

ENTER

Average bullsoil

temperature - Ts

ro 1 1 5 1 15 1 125 bull

ENTER ENTER ENTER totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hft bull he bull he

(cm) (cm) (cm)

bull 1 5 1 - 1

ENTER ENTER Soil

stratum A User^defined bull SCS bull stratum A soil type soil vapor

(used to estimate OR perrrieability soil vapor K bull

permeability) (cm) 1

SL 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

Pb

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Sitratum A

soil water-filled bull porosity

(cmcm)

ENTER Stratum B

SCS soiltype

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

Pb^

(gcm)

ENTER Stratum B soil total porosity

Ajnitless^

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS soil type

LookupSoil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

VS

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor width

W B

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width

w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

ENTER Average vapor

flow rate into bidg OR

Leave blank to calcul

bull Qsoil

(Lm)

10 40 8839 8839 244 01 083

Appx B-5 PCExIS 1 of 3 982009

AR100320

APPENDIX B-5-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal Unit

Diffusivity Diffusivity at reference reference the riormal boiling Critical Molecular risk Reference in air in water temperature temperature boiling point point teriiperature weight factor cone

Da Dbdquo H TR AHb TB Tc MW URF RfC

(cms) (cnis) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) (^gm)- (mgm)

1 720E-02 1 820E-06 1 184E-02 1 25 1 8288 1 39440 1 62020 1 16583 1 59E-06 1 60E-01 1

J

AppxB-5PCExls 2 of 3 - 982009

AR100321

APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

T

(sec)

Source-building

separation

LT

bull (cm)

Stratum A soil

air-filled porosity

Oa (cmcm)

Stratum B - soil air-filled porosity

ea (cmcm)

Stratum C soil

air-filled porosity

ea= - (cmcm)

Stratum A effective total fluid

saturation

sbdquo (cmcm)

Stratum A soil

intrinsic permeability

ki (cm)

Stratum A soil

relative air permeability

- ^ g

(cm)

Stratum A soil

effective vapor permeability

kv (cm)

Floor-wall

seam perimeter

^crack

(cm)

Soil gas

cone

(ngm)

BIdg venfilation

rate

Qbuildins

bull (cms)

bull bull

1 946E+08

Area of enclosed

space below grade

AB

(cm)

1

bullCrack-to-total

area ratio

1 (unitless)

0284 1

Crack bull depth below grade

Zcrack

(cm) -

0284 1

Enthalpy of vaporization at bull

ave soil temperature

bull A H V TS

(calmol)

0284

Henrys law constant at

ave soil temperature

HTS (atm-mmol)

0184

-Henrys law constant at

ave soil temperature

HTS

(unitless)

1 596E-09

Vapor viscosity at

ave soil temperature

HTS

(gcm-s)

0901

Stratum A

effective diffusion

coefficient bull D = bull

(cms)

537E-09

Stratum B

effective diffusion

coefficient

D--B (cms)

35357 1

Stratum C

effective diffusion bull

coefficient

D-c (crris)

149E+05

Total overall

effective bulldiffusion coefficient

DT

(cms)

440E+06 1

Difftjsion path

length

U (cm)

1 787E+07

Convection path

length

bull Lp

(cm)

4 49E-05

Source vapor cone

^source

(ngm)

15 1

Crack radius

Tcrack

(cm)

9528 1

Average vapor

flow rate intobldg

Qsoil (cms)

908E-03

Crack effective diffusion

coefficient pcrack

bull ( c m s ) bull

387E-01

Area of crack

Abdquoack (cm)

1 176E-04

Exponent of equivalent foundafion

Peclet number

exp(Pe)

(unitless)

bull

1 15-

1 END

149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08

727E-03

Infinite source indoor

attenuation coefficient

a

(unitless)

108E-05

OOOE+00

Infinite source

bIdg cone

Cburldtng

(Mgm)

161 E+00

OOOE+00 1

Unit risk

factor

URF

(ugm)-

59E-06 1

727E-03

Reference cone

RfC (mgm)

60E-01

1 1

Appx B-5 PCExls 3 of 3 982009

AR100322

APPENDIX B-6-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ersion31 0204

Reset to Defaults

t

Soil Gas Concentration Data ENTER

Chemical CAS No

(numbers only

no dashes)

79016

ENTER ENTER Soil Soil gas gas

cone OR cone C C -

bull (ngm) (ppmv)

782E+03

Chemical

Trichloroethylene

MORE ENTER Depth

below grade to bottom-

of enclosed space floor

LF

(cm)

ENTER

Soil gas sarnpling

depth below grade

U (cm)

ENTER

Average soil

temperature Ts

(degC)

1 15 1 15 t 125

ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e

(cm) (cm) (cm)

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estimate OR permeability soil vapor

permeability)

k (cm)

bull S L 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil bull-Parameters

ENTER Stratum A

soil dry bulk density

P b -

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Stratum A bull

soilwaterrfilled porosity

(cmcm) bull

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

bull P ^ (gcm)

ENTER Stratum B soil total

porosity

nlaquo

(unitless) -

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS bull soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor

width W B

(cm)

ENTER

Enclosed space height

H B bull

( c m ) bull

ENTER

Floor-wall seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bIdg OR

Leave blank to calculc

Qsoil

(Lm) -

Appx B-6 TCExIs 1 of 3 982009

A

AR100323

APPENDIX B-6-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight

Da Dbdquo H TR AH^b TB TC MW

Unit risk Reference

factor cone URF RfC

(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)

1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1

Appx B-6 TCExIs 2 of 3 982009

AR100324

APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

(sec)

Source-building

separation LT

(cm)

Stratum A soil

air-filled porosity

bull ea (cmcm)

Stratum B Soil

air-fllled porosity

e^ bull (cmcm)

Stratum C soil

air-filled porosity

(cmcm)

StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air

saturation permeability permeability

S|e k krg (cmcm) (cm) (cm)

Stratum A Floor-soil wall BIdg

effective vapor seam Soil ventilafion permeability perimeter gas rate

k^ bull Xack c o n e Qbuildins

(cm) (cm) (ngm) (cms)

946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |

Area of enclosed

space below grade

AB

(cm)

Ciack- to-total

area ratio

1 (unitless)

Crack depth below grade

Zcrack

(cm)

Enthalpy of vaporization at

ave soil temperature

A H J S

(calmol)

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law bull constant at

ave soil temperature

HTS

(unitless)

Vapor viscosity at

ave soil temperature

|JTS

(gcm^s)

Stratum A

effective diffusion

coefficient

(cms)

Stratum B

effective -diffusion

coefficient

D=B (cms)

Stratum ^ C effective diffusion

coefficient

D=c (cms)

Total overall

effective diffusion

coefficient

DT

(cms)

I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03

Diffusion path

length

Li (cm) bull

Convection bull path

length

Lp

(cm)

Source vapor cone bull

^source

(ngm)

Crack radius

rcrack

(cm)

Average vapor

- flow rate intobldg

Qsoil

(cms)

Crack effective diffusion

bull coefficient Qcrack

(cms)

Area of crack

^crack

(cm)

Exponent of equivalent foundation

Peclet bull number

exp(Pe)

(unitless)

bull bull

1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07

Infinite source Indoor

attenuation coefficient

a

(unitless)

108E-05

Infinite source

bIdg concgt

^building

(ngm)

844E-02

Unit risk

factor

URF

(ngm)-

Reference cone

RfC

(mgm)

1 1E-04 1 40E-02 1

END

Appx B-6 TCExIs 3 of 3 982009

AR100325

Office of Waste Management 1356 Hansford Street

Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256

West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director

ORDER

ISSUED UNDER THE

HAZARDOUS WASTE MANAGEMENT ACT

CHAPTER 22 ARTICLE 18

OF THE WEST VIRGINIA CODE^ AS AMENDED

y Order Number HW-011-80

To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704

ATTEMTION MREDARMON

Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull

AR100326

ViWJ011-laquo9 PageNunil)er2

BASIS FOR ORDER

As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following

A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^

B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator

C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities

0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94

^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement

P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following

1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater

2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was

^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment

CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable

CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order

AR100327

H W - 0 1 1 - 9 9 Page Number 3

REQUIREMENTS OF ORDER

Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows

1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^

2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore

remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling

GENERAL PROVaiONS

1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order

2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order

3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order

Effective Date

Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief

Wt T 1 V Oflice of Waste Management

AR100328

^ ^ S I S

^wmmmmamn

AR100329

Page 21: SDMS DocID 2121999 · International Enterprises Corp. building (Coyne Building), which is located at 1111 Vernon Street, Westmoreland District, Wayne County, West Virginia. The following

TABLE 4

FACTORS USED IN DOSE CALCULATIONS INHALATION OF VOLATILE EMISSIONS

Coyne Textile Services Facility - Huntington West Virginia

Symbol

CA

IRA

ET

EF

ED-

BW

AT

Exposure Factor

Constituent Concentration in Air

Inhalation Rate

Exposure Time

Exposure Frequency

Exposure Duration

Body Weight

Averaging Time

Indoor Worker

Constituent-Specific See Table 3

25 m hour

8 hrday

250 daysyear

25 years

bull 70 kg

9125 days (NC)

25550 days (C)

Total Dose = CA x IR^ x ET x EF x ED x 1BW x 1AT

(NC) - Non-carcinogenic Averaging Time

(C) - Carcinogenic Averaging Time

Coyne VI Memo Tables_09-08-09xls 982009

AR100298

TABLES TOXICITY VALUES FOR CHEMICALS OF CONCERN

Coyne Textile Services Facility - Huntington West Virginia

Chemical of Concern

Volatile Organics

124-Trimethylbenzene

12-Dichloroethene (cis)

Chloroform

Methylene chloride

tetrachloroethene

Triehloroethene

Target Organ Critical Effect

blood

bullblood

liver

liver

liver CMS

liver kidney fetus CNS

Chroniclnhalation Reference Dose

(mgkg-day)

200E-03 P

1 OOE-02 R

140E-02 E

286E-01 M

771 E-02 M

1OOE-02 E

Inhalation Cancer ^ Slope Factor

(mgkg-day)^

NA

NA

805E-02 1

165E-03 1

200E-02 0

400E-01 E

(I) - Integrated Risk Information System (IRIS USEPA 2009)

(P) - Provisional Peer-Reviewed Toxicity Value (PPRTV) as presented in USEPA Regional Screening Tables (ORNL 2009)

(R) - Calculated assuming route-to-route extrapolation as per WVDEP

(E)-Provisional value from the National Center for Environmental Assessment (as per WVDEP)

(M)-Chronic Minimal Risk Level (MRL ATSDR 2009)

(0) - Value cited by USEPA Region 3 attributed to other sources (as per WVDEP)

Coyne VI Memo Tables_09-08-09xls 982009

AR100299

TABLE 6

NONCANCER HAZARD INDEX AND POTENTIAL CANCER RISK FOR AN INDOOR WORKER

Coyne Textile Services Facility - Huntington West Virginia

bull

Constituent

Volatile Organics

124-Trinnethylbehzene

12-Dichlorpethene (cis)

Chloroform

Methylene chloride

Tetrachloroethene Triehloroethene

EPC in Indoor Air

(mgm)

213E-06

651 E-05

- 638E-05

164E-05

161 E-03

844E-05

Intake (ADD)

(mgkg-d)

416E-07

127E-05

125E-05

321 E-06

315E-04 l65E-05

RfDi

(mgkg-d)

200E-03

1OOE-02

140E-02

286E-01

771 E-02 1 OOE-02

Hazard

Quotient

208E-04

127E-03

892E-04

112E-05

408E-03 165E-03

Intake (LADD)

(mgkg-d)

) 149E-07

455E-06 bull 446E-06

115E-06

112E-04 590E-06

CSFi

(mgkg-d)

NA

NA

805E-02

165E-03

200E-02

400E-01

Potential

Cancer Risk

NA

NA

359E-07

189E-09

225E-06 236E-06

Total Hazard Index

00081 Total

Cancer Risk 497E-06

Total Blood HI = Total Liver HI =

Total Central Nervous System HI = Total Kidney HI =

Total Fetal HI =

bull 00015 00066 00057 00017 00017

Notes NA = Toxicity values are not available for this endpoint or exposure pathway

Coyne VI Memo Tables_09-08-09xls 982009

AR100300

APPENDIX A

SUBSLAB VAPOR ANALYTICAL DATA

AR100301

Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility Huntington West Virginia

Sample

Consti tuent

Volatile Organics (ugm) 111-Trlchloroethane 1122-Tetrachloroethane 112-Trichloro-122-trifluoroethane 112-Trichloroethane 11-Dichioroethane 11-Dichloroethene 124-Trichloroberi2ene 124-Trimethylbenzene 12-Dibromoethane 12-Dichloroben2ene 12-Dichloroethane 12-Dichloroethene-(cis) -12-Dichloroethene (trans) 12-Dichloropropane 12-Dichlorotetrafluoroethane 135-Trimethylbenzene 13-Butadiene 13-Dichlorobenzene 13-Hexachlorobutadiene 14-Dichlorobenzene 224-trimethVlpentane 2-Chlorotoluene 4-Ethyltoluene Acetone Allyl Chloride Benzene Bromodichloromethane Bromoform Bromomethane Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 13-Dichloropropene (cis) Cyclohexane Dibromochloromethane

Identif ication Sample Date

CAS No

71-55-6 79-34-5 76-13-1 79-00-5 75-34-3 75-35-4 120-82-1 95-63-6 106-93-4 95-50-1 107-06-2 156-59-2 156-60-5 78-87-5 76-14-2 108-67-8 106-99^0 541-73-1 87-68-3 106-46-7 540-84r1 95-49-8

622-96-8 67-64-1 107-05-1 71-43-2 75-27-4 75-252 74-83-9 75-15-0 56-23-5 108-90-7 75-00-3 67-66-3 74-87-3

10061-01-5 110-82-7 124-48-1

lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt

lt lt lt lt lt lt lt lt lt lt lt lt

lt

VP-01 8132009

22 28 31 22 16 16 30 20 31 24 16 16 16 19 28 20 89 24 43 24

1 9 21 20 796 13 13 27 41 16 13 25 18 11 20 83 18 52 34

lt lt lt lt lt lt lt lt lt lt lt

lt lt lt lt lt lt lt lt lt lt lt

lt lt lt lt lt lt lt lt lt

lt lt lt lt

VP-02 8132009

218 2 7 5 307 218 162 159 297

bull 197 307 240 162 369 159 185 280 197 89

240 427 240 187 207 197

1880 125 128 268 414 155 125 252 184 106

5910 83 182 138 341

lt lt lt lt lt lt lt

lt lt lt

lt lt lt lt lt lt lt bull

lt lt lt lt

lt lt lt lt lt lt lt lt lt lt lt lt lt lt

VP-03 8132009

218 275 307 218

bull 162 159 297 197 307 240 162

6030 159 185 280 197 89

240 427 240 187 207 197

1750 125 128 268 414 155 125 252 184 106 195 83 182 138 341

Appx A SG Dataxis Page 1 of 2 982009

AR100302

Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility bull Huntington West Virginia

Consti tuent

Volatile Organics (ugm^) Dichlorodifluoromethane Ethylbenzene Methyl ethyl ketone Methyl Isobutyl ketone Methyl tert-butyl ether Methylene chloride n-Heptane jn-Hexane Styrene Tert-butyl alcohol Tetrachloroethene iToluene 13-Dichloropropene (trans) Triehloroethene Trichlorofluoromethane Vinyl bromide Vinyl chloride Xylene (o) Xylenes (mampp)

Sample Identif ication Sample Date

CAS No

75-71-8 100-41-4 78-93-3 108-10-1

1634-04-4 75-09-2

142-82-5 bull 110-54-3

100-42-5 75-65-0 127-18-4 108-88-3

10061-02-6 79-01-6 75-69-4 593-60-2 75-01-4 95-47-6

179601-23-1

lt lt

lt lt lt lt

lt lt

lt

lt lt lt lt lt

VP01 8132009

20 17 23 16 14 14 16

173 17 12 bull

11200 18 18 91 23 18 10 17 17

lt lt lt lt lt

lt

lt lt

lt lt

lt lt lt lt lt

VP-02 8132009

198 174 118 164 144

1520 164 -183 170 121

149000 151 182

2360 225 175 102 174 174

VP-03 8132009

lt 198 lt 174 lt 118 lt 164 lt 144

1160 lt 164

144 lt 170 ltbull 121

90500 lt 151 lt 182

7820 lt 225 lt 175 lt 102

208 387

Appx A SG Dataxis Page 2 of 2 982009

AR100303

APPENDIX B

CALCULATION OF TRANSPORT FACTORS USED TO ESTIMATE INDOOR AIR CONCENTRATIONS

AR100304

APPENDIX B

Calculation of Transport Factors Used to Estimate Indoor Air Concentrations

This appendix presents the methodology for calculating transport factors that are used to convert subslab

vapor concentrations to concentrations in indoor air 124-Trimethylbenzene 12-dichloroethene (cis)

chloroform methylene chloride tetrachloroethene and triehloroethene were identified as contaminants of

concern (COC) for potential vapor intrusion from subslab vapor associated with the Coyne Textile

Services Facility located in Huntington West Virginia (site) In this appendix the transport factors are

calculated to estimate the concentrations of COC in indoor air of the existing plant building located at the

site ~

Transport Factor for Indoor Air

The concentration of a constituent in indoor air (da) is proportional to the concentration of the constituent

in the subslab vapors immediately beneath the building foundation (ie subslab vapor concentration or

Csubsiab) The following equation is used to calculate da from Csubsiab

^ wja ~ ^subslab X I r

where

Cia = concentration of constituent in indoor air (mgm^) -

Csubsiab^ concentration of constituent in subslab vapors (mgm^) and

TF = transport factor from subslab vapors to indoor air

The transport factor (TF) is an infinite source attenuation coefficient andcan be calculated based on a

model developed by Johnson and Ettinger (1991) t he equation for calculating TF is as follows

(Deff X A B ) ( Q B X L T ) X expKQso i l X Lcrabk)(Dcrack X Acrack)]

exp[ (Qsoi l X Lcrack)(Dcrack X Acrack)] + (Deff X A B ) ( Q B X L T ) + (Deff X AB)(Qsoi l X L j ) X (exp [ (Qso i l X Lcrack)(Dcrack X Acrack)] - 1)

where

Deff = effective diffusion coefficient for vadose zone soil (cm^sec)

AB = area of enclosed space below grade (cm^)

QB = building ventilation rate (cm^sec)

LT = distance from contaminant source to building foundation (cm)

Qsoii = volumetric flow rate of vapors into the building (cm^sec)

Lcrack = foundatlon thickness (cm)

Dcrack = vapor diffusion coefficient through crack (cm^sec) and

Acrack = area of cracks through which vapors can pass (cm^)

AR100305

To solve this equation the USEPAs SG-ADV spreadsheet Version 31 most recently updated in

February 2004 was implemented A combination of site-specific factors and default values from the

Users Guide for Evaluating Subsurface Vapor Intrusion Into Buildings (USEPA 2004) were used as input

values in the model All input values are defined below and presented in Tables B-1-A through B-6-A

bull The initial subslab vapor concentration (Csubsiab) is the maximum detected concentration(in units

of ugm ) of samples VP-01 VP-02 and VP-03 that was presented in Table 3 of the report

bull The depth below grade to the bottom of the enclosed space floor (Lp) is set to 15 cm the default

value provided by USEPA (2004) for a slab-on-grade structure

bull The vapor sampling depth below grade (Lg) is a site-specific value The vapor samples were

collected from immediately beneath the building floor therefore Lj has been set to 15 cm

bull The average soilgroundwater temperature (Ts) is set to 125degC the average value for West

Virginia as estimated frorri Figure 8 of the vapor intrusion users guide (USEPA 2004)

bull The soil type used to estimate vapor permeability is assumed to be sandy loam (SL) The

associated soil properties for a sandy loam soil type are as follows the soil dry bulk density (Pb) is

162 gcm the total porosity (n) is 0387 (cm^-aircm^) and the water-filled porosity (nw) is 0103

(cm -HzOcm )

bull The floor thickness (Lcrack) is set to the USEPA (2004) default value of 10 cm

bull The soil-building pressure differential (AP) is set to the USEPA (2004) default value of 40 gcm-s^

bull The building dimensions are siterspecific based on the existing plant building located at the site

The existing structure is approximately 84000 square feet (Dolphin 2000) therefore the

dimensions are set to 8839 cm (290 feet) length by 8839 cm (290 feet) The USEPA (2004)

default value of 244 cm vyas used for the height

bull Thefloor-wall seam crack width (w) is set to the USEPA (2004)-default value of 01 cm

bull The indoor air exchange rate (ER) is set to 083hour This is the value provided by ASTM (2002)

for commercial and industrial buildings

AR100306

Tables B-1-B through B-6-B present the constituent-specific properties for COC that were used in the TF

calculations Tables B-1-C through B-6-C present the intermediate calculations used to determine the

indoor air attenuation coefficients (ie the transport factors) The shaded boxes in Tables B-1-C through

B-6-C also present the resulting TF values that are applied to the concentrations of COC in subslab

vapor and the estimated indoor air concentrations

References

American Society for Testing and Materials (ASTM 2002) Standard Guide for Risk-Based Corrective Action Applied at Petroleum Release Sites ASTM E-1739-95 (Reapproved 2002)

Johnson PC and RA Ettinger (1991) Heuristic model for predicting the intrusion r-ate of contaminant vapors into buildings Environ Sci Technolpgy 25 1445-1452

Dolphin Environmental LLC (Dolphin 2000) Site Characterization Report Mach 14 2000

United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004

AR100307

APPENDIX B-1-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV Nersion31 0204

Reset to Defaults

ENTER -

Chemical CAS No

(numbers only

no dasties)

95636

ENTER Soil gas

cone

Cg (ngm)

Soil Gas Concentration Data ENTER

Soil gas

OR cone

bull - c bull (PPmv)

197E+02

Chemical

124-Trimethylbenzene

MORE ENTER Depth

below grade to bottom

of enclosed space floor

U bull (cm)

ENTER

Soil gas sampling

depth below grade

U (cm) bull

ENTER

Average soil

temperature Ts

CO

1 15 1 1 5 bull125

ENTER ENTER ENTER Totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hft ha he

(cm) (cm) (cm)

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estirnate OR permeability | soil vapor

permeability) k v bull

(cm)

SL 1 1

MORE ENTER

stratum A SCS

soil type

Lookup Soil Parameters

ENTER stratum A soil dry

bulk density P

(gcm)

ENTER Stratum A soil total porosity

(unitless)

ENTER bull stratum A soil water-filled

porosity

(cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

nlaquo

(unitless)

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gchi-s^)

ENTER Enclosed

space floor

length bull LB

(cm)

ENTER Enclosed

space floor

width WB

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

bull Floor-wall seam crack

width w

(cm)

bullENTER

Indoor air exchange

rate ER

(1h) bull

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bidg OR

Leave blank to caicuij

(Lm)

Appx B-1 124-TMBxls 1 of 3 982009

AR100308

APPENDIX B-1-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of ^ bull law constant law constant vaporization at Normal

Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temperature boiling point point temperature weight

D bull Dbdquo H T R bull AHbdquo TB Tc IVIW

Unit risk Reference

factor cone URF RfC

(cms) (cmls) (atm-mmol) CO (calmol) (degK) (degK) (gmol) bull (ugm)- (mgm)

1 606E-02 1 792E-06 1 bull 614E-C3 1 25 1 9369 1 44230 | 64917 1 12020 1 OOE+00 1 60E-03 1

Appx B-1 124-TMBxls 2 of 3 982009

AR100309

APPENDIX B-1-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

(sec)

Source-building

separation

LT bull

(cm) bull

Stratum A soil

air-filled porosity

Q A

Stratum B soil

air-filled porosity

(cmcm) (cmcm)

Stratum C soil air-filled porosity

(cmcm)

Stratum A effective total fluid

saturation

Se

(cmcm)

Stratum A soil

bullintrinsic permeability

^ (cm)

stratum A Stratum A Floor- soil soli wall BIdg

relative air effective vapor seam Soil bull ventilation permeability permeability perimeter gas rate-

kfg ky Xgrack c o n e - QbuHdinpound

(cm) - (cm) (cm) (ngm) (cms)

946E+08 1 0284 0284 0284 0184 596E-09 0901 537E-09 35357 I 197E+02 | 439E+06 |

Area of enclosed

space below grade

As (cm)

Crack-to-total area ratio

1 bull

(unitless)

Crack depth

below grade

Zcfack

(cm)

Enthalpy of vaporization at

ave soil temperature

AHvjs

(calmol) bull

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law constant at

ave soil bull temperature

bull HTS

(unitless)

Vapor bull viscosity at

ave soil temperature

HTS

(gcm-s)

Stratum A

effective diffusion

coefficient

D (cms)

Stratum-B

effective diffusion coefficient

DB (cms)

Stratum C effective diffusion

coefficient

D-c (cms)

Total - overall effective diffusion

coefficient

D ^ (cms)

Diffusion path

length

L-

(cm)

I 787E+07 I 449E-05 | 15 | 11661 260E-03 111E-01 176E-04 I 612E-03 j OOOE+00 | OOOE+00 | 612E-03 j

bull Convection path

length

Lp

(cm)

Source vapor cone

^source

(ngm)

Crack radius

Tcfack

(cm)

Average vapor

flow rate into bIdg

Qsoii

(cms)

Crack effective diffusion

coefficient pcrack

(cms)

Area of CTack

Acack

(cm)

Exponent of equivalent foundation

Peclet number

exp(Pe)

(unitless)

bull bull - bull bull bull bull

1 15 1 197E+02 1 010 1 474E+01 612E-03 bull 354E-t-03 1 336E+09

Infinite source Indoor

~ attenuation coefficient

a

(unitless)

108E-05

Infinite source

btJbldgjJSv-L ^Ppncji3i-

virhpbiiilding bullbull ^lHltti^m)ilg

213E-03

Unit risk

factor

URF

(ngm)-

Reference cone

RfC (mgm)

NA 60E-03 1

I END

Appx B-1 124-TMBxls 3 of 3 982009

AR100310

APPENDIX B-2-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV Nersion31 020^

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

156592

Soil Gas Concentration Data ENTER

Soil gas

cone OR c

(ngm) bull

ENTER Soil bull-gas

cone

c (ppmv)

603E+03 1

Chemical

cis-12-Dichloroethylene

MORE ENTER Depth

below grade to bottom

of enclosed space floor

LF

(cm)

ENTER

Soil gas sampling

depth below grade

U (cm)

ENTER

Average soil

temperature bull Ts

(degC)

1 15 1 bull 15 125

ENTER ENTER ENTER Totalsmust add ijp tb value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hA hB he

bull (cm) (cm) (cm)

15 1 1

ENTER Soil

straturh A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estimate OR permeability | soil vapor

permeability) kv

(cm)

SL 1 |

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

P (gcm)

ENTER Stratum A soil total porosity

bull n

(unitless)

ENTER Stratum A

soil water-filled porosity

(cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

ENTER Stratum B

soil water-filled porosity

ENTER Stratum C

SCS soil type

(unitless) (cmcm)

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure differential

AP

(gcm-s)

ENTER Enclosed bull

space floor

length

LB (cm)

ENTER Enclosed

space floor

width WB

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER

Average vapor flow rate into bIdg

OR Leave blank to calculi

Qsoil

(Lm)

Appx B-2 cis-12-DCExls 1 of 3 982009

AR100311

APPENDIX B-2-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Diffusivity in air

Da

(cms)

Diffusivity in water

Dw (cms)

Henrys law constant at reference temperature

H

(atm-mmoi)

Henrys law constant

reference temperature

bull T R

CC)

Enthalpy of vaporization at

the normal boiling point

AHbdquob

(calmol)

Normal boiling point

TB

(degK)

Critical temperature

Tc (degK)

Molecular weight

MW

(gmol)

Unit risk

factor URF

(ngm)

Reference cone

RfC (mgm)

1 736E-02 1 113E-05 1 407E-03 j 1 25 1 bull 7192 1 33365 1 54400 1 9694 1 OOE+00 j 35E-02 1

Appx B-2 cis-12-DCExls 2 of 3 982009

AR100312

APPENDIX B-2-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

stratum A Stratum B Stratum C Source- soil soil soil

Exposure building air-filled air-filled air-filled

duration separation porosity porosity porosity

T LT ea e^ bull e= (sec) (cm) (cmcm) (cmcm) (cmcm)

I 946E+08n^

Stratum A Stratum A Stratum A Stratum A Floor-effective soil soil soil wall total fluid intrinsic relative air effective vapor seam

saturation permeability permeability permeability perimeter

Ste kj krg ky Acrack

(cmcm) (cm) (cm) (cm) (cm)

Soil gas

cone (ngm)

I 0284 I 0284~ 0284 0184 I 596E-09 | 090T 537E-09 35357 603E+03

BIdg ventilation

rate

JbulldinE

(cms)

439E+06

Area of enclosed

space below grade

AB

(cm)

Crack-to-total

area ratio

n (unitless)

Crack depth below grade

Zltiack (cm)

Erithalpy of vaporization at

ave soil temperature

AHvTs (calmol)

Henryslaw constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law constant at

ave soil temperature

HTS

(unitless) bull

Vapor viscosity at

ave soil bull temperature

HTS

bull (gcm-s)

Stratum A

effective bull diffusion

coefficient

D^A-(cms)

Stratum B

effective bull diffusion

coefficient

D=B

(cms)

Stratum C

effective diffusion bull

coefficient

D=e (cms)

Total overall

effective diffusion

coefficient

DT

(cms)

Diffusion path

length

Ld

(cm)

I 787E+07 I bull449E-05 | 15 bull7709 230E-03 982E-02 176E-04 | 743E-03 | OOOE+00 | OOOE+00 | 743E-03 |

bull bull bull -

Convecfion path -bull

length

Lp (cm)

Source vapor cone

-source

(Mgm)

Crack radius

fcrack

(cm)

Average vapor

flow rate into bIdg

Qaoil bull

(cms)

Crack effective diffusion

coefficient pcack

(cms)

Area of crack

crack

(cm)-

Exponent of equivalent foundation

Peclet number

exp(Pef)

(unitless)

bull

1 15 -1 603E+03 1 010 1 474E+01 743E-03 354E+03 1 697E+07

Infinite source Indoor

attenuation coefficient

poundbullbullbull C t

pound(unitless)

bullsiilaquogt j ii08E-05

Infinite [ source

bIdg cone

Cbujidjng

(pgm)

651 E-02 iKrt

Unit risk

factor

URF

(ngm)-

Reference cone

RfC

(mgm)

NA 35E-02 1

I END I

Appx B-2 cis-12-DCExls 3o f3 982009

AR100313

APPENDIX B-3-A DATA ENTRY SHEET

Coyne Texti le Services - Hunt ington West Virginia

SG-ADV Version 31 0204

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

67663

Soil Gas Concentration Data ENTER ENTER

Soil Soil gas gas

cone OR cone c C

(^gm) (ppmv)

591 E+03

bull

Chemical

Chloroform

MORE ENTER Depth

below grade tb bottom

of enclosed space floor

bull LF

(cm)

ENTER

Soil gas sampling depth

below grade

(cm)

ENTER

Average soil

temperature-Ts

CO bull

1 15 1 15 1 125

ENTER ENTER ENTER Totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

IIA hs he (cm) (cm) (cm)

1 5 bull 1 1

ENTER ENTER Soil - bull

stratum A User-defined SCS stratum A

soil type bull soil vapor (used to estimate OR permeability

soil vapor k

bull permeability) (cm) 1

SL 1 1 bull

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A soil dry

bulk density

Pb (gcm)

ENTER Stratum A soil total porosity

nV (unitless)

ENTER Stratum A

-soilwater-filled bullporosity

Sraquo (cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

(unitless)

ENTER Stratum B

soil water-filled porosity

bull ebdquo=

(cmcm) bull

ENTER Straturri C

SCS bull soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

- c rack

(cm)

ENTER

Soil-bldg pressure

differential AP^

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor

width bull W B

(cm)

ENTER

Enclosed space

height HB

(cm)

ENTER

bull Floor-wall^ seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bidg OR

Leave blank to calculi

Qsoil bull

(Lm)

I -I

Appx B-3 Chloroformxls 1 of 3 982009

AR100314

APPENDIX B-3-B CHEMICALPROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Diffusivity in air

D (cms)

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffijsivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature

Dbdquo H TR A H bdquo TB Tc

(cm s) (atm-m mol) ro (calmol) (degK) (degK)

Molecular weight

MW

(gmol)

Unit risk

factor URF

(ngm)-

Reference cone

RfC

(mgm)

104E-01 100E-05 I 366E-03 25 6988 33432 53640 11938 I 23E-05 | OOE+00

Appx B-3 Chloroformxls 2 of 3 982009

AR100315

APPENDIX B-3-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure

duration

(sec)

Source-

building

separation

LT

(cm)

Stratum A

soil

air-filled

porosity

Sa

( cm cm )

Stratum B

soil

air-filled

porosity

( cm cm )

Stratum C

soil

air-filled

porosity

( c m c m )

Stratum A

effective

total fluid

saturation

( c m c m )

Stratum A

soil

intrinsic

penmeability

k

(cm )

Stratum A

- soil

relative air

permeabil i ty

(cm )

Stratum A

soil

effective vapor

permeability

kv

(cm )

Floor-

wall

seam

perimeter

gtcrack

(cm)

Soil gas

cone

(ngm)

BIdg

venfilation

rate

^buildlriE

(cms)

I 9 4 6 E + 0 8 ~ T I 0284 T 596E-09 I 0-901 I 537E-09 | 35357 | 591 E+03 j 439E+06 | 1 0 284 0284 0184

Area of

enclosed

space

below

grade

A B

( c m )

Crack-

to-total

area

ratio

n

(unitless)

Crack

depth

bull below

grade

^crack

(cm)

Enthalpy of

vaporization at

ave soil

temperature

AHTs bull

(calmol)

Henry s law

constant at

ave soil

temperature

HTS

(a tm-m mol j

Henrys law

constant at

ave soil

bull temperature

HTS

(unitless) bull

Vapor

viscosity at

ave soil-

temperature

^HTS

(gcm-s)

Stratum

A

effective

diffusion

coefficient

(cm s)

Stratum

B

effective

difftjsion

coefficient

D B

(cms) bull

S t ra tum

C

effective

diffusion

coefficient

Dc

(cm s)

Total

overall

effective

bull diffusion

coefficient

D T

(cm s)

Diffi jsion

path

length

Ld

(cm)

I 787E+07 I 449E-05 j - bull 15 7528 210E-03 896E-02 176E-04 I 105E-02 | OOOE+00 | OOOE+00 | 105E-02

Convection

path length

Lp

(cm)

Source

vapor

cone -

^source

- (ngm)

Crack

radius

Tcrack

(cm)

Average

vapor

flow rate

into bidg

Qsoil

(cms)

Crack

effective

diffusion

coefficient Qcrack

bull (cms)

Area of crack

Acrack

(cm)

Exponent of

equivalent

foundation

Peclet number

exp(Pe)

(unitless)

V bull bull

1 15 1 591 E+03 1 010 1 474E+01 105E-02 354E+03 1 355E+05

Infinite

source

indoor

attenuation

coefficient

d

(unitless)

bull 108E-05

Infinite

source

bIdg

cone

^ b u i l d i n g

i (^gm)

bull bull

i 638E-02 -

Unit

risk bull factor

URF

(ngmY

Reference

cone

RfC

(mgm)

~ 23E-05 NA 1

I END

Appx B-3 Chloroform xls 3 of 3 982009

AR100316

APPENDIX B-4-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ersion 31-020^

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

nodashes)

bull 75092

ENTER Soil gas

cone

c (ngm)

Soil Gas Concentration Data ENTER

Soil gas bull

OR cone

bull C

(ppmv)

152E+03

bull bull

Chemical

Methylene chloride

MORE

MORE 4gt

ENTER Depth

below grade to bottom

of enclosed space floor

LF -

(cm)

ENTER

Soil gas sampling depth

below grade

bull U

(cm)

ENTER

Average soil

temperature

Ts bull CC)

bull bull bull bull

1 15 1 15 125

ENTER Totals

Thickness of soil

stratum A h

(cm)

ENTER ENTER must add up to value of Ls (cell F24

Thickness Thickness of soil of soil

stratum B stratum C (Enter value or 0) (Enter value or 0)

he he bull

(cm) bull (cm) -

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(usedto estimate OR perrrieability | soil vapor

permeability)

k bull

(cm)

SL 1 bull 1

ENTER Stratum A

SCS soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

Pb (gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Stratum A

soil water-filled porosity

9w (cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

Pb^

(gcm)

ENTER Stratum B soil total porosity

n^

(unitless)

ENTER Stratum B

soil water-filled porosity

(crhcm)

ENTER Stratum C

SCS soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE 4gt

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

bull Soil-bldg pressure

differential AP^

(gcm-s)

ENTER Enclosed

space floor

length LB

(cm)

ENTER Enclosed

space floor

width bull W B

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width

w

(cm)

ENTER

Indoor air exchange

rate

ER (1h)

ENTER Average vapor

flow rate into bidg OR

Leave blank to calculc

Qsoil

(Lm)

10 40 8839 8839 244 01 083

Appx B-4 MCxIs 1 of 3 982009

AR100317

Diffijsivity in air

D

APPENDIX B-4-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffusivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature

Pw H TR AHt TB TC

Molecular weight

MW

Unit risk

factor URF

Reference cone

RfC

(cms) (cms) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) bull (ngm)- (mgm)

bull bull

1 101E-01 1 117E-05 1 218E-03 1 25 | 6706 1 31300 1 51000 1 8493 1 47E-07 1 30E+00 1

Appx B-4 MCxIs 2 of 3 982009

AR100318

APPENDIX B-4-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

T

(sec)

Source- -building

separation

LT

(cm)

Stratum A soil

air-filled porosity

e a bull

(cmcm)

Stratum B soil

bullair-filled porosity bull

ea^ (cmcm)

Stratum C soil

air-filled porosity

ea= (cmcmj

Stratum A effective total fluid

saturation

Sc bull

(cmcm)

Stratum A soil

intrinsic pemneability

ki (cm)

Stratum A soil

relative air permeability

^ ^ g

(cm)

stratumA bull soil effective vapor permeability

K (cm)

Floor-wall

seam perimeter

Xcrack

(cm)

Soil gas

cone (ngm)

BIdg ventilation

rate

Qbuildinc

(cms)

1 946E+08

Area of -enclosed

space below

bull grade

AB

(cm)

1

Crack-to-total

area rafio

Tl

(unitless)

0284 1

Crack depth below grade

Zcrack

(cm)

0284 1

bull Enthalpy of vaporization at

ave soil temperature

AHTs (calmol)

0284

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

0184

Henrys law constant at ave soil

temperature

HTS

bull (unitless)

1 596E-09

Vapor viscosity at

ave soil temperature

Mrs (gcm-s)

0901

Stratum A

effective diffusion

coefficient

D (cms)

537E-09

Stratum B

effective diffusion

coefficient

D-B (cms)

35357 1

Stratum C -

effective diffusion

coefficient

D-c ^ (cms)

152E+03

Total bull overall

bull effective diffusion

coefficient

D ^

(cms)

440E+06 1

Difftjsion path

length

Ld (cm)

1 787E+07

Convection path

length

Lp (cm)

4 49E-05

Source vapor cone

Csource

(ngm)

15 1

Crack radius

Tcrack

(cm)

7007 bull 1

Average vapor

flow rate intobldg

Qsoil

(cms)

130E-03

Crack effective diffusion

coefficient pcrack

(cms)-

555E-02

bull ^

Area of crack

Acrack

(cm) bull

1 176E-04

Exponent of equivalent foundation

Peclet number

exp(Pe)

(unitless) bull

bull bull

1 15

1 END

152E+03 010 1 474E+01 1 102E-02 354E+03 1 519E+05

102E-02

Infinite source

indoor ^attenuation coefficient

bull a

(unitless)

aiii08E-05

0 OOE+00

bull

Infinite bull source

bIdg ^ cone

^bu i l d i ng

(MQm)

164E-02

OOOE+00 1

Unit risk

factor

URF

(ngm)-

47E-07 1

102E-02 j

Reference cone

RfC

(mgm)

30E+00 j

1 1

Appx B-4 MCxIs 3 of 3 982009

AR100319

APPENDIX B-5-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ^erslon 31 0204

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

127184

Soil Gas Concentration Data ENTER ^ ENTER

Soil -Soi l bull gas gas

cone OR cone Cg C bull

(tgm) (ppmv)

149E+05 1

Chemical

bull Tetrachlbroethylene

MORE 4

ENTER Depth

below grade to bottom

ofenclosecJ space floor

LF

(cm)

ENTER

Soil gas bull sampling

depth below grade

u bull (cm)

ENTER

Average bullsoil

temperature - Ts

ro 1 1 5 1 15 1 125 bull

ENTER ENTER ENTER totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hft bull he bull he

(cm) (cm) (cm)

bull 1 5 1 - 1

ENTER ENTER Soil

stratum A User^defined bull SCS bull stratum A soil type soil vapor

(used to estimate OR perrrieability soil vapor K bull

permeability) (cm) 1

SL 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

Pb

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Sitratum A

soil water-filled bull porosity

(cmcm)

ENTER Stratum B

SCS soiltype

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

Pb^

(gcm)

ENTER Stratum B soil total porosity

Ajnitless^

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS soil type

LookupSoil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

VS

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor width

W B

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width

w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

ENTER Average vapor

flow rate into bidg OR

Leave blank to calcul

bull Qsoil

(Lm)

10 40 8839 8839 244 01 083

Appx B-5 PCExIS 1 of 3 982009

AR100320

APPENDIX B-5-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal Unit

Diffusivity Diffusivity at reference reference the riormal boiling Critical Molecular risk Reference in air in water temperature temperature boiling point point teriiperature weight factor cone

Da Dbdquo H TR AHb TB Tc MW URF RfC

(cms) (cnis) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) (^gm)- (mgm)

1 720E-02 1 820E-06 1 184E-02 1 25 1 8288 1 39440 1 62020 1 16583 1 59E-06 1 60E-01 1

J

AppxB-5PCExls 2 of 3 - 982009

AR100321

APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

T

(sec)

Source-building

separation

LT

bull (cm)

Stratum A soil

air-filled porosity

Oa (cmcm)

Stratum B - soil air-filled porosity

ea (cmcm)

Stratum C soil

air-filled porosity

ea= - (cmcm)

Stratum A effective total fluid

saturation

sbdquo (cmcm)

Stratum A soil

intrinsic permeability

ki (cm)

Stratum A soil

relative air permeability

- ^ g

(cm)

Stratum A soil

effective vapor permeability

kv (cm)

Floor-wall

seam perimeter

^crack

(cm)

Soil gas

cone

(ngm)

BIdg venfilation

rate

Qbuildins

bull (cms)

bull bull

1 946E+08

Area of enclosed

space below grade

AB

(cm)

1

bullCrack-to-total

area ratio

1 (unitless)

0284 1

Crack bull depth below grade

Zcrack

(cm) -

0284 1

Enthalpy of vaporization at bull

ave soil temperature

bull A H V TS

(calmol)

0284

Henrys law constant at

ave soil temperature

HTS (atm-mmol)

0184

-Henrys law constant at

ave soil temperature

HTS

(unitless)

1 596E-09

Vapor viscosity at

ave soil temperature

HTS

(gcm-s)

0901

Stratum A

effective diffusion

coefficient bull D = bull

(cms)

537E-09

Stratum B

effective diffusion

coefficient

D--B (cms)

35357 1

Stratum C

effective diffusion bull

coefficient

D-c (crris)

149E+05

Total overall

effective bulldiffusion coefficient

DT

(cms)

440E+06 1

Difftjsion path

length

U (cm)

1 787E+07

Convection path

length

bull Lp

(cm)

4 49E-05

Source vapor cone

^source

(ngm)

15 1

Crack radius

Tcrack

(cm)

9528 1

Average vapor

flow rate intobldg

Qsoil (cms)

908E-03

Crack effective diffusion

coefficient pcrack

bull ( c m s ) bull

387E-01

Area of crack

Abdquoack (cm)

1 176E-04

Exponent of equivalent foundafion

Peclet number

exp(Pe)

(unitless)

bull

1 15-

1 END

149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08

727E-03

Infinite source indoor

attenuation coefficient

a

(unitless)

108E-05

OOOE+00

Infinite source

bIdg cone

Cburldtng

(Mgm)

161 E+00

OOOE+00 1

Unit risk

factor

URF

(ugm)-

59E-06 1

727E-03

Reference cone

RfC (mgm)

60E-01

1 1

Appx B-5 PCExls 3 of 3 982009

AR100322

APPENDIX B-6-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ersion31 0204

Reset to Defaults

t

Soil Gas Concentration Data ENTER

Chemical CAS No

(numbers only

no dashes)

79016

ENTER ENTER Soil Soil gas gas

cone OR cone C C -

bull (ngm) (ppmv)

782E+03

Chemical

Trichloroethylene

MORE ENTER Depth

below grade to bottom-

of enclosed space floor

LF

(cm)

ENTER

Soil gas sarnpling

depth below grade

U (cm)

ENTER

Average soil

temperature Ts

(degC)

1 15 1 15 t 125

ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e

(cm) (cm) (cm)

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estimate OR permeability soil vapor

permeability)

k (cm)

bull S L 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil bull-Parameters

ENTER Stratum A

soil dry bulk density

P b -

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Stratum A bull

soilwaterrfilled porosity

(cmcm) bull

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

bull P ^ (gcm)

ENTER Stratum B soil total

porosity

nlaquo

(unitless) -

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS bull soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor

width W B

(cm)

ENTER

Enclosed space height

H B bull

( c m ) bull

ENTER

Floor-wall seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bIdg OR

Leave blank to calculc

Qsoil

(Lm) -

Appx B-6 TCExIs 1 of 3 982009

A

AR100323

APPENDIX B-6-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight

Da Dbdquo H TR AH^b TB TC MW

Unit risk Reference

factor cone URF RfC

(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)

1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1

Appx B-6 TCExIs 2 of 3 982009

AR100324

APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

(sec)

Source-building

separation LT

(cm)

Stratum A soil

air-filled porosity

bull ea (cmcm)

Stratum B Soil

air-fllled porosity

e^ bull (cmcm)

Stratum C soil

air-filled porosity

(cmcm)

StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air

saturation permeability permeability

S|e k krg (cmcm) (cm) (cm)

Stratum A Floor-soil wall BIdg

effective vapor seam Soil ventilafion permeability perimeter gas rate

k^ bull Xack c o n e Qbuildins

(cm) (cm) (ngm) (cms)

946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |

Area of enclosed

space below grade

AB

(cm)

Ciack- to-total

area ratio

1 (unitless)

Crack depth below grade

Zcrack

(cm)

Enthalpy of vaporization at

ave soil temperature

A H J S

(calmol)

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law bull constant at

ave soil temperature

HTS

(unitless)

Vapor viscosity at

ave soil temperature

|JTS

(gcm^s)

Stratum A

effective diffusion

coefficient

(cms)

Stratum B

effective -diffusion

coefficient

D=B (cms)

Stratum ^ C effective diffusion

coefficient

D=c (cms)

Total overall

effective diffusion

coefficient

DT

(cms)

I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03

Diffusion path

length

Li (cm) bull

Convection bull path

length

Lp

(cm)

Source vapor cone bull

^source

(ngm)

Crack radius

rcrack

(cm)

Average vapor

- flow rate intobldg

Qsoil

(cms)

Crack effective diffusion

bull coefficient Qcrack

(cms)

Area of crack

^crack

(cm)

Exponent of equivalent foundation

Peclet bull number

exp(Pe)

(unitless)

bull bull

1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07

Infinite source Indoor

attenuation coefficient

a

(unitless)

108E-05

Infinite source

bIdg concgt

^building

(ngm)

844E-02

Unit risk

factor

URF

(ngm)-

Reference cone

RfC

(mgm)

1 1E-04 1 40E-02 1

END

Appx B-6 TCExIs 3 of 3 982009

AR100325

Office of Waste Management 1356 Hansford Street

Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256

West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director

ORDER

ISSUED UNDER THE

HAZARDOUS WASTE MANAGEMENT ACT

CHAPTER 22 ARTICLE 18

OF THE WEST VIRGINIA CODE^ AS AMENDED

y Order Number HW-011-80

To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704

ATTEMTION MREDARMON

Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull

AR100326

ViWJ011-laquo9 PageNunil)er2

BASIS FOR ORDER

As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following

A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^

B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator

C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities

0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94

^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement

P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following

1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater

2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was

^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment

CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable

CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order

AR100327

H W - 0 1 1 - 9 9 Page Number 3

REQUIREMENTS OF ORDER

Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows

1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^

2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore

remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling

GENERAL PROVaiONS

1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order

2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order

3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order

Effective Date

Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief

Wt T 1 V Oflice of Waste Management

AR100328

^ ^ S I S

^wmmmmamn

AR100329

Page 22: SDMS DocID 2121999 · International Enterprises Corp. building (Coyne Building), which is located at 1111 Vernon Street, Westmoreland District, Wayne County, West Virginia. The following

TABLES TOXICITY VALUES FOR CHEMICALS OF CONCERN

Coyne Textile Services Facility - Huntington West Virginia

Chemical of Concern

Volatile Organics

124-Trimethylbenzene

12-Dichloroethene (cis)

Chloroform

Methylene chloride

tetrachloroethene

Triehloroethene

Target Organ Critical Effect

blood

bullblood

liver

liver

liver CMS

liver kidney fetus CNS

Chroniclnhalation Reference Dose

(mgkg-day)

200E-03 P

1 OOE-02 R

140E-02 E

286E-01 M

771 E-02 M

1OOE-02 E

Inhalation Cancer ^ Slope Factor

(mgkg-day)^

NA

NA

805E-02 1

165E-03 1

200E-02 0

400E-01 E

(I) - Integrated Risk Information System (IRIS USEPA 2009)

(P) - Provisional Peer-Reviewed Toxicity Value (PPRTV) as presented in USEPA Regional Screening Tables (ORNL 2009)

(R) - Calculated assuming route-to-route extrapolation as per WVDEP

(E)-Provisional value from the National Center for Environmental Assessment (as per WVDEP)

(M)-Chronic Minimal Risk Level (MRL ATSDR 2009)

(0) - Value cited by USEPA Region 3 attributed to other sources (as per WVDEP)

Coyne VI Memo Tables_09-08-09xls 982009

AR100299

TABLE 6

NONCANCER HAZARD INDEX AND POTENTIAL CANCER RISK FOR AN INDOOR WORKER

Coyne Textile Services Facility - Huntington West Virginia

bull

Constituent

Volatile Organics

124-Trinnethylbehzene

12-Dichlorpethene (cis)

Chloroform

Methylene chloride

Tetrachloroethene Triehloroethene

EPC in Indoor Air

(mgm)

213E-06

651 E-05

- 638E-05

164E-05

161 E-03

844E-05

Intake (ADD)

(mgkg-d)

416E-07

127E-05

125E-05

321 E-06

315E-04 l65E-05

RfDi

(mgkg-d)

200E-03

1OOE-02

140E-02

286E-01

771 E-02 1 OOE-02

Hazard

Quotient

208E-04

127E-03

892E-04

112E-05

408E-03 165E-03

Intake (LADD)

(mgkg-d)

) 149E-07

455E-06 bull 446E-06

115E-06

112E-04 590E-06

CSFi

(mgkg-d)

NA

NA

805E-02

165E-03

200E-02

400E-01

Potential

Cancer Risk

NA

NA

359E-07

189E-09

225E-06 236E-06

Total Hazard Index

00081 Total

Cancer Risk 497E-06

Total Blood HI = Total Liver HI =

Total Central Nervous System HI = Total Kidney HI =

Total Fetal HI =

bull 00015 00066 00057 00017 00017

Notes NA = Toxicity values are not available for this endpoint or exposure pathway

Coyne VI Memo Tables_09-08-09xls 982009

AR100300

APPENDIX A

SUBSLAB VAPOR ANALYTICAL DATA

AR100301

Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility Huntington West Virginia

Sample

Consti tuent

Volatile Organics (ugm) 111-Trlchloroethane 1122-Tetrachloroethane 112-Trichloro-122-trifluoroethane 112-Trichloroethane 11-Dichioroethane 11-Dichloroethene 124-Trichloroberi2ene 124-Trimethylbenzene 12-Dibromoethane 12-Dichloroben2ene 12-Dichloroethane 12-Dichloroethene-(cis) -12-Dichloroethene (trans) 12-Dichloropropane 12-Dichlorotetrafluoroethane 135-Trimethylbenzene 13-Butadiene 13-Dichlorobenzene 13-Hexachlorobutadiene 14-Dichlorobenzene 224-trimethVlpentane 2-Chlorotoluene 4-Ethyltoluene Acetone Allyl Chloride Benzene Bromodichloromethane Bromoform Bromomethane Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 13-Dichloropropene (cis) Cyclohexane Dibromochloromethane

Identif ication Sample Date

CAS No

71-55-6 79-34-5 76-13-1 79-00-5 75-34-3 75-35-4 120-82-1 95-63-6 106-93-4 95-50-1 107-06-2 156-59-2 156-60-5 78-87-5 76-14-2 108-67-8 106-99^0 541-73-1 87-68-3 106-46-7 540-84r1 95-49-8

622-96-8 67-64-1 107-05-1 71-43-2 75-27-4 75-252 74-83-9 75-15-0 56-23-5 108-90-7 75-00-3 67-66-3 74-87-3

10061-01-5 110-82-7 124-48-1

lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt

lt lt lt lt lt lt lt lt lt lt lt lt

lt

VP-01 8132009

22 28 31 22 16 16 30 20 31 24 16 16 16 19 28 20 89 24 43 24

1 9 21 20 796 13 13 27 41 16 13 25 18 11 20 83 18 52 34

lt lt lt lt lt lt lt lt lt lt lt

lt lt lt lt lt lt lt lt lt lt lt

lt lt lt lt lt lt lt lt lt

lt lt lt lt

VP-02 8132009

218 2 7 5 307 218 162 159 297

bull 197 307 240 162 369 159 185 280 197 89

240 427 240 187 207 197

1880 125 128 268 414 155 125 252 184 106

5910 83 182 138 341

lt lt lt lt lt lt lt

lt lt lt

lt lt lt lt lt lt lt bull

lt lt lt lt

lt lt lt lt lt lt lt lt lt lt lt lt lt lt

VP-03 8132009

218 275 307 218

bull 162 159 297 197 307 240 162

6030 159 185 280 197 89

240 427 240 187 207 197

1750 125 128 268 414 155 125 252 184 106 195 83 182 138 341

Appx A SG Dataxis Page 1 of 2 982009

AR100302

Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility bull Huntington West Virginia

Consti tuent

Volatile Organics (ugm^) Dichlorodifluoromethane Ethylbenzene Methyl ethyl ketone Methyl Isobutyl ketone Methyl tert-butyl ether Methylene chloride n-Heptane jn-Hexane Styrene Tert-butyl alcohol Tetrachloroethene iToluene 13-Dichloropropene (trans) Triehloroethene Trichlorofluoromethane Vinyl bromide Vinyl chloride Xylene (o) Xylenes (mampp)

Sample Identif ication Sample Date

CAS No

75-71-8 100-41-4 78-93-3 108-10-1

1634-04-4 75-09-2

142-82-5 bull 110-54-3

100-42-5 75-65-0 127-18-4 108-88-3

10061-02-6 79-01-6 75-69-4 593-60-2 75-01-4 95-47-6

179601-23-1

lt lt

lt lt lt lt

lt lt

lt

lt lt lt lt lt

VP01 8132009

20 17 23 16 14 14 16

173 17 12 bull

11200 18 18 91 23 18 10 17 17

lt lt lt lt lt

lt

lt lt

lt lt

lt lt lt lt lt

VP-02 8132009

198 174 118 164 144

1520 164 -183 170 121

149000 151 182

2360 225 175 102 174 174

VP-03 8132009

lt 198 lt 174 lt 118 lt 164 lt 144

1160 lt 164

144 lt 170 ltbull 121

90500 lt 151 lt 182

7820 lt 225 lt 175 lt 102

208 387

Appx A SG Dataxis Page 2 of 2 982009

AR100303

APPENDIX B

CALCULATION OF TRANSPORT FACTORS USED TO ESTIMATE INDOOR AIR CONCENTRATIONS

AR100304

APPENDIX B

Calculation of Transport Factors Used to Estimate Indoor Air Concentrations

This appendix presents the methodology for calculating transport factors that are used to convert subslab

vapor concentrations to concentrations in indoor air 124-Trimethylbenzene 12-dichloroethene (cis)

chloroform methylene chloride tetrachloroethene and triehloroethene were identified as contaminants of

concern (COC) for potential vapor intrusion from subslab vapor associated with the Coyne Textile

Services Facility located in Huntington West Virginia (site) In this appendix the transport factors are

calculated to estimate the concentrations of COC in indoor air of the existing plant building located at the

site ~

Transport Factor for Indoor Air

The concentration of a constituent in indoor air (da) is proportional to the concentration of the constituent

in the subslab vapors immediately beneath the building foundation (ie subslab vapor concentration or

Csubsiab) The following equation is used to calculate da from Csubsiab

^ wja ~ ^subslab X I r

where

Cia = concentration of constituent in indoor air (mgm^) -

Csubsiab^ concentration of constituent in subslab vapors (mgm^) and

TF = transport factor from subslab vapors to indoor air

The transport factor (TF) is an infinite source attenuation coefficient andcan be calculated based on a

model developed by Johnson and Ettinger (1991) t he equation for calculating TF is as follows

(Deff X A B ) ( Q B X L T ) X expKQso i l X Lcrabk)(Dcrack X Acrack)]

exp[ (Qsoi l X Lcrack)(Dcrack X Acrack)] + (Deff X A B ) ( Q B X L T ) + (Deff X AB)(Qsoi l X L j ) X (exp [ (Qso i l X Lcrack)(Dcrack X Acrack)] - 1)

where

Deff = effective diffusion coefficient for vadose zone soil (cm^sec)

AB = area of enclosed space below grade (cm^)

QB = building ventilation rate (cm^sec)

LT = distance from contaminant source to building foundation (cm)

Qsoii = volumetric flow rate of vapors into the building (cm^sec)

Lcrack = foundatlon thickness (cm)

Dcrack = vapor diffusion coefficient through crack (cm^sec) and

Acrack = area of cracks through which vapors can pass (cm^)

AR100305

To solve this equation the USEPAs SG-ADV spreadsheet Version 31 most recently updated in

February 2004 was implemented A combination of site-specific factors and default values from the

Users Guide for Evaluating Subsurface Vapor Intrusion Into Buildings (USEPA 2004) were used as input

values in the model All input values are defined below and presented in Tables B-1-A through B-6-A

bull The initial subslab vapor concentration (Csubsiab) is the maximum detected concentration(in units

of ugm ) of samples VP-01 VP-02 and VP-03 that was presented in Table 3 of the report

bull The depth below grade to the bottom of the enclosed space floor (Lp) is set to 15 cm the default

value provided by USEPA (2004) for a slab-on-grade structure

bull The vapor sampling depth below grade (Lg) is a site-specific value The vapor samples were

collected from immediately beneath the building floor therefore Lj has been set to 15 cm

bull The average soilgroundwater temperature (Ts) is set to 125degC the average value for West

Virginia as estimated frorri Figure 8 of the vapor intrusion users guide (USEPA 2004)

bull The soil type used to estimate vapor permeability is assumed to be sandy loam (SL) The

associated soil properties for a sandy loam soil type are as follows the soil dry bulk density (Pb) is

162 gcm the total porosity (n) is 0387 (cm^-aircm^) and the water-filled porosity (nw) is 0103

(cm -HzOcm )

bull The floor thickness (Lcrack) is set to the USEPA (2004) default value of 10 cm

bull The soil-building pressure differential (AP) is set to the USEPA (2004) default value of 40 gcm-s^

bull The building dimensions are siterspecific based on the existing plant building located at the site

The existing structure is approximately 84000 square feet (Dolphin 2000) therefore the

dimensions are set to 8839 cm (290 feet) length by 8839 cm (290 feet) The USEPA (2004)

default value of 244 cm vyas used for the height

bull Thefloor-wall seam crack width (w) is set to the USEPA (2004)-default value of 01 cm

bull The indoor air exchange rate (ER) is set to 083hour This is the value provided by ASTM (2002)

for commercial and industrial buildings

AR100306

Tables B-1-B through B-6-B present the constituent-specific properties for COC that were used in the TF

calculations Tables B-1-C through B-6-C present the intermediate calculations used to determine the

indoor air attenuation coefficients (ie the transport factors) The shaded boxes in Tables B-1-C through

B-6-C also present the resulting TF values that are applied to the concentrations of COC in subslab

vapor and the estimated indoor air concentrations

References

American Society for Testing and Materials (ASTM 2002) Standard Guide for Risk-Based Corrective Action Applied at Petroleum Release Sites ASTM E-1739-95 (Reapproved 2002)

Johnson PC and RA Ettinger (1991) Heuristic model for predicting the intrusion r-ate of contaminant vapors into buildings Environ Sci Technolpgy 25 1445-1452

Dolphin Environmental LLC (Dolphin 2000) Site Characterization Report Mach 14 2000

United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004

AR100307

APPENDIX B-1-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV Nersion31 0204

Reset to Defaults

ENTER -

Chemical CAS No

(numbers only

no dasties)

95636

ENTER Soil gas

cone

Cg (ngm)

Soil Gas Concentration Data ENTER

Soil gas

OR cone

bull - c bull (PPmv)

197E+02

Chemical

124-Trimethylbenzene

MORE ENTER Depth

below grade to bottom

of enclosed space floor

U bull (cm)

ENTER

Soil gas sampling

depth below grade

U (cm) bull

ENTER

Average soil

temperature Ts

CO

1 15 1 1 5 bull125

ENTER ENTER ENTER Totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hft ha he

(cm) (cm) (cm)

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estirnate OR permeability | soil vapor

permeability) k v bull

(cm)

SL 1 1

MORE ENTER

stratum A SCS

soil type

Lookup Soil Parameters

ENTER stratum A soil dry

bulk density P

(gcm)

ENTER Stratum A soil total porosity

(unitless)

ENTER bull stratum A soil water-filled

porosity

(cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

nlaquo

(unitless)

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gchi-s^)

ENTER Enclosed

space floor

length bull LB

(cm)

ENTER Enclosed

space floor

width WB

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

bull Floor-wall seam crack

width w

(cm)

bullENTER

Indoor air exchange

rate ER

(1h) bull

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bidg OR

Leave blank to caicuij

(Lm)

Appx B-1 124-TMBxls 1 of 3 982009

AR100308

APPENDIX B-1-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of ^ bull law constant law constant vaporization at Normal

Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temperature boiling point point temperature weight

D bull Dbdquo H T R bull AHbdquo TB Tc IVIW

Unit risk Reference

factor cone URF RfC

(cms) (cmls) (atm-mmol) CO (calmol) (degK) (degK) (gmol) bull (ugm)- (mgm)

1 606E-02 1 792E-06 1 bull 614E-C3 1 25 1 9369 1 44230 | 64917 1 12020 1 OOE+00 1 60E-03 1

Appx B-1 124-TMBxls 2 of 3 982009

AR100309

APPENDIX B-1-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

(sec)

Source-building

separation

LT bull

(cm) bull

Stratum A soil

air-filled porosity

Q A

Stratum B soil

air-filled porosity

(cmcm) (cmcm)

Stratum C soil air-filled porosity

(cmcm)

Stratum A effective total fluid

saturation

Se

(cmcm)

Stratum A soil

bullintrinsic permeability

^ (cm)

stratum A Stratum A Floor- soil soli wall BIdg

relative air effective vapor seam Soil bull ventilation permeability permeability perimeter gas rate-

kfg ky Xgrack c o n e - QbuHdinpound

(cm) - (cm) (cm) (ngm) (cms)

946E+08 1 0284 0284 0284 0184 596E-09 0901 537E-09 35357 I 197E+02 | 439E+06 |

Area of enclosed

space below grade

As (cm)

Crack-to-total area ratio

1 bull

(unitless)

Crack depth

below grade

Zcfack

(cm)

Enthalpy of vaporization at

ave soil temperature

AHvjs

(calmol) bull

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law constant at

ave soil bull temperature

bull HTS

(unitless)

Vapor bull viscosity at

ave soil temperature

HTS

(gcm-s)

Stratum A

effective diffusion

coefficient

D (cms)

Stratum-B

effective diffusion coefficient

DB (cms)

Stratum C effective diffusion

coefficient

D-c (cms)

Total - overall effective diffusion

coefficient

D ^ (cms)

Diffusion path

length

L-

(cm)

I 787E+07 I 449E-05 | 15 | 11661 260E-03 111E-01 176E-04 I 612E-03 j OOOE+00 | OOOE+00 | 612E-03 j

bull Convection path

length

Lp

(cm)

Source vapor cone

^source

(ngm)

Crack radius

Tcfack

(cm)

Average vapor

flow rate into bIdg

Qsoii

(cms)

Crack effective diffusion

coefficient pcrack

(cms)

Area of CTack

Acack

(cm)

Exponent of equivalent foundation

Peclet number

exp(Pe)

(unitless)

bull bull - bull bull bull bull

1 15 1 197E+02 1 010 1 474E+01 612E-03 bull 354E-t-03 1 336E+09

Infinite source Indoor

~ attenuation coefficient

a

(unitless)

108E-05

Infinite source

btJbldgjJSv-L ^Ppncji3i-

virhpbiiilding bullbull ^lHltti^m)ilg

213E-03

Unit risk

factor

URF

(ngm)-

Reference cone

RfC (mgm)

NA 60E-03 1

I END

Appx B-1 124-TMBxls 3 of 3 982009

AR100310

APPENDIX B-2-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV Nersion31 020^

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

156592

Soil Gas Concentration Data ENTER

Soil gas

cone OR c

(ngm) bull

ENTER Soil bull-gas

cone

c (ppmv)

603E+03 1

Chemical

cis-12-Dichloroethylene

MORE ENTER Depth

below grade to bottom

of enclosed space floor

LF

(cm)

ENTER

Soil gas sampling

depth below grade

U (cm)

ENTER

Average soil

temperature bull Ts

(degC)

1 15 1 bull 15 125

ENTER ENTER ENTER Totalsmust add ijp tb value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hA hB he

bull (cm) (cm) (cm)

15 1 1

ENTER Soil

straturh A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estimate OR permeability | soil vapor

permeability) kv

(cm)

SL 1 |

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

P (gcm)

ENTER Stratum A soil total porosity

bull n

(unitless)

ENTER Stratum A

soil water-filled porosity

(cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

ENTER Stratum B

soil water-filled porosity

ENTER Stratum C

SCS soil type

(unitless) (cmcm)

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure differential

AP

(gcm-s)

ENTER Enclosed bull

space floor

length

LB (cm)

ENTER Enclosed

space floor

width WB

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER

Average vapor flow rate into bIdg

OR Leave blank to calculi

Qsoil

(Lm)

Appx B-2 cis-12-DCExls 1 of 3 982009

AR100311

APPENDIX B-2-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Diffusivity in air

Da

(cms)

Diffusivity in water

Dw (cms)

Henrys law constant at reference temperature

H

(atm-mmoi)

Henrys law constant

reference temperature

bull T R

CC)

Enthalpy of vaporization at

the normal boiling point

AHbdquob

(calmol)

Normal boiling point

TB

(degK)

Critical temperature

Tc (degK)

Molecular weight

MW

(gmol)

Unit risk

factor URF

(ngm)

Reference cone

RfC (mgm)

1 736E-02 1 113E-05 1 407E-03 j 1 25 1 bull 7192 1 33365 1 54400 1 9694 1 OOE+00 j 35E-02 1

Appx B-2 cis-12-DCExls 2 of 3 982009

AR100312

APPENDIX B-2-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

stratum A Stratum B Stratum C Source- soil soil soil

Exposure building air-filled air-filled air-filled

duration separation porosity porosity porosity

T LT ea e^ bull e= (sec) (cm) (cmcm) (cmcm) (cmcm)

I 946E+08n^

Stratum A Stratum A Stratum A Stratum A Floor-effective soil soil soil wall total fluid intrinsic relative air effective vapor seam

saturation permeability permeability permeability perimeter

Ste kj krg ky Acrack

(cmcm) (cm) (cm) (cm) (cm)

Soil gas

cone (ngm)

I 0284 I 0284~ 0284 0184 I 596E-09 | 090T 537E-09 35357 603E+03

BIdg ventilation

rate

JbulldinE

(cms)

439E+06

Area of enclosed

space below grade

AB

(cm)

Crack-to-total

area ratio

n (unitless)

Crack depth below grade

Zltiack (cm)

Erithalpy of vaporization at

ave soil temperature

AHvTs (calmol)

Henryslaw constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law constant at

ave soil temperature

HTS

(unitless) bull

Vapor viscosity at

ave soil bull temperature

HTS

bull (gcm-s)

Stratum A

effective bull diffusion

coefficient

D^A-(cms)

Stratum B

effective bull diffusion

coefficient

D=B

(cms)

Stratum C

effective diffusion bull

coefficient

D=e (cms)

Total overall

effective diffusion

coefficient

DT

(cms)

Diffusion path

length

Ld

(cm)

I 787E+07 I bull449E-05 | 15 bull7709 230E-03 982E-02 176E-04 | 743E-03 | OOOE+00 | OOOE+00 | 743E-03 |

bull bull bull -

Convecfion path -bull

length

Lp (cm)

Source vapor cone

-source

(Mgm)

Crack radius

fcrack

(cm)

Average vapor

flow rate into bIdg

Qaoil bull

(cms)

Crack effective diffusion

coefficient pcack

(cms)

Area of crack

crack

(cm)-

Exponent of equivalent foundation

Peclet number

exp(Pef)

(unitless)

bull

1 15 -1 603E+03 1 010 1 474E+01 743E-03 354E+03 1 697E+07

Infinite source Indoor

attenuation coefficient

poundbullbullbull C t

pound(unitless)

bullsiilaquogt j ii08E-05

Infinite [ source

bIdg cone

Cbujidjng

(pgm)

651 E-02 iKrt

Unit risk

factor

URF

(ngm)-

Reference cone

RfC

(mgm)

NA 35E-02 1

I END I

Appx B-2 cis-12-DCExls 3o f3 982009

AR100313

APPENDIX B-3-A DATA ENTRY SHEET

Coyne Texti le Services - Hunt ington West Virginia

SG-ADV Version 31 0204

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

67663

Soil Gas Concentration Data ENTER ENTER

Soil Soil gas gas

cone OR cone c C

(^gm) (ppmv)

591 E+03

bull

Chemical

Chloroform

MORE ENTER Depth

below grade tb bottom

of enclosed space floor

bull LF

(cm)

ENTER

Soil gas sampling depth

below grade

(cm)

ENTER

Average soil

temperature-Ts

CO bull

1 15 1 15 1 125

ENTER ENTER ENTER Totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

IIA hs he (cm) (cm) (cm)

1 5 bull 1 1

ENTER ENTER Soil - bull

stratum A User-defined SCS stratum A

soil type bull soil vapor (used to estimate OR permeability

soil vapor k

bull permeability) (cm) 1

SL 1 1 bull

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A soil dry

bulk density

Pb (gcm)

ENTER Stratum A soil total porosity

nV (unitless)

ENTER Stratum A

-soilwater-filled bullporosity

Sraquo (cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

(unitless)

ENTER Stratum B

soil water-filled porosity

bull ebdquo=

(cmcm) bull

ENTER Straturri C

SCS bull soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

- c rack

(cm)

ENTER

Soil-bldg pressure

differential AP^

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor

width bull W B

(cm)

ENTER

Enclosed space

height HB

(cm)

ENTER

bull Floor-wall^ seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bidg OR

Leave blank to calculi

Qsoil bull

(Lm)

I -I

Appx B-3 Chloroformxls 1 of 3 982009

AR100314

APPENDIX B-3-B CHEMICALPROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Diffusivity in air

D (cms)

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffijsivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature

Dbdquo H TR A H bdquo TB Tc

(cm s) (atm-m mol) ro (calmol) (degK) (degK)

Molecular weight

MW

(gmol)

Unit risk

factor URF

(ngm)-

Reference cone

RfC

(mgm)

104E-01 100E-05 I 366E-03 25 6988 33432 53640 11938 I 23E-05 | OOE+00

Appx B-3 Chloroformxls 2 of 3 982009

AR100315

APPENDIX B-3-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure

duration

(sec)

Source-

building

separation

LT

(cm)

Stratum A

soil

air-filled

porosity

Sa

( cm cm )

Stratum B

soil

air-filled

porosity

( cm cm )

Stratum C

soil

air-filled

porosity

( c m c m )

Stratum A

effective

total fluid

saturation

( c m c m )

Stratum A

soil

intrinsic

penmeability

k

(cm )

Stratum A

- soil

relative air

permeabil i ty

(cm )

Stratum A

soil

effective vapor

permeability

kv

(cm )

Floor-

wall

seam

perimeter

gtcrack

(cm)

Soil gas

cone

(ngm)

BIdg

venfilation

rate

^buildlriE

(cms)

I 9 4 6 E + 0 8 ~ T I 0284 T 596E-09 I 0-901 I 537E-09 | 35357 | 591 E+03 j 439E+06 | 1 0 284 0284 0184

Area of

enclosed

space

below

grade

A B

( c m )

Crack-

to-total

area

ratio

n

(unitless)

Crack

depth

bull below

grade

^crack

(cm)

Enthalpy of

vaporization at

ave soil

temperature

AHTs bull

(calmol)

Henry s law

constant at

ave soil

temperature

HTS

(a tm-m mol j

Henrys law

constant at

ave soil

bull temperature

HTS

(unitless) bull

Vapor

viscosity at

ave soil-

temperature

^HTS

(gcm-s)

Stratum

A

effective

diffusion

coefficient

(cm s)

Stratum

B

effective

difftjsion

coefficient

D B

(cms) bull

S t ra tum

C

effective

diffusion

coefficient

Dc

(cm s)

Total

overall

effective

bull diffusion

coefficient

D T

(cm s)

Diffi jsion

path

length

Ld

(cm)

I 787E+07 I 449E-05 j - bull 15 7528 210E-03 896E-02 176E-04 I 105E-02 | OOOE+00 | OOOE+00 | 105E-02

Convection

path length

Lp

(cm)

Source

vapor

cone -

^source

- (ngm)

Crack

radius

Tcrack

(cm)

Average

vapor

flow rate

into bidg

Qsoil

(cms)

Crack

effective

diffusion

coefficient Qcrack

bull (cms)

Area of crack

Acrack

(cm)

Exponent of

equivalent

foundation

Peclet number

exp(Pe)

(unitless)

V bull bull

1 15 1 591 E+03 1 010 1 474E+01 105E-02 354E+03 1 355E+05

Infinite

source

indoor

attenuation

coefficient

d

(unitless)

bull 108E-05

Infinite

source

bIdg

cone

^ b u i l d i n g

i (^gm)

bull bull

i 638E-02 -

Unit

risk bull factor

URF

(ngmY

Reference

cone

RfC

(mgm)

~ 23E-05 NA 1

I END

Appx B-3 Chloroform xls 3 of 3 982009

AR100316

APPENDIX B-4-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ersion 31-020^

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

nodashes)

bull 75092

ENTER Soil gas

cone

c (ngm)

Soil Gas Concentration Data ENTER

Soil gas bull

OR cone

bull C

(ppmv)

152E+03

bull bull

Chemical

Methylene chloride

MORE

MORE 4gt

ENTER Depth

below grade to bottom

of enclosed space floor

LF -

(cm)

ENTER

Soil gas sampling depth

below grade

bull U

(cm)

ENTER

Average soil

temperature

Ts bull CC)

bull bull bull bull

1 15 1 15 125

ENTER Totals

Thickness of soil

stratum A h

(cm)

ENTER ENTER must add up to value of Ls (cell F24

Thickness Thickness of soil of soil

stratum B stratum C (Enter value or 0) (Enter value or 0)

he he bull

(cm) bull (cm) -

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(usedto estimate OR perrrieability | soil vapor

permeability)

k bull

(cm)

SL 1 bull 1

ENTER Stratum A

SCS soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

Pb (gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Stratum A

soil water-filled porosity

9w (cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

Pb^

(gcm)

ENTER Stratum B soil total porosity

n^

(unitless)

ENTER Stratum B

soil water-filled porosity

(crhcm)

ENTER Stratum C

SCS soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE 4gt

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

bull Soil-bldg pressure

differential AP^

(gcm-s)

ENTER Enclosed

space floor

length LB

(cm)

ENTER Enclosed

space floor

width bull W B

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width

w

(cm)

ENTER

Indoor air exchange

rate

ER (1h)

ENTER Average vapor

flow rate into bidg OR

Leave blank to calculc

Qsoil

(Lm)

10 40 8839 8839 244 01 083

Appx B-4 MCxIs 1 of 3 982009

AR100317

Diffijsivity in air

D

APPENDIX B-4-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffusivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature

Pw H TR AHt TB TC

Molecular weight

MW

Unit risk

factor URF

Reference cone

RfC

(cms) (cms) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) bull (ngm)- (mgm)

bull bull

1 101E-01 1 117E-05 1 218E-03 1 25 | 6706 1 31300 1 51000 1 8493 1 47E-07 1 30E+00 1

Appx B-4 MCxIs 2 of 3 982009

AR100318

APPENDIX B-4-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

T

(sec)

Source- -building

separation

LT

(cm)

Stratum A soil

air-filled porosity

e a bull

(cmcm)

Stratum B soil

bullair-filled porosity bull

ea^ (cmcm)

Stratum C soil

air-filled porosity

ea= (cmcmj

Stratum A effective total fluid

saturation

Sc bull

(cmcm)

Stratum A soil

intrinsic pemneability

ki (cm)

Stratum A soil

relative air permeability

^ ^ g

(cm)

stratumA bull soil effective vapor permeability

K (cm)

Floor-wall

seam perimeter

Xcrack

(cm)

Soil gas

cone (ngm)

BIdg ventilation

rate

Qbuildinc

(cms)

1 946E+08

Area of -enclosed

space below

bull grade

AB

(cm)

1

Crack-to-total

area rafio

Tl

(unitless)

0284 1

Crack depth below grade

Zcrack

(cm)

0284 1

bull Enthalpy of vaporization at

ave soil temperature

AHTs (calmol)

0284

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

0184

Henrys law constant at ave soil

temperature

HTS

bull (unitless)

1 596E-09

Vapor viscosity at

ave soil temperature

Mrs (gcm-s)

0901

Stratum A

effective diffusion

coefficient

D (cms)

537E-09

Stratum B

effective diffusion

coefficient

D-B (cms)

35357 1

Stratum C -

effective diffusion

coefficient

D-c ^ (cms)

152E+03

Total bull overall

bull effective diffusion

coefficient

D ^

(cms)

440E+06 1

Difftjsion path

length

Ld (cm)

1 787E+07

Convection path

length

Lp (cm)

4 49E-05

Source vapor cone

Csource

(ngm)

15 1

Crack radius

Tcrack

(cm)

7007 bull 1

Average vapor

flow rate intobldg

Qsoil

(cms)

130E-03

Crack effective diffusion

coefficient pcrack

(cms)-

555E-02

bull ^

Area of crack

Acrack

(cm) bull

1 176E-04

Exponent of equivalent foundation

Peclet number

exp(Pe)

(unitless) bull

bull bull

1 15

1 END

152E+03 010 1 474E+01 1 102E-02 354E+03 1 519E+05

102E-02

Infinite source

indoor ^attenuation coefficient

bull a

(unitless)

aiii08E-05

0 OOE+00

bull

Infinite bull source

bIdg ^ cone

^bu i l d i ng

(MQm)

164E-02

OOOE+00 1

Unit risk

factor

URF

(ngm)-

47E-07 1

102E-02 j

Reference cone

RfC

(mgm)

30E+00 j

1 1

Appx B-4 MCxIs 3 of 3 982009

AR100319

APPENDIX B-5-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ^erslon 31 0204

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

127184

Soil Gas Concentration Data ENTER ^ ENTER

Soil -Soi l bull gas gas

cone OR cone Cg C bull

(tgm) (ppmv)

149E+05 1

Chemical

bull Tetrachlbroethylene

MORE 4

ENTER Depth

below grade to bottom

ofenclosecJ space floor

LF

(cm)

ENTER

Soil gas bull sampling

depth below grade

u bull (cm)

ENTER

Average bullsoil

temperature - Ts

ro 1 1 5 1 15 1 125 bull

ENTER ENTER ENTER totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hft bull he bull he

(cm) (cm) (cm)

bull 1 5 1 - 1

ENTER ENTER Soil

stratum A User^defined bull SCS bull stratum A soil type soil vapor

(used to estimate OR perrrieability soil vapor K bull

permeability) (cm) 1

SL 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

Pb

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Sitratum A

soil water-filled bull porosity

(cmcm)

ENTER Stratum B

SCS soiltype

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

Pb^

(gcm)

ENTER Stratum B soil total porosity

Ajnitless^

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS soil type

LookupSoil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

VS

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor width

W B

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width

w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

ENTER Average vapor

flow rate into bidg OR

Leave blank to calcul

bull Qsoil

(Lm)

10 40 8839 8839 244 01 083

Appx B-5 PCExIS 1 of 3 982009

AR100320

APPENDIX B-5-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal Unit

Diffusivity Diffusivity at reference reference the riormal boiling Critical Molecular risk Reference in air in water temperature temperature boiling point point teriiperature weight factor cone

Da Dbdquo H TR AHb TB Tc MW URF RfC

(cms) (cnis) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) (^gm)- (mgm)

1 720E-02 1 820E-06 1 184E-02 1 25 1 8288 1 39440 1 62020 1 16583 1 59E-06 1 60E-01 1

J

AppxB-5PCExls 2 of 3 - 982009

AR100321

APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

T

(sec)

Source-building

separation

LT

bull (cm)

Stratum A soil

air-filled porosity

Oa (cmcm)

Stratum B - soil air-filled porosity

ea (cmcm)

Stratum C soil

air-filled porosity

ea= - (cmcm)

Stratum A effective total fluid

saturation

sbdquo (cmcm)

Stratum A soil

intrinsic permeability

ki (cm)

Stratum A soil

relative air permeability

- ^ g

(cm)

Stratum A soil

effective vapor permeability

kv (cm)

Floor-wall

seam perimeter

^crack

(cm)

Soil gas

cone

(ngm)

BIdg venfilation

rate

Qbuildins

bull (cms)

bull bull

1 946E+08

Area of enclosed

space below grade

AB

(cm)

1

bullCrack-to-total

area ratio

1 (unitless)

0284 1

Crack bull depth below grade

Zcrack

(cm) -

0284 1

Enthalpy of vaporization at bull

ave soil temperature

bull A H V TS

(calmol)

0284

Henrys law constant at

ave soil temperature

HTS (atm-mmol)

0184

-Henrys law constant at

ave soil temperature

HTS

(unitless)

1 596E-09

Vapor viscosity at

ave soil temperature

HTS

(gcm-s)

0901

Stratum A

effective diffusion

coefficient bull D = bull

(cms)

537E-09

Stratum B

effective diffusion

coefficient

D--B (cms)

35357 1

Stratum C

effective diffusion bull

coefficient

D-c (crris)

149E+05

Total overall

effective bulldiffusion coefficient

DT

(cms)

440E+06 1

Difftjsion path

length

U (cm)

1 787E+07

Convection path

length

bull Lp

(cm)

4 49E-05

Source vapor cone

^source

(ngm)

15 1

Crack radius

Tcrack

(cm)

9528 1

Average vapor

flow rate intobldg

Qsoil (cms)

908E-03

Crack effective diffusion

coefficient pcrack

bull ( c m s ) bull

387E-01

Area of crack

Abdquoack (cm)

1 176E-04

Exponent of equivalent foundafion

Peclet number

exp(Pe)

(unitless)

bull

1 15-

1 END

149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08

727E-03

Infinite source indoor

attenuation coefficient

a

(unitless)

108E-05

OOOE+00

Infinite source

bIdg cone

Cburldtng

(Mgm)

161 E+00

OOOE+00 1

Unit risk

factor

URF

(ugm)-

59E-06 1

727E-03

Reference cone

RfC (mgm)

60E-01

1 1

Appx B-5 PCExls 3 of 3 982009

AR100322

APPENDIX B-6-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ersion31 0204

Reset to Defaults

t

Soil Gas Concentration Data ENTER

Chemical CAS No

(numbers only

no dashes)

79016

ENTER ENTER Soil Soil gas gas

cone OR cone C C -

bull (ngm) (ppmv)

782E+03

Chemical

Trichloroethylene

MORE ENTER Depth

below grade to bottom-

of enclosed space floor

LF

(cm)

ENTER

Soil gas sarnpling

depth below grade

U (cm)

ENTER

Average soil

temperature Ts

(degC)

1 15 1 15 t 125

ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e

(cm) (cm) (cm)

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estimate OR permeability soil vapor

permeability)

k (cm)

bull S L 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil bull-Parameters

ENTER Stratum A

soil dry bulk density

P b -

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Stratum A bull

soilwaterrfilled porosity

(cmcm) bull

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

bull P ^ (gcm)

ENTER Stratum B soil total

porosity

nlaquo

(unitless) -

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS bull soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor

width W B

(cm)

ENTER

Enclosed space height

H B bull

( c m ) bull

ENTER

Floor-wall seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bIdg OR

Leave blank to calculc

Qsoil

(Lm) -

Appx B-6 TCExIs 1 of 3 982009

A

AR100323

APPENDIX B-6-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight

Da Dbdquo H TR AH^b TB TC MW

Unit risk Reference

factor cone URF RfC

(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)

1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1

Appx B-6 TCExIs 2 of 3 982009

AR100324

APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

(sec)

Source-building

separation LT

(cm)

Stratum A soil

air-filled porosity

bull ea (cmcm)

Stratum B Soil

air-fllled porosity

e^ bull (cmcm)

Stratum C soil

air-filled porosity

(cmcm)

StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air

saturation permeability permeability

S|e k krg (cmcm) (cm) (cm)

Stratum A Floor-soil wall BIdg

effective vapor seam Soil ventilafion permeability perimeter gas rate

k^ bull Xack c o n e Qbuildins

(cm) (cm) (ngm) (cms)

946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |

Area of enclosed

space below grade

AB

(cm)

Ciack- to-total

area ratio

1 (unitless)

Crack depth below grade

Zcrack

(cm)

Enthalpy of vaporization at

ave soil temperature

A H J S

(calmol)

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law bull constant at

ave soil temperature

HTS

(unitless)

Vapor viscosity at

ave soil temperature

|JTS

(gcm^s)

Stratum A

effective diffusion

coefficient

(cms)

Stratum B

effective -diffusion

coefficient

D=B (cms)

Stratum ^ C effective diffusion

coefficient

D=c (cms)

Total overall

effective diffusion

coefficient

DT

(cms)

I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03

Diffusion path

length

Li (cm) bull

Convection bull path

length

Lp

(cm)

Source vapor cone bull

^source

(ngm)

Crack radius

rcrack

(cm)

Average vapor

- flow rate intobldg

Qsoil

(cms)

Crack effective diffusion

bull coefficient Qcrack

(cms)

Area of crack

^crack

(cm)

Exponent of equivalent foundation

Peclet bull number

exp(Pe)

(unitless)

bull bull

1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07

Infinite source Indoor

attenuation coefficient

a

(unitless)

108E-05

Infinite source

bIdg concgt

^building

(ngm)

844E-02

Unit risk

factor

URF

(ngm)-

Reference cone

RfC

(mgm)

1 1E-04 1 40E-02 1

END

Appx B-6 TCExIs 3 of 3 982009

AR100325

Office of Waste Management 1356 Hansford Street

Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256

West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director

ORDER

ISSUED UNDER THE

HAZARDOUS WASTE MANAGEMENT ACT

CHAPTER 22 ARTICLE 18

OF THE WEST VIRGINIA CODE^ AS AMENDED

y Order Number HW-011-80

To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704

ATTEMTION MREDARMON

Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull

AR100326

ViWJ011-laquo9 PageNunil)er2

BASIS FOR ORDER

As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following

A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^

B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator

C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities

0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94

^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement

P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following

1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater

2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was

^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment

CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable

CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order

AR100327

H W - 0 1 1 - 9 9 Page Number 3

REQUIREMENTS OF ORDER

Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows

1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^

2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore

remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling

GENERAL PROVaiONS

1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order

2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order

3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order

Effective Date

Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief

Wt T 1 V Oflice of Waste Management

AR100328

^ ^ S I S

^wmmmmamn

AR100329

Page 23: SDMS DocID 2121999 · International Enterprises Corp. building (Coyne Building), which is located at 1111 Vernon Street, Westmoreland District, Wayne County, West Virginia. The following

TABLE 6

NONCANCER HAZARD INDEX AND POTENTIAL CANCER RISK FOR AN INDOOR WORKER

Coyne Textile Services Facility - Huntington West Virginia

bull

Constituent

Volatile Organics

124-Trinnethylbehzene

12-Dichlorpethene (cis)

Chloroform

Methylene chloride

Tetrachloroethene Triehloroethene

EPC in Indoor Air

(mgm)

213E-06

651 E-05

- 638E-05

164E-05

161 E-03

844E-05

Intake (ADD)

(mgkg-d)

416E-07

127E-05

125E-05

321 E-06

315E-04 l65E-05

RfDi

(mgkg-d)

200E-03

1OOE-02

140E-02

286E-01

771 E-02 1 OOE-02

Hazard

Quotient

208E-04

127E-03

892E-04

112E-05

408E-03 165E-03

Intake (LADD)

(mgkg-d)

) 149E-07

455E-06 bull 446E-06

115E-06

112E-04 590E-06

CSFi

(mgkg-d)

NA

NA

805E-02

165E-03

200E-02

400E-01

Potential

Cancer Risk

NA

NA

359E-07

189E-09

225E-06 236E-06

Total Hazard Index

00081 Total

Cancer Risk 497E-06

Total Blood HI = Total Liver HI =

Total Central Nervous System HI = Total Kidney HI =

Total Fetal HI =

bull 00015 00066 00057 00017 00017

Notes NA = Toxicity values are not available for this endpoint or exposure pathway

Coyne VI Memo Tables_09-08-09xls 982009

AR100300

APPENDIX A

SUBSLAB VAPOR ANALYTICAL DATA

AR100301

Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility Huntington West Virginia

Sample

Consti tuent

Volatile Organics (ugm) 111-Trlchloroethane 1122-Tetrachloroethane 112-Trichloro-122-trifluoroethane 112-Trichloroethane 11-Dichioroethane 11-Dichloroethene 124-Trichloroberi2ene 124-Trimethylbenzene 12-Dibromoethane 12-Dichloroben2ene 12-Dichloroethane 12-Dichloroethene-(cis) -12-Dichloroethene (trans) 12-Dichloropropane 12-Dichlorotetrafluoroethane 135-Trimethylbenzene 13-Butadiene 13-Dichlorobenzene 13-Hexachlorobutadiene 14-Dichlorobenzene 224-trimethVlpentane 2-Chlorotoluene 4-Ethyltoluene Acetone Allyl Chloride Benzene Bromodichloromethane Bromoform Bromomethane Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 13-Dichloropropene (cis) Cyclohexane Dibromochloromethane

Identif ication Sample Date

CAS No

71-55-6 79-34-5 76-13-1 79-00-5 75-34-3 75-35-4 120-82-1 95-63-6 106-93-4 95-50-1 107-06-2 156-59-2 156-60-5 78-87-5 76-14-2 108-67-8 106-99^0 541-73-1 87-68-3 106-46-7 540-84r1 95-49-8

622-96-8 67-64-1 107-05-1 71-43-2 75-27-4 75-252 74-83-9 75-15-0 56-23-5 108-90-7 75-00-3 67-66-3 74-87-3

10061-01-5 110-82-7 124-48-1

lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt

lt lt lt lt lt lt lt lt lt lt lt lt

lt

VP-01 8132009

22 28 31 22 16 16 30 20 31 24 16 16 16 19 28 20 89 24 43 24

1 9 21 20 796 13 13 27 41 16 13 25 18 11 20 83 18 52 34

lt lt lt lt lt lt lt lt lt lt lt

lt lt lt lt lt lt lt lt lt lt lt

lt lt lt lt lt lt lt lt lt

lt lt lt lt

VP-02 8132009

218 2 7 5 307 218 162 159 297

bull 197 307 240 162 369 159 185 280 197 89

240 427 240 187 207 197

1880 125 128 268 414 155 125 252 184 106

5910 83 182 138 341

lt lt lt lt lt lt lt

lt lt lt

lt lt lt lt lt lt lt bull

lt lt lt lt

lt lt lt lt lt lt lt lt lt lt lt lt lt lt

VP-03 8132009

218 275 307 218

bull 162 159 297 197 307 240 162

6030 159 185 280 197 89

240 427 240 187 207 197

1750 125 128 268 414 155 125 252 184 106 195 83 182 138 341

Appx A SG Dataxis Page 1 of 2 982009

AR100302

Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility bull Huntington West Virginia

Consti tuent

Volatile Organics (ugm^) Dichlorodifluoromethane Ethylbenzene Methyl ethyl ketone Methyl Isobutyl ketone Methyl tert-butyl ether Methylene chloride n-Heptane jn-Hexane Styrene Tert-butyl alcohol Tetrachloroethene iToluene 13-Dichloropropene (trans) Triehloroethene Trichlorofluoromethane Vinyl bromide Vinyl chloride Xylene (o) Xylenes (mampp)

Sample Identif ication Sample Date

CAS No

75-71-8 100-41-4 78-93-3 108-10-1

1634-04-4 75-09-2

142-82-5 bull 110-54-3

100-42-5 75-65-0 127-18-4 108-88-3

10061-02-6 79-01-6 75-69-4 593-60-2 75-01-4 95-47-6

179601-23-1

lt lt

lt lt lt lt

lt lt

lt

lt lt lt lt lt

VP01 8132009

20 17 23 16 14 14 16

173 17 12 bull

11200 18 18 91 23 18 10 17 17

lt lt lt lt lt

lt

lt lt

lt lt

lt lt lt lt lt

VP-02 8132009

198 174 118 164 144

1520 164 -183 170 121

149000 151 182

2360 225 175 102 174 174

VP-03 8132009

lt 198 lt 174 lt 118 lt 164 lt 144

1160 lt 164

144 lt 170 ltbull 121

90500 lt 151 lt 182

7820 lt 225 lt 175 lt 102

208 387

Appx A SG Dataxis Page 2 of 2 982009

AR100303

APPENDIX B

CALCULATION OF TRANSPORT FACTORS USED TO ESTIMATE INDOOR AIR CONCENTRATIONS

AR100304

APPENDIX B

Calculation of Transport Factors Used to Estimate Indoor Air Concentrations

This appendix presents the methodology for calculating transport factors that are used to convert subslab

vapor concentrations to concentrations in indoor air 124-Trimethylbenzene 12-dichloroethene (cis)

chloroform methylene chloride tetrachloroethene and triehloroethene were identified as contaminants of

concern (COC) for potential vapor intrusion from subslab vapor associated with the Coyne Textile

Services Facility located in Huntington West Virginia (site) In this appendix the transport factors are

calculated to estimate the concentrations of COC in indoor air of the existing plant building located at the

site ~

Transport Factor for Indoor Air

The concentration of a constituent in indoor air (da) is proportional to the concentration of the constituent

in the subslab vapors immediately beneath the building foundation (ie subslab vapor concentration or

Csubsiab) The following equation is used to calculate da from Csubsiab

^ wja ~ ^subslab X I r

where

Cia = concentration of constituent in indoor air (mgm^) -

Csubsiab^ concentration of constituent in subslab vapors (mgm^) and

TF = transport factor from subslab vapors to indoor air

The transport factor (TF) is an infinite source attenuation coefficient andcan be calculated based on a

model developed by Johnson and Ettinger (1991) t he equation for calculating TF is as follows

(Deff X A B ) ( Q B X L T ) X expKQso i l X Lcrabk)(Dcrack X Acrack)]

exp[ (Qsoi l X Lcrack)(Dcrack X Acrack)] + (Deff X A B ) ( Q B X L T ) + (Deff X AB)(Qsoi l X L j ) X (exp [ (Qso i l X Lcrack)(Dcrack X Acrack)] - 1)

where

Deff = effective diffusion coefficient for vadose zone soil (cm^sec)

AB = area of enclosed space below grade (cm^)

QB = building ventilation rate (cm^sec)

LT = distance from contaminant source to building foundation (cm)

Qsoii = volumetric flow rate of vapors into the building (cm^sec)

Lcrack = foundatlon thickness (cm)

Dcrack = vapor diffusion coefficient through crack (cm^sec) and

Acrack = area of cracks through which vapors can pass (cm^)

AR100305

To solve this equation the USEPAs SG-ADV spreadsheet Version 31 most recently updated in

February 2004 was implemented A combination of site-specific factors and default values from the

Users Guide for Evaluating Subsurface Vapor Intrusion Into Buildings (USEPA 2004) were used as input

values in the model All input values are defined below and presented in Tables B-1-A through B-6-A

bull The initial subslab vapor concentration (Csubsiab) is the maximum detected concentration(in units

of ugm ) of samples VP-01 VP-02 and VP-03 that was presented in Table 3 of the report

bull The depth below grade to the bottom of the enclosed space floor (Lp) is set to 15 cm the default

value provided by USEPA (2004) for a slab-on-grade structure

bull The vapor sampling depth below grade (Lg) is a site-specific value The vapor samples were

collected from immediately beneath the building floor therefore Lj has been set to 15 cm

bull The average soilgroundwater temperature (Ts) is set to 125degC the average value for West

Virginia as estimated frorri Figure 8 of the vapor intrusion users guide (USEPA 2004)

bull The soil type used to estimate vapor permeability is assumed to be sandy loam (SL) The

associated soil properties for a sandy loam soil type are as follows the soil dry bulk density (Pb) is

162 gcm the total porosity (n) is 0387 (cm^-aircm^) and the water-filled porosity (nw) is 0103

(cm -HzOcm )

bull The floor thickness (Lcrack) is set to the USEPA (2004) default value of 10 cm

bull The soil-building pressure differential (AP) is set to the USEPA (2004) default value of 40 gcm-s^

bull The building dimensions are siterspecific based on the existing plant building located at the site

The existing structure is approximately 84000 square feet (Dolphin 2000) therefore the

dimensions are set to 8839 cm (290 feet) length by 8839 cm (290 feet) The USEPA (2004)

default value of 244 cm vyas used for the height

bull Thefloor-wall seam crack width (w) is set to the USEPA (2004)-default value of 01 cm

bull The indoor air exchange rate (ER) is set to 083hour This is the value provided by ASTM (2002)

for commercial and industrial buildings

AR100306

Tables B-1-B through B-6-B present the constituent-specific properties for COC that were used in the TF

calculations Tables B-1-C through B-6-C present the intermediate calculations used to determine the

indoor air attenuation coefficients (ie the transport factors) The shaded boxes in Tables B-1-C through

B-6-C also present the resulting TF values that are applied to the concentrations of COC in subslab

vapor and the estimated indoor air concentrations

References

American Society for Testing and Materials (ASTM 2002) Standard Guide for Risk-Based Corrective Action Applied at Petroleum Release Sites ASTM E-1739-95 (Reapproved 2002)

Johnson PC and RA Ettinger (1991) Heuristic model for predicting the intrusion r-ate of contaminant vapors into buildings Environ Sci Technolpgy 25 1445-1452

Dolphin Environmental LLC (Dolphin 2000) Site Characterization Report Mach 14 2000

United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004

AR100307

APPENDIX B-1-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV Nersion31 0204

Reset to Defaults

ENTER -

Chemical CAS No

(numbers only

no dasties)

95636

ENTER Soil gas

cone

Cg (ngm)

Soil Gas Concentration Data ENTER

Soil gas

OR cone

bull - c bull (PPmv)

197E+02

Chemical

124-Trimethylbenzene

MORE ENTER Depth

below grade to bottom

of enclosed space floor

U bull (cm)

ENTER

Soil gas sampling

depth below grade

U (cm) bull

ENTER

Average soil

temperature Ts

CO

1 15 1 1 5 bull125

ENTER ENTER ENTER Totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hft ha he

(cm) (cm) (cm)

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estirnate OR permeability | soil vapor

permeability) k v bull

(cm)

SL 1 1

MORE ENTER

stratum A SCS

soil type

Lookup Soil Parameters

ENTER stratum A soil dry

bulk density P

(gcm)

ENTER Stratum A soil total porosity

(unitless)

ENTER bull stratum A soil water-filled

porosity

(cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

nlaquo

(unitless)

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gchi-s^)

ENTER Enclosed

space floor

length bull LB

(cm)

ENTER Enclosed

space floor

width WB

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

bull Floor-wall seam crack

width w

(cm)

bullENTER

Indoor air exchange

rate ER

(1h) bull

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bidg OR

Leave blank to caicuij

(Lm)

Appx B-1 124-TMBxls 1 of 3 982009

AR100308

APPENDIX B-1-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of ^ bull law constant law constant vaporization at Normal

Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temperature boiling point point temperature weight

D bull Dbdquo H T R bull AHbdquo TB Tc IVIW

Unit risk Reference

factor cone URF RfC

(cms) (cmls) (atm-mmol) CO (calmol) (degK) (degK) (gmol) bull (ugm)- (mgm)

1 606E-02 1 792E-06 1 bull 614E-C3 1 25 1 9369 1 44230 | 64917 1 12020 1 OOE+00 1 60E-03 1

Appx B-1 124-TMBxls 2 of 3 982009

AR100309

APPENDIX B-1-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

(sec)

Source-building

separation

LT bull

(cm) bull

Stratum A soil

air-filled porosity

Q A

Stratum B soil

air-filled porosity

(cmcm) (cmcm)

Stratum C soil air-filled porosity

(cmcm)

Stratum A effective total fluid

saturation

Se

(cmcm)

Stratum A soil

bullintrinsic permeability

^ (cm)

stratum A Stratum A Floor- soil soli wall BIdg

relative air effective vapor seam Soil bull ventilation permeability permeability perimeter gas rate-

kfg ky Xgrack c o n e - QbuHdinpound

(cm) - (cm) (cm) (ngm) (cms)

946E+08 1 0284 0284 0284 0184 596E-09 0901 537E-09 35357 I 197E+02 | 439E+06 |

Area of enclosed

space below grade

As (cm)

Crack-to-total area ratio

1 bull

(unitless)

Crack depth

below grade

Zcfack

(cm)

Enthalpy of vaporization at

ave soil temperature

AHvjs

(calmol) bull

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law constant at

ave soil bull temperature

bull HTS

(unitless)

Vapor bull viscosity at

ave soil temperature

HTS

(gcm-s)

Stratum A

effective diffusion

coefficient

D (cms)

Stratum-B

effective diffusion coefficient

DB (cms)

Stratum C effective diffusion

coefficient

D-c (cms)

Total - overall effective diffusion

coefficient

D ^ (cms)

Diffusion path

length

L-

(cm)

I 787E+07 I 449E-05 | 15 | 11661 260E-03 111E-01 176E-04 I 612E-03 j OOOE+00 | OOOE+00 | 612E-03 j

bull Convection path

length

Lp

(cm)

Source vapor cone

^source

(ngm)

Crack radius

Tcfack

(cm)

Average vapor

flow rate into bIdg

Qsoii

(cms)

Crack effective diffusion

coefficient pcrack

(cms)

Area of CTack

Acack

(cm)

Exponent of equivalent foundation

Peclet number

exp(Pe)

(unitless)

bull bull - bull bull bull bull

1 15 1 197E+02 1 010 1 474E+01 612E-03 bull 354E-t-03 1 336E+09

Infinite source Indoor

~ attenuation coefficient

a

(unitless)

108E-05

Infinite source

btJbldgjJSv-L ^Ppncji3i-

virhpbiiilding bullbull ^lHltti^m)ilg

213E-03

Unit risk

factor

URF

(ngm)-

Reference cone

RfC (mgm)

NA 60E-03 1

I END

Appx B-1 124-TMBxls 3 of 3 982009

AR100310

APPENDIX B-2-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV Nersion31 020^

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

156592

Soil Gas Concentration Data ENTER

Soil gas

cone OR c

(ngm) bull

ENTER Soil bull-gas

cone

c (ppmv)

603E+03 1

Chemical

cis-12-Dichloroethylene

MORE ENTER Depth

below grade to bottom

of enclosed space floor

LF

(cm)

ENTER

Soil gas sampling

depth below grade

U (cm)

ENTER

Average soil

temperature bull Ts

(degC)

1 15 1 bull 15 125

ENTER ENTER ENTER Totalsmust add ijp tb value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hA hB he

bull (cm) (cm) (cm)

15 1 1

ENTER Soil

straturh A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estimate OR permeability | soil vapor

permeability) kv

(cm)

SL 1 |

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

P (gcm)

ENTER Stratum A soil total porosity

bull n

(unitless)

ENTER Stratum A

soil water-filled porosity

(cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

ENTER Stratum B

soil water-filled porosity

ENTER Stratum C

SCS soil type

(unitless) (cmcm)

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure differential

AP

(gcm-s)

ENTER Enclosed bull

space floor

length

LB (cm)

ENTER Enclosed

space floor

width WB

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER

Average vapor flow rate into bIdg

OR Leave blank to calculi

Qsoil

(Lm)

Appx B-2 cis-12-DCExls 1 of 3 982009

AR100311

APPENDIX B-2-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Diffusivity in air

Da

(cms)

Diffusivity in water

Dw (cms)

Henrys law constant at reference temperature

H

(atm-mmoi)

Henrys law constant

reference temperature

bull T R

CC)

Enthalpy of vaporization at

the normal boiling point

AHbdquob

(calmol)

Normal boiling point

TB

(degK)

Critical temperature

Tc (degK)

Molecular weight

MW

(gmol)

Unit risk

factor URF

(ngm)

Reference cone

RfC (mgm)

1 736E-02 1 113E-05 1 407E-03 j 1 25 1 bull 7192 1 33365 1 54400 1 9694 1 OOE+00 j 35E-02 1

Appx B-2 cis-12-DCExls 2 of 3 982009

AR100312

APPENDIX B-2-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

stratum A Stratum B Stratum C Source- soil soil soil

Exposure building air-filled air-filled air-filled

duration separation porosity porosity porosity

T LT ea e^ bull e= (sec) (cm) (cmcm) (cmcm) (cmcm)

I 946E+08n^

Stratum A Stratum A Stratum A Stratum A Floor-effective soil soil soil wall total fluid intrinsic relative air effective vapor seam

saturation permeability permeability permeability perimeter

Ste kj krg ky Acrack

(cmcm) (cm) (cm) (cm) (cm)

Soil gas

cone (ngm)

I 0284 I 0284~ 0284 0184 I 596E-09 | 090T 537E-09 35357 603E+03

BIdg ventilation

rate

JbulldinE

(cms)

439E+06

Area of enclosed

space below grade

AB

(cm)

Crack-to-total

area ratio

n (unitless)

Crack depth below grade

Zltiack (cm)

Erithalpy of vaporization at

ave soil temperature

AHvTs (calmol)

Henryslaw constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law constant at

ave soil temperature

HTS

(unitless) bull

Vapor viscosity at

ave soil bull temperature

HTS

bull (gcm-s)

Stratum A

effective bull diffusion

coefficient

D^A-(cms)

Stratum B

effective bull diffusion

coefficient

D=B

(cms)

Stratum C

effective diffusion bull

coefficient

D=e (cms)

Total overall

effective diffusion

coefficient

DT

(cms)

Diffusion path

length

Ld

(cm)

I 787E+07 I bull449E-05 | 15 bull7709 230E-03 982E-02 176E-04 | 743E-03 | OOOE+00 | OOOE+00 | 743E-03 |

bull bull bull -

Convecfion path -bull

length

Lp (cm)

Source vapor cone

-source

(Mgm)

Crack radius

fcrack

(cm)

Average vapor

flow rate into bIdg

Qaoil bull

(cms)

Crack effective diffusion

coefficient pcack

(cms)

Area of crack

crack

(cm)-

Exponent of equivalent foundation

Peclet number

exp(Pef)

(unitless)

bull

1 15 -1 603E+03 1 010 1 474E+01 743E-03 354E+03 1 697E+07

Infinite source Indoor

attenuation coefficient

poundbullbullbull C t

pound(unitless)

bullsiilaquogt j ii08E-05

Infinite [ source

bIdg cone

Cbujidjng

(pgm)

651 E-02 iKrt

Unit risk

factor

URF

(ngm)-

Reference cone

RfC

(mgm)

NA 35E-02 1

I END I

Appx B-2 cis-12-DCExls 3o f3 982009

AR100313

APPENDIX B-3-A DATA ENTRY SHEET

Coyne Texti le Services - Hunt ington West Virginia

SG-ADV Version 31 0204

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

67663

Soil Gas Concentration Data ENTER ENTER

Soil Soil gas gas

cone OR cone c C

(^gm) (ppmv)

591 E+03

bull

Chemical

Chloroform

MORE ENTER Depth

below grade tb bottom

of enclosed space floor

bull LF

(cm)

ENTER

Soil gas sampling depth

below grade

(cm)

ENTER

Average soil

temperature-Ts

CO bull

1 15 1 15 1 125

ENTER ENTER ENTER Totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

IIA hs he (cm) (cm) (cm)

1 5 bull 1 1

ENTER ENTER Soil - bull

stratum A User-defined SCS stratum A

soil type bull soil vapor (used to estimate OR permeability

soil vapor k

bull permeability) (cm) 1

SL 1 1 bull

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A soil dry

bulk density

Pb (gcm)

ENTER Stratum A soil total porosity

nV (unitless)

ENTER Stratum A

-soilwater-filled bullporosity

Sraquo (cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

(unitless)

ENTER Stratum B

soil water-filled porosity

bull ebdquo=

(cmcm) bull

ENTER Straturri C

SCS bull soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

- c rack

(cm)

ENTER

Soil-bldg pressure

differential AP^

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor

width bull W B

(cm)

ENTER

Enclosed space

height HB

(cm)

ENTER

bull Floor-wall^ seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bidg OR

Leave blank to calculi

Qsoil bull

(Lm)

I -I

Appx B-3 Chloroformxls 1 of 3 982009

AR100314

APPENDIX B-3-B CHEMICALPROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Diffusivity in air

D (cms)

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffijsivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature

Dbdquo H TR A H bdquo TB Tc

(cm s) (atm-m mol) ro (calmol) (degK) (degK)

Molecular weight

MW

(gmol)

Unit risk

factor URF

(ngm)-

Reference cone

RfC

(mgm)

104E-01 100E-05 I 366E-03 25 6988 33432 53640 11938 I 23E-05 | OOE+00

Appx B-3 Chloroformxls 2 of 3 982009

AR100315

APPENDIX B-3-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure

duration

(sec)

Source-

building

separation

LT

(cm)

Stratum A

soil

air-filled

porosity

Sa

( cm cm )

Stratum B

soil

air-filled

porosity

( cm cm )

Stratum C

soil

air-filled

porosity

( c m c m )

Stratum A

effective

total fluid

saturation

( c m c m )

Stratum A

soil

intrinsic

penmeability

k

(cm )

Stratum A

- soil

relative air

permeabil i ty

(cm )

Stratum A

soil

effective vapor

permeability

kv

(cm )

Floor-

wall

seam

perimeter

gtcrack

(cm)

Soil gas

cone

(ngm)

BIdg

venfilation

rate

^buildlriE

(cms)

I 9 4 6 E + 0 8 ~ T I 0284 T 596E-09 I 0-901 I 537E-09 | 35357 | 591 E+03 j 439E+06 | 1 0 284 0284 0184

Area of

enclosed

space

below

grade

A B

( c m )

Crack-

to-total

area

ratio

n

(unitless)

Crack

depth

bull below

grade

^crack

(cm)

Enthalpy of

vaporization at

ave soil

temperature

AHTs bull

(calmol)

Henry s law

constant at

ave soil

temperature

HTS

(a tm-m mol j

Henrys law

constant at

ave soil

bull temperature

HTS

(unitless) bull

Vapor

viscosity at

ave soil-

temperature

^HTS

(gcm-s)

Stratum

A

effective

diffusion

coefficient

(cm s)

Stratum

B

effective

difftjsion

coefficient

D B

(cms) bull

S t ra tum

C

effective

diffusion

coefficient

Dc

(cm s)

Total

overall

effective

bull diffusion

coefficient

D T

(cm s)

Diffi jsion

path

length

Ld

(cm)

I 787E+07 I 449E-05 j - bull 15 7528 210E-03 896E-02 176E-04 I 105E-02 | OOOE+00 | OOOE+00 | 105E-02

Convection

path length

Lp

(cm)

Source

vapor

cone -

^source

- (ngm)

Crack

radius

Tcrack

(cm)

Average

vapor

flow rate

into bidg

Qsoil

(cms)

Crack

effective

diffusion

coefficient Qcrack

bull (cms)

Area of crack

Acrack

(cm)

Exponent of

equivalent

foundation

Peclet number

exp(Pe)

(unitless)

V bull bull

1 15 1 591 E+03 1 010 1 474E+01 105E-02 354E+03 1 355E+05

Infinite

source

indoor

attenuation

coefficient

d

(unitless)

bull 108E-05

Infinite

source

bIdg

cone

^ b u i l d i n g

i (^gm)

bull bull

i 638E-02 -

Unit

risk bull factor

URF

(ngmY

Reference

cone

RfC

(mgm)

~ 23E-05 NA 1

I END

Appx B-3 Chloroform xls 3 of 3 982009

AR100316

APPENDIX B-4-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ersion 31-020^

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

nodashes)

bull 75092

ENTER Soil gas

cone

c (ngm)

Soil Gas Concentration Data ENTER

Soil gas bull

OR cone

bull C

(ppmv)

152E+03

bull bull

Chemical

Methylene chloride

MORE

MORE 4gt

ENTER Depth

below grade to bottom

of enclosed space floor

LF -

(cm)

ENTER

Soil gas sampling depth

below grade

bull U

(cm)

ENTER

Average soil

temperature

Ts bull CC)

bull bull bull bull

1 15 1 15 125

ENTER Totals

Thickness of soil

stratum A h

(cm)

ENTER ENTER must add up to value of Ls (cell F24

Thickness Thickness of soil of soil

stratum B stratum C (Enter value or 0) (Enter value or 0)

he he bull

(cm) bull (cm) -

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(usedto estimate OR perrrieability | soil vapor

permeability)

k bull

(cm)

SL 1 bull 1

ENTER Stratum A

SCS soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

Pb (gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Stratum A

soil water-filled porosity

9w (cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

Pb^

(gcm)

ENTER Stratum B soil total porosity

n^

(unitless)

ENTER Stratum B

soil water-filled porosity

(crhcm)

ENTER Stratum C

SCS soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE 4gt

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

bull Soil-bldg pressure

differential AP^

(gcm-s)

ENTER Enclosed

space floor

length LB

(cm)

ENTER Enclosed

space floor

width bull W B

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width

w

(cm)

ENTER

Indoor air exchange

rate

ER (1h)

ENTER Average vapor

flow rate into bidg OR

Leave blank to calculc

Qsoil

(Lm)

10 40 8839 8839 244 01 083

Appx B-4 MCxIs 1 of 3 982009

AR100317

Diffijsivity in air

D

APPENDIX B-4-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffusivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature

Pw H TR AHt TB TC

Molecular weight

MW

Unit risk

factor URF

Reference cone

RfC

(cms) (cms) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) bull (ngm)- (mgm)

bull bull

1 101E-01 1 117E-05 1 218E-03 1 25 | 6706 1 31300 1 51000 1 8493 1 47E-07 1 30E+00 1

Appx B-4 MCxIs 2 of 3 982009

AR100318

APPENDIX B-4-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

T

(sec)

Source- -building

separation

LT

(cm)

Stratum A soil

air-filled porosity

e a bull

(cmcm)

Stratum B soil

bullair-filled porosity bull

ea^ (cmcm)

Stratum C soil

air-filled porosity

ea= (cmcmj

Stratum A effective total fluid

saturation

Sc bull

(cmcm)

Stratum A soil

intrinsic pemneability

ki (cm)

Stratum A soil

relative air permeability

^ ^ g

(cm)

stratumA bull soil effective vapor permeability

K (cm)

Floor-wall

seam perimeter

Xcrack

(cm)

Soil gas

cone (ngm)

BIdg ventilation

rate

Qbuildinc

(cms)

1 946E+08

Area of -enclosed

space below

bull grade

AB

(cm)

1

Crack-to-total

area rafio

Tl

(unitless)

0284 1

Crack depth below grade

Zcrack

(cm)

0284 1

bull Enthalpy of vaporization at

ave soil temperature

AHTs (calmol)

0284

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

0184

Henrys law constant at ave soil

temperature

HTS

bull (unitless)

1 596E-09

Vapor viscosity at

ave soil temperature

Mrs (gcm-s)

0901

Stratum A

effective diffusion

coefficient

D (cms)

537E-09

Stratum B

effective diffusion

coefficient

D-B (cms)

35357 1

Stratum C -

effective diffusion

coefficient

D-c ^ (cms)

152E+03

Total bull overall

bull effective diffusion

coefficient

D ^

(cms)

440E+06 1

Difftjsion path

length

Ld (cm)

1 787E+07

Convection path

length

Lp (cm)

4 49E-05

Source vapor cone

Csource

(ngm)

15 1

Crack radius

Tcrack

(cm)

7007 bull 1

Average vapor

flow rate intobldg

Qsoil

(cms)

130E-03

Crack effective diffusion

coefficient pcrack

(cms)-

555E-02

bull ^

Area of crack

Acrack

(cm) bull

1 176E-04

Exponent of equivalent foundation

Peclet number

exp(Pe)

(unitless) bull

bull bull

1 15

1 END

152E+03 010 1 474E+01 1 102E-02 354E+03 1 519E+05

102E-02

Infinite source

indoor ^attenuation coefficient

bull a

(unitless)

aiii08E-05

0 OOE+00

bull

Infinite bull source

bIdg ^ cone

^bu i l d i ng

(MQm)

164E-02

OOOE+00 1

Unit risk

factor

URF

(ngm)-

47E-07 1

102E-02 j

Reference cone

RfC

(mgm)

30E+00 j

1 1

Appx B-4 MCxIs 3 of 3 982009

AR100319

APPENDIX B-5-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ^erslon 31 0204

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

127184

Soil Gas Concentration Data ENTER ^ ENTER

Soil -Soi l bull gas gas

cone OR cone Cg C bull

(tgm) (ppmv)

149E+05 1

Chemical

bull Tetrachlbroethylene

MORE 4

ENTER Depth

below grade to bottom

ofenclosecJ space floor

LF

(cm)

ENTER

Soil gas bull sampling

depth below grade

u bull (cm)

ENTER

Average bullsoil

temperature - Ts

ro 1 1 5 1 15 1 125 bull

ENTER ENTER ENTER totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hft bull he bull he

(cm) (cm) (cm)

bull 1 5 1 - 1

ENTER ENTER Soil

stratum A User^defined bull SCS bull stratum A soil type soil vapor

(used to estimate OR perrrieability soil vapor K bull

permeability) (cm) 1

SL 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

Pb

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Sitratum A

soil water-filled bull porosity

(cmcm)

ENTER Stratum B

SCS soiltype

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

Pb^

(gcm)

ENTER Stratum B soil total porosity

Ajnitless^

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS soil type

LookupSoil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

VS

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor width

W B

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width

w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

ENTER Average vapor

flow rate into bidg OR

Leave blank to calcul

bull Qsoil

(Lm)

10 40 8839 8839 244 01 083

Appx B-5 PCExIS 1 of 3 982009

AR100320

APPENDIX B-5-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal Unit

Diffusivity Diffusivity at reference reference the riormal boiling Critical Molecular risk Reference in air in water temperature temperature boiling point point teriiperature weight factor cone

Da Dbdquo H TR AHb TB Tc MW URF RfC

(cms) (cnis) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) (^gm)- (mgm)

1 720E-02 1 820E-06 1 184E-02 1 25 1 8288 1 39440 1 62020 1 16583 1 59E-06 1 60E-01 1

J

AppxB-5PCExls 2 of 3 - 982009

AR100321

APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

T

(sec)

Source-building

separation

LT

bull (cm)

Stratum A soil

air-filled porosity

Oa (cmcm)

Stratum B - soil air-filled porosity

ea (cmcm)

Stratum C soil

air-filled porosity

ea= - (cmcm)

Stratum A effective total fluid

saturation

sbdquo (cmcm)

Stratum A soil

intrinsic permeability

ki (cm)

Stratum A soil

relative air permeability

- ^ g

(cm)

Stratum A soil

effective vapor permeability

kv (cm)

Floor-wall

seam perimeter

^crack

(cm)

Soil gas

cone

(ngm)

BIdg venfilation

rate

Qbuildins

bull (cms)

bull bull

1 946E+08

Area of enclosed

space below grade

AB

(cm)

1

bullCrack-to-total

area ratio

1 (unitless)

0284 1

Crack bull depth below grade

Zcrack

(cm) -

0284 1

Enthalpy of vaporization at bull

ave soil temperature

bull A H V TS

(calmol)

0284

Henrys law constant at

ave soil temperature

HTS (atm-mmol)

0184

-Henrys law constant at

ave soil temperature

HTS

(unitless)

1 596E-09

Vapor viscosity at

ave soil temperature

HTS

(gcm-s)

0901

Stratum A

effective diffusion

coefficient bull D = bull

(cms)

537E-09

Stratum B

effective diffusion

coefficient

D--B (cms)

35357 1

Stratum C

effective diffusion bull

coefficient

D-c (crris)

149E+05

Total overall

effective bulldiffusion coefficient

DT

(cms)

440E+06 1

Difftjsion path

length

U (cm)

1 787E+07

Convection path

length

bull Lp

(cm)

4 49E-05

Source vapor cone

^source

(ngm)

15 1

Crack radius

Tcrack

(cm)

9528 1

Average vapor

flow rate intobldg

Qsoil (cms)

908E-03

Crack effective diffusion

coefficient pcrack

bull ( c m s ) bull

387E-01

Area of crack

Abdquoack (cm)

1 176E-04

Exponent of equivalent foundafion

Peclet number

exp(Pe)

(unitless)

bull

1 15-

1 END

149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08

727E-03

Infinite source indoor

attenuation coefficient

a

(unitless)

108E-05

OOOE+00

Infinite source

bIdg cone

Cburldtng

(Mgm)

161 E+00

OOOE+00 1

Unit risk

factor

URF

(ugm)-

59E-06 1

727E-03

Reference cone

RfC (mgm)

60E-01

1 1

Appx B-5 PCExls 3 of 3 982009

AR100322

APPENDIX B-6-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ersion31 0204

Reset to Defaults

t

Soil Gas Concentration Data ENTER

Chemical CAS No

(numbers only

no dashes)

79016

ENTER ENTER Soil Soil gas gas

cone OR cone C C -

bull (ngm) (ppmv)

782E+03

Chemical

Trichloroethylene

MORE ENTER Depth

below grade to bottom-

of enclosed space floor

LF

(cm)

ENTER

Soil gas sarnpling

depth below grade

U (cm)

ENTER

Average soil

temperature Ts

(degC)

1 15 1 15 t 125

ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e

(cm) (cm) (cm)

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estimate OR permeability soil vapor

permeability)

k (cm)

bull S L 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil bull-Parameters

ENTER Stratum A

soil dry bulk density

P b -

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Stratum A bull

soilwaterrfilled porosity

(cmcm) bull

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

bull P ^ (gcm)

ENTER Stratum B soil total

porosity

nlaquo

(unitless) -

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS bull soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor

width W B

(cm)

ENTER

Enclosed space height

H B bull

( c m ) bull

ENTER

Floor-wall seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bIdg OR

Leave blank to calculc

Qsoil

(Lm) -

Appx B-6 TCExIs 1 of 3 982009

A

AR100323

APPENDIX B-6-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight

Da Dbdquo H TR AH^b TB TC MW

Unit risk Reference

factor cone URF RfC

(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)

1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1

Appx B-6 TCExIs 2 of 3 982009

AR100324

APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

(sec)

Source-building

separation LT

(cm)

Stratum A soil

air-filled porosity

bull ea (cmcm)

Stratum B Soil

air-fllled porosity

e^ bull (cmcm)

Stratum C soil

air-filled porosity

(cmcm)

StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air

saturation permeability permeability

S|e k krg (cmcm) (cm) (cm)

Stratum A Floor-soil wall BIdg

effective vapor seam Soil ventilafion permeability perimeter gas rate

k^ bull Xack c o n e Qbuildins

(cm) (cm) (ngm) (cms)

946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |

Area of enclosed

space below grade

AB

(cm)

Ciack- to-total

area ratio

1 (unitless)

Crack depth below grade

Zcrack

(cm)

Enthalpy of vaporization at

ave soil temperature

A H J S

(calmol)

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law bull constant at

ave soil temperature

HTS

(unitless)

Vapor viscosity at

ave soil temperature

|JTS

(gcm^s)

Stratum A

effective diffusion

coefficient

(cms)

Stratum B

effective -diffusion

coefficient

D=B (cms)

Stratum ^ C effective diffusion

coefficient

D=c (cms)

Total overall

effective diffusion

coefficient

DT

(cms)

I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03

Diffusion path

length

Li (cm) bull

Convection bull path

length

Lp

(cm)

Source vapor cone bull

^source

(ngm)

Crack radius

rcrack

(cm)

Average vapor

- flow rate intobldg

Qsoil

(cms)

Crack effective diffusion

bull coefficient Qcrack

(cms)

Area of crack

^crack

(cm)

Exponent of equivalent foundation

Peclet bull number

exp(Pe)

(unitless)

bull bull

1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07

Infinite source Indoor

attenuation coefficient

a

(unitless)

108E-05

Infinite source

bIdg concgt

^building

(ngm)

844E-02

Unit risk

factor

URF

(ngm)-

Reference cone

RfC

(mgm)

1 1E-04 1 40E-02 1

END

Appx B-6 TCExIs 3 of 3 982009

AR100325

Office of Waste Management 1356 Hansford Street

Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256

West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director

ORDER

ISSUED UNDER THE

HAZARDOUS WASTE MANAGEMENT ACT

CHAPTER 22 ARTICLE 18

OF THE WEST VIRGINIA CODE^ AS AMENDED

y Order Number HW-011-80

To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704

ATTEMTION MREDARMON

Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull

AR100326

ViWJ011-laquo9 PageNunil)er2

BASIS FOR ORDER

As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following

A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^

B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator

C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities

0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94

^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement

P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following

1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater

2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was

^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment

CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable

CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order

AR100327

H W - 0 1 1 - 9 9 Page Number 3

REQUIREMENTS OF ORDER

Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows

1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^

2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore

remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling

GENERAL PROVaiONS

1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order

2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order

3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order

Effective Date

Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief

Wt T 1 V Oflice of Waste Management

AR100328

^ ^ S I S

^wmmmmamn

AR100329

Page 24: SDMS DocID 2121999 · International Enterprises Corp. building (Coyne Building), which is located at 1111 Vernon Street, Westmoreland District, Wayne County, West Virginia. The following

APPENDIX A

SUBSLAB VAPOR ANALYTICAL DATA

AR100301

Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility Huntington West Virginia

Sample

Consti tuent

Volatile Organics (ugm) 111-Trlchloroethane 1122-Tetrachloroethane 112-Trichloro-122-trifluoroethane 112-Trichloroethane 11-Dichioroethane 11-Dichloroethene 124-Trichloroberi2ene 124-Trimethylbenzene 12-Dibromoethane 12-Dichloroben2ene 12-Dichloroethane 12-Dichloroethene-(cis) -12-Dichloroethene (trans) 12-Dichloropropane 12-Dichlorotetrafluoroethane 135-Trimethylbenzene 13-Butadiene 13-Dichlorobenzene 13-Hexachlorobutadiene 14-Dichlorobenzene 224-trimethVlpentane 2-Chlorotoluene 4-Ethyltoluene Acetone Allyl Chloride Benzene Bromodichloromethane Bromoform Bromomethane Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 13-Dichloropropene (cis) Cyclohexane Dibromochloromethane

Identif ication Sample Date

CAS No

71-55-6 79-34-5 76-13-1 79-00-5 75-34-3 75-35-4 120-82-1 95-63-6 106-93-4 95-50-1 107-06-2 156-59-2 156-60-5 78-87-5 76-14-2 108-67-8 106-99^0 541-73-1 87-68-3 106-46-7 540-84r1 95-49-8

622-96-8 67-64-1 107-05-1 71-43-2 75-27-4 75-252 74-83-9 75-15-0 56-23-5 108-90-7 75-00-3 67-66-3 74-87-3

10061-01-5 110-82-7 124-48-1

lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt

lt lt lt lt lt lt lt lt lt lt lt lt

lt

VP-01 8132009

22 28 31 22 16 16 30 20 31 24 16 16 16 19 28 20 89 24 43 24

1 9 21 20 796 13 13 27 41 16 13 25 18 11 20 83 18 52 34

lt lt lt lt lt lt lt lt lt lt lt

lt lt lt lt lt lt lt lt lt lt lt

lt lt lt lt lt lt lt lt lt

lt lt lt lt

VP-02 8132009

218 2 7 5 307 218 162 159 297

bull 197 307 240 162 369 159 185 280 197 89

240 427 240 187 207 197

1880 125 128 268 414 155 125 252 184 106

5910 83 182 138 341

lt lt lt lt lt lt lt

lt lt lt

lt lt lt lt lt lt lt bull

lt lt lt lt

lt lt lt lt lt lt lt lt lt lt lt lt lt lt

VP-03 8132009

218 275 307 218

bull 162 159 297 197 307 240 162

6030 159 185 280 197 89

240 427 240 187 207 197

1750 125 128 268 414 155 125 252 184 106 195 83 182 138 341

Appx A SG Dataxis Page 1 of 2 982009

AR100302

Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility bull Huntington West Virginia

Consti tuent

Volatile Organics (ugm^) Dichlorodifluoromethane Ethylbenzene Methyl ethyl ketone Methyl Isobutyl ketone Methyl tert-butyl ether Methylene chloride n-Heptane jn-Hexane Styrene Tert-butyl alcohol Tetrachloroethene iToluene 13-Dichloropropene (trans) Triehloroethene Trichlorofluoromethane Vinyl bromide Vinyl chloride Xylene (o) Xylenes (mampp)

Sample Identif ication Sample Date

CAS No

75-71-8 100-41-4 78-93-3 108-10-1

1634-04-4 75-09-2

142-82-5 bull 110-54-3

100-42-5 75-65-0 127-18-4 108-88-3

10061-02-6 79-01-6 75-69-4 593-60-2 75-01-4 95-47-6

179601-23-1

lt lt

lt lt lt lt

lt lt

lt

lt lt lt lt lt

VP01 8132009

20 17 23 16 14 14 16

173 17 12 bull

11200 18 18 91 23 18 10 17 17

lt lt lt lt lt

lt

lt lt

lt lt

lt lt lt lt lt

VP-02 8132009

198 174 118 164 144

1520 164 -183 170 121

149000 151 182

2360 225 175 102 174 174

VP-03 8132009

lt 198 lt 174 lt 118 lt 164 lt 144

1160 lt 164

144 lt 170 ltbull 121

90500 lt 151 lt 182

7820 lt 225 lt 175 lt 102

208 387

Appx A SG Dataxis Page 2 of 2 982009

AR100303

APPENDIX B

CALCULATION OF TRANSPORT FACTORS USED TO ESTIMATE INDOOR AIR CONCENTRATIONS

AR100304

APPENDIX B

Calculation of Transport Factors Used to Estimate Indoor Air Concentrations

This appendix presents the methodology for calculating transport factors that are used to convert subslab

vapor concentrations to concentrations in indoor air 124-Trimethylbenzene 12-dichloroethene (cis)

chloroform methylene chloride tetrachloroethene and triehloroethene were identified as contaminants of

concern (COC) for potential vapor intrusion from subslab vapor associated with the Coyne Textile

Services Facility located in Huntington West Virginia (site) In this appendix the transport factors are

calculated to estimate the concentrations of COC in indoor air of the existing plant building located at the

site ~

Transport Factor for Indoor Air

The concentration of a constituent in indoor air (da) is proportional to the concentration of the constituent

in the subslab vapors immediately beneath the building foundation (ie subslab vapor concentration or

Csubsiab) The following equation is used to calculate da from Csubsiab

^ wja ~ ^subslab X I r

where

Cia = concentration of constituent in indoor air (mgm^) -

Csubsiab^ concentration of constituent in subslab vapors (mgm^) and

TF = transport factor from subslab vapors to indoor air

The transport factor (TF) is an infinite source attenuation coefficient andcan be calculated based on a

model developed by Johnson and Ettinger (1991) t he equation for calculating TF is as follows

(Deff X A B ) ( Q B X L T ) X expKQso i l X Lcrabk)(Dcrack X Acrack)]

exp[ (Qsoi l X Lcrack)(Dcrack X Acrack)] + (Deff X A B ) ( Q B X L T ) + (Deff X AB)(Qsoi l X L j ) X (exp [ (Qso i l X Lcrack)(Dcrack X Acrack)] - 1)

where

Deff = effective diffusion coefficient for vadose zone soil (cm^sec)

AB = area of enclosed space below grade (cm^)

QB = building ventilation rate (cm^sec)

LT = distance from contaminant source to building foundation (cm)

Qsoii = volumetric flow rate of vapors into the building (cm^sec)

Lcrack = foundatlon thickness (cm)

Dcrack = vapor diffusion coefficient through crack (cm^sec) and

Acrack = area of cracks through which vapors can pass (cm^)

AR100305

To solve this equation the USEPAs SG-ADV spreadsheet Version 31 most recently updated in

February 2004 was implemented A combination of site-specific factors and default values from the

Users Guide for Evaluating Subsurface Vapor Intrusion Into Buildings (USEPA 2004) were used as input

values in the model All input values are defined below and presented in Tables B-1-A through B-6-A

bull The initial subslab vapor concentration (Csubsiab) is the maximum detected concentration(in units

of ugm ) of samples VP-01 VP-02 and VP-03 that was presented in Table 3 of the report

bull The depth below grade to the bottom of the enclosed space floor (Lp) is set to 15 cm the default

value provided by USEPA (2004) for a slab-on-grade structure

bull The vapor sampling depth below grade (Lg) is a site-specific value The vapor samples were

collected from immediately beneath the building floor therefore Lj has been set to 15 cm

bull The average soilgroundwater temperature (Ts) is set to 125degC the average value for West

Virginia as estimated frorri Figure 8 of the vapor intrusion users guide (USEPA 2004)

bull The soil type used to estimate vapor permeability is assumed to be sandy loam (SL) The

associated soil properties for a sandy loam soil type are as follows the soil dry bulk density (Pb) is

162 gcm the total porosity (n) is 0387 (cm^-aircm^) and the water-filled porosity (nw) is 0103

(cm -HzOcm )

bull The floor thickness (Lcrack) is set to the USEPA (2004) default value of 10 cm

bull The soil-building pressure differential (AP) is set to the USEPA (2004) default value of 40 gcm-s^

bull The building dimensions are siterspecific based on the existing plant building located at the site

The existing structure is approximately 84000 square feet (Dolphin 2000) therefore the

dimensions are set to 8839 cm (290 feet) length by 8839 cm (290 feet) The USEPA (2004)

default value of 244 cm vyas used for the height

bull Thefloor-wall seam crack width (w) is set to the USEPA (2004)-default value of 01 cm

bull The indoor air exchange rate (ER) is set to 083hour This is the value provided by ASTM (2002)

for commercial and industrial buildings

AR100306

Tables B-1-B through B-6-B present the constituent-specific properties for COC that were used in the TF

calculations Tables B-1-C through B-6-C present the intermediate calculations used to determine the

indoor air attenuation coefficients (ie the transport factors) The shaded boxes in Tables B-1-C through

B-6-C also present the resulting TF values that are applied to the concentrations of COC in subslab

vapor and the estimated indoor air concentrations

References

American Society for Testing and Materials (ASTM 2002) Standard Guide for Risk-Based Corrective Action Applied at Petroleum Release Sites ASTM E-1739-95 (Reapproved 2002)

Johnson PC and RA Ettinger (1991) Heuristic model for predicting the intrusion r-ate of contaminant vapors into buildings Environ Sci Technolpgy 25 1445-1452

Dolphin Environmental LLC (Dolphin 2000) Site Characterization Report Mach 14 2000

United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004

AR100307

APPENDIX B-1-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV Nersion31 0204

Reset to Defaults

ENTER -

Chemical CAS No

(numbers only

no dasties)

95636

ENTER Soil gas

cone

Cg (ngm)

Soil Gas Concentration Data ENTER

Soil gas

OR cone

bull - c bull (PPmv)

197E+02

Chemical

124-Trimethylbenzene

MORE ENTER Depth

below grade to bottom

of enclosed space floor

U bull (cm)

ENTER

Soil gas sampling

depth below grade

U (cm) bull

ENTER

Average soil

temperature Ts

CO

1 15 1 1 5 bull125

ENTER ENTER ENTER Totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hft ha he

(cm) (cm) (cm)

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estirnate OR permeability | soil vapor

permeability) k v bull

(cm)

SL 1 1

MORE ENTER

stratum A SCS

soil type

Lookup Soil Parameters

ENTER stratum A soil dry

bulk density P

(gcm)

ENTER Stratum A soil total porosity

(unitless)

ENTER bull stratum A soil water-filled

porosity

(cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

nlaquo

(unitless)

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gchi-s^)

ENTER Enclosed

space floor

length bull LB

(cm)

ENTER Enclosed

space floor

width WB

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

bull Floor-wall seam crack

width w

(cm)

bullENTER

Indoor air exchange

rate ER

(1h) bull

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bidg OR

Leave blank to caicuij

(Lm)

Appx B-1 124-TMBxls 1 of 3 982009

AR100308

APPENDIX B-1-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of ^ bull law constant law constant vaporization at Normal

Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temperature boiling point point temperature weight

D bull Dbdquo H T R bull AHbdquo TB Tc IVIW

Unit risk Reference

factor cone URF RfC

(cms) (cmls) (atm-mmol) CO (calmol) (degK) (degK) (gmol) bull (ugm)- (mgm)

1 606E-02 1 792E-06 1 bull 614E-C3 1 25 1 9369 1 44230 | 64917 1 12020 1 OOE+00 1 60E-03 1

Appx B-1 124-TMBxls 2 of 3 982009

AR100309

APPENDIX B-1-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

(sec)

Source-building

separation

LT bull

(cm) bull

Stratum A soil

air-filled porosity

Q A

Stratum B soil

air-filled porosity

(cmcm) (cmcm)

Stratum C soil air-filled porosity

(cmcm)

Stratum A effective total fluid

saturation

Se

(cmcm)

Stratum A soil

bullintrinsic permeability

^ (cm)

stratum A Stratum A Floor- soil soli wall BIdg

relative air effective vapor seam Soil bull ventilation permeability permeability perimeter gas rate-

kfg ky Xgrack c o n e - QbuHdinpound

(cm) - (cm) (cm) (ngm) (cms)

946E+08 1 0284 0284 0284 0184 596E-09 0901 537E-09 35357 I 197E+02 | 439E+06 |

Area of enclosed

space below grade

As (cm)

Crack-to-total area ratio

1 bull

(unitless)

Crack depth

below grade

Zcfack

(cm)

Enthalpy of vaporization at

ave soil temperature

AHvjs

(calmol) bull

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law constant at

ave soil bull temperature

bull HTS

(unitless)

Vapor bull viscosity at

ave soil temperature

HTS

(gcm-s)

Stratum A

effective diffusion

coefficient

D (cms)

Stratum-B

effective diffusion coefficient

DB (cms)

Stratum C effective diffusion

coefficient

D-c (cms)

Total - overall effective diffusion

coefficient

D ^ (cms)

Diffusion path

length

L-

(cm)

I 787E+07 I 449E-05 | 15 | 11661 260E-03 111E-01 176E-04 I 612E-03 j OOOE+00 | OOOE+00 | 612E-03 j

bull Convection path

length

Lp

(cm)

Source vapor cone

^source

(ngm)

Crack radius

Tcfack

(cm)

Average vapor

flow rate into bIdg

Qsoii

(cms)

Crack effective diffusion

coefficient pcrack

(cms)

Area of CTack

Acack

(cm)

Exponent of equivalent foundation

Peclet number

exp(Pe)

(unitless)

bull bull - bull bull bull bull

1 15 1 197E+02 1 010 1 474E+01 612E-03 bull 354E-t-03 1 336E+09

Infinite source Indoor

~ attenuation coefficient

a

(unitless)

108E-05

Infinite source

btJbldgjJSv-L ^Ppncji3i-

virhpbiiilding bullbull ^lHltti^m)ilg

213E-03

Unit risk

factor

URF

(ngm)-

Reference cone

RfC (mgm)

NA 60E-03 1

I END

Appx B-1 124-TMBxls 3 of 3 982009

AR100310

APPENDIX B-2-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV Nersion31 020^

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

156592

Soil Gas Concentration Data ENTER

Soil gas

cone OR c

(ngm) bull

ENTER Soil bull-gas

cone

c (ppmv)

603E+03 1

Chemical

cis-12-Dichloroethylene

MORE ENTER Depth

below grade to bottom

of enclosed space floor

LF

(cm)

ENTER

Soil gas sampling

depth below grade

U (cm)

ENTER

Average soil

temperature bull Ts

(degC)

1 15 1 bull 15 125

ENTER ENTER ENTER Totalsmust add ijp tb value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hA hB he

bull (cm) (cm) (cm)

15 1 1

ENTER Soil

straturh A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estimate OR permeability | soil vapor

permeability) kv

(cm)

SL 1 |

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

P (gcm)

ENTER Stratum A soil total porosity

bull n

(unitless)

ENTER Stratum A

soil water-filled porosity

(cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

ENTER Stratum B

soil water-filled porosity

ENTER Stratum C

SCS soil type

(unitless) (cmcm)

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure differential

AP

(gcm-s)

ENTER Enclosed bull

space floor

length

LB (cm)

ENTER Enclosed

space floor

width WB

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER

Average vapor flow rate into bIdg

OR Leave blank to calculi

Qsoil

(Lm)

Appx B-2 cis-12-DCExls 1 of 3 982009

AR100311

APPENDIX B-2-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Diffusivity in air

Da

(cms)

Diffusivity in water

Dw (cms)

Henrys law constant at reference temperature

H

(atm-mmoi)

Henrys law constant

reference temperature

bull T R

CC)

Enthalpy of vaporization at

the normal boiling point

AHbdquob

(calmol)

Normal boiling point

TB

(degK)

Critical temperature

Tc (degK)

Molecular weight

MW

(gmol)

Unit risk

factor URF

(ngm)

Reference cone

RfC (mgm)

1 736E-02 1 113E-05 1 407E-03 j 1 25 1 bull 7192 1 33365 1 54400 1 9694 1 OOE+00 j 35E-02 1

Appx B-2 cis-12-DCExls 2 of 3 982009

AR100312

APPENDIX B-2-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

stratum A Stratum B Stratum C Source- soil soil soil

Exposure building air-filled air-filled air-filled

duration separation porosity porosity porosity

T LT ea e^ bull e= (sec) (cm) (cmcm) (cmcm) (cmcm)

I 946E+08n^

Stratum A Stratum A Stratum A Stratum A Floor-effective soil soil soil wall total fluid intrinsic relative air effective vapor seam

saturation permeability permeability permeability perimeter

Ste kj krg ky Acrack

(cmcm) (cm) (cm) (cm) (cm)

Soil gas

cone (ngm)

I 0284 I 0284~ 0284 0184 I 596E-09 | 090T 537E-09 35357 603E+03

BIdg ventilation

rate

JbulldinE

(cms)

439E+06

Area of enclosed

space below grade

AB

(cm)

Crack-to-total

area ratio

n (unitless)

Crack depth below grade

Zltiack (cm)

Erithalpy of vaporization at

ave soil temperature

AHvTs (calmol)

Henryslaw constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law constant at

ave soil temperature

HTS

(unitless) bull

Vapor viscosity at

ave soil bull temperature

HTS

bull (gcm-s)

Stratum A

effective bull diffusion

coefficient

D^A-(cms)

Stratum B

effective bull diffusion

coefficient

D=B

(cms)

Stratum C

effective diffusion bull

coefficient

D=e (cms)

Total overall

effective diffusion

coefficient

DT

(cms)

Diffusion path

length

Ld

(cm)

I 787E+07 I bull449E-05 | 15 bull7709 230E-03 982E-02 176E-04 | 743E-03 | OOOE+00 | OOOE+00 | 743E-03 |

bull bull bull -

Convecfion path -bull

length

Lp (cm)

Source vapor cone

-source

(Mgm)

Crack radius

fcrack

(cm)

Average vapor

flow rate into bIdg

Qaoil bull

(cms)

Crack effective diffusion

coefficient pcack

(cms)

Area of crack

crack

(cm)-

Exponent of equivalent foundation

Peclet number

exp(Pef)

(unitless)

bull

1 15 -1 603E+03 1 010 1 474E+01 743E-03 354E+03 1 697E+07

Infinite source Indoor

attenuation coefficient

poundbullbullbull C t

pound(unitless)

bullsiilaquogt j ii08E-05

Infinite [ source

bIdg cone

Cbujidjng

(pgm)

651 E-02 iKrt

Unit risk

factor

URF

(ngm)-

Reference cone

RfC

(mgm)

NA 35E-02 1

I END I

Appx B-2 cis-12-DCExls 3o f3 982009

AR100313

APPENDIX B-3-A DATA ENTRY SHEET

Coyne Texti le Services - Hunt ington West Virginia

SG-ADV Version 31 0204

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

67663

Soil Gas Concentration Data ENTER ENTER

Soil Soil gas gas

cone OR cone c C

(^gm) (ppmv)

591 E+03

bull

Chemical

Chloroform

MORE ENTER Depth

below grade tb bottom

of enclosed space floor

bull LF

(cm)

ENTER

Soil gas sampling depth

below grade

(cm)

ENTER

Average soil

temperature-Ts

CO bull

1 15 1 15 1 125

ENTER ENTER ENTER Totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

IIA hs he (cm) (cm) (cm)

1 5 bull 1 1

ENTER ENTER Soil - bull

stratum A User-defined SCS stratum A

soil type bull soil vapor (used to estimate OR permeability

soil vapor k

bull permeability) (cm) 1

SL 1 1 bull

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A soil dry

bulk density

Pb (gcm)

ENTER Stratum A soil total porosity

nV (unitless)

ENTER Stratum A

-soilwater-filled bullporosity

Sraquo (cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

(unitless)

ENTER Stratum B

soil water-filled porosity

bull ebdquo=

(cmcm) bull

ENTER Straturri C

SCS bull soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

- c rack

(cm)

ENTER

Soil-bldg pressure

differential AP^

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor

width bull W B

(cm)

ENTER

Enclosed space

height HB

(cm)

ENTER

bull Floor-wall^ seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bidg OR

Leave blank to calculi

Qsoil bull

(Lm)

I -I

Appx B-3 Chloroformxls 1 of 3 982009

AR100314

APPENDIX B-3-B CHEMICALPROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Diffusivity in air

D (cms)

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffijsivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature

Dbdquo H TR A H bdquo TB Tc

(cm s) (atm-m mol) ro (calmol) (degK) (degK)

Molecular weight

MW

(gmol)

Unit risk

factor URF

(ngm)-

Reference cone

RfC

(mgm)

104E-01 100E-05 I 366E-03 25 6988 33432 53640 11938 I 23E-05 | OOE+00

Appx B-3 Chloroformxls 2 of 3 982009

AR100315

APPENDIX B-3-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure

duration

(sec)

Source-

building

separation

LT

(cm)

Stratum A

soil

air-filled

porosity

Sa

( cm cm )

Stratum B

soil

air-filled

porosity

( cm cm )

Stratum C

soil

air-filled

porosity

( c m c m )

Stratum A

effective

total fluid

saturation

( c m c m )

Stratum A

soil

intrinsic

penmeability

k

(cm )

Stratum A

- soil

relative air

permeabil i ty

(cm )

Stratum A

soil

effective vapor

permeability

kv

(cm )

Floor-

wall

seam

perimeter

gtcrack

(cm)

Soil gas

cone

(ngm)

BIdg

venfilation

rate

^buildlriE

(cms)

I 9 4 6 E + 0 8 ~ T I 0284 T 596E-09 I 0-901 I 537E-09 | 35357 | 591 E+03 j 439E+06 | 1 0 284 0284 0184

Area of

enclosed

space

below

grade

A B

( c m )

Crack-

to-total

area

ratio

n

(unitless)

Crack

depth

bull below

grade

^crack

(cm)

Enthalpy of

vaporization at

ave soil

temperature

AHTs bull

(calmol)

Henry s law

constant at

ave soil

temperature

HTS

(a tm-m mol j

Henrys law

constant at

ave soil

bull temperature

HTS

(unitless) bull

Vapor

viscosity at

ave soil-

temperature

^HTS

(gcm-s)

Stratum

A

effective

diffusion

coefficient

(cm s)

Stratum

B

effective

difftjsion

coefficient

D B

(cms) bull

S t ra tum

C

effective

diffusion

coefficient

Dc

(cm s)

Total

overall

effective

bull diffusion

coefficient

D T

(cm s)

Diffi jsion

path

length

Ld

(cm)

I 787E+07 I 449E-05 j - bull 15 7528 210E-03 896E-02 176E-04 I 105E-02 | OOOE+00 | OOOE+00 | 105E-02

Convection

path length

Lp

(cm)

Source

vapor

cone -

^source

- (ngm)

Crack

radius

Tcrack

(cm)

Average

vapor

flow rate

into bidg

Qsoil

(cms)

Crack

effective

diffusion

coefficient Qcrack

bull (cms)

Area of crack

Acrack

(cm)

Exponent of

equivalent

foundation

Peclet number

exp(Pe)

(unitless)

V bull bull

1 15 1 591 E+03 1 010 1 474E+01 105E-02 354E+03 1 355E+05

Infinite

source

indoor

attenuation

coefficient

d

(unitless)

bull 108E-05

Infinite

source

bIdg

cone

^ b u i l d i n g

i (^gm)

bull bull

i 638E-02 -

Unit

risk bull factor

URF

(ngmY

Reference

cone

RfC

(mgm)

~ 23E-05 NA 1

I END

Appx B-3 Chloroform xls 3 of 3 982009

AR100316

APPENDIX B-4-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ersion 31-020^

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

nodashes)

bull 75092

ENTER Soil gas

cone

c (ngm)

Soil Gas Concentration Data ENTER

Soil gas bull

OR cone

bull C

(ppmv)

152E+03

bull bull

Chemical

Methylene chloride

MORE

MORE 4gt

ENTER Depth

below grade to bottom

of enclosed space floor

LF -

(cm)

ENTER

Soil gas sampling depth

below grade

bull U

(cm)

ENTER

Average soil

temperature

Ts bull CC)

bull bull bull bull

1 15 1 15 125

ENTER Totals

Thickness of soil

stratum A h

(cm)

ENTER ENTER must add up to value of Ls (cell F24

Thickness Thickness of soil of soil

stratum B stratum C (Enter value or 0) (Enter value or 0)

he he bull

(cm) bull (cm) -

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(usedto estimate OR perrrieability | soil vapor

permeability)

k bull

(cm)

SL 1 bull 1

ENTER Stratum A

SCS soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

Pb (gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Stratum A

soil water-filled porosity

9w (cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

Pb^

(gcm)

ENTER Stratum B soil total porosity

n^

(unitless)

ENTER Stratum B

soil water-filled porosity

(crhcm)

ENTER Stratum C

SCS soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE 4gt

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

bull Soil-bldg pressure

differential AP^

(gcm-s)

ENTER Enclosed

space floor

length LB

(cm)

ENTER Enclosed

space floor

width bull W B

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width

w

(cm)

ENTER

Indoor air exchange

rate

ER (1h)

ENTER Average vapor

flow rate into bidg OR

Leave blank to calculc

Qsoil

(Lm)

10 40 8839 8839 244 01 083

Appx B-4 MCxIs 1 of 3 982009

AR100317

Diffijsivity in air

D

APPENDIX B-4-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffusivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature

Pw H TR AHt TB TC

Molecular weight

MW

Unit risk

factor URF

Reference cone

RfC

(cms) (cms) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) bull (ngm)- (mgm)

bull bull

1 101E-01 1 117E-05 1 218E-03 1 25 | 6706 1 31300 1 51000 1 8493 1 47E-07 1 30E+00 1

Appx B-4 MCxIs 2 of 3 982009

AR100318

APPENDIX B-4-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

T

(sec)

Source- -building

separation

LT

(cm)

Stratum A soil

air-filled porosity

e a bull

(cmcm)

Stratum B soil

bullair-filled porosity bull

ea^ (cmcm)

Stratum C soil

air-filled porosity

ea= (cmcmj

Stratum A effective total fluid

saturation

Sc bull

(cmcm)

Stratum A soil

intrinsic pemneability

ki (cm)

Stratum A soil

relative air permeability

^ ^ g

(cm)

stratumA bull soil effective vapor permeability

K (cm)

Floor-wall

seam perimeter

Xcrack

(cm)

Soil gas

cone (ngm)

BIdg ventilation

rate

Qbuildinc

(cms)

1 946E+08

Area of -enclosed

space below

bull grade

AB

(cm)

1

Crack-to-total

area rafio

Tl

(unitless)

0284 1

Crack depth below grade

Zcrack

(cm)

0284 1

bull Enthalpy of vaporization at

ave soil temperature

AHTs (calmol)

0284

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

0184

Henrys law constant at ave soil

temperature

HTS

bull (unitless)

1 596E-09

Vapor viscosity at

ave soil temperature

Mrs (gcm-s)

0901

Stratum A

effective diffusion

coefficient

D (cms)

537E-09

Stratum B

effective diffusion

coefficient

D-B (cms)

35357 1

Stratum C -

effective diffusion

coefficient

D-c ^ (cms)

152E+03

Total bull overall

bull effective diffusion

coefficient

D ^

(cms)

440E+06 1

Difftjsion path

length

Ld (cm)

1 787E+07

Convection path

length

Lp (cm)

4 49E-05

Source vapor cone

Csource

(ngm)

15 1

Crack radius

Tcrack

(cm)

7007 bull 1

Average vapor

flow rate intobldg

Qsoil

(cms)

130E-03

Crack effective diffusion

coefficient pcrack

(cms)-

555E-02

bull ^

Area of crack

Acrack

(cm) bull

1 176E-04

Exponent of equivalent foundation

Peclet number

exp(Pe)

(unitless) bull

bull bull

1 15

1 END

152E+03 010 1 474E+01 1 102E-02 354E+03 1 519E+05

102E-02

Infinite source

indoor ^attenuation coefficient

bull a

(unitless)

aiii08E-05

0 OOE+00

bull

Infinite bull source

bIdg ^ cone

^bu i l d i ng

(MQm)

164E-02

OOOE+00 1

Unit risk

factor

URF

(ngm)-

47E-07 1

102E-02 j

Reference cone

RfC

(mgm)

30E+00 j

1 1

Appx B-4 MCxIs 3 of 3 982009

AR100319

APPENDIX B-5-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ^erslon 31 0204

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

127184

Soil Gas Concentration Data ENTER ^ ENTER

Soil -Soi l bull gas gas

cone OR cone Cg C bull

(tgm) (ppmv)

149E+05 1

Chemical

bull Tetrachlbroethylene

MORE 4

ENTER Depth

below grade to bottom

ofenclosecJ space floor

LF

(cm)

ENTER

Soil gas bull sampling

depth below grade

u bull (cm)

ENTER

Average bullsoil

temperature - Ts

ro 1 1 5 1 15 1 125 bull

ENTER ENTER ENTER totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hft bull he bull he

(cm) (cm) (cm)

bull 1 5 1 - 1

ENTER ENTER Soil

stratum A User^defined bull SCS bull stratum A soil type soil vapor

(used to estimate OR perrrieability soil vapor K bull

permeability) (cm) 1

SL 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

Pb

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Sitratum A

soil water-filled bull porosity

(cmcm)

ENTER Stratum B

SCS soiltype

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

Pb^

(gcm)

ENTER Stratum B soil total porosity

Ajnitless^

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS soil type

LookupSoil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

VS

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor width

W B

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width

w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

ENTER Average vapor

flow rate into bidg OR

Leave blank to calcul

bull Qsoil

(Lm)

10 40 8839 8839 244 01 083

Appx B-5 PCExIS 1 of 3 982009

AR100320

APPENDIX B-5-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal Unit

Diffusivity Diffusivity at reference reference the riormal boiling Critical Molecular risk Reference in air in water temperature temperature boiling point point teriiperature weight factor cone

Da Dbdquo H TR AHb TB Tc MW URF RfC

(cms) (cnis) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) (^gm)- (mgm)

1 720E-02 1 820E-06 1 184E-02 1 25 1 8288 1 39440 1 62020 1 16583 1 59E-06 1 60E-01 1

J

AppxB-5PCExls 2 of 3 - 982009

AR100321

APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

T

(sec)

Source-building

separation

LT

bull (cm)

Stratum A soil

air-filled porosity

Oa (cmcm)

Stratum B - soil air-filled porosity

ea (cmcm)

Stratum C soil

air-filled porosity

ea= - (cmcm)

Stratum A effective total fluid

saturation

sbdquo (cmcm)

Stratum A soil

intrinsic permeability

ki (cm)

Stratum A soil

relative air permeability

- ^ g

(cm)

Stratum A soil

effective vapor permeability

kv (cm)

Floor-wall

seam perimeter

^crack

(cm)

Soil gas

cone

(ngm)

BIdg venfilation

rate

Qbuildins

bull (cms)

bull bull

1 946E+08

Area of enclosed

space below grade

AB

(cm)

1

bullCrack-to-total

area ratio

1 (unitless)

0284 1

Crack bull depth below grade

Zcrack

(cm) -

0284 1

Enthalpy of vaporization at bull

ave soil temperature

bull A H V TS

(calmol)

0284

Henrys law constant at

ave soil temperature

HTS (atm-mmol)

0184

-Henrys law constant at

ave soil temperature

HTS

(unitless)

1 596E-09

Vapor viscosity at

ave soil temperature

HTS

(gcm-s)

0901

Stratum A

effective diffusion

coefficient bull D = bull

(cms)

537E-09

Stratum B

effective diffusion

coefficient

D--B (cms)

35357 1

Stratum C

effective diffusion bull

coefficient

D-c (crris)

149E+05

Total overall

effective bulldiffusion coefficient

DT

(cms)

440E+06 1

Difftjsion path

length

U (cm)

1 787E+07

Convection path

length

bull Lp

(cm)

4 49E-05

Source vapor cone

^source

(ngm)

15 1

Crack radius

Tcrack

(cm)

9528 1

Average vapor

flow rate intobldg

Qsoil (cms)

908E-03

Crack effective diffusion

coefficient pcrack

bull ( c m s ) bull

387E-01

Area of crack

Abdquoack (cm)

1 176E-04

Exponent of equivalent foundafion

Peclet number

exp(Pe)

(unitless)

bull

1 15-

1 END

149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08

727E-03

Infinite source indoor

attenuation coefficient

a

(unitless)

108E-05

OOOE+00

Infinite source

bIdg cone

Cburldtng

(Mgm)

161 E+00

OOOE+00 1

Unit risk

factor

URF

(ugm)-

59E-06 1

727E-03

Reference cone

RfC (mgm)

60E-01

1 1

Appx B-5 PCExls 3 of 3 982009

AR100322

APPENDIX B-6-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ersion31 0204

Reset to Defaults

t

Soil Gas Concentration Data ENTER

Chemical CAS No

(numbers only

no dashes)

79016

ENTER ENTER Soil Soil gas gas

cone OR cone C C -

bull (ngm) (ppmv)

782E+03

Chemical

Trichloroethylene

MORE ENTER Depth

below grade to bottom-

of enclosed space floor

LF

(cm)

ENTER

Soil gas sarnpling

depth below grade

U (cm)

ENTER

Average soil

temperature Ts

(degC)

1 15 1 15 t 125

ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e

(cm) (cm) (cm)

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estimate OR permeability soil vapor

permeability)

k (cm)

bull S L 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil bull-Parameters

ENTER Stratum A

soil dry bulk density

P b -

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Stratum A bull

soilwaterrfilled porosity

(cmcm) bull

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

bull P ^ (gcm)

ENTER Stratum B soil total

porosity

nlaquo

(unitless) -

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS bull soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor

width W B

(cm)

ENTER

Enclosed space height

H B bull

( c m ) bull

ENTER

Floor-wall seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bIdg OR

Leave blank to calculc

Qsoil

(Lm) -

Appx B-6 TCExIs 1 of 3 982009

A

AR100323

APPENDIX B-6-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight

Da Dbdquo H TR AH^b TB TC MW

Unit risk Reference

factor cone URF RfC

(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)

1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1

Appx B-6 TCExIs 2 of 3 982009

AR100324

APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

(sec)

Source-building

separation LT

(cm)

Stratum A soil

air-filled porosity

bull ea (cmcm)

Stratum B Soil

air-fllled porosity

e^ bull (cmcm)

Stratum C soil

air-filled porosity

(cmcm)

StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air

saturation permeability permeability

S|e k krg (cmcm) (cm) (cm)

Stratum A Floor-soil wall BIdg

effective vapor seam Soil ventilafion permeability perimeter gas rate

k^ bull Xack c o n e Qbuildins

(cm) (cm) (ngm) (cms)

946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |

Area of enclosed

space below grade

AB

(cm)

Ciack- to-total

area ratio

1 (unitless)

Crack depth below grade

Zcrack

(cm)

Enthalpy of vaporization at

ave soil temperature

A H J S

(calmol)

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law bull constant at

ave soil temperature

HTS

(unitless)

Vapor viscosity at

ave soil temperature

|JTS

(gcm^s)

Stratum A

effective diffusion

coefficient

(cms)

Stratum B

effective -diffusion

coefficient

D=B (cms)

Stratum ^ C effective diffusion

coefficient

D=c (cms)

Total overall

effective diffusion

coefficient

DT

(cms)

I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03

Diffusion path

length

Li (cm) bull

Convection bull path

length

Lp

(cm)

Source vapor cone bull

^source

(ngm)

Crack radius

rcrack

(cm)

Average vapor

- flow rate intobldg

Qsoil

(cms)

Crack effective diffusion

bull coefficient Qcrack

(cms)

Area of crack

^crack

(cm)

Exponent of equivalent foundation

Peclet bull number

exp(Pe)

(unitless)

bull bull

1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07

Infinite source Indoor

attenuation coefficient

a

(unitless)

108E-05

Infinite source

bIdg concgt

^building

(ngm)

844E-02

Unit risk

factor

URF

(ngm)-

Reference cone

RfC

(mgm)

1 1E-04 1 40E-02 1

END

Appx B-6 TCExIs 3 of 3 982009

AR100325

Office of Waste Management 1356 Hansford Street

Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256

West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director

ORDER

ISSUED UNDER THE

HAZARDOUS WASTE MANAGEMENT ACT

CHAPTER 22 ARTICLE 18

OF THE WEST VIRGINIA CODE^ AS AMENDED

y Order Number HW-011-80

To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704

ATTEMTION MREDARMON

Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull

AR100326

ViWJ011-laquo9 PageNunil)er2

BASIS FOR ORDER

As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following

A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^

B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator

C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities

0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94

^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement

P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following

1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater

2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was

^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment

CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable

CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order

AR100327

H W - 0 1 1 - 9 9 Page Number 3

REQUIREMENTS OF ORDER

Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows

1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^

2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore

remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling

GENERAL PROVaiONS

1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order

2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order

3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order

Effective Date

Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief

Wt T 1 V Oflice of Waste Management

AR100328

^ ^ S I S

^wmmmmamn

AR100329

Page 25: SDMS DocID 2121999 · International Enterprises Corp. building (Coyne Building), which is located at 1111 Vernon Street, Westmoreland District, Wayne County, West Virginia. The following

Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility Huntington West Virginia

Sample

Consti tuent

Volatile Organics (ugm) 111-Trlchloroethane 1122-Tetrachloroethane 112-Trichloro-122-trifluoroethane 112-Trichloroethane 11-Dichioroethane 11-Dichloroethene 124-Trichloroberi2ene 124-Trimethylbenzene 12-Dibromoethane 12-Dichloroben2ene 12-Dichloroethane 12-Dichloroethene-(cis) -12-Dichloroethene (trans) 12-Dichloropropane 12-Dichlorotetrafluoroethane 135-Trimethylbenzene 13-Butadiene 13-Dichlorobenzene 13-Hexachlorobutadiene 14-Dichlorobenzene 224-trimethVlpentane 2-Chlorotoluene 4-Ethyltoluene Acetone Allyl Chloride Benzene Bromodichloromethane Bromoform Bromomethane Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 13-Dichloropropene (cis) Cyclohexane Dibromochloromethane

Identif ication Sample Date

CAS No

71-55-6 79-34-5 76-13-1 79-00-5 75-34-3 75-35-4 120-82-1 95-63-6 106-93-4 95-50-1 107-06-2 156-59-2 156-60-5 78-87-5 76-14-2 108-67-8 106-99^0 541-73-1 87-68-3 106-46-7 540-84r1 95-49-8

622-96-8 67-64-1 107-05-1 71-43-2 75-27-4 75-252 74-83-9 75-15-0 56-23-5 108-90-7 75-00-3 67-66-3 74-87-3

10061-01-5 110-82-7 124-48-1

lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt lt

lt lt lt lt lt lt lt lt lt lt lt lt

lt

VP-01 8132009

22 28 31 22 16 16 30 20 31 24 16 16 16 19 28 20 89 24 43 24

1 9 21 20 796 13 13 27 41 16 13 25 18 11 20 83 18 52 34

lt lt lt lt lt lt lt lt lt lt lt

lt lt lt lt lt lt lt lt lt lt lt

lt lt lt lt lt lt lt lt lt

lt lt lt lt

VP-02 8132009

218 2 7 5 307 218 162 159 297

bull 197 307 240 162 369 159 185 280 197 89

240 427 240 187 207 197

1880 125 128 268 414 155 125 252 184 106

5910 83 182 138 341

lt lt lt lt lt lt lt

lt lt lt

lt lt lt lt lt lt lt bull

lt lt lt lt

lt lt lt lt lt lt lt lt lt lt lt lt lt lt

VP-03 8132009

218 275 307 218

bull 162 159 297 197 307 240 162

6030 159 185 280 197 89

240 427 240 187 207 197

1750 125 128 268 414 155 125 252 184 106 195 83 182 138 341

Appx A SG Dataxis Page 1 of 2 982009

AR100302

Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility bull Huntington West Virginia

Consti tuent

Volatile Organics (ugm^) Dichlorodifluoromethane Ethylbenzene Methyl ethyl ketone Methyl Isobutyl ketone Methyl tert-butyl ether Methylene chloride n-Heptane jn-Hexane Styrene Tert-butyl alcohol Tetrachloroethene iToluene 13-Dichloropropene (trans) Triehloroethene Trichlorofluoromethane Vinyl bromide Vinyl chloride Xylene (o) Xylenes (mampp)

Sample Identif ication Sample Date

CAS No

75-71-8 100-41-4 78-93-3 108-10-1

1634-04-4 75-09-2

142-82-5 bull 110-54-3

100-42-5 75-65-0 127-18-4 108-88-3

10061-02-6 79-01-6 75-69-4 593-60-2 75-01-4 95-47-6

179601-23-1

lt lt

lt lt lt lt

lt lt

lt

lt lt lt lt lt

VP01 8132009

20 17 23 16 14 14 16

173 17 12 bull

11200 18 18 91 23 18 10 17 17

lt lt lt lt lt

lt

lt lt

lt lt

lt lt lt lt lt

VP-02 8132009

198 174 118 164 144

1520 164 -183 170 121

149000 151 182

2360 225 175 102 174 174

VP-03 8132009

lt 198 lt 174 lt 118 lt 164 lt 144

1160 lt 164

144 lt 170 ltbull 121

90500 lt 151 lt 182

7820 lt 225 lt 175 lt 102

208 387

Appx A SG Dataxis Page 2 of 2 982009

AR100303

APPENDIX B

CALCULATION OF TRANSPORT FACTORS USED TO ESTIMATE INDOOR AIR CONCENTRATIONS

AR100304

APPENDIX B

Calculation of Transport Factors Used to Estimate Indoor Air Concentrations

This appendix presents the methodology for calculating transport factors that are used to convert subslab

vapor concentrations to concentrations in indoor air 124-Trimethylbenzene 12-dichloroethene (cis)

chloroform methylene chloride tetrachloroethene and triehloroethene were identified as contaminants of

concern (COC) for potential vapor intrusion from subslab vapor associated with the Coyne Textile

Services Facility located in Huntington West Virginia (site) In this appendix the transport factors are

calculated to estimate the concentrations of COC in indoor air of the existing plant building located at the

site ~

Transport Factor for Indoor Air

The concentration of a constituent in indoor air (da) is proportional to the concentration of the constituent

in the subslab vapors immediately beneath the building foundation (ie subslab vapor concentration or

Csubsiab) The following equation is used to calculate da from Csubsiab

^ wja ~ ^subslab X I r

where

Cia = concentration of constituent in indoor air (mgm^) -

Csubsiab^ concentration of constituent in subslab vapors (mgm^) and

TF = transport factor from subslab vapors to indoor air

The transport factor (TF) is an infinite source attenuation coefficient andcan be calculated based on a

model developed by Johnson and Ettinger (1991) t he equation for calculating TF is as follows

(Deff X A B ) ( Q B X L T ) X expKQso i l X Lcrabk)(Dcrack X Acrack)]

exp[ (Qsoi l X Lcrack)(Dcrack X Acrack)] + (Deff X A B ) ( Q B X L T ) + (Deff X AB)(Qsoi l X L j ) X (exp [ (Qso i l X Lcrack)(Dcrack X Acrack)] - 1)

where

Deff = effective diffusion coefficient for vadose zone soil (cm^sec)

AB = area of enclosed space below grade (cm^)

QB = building ventilation rate (cm^sec)

LT = distance from contaminant source to building foundation (cm)

Qsoii = volumetric flow rate of vapors into the building (cm^sec)

Lcrack = foundatlon thickness (cm)

Dcrack = vapor diffusion coefficient through crack (cm^sec) and

Acrack = area of cracks through which vapors can pass (cm^)

AR100305

To solve this equation the USEPAs SG-ADV spreadsheet Version 31 most recently updated in

February 2004 was implemented A combination of site-specific factors and default values from the

Users Guide for Evaluating Subsurface Vapor Intrusion Into Buildings (USEPA 2004) were used as input

values in the model All input values are defined below and presented in Tables B-1-A through B-6-A

bull The initial subslab vapor concentration (Csubsiab) is the maximum detected concentration(in units

of ugm ) of samples VP-01 VP-02 and VP-03 that was presented in Table 3 of the report

bull The depth below grade to the bottom of the enclosed space floor (Lp) is set to 15 cm the default

value provided by USEPA (2004) for a slab-on-grade structure

bull The vapor sampling depth below grade (Lg) is a site-specific value The vapor samples were

collected from immediately beneath the building floor therefore Lj has been set to 15 cm

bull The average soilgroundwater temperature (Ts) is set to 125degC the average value for West

Virginia as estimated frorri Figure 8 of the vapor intrusion users guide (USEPA 2004)

bull The soil type used to estimate vapor permeability is assumed to be sandy loam (SL) The

associated soil properties for a sandy loam soil type are as follows the soil dry bulk density (Pb) is

162 gcm the total porosity (n) is 0387 (cm^-aircm^) and the water-filled porosity (nw) is 0103

(cm -HzOcm )

bull The floor thickness (Lcrack) is set to the USEPA (2004) default value of 10 cm

bull The soil-building pressure differential (AP) is set to the USEPA (2004) default value of 40 gcm-s^

bull The building dimensions are siterspecific based on the existing plant building located at the site

The existing structure is approximately 84000 square feet (Dolphin 2000) therefore the

dimensions are set to 8839 cm (290 feet) length by 8839 cm (290 feet) The USEPA (2004)

default value of 244 cm vyas used for the height

bull Thefloor-wall seam crack width (w) is set to the USEPA (2004)-default value of 01 cm

bull The indoor air exchange rate (ER) is set to 083hour This is the value provided by ASTM (2002)

for commercial and industrial buildings

AR100306

Tables B-1-B through B-6-B present the constituent-specific properties for COC that were used in the TF

calculations Tables B-1-C through B-6-C present the intermediate calculations used to determine the

indoor air attenuation coefficients (ie the transport factors) The shaded boxes in Tables B-1-C through

B-6-C also present the resulting TF values that are applied to the concentrations of COC in subslab

vapor and the estimated indoor air concentrations

References

American Society for Testing and Materials (ASTM 2002) Standard Guide for Risk-Based Corrective Action Applied at Petroleum Release Sites ASTM E-1739-95 (Reapproved 2002)

Johnson PC and RA Ettinger (1991) Heuristic model for predicting the intrusion r-ate of contaminant vapors into buildings Environ Sci Technolpgy 25 1445-1452

Dolphin Environmental LLC (Dolphin 2000) Site Characterization Report Mach 14 2000

United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004

AR100307

APPENDIX B-1-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV Nersion31 0204

Reset to Defaults

ENTER -

Chemical CAS No

(numbers only

no dasties)

95636

ENTER Soil gas

cone

Cg (ngm)

Soil Gas Concentration Data ENTER

Soil gas

OR cone

bull - c bull (PPmv)

197E+02

Chemical

124-Trimethylbenzene

MORE ENTER Depth

below grade to bottom

of enclosed space floor

U bull (cm)

ENTER

Soil gas sampling

depth below grade

U (cm) bull

ENTER

Average soil

temperature Ts

CO

1 15 1 1 5 bull125

ENTER ENTER ENTER Totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hft ha he

(cm) (cm) (cm)

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estirnate OR permeability | soil vapor

permeability) k v bull

(cm)

SL 1 1

MORE ENTER

stratum A SCS

soil type

Lookup Soil Parameters

ENTER stratum A soil dry

bulk density P

(gcm)

ENTER Stratum A soil total porosity

(unitless)

ENTER bull stratum A soil water-filled

porosity

(cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

nlaquo

(unitless)

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gchi-s^)

ENTER Enclosed

space floor

length bull LB

(cm)

ENTER Enclosed

space floor

width WB

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

bull Floor-wall seam crack

width w

(cm)

bullENTER

Indoor air exchange

rate ER

(1h) bull

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bidg OR

Leave blank to caicuij

(Lm)

Appx B-1 124-TMBxls 1 of 3 982009

AR100308

APPENDIX B-1-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of ^ bull law constant law constant vaporization at Normal

Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temperature boiling point point temperature weight

D bull Dbdquo H T R bull AHbdquo TB Tc IVIW

Unit risk Reference

factor cone URF RfC

(cms) (cmls) (atm-mmol) CO (calmol) (degK) (degK) (gmol) bull (ugm)- (mgm)

1 606E-02 1 792E-06 1 bull 614E-C3 1 25 1 9369 1 44230 | 64917 1 12020 1 OOE+00 1 60E-03 1

Appx B-1 124-TMBxls 2 of 3 982009

AR100309

APPENDIX B-1-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

(sec)

Source-building

separation

LT bull

(cm) bull

Stratum A soil

air-filled porosity

Q A

Stratum B soil

air-filled porosity

(cmcm) (cmcm)

Stratum C soil air-filled porosity

(cmcm)

Stratum A effective total fluid

saturation

Se

(cmcm)

Stratum A soil

bullintrinsic permeability

^ (cm)

stratum A Stratum A Floor- soil soli wall BIdg

relative air effective vapor seam Soil bull ventilation permeability permeability perimeter gas rate-

kfg ky Xgrack c o n e - QbuHdinpound

(cm) - (cm) (cm) (ngm) (cms)

946E+08 1 0284 0284 0284 0184 596E-09 0901 537E-09 35357 I 197E+02 | 439E+06 |

Area of enclosed

space below grade

As (cm)

Crack-to-total area ratio

1 bull

(unitless)

Crack depth

below grade

Zcfack

(cm)

Enthalpy of vaporization at

ave soil temperature

AHvjs

(calmol) bull

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law constant at

ave soil bull temperature

bull HTS

(unitless)

Vapor bull viscosity at

ave soil temperature

HTS

(gcm-s)

Stratum A

effective diffusion

coefficient

D (cms)

Stratum-B

effective diffusion coefficient

DB (cms)

Stratum C effective diffusion

coefficient

D-c (cms)

Total - overall effective diffusion

coefficient

D ^ (cms)

Diffusion path

length

L-

(cm)

I 787E+07 I 449E-05 | 15 | 11661 260E-03 111E-01 176E-04 I 612E-03 j OOOE+00 | OOOE+00 | 612E-03 j

bull Convection path

length

Lp

(cm)

Source vapor cone

^source

(ngm)

Crack radius

Tcfack

(cm)

Average vapor

flow rate into bIdg

Qsoii

(cms)

Crack effective diffusion

coefficient pcrack

(cms)

Area of CTack

Acack

(cm)

Exponent of equivalent foundation

Peclet number

exp(Pe)

(unitless)

bull bull - bull bull bull bull

1 15 1 197E+02 1 010 1 474E+01 612E-03 bull 354E-t-03 1 336E+09

Infinite source Indoor

~ attenuation coefficient

a

(unitless)

108E-05

Infinite source

btJbldgjJSv-L ^Ppncji3i-

virhpbiiilding bullbull ^lHltti^m)ilg

213E-03

Unit risk

factor

URF

(ngm)-

Reference cone

RfC (mgm)

NA 60E-03 1

I END

Appx B-1 124-TMBxls 3 of 3 982009

AR100310

APPENDIX B-2-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV Nersion31 020^

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

156592

Soil Gas Concentration Data ENTER

Soil gas

cone OR c

(ngm) bull

ENTER Soil bull-gas

cone

c (ppmv)

603E+03 1

Chemical

cis-12-Dichloroethylene

MORE ENTER Depth

below grade to bottom

of enclosed space floor

LF

(cm)

ENTER

Soil gas sampling

depth below grade

U (cm)

ENTER

Average soil

temperature bull Ts

(degC)

1 15 1 bull 15 125

ENTER ENTER ENTER Totalsmust add ijp tb value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hA hB he

bull (cm) (cm) (cm)

15 1 1

ENTER Soil

straturh A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estimate OR permeability | soil vapor

permeability) kv

(cm)

SL 1 |

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

P (gcm)

ENTER Stratum A soil total porosity

bull n

(unitless)

ENTER Stratum A

soil water-filled porosity

(cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

ENTER Stratum B

soil water-filled porosity

ENTER Stratum C

SCS soil type

(unitless) (cmcm)

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure differential

AP

(gcm-s)

ENTER Enclosed bull

space floor

length

LB (cm)

ENTER Enclosed

space floor

width WB

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER

Average vapor flow rate into bIdg

OR Leave blank to calculi

Qsoil

(Lm)

Appx B-2 cis-12-DCExls 1 of 3 982009

AR100311

APPENDIX B-2-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Diffusivity in air

Da

(cms)

Diffusivity in water

Dw (cms)

Henrys law constant at reference temperature

H

(atm-mmoi)

Henrys law constant

reference temperature

bull T R

CC)

Enthalpy of vaporization at

the normal boiling point

AHbdquob

(calmol)

Normal boiling point

TB

(degK)

Critical temperature

Tc (degK)

Molecular weight

MW

(gmol)

Unit risk

factor URF

(ngm)

Reference cone

RfC (mgm)

1 736E-02 1 113E-05 1 407E-03 j 1 25 1 bull 7192 1 33365 1 54400 1 9694 1 OOE+00 j 35E-02 1

Appx B-2 cis-12-DCExls 2 of 3 982009

AR100312

APPENDIX B-2-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

stratum A Stratum B Stratum C Source- soil soil soil

Exposure building air-filled air-filled air-filled

duration separation porosity porosity porosity

T LT ea e^ bull e= (sec) (cm) (cmcm) (cmcm) (cmcm)

I 946E+08n^

Stratum A Stratum A Stratum A Stratum A Floor-effective soil soil soil wall total fluid intrinsic relative air effective vapor seam

saturation permeability permeability permeability perimeter

Ste kj krg ky Acrack

(cmcm) (cm) (cm) (cm) (cm)

Soil gas

cone (ngm)

I 0284 I 0284~ 0284 0184 I 596E-09 | 090T 537E-09 35357 603E+03

BIdg ventilation

rate

JbulldinE

(cms)

439E+06

Area of enclosed

space below grade

AB

(cm)

Crack-to-total

area ratio

n (unitless)

Crack depth below grade

Zltiack (cm)

Erithalpy of vaporization at

ave soil temperature

AHvTs (calmol)

Henryslaw constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law constant at

ave soil temperature

HTS

(unitless) bull

Vapor viscosity at

ave soil bull temperature

HTS

bull (gcm-s)

Stratum A

effective bull diffusion

coefficient

D^A-(cms)

Stratum B

effective bull diffusion

coefficient

D=B

(cms)

Stratum C

effective diffusion bull

coefficient

D=e (cms)

Total overall

effective diffusion

coefficient

DT

(cms)

Diffusion path

length

Ld

(cm)

I 787E+07 I bull449E-05 | 15 bull7709 230E-03 982E-02 176E-04 | 743E-03 | OOOE+00 | OOOE+00 | 743E-03 |

bull bull bull -

Convecfion path -bull

length

Lp (cm)

Source vapor cone

-source

(Mgm)

Crack radius

fcrack

(cm)

Average vapor

flow rate into bIdg

Qaoil bull

(cms)

Crack effective diffusion

coefficient pcack

(cms)

Area of crack

crack

(cm)-

Exponent of equivalent foundation

Peclet number

exp(Pef)

(unitless)

bull

1 15 -1 603E+03 1 010 1 474E+01 743E-03 354E+03 1 697E+07

Infinite source Indoor

attenuation coefficient

poundbullbullbull C t

pound(unitless)

bullsiilaquogt j ii08E-05

Infinite [ source

bIdg cone

Cbujidjng

(pgm)

651 E-02 iKrt

Unit risk

factor

URF

(ngm)-

Reference cone

RfC

(mgm)

NA 35E-02 1

I END I

Appx B-2 cis-12-DCExls 3o f3 982009

AR100313

APPENDIX B-3-A DATA ENTRY SHEET

Coyne Texti le Services - Hunt ington West Virginia

SG-ADV Version 31 0204

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

67663

Soil Gas Concentration Data ENTER ENTER

Soil Soil gas gas

cone OR cone c C

(^gm) (ppmv)

591 E+03

bull

Chemical

Chloroform

MORE ENTER Depth

below grade tb bottom

of enclosed space floor

bull LF

(cm)

ENTER

Soil gas sampling depth

below grade

(cm)

ENTER

Average soil

temperature-Ts

CO bull

1 15 1 15 1 125

ENTER ENTER ENTER Totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

IIA hs he (cm) (cm) (cm)

1 5 bull 1 1

ENTER ENTER Soil - bull

stratum A User-defined SCS stratum A

soil type bull soil vapor (used to estimate OR permeability

soil vapor k

bull permeability) (cm) 1

SL 1 1 bull

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A soil dry

bulk density

Pb (gcm)

ENTER Stratum A soil total porosity

nV (unitless)

ENTER Stratum A

-soilwater-filled bullporosity

Sraquo (cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

(unitless)

ENTER Stratum B

soil water-filled porosity

bull ebdquo=

(cmcm) bull

ENTER Straturri C

SCS bull soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

- c rack

(cm)

ENTER

Soil-bldg pressure

differential AP^

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor

width bull W B

(cm)

ENTER

Enclosed space

height HB

(cm)

ENTER

bull Floor-wall^ seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bidg OR

Leave blank to calculi

Qsoil bull

(Lm)

I -I

Appx B-3 Chloroformxls 1 of 3 982009

AR100314

APPENDIX B-3-B CHEMICALPROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Diffusivity in air

D (cms)

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffijsivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature

Dbdquo H TR A H bdquo TB Tc

(cm s) (atm-m mol) ro (calmol) (degK) (degK)

Molecular weight

MW

(gmol)

Unit risk

factor URF

(ngm)-

Reference cone

RfC

(mgm)

104E-01 100E-05 I 366E-03 25 6988 33432 53640 11938 I 23E-05 | OOE+00

Appx B-3 Chloroformxls 2 of 3 982009

AR100315

APPENDIX B-3-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure

duration

(sec)

Source-

building

separation

LT

(cm)

Stratum A

soil

air-filled

porosity

Sa

( cm cm )

Stratum B

soil

air-filled

porosity

( cm cm )

Stratum C

soil

air-filled

porosity

( c m c m )

Stratum A

effective

total fluid

saturation

( c m c m )

Stratum A

soil

intrinsic

penmeability

k

(cm )

Stratum A

- soil

relative air

permeabil i ty

(cm )

Stratum A

soil

effective vapor

permeability

kv

(cm )

Floor-

wall

seam

perimeter

gtcrack

(cm)

Soil gas

cone

(ngm)

BIdg

venfilation

rate

^buildlriE

(cms)

I 9 4 6 E + 0 8 ~ T I 0284 T 596E-09 I 0-901 I 537E-09 | 35357 | 591 E+03 j 439E+06 | 1 0 284 0284 0184

Area of

enclosed

space

below

grade

A B

( c m )

Crack-

to-total

area

ratio

n

(unitless)

Crack

depth

bull below

grade

^crack

(cm)

Enthalpy of

vaporization at

ave soil

temperature

AHTs bull

(calmol)

Henry s law

constant at

ave soil

temperature

HTS

(a tm-m mol j

Henrys law

constant at

ave soil

bull temperature

HTS

(unitless) bull

Vapor

viscosity at

ave soil-

temperature

^HTS

(gcm-s)

Stratum

A

effective

diffusion

coefficient

(cm s)

Stratum

B

effective

difftjsion

coefficient

D B

(cms) bull

S t ra tum

C

effective

diffusion

coefficient

Dc

(cm s)

Total

overall

effective

bull diffusion

coefficient

D T

(cm s)

Diffi jsion

path

length

Ld

(cm)

I 787E+07 I 449E-05 j - bull 15 7528 210E-03 896E-02 176E-04 I 105E-02 | OOOE+00 | OOOE+00 | 105E-02

Convection

path length

Lp

(cm)

Source

vapor

cone -

^source

- (ngm)

Crack

radius

Tcrack

(cm)

Average

vapor

flow rate

into bidg

Qsoil

(cms)

Crack

effective

diffusion

coefficient Qcrack

bull (cms)

Area of crack

Acrack

(cm)

Exponent of

equivalent

foundation

Peclet number

exp(Pe)

(unitless)

V bull bull

1 15 1 591 E+03 1 010 1 474E+01 105E-02 354E+03 1 355E+05

Infinite

source

indoor

attenuation

coefficient

d

(unitless)

bull 108E-05

Infinite

source

bIdg

cone

^ b u i l d i n g

i (^gm)

bull bull

i 638E-02 -

Unit

risk bull factor

URF

(ngmY

Reference

cone

RfC

(mgm)

~ 23E-05 NA 1

I END

Appx B-3 Chloroform xls 3 of 3 982009

AR100316

APPENDIX B-4-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ersion 31-020^

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

nodashes)

bull 75092

ENTER Soil gas

cone

c (ngm)

Soil Gas Concentration Data ENTER

Soil gas bull

OR cone

bull C

(ppmv)

152E+03

bull bull

Chemical

Methylene chloride

MORE

MORE 4gt

ENTER Depth

below grade to bottom

of enclosed space floor

LF -

(cm)

ENTER

Soil gas sampling depth

below grade

bull U

(cm)

ENTER

Average soil

temperature

Ts bull CC)

bull bull bull bull

1 15 1 15 125

ENTER Totals

Thickness of soil

stratum A h

(cm)

ENTER ENTER must add up to value of Ls (cell F24

Thickness Thickness of soil of soil

stratum B stratum C (Enter value or 0) (Enter value or 0)

he he bull

(cm) bull (cm) -

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(usedto estimate OR perrrieability | soil vapor

permeability)

k bull

(cm)

SL 1 bull 1

ENTER Stratum A

SCS soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

Pb (gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Stratum A

soil water-filled porosity

9w (cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

Pb^

(gcm)

ENTER Stratum B soil total porosity

n^

(unitless)

ENTER Stratum B

soil water-filled porosity

(crhcm)

ENTER Stratum C

SCS soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE 4gt

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

bull Soil-bldg pressure

differential AP^

(gcm-s)

ENTER Enclosed

space floor

length LB

(cm)

ENTER Enclosed

space floor

width bull W B

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width

w

(cm)

ENTER

Indoor air exchange

rate

ER (1h)

ENTER Average vapor

flow rate into bidg OR

Leave blank to calculc

Qsoil

(Lm)

10 40 8839 8839 244 01 083

Appx B-4 MCxIs 1 of 3 982009

AR100317

Diffijsivity in air

D

APPENDIX B-4-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffusivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature

Pw H TR AHt TB TC

Molecular weight

MW

Unit risk

factor URF

Reference cone

RfC

(cms) (cms) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) bull (ngm)- (mgm)

bull bull

1 101E-01 1 117E-05 1 218E-03 1 25 | 6706 1 31300 1 51000 1 8493 1 47E-07 1 30E+00 1

Appx B-4 MCxIs 2 of 3 982009

AR100318

APPENDIX B-4-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

T

(sec)

Source- -building

separation

LT

(cm)

Stratum A soil

air-filled porosity

e a bull

(cmcm)

Stratum B soil

bullair-filled porosity bull

ea^ (cmcm)

Stratum C soil

air-filled porosity

ea= (cmcmj

Stratum A effective total fluid

saturation

Sc bull

(cmcm)

Stratum A soil

intrinsic pemneability

ki (cm)

Stratum A soil

relative air permeability

^ ^ g

(cm)

stratumA bull soil effective vapor permeability

K (cm)

Floor-wall

seam perimeter

Xcrack

(cm)

Soil gas

cone (ngm)

BIdg ventilation

rate

Qbuildinc

(cms)

1 946E+08

Area of -enclosed

space below

bull grade

AB

(cm)

1

Crack-to-total

area rafio

Tl

(unitless)

0284 1

Crack depth below grade

Zcrack

(cm)

0284 1

bull Enthalpy of vaporization at

ave soil temperature

AHTs (calmol)

0284

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

0184

Henrys law constant at ave soil

temperature

HTS

bull (unitless)

1 596E-09

Vapor viscosity at

ave soil temperature

Mrs (gcm-s)

0901

Stratum A

effective diffusion

coefficient

D (cms)

537E-09

Stratum B

effective diffusion

coefficient

D-B (cms)

35357 1

Stratum C -

effective diffusion

coefficient

D-c ^ (cms)

152E+03

Total bull overall

bull effective diffusion

coefficient

D ^

(cms)

440E+06 1

Difftjsion path

length

Ld (cm)

1 787E+07

Convection path

length

Lp (cm)

4 49E-05

Source vapor cone

Csource

(ngm)

15 1

Crack radius

Tcrack

(cm)

7007 bull 1

Average vapor

flow rate intobldg

Qsoil

(cms)

130E-03

Crack effective diffusion

coefficient pcrack

(cms)-

555E-02

bull ^

Area of crack

Acrack

(cm) bull

1 176E-04

Exponent of equivalent foundation

Peclet number

exp(Pe)

(unitless) bull

bull bull

1 15

1 END

152E+03 010 1 474E+01 1 102E-02 354E+03 1 519E+05

102E-02

Infinite source

indoor ^attenuation coefficient

bull a

(unitless)

aiii08E-05

0 OOE+00

bull

Infinite bull source

bIdg ^ cone

^bu i l d i ng

(MQm)

164E-02

OOOE+00 1

Unit risk

factor

URF

(ngm)-

47E-07 1

102E-02 j

Reference cone

RfC

(mgm)

30E+00 j

1 1

Appx B-4 MCxIs 3 of 3 982009

AR100319

APPENDIX B-5-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ^erslon 31 0204

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

127184

Soil Gas Concentration Data ENTER ^ ENTER

Soil -Soi l bull gas gas

cone OR cone Cg C bull

(tgm) (ppmv)

149E+05 1

Chemical

bull Tetrachlbroethylene

MORE 4

ENTER Depth

below grade to bottom

ofenclosecJ space floor

LF

(cm)

ENTER

Soil gas bull sampling

depth below grade

u bull (cm)

ENTER

Average bullsoil

temperature - Ts

ro 1 1 5 1 15 1 125 bull

ENTER ENTER ENTER totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hft bull he bull he

(cm) (cm) (cm)

bull 1 5 1 - 1

ENTER ENTER Soil

stratum A User^defined bull SCS bull stratum A soil type soil vapor

(used to estimate OR perrrieability soil vapor K bull

permeability) (cm) 1

SL 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

Pb

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Sitratum A

soil water-filled bull porosity

(cmcm)

ENTER Stratum B

SCS soiltype

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

Pb^

(gcm)

ENTER Stratum B soil total porosity

Ajnitless^

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS soil type

LookupSoil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

VS

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor width

W B

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width

w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

ENTER Average vapor

flow rate into bidg OR

Leave blank to calcul

bull Qsoil

(Lm)

10 40 8839 8839 244 01 083

Appx B-5 PCExIS 1 of 3 982009

AR100320

APPENDIX B-5-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal Unit

Diffusivity Diffusivity at reference reference the riormal boiling Critical Molecular risk Reference in air in water temperature temperature boiling point point teriiperature weight factor cone

Da Dbdquo H TR AHb TB Tc MW URF RfC

(cms) (cnis) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) (^gm)- (mgm)

1 720E-02 1 820E-06 1 184E-02 1 25 1 8288 1 39440 1 62020 1 16583 1 59E-06 1 60E-01 1

J

AppxB-5PCExls 2 of 3 - 982009

AR100321

APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

T

(sec)

Source-building

separation

LT

bull (cm)

Stratum A soil

air-filled porosity

Oa (cmcm)

Stratum B - soil air-filled porosity

ea (cmcm)

Stratum C soil

air-filled porosity

ea= - (cmcm)

Stratum A effective total fluid

saturation

sbdquo (cmcm)

Stratum A soil

intrinsic permeability

ki (cm)

Stratum A soil

relative air permeability

- ^ g

(cm)

Stratum A soil

effective vapor permeability

kv (cm)

Floor-wall

seam perimeter

^crack

(cm)

Soil gas

cone

(ngm)

BIdg venfilation

rate

Qbuildins

bull (cms)

bull bull

1 946E+08

Area of enclosed

space below grade

AB

(cm)

1

bullCrack-to-total

area ratio

1 (unitless)

0284 1

Crack bull depth below grade

Zcrack

(cm) -

0284 1

Enthalpy of vaporization at bull

ave soil temperature

bull A H V TS

(calmol)

0284

Henrys law constant at

ave soil temperature

HTS (atm-mmol)

0184

-Henrys law constant at

ave soil temperature

HTS

(unitless)

1 596E-09

Vapor viscosity at

ave soil temperature

HTS

(gcm-s)

0901

Stratum A

effective diffusion

coefficient bull D = bull

(cms)

537E-09

Stratum B

effective diffusion

coefficient

D--B (cms)

35357 1

Stratum C

effective diffusion bull

coefficient

D-c (crris)

149E+05

Total overall

effective bulldiffusion coefficient

DT

(cms)

440E+06 1

Difftjsion path

length

U (cm)

1 787E+07

Convection path

length

bull Lp

(cm)

4 49E-05

Source vapor cone

^source

(ngm)

15 1

Crack radius

Tcrack

(cm)

9528 1

Average vapor

flow rate intobldg

Qsoil (cms)

908E-03

Crack effective diffusion

coefficient pcrack

bull ( c m s ) bull

387E-01

Area of crack

Abdquoack (cm)

1 176E-04

Exponent of equivalent foundafion

Peclet number

exp(Pe)

(unitless)

bull

1 15-

1 END

149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08

727E-03

Infinite source indoor

attenuation coefficient

a

(unitless)

108E-05

OOOE+00

Infinite source

bIdg cone

Cburldtng

(Mgm)

161 E+00

OOOE+00 1

Unit risk

factor

URF

(ugm)-

59E-06 1

727E-03

Reference cone

RfC (mgm)

60E-01

1 1

Appx B-5 PCExls 3 of 3 982009

AR100322

APPENDIX B-6-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ersion31 0204

Reset to Defaults

t

Soil Gas Concentration Data ENTER

Chemical CAS No

(numbers only

no dashes)

79016

ENTER ENTER Soil Soil gas gas

cone OR cone C C -

bull (ngm) (ppmv)

782E+03

Chemical

Trichloroethylene

MORE ENTER Depth

below grade to bottom-

of enclosed space floor

LF

(cm)

ENTER

Soil gas sarnpling

depth below grade

U (cm)

ENTER

Average soil

temperature Ts

(degC)

1 15 1 15 t 125

ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e

(cm) (cm) (cm)

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estimate OR permeability soil vapor

permeability)

k (cm)

bull S L 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil bull-Parameters

ENTER Stratum A

soil dry bulk density

P b -

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Stratum A bull

soilwaterrfilled porosity

(cmcm) bull

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

bull P ^ (gcm)

ENTER Stratum B soil total

porosity

nlaquo

(unitless) -

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS bull soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor

width W B

(cm)

ENTER

Enclosed space height

H B bull

( c m ) bull

ENTER

Floor-wall seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bIdg OR

Leave blank to calculc

Qsoil

(Lm) -

Appx B-6 TCExIs 1 of 3 982009

A

AR100323

APPENDIX B-6-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight

Da Dbdquo H TR AH^b TB TC MW

Unit risk Reference

factor cone URF RfC

(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)

1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1

Appx B-6 TCExIs 2 of 3 982009

AR100324

APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

(sec)

Source-building

separation LT

(cm)

Stratum A soil

air-filled porosity

bull ea (cmcm)

Stratum B Soil

air-fllled porosity

e^ bull (cmcm)

Stratum C soil

air-filled porosity

(cmcm)

StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air

saturation permeability permeability

S|e k krg (cmcm) (cm) (cm)

Stratum A Floor-soil wall BIdg

effective vapor seam Soil ventilafion permeability perimeter gas rate

k^ bull Xack c o n e Qbuildins

(cm) (cm) (ngm) (cms)

946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |

Area of enclosed

space below grade

AB

(cm)

Ciack- to-total

area ratio

1 (unitless)

Crack depth below grade

Zcrack

(cm)

Enthalpy of vaporization at

ave soil temperature

A H J S

(calmol)

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law bull constant at

ave soil temperature

HTS

(unitless)

Vapor viscosity at

ave soil temperature

|JTS

(gcm^s)

Stratum A

effective diffusion

coefficient

(cms)

Stratum B

effective -diffusion

coefficient

D=B (cms)

Stratum ^ C effective diffusion

coefficient

D=c (cms)

Total overall

effective diffusion

coefficient

DT

(cms)

I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03

Diffusion path

length

Li (cm) bull

Convection bull path

length

Lp

(cm)

Source vapor cone bull

^source

(ngm)

Crack radius

rcrack

(cm)

Average vapor

- flow rate intobldg

Qsoil

(cms)

Crack effective diffusion

bull coefficient Qcrack

(cms)

Area of crack

^crack

(cm)

Exponent of equivalent foundation

Peclet bull number

exp(Pe)

(unitless)

bull bull

1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07

Infinite source Indoor

attenuation coefficient

a

(unitless)

108E-05

Infinite source

bIdg concgt

^building

(ngm)

844E-02

Unit risk

factor

URF

(ngm)-

Reference cone

RfC

(mgm)

1 1E-04 1 40E-02 1

END

Appx B-6 TCExIs 3 of 3 982009

AR100325

Office of Waste Management 1356 Hansford Street

Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256

West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director

ORDER

ISSUED UNDER THE

HAZARDOUS WASTE MANAGEMENT ACT

CHAPTER 22 ARTICLE 18

OF THE WEST VIRGINIA CODE^ AS AMENDED

y Order Number HW-011-80

To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704

ATTEMTION MREDARMON

Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull

AR100326

ViWJ011-laquo9 PageNunil)er2

BASIS FOR ORDER

As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following

A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^

B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator

C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities

0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94

^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement

P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following

1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater

2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was

^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment

CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable

CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order

AR100327

H W - 0 1 1 - 9 9 Page Number 3

REQUIREMENTS OF ORDER

Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows

1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^

2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore

remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling

GENERAL PROVaiONS

1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order

2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order

3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order

Effective Date

Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief

Wt T 1 V Oflice of Waste Management

AR100328

^ ^ S I S

^wmmmmamn

AR100329

Page 26: SDMS DocID 2121999 · International Enterprises Corp. building (Coyne Building), which is located at 1111 Vernon Street, Westmoreland District, Wayne County, West Virginia. The following

Table A-1 Subslab Vapor Analytical Data Coyne Textile Services Facility bull Huntington West Virginia

Consti tuent

Volatile Organics (ugm^) Dichlorodifluoromethane Ethylbenzene Methyl ethyl ketone Methyl Isobutyl ketone Methyl tert-butyl ether Methylene chloride n-Heptane jn-Hexane Styrene Tert-butyl alcohol Tetrachloroethene iToluene 13-Dichloropropene (trans) Triehloroethene Trichlorofluoromethane Vinyl bromide Vinyl chloride Xylene (o) Xylenes (mampp)

Sample Identif ication Sample Date

CAS No

75-71-8 100-41-4 78-93-3 108-10-1

1634-04-4 75-09-2

142-82-5 bull 110-54-3

100-42-5 75-65-0 127-18-4 108-88-3

10061-02-6 79-01-6 75-69-4 593-60-2 75-01-4 95-47-6

179601-23-1

lt lt

lt lt lt lt

lt lt

lt

lt lt lt lt lt

VP01 8132009

20 17 23 16 14 14 16

173 17 12 bull

11200 18 18 91 23 18 10 17 17

lt lt lt lt lt

lt

lt lt

lt lt

lt lt lt lt lt

VP-02 8132009

198 174 118 164 144

1520 164 -183 170 121

149000 151 182

2360 225 175 102 174 174

VP-03 8132009

lt 198 lt 174 lt 118 lt 164 lt 144

1160 lt 164

144 lt 170 ltbull 121

90500 lt 151 lt 182

7820 lt 225 lt 175 lt 102

208 387

Appx A SG Dataxis Page 2 of 2 982009

AR100303

APPENDIX B

CALCULATION OF TRANSPORT FACTORS USED TO ESTIMATE INDOOR AIR CONCENTRATIONS

AR100304

APPENDIX B

Calculation of Transport Factors Used to Estimate Indoor Air Concentrations

This appendix presents the methodology for calculating transport factors that are used to convert subslab

vapor concentrations to concentrations in indoor air 124-Trimethylbenzene 12-dichloroethene (cis)

chloroform methylene chloride tetrachloroethene and triehloroethene were identified as contaminants of

concern (COC) for potential vapor intrusion from subslab vapor associated with the Coyne Textile

Services Facility located in Huntington West Virginia (site) In this appendix the transport factors are

calculated to estimate the concentrations of COC in indoor air of the existing plant building located at the

site ~

Transport Factor for Indoor Air

The concentration of a constituent in indoor air (da) is proportional to the concentration of the constituent

in the subslab vapors immediately beneath the building foundation (ie subslab vapor concentration or

Csubsiab) The following equation is used to calculate da from Csubsiab

^ wja ~ ^subslab X I r

where

Cia = concentration of constituent in indoor air (mgm^) -

Csubsiab^ concentration of constituent in subslab vapors (mgm^) and

TF = transport factor from subslab vapors to indoor air

The transport factor (TF) is an infinite source attenuation coefficient andcan be calculated based on a

model developed by Johnson and Ettinger (1991) t he equation for calculating TF is as follows

(Deff X A B ) ( Q B X L T ) X expKQso i l X Lcrabk)(Dcrack X Acrack)]

exp[ (Qsoi l X Lcrack)(Dcrack X Acrack)] + (Deff X A B ) ( Q B X L T ) + (Deff X AB)(Qsoi l X L j ) X (exp [ (Qso i l X Lcrack)(Dcrack X Acrack)] - 1)

where

Deff = effective diffusion coefficient for vadose zone soil (cm^sec)

AB = area of enclosed space below grade (cm^)

QB = building ventilation rate (cm^sec)

LT = distance from contaminant source to building foundation (cm)

Qsoii = volumetric flow rate of vapors into the building (cm^sec)

Lcrack = foundatlon thickness (cm)

Dcrack = vapor diffusion coefficient through crack (cm^sec) and

Acrack = area of cracks through which vapors can pass (cm^)

AR100305

To solve this equation the USEPAs SG-ADV spreadsheet Version 31 most recently updated in

February 2004 was implemented A combination of site-specific factors and default values from the

Users Guide for Evaluating Subsurface Vapor Intrusion Into Buildings (USEPA 2004) were used as input

values in the model All input values are defined below and presented in Tables B-1-A through B-6-A

bull The initial subslab vapor concentration (Csubsiab) is the maximum detected concentration(in units

of ugm ) of samples VP-01 VP-02 and VP-03 that was presented in Table 3 of the report

bull The depth below grade to the bottom of the enclosed space floor (Lp) is set to 15 cm the default

value provided by USEPA (2004) for a slab-on-grade structure

bull The vapor sampling depth below grade (Lg) is a site-specific value The vapor samples were

collected from immediately beneath the building floor therefore Lj has been set to 15 cm

bull The average soilgroundwater temperature (Ts) is set to 125degC the average value for West

Virginia as estimated frorri Figure 8 of the vapor intrusion users guide (USEPA 2004)

bull The soil type used to estimate vapor permeability is assumed to be sandy loam (SL) The

associated soil properties for a sandy loam soil type are as follows the soil dry bulk density (Pb) is

162 gcm the total porosity (n) is 0387 (cm^-aircm^) and the water-filled porosity (nw) is 0103

(cm -HzOcm )

bull The floor thickness (Lcrack) is set to the USEPA (2004) default value of 10 cm

bull The soil-building pressure differential (AP) is set to the USEPA (2004) default value of 40 gcm-s^

bull The building dimensions are siterspecific based on the existing plant building located at the site

The existing structure is approximately 84000 square feet (Dolphin 2000) therefore the

dimensions are set to 8839 cm (290 feet) length by 8839 cm (290 feet) The USEPA (2004)

default value of 244 cm vyas used for the height

bull Thefloor-wall seam crack width (w) is set to the USEPA (2004)-default value of 01 cm

bull The indoor air exchange rate (ER) is set to 083hour This is the value provided by ASTM (2002)

for commercial and industrial buildings

AR100306

Tables B-1-B through B-6-B present the constituent-specific properties for COC that were used in the TF

calculations Tables B-1-C through B-6-C present the intermediate calculations used to determine the

indoor air attenuation coefficients (ie the transport factors) The shaded boxes in Tables B-1-C through

B-6-C also present the resulting TF values that are applied to the concentrations of COC in subslab

vapor and the estimated indoor air concentrations

References

American Society for Testing and Materials (ASTM 2002) Standard Guide for Risk-Based Corrective Action Applied at Petroleum Release Sites ASTM E-1739-95 (Reapproved 2002)

Johnson PC and RA Ettinger (1991) Heuristic model for predicting the intrusion r-ate of contaminant vapors into buildings Environ Sci Technolpgy 25 1445-1452

Dolphin Environmental LLC (Dolphin 2000) Site Characterization Report Mach 14 2000

United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004

AR100307

APPENDIX B-1-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV Nersion31 0204

Reset to Defaults

ENTER -

Chemical CAS No

(numbers only

no dasties)

95636

ENTER Soil gas

cone

Cg (ngm)

Soil Gas Concentration Data ENTER

Soil gas

OR cone

bull - c bull (PPmv)

197E+02

Chemical

124-Trimethylbenzene

MORE ENTER Depth

below grade to bottom

of enclosed space floor

U bull (cm)

ENTER

Soil gas sampling

depth below grade

U (cm) bull

ENTER

Average soil

temperature Ts

CO

1 15 1 1 5 bull125

ENTER ENTER ENTER Totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hft ha he

(cm) (cm) (cm)

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estirnate OR permeability | soil vapor

permeability) k v bull

(cm)

SL 1 1

MORE ENTER

stratum A SCS

soil type

Lookup Soil Parameters

ENTER stratum A soil dry

bulk density P

(gcm)

ENTER Stratum A soil total porosity

(unitless)

ENTER bull stratum A soil water-filled

porosity

(cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

nlaquo

(unitless)

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gchi-s^)

ENTER Enclosed

space floor

length bull LB

(cm)

ENTER Enclosed

space floor

width WB

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

bull Floor-wall seam crack

width w

(cm)

bullENTER

Indoor air exchange

rate ER

(1h) bull

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bidg OR

Leave blank to caicuij

(Lm)

Appx B-1 124-TMBxls 1 of 3 982009

AR100308

APPENDIX B-1-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of ^ bull law constant law constant vaporization at Normal

Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temperature boiling point point temperature weight

D bull Dbdquo H T R bull AHbdquo TB Tc IVIW

Unit risk Reference

factor cone URF RfC

(cms) (cmls) (atm-mmol) CO (calmol) (degK) (degK) (gmol) bull (ugm)- (mgm)

1 606E-02 1 792E-06 1 bull 614E-C3 1 25 1 9369 1 44230 | 64917 1 12020 1 OOE+00 1 60E-03 1

Appx B-1 124-TMBxls 2 of 3 982009

AR100309

APPENDIX B-1-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

(sec)

Source-building

separation

LT bull

(cm) bull

Stratum A soil

air-filled porosity

Q A

Stratum B soil

air-filled porosity

(cmcm) (cmcm)

Stratum C soil air-filled porosity

(cmcm)

Stratum A effective total fluid

saturation

Se

(cmcm)

Stratum A soil

bullintrinsic permeability

^ (cm)

stratum A Stratum A Floor- soil soli wall BIdg

relative air effective vapor seam Soil bull ventilation permeability permeability perimeter gas rate-

kfg ky Xgrack c o n e - QbuHdinpound

(cm) - (cm) (cm) (ngm) (cms)

946E+08 1 0284 0284 0284 0184 596E-09 0901 537E-09 35357 I 197E+02 | 439E+06 |

Area of enclosed

space below grade

As (cm)

Crack-to-total area ratio

1 bull

(unitless)

Crack depth

below grade

Zcfack

(cm)

Enthalpy of vaporization at

ave soil temperature

AHvjs

(calmol) bull

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law constant at

ave soil bull temperature

bull HTS

(unitless)

Vapor bull viscosity at

ave soil temperature

HTS

(gcm-s)

Stratum A

effective diffusion

coefficient

D (cms)

Stratum-B

effective diffusion coefficient

DB (cms)

Stratum C effective diffusion

coefficient

D-c (cms)

Total - overall effective diffusion

coefficient

D ^ (cms)

Diffusion path

length

L-

(cm)

I 787E+07 I 449E-05 | 15 | 11661 260E-03 111E-01 176E-04 I 612E-03 j OOOE+00 | OOOE+00 | 612E-03 j

bull Convection path

length

Lp

(cm)

Source vapor cone

^source

(ngm)

Crack radius

Tcfack

(cm)

Average vapor

flow rate into bIdg

Qsoii

(cms)

Crack effective diffusion

coefficient pcrack

(cms)

Area of CTack

Acack

(cm)

Exponent of equivalent foundation

Peclet number

exp(Pe)

(unitless)

bull bull - bull bull bull bull

1 15 1 197E+02 1 010 1 474E+01 612E-03 bull 354E-t-03 1 336E+09

Infinite source Indoor

~ attenuation coefficient

a

(unitless)

108E-05

Infinite source

btJbldgjJSv-L ^Ppncji3i-

virhpbiiilding bullbull ^lHltti^m)ilg

213E-03

Unit risk

factor

URF

(ngm)-

Reference cone

RfC (mgm)

NA 60E-03 1

I END

Appx B-1 124-TMBxls 3 of 3 982009

AR100310

APPENDIX B-2-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV Nersion31 020^

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

156592

Soil Gas Concentration Data ENTER

Soil gas

cone OR c

(ngm) bull

ENTER Soil bull-gas

cone

c (ppmv)

603E+03 1

Chemical

cis-12-Dichloroethylene

MORE ENTER Depth

below grade to bottom

of enclosed space floor

LF

(cm)

ENTER

Soil gas sampling

depth below grade

U (cm)

ENTER

Average soil

temperature bull Ts

(degC)

1 15 1 bull 15 125

ENTER ENTER ENTER Totalsmust add ijp tb value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hA hB he

bull (cm) (cm) (cm)

15 1 1

ENTER Soil

straturh A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estimate OR permeability | soil vapor

permeability) kv

(cm)

SL 1 |

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

P (gcm)

ENTER Stratum A soil total porosity

bull n

(unitless)

ENTER Stratum A

soil water-filled porosity

(cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

ENTER Stratum B

soil water-filled porosity

ENTER Stratum C

SCS soil type

(unitless) (cmcm)

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure differential

AP

(gcm-s)

ENTER Enclosed bull

space floor

length

LB (cm)

ENTER Enclosed

space floor

width WB

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER

Average vapor flow rate into bIdg

OR Leave blank to calculi

Qsoil

(Lm)

Appx B-2 cis-12-DCExls 1 of 3 982009

AR100311

APPENDIX B-2-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Diffusivity in air

Da

(cms)

Diffusivity in water

Dw (cms)

Henrys law constant at reference temperature

H

(atm-mmoi)

Henrys law constant

reference temperature

bull T R

CC)

Enthalpy of vaporization at

the normal boiling point

AHbdquob

(calmol)

Normal boiling point

TB

(degK)

Critical temperature

Tc (degK)

Molecular weight

MW

(gmol)

Unit risk

factor URF

(ngm)

Reference cone

RfC (mgm)

1 736E-02 1 113E-05 1 407E-03 j 1 25 1 bull 7192 1 33365 1 54400 1 9694 1 OOE+00 j 35E-02 1

Appx B-2 cis-12-DCExls 2 of 3 982009

AR100312

APPENDIX B-2-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

stratum A Stratum B Stratum C Source- soil soil soil

Exposure building air-filled air-filled air-filled

duration separation porosity porosity porosity

T LT ea e^ bull e= (sec) (cm) (cmcm) (cmcm) (cmcm)

I 946E+08n^

Stratum A Stratum A Stratum A Stratum A Floor-effective soil soil soil wall total fluid intrinsic relative air effective vapor seam

saturation permeability permeability permeability perimeter

Ste kj krg ky Acrack

(cmcm) (cm) (cm) (cm) (cm)

Soil gas

cone (ngm)

I 0284 I 0284~ 0284 0184 I 596E-09 | 090T 537E-09 35357 603E+03

BIdg ventilation

rate

JbulldinE

(cms)

439E+06

Area of enclosed

space below grade

AB

(cm)

Crack-to-total

area ratio

n (unitless)

Crack depth below grade

Zltiack (cm)

Erithalpy of vaporization at

ave soil temperature

AHvTs (calmol)

Henryslaw constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law constant at

ave soil temperature

HTS

(unitless) bull

Vapor viscosity at

ave soil bull temperature

HTS

bull (gcm-s)

Stratum A

effective bull diffusion

coefficient

D^A-(cms)

Stratum B

effective bull diffusion

coefficient

D=B

(cms)

Stratum C

effective diffusion bull

coefficient

D=e (cms)

Total overall

effective diffusion

coefficient

DT

(cms)

Diffusion path

length

Ld

(cm)

I 787E+07 I bull449E-05 | 15 bull7709 230E-03 982E-02 176E-04 | 743E-03 | OOOE+00 | OOOE+00 | 743E-03 |

bull bull bull -

Convecfion path -bull

length

Lp (cm)

Source vapor cone

-source

(Mgm)

Crack radius

fcrack

(cm)

Average vapor

flow rate into bIdg

Qaoil bull

(cms)

Crack effective diffusion

coefficient pcack

(cms)

Area of crack

crack

(cm)-

Exponent of equivalent foundation

Peclet number

exp(Pef)

(unitless)

bull

1 15 -1 603E+03 1 010 1 474E+01 743E-03 354E+03 1 697E+07

Infinite source Indoor

attenuation coefficient

poundbullbullbull C t

pound(unitless)

bullsiilaquogt j ii08E-05

Infinite [ source

bIdg cone

Cbujidjng

(pgm)

651 E-02 iKrt

Unit risk

factor

URF

(ngm)-

Reference cone

RfC

(mgm)

NA 35E-02 1

I END I

Appx B-2 cis-12-DCExls 3o f3 982009

AR100313

APPENDIX B-3-A DATA ENTRY SHEET

Coyne Texti le Services - Hunt ington West Virginia

SG-ADV Version 31 0204

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

67663

Soil Gas Concentration Data ENTER ENTER

Soil Soil gas gas

cone OR cone c C

(^gm) (ppmv)

591 E+03

bull

Chemical

Chloroform

MORE ENTER Depth

below grade tb bottom

of enclosed space floor

bull LF

(cm)

ENTER

Soil gas sampling depth

below grade

(cm)

ENTER

Average soil

temperature-Ts

CO bull

1 15 1 15 1 125

ENTER ENTER ENTER Totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

IIA hs he (cm) (cm) (cm)

1 5 bull 1 1

ENTER ENTER Soil - bull

stratum A User-defined SCS stratum A

soil type bull soil vapor (used to estimate OR permeability

soil vapor k

bull permeability) (cm) 1

SL 1 1 bull

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A soil dry

bulk density

Pb (gcm)

ENTER Stratum A soil total porosity

nV (unitless)

ENTER Stratum A

-soilwater-filled bullporosity

Sraquo (cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

(unitless)

ENTER Stratum B

soil water-filled porosity

bull ebdquo=

(cmcm) bull

ENTER Straturri C

SCS bull soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

- c rack

(cm)

ENTER

Soil-bldg pressure

differential AP^

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor

width bull W B

(cm)

ENTER

Enclosed space

height HB

(cm)

ENTER

bull Floor-wall^ seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bidg OR

Leave blank to calculi

Qsoil bull

(Lm)

I -I

Appx B-3 Chloroformxls 1 of 3 982009

AR100314

APPENDIX B-3-B CHEMICALPROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Diffusivity in air

D (cms)

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffijsivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature

Dbdquo H TR A H bdquo TB Tc

(cm s) (atm-m mol) ro (calmol) (degK) (degK)

Molecular weight

MW

(gmol)

Unit risk

factor URF

(ngm)-

Reference cone

RfC

(mgm)

104E-01 100E-05 I 366E-03 25 6988 33432 53640 11938 I 23E-05 | OOE+00

Appx B-3 Chloroformxls 2 of 3 982009

AR100315

APPENDIX B-3-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure

duration

(sec)

Source-

building

separation

LT

(cm)

Stratum A

soil

air-filled

porosity

Sa

( cm cm )

Stratum B

soil

air-filled

porosity

( cm cm )

Stratum C

soil

air-filled

porosity

( c m c m )

Stratum A

effective

total fluid

saturation

( c m c m )

Stratum A

soil

intrinsic

penmeability

k

(cm )

Stratum A

- soil

relative air

permeabil i ty

(cm )

Stratum A

soil

effective vapor

permeability

kv

(cm )

Floor-

wall

seam

perimeter

gtcrack

(cm)

Soil gas

cone

(ngm)

BIdg

venfilation

rate

^buildlriE

(cms)

I 9 4 6 E + 0 8 ~ T I 0284 T 596E-09 I 0-901 I 537E-09 | 35357 | 591 E+03 j 439E+06 | 1 0 284 0284 0184

Area of

enclosed

space

below

grade

A B

( c m )

Crack-

to-total

area

ratio

n

(unitless)

Crack

depth

bull below

grade

^crack

(cm)

Enthalpy of

vaporization at

ave soil

temperature

AHTs bull

(calmol)

Henry s law

constant at

ave soil

temperature

HTS

(a tm-m mol j

Henrys law

constant at

ave soil

bull temperature

HTS

(unitless) bull

Vapor

viscosity at

ave soil-

temperature

^HTS

(gcm-s)

Stratum

A

effective

diffusion

coefficient

(cm s)

Stratum

B

effective

difftjsion

coefficient

D B

(cms) bull

S t ra tum

C

effective

diffusion

coefficient

Dc

(cm s)

Total

overall

effective

bull diffusion

coefficient

D T

(cm s)

Diffi jsion

path

length

Ld

(cm)

I 787E+07 I 449E-05 j - bull 15 7528 210E-03 896E-02 176E-04 I 105E-02 | OOOE+00 | OOOE+00 | 105E-02

Convection

path length

Lp

(cm)

Source

vapor

cone -

^source

- (ngm)

Crack

radius

Tcrack

(cm)

Average

vapor

flow rate

into bidg

Qsoil

(cms)

Crack

effective

diffusion

coefficient Qcrack

bull (cms)

Area of crack

Acrack

(cm)

Exponent of

equivalent

foundation

Peclet number

exp(Pe)

(unitless)

V bull bull

1 15 1 591 E+03 1 010 1 474E+01 105E-02 354E+03 1 355E+05

Infinite

source

indoor

attenuation

coefficient

d

(unitless)

bull 108E-05

Infinite

source

bIdg

cone

^ b u i l d i n g

i (^gm)

bull bull

i 638E-02 -

Unit

risk bull factor

URF

(ngmY

Reference

cone

RfC

(mgm)

~ 23E-05 NA 1

I END

Appx B-3 Chloroform xls 3 of 3 982009

AR100316

APPENDIX B-4-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ersion 31-020^

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

nodashes)

bull 75092

ENTER Soil gas

cone

c (ngm)

Soil Gas Concentration Data ENTER

Soil gas bull

OR cone

bull C

(ppmv)

152E+03

bull bull

Chemical

Methylene chloride

MORE

MORE 4gt

ENTER Depth

below grade to bottom

of enclosed space floor

LF -

(cm)

ENTER

Soil gas sampling depth

below grade

bull U

(cm)

ENTER

Average soil

temperature

Ts bull CC)

bull bull bull bull

1 15 1 15 125

ENTER Totals

Thickness of soil

stratum A h

(cm)

ENTER ENTER must add up to value of Ls (cell F24

Thickness Thickness of soil of soil

stratum B stratum C (Enter value or 0) (Enter value or 0)

he he bull

(cm) bull (cm) -

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(usedto estimate OR perrrieability | soil vapor

permeability)

k bull

(cm)

SL 1 bull 1

ENTER Stratum A

SCS soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

Pb (gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Stratum A

soil water-filled porosity

9w (cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

Pb^

(gcm)

ENTER Stratum B soil total porosity

n^

(unitless)

ENTER Stratum B

soil water-filled porosity

(crhcm)

ENTER Stratum C

SCS soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE 4gt

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

bull Soil-bldg pressure

differential AP^

(gcm-s)

ENTER Enclosed

space floor

length LB

(cm)

ENTER Enclosed

space floor

width bull W B

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width

w

(cm)

ENTER

Indoor air exchange

rate

ER (1h)

ENTER Average vapor

flow rate into bidg OR

Leave blank to calculc

Qsoil

(Lm)

10 40 8839 8839 244 01 083

Appx B-4 MCxIs 1 of 3 982009

AR100317

Diffijsivity in air

D

APPENDIX B-4-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffusivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature

Pw H TR AHt TB TC

Molecular weight

MW

Unit risk

factor URF

Reference cone

RfC

(cms) (cms) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) bull (ngm)- (mgm)

bull bull

1 101E-01 1 117E-05 1 218E-03 1 25 | 6706 1 31300 1 51000 1 8493 1 47E-07 1 30E+00 1

Appx B-4 MCxIs 2 of 3 982009

AR100318

APPENDIX B-4-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

T

(sec)

Source- -building

separation

LT

(cm)

Stratum A soil

air-filled porosity

e a bull

(cmcm)

Stratum B soil

bullair-filled porosity bull

ea^ (cmcm)

Stratum C soil

air-filled porosity

ea= (cmcmj

Stratum A effective total fluid

saturation

Sc bull

(cmcm)

Stratum A soil

intrinsic pemneability

ki (cm)

Stratum A soil

relative air permeability

^ ^ g

(cm)

stratumA bull soil effective vapor permeability

K (cm)

Floor-wall

seam perimeter

Xcrack

(cm)

Soil gas

cone (ngm)

BIdg ventilation

rate

Qbuildinc

(cms)

1 946E+08

Area of -enclosed

space below

bull grade

AB

(cm)

1

Crack-to-total

area rafio

Tl

(unitless)

0284 1

Crack depth below grade

Zcrack

(cm)

0284 1

bull Enthalpy of vaporization at

ave soil temperature

AHTs (calmol)

0284

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

0184

Henrys law constant at ave soil

temperature

HTS

bull (unitless)

1 596E-09

Vapor viscosity at

ave soil temperature

Mrs (gcm-s)

0901

Stratum A

effective diffusion

coefficient

D (cms)

537E-09

Stratum B

effective diffusion

coefficient

D-B (cms)

35357 1

Stratum C -

effective diffusion

coefficient

D-c ^ (cms)

152E+03

Total bull overall

bull effective diffusion

coefficient

D ^

(cms)

440E+06 1

Difftjsion path

length

Ld (cm)

1 787E+07

Convection path

length

Lp (cm)

4 49E-05

Source vapor cone

Csource

(ngm)

15 1

Crack radius

Tcrack

(cm)

7007 bull 1

Average vapor

flow rate intobldg

Qsoil

(cms)

130E-03

Crack effective diffusion

coefficient pcrack

(cms)-

555E-02

bull ^

Area of crack

Acrack

(cm) bull

1 176E-04

Exponent of equivalent foundation

Peclet number

exp(Pe)

(unitless) bull

bull bull

1 15

1 END

152E+03 010 1 474E+01 1 102E-02 354E+03 1 519E+05

102E-02

Infinite source

indoor ^attenuation coefficient

bull a

(unitless)

aiii08E-05

0 OOE+00

bull

Infinite bull source

bIdg ^ cone

^bu i l d i ng

(MQm)

164E-02

OOOE+00 1

Unit risk

factor

URF

(ngm)-

47E-07 1

102E-02 j

Reference cone

RfC

(mgm)

30E+00 j

1 1

Appx B-4 MCxIs 3 of 3 982009

AR100319

APPENDIX B-5-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ^erslon 31 0204

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

127184

Soil Gas Concentration Data ENTER ^ ENTER

Soil -Soi l bull gas gas

cone OR cone Cg C bull

(tgm) (ppmv)

149E+05 1

Chemical

bull Tetrachlbroethylene

MORE 4

ENTER Depth

below grade to bottom

ofenclosecJ space floor

LF

(cm)

ENTER

Soil gas bull sampling

depth below grade

u bull (cm)

ENTER

Average bullsoil

temperature - Ts

ro 1 1 5 1 15 1 125 bull

ENTER ENTER ENTER totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hft bull he bull he

(cm) (cm) (cm)

bull 1 5 1 - 1

ENTER ENTER Soil

stratum A User^defined bull SCS bull stratum A soil type soil vapor

(used to estimate OR perrrieability soil vapor K bull

permeability) (cm) 1

SL 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

Pb

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Sitratum A

soil water-filled bull porosity

(cmcm)

ENTER Stratum B

SCS soiltype

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

Pb^

(gcm)

ENTER Stratum B soil total porosity

Ajnitless^

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS soil type

LookupSoil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

VS

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor width

W B

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width

w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

ENTER Average vapor

flow rate into bidg OR

Leave blank to calcul

bull Qsoil

(Lm)

10 40 8839 8839 244 01 083

Appx B-5 PCExIS 1 of 3 982009

AR100320

APPENDIX B-5-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal Unit

Diffusivity Diffusivity at reference reference the riormal boiling Critical Molecular risk Reference in air in water temperature temperature boiling point point teriiperature weight factor cone

Da Dbdquo H TR AHb TB Tc MW URF RfC

(cms) (cnis) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) (^gm)- (mgm)

1 720E-02 1 820E-06 1 184E-02 1 25 1 8288 1 39440 1 62020 1 16583 1 59E-06 1 60E-01 1

J

AppxB-5PCExls 2 of 3 - 982009

AR100321

APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

T

(sec)

Source-building

separation

LT

bull (cm)

Stratum A soil

air-filled porosity

Oa (cmcm)

Stratum B - soil air-filled porosity

ea (cmcm)

Stratum C soil

air-filled porosity

ea= - (cmcm)

Stratum A effective total fluid

saturation

sbdquo (cmcm)

Stratum A soil

intrinsic permeability

ki (cm)

Stratum A soil

relative air permeability

- ^ g

(cm)

Stratum A soil

effective vapor permeability

kv (cm)

Floor-wall

seam perimeter

^crack

(cm)

Soil gas

cone

(ngm)

BIdg venfilation

rate

Qbuildins

bull (cms)

bull bull

1 946E+08

Area of enclosed

space below grade

AB

(cm)

1

bullCrack-to-total

area ratio

1 (unitless)

0284 1

Crack bull depth below grade

Zcrack

(cm) -

0284 1

Enthalpy of vaporization at bull

ave soil temperature

bull A H V TS

(calmol)

0284

Henrys law constant at

ave soil temperature

HTS (atm-mmol)

0184

-Henrys law constant at

ave soil temperature

HTS

(unitless)

1 596E-09

Vapor viscosity at

ave soil temperature

HTS

(gcm-s)

0901

Stratum A

effective diffusion

coefficient bull D = bull

(cms)

537E-09

Stratum B

effective diffusion

coefficient

D--B (cms)

35357 1

Stratum C

effective diffusion bull

coefficient

D-c (crris)

149E+05

Total overall

effective bulldiffusion coefficient

DT

(cms)

440E+06 1

Difftjsion path

length

U (cm)

1 787E+07

Convection path

length

bull Lp

(cm)

4 49E-05

Source vapor cone

^source

(ngm)

15 1

Crack radius

Tcrack

(cm)

9528 1

Average vapor

flow rate intobldg

Qsoil (cms)

908E-03

Crack effective diffusion

coefficient pcrack

bull ( c m s ) bull

387E-01

Area of crack

Abdquoack (cm)

1 176E-04

Exponent of equivalent foundafion

Peclet number

exp(Pe)

(unitless)

bull

1 15-

1 END

149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08

727E-03

Infinite source indoor

attenuation coefficient

a

(unitless)

108E-05

OOOE+00

Infinite source

bIdg cone

Cburldtng

(Mgm)

161 E+00

OOOE+00 1

Unit risk

factor

URF

(ugm)-

59E-06 1

727E-03

Reference cone

RfC (mgm)

60E-01

1 1

Appx B-5 PCExls 3 of 3 982009

AR100322

APPENDIX B-6-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ersion31 0204

Reset to Defaults

t

Soil Gas Concentration Data ENTER

Chemical CAS No

(numbers only

no dashes)

79016

ENTER ENTER Soil Soil gas gas

cone OR cone C C -

bull (ngm) (ppmv)

782E+03

Chemical

Trichloroethylene

MORE ENTER Depth

below grade to bottom-

of enclosed space floor

LF

(cm)

ENTER

Soil gas sarnpling

depth below grade

U (cm)

ENTER

Average soil

temperature Ts

(degC)

1 15 1 15 t 125

ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e

(cm) (cm) (cm)

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estimate OR permeability soil vapor

permeability)

k (cm)

bull S L 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil bull-Parameters

ENTER Stratum A

soil dry bulk density

P b -

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Stratum A bull

soilwaterrfilled porosity

(cmcm) bull

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

bull P ^ (gcm)

ENTER Stratum B soil total

porosity

nlaquo

(unitless) -

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS bull soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor

width W B

(cm)

ENTER

Enclosed space height

H B bull

( c m ) bull

ENTER

Floor-wall seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bIdg OR

Leave blank to calculc

Qsoil

(Lm) -

Appx B-6 TCExIs 1 of 3 982009

A

AR100323

APPENDIX B-6-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight

Da Dbdquo H TR AH^b TB TC MW

Unit risk Reference

factor cone URF RfC

(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)

1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1

Appx B-6 TCExIs 2 of 3 982009

AR100324

APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

(sec)

Source-building

separation LT

(cm)

Stratum A soil

air-filled porosity

bull ea (cmcm)

Stratum B Soil

air-fllled porosity

e^ bull (cmcm)

Stratum C soil

air-filled porosity

(cmcm)

StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air

saturation permeability permeability

S|e k krg (cmcm) (cm) (cm)

Stratum A Floor-soil wall BIdg

effective vapor seam Soil ventilafion permeability perimeter gas rate

k^ bull Xack c o n e Qbuildins

(cm) (cm) (ngm) (cms)

946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |

Area of enclosed

space below grade

AB

(cm)

Ciack- to-total

area ratio

1 (unitless)

Crack depth below grade

Zcrack

(cm)

Enthalpy of vaporization at

ave soil temperature

A H J S

(calmol)

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law bull constant at

ave soil temperature

HTS

(unitless)

Vapor viscosity at

ave soil temperature

|JTS

(gcm^s)

Stratum A

effective diffusion

coefficient

(cms)

Stratum B

effective -diffusion

coefficient

D=B (cms)

Stratum ^ C effective diffusion

coefficient

D=c (cms)

Total overall

effective diffusion

coefficient

DT

(cms)

I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03

Diffusion path

length

Li (cm) bull

Convection bull path

length

Lp

(cm)

Source vapor cone bull

^source

(ngm)

Crack radius

rcrack

(cm)

Average vapor

- flow rate intobldg

Qsoil

(cms)

Crack effective diffusion

bull coefficient Qcrack

(cms)

Area of crack

^crack

(cm)

Exponent of equivalent foundation

Peclet bull number

exp(Pe)

(unitless)

bull bull

1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07

Infinite source Indoor

attenuation coefficient

a

(unitless)

108E-05

Infinite source

bIdg concgt

^building

(ngm)

844E-02

Unit risk

factor

URF

(ngm)-

Reference cone

RfC

(mgm)

1 1E-04 1 40E-02 1

END

Appx B-6 TCExIs 3 of 3 982009

AR100325

Office of Waste Management 1356 Hansford Street

Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256

West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director

ORDER

ISSUED UNDER THE

HAZARDOUS WASTE MANAGEMENT ACT

CHAPTER 22 ARTICLE 18

OF THE WEST VIRGINIA CODE^ AS AMENDED

y Order Number HW-011-80

To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704

ATTEMTION MREDARMON

Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull

AR100326

ViWJ011-laquo9 PageNunil)er2

BASIS FOR ORDER

As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following

A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^

B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator

C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities

0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94

^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement

P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following

1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater

2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was

^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment

CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable

CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order

AR100327

H W - 0 1 1 - 9 9 Page Number 3

REQUIREMENTS OF ORDER

Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows

1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^

2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore

remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling

GENERAL PROVaiONS

1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order

2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order

3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order

Effective Date

Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief

Wt T 1 V Oflice of Waste Management

AR100328

^ ^ S I S

^wmmmmamn

AR100329

Page 27: SDMS DocID 2121999 · International Enterprises Corp. building (Coyne Building), which is located at 1111 Vernon Street, Westmoreland District, Wayne County, West Virginia. The following

APPENDIX B

CALCULATION OF TRANSPORT FACTORS USED TO ESTIMATE INDOOR AIR CONCENTRATIONS

AR100304

APPENDIX B

Calculation of Transport Factors Used to Estimate Indoor Air Concentrations

This appendix presents the methodology for calculating transport factors that are used to convert subslab

vapor concentrations to concentrations in indoor air 124-Trimethylbenzene 12-dichloroethene (cis)

chloroform methylene chloride tetrachloroethene and triehloroethene were identified as contaminants of

concern (COC) for potential vapor intrusion from subslab vapor associated with the Coyne Textile

Services Facility located in Huntington West Virginia (site) In this appendix the transport factors are

calculated to estimate the concentrations of COC in indoor air of the existing plant building located at the

site ~

Transport Factor for Indoor Air

The concentration of a constituent in indoor air (da) is proportional to the concentration of the constituent

in the subslab vapors immediately beneath the building foundation (ie subslab vapor concentration or

Csubsiab) The following equation is used to calculate da from Csubsiab

^ wja ~ ^subslab X I r

where

Cia = concentration of constituent in indoor air (mgm^) -

Csubsiab^ concentration of constituent in subslab vapors (mgm^) and

TF = transport factor from subslab vapors to indoor air

The transport factor (TF) is an infinite source attenuation coefficient andcan be calculated based on a

model developed by Johnson and Ettinger (1991) t he equation for calculating TF is as follows

(Deff X A B ) ( Q B X L T ) X expKQso i l X Lcrabk)(Dcrack X Acrack)]

exp[ (Qsoi l X Lcrack)(Dcrack X Acrack)] + (Deff X A B ) ( Q B X L T ) + (Deff X AB)(Qsoi l X L j ) X (exp [ (Qso i l X Lcrack)(Dcrack X Acrack)] - 1)

where

Deff = effective diffusion coefficient for vadose zone soil (cm^sec)

AB = area of enclosed space below grade (cm^)

QB = building ventilation rate (cm^sec)

LT = distance from contaminant source to building foundation (cm)

Qsoii = volumetric flow rate of vapors into the building (cm^sec)

Lcrack = foundatlon thickness (cm)

Dcrack = vapor diffusion coefficient through crack (cm^sec) and

Acrack = area of cracks through which vapors can pass (cm^)

AR100305

To solve this equation the USEPAs SG-ADV spreadsheet Version 31 most recently updated in

February 2004 was implemented A combination of site-specific factors and default values from the

Users Guide for Evaluating Subsurface Vapor Intrusion Into Buildings (USEPA 2004) were used as input

values in the model All input values are defined below and presented in Tables B-1-A through B-6-A

bull The initial subslab vapor concentration (Csubsiab) is the maximum detected concentration(in units

of ugm ) of samples VP-01 VP-02 and VP-03 that was presented in Table 3 of the report

bull The depth below grade to the bottom of the enclosed space floor (Lp) is set to 15 cm the default

value provided by USEPA (2004) for a slab-on-grade structure

bull The vapor sampling depth below grade (Lg) is a site-specific value The vapor samples were

collected from immediately beneath the building floor therefore Lj has been set to 15 cm

bull The average soilgroundwater temperature (Ts) is set to 125degC the average value for West

Virginia as estimated frorri Figure 8 of the vapor intrusion users guide (USEPA 2004)

bull The soil type used to estimate vapor permeability is assumed to be sandy loam (SL) The

associated soil properties for a sandy loam soil type are as follows the soil dry bulk density (Pb) is

162 gcm the total porosity (n) is 0387 (cm^-aircm^) and the water-filled porosity (nw) is 0103

(cm -HzOcm )

bull The floor thickness (Lcrack) is set to the USEPA (2004) default value of 10 cm

bull The soil-building pressure differential (AP) is set to the USEPA (2004) default value of 40 gcm-s^

bull The building dimensions are siterspecific based on the existing plant building located at the site

The existing structure is approximately 84000 square feet (Dolphin 2000) therefore the

dimensions are set to 8839 cm (290 feet) length by 8839 cm (290 feet) The USEPA (2004)

default value of 244 cm vyas used for the height

bull Thefloor-wall seam crack width (w) is set to the USEPA (2004)-default value of 01 cm

bull The indoor air exchange rate (ER) is set to 083hour This is the value provided by ASTM (2002)

for commercial and industrial buildings

AR100306

Tables B-1-B through B-6-B present the constituent-specific properties for COC that were used in the TF

calculations Tables B-1-C through B-6-C present the intermediate calculations used to determine the

indoor air attenuation coefficients (ie the transport factors) The shaded boxes in Tables B-1-C through

B-6-C also present the resulting TF values that are applied to the concentrations of COC in subslab

vapor and the estimated indoor air concentrations

References

American Society for Testing and Materials (ASTM 2002) Standard Guide for Risk-Based Corrective Action Applied at Petroleum Release Sites ASTM E-1739-95 (Reapproved 2002)

Johnson PC and RA Ettinger (1991) Heuristic model for predicting the intrusion r-ate of contaminant vapors into buildings Environ Sci Technolpgy 25 1445-1452

Dolphin Environmental LLC (Dolphin 2000) Site Characterization Report Mach 14 2000

United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004

AR100307

APPENDIX B-1-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV Nersion31 0204

Reset to Defaults

ENTER -

Chemical CAS No

(numbers only

no dasties)

95636

ENTER Soil gas

cone

Cg (ngm)

Soil Gas Concentration Data ENTER

Soil gas

OR cone

bull - c bull (PPmv)

197E+02

Chemical

124-Trimethylbenzene

MORE ENTER Depth

below grade to bottom

of enclosed space floor

U bull (cm)

ENTER

Soil gas sampling

depth below grade

U (cm) bull

ENTER

Average soil

temperature Ts

CO

1 15 1 1 5 bull125

ENTER ENTER ENTER Totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hft ha he

(cm) (cm) (cm)

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estirnate OR permeability | soil vapor

permeability) k v bull

(cm)

SL 1 1

MORE ENTER

stratum A SCS

soil type

Lookup Soil Parameters

ENTER stratum A soil dry

bulk density P

(gcm)

ENTER Stratum A soil total porosity

(unitless)

ENTER bull stratum A soil water-filled

porosity

(cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

nlaquo

(unitless)

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gchi-s^)

ENTER Enclosed

space floor

length bull LB

(cm)

ENTER Enclosed

space floor

width WB

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

bull Floor-wall seam crack

width w

(cm)

bullENTER

Indoor air exchange

rate ER

(1h) bull

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bidg OR

Leave blank to caicuij

(Lm)

Appx B-1 124-TMBxls 1 of 3 982009

AR100308

APPENDIX B-1-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of ^ bull law constant law constant vaporization at Normal

Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temperature boiling point point temperature weight

D bull Dbdquo H T R bull AHbdquo TB Tc IVIW

Unit risk Reference

factor cone URF RfC

(cms) (cmls) (atm-mmol) CO (calmol) (degK) (degK) (gmol) bull (ugm)- (mgm)

1 606E-02 1 792E-06 1 bull 614E-C3 1 25 1 9369 1 44230 | 64917 1 12020 1 OOE+00 1 60E-03 1

Appx B-1 124-TMBxls 2 of 3 982009

AR100309

APPENDIX B-1-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

(sec)

Source-building

separation

LT bull

(cm) bull

Stratum A soil

air-filled porosity

Q A

Stratum B soil

air-filled porosity

(cmcm) (cmcm)

Stratum C soil air-filled porosity

(cmcm)

Stratum A effective total fluid

saturation

Se

(cmcm)

Stratum A soil

bullintrinsic permeability

^ (cm)

stratum A Stratum A Floor- soil soli wall BIdg

relative air effective vapor seam Soil bull ventilation permeability permeability perimeter gas rate-

kfg ky Xgrack c o n e - QbuHdinpound

(cm) - (cm) (cm) (ngm) (cms)

946E+08 1 0284 0284 0284 0184 596E-09 0901 537E-09 35357 I 197E+02 | 439E+06 |

Area of enclosed

space below grade

As (cm)

Crack-to-total area ratio

1 bull

(unitless)

Crack depth

below grade

Zcfack

(cm)

Enthalpy of vaporization at

ave soil temperature

AHvjs

(calmol) bull

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law constant at

ave soil bull temperature

bull HTS

(unitless)

Vapor bull viscosity at

ave soil temperature

HTS

(gcm-s)

Stratum A

effective diffusion

coefficient

D (cms)

Stratum-B

effective diffusion coefficient

DB (cms)

Stratum C effective diffusion

coefficient

D-c (cms)

Total - overall effective diffusion

coefficient

D ^ (cms)

Diffusion path

length

L-

(cm)

I 787E+07 I 449E-05 | 15 | 11661 260E-03 111E-01 176E-04 I 612E-03 j OOOE+00 | OOOE+00 | 612E-03 j

bull Convection path

length

Lp

(cm)

Source vapor cone

^source

(ngm)

Crack radius

Tcfack

(cm)

Average vapor

flow rate into bIdg

Qsoii

(cms)

Crack effective diffusion

coefficient pcrack

(cms)

Area of CTack

Acack

(cm)

Exponent of equivalent foundation

Peclet number

exp(Pe)

(unitless)

bull bull - bull bull bull bull

1 15 1 197E+02 1 010 1 474E+01 612E-03 bull 354E-t-03 1 336E+09

Infinite source Indoor

~ attenuation coefficient

a

(unitless)

108E-05

Infinite source

btJbldgjJSv-L ^Ppncji3i-

virhpbiiilding bullbull ^lHltti^m)ilg

213E-03

Unit risk

factor

URF

(ngm)-

Reference cone

RfC (mgm)

NA 60E-03 1

I END

Appx B-1 124-TMBxls 3 of 3 982009

AR100310

APPENDIX B-2-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV Nersion31 020^

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

156592

Soil Gas Concentration Data ENTER

Soil gas

cone OR c

(ngm) bull

ENTER Soil bull-gas

cone

c (ppmv)

603E+03 1

Chemical

cis-12-Dichloroethylene

MORE ENTER Depth

below grade to bottom

of enclosed space floor

LF

(cm)

ENTER

Soil gas sampling

depth below grade

U (cm)

ENTER

Average soil

temperature bull Ts

(degC)

1 15 1 bull 15 125

ENTER ENTER ENTER Totalsmust add ijp tb value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hA hB he

bull (cm) (cm) (cm)

15 1 1

ENTER Soil

straturh A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estimate OR permeability | soil vapor

permeability) kv

(cm)

SL 1 |

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

P (gcm)

ENTER Stratum A soil total porosity

bull n

(unitless)

ENTER Stratum A

soil water-filled porosity

(cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

ENTER Stratum B

soil water-filled porosity

ENTER Stratum C

SCS soil type

(unitless) (cmcm)

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure differential

AP

(gcm-s)

ENTER Enclosed bull

space floor

length

LB (cm)

ENTER Enclosed

space floor

width WB

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER

Average vapor flow rate into bIdg

OR Leave blank to calculi

Qsoil

(Lm)

Appx B-2 cis-12-DCExls 1 of 3 982009

AR100311

APPENDIX B-2-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Diffusivity in air

Da

(cms)

Diffusivity in water

Dw (cms)

Henrys law constant at reference temperature

H

(atm-mmoi)

Henrys law constant

reference temperature

bull T R

CC)

Enthalpy of vaporization at

the normal boiling point

AHbdquob

(calmol)

Normal boiling point

TB

(degK)

Critical temperature

Tc (degK)

Molecular weight

MW

(gmol)

Unit risk

factor URF

(ngm)

Reference cone

RfC (mgm)

1 736E-02 1 113E-05 1 407E-03 j 1 25 1 bull 7192 1 33365 1 54400 1 9694 1 OOE+00 j 35E-02 1

Appx B-2 cis-12-DCExls 2 of 3 982009

AR100312

APPENDIX B-2-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

stratum A Stratum B Stratum C Source- soil soil soil

Exposure building air-filled air-filled air-filled

duration separation porosity porosity porosity

T LT ea e^ bull e= (sec) (cm) (cmcm) (cmcm) (cmcm)

I 946E+08n^

Stratum A Stratum A Stratum A Stratum A Floor-effective soil soil soil wall total fluid intrinsic relative air effective vapor seam

saturation permeability permeability permeability perimeter

Ste kj krg ky Acrack

(cmcm) (cm) (cm) (cm) (cm)

Soil gas

cone (ngm)

I 0284 I 0284~ 0284 0184 I 596E-09 | 090T 537E-09 35357 603E+03

BIdg ventilation

rate

JbulldinE

(cms)

439E+06

Area of enclosed

space below grade

AB

(cm)

Crack-to-total

area ratio

n (unitless)

Crack depth below grade

Zltiack (cm)

Erithalpy of vaporization at

ave soil temperature

AHvTs (calmol)

Henryslaw constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law constant at

ave soil temperature

HTS

(unitless) bull

Vapor viscosity at

ave soil bull temperature

HTS

bull (gcm-s)

Stratum A

effective bull diffusion

coefficient

D^A-(cms)

Stratum B

effective bull diffusion

coefficient

D=B

(cms)

Stratum C

effective diffusion bull

coefficient

D=e (cms)

Total overall

effective diffusion

coefficient

DT

(cms)

Diffusion path

length

Ld

(cm)

I 787E+07 I bull449E-05 | 15 bull7709 230E-03 982E-02 176E-04 | 743E-03 | OOOE+00 | OOOE+00 | 743E-03 |

bull bull bull -

Convecfion path -bull

length

Lp (cm)

Source vapor cone

-source

(Mgm)

Crack radius

fcrack

(cm)

Average vapor

flow rate into bIdg

Qaoil bull

(cms)

Crack effective diffusion

coefficient pcack

(cms)

Area of crack

crack

(cm)-

Exponent of equivalent foundation

Peclet number

exp(Pef)

(unitless)

bull

1 15 -1 603E+03 1 010 1 474E+01 743E-03 354E+03 1 697E+07

Infinite source Indoor

attenuation coefficient

poundbullbullbull C t

pound(unitless)

bullsiilaquogt j ii08E-05

Infinite [ source

bIdg cone

Cbujidjng

(pgm)

651 E-02 iKrt

Unit risk

factor

URF

(ngm)-

Reference cone

RfC

(mgm)

NA 35E-02 1

I END I

Appx B-2 cis-12-DCExls 3o f3 982009

AR100313

APPENDIX B-3-A DATA ENTRY SHEET

Coyne Texti le Services - Hunt ington West Virginia

SG-ADV Version 31 0204

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

67663

Soil Gas Concentration Data ENTER ENTER

Soil Soil gas gas

cone OR cone c C

(^gm) (ppmv)

591 E+03

bull

Chemical

Chloroform

MORE ENTER Depth

below grade tb bottom

of enclosed space floor

bull LF

(cm)

ENTER

Soil gas sampling depth

below grade

(cm)

ENTER

Average soil

temperature-Ts

CO bull

1 15 1 15 1 125

ENTER ENTER ENTER Totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

IIA hs he (cm) (cm) (cm)

1 5 bull 1 1

ENTER ENTER Soil - bull

stratum A User-defined SCS stratum A

soil type bull soil vapor (used to estimate OR permeability

soil vapor k

bull permeability) (cm) 1

SL 1 1 bull

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A soil dry

bulk density

Pb (gcm)

ENTER Stratum A soil total porosity

nV (unitless)

ENTER Stratum A

-soilwater-filled bullporosity

Sraquo (cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

(unitless)

ENTER Stratum B

soil water-filled porosity

bull ebdquo=

(cmcm) bull

ENTER Straturri C

SCS bull soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

- c rack

(cm)

ENTER

Soil-bldg pressure

differential AP^

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor

width bull W B

(cm)

ENTER

Enclosed space

height HB

(cm)

ENTER

bull Floor-wall^ seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bidg OR

Leave blank to calculi

Qsoil bull

(Lm)

I -I

Appx B-3 Chloroformxls 1 of 3 982009

AR100314

APPENDIX B-3-B CHEMICALPROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Diffusivity in air

D (cms)

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffijsivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature

Dbdquo H TR A H bdquo TB Tc

(cm s) (atm-m mol) ro (calmol) (degK) (degK)

Molecular weight

MW

(gmol)

Unit risk

factor URF

(ngm)-

Reference cone

RfC

(mgm)

104E-01 100E-05 I 366E-03 25 6988 33432 53640 11938 I 23E-05 | OOE+00

Appx B-3 Chloroformxls 2 of 3 982009

AR100315

APPENDIX B-3-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure

duration

(sec)

Source-

building

separation

LT

(cm)

Stratum A

soil

air-filled

porosity

Sa

( cm cm )

Stratum B

soil

air-filled

porosity

( cm cm )

Stratum C

soil

air-filled

porosity

( c m c m )

Stratum A

effective

total fluid

saturation

( c m c m )

Stratum A

soil

intrinsic

penmeability

k

(cm )

Stratum A

- soil

relative air

permeabil i ty

(cm )

Stratum A

soil

effective vapor

permeability

kv

(cm )

Floor-

wall

seam

perimeter

gtcrack

(cm)

Soil gas

cone

(ngm)

BIdg

venfilation

rate

^buildlriE

(cms)

I 9 4 6 E + 0 8 ~ T I 0284 T 596E-09 I 0-901 I 537E-09 | 35357 | 591 E+03 j 439E+06 | 1 0 284 0284 0184

Area of

enclosed

space

below

grade

A B

( c m )

Crack-

to-total

area

ratio

n

(unitless)

Crack

depth

bull below

grade

^crack

(cm)

Enthalpy of

vaporization at

ave soil

temperature

AHTs bull

(calmol)

Henry s law

constant at

ave soil

temperature

HTS

(a tm-m mol j

Henrys law

constant at

ave soil

bull temperature

HTS

(unitless) bull

Vapor

viscosity at

ave soil-

temperature

^HTS

(gcm-s)

Stratum

A

effective

diffusion

coefficient

(cm s)

Stratum

B

effective

difftjsion

coefficient

D B

(cms) bull

S t ra tum

C

effective

diffusion

coefficient

Dc

(cm s)

Total

overall

effective

bull diffusion

coefficient

D T

(cm s)

Diffi jsion

path

length

Ld

(cm)

I 787E+07 I 449E-05 j - bull 15 7528 210E-03 896E-02 176E-04 I 105E-02 | OOOE+00 | OOOE+00 | 105E-02

Convection

path length

Lp

(cm)

Source

vapor

cone -

^source

- (ngm)

Crack

radius

Tcrack

(cm)

Average

vapor

flow rate

into bidg

Qsoil

(cms)

Crack

effective

diffusion

coefficient Qcrack

bull (cms)

Area of crack

Acrack

(cm)

Exponent of

equivalent

foundation

Peclet number

exp(Pe)

(unitless)

V bull bull

1 15 1 591 E+03 1 010 1 474E+01 105E-02 354E+03 1 355E+05

Infinite

source

indoor

attenuation

coefficient

d

(unitless)

bull 108E-05

Infinite

source

bIdg

cone

^ b u i l d i n g

i (^gm)

bull bull

i 638E-02 -

Unit

risk bull factor

URF

(ngmY

Reference

cone

RfC

(mgm)

~ 23E-05 NA 1

I END

Appx B-3 Chloroform xls 3 of 3 982009

AR100316

APPENDIX B-4-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ersion 31-020^

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

nodashes)

bull 75092

ENTER Soil gas

cone

c (ngm)

Soil Gas Concentration Data ENTER

Soil gas bull

OR cone

bull C

(ppmv)

152E+03

bull bull

Chemical

Methylene chloride

MORE

MORE 4gt

ENTER Depth

below grade to bottom

of enclosed space floor

LF -

(cm)

ENTER

Soil gas sampling depth

below grade

bull U

(cm)

ENTER

Average soil

temperature

Ts bull CC)

bull bull bull bull

1 15 1 15 125

ENTER Totals

Thickness of soil

stratum A h

(cm)

ENTER ENTER must add up to value of Ls (cell F24

Thickness Thickness of soil of soil

stratum B stratum C (Enter value or 0) (Enter value or 0)

he he bull

(cm) bull (cm) -

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(usedto estimate OR perrrieability | soil vapor

permeability)

k bull

(cm)

SL 1 bull 1

ENTER Stratum A

SCS soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

Pb (gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Stratum A

soil water-filled porosity

9w (cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

Pb^

(gcm)

ENTER Stratum B soil total porosity

n^

(unitless)

ENTER Stratum B

soil water-filled porosity

(crhcm)

ENTER Stratum C

SCS soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE 4gt

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

bull Soil-bldg pressure

differential AP^

(gcm-s)

ENTER Enclosed

space floor

length LB

(cm)

ENTER Enclosed

space floor

width bull W B

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width

w

(cm)

ENTER

Indoor air exchange

rate

ER (1h)

ENTER Average vapor

flow rate into bidg OR

Leave blank to calculc

Qsoil

(Lm)

10 40 8839 8839 244 01 083

Appx B-4 MCxIs 1 of 3 982009

AR100317

Diffijsivity in air

D

APPENDIX B-4-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffusivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature

Pw H TR AHt TB TC

Molecular weight

MW

Unit risk

factor URF

Reference cone

RfC

(cms) (cms) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) bull (ngm)- (mgm)

bull bull

1 101E-01 1 117E-05 1 218E-03 1 25 | 6706 1 31300 1 51000 1 8493 1 47E-07 1 30E+00 1

Appx B-4 MCxIs 2 of 3 982009

AR100318

APPENDIX B-4-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

T

(sec)

Source- -building

separation

LT

(cm)

Stratum A soil

air-filled porosity

e a bull

(cmcm)

Stratum B soil

bullair-filled porosity bull

ea^ (cmcm)

Stratum C soil

air-filled porosity

ea= (cmcmj

Stratum A effective total fluid

saturation

Sc bull

(cmcm)

Stratum A soil

intrinsic pemneability

ki (cm)

Stratum A soil

relative air permeability

^ ^ g

(cm)

stratumA bull soil effective vapor permeability

K (cm)

Floor-wall

seam perimeter

Xcrack

(cm)

Soil gas

cone (ngm)

BIdg ventilation

rate

Qbuildinc

(cms)

1 946E+08

Area of -enclosed

space below

bull grade

AB

(cm)

1

Crack-to-total

area rafio

Tl

(unitless)

0284 1

Crack depth below grade

Zcrack

(cm)

0284 1

bull Enthalpy of vaporization at

ave soil temperature

AHTs (calmol)

0284

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

0184

Henrys law constant at ave soil

temperature

HTS

bull (unitless)

1 596E-09

Vapor viscosity at

ave soil temperature

Mrs (gcm-s)

0901

Stratum A

effective diffusion

coefficient

D (cms)

537E-09

Stratum B

effective diffusion

coefficient

D-B (cms)

35357 1

Stratum C -

effective diffusion

coefficient

D-c ^ (cms)

152E+03

Total bull overall

bull effective diffusion

coefficient

D ^

(cms)

440E+06 1

Difftjsion path

length

Ld (cm)

1 787E+07

Convection path

length

Lp (cm)

4 49E-05

Source vapor cone

Csource

(ngm)

15 1

Crack radius

Tcrack

(cm)

7007 bull 1

Average vapor

flow rate intobldg

Qsoil

(cms)

130E-03

Crack effective diffusion

coefficient pcrack

(cms)-

555E-02

bull ^

Area of crack

Acrack

(cm) bull

1 176E-04

Exponent of equivalent foundation

Peclet number

exp(Pe)

(unitless) bull

bull bull

1 15

1 END

152E+03 010 1 474E+01 1 102E-02 354E+03 1 519E+05

102E-02

Infinite source

indoor ^attenuation coefficient

bull a

(unitless)

aiii08E-05

0 OOE+00

bull

Infinite bull source

bIdg ^ cone

^bu i l d i ng

(MQm)

164E-02

OOOE+00 1

Unit risk

factor

URF

(ngm)-

47E-07 1

102E-02 j

Reference cone

RfC

(mgm)

30E+00 j

1 1

Appx B-4 MCxIs 3 of 3 982009

AR100319

APPENDIX B-5-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ^erslon 31 0204

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

127184

Soil Gas Concentration Data ENTER ^ ENTER

Soil -Soi l bull gas gas

cone OR cone Cg C bull

(tgm) (ppmv)

149E+05 1

Chemical

bull Tetrachlbroethylene

MORE 4

ENTER Depth

below grade to bottom

ofenclosecJ space floor

LF

(cm)

ENTER

Soil gas bull sampling

depth below grade

u bull (cm)

ENTER

Average bullsoil

temperature - Ts

ro 1 1 5 1 15 1 125 bull

ENTER ENTER ENTER totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hft bull he bull he

(cm) (cm) (cm)

bull 1 5 1 - 1

ENTER ENTER Soil

stratum A User^defined bull SCS bull stratum A soil type soil vapor

(used to estimate OR perrrieability soil vapor K bull

permeability) (cm) 1

SL 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

Pb

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Sitratum A

soil water-filled bull porosity

(cmcm)

ENTER Stratum B

SCS soiltype

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

Pb^

(gcm)

ENTER Stratum B soil total porosity

Ajnitless^

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS soil type

LookupSoil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

VS

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor width

W B

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width

w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

ENTER Average vapor

flow rate into bidg OR

Leave blank to calcul

bull Qsoil

(Lm)

10 40 8839 8839 244 01 083

Appx B-5 PCExIS 1 of 3 982009

AR100320

APPENDIX B-5-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal Unit

Diffusivity Diffusivity at reference reference the riormal boiling Critical Molecular risk Reference in air in water temperature temperature boiling point point teriiperature weight factor cone

Da Dbdquo H TR AHb TB Tc MW URF RfC

(cms) (cnis) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) (^gm)- (mgm)

1 720E-02 1 820E-06 1 184E-02 1 25 1 8288 1 39440 1 62020 1 16583 1 59E-06 1 60E-01 1

J

AppxB-5PCExls 2 of 3 - 982009

AR100321

APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

T

(sec)

Source-building

separation

LT

bull (cm)

Stratum A soil

air-filled porosity

Oa (cmcm)

Stratum B - soil air-filled porosity

ea (cmcm)

Stratum C soil

air-filled porosity

ea= - (cmcm)

Stratum A effective total fluid

saturation

sbdquo (cmcm)

Stratum A soil

intrinsic permeability

ki (cm)

Stratum A soil

relative air permeability

- ^ g

(cm)

Stratum A soil

effective vapor permeability

kv (cm)

Floor-wall

seam perimeter

^crack

(cm)

Soil gas

cone

(ngm)

BIdg venfilation

rate

Qbuildins

bull (cms)

bull bull

1 946E+08

Area of enclosed

space below grade

AB

(cm)

1

bullCrack-to-total

area ratio

1 (unitless)

0284 1

Crack bull depth below grade

Zcrack

(cm) -

0284 1

Enthalpy of vaporization at bull

ave soil temperature

bull A H V TS

(calmol)

0284

Henrys law constant at

ave soil temperature

HTS (atm-mmol)

0184

-Henrys law constant at

ave soil temperature

HTS

(unitless)

1 596E-09

Vapor viscosity at

ave soil temperature

HTS

(gcm-s)

0901

Stratum A

effective diffusion

coefficient bull D = bull

(cms)

537E-09

Stratum B

effective diffusion

coefficient

D--B (cms)

35357 1

Stratum C

effective diffusion bull

coefficient

D-c (crris)

149E+05

Total overall

effective bulldiffusion coefficient

DT

(cms)

440E+06 1

Difftjsion path

length

U (cm)

1 787E+07

Convection path

length

bull Lp

(cm)

4 49E-05

Source vapor cone

^source

(ngm)

15 1

Crack radius

Tcrack

(cm)

9528 1

Average vapor

flow rate intobldg

Qsoil (cms)

908E-03

Crack effective diffusion

coefficient pcrack

bull ( c m s ) bull

387E-01

Area of crack

Abdquoack (cm)

1 176E-04

Exponent of equivalent foundafion

Peclet number

exp(Pe)

(unitless)

bull

1 15-

1 END

149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08

727E-03

Infinite source indoor

attenuation coefficient

a

(unitless)

108E-05

OOOE+00

Infinite source

bIdg cone

Cburldtng

(Mgm)

161 E+00

OOOE+00 1

Unit risk

factor

URF

(ugm)-

59E-06 1

727E-03

Reference cone

RfC (mgm)

60E-01

1 1

Appx B-5 PCExls 3 of 3 982009

AR100322

APPENDIX B-6-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ersion31 0204

Reset to Defaults

t

Soil Gas Concentration Data ENTER

Chemical CAS No

(numbers only

no dashes)

79016

ENTER ENTER Soil Soil gas gas

cone OR cone C C -

bull (ngm) (ppmv)

782E+03

Chemical

Trichloroethylene

MORE ENTER Depth

below grade to bottom-

of enclosed space floor

LF

(cm)

ENTER

Soil gas sarnpling

depth below grade

U (cm)

ENTER

Average soil

temperature Ts

(degC)

1 15 1 15 t 125

ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e

(cm) (cm) (cm)

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estimate OR permeability soil vapor

permeability)

k (cm)

bull S L 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil bull-Parameters

ENTER Stratum A

soil dry bulk density

P b -

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Stratum A bull

soilwaterrfilled porosity

(cmcm) bull

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

bull P ^ (gcm)

ENTER Stratum B soil total

porosity

nlaquo

(unitless) -

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS bull soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor

width W B

(cm)

ENTER

Enclosed space height

H B bull

( c m ) bull

ENTER

Floor-wall seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bIdg OR

Leave blank to calculc

Qsoil

(Lm) -

Appx B-6 TCExIs 1 of 3 982009

A

AR100323

APPENDIX B-6-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight

Da Dbdquo H TR AH^b TB TC MW

Unit risk Reference

factor cone URF RfC

(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)

1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1

Appx B-6 TCExIs 2 of 3 982009

AR100324

APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

(sec)

Source-building

separation LT

(cm)

Stratum A soil

air-filled porosity

bull ea (cmcm)

Stratum B Soil

air-fllled porosity

e^ bull (cmcm)

Stratum C soil

air-filled porosity

(cmcm)

StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air

saturation permeability permeability

S|e k krg (cmcm) (cm) (cm)

Stratum A Floor-soil wall BIdg

effective vapor seam Soil ventilafion permeability perimeter gas rate

k^ bull Xack c o n e Qbuildins

(cm) (cm) (ngm) (cms)

946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |

Area of enclosed

space below grade

AB

(cm)

Ciack- to-total

area ratio

1 (unitless)

Crack depth below grade

Zcrack

(cm)

Enthalpy of vaporization at

ave soil temperature

A H J S

(calmol)

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law bull constant at

ave soil temperature

HTS

(unitless)

Vapor viscosity at

ave soil temperature

|JTS

(gcm^s)

Stratum A

effective diffusion

coefficient

(cms)

Stratum B

effective -diffusion

coefficient

D=B (cms)

Stratum ^ C effective diffusion

coefficient

D=c (cms)

Total overall

effective diffusion

coefficient

DT

(cms)

I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03

Diffusion path

length

Li (cm) bull

Convection bull path

length

Lp

(cm)

Source vapor cone bull

^source

(ngm)

Crack radius

rcrack

(cm)

Average vapor

- flow rate intobldg

Qsoil

(cms)

Crack effective diffusion

bull coefficient Qcrack

(cms)

Area of crack

^crack

(cm)

Exponent of equivalent foundation

Peclet bull number

exp(Pe)

(unitless)

bull bull

1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07

Infinite source Indoor

attenuation coefficient

a

(unitless)

108E-05

Infinite source

bIdg concgt

^building

(ngm)

844E-02

Unit risk

factor

URF

(ngm)-

Reference cone

RfC

(mgm)

1 1E-04 1 40E-02 1

END

Appx B-6 TCExIs 3 of 3 982009

AR100325

Office of Waste Management 1356 Hansford Street

Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256

West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director

ORDER

ISSUED UNDER THE

HAZARDOUS WASTE MANAGEMENT ACT

CHAPTER 22 ARTICLE 18

OF THE WEST VIRGINIA CODE^ AS AMENDED

y Order Number HW-011-80

To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704

ATTEMTION MREDARMON

Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull

AR100326

ViWJ011-laquo9 PageNunil)er2

BASIS FOR ORDER

As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following

A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^

B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator

C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities

0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94

^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement

P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following

1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater

2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was

^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment

CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable

CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order

AR100327

H W - 0 1 1 - 9 9 Page Number 3

REQUIREMENTS OF ORDER

Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows

1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^

2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore

remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling

GENERAL PROVaiONS

1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order

2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order

3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order

Effective Date

Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief

Wt T 1 V Oflice of Waste Management

AR100328

^ ^ S I S

^wmmmmamn

AR100329

Page 28: SDMS DocID 2121999 · International Enterprises Corp. building (Coyne Building), which is located at 1111 Vernon Street, Westmoreland District, Wayne County, West Virginia. The following

APPENDIX B

Calculation of Transport Factors Used to Estimate Indoor Air Concentrations

This appendix presents the methodology for calculating transport factors that are used to convert subslab

vapor concentrations to concentrations in indoor air 124-Trimethylbenzene 12-dichloroethene (cis)

chloroform methylene chloride tetrachloroethene and triehloroethene were identified as contaminants of

concern (COC) for potential vapor intrusion from subslab vapor associated with the Coyne Textile

Services Facility located in Huntington West Virginia (site) In this appendix the transport factors are

calculated to estimate the concentrations of COC in indoor air of the existing plant building located at the

site ~

Transport Factor for Indoor Air

The concentration of a constituent in indoor air (da) is proportional to the concentration of the constituent

in the subslab vapors immediately beneath the building foundation (ie subslab vapor concentration or

Csubsiab) The following equation is used to calculate da from Csubsiab

^ wja ~ ^subslab X I r

where

Cia = concentration of constituent in indoor air (mgm^) -

Csubsiab^ concentration of constituent in subslab vapors (mgm^) and

TF = transport factor from subslab vapors to indoor air

The transport factor (TF) is an infinite source attenuation coefficient andcan be calculated based on a

model developed by Johnson and Ettinger (1991) t he equation for calculating TF is as follows

(Deff X A B ) ( Q B X L T ) X expKQso i l X Lcrabk)(Dcrack X Acrack)]

exp[ (Qsoi l X Lcrack)(Dcrack X Acrack)] + (Deff X A B ) ( Q B X L T ) + (Deff X AB)(Qsoi l X L j ) X (exp [ (Qso i l X Lcrack)(Dcrack X Acrack)] - 1)

where

Deff = effective diffusion coefficient for vadose zone soil (cm^sec)

AB = area of enclosed space below grade (cm^)

QB = building ventilation rate (cm^sec)

LT = distance from contaminant source to building foundation (cm)

Qsoii = volumetric flow rate of vapors into the building (cm^sec)

Lcrack = foundatlon thickness (cm)

Dcrack = vapor diffusion coefficient through crack (cm^sec) and

Acrack = area of cracks through which vapors can pass (cm^)

AR100305

To solve this equation the USEPAs SG-ADV spreadsheet Version 31 most recently updated in

February 2004 was implemented A combination of site-specific factors and default values from the

Users Guide for Evaluating Subsurface Vapor Intrusion Into Buildings (USEPA 2004) were used as input

values in the model All input values are defined below and presented in Tables B-1-A through B-6-A

bull The initial subslab vapor concentration (Csubsiab) is the maximum detected concentration(in units

of ugm ) of samples VP-01 VP-02 and VP-03 that was presented in Table 3 of the report

bull The depth below grade to the bottom of the enclosed space floor (Lp) is set to 15 cm the default

value provided by USEPA (2004) for a slab-on-grade structure

bull The vapor sampling depth below grade (Lg) is a site-specific value The vapor samples were

collected from immediately beneath the building floor therefore Lj has been set to 15 cm

bull The average soilgroundwater temperature (Ts) is set to 125degC the average value for West

Virginia as estimated frorri Figure 8 of the vapor intrusion users guide (USEPA 2004)

bull The soil type used to estimate vapor permeability is assumed to be sandy loam (SL) The

associated soil properties for a sandy loam soil type are as follows the soil dry bulk density (Pb) is

162 gcm the total porosity (n) is 0387 (cm^-aircm^) and the water-filled porosity (nw) is 0103

(cm -HzOcm )

bull The floor thickness (Lcrack) is set to the USEPA (2004) default value of 10 cm

bull The soil-building pressure differential (AP) is set to the USEPA (2004) default value of 40 gcm-s^

bull The building dimensions are siterspecific based on the existing plant building located at the site

The existing structure is approximately 84000 square feet (Dolphin 2000) therefore the

dimensions are set to 8839 cm (290 feet) length by 8839 cm (290 feet) The USEPA (2004)

default value of 244 cm vyas used for the height

bull Thefloor-wall seam crack width (w) is set to the USEPA (2004)-default value of 01 cm

bull The indoor air exchange rate (ER) is set to 083hour This is the value provided by ASTM (2002)

for commercial and industrial buildings

AR100306

Tables B-1-B through B-6-B present the constituent-specific properties for COC that were used in the TF

calculations Tables B-1-C through B-6-C present the intermediate calculations used to determine the

indoor air attenuation coefficients (ie the transport factors) The shaded boxes in Tables B-1-C through

B-6-C also present the resulting TF values that are applied to the concentrations of COC in subslab

vapor and the estimated indoor air concentrations

References

American Society for Testing and Materials (ASTM 2002) Standard Guide for Risk-Based Corrective Action Applied at Petroleum Release Sites ASTM E-1739-95 (Reapproved 2002)

Johnson PC and RA Ettinger (1991) Heuristic model for predicting the intrusion r-ate of contaminant vapors into buildings Environ Sci Technolpgy 25 1445-1452

Dolphin Environmental LLC (Dolphin 2000) Site Characterization Report Mach 14 2000

United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004

AR100307

APPENDIX B-1-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV Nersion31 0204

Reset to Defaults

ENTER -

Chemical CAS No

(numbers only

no dasties)

95636

ENTER Soil gas

cone

Cg (ngm)

Soil Gas Concentration Data ENTER

Soil gas

OR cone

bull - c bull (PPmv)

197E+02

Chemical

124-Trimethylbenzene

MORE ENTER Depth

below grade to bottom

of enclosed space floor

U bull (cm)

ENTER

Soil gas sampling

depth below grade

U (cm) bull

ENTER

Average soil

temperature Ts

CO

1 15 1 1 5 bull125

ENTER ENTER ENTER Totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hft ha he

(cm) (cm) (cm)

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estirnate OR permeability | soil vapor

permeability) k v bull

(cm)

SL 1 1

MORE ENTER

stratum A SCS

soil type

Lookup Soil Parameters

ENTER stratum A soil dry

bulk density P

(gcm)

ENTER Stratum A soil total porosity

(unitless)

ENTER bull stratum A soil water-filled

porosity

(cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

nlaquo

(unitless)

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gchi-s^)

ENTER Enclosed

space floor

length bull LB

(cm)

ENTER Enclosed

space floor

width WB

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

bull Floor-wall seam crack

width w

(cm)

bullENTER

Indoor air exchange

rate ER

(1h) bull

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bidg OR

Leave blank to caicuij

(Lm)

Appx B-1 124-TMBxls 1 of 3 982009

AR100308

APPENDIX B-1-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of ^ bull law constant law constant vaporization at Normal

Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temperature boiling point point temperature weight

D bull Dbdquo H T R bull AHbdquo TB Tc IVIW

Unit risk Reference

factor cone URF RfC

(cms) (cmls) (atm-mmol) CO (calmol) (degK) (degK) (gmol) bull (ugm)- (mgm)

1 606E-02 1 792E-06 1 bull 614E-C3 1 25 1 9369 1 44230 | 64917 1 12020 1 OOE+00 1 60E-03 1

Appx B-1 124-TMBxls 2 of 3 982009

AR100309

APPENDIX B-1-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

(sec)

Source-building

separation

LT bull

(cm) bull

Stratum A soil

air-filled porosity

Q A

Stratum B soil

air-filled porosity

(cmcm) (cmcm)

Stratum C soil air-filled porosity

(cmcm)

Stratum A effective total fluid

saturation

Se

(cmcm)

Stratum A soil

bullintrinsic permeability

^ (cm)

stratum A Stratum A Floor- soil soli wall BIdg

relative air effective vapor seam Soil bull ventilation permeability permeability perimeter gas rate-

kfg ky Xgrack c o n e - QbuHdinpound

(cm) - (cm) (cm) (ngm) (cms)

946E+08 1 0284 0284 0284 0184 596E-09 0901 537E-09 35357 I 197E+02 | 439E+06 |

Area of enclosed

space below grade

As (cm)

Crack-to-total area ratio

1 bull

(unitless)

Crack depth

below grade

Zcfack

(cm)

Enthalpy of vaporization at

ave soil temperature

AHvjs

(calmol) bull

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law constant at

ave soil bull temperature

bull HTS

(unitless)

Vapor bull viscosity at

ave soil temperature

HTS

(gcm-s)

Stratum A

effective diffusion

coefficient

D (cms)

Stratum-B

effective diffusion coefficient

DB (cms)

Stratum C effective diffusion

coefficient

D-c (cms)

Total - overall effective diffusion

coefficient

D ^ (cms)

Diffusion path

length

L-

(cm)

I 787E+07 I 449E-05 | 15 | 11661 260E-03 111E-01 176E-04 I 612E-03 j OOOE+00 | OOOE+00 | 612E-03 j

bull Convection path

length

Lp

(cm)

Source vapor cone

^source

(ngm)

Crack radius

Tcfack

(cm)

Average vapor

flow rate into bIdg

Qsoii

(cms)

Crack effective diffusion

coefficient pcrack

(cms)

Area of CTack

Acack

(cm)

Exponent of equivalent foundation

Peclet number

exp(Pe)

(unitless)

bull bull - bull bull bull bull

1 15 1 197E+02 1 010 1 474E+01 612E-03 bull 354E-t-03 1 336E+09

Infinite source Indoor

~ attenuation coefficient

a

(unitless)

108E-05

Infinite source

btJbldgjJSv-L ^Ppncji3i-

virhpbiiilding bullbull ^lHltti^m)ilg

213E-03

Unit risk

factor

URF

(ngm)-

Reference cone

RfC (mgm)

NA 60E-03 1

I END

Appx B-1 124-TMBxls 3 of 3 982009

AR100310

APPENDIX B-2-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV Nersion31 020^

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

156592

Soil Gas Concentration Data ENTER

Soil gas

cone OR c

(ngm) bull

ENTER Soil bull-gas

cone

c (ppmv)

603E+03 1

Chemical

cis-12-Dichloroethylene

MORE ENTER Depth

below grade to bottom

of enclosed space floor

LF

(cm)

ENTER

Soil gas sampling

depth below grade

U (cm)

ENTER

Average soil

temperature bull Ts

(degC)

1 15 1 bull 15 125

ENTER ENTER ENTER Totalsmust add ijp tb value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hA hB he

bull (cm) (cm) (cm)

15 1 1

ENTER Soil

straturh A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estimate OR permeability | soil vapor

permeability) kv

(cm)

SL 1 |

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

P (gcm)

ENTER Stratum A soil total porosity

bull n

(unitless)

ENTER Stratum A

soil water-filled porosity

(cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

ENTER Stratum B

soil water-filled porosity

ENTER Stratum C

SCS soil type

(unitless) (cmcm)

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure differential

AP

(gcm-s)

ENTER Enclosed bull

space floor

length

LB (cm)

ENTER Enclosed

space floor

width WB

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER

Average vapor flow rate into bIdg

OR Leave blank to calculi

Qsoil

(Lm)

Appx B-2 cis-12-DCExls 1 of 3 982009

AR100311

APPENDIX B-2-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Diffusivity in air

Da

(cms)

Diffusivity in water

Dw (cms)

Henrys law constant at reference temperature

H

(atm-mmoi)

Henrys law constant

reference temperature

bull T R

CC)

Enthalpy of vaporization at

the normal boiling point

AHbdquob

(calmol)

Normal boiling point

TB

(degK)

Critical temperature

Tc (degK)

Molecular weight

MW

(gmol)

Unit risk

factor URF

(ngm)

Reference cone

RfC (mgm)

1 736E-02 1 113E-05 1 407E-03 j 1 25 1 bull 7192 1 33365 1 54400 1 9694 1 OOE+00 j 35E-02 1

Appx B-2 cis-12-DCExls 2 of 3 982009

AR100312

APPENDIX B-2-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

stratum A Stratum B Stratum C Source- soil soil soil

Exposure building air-filled air-filled air-filled

duration separation porosity porosity porosity

T LT ea e^ bull e= (sec) (cm) (cmcm) (cmcm) (cmcm)

I 946E+08n^

Stratum A Stratum A Stratum A Stratum A Floor-effective soil soil soil wall total fluid intrinsic relative air effective vapor seam

saturation permeability permeability permeability perimeter

Ste kj krg ky Acrack

(cmcm) (cm) (cm) (cm) (cm)

Soil gas

cone (ngm)

I 0284 I 0284~ 0284 0184 I 596E-09 | 090T 537E-09 35357 603E+03

BIdg ventilation

rate

JbulldinE

(cms)

439E+06

Area of enclosed

space below grade

AB

(cm)

Crack-to-total

area ratio

n (unitless)

Crack depth below grade

Zltiack (cm)

Erithalpy of vaporization at

ave soil temperature

AHvTs (calmol)

Henryslaw constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law constant at

ave soil temperature

HTS

(unitless) bull

Vapor viscosity at

ave soil bull temperature

HTS

bull (gcm-s)

Stratum A

effective bull diffusion

coefficient

D^A-(cms)

Stratum B

effective bull diffusion

coefficient

D=B

(cms)

Stratum C

effective diffusion bull

coefficient

D=e (cms)

Total overall

effective diffusion

coefficient

DT

(cms)

Diffusion path

length

Ld

(cm)

I 787E+07 I bull449E-05 | 15 bull7709 230E-03 982E-02 176E-04 | 743E-03 | OOOE+00 | OOOE+00 | 743E-03 |

bull bull bull -

Convecfion path -bull

length

Lp (cm)

Source vapor cone

-source

(Mgm)

Crack radius

fcrack

(cm)

Average vapor

flow rate into bIdg

Qaoil bull

(cms)

Crack effective diffusion

coefficient pcack

(cms)

Area of crack

crack

(cm)-

Exponent of equivalent foundation

Peclet number

exp(Pef)

(unitless)

bull

1 15 -1 603E+03 1 010 1 474E+01 743E-03 354E+03 1 697E+07

Infinite source Indoor

attenuation coefficient

poundbullbullbull C t

pound(unitless)

bullsiilaquogt j ii08E-05

Infinite [ source

bIdg cone

Cbujidjng

(pgm)

651 E-02 iKrt

Unit risk

factor

URF

(ngm)-

Reference cone

RfC

(mgm)

NA 35E-02 1

I END I

Appx B-2 cis-12-DCExls 3o f3 982009

AR100313

APPENDIX B-3-A DATA ENTRY SHEET

Coyne Texti le Services - Hunt ington West Virginia

SG-ADV Version 31 0204

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

67663

Soil Gas Concentration Data ENTER ENTER

Soil Soil gas gas

cone OR cone c C

(^gm) (ppmv)

591 E+03

bull

Chemical

Chloroform

MORE ENTER Depth

below grade tb bottom

of enclosed space floor

bull LF

(cm)

ENTER

Soil gas sampling depth

below grade

(cm)

ENTER

Average soil

temperature-Ts

CO bull

1 15 1 15 1 125

ENTER ENTER ENTER Totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

IIA hs he (cm) (cm) (cm)

1 5 bull 1 1

ENTER ENTER Soil - bull

stratum A User-defined SCS stratum A

soil type bull soil vapor (used to estimate OR permeability

soil vapor k

bull permeability) (cm) 1

SL 1 1 bull

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A soil dry

bulk density

Pb (gcm)

ENTER Stratum A soil total porosity

nV (unitless)

ENTER Stratum A

-soilwater-filled bullporosity

Sraquo (cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

(unitless)

ENTER Stratum B

soil water-filled porosity

bull ebdquo=

(cmcm) bull

ENTER Straturri C

SCS bull soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

- c rack

(cm)

ENTER

Soil-bldg pressure

differential AP^

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor

width bull W B

(cm)

ENTER

Enclosed space

height HB

(cm)

ENTER

bull Floor-wall^ seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bidg OR

Leave blank to calculi

Qsoil bull

(Lm)

I -I

Appx B-3 Chloroformxls 1 of 3 982009

AR100314

APPENDIX B-3-B CHEMICALPROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Diffusivity in air

D (cms)

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffijsivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature

Dbdquo H TR A H bdquo TB Tc

(cm s) (atm-m mol) ro (calmol) (degK) (degK)

Molecular weight

MW

(gmol)

Unit risk

factor URF

(ngm)-

Reference cone

RfC

(mgm)

104E-01 100E-05 I 366E-03 25 6988 33432 53640 11938 I 23E-05 | OOE+00

Appx B-3 Chloroformxls 2 of 3 982009

AR100315

APPENDIX B-3-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure

duration

(sec)

Source-

building

separation

LT

(cm)

Stratum A

soil

air-filled

porosity

Sa

( cm cm )

Stratum B

soil

air-filled

porosity

( cm cm )

Stratum C

soil

air-filled

porosity

( c m c m )

Stratum A

effective

total fluid

saturation

( c m c m )

Stratum A

soil

intrinsic

penmeability

k

(cm )

Stratum A

- soil

relative air

permeabil i ty

(cm )

Stratum A

soil

effective vapor

permeability

kv

(cm )

Floor-

wall

seam

perimeter

gtcrack

(cm)

Soil gas

cone

(ngm)

BIdg

venfilation

rate

^buildlriE

(cms)

I 9 4 6 E + 0 8 ~ T I 0284 T 596E-09 I 0-901 I 537E-09 | 35357 | 591 E+03 j 439E+06 | 1 0 284 0284 0184

Area of

enclosed

space

below

grade

A B

( c m )

Crack-

to-total

area

ratio

n

(unitless)

Crack

depth

bull below

grade

^crack

(cm)

Enthalpy of

vaporization at

ave soil

temperature

AHTs bull

(calmol)

Henry s law

constant at

ave soil

temperature

HTS

(a tm-m mol j

Henrys law

constant at

ave soil

bull temperature

HTS

(unitless) bull

Vapor

viscosity at

ave soil-

temperature

^HTS

(gcm-s)

Stratum

A

effective

diffusion

coefficient

(cm s)

Stratum

B

effective

difftjsion

coefficient

D B

(cms) bull

S t ra tum

C

effective

diffusion

coefficient

Dc

(cm s)

Total

overall

effective

bull diffusion

coefficient

D T

(cm s)

Diffi jsion

path

length

Ld

(cm)

I 787E+07 I 449E-05 j - bull 15 7528 210E-03 896E-02 176E-04 I 105E-02 | OOOE+00 | OOOE+00 | 105E-02

Convection

path length

Lp

(cm)

Source

vapor

cone -

^source

- (ngm)

Crack

radius

Tcrack

(cm)

Average

vapor

flow rate

into bidg

Qsoil

(cms)

Crack

effective

diffusion

coefficient Qcrack

bull (cms)

Area of crack

Acrack

(cm)

Exponent of

equivalent

foundation

Peclet number

exp(Pe)

(unitless)

V bull bull

1 15 1 591 E+03 1 010 1 474E+01 105E-02 354E+03 1 355E+05

Infinite

source

indoor

attenuation

coefficient

d

(unitless)

bull 108E-05

Infinite

source

bIdg

cone

^ b u i l d i n g

i (^gm)

bull bull

i 638E-02 -

Unit

risk bull factor

URF

(ngmY

Reference

cone

RfC

(mgm)

~ 23E-05 NA 1

I END

Appx B-3 Chloroform xls 3 of 3 982009

AR100316

APPENDIX B-4-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ersion 31-020^

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

nodashes)

bull 75092

ENTER Soil gas

cone

c (ngm)

Soil Gas Concentration Data ENTER

Soil gas bull

OR cone

bull C

(ppmv)

152E+03

bull bull

Chemical

Methylene chloride

MORE

MORE 4gt

ENTER Depth

below grade to bottom

of enclosed space floor

LF -

(cm)

ENTER

Soil gas sampling depth

below grade

bull U

(cm)

ENTER

Average soil

temperature

Ts bull CC)

bull bull bull bull

1 15 1 15 125

ENTER Totals

Thickness of soil

stratum A h

(cm)

ENTER ENTER must add up to value of Ls (cell F24

Thickness Thickness of soil of soil

stratum B stratum C (Enter value or 0) (Enter value or 0)

he he bull

(cm) bull (cm) -

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(usedto estimate OR perrrieability | soil vapor

permeability)

k bull

(cm)

SL 1 bull 1

ENTER Stratum A

SCS soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

Pb (gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Stratum A

soil water-filled porosity

9w (cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

Pb^

(gcm)

ENTER Stratum B soil total porosity

n^

(unitless)

ENTER Stratum B

soil water-filled porosity

(crhcm)

ENTER Stratum C

SCS soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE 4gt

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

bull Soil-bldg pressure

differential AP^

(gcm-s)

ENTER Enclosed

space floor

length LB

(cm)

ENTER Enclosed

space floor

width bull W B

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width

w

(cm)

ENTER

Indoor air exchange

rate

ER (1h)

ENTER Average vapor

flow rate into bidg OR

Leave blank to calculc

Qsoil

(Lm)

10 40 8839 8839 244 01 083

Appx B-4 MCxIs 1 of 3 982009

AR100317

Diffijsivity in air

D

APPENDIX B-4-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffusivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature

Pw H TR AHt TB TC

Molecular weight

MW

Unit risk

factor URF

Reference cone

RfC

(cms) (cms) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) bull (ngm)- (mgm)

bull bull

1 101E-01 1 117E-05 1 218E-03 1 25 | 6706 1 31300 1 51000 1 8493 1 47E-07 1 30E+00 1

Appx B-4 MCxIs 2 of 3 982009

AR100318

APPENDIX B-4-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

T

(sec)

Source- -building

separation

LT

(cm)

Stratum A soil

air-filled porosity

e a bull

(cmcm)

Stratum B soil

bullair-filled porosity bull

ea^ (cmcm)

Stratum C soil

air-filled porosity

ea= (cmcmj

Stratum A effective total fluid

saturation

Sc bull

(cmcm)

Stratum A soil

intrinsic pemneability

ki (cm)

Stratum A soil

relative air permeability

^ ^ g

(cm)

stratumA bull soil effective vapor permeability

K (cm)

Floor-wall

seam perimeter

Xcrack

(cm)

Soil gas

cone (ngm)

BIdg ventilation

rate

Qbuildinc

(cms)

1 946E+08

Area of -enclosed

space below

bull grade

AB

(cm)

1

Crack-to-total

area rafio

Tl

(unitless)

0284 1

Crack depth below grade

Zcrack

(cm)

0284 1

bull Enthalpy of vaporization at

ave soil temperature

AHTs (calmol)

0284

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

0184

Henrys law constant at ave soil

temperature

HTS

bull (unitless)

1 596E-09

Vapor viscosity at

ave soil temperature

Mrs (gcm-s)

0901

Stratum A

effective diffusion

coefficient

D (cms)

537E-09

Stratum B

effective diffusion

coefficient

D-B (cms)

35357 1

Stratum C -

effective diffusion

coefficient

D-c ^ (cms)

152E+03

Total bull overall

bull effective diffusion

coefficient

D ^

(cms)

440E+06 1

Difftjsion path

length

Ld (cm)

1 787E+07

Convection path

length

Lp (cm)

4 49E-05

Source vapor cone

Csource

(ngm)

15 1

Crack radius

Tcrack

(cm)

7007 bull 1

Average vapor

flow rate intobldg

Qsoil

(cms)

130E-03

Crack effective diffusion

coefficient pcrack

(cms)-

555E-02

bull ^

Area of crack

Acrack

(cm) bull

1 176E-04

Exponent of equivalent foundation

Peclet number

exp(Pe)

(unitless) bull

bull bull

1 15

1 END

152E+03 010 1 474E+01 1 102E-02 354E+03 1 519E+05

102E-02

Infinite source

indoor ^attenuation coefficient

bull a

(unitless)

aiii08E-05

0 OOE+00

bull

Infinite bull source

bIdg ^ cone

^bu i l d i ng

(MQm)

164E-02

OOOE+00 1

Unit risk

factor

URF

(ngm)-

47E-07 1

102E-02 j

Reference cone

RfC

(mgm)

30E+00 j

1 1

Appx B-4 MCxIs 3 of 3 982009

AR100319

APPENDIX B-5-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ^erslon 31 0204

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

127184

Soil Gas Concentration Data ENTER ^ ENTER

Soil -Soi l bull gas gas

cone OR cone Cg C bull

(tgm) (ppmv)

149E+05 1

Chemical

bull Tetrachlbroethylene

MORE 4

ENTER Depth

below grade to bottom

ofenclosecJ space floor

LF

(cm)

ENTER

Soil gas bull sampling

depth below grade

u bull (cm)

ENTER

Average bullsoil

temperature - Ts

ro 1 1 5 1 15 1 125 bull

ENTER ENTER ENTER totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hft bull he bull he

(cm) (cm) (cm)

bull 1 5 1 - 1

ENTER ENTER Soil

stratum A User^defined bull SCS bull stratum A soil type soil vapor

(used to estimate OR perrrieability soil vapor K bull

permeability) (cm) 1

SL 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

Pb

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Sitratum A

soil water-filled bull porosity

(cmcm)

ENTER Stratum B

SCS soiltype

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

Pb^

(gcm)

ENTER Stratum B soil total porosity

Ajnitless^

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS soil type

LookupSoil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

VS

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor width

W B

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width

w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

ENTER Average vapor

flow rate into bidg OR

Leave blank to calcul

bull Qsoil

(Lm)

10 40 8839 8839 244 01 083

Appx B-5 PCExIS 1 of 3 982009

AR100320

APPENDIX B-5-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal Unit

Diffusivity Diffusivity at reference reference the riormal boiling Critical Molecular risk Reference in air in water temperature temperature boiling point point teriiperature weight factor cone

Da Dbdquo H TR AHb TB Tc MW URF RfC

(cms) (cnis) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) (^gm)- (mgm)

1 720E-02 1 820E-06 1 184E-02 1 25 1 8288 1 39440 1 62020 1 16583 1 59E-06 1 60E-01 1

J

AppxB-5PCExls 2 of 3 - 982009

AR100321

APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

T

(sec)

Source-building

separation

LT

bull (cm)

Stratum A soil

air-filled porosity

Oa (cmcm)

Stratum B - soil air-filled porosity

ea (cmcm)

Stratum C soil

air-filled porosity

ea= - (cmcm)

Stratum A effective total fluid

saturation

sbdquo (cmcm)

Stratum A soil

intrinsic permeability

ki (cm)

Stratum A soil

relative air permeability

- ^ g

(cm)

Stratum A soil

effective vapor permeability

kv (cm)

Floor-wall

seam perimeter

^crack

(cm)

Soil gas

cone

(ngm)

BIdg venfilation

rate

Qbuildins

bull (cms)

bull bull

1 946E+08

Area of enclosed

space below grade

AB

(cm)

1

bullCrack-to-total

area ratio

1 (unitless)

0284 1

Crack bull depth below grade

Zcrack

(cm) -

0284 1

Enthalpy of vaporization at bull

ave soil temperature

bull A H V TS

(calmol)

0284

Henrys law constant at

ave soil temperature

HTS (atm-mmol)

0184

-Henrys law constant at

ave soil temperature

HTS

(unitless)

1 596E-09

Vapor viscosity at

ave soil temperature

HTS

(gcm-s)

0901

Stratum A

effective diffusion

coefficient bull D = bull

(cms)

537E-09

Stratum B

effective diffusion

coefficient

D--B (cms)

35357 1

Stratum C

effective diffusion bull

coefficient

D-c (crris)

149E+05

Total overall

effective bulldiffusion coefficient

DT

(cms)

440E+06 1

Difftjsion path

length

U (cm)

1 787E+07

Convection path

length

bull Lp

(cm)

4 49E-05

Source vapor cone

^source

(ngm)

15 1

Crack radius

Tcrack

(cm)

9528 1

Average vapor

flow rate intobldg

Qsoil (cms)

908E-03

Crack effective diffusion

coefficient pcrack

bull ( c m s ) bull

387E-01

Area of crack

Abdquoack (cm)

1 176E-04

Exponent of equivalent foundafion

Peclet number

exp(Pe)

(unitless)

bull

1 15-

1 END

149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08

727E-03

Infinite source indoor

attenuation coefficient

a

(unitless)

108E-05

OOOE+00

Infinite source

bIdg cone

Cburldtng

(Mgm)

161 E+00

OOOE+00 1

Unit risk

factor

URF

(ugm)-

59E-06 1

727E-03

Reference cone

RfC (mgm)

60E-01

1 1

Appx B-5 PCExls 3 of 3 982009

AR100322

APPENDIX B-6-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ersion31 0204

Reset to Defaults

t

Soil Gas Concentration Data ENTER

Chemical CAS No

(numbers only

no dashes)

79016

ENTER ENTER Soil Soil gas gas

cone OR cone C C -

bull (ngm) (ppmv)

782E+03

Chemical

Trichloroethylene

MORE ENTER Depth

below grade to bottom-

of enclosed space floor

LF

(cm)

ENTER

Soil gas sarnpling

depth below grade

U (cm)

ENTER

Average soil

temperature Ts

(degC)

1 15 1 15 t 125

ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e

(cm) (cm) (cm)

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estimate OR permeability soil vapor

permeability)

k (cm)

bull S L 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil bull-Parameters

ENTER Stratum A

soil dry bulk density

P b -

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Stratum A bull

soilwaterrfilled porosity

(cmcm) bull

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

bull P ^ (gcm)

ENTER Stratum B soil total

porosity

nlaquo

(unitless) -

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS bull soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor

width W B

(cm)

ENTER

Enclosed space height

H B bull

( c m ) bull

ENTER

Floor-wall seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bIdg OR

Leave blank to calculc

Qsoil

(Lm) -

Appx B-6 TCExIs 1 of 3 982009

A

AR100323

APPENDIX B-6-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight

Da Dbdquo H TR AH^b TB TC MW

Unit risk Reference

factor cone URF RfC

(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)

1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1

Appx B-6 TCExIs 2 of 3 982009

AR100324

APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

(sec)

Source-building

separation LT

(cm)

Stratum A soil

air-filled porosity

bull ea (cmcm)

Stratum B Soil

air-fllled porosity

e^ bull (cmcm)

Stratum C soil

air-filled porosity

(cmcm)

StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air

saturation permeability permeability

S|e k krg (cmcm) (cm) (cm)

Stratum A Floor-soil wall BIdg

effective vapor seam Soil ventilafion permeability perimeter gas rate

k^ bull Xack c o n e Qbuildins

(cm) (cm) (ngm) (cms)

946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |

Area of enclosed

space below grade

AB

(cm)

Ciack- to-total

area ratio

1 (unitless)

Crack depth below grade

Zcrack

(cm)

Enthalpy of vaporization at

ave soil temperature

A H J S

(calmol)

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law bull constant at

ave soil temperature

HTS

(unitless)

Vapor viscosity at

ave soil temperature

|JTS

(gcm^s)

Stratum A

effective diffusion

coefficient

(cms)

Stratum B

effective -diffusion

coefficient

D=B (cms)

Stratum ^ C effective diffusion

coefficient

D=c (cms)

Total overall

effective diffusion

coefficient

DT

(cms)

I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03

Diffusion path

length

Li (cm) bull

Convection bull path

length

Lp

(cm)

Source vapor cone bull

^source

(ngm)

Crack radius

rcrack

(cm)

Average vapor

- flow rate intobldg

Qsoil

(cms)

Crack effective diffusion

bull coefficient Qcrack

(cms)

Area of crack

^crack

(cm)

Exponent of equivalent foundation

Peclet bull number

exp(Pe)

(unitless)

bull bull

1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07

Infinite source Indoor

attenuation coefficient

a

(unitless)

108E-05

Infinite source

bIdg concgt

^building

(ngm)

844E-02

Unit risk

factor

URF

(ngm)-

Reference cone

RfC

(mgm)

1 1E-04 1 40E-02 1

END

Appx B-6 TCExIs 3 of 3 982009

AR100325

Office of Waste Management 1356 Hansford Street

Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256

West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director

ORDER

ISSUED UNDER THE

HAZARDOUS WASTE MANAGEMENT ACT

CHAPTER 22 ARTICLE 18

OF THE WEST VIRGINIA CODE^ AS AMENDED

y Order Number HW-011-80

To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704

ATTEMTION MREDARMON

Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull

AR100326

ViWJ011-laquo9 PageNunil)er2

BASIS FOR ORDER

As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following

A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^

B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator

C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities

0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94

^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement

P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following

1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater

2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was

^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment

CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable

CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order

AR100327

H W - 0 1 1 - 9 9 Page Number 3

REQUIREMENTS OF ORDER

Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows

1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^

2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore

remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling

GENERAL PROVaiONS

1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order

2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order

3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order

Effective Date

Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief

Wt T 1 V Oflice of Waste Management

AR100328

^ ^ S I S

^wmmmmamn

AR100329

Page 29: SDMS DocID 2121999 · International Enterprises Corp. building (Coyne Building), which is located at 1111 Vernon Street, Westmoreland District, Wayne County, West Virginia. The following

To solve this equation the USEPAs SG-ADV spreadsheet Version 31 most recently updated in

February 2004 was implemented A combination of site-specific factors and default values from the

Users Guide for Evaluating Subsurface Vapor Intrusion Into Buildings (USEPA 2004) were used as input

values in the model All input values are defined below and presented in Tables B-1-A through B-6-A

bull The initial subslab vapor concentration (Csubsiab) is the maximum detected concentration(in units

of ugm ) of samples VP-01 VP-02 and VP-03 that was presented in Table 3 of the report

bull The depth below grade to the bottom of the enclosed space floor (Lp) is set to 15 cm the default

value provided by USEPA (2004) for a slab-on-grade structure

bull The vapor sampling depth below grade (Lg) is a site-specific value The vapor samples were

collected from immediately beneath the building floor therefore Lj has been set to 15 cm

bull The average soilgroundwater temperature (Ts) is set to 125degC the average value for West

Virginia as estimated frorri Figure 8 of the vapor intrusion users guide (USEPA 2004)

bull The soil type used to estimate vapor permeability is assumed to be sandy loam (SL) The

associated soil properties for a sandy loam soil type are as follows the soil dry bulk density (Pb) is

162 gcm the total porosity (n) is 0387 (cm^-aircm^) and the water-filled porosity (nw) is 0103

(cm -HzOcm )

bull The floor thickness (Lcrack) is set to the USEPA (2004) default value of 10 cm

bull The soil-building pressure differential (AP) is set to the USEPA (2004) default value of 40 gcm-s^

bull The building dimensions are siterspecific based on the existing plant building located at the site

The existing structure is approximately 84000 square feet (Dolphin 2000) therefore the

dimensions are set to 8839 cm (290 feet) length by 8839 cm (290 feet) The USEPA (2004)

default value of 244 cm vyas used for the height

bull Thefloor-wall seam crack width (w) is set to the USEPA (2004)-default value of 01 cm

bull The indoor air exchange rate (ER) is set to 083hour This is the value provided by ASTM (2002)

for commercial and industrial buildings

AR100306

Tables B-1-B through B-6-B present the constituent-specific properties for COC that were used in the TF

calculations Tables B-1-C through B-6-C present the intermediate calculations used to determine the

indoor air attenuation coefficients (ie the transport factors) The shaded boxes in Tables B-1-C through

B-6-C also present the resulting TF values that are applied to the concentrations of COC in subslab

vapor and the estimated indoor air concentrations

References

American Society for Testing and Materials (ASTM 2002) Standard Guide for Risk-Based Corrective Action Applied at Petroleum Release Sites ASTM E-1739-95 (Reapproved 2002)

Johnson PC and RA Ettinger (1991) Heuristic model for predicting the intrusion r-ate of contaminant vapors into buildings Environ Sci Technolpgy 25 1445-1452

Dolphin Environmental LLC (Dolphin 2000) Site Characterization Report Mach 14 2000

United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004

AR100307

APPENDIX B-1-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV Nersion31 0204

Reset to Defaults

ENTER -

Chemical CAS No

(numbers only

no dasties)

95636

ENTER Soil gas

cone

Cg (ngm)

Soil Gas Concentration Data ENTER

Soil gas

OR cone

bull - c bull (PPmv)

197E+02

Chemical

124-Trimethylbenzene

MORE ENTER Depth

below grade to bottom

of enclosed space floor

U bull (cm)

ENTER

Soil gas sampling

depth below grade

U (cm) bull

ENTER

Average soil

temperature Ts

CO

1 15 1 1 5 bull125

ENTER ENTER ENTER Totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hft ha he

(cm) (cm) (cm)

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estirnate OR permeability | soil vapor

permeability) k v bull

(cm)

SL 1 1

MORE ENTER

stratum A SCS

soil type

Lookup Soil Parameters

ENTER stratum A soil dry

bulk density P

(gcm)

ENTER Stratum A soil total porosity

(unitless)

ENTER bull stratum A soil water-filled

porosity

(cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

nlaquo

(unitless)

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gchi-s^)

ENTER Enclosed

space floor

length bull LB

(cm)

ENTER Enclosed

space floor

width WB

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

bull Floor-wall seam crack

width w

(cm)

bullENTER

Indoor air exchange

rate ER

(1h) bull

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bidg OR

Leave blank to caicuij

(Lm)

Appx B-1 124-TMBxls 1 of 3 982009

AR100308

APPENDIX B-1-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of ^ bull law constant law constant vaporization at Normal

Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temperature boiling point point temperature weight

D bull Dbdquo H T R bull AHbdquo TB Tc IVIW

Unit risk Reference

factor cone URF RfC

(cms) (cmls) (atm-mmol) CO (calmol) (degK) (degK) (gmol) bull (ugm)- (mgm)

1 606E-02 1 792E-06 1 bull 614E-C3 1 25 1 9369 1 44230 | 64917 1 12020 1 OOE+00 1 60E-03 1

Appx B-1 124-TMBxls 2 of 3 982009

AR100309

APPENDIX B-1-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

(sec)

Source-building

separation

LT bull

(cm) bull

Stratum A soil

air-filled porosity

Q A

Stratum B soil

air-filled porosity

(cmcm) (cmcm)

Stratum C soil air-filled porosity

(cmcm)

Stratum A effective total fluid

saturation

Se

(cmcm)

Stratum A soil

bullintrinsic permeability

^ (cm)

stratum A Stratum A Floor- soil soli wall BIdg

relative air effective vapor seam Soil bull ventilation permeability permeability perimeter gas rate-

kfg ky Xgrack c o n e - QbuHdinpound

(cm) - (cm) (cm) (ngm) (cms)

946E+08 1 0284 0284 0284 0184 596E-09 0901 537E-09 35357 I 197E+02 | 439E+06 |

Area of enclosed

space below grade

As (cm)

Crack-to-total area ratio

1 bull

(unitless)

Crack depth

below grade

Zcfack

(cm)

Enthalpy of vaporization at

ave soil temperature

AHvjs

(calmol) bull

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law constant at

ave soil bull temperature

bull HTS

(unitless)

Vapor bull viscosity at

ave soil temperature

HTS

(gcm-s)

Stratum A

effective diffusion

coefficient

D (cms)

Stratum-B

effective diffusion coefficient

DB (cms)

Stratum C effective diffusion

coefficient

D-c (cms)

Total - overall effective diffusion

coefficient

D ^ (cms)

Diffusion path

length

L-

(cm)

I 787E+07 I 449E-05 | 15 | 11661 260E-03 111E-01 176E-04 I 612E-03 j OOOE+00 | OOOE+00 | 612E-03 j

bull Convection path

length

Lp

(cm)

Source vapor cone

^source

(ngm)

Crack radius

Tcfack

(cm)

Average vapor

flow rate into bIdg

Qsoii

(cms)

Crack effective diffusion

coefficient pcrack

(cms)

Area of CTack

Acack

(cm)

Exponent of equivalent foundation

Peclet number

exp(Pe)

(unitless)

bull bull - bull bull bull bull

1 15 1 197E+02 1 010 1 474E+01 612E-03 bull 354E-t-03 1 336E+09

Infinite source Indoor

~ attenuation coefficient

a

(unitless)

108E-05

Infinite source

btJbldgjJSv-L ^Ppncji3i-

virhpbiiilding bullbull ^lHltti^m)ilg

213E-03

Unit risk

factor

URF

(ngm)-

Reference cone

RfC (mgm)

NA 60E-03 1

I END

Appx B-1 124-TMBxls 3 of 3 982009

AR100310

APPENDIX B-2-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV Nersion31 020^

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

156592

Soil Gas Concentration Data ENTER

Soil gas

cone OR c

(ngm) bull

ENTER Soil bull-gas

cone

c (ppmv)

603E+03 1

Chemical

cis-12-Dichloroethylene

MORE ENTER Depth

below grade to bottom

of enclosed space floor

LF

(cm)

ENTER

Soil gas sampling

depth below grade

U (cm)

ENTER

Average soil

temperature bull Ts

(degC)

1 15 1 bull 15 125

ENTER ENTER ENTER Totalsmust add ijp tb value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hA hB he

bull (cm) (cm) (cm)

15 1 1

ENTER Soil

straturh A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estimate OR permeability | soil vapor

permeability) kv

(cm)

SL 1 |

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

P (gcm)

ENTER Stratum A soil total porosity

bull n

(unitless)

ENTER Stratum A

soil water-filled porosity

(cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

ENTER Stratum B

soil water-filled porosity

ENTER Stratum C

SCS soil type

(unitless) (cmcm)

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure differential

AP

(gcm-s)

ENTER Enclosed bull

space floor

length

LB (cm)

ENTER Enclosed

space floor

width WB

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER

Average vapor flow rate into bIdg

OR Leave blank to calculi

Qsoil

(Lm)

Appx B-2 cis-12-DCExls 1 of 3 982009

AR100311

APPENDIX B-2-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Diffusivity in air

Da

(cms)

Diffusivity in water

Dw (cms)

Henrys law constant at reference temperature

H

(atm-mmoi)

Henrys law constant

reference temperature

bull T R

CC)

Enthalpy of vaporization at

the normal boiling point

AHbdquob

(calmol)

Normal boiling point

TB

(degK)

Critical temperature

Tc (degK)

Molecular weight

MW

(gmol)

Unit risk

factor URF

(ngm)

Reference cone

RfC (mgm)

1 736E-02 1 113E-05 1 407E-03 j 1 25 1 bull 7192 1 33365 1 54400 1 9694 1 OOE+00 j 35E-02 1

Appx B-2 cis-12-DCExls 2 of 3 982009

AR100312

APPENDIX B-2-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

stratum A Stratum B Stratum C Source- soil soil soil

Exposure building air-filled air-filled air-filled

duration separation porosity porosity porosity

T LT ea e^ bull e= (sec) (cm) (cmcm) (cmcm) (cmcm)

I 946E+08n^

Stratum A Stratum A Stratum A Stratum A Floor-effective soil soil soil wall total fluid intrinsic relative air effective vapor seam

saturation permeability permeability permeability perimeter

Ste kj krg ky Acrack

(cmcm) (cm) (cm) (cm) (cm)

Soil gas

cone (ngm)

I 0284 I 0284~ 0284 0184 I 596E-09 | 090T 537E-09 35357 603E+03

BIdg ventilation

rate

JbulldinE

(cms)

439E+06

Area of enclosed

space below grade

AB

(cm)

Crack-to-total

area ratio

n (unitless)

Crack depth below grade

Zltiack (cm)

Erithalpy of vaporization at

ave soil temperature

AHvTs (calmol)

Henryslaw constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law constant at

ave soil temperature

HTS

(unitless) bull

Vapor viscosity at

ave soil bull temperature

HTS

bull (gcm-s)

Stratum A

effective bull diffusion

coefficient

D^A-(cms)

Stratum B

effective bull diffusion

coefficient

D=B

(cms)

Stratum C

effective diffusion bull

coefficient

D=e (cms)

Total overall

effective diffusion

coefficient

DT

(cms)

Diffusion path

length

Ld

(cm)

I 787E+07 I bull449E-05 | 15 bull7709 230E-03 982E-02 176E-04 | 743E-03 | OOOE+00 | OOOE+00 | 743E-03 |

bull bull bull -

Convecfion path -bull

length

Lp (cm)

Source vapor cone

-source

(Mgm)

Crack radius

fcrack

(cm)

Average vapor

flow rate into bIdg

Qaoil bull

(cms)

Crack effective diffusion

coefficient pcack

(cms)

Area of crack

crack

(cm)-

Exponent of equivalent foundation

Peclet number

exp(Pef)

(unitless)

bull

1 15 -1 603E+03 1 010 1 474E+01 743E-03 354E+03 1 697E+07

Infinite source Indoor

attenuation coefficient

poundbullbullbull C t

pound(unitless)

bullsiilaquogt j ii08E-05

Infinite [ source

bIdg cone

Cbujidjng

(pgm)

651 E-02 iKrt

Unit risk

factor

URF

(ngm)-

Reference cone

RfC

(mgm)

NA 35E-02 1

I END I

Appx B-2 cis-12-DCExls 3o f3 982009

AR100313

APPENDIX B-3-A DATA ENTRY SHEET

Coyne Texti le Services - Hunt ington West Virginia

SG-ADV Version 31 0204

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

67663

Soil Gas Concentration Data ENTER ENTER

Soil Soil gas gas

cone OR cone c C

(^gm) (ppmv)

591 E+03

bull

Chemical

Chloroform

MORE ENTER Depth

below grade tb bottom

of enclosed space floor

bull LF

(cm)

ENTER

Soil gas sampling depth

below grade

(cm)

ENTER

Average soil

temperature-Ts

CO bull

1 15 1 15 1 125

ENTER ENTER ENTER Totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

IIA hs he (cm) (cm) (cm)

1 5 bull 1 1

ENTER ENTER Soil - bull

stratum A User-defined SCS stratum A

soil type bull soil vapor (used to estimate OR permeability

soil vapor k

bull permeability) (cm) 1

SL 1 1 bull

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A soil dry

bulk density

Pb (gcm)

ENTER Stratum A soil total porosity

nV (unitless)

ENTER Stratum A

-soilwater-filled bullporosity

Sraquo (cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

(unitless)

ENTER Stratum B

soil water-filled porosity

bull ebdquo=

(cmcm) bull

ENTER Straturri C

SCS bull soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

- c rack

(cm)

ENTER

Soil-bldg pressure

differential AP^

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor

width bull W B

(cm)

ENTER

Enclosed space

height HB

(cm)

ENTER

bull Floor-wall^ seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bidg OR

Leave blank to calculi

Qsoil bull

(Lm)

I -I

Appx B-3 Chloroformxls 1 of 3 982009

AR100314

APPENDIX B-3-B CHEMICALPROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Diffusivity in air

D (cms)

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffijsivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature

Dbdquo H TR A H bdquo TB Tc

(cm s) (atm-m mol) ro (calmol) (degK) (degK)

Molecular weight

MW

(gmol)

Unit risk

factor URF

(ngm)-

Reference cone

RfC

(mgm)

104E-01 100E-05 I 366E-03 25 6988 33432 53640 11938 I 23E-05 | OOE+00

Appx B-3 Chloroformxls 2 of 3 982009

AR100315

APPENDIX B-3-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure

duration

(sec)

Source-

building

separation

LT

(cm)

Stratum A

soil

air-filled

porosity

Sa

( cm cm )

Stratum B

soil

air-filled

porosity

( cm cm )

Stratum C

soil

air-filled

porosity

( c m c m )

Stratum A

effective

total fluid

saturation

( c m c m )

Stratum A

soil

intrinsic

penmeability

k

(cm )

Stratum A

- soil

relative air

permeabil i ty

(cm )

Stratum A

soil

effective vapor

permeability

kv

(cm )

Floor-

wall

seam

perimeter

gtcrack

(cm)

Soil gas

cone

(ngm)

BIdg

venfilation

rate

^buildlriE

(cms)

I 9 4 6 E + 0 8 ~ T I 0284 T 596E-09 I 0-901 I 537E-09 | 35357 | 591 E+03 j 439E+06 | 1 0 284 0284 0184

Area of

enclosed

space

below

grade

A B

( c m )

Crack-

to-total

area

ratio

n

(unitless)

Crack

depth

bull below

grade

^crack

(cm)

Enthalpy of

vaporization at

ave soil

temperature

AHTs bull

(calmol)

Henry s law

constant at

ave soil

temperature

HTS

(a tm-m mol j

Henrys law

constant at

ave soil

bull temperature

HTS

(unitless) bull

Vapor

viscosity at

ave soil-

temperature

^HTS

(gcm-s)

Stratum

A

effective

diffusion

coefficient

(cm s)

Stratum

B

effective

difftjsion

coefficient

D B

(cms) bull

S t ra tum

C

effective

diffusion

coefficient

Dc

(cm s)

Total

overall

effective

bull diffusion

coefficient

D T

(cm s)

Diffi jsion

path

length

Ld

(cm)

I 787E+07 I 449E-05 j - bull 15 7528 210E-03 896E-02 176E-04 I 105E-02 | OOOE+00 | OOOE+00 | 105E-02

Convection

path length

Lp

(cm)

Source

vapor

cone -

^source

- (ngm)

Crack

radius

Tcrack

(cm)

Average

vapor

flow rate

into bidg

Qsoil

(cms)

Crack

effective

diffusion

coefficient Qcrack

bull (cms)

Area of crack

Acrack

(cm)

Exponent of

equivalent

foundation

Peclet number

exp(Pe)

(unitless)

V bull bull

1 15 1 591 E+03 1 010 1 474E+01 105E-02 354E+03 1 355E+05

Infinite

source

indoor

attenuation

coefficient

d

(unitless)

bull 108E-05

Infinite

source

bIdg

cone

^ b u i l d i n g

i (^gm)

bull bull

i 638E-02 -

Unit

risk bull factor

URF

(ngmY

Reference

cone

RfC

(mgm)

~ 23E-05 NA 1

I END

Appx B-3 Chloroform xls 3 of 3 982009

AR100316

APPENDIX B-4-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ersion 31-020^

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

nodashes)

bull 75092

ENTER Soil gas

cone

c (ngm)

Soil Gas Concentration Data ENTER

Soil gas bull

OR cone

bull C

(ppmv)

152E+03

bull bull

Chemical

Methylene chloride

MORE

MORE 4gt

ENTER Depth

below grade to bottom

of enclosed space floor

LF -

(cm)

ENTER

Soil gas sampling depth

below grade

bull U

(cm)

ENTER

Average soil

temperature

Ts bull CC)

bull bull bull bull

1 15 1 15 125

ENTER Totals

Thickness of soil

stratum A h

(cm)

ENTER ENTER must add up to value of Ls (cell F24

Thickness Thickness of soil of soil

stratum B stratum C (Enter value or 0) (Enter value or 0)

he he bull

(cm) bull (cm) -

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(usedto estimate OR perrrieability | soil vapor

permeability)

k bull

(cm)

SL 1 bull 1

ENTER Stratum A

SCS soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

Pb (gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Stratum A

soil water-filled porosity

9w (cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

Pb^

(gcm)

ENTER Stratum B soil total porosity

n^

(unitless)

ENTER Stratum B

soil water-filled porosity

(crhcm)

ENTER Stratum C

SCS soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE 4gt

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

bull Soil-bldg pressure

differential AP^

(gcm-s)

ENTER Enclosed

space floor

length LB

(cm)

ENTER Enclosed

space floor

width bull W B

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width

w

(cm)

ENTER

Indoor air exchange

rate

ER (1h)

ENTER Average vapor

flow rate into bidg OR

Leave blank to calculc

Qsoil

(Lm)

10 40 8839 8839 244 01 083

Appx B-4 MCxIs 1 of 3 982009

AR100317

Diffijsivity in air

D

APPENDIX B-4-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffusivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature

Pw H TR AHt TB TC

Molecular weight

MW

Unit risk

factor URF

Reference cone

RfC

(cms) (cms) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) bull (ngm)- (mgm)

bull bull

1 101E-01 1 117E-05 1 218E-03 1 25 | 6706 1 31300 1 51000 1 8493 1 47E-07 1 30E+00 1

Appx B-4 MCxIs 2 of 3 982009

AR100318

APPENDIX B-4-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

T

(sec)

Source- -building

separation

LT

(cm)

Stratum A soil

air-filled porosity

e a bull

(cmcm)

Stratum B soil

bullair-filled porosity bull

ea^ (cmcm)

Stratum C soil

air-filled porosity

ea= (cmcmj

Stratum A effective total fluid

saturation

Sc bull

(cmcm)

Stratum A soil

intrinsic pemneability

ki (cm)

Stratum A soil

relative air permeability

^ ^ g

(cm)

stratumA bull soil effective vapor permeability

K (cm)

Floor-wall

seam perimeter

Xcrack

(cm)

Soil gas

cone (ngm)

BIdg ventilation

rate

Qbuildinc

(cms)

1 946E+08

Area of -enclosed

space below

bull grade

AB

(cm)

1

Crack-to-total

area rafio

Tl

(unitless)

0284 1

Crack depth below grade

Zcrack

(cm)

0284 1

bull Enthalpy of vaporization at

ave soil temperature

AHTs (calmol)

0284

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

0184

Henrys law constant at ave soil

temperature

HTS

bull (unitless)

1 596E-09

Vapor viscosity at

ave soil temperature

Mrs (gcm-s)

0901

Stratum A

effective diffusion

coefficient

D (cms)

537E-09

Stratum B

effective diffusion

coefficient

D-B (cms)

35357 1

Stratum C -

effective diffusion

coefficient

D-c ^ (cms)

152E+03

Total bull overall

bull effective diffusion

coefficient

D ^

(cms)

440E+06 1

Difftjsion path

length

Ld (cm)

1 787E+07

Convection path

length

Lp (cm)

4 49E-05

Source vapor cone

Csource

(ngm)

15 1

Crack radius

Tcrack

(cm)

7007 bull 1

Average vapor

flow rate intobldg

Qsoil

(cms)

130E-03

Crack effective diffusion

coefficient pcrack

(cms)-

555E-02

bull ^

Area of crack

Acrack

(cm) bull

1 176E-04

Exponent of equivalent foundation

Peclet number

exp(Pe)

(unitless) bull

bull bull

1 15

1 END

152E+03 010 1 474E+01 1 102E-02 354E+03 1 519E+05

102E-02

Infinite source

indoor ^attenuation coefficient

bull a

(unitless)

aiii08E-05

0 OOE+00

bull

Infinite bull source

bIdg ^ cone

^bu i l d i ng

(MQm)

164E-02

OOOE+00 1

Unit risk

factor

URF

(ngm)-

47E-07 1

102E-02 j

Reference cone

RfC

(mgm)

30E+00 j

1 1

Appx B-4 MCxIs 3 of 3 982009

AR100319

APPENDIX B-5-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ^erslon 31 0204

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

127184

Soil Gas Concentration Data ENTER ^ ENTER

Soil -Soi l bull gas gas

cone OR cone Cg C bull

(tgm) (ppmv)

149E+05 1

Chemical

bull Tetrachlbroethylene

MORE 4

ENTER Depth

below grade to bottom

ofenclosecJ space floor

LF

(cm)

ENTER

Soil gas bull sampling

depth below grade

u bull (cm)

ENTER

Average bullsoil

temperature - Ts

ro 1 1 5 1 15 1 125 bull

ENTER ENTER ENTER totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hft bull he bull he

(cm) (cm) (cm)

bull 1 5 1 - 1

ENTER ENTER Soil

stratum A User^defined bull SCS bull stratum A soil type soil vapor

(used to estimate OR perrrieability soil vapor K bull

permeability) (cm) 1

SL 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

Pb

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Sitratum A

soil water-filled bull porosity

(cmcm)

ENTER Stratum B

SCS soiltype

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

Pb^

(gcm)

ENTER Stratum B soil total porosity

Ajnitless^

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS soil type

LookupSoil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

VS

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor width

W B

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width

w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

ENTER Average vapor

flow rate into bidg OR

Leave blank to calcul

bull Qsoil

(Lm)

10 40 8839 8839 244 01 083

Appx B-5 PCExIS 1 of 3 982009

AR100320

APPENDIX B-5-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal Unit

Diffusivity Diffusivity at reference reference the riormal boiling Critical Molecular risk Reference in air in water temperature temperature boiling point point teriiperature weight factor cone

Da Dbdquo H TR AHb TB Tc MW URF RfC

(cms) (cnis) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) (^gm)- (mgm)

1 720E-02 1 820E-06 1 184E-02 1 25 1 8288 1 39440 1 62020 1 16583 1 59E-06 1 60E-01 1

J

AppxB-5PCExls 2 of 3 - 982009

AR100321

APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

T

(sec)

Source-building

separation

LT

bull (cm)

Stratum A soil

air-filled porosity

Oa (cmcm)

Stratum B - soil air-filled porosity

ea (cmcm)

Stratum C soil

air-filled porosity

ea= - (cmcm)

Stratum A effective total fluid

saturation

sbdquo (cmcm)

Stratum A soil

intrinsic permeability

ki (cm)

Stratum A soil

relative air permeability

- ^ g

(cm)

Stratum A soil

effective vapor permeability

kv (cm)

Floor-wall

seam perimeter

^crack

(cm)

Soil gas

cone

(ngm)

BIdg venfilation

rate

Qbuildins

bull (cms)

bull bull

1 946E+08

Area of enclosed

space below grade

AB

(cm)

1

bullCrack-to-total

area ratio

1 (unitless)

0284 1

Crack bull depth below grade

Zcrack

(cm) -

0284 1

Enthalpy of vaporization at bull

ave soil temperature

bull A H V TS

(calmol)

0284

Henrys law constant at

ave soil temperature

HTS (atm-mmol)

0184

-Henrys law constant at

ave soil temperature

HTS

(unitless)

1 596E-09

Vapor viscosity at

ave soil temperature

HTS

(gcm-s)

0901

Stratum A

effective diffusion

coefficient bull D = bull

(cms)

537E-09

Stratum B

effective diffusion

coefficient

D--B (cms)

35357 1

Stratum C

effective diffusion bull

coefficient

D-c (crris)

149E+05

Total overall

effective bulldiffusion coefficient

DT

(cms)

440E+06 1

Difftjsion path

length

U (cm)

1 787E+07

Convection path

length

bull Lp

(cm)

4 49E-05

Source vapor cone

^source

(ngm)

15 1

Crack radius

Tcrack

(cm)

9528 1

Average vapor

flow rate intobldg

Qsoil (cms)

908E-03

Crack effective diffusion

coefficient pcrack

bull ( c m s ) bull

387E-01

Area of crack

Abdquoack (cm)

1 176E-04

Exponent of equivalent foundafion

Peclet number

exp(Pe)

(unitless)

bull

1 15-

1 END

149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08

727E-03

Infinite source indoor

attenuation coefficient

a

(unitless)

108E-05

OOOE+00

Infinite source

bIdg cone

Cburldtng

(Mgm)

161 E+00

OOOE+00 1

Unit risk

factor

URF

(ugm)-

59E-06 1

727E-03

Reference cone

RfC (mgm)

60E-01

1 1

Appx B-5 PCExls 3 of 3 982009

AR100322

APPENDIX B-6-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ersion31 0204

Reset to Defaults

t

Soil Gas Concentration Data ENTER

Chemical CAS No

(numbers only

no dashes)

79016

ENTER ENTER Soil Soil gas gas

cone OR cone C C -

bull (ngm) (ppmv)

782E+03

Chemical

Trichloroethylene

MORE ENTER Depth

below grade to bottom-

of enclosed space floor

LF

(cm)

ENTER

Soil gas sarnpling

depth below grade

U (cm)

ENTER

Average soil

temperature Ts

(degC)

1 15 1 15 t 125

ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e

(cm) (cm) (cm)

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estimate OR permeability soil vapor

permeability)

k (cm)

bull S L 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil bull-Parameters

ENTER Stratum A

soil dry bulk density

P b -

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Stratum A bull

soilwaterrfilled porosity

(cmcm) bull

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

bull P ^ (gcm)

ENTER Stratum B soil total

porosity

nlaquo

(unitless) -

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS bull soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor

width W B

(cm)

ENTER

Enclosed space height

H B bull

( c m ) bull

ENTER

Floor-wall seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bIdg OR

Leave blank to calculc

Qsoil

(Lm) -

Appx B-6 TCExIs 1 of 3 982009

A

AR100323

APPENDIX B-6-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight

Da Dbdquo H TR AH^b TB TC MW

Unit risk Reference

factor cone URF RfC

(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)

1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1

Appx B-6 TCExIs 2 of 3 982009

AR100324

APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

(sec)

Source-building

separation LT

(cm)

Stratum A soil

air-filled porosity

bull ea (cmcm)

Stratum B Soil

air-fllled porosity

e^ bull (cmcm)

Stratum C soil

air-filled porosity

(cmcm)

StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air

saturation permeability permeability

S|e k krg (cmcm) (cm) (cm)

Stratum A Floor-soil wall BIdg

effective vapor seam Soil ventilafion permeability perimeter gas rate

k^ bull Xack c o n e Qbuildins

(cm) (cm) (ngm) (cms)

946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |

Area of enclosed

space below grade

AB

(cm)

Ciack- to-total

area ratio

1 (unitless)

Crack depth below grade

Zcrack

(cm)

Enthalpy of vaporization at

ave soil temperature

A H J S

(calmol)

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law bull constant at

ave soil temperature

HTS

(unitless)

Vapor viscosity at

ave soil temperature

|JTS

(gcm^s)

Stratum A

effective diffusion

coefficient

(cms)

Stratum B

effective -diffusion

coefficient

D=B (cms)

Stratum ^ C effective diffusion

coefficient

D=c (cms)

Total overall

effective diffusion

coefficient

DT

(cms)

I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03

Diffusion path

length

Li (cm) bull

Convection bull path

length

Lp

(cm)

Source vapor cone bull

^source

(ngm)

Crack radius

rcrack

(cm)

Average vapor

- flow rate intobldg

Qsoil

(cms)

Crack effective diffusion

bull coefficient Qcrack

(cms)

Area of crack

^crack

(cm)

Exponent of equivalent foundation

Peclet bull number

exp(Pe)

(unitless)

bull bull

1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07

Infinite source Indoor

attenuation coefficient

a

(unitless)

108E-05

Infinite source

bIdg concgt

^building

(ngm)

844E-02

Unit risk

factor

URF

(ngm)-

Reference cone

RfC

(mgm)

1 1E-04 1 40E-02 1

END

Appx B-6 TCExIs 3 of 3 982009

AR100325

Office of Waste Management 1356 Hansford Street

Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256

West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director

ORDER

ISSUED UNDER THE

HAZARDOUS WASTE MANAGEMENT ACT

CHAPTER 22 ARTICLE 18

OF THE WEST VIRGINIA CODE^ AS AMENDED

y Order Number HW-011-80

To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704

ATTEMTION MREDARMON

Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull

AR100326

ViWJ011-laquo9 PageNunil)er2

BASIS FOR ORDER

As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following

A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^

B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator

C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities

0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94

^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement

P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following

1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater

2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was

^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment

CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable

CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order

AR100327

H W - 0 1 1 - 9 9 Page Number 3

REQUIREMENTS OF ORDER

Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows

1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^

2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore

remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling

GENERAL PROVaiONS

1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order

2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order

3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order

Effective Date

Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief

Wt T 1 V Oflice of Waste Management

AR100328

^ ^ S I S

^wmmmmamn

AR100329

Page 30: SDMS DocID 2121999 · International Enterprises Corp. building (Coyne Building), which is located at 1111 Vernon Street, Westmoreland District, Wayne County, West Virginia. The following

Tables B-1-B through B-6-B present the constituent-specific properties for COC that were used in the TF

calculations Tables B-1-C through B-6-C present the intermediate calculations used to determine the

indoor air attenuation coefficients (ie the transport factors) The shaded boxes in Tables B-1-C through

B-6-C also present the resulting TF values that are applied to the concentrations of COC in subslab

vapor and the estimated indoor air concentrations

References

American Society for Testing and Materials (ASTM 2002) Standard Guide for Risk-Based Corrective Action Applied at Petroleum Release Sites ASTM E-1739-95 (Reapproved 2002)

Johnson PC and RA Ettinger (1991) Heuristic model for predicting the intrusion r-ate of contaminant vapors into buildings Environ Sci Technolpgy 25 1445-1452

Dolphin Environmental LLC (Dolphin 2000) Site Characterization Report Mach 14 2000

United States Environmental Protection Agency (USEPA 2004) Users Guide for Evaluating Subsurface Vapor Intrusion into Buildings February 22 2004

AR100307

APPENDIX B-1-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV Nersion31 0204

Reset to Defaults

ENTER -

Chemical CAS No

(numbers only

no dasties)

95636

ENTER Soil gas

cone

Cg (ngm)

Soil Gas Concentration Data ENTER

Soil gas

OR cone

bull - c bull (PPmv)

197E+02

Chemical

124-Trimethylbenzene

MORE ENTER Depth

below grade to bottom

of enclosed space floor

U bull (cm)

ENTER

Soil gas sampling

depth below grade

U (cm) bull

ENTER

Average soil

temperature Ts

CO

1 15 1 1 5 bull125

ENTER ENTER ENTER Totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hft ha he

(cm) (cm) (cm)

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estirnate OR permeability | soil vapor

permeability) k v bull

(cm)

SL 1 1

MORE ENTER

stratum A SCS

soil type

Lookup Soil Parameters

ENTER stratum A soil dry

bulk density P

(gcm)

ENTER Stratum A soil total porosity

(unitless)

ENTER bull stratum A soil water-filled

porosity

(cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

nlaquo

(unitless)

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gchi-s^)

ENTER Enclosed

space floor

length bull LB

(cm)

ENTER Enclosed

space floor

width WB

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

bull Floor-wall seam crack

width w

(cm)

bullENTER

Indoor air exchange

rate ER

(1h) bull

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bidg OR

Leave blank to caicuij

(Lm)

Appx B-1 124-TMBxls 1 of 3 982009

AR100308

APPENDIX B-1-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of ^ bull law constant law constant vaporization at Normal

Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temperature boiling point point temperature weight

D bull Dbdquo H T R bull AHbdquo TB Tc IVIW

Unit risk Reference

factor cone URF RfC

(cms) (cmls) (atm-mmol) CO (calmol) (degK) (degK) (gmol) bull (ugm)- (mgm)

1 606E-02 1 792E-06 1 bull 614E-C3 1 25 1 9369 1 44230 | 64917 1 12020 1 OOE+00 1 60E-03 1

Appx B-1 124-TMBxls 2 of 3 982009

AR100309

APPENDIX B-1-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

(sec)

Source-building

separation

LT bull

(cm) bull

Stratum A soil

air-filled porosity

Q A

Stratum B soil

air-filled porosity

(cmcm) (cmcm)

Stratum C soil air-filled porosity

(cmcm)

Stratum A effective total fluid

saturation

Se

(cmcm)

Stratum A soil

bullintrinsic permeability

^ (cm)

stratum A Stratum A Floor- soil soli wall BIdg

relative air effective vapor seam Soil bull ventilation permeability permeability perimeter gas rate-

kfg ky Xgrack c o n e - QbuHdinpound

(cm) - (cm) (cm) (ngm) (cms)

946E+08 1 0284 0284 0284 0184 596E-09 0901 537E-09 35357 I 197E+02 | 439E+06 |

Area of enclosed

space below grade

As (cm)

Crack-to-total area ratio

1 bull

(unitless)

Crack depth

below grade

Zcfack

(cm)

Enthalpy of vaporization at

ave soil temperature

AHvjs

(calmol) bull

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law constant at

ave soil bull temperature

bull HTS

(unitless)

Vapor bull viscosity at

ave soil temperature

HTS

(gcm-s)

Stratum A

effective diffusion

coefficient

D (cms)

Stratum-B

effective diffusion coefficient

DB (cms)

Stratum C effective diffusion

coefficient

D-c (cms)

Total - overall effective diffusion

coefficient

D ^ (cms)

Diffusion path

length

L-

(cm)

I 787E+07 I 449E-05 | 15 | 11661 260E-03 111E-01 176E-04 I 612E-03 j OOOE+00 | OOOE+00 | 612E-03 j

bull Convection path

length

Lp

(cm)

Source vapor cone

^source

(ngm)

Crack radius

Tcfack

(cm)

Average vapor

flow rate into bIdg

Qsoii

(cms)

Crack effective diffusion

coefficient pcrack

(cms)

Area of CTack

Acack

(cm)

Exponent of equivalent foundation

Peclet number

exp(Pe)

(unitless)

bull bull - bull bull bull bull

1 15 1 197E+02 1 010 1 474E+01 612E-03 bull 354E-t-03 1 336E+09

Infinite source Indoor

~ attenuation coefficient

a

(unitless)

108E-05

Infinite source

btJbldgjJSv-L ^Ppncji3i-

virhpbiiilding bullbull ^lHltti^m)ilg

213E-03

Unit risk

factor

URF

(ngm)-

Reference cone

RfC (mgm)

NA 60E-03 1

I END

Appx B-1 124-TMBxls 3 of 3 982009

AR100310

APPENDIX B-2-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV Nersion31 020^

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

156592

Soil Gas Concentration Data ENTER

Soil gas

cone OR c

(ngm) bull

ENTER Soil bull-gas

cone

c (ppmv)

603E+03 1

Chemical

cis-12-Dichloroethylene

MORE ENTER Depth

below grade to bottom

of enclosed space floor

LF

(cm)

ENTER

Soil gas sampling

depth below grade

U (cm)

ENTER

Average soil

temperature bull Ts

(degC)

1 15 1 bull 15 125

ENTER ENTER ENTER Totalsmust add ijp tb value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hA hB he

bull (cm) (cm) (cm)

15 1 1

ENTER Soil

straturh A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estimate OR permeability | soil vapor

permeability) kv

(cm)

SL 1 |

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

P (gcm)

ENTER Stratum A soil total porosity

bull n

(unitless)

ENTER Stratum A

soil water-filled porosity

(cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

ENTER Stratum B

soil water-filled porosity

ENTER Stratum C

SCS soil type

(unitless) (cmcm)

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure differential

AP

(gcm-s)

ENTER Enclosed bull

space floor

length

LB (cm)

ENTER Enclosed

space floor

width WB

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER

Average vapor flow rate into bIdg

OR Leave blank to calculi

Qsoil

(Lm)

Appx B-2 cis-12-DCExls 1 of 3 982009

AR100311

APPENDIX B-2-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Diffusivity in air

Da

(cms)

Diffusivity in water

Dw (cms)

Henrys law constant at reference temperature

H

(atm-mmoi)

Henrys law constant

reference temperature

bull T R

CC)

Enthalpy of vaporization at

the normal boiling point

AHbdquob

(calmol)

Normal boiling point

TB

(degK)

Critical temperature

Tc (degK)

Molecular weight

MW

(gmol)

Unit risk

factor URF

(ngm)

Reference cone

RfC (mgm)

1 736E-02 1 113E-05 1 407E-03 j 1 25 1 bull 7192 1 33365 1 54400 1 9694 1 OOE+00 j 35E-02 1

Appx B-2 cis-12-DCExls 2 of 3 982009

AR100312

APPENDIX B-2-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

stratum A Stratum B Stratum C Source- soil soil soil

Exposure building air-filled air-filled air-filled

duration separation porosity porosity porosity

T LT ea e^ bull e= (sec) (cm) (cmcm) (cmcm) (cmcm)

I 946E+08n^

Stratum A Stratum A Stratum A Stratum A Floor-effective soil soil soil wall total fluid intrinsic relative air effective vapor seam

saturation permeability permeability permeability perimeter

Ste kj krg ky Acrack

(cmcm) (cm) (cm) (cm) (cm)

Soil gas

cone (ngm)

I 0284 I 0284~ 0284 0184 I 596E-09 | 090T 537E-09 35357 603E+03

BIdg ventilation

rate

JbulldinE

(cms)

439E+06

Area of enclosed

space below grade

AB

(cm)

Crack-to-total

area ratio

n (unitless)

Crack depth below grade

Zltiack (cm)

Erithalpy of vaporization at

ave soil temperature

AHvTs (calmol)

Henryslaw constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law constant at

ave soil temperature

HTS

(unitless) bull

Vapor viscosity at

ave soil bull temperature

HTS

bull (gcm-s)

Stratum A

effective bull diffusion

coefficient

D^A-(cms)

Stratum B

effective bull diffusion

coefficient

D=B

(cms)

Stratum C

effective diffusion bull

coefficient

D=e (cms)

Total overall

effective diffusion

coefficient

DT

(cms)

Diffusion path

length

Ld

(cm)

I 787E+07 I bull449E-05 | 15 bull7709 230E-03 982E-02 176E-04 | 743E-03 | OOOE+00 | OOOE+00 | 743E-03 |

bull bull bull -

Convecfion path -bull

length

Lp (cm)

Source vapor cone

-source

(Mgm)

Crack radius

fcrack

(cm)

Average vapor

flow rate into bIdg

Qaoil bull

(cms)

Crack effective diffusion

coefficient pcack

(cms)

Area of crack

crack

(cm)-

Exponent of equivalent foundation

Peclet number

exp(Pef)

(unitless)

bull

1 15 -1 603E+03 1 010 1 474E+01 743E-03 354E+03 1 697E+07

Infinite source Indoor

attenuation coefficient

poundbullbullbull C t

pound(unitless)

bullsiilaquogt j ii08E-05

Infinite [ source

bIdg cone

Cbujidjng

(pgm)

651 E-02 iKrt

Unit risk

factor

URF

(ngm)-

Reference cone

RfC

(mgm)

NA 35E-02 1

I END I

Appx B-2 cis-12-DCExls 3o f3 982009

AR100313

APPENDIX B-3-A DATA ENTRY SHEET

Coyne Texti le Services - Hunt ington West Virginia

SG-ADV Version 31 0204

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

67663

Soil Gas Concentration Data ENTER ENTER

Soil Soil gas gas

cone OR cone c C

(^gm) (ppmv)

591 E+03

bull

Chemical

Chloroform

MORE ENTER Depth

below grade tb bottom

of enclosed space floor

bull LF

(cm)

ENTER

Soil gas sampling depth

below grade

(cm)

ENTER

Average soil

temperature-Ts

CO bull

1 15 1 15 1 125

ENTER ENTER ENTER Totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

IIA hs he (cm) (cm) (cm)

1 5 bull 1 1

ENTER ENTER Soil - bull

stratum A User-defined SCS stratum A

soil type bull soil vapor (used to estimate OR permeability

soil vapor k

bull permeability) (cm) 1

SL 1 1 bull

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A soil dry

bulk density

Pb (gcm)

ENTER Stratum A soil total porosity

nV (unitless)

ENTER Stratum A

-soilwater-filled bullporosity

Sraquo (cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

(unitless)

ENTER Stratum B

soil water-filled porosity

bull ebdquo=

(cmcm) bull

ENTER Straturri C

SCS bull soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

- c rack

(cm)

ENTER

Soil-bldg pressure

differential AP^

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor

width bull W B

(cm)

ENTER

Enclosed space

height HB

(cm)

ENTER

bull Floor-wall^ seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bidg OR

Leave blank to calculi

Qsoil bull

(Lm)

I -I

Appx B-3 Chloroformxls 1 of 3 982009

AR100314

APPENDIX B-3-B CHEMICALPROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Diffusivity in air

D (cms)

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffijsivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature

Dbdquo H TR A H bdquo TB Tc

(cm s) (atm-m mol) ro (calmol) (degK) (degK)

Molecular weight

MW

(gmol)

Unit risk

factor URF

(ngm)-

Reference cone

RfC

(mgm)

104E-01 100E-05 I 366E-03 25 6988 33432 53640 11938 I 23E-05 | OOE+00

Appx B-3 Chloroformxls 2 of 3 982009

AR100315

APPENDIX B-3-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure

duration

(sec)

Source-

building

separation

LT

(cm)

Stratum A

soil

air-filled

porosity

Sa

( cm cm )

Stratum B

soil

air-filled

porosity

( cm cm )

Stratum C

soil

air-filled

porosity

( c m c m )

Stratum A

effective

total fluid

saturation

( c m c m )

Stratum A

soil

intrinsic

penmeability

k

(cm )

Stratum A

- soil

relative air

permeabil i ty

(cm )

Stratum A

soil

effective vapor

permeability

kv

(cm )

Floor-

wall

seam

perimeter

gtcrack

(cm)

Soil gas

cone

(ngm)

BIdg

venfilation

rate

^buildlriE

(cms)

I 9 4 6 E + 0 8 ~ T I 0284 T 596E-09 I 0-901 I 537E-09 | 35357 | 591 E+03 j 439E+06 | 1 0 284 0284 0184

Area of

enclosed

space

below

grade

A B

( c m )

Crack-

to-total

area

ratio

n

(unitless)

Crack

depth

bull below

grade

^crack

(cm)

Enthalpy of

vaporization at

ave soil

temperature

AHTs bull

(calmol)

Henry s law

constant at

ave soil

temperature

HTS

(a tm-m mol j

Henrys law

constant at

ave soil

bull temperature

HTS

(unitless) bull

Vapor

viscosity at

ave soil-

temperature

^HTS

(gcm-s)

Stratum

A

effective

diffusion

coefficient

(cm s)

Stratum

B

effective

difftjsion

coefficient

D B

(cms) bull

S t ra tum

C

effective

diffusion

coefficient

Dc

(cm s)

Total

overall

effective

bull diffusion

coefficient

D T

(cm s)

Diffi jsion

path

length

Ld

(cm)

I 787E+07 I 449E-05 j - bull 15 7528 210E-03 896E-02 176E-04 I 105E-02 | OOOE+00 | OOOE+00 | 105E-02

Convection

path length

Lp

(cm)

Source

vapor

cone -

^source

- (ngm)

Crack

radius

Tcrack

(cm)

Average

vapor

flow rate

into bidg

Qsoil

(cms)

Crack

effective

diffusion

coefficient Qcrack

bull (cms)

Area of crack

Acrack

(cm)

Exponent of

equivalent

foundation

Peclet number

exp(Pe)

(unitless)

V bull bull

1 15 1 591 E+03 1 010 1 474E+01 105E-02 354E+03 1 355E+05

Infinite

source

indoor

attenuation

coefficient

d

(unitless)

bull 108E-05

Infinite

source

bIdg

cone

^ b u i l d i n g

i (^gm)

bull bull

i 638E-02 -

Unit

risk bull factor

URF

(ngmY

Reference

cone

RfC

(mgm)

~ 23E-05 NA 1

I END

Appx B-3 Chloroform xls 3 of 3 982009

AR100316

APPENDIX B-4-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ersion 31-020^

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

nodashes)

bull 75092

ENTER Soil gas

cone

c (ngm)

Soil Gas Concentration Data ENTER

Soil gas bull

OR cone

bull C

(ppmv)

152E+03

bull bull

Chemical

Methylene chloride

MORE

MORE 4gt

ENTER Depth

below grade to bottom

of enclosed space floor

LF -

(cm)

ENTER

Soil gas sampling depth

below grade

bull U

(cm)

ENTER

Average soil

temperature

Ts bull CC)

bull bull bull bull

1 15 1 15 125

ENTER Totals

Thickness of soil

stratum A h

(cm)

ENTER ENTER must add up to value of Ls (cell F24

Thickness Thickness of soil of soil

stratum B stratum C (Enter value or 0) (Enter value or 0)

he he bull

(cm) bull (cm) -

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(usedto estimate OR perrrieability | soil vapor

permeability)

k bull

(cm)

SL 1 bull 1

ENTER Stratum A

SCS soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

Pb (gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Stratum A

soil water-filled porosity

9w (cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

Pb^

(gcm)

ENTER Stratum B soil total porosity

n^

(unitless)

ENTER Stratum B

soil water-filled porosity

(crhcm)

ENTER Stratum C

SCS soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE 4gt

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

bull Soil-bldg pressure

differential AP^

(gcm-s)

ENTER Enclosed

space floor

length LB

(cm)

ENTER Enclosed

space floor

width bull W B

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width

w

(cm)

ENTER

Indoor air exchange

rate

ER (1h)

ENTER Average vapor

flow rate into bidg OR

Leave blank to calculc

Qsoil

(Lm)

10 40 8839 8839 244 01 083

Appx B-4 MCxIs 1 of 3 982009

AR100317

Diffijsivity in air

D

APPENDIX B-4-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffusivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature

Pw H TR AHt TB TC

Molecular weight

MW

Unit risk

factor URF

Reference cone

RfC

(cms) (cms) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) bull (ngm)- (mgm)

bull bull

1 101E-01 1 117E-05 1 218E-03 1 25 | 6706 1 31300 1 51000 1 8493 1 47E-07 1 30E+00 1

Appx B-4 MCxIs 2 of 3 982009

AR100318

APPENDIX B-4-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

T

(sec)

Source- -building

separation

LT

(cm)

Stratum A soil

air-filled porosity

e a bull

(cmcm)

Stratum B soil

bullair-filled porosity bull

ea^ (cmcm)

Stratum C soil

air-filled porosity

ea= (cmcmj

Stratum A effective total fluid

saturation

Sc bull

(cmcm)

Stratum A soil

intrinsic pemneability

ki (cm)

Stratum A soil

relative air permeability

^ ^ g

(cm)

stratumA bull soil effective vapor permeability

K (cm)

Floor-wall

seam perimeter

Xcrack

(cm)

Soil gas

cone (ngm)

BIdg ventilation

rate

Qbuildinc

(cms)

1 946E+08

Area of -enclosed

space below

bull grade

AB

(cm)

1

Crack-to-total

area rafio

Tl

(unitless)

0284 1

Crack depth below grade

Zcrack

(cm)

0284 1

bull Enthalpy of vaporization at

ave soil temperature

AHTs (calmol)

0284

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

0184

Henrys law constant at ave soil

temperature

HTS

bull (unitless)

1 596E-09

Vapor viscosity at

ave soil temperature

Mrs (gcm-s)

0901

Stratum A

effective diffusion

coefficient

D (cms)

537E-09

Stratum B

effective diffusion

coefficient

D-B (cms)

35357 1

Stratum C -

effective diffusion

coefficient

D-c ^ (cms)

152E+03

Total bull overall

bull effective diffusion

coefficient

D ^

(cms)

440E+06 1

Difftjsion path

length

Ld (cm)

1 787E+07

Convection path

length

Lp (cm)

4 49E-05

Source vapor cone

Csource

(ngm)

15 1

Crack radius

Tcrack

(cm)

7007 bull 1

Average vapor

flow rate intobldg

Qsoil

(cms)

130E-03

Crack effective diffusion

coefficient pcrack

(cms)-

555E-02

bull ^

Area of crack

Acrack

(cm) bull

1 176E-04

Exponent of equivalent foundation

Peclet number

exp(Pe)

(unitless) bull

bull bull

1 15

1 END

152E+03 010 1 474E+01 1 102E-02 354E+03 1 519E+05

102E-02

Infinite source

indoor ^attenuation coefficient

bull a

(unitless)

aiii08E-05

0 OOE+00

bull

Infinite bull source

bIdg ^ cone

^bu i l d i ng

(MQm)

164E-02

OOOE+00 1

Unit risk

factor

URF

(ngm)-

47E-07 1

102E-02 j

Reference cone

RfC

(mgm)

30E+00 j

1 1

Appx B-4 MCxIs 3 of 3 982009

AR100319

APPENDIX B-5-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ^erslon 31 0204

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

127184

Soil Gas Concentration Data ENTER ^ ENTER

Soil -Soi l bull gas gas

cone OR cone Cg C bull

(tgm) (ppmv)

149E+05 1

Chemical

bull Tetrachlbroethylene

MORE 4

ENTER Depth

below grade to bottom

ofenclosecJ space floor

LF

(cm)

ENTER

Soil gas bull sampling

depth below grade

u bull (cm)

ENTER

Average bullsoil

temperature - Ts

ro 1 1 5 1 15 1 125 bull

ENTER ENTER ENTER totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hft bull he bull he

(cm) (cm) (cm)

bull 1 5 1 - 1

ENTER ENTER Soil

stratum A User^defined bull SCS bull stratum A soil type soil vapor

(used to estimate OR perrrieability soil vapor K bull

permeability) (cm) 1

SL 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

Pb

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Sitratum A

soil water-filled bull porosity

(cmcm)

ENTER Stratum B

SCS soiltype

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

Pb^

(gcm)

ENTER Stratum B soil total porosity

Ajnitless^

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS soil type

LookupSoil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

VS

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor width

W B

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width

w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

ENTER Average vapor

flow rate into bidg OR

Leave blank to calcul

bull Qsoil

(Lm)

10 40 8839 8839 244 01 083

Appx B-5 PCExIS 1 of 3 982009

AR100320

APPENDIX B-5-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal Unit

Diffusivity Diffusivity at reference reference the riormal boiling Critical Molecular risk Reference in air in water temperature temperature boiling point point teriiperature weight factor cone

Da Dbdquo H TR AHb TB Tc MW URF RfC

(cms) (cnis) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) (^gm)- (mgm)

1 720E-02 1 820E-06 1 184E-02 1 25 1 8288 1 39440 1 62020 1 16583 1 59E-06 1 60E-01 1

J

AppxB-5PCExls 2 of 3 - 982009

AR100321

APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

T

(sec)

Source-building

separation

LT

bull (cm)

Stratum A soil

air-filled porosity

Oa (cmcm)

Stratum B - soil air-filled porosity

ea (cmcm)

Stratum C soil

air-filled porosity

ea= - (cmcm)

Stratum A effective total fluid

saturation

sbdquo (cmcm)

Stratum A soil

intrinsic permeability

ki (cm)

Stratum A soil

relative air permeability

- ^ g

(cm)

Stratum A soil

effective vapor permeability

kv (cm)

Floor-wall

seam perimeter

^crack

(cm)

Soil gas

cone

(ngm)

BIdg venfilation

rate

Qbuildins

bull (cms)

bull bull

1 946E+08

Area of enclosed

space below grade

AB

(cm)

1

bullCrack-to-total

area ratio

1 (unitless)

0284 1

Crack bull depth below grade

Zcrack

(cm) -

0284 1

Enthalpy of vaporization at bull

ave soil temperature

bull A H V TS

(calmol)

0284

Henrys law constant at

ave soil temperature

HTS (atm-mmol)

0184

-Henrys law constant at

ave soil temperature

HTS

(unitless)

1 596E-09

Vapor viscosity at

ave soil temperature

HTS

(gcm-s)

0901

Stratum A

effective diffusion

coefficient bull D = bull

(cms)

537E-09

Stratum B

effective diffusion

coefficient

D--B (cms)

35357 1

Stratum C

effective diffusion bull

coefficient

D-c (crris)

149E+05

Total overall

effective bulldiffusion coefficient

DT

(cms)

440E+06 1

Difftjsion path

length

U (cm)

1 787E+07

Convection path

length

bull Lp

(cm)

4 49E-05

Source vapor cone

^source

(ngm)

15 1

Crack radius

Tcrack

(cm)

9528 1

Average vapor

flow rate intobldg

Qsoil (cms)

908E-03

Crack effective diffusion

coefficient pcrack

bull ( c m s ) bull

387E-01

Area of crack

Abdquoack (cm)

1 176E-04

Exponent of equivalent foundafion

Peclet number

exp(Pe)

(unitless)

bull

1 15-

1 END

149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08

727E-03

Infinite source indoor

attenuation coefficient

a

(unitless)

108E-05

OOOE+00

Infinite source

bIdg cone

Cburldtng

(Mgm)

161 E+00

OOOE+00 1

Unit risk

factor

URF

(ugm)-

59E-06 1

727E-03

Reference cone

RfC (mgm)

60E-01

1 1

Appx B-5 PCExls 3 of 3 982009

AR100322

APPENDIX B-6-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ersion31 0204

Reset to Defaults

t

Soil Gas Concentration Data ENTER

Chemical CAS No

(numbers only

no dashes)

79016

ENTER ENTER Soil Soil gas gas

cone OR cone C C -

bull (ngm) (ppmv)

782E+03

Chemical

Trichloroethylene

MORE ENTER Depth

below grade to bottom-

of enclosed space floor

LF

(cm)

ENTER

Soil gas sarnpling

depth below grade

U (cm)

ENTER

Average soil

temperature Ts

(degC)

1 15 1 15 t 125

ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e

(cm) (cm) (cm)

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estimate OR permeability soil vapor

permeability)

k (cm)

bull S L 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil bull-Parameters

ENTER Stratum A

soil dry bulk density

P b -

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Stratum A bull

soilwaterrfilled porosity

(cmcm) bull

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

bull P ^ (gcm)

ENTER Stratum B soil total

porosity

nlaquo

(unitless) -

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS bull soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor

width W B

(cm)

ENTER

Enclosed space height

H B bull

( c m ) bull

ENTER

Floor-wall seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bIdg OR

Leave blank to calculc

Qsoil

(Lm) -

Appx B-6 TCExIs 1 of 3 982009

A

AR100323

APPENDIX B-6-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight

Da Dbdquo H TR AH^b TB TC MW

Unit risk Reference

factor cone URF RfC

(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)

1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1

Appx B-6 TCExIs 2 of 3 982009

AR100324

APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

(sec)

Source-building

separation LT

(cm)

Stratum A soil

air-filled porosity

bull ea (cmcm)

Stratum B Soil

air-fllled porosity

e^ bull (cmcm)

Stratum C soil

air-filled porosity

(cmcm)

StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air

saturation permeability permeability

S|e k krg (cmcm) (cm) (cm)

Stratum A Floor-soil wall BIdg

effective vapor seam Soil ventilafion permeability perimeter gas rate

k^ bull Xack c o n e Qbuildins

(cm) (cm) (ngm) (cms)

946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |

Area of enclosed

space below grade

AB

(cm)

Ciack- to-total

area ratio

1 (unitless)

Crack depth below grade

Zcrack

(cm)

Enthalpy of vaporization at

ave soil temperature

A H J S

(calmol)

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law bull constant at

ave soil temperature

HTS

(unitless)

Vapor viscosity at

ave soil temperature

|JTS

(gcm^s)

Stratum A

effective diffusion

coefficient

(cms)

Stratum B

effective -diffusion

coefficient

D=B (cms)

Stratum ^ C effective diffusion

coefficient

D=c (cms)

Total overall

effective diffusion

coefficient

DT

(cms)

I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03

Diffusion path

length

Li (cm) bull

Convection bull path

length

Lp

(cm)

Source vapor cone bull

^source

(ngm)

Crack radius

rcrack

(cm)

Average vapor

- flow rate intobldg

Qsoil

(cms)

Crack effective diffusion

bull coefficient Qcrack

(cms)

Area of crack

^crack

(cm)

Exponent of equivalent foundation

Peclet bull number

exp(Pe)

(unitless)

bull bull

1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07

Infinite source Indoor

attenuation coefficient

a

(unitless)

108E-05

Infinite source

bIdg concgt

^building

(ngm)

844E-02

Unit risk

factor

URF

(ngm)-

Reference cone

RfC

(mgm)

1 1E-04 1 40E-02 1

END

Appx B-6 TCExIs 3 of 3 982009

AR100325

Office of Waste Management 1356 Hansford Street

Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256

West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director

ORDER

ISSUED UNDER THE

HAZARDOUS WASTE MANAGEMENT ACT

CHAPTER 22 ARTICLE 18

OF THE WEST VIRGINIA CODE^ AS AMENDED

y Order Number HW-011-80

To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704

ATTEMTION MREDARMON

Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull

AR100326

ViWJ011-laquo9 PageNunil)er2

BASIS FOR ORDER

As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following

A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^

B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator

C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities

0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94

^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement

P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following

1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater

2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was

^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment

CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable

CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order

AR100327

H W - 0 1 1 - 9 9 Page Number 3

REQUIREMENTS OF ORDER

Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows

1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^

2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore

remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling

GENERAL PROVaiONS

1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order

2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order

3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order

Effective Date

Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief

Wt T 1 V Oflice of Waste Management

AR100328

^ ^ S I S

^wmmmmamn

AR100329

Page 31: SDMS DocID 2121999 · International Enterprises Corp. building (Coyne Building), which is located at 1111 Vernon Street, Westmoreland District, Wayne County, West Virginia. The following

APPENDIX B-1-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV Nersion31 0204

Reset to Defaults

ENTER -

Chemical CAS No

(numbers only

no dasties)

95636

ENTER Soil gas

cone

Cg (ngm)

Soil Gas Concentration Data ENTER

Soil gas

OR cone

bull - c bull (PPmv)

197E+02

Chemical

124-Trimethylbenzene

MORE ENTER Depth

below grade to bottom

of enclosed space floor

U bull (cm)

ENTER

Soil gas sampling

depth below grade

U (cm) bull

ENTER

Average soil

temperature Ts

CO

1 15 1 1 5 bull125

ENTER ENTER ENTER Totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hft ha he

(cm) (cm) (cm)

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estirnate OR permeability | soil vapor

permeability) k v bull

(cm)

SL 1 1

MORE ENTER

stratum A SCS

soil type

Lookup Soil Parameters

ENTER stratum A soil dry

bulk density P

(gcm)

ENTER Stratum A soil total porosity

(unitless)

ENTER bull stratum A soil water-filled

porosity

(cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

nlaquo

(unitless)

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gchi-s^)

ENTER Enclosed

space floor

length bull LB

(cm)

ENTER Enclosed

space floor

width WB

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

bull Floor-wall seam crack

width w

(cm)

bullENTER

Indoor air exchange

rate ER

(1h) bull

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bidg OR

Leave blank to caicuij

(Lm)

Appx B-1 124-TMBxls 1 of 3 982009

AR100308

APPENDIX B-1-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of ^ bull law constant law constant vaporization at Normal

Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temperature boiling point point temperature weight

D bull Dbdquo H T R bull AHbdquo TB Tc IVIW

Unit risk Reference

factor cone URF RfC

(cms) (cmls) (atm-mmol) CO (calmol) (degK) (degK) (gmol) bull (ugm)- (mgm)

1 606E-02 1 792E-06 1 bull 614E-C3 1 25 1 9369 1 44230 | 64917 1 12020 1 OOE+00 1 60E-03 1

Appx B-1 124-TMBxls 2 of 3 982009

AR100309

APPENDIX B-1-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

(sec)

Source-building

separation

LT bull

(cm) bull

Stratum A soil

air-filled porosity

Q A

Stratum B soil

air-filled porosity

(cmcm) (cmcm)

Stratum C soil air-filled porosity

(cmcm)

Stratum A effective total fluid

saturation

Se

(cmcm)

Stratum A soil

bullintrinsic permeability

^ (cm)

stratum A Stratum A Floor- soil soli wall BIdg

relative air effective vapor seam Soil bull ventilation permeability permeability perimeter gas rate-

kfg ky Xgrack c o n e - QbuHdinpound

(cm) - (cm) (cm) (ngm) (cms)

946E+08 1 0284 0284 0284 0184 596E-09 0901 537E-09 35357 I 197E+02 | 439E+06 |

Area of enclosed

space below grade

As (cm)

Crack-to-total area ratio

1 bull

(unitless)

Crack depth

below grade

Zcfack

(cm)

Enthalpy of vaporization at

ave soil temperature

AHvjs

(calmol) bull

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law constant at

ave soil bull temperature

bull HTS

(unitless)

Vapor bull viscosity at

ave soil temperature

HTS

(gcm-s)

Stratum A

effective diffusion

coefficient

D (cms)

Stratum-B

effective diffusion coefficient

DB (cms)

Stratum C effective diffusion

coefficient

D-c (cms)

Total - overall effective diffusion

coefficient

D ^ (cms)

Diffusion path

length

L-

(cm)

I 787E+07 I 449E-05 | 15 | 11661 260E-03 111E-01 176E-04 I 612E-03 j OOOE+00 | OOOE+00 | 612E-03 j

bull Convection path

length

Lp

(cm)

Source vapor cone

^source

(ngm)

Crack radius

Tcfack

(cm)

Average vapor

flow rate into bIdg

Qsoii

(cms)

Crack effective diffusion

coefficient pcrack

(cms)

Area of CTack

Acack

(cm)

Exponent of equivalent foundation

Peclet number

exp(Pe)

(unitless)

bull bull - bull bull bull bull

1 15 1 197E+02 1 010 1 474E+01 612E-03 bull 354E-t-03 1 336E+09

Infinite source Indoor

~ attenuation coefficient

a

(unitless)

108E-05

Infinite source

btJbldgjJSv-L ^Ppncji3i-

virhpbiiilding bullbull ^lHltti^m)ilg

213E-03

Unit risk

factor

URF

(ngm)-

Reference cone

RfC (mgm)

NA 60E-03 1

I END

Appx B-1 124-TMBxls 3 of 3 982009

AR100310

APPENDIX B-2-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV Nersion31 020^

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

156592

Soil Gas Concentration Data ENTER

Soil gas

cone OR c

(ngm) bull

ENTER Soil bull-gas

cone

c (ppmv)

603E+03 1

Chemical

cis-12-Dichloroethylene

MORE ENTER Depth

below grade to bottom

of enclosed space floor

LF

(cm)

ENTER

Soil gas sampling

depth below grade

U (cm)

ENTER

Average soil

temperature bull Ts

(degC)

1 15 1 bull 15 125

ENTER ENTER ENTER Totalsmust add ijp tb value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hA hB he

bull (cm) (cm) (cm)

15 1 1

ENTER Soil

straturh A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estimate OR permeability | soil vapor

permeability) kv

(cm)

SL 1 |

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

P (gcm)

ENTER Stratum A soil total porosity

bull n

(unitless)

ENTER Stratum A

soil water-filled porosity

(cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

ENTER Stratum B

soil water-filled porosity

ENTER Stratum C

SCS soil type

(unitless) (cmcm)

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure differential

AP

(gcm-s)

ENTER Enclosed bull

space floor

length

LB (cm)

ENTER Enclosed

space floor

width WB

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER

Average vapor flow rate into bIdg

OR Leave blank to calculi

Qsoil

(Lm)

Appx B-2 cis-12-DCExls 1 of 3 982009

AR100311

APPENDIX B-2-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Diffusivity in air

Da

(cms)

Diffusivity in water

Dw (cms)

Henrys law constant at reference temperature

H

(atm-mmoi)

Henrys law constant

reference temperature

bull T R

CC)

Enthalpy of vaporization at

the normal boiling point

AHbdquob

(calmol)

Normal boiling point

TB

(degK)

Critical temperature

Tc (degK)

Molecular weight

MW

(gmol)

Unit risk

factor URF

(ngm)

Reference cone

RfC (mgm)

1 736E-02 1 113E-05 1 407E-03 j 1 25 1 bull 7192 1 33365 1 54400 1 9694 1 OOE+00 j 35E-02 1

Appx B-2 cis-12-DCExls 2 of 3 982009

AR100312

APPENDIX B-2-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

stratum A Stratum B Stratum C Source- soil soil soil

Exposure building air-filled air-filled air-filled

duration separation porosity porosity porosity

T LT ea e^ bull e= (sec) (cm) (cmcm) (cmcm) (cmcm)

I 946E+08n^

Stratum A Stratum A Stratum A Stratum A Floor-effective soil soil soil wall total fluid intrinsic relative air effective vapor seam

saturation permeability permeability permeability perimeter

Ste kj krg ky Acrack

(cmcm) (cm) (cm) (cm) (cm)

Soil gas

cone (ngm)

I 0284 I 0284~ 0284 0184 I 596E-09 | 090T 537E-09 35357 603E+03

BIdg ventilation

rate

JbulldinE

(cms)

439E+06

Area of enclosed

space below grade

AB

(cm)

Crack-to-total

area ratio

n (unitless)

Crack depth below grade

Zltiack (cm)

Erithalpy of vaporization at

ave soil temperature

AHvTs (calmol)

Henryslaw constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law constant at

ave soil temperature

HTS

(unitless) bull

Vapor viscosity at

ave soil bull temperature

HTS

bull (gcm-s)

Stratum A

effective bull diffusion

coefficient

D^A-(cms)

Stratum B

effective bull diffusion

coefficient

D=B

(cms)

Stratum C

effective diffusion bull

coefficient

D=e (cms)

Total overall

effective diffusion

coefficient

DT

(cms)

Diffusion path

length

Ld

(cm)

I 787E+07 I bull449E-05 | 15 bull7709 230E-03 982E-02 176E-04 | 743E-03 | OOOE+00 | OOOE+00 | 743E-03 |

bull bull bull -

Convecfion path -bull

length

Lp (cm)

Source vapor cone

-source

(Mgm)

Crack radius

fcrack

(cm)

Average vapor

flow rate into bIdg

Qaoil bull

(cms)

Crack effective diffusion

coefficient pcack

(cms)

Area of crack

crack

(cm)-

Exponent of equivalent foundation

Peclet number

exp(Pef)

(unitless)

bull

1 15 -1 603E+03 1 010 1 474E+01 743E-03 354E+03 1 697E+07

Infinite source Indoor

attenuation coefficient

poundbullbullbull C t

pound(unitless)

bullsiilaquogt j ii08E-05

Infinite [ source

bIdg cone

Cbujidjng

(pgm)

651 E-02 iKrt

Unit risk

factor

URF

(ngm)-

Reference cone

RfC

(mgm)

NA 35E-02 1

I END I

Appx B-2 cis-12-DCExls 3o f3 982009

AR100313

APPENDIX B-3-A DATA ENTRY SHEET

Coyne Texti le Services - Hunt ington West Virginia

SG-ADV Version 31 0204

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

67663

Soil Gas Concentration Data ENTER ENTER

Soil Soil gas gas

cone OR cone c C

(^gm) (ppmv)

591 E+03

bull

Chemical

Chloroform

MORE ENTER Depth

below grade tb bottom

of enclosed space floor

bull LF

(cm)

ENTER

Soil gas sampling depth

below grade

(cm)

ENTER

Average soil

temperature-Ts

CO bull

1 15 1 15 1 125

ENTER ENTER ENTER Totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

IIA hs he (cm) (cm) (cm)

1 5 bull 1 1

ENTER ENTER Soil - bull

stratum A User-defined SCS stratum A

soil type bull soil vapor (used to estimate OR permeability

soil vapor k

bull permeability) (cm) 1

SL 1 1 bull

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A soil dry

bulk density

Pb (gcm)

ENTER Stratum A soil total porosity

nV (unitless)

ENTER Stratum A

-soilwater-filled bullporosity

Sraquo (cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

(unitless)

ENTER Stratum B

soil water-filled porosity

bull ebdquo=

(cmcm) bull

ENTER Straturri C

SCS bull soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

- c rack

(cm)

ENTER

Soil-bldg pressure

differential AP^

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor

width bull W B

(cm)

ENTER

Enclosed space

height HB

(cm)

ENTER

bull Floor-wall^ seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bidg OR

Leave blank to calculi

Qsoil bull

(Lm)

I -I

Appx B-3 Chloroformxls 1 of 3 982009

AR100314

APPENDIX B-3-B CHEMICALPROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Diffusivity in air

D (cms)

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffijsivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature

Dbdquo H TR A H bdquo TB Tc

(cm s) (atm-m mol) ro (calmol) (degK) (degK)

Molecular weight

MW

(gmol)

Unit risk

factor URF

(ngm)-

Reference cone

RfC

(mgm)

104E-01 100E-05 I 366E-03 25 6988 33432 53640 11938 I 23E-05 | OOE+00

Appx B-3 Chloroformxls 2 of 3 982009

AR100315

APPENDIX B-3-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure

duration

(sec)

Source-

building

separation

LT

(cm)

Stratum A

soil

air-filled

porosity

Sa

( cm cm )

Stratum B

soil

air-filled

porosity

( cm cm )

Stratum C

soil

air-filled

porosity

( c m c m )

Stratum A

effective

total fluid

saturation

( c m c m )

Stratum A

soil

intrinsic

penmeability

k

(cm )

Stratum A

- soil

relative air

permeabil i ty

(cm )

Stratum A

soil

effective vapor

permeability

kv

(cm )

Floor-

wall

seam

perimeter

gtcrack

(cm)

Soil gas

cone

(ngm)

BIdg

venfilation

rate

^buildlriE

(cms)

I 9 4 6 E + 0 8 ~ T I 0284 T 596E-09 I 0-901 I 537E-09 | 35357 | 591 E+03 j 439E+06 | 1 0 284 0284 0184

Area of

enclosed

space

below

grade

A B

( c m )

Crack-

to-total

area

ratio

n

(unitless)

Crack

depth

bull below

grade

^crack

(cm)

Enthalpy of

vaporization at

ave soil

temperature

AHTs bull

(calmol)

Henry s law

constant at

ave soil

temperature

HTS

(a tm-m mol j

Henrys law

constant at

ave soil

bull temperature

HTS

(unitless) bull

Vapor

viscosity at

ave soil-

temperature

^HTS

(gcm-s)

Stratum

A

effective

diffusion

coefficient

(cm s)

Stratum

B

effective

difftjsion

coefficient

D B

(cms) bull

S t ra tum

C

effective

diffusion

coefficient

Dc

(cm s)

Total

overall

effective

bull diffusion

coefficient

D T

(cm s)

Diffi jsion

path

length

Ld

(cm)

I 787E+07 I 449E-05 j - bull 15 7528 210E-03 896E-02 176E-04 I 105E-02 | OOOE+00 | OOOE+00 | 105E-02

Convection

path length

Lp

(cm)

Source

vapor

cone -

^source

- (ngm)

Crack

radius

Tcrack

(cm)

Average

vapor

flow rate

into bidg

Qsoil

(cms)

Crack

effective

diffusion

coefficient Qcrack

bull (cms)

Area of crack

Acrack

(cm)

Exponent of

equivalent

foundation

Peclet number

exp(Pe)

(unitless)

V bull bull

1 15 1 591 E+03 1 010 1 474E+01 105E-02 354E+03 1 355E+05

Infinite

source

indoor

attenuation

coefficient

d

(unitless)

bull 108E-05

Infinite

source

bIdg

cone

^ b u i l d i n g

i (^gm)

bull bull

i 638E-02 -

Unit

risk bull factor

URF

(ngmY

Reference

cone

RfC

(mgm)

~ 23E-05 NA 1

I END

Appx B-3 Chloroform xls 3 of 3 982009

AR100316

APPENDIX B-4-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ersion 31-020^

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

nodashes)

bull 75092

ENTER Soil gas

cone

c (ngm)

Soil Gas Concentration Data ENTER

Soil gas bull

OR cone

bull C

(ppmv)

152E+03

bull bull

Chemical

Methylene chloride

MORE

MORE 4gt

ENTER Depth

below grade to bottom

of enclosed space floor

LF -

(cm)

ENTER

Soil gas sampling depth

below grade

bull U

(cm)

ENTER

Average soil

temperature

Ts bull CC)

bull bull bull bull

1 15 1 15 125

ENTER Totals

Thickness of soil

stratum A h

(cm)

ENTER ENTER must add up to value of Ls (cell F24

Thickness Thickness of soil of soil

stratum B stratum C (Enter value or 0) (Enter value or 0)

he he bull

(cm) bull (cm) -

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(usedto estimate OR perrrieability | soil vapor

permeability)

k bull

(cm)

SL 1 bull 1

ENTER Stratum A

SCS soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

Pb (gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Stratum A

soil water-filled porosity

9w (cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

Pb^

(gcm)

ENTER Stratum B soil total porosity

n^

(unitless)

ENTER Stratum B

soil water-filled porosity

(crhcm)

ENTER Stratum C

SCS soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE 4gt

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

bull Soil-bldg pressure

differential AP^

(gcm-s)

ENTER Enclosed

space floor

length LB

(cm)

ENTER Enclosed

space floor

width bull W B

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width

w

(cm)

ENTER

Indoor air exchange

rate

ER (1h)

ENTER Average vapor

flow rate into bidg OR

Leave blank to calculc

Qsoil

(Lm)

10 40 8839 8839 244 01 083

Appx B-4 MCxIs 1 of 3 982009

AR100317

Diffijsivity in air

D

APPENDIX B-4-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffusivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature

Pw H TR AHt TB TC

Molecular weight

MW

Unit risk

factor URF

Reference cone

RfC

(cms) (cms) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) bull (ngm)- (mgm)

bull bull

1 101E-01 1 117E-05 1 218E-03 1 25 | 6706 1 31300 1 51000 1 8493 1 47E-07 1 30E+00 1

Appx B-4 MCxIs 2 of 3 982009

AR100318

APPENDIX B-4-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

T

(sec)

Source- -building

separation

LT

(cm)

Stratum A soil

air-filled porosity

e a bull

(cmcm)

Stratum B soil

bullair-filled porosity bull

ea^ (cmcm)

Stratum C soil

air-filled porosity

ea= (cmcmj

Stratum A effective total fluid

saturation

Sc bull

(cmcm)

Stratum A soil

intrinsic pemneability

ki (cm)

Stratum A soil

relative air permeability

^ ^ g

(cm)

stratumA bull soil effective vapor permeability

K (cm)

Floor-wall

seam perimeter

Xcrack

(cm)

Soil gas

cone (ngm)

BIdg ventilation

rate

Qbuildinc

(cms)

1 946E+08

Area of -enclosed

space below

bull grade

AB

(cm)

1

Crack-to-total

area rafio

Tl

(unitless)

0284 1

Crack depth below grade

Zcrack

(cm)

0284 1

bull Enthalpy of vaporization at

ave soil temperature

AHTs (calmol)

0284

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

0184

Henrys law constant at ave soil

temperature

HTS

bull (unitless)

1 596E-09

Vapor viscosity at

ave soil temperature

Mrs (gcm-s)

0901

Stratum A

effective diffusion

coefficient

D (cms)

537E-09

Stratum B

effective diffusion

coefficient

D-B (cms)

35357 1

Stratum C -

effective diffusion

coefficient

D-c ^ (cms)

152E+03

Total bull overall

bull effective diffusion

coefficient

D ^

(cms)

440E+06 1

Difftjsion path

length

Ld (cm)

1 787E+07

Convection path

length

Lp (cm)

4 49E-05

Source vapor cone

Csource

(ngm)

15 1

Crack radius

Tcrack

(cm)

7007 bull 1

Average vapor

flow rate intobldg

Qsoil

(cms)

130E-03

Crack effective diffusion

coefficient pcrack

(cms)-

555E-02

bull ^

Area of crack

Acrack

(cm) bull

1 176E-04

Exponent of equivalent foundation

Peclet number

exp(Pe)

(unitless) bull

bull bull

1 15

1 END

152E+03 010 1 474E+01 1 102E-02 354E+03 1 519E+05

102E-02

Infinite source

indoor ^attenuation coefficient

bull a

(unitless)

aiii08E-05

0 OOE+00

bull

Infinite bull source

bIdg ^ cone

^bu i l d i ng

(MQm)

164E-02

OOOE+00 1

Unit risk

factor

URF

(ngm)-

47E-07 1

102E-02 j

Reference cone

RfC

(mgm)

30E+00 j

1 1

Appx B-4 MCxIs 3 of 3 982009

AR100319

APPENDIX B-5-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ^erslon 31 0204

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

127184

Soil Gas Concentration Data ENTER ^ ENTER

Soil -Soi l bull gas gas

cone OR cone Cg C bull

(tgm) (ppmv)

149E+05 1

Chemical

bull Tetrachlbroethylene

MORE 4

ENTER Depth

below grade to bottom

ofenclosecJ space floor

LF

(cm)

ENTER

Soil gas bull sampling

depth below grade

u bull (cm)

ENTER

Average bullsoil

temperature - Ts

ro 1 1 5 1 15 1 125 bull

ENTER ENTER ENTER totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hft bull he bull he

(cm) (cm) (cm)

bull 1 5 1 - 1

ENTER ENTER Soil

stratum A User^defined bull SCS bull stratum A soil type soil vapor

(used to estimate OR perrrieability soil vapor K bull

permeability) (cm) 1

SL 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

Pb

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Sitratum A

soil water-filled bull porosity

(cmcm)

ENTER Stratum B

SCS soiltype

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

Pb^

(gcm)

ENTER Stratum B soil total porosity

Ajnitless^

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS soil type

LookupSoil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

VS

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor width

W B

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width

w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

ENTER Average vapor

flow rate into bidg OR

Leave blank to calcul

bull Qsoil

(Lm)

10 40 8839 8839 244 01 083

Appx B-5 PCExIS 1 of 3 982009

AR100320

APPENDIX B-5-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal Unit

Diffusivity Diffusivity at reference reference the riormal boiling Critical Molecular risk Reference in air in water temperature temperature boiling point point teriiperature weight factor cone

Da Dbdquo H TR AHb TB Tc MW URF RfC

(cms) (cnis) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) (^gm)- (mgm)

1 720E-02 1 820E-06 1 184E-02 1 25 1 8288 1 39440 1 62020 1 16583 1 59E-06 1 60E-01 1

J

AppxB-5PCExls 2 of 3 - 982009

AR100321

APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

T

(sec)

Source-building

separation

LT

bull (cm)

Stratum A soil

air-filled porosity

Oa (cmcm)

Stratum B - soil air-filled porosity

ea (cmcm)

Stratum C soil

air-filled porosity

ea= - (cmcm)

Stratum A effective total fluid

saturation

sbdquo (cmcm)

Stratum A soil

intrinsic permeability

ki (cm)

Stratum A soil

relative air permeability

- ^ g

(cm)

Stratum A soil

effective vapor permeability

kv (cm)

Floor-wall

seam perimeter

^crack

(cm)

Soil gas

cone

(ngm)

BIdg venfilation

rate

Qbuildins

bull (cms)

bull bull

1 946E+08

Area of enclosed

space below grade

AB

(cm)

1

bullCrack-to-total

area ratio

1 (unitless)

0284 1

Crack bull depth below grade

Zcrack

(cm) -

0284 1

Enthalpy of vaporization at bull

ave soil temperature

bull A H V TS

(calmol)

0284

Henrys law constant at

ave soil temperature

HTS (atm-mmol)

0184

-Henrys law constant at

ave soil temperature

HTS

(unitless)

1 596E-09

Vapor viscosity at

ave soil temperature

HTS

(gcm-s)

0901

Stratum A

effective diffusion

coefficient bull D = bull

(cms)

537E-09

Stratum B

effective diffusion

coefficient

D--B (cms)

35357 1

Stratum C

effective diffusion bull

coefficient

D-c (crris)

149E+05

Total overall

effective bulldiffusion coefficient

DT

(cms)

440E+06 1

Difftjsion path

length

U (cm)

1 787E+07

Convection path

length

bull Lp

(cm)

4 49E-05

Source vapor cone

^source

(ngm)

15 1

Crack radius

Tcrack

(cm)

9528 1

Average vapor

flow rate intobldg

Qsoil (cms)

908E-03

Crack effective diffusion

coefficient pcrack

bull ( c m s ) bull

387E-01

Area of crack

Abdquoack (cm)

1 176E-04

Exponent of equivalent foundafion

Peclet number

exp(Pe)

(unitless)

bull

1 15-

1 END

149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08

727E-03

Infinite source indoor

attenuation coefficient

a

(unitless)

108E-05

OOOE+00

Infinite source

bIdg cone

Cburldtng

(Mgm)

161 E+00

OOOE+00 1

Unit risk

factor

URF

(ugm)-

59E-06 1

727E-03

Reference cone

RfC (mgm)

60E-01

1 1

Appx B-5 PCExls 3 of 3 982009

AR100322

APPENDIX B-6-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ersion31 0204

Reset to Defaults

t

Soil Gas Concentration Data ENTER

Chemical CAS No

(numbers only

no dashes)

79016

ENTER ENTER Soil Soil gas gas

cone OR cone C C -

bull (ngm) (ppmv)

782E+03

Chemical

Trichloroethylene

MORE ENTER Depth

below grade to bottom-

of enclosed space floor

LF

(cm)

ENTER

Soil gas sarnpling

depth below grade

U (cm)

ENTER

Average soil

temperature Ts

(degC)

1 15 1 15 t 125

ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e

(cm) (cm) (cm)

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estimate OR permeability soil vapor

permeability)

k (cm)

bull S L 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil bull-Parameters

ENTER Stratum A

soil dry bulk density

P b -

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Stratum A bull

soilwaterrfilled porosity

(cmcm) bull

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

bull P ^ (gcm)

ENTER Stratum B soil total

porosity

nlaquo

(unitless) -

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS bull soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor

width W B

(cm)

ENTER

Enclosed space height

H B bull

( c m ) bull

ENTER

Floor-wall seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bIdg OR

Leave blank to calculc

Qsoil

(Lm) -

Appx B-6 TCExIs 1 of 3 982009

A

AR100323

APPENDIX B-6-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight

Da Dbdquo H TR AH^b TB TC MW

Unit risk Reference

factor cone URF RfC

(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)

1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1

Appx B-6 TCExIs 2 of 3 982009

AR100324

APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

(sec)

Source-building

separation LT

(cm)

Stratum A soil

air-filled porosity

bull ea (cmcm)

Stratum B Soil

air-fllled porosity

e^ bull (cmcm)

Stratum C soil

air-filled porosity

(cmcm)

StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air

saturation permeability permeability

S|e k krg (cmcm) (cm) (cm)

Stratum A Floor-soil wall BIdg

effective vapor seam Soil ventilafion permeability perimeter gas rate

k^ bull Xack c o n e Qbuildins

(cm) (cm) (ngm) (cms)

946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |

Area of enclosed

space below grade

AB

(cm)

Ciack- to-total

area ratio

1 (unitless)

Crack depth below grade

Zcrack

(cm)

Enthalpy of vaporization at

ave soil temperature

A H J S

(calmol)

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law bull constant at

ave soil temperature

HTS

(unitless)

Vapor viscosity at

ave soil temperature

|JTS

(gcm^s)

Stratum A

effective diffusion

coefficient

(cms)

Stratum B

effective -diffusion

coefficient

D=B (cms)

Stratum ^ C effective diffusion

coefficient

D=c (cms)

Total overall

effective diffusion

coefficient

DT

(cms)

I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03

Diffusion path

length

Li (cm) bull

Convection bull path

length

Lp

(cm)

Source vapor cone bull

^source

(ngm)

Crack radius

rcrack

(cm)

Average vapor

- flow rate intobldg

Qsoil

(cms)

Crack effective diffusion

bull coefficient Qcrack

(cms)

Area of crack

^crack

(cm)

Exponent of equivalent foundation

Peclet bull number

exp(Pe)

(unitless)

bull bull

1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07

Infinite source Indoor

attenuation coefficient

a

(unitless)

108E-05

Infinite source

bIdg concgt

^building

(ngm)

844E-02

Unit risk

factor

URF

(ngm)-

Reference cone

RfC

(mgm)

1 1E-04 1 40E-02 1

END

Appx B-6 TCExIs 3 of 3 982009

AR100325

Office of Waste Management 1356 Hansford Street

Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256

West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director

ORDER

ISSUED UNDER THE

HAZARDOUS WASTE MANAGEMENT ACT

CHAPTER 22 ARTICLE 18

OF THE WEST VIRGINIA CODE^ AS AMENDED

y Order Number HW-011-80

To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704

ATTEMTION MREDARMON

Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull

AR100326

ViWJ011-laquo9 PageNunil)er2

BASIS FOR ORDER

As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following

A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^

B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator

C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities

0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94

^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement

P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following

1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater

2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was

^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment

CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable

CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order

AR100327

H W - 0 1 1 - 9 9 Page Number 3

REQUIREMENTS OF ORDER

Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows

1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^

2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore

remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling

GENERAL PROVaiONS

1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order

2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order

3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order

Effective Date

Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief

Wt T 1 V Oflice of Waste Management

AR100328

^ ^ S I S

^wmmmmamn

AR100329

Page 32: SDMS DocID 2121999 · International Enterprises Corp. building (Coyne Building), which is located at 1111 Vernon Street, Westmoreland District, Wayne County, West Virginia. The following

APPENDIX B-1-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of ^ bull law constant law constant vaporization at Normal

Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temperature boiling point point temperature weight

D bull Dbdquo H T R bull AHbdquo TB Tc IVIW

Unit risk Reference

factor cone URF RfC

(cms) (cmls) (atm-mmol) CO (calmol) (degK) (degK) (gmol) bull (ugm)- (mgm)

1 606E-02 1 792E-06 1 bull 614E-C3 1 25 1 9369 1 44230 | 64917 1 12020 1 OOE+00 1 60E-03 1

Appx B-1 124-TMBxls 2 of 3 982009

AR100309

APPENDIX B-1-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

(sec)

Source-building

separation

LT bull

(cm) bull

Stratum A soil

air-filled porosity

Q A

Stratum B soil

air-filled porosity

(cmcm) (cmcm)

Stratum C soil air-filled porosity

(cmcm)

Stratum A effective total fluid

saturation

Se

(cmcm)

Stratum A soil

bullintrinsic permeability

^ (cm)

stratum A Stratum A Floor- soil soli wall BIdg

relative air effective vapor seam Soil bull ventilation permeability permeability perimeter gas rate-

kfg ky Xgrack c o n e - QbuHdinpound

(cm) - (cm) (cm) (ngm) (cms)

946E+08 1 0284 0284 0284 0184 596E-09 0901 537E-09 35357 I 197E+02 | 439E+06 |

Area of enclosed

space below grade

As (cm)

Crack-to-total area ratio

1 bull

(unitless)

Crack depth

below grade

Zcfack

(cm)

Enthalpy of vaporization at

ave soil temperature

AHvjs

(calmol) bull

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law constant at

ave soil bull temperature

bull HTS

(unitless)

Vapor bull viscosity at

ave soil temperature

HTS

(gcm-s)

Stratum A

effective diffusion

coefficient

D (cms)

Stratum-B

effective diffusion coefficient

DB (cms)

Stratum C effective diffusion

coefficient

D-c (cms)

Total - overall effective diffusion

coefficient

D ^ (cms)

Diffusion path

length

L-

(cm)

I 787E+07 I 449E-05 | 15 | 11661 260E-03 111E-01 176E-04 I 612E-03 j OOOE+00 | OOOE+00 | 612E-03 j

bull Convection path

length

Lp

(cm)

Source vapor cone

^source

(ngm)

Crack radius

Tcfack

(cm)

Average vapor

flow rate into bIdg

Qsoii

(cms)

Crack effective diffusion

coefficient pcrack

(cms)

Area of CTack

Acack

(cm)

Exponent of equivalent foundation

Peclet number

exp(Pe)

(unitless)

bull bull - bull bull bull bull

1 15 1 197E+02 1 010 1 474E+01 612E-03 bull 354E-t-03 1 336E+09

Infinite source Indoor

~ attenuation coefficient

a

(unitless)

108E-05

Infinite source

btJbldgjJSv-L ^Ppncji3i-

virhpbiiilding bullbull ^lHltti^m)ilg

213E-03

Unit risk

factor

URF

(ngm)-

Reference cone

RfC (mgm)

NA 60E-03 1

I END

Appx B-1 124-TMBxls 3 of 3 982009

AR100310

APPENDIX B-2-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV Nersion31 020^

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

156592

Soil Gas Concentration Data ENTER

Soil gas

cone OR c

(ngm) bull

ENTER Soil bull-gas

cone

c (ppmv)

603E+03 1

Chemical

cis-12-Dichloroethylene

MORE ENTER Depth

below grade to bottom

of enclosed space floor

LF

(cm)

ENTER

Soil gas sampling

depth below grade

U (cm)

ENTER

Average soil

temperature bull Ts

(degC)

1 15 1 bull 15 125

ENTER ENTER ENTER Totalsmust add ijp tb value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hA hB he

bull (cm) (cm) (cm)

15 1 1

ENTER Soil

straturh A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estimate OR permeability | soil vapor

permeability) kv

(cm)

SL 1 |

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

P (gcm)

ENTER Stratum A soil total porosity

bull n

(unitless)

ENTER Stratum A

soil water-filled porosity

(cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

ENTER Stratum B

soil water-filled porosity

ENTER Stratum C

SCS soil type

(unitless) (cmcm)

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure differential

AP

(gcm-s)

ENTER Enclosed bull

space floor

length

LB (cm)

ENTER Enclosed

space floor

width WB

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER

Average vapor flow rate into bIdg

OR Leave blank to calculi

Qsoil

(Lm)

Appx B-2 cis-12-DCExls 1 of 3 982009

AR100311

APPENDIX B-2-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Diffusivity in air

Da

(cms)

Diffusivity in water

Dw (cms)

Henrys law constant at reference temperature

H

(atm-mmoi)

Henrys law constant

reference temperature

bull T R

CC)

Enthalpy of vaporization at

the normal boiling point

AHbdquob

(calmol)

Normal boiling point

TB

(degK)

Critical temperature

Tc (degK)

Molecular weight

MW

(gmol)

Unit risk

factor URF

(ngm)

Reference cone

RfC (mgm)

1 736E-02 1 113E-05 1 407E-03 j 1 25 1 bull 7192 1 33365 1 54400 1 9694 1 OOE+00 j 35E-02 1

Appx B-2 cis-12-DCExls 2 of 3 982009

AR100312

APPENDIX B-2-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

stratum A Stratum B Stratum C Source- soil soil soil

Exposure building air-filled air-filled air-filled

duration separation porosity porosity porosity

T LT ea e^ bull e= (sec) (cm) (cmcm) (cmcm) (cmcm)

I 946E+08n^

Stratum A Stratum A Stratum A Stratum A Floor-effective soil soil soil wall total fluid intrinsic relative air effective vapor seam

saturation permeability permeability permeability perimeter

Ste kj krg ky Acrack

(cmcm) (cm) (cm) (cm) (cm)

Soil gas

cone (ngm)

I 0284 I 0284~ 0284 0184 I 596E-09 | 090T 537E-09 35357 603E+03

BIdg ventilation

rate

JbulldinE

(cms)

439E+06

Area of enclosed

space below grade

AB

(cm)

Crack-to-total

area ratio

n (unitless)

Crack depth below grade

Zltiack (cm)

Erithalpy of vaporization at

ave soil temperature

AHvTs (calmol)

Henryslaw constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law constant at

ave soil temperature

HTS

(unitless) bull

Vapor viscosity at

ave soil bull temperature

HTS

bull (gcm-s)

Stratum A

effective bull diffusion

coefficient

D^A-(cms)

Stratum B

effective bull diffusion

coefficient

D=B

(cms)

Stratum C

effective diffusion bull

coefficient

D=e (cms)

Total overall

effective diffusion

coefficient

DT

(cms)

Diffusion path

length

Ld

(cm)

I 787E+07 I bull449E-05 | 15 bull7709 230E-03 982E-02 176E-04 | 743E-03 | OOOE+00 | OOOE+00 | 743E-03 |

bull bull bull -

Convecfion path -bull

length

Lp (cm)

Source vapor cone

-source

(Mgm)

Crack radius

fcrack

(cm)

Average vapor

flow rate into bIdg

Qaoil bull

(cms)

Crack effective diffusion

coefficient pcack

(cms)

Area of crack

crack

(cm)-

Exponent of equivalent foundation

Peclet number

exp(Pef)

(unitless)

bull

1 15 -1 603E+03 1 010 1 474E+01 743E-03 354E+03 1 697E+07

Infinite source Indoor

attenuation coefficient

poundbullbullbull C t

pound(unitless)

bullsiilaquogt j ii08E-05

Infinite [ source

bIdg cone

Cbujidjng

(pgm)

651 E-02 iKrt

Unit risk

factor

URF

(ngm)-

Reference cone

RfC

(mgm)

NA 35E-02 1

I END I

Appx B-2 cis-12-DCExls 3o f3 982009

AR100313

APPENDIX B-3-A DATA ENTRY SHEET

Coyne Texti le Services - Hunt ington West Virginia

SG-ADV Version 31 0204

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

67663

Soil Gas Concentration Data ENTER ENTER

Soil Soil gas gas

cone OR cone c C

(^gm) (ppmv)

591 E+03

bull

Chemical

Chloroform

MORE ENTER Depth

below grade tb bottom

of enclosed space floor

bull LF

(cm)

ENTER

Soil gas sampling depth

below grade

(cm)

ENTER

Average soil

temperature-Ts

CO bull

1 15 1 15 1 125

ENTER ENTER ENTER Totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

IIA hs he (cm) (cm) (cm)

1 5 bull 1 1

ENTER ENTER Soil - bull

stratum A User-defined SCS stratum A

soil type bull soil vapor (used to estimate OR permeability

soil vapor k

bull permeability) (cm) 1

SL 1 1 bull

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A soil dry

bulk density

Pb (gcm)

ENTER Stratum A soil total porosity

nV (unitless)

ENTER Stratum A

-soilwater-filled bullporosity

Sraquo (cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

(unitless)

ENTER Stratum B

soil water-filled porosity

bull ebdquo=

(cmcm) bull

ENTER Straturri C

SCS bull soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

- c rack

(cm)

ENTER

Soil-bldg pressure

differential AP^

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor

width bull W B

(cm)

ENTER

Enclosed space

height HB

(cm)

ENTER

bull Floor-wall^ seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bidg OR

Leave blank to calculi

Qsoil bull

(Lm)

I -I

Appx B-3 Chloroformxls 1 of 3 982009

AR100314

APPENDIX B-3-B CHEMICALPROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Diffusivity in air

D (cms)

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffijsivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature

Dbdquo H TR A H bdquo TB Tc

(cm s) (atm-m mol) ro (calmol) (degK) (degK)

Molecular weight

MW

(gmol)

Unit risk

factor URF

(ngm)-

Reference cone

RfC

(mgm)

104E-01 100E-05 I 366E-03 25 6988 33432 53640 11938 I 23E-05 | OOE+00

Appx B-3 Chloroformxls 2 of 3 982009

AR100315

APPENDIX B-3-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure

duration

(sec)

Source-

building

separation

LT

(cm)

Stratum A

soil

air-filled

porosity

Sa

( cm cm )

Stratum B

soil

air-filled

porosity

( cm cm )

Stratum C

soil

air-filled

porosity

( c m c m )

Stratum A

effective

total fluid

saturation

( c m c m )

Stratum A

soil

intrinsic

penmeability

k

(cm )

Stratum A

- soil

relative air

permeabil i ty

(cm )

Stratum A

soil

effective vapor

permeability

kv

(cm )

Floor-

wall

seam

perimeter

gtcrack

(cm)

Soil gas

cone

(ngm)

BIdg

venfilation

rate

^buildlriE

(cms)

I 9 4 6 E + 0 8 ~ T I 0284 T 596E-09 I 0-901 I 537E-09 | 35357 | 591 E+03 j 439E+06 | 1 0 284 0284 0184

Area of

enclosed

space

below

grade

A B

( c m )

Crack-

to-total

area

ratio

n

(unitless)

Crack

depth

bull below

grade

^crack

(cm)

Enthalpy of

vaporization at

ave soil

temperature

AHTs bull

(calmol)

Henry s law

constant at

ave soil

temperature

HTS

(a tm-m mol j

Henrys law

constant at

ave soil

bull temperature

HTS

(unitless) bull

Vapor

viscosity at

ave soil-

temperature

^HTS

(gcm-s)

Stratum

A

effective

diffusion

coefficient

(cm s)

Stratum

B

effective

difftjsion

coefficient

D B

(cms) bull

S t ra tum

C

effective

diffusion

coefficient

Dc

(cm s)

Total

overall

effective

bull diffusion

coefficient

D T

(cm s)

Diffi jsion

path

length

Ld

(cm)

I 787E+07 I 449E-05 j - bull 15 7528 210E-03 896E-02 176E-04 I 105E-02 | OOOE+00 | OOOE+00 | 105E-02

Convection

path length

Lp

(cm)

Source

vapor

cone -

^source

- (ngm)

Crack

radius

Tcrack

(cm)

Average

vapor

flow rate

into bidg

Qsoil

(cms)

Crack

effective

diffusion

coefficient Qcrack

bull (cms)

Area of crack

Acrack

(cm)

Exponent of

equivalent

foundation

Peclet number

exp(Pe)

(unitless)

V bull bull

1 15 1 591 E+03 1 010 1 474E+01 105E-02 354E+03 1 355E+05

Infinite

source

indoor

attenuation

coefficient

d

(unitless)

bull 108E-05

Infinite

source

bIdg

cone

^ b u i l d i n g

i (^gm)

bull bull

i 638E-02 -

Unit

risk bull factor

URF

(ngmY

Reference

cone

RfC

(mgm)

~ 23E-05 NA 1

I END

Appx B-3 Chloroform xls 3 of 3 982009

AR100316

APPENDIX B-4-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ersion 31-020^

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

nodashes)

bull 75092

ENTER Soil gas

cone

c (ngm)

Soil Gas Concentration Data ENTER

Soil gas bull

OR cone

bull C

(ppmv)

152E+03

bull bull

Chemical

Methylene chloride

MORE

MORE 4gt

ENTER Depth

below grade to bottom

of enclosed space floor

LF -

(cm)

ENTER

Soil gas sampling depth

below grade

bull U

(cm)

ENTER

Average soil

temperature

Ts bull CC)

bull bull bull bull

1 15 1 15 125

ENTER Totals

Thickness of soil

stratum A h

(cm)

ENTER ENTER must add up to value of Ls (cell F24

Thickness Thickness of soil of soil

stratum B stratum C (Enter value or 0) (Enter value or 0)

he he bull

(cm) bull (cm) -

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(usedto estimate OR perrrieability | soil vapor

permeability)

k bull

(cm)

SL 1 bull 1

ENTER Stratum A

SCS soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

Pb (gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Stratum A

soil water-filled porosity

9w (cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

Pb^

(gcm)

ENTER Stratum B soil total porosity

n^

(unitless)

ENTER Stratum B

soil water-filled porosity

(crhcm)

ENTER Stratum C

SCS soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE 4gt

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

bull Soil-bldg pressure

differential AP^

(gcm-s)

ENTER Enclosed

space floor

length LB

(cm)

ENTER Enclosed

space floor

width bull W B

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width

w

(cm)

ENTER

Indoor air exchange

rate

ER (1h)

ENTER Average vapor

flow rate into bidg OR

Leave blank to calculc

Qsoil

(Lm)

10 40 8839 8839 244 01 083

Appx B-4 MCxIs 1 of 3 982009

AR100317

Diffijsivity in air

D

APPENDIX B-4-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffusivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature

Pw H TR AHt TB TC

Molecular weight

MW

Unit risk

factor URF

Reference cone

RfC

(cms) (cms) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) bull (ngm)- (mgm)

bull bull

1 101E-01 1 117E-05 1 218E-03 1 25 | 6706 1 31300 1 51000 1 8493 1 47E-07 1 30E+00 1

Appx B-4 MCxIs 2 of 3 982009

AR100318

APPENDIX B-4-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

T

(sec)

Source- -building

separation

LT

(cm)

Stratum A soil

air-filled porosity

e a bull

(cmcm)

Stratum B soil

bullair-filled porosity bull

ea^ (cmcm)

Stratum C soil

air-filled porosity

ea= (cmcmj

Stratum A effective total fluid

saturation

Sc bull

(cmcm)

Stratum A soil

intrinsic pemneability

ki (cm)

Stratum A soil

relative air permeability

^ ^ g

(cm)

stratumA bull soil effective vapor permeability

K (cm)

Floor-wall

seam perimeter

Xcrack

(cm)

Soil gas

cone (ngm)

BIdg ventilation

rate

Qbuildinc

(cms)

1 946E+08

Area of -enclosed

space below

bull grade

AB

(cm)

1

Crack-to-total

area rafio

Tl

(unitless)

0284 1

Crack depth below grade

Zcrack

(cm)

0284 1

bull Enthalpy of vaporization at

ave soil temperature

AHTs (calmol)

0284

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

0184

Henrys law constant at ave soil

temperature

HTS

bull (unitless)

1 596E-09

Vapor viscosity at

ave soil temperature

Mrs (gcm-s)

0901

Stratum A

effective diffusion

coefficient

D (cms)

537E-09

Stratum B

effective diffusion

coefficient

D-B (cms)

35357 1

Stratum C -

effective diffusion

coefficient

D-c ^ (cms)

152E+03

Total bull overall

bull effective diffusion

coefficient

D ^

(cms)

440E+06 1

Difftjsion path

length

Ld (cm)

1 787E+07

Convection path

length

Lp (cm)

4 49E-05

Source vapor cone

Csource

(ngm)

15 1

Crack radius

Tcrack

(cm)

7007 bull 1

Average vapor

flow rate intobldg

Qsoil

(cms)

130E-03

Crack effective diffusion

coefficient pcrack

(cms)-

555E-02

bull ^

Area of crack

Acrack

(cm) bull

1 176E-04

Exponent of equivalent foundation

Peclet number

exp(Pe)

(unitless) bull

bull bull

1 15

1 END

152E+03 010 1 474E+01 1 102E-02 354E+03 1 519E+05

102E-02

Infinite source

indoor ^attenuation coefficient

bull a

(unitless)

aiii08E-05

0 OOE+00

bull

Infinite bull source

bIdg ^ cone

^bu i l d i ng

(MQm)

164E-02

OOOE+00 1

Unit risk

factor

URF

(ngm)-

47E-07 1

102E-02 j

Reference cone

RfC

(mgm)

30E+00 j

1 1

Appx B-4 MCxIs 3 of 3 982009

AR100319

APPENDIX B-5-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ^erslon 31 0204

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

127184

Soil Gas Concentration Data ENTER ^ ENTER

Soil -Soi l bull gas gas

cone OR cone Cg C bull

(tgm) (ppmv)

149E+05 1

Chemical

bull Tetrachlbroethylene

MORE 4

ENTER Depth

below grade to bottom

ofenclosecJ space floor

LF

(cm)

ENTER

Soil gas bull sampling

depth below grade

u bull (cm)

ENTER

Average bullsoil

temperature - Ts

ro 1 1 5 1 15 1 125 bull

ENTER ENTER ENTER totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hft bull he bull he

(cm) (cm) (cm)

bull 1 5 1 - 1

ENTER ENTER Soil

stratum A User^defined bull SCS bull stratum A soil type soil vapor

(used to estimate OR perrrieability soil vapor K bull

permeability) (cm) 1

SL 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

Pb

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Sitratum A

soil water-filled bull porosity

(cmcm)

ENTER Stratum B

SCS soiltype

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

Pb^

(gcm)

ENTER Stratum B soil total porosity

Ajnitless^

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS soil type

LookupSoil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

VS

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor width

W B

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width

w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

ENTER Average vapor

flow rate into bidg OR

Leave blank to calcul

bull Qsoil

(Lm)

10 40 8839 8839 244 01 083

Appx B-5 PCExIS 1 of 3 982009

AR100320

APPENDIX B-5-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal Unit

Diffusivity Diffusivity at reference reference the riormal boiling Critical Molecular risk Reference in air in water temperature temperature boiling point point teriiperature weight factor cone

Da Dbdquo H TR AHb TB Tc MW URF RfC

(cms) (cnis) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) (^gm)- (mgm)

1 720E-02 1 820E-06 1 184E-02 1 25 1 8288 1 39440 1 62020 1 16583 1 59E-06 1 60E-01 1

J

AppxB-5PCExls 2 of 3 - 982009

AR100321

APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

T

(sec)

Source-building

separation

LT

bull (cm)

Stratum A soil

air-filled porosity

Oa (cmcm)

Stratum B - soil air-filled porosity

ea (cmcm)

Stratum C soil

air-filled porosity

ea= - (cmcm)

Stratum A effective total fluid

saturation

sbdquo (cmcm)

Stratum A soil

intrinsic permeability

ki (cm)

Stratum A soil

relative air permeability

- ^ g

(cm)

Stratum A soil

effective vapor permeability

kv (cm)

Floor-wall

seam perimeter

^crack

(cm)

Soil gas

cone

(ngm)

BIdg venfilation

rate

Qbuildins

bull (cms)

bull bull

1 946E+08

Area of enclosed

space below grade

AB

(cm)

1

bullCrack-to-total

area ratio

1 (unitless)

0284 1

Crack bull depth below grade

Zcrack

(cm) -

0284 1

Enthalpy of vaporization at bull

ave soil temperature

bull A H V TS

(calmol)

0284

Henrys law constant at

ave soil temperature

HTS (atm-mmol)

0184

-Henrys law constant at

ave soil temperature

HTS

(unitless)

1 596E-09

Vapor viscosity at

ave soil temperature

HTS

(gcm-s)

0901

Stratum A

effective diffusion

coefficient bull D = bull

(cms)

537E-09

Stratum B

effective diffusion

coefficient

D--B (cms)

35357 1

Stratum C

effective diffusion bull

coefficient

D-c (crris)

149E+05

Total overall

effective bulldiffusion coefficient

DT

(cms)

440E+06 1

Difftjsion path

length

U (cm)

1 787E+07

Convection path

length

bull Lp

(cm)

4 49E-05

Source vapor cone

^source

(ngm)

15 1

Crack radius

Tcrack

(cm)

9528 1

Average vapor

flow rate intobldg

Qsoil (cms)

908E-03

Crack effective diffusion

coefficient pcrack

bull ( c m s ) bull

387E-01

Area of crack

Abdquoack (cm)

1 176E-04

Exponent of equivalent foundafion

Peclet number

exp(Pe)

(unitless)

bull

1 15-

1 END

149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08

727E-03

Infinite source indoor

attenuation coefficient

a

(unitless)

108E-05

OOOE+00

Infinite source

bIdg cone

Cburldtng

(Mgm)

161 E+00

OOOE+00 1

Unit risk

factor

URF

(ugm)-

59E-06 1

727E-03

Reference cone

RfC (mgm)

60E-01

1 1

Appx B-5 PCExls 3 of 3 982009

AR100322

APPENDIX B-6-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ersion31 0204

Reset to Defaults

t

Soil Gas Concentration Data ENTER

Chemical CAS No

(numbers only

no dashes)

79016

ENTER ENTER Soil Soil gas gas

cone OR cone C C -

bull (ngm) (ppmv)

782E+03

Chemical

Trichloroethylene

MORE ENTER Depth

below grade to bottom-

of enclosed space floor

LF

(cm)

ENTER

Soil gas sarnpling

depth below grade

U (cm)

ENTER

Average soil

temperature Ts

(degC)

1 15 1 15 t 125

ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e

(cm) (cm) (cm)

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estimate OR permeability soil vapor

permeability)

k (cm)

bull S L 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil bull-Parameters

ENTER Stratum A

soil dry bulk density

P b -

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Stratum A bull

soilwaterrfilled porosity

(cmcm) bull

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

bull P ^ (gcm)

ENTER Stratum B soil total

porosity

nlaquo

(unitless) -

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS bull soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor

width W B

(cm)

ENTER

Enclosed space height

H B bull

( c m ) bull

ENTER

Floor-wall seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bIdg OR

Leave blank to calculc

Qsoil

(Lm) -

Appx B-6 TCExIs 1 of 3 982009

A

AR100323

APPENDIX B-6-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight

Da Dbdquo H TR AH^b TB TC MW

Unit risk Reference

factor cone URF RfC

(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)

1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1

Appx B-6 TCExIs 2 of 3 982009

AR100324

APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

(sec)

Source-building

separation LT

(cm)

Stratum A soil

air-filled porosity

bull ea (cmcm)

Stratum B Soil

air-fllled porosity

e^ bull (cmcm)

Stratum C soil

air-filled porosity

(cmcm)

StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air

saturation permeability permeability

S|e k krg (cmcm) (cm) (cm)

Stratum A Floor-soil wall BIdg

effective vapor seam Soil ventilafion permeability perimeter gas rate

k^ bull Xack c o n e Qbuildins

(cm) (cm) (ngm) (cms)

946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |

Area of enclosed

space below grade

AB

(cm)

Ciack- to-total

area ratio

1 (unitless)

Crack depth below grade

Zcrack

(cm)

Enthalpy of vaporization at

ave soil temperature

A H J S

(calmol)

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law bull constant at

ave soil temperature

HTS

(unitless)

Vapor viscosity at

ave soil temperature

|JTS

(gcm^s)

Stratum A

effective diffusion

coefficient

(cms)

Stratum B

effective -diffusion

coefficient

D=B (cms)

Stratum ^ C effective diffusion

coefficient

D=c (cms)

Total overall

effective diffusion

coefficient

DT

(cms)

I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03

Diffusion path

length

Li (cm) bull

Convection bull path

length

Lp

(cm)

Source vapor cone bull

^source

(ngm)

Crack radius

rcrack

(cm)

Average vapor

- flow rate intobldg

Qsoil

(cms)

Crack effective diffusion

bull coefficient Qcrack

(cms)

Area of crack

^crack

(cm)

Exponent of equivalent foundation

Peclet bull number

exp(Pe)

(unitless)

bull bull

1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07

Infinite source Indoor

attenuation coefficient

a

(unitless)

108E-05

Infinite source

bIdg concgt

^building

(ngm)

844E-02

Unit risk

factor

URF

(ngm)-

Reference cone

RfC

(mgm)

1 1E-04 1 40E-02 1

END

Appx B-6 TCExIs 3 of 3 982009

AR100325

Office of Waste Management 1356 Hansford Street

Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256

West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director

ORDER

ISSUED UNDER THE

HAZARDOUS WASTE MANAGEMENT ACT

CHAPTER 22 ARTICLE 18

OF THE WEST VIRGINIA CODE^ AS AMENDED

y Order Number HW-011-80

To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704

ATTEMTION MREDARMON

Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull

AR100326

ViWJ011-laquo9 PageNunil)er2

BASIS FOR ORDER

As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following

A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^

B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator

C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities

0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94

^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement

P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following

1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater

2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was

^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment

CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable

CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order

AR100327

H W - 0 1 1 - 9 9 Page Number 3

REQUIREMENTS OF ORDER

Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows

1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^

2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore

remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling

GENERAL PROVaiONS

1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order

2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order

3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order

Effective Date

Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief

Wt T 1 V Oflice of Waste Management

AR100328

^ ^ S I S

^wmmmmamn

AR100329

Page 33: SDMS DocID 2121999 · International Enterprises Corp. building (Coyne Building), which is located at 1111 Vernon Street, Westmoreland District, Wayne County, West Virginia. The following

APPENDIX B-1-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

(sec)

Source-building

separation

LT bull

(cm) bull

Stratum A soil

air-filled porosity

Q A

Stratum B soil

air-filled porosity

(cmcm) (cmcm)

Stratum C soil air-filled porosity

(cmcm)

Stratum A effective total fluid

saturation

Se

(cmcm)

Stratum A soil

bullintrinsic permeability

^ (cm)

stratum A Stratum A Floor- soil soli wall BIdg

relative air effective vapor seam Soil bull ventilation permeability permeability perimeter gas rate-

kfg ky Xgrack c o n e - QbuHdinpound

(cm) - (cm) (cm) (ngm) (cms)

946E+08 1 0284 0284 0284 0184 596E-09 0901 537E-09 35357 I 197E+02 | 439E+06 |

Area of enclosed

space below grade

As (cm)

Crack-to-total area ratio

1 bull

(unitless)

Crack depth

below grade

Zcfack

(cm)

Enthalpy of vaporization at

ave soil temperature

AHvjs

(calmol) bull

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law constant at

ave soil bull temperature

bull HTS

(unitless)

Vapor bull viscosity at

ave soil temperature

HTS

(gcm-s)

Stratum A

effective diffusion

coefficient

D (cms)

Stratum-B

effective diffusion coefficient

DB (cms)

Stratum C effective diffusion

coefficient

D-c (cms)

Total - overall effective diffusion

coefficient

D ^ (cms)

Diffusion path

length

L-

(cm)

I 787E+07 I 449E-05 | 15 | 11661 260E-03 111E-01 176E-04 I 612E-03 j OOOE+00 | OOOE+00 | 612E-03 j

bull Convection path

length

Lp

(cm)

Source vapor cone

^source

(ngm)

Crack radius

Tcfack

(cm)

Average vapor

flow rate into bIdg

Qsoii

(cms)

Crack effective diffusion

coefficient pcrack

(cms)

Area of CTack

Acack

(cm)

Exponent of equivalent foundation

Peclet number

exp(Pe)

(unitless)

bull bull - bull bull bull bull

1 15 1 197E+02 1 010 1 474E+01 612E-03 bull 354E-t-03 1 336E+09

Infinite source Indoor

~ attenuation coefficient

a

(unitless)

108E-05

Infinite source

btJbldgjJSv-L ^Ppncji3i-

virhpbiiilding bullbull ^lHltti^m)ilg

213E-03

Unit risk

factor

URF

(ngm)-

Reference cone

RfC (mgm)

NA 60E-03 1

I END

Appx B-1 124-TMBxls 3 of 3 982009

AR100310

APPENDIX B-2-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV Nersion31 020^

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

156592

Soil Gas Concentration Data ENTER

Soil gas

cone OR c

(ngm) bull

ENTER Soil bull-gas

cone

c (ppmv)

603E+03 1

Chemical

cis-12-Dichloroethylene

MORE ENTER Depth

below grade to bottom

of enclosed space floor

LF

(cm)

ENTER

Soil gas sampling

depth below grade

U (cm)

ENTER

Average soil

temperature bull Ts

(degC)

1 15 1 bull 15 125

ENTER ENTER ENTER Totalsmust add ijp tb value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hA hB he

bull (cm) (cm) (cm)

15 1 1

ENTER Soil

straturh A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estimate OR permeability | soil vapor

permeability) kv

(cm)

SL 1 |

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

P (gcm)

ENTER Stratum A soil total porosity

bull n

(unitless)

ENTER Stratum A

soil water-filled porosity

(cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

ENTER Stratum B

soil water-filled porosity

ENTER Stratum C

SCS soil type

(unitless) (cmcm)

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure differential

AP

(gcm-s)

ENTER Enclosed bull

space floor

length

LB (cm)

ENTER Enclosed

space floor

width WB

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER

Average vapor flow rate into bIdg

OR Leave blank to calculi

Qsoil

(Lm)

Appx B-2 cis-12-DCExls 1 of 3 982009

AR100311

APPENDIX B-2-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Diffusivity in air

Da

(cms)

Diffusivity in water

Dw (cms)

Henrys law constant at reference temperature

H

(atm-mmoi)

Henrys law constant

reference temperature

bull T R

CC)

Enthalpy of vaporization at

the normal boiling point

AHbdquob

(calmol)

Normal boiling point

TB

(degK)

Critical temperature

Tc (degK)

Molecular weight

MW

(gmol)

Unit risk

factor URF

(ngm)

Reference cone

RfC (mgm)

1 736E-02 1 113E-05 1 407E-03 j 1 25 1 bull 7192 1 33365 1 54400 1 9694 1 OOE+00 j 35E-02 1

Appx B-2 cis-12-DCExls 2 of 3 982009

AR100312

APPENDIX B-2-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

stratum A Stratum B Stratum C Source- soil soil soil

Exposure building air-filled air-filled air-filled

duration separation porosity porosity porosity

T LT ea e^ bull e= (sec) (cm) (cmcm) (cmcm) (cmcm)

I 946E+08n^

Stratum A Stratum A Stratum A Stratum A Floor-effective soil soil soil wall total fluid intrinsic relative air effective vapor seam

saturation permeability permeability permeability perimeter

Ste kj krg ky Acrack

(cmcm) (cm) (cm) (cm) (cm)

Soil gas

cone (ngm)

I 0284 I 0284~ 0284 0184 I 596E-09 | 090T 537E-09 35357 603E+03

BIdg ventilation

rate

JbulldinE

(cms)

439E+06

Area of enclosed

space below grade

AB

(cm)

Crack-to-total

area ratio

n (unitless)

Crack depth below grade

Zltiack (cm)

Erithalpy of vaporization at

ave soil temperature

AHvTs (calmol)

Henryslaw constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law constant at

ave soil temperature

HTS

(unitless) bull

Vapor viscosity at

ave soil bull temperature

HTS

bull (gcm-s)

Stratum A

effective bull diffusion

coefficient

D^A-(cms)

Stratum B

effective bull diffusion

coefficient

D=B

(cms)

Stratum C

effective diffusion bull

coefficient

D=e (cms)

Total overall

effective diffusion

coefficient

DT

(cms)

Diffusion path

length

Ld

(cm)

I 787E+07 I bull449E-05 | 15 bull7709 230E-03 982E-02 176E-04 | 743E-03 | OOOE+00 | OOOE+00 | 743E-03 |

bull bull bull -

Convecfion path -bull

length

Lp (cm)

Source vapor cone

-source

(Mgm)

Crack radius

fcrack

(cm)

Average vapor

flow rate into bIdg

Qaoil bull

(cms)

Crack effective diffusion

coefficient pcack

(cms)

Area of crack

crack

(cm)-

Exponent of equivalent foundation

Peclet number

exp(Pef)

(unitless)

bull

1 15 -1 603E+03 1 010 1 474E+01 743E-03 354E+03 1 697E+07

Infinite source Indoor

attenuation coefficient

poundbullbullbull C t

pound(unitless)

bullsiilaquogt j ii08E-05

Infinite [ source

bIdg cone

Cbujidjng

(pgm)

651 E-02 iKrt

Unit risk

factor

URF

(ngm)-

Reference cone

RfC

(mgm)

NA 35E-02 1

I END I

Appx B-2 cis-12-DCExls 3o f3 982009

AR100313

APPENDIX B-3-A DATA ENTRY SHEET

Coyne Texti le Services - Hunt ington West Virginia

SG-ADV Version 31 0204

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

67663

Soil Gas Concentration Data ENTER ENTER

Soil Soil gas gas

cone OR cone c C

(^gm) (ppmv)

591 E+03

bull

Chemical

Chloroform

MORE ENTER Depth

below grade tb bottom

of enclosed space floor

bull LF

(cm)

ENTER

Soil gas sampling depth

below grade

(cm)

ENTER

Average soil

temperature-Ts

CO bull

1 15 1 15 1 125

ENTER ENTER ENTER Totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

IIA hs he (cm) (cm) (cm)

1 5 bull 1 1

ENTER ENTER Soil - bull

stratum A User-defined SCS stratum A

soil type bull soil vapor (used to estimate OR permeability

soil vapor k

bull permeability) (cm) 1

SL 1 1 bull

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A soil dry

bulk density

Pb (gcm)

ENTER Stratum A soil total porosity

nV (unitless)

ENTER Stratum A

-soilwater-filled bullporosity

Sraquo (cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

(unitless)

ENTER Stratum B

soil water-filled porosity

bull ebdquo=

(cmcm) bull

ENTER Straturri C

SCS bull soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

- c rack

(cm)

ENTER

Soil-bldg pressure

differential AP^

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor

width bull W B

(cm)

ENTER

Enclosed space

height HB

(cm)

ENTER

bull Floor-wall^ seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bidg OR

Leave blank to calculi

Qsoil bull

(Lm)

I -I

Appx B-3 Chloroformxls 1 of 3 982009

AR100314

APPENDIX B-3-B CHEMICALPROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Diffusivity in air

D (cms)

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffijsivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature

Dbdquo H TR A H bdquo TB Tc

(cm s) (atm-m mol) ro (calmol) (degK) (degK)

Molecular weight

MW

(gmol)

Unit risk

factor URF

(ngm)-

Reference cone

RfC

(mgm)

104E-01 100E-05 I 366E-03 25 6988 33432 53640 11938 I 23E-05 | OOE+00

Appx B-3 Chloroformxls 2 of 3 982009

AR100315

APPENDIX B-3-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure

duration

(sec)

Source-

building

separation

LT

(cm)

Stratum A

soil

air-filled

porosity

Sa

( cm cm )

Stratum B

soil

air-filled

porosity

( cm cm )

Stratum C

soil

air-filled

porosity

( c m c m )

Stratum A

effective

total fluid

saturation

( c m c m )

Stratum A

soil

intrinsic

penmeability

k

(cm )

Stratum A

- soil

relative air

permeabil i ty

(cm )

Stratum A

soil

effective vapor

permeability

kv

(cm )

Floor-

wall

seam

perimeter

gtcrack

(cm)

Soil gas

cone

(ngm)

BIdg

venfilation

rate

^buildlriE

(cms)

I 9 4 6 E + 0 8 ~ T I 0284 T 596E-09 I 0-901 I 537E-09 | 35357 | 591 E+03 j 439E+06 | 1 0 284 0284 0184

Area of

enclosed

space

below

grade

A B

( c m )

Crack-

to-total

area

ratio

n

(unitless)

Crack

depth

bull below

grade

^crack

(cm)

Enthalpy of

vaporization at

ave soil

temperature

AHTs bull

(calmol)

Henry s law

constant at

ave soil

temperature

HTS

(a tm-m mol j

Henrys law

constant at

ave soil

bull temperature

HTS

(unitless) bull

Vapor

viscosity at

ave soil-

temperature

^HTS

(gcm-s)

Stratum

A

effective

diffusion

coefficient

(cm s)

Stratum

B

effective

difftjsion

coefficient

D B

(cms) bull

S t ra tum

C

effective

diffusion

coefficient

Dc

(cm s)

Total

overall

effective

bull diffusion

coefficient

D T

(cm s)

Diffi jsion

path

length

Ld

(cm)

I 787E+07 I 449E-05 j - bull 15 7528 210E-03 896E-02 176E-04 I 105E-02 | OOOE+00 | OOOE+00 | 105E-02

Convection

path length

Lp

(cm)

Source

vapor

cone -

^source

- (ngm)

Crack

radius

Tcrack

(cm)

Average

vapor

flow rate

into bidg

Qsoil

(cms)

Crack

effective

diffusion

coefficient Qcrack

bull (cms)

Area of crack

Acrack

(cm)

Exponent of

equivalent

foundation

Peclet number

exp(Pe)

(unitless)

V bull bull

1 15 1 591 E+03 1 010 1 474E+01 105E-02 354E+03 1 355E+05

Infinite

source

indoor

attenuation

coefficient

d

(unitless)

bull 108E-05

Infinite

source

bIdg

cone

^ b u i l d i n g

i (^gm)

bull bull

i 638E-02 -

Unit

risk bull factor

URF

(ngmY

Reference

cone

RfC

(mgm)

~ 23E-05 NA 1

I END

Appx B-3 Chloroform xls 3 of 3 982009

AR100316

APPENDIX B-4-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ersion 31-020^

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

nodashes)

bull 75092

ENTER Soil gas

cone

c (ngm)

Soil Gas Concentration Data ENTER

Soil gas bull

OR cone

bull C

(ppmv)

152E+03

bull bull

Chemical

Methylene chloride

MORE

MORE 4gt

ENTER Depth

below grade to bottom

of enclosed space floor

LF -

(cm)

ENTER

Soil gas sampling depth

below grade

bull U

(cm)

ENTER

Average soil

temperature

Ts bull CC)

bull bull bull bull

1 15 1 15 125

ENTER Totals

Thickness of soil

stratum A h

(cm)

ENTER ENTER must add up to value of Ls (cell F24

Thickness Thickness of soil of soil

stratum B stratum C (Enter value or 0) (Enter value or 0)

he he bull

(cm) bull (cm) -

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(usedto estimate OR perrrieability | soil vapor

permeability)

k bull

(cm)

SL 1 bull 1

ENTER Stratum A

SCS soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

Pb (gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Stratum A

soil water-filled porosity

9w (cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

Pb^

(gcm)

ENTER Stratum B soil total porosity

n^

(unitless)

ENTER Stratum B

soil water-filled porosity

(crhcm)

ENTER Stratum C

SCS soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE 4gt

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

bull Soil-bldg pressure

differential AP^

(gcm-s)

ENTER Enclosed

space floor

length LB

(cm)

ENTER Enclosed

space floor

width bull W B

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width

w

(cm)

ENTER

Indoor air exchange

rate

ER (1h)

ENTER Average vapor

flow rate into bidg OR

Leave blank to calculc

Qsoil

(Lm)

10 40 8839 8839 244 01 083

Appx B-4 MCxIs 1 of 3 982009

AR100317

Diffijsivity in air

D

APPENDIX B-4-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffusivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature

Pw H TR AHt TB TC

Molecular weight

MW

Unit risk

factor URF

Reference cone

RfC

(cms) (cms) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) bull (ngm)- (mgm)

bull bull

1 101E-01 1 117E-05 1 218E-03 1 25 | 6706 1 31300 1 51000 1 8493 1 47E-07 1 30E+00 1

Appx B-4 MCxIs 2 of 3 982009

AR100318

APPENDIX B-4-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

T

(sec)

Source- -building

separation

LT

(cm)

Stratum A soil

air-filled porosity

e a bull

(cmcm)

Stratum B soil

bullair-filled porosity bull

ea^ (cmcm)

Stratum C soil

air-filled porosity

ea= (cmcmj

Stratum A effective total fluid

saturation

Sc bull

(cmcm)

Stratum A soil

intrinsic pemneability

ki (cm)

Stratum A soil

relative air permeability

^ ^ g

(cm)

stratumA bull soil effective vapor permeability

K (cm)

Floor-wall

seam perimeter

Xcrack

(cm)

Soil gas

cone (ngm)

BIdg ventilation

rate

Qbuildinc

(cms)

1 946E+08

Area of -enclosed

space below

bull grade

AB

(cm)

1

Crack-to-total

area rafio

Tl

(unitless)

0284 1

Crack depth below grade

Zcrack

(cm)

0284 1

bull Enthalpy of vaporization at

ave soil temperature

AHTs (calmol)

0284

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

0184

Henrys law constant at ave soil

temperature

HTS

bull (unitless)

1 596E-09

Vapor viscosity at

ave soil temperature

Mrs (gcm-s)

0901

Stratum A

effective diffusion

coefficient

D (cms)

537E-09

Stratum B

effective diffusion

coefficient

D-B (cms)

35357 1

Stratum C -

effective diffusion

coefficient

D-c ^ (cms)

152E+03

Total bull overall

bull effective diffusion

coefficient

D ^

(cms)

440E+06 1

Difftjsion path

length

Ld (cm)

1 787E+07

Convection path

length

Lp (cm)

4 49E-05

Source vapor cone

Csource

(ngm)

15 1

Crack radius

Tcrack

(cm)

7007 bull 1

Average vapor

flow rate intobldg

Qsoil

(cms)

130E-03

Crack effective diffusion

coefficient pcrack

(cms)-

555E-02

bull ^

Area of crack

Acrack

(cm) bull

1 176E-04

Exponent of equivalent foundation

Peclet number

exp(Pe)

(unitless) bull

bull bull

1 15

1 END

152E+03 010 1 474E+01 1 102E-02 354E+03 1 519E+05

102E-02

Infinite source

indoor ^attenuation coefficient

bull a

(unitless)

aiii08E-05

0 OOE+00

bull

Infinite bull source

bIdg ^ cone

^bu i l d i ng

(MQm)

164E-02

OOOE+00 1

Unit risk

factor

URF

(ngm)-

47E-07 1

102E-02 j

Reference cone

RfC

(mgm)

30E+00 j

1 1

Appx B-4 MCxIs 3 of 3 982009

AR100319

APPENDIX B-5-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ^erslon 31 0204

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

127184

Soil Gas Concentration Data ENTER ^ ENTER

Soil -Soi l bull gas gas

cone OR cone Cg C bull

(tgm) (ppmv)

149E+05 1

Chemical

bull Tetrachlbroethylene

MORE 4

ENTER Depth

below grade to bottom

ofenclosecJ space floor

LF

(cm)

ENTER

Soil gas bull sampling

depth below grade

u bull (cm)

ENTER

Average bullsoil

temperature - Ts

ro 1 1 5 1 15 1 125 bull

ENTER ENTER ENTER totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hft bull he bull he

(cm) (cm) (cm)

bull 1 5 1 - 1

ENTER ENTER Soil

stratum A User^defined bull SCS bull stratum A soil type soil vapor

(used to estimate OR perrrieability soil vapor K bull

permeability) (cm) 1

SL 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

Pb

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Sitratum A

soil water-filled bull porosity

(cmcm)

ENTER Stratum B

SCS soiltype

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

Pb^

(gcm)

ENTER Stratum B soil total porosity

Ajnitless^

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS soil type

LookupSoil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

VS

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor width

W B

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width

w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

ENTER Average vapor

flow rate into bidg OR

Leave blank to calcul

bull Qsoil

(Lm)

10 40 8839 8839 244 01 083

Appx B-5 PCExIS 1 of 3 982009

AR100320

APPENDIX B-5-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal Unit

Diffusivity Diffusivity at reference reference the riormal boiling Critical Molecular risk Reference in air in water temperature temperature boiling point point teriiperature weight factor cone

Da Dbdquo H TR AHb TB Tc MW URF RfC

(cms) (cnis) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) (^gm)- (mgm)

1 720E-02 1 820E-06 1 184E-02 1 25 1 8288 1 39440 1 62020 1 16583 1 59E-06 1 60E-01 1

J

AppxB-5PCExls 2 of 3 - 982009

AR100321

APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

T

(sec)

Source-building

separation

LT

bull (cm)

Stratum A soil

air-filled porosity

Oa (cmcm)

Stratum B - soil air-filled porosity

ea (cmcm)

Stratum C soil

air-filled porosity

ea= - (cmcm)

Stratum A effective total fluid

saturation

sbdquo (cmcm)

Stratum A soil

intrinsic permeability

ki (cm)

Stratum A soil

relative air permeability

- ^ g

(cm)

Stratum A soil

effective vapor permeability

kv (cm)

Floor-wall

seam perimeter

^crack

(cm)

Soil gas

cone

(ngm)

BIdg venfilation

rate

Qbuildins

bull (cms)

bull bull

1 946E+08

Area of enclosed

space below grade

AB

(cm)

1

bullCrack-to-total

area ratio

1 (unitless)

0284 1

Crack bull depth below grade

Zcrack

(cm) -

0284 1

Enthalpy of vaporization at bull

ave soil temperature

bull A H V TS

(calmol)

0284

Henrys law constant at

ave soil temperature

HTS (atm-mmol)

0184

-Henrys law constant at

ave soil temperature

HTS

(unitless)

1 596E-09

Vapor viscosity at

ave soil temperature

HTS

(gcm-s)

0901

Stratum A

effective diffusion

coefficient bull D = bull

(cms)

537E-09

Stratum B

effective diffusion

coefficient

D--B (cms)

35357 1

Stratum C

effective diffusion bull

coefficient

D-c (crris)

149E+05

Total overall

effective bulldiffusion coefficient

DT

(cms)

440E+06 1

Difftjsion path

length

U (cm)

1 787E+07

Convection path

length

bull Lp

(cm)

4 49E-05

Source vapor cone

^source

(ngm)

15 1

Crack radius

Tcrack

(cm)

9528 1

Average vapor

flow rate intobldg

Qsoil (cms)

908E-03

Crack effective diffusion

coefficient pcrack

bull ( c m s ) bull

387E-01

Area of crack

Abdquoack (cm)

1 176E-04

Exponent of equivalent foundafion

Peclet number

exp(Pe)

(unitless)

bull

1 15-

1 END

149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08

727E-03

Infinite source indoor

attenuation coefficient

a

(unitless)

108E-05

OOOE+00

Infinite source

bIdg cone

Cburldtng

(Mgm)

161 E+00

OOOE+00 1

Unit risk

factor

URF

(ugm)-

59E-06 1

727E-03

Reference cone

RfC (mgm)

60E-01

1 1

Appx B-5 PCExls 3 of 3 982009

AR100322

APPENDIX B-6-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ersion31 0204

Reset to Defaults

t

Soil Gas Concentration Data ENTER

Chemical CAS No

(numbers only

no dashes)

79016

ENTER ENTER Soil Soil gas gas

cone OR cone C C -

bull (ngm) (ppmv)

782E+03

Chemical

Trichloroethylene

MORE ENTER Depth

below grade to bottom-

of enclosed space floor

LF

(cm)

ENTER

Soil gas sarnpling

depth below grade

U (cm)

ENTER

Average soil

temperature Ts

(degC)

1 15 1 15 t 125

ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e

(cm) (cm) (cm)

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estimate OR permeability soil vapor

permeability)

k (cm)

bull S L 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil bull-Parameters

ENTER Stratum A

soil dry bulk density

P b -

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Stratum A bull

soilwaterrfilled porosity

(cmcm) bull

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

bull P ^ (gcm)

ENTER Stratum B soil total

porosity

nlaquo

(unitless) -

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS bull soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor

width W B

(cm)

ENTER

Enclosed space height

H B bull

( c m ) bull

ENTER

Floor-wall seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bIdg OR

Leave blank to calculc

Qsoil

(Lm) -

Appx B-6 TCExIs 1 of 3 982009

A

AR100323

APPENDIX B-6-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight

Da Dbdquo H TR AH^b TB TC MW

Unit risk Reference

factor cone URF RfC

(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)

1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1

Appx B-6 TCExIs 2 of 3 982009

AR100324

APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

(sec)

Source-building

separation LT

(cm)

Stratum A soil

air-filled porosity

bull ea (cmcm)

Stratum B Soil

air-fllled porosity

e^ bull (cmcm)

Stratum C soil

air-filled porosity

(cmcm)

StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air

saturation permeability permeability

S|e k krg (cmcm) (cm) (cm)

Stratum A Floor-soil wall BIdg

effective vapor seam Soil ventilafion permeability perimeter gas rate

k^ bull Xack c o n e Qbuildins

(cm) (cm) (ngm) (cms)

946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |

Area of enclosed

space below grade

AB

(cm)

Ciack- to-total

area ratio

1 (unitless)

Crack depth below grade

Zcrack

(cm)

Enthalpy of vaporization at

ave soil temperature

A H J S

(calmol)

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law bull constant at

ave soil temperature

HTS

(unitless)

Vapor viscosity at

ave soil temperature

|JTS

(gcm^s)

Stratum A

effective diffusion

coefficient

(cms)

Stratum B

effective -diffusion

coefficient

D=B (cms)

Stratum ^ C effective diffusion

coefficient

D=c (cms)

Total overall

effective diffusion

coefficient

DT

(cms)

I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03

Diffusion path

length

Li (cm) bull

Convection bull path

length

Lp

(cm)

Source vapor cone bull

^source

(ngm)

Crack radius

rcrack

(cm)

Average vapor

- flow rate intobldg

Qsoil

(cms)

Crack effective diffusion

bull coefficient Qcrack

(cms)

Area of crack

^crack

(cm)

Exponent of equivalent foundation

Peclet bull number

exp(Pe)

(unitless)

bull bull

1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07

Infinite source Indoor

attenuation coefficient

a

(unitless)

108E-05

Infinite source

bIdg concgt

^building

(ngm)

844E-02

Unit risk

factor

URF

(ngm)-

Reference cone

RfC

(mgm)

1 1E-04 1 40E-02 1

END

Appx B-6 TCExIs 3 of 3 982009

AR100325

Office of Waste Management 1356 Hansford Street

Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256

West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director

ORDER

ISSUED UNDER THE

HAZARDOUS WASTE MANAGEMENT ACT

CHAPTER 22 ARTICLE 18

OF THE WEST VIRGINIA CODE^ AS AMENDED

y Order Number HW-011-80

To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704

ATTEMTION MREDARMON

Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull

AR100326

ViWJ011-laquo9 PageNunil)er2

BASIS FOR ORDER

As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following

A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^

B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator

C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities

0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94

^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement

P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following

1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater

2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was

^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment

CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable

CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order

AR100327

H W - 0 1 1 - 9 9 Page Number 3

REQUIREMENTS OF ORDER

Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows

1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^

2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore

remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling

GENERAL PROVaiONS

1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order

2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order

3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order

Effective Date

Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief

Wt T 1 V Oflice of Waste Management

AR100328

^ ^ S I S

^wmmmmamn

AR100329

Page 34: SDMS DocID 2121999 · International Enterprises Corp. building (Coyne Building), which is located at 1111 Vernon Street, Westmoreland District, Wayne County, West Virginia. The following

APPENDIX B-2-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV Nersion31 020^

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

156592

Soil Gas Concentration Data ENTER

Soil gas

cone OR c

(ngm) bull

ENTER Soil bull-gas

cone

c (ppmv)

603E+03 1

Chemical

cis-12-Dichloroethylene

MORE ENTER Depth

below grade to bottom

of enclosed space floor

LF

(cm)

ENTER

Soil gas sampling

depth below grade

U (cm)

ENTER

Average soil

temperature bull Ts

(degC)

1 15 1 bull 15 125

ENTER ENTER ENTER Totalsmust add ijp tb value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hA hB he

bull (cm) (cm) (cm)

15 1 1

ENTER Soil

straturh A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estimate OR permeability | soil vapor

permeability) kv

(cm)

SL 1 |

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

P (gcm)

ENTER Stratum A soil total porosity

bull n

(unitless)

ENTER Stratum A

soil water-filled porosity

(cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

ENTER Stratum B

soil water-filled porosity

ENTER Stratum C

SCS soil type

(unitless) (cmcm)

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure differential

AP

(gcm-s)

ENTER Enclosed bull

space floor

length

LB (cm)

ENTER Enclosed

space floor

width WB

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER

Average vapor flow rate into bIdg

OR Leave blank to calculi

Qsoil

(Lm)

Appx B-2 cis-12-DCExls 1 of 3 982009

AR100311

APPENDIX B-2-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Diffusivity in air

Da

(cms)

Diffusivity in water

Dw (cms)

Henrys law constant at reference temperature

H

(atm-mmoi)

Henrys law constant

reference temperature

bull T R

CC)

Enthalpy of vaporization at

the normal boiling point

AHbdquob

(calmol)

Normal boiling point

TB

(degK)

Critical temperature

Tc (degK)

Molecular weight

MW

(gmol)

Unit risk

factor URF

(ngm)

Reference cone

RfC (mgm)

1 736E-02 1 113E-05 1 407E-03 j 1 25 1 bull 7192 1 33365 1 54400 1 9694 1 OOE+00 j 35E-02 1

Appx B-2 cis-12-DCExls 2 of 3 982009

AR100312

APPENDIX B-2-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

stratum A Stratum B Stratum C Source- soil soil soil

Exposure building air-filled air-filled air-filled

duration separation porosity porosity porosity

T LT ea e^ bull e= (sec) (cm) (cmcm) (cmcm) (cmcm)

I 946E+08n^

Stratum A Stratum A Stratum A Stratum A Floor-effective soil soil soil wall total fluid intrinsic relative air effective vapor seam

saturation permeability permeability permeability perimeter

Ste kj krg ky Acrack

(cmcm) (cm) (cm) (cm) (cm)

Soil gas

cone (ngm)

I 0284 I 0284~ 0284 0184 I 596E-09 | 090T 537E-09 35357 603E+03

BIdg ventilation

rate

JbulldinE

(cms)

439E+06

Area of enclosed

space below grade

AB

(cm)

Crack-to-total

area ratio

n (unitless)

Crack depth below grade

Zltiack (cm)

Erithalpy of vaporization at

ave soil temperature

AHvTs (calmol)

Henryslaw constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law constant at

ave soil temperature

HTS

(unitless) bull

Vapor viscosity at

ave soil bull temperature

HTS

bull (gcm-s)

Stratum A

effective bull diffusion

coefficient

D^A-(cms)

Stratum B

effective bull diffusion

coefficient

D=B

(cms)

Stratum C

effective diffusion bull

coefficient

D=e (cms)

Total overall

effective diffusion

coefficient

DT

(cms)

Diffusion path

length

Ld

(cm)

I 787E+07 I bull449E-05 | 15 bull7709 230E-03 982E-02 176E-04 | 743E-03 | OOOE+00 | OOOE+00 | 743E-03 |

bull bull bull -

Convecfion path -bull

length

Lp (cm)

Source vapor cone

-source

(Mgm)

Crack radius

fcrack

(cm)

Average vapor

flow rate into bIdg

Qaoil bull

(cms)

Crack effective diffusion

coefficient pcack

(cms)

Area of crack

crack

(cm)-

Exponent of equivalent foundation

Peclet number

exp(Pef)

(unitless)

bull

1 15 -1 603E+03 1 010 1 474E+01 743E-03 354E+03 1 697E+07

Infinite source Indoor

attenuation coefficient

poundbullbullbull C t

pound(unitless)

bullsiilaquogt j ii08E-05

Infinite [ source

bIdg cone

Cbujidjng

(pgm)

651 E-02 iKrt

Unit risk

factor

URF

(ngm)-

Reference cone

RfC

(mgm)

NA 35E-02 1

I END I

Appx B-2 cis-12-DCExls 3o f3 982009

AR100313

APPENDIX B-3-A DATA ENTRY SHEET

Coyne Texti le Services - Hunt ington West Virginia

SG-ADV Version 31 0204

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

67663

Soil Gas Concentration Data ENTER ENTER

Soil Soil gas gas

cone OR cone c C

(^gm) (ppmv)

591 E+03

bull

Chemical

Chloroform

MORE ENTER Depth

below grade tb bottom

of enclosed space floor

bull LF

(cm)

ENTER

Soil gas sampling depth

below grade

(cm)

ENTER

Average soil

temperature-Ts

CO bull

1 15 1 15 1 125

ENTER ENTER ENTER Totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

IIA hs he (cm) (cm) (cm)

1 5 bull 1 1

ENTER ENTER Soil - bull

stratum A User-defined SCS stratum A

soil type bull soil vapor (used to estimate OR permeability

soil vapor k

bull permeability) (cm) 1

SL 1 1 bull

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A soil dry

bulk density

Pb (gcm)

ENTER Stratum A soil total porosity

nV (unitless)

ENTER Stratum A

-soilwater-filled bullporosity

Sraquo (cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

(unitless)

ENTER Stratum B

soil water-filled porosity

bull ebdquo=

(cmcm) bull

ENTER Straturri C

SCS bull soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

- c rack

(cm)

ENTER

Soil-bldg pressure

differential AP^

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor

width bull W B

(cm)

ENTER

Enclosed space

height HB

(cm)

ENTER

bull Floor-wall^ seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bidg OR

Leave blank to calculi

Qsoil bull

(Lm)

I -I

Appx B-3 Chloroformxls 1 of 3 982009

AR100314

APPENDIX B-3-B CHEMICALPROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Diffusivity in air

D (cms)

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffijsivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature

Dbdquo H TR A H bdquo TB Tc

(cm s) (atm-m mol) ro (calmol) (degK) (degK)

Molecular weight

MW

(gmol)

Unit risk

factor URF

(ngm)-

Reference cone

RfC

(mgm)

104E-01 100E-05 I 366E-03 25 6988 33432 53640 11938 I 23E-05 | OOE+00

Appx B-3 Chloroformxls 2 of 3 982009

AR100315

APPENDIX B-3-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure

duration

(sec)

Source-

building

separation

LT

(cm)

Stratum A

soil

air-filled

porosity

Sa

( cm cm )

Stratum B

soil

air-filled

porosity

( cm cm )

Stratum C

soil

air-filled

porosity

( c m c m )

Stratum A

effective

total fluid

saturation

( c m c m )

Stratum A

soil

intrinsic

penmeability

k

(cm )

Stratum A

- soil

relative air

permeabil i ty

(cm )

Stratum A

soil

effective vapor

permeability

kv

(cm )

Floor-

wall

seam

perimeter

gtcrack

(cm)

Soil gas

cone

(ngm)

BIdg

venfilation

rate

^buildlriE

(cms)

I 9 4 6 E + 0 8 ~ T I 0284 T 596E-09 I 0-901 I 537E-09 | 35357 | 591 E+03 j 439E+06 | 1 0 284 0284 0184

Area of

enclosed

space

below

grade

A B

( c m )

Crack-

to-total

area

ratio

n

(unitless)

Crack

depth

bull below

grade

^crack

(cm)

Enthalpy of

vaporization at

ave soil

temperature

AHTs bull

(calmol)

Henry s law

constant at

ave soil

temperature

HTS

(a tm-m mol j

Henrys law

constant at

ave soil

bull temperature

HTS

(unitless) bull

Vapor

viscosity at

ave soil-

temperature

^HTS

(gcm-s)

Stratum

A

effective

diffusion

coefficient

(cm s)

Stratum

B

effective

difftjsion

coefficient

D B

(cms) bull

S t ra tum

C

effective

diffusion

coefficient

Dc

(cm s)

Total

overall

effective

bull diffusion

coefficient

D T

(cm s)

Diffi jsion

path

length

Ld

(cm)

I 787E+07 I 449E-05 j - bull 15 7528 210E-03 896E-02 176E-04 I 105E-02 | OOOE+00 | OOOE+00 | 105E-02

Convection

path length

Lp

(cm)

Source

vapor

cone -

^source

- (ngm)

Crack

radius

Tcrack

(cm)

Average

vapor

flow rate

into bidg

Qsoil

(cms)

Crack

effective

diffusion

coefficient Qcrack

bull (cms)

Area of crack

Acrack

(cm)

Exponent of

equivalent

foundation

Peclet number

exp(Pe)

(unitless)

V bull bull

1 15 1 591 E+03 1 010 1 474E+01 105E-02 354E+03 1 355E+05

Infinite

source

indoor

attenuation

coefficient

d

(unitless)

bull 108E-05

Infinite

source

bIdg

cone

^ b u i l d i n g

i (^gm)

bull bull

i 638E-02 -

Unit

risk bull factor

URF

(ngmY

Reference

cone

RfC

(mgm)

~ 23E-05 NA 1

I END

Appx B-3 Chloroform xls 3 of 3 982009

AR100316

APPENDIX B-4-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ersion 31-020^

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

nodashes)

bull 75092

ENTER Soil gas

cone

c (ngm)

Soil Gas Concentration Data ENTER

Soil gas bull

OR cone

bull C

(ppmv)

152E+03

bull bull

Chemical

Methylene chloride

MORE

MORE 4gt

ENTER Depth

below grade to bottom

of enclosed space floor

LF -

(cm)

ENTER

Soil gas sampling depth

below grade

bull U

(cm)

ENTER

Average soil

temperature

Ts bull CC)

bull bull bull bull

1 15 1 15 125

ENTER Totals

Thickness of soil

stratum A h

(cm)

ENTER ENTER must add up to value of Ls (cell F24

Thickness Thickness of soil of soil

stratum B stratum C (Enter value or 0) (Enter value or 0)

he he bull

(cm) bull (cm) -

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(usedto estimate OR perrrieability | soil vapor

permeability)

k bull

(cm)

SL 1 bull 1

ENTER Stratum A

SCS soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

Pb (gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Stratum A

soil water-filled porosity

9w (cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

Pb^

(gcm)

ENTER Stratum B soil total porosity

n^

(unitless)

ENTER Stratum B

soil water-filled porosity

(crhcm)

ENTER Stratum C

SCS soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE 4gt

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

bull Soil-bldg pressure

differential AP^

(gcm-s)

ENTER Enclosed

space floor

length LB

(cm)

ENTER Enclosed

space floor

width bull W B

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width

w

(cm)

ENTER

Indoor air exchange

rate

ER (1h)

ENTER Average vapor

flow rate into bidg OR

Leave blank to calculc

Qsoil

(Lm)

10 40 8839 8839 244 01 083

Appx B-4 MCxIs 1 of 3 982009

AR100317

Diffijsivity in air

D

APPENDIX B-4-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffusivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature

Pw H TR AHt TB TC

Molecular weight

MW

Unit risk

factor URF

Reference cone

RfC

(cms) (cms) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) bull (ngm)- (mgm)

bull bull

1 101E-01 1 117E-05 1 218E-03 1 25 | 6706 1 31300 1 51000 1 8493 1 47E-07 1 30E+00 1

Appx B-4 MCxIs 2 of 3 982009

AR100318

APPENDIX B-4-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

T

(sec)

Source- -building

separation

LT

(cm)

Stratum A soil

air-filled porosity

e a bull

(cmcm)

Stratum B soil

bullair-filled porosity bull

ea^ (cmcm)

Stratum C soil

air-filled porosity

ea= (cmcmj

Stratum A effective total fluid

saturation

Sc bull

(cmcm)

Stratum A soil

intrinsic pemneability

ki (cm)

Stratum A soil

relative air permeability

^ ^ g

(cm)

stratumA bull soil effective vapor permeability

K (cm)

Floor-wall

seam perimeter

Xcrack

(cm)

Soil gas

cone (ngm)

BIdg ventilation

rate

Qbuildinc

(cms)

1 946E+08

Area of -enclosed

space below

bull grade

AB

(cm)

1

Crack-to-total

area rafio

Tl

(unitless)

0284 1

Crack depth below grade

Zcrack

(cm)

0284 1

bull Enthalpy of vaporization at

ave soil temperature

AHTs (calmol)

0284

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

0184

Henrys law constant at ave soil

temperature

HTS

bull (unitless)

1 596E-09

Vapor viscosity at

ave soil temperature

Mrs (gcm-s)

0901

Stratum A

effective diffusion

coefficient

D (cms)

537E-09

Stratum B

effective diffusion

coefficient

D-B (cms)

35357 1

Stratum C -

effective diffusion

coefficient

D-c ^ (cms)

152E+03

Total bull overall

bull effective diffusion

coefficient

D ^

(cms)

440E+06 1

Difftjsion path

length

Ld (cm)

1 787E+07

Convection path

length

Lp (cm)

4 49E-05

Source vapor cone

Csource

(ngm)

15 1

Crack radius

Tcrack

(cm)

7007 bull 1

Average vapor

flow rate intobldg

Qsoil

(cms)

130E-03

Crack effective diffusion

coefficient pcrack

(cms)-

555E-02

bull ^

Area of crack

Acrack

(cm) bull

1 176E-04

Exponent of equivalent foundation

Peclet number

exp(Pe)

(unitless) bull

bull bull

1 15

1 END

152E+03 010 1 474E+01 1 102E-02 354E+03 1 519E+05

102E-02

Infinite source

indoor ^attenuation coefficient

bull a

(unitless)

aiii08E-05

0 OOE+00

bull

Infinite bull source

bIdg ^ cone

^bu i l d i ng

(MQm)

164E-02

OOOE+00 1

Unit risk

factor

URF

(ngm)-

47E-07 1

102E-02 j

Reference cone

RfC

(mgm)

30E+00 j

1 1

Appx B-4 MCxIs 3 of 3 982009

AR100319

APPENDIX B-5-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ^erslon 31 0204

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

127184

Soil Gas Concentration Data ENTER ^ ENTER

Soil -Soi l bull gas gas

cone OR cone Cg C bull

(tgm) (ppmv)

149E+05 1

Chemical

bull Tetrachlbroethylene

MORE 4

ENTER Depth

below grade to bottom

ofenclosecJ space floor

LF

(cm)

ENTER

Soil gas bull sampling

depth below grade

u bull (cm)

ENTER

Average bullsoil

temperature - Ts

ro 1 1 5 1 15 1 125 bull

ENTER ENTER ENTER totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hft bull he bull he

(cm) (cm) (cm)

bull 1 5 1 - 1

ENTER ENTER Soil

stratum A User^defined bull SCS bull stratum A soil type soil vapor

(used to estimate OR perrrieability soil vapor K bull

permeability) (cm) 1

SL 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

Pb

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Sitratum A

soil water-filled bull porosity

(cmcm)

ENTER Stratum B

SCS soiltype

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

Pb^

(gcm)

ENTER Stratum B soil total porosity

Ajnitless^

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS soil type

LookupSoil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

VS

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor width

W B

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width

w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

ENTER Average vapor

flow rate into bidg OR

Leave blank to calcul

bull Qsoil

(Lm)

10 40 8839 8839 244 01 083

Appx B-5 PCExIS 1 of 3 982009

AR100320

APPENDIX B-5-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal Unit

Diffusivity Diffusivity at reference reference the riormal boiling Critical Molecular risk Reference in air in water temperature temperature boiling point point teriiperature weight factor cone

Da Dbdquo H TR AHb TB Tc MW URF RfC

(cms) (cnis) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) (^gm)- (mgm)

1 720E-02 1 820E-06 1 184E-02 1 25 1 8288 1 39440 1 62020 1 16583 1 59E-06 1 60E-01 1

J

AppxB-5PCExls 2 of 3 - 982009

AR100321

APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

T

(sec)

Source-building

separation

LT

bull (cm)

Stratum A soil

air-filled porosity

Oa (cmcm)

Stratum B - soil air-filled porosity

ea (cmcm)

Stratum C soil

air-filled porosity

ea= - (cmcm)

Stratum A effective total fluid

saturation

sbdquo (cmcm)

Stratum A soil

intrinsic permeability

ki (cm)

Stratum A soil

relative air permeability

- ^ g

(cm)

Stratum A soil

effective vapor permeability

kv (cm)

Floor-wall

seam perimeter

^crack

(cm)

Soil gas

cone

(ngm)

BIdg venfilation

rate

Qbuildins

bull (cms)

bull bull

1 946E+08

Area of enclosed

space below grade

AB

(cm)

1

bullCrack-to-total

area ratio

1 (unitless)

0284 1

Crack bull depth below grade

Zcrack

(cm) -

0284 1

Enthalpy of vaporization at bull

ave soil temperature

bull A H V TS

(calmol)

0284

Henrys law constant at

ave soil temperature

HTS (atm-mmol)

0184

-Henrys law constant at

ave soil temperature

HTS

(unitless)

1 596E-09

Vapor viscosity at

ave soil temperature

HTS

(gcm-s)

0901

Stratum A

effective diffusion

coefficient bull D = bull

(cms)

537E-09

Stratum B

effective diffusion

coefficient

D--B (cms)

35357 1

Stratum C

effective diffusion bull

coefficient

D-c (crris)

149E+05

Total overall

effective bulldiffusion coefficient

DT

(cms)

440E+06 1

Difftjsion path

length

U (cm)

1 787E+07

Convection path

length

bull Lp

(cm)

4 49E-05

Source vapor cone

^source

(ngm)

15 1

Crack radius

Tcrack

(cm)

9528 1

Average vapor

flow rate intobldg

Qsoil (cms)

908E-03

Crack effective diffusion

coefficient pcrack

bull ( c m s ) bull

387E-01

Area of crack

Abdquoack (cm)

1 176E-04

Exponent of equivalent foundafion

Peclet number

exp(Pe)

(unitless)

bull

1 15-

1 END

149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08

727E-03

Infinite source indoor

attenuation coefficient

a

(unitless)

108E-05

OOOE+00

Infinite source

bIdg cone

Cburldtng

(Mgm)

161 E+00

OOOE+00 1

Unit risk

factor

URF

(ugm)-

59E-06 1

727E-03

Reference cone

RfC (mgm)

60E-01

1 1

Appx B-5 PCExls 3 of 3 982009

AR100322

APPENDIX B-6-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ersion31 0204

Reset to Defaults

t

Soil Gas Concentration Data ENTER

Chemical CAS No

(numbers only

no dashes)

79016

ENTER ENTER Soil Soil gas gas

cone OR cone C C -

bull (ngm) (ppmv)

782E+03

Chemical

Trichloroethylene

MORE ENTER Depth

below grade to bottom-

of enclosed space floor

LF

(cm)

ENTER

Soil gas sarnpling

depth below grade

U (cm)

ENTER

Average soil

temperature Ts

(degC)

1 15 1 15 t 125

ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e

(cm) (cm) (cm)

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estimate OR permeability soil vapor

permeability)

k (cm)

bull S L 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil bull-Parameters

ENTER Stratum A

soil dry bulk density

P b -

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Stratum A bull

soilwaterrfilled porosity

(cmcm) bull

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

bull P ^ (gcm)

ENTER Stratum B soil total

porosity

nlaquo

(unitless) -

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS bull soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor

width W B

(cm)

ENTER

Enclosed space height

H B bull

( c m ) bull

ENTER

Floor-wall seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bIdg OR

Leave blank to calculc

Qsoil

(Lm) -

Appx B-6 TCExIs 1 of 3 982009

A

AR100323

APPENDIX B-6-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight

Da Dbdquo H TR AH^b TB TC MW

Unit risk Reference

factor cone URF RfC

(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)

1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1

Appx B-6 TCExIs 2 of 3 982009

AR100324

APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

(sec)

Source-building

separation LT

(cm)

Stratum A soil

air-filled porosity

bull ea (cmcm)

Stratum B Soil

air-fllled porosity

e^ bull (cmcm)

Stratum C soil

air-filled porosity

(cmcm)

StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air

saturation permeability permeability

S|e k krg (cmcm) (cm) (cm)

Stratum A Floor-soil wall BIdg

effective vapor seam Soil ventilafion permeability perimeter gas rate

k^ bull Xack c o n e Qbuildins

(cm) (cm) (ngm) (cms)

946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |

Area of enclosed

space below grade

AB

(cm)

Ciack- to-total

area ratio

1 (unitless)

Crack depth below grade

Zcrack

(cm)

Enthalpy of vaporization at

ave soil temperature

A H J S

(calmol)

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law bull constant at

ave soil temperature

HTS

(unitless)

Vapor viscosity at

ave soil temperature

|JTS

(gcm^s)

Stratum A

effective diffusion

coefficient

(cms)

Stratum B

effective -diffusion

coefficient

D=B (cms)

Stratum ^ C effective diffusion

coefficient

D=c (cms)

Total overall

effective diffusion

coefficient

DT

(cms)

I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03

Diffusion path

length

Li (cm) bull

Convection bull path

length

Lp

(cm)

Source vapor cone bull

^source

(ngm)

Crack radius

rcrack

(cm)

Average vapor

- flow rate intobldg

Qsoil

(cms)

Crack effective diffusion

bull coefficient Qcrack

(cms)

Area of crack

^crack

(cm)

Exponent of equivalent foundation

Peclet bull number

exp(Pe)

(unitless)

bull bull

1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07

Infinite source Indoor

attenuation coefficient

a

(unitless)

108E-05

Infinite source

bIdg concgt

^building

(ngm)

844E-02

Unit risk

factor

URF

(ngm)-

Reference cone

RfC

(mgm)

1 1E-04 1 40E-02 1

END

Appx B-6 TCExIs 3 of 3 982009

AR100325

Office of Waste Management 1356 Hansford Street

Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256

West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director

ORDER

ISSUED UNDER THE

HAZARDOUS WASTE MANAGEMENT ACT

CHAPTER 22 ARTICLE 18

OF THE WEST VIRGINIA CODE^ AS AMENDED

y Order Number HW-011-80

To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704

ATTEMTION MREDARMON

Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull

AR100326

ViWJ011-laquo9 PageNunil)er2

BASIS FOR ORDER

As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following

A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^

B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator

C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities

0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94

^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement

P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following

1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater

2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was

^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment

CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable

CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order

AR100327

H W - 0 1 1 - 9 9 Page Number 3

REQUIREMENTS OF ORDER

Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows

1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^

2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore

remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling

GENERAL PROVaiONS

1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order

2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order

3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order

Effective Date

Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief

Wt T 1 V Oflice of Waste Management

AR100328

^ ^ S I S

^wmmmmamn

AR100329

Page 35: SDMS DocID 2121999 · International Enterprises Corp. building (Coyne Building), which is located at 1111 Vernon Street, Westmoreland District, Wayne County, West Virginia. The following

APPENDIX B-2-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Diffusivity in air

Da

(cms)

Diffusivity in water

Dw (cms)

Henrys law constant at reference temperature

H

(atm-mmoi)

Henrys law constant

reference temperature

bull T R

CC)

Enthalpy of vaporization at

the normal boiling point

AHbdquob

(calmol)

Normal boiling point

TB

(degK)

Critical temperature

Tc (degK)

Molecular weight

MW

(gmol)

Unit risk

factor URF

(ngm)

Reference cone

RfC (mgm)

1 736E-02 1 113E-05 1 407E-03 j 1 25 1 bull 7192 1 33365 1 54400 1 9694 1 OOE+00 j 35E-02 1

Appx B-2 cis-12-DCExls 2 of 3 982009

AR100312

APPENDIX B-2-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

stratum A Stratum B Stratum C Source- soil soil soil

Exposure building air-filled air-filled air-filled

duration separation porosity porosity porosity

T LT ea e^ bull e= (sec) (cm) (cmcm) (cmcm) (cmcm)

I 946E+08n^

Stratum A Stratum A Stratum A Stratum A Floor-effective soil soil soil wall total fluid intrinsic relative air effective vapor seam

saturation permeability permeability permeability perimeter

Ste kj krg ky Acrack

(cmcm) (cm) (cm) (cm) (cm)

Soil gas

cone (ngm)

I 0284 I 0284~ 0284 0184 I 596E-09 | 090T 537E-09 35357 603E+03

BIdg ventilation

rate

JbulldinE

(cms)

439E+06

Area of enclosed

space below grade

AB

(cm)

Crack-to-total

area ratio

n (unitless)

Crack depth below grade

Zltiack (cm)

Erithalpy of vaporization at

ave soil temperature

AHvTs (calmol)

Henryslaw constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law constant at

ave soil temperature

HTS

(unitless) bull

Vapor viscosity at

ave soil bull temperature

HTS

bull (gcm-s)

Stratum A

effective bull diffusion

coefficient

D^A-(cms)

Stratum B

effective bull diffusion

coefficient

D=B

(cms)

Stratum C

effective diffusion bull

coefficient

D=e (cms)

Total overall

effective diffusion

coefficient

DT

(cms)

Diffusion path

length

Ld

(cm)

I 787E+07 I bull449E-05 | 15 bull7709 230E-03 982E-02 176E-04 | 743E-03 | OOOE+00 | OOOE+00 | 743E-03 |

bull bull bull -

Convecfion path -bull

length

Lp (cm)

Source vapor cone

-source

(Mgm)

Crack radius

fcrack

(cm)

Average vapor

flow rate into bIdg

Qaoil bull

(cms)

Crack effective diffusion

coefficient pcack

(cms)

Area of crack

crack

(cm)-

Exponent of equivalent foundation

Peclet number

exp(Pef)

(unitless)

bull

1 15 -1 603E+03 1 010 1 474E+01 743E-03 354E+03 1 697E+07

Infinite source Indoor

attenuation coefficient

poundbullbullbull C t

pound(unitless)

bullsiilaquogt j ii08E-05

Infinite [ source

bIdg cone

Cbujidjng

(pgm)

651 E-02 iKrt

Unit risk

factor

URF

(ngm)-

Reference cone

RfC

(mgm)

NA 35E-02 1

I END I

Appx B-2 cis-12-DCExls 3o f3 982009

AR100313

APPENDIX B-3-A DATA ENTRY SHEET

Coyne Texti le Services - Hunt ington West Virginia

SG-ADV Version 31 0204

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

67663

Soil Gas Concentration Data ENTER ENTER

Soil Soil gas gas

cone OR cone c C

(^gm) (ppmv)

591 E+03

bull

Chemical

Chloroform

MORE ENTER Depth

below grade tb bottom

of enclosed space floor

bull LF

(cm)

ENTER

Soil gas sampling depth

below grade

(cm)

ENTER

Average soil

temperature-Ts

CO bull

1 15 1 15 1 125

ENTER ENTER ENTER Totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

IIA hs he (cm) (cm) (cm)

1 5 bull 1 1

ENTER ENTER Soil - bull

stratum A User-defined SCS stratum A

soil type bull soil vapor (used to estimate OR permeability

soil vapor k

bull permeability) (cm) 1

SL 1 1 bull

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A soil dry

bulk density

Pb (gcm)

ENTER Stratum A soil total porosity

nV (unitless)

ENTER Stratum A

-soilwater-filled bullporosity

Sraquo (cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

(unitless)

ENTER Stratum B

soil water-filled porosity

bull ebdquo=

(cmcm) bull

ENTER Straturri C

SCS bull soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

- c rack

(cm)

ENTER

Soil-bldg pressure

differential AP^

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor

width bull W B

(cm)

ENTER

Enclosed space

height HB

(cm)

ENTER

bull Floor-wall^ seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bidg OR

Leave blank to calculi

Qsoil bull

(Lm)

I -I

Appx B-3 Chloroformxls 1 of 3 982009

AR100314

APPENDIX B-3-B CHEMICALPROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Diffusivity in air

D (cms)

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffijsivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature

Dbdquo H TR A H bdquo TB Tc

(cm s) (atm-m mol) ro (calmol) (degK) (degK)

Molecular weight

MW

(gmol)

Unit risk

factor URF

(ngm)-

Reference cone

RfC

(mgm)

104E-01 100E-05 I 366E-03 25 6988 33432 53640 11938 I 23E-05 | OOE+00

Appx B-3 Chloroformxls 2 of 3 982009

AR100315

APPENDIX B-3-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure

duration

(sec)

Source-

building

separation

LT

(cm)

Stratum A

soil

air-filled

porosity

Sa

( cm cm )

Stratum B

soil

air-filled

porosity

( cm cm )

Stratum C

soil

air-filled

porosity

( c m c m )

Stratum A

effective

total fluid

saturation

( c m c m )

Stratum A

soil

intrinsic

penmeability

k

(cm )

Stratum A

- soil

relative air

permeabil i ty

(cm )

Stratum A

soil

effective vapor

permeability

kv

(cm )

Floor-

wall

seam

perimeter

gtcrack

(cm)

Soil gas

cone

(ngm)

BIdg

venfilation

rate

^buildlriE

(cms)

I 9 4 6 E + 0 8 ~ T I 0284 T 596E-09 I 0-901 I 537E-09 | 35357 | 591 E+03 j 439E+06 | 1 0 284 0284 0184

Area of

enclosed

space

below

grade

A B

( c m )

Crack-

to-total

area

ratio

n

(unitless)

Crack

depth

bull below

grade

^crack

(cm)

Enthalpy of

vaporization at

ave soil

temperature

AHTs bull

(calmol)

Henry s law

constant at

ave soil

temperature

HTS

(a tm-m mol j

Henrys law

constant at

ave soil

bull temperature

HTS

(unitless) bull

Vapor

viscosity at

ave soil-

temperature

^HTS

(gcm-s)

Stratum

A

effective

diffusion

coefficient

(cm s)

Stratum

B

effective

difftjsion

coefficient

D B

(cms) bull

S t ra tum

C

effective

diffusion

coefficient

Dc

(cm s)

Total

overall

effective

bull diffusion

coefficient

D T

(cm s)

Diffi jsion

path

length

Ld

(cm)

I 787E+07 I 449E-05 j - bull 15 7528 210E-03 896E-02 176E-04 I 105E-02 | OOOE+00 | OOOE+00 | 105E-02

Convection

path length

Lp

(cm)

Source

vapor

cone -

^source

- (ngm)

Crack

radius

Tcrack

(cm)

Average

vapor

flow rate

into bidg

Qsoil

(cms)

Crack

effective

diffusion

coefficient Qcrack

bull (cms)

Area of crack

Acrack

(cm)

Exponent of

equivalent

foundation

Peclet number

exp(Pe)

(unitless)

V bull bull

1 15 1 591 E+03 1 010 1 474E+01 105E-02 354E+03 1 355E+05

Infinite

source

indoor

attenuation

coefficient

d

(unitless)

bull 108E-05

Infinite

source

bIdg

cone

^ b u i l d i n g

i (^gm)

bull bull

i 638E-02 -

Unit

risk bull factor

URF

(ngmY

Reference

cone

RfC

(mgm)

~ 23E-05 NA 1

I END

Appx B-3 Chloroform xls 3 of 3 982009

AR100316

APPENDIX B-4-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ersion 31-020^

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

nodashes)

bull 75092

ENTER Soil gas

cone

c (ngm)

Soil Gas Concentration Data ENTER

Soil gas bull

OR cone

bull C

(ppmv)

152E+03

bull bull

Chemical

Methylene chloride

MORE

MORE 4gt

ENTER Depth

below grade to bottom

of enclosed space floor

LF -

(cm)

ENTER

Soil gas sampling depth

below grade

bull U

(cm)

ENTER

Average soil

temperature

Ts bull CC)

bull bull bull bull

1 15 1 15 125

ENTER Totals

Thickness of soil

stratum A h

(cm)

ENTER ENTER must add up to value of Ls (cell F24

Thickness Thickness of soil of soil

stratum B stratum C (Enter value or 0) (Enter value or 0)

he he bull

(cm) bull (cm) -

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(usedto estimate OR perrrieability | soil vapor

permeability)

k bull

(cm)

SL 1 bull 1

ENTER Stratum A

SCS soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

Pb (gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Stratum A

soil water-filled porosity

9w (cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

Pb^

(gcm)

ENTER Stratum B soil total porosity

n^

(unitless)

ENTER Stratum B

soil water-filled porosity

(crhcm)

ENTER Stratum C

SCS soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE 4gt

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

bull Soil-bldg pressure

differential AP^

(gcm-s)

ENTER Enclosed

space floor

length LB

(cm)

ENTER Enclosed

space floor

width bull W B

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width

w

(cm)

ENTER

Indoor air exchange

rate

ER (1h)

ENTER Average vapor

flow rate into bidg OR

Leave blank to calculc

Qsoil

(Lm)

10 40 8839 8839 244 01 083

Appx B-4 MCxIs 1 of 3 982009

AR100317

Diffijsivity in air

D

APPENDIX B-4-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffusivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature

Pw H TR AHt TB TC

Molecular weight

MW

Unit risk

factor URF

Reference cone

RfC

(cms) (cms) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) bull (ngm)- (mgm)

bull bull

1 101E-01 1 117E-05 1 218E-03 1 25 | 6706 1 31300 1 51000 1 8493 1 47E-07 1 30E+00 1

Appx B-4 MCxIs 2 of 3 982009

AR100318

APPENDIX B-4-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

T

(sec)

Source- -building

separation

LT

(cm)

Stratum A soil

air-filled porosity

e a bull

(cmcm)

Stratum B soil

bullair-filled porosity bull

ea^ (cmcm)

Stratum C soil

air-filled porosity

ea= (cmcmj

Stratum A effective total fluid

saturation

Sc bull

(cmcm)

Stratum A soil

intrinsic pemneability

ki (cm)

Stratum A soil

relative air permeability

^ ^ g

(cm)

stratumA bull soil effective vapor permeability

K (cm)

Floor-wall

seam perimeter

Xcrack

(cm)

Soil gas

cone (ngm)

BIdg ventilation

rate

Qbuildinc

(cms)

1 946E+08

Area of -enclosed

space below

bull grade

AB

(cm)

1

Crack-to-total

area rafio

Tl

(unitless)

0284 1

Crack depth below grade

Zcrack

(cm)

0284 1

bull Enthalpy of vaporization at

ave soil temperature

AHTs (calmol)

0284

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

0184

Henrys law constant at ave soil

temperature

HTS

bull (unitless)

1 596E-09

Vapor viscosity at

ave soil temperature

Mrs (gcm-s)

0901

Stratum A

effective diffusion

coefficient

D (cms)

537E-09

Stratum B

effective diffusion

coefficient

D-B (cms)

35357 1

Stratum C -

effective diffusion

coefficient

D-c ^ (cms)

152E+03

Total bull overall

bull effective diffusion

coefficient

D ^

(cms)

440E+06 1

Difftjsion path

length

Ld (cm)

1 787E+07

Convection path

length

Lp (cm)

4 49E-05

Source vapor cone

Csource

(ngm)

15 1

Crack radius

Tcrack

(cm)

7007 bull 1

Average vapor

flow rate intobldg

Qsoil

(cms)

130E-03

Crack effective diffusion

coefficient pcrack

(cms)-

555E-02

bull ^

Area of crack

Acrack

(cm) bull

1 176E-04

Exponent of equivalent foundation

Peclet number

exp(Pe)

(unitless) bull

bull bull

1 15

1 END

152E+03 010 1 474E+01 1 102E-02 354E+03 1 519E+05

102E-02

Infinite source

indoor ^attenuation coefficient

bull a

(unitless)

aiii08E-05

0 OOE+00

bull

Infinite bull source

bIdg ^ cone

^bu i l d i ng

(MQm)

164E-02

OOOE+00 1

Unit risk

factor

URF

(ngm)-

47E-07 1

102E-02 j

Reference cone

RfC

(mgm)

30E+00 j

1 1

Appx B-4 MCxIs 3 of 3 982009

AR100319

APPENDIX B-5-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ^erslon 31 0204

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

127184

Soil Gas Concentration Data ENTER ^ ENTER

Soil -Soi l bull gas gas

cone OR cone Cg C bull

(tgm) (ppmv)

149E+05 1

Chemical

bull Tetrachlbroethylene

MORE 4

ENTER Depth

below grade to bottom

ofenclosecJ space floor

LF

(cm)

ENTER

Soil gas bull sampling

depth below grade

u bull (cm)

ENTER

Average bullsoil

temperature - Ts

ro 1 1 5 1 15 1 125 bull

ENTER ENTER ENTER totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hft bull he bull he

(cm) (cm) (cm)

bull 1 5 1 - 1

ENTER ENTER Soil

stratum A User^defined bull SCS bull stratum A soil type soil vapor

(used to estimate OR perrrieability soil vapor K bull

permeability) (cm) 1

SL 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

Pb

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Sitratum A

soil water-filled bull porosity

(cmcm)

ENTER Stratum B

SCS soiltype

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

Pb^

(gcm)

ENTER Stratum B soil total porosity

Ajnitless^

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS soil type

LookupSoil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

VS

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor width

W B

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width

w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

ENTER Average vapor

flow rate into bidg OR

Leave blank to calcul

bull Qsoil

(Lm)

10 40 8839 8839 244 01 083

Appx B-5 PCExIS 1 of 3 982009

AR100320

APPENDIX B-5-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal Unit

Diffusivity Diffusivity at reference reference the riormal boiling Critical Molecular risk Reference in air in water temperature temperature boiling point point teriiperature weight factor cone

Da Dbdquo H TR AHb TB Tc MW URF RfC

(cms) (cnis) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) (^gm)- (mgm)

1 720E-02 1 820E-06 1 184E-02 1 25 1 8288 1 39440 1 62020 1 16583 1 59E-06 1 60E-01 1

J

AppxB-5PCExls 2 of 3 - 982009

AR100321

APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

T

(sec)

Source-building

separation

LT

bull (cm)

Stratum A soil

air-filled porosity

Oa (cmcm)

Stratum B - soil air-filled porosity

ea (cmcm)

Stratum C soil

air-filled porosity

ea= - (cmcm)

Stratum A effective total fluid

saturation

sbdquo (cmcm)

Stratum A soil

intrinsic permeability

ki (cm)

Stratum A soil

relative air permeability

- ^ g

(cm)

Stratum A soil

effective vapor permeability

kv (cm)

Floor-wall

seam perimeter

^crack

(cm)

Soil gas

cone

(ngm)

BIdg venfilation

rate

Qbuildins

bull (cms)

bull bull

1 946E+08

Area of enclosed

space below grade

AB

(cm)

1

bullCrack-to-total

area ratio

1 (unitless)

0284 1

Crack bull depth below grade

Zcrack

(cm) -

0284 1

Enthalpy of vaporization at bull

ave soil temperature

bull A H V TS

(calmol)

0284

Henrys law constant at

ave soil temperature

HTS (atm-mmol)

0184

-Henrys law constant at

ave soil temperature

HTS

(unitless)

1 596E-09

Vapor viscosity at

ave soil temperature

HTS

(gcm-s)

0901

Stratum A

effective diffusion

coefficient bull D = bull

(cms)

537E-09

Stratum B

effective diffusion

coefficient

D--B (cms)

35357 1

Stratum C

effective diffusion bull

coefficient

D-c (crris)

149E+05

Total overall

effective bulldiffusion coefficient

DT

(cms)

440E+06 1

Difftjsion path

length

U (cm)

1 787E+07

Convection path

length

bull Lp

(cm)

4 49E-05

Source vapor cone

^source

(ngm)

15 1

Crack radius

Tcrack

(cm)

9528 1

Average vapor

flow rate intobldg

Qsoil (cms)

908E-03

Crack effective diffusion

coefficient pcrack

bull ( c m s ) bull

387E-01

Area of crack

Abdquoack (cm)

1 176E-04

Exponent of equivalent foundafion

Peclet number

exp(Pe)

(unitless)

bull

1 15-

1 END

149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08

727E-03

Infinite source indoor

attenuation coefficient

a

(unitless)

108E-05

OOOE+00

Infinite source

bIdg cone

Cburldtng

(Mgm)

161 E+00

OOOE+00 1

Unit risk

factor

URF

(ugm)-

59E-06 1

727E-03

Reference cone

RfC (mgm)

60E-01

1 1

Appx B-5 PCExls 3 of 3 982009

AR100322

APPENDIX B-6-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ersion31 0204

Reset to Defaults

t

Soil Gas Concentration Data ENTER

Chemical CAS No

(numbers only

no dashes)

79016

ENTER ENTER Soil Soil gas gas

cone OR cone C C -

bull (ngm) (ppmv)

782E+03

Chemical

Trichloroethylene

MORE ENTER Depth

below grade to bottom-

of enclosed space floor

LF

(cm)

ENTER

Soil gas sarnpling

depth below grade

U (cm)

ENTER

Average soil

temperature Ts

(degC)

1 15 1 15 t 125

ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e

(cm) (cm) (cm)

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estimate OR permeability soil vapor

permeability)

k (cm)

bull S L 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil bull-Parameters

ENTER Stratum A

soil dry bulk density

P b -

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Stratum A bull

soilwaterrfilled porosity

(cmcm) bull

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

bull P ^ (gcm)

ENTER Stratum B soil total

porosity

nlaquo

(unitless) -

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS bull soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor

width W B

(cm)

ENTER

Enclosed space height

H B bull

( c m ) bull

ENTER

Floor-wall seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bIdg OR

Leave blank to calculc

Qsoil

(Lm) -

Appx B-6 TCExIs 1 of 3 982009

A

AR100323

APPENDIX B-6-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight

Da Dbdquo H TR AH^b TB TC MW

Unit risk Reference

factor cone URF RfC

(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)

1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1

Appx B-6 TCExIs 2 of 3 982009

AR100324

APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

(sec)

Source-building

separation LT

(cm)

Stratum A soil

air-filled porosity

bull ea (cmcm)

Stratum B Soil

air-fllled porosity

e^ bull (cmcm)

Stratum C soil

air-filled porosity

(cmcm)

StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air

saturation permeability permeability

S|e k krg (cmcm) (cm) (cm)

Stratum A Floor-soil wall BIdg

effective vapor seam Soil ventilafion permeability perimeter gas rate

k^ bull Xack c o n e Qbuildins

(cm) (cm) (ngm) (cms)

946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |

Area of enclosed

space below grade

AB

(cm)

Ciack- to-total

area ratio

1 (unitless)

Crack depth below grade

Zcrack

(cm)

Enthalpy of vaporization at

ave soil temperature

A H J S

(calmol)

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law bull constant at

ave soil temperature

HTS

(unitless)

Vapor viscosity at

ave soil temperature

|JTS

(gcm^s)

Stratum A

effective diffusion

coefficient

(cms)

Stratum B

effective -diffusion

coefficient

D=B (cms)

Stratum ^ C effective diffusion

coefficient

D=c (cms)

Total overall

effective diffusion

coefficient

DT

(cms)

I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03

Diffusion path

length

Li (cm) bull

Convection bull path

length

Lp

(cm)

Source vapor cone bull

^source

(ngm)

Crack radius

rcrack

(cm)

Average vapor

- flow rate intobldg

Qsoil

(cms)

Crack effective diffusion

bull coefficient Qcrack

(cms)

Area of crack

^crack

(cm)

Exponent of equivalent foundation

Peclet bull number

exp(Pe)

(unitless)

bull bull

1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07

Infinite source Indoor

attenuation coefficient

a

(unitless)

108E-05

Infinite source

bIdg concgt

^building

(ngm)

844E-02

Unit risk

factor

URF

(ngm)-

Reference cone

RfC

(mgm)

1 1E-04 1 40E-02 1

END

Appx B-6 TCExIs 3 of 3 982009

AR100325

Office of Waste Management 1356 Hansford Street

Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256

West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director

ORDER

ISSUED UNDER THE

HAZARDOUS WASTE MANAGEMENT ACT

CHAPTER 22 ARTICLE 18

OF THE WEST VIRGINIA CODE^ AS AMENDED

y Order Number HW-011-80

To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704

ATTEMTION MREDARMON

Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull

AR100326

ViWJ011-laquo9 PageNunil)er2

BASIS FOR ORDER

As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following

A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^

B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator

C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities

0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94

^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement

P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following

1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater

2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was

^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment

CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable

CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order

AR100327

H W - 0 1 1 - 9 9 Page Number 3

REQUIREMENTS OF ORDER

Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows

1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^

2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore

remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling

GENERAL PROVaiONS

1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order

2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order

3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order

Effective Date

Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief

Wt T 1 V Oflice of Waste Management

AR100328

^ ^ S I S

^wmmmmamn

AR100329

Page 36: SDMS DocID 2121999 · International Enterprises Corp. building (Coyne Building), which is located at 1111 Vernon Street, Westmoreland District, Wayne County, West Virginia. The following

APPENDIX B-2-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

stratum A Stratum B Stratum C Source- soil soil soil

Exposure building air-filled air-filled air-filled

duration separation porosity porosity porosity

T LT ea e^ bull e= (sec) (cm) (cmcm) (cmcm) (cmcm)

I 946E+08n^

Stratum A Stratum A Stratum A Stratum A Floor-effective soil soil soil wall total fluid intrinsic relative air effective vapor seam

saturation permeability permeability permeability perimeter

Ste kj krg ky Acrack

(cmcm) (cm) (cm) (cm) (cm)

Soil gas

cone (ngm)

I 0284 I 0284~ 0284 0184 I 596E-09 | 090T 537E-09 35357 603E+03

BIdg ventilation

rate

JbulldinE

(cms)

439E+06

Area of enclosed

space below grade

AB

(cm)

Crack-to-total

area ratio

n (unitless)

Crack depth below grade

Zltiack (cm)

Erithalpy of vaporization at

ave soil temperature

AHvTs (calmol)

Henryslaw constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law constant at

ave soil temperature

HTS

(unitless) bull

Vapor viscosity at

ave soil bull temperature

HTS

bull (gcm-s)

Stratum A

effective bull diffusion

coefficient

D^A-(cms)

Stratum B

effective bull diffusion

coefficient

D=B

(cms)

Stratum C

effective diffusion bull

coefficient

D=e (cms)

Total overall

effective diffusion

coefficient

DT

(cms)

Diffusion path

length

Ld

(cm)

I 787E+07 I bull449E-05 | 15 bull7709 230E-03 982E-02 176E-04 | 743E-03 | OOOE+00 | OOOE+00 | 743E-03 |

bull bull bull -

Convecfion path -bull

length

Lp (cm)

Source vapor cone

-source

(Mgm)

Crack radius

fcrack

(cm)

Average vapor

flow rate into bIdg

Qaoil bull

(cms)

Crack effective diffusion

coefficient pcack

(cms)

Area of crack

crack

(cm)-

Exponent of equivalent foundation

Peclet number

exp(Pef)

(unitless)

bull

1 15 -1 603E+03 1 010 1 474E+01 743E-03 354E+03 1 697E+07

Infinite source Indoor

attenuation coefficient

poundbullbullbull C t

pound(unitless)

bullsiilaquogt j ii08E-05

Infinite [ source

bIdg cone

Cbujidjng

(pgm)

651 E-02 iKrt

Unit risk

factor

URF

(ngm)-

Reference cone

RfC

(mgm)

NA 35E-02 1

I END I

Appx B-2 cis-12-DCExls 3o f3 982009

AR100313

APPENDIX B-3-A DATA ENTRY SHEET

Coyne Texti le Services - Hunt ington West Virginia

SG-ADV Version 31 0204

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

67663

Soil Gas Concentration Data ENTER ENTER

Soil Soil gas gas

cone OR cone c C

(^gm) (ppmv)

591 E+03

bull

Chemical

Chloroform

MORE ENTER Depth

below grade tb bottom

of enclosed space floor

bull LF

(cm)

ENTER

Soil gas sampling depth

below grade

(cm)

ENTER

Average soil

temperature-Ts

CO bull

1 15 1 15 1 125

ENTER ENTER ENTER Totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

IIA hs he (cm) (cm) (cm)

1 5 bull 1 1

ENTER ENTER Soil - bull

stratum A User-defined SCS stratum A

soil type bull soil vapor (used to estimate OR permeability

soil vapor k

bull permeability) (cm) 1

SL 1 1 bull

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A soil dry

bulk density

Pb (gcm)

ENTER Stratum A soil total porosity

nV (unitless)

ENTER Stratum A

-soilwater-filled bullporosity

Sraquo (cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

(unitless)

ENTER Stratum B

soil water-filled porosity

bull ebdquo=

(cmcm) bull

ENTER Straturri C

SCS bull soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

- c rack

(cm)

ENTER

Soil-bldg pressure

differential AP^

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor

width bull W B

(cm)

ENTER

Enclosed space

height HB

(cm)

ENTER

bull Floor-wall^ seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bidg OR

Leave blank to calculi

Qsoil bull

(Lm)

I -I

Appx B-3 Chloroformxls 1 of 3 982009

AR100314

APPENDIX B-3-B CHEMICALPROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Diffusivity in air

D (cms)

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffijsivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature

Dbdquo H TR A H bdquo TB Tc

(cm s) (atm-m mol) ro (calmol) (degK) (degK)

Molecular weight

MW

(gmol)

Unit risk

factor URF

(ngm)-

Reference cone

RfC

(mgm)

104E-01 100E-05 I 366E-03 25 6988 33432 53640 11938 I 23E-05 | OOE+00

Appx B-3 Chloroformxls 2 of 3 982009

AR100315

APPENDIX B-3-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure

duration

(sec)

Source-

building

separation

LT

(cm)

Stratum A

soil

air-filled

porosity

Sa

( cm cm )

Stratum B

soil

air-filled

porosity

( cm cm )

Stratum C

soil

air-filled

porosity

( c m c m )

Stratum A

effective

total fluid

saturation

( c m c m )

Stratum A

soil

intrinsic

penmeability

k

(cm )

Stratum A

- soil

relative air

permeabil i ty

(cm )

Stratum A

soil

effective vapor

permeability

kv

(cm )

Floor-

wall

seam

perimeter

gtcrack

(cm)

Soil gas

cone

(ngm)

BIdg

venfilation

rate

^buildlriE

(cms)

I 9 4 6 E + 0 8 ~ T I 0284 T 596E-09 I 0-901 I 537E-09 | 35357 | 591 E+03 j 439E+06 | 1 0 284 0284 0184

Area of

enclosed

space

below

grade

A B

( c m )

Crack-

to-total

area

ratio

n

(unitless)

Crack

depth

bull below

grade

^crack

(cm)

Enthalpy of

vaporization at

ave soil

temperature

AHTs bull

(calmol)

Henry s law

constant at

ave soil

temperature

HTS

(a tm-m mol j

Henrys law

constant at

ave soil

bull temperature

HTS

(unitless) bull

Vapor

viscosity at

ave soil-

temperature

^HTS

(gcm-s)

Stratum

A

effective

diffusion

coefficient

(cm s)

Stratum

B

effective

difftjsion

coefficient

D B

(cms) bull

S t ra tum

C

effective

diffusion

coefficient

Dc

(cm s)

Total

overall

effective

bull diffusion

coefficient

D T

(cm s)

Diffi jsion

path

length

Ld

(cm)

I 787E+07 I 449E-05 j - bull 15 7528 210E-03 896E-02 176E-04 I 105E-02 | OOOE+00 | OOOE+00 | 105E-02

Convection

path length

Lp

(cm)

Source

vapor

cone -

^source

- (ngm)

Crack

radius

Tcrack

(cm)

Average

vapor

flow rate

into bidg

Qsoil

(cms)

Crack

effective

diffusion

coefficient Qcrack

bull (cms)

Area of crack

Acrack

(cm)

Exponent of

equivalent

foundation

Peclet number

exp(Pe)

(unitless)

V bull bull

1 15 1 591 E+03 1 010 1 474E+01 105E-02 354E+03 1 355E+05

Infinite

source

indoor

attenuation

coefficient

d

(unitless)

bull 108E-05

Infinite

source

bIdg

cone

^ b u i l d i n g

i (^gm)

bull bull

i 638E-02 -

Unit

risk bull factor

URF

(ngmY

Reference

cone

RfC

(mgm)

~ 23E-05 NA 1

I END

Appx B-3 Chloroform xls 3 of 3 982009

AR100316

APPENDIX B-4-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ersion 31-020^

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

nodashes)

bull 75092

ENTER Soil gas

cone

c (ngm)

Soil Gas Concentration Data ENTER

Soil gas bull

OR cone

bull C

(ppmv)

152E+03

bull bull

Chemical

Methylene chloride

MORE

MORE 4gt

ENTER Depth

below grade to bottom

of enclosed space floor

LF -

(cm)

ENTER

Soil gas sampling depth

below grade

bull U

(cm)

ENTER

Average soil

temperature

Ts bull CC)

bull bull bull bull

1 15 1 15 125

ENTER Totals

Thickness of soil

stratum A h

(cm)

ENTER ENTER must add up to value of Ls (cell F24

Thickness Thickness of soil of soil

stratum B stratum C (Enter value or 0) (Enter value or 0)

he he bull

(cm) bull (cm) -

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(usedto estimate OR perrrieability | soil vapor

permeability)

k bull

(cm)

SL 1 bull 1

ENTER Stratum A

SCS soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

Pb (gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Stratum A

soil water-filled porosity

9w (cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

Pb^

(gcm)

ENTER Stratum B soil total porosity

n^

(unitless)

ENTER Stratum B

soil water-filled porosity

(crhcm)

ENTER Stratum C

SCS soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE 4gt

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

bull Soil-bldg pressure

differential AP^

(gcm-s)

ENTER Enclosed

space floor

length LB

(cm)

ENTER Enclosed

space floor

width bull W B

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width

w

(cm)

ENTER

Indoor air exchange

rate

ER (1h)

ENTER Average vapor

flow rate into bidg OR

Leave blank to calculc

Qsoil

(Lm)

10 40 8839 8839 244 01 083

Appx B-4 MCxIs 1 of 3 982009

AR100317

Diffijsivity in air

D

APPENDIX B-4-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffusivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature

Pw H TR AHt TB TC

Molecular weight

MW

Unit risk

factor URF

Reference cone

RfC

(cms) (cms) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) bull (ngm)- (mgm)

bull bull

1 101E-01 1 117E-05 1 218E-03 1 25 | 6706 1 31300 1 51000 1 8493 1 47E-07 1 30E+00 1

Appx B-4 MCxIs 2 of 3 982009

AR100318

APPENDIX B-4-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

T

(sec)

Source- -building

separation

LT

(cm)

Stratum A soil

air-filled porosity

e a bull

(cmcm)

Stratum B soil

bullair-filled porosity bull

ea^ (cmcm)

Stratum C soil

air-filled porosity

ea= (cmcmj

Stratum A effective total fluid

saturation

Sc bull

(cmcm)

Stratum A soil

intrinsic pemneability

ki (cm)

Stratum A soil

relative air permeability

^ ^ g

(cm)

stratumA bull soil effective vapor permeability

K (cm)

Floor-wall

seam perimeter

Xcrack

(cm)

Soil gas

cone (ngm)

BIdg ventilation

rate

Qbuildinc

(cms)

1 946E+08

Area of -enclosed

space below

bull grade

AB

(cm)

1

Crack-to-total

area rafio

Tl

(unitless)

0284 1

Crack depth below grade

Zcrack

(cm)

0284 1

bull Enthalpy of vaporization at

ave soil temperature

AHTs (calmol)

0284

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

0184

Henrys law constant at ave soil

temperature

HTS

bull (unitless)

1 596E-09

Vapor viscosity at

ave soil temperature

Mrs (gcm-s)

0901

Stratum A

effective diffusion

coefficient

D (cms)

537E-09

Stratum B

effective diffusion

coefficient

D-B (cms)

35357 1

Stratum C -

effective diffusion

coefficient

D-c ^ (cms)

152E+03

Total bull overall

bull effective diffusion

coefficient

D ^

(cms)

440E+06 1

Difftjsion path

length

Ld (cm)

1 787E+07

Convection path

length

Lp (cm)

4 49E-05

Source vapor cone

Csource

(ngm)

15 1

Crack radius

Tcrack

(cm)

7007 bull 1

Average vapor

flow rate intobldg

Qsoil

(cms)

130E-03

Crack effective diffusion

coefficient pcrack

(cms)-

555E-02

bull ^

Area of crack

Acrack

(cm) bull

1 176E-04

Exponent of equivalent foundation

Peclet number

exp(Pe)

(unitless) bull

bull bull

1 15

1 END

152E+03 010 1 474E+01 1 102E-02 354E+03 1 519E+05

102E-02

Infinite source

indoor ^attenuation coefficient

bull a

(unitless)

aiii08E-05

0 OOE+00

bull

Infinite bull source

bIdg ^ cone

^bu i l d i ng

(MQm)

164E-02

OOOE+00 1

Unit risk

factor

URF

(ngm)-

47E-07 1

102E-02 j

Reference cone

RfC

(mgm)

30E+00 j

1 1

Appx B-4 MCxIs 3 of 3 982009

AR100319

APPENDIX B-5-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ^erslon 31 0204

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

127184

Soil Gas Concentration Data ENTER ^ ENTER

Soil -Soi l bull gas gas

cone OR cone Cg C bull

(tgm) (ppmv)

149E+05 1

Chemical

bull Tetrachlbroethylene

MORE 4

ENTER Depth

below grade to bottom

ofenclosecJ space floor

LF

(cm)

ENTER

Soil gas bull sampling

depth below grade

u bull (cm)

ENTER

Average bullsoil

temperature - Ts

ro 1 1 5 1 15 1 125 bull

ENTER ENTER ENTER totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hft bull he bull he

(cm) (cm) (cm)

bull 1 5 1 - 1

ENTER ENTER Soil

stratum A User^defined bull SCS bull stratum A soil type soil vapor

(used to estimate OR perrrieability soil vapor K bull

permeability) (cm) 1

SL 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

Pb

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Sitratum A

soil water-filled bull porosity

(cmcm)

ENTER Stratum B

SCS soiltype

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

Pb^

(gcm)

ENTER Stratum B soil total porosity

Ajnitless^

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS soil type

LookupSoil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

VS

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor width

W B

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width

w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

ENTER Average vapor

flow rate into bidg OR

Leave blank to calcul

bull Qsoil

(Lm)

10 40 8839 8839 244 01 083

Appx B-5 PCExIS 1 of 3 982009

AR100320

APPENDIX B-5-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal Unit

Diffusivity Diffusivity at reference reference the riormal boiling Critical Molecular risk Reference in air in water temperature temperature boiling point point teriiperature weight factor cone

Da Dbdquo H TR AHb TB Tc MW URF RfC

(cms) (cnis) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) (^gm)- (mgm)

1 720E-02 1 820E-06 1 184E-02 1 25 1 8288 1 39440 1 62020 1 16583 1 59E-06 1 60E-01 1

J

AppxB-5PCExls 2 of 3 - 982009

AR100321

APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

T

(sec)

Source-building

separation

LT

bull (cm)

Stratum A soil

air-filled porosity

Oa (cmcm)

Stratum B - soil air-filled porosity

ea (cmcm)

Stratum C soil

air-filled porosity

ea= - (cmcm)

Stratum A effective total fluid

saturation

sbdquo (cmcm)

Stratum A soil

intrinsic permeability

ki (cm)

Stratum A soil

relative air permeability

- ^ g

(cm)

Stratum A soil

effective vapor permeability

kv (cm)

Floor-wall

seam perimeter

^crack

(cm)

Soil gas

cone

(ngm)

BIdg venfilation

rate

Qbuildins

bull (cms)

bull bull

1 946E+08

Area of enclosed

space below grade

AB

(cm)

1

bullCrack-to-total

area ratio

1 (unitless)

0284 1

Crack bull depth below grade

Zcrack

(cm) -

0284 1

Enthalpy of vaporization at bull

ave soil temperature

bull A H V TS

(calmol)

0284

Henrys law constant at

ave soil temperature

HTS (atm-mmol)

0184

-Henrys law constant at

ave soil temperature

HTS

(unitless)

1 596E-09

Vapor viscosity at

ave soil temperature

HTS

(gcm-s)

0901

Stratum A

effective diffusion

coefficient bull D = bull

(cms)

537E-09

Stratum B

effective diffusion

coefficient

D--B (cms)

35357 1

Stratum C

effective diffusion bull

coefficient

D-c (crris)

149E+05

Total overall

effective bulldiffusion coefficient

DT

(cms)

440E+06 1

Difftjsion path

length

U (cm)

1 787E+07

Convection path

length

bull Lp

(cm)

4 49E-05

Source vapor cone

^source

(ngm)

15 1

Crack radius

Tcrack

(cm)

9528 1

Average vapor

flow rate intobldg

Qsoil (cms)

908E-03

Crack effective diffusion

coefficient pcrack

bull ( c m s ) bull

387E-01

Area of crack

Abdquoack (cm)

1 176E-04

Exponent of equivalent foundafion

Peclet number

exp(Pe)

(unitless)

bull

1 15-

1 END

149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08

727E-03

Infinite source indoor

attenuation coefficient

a

(unitless)

108E-05

OOOE+00

Infinite source

bIdg cone

Cburldtng

(Mgm)

161 E+00

OOOE+00 1

Unit risk

factor

URF

(ugm)-

59E-06 1

727E-03

Reference cone

RfC (mgm)

60E-01

1 1

Appx B-5 PCExls 3 of 3 982009

AR100322

APPENDIX B-6-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ersion31 0204

Reset to Defaults

t

Soil Gas Concentration Data ENTER

Chemical CAS No

(numbers only

no dashes)

79016

ENTER ENTER Soil Soil gas gas

cone OR cone C C -

bull (ngm) (ppmv)

782E+03

Chemical

Trichloroethylene

MORE ENTER Depth

below grade to bottom-

of enclosed space floor

LF

(cm)

ENTER

Soil gas sarnpling

depth below grade

U (cm)

ENTER

Average soil

temperature Ts

(degC)

1 15 1 15 t 125

ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e

(cm) (cm) (cm)

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estimate OR permeability soil vapor

permeability)

k (cm)

bull S L 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil bull-Parameters

ENTER Stratum A

soil dry bulk density

P b -

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Stratum A bull

soilwaterrfilled porosity

(cmcm) bull

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

bull P ^ (gcm)

ENTER Stratum B soil total

porosity

nlaquo

(unitless) -

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS bull soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor

width W B

(cm)

ENTER

Enclosed space height

H B bull

( c m ) bull

ENTER

Floor-wall seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bIdg OR

Leave blank to calculc

Qsoil

(Lm) -

Appx B-6 TCExIs 1 of 3 982009

A

AR100323

APPENDIX B-6-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight

Da Dbdquo H TR AH^b TB TC MW

Unit risk Reference

factor cone URF RfC

(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)

1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1

Appx B-6 TCExIs 2 of 3 982009

AR100324

APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

(sec)

Source-building

separation LT

(cm)

Stratum A soil

air-filled porosity

bull ea (cmcm)

Stratum B Soil

air-fllled porosity

e^ bull (cmcm)

Stratum C soil

air-filled porosity

(cmcm)

StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air

saturation permeability permeability

S|e k krg (cmcm) (cm) (cm)

Stratum A Floor-soil wall BIdg

effective vapor seam Soil ventilafion permeability perimeter gas rate

k^ bull Xack c o n e Qbuildins

(cm) (cm) (ngm) (cms)

946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |

Area of enclosed

space below grade

AB

(cm)

Ciack- to-total

area ratio

1 (unitless)

Crack depth below grade

Zcrack

(cm)

Enthalpy of vaporization at

ave soil temperature

A H J S

(calmol)

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law bull constant at

ave soil temperature

HTS

(unitless)

Vapor viscosity at

ave soil temperature

|JTS

(gcm^s)

Stratum A

effective diffusion

coefficient

(cms)

Stratum B

effective -diffusion

coefficient

D=B (cms)

Stratum ^ C effective diffusion

coefficient

D=c (cms)

Total overall

effective diffusion

coefficient

DT

(cms)

I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03

Diffusion path

length

Li (cm) bull

Convection bull path

length

Lp

(cm)

Source vapor cone bull

^source

(ngm)

Crack radius

rcrack

(cm)

Average vapor

- flow rate intobldg

Qsoil

(cms)

Crack effective diffusion

bull coefficient Qcrack

(cms)

Area of crack

^crack

(cm)

Exponent of equivalent foundation

Peclet bull number

exp(Pe)

(unitless)

bull bull

1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07

Infinite source Indoor

attenuation coefficient

a

(unitless)

108E-05

Infinite source

bIdg concgt

^building

(ngm)

844E-02

Unit risk

factor

URF

(ngm)-

Reference cone

RfC

(mgm)

1 1E-04 1 40E-02 1

END

Appx B-6 TCExIs 3 of 3 982009

AR100325

Office of Waste Management 1356 Hansford Street

Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256

West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director

ORDER

ISSUED UNDER THE

HAZARDOUS WASTE MANAGEMENT ACT

CHAPTER 22 ARTICLE 18

OF THE WEST VIRGINIA CODE^ AS AMENDED

y Order Number HW-011-80

To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704

ATTEMTION MREDARMON

Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull

AR100326

ViWJ011-laquo9 PageNunil)er2

BASIS FOR ORDER

As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following

A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^

B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator

C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities

0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94

^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement

P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following

1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater

2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was

^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment

CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable

CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order

AR100327

H W - 0 1 1 - 9 9 Page Number 3

REQUIREMENTS OF ORDER

Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows

1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^

2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore

remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling

GENERAL PROVaiONS

1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order

2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order

3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order

Effective Date

Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief

Wt T 1 V Oflice of Waste Management

AR100328

^ ^ S I S

^wmmmmamn

AR100329

Page 37: SDMS DocID 2121999 · International Enterprises Corp. building (Coyne Building), which is located at 1111 Vernon Street, Westmoreland District, Wayne County, West Virginia. The following

APPENDIX B-3-A DATA ENTRY SHEET

Coyne Texti le Services - Hunt ington West Virginia

SG-ADV Version 31 0204

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

67663

Soil Gas Concentration Data ENTER ENTER

Soil Soil gas gas

cone OR cone c C

(^gm) (ppmv)

591 E+03

bull

Chemical

Chloroform

MORE ENTER Depth

below grade tb bottom

of enclosed space floor

bull LF

(cm)

ENTER

Soil gas sampling depth

below grade

(cm)

ENTER

Average soil

temperature-Ts

CO bull

1 15 1 15 1 125

ENTER ENTER ENTER Totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

IIA hs he (cm) (cm) (cm)

1 5 bull 1 1

ENTER ENTER Soil - bull

stratum A User-defined SCS stratum A

soil type bull soil vapor (used to estimate OR permeability

soil vapor k

bull permeability) (cm) 1

SL 1 1 bull

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A soil dry

bulk density

Pb (gcm)

ENTER Stratum A soil total porosity

nV (unitless)

ENTER Stratum A

-soilwater-filled bullporosity

Sraquo (cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

(gcm)

ENTER Stratum B soil total porosity

(unitless)

ENTER Stratum B

soil water-filled porosity

bull ebdquo=

(cmcm) bull

ENTER Straturri C

SCS bull soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

- c rack

(cm)

ENTER

Soil-bldg pressure

differential AP^

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor

width bull W B

(cm)

ENTER

Enclosed space

height HB

(cm)

ENTER

bull Floor-wall^ seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bidg OR

Leave blank to calculi

Qsoil bull

(Lm)

I -I

Appx B-3 Chloroformxls 1 of 3 982009

AR100314

APPENDIX B-3-B CHEMICALPROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Diffusivity in air

D (cms)

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffijsivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature

Dbdquo H TR A H bdquo TB Tc

(cm s) (atm-m mol) ro (calmol) (degK) (degK)

Molecular weight

MW

(gmol)

Unit risk

factor URF

(ngm)-

Reference cone

RfC

(mgm)

104E-01 100E-05 I 366E-03 25 6988 33432 53640 11938 I 23E-05 | OOE+00

Appx B-3 Chloroformxls 2 of 3 982009

AR100315

APPENDIX B-3-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure

duration

(sec)

Source-

building

separation

LT

(cm)

Stratum A

soil

air-filled

porosity

Sa

( cm cm )

Stratum B

soil

air-filled

porosity

( cm cm )

Stratum C

soil

air-filled

porosity

( c m c m )

Stratum A

effective

total fluid

saturation

( c m c m )

Stratum A

soil

intrinsic

penmeability

k

(cm )

Stratum A

- soil

relative air

permeabil i ty

(cm )

Stratum A

soil

effective vapor

permeability

kv

(cm )

Floor-

wall

seam

perimeter

gtcrack

(cm)

Soil gas

cone

(ngm)

BIdg

venfilation

rate

^buildlriE

(cms)

I 9 4 6 E + 0 8 ~ T I 0284 T 596E-09 I 0-901 I 537E-09 | 35357 | 591 E+03 j 439E+06 | 1 0 284 0284 0184

Area of

enclosed

space

below

grade

A B

( c m )

Crack-

to-total

area

ratio

n

(unitless)

Crack

depth

bull below

grade

^crack

(cm)

Enthalpy of

vaporization at

ave soil

temperature

AHTs bull

(calmol)

Henry s law

constant at

ave soil

temperature

HTS

(a tm-m mol j

Henrys law

constant at

ave soil

bull temperature

HTS

(unitless) bull

Vapor

viscosity at

ave soil-

temperature

^HTS

(gcm-s)

Stratum

A

effective

diffusion

coefficient

(cm s)

Stratum

B

effective

difftjsion

coefficient

D B

(cms) bull

S t ra tum

C

effective

diffusion

coefficient

Dc

(cm s)

Total

overall

effective

bull diffusion

coefficient

D T

(cm s)

Diffi jsion

path

length

Ld

(cm)

I 787E+07 I 449E-05 j - bull 15 7528 210E-03 896E-02 176E-04 I 105E-02 | OOOE+00 | OOOE+00 | 105E-02

Convection

path length

Lp

(cm)

Source

vapor

cone -

^source

- (ngm)

Crack

radius

Tcrack

(cm)

Average

vapor

flow rate

into bidg

Qsoil

(cms)

Crack

effective

diffusion

coefficient Qcrack

bull (cms)

Area of crack

Acrack

(cm)

Exponent of

equivalent

foundation

Peclet number

exp(Pe)

(unitless)

V bull bull

1 15 1 591 E+03 1 010 1 474E+01 105E-02 354E+03 1 355E+05

Infinite

source

indoor

attenuation

coefficient

d

(unitless)

bull 108E-05

Infinite

source

bIdg

cone

^ b u i l d i n g

i (^gm)

bull bull

i 638E-02 -

Unit

risk bull factor

URF

(ngmY

Reference

cone

RfC

(mgm)

~ 23E-05 NA 1

I END

Appx B-3 Chloroform xls 3 of 3 982009

AR100316

APPENDIX B-4-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ersion 31-020^

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

nodashes)

bull 75092

ENTER Soil gas

cone

c (ngm)

Soil Gas Concentration Data ENTER

Soil gas bull

OR cone

bull C

(ppmv)

152E+03

bull bull

Chemical

Methylene chloride

MORE

MORE 4gt

ENTER Depth

below grade to bottom

of enclosed space floor

LF -

(cm)

ENTER

Soil gas sampling depth

below grade

bull U

(cm)

ENTER

Average soil

temperature

Ts bull CC)

bull bull bull bull

1 15 1 15 125

ENTER Totals

Thickness of soil

stratum A h

(cm)

ENTER ENTER must add up to value of Ls (cell F24

Thickness Thickness of soil of soil

stratum B stratum C (Enter value or 0) (Enter value or 0)

he he bull

(cm) bull (cm) -

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(usedto estimate OR perrrieability | soil vapor

permeability)

k bull

(cm)

SL 1 bull 1

ENTER Stratum A

SCS soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

Pb (gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Stratum A

soil water-filled porosity

9w (cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

Pb^

(gcm)

ENTER Stratum B soil total porosity

n^

(unitless)

ENTER Stratum B

soil water-filled porosity

(crhcm)

ENTER Stratum C

SCS soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE 4gt

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

bull Soil-bldg pressure

differential AP^

(gcm-s)

ENTER Enclosed

space floor

length LB

(cm)

ENTER Enclosed

space floor

width bull W B

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width

w

(cm)

ENTER

Indoor air exchange

rate

ER (1h)

ENTER Average vapor

flow rate into bidg OR

Leave blank to calculc

Qsoil

(Lm)

10 40 8839 8839 244 01 083

Appx B-4 MCxIs 1 of 3 982009

AR100317

Diffijsivity in air

D

APPENDIX B-4-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffusivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature

Pw H TR AHt TB TC

Molecular weight

MW

Unit risk

factor URF

Reference cone

RfC

(cms) (cms) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) bull (ngm)- (mgm)

bull bull

1 101E-01 1 117E-05 1 218E-03 1 25 | 6706 1 31300 1 51000 1 8493 1 47E-07 1 30E+00 1

Appx B-4 MCxIs 2 of 3 982009

AR100318

APPENDIX B-4-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

T

(sec)

Source- -building

separation

LT

(cm)

Stratum A soil

air-filled porosity

e a bull

(cmcm)

Stratum B soil

bullair-filled porosity bull

ea^ (cmcm)

Stratum C soil

air-filled porosity

ea= (cmcmj

Stratum A effective total fluid

saturation

Sc bull

(cmcm)

Stratum A soil

intrinsic pemneability

ki (cm)

Stratum A soil

relative air permeability

^ ^ g

(cm)

stratumA bull soil effective vapor permeability

K (cm)

Floor-wall

seam perimeter

Xcrack

(cm)

Soil gas

cone (ngm)

BIdg ventilation

rate

Qbuildinc

(cms)

1 946E+08

Area of -enclosed

space below

bull grade

AB

(cm)

1

Crack-to-total

area rafio

Tl

(unitless)

0284 1

Crack depth below grade

Zcrack

(cm)

0284 1

bull Enthalpy of vaporization at

ave soil temperature

AHTs (calmol)

0284

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

0184

Henrys law constant at ave soil

temperature

HTS

bull (unitless)

1 596E-09

Vapor viscosity at

ave soil temperature

Mrs (gcm-s)

0901

Stratum A

effective diffusion

coefficient

D (cms)

537E-09

Stratum B

effective diffusion

coefficient

D-B (cms)

35357 1

Stratum C -

effective diffusion

coefficient

D-c ^ (cms)

152E+03

Total bull overall

bull effective diffusion

coefficient

D ^

(cms)

440E+06 1

Difftjsion path

length

Ld (cm)

1 787E+07

Convection path

length

Lp (cm)

4 49E-05

Source vapor cone

Csource

(ngm)

15 1

Crack radius

Tcrack

(cm)

7007 bull 1

Average vapor

flow rate intobldg

Qsoil

(cms)

130E-03

Crack effective diffusion

coefficient pcrack

(cms)-

555E-02

bull ^

Area of crack

Acrack

(cm) bull

1 176E-04

Exponent of equivalent foundation

Peclet number

exp(Pe)

(unitless) bull

bull bull

1 15

1 END

152E+03 010 1 474E+01 1 102E-02 354E+03 1 519E+05

102E-02

Infinite source

indoor ^attenuation coefficient

bull a

(unitless)

aiii08E-05

0 OOE+00

bull

Infinite bull source

bIdg ^ cone

^bu i l d i ng

(MQm)

164E-02

OOOE+00 1

Unit risk

factor

URF

(ngm)-

47E-07 1

102E-02 j

Reference cone

RfC

(mgm)

30E+00 j

1 1

Appx B-4 MCxIs 3 of 3 982009

AR100319

APPENDIX B-5-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ^erslon 31 0204

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

127184

Soil Gas Concentration Data ENTER ^ ENTER

Soil -Soi l bull gas gas

cone OR cone Cg C bull

(tgm) (ppmv)

149E+05 1

Chemical

bull Tetrachlbroethylene

MORE 4

ENTER Depth

below grade to bottom

ofenclosecJ space floor

LF

(cm)

ENTER

Soil gas bull sampling

depth below grade

u bull (cm)

ENTER

Average bullsoil

temperature - Ts

ro 1 1 5 1 15 1 125 bull

ENTER ENTER ENTER totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hft bull he bull he

(cm) (cm) (cm)

bull 1 5 1 - 1

ENTER ENTER Soil

stratum A User^defined bull SCS bull stratum A soil type soil vapor

(used to estimate OR perrrieability soil vapor K bull

permeability) (cm) 1

SL 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

Pb

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Sitratum A

soil water-filled bull porosity

(cmcm)

ENTER Stratum B

SCS soiltype

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

Pb^

(gcm)

ENTER Stratum B soil total porosity

Ajnitless^

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS soil type

LookupSoil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

VS

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor width

W B

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width

w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

ENTER Average vapor

flow rate into bidg OR

Leave blank to calcul

bull Qsoil

(Lm)

10 40 8839 8839 244 01 083

Appx B-5 PCExIS 1 of 3 982009

AR100320

APPENDIX B-5-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal Unit

Diffusivity Diffusivity at reference reference the riormal boiling Critical Molecular risk Reference in air in water temperature temperature boiling point point teriiperature weight factor cone

Da Dbdquo H TR AHb TB Tc MW URF RfC

(cms) (cnis) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) (^gm)- (mgm)

1 720E-02 1 820E-06 1 184E-02 1 25 1 8288 1 39440 1 62020 1 16583 1 59E-06 1 60E-01 1

J

AppxB-5PCExls 2 of 3 - 982009

AR100321

APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

T

(sec)

Source-building

separation

LT

bull (cm)

Stratum A soil

air-filled porosity

Oa (cmcm)

Stratum B - soil air-filled porosity

ea (cmcm)

Stratum C soil

air-filled porosity

ea= - (cmcm)

Stratum A effective total fluid

saturation

sbdquo (cmcm)

Stratum A soil

intrinsic permeability

ki (cm)

Stratum A soil

relative air permeability

- ^ g

(cm)

Stratum A soil

effective vapor permeability

kv (cm)

Floor-wall

seam perimeter

^crack

(cm)

Soil gas

cone

(ngm)

BIdg venfilation

rate

Qbuildins

bull (cms)

bull bull

1 946E+08

Area of enclosed

space below grade

AB

(cm)

1

bullCrack-to-total

area ratio

1 (unitless)

0284 1

Crack bull depth below grade

Zcrack

(cm) -

0284 1

Enthalpy of vaporization at bull

ave soil temperature

bull A H V TS

(calmol)

0284

Henrys law constant at

ave soil temperature

HTS (atm-mmol)

0184

-Henrys law constant at

ave soil temperature

HTS

(unitless)

1 596E-09

Vapor viscosity at

ave soil temperature

HTS

(gcm-s)

0901

Stratum A

effective diffusion

coefficient bull D = bull

(cms)

537E-09

Stratum B

effective diffusion

coefficient

D--B (cms)

35357 1

Stratum C

effective diffusion bull

coefficient

D-c (crris)

149E+05

Total overall

effective bulldiffusion coefficient

DT

(cms)

440E+06 1

Difftjsion path

length

U (cm)

1 787E+07

Convection path

length

bull Lp

(cm)

4 49E-05

Source vapor cone

^source

(ngm)

15 1

Crack radius

Tcrack

(cm)

9528 1

Average vapor

flow rate intobldg

Qsoil (cms)

908E-03

Crack effective diffusion

coefficient pcrack

bull ( c m s ) bull

387E-01

Area of crack

Abdquoack (cm)

1 176E-04

Exponent of equivalent foundafion

Peclet number

exp(Pe)

(unitless)

bull

1 15-

1 END

149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08

727E-03

Infinite source indoor

attenuation coefficient

a

(unitless)

108E-05

OOOE+00

Infinite source

bIdg cone

Cburldtng

(Mgm)

161 E+00

OOOE+00 1

Unit risk

factor

URF

(ugm)-

59E-06 1

727E-03

Reference cone

RfC (mgm)

60E-01

1 1

Appx B-5 PCExls 3 of 3 982009

AR100322

APPENDIX B-6-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ersion31 0204

Reset to Defaults

t

Soil Gas Concentration Data ENTER

Chemical CAS No

(numbers only

no dashes)

79016

ENTER ENTER Soil Soil gas gas

cone OR cone C C -

bull (ngm) (ppmv)

782E+03

Chemical

Trichloroethylene

MORE ENTER Depth

below grade to bottom-

of enclosed space floor

LF

(cm)

ENTER

Soil gas sarnpling

depth below grade

U (cm)

ENTER

Average soil

temperature Ts

(degC)

1 15 1 15 t 125

ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e

(cm) (cm) (cm)

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estimate OR permeability soil vapor

permeability)

k (cm)

bull S L 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil bull-Parameters

ENTER Stratum A

soil dry bulk density

P b -

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Stratum A bull

soilwaterrfilled porosity

(cmcm) bull

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

bull P ^ (gcm)

ENTER Stratum B soil total

porosity

nlaquo

(unitless) -

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS bull soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor

width W B

(cm)

ENTER

Enclosed space height

H B bull

( c m ) bull

ENTER

Floor-wall seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bIdg OR

Leave blank to calculc

Qsoil

(Lm) -

Appx B-6 TCExIs 1 of 3 982009

A

AR100323

APPENDIX B-6-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight

Da Dbdquo H TR AH^b TB TC MW

Unit risk Reference

factor cone URF RfC

(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)

1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1

Appx B-6 TCExIs 2 of 3 982009

AR100324

APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

(sec)

Source-building

separation LT

(cm)

Stratum A soil

air-filled porosity

bull ea (cmcm)

Stratum B Soil

air-fllled porosity

e^ bull (cmcm)

Stratum C soil

air-filled porosity

(cmcm)

StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air

saturation permeability permeability

S|e k krg (cmcm) (cm) (cm)

Stratum A Floor-soil wall BIdg

effective vapor seam Soil ventilafion permeability perimeter gas rate

k^ bull Xack c o n e Qbuildins

(cm) (cm) (ngm) (cms)

946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |

Area of enclosed

space below grade

AB

(cm)

Ciack- to-total

area ratio

1 (unitless)

Crack depth below grade

Zcrack

(cm)

Enthalpy of vaporization at

ave soil temperature

A H J S

(calmol)

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law bull constant at

ave soil temperature

HTS

(unitless)

Vapor viscosity at

ave soil temperature

|JTS

(gcm^s)

Stratum A

effective diffusion

coefficient

(cms)

Stratum B

effective -diffusion

coefficient

D=B (cms)

Stratum ^ C effective diffusion

coefficient

D=c (cms)

Total overall

effective diffusion

coefficient

DT

(cms)

I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03

Diffusion path

length

Li (cm) bull

Convection bull path

length

Lp

(cm)

Source vapor cone bull

^source

(ngm)

Crack radius

rcrack

(cm)

Average vapor

- flow rate intobldg

Qsoil

(cms)

Crack effective diffusion

bull coefficient Qcrack

(cms)

Area of crack

^crack

(cm)

Exponent of equivalent foundation

Peclet bull number

exp(Pe)

(unitless)

bull bull

1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07

Infinite source Indoor

attenuation coefficient

a

(unitless)

108E-05

Infinite source

bIdg concgt

^building

(ngm)

844E-02

Unit risk

factor

URF

(ngm)-

Reference cone

RfC

(mgm)

1 1E-04 1 40E-02 1

END

Appx B-6 TCExIs 3 of 3 982009

AR100325

Office of Waste Management 1356 Hansford Street

Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256

West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director

ORDER

ISSUED UNDER THE

HAZARDOUS WASTE MANAGEMENT ACT

CHAPTER 22 ARTICLE 18

OF THE WEST VIRGINIA CODE^ AS AMENDED

y Order Number HW-011-80

To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704

ATTEMTION MREDARMON

Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull

AR100326

ViWJ011-laquo9 PageNunil)er2

BASIS FOR ORDER

As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following

A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^

B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator

C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities

0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94

^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement

P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following

1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater

2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was

^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment

CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable

CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order

AR100327

H W - 0 1 1 - 9 9 Page Number 3

REQUIREMENTS OF ORDER

Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows

1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^

2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore

remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling

GENERAL PROVaiONS

1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order

2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order

3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order

Effective Date

Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief

Wt T 1 V Oflice of Waste Management

AR100328

^ ^ S I S

^wmmmmamn

AR100329

Page 38: SDMS DocID 2121999 · International Enterprises Corp. building (Coyne Building), which is located at 1111 Vernon Street, Westmoreland District, Wayne County, West Virginia. The following

APPENDIX B-3-B CHEMICALPROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Diffusivity in air

D (cms)

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffijsivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature

Dbdquo H TR A H bdquo TB Tc

(cm s) (atm-m mol) ro (calmol) (degK) (degK)

Molecular weight

MW

(gmol)

Unit risk

factor URF

(ngm)-

Reference cone

RfC

(mgm)

104E-01 100E-05 I 366E-03 25 6988 33432 53640 11938 I 23E-05 | OOE+00

Appx B-3 Chloroformxls 2 of 3 982009

AR100315

APPENDIX B-3-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure

duration

(sec)

Source-

building

separation

LT

(cm)

Stratum A

soil

air-filled

porosity

Sa

( cm cm )

Stratum B

soil

air-filled

porosity

( cm cm )

Stratum C

soil

air-filled

porosity

( c m c m )

Stratum A

effective

total fluid

saturation

( c m c m )

Stratum A

soil

intrinsic

penmeability

k

(cm )

Stratum A

- soil

relative air

permeabil i ty

(cm )

Stratum A

soil

effective vapor

permeability

kv

(cm )

Floor-

wall

seam

perimeter

gtcrack

(cm)

Soil gas

cone

(ngm)

BIdg

venfilation

rate

^buildlriE

(cms)

I 9 4 6 E + 0 8 ~ T I 0284 T 596E-09 I 0-901 I 537E-09 | 35357 | 591 E+03 j 439E+06 | 1 0 284 0284 0184

Area of

enclosed

space

below

grade

A B

( c m )

Crack-

to-total

area

ratio

n

(unitless)

Crack

depth

bull below

grade

^crack

(cm)

Enthalpy of

vaporization at

ave soil

temperature

AHTs bull

(calmol)

Henry s law

constant at

ave soil

temperature

HTS

(a tm-m mol j

Henrys law

constant at

ave soil

bull temperature

HTS

(unitless) bull

Vapor

viscosity at

ave soil-

temperature

^HTS

(gcm-s)

Stratum

A

effective

diffusion

coefficient

(cm s)

Stratum

B

effective

difftjsion

coefficient

D B

(cms) bull

S t ra tum

C

effective

diffusion

coefficient

Dc

(cm s)

Total

overall

effective

bull diffusion

coefficient

D T

(cm s)

Diffi jsion

path

length

Ld

(cm)

I 787E+07 I 449E-05 j - bull 15 7528 210E-03 896E-02 176E-04 I 105E-02 | OOOE+00 | OOOE+00 | 105E-02

Convection

path length

Lp

(cm)

Source

vapor

cone -

^source

- (ngm)

Crack

radius

Tcrack

(cm)

Average

vapor

flow rate

into bidg

Qsoil

(cms)

Crack

effective

diffusion

coefficient Qcrack

bull (cms)

Area of crack

Acrack

(cm)

Exponent of

equivalent

foundation

Peclet number

exp(Pe)

(unitless)

V bull bull

1 15 1 591 E+03 1 010 1 474E+01 105E-02 354E+03 1 355E+05

Infinite

source

indoor

attenuation

coefficient

d

(unitless)

bull 108E-05

Infinite

source

bIdg

cone

^ b u i l d i n g

i (^gm)

bull bull

i 638E-02 -

Unit

risk bull factor

URF

(ngmY

Reference

cone

RfC

(mgm)

~ 23E-05 NA 1

I END

Appx B-3 Chloroform xls 3 of 3 982009

AR100316

APPENDIX B-4-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ersion 31-020^

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

nodashes)

bull 75092

ENTER Soil gas

cone

c (ngm)

Soil Gas Concentration Data ENTER

Soil gas bull

OR cone

bull C

(ppmv)

152E+03

bull bull

Chemical

Methylene chloride

MORE

MORE 4gt

ENTER Depth

below grade to bottom

of enclosed space floor

LF -

(cm)

ENTER

Soil gas sampling depth

below grade

bull U

(cm)

ENTER

Average soil

temperature

Ts bull CC)

bull bull bull bull

1 15 1 15 125

ENTER Totals

Thickness of soil

stratum A h

(cm)

ENTER ENTER must add up to value of Ls (cell F24

Thickness Thickness of soil of soil

stratum B stratum C (Enter value or 0) (Enter value or 0)

he he bull

(cm) bull (cm) -

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(usedto estimate OR perrrieability | soil vapor

permeability)

k bull

(cm)

SL 1 bull 1

ENTER Stratum A

SCS soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

Pb (gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Stratum A

soil water-filled porosity

9w (cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

Pb^

(gcm)

ENTER Stratum B soil total porosity

n^

(unitless)

ENTER Stratum B

soil water-filled porosity

(crhcm)

ENTER Stratum C

SCS soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE 4gt

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

bull Soil-bldg pressure

differential AP^

(gcm-s)

ENTER Enclosed

space floor

length LB

(cm)

ENTER Enclosed

space floor

width bull W B

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width

w

(cm)

ENTER

Indoor air exchange

rate

ER (1h)

ENTER Average vapor

flow rate into bidg OR

Leave blank to calculc

Qsoil

(Lm)

10 40 8839 8839 244 01 083

Appx B-4 MCxIs 1 of 3 982009

AR100317

Diffijsivity in air

D

APPENDIX B-4-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffusivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature

Pw H TR AHt TB TC

Molecular weight

MW

Unit risk

factor URF

Reference cone

RfC

(cms) (cms) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) bull (ngm)- (mgm)

bull bull

1 101E-01 1 117E-05 1 218E-03 1 25 | 6706 1 31300 1 51000 1 8493 1 47E-07 1 30E+00 1

Appx B-4 MCxIs 2 of 3 982009

AR100318

APPENDIX B-4-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

T

(sec)

Source- -building

separation

LT

(cm)

Stratum A soil

air-filled porosity

e a bull

(cmcm)

Stratum B soil

bullair-filled porosity bull

ea^ (cmcm)

Stratum C soil

air-filled porosity

ea= (cmcmj

Stratum A effective total fluid

saturation

Sc bull

(cmcm)

Stratum A soil

intrinsic pemneability

ki (cm)

Stratum A soil

relative air permeability

^ ^ g

(cm)

stratumA bull soil effective vapor permeability

K (cm)

Floor-wall

seam perimeter

Xcrack

(cm)

Soil gas

cone (ngm)

BIdg ventilation

rate

Qbuildinc

(cms)

1 946E+08

Area of -enclosed

space below

bull grade

AB

(cm)

1

Crack-to-total

area rafio

Tl

(unitless)

0284 1

Crack depth below grade

Zcrack

(cm)

0284 1

bull Enthalpy of vaporization at

ave soil temperature

AHTs (calmol)

0284

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

0184

Henrys law constant at ave soil

temperature

HTS

bull (unitless)

1 596E-09

Vapor viscosity at

ave soil temperature

Mrs (gcm-s)

0901

Stratum A

effective diffusion

coefficient

D (cms)

537E-09

Stratum B

effective diffusion

coefficient

D-B (cms)

35357 1

Stratum C -

effective diffusion

coefficient

D-c ^ (cms)

152E+03

Total bull overall

bull effective diffusion

coefficient

D ^

(cms)

440E+06 1

Difftjsion path

length

Ld (cm)

1 787E+07

Convection path

length

Lp (cm)

4 49E-05

Source vapor cone

Csource

(ngm)

15 1

Crack radius

Tcrack

(cm)

7007 bull 1

Average vapor

flow rate intobldg

Qsoil

(cms)

130E-03

Crack effective diffusion

coefficient pcrack

(cms)-

555E-02

bull ^

Area of crack

Acrack

(cm) bull

1 176E-04

Exponent of equivalent foundation

Peclet number

exp(Pe)

(unitless) bull

bull bull

1 15

1 END

152E+03 010 1 474E+01 1 102E-02 354E+03 1 519E+05

102E-02

Infinite source

indoor ^attenuation coefficient

bull a

(unitless)

aiii08E-05

0 OOE+00

bull

Infinite bull source

bIdg ^ cone

^bu i l d i ng

(MQm)

164E-02

OOOE+00 1

Unit risk

factor

URF

(ngm)-

47E-07 1

102E-02 j

Reference cone

RfC

(mgm)

30E+00 j

1 1

Appx B-4 MCxIs 3 of 3 982009

AR100319

APPENDIX B-5-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ^erslon 31 0204

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

127184

Soil Gas Concentration Data ENTER ^ ENTER

Soil -Soi l bull gas gas

cone OR cone Cg C bull

(tgm) (ppmv)

149E+05 1

Chemical

bull Tetrachlbroethylene

MORE 4

ENTER Depth

below grade to bottom

ofenclosecJ space floor

LF

(cm)

ENTER

Soil gas bull sampling

depth below grade

u bull (cm)

ENTER

Average bullsoil

temperature - Ts

ro 1 1 5 1 15 1 125 bull

ENTER ENTER ENTER totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hft bull he bull he

(cm) (cm) (cm)

bull 1 5 1 - 1

ENTER ENTER Soil

stratum A User^defined bull SCS bull stratum A soil type soil vapor

(used to estimate OR perrrieability soil vapor K bull

permeability) (cm) 1

SL 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

Pb

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Sitratum A

soil water-filled bull porosity

(cmcm)

ENTER Stratum B

SCS soiltype

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

Pb^

(gcm)

ENTER Stratum B soil total porosity

Ajnitless^

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS soil type

LookupSoil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

VS

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor width

W B

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width

w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

ENTER Average vapor

flow rate into bidg OR

Leave blank to calcul

bull Qsoil

(Lm)

10 40 8839 8839 244 01 083

Appx B-5 PCExIS 1 of 3 982009

AR100320

APPENDIX B-5-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal Unit

Diffusivity Diffusivity at reference reference the riormal boiling Critical Molecular risk Reference in air in water temperature temperature boiling point point teriiperature weight factor cone

Da Dbdquo H TR AHb TB Tc MW URF RfC

(cms) (cnis) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) (^gm)- (mgm)

1 720E-02 1 820E-06 1 184E-02 1 25 1 8288 1 39440 1 62020 1 16583 1 59E-06 1 60E-01 1

J

AppxB-5PCExls 2 of 3 - 982009

AR100321

APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

T

(sec)

Source-building

separation

LT

bull (cm)

Stratum A soil

air-filled porosity

Oa (cmcm)

Stratum B - soil air-filled porosity

ea (cmcm)

Stratum C soil

air-filled porosity

ea= - (cmcm)

Stratum A effective total fluid

saturation

sbdquo (cmcm)

Stratum A soil

intrinsic permeability

ki (cm)

Stratum A soil

relative air permeability

- ^ g

(cm)

Stratum A soil

effective vapor permeability

kv (cm)

Floor-wall

seam perimeter

^crack

(cm)

Soil gas

cone

(ngm)

BIdg venfilation

rate

Qbuildins

bull (cms)

bull bull

1 946E+08

Area of enclosed

space below grade

AB

(cm)

1

bullCrack-to-total

area ratio

1 (unitless)

0284 1

Crack bull depth below grade

Zcrack

(cm) -

0284 1

Enthalpy of vaporization at bull

ave soil temperature

bull A H V TS

(calmol)

0284

Henrys law constant at

ave soil temperature

HTS (atm-mmol)

0184

-Henrys law constant at

ave soil temperature

HTS

(unitless)

1 596E-09

Vapor viscosity at

ave soil temperature

HTS

(gcm-s)

0901

Stratum A

effective diffusion

coefficient bull D = bull

(cms)

537E-09

Stratum B

effective diffusion

coefficient

D--B (cms)

35357 1

Stratum C

effective diffusion bull

coefficient

D-c (crris)

149E+05

Total overall

effective bulldiffusion coefficient

DT

(cms)

440E+06 1

Difftjsion path

length

U (cm)

1 787E+07

Convection path

length

bull Lp

(cm)

4 49E-05

Source vapor cone

^source

(ngm)

15 1

Crack radius

Tcrack

(cm)

9528 1

Average vapor

flow rate intobldg

Qsoil (cms)

908E-03

Crack effective diffusion

coefficient pcrack

bull ( c m s ) bull

387E-01

Area of crack

Abdquoack (cm)

1 176E-04

Exponent of equivalent foundafion

Peclet number

exp(Pe)

(unitless)

bull

1 15-

1 END

149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08

727E-03

Infinite source indoor

attenuation coefficient

a

(unitless)

108E-05

OOOE+00

Infinite source

bIdg cone

Cburldtng

(Mgm)

161 E+00

OOOE+00 1

Unit risk

factor

URF

(ugm)-

59E-06 1

727E-03

Reference cone

RfC (mgm)

60E-01

1 1

Appx B-5 PCExls 3 of 3 982009

AR100322

APPENDIX B-6-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ersion31 0204

Reset to Defaults

t

Soil Gas Concentration Data ENTER

Chemical CAS No

(numbers only

no dashes)

79016

ENTER ENTER Soil Soil gas gas

cone OR cone C C -

bull (ngm) (ppmv)

782E+03

Chemical

Trichloroethylene

MORE ENTER Depth

below grade to bottom-

of enclosed space floor

LF

(cm)

ENTER

Soil gas sarnpling

depth below grade

U (cm)

ENTER

Average soil

temperature Ts

(degC)

1 15 1 15 t 125

ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e

(cm) (cm) (cm)

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estimate OR permeability soil vapor

permeability)

k (cm)

bull S L 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil bull-Parameters

ENTER Stratum A

soil dry bulk density

P b -

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Stratum A bull

soilwaterrfilled porosity

(cmcm) bull

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

bull P ^ (gcm)

ENTER Stratum B soil total

porosity

nlaquo

(unitless) -

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS bull soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor

width W B

(cm)

ENTER

Enclosed space height

H B bull

( c m ) bull

ENTER

Floor-wall seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bIdg OR

Leave blank to calculc

Qsoil

(Lm) -

Appx B-6 TCExIs 1 of 3 982009

A

AR100323

APPENDIX B-6-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight

Da Dbdquo H TR AH^b TB TC MW

Unit risk Reference

factor cone URF RfC

(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)

1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1

Appx B-6 TCExIs 2 of 3 982009

AR100324

APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

(sec)

Source-building

separation LT

(cm)

Stratum A soil

air-filled porosity

bull ea (cmcm)

Stratum B Soil

air-fllled porosity

e^ bull (cmcm)

Stratum C soil

air-filled porosity

(cmcm)

StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air

saturation permeability permeability

S|e k krg (cmcm) (cm) (cm)

Stratum A Floor-soil wall BIdg

effective vapor seam Soil ventilafion permeability perimeter gas rate

k^ bull Xack c o n e Qbuildins

(cm) (cm) (ngm) (cms)

946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |

Area of enclosed

space below grade

AB

(cm)

Ciack- to-total

area ratio

1 (unitless)

Crack depth below grade

Zcrack

(cm)

Enthalpy of vaporization at

ave soil temperature

A H J S

(calmol)

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law bull constant at

ave soil temperature

HTS

(unitless)

Vapor viscosity at

ave soil temperature

|JTS

(gcm^s)

Stratum A

effective diffusion

coefficient

(cms)

Stratum B

effective -diffusion

coefficient

D=B (cms)

Stratum ^ C effective diffusion

coefficient

D=c (cms)

Total overall

effective diffusion

coefficient

DT

(cms)

I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03

Diffusion path

length

Li (cm) bull

Convection bull path

length

Lp

(cm)

Source vapor cone bull

^source

(ngm)

Crack radius

rcrack

(cm)

Average vapor

- flow rate intobldg

Qsoil

(cms)

Crack effective diffusion

bull coefficient Qcrack

(cms)

Area of crack

^crack

(cm)

Exponent of equivalent foundation

Peclet bull number

exp(Pe)

(unitless)

bull bull

1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07

Infinite source Indoor

attenuation coefficient

a

(unitless)

108E-05

Infinite source

bIdg concgt

^building

(ngm)

844E-02

Unit risk

factor

URF

(ngm)-

Reference cone

RfC

(mgm)

1 1E-04 1 40E-02 1

END

Appx B-6 TCExIs 3 of 3 982009

AR100325

Office of Waste Management 1356 Hansford Street

Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256

West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director

ORDER

ISSUED UNDER THE

HAZARDOUS WASTE MANAGEMENT ACT

CHAPTER 22 ARTICLE 18

OF THE WEST VIRGINIA CODE^ AS AMENDED

y Order Number HW-011-80

To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704

ATTEMTION MREDARMON

Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull

AR100326

ViWJ011-laquo9 PageNunil)er2

BASIS FOR ORDER

As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following

A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^

B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator

C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities

0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94

^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement

P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following

1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater

2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was

^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment

CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable

CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order

AR100327

H W - 0 1 1 - 9 9 Page Number 3

REQUIREMENTS OF ORDER

Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows

1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^

2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore

remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling

GENERAL PROVaiONS

1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order

2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order

3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order

Effective Date

Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief

Wt T 1 V Oflice of Waste Management

AR100328

^ ^ S I S

^wmmmmamn

AR100329

Page 39: SDMS DocID 2121999 · International Enterprises Corp. building (Coyne Building), which is located at 1111 Vernon Street, Westmoreland District, Wayne County, West Virginia. The following

APPENDIX B-3-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure

duration

(sec)

Source-

building

separation

LT

(cm)

Stratum A

soil

air-filled

porosity

Sa

( cm cm )

Stratum B

soil

air-filled

porosity

( cm cm )

Stratum C

soil

air-filled

porosity

( c m c m )

Stratum A

effective

total fluid

saturation

( c m c m )

Stratum A

soil

intrinsic

penmeability

k

(cm )

Stratum A

- soil

relative air

permeabil i ty

(cm )

Stratum A

soil

effective vapor

permeability

kv

(cm )

Floor-

wall

seam

perimeter

gtcrack

(cm)

Soil gas

cone

(ngm)

BIdg

venfilation

rate

^buildlriE

(cms)

I 9 4 6 E + 0 8 ~ T I 0284 T 596E-09 I 0-901 I 537E-09 | 35357 | 591 E+03 j 439E+06 | 1 0 284 0284 0184

Area of

enclosed

space

below

grade

A B

( c m )

Crack-

to-total

area

ratio

n

(unitless)

Crack

depth

bull below

grade

^crack

(cm)

Enthalpy of

vaporization at

ave soil

temperature

AHTs bull

(calmol)

Henry s law

constant at

ave soil

temperature

HTS

(a tm-m mol j

Henrys law

constant at

ave soil

bull temperature

HTS

(unitless) bull

Vapor

viscosity at

ave soil-

temperature

^HTS

(gcm-s)

Stratum

A

effective

diffusion

coefficient

(cm s)

Stratum

B

effective

difftjsion

coefficient

D B

(cms) bull

S t ra tum

C

effective

diffusion

coefficient

Dc

(cm s)

Total

overall

effective

bull diffusion

coefficient

D T

(cm s)

Diffi jsion

path

length

Ld

(cm)

I 787E+07 I 449E-05 j - bull 15 7528 210E-03 896E-02 176E-04 I 105E-02 | OOOE+00 | OOOE+00 | 105E-02

Convection

path length

Lp

(cm)

Source

vapor

cone -

^source

- (ngm)

Crack

radius

Tcrack

(cm)

Average

vapor

flow rate

into bidg

Qsoil

(cms)

Crack

effective

diffusion

coefficient Qcrack

bull (cms)

Area of crack

Acrack

(cm)

Exponent of

equivalent

foundation

Peclet number

exp(Pe)

(unitless)

V bull bull

1 15 1 591 E+03 1 010 1 474E+01 105E-02 354E+03 1 355E+05

Infinite

source

indoor

attenuation

coefficient

d

(unitless)

bull 108E-05

Infinite

source

bIdg

cone

^ b u i l d i n g

i (^gm)

bull bull

i 638E-02 -

Unit

risk bull factor

URF

(ngmY

Reference

cone

RfC

(mgm)

~ 23E-05 NA 1

I END

Appx B-3 Chloroform xls 3 of 3 982009

AR100316

APPENDIX B-4-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ersion 31-020^

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

nodashes)

bull 75092

ENTER Soil gas

cone

c (ngm)

Soil Gas Concentration Data ENTER

Soil gas bull

OR cone

bull C

(ppmv)

152E+03

bull bull

Chemical

Methylene chloride

MORE

MORE 4gt

ENTER Depth

below grade to bottom

of enclosed space floor

LF -

(cm)

ENTER

Soil gas sampling depth

below grade

bull U

(cm)

ENTER

Average soil

temperature

Ts bull CC)

bull bull bull bull

1 15 1 15 125

ENTER Totals

Thickness of soil

stratum A h

(cm)

ENTER ENTER must add up to value of Ls (cell F24

Thickness Thickness of soil of soil

stratum B stratum C (Enter value or 0) (Enter value or 0)

he he bull

(cm) bull (cm) -

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(usedto estimate OR perrrieability | soil vapor

permeability)

k bull

(cm)

SL 1 bull 1

ENTER Stratum A

SCS soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

Pb (gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Stratum A

soil water-filled porosity

9w (cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

Pb^

(gcm)

ENTER Stratum B soil total porosity

n^

(unitless)

ENTER Stratum B

soil water-filled porosity

(crhcm)

ENTER Stratum C

SCS soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE 4gt

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

bull Soil-bldg pressure

differential AP^

(gcm-s)

ENTER Enclosed

space floor

length LB

(cm)

ENTER Enclosed

space floor

width bull W B

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width

w

(cm)

ENTER

Indoor air exchange

rate

ER (1h)

ENTER Average vapor

flow rate into bidg OR

Leave blank to calculc

Qsoil

(Lm)

10 40 8839 8839 244 01 083

Appx B-4 MCxIs 1 of 3 982009

AR100317

Diffijsivity in air

D

APPENDIX B-4-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffusivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature

Pw H TR AHt TB TC

Molecular weight

MW

Unit risk

factor URF

Reference cone

RfC

(cms) (cms) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) bull (ngm)- (mgm)

bull bull

1 101E-01 1 117E-05 1 218E-03 1 25 | 6706 1 31300 1 51000 1 8493 1 47E-07 1 30E+00 1

Appx B-4 MCxIs 2 of 3 982009

AR100318

APPENDIX B-4-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

T

(sec)

Source- -building

separation

LT

(cm)

Stratum A soil

air-filled porosity

e a bull

(cmcm)

Stratum B soil

bullair-filled porosity bull

ea^ (cmcm)

Stratum C soil

air-filled porosity

ea= (cmcmj

Stratum A effective total fluid

saturation

Sc bull

(cmcm)

Stratum A soil

intrinsic pemneability

ki (cm)

Stratum A soil

relative air permeability

^ ^ g

(cm)

stratumA bull soil effective vapor permeability

K (cm)

Floor-wall

seam perimeter

Xcrack

(cm)

Soil gas

cone (ngm)

BIdg ventilation

rate

Qbuildinc

(cms)

1 946E+08

Area of -enclosed

space below

bull grade

AB

(cm)

1

Crack-to-total

area rafio

Tl

(unitless)

0284 1

Crack depth below grade

Zcrack

(cm)

0284 1

bull Enthalpy of vaporization at

ave soil temperature

AHTs (calmol)

0284

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

0184

Henrys law constant at ave soil

temperature

HTS

bull (unitless)

1 596E-09

Vapor viscosity at

ave soil temperature

Mrs (gcm-s)

0901

Stratum A

effective diffusion

coefficient

D (cms)

537E-09

Stratum B

effective diffusion

coefficient

D-B (cms)

35357 1

Stratum C -

effective diffusion

coefficient

D-c ^ (cms)

152E+03

Total bull overall

bull effective diffusion

coefficient

D ^

(cms)

440E+06 1

Difftjsion path

length

Ld (cm)

1 787E+07

Convection path

length

Lp (cm)

4 49E-05

Source vapor cone

Csource

(ngm)

15 1

Crack radius

Tcrack

(cm)

7007 bull 1

Average vapor

flow rate intobldg

Qsoil

(cms)

130E-03

Crack effective diffusion

coefficient pcrack

(cms)-

555E-02

bull ^

Area of crack

Acrack

(cm) bull

1 176E-04

Exponent of equivalent foundation

Peclet number

exp(Pe)

(unitless) bull

bull bull

1 15

1 END

152E+03 010 1 474E+01 1 102E-02 354E+03 1 519E+05

102E-02

Infinite source

indoor ^attenuation coefficient

bull a

(unitless)

aiii08E-05

0 OOE+00

bull

Infinite bull source

bIdg ^ cone

^bu i l d i ng

(MQm)

164E-02

OOOE+00 1

Unit risk

factor

URF

(ngm)-

47E-07 1

102E-02 j

Reference cone

RfC

(mgm)

30E+00 j

1 1

Appx B-4 MCxIs 3 of 3 982009

AR100319

APPENDIX B-5-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ^erslon 31 0204

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

127184

Soil Gas Concentration Data ENTER ^ ENTER

Soil -Soi l bull gas gas

cone OR cone Cg C bull

(tgm) (ppmv)

149E+05 1

Chemical

bull Tetrachlbroethylene

MORE 4

ENTER Depth

below grade to bottom

ofenclosecJ space floor

LF

(cm)

ENTER

Soil gas bull sampling

depth below grade

u bull (cm)

ENTER

Average bullsoil

temperature - Ts

ro 1 1 5 1 15 1 125 bull

ENTER ENTER ENTER totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hft bull he bull he

(cm) (cm) (cm)

bull 1 5 1 - 1

ENTER ENTER Soil

stratum A User^defined bull SCS bull stratum A soil type soil vapor

(used to estimate OR perrrieability soil vapor K bull

permeability) (cm) 1

SL 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

Pb

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Sitratum A

soil water-filled bull porosity

(cmcm)

ENTER Stratum B

SCS soiltype

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

Pb^

(gcm)

ENTER Stratum B soil total porosity

Ajnitless^

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS soil type

LookupSoil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

VS

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor width

W B

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width

w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

ENTER Average vapor

flow rate into bidg OR

Leave blank to calcul

bull Qsoil

(Lm)

10 40 8839 8839 244 01 083

Appx B-5 PCExIS 1 of 3 982009

AR100320

APPENDIX B-5-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal Unit

Diffusivity Diffusivity at reference reference the riormal boiling Critical Molecular risk Reference in air in water temperature temperature boiling point point teriiperature weight factor cone

Da Dbdquo H TR AHb TB Tc MW URF RfC

(cms) (cnis) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) (^gm)- (mgm)

1 720E-02 1 820E-06 1 184E-02 1 25 1 8288 1 39440 1 62020 1 16583 1 59E-06 1 60E-01 1

J

AppxB-5PCExls 2 of 3 - 982009

AR100321

APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

T

(sec)

Source-building

separation

LT

bull (cm)

Stratum A soil

air-filled porosity

Oa (cmcm)

Stratum B - soil air-filled porosity

ea (cmcm)

Stratum C soil

air-filled porosity

ea= - (cmcm)

Stratum A effective total fluid

saturation

sbdquo (cmcm)

Stratum A soil

intrinsic permeability

ki (cm)

Stratum A soil

relative air permeability

- ^ g

(cm)

Stratum A soil

effective vapor permeability

kv (cm)

Floor-wall

seam perimeter

^crack

(cm)

Soil gas

cone

(ngm)

BIdg venfilation

rate

Qbuildins

bull (cms)

bull bull

1 946E+08

Area of enclosed

space below grade

AB

(cm)

1

bullCrack-to-total

area ratio

1 (unitless)

0284 1

Crack bull depth below grade

Zcrack

(cm) -

0284 1

Enthalpy of vaporization at bull

ave soil temperature

bull A H V TS

(calmol)

0284

Henrys law constant at

ave soil temperature

HTS (atm-mmol)

0184

-Henrys law constant at

ave soil temperature

HTS

(unitless)

1 596E-09

Vapor viscosity at

ave soil temperature

HTS

(gcm-s)

0901

Stratum A

effective diffusion

coefficient bull D = bull

(cms)

537E-09

Stratum B

effective diffusion

coefficient

D--B (cms)

35357 1

Stratum C

effective diffusion bull

coefficient

D-c (crris)

149E+05

Total overall

effective bulldiffusion coefficient

DT

(cms)

440E+06 1

Difftjsion path

length

U (cm)

1 787E+07

Convection path

length

bull Lp

(cm)

4 49E-05

Source vapor cone

^source

(ngm)

15 1

Crack radius

Tcrack

(cm)

9528 1

Average vapor

flow rate intobldg

Qsoil (cms)

908E-03

Crack effective diffusion

coefficient pcrack

bull ( c m s ) bull

387E-01

Area of crack

Abdquoack (cm)

1 176E-04

Exponent of equivalent foundafion

Peclet number

exp(Pe)

(unitless)

bull

1 15-

1 END

149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08

727E-03

Infinite source indoor

attenuation coefficient

a

(unitless)

108E-05

OOOE+00

Infinite source

bIdg cone

Cburldtng

(Mgm)

161 E+00

OOOE+00 1

Unit risk

factor

URF

(ugm)-

59E-06 1

727E-03

Reference cone

RfC (mgm)

60E-01

1 1

Appx B-5 PCExls 3 of 3 982009

AR100322

APPENDIX B-6-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ersion31 0204

Reset to Defaults

t

Soil Gas Concentration Data ENTER

Chemical CAS No

(numbers only

no dashes)

79016

ENTER ENTER Soil Soil gas gas

cone OR cone C C -

bull (ngm) (ppmv)

782E+03

Chemical

Trichloroethylene

MORE ENTER Depth

below grade to bottom-

of enclosed space floor

LF

(cm)

ENTER

Soil gas sarnpling

depth below grade

U (cm)

ENTER

Average soil

temperature Ts

(degC)

1 15 1 15 t 125

ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e

(cm) (cm) (cm)

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estimate OR permeability soil vapor

permeability)

k (cm)

bull S L 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil bull-Parameters

ENTER Stratum A

soil dry bulk density

P b -

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Stratum A bull

soilwaterrfilled porosity

(cmcm) bull

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

bull P ^ (gcm)

ENTER Stratum B soil total

porosity

nlaquo

(unitless) -

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS bull soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor

width W B

(cm)

ENTER

Enclosed space height

H B bull

( c m ) bull

ENTER

Floor-wall seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bIdg OR

Leave blank to calculc

Qsoil

(Lm) -

Appx B-6 TCExIs 1 of 3 982009

A

AR100323

APPENDIX B-6-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight

Da Dbdquo H TR AH^b TB TC MW

Unit risk Reference

factor cone URF RfC

(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)

1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1

Appx B-6 TCExIs 2 of 3 982009

AR100324

APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

(sec)

Source-building

separation LT

(cm)

Stratum A soil

air-filled porosity

bull ea (cmcm)

Stratum B Soil

air-fllled porosity

e^ bull (cmcm)

Stratum C soil

air-filled porosity

(cmcm)

StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air

saturation permeability permeability

S|e k krg (cmcm) (cm) (cm)

Stratum A Floor-soil wall BIdg

effective vapor seam Soil ventilafion permeability perimeter gas rate

k^ bull Xack c o n e Qbuildins

(cm) (cm) (ngm) (cms)

946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |

Area of enclosed

space below grade

AB

(cm)

Ciack- to-total

area ratio

1 (unitless)

Crack depth below grade

Zcrack

(cm)

Enthalpy of vaporization at

ave soil temperature

A H J S

(calmol)

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law bull constant at

ave soil temperature

HTS

(unitless)

Vapor viscosity at

ave soil temperature

|JTS

(gcm^s)

Stratum A

effective diffusion

coefficient

(cms)

Stratum B

effective -diffusion

coefficient

D=B (cms)

Stratum ^ C effective diffusion

coefficient

D=c (cms)

Total overall

effective diffusion

coefficient

DT

(cms)

I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03

Diffusion path

length

Li (cm) bull

Convection bull path

length

Lp

(cm)

Source vapor cone bull

^source

(ngm)

Crack radius

rcrack

(cm)

Average vapor

- flow rate intobldg

Qsoil

(cms)

Crack effective diffusion

bull coefficient Qcrack

(cms)

Area of crack

^crack

(cm)

Exponent of equivalent foundation

Peclet bull number

exp(Pe)

(unitless)

bull bull

1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07

Infinite source Indoor

attenuation coefficient

a

(unitless)

108E-05

Infinite source

bIdg concgt

^building

(ngm)

844E-02

Unit risk

factor

URF

(ngm)-

Reference cone

RfC

(mgm)

1 1E-04 1 40E-02 1

END

Appx B-6 TCExIs 3 of 3 982009

AR100325

Office of Waste Management 1356 Hansford Street

Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256

West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director

ORDER

ISSUED UNDER THE

HAZARDOUS WASTE MANAGEMENT ACT

CHAPTER 22 ARTICLE 18

OF THE WEST VIRGINIA CODE^ AS AMENDED

y Order Number HW-011-80

To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704

ATTEMTION MREDARMON

Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull

AR100326

ViWJ011-laquo9 PageNunil)er2

BASIS FOR ORDER

As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following

A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^

B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator

C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities

0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94

^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement

P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following

1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater

2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was

^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment

CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable

CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order

AR100327

H W - 0 1 1 - 9 9 Page Number 3

REQUIREMENTS OF ORDER

Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows

1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^

2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore

remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling

GENERAL PROVaiONS

1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order

2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order

3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order

Effective Date

Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief

Wt T 1 V Oflice of Waste Management

AR100328

^ ^ S I S

^wmmmmamn

AR100329

Page 40: SDMS DocID 2121999 · International Enterprises Corp. building (Coyne Building), which is located at 1111 Vernon Street, Westmoreland District, Wayne County, West Virginia. The following

APPENDIX B-4-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ersion 31-020^

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

nodashes)

bull 75092

ENTER Soil gas

cone

c (ngm)

Soil Gas Concentration Data ENTER

Soil gas bull

OR cone

bull C

(ppmv)

152E+03

bull bull

Chemical

Methylene chloride

MORE

MORE 4gt

ENTER Depth

below grade to bottom

of enclosed space floor

LF -

(cm)

ENTER

Soil gas sampling depth

below grade

bull U

(cm)

ENTER

Average soil

temperature

Ts bull CC)

bull bull bull bull

1 15 1 15 125

ENTER Totals

Thickness of soil

stratum A h

(cm)

ENTER ENTER must add up to value of Ls (cell F24

Thickness Thickness of soil of soil

stratum B stratum C (Enter value or 0) (Enter value or 0)

he he bull

(cm) bull (cm) -

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(usedto estimate OR perrrieability | soil vapor

permeability)

k bull

(cm)

SL 1 bull 1

ENTER Stratum A

SCS soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

Pb (gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Stratum A

soil water-filled porosity

9w (cmcm)

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

Pb^

(gcm)

ENTER Stratum B soil total porosity

n^

(unitless)

ENTER Stratum B

soil water-filled porosity

(crhcm)

ENTER Stratum C

SCS soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE 4gt

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

bull Soil-bldg pressure

differential AP^

(gcm-s)

ENTER Enclosed

space floor

length LB

(cm)

ENTER Enclosed

space floor

width bull W B

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width

w

(cm)

ENTER

Indoor air exchange

rate

ER (1h)

ENTER Average vapor

flow rate into bidg OR

Leave blank to calculc

Qsoil

(Lm)

10 40 8839 8839 244 01 083

Appx B-4 MCxIs 1 of 3 982009

AR100317

Diffijsivity in air

D

APPENDIX B-4-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffusivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature

Pw H TR AHt TB TC

Molecular weight

MW

Unit risk

factor URF

Reference cone

RfC

(cms) (cms) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) bull (ngm)- (mgm)

bull bull

1 101E-01 1 117E-05 1 218E-03 1 25 | 6706 1 31300 1 51000 1 8493 1 47E-07 1 30E+00 1

Appx B-4 MCxIs 2 of 3 982009

AR100318

APPENDIX B-4-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

T

(sec)

Source- -building

separation

LT

(cm)

Stratum A soil

air-filled porosity

e a bull

(cmcm)

Stratum B soil

bullair-filled porosity bull

ea^ (cmcm)

Stratum C soil

air-filled porosity

ea= (cmcmj

Stratum A effective total fluid

saturation

Sc bull

(cmcm)

Stratum A soil

intrinsic pemneability

ki (cm)

Stratum A soil

relative air permeability

^ ^ g

(cm)

stratumA bull soil effective vapor permeability

K (cm)

Floor-wall

seam perimeter

Xcrack

(cm)

Soil gas

cone (ngm)

BIdg ventilation

rate

Qbuildinc

(cms)

1 946E+08

Area of -enclosed

space below

bull grade

AB

(cm)

1

Crack-to-total

area rafio

Tl

(unitless)

0284 1

Crack depth below grade

Zcrack

(cm)

0284 1

bull Enthalpy of vaporization at

ave soil temperature

AHTs (calmol)

0284

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

0184

Henrys law constant at ave soil

temperature

HTS

bull (unitless)

1 596E-09

Vapor viscosity at

ave soil temperature

Mrs (gcm-s)

0901

Stratum A

effective diffusion

coefficient

D (cms)

537E-09

Stratum B

effective diffusion

coefficient

D-B (cms)

35357 1

Stratum C -

effective diffusion

coefficient

D-c ^ (cms)

152E+03

Total bull overall

bull effective diffusion

coefficient

D ^

(cms)

440E+06 1

Difftjsion path

length

Ld (cm)

1 787E+07

Convection path

length

Lp (cm)

4 49E-05

Source vapor cone

Csource

(ngm)

15 1

Crack radius

Tcrack

(cm)

7007 bull 1

Average vapor

flow rate intobldg

Qsoil

(cms)

130E-03

Crack effective diffusion

coefficient pcrack

(cms)-

555E-02

bull ^

Area of crack

Acrack

(cm) bull

1 176E-04

Exponent of equivalent foundation

Peclet number

exp(Pe)

(unitless) bull

bull bull

1 15

1 END

152E+03 010 1 474E+01 1 102E-02 354E+03 1 519E+05

102E-02

Infinite source

indoor ^attenuation coefficient

bull a

(unitless)

aiii08E-05

0 OOE+00

bull

Infinite bull source

bIdg ^ cone

^bu i l d i ng

(MQm)

164E-02

OOOE+00 1

Unit risk

factor

URF

(ngm)-

47E-07 1

102E-02 j

Reference cone

RfC

(mgm)

30E+00 j

1 1

Appx B-4 MCxIs 3 of 3 982009

AR100319

APPENDIX B-5-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ^erslon 31 0204

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

127184

Soil Gas Concentration Data ENTER ^ ENTER

Soil -Soi l bull gas gas

cone OR cone Cg C bull

(tgm) (ppmv)

149E+05 1

Chemical

bull Tetrachlbroethylene

MORE 4

ENTER Depth

below grade to bottom

ofenclosecJ space floor

LF

(cm)

ENTER

Soil gas bull sampling

depth below grade

u bull (cm)

ENTER

Average bullsoil

temperature - Ts

ro 1 1 5 1 15 1 125 bull

ENTER ENTER ENTER totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hft bull he bull he

(cm) (cm) (cm)

bull 1 5 1 - 1

ENTER ENTER Soil

stratum A User^defined bull SCS bull stratum A soil type soil vapor

(used to estimate OR perrrieability soil vapor K bull

permeability) (cm) 1

SL 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

Pb

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Sitratum A

soil water-filled bull porosity

(cmcm)

ENTER Stratum B

SCS soiltype

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

Pb^

(gcm)

ENTER Stratum B soil total porosity

Ajnitless^

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS soil type

LookupSoil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

VS

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor width

W B

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width

w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

ENTER Average vapor

flow rate into bidg OR

Leave blank to calcul

bull Qsoil

(Lm)

10 40 8839 8839 244 01 083

Appx B-5 PCExIS 1 of 3 982009

AR100320

APPENDIX B-5-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal Unit

Diffusivity Diffusivity at reference reference the riormal boiling Critical Molecular risk Reference in air in water temperature temperature boiling point point teriiperature weight factor cone

Da Dbdquo H TR AHb TB Tc MW URF RfC

(cms) (cnis) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) (^gm)- (mgm)

1 720E-02 1 820E-06 1 184E-02 1 25 1 8288 1 39440 1 62020 1 16583 1 59E-06 1 60E-01 1

J

AppxB-5PCExls 2 of 3 - 982009

AR100321

APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

T

(sec)

Source-building

separation

LT

bull (cm)

Stratum A soil

air-filled porosity

Oa (cmcm)

Stratum B - soil air-filled porosity

ea (cmcm)

Stratum C soil

air-filled porosity

ea= - (cmcm)

Stratum A effective total fluid

saturation

sbdquo (cmcm)

Stratum A soil

intrinsic permeability

ki (cm)

Stratum A soil

relative air permeability

- ^ g

(cm)

Stratum A soil

effective vapor permeability

kv (cm)

Floor-wall

seam perimeter

^crack

(cm)

Soil gas

cone

(ngm)

BIdg venfilation

rate

Qbuildins

bull (cms)

bull bull

1 946E+08

Area of enclosed

space below grade

AB

(cm)

1

bullCrack-to-total

area ratio

1 (unitless)

0284 1

Crack bull depth below grade

Zcrack

(cm) -

0284 1

Enthalpy of vaporization at bull

ave soil temperature

bull A H V TS

(calmol)

0284

Henrys law constant at

ave soil temperature

HTS (atm-mmol)

0184

-Henrys law constant at

ave soil temperature

HTS

(unitless)

1 596E-09

Vapor viscosity at

ave soil temperature

HTS

(gcm-s)

0901

Stratum A

effective diffusion

coefficient bull D = bull

(cms)

537E-09

Stratum B

effective diffusion

coefficient

D--B (cms)

35357 1

Stratum C

effective diffusion bull

coefficient

D-c (crris)

149E+05

Total overall

effective bulldiffusion coefficient

DT

(cms)

440E+06 1

Difftjsion path

length

U (cm)

1 787E+07

Convection path

length

bull Lp

(cm)

4 49E-05

Source vapor cone

^source

(ngm)

15 1

Crack radius

Tcrack

(cm)

9528 1

Average vapor

flow rate intobldg

Qsoil (cms)

908E-03

Crack effective diffusion

coefficient pcrack

bull ( c m s ) bull

387E-01

Area of crack

Abdquoack (cm)

1 176E-04

Exponent of equivalent foundafion

Peclet number

exp(Pe)

(unitless)

bull

1 15-

1 END

149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08

727E-03

Infinite source indoor

attenuation coefficient

a

(unitless)

108E-05

OOOE+00

Infinite source

bIdg cone

Cburldtng

(Mgm)

161 E+00

OOOE+00 1

Unit risk

factor

URF

(ugm)-

59E-06 1

727E-03

Reference cone

RfC (mgm)

60E-01

1 1

Appx B-5 PCExls 3 of 3 982009

AR100322

APPENDIX B-6-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ersion31 0204

Reset to Defaults

t

Soil Gas Concentration Data ENTER

Chemical CAS No

(numbers only

no dashes)

79016

ENTER ENTER Soil Soil gas gas

cone OR cone C C -

bull (ngm) (ppmv)

782E+03

Chemical

Trichloroethylene

MORE ENTER Depth

below grade to bottom-

of enclosed space floor

LF

(cm)

ENTER

Soil gas sarnpling

depth below grade

U (cm)

ENTER

Average soil

temperature Ts

(degC)

1 15 1 15 t 125

ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e

(cm) (cm) (cm)

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estimate OR permeability soil vapor

permeability)

k (cm)

bull S L 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil bull-Parameters

ENTER Stratum A

soil dry bulk density

P b -

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Stratum A bull

soilwaterrfilled porosity

(cmcm) bull

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

bull P ^ (gcm)

ENTER Stratum B soil total

porosity

nlaquo

(unitless) -

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS bull soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor

width W B

(cm)

ENTER

Enclosed space height

H B bull

( c m ) bull

ENTER

Floor-wall seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bIdg OR

Leave blank to calculc

Qsoil

(Lm) -

Appx B-6 TCExIs 1 of 3 982009

A

AR100323

APPENDIX B-6-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight

Da Dbdquo H TR AH^b TB TC MW

Unit risk Reference

factor cone URF RfC

(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)

1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1

Appx B-6 TCExIs 2 of 3 982009

AR100324

APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

(sec)

Source-building

separation LT

(cm)

Stratum A soil

air-filled porosity

bull ea (cmcm)

Stratum B Soil

air-fllled porosity

e^ bull (cmcm)

Stratum C soil

air-filled porosity

(cmcm)

StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air

saturation permeability permeability

S|e k krg (cmcm) (cm) (cm)

Stratum A Floor-soil wall BIdg

effective vapor seam Soil ventilafion permeability perimeter gas rate

k^ bull Xack c o n e Qbuildins

(cm) (cm) (ngm) (cms)

946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |

Area of enclosed

space below grade

AB

(cm)

Ciack- to-total

area ratio

1 (unitless)

Crack depth below grade

Zcrack

(cm)

Enthalpy of vaporization at

ave soil temperature

A H J S

(calmol)

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law bull constant at

ave soil temperature

HTS

(unitless)

Vapor viscosity at

ave soil temperature

|JTS

(gcm^s)

Stratum A

effective diffusion

coefficient

(cms)

Stratum B

effective -diffusion

coefficient

D=B (cms)

Stratum ^ C effective diffusion

coefficient

D=c (cms)

Total overall

effective diffusion

coefficient

DT

(cms)

I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03

Diffusion path

length

Li (cm) bull

Convection bull path

length

Lp

(cm)

Source vapor cone bull

^source

(ngm)

Crack radius

rcrack

(cm)

Average vapor

- flow rate intobldg

Qsoil

(cms)

Crack effective diffusion

bull coefficient Qcrack

(cms)

Area of crack

^crack

(cm)

Exponent of equivalent foundation

Peclet bull number

exp(Pe)

(unitless)

bull bull

1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07

Infinite source Indoor

attenuation coefficient

a

(unitless)

108E-05

Infinite source

bIdg concgt

^building

(ngm)

844E-02

Unit risk

factor

URF

(ngm)-

Reference cone

RfC

(mgm)

1 1E-04 1 40E-02 1

END

Appx B-6 TCExIs 3 of 3 982009

AR100325

Office of Waste Management 1356 Hansford Street

Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256

West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director

ORDER

ISSUED UNDER THE

HAZARDOUS WASTE MANAGEMENT ACT

CHAPTER 22 ARTICLE 18

OF THE WEST VIRGINIA CODE^ AS AMENDED

y Order Number HW-011-80

To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704

ATTEMTION MREDARMON

Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull

AR100326

ViWJ011-laquo9 PageNunil)er2

BASIS FOR ORDER

As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following

A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^

B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator

C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities

0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94

^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement

P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following

1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater

2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was

^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment

CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable

CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order

AR100327

H W - 0 1 1 - 9 9 Page Number 3

REQUIREMENTS OF ORDER

Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows

1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^

2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore

remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling

GENERAL PROVaiONS

1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order

2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order

3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order

Effective Date

Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief

Wt T 1 V Oflice of Waste Management

AR100328

^ ^ S I S

^wmmmmamn

AR100329

Page 41: SDMS DocID 2121999 · International Enterprises Corp. building (Coyne Building), which is located at 1111 Vernon Street, Westmoreland District, Wayne County, West Virginia. The following

Diffijsivity in air

D

APPENDIX B-4-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffusivity at reference reference the normal boiling Critical in water temperature temperature boiling point point temperature

Pw H TR AHt TB TC

Molecular weight

MW

Unit risk

factor URF

Reference cone

RfC

(cms) (cms) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) bull (ngm)- (mgm)

bull bull

1 101E-01 1 117E-05 1 218E-03 1 25 | 6706 1 31300 1 51000 1 8493 1 47E-07 1 30E+00 1

Appx B-4 MCxIs 2 of 3 982009

AR100318

APPENDIX B-4-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

T

(sec)

Source- -building

separation

LT

(cm)

Stratum A soil

air-filled porosity

e a bull

(cmcm)

Stratum B soil

bullair-filled porosity bull

ea^ (cmcm)

Stratum C soil

air-filled porosity

ea= (cmcmj

Stratum A effective total fluid

saturation

Sc bull

(cmcm)

Stratum A soil

intrinsic pemneability

ki (cm)

Stratum A soil

relative air permeability

^ ^ g

(cm)

stratumA bull soil effective vapor permeability

K (cm)

Floor-wall

seam perimeter

Xcrack

(cm)

Soil gas

cone (ngm)

BIdg ventilation

rate

Qbuildinc

(cms)

1 946E+08

Area of -enclosed

space below

bull grade

AB

(cm)

1

Crack-to-total

area rafio

Tl

(unitless)

0284 1

Crack depth below grade

Zcrack

(cm)

0284 1

bull Enthalpy of vaporization at

ave soil temperature

AHTs (calmol)

0284

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

0184

Henrys law constant at ave soil

temperature

HTS

bull (unitless)

1 596E-09

Vapor viscosity at

ave soil temperature

Mrs (gcm-s)

0901

Stratum A

effective diffusion

coefficient

D (cms)

537E-09

Stratum B

effective diffusion

coefficient

D-B (cms)

35357 1

Stratum C -

effective diffusion

coefficient

D-c ^ (cms)

152E+03

Total bull overall

bull effective diffusion

coefficient

D ^

(cms)

440E+06 1

Difftjsion path

length

Ld (cm)

1 787E+07

Convection path

length

Lp (cm)

4 49E-05

Source vapor cone

Csource

(ngm)

15 1

Crack radius

Tcrack

(cm)

7007 bull 1

Average vapor

flow rate intobldg

Qsoil

(cms)

130E-03

Crack effective diffusion

coefficient pcrack

(cms)-

555E-02

bull ^

Area of crack

Acrack

(cm) bull

1 176E-04

Exponent of equivalent foundation

Peclet number

exp(Pe)

(unitless) bull

bull bull

1 15

1 END

152E+03 010 1 474E+01 1 102E-02 354E+03 1 519E+05

102E-02

Infinite source

indoor ^attenuation coefficient

bull a

(unitless)

aiii08E-05

0 OOE+00

bull

Infinite bull source

bIdg ^ cone

^bu i l d i ng

(MQm)

164E-02

OOOE+00 1

Unit risk

factor

URF

(ngm)-

47E-07 1

102E-02 j

Reference cone

RfC

(mgm)

30E+00 j

1 1

Appx B-4 MCxIs 3 of 3 982009

AR100319

APPENDIX B-5-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ^erslon 31 0204

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

127184

Soil Gas Concentration Data ENTER ^ ENTER

Soil -Soi l bull gas gas

cone OR cone Cg C bull

(tgm) (ppmv)

149E+05 1

Chemical

bull Tetrachlbroethylene

MORE 4

ENTER Depth

below grade to bottom

ofenclosecJ space floor

LF

(cm)

ENTER

Soil gas bull sampling

depth below grade

u bull (cm)

ENTER

Average bullsoil

temperature - Ts

ro 1 1 5 1 15 1 125 bull

ENTER ENTER ENTER totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hft bull he bull he

(cm) (cm) (cm)

bull 1 5 1 - 1

ENTER ENTER Soil

stratum A User^defined bull SCS bull stratum A soil type soil vapor

(used to estimate OR perrrieability soil vapor K bull

permeability) (cm) 1

SL 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

Pb

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Sitratum A

soil water-filled bull porosity

(cmcm)

ENTER Stratum B

SCS soiltype

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

Pb^

(gcm)

ENTER Stratum B soil total porosity

Ajnitless^

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS soil type

LookupSoil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

VS

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor width

W B

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width

w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

ENTER Average vapor

flow rate into bidg OR

Leave blank to calcul

bull Qsoil

(Lm)

10 40 8839 8839 244 01 083

Appx B-5 PCExIS 1 of 3 982009

AR100320

APPENDIX B-5-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal Unit

Diffusivity Diffusivity at reference reference the riormal boiling Critical Molecular risk Reference in air in water temperature temperature boiling point point teriiperature weight factor cone

Da Dbdquo H TR AHb TB Tc MW URF RfC

(cms) (cnis) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) (^gm)- (mgm)

1 720E-02 1 820E-06 1 184E-02 1 25 1 8288 1 39440 1 62020 1 16583 1 59E-06 1 60E-01 1

J

AppxB-5PCExls 2 of 3 - 982009

AR100321

APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

T

(sec)

Source-building

separation

LT

bull (cm)

Stratum A soil

air-filled porosity

Oa (cmcm)

Stratum B - soil air-filled porosity

ea (cmcm)

Stratum C soil

air-filled porosity

ea= - (cmcm)

Stratum A effective total fluid

saturation

sbdquo (cmcm)

Stratum A soil

intrinsic permeability

ki (cm)

Stratum A soil

relative air permeability

- ^ g

(cm)

Stratum A soil

effective vapor permeability

kv (cm)

Floor-wall

seam perimeter

^crack

(cm)

Soil gas

cone

(ngm)

BIdg venfilation

rate

Qbuildins

bull (cms)

bull bull

1 946E+08

Area of enclosed

space below grade

AB

(cm)

1

bullCrack-to-total

area ratio

1 (unitless)

0284 1

Crack bull depth below grade

Zcrack

(cm) -

0284 1

Enthalpy of vaporization at bull

ave soil temperature

bull A H V TS

(calmol)

0284

Henrys law constant at

ave soil temperature

HTS (atm-mmol)

0184

-Henrys law constant at

ave soil temperature

HTS

(unitless)

1 596E-09

Vapor viscosity at

ave soil temperature

HTS

(gcm-s)

0901

Stratum A

effective diffusion

coefficient bull D = bull

(cms)

537E-09

Stratum B

effective diffusion

coefficient

D--B (cms)

35357 1

Stratum C

effective diffusion bull

coefficient

D-c (crris)

149E+05

Total overall

effective bulldiffusion coefficient

DT

(cms)

440E+06 1

Difftjsion path

length

U (cm)

1 787E+07

Convection path

length

bull Lp

(cm)

4 49E-05

Source vapor cone

^source

(ngm)

15 1

Crack radius

Tcrack

(cm)

9528 1

Average vapor

flow rate intobldg

Qsoil (cms)

908E-03

Crack effective diffusion

coefficient pcrack

bull ( c m s ) bull

387E-01

Area of crack

Abdquoack (cm)

1 176E-04

Exponent of equivalent foundafion

Peclet number

exp(Pe)

(unitless)

bull

1 15-

1 END

149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08

727E-03

Infinite source indoor

attenuation coefficient

a

(unitless)

108E-05

OOOE+00

Infinite source

bIdg cone

Cburldtng

(Mgm)

161 E+00

OOOE+00 1

Unit risk

factor

URF

(ugm)-

59E-06 1

727E-03

Reference cone

RfC (mgm)

60E-01

1 1

Appx B-5 PCExls 3 of 3 982009

AR100322

APPENDIX B-6-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ersion31 0204

Reset to Defaults

t

Soil Gas Concentration Data ENTER

Chemical CAS No

(numbers only

no dashes)

79016

ENTER ENTER Soil Soil gas gas

cone OR cone C C -

bull (ngm) (ppmv)

782E+03

Chemical

Trichloroethylene

MORE ENTER Depth

below grade to bottom-

of enclosed space floor

LF

(cm)

ENTER

Soil gas sarnpling

depth below grade

U (cm)

ENTER

Average soil

temperature Ts

(degC)

1 15 1 15 t 125

ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e

(cm) (cm) (cm)

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estimate OR permeability soil vapor

permeability)

k (cm)

bull S L 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil bull-Parameters

ENTER Stratum A

soil dry bulk density

P b -

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Stratum A bull

soilwaterrfilled porosity

(cmcm) bull

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

bull P ^ (gcm)

ENTER Stratum B soil total

porosity

nlaquo

(unitless) -

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS bull soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor

width W B

(cm)

ENTER

Enclosed space height

H B bull

( c m ) bull

ENTER

Floor-wall seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bIdg OR

Leave blank to calculc

Qsoil

(Lm) -

Appx B-6 TCExIs 1 of 3 982009

A

AR100323

APPENDIX B-6-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight

Da Dbdquo H TR AH^b TB TC MW

Unit risk Reference

factor cone URF RfC

(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)

1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1

Appx B-6 TCExIs 2 of 3 982009

AR100324

APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

(sec)

Source-building

separation LT

(cm)

Stratum A soil

air-filled porosity

bull ea (cmcm)

Stratum B Soil

air-fllled porosity

e^ bull (cmcm)

Stratum C soil

air-filled porosity

(cmcm)

StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air

saturation permeability permeability

S|e k krg (cmcm) (cm) (cm)

Stratum A Floor-soil wall BIdg

effective vapor seam Soil ventilafion permeability perimeter gas rate

k^ bull Xack c o n e Qbuildins

(cm) (cm) (ngm) (cms)

946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |

Area of enclosed

space below grade

AB

(cm)

Ciack- to-total

area ratio

1 (unitless)

Crack depth below grade

Zcrack

(cm)

Enthalpy of vaporization at

ave soil temperature

A H J S

(calmol)

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law bull constant at

ave soil temperature

HTS

(unitless)

Vapor viscosity at

ave soil temperature

|JTS

(gcm^s)

Stratum A

effective diffusion

coefficient

(cms)

Stratum B

effective -diffusion

coefficient

D=B (cms)

Stratum ^ C effective diffusion

coefficient

D=c (cms)

Total overall

effective diffusion

coefficient

DT

(cms)

I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03

Diffusion path

length

Li (cm) bull

Convection bull path

length

Lp

(cm)

Source vapor cone bull

^source

(ngm)

Crack radius

rcrack

(cm)

Average vapor

- flow rate intobldg

Qsoil

(cms)

Crack effective diffusion

bull coefficient Qcrack

(cms)

Area of crack

^crack

(cm)

Exponent of equivalent foundation

Peclet bull number

exp(Pe)

(unitless)

bull bull

1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07

Infinite source Indoor

attenuation coefficient

a

(unitless)

108E-05

Infinite source

bIdg concgt

^building

(ngm)

844E-02

Unit risk

factor

URF

(ngm)-

Reference cone

RfC

(mgm)

1 1E-04 1 40E-02 1

END

Appx B-6 TCExIs 3 of 3 982009

AR100325

Office of Waste Management 1356 Hansford Street

Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256

West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director

ORDER

ISSUED UNDER THE

HAZARDOUS WASTE MANAGEMENT ACT

CHAPTER 22 ARTICLE 18

OF THE WEST VIRGINIA CODE^ AS AMENDED

y Order Number HW-011-80

To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704

ATTEMTION MREDARMON

Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull

AR100326

ViWJ011-laquo9 PageNunil)er2

BASIS FOR ORDER

As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following

A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^

B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator

C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities

0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94

^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement

P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following

1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater

2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was

^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment

CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable

CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order

AR100327

H W - 0 1 1 - 9 9 Page Number 3

REQUIREMENTS OF ORDER

Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows

1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^

2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore

remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling

GENERAL PROVaiONS

1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order

2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order

3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order

Effective Date

Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief

Wt T 1 V Oflice of Waste Management

AR100328

^ ^ S I S

^wmmmmamn

AR100329

Page 42: SDMS DocID 2121999 · International Enterprises Corp. building (Coyne Building), which is located at 1111 Vernon Street, Westmoreland District, Wayne County, West Virginia. The following

APPENDIX B-4-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

T

(sec)

Source- -building

separation

LT

(cm)

Stratum A soil

air-filled porosity

e a bull

(cmcm)

Stratum B soil

bullair-filled porosity bull

ea^ (cmcm)

Stratum C soil

air-filled porosity

ea= (cmcmj

Stratum A effective total fluid

saturation

Sc bull

(cmcm)

Stratum A soil

intrinsic pemneability

ki (cm)

Stratum A soil

relative air permeability

^ ^ g

(cm)

stratumA bull soil effective vapor permeability

K (cm)

Floor-wall

seam perimeter

Xcrack

(cm)

Soil gas

cone (ngm)

BIdg ventilation

rate

Qbuildinc

(cms)

1 946E+08

Area of -enclosed

space below

bull grade

AB

(cm)

1

Crack-to-total

area rafio

Tl

(unitless)

0284 1

Crack depth below grade

Zcrack

(cm)

0284 1

bull Enthalpy of vaporization at

ave soil temperature

AHTs (calmol)

0284

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

0184

Henrys law constant at ave soil

temperature

HTS

bull (unitless)

1 596E-09

Vapor viscosity at

ave soil temperature

Mrs (gcm-s)

0901

Stratum A

effective diffusion

coefficient

D (cms)

537E-09

Stratum B

effective diffusion

coefficient

D-B (cms)

35357 1

Stratum C -

effective diffusion

coefficient

D-c ^ (cms)

152E+03

Total bull overall

bull effective diffusion

coefficient

D ^

(cms)

440E+06 1

Difftjsion path

length

Ld (cm)

1 787E+07

Convection path

length

Lp (cm)

4 49E-05

Source vapor cone

Csource

(ngm)

15 1

Crack radius

Tcrack

(cm)

7007 bull 1

Average vapor

flow rate intobldg

Qsoil

(cms)

130E-03

Crack effective diffusion

coefficient pcrack

(cms)-

555E-02

bull ^

Area of crack

Acrack

(cm) bull

1 176E-04

Exponent of equivalent foundation

Peclet number

exp(Pe)

(unitless) bull

bull bull

1 15

1 END

152E+03 010 1 474E+01 1 102E-02 354E+03 1 519E+05

102E-02

Infinite source

indoor ^attenuation coefficient

bull a

(unitless)

aiii08E-05

0 OOE+00

bull

Infinite bull source

bIdg ^ cone

^bu i l d i ng

(MQm)

164E-02

OOOE+00 1

Unit risk

factor

URF

(ngm)-

47E-07 1

102E-02 j

Reference cone

RfC

(mgm)

30E+00 j

1 1

Appx B-4 MCxIs 3 of 3 982009

AR100319

APPENDIX B-5-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ^erslon 31 0204

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

127184

Soil Gas Concentration Data ENTER ^ ENTER

Soil -Soi l bull gas gas

cone OR cone Cg C bull

(tgm) (ppmv)

149E+05 1

Chemical

bull Tetrachlbroethylene

MORE 4

ENTER Depth

below grade to bottom

ofenclosecJ space floor

LF

(cm)

ENTER

Soil gas bull sampling

depth below grade

u bull (cm)

ENTER

Average bullsoil

temperature - Ts

ro 1 1 5 1 15 1 125 bull

ENTER ENTER ENTER totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hft bull he bull he

(cm) (cm) (cm)

bull 1 5 1 - 1

ENTER ENTER Soil

stratum A User^defined bull SCS bull stratum A soil type soil vapor

(used to estimate OR perrrieability soil vapor K bull

permeability) (cm) 1

SL 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

Pb

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Sitratum A

soil water-filled bull porosity

(cmcm)

ENTER Stratum B

SCS soiltype

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

Pb^

(gcm)

ENTER Stratum B soil total porosity

Ajnitless^

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS soil type

LookupSoil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

VS

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor width

W B

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width

w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

ENTER Average vapor

flow rate into bidg OR

Leave blank to calcul

bull Qsoil

(Lm)

10 40 8839 8839 244 01 083

Appx B-5 PCExIS 1 of 3 982009

AR100320

APPENDIX B-5-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal Unit

Diffusivity Diffusivity at reference reference the riormal boiling Critical Molecular risk Reference in air in water temperature temperature boiling point point teriiperature weight factor cone

Da Dbdquo H TR AHb TB Tc MW URF RfC

(cms) (cnis) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) (^gm)- (mgm)

1 720E-02 1 820E-06 1 184E-02 1 25 1 8288 1 39440 1 62020 1 16583 1 59E-06 1 60E-01 1

J

AppxB-5PCExls 2 of 3 - 982009

AR100321

APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

T

(sec)

Source-building

separation

LT

bull (cm)

Stratum A soil

air-filled porosity

Oa (cmcm)

Stratum B - soil air-filled porosity

ea (cmcm)

Stratum C soil

air-filled porosity

ea= - (cmcm)

Stratum A effective total fluid

saturation

sbdquo (cmcm)

Stratum A soil

intrinsic permeability

ki (cm)

Stratum A soil

relative air permeability

- ^ g

(cm)

Stratum A soil

effective vapor permeability

kv (cm)

Floor-wall

seam perimeter

^crack

(cm)

Soil gas

cone

(ngm)

BIdg venfilation

rate

Qbuildins

bull (cms)

bull bull

1 946E+08

Area of enclosed

space below grade

AB

(cm)

1

bullCrack-to-total

area ratio

1 (unitless)

0284 1

Crack bull depth below grade

Zcrack

(cm) -

0284 1

Enthalpy of vaporization at bull

ave soil temperature

bull A H V TS

(calmol)

0284

Henrys law constant at

ave soil temperature

HTS (atm-mmol)

0184

-Henrys law constant at

ave soil temperature

HTS

(unitless)

1 596E-09

Vapor viscosity at

ave soil temperature

HTS

(gcm-s)

0901

Stratum A

effective diffusion

coefficient bull D = bull

(cms)

537E-09

Stratum B

effective diffusion

coefficient

D--B (cms)

35357 1

Stratum C

effective diffusion bull

coefficient

D-c (crris)

149E+05

Total overall

effective bulldiffusion coefficient

DT

(cms)

440E+06 1

Difftjsion path

length

U (cm)

1 787E+07

Convection path

length

bull Lp

(cm)

4 49E-05

Source vapor cone

^source

(ngm)

15 1

Crack radius

Tcrack

(cm)

9528 1

Average vapor

flow rate intobldg

Qsoil (cms)

908E-03

Crack effective diffusion

coefficient pcrack

bull ( c m s ) bull

387E-01

Area of crack

Abdquoack (cm)

1 176E-04

Exponent of equivalent foundafion

Peclet number

exp(Pe)

(unitless)

bull

1 15-

1 END

149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08

727E-03

Infinite source indoor

attenuation coefficient

a

(unitless)

108E-05

OOOE+00

Infinite source

bIdg cone

Cburldtng

(Mgm)

161 E+00

OOOE+00 1

Unit risk

factor

URF

(ugm)-

59E-06 1

727E-03

Reference cone

RfC (mgm)

60E-01

1 1

Appx B-5 PCExls 3 of 3 982009

AR100322

APPENDIX B-6-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ersion31 0204

Reset to Defaults

t

Soil Gas Concentration Data ENTER

Chemical CAS No

(numbers only

no dashes)

79016

ENTER ENTER Soil Soil gas gas

cone OR cone C C -

bull (ngm) (ppmv)

782E+03

Chemical

Trichloroethylene

MORE ENTER Depth

below grade to bottom-

of enclosed space floor

LF

(cm)

ENTER

Soil gas sarnpling

depth below grade

U (cm)

ENTER

Average soil

temperature Ts

(degC)

1 15 1 15 t 125

ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e

(cm) (cm) (cm)

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estimate OR permeability soil vapor

permeability)

k (cm)

bull S L 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil bull-Parameters

ENTER Stratum A

soil dry bulk density

P b -

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Stratum A bull

soilwaterrfilled porosity

(cmcm) bull

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

bull P ^ (gcm)

ENTER Stratum B soil total

porosity

nlaquo

(unitless) -

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS bull soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor

width W B

(cm)

ENTER

Enclosed space height

H B bull

( c m ) bull

ENTER

Floor-wall seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bIdg OR

Leave blank to calculc

Qsoil

(Lm) -

Appx B-6 TCExIs 1 of 3 982009

A

AR100323

APPENDIX B-6-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight

Da Dbdquo H TR AH^b TB TC MW

Unit risk Reference

factor cone URF RfC

(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)

1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1

Appx B-6 TCExIs 2 of 3 982009

AR100324

APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

(sec)

Source-building

separation LT

(cm)

Stratum A soil

air-filled porosity

bull ea (cmcm)

Stratum B Soil

air-fllled porosity

e^ bull (cmcm)

Stratum C soil

air-filled porosity

(cmcm)

StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air

saturation permeability permeability

S|e k krg (cmcm) (cm) (cm)

Stratum A Floor-soil wall BIdg

effective vapor seam Soil ventilafion permeability perimeter gas rate

k^ bull Xack c o n e Qbuildins

(cm) (cm) (ngm) (cms)

946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |

Area of enclosed

space below grade

AB

(cm)

Ciack- to-total

area ratio

1 (unitless)

Crack depth below grade

Zcrack

(cm)

Enthalpy of vaporization at

ave soil temperature

A H J S

(calmol)

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law bull constant at

ave soil temperature

HTS

(unitless)

Vapor viscosity at

ave soil temperature

|JTS

(gcm^s)

Stratum A

effective diffusion

coefficient

(cms)

Stratum B

effective -diffusion

coefficient

D=B (cms)

Stratum ^ C effective diffusion

coefficient

D=c (cms)

Total overall

effective diffusion

coefficient

DT

(cms)

I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03

Diffusion path

length

Li (cm) bull

Convection bull path

length

Lp

(cm)

Source vapor cone bull

^source

(ngm)

Crack radius

rcrack

(cm)

Average vapor

- flow rate intobldg

Qsoil

(cms)

Crack effective diffusion

bull coefficient Qcrack

(cms)

Area of crack

^crack

(cm)

Exponent of equivalent foundation

Peclet bull number

exp(Pe)

(unitless)

bull bull

1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07

Infinite source Indoor

attenuation coefficient

a

(unitless)

108E-05

Infinite source

bIdg concgt

^building

(ngm)

844E-02

Unit risk

factor

URF

(ngm)-

Reference cone

RfC

(mgm)

1 1E-04 1 40E-02 1

END

Appx B-6 TCExIs 3 of 3 982009

AR100325

Office of Waste Management 1356 Hansford Street

Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256

West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director

ORDER

ISSUED UNDER THE

HAZARDOUS WASTE MANAGEMENT ACT

CHAPTER 22 ARTICLE 18

OF THE WEST VIRGINIA CODE^ AS AMENDED

y Order Number HW-011-80

To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704

ATTEMTION MREDARMON

Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull

AR100326

ViWJ011-laquo9 PageNunil)er2

BASIS FOR ORDER

As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following

A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^

B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator

C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities

0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94

^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement

P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following

1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater

2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was

^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment

CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable

CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order

AR100327

H W - 0 1 1 - 9 9 Page Number 3

REQUIREMENTS OF ORDER

Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows

1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^

2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore

remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling

GENERAL PROVaiONS

1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order

2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order

3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order

Effective Date

Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief

Wt T 1 V Oflice of Waste Management

AR100328

^ ^ S I S

^wmmmmamn

AR100329

Page 43: SDMS DocID 2121999 · International Enterprises Corp. building (Coyne Building), which is located at 1111 Vernon Street, Westmoreland District, Wayne County, West Virginia. The following

APPENDIX B-5-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ^erslon 31 0204

Reset to Defaults

ENTER

Chemical CAS No

(numbers only

no dashes)

127184

Soil Gas Concentration Data ENTER ^ ENTER

Soil -Soi l bull gas gas

cone OR cone Cg C bull

(tgm) (ppmv)

149E+05 1

Chemical

bull Tetrachlbroethylene

MORE 4

ENTER Depth

below grade to bottom

ofenclosecJ space floor

LF

(cm)

ENTER

Soil gas bull sampling

depth below grade

u bull (cm)

ENTER

Average bullsoil

temperature - Ts

ro 1 1 5 1 15 1 125 bull

ENTER ENTER ENTER totals must add up to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratum A (Enter value or 0) (Enter value or 0)

hft bull he bull he

(cm) (cm) (cm)

bull 1 5 1 - 1

ENTER ENTER Soil

stratum A User^defined bull SCS bull stratum A soil type soil vapor

(used to estimate OR perrrieability soil vapor K bull

permeability) (cm) 1

SL 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil Parameters

ENTER Stratum A

soil dry bulk density

Pb

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Sitratum A

soil water-filled bull porosity

(cmcm)

ENTER Stratum B

SCS soiltype

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

Pb^

(gcm)

ENTER Stratum B soil total porosity

Ajnitless^

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS soil type

LookupSoil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

VS

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor width

W B

(cm)

ENTER

Enclosed space height

HB

(cm)

ENTER

Floor-wall seam crack

width

w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

ENTER Average vapor

flow rate into bidg OR

Leave blank to calcul

bull Qsoil

(Lm)

10 40 8839 8839 244 01 083

Appx B-5 PCExIS 1 of 3 982009

AR100320

APPENDIX B-5-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal Unit

Diffusivity Diffusivity at reference reference the riormal boiling Critical Molecular risk Reference in air in water temperature temperature boiling point point teriiperature weight factor cone

Da Dbdquo H TR AHb TB Tc MW URF RfC

(cms) (cnis) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) (^gm)- (mgm)

1 720E-02 1 820E-06 1 184E-02 1 25 1 8288 1 39440 1 62020 1 16583 1 59E-06 1 60E-01 1

J

AppxB-5PCExls 2 of 3 - 982009

AR100321

APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

T

(sec)

Source-building

separation

LT

bull (cm)

Stratum A soil

air-filled porosity

Oa (cmcm)

Stratum B - soil air-filled porosity

ea (cmcm)

Stratum C soil

air-filled porosity

ea= - (cmcm)

Stratum A effective total fluid

saturation

sbdquo (cmcm)

Stratum A soil

intrinsic permeability

ki (cm)

Stratum A soil

relative air permeability

- ^ g

(cm)

Stratum A soil

effective vapor permeability

kv (cm)

Floor-wall

seam perimeter

^crack

(cm)

Soil gas

cone

(ngm)

BIdg venfilation

rate

Qbuildins

bull (cms)

bull bull

1 946E+08

Area of enclosed

space below grade

AB

(cm)

1

bullCrack-to-total

area ratio

1 (unitless)

0284 1

Crack bull depth below grade

Zcrack

(cm) -

0284 1

Enthalpy of vaporization at bull

ave soil temperature

bull A H V TS

(calmol)

0284

Henrys law constant at

ave soil temperature

HTS (atm-mmol)

0184

-Henrys law constant at

ave soil temperature

HTS

(unitless)

1 596E-09

Vapor viscosity at

ave soil temperature

HTS

(gcm-s)

0901

Stratum A

effective diffusion

coefficient bull D = bull

(cms)

537E-09

Stratum B

effective diffusion

coefficient

D--B (cms)

35357 1

Stratum C

effective diffusion bull

coefficient

D-c (crris)

149E+05

Total overall

effective bulldiffusion coefficient

DT

(cms)

440E+06 1

Difftjsion path

length

U (cm)

1 787E+07

Convection path

length

bull Lp

(cm)

4 49E-05

Source vapor cone

^source

(ngm)

15 1

Crack radius

Tcrack

(cm)

9528 1

Average vapor

flow rate intobldg

Qsoil (cms)

908E-03

Crack effective diffusion

coefficient pcrack

bull ( c m s ) bull

387E-01

Area of crack

Abdquoack (cm)

1 176E-04

Exponent of equivalent foundafion

Peclet number

exp(Pe)

(unitless)

bull

1 15-

1 END

149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08

727E-03

Infinite source indoor

attenuation coefficient

a

(unitless)

108E-05

OOOE+00

Infinite source

bIdg cone

Cburldtng

(Mgm)

161 E+00

OOOE+00 1

Unit risk

factor

URF

(ugm)-

59E-06 1

727E-03

Reference cone

RfC (mgm)

60E-01

1 1

Appx B-5 PCExls 3 of 3 982009

AR100322

APPENDIX B-6-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ersion31 0204

Reset to Defaults

t

Soil Gas Concentration Data ENTER

Chemical CAS No

(numbers only

no dashes)

79016

ENTER ENTER Soil Soil gas gas

cone OR cone C C -

bull (ngm) (ppmv)

782E+03

Chemical

Trichloroethylene

MORE ENTER Depth

below grade to bottom-

of enclosed space floor

LF

(cm)

ENTER

Soil gas sarnpling

depth below grade

U (cm)

ENTER

Average soil

temperature Ts

(degC)

1 15 1 15 t 125

ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e

(cm) (cm) (cm)

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estimate OR permeability soil vapor

permeability)

k (cm)

bull S L 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil bull-Parameters

ENTER Stratum A

soil dry bulk density

P b -

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Stratum A bull

soilwaterrfilled porosity

(cmcm) bull

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

bull P ^ (gcm)

ENTER Stratum B soil total

porosity

nlaquo

(unitless) -

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS bull soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor

width W B

(cm)

ENTER

Enclosed space height

H B bull

( c m ) bull

ENTER

Floor-wall seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bIdg OR

Leave blank to calculc

Qsoil

(Lm) -

Appx B-6 TCExIs 1 of 3 982009

A

AR100323

APPENDIX B-6-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight

Da Dbdquo H TR AH^b TB TC MW

Unit risk Reference

factor cone URF RfC

(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)

1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1

Appx B-6 TCExIs 2 of 3 982009

AR100324

APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

(sec)

Source-building

separation LT

(cm)

Stratum A soil

air-filled porosity

bull ea (cmcm)

Stratum B Soil

air-fllled porosity

e^ bull (cmcm)

Stratum C soil

air-filled porosity

(cmcm)

StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air

saturation permeability permeability

S|e k krg (cmcm) (cm) (cm)

Stratum A Floor-soil wall BIdg

effective vapor seam Soil ventilafion permeability perimeter gas rate

k^ bull Xack c o n e Qbuildins

(cm) (cm) (ngm) (cms)

946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |

Area of enclosed

space below grade

AB

(cm)

Ciack- to-total

area ratio

1 (unitless)

Crack depth below grade

Zcrack

(cm)

Enthalpy of vaporization at

ave soil temperature

A H J S

(calmol)

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law bull constant at

ave soil temperature

HTS

(unitless)

Vapor viscosity at

ave soil temperature

|JTS

(gcm^s)

Stratum A

effective diffusion

coefficient

(cms)

Stratum B

effective -diffusion

coefficient

D=B (cms)

Stratum ^ C effective diffusion

coefficient

D=c (cms)

Total overall

effective diffusion

coefficient

DT

(cms)

I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03

Diffusion path

length

Li (cm) bull

Convection bull path

length

Lp

(cm)

Source vapor cone bull

^source

(ngm)

Crack radius

rcrack

(cm)

Average vapor

- flow rate intobldg

Qsoil

(cms)

Crack effective diffusion

bull coefficient Qcrack

(cms)

Area of crack

^crack

(cm)

Exponent of equivalent foundation

Peclet bull number

exp(Pe)

(unitless)

bull bull

1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07

Infinite source Indoor

attenuation coefficient

a

(unitless)

108E-05

Infinite source

bIdg concgt

^building

(ngm)

844E-02

Unit risk

factor

URF

(ngm)-

Reference cone

RfC

(mgm)

1 1E-04 1 40E-02 1

END

Appx B-6 TCExIs 3 of 3 982009

AR100325

Office of Waste Management 1356 Hansford Street

Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256

West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director

ORDER

ISSUED UNDER THE

HAZARDOUS WASTE MANAGEMENT ACT

CHAPTER 22 ARTICLE 18

OF THE WEST VIRGINIA CODE^ AS AMENDED

y Order Number HW-011-80

To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704

ATTEMTION MREDARMON

Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull

AR100326

ViWJ011-laquo9 PageNunil)er2

BASIS FOR ORDER

As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following

A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^

B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator

C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities

0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94

^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement

P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following

1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater

2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was

^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment

CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable

CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order

AR100327

H W - 0 1 1 - 9 9 Page Number 3

REQUIREMENTS OF ORDER

Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows

1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^

2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore

remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling

GENERAL PROVaiONS

1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order

2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order

3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order

Effective Date

Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief

Wt T 1 V Oflice of Waste Management

AR100328

^ ^ S I S

^wmmmmamn

AR100329

Page 44: SDMS DocID 2121999 · International Enterprises Corp. building (Coyne Building), which is located at 1111 Vernon Street, Westmoreland District, Wayne County, West Virginia. The following

APPENDIX B-5-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

Henrys Henrys Enthalpy of law constant law constant vaporization at Normal Unit

Diffusivity Diffusivity at reference reference the riormal boiling Critical Molecular risk Reference in air in water temperature temperature boiling point point teriiperature weight factor cone

Da Dbdquo H TR AHb TB Tc MW URF RfC

(cms) (cnis) (atm-mmol) (degC) (calmol) (degK) (degK) (gmol) (^gm)- (mgm)

1 720E-02 1 820E-06 1 184E-02 1 25 1 8288 1 39440 1 62020 1 16583 1 59E-06 1 60E-01 1

J

AppxB-5PCExls 2 of 3 - 982009

AR100321

APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

T

(sec)

Source-building

separation

LT

bull (cm)

Stratum A soil

air-filled porosity

Oa (cmcm)

Stratum B - soil air-filled porosity

ea (cmcm)

Stratum C soil

air-filled porosity

ea= - (cmcm)

Stratum A effective total fluid

saturation

sbdquo (cmcm)

Stratum A soil

intrinsic permeability

ki (cm)

Stratum A soil

relative air permeability

- ^ g

(cm)

Stratum A soil

effective vapor permeability

kv (cm)

Floor-wall

seam perimeter

^crack

(cm)

Soil gas

cone

(ngm)

BIdg venfilation

rate

Qbuildins

bull (cms)

bull bull

1 946E+08

Area of enclosed

space below grade

AB

(cm)

1

bullCrack-to-total

area ratio

1 (unitless)

0284 1

Crack bull depth below grade

Zcrack

(cm) -

0284 1

Enthalpy of vaporization at bull

ave soil temperature

bull A H V TS

(calmol)

0284

Henrys law constant at

ave soil temperature

HTS (atm-mmol)

0184

-Henrys law constant at

ave soil temperature

HTS

(unitless)

1 596E-09

Vapor viscosity at

ave soil temperature

HTS

(gcm-s)

0901

Stratum A

effective diffusion

coefficient bull D = bull

(cms)

537E-09

Stratum B

effective diffusion

coefficient

D--B (cms)

35357 1

Stratum C

effective diffusion bull

coefficient

D-c (crris)

149E+05

Total overall

effective bulldiffusion coefficient

DT

(cms)

440E+06 1

Difftjsion path

length

U (cm)

1 787E+07

Convection path

length

bull Lp

(cm)

4 49E-05

Source vapor cone

^source

(ngm)

15 1

Crack radius

Tcrack

(cm)

9528 1

Average vapor

flow rate intobldg

Qsoil (cms)

908E-03

Crack effective diffusion

coefficient pcrack

bull ( c m s ) bull

387E-01

Area of crack

Abdquoack (cm)

1 176E-04

Exponent of equivalent foundafion

Peclet number

exp(Pe)

(unitless)

bull

1 15-

1 END

149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08

727E-03

Infinite source indoor

attenuation coefficient

a

(unitless)

108E-05

OOOE+00

Infinite source

bIdg cone

Cburldtng

(Mgm)

161 E+00

OOOE+00 1

Unit risk

factor

URF

(ugm)-

59E-06 1

727E-03

Reference cone

RfC (mgm)

60E-01

1 1

Appx B-5 PCExls 3 of 3 982009

AR100322

APPENDIX B-6-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ersion31 0204

Reset to Defaults

t

Soil Gas Concentration Data ENTER

Chemical CAS No

(numbers only

no dashes)

79016

ENTER ENTER Soil Soil gas gas

cone OR cone C C -

bull (ngm) (ppmv)

782E+03

Chemical

Trichloroethylene

MORE ENTER Depth

below grade to bottom-

of enclosed space floor

LF

(cm)

ENTER

Soil gas sarnpling

depth below grade

U (cm)

ENTER

Average soil

temperature Ts

(degC)

1 15 1 15 t 125

ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e

(cm) (cm) (cm)

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estimate OR permeability soil vapor

permeability)

k (cm)

bull S L 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil bull-Parameters

ENTER Stratum A

soil dry bulk density

P b -

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Stratum A bull

soilwaterrfilled porosity

(cmcm) bull

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

bull P ^ (gcm)

ENTER Stratum B soil total

porosity

nlaquo

(unitless) -

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS bull soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor

width W B

(cm)

ENTER

Enclosed space height

H B bull

( c m ) bull

ENTER

Floor-wall seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bIdg OR

Leave blank to calculc

Qsoil

(Lm) -

Appx B-6 TCExIs 1 of 3 982009

A

AR100323

APPENDIX B-6-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight

Da Dbdquo H TR AH^b TB TC MW

Unit risk Reference

factor cone URF RfC

(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)

1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1

Appx B-6 TCExIs 2 of 3 982009

AR100324

APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

(sec)

Source-building

separation LT

(cm)

Stratum A soil

air-filled porosity

bull ea (cmcm)

Stratum B Soil

air-fllled porosity

e^ bull (cmcm)

Stratum C soil

air-filled porosity

(cmcm)

StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air

saturation permeability permeability

S|e k krg (cmcm) (cm) (cm)

Stratum A Floor-soil wall BIdg

effective vapor seam Soil ventilafion permeability perimeter gas rate

k^ bull Xack c o n e Qbuildins

(cm) (cm) (ngm) (cms)

946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |

Area of enclosed

space below grade

AB

(cm)

Ciack- to-total

area ratio

1 (unitless)

Crack depth below grade

Zcrack

(cm)

Enthalpy of vaporization at

ave soil temperature

A H J S

(calmol)

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law bull constant at

ave soil temperature

HTS

(unitless)

Vapor viscosity at

ave soil temperature

|JTS

(gcm^s)

Stratum A

effective diffusion

coefficient

(cms)

Stratum B

effective -diffusion

coefficient

D=B (cms)

Stratum ^ C effective diffusion

coefficient

D=c (cms)

Total overall

effective diffusion

coefficient

DT

(cms)

I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03

Diffusion path

length

Li (cm) bull

Convection bull path

length

Lp

(cm)

Source vapor cone bull

^source

(ngm)

Crack radius

rcrack

(cm)

Average vapor

- flow rate intobldg

Qsoil

(cms)

Crack effective diffusion

bull coefficient Qcrack

(cms)

Area of crack

^crack

(cm)

Exponent of equivalent foundation

Peclet bull number

exp(Pe)

(unitless)

bull bull

1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07

Infinite source Indoor

attenuation coefficient

a

(unitless)

108E-05

Infinite source

bIdg concgt

^building

(ngm)

844E-02

Unit risk

factor

URF

(ngm)-

Reference cone

RfC

(mgm)

1 1E-04 1 40E-02 1

END

Appx B-6 TCExIs 3 of 3 982009

AR100325

Office of Waste Management 1356 Hansford Street

Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256

West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director

ORDER

ISSUED UNDER THE

HAZARDOUS WASTE MANAGEMENT ACT

CHAPTER 22 ARTICLE 18

OF THE WEST VIRGINIA CODE^ AS AMENDED

y Order Number HW-011-80

To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704

ATTEMTION MREDARMON

Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull

AR100326

ViWJ011-laquo9 PageNunil)er2

BASIS FOR ORDER

As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following

A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^

B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator

C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities

0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94

^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement

P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following

1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater

2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was

^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment

CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable

CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order

AR100327

H W - 0 1 1 - 9 9 Page Number 3

REQUIREMENTS OF ORDER

Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows

1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^

2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore

remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling

GENERAL PROVaiONS

1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order

2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order

3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order

Effective Date

Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief

Wt T 1 V Oflice of Waste Management

AR100328

^ ^ S I S

^wmmmmamn

AR100329

Page 45: SDMS DocID 2121999 · International Enterprises Corp. building (Coyne Building), which is located at 1111 Vernon Street, Westmoreland District, Wayne County, West Virginia. The following

APPENDIX B-5-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

T

(sec)

Source-building

separation

LT

bull (cm)

Stratum A soil

air-filled porosity

Oa (cmcm)

Stratum B - soil air-filled porosity

ea (cmcm)

Stratum C soil

air-filled porosity

ea= - (cmcm)

Stratum A effective total fluid

saturation

sbdquo (cmcm)

Stratum A soil

intrinsic permeability

ki (cm)

Stratum A soil

relative air permeability

- ^ g

(cm)

Stratum A soil

effective vapor permeability

kv (cm)

Floor-wall

seam perimeter

^crack

(cm)

Soil gas

cone

(ngm)

BIdg venfilation

rate

Qbuildins

bull (cms)

bull bull

1 946E+08

Area of enclosed

space below grade

AB

(cm)

1

bullCrack-to-total

area ratio

1 (unitless)

0284 1

Crack bull depth below grade

Zcrack

(cm) -

0284 1

Enthalpy of vaporization at bull

ave soil temperature

bull A H V TS

(calmol)

0284

Henrys law constant at

ave soil temperature

HTS (atm-mmol)

0184

-Henrys law constant at

ave soil temperature

HTS

(unitless)

1 596E-09

Vapor viscosity at

ave soil temperature

HTS

(gcm-s)

0901

Stratum A

effective diffusion

coefficient bull D = bull

(cms)

537E-09

Stratum B

effective diffusion

coefficient

D--B (cms)

35357 1

Stratum C

effective diffusion bull

coefficient

D-c (crris)

149E+05

Total overall

effective bulldiffusion coefficient

DT

(cms)

440E+06 1

Difftjsion path

length

U (cm)

1 787E+07

Convection path

length

bull Lp

(cm)

4 49E-05

Source vapor cone

^source

(ngm)

15 1

Crack radius

Tcrack

(cm)

9528 1

Average vapor

flow rate intobldg

Qsoil (cms)

908E-03

Crack effective diffusion

coefficient pcrack

bull ( c m s ) bull

387E-01

Area of crack

Abdquoack (cm)

1 176E-04

Exponent of equivalent foundafion

Peclet number

exp(Pe)

(unitless)

bull

1 15-

1 END

149E+05 010 1 474E+01 1 727E-03 354E+03 1 104E+08

727E-03

Infinite source indoor

attenuation coefficient

a

(unitless)

108E-05

OOOE+00

Infinite source

bIdg cone

Cburldtng

(Mgm)

161 E+00

OOOE+00 1

Unit risk

factor

URF

(ugm)-

59E-06 1

727E-03

Reference cone

RfC (mgm)

60E-01

1 1

Appx B-5 PCExls 3 of 3 982009

AR100322

APPENDIX B-6-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ersion31 0204

Reset to Defaults

t

Soil Gas Concentration Data ENTER

Chemical CAS No

(numbers only

no dashes)

79016

ENTER ENTER Soil Soil gas gas

cone OR cone C C -

bull (ngm) (ppmv)

782E+03

Chemical

Trichloroethylene

MORE ENTER Depth

below grade to bottom-

of enclosed space floor

LF

(cm)

ENTER

Soil gas sarnpling

depth below grade

U (cm)

ENTER

Average soil

temperature Ts

(degC)

1 15 1 15 t 125

ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e

(cm) (cm) (cm)

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estimate OR permeability soil vapor

permeability)

k (cm)

bull S L 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil bull-Parameters

ENTER Stratum A

soil dry bulk density

P b -

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Stratum A bull

soilwaterrfilled porosity

(cmcm) bull

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

bull P ^ (gcm)

ENTER Stratum B soil total

porosity

nlaquo

(unitless) -

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS bull soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor

width W B

(cm)

ENTER

Enclosed space height

H B bull

( c m ) bull

ENTER

Floor-wall seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bIdg OR

Leave blank to calculc

Qsoil

(Lm) -

Appx B-6 TCExIs 1 of 3 982009

A

AR100323

APPENDIX B-6-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight

Da Dbdquo H TR AH^b TB TC MW

Unit risk Reference

factor cone URF RfC

(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)

1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1

Appx B-6 TCExIs 2 of 3 982009

AR100324

APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

(sec)

Source-building

separation LT

(cm)

Stratum A soil

air-filled porosity

bull ea (cmcm)

Stratum B Soil

air-fllled porosity

e^ bull (cmcm)

Stratum C soil

air-filled porosity

(cmcm)

StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air

saturation permeability permeability

S|e k krg (cmcm) (cm) (cm)

Stratum A Floor-soil wall BIdg

effective vapor seam Soil ventilafion permeability perimeter gas rate

k^ bull Xack c o n e Qbuildins

(cm) (cm) (ngm) (cms)

946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |

Area of enclosed

space below grade

AB

(cm)

Ciack- to-total

area ratio

1 (unitless)

Crack depth below grade

Zcrack

(cm)

Enthalpy of vaporization at

ave soil temperature

A H J S

(calmol)

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law bull constant at

ave soil temperature

HTS

(unitless)

Vapor viscosity at

ave soil temperature

|JTS

(gcm^s)

Stratum A

effective diffusion

coefficient

(cms)

Stratum B

effective -diffusion

coefficient

D=B (cms)

Stratum ^ C effective diffusion

coefficient

D=c (cms)

Total overall

effective diffusion

coefficient

DT

(cms)

I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03

Diffusion path

length

Li (cm) bull

Convection bull path

length

Lp

(cm)

Source vapor cone bull

^source

(ngm)

Crack radius

rcrack

(cm)

Average vapor

- flow rate intobldg

Qsoil

(cms)

Crack effective diffusion

bull coefficient Qcrack

(cms)

Area of crack

^crack

(cm)

Exponent of equivalent foundation

Peclet bull number

exp(Pe)

(unitless)

bull bull

1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07

Infinite source Indoor

attenuation coefficient

a

(unitless)

108E-05

Infinite source

bIdg concgt

^building

(ngm)

844E-02

Unit risk

factor

URF

(ngm)-

Reference cone

RfC

(mgm)

1 1E-04 1 40E-02 1

END

Appx B-6 TCExIs 3 of 3 982009

AR100325

Office of Waste Management 1356 Hansford Street

Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256

West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director

ORDER

ISSUED UNDER THE

HAZARDOUS WASTE MANAGEMENT ACT

CHAPTER 22 ARTICLE 18

OF THE WEST VIRGINIA CODE^ AS AMENDED

y Order Number HW-011-80

To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704

ATTEMTION MREDARMON

Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull

AR100326

ViWJ011-laquo9 PageNunil)er2

BASIS FOR ORDER

As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following

A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^

B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator

C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities

0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94

^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement

P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following

1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater

2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was

^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment

CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable

CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order

AR100327

H W - 0 1 1 - 9 9 Page Number 3

REQUIREMENTS OF ORDER

Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows

1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^

2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore

remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling

GENERAL PROVaiONS

1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order

2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order

3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order

Effective Date

Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief

Wt T 1 V Oflice of Waste Management

AR100328

^ ^ S I S

^wmmmmamn

AR100329

Page 46: SDMS DocID 2121999 · International Enterprises Corp. building (Coyne Building), which is located at 1111 Vernon Street, Westmoreland District, Wayne County, West Virginia. The following

APPENDIX B-6-A DATA ENTRY SHEET

Coyne Textile Services - Huntington West Virginia

SG-ADV ersion31 0204

Reset to Defaults

t

Soil Gas Concentration Data ENTER

Chemical CAS No

(numbers only

no dashes)

79016

ENTER ENTER Soil Soil gas gas

cone OR cone C C -

bull (ngm) (ppmv)

782E+03

Chemical

Trichloroethylene

MORE ENTER Depth

below grade to bottom-

of enclosed space floor

LF

(cm)

ENTER

Soil gas sarnpling

depth below grade

U (cm)

ENTER

Average soil

temperature Ts

(degC)

1 15 1 15 t 125

ENTER ENTER ENTER Totalsmust addup to value of Ls (cell F24

Thickness Thickness Thickness of soil of soil

of soil stratum B stratum C stratumA bull (Enter value or 0) (Enter value or 0) bull hf l hB h e

(cm) (cm) (cm)

15 1 1

ENTER Soil

stratum A SCS

soil type

ENTER

User-defined stratum A soil vapor

(used to estimate OR permeability soil vapor

permeability)

k (cm)

bull S L 1 1

MORE ENTER

Stratum A SCS

soil type

Lookup Soil bull-Parameters

ENTER Stratum A

soil dry bulk density

P b -

(gcm)

ENTER Stratum A soil total porosity

n

(unitless)

ENTER Stratum A bull

soilwaterrfilled porosity

(cmcm) bull

ENTER Stratum B

SCS soil type

Lookup Soil Parameters

ENTER Stratum B

soil dry bulk density

bull P ^ (gcm)

ENTER Stratum B soil total

porosity

nlaquo

(unitless) -

ENTER Stratum B

soil water-filled porosity

(cmcm)

ENTER Stratum C

SCS bull soil type

Lookup Soil Parameters

SL 162 0387 0103 SL 162 0387 0103 SL

MORE

ENTER Enclosed

space floor

thickness

Lcrack

(cm)

ENTER

Soil-bldg pressure

differential AP

(gcm-s)

ENTER Enclosed

space floor

length

LB

(cm)

ENTER Enclosed

space floor

width W B

(cm)

ENTER

Enclosed space height

H B bull

( c m ) bull

ENTER

Floor-wall seam crack

width w

(cm)

ENTER

Indoor air exchange

rate ER

(1h)

10 40 8839 8839 244 01 083

ENTER Average vapor

flow rate into bIdg OR

Leave blank to calculc

Qsoil

(Lm) -

Appx B-6 TCExIs 1 of 3 982009

A

AR100323

APPENDIX B-6-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight

Da Dbdquo H TR AH^b TB TC MW

Unit risk Reference

factor cone URF RfC

(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)

1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1

Appx B-6 TCExIs 2 of 3 982009

AR100324

APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

(sec)

Source-building

separation LT

(cm)

Stratum A soil

air-filled porosity

bull ea (cmcm)

Stratum B Soil

air-fllled porosity

e^ bull (cmcm)

Stratum C soil

air-filled porosity

(cmcm)

StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air

saturation permeability permeability

S|e k krg (cmcm) (cm) (cm)

Stratum A Floor-soil wall BIdg

effective vapor seam Soil ventilafion permeability perimeter gas rate

k^ bull Xack c o n e Qbuildins

(cm) (cm) (ngm) (cms)

946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |

Area of enclosed

space below grade

AB

(cm)

Ciack- to-total

area ratio

1 (unitless)

Crack depth below grade

Zcrack

(cm)

Enthalpy of vaporization at

ave soil temperature

A H J S

(calmol)

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law bull constant at

ave soil temperature

HTS

(unitless)

Vapor viscosity at

ave soil temperature

|JTS

(gcm^s)

Stratum A

effective diffusion

coefficient

(cms)

Stratum B

effective -diffusion

coefficient

D=B (cms)

Stratum ^ C effective diffusion

coefficient

D=c (cms)

Total overall

effective diffusion

coefficient

DT

(cms)

I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03

Diffusion path

length

Li (cm) bull

Convection bull path

length

Lp

(cm)

Source vapor cone bull

^source

(ngm)

Crack radius

rcrack

(cm)

Average vapor

- flow rate intobldg

Qsoil

(cms)

Crack effective diffusion

bull coefficient Qcrack

(cms)

Area of crack

^crack

(cm)

Exponent of equivalent foundation

Peclet bull number

exp(Pe)

(unitless)

bull bull

1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07

Infinite source Indoor

attenuation coefficient

a

(unitless)

108E-05

Infinite source

bIdg concgt

^building

(ngm)

844E-02

Unit risk

factor

URF

(ngm)-

Reference cone

RfC

(mgm)

1 1E-04 1 40E-02 1

END

Appx B-6 TCExIs 3 of 3 982009

AR100325

Office of Waste Management 1356 Hansford Street

Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256

West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director

ORDER

ISSUED UNDER THE

HAZARDOUS WASTE MANAGEMENT ACT

CHAPTER 22 ARTICLE 18

OF THE WEST VIRGINIA CODE^ AS AMENDED

y Order Number HW-011-80

To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704

ATTEMTION MREDARMON

Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull

AR100326

ViWJ011-laquo9 PageNunil)er2

BASIS FOR ORDER

As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following

A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^

B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator

C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities

0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94

^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement

P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following

1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater

2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was

^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment

CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable

CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order

AR100327

H W - 0 1 1 - 9 9 Page Number 3

REQUIREMENTS OF ORDER

Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows

1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^

2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore

remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling

GENERAL PROVaiONS

1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order

2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order

3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order

Effective Date

Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief

Wt T 1 V Oflice of Waste Management

AR100328

^ ^ S I S

^wmmmmamn

AR100329

Page 47: SDMS DocID 2121999 · International Enterprises Corp. building (Coyne Building), which is located at 1111 Vernon Street, Westmoreland District, Wayne County, West Virginia. The following

APPENDIX B-6-B CHEMICAL PROPERTIES SHEET

Coyne Textile Services - Huntington West Virginia

bull Henrys Henrys Enthalpy of law constant law constant vaporization at Normal

Diffusivity Diffusivity at reference reference the normal boiling Critical Molecular in air in water temperature temper^ature boiling point point temperature weight

Da Dbdquo H TR AH^b TB TC MW

Unit risk Reference

factor cone URF RfC

(cms) (cms) (atm-mmol) CO (calmol) (degK) (degK) (gmol) (ngm)- (mgm)

1 790E-02 1 910E-06 1 103E-02 1 25 1 7505 1 36036 1 54420 1 13139 1 11E-04 1 40E-02 1

Appx B-6 TCExIs 2 of 3 982009

AR100324

APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

(sec)

Source-building

separation LT

(cm)

Stratum A soil

air-filled porosity

bull ea (cmcm)

Stratum B Soil

air-fllled porosity

e^ bull (cmcm)

Stratum C soil

air-filled porosity

(cmcm)

StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air

saturation permeability permeability

S|e k krg (cmcm) (cm) (cm)

Stratum A Floor-soil wall BIdg

effective vapor seam Soil ventilafion permeability perimeter gas rate

k^ bull Xack c o n e Qbuildins

(cm) (cm) (ngm) (cms)

946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |

Area of enclosed

space below grade

AB

(cm)

Ciack- to-total

area ratio

1 (unitless)

Crack depth below grade

Zcrack

(cm)

Enthalpy of vaporization at

ave soil temperature

A H J S

(calmol)

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law bull constant at

ave soil temperature

HTS

(unitless)

Vapor viscosity at

ave soil temperature

|JTS

(gcm^s)

Stratum A

effective diffusion

coefficient

(cms)

Stratum B

effective -diffusion

coefficient

D=B (cms)

Stratum ^ C effective diffusion

coefficient

D=c (cms)

Total overall

effective diffusion

coefficient

DT

(cms)

I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03

Diffusion path

length

Li (cm) bull

Convection bull path

length

Lp

(cm)

Source vapor cone bull

^source

(ngm)

Crack radius

rcrack

(cm)

Average vapor

- flow rate intobldg

Qsoil

(cms)

Crack effective diffusion

bull coefficient Qcrack

(cms)

Area of crack

^crack

(cm)

Exponent of equivalent foundation

Peclet bull number

exp(Pe)

(unitless)

bull bull

1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07

Infinite source Indoor

attenuation coefficient

a

(unitless)

108E-05

Infinite source

bIdg concgt

^building

(ngm)

844E-02

Unit risk

factor

URF

(ngm)-

Reference cone

RfC

(mgm)

1 1E-04 1 40E-02 1

END

Appx B-6 TCExIs 3 of 3 982009

AR100325

Office of Waste Management 1356 Hansford Street

Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256

West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director

ORDER

ISSUED UNDER THE

HAZARDOUS WASTE MANAGEMENT ACT

CHAPTER 22 ARTICLE 18

OF THE WEST VIRGINIA CODE^ AS AMENDED

y Order Number HW-011-80

To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704

ATTEMTION MREDARMON

Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull

AR100326

ViWJ011-laquo9 PageNunil)er2

BASIS FOR ORDER

As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following

A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^

B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator

C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities

0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94

^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement

P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following

1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater

2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was

^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment

CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable

CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order

AR100327

H W - 0 1 1 - 9 9 Page Number 3

REQUIREMENTS OF ORDER

Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows

1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^

2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore

remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling

GENERAL PROVaiONS

1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order

2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order

3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order

Effective Date

Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief

Wt T 1 V Oflice of Waste Management

AR100328

^ ^ S I S

^wmmmmamn

AR100329

Page 48: SDMS DocID 2121999 · International Enterprises Corp. building (Coyne Building), which is located at 1111 Vernon Street, Westmoreland District, Wayne County, West Virginia. The following

APPENDIX B-6-C INTERMEDIATE CALCULATIONS SHEET

Coyne Textile Services - Huntington West Virginia

Exposure duration

(sec)

Source-building

separation LT

(cm)

Stratum A soil

air-filled porosity

bull ea (cmcm)

Stratum B Soil

air-fllled porosity

e^ bull (cmcm)

Stratum C soil

air-filled porosity

(cmcm)

StratumA StratumA StratumA effective soil soil total fluid intrinsic relafive air

saturation permeability permeability

S|e k krg (cmcm) (cm) (cm)

Stratum A Floor-soil wall BIdg

effective vapor seam Soil ventilafion permeability perimeter gas rate

k^ bull Xack c o n e Qbuildins

(cm) (cm) (ngm) (cms)

946E+08 I 1 I 0-284 0284 0284 0184 596E-09 I 0901 537E-09 I 35357 j 782E+03 | 440E+06 bull |

Area of enclosed

space below grade

AB

(cm)

Ciack- to-total

area ratio

1 (unitless)

Crack depth below grade

Zcrack

(cm)

Enthalpy of vaporization at

ave soil temperature

A H J S

(calmol)

Henrys law constant at

ave soil temperature

HTS

(atm-mmol)

Henrys law bull constant at

ave soil temperature

HTS

(unitless)

Vapor viscosity at

ave soil temperature

|JTS

(gcm^s)

Stratum A

effective diffusion

coefficient

(cms)

Stratum B

effective -diffusion

coefficient

D=B (cms)

Stratum ^ C effective diffusion

coefficient

D=c (cms)

Total overall

effective diffusion

coefficient

DT

(cms)

I 787E+07 I 449E-05 | bull 15 | 8526 547E-03 234E-01 176E-04 I 798E-03 | OOOE+00 j OOOE+00 | 798E^03

Diffusion path

length

Li (cm) bull

Convection bull path

length

Lp

(cm)

Source vapor cone bull

^source

(ngm)

Crack radius

rcrack

(cm)

Average vapor

- flow rate intobldg

Qsoil

(cms)

Crack effective diffusion

bull coefficient Qcrack

(cms)

Area of crack

^crack

(cm)

Exponent of equivalent foundation

Peclet bull number

exp(Pe)

(unitless)

bull bull

1 15 1 782E+03 1 bull 010 1 474E+01 798E-03 354E+03 1 203E+07

Infinite source Indoor

attenuation coefficient

a

(unitless)

108E-05

Infinite source

bIdg concgt

^building

(ngm)

844E-02

Unit risk

factor

URF

(ngm)-

Reference cone

RfC

(mgm)

1 1E-04 1 40E-02 1

END

Appx B-6 TCExIs 3 of 3 982009

AR100325

Office of Waste Management 1356 Hansford Street

Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256

West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director

ORDER

ISSUED UNDER THE

HAZARDOUS WASTE MANAGEMENT ACT

CHAPTER 22 ARTICLE 18

OF THE WEST VIRGINIA CODE^ AS AMENDED

y Order Number HW-011-80

To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704

ATTEMTION MREDARMON

Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull

AR100326

ViWJ011-laquo9 PageNunil)er2

BASIS FOR ORDER

As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following

A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^

B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator

C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities

0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94

^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement

P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following

1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater

2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was

^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment

CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable

CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order

AR100327

H W - 0 1 1 - 9 9 Page Number 3

REQUIREMENTS OF ORDER

Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows

1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^

2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore

remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling

GENERAL PROVaiONS

1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order

2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order

3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order

Effective Date

Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief

Wt T 1 V Oflice of Waste Management

AR100328

^ ^ S I S

^wmmmmamn

AR100329

Page 49: SDMS DocID 2121999 · International Enterprises Corp. building (Coyne Building), which is located at 1111 Vernon Street, Westmoreland District, Wayne County, West Virginia. The following

Office of Waste Management 1356 Hansford Street

Charleston WV 25301-1401 (304) 558-2505 (304) 558-0256

West Virginia Division of Environmental Protection Cecil R Undeiwood Michsd P Miano Oovemor Director

ORDER

ISSUED UNDER THE

HAZARDOUS WASTE MANAGEMENT ACT

CHAPTER 22 ARTICLE 18

OF THE WEST VIRGINIA CODE^ AS AMENDED

y Order Number HW-011-80

To Mr Ed Annon Coyne Texble Servicas 1111 Vemon Street Huntington WestVirolnla 25704

ATTEMTION MREDARMON

Tills Order is issued tty the Director of the West Vliglnia Division of Environmental Protection through his authorized representative the Chief of the Office of Waste Management under the authority of the West Virginia Code as amended Chapter 22 Ariide 18 Sections 14 and 15 to Coyne Textile Services Inc (hereinafter CTS) The Director has adopted and Incorporatad tgty reference the applicable sections of 40 CFR parts 260 thiltgtugh 279 into the Hazardous Waste Management Rule (formerty 47 CSR 35 and hereinafter 33 CSR 20) bullbull

AR100326

ViWJ011-laquo9 PageNunil)er2

BASIS FOR ORDER

As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following

A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^

B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator

C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities

0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94

^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement

P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following

1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater

2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was

^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment

CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable

CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order

AR100327

H W - 0 1 1 - 9 9 Page Number 3

REQUIREMENTS OF ORDER

Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows

1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^

2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore

remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling

GENERAL PROVaiONS

1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order

2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order

3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order

Effective Date

Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief

Wt T 1 V Oflice of Waste Management

AR100328

^ ^ S I S

^wmmmmamn

AR100329

Page 50: SDMS DocID 2121999 · International Enterprises Corp. building (Coyne Building), which is located at 1111 Vernon Street, Westmoreland District, Wayne County, West Virginia. The following

ViWJ011-laquo9 PageNunil)er2

BASIS FOR ORDER

As the result of a Compliance Evaluation Inspection (hereinafter CEI) and Compliance Schedule Evaluation Reports and In support of this Order the Chief hereby finds the following

A) CTS owns and operates a facility forthe cleaning of industrial laundry at a site located at 1111 ^ Vemon Street in Huntington West Vn^^nia (hereinafter the sSte)^

B) As a result of the construction and operation of a wastewater treatment sludge tank CTS generates hazardous waste In amounts sufficient to classify it as a L^ige Quantity Generator

C) On September 16 1994 CTS entered into Consent Order HW-395-94 which provided an agreed schedule and framework for site assessment and riemedial activities

0) On August 231996 authorized representatives ofttra Chief conducted a CEI and a Compliance Schedule Evaluation inspection at CTS to assess ctirrent compliance with 33 CSR 20 and to assess the static of the site clean-up and monitoring plan ordered by Order HW-395-94

^ During the referenced Inspection reports authorized representatives of the Chief cited ten violations of 33 CSR 20 and one violation of Order HW-395-84 Nine of the eleven dted violations were addressed fay the Notice of Violation (hereinafter NOV) attached to the referenced Inspection reports The two unaddressed violations on ttie NOV were referred for enforcement

P) On October 29 1997 authorized representatives of the Chief conducted a Compliance Schedule Evaluation at CTS and noted additional and repeat vblations of 33 CSR 20 The violafions addressed tiy this Order are the following

1) The fedfity has failed to no for hazatdous waste activity The violation derives from CTSs discoveiy waste sampOng and CIOSUIB of a concrete pit (sump) containing hazardous waste tetrachloroethylene also known as perdiloroethylene This sump contained a RCRA hazardous waste and was In violation of 40 CFR Section 26212 as referenced by 33 CSR 20 The Chief believes that visual inspection of the sump is insufficient to ascertain if perchkirettiylene has mtgntted through the concrete sump and into the underlying oil andor groundwater

2) CTS fiaDed to hplify ttta Chief or his authorized representatives at least 48 hours in advance of the site work conducted in December 1995 regarding the tiazardous waste removed from the sump Although this failure was not a technical violattoh of requirement 3D of Order HW-395-94 failure to notify the Chief of the discovery waste sampling and closure of the sump violated the spirit of Older HW-395-04 and the atmve dted regulation and was

^ in vtolatnn of Chapter 22 Aitkde 18 Section 14 of the Code whteh requires the submittal of a plan In the event that hazardous waste may have been released to the environment

CTS (fid however send the contents of the sump to a penniBed hazardous waste treabnem storage and disposal fac and visually examined the sump prior to fQGng it with concrete Tbe Chief contends however that a visuai examjnafion atone carmot emure that a rslsase of hazardous waste has not occurred through the sump walls or floor tMcause concrete is not inipemheable

CTS has provided the Chief wAh a copy of a plan to ascertain the extent of any and all hazardous waste contamination from the tetrachtorpethylene pH atthe site in compliance with Chapter 22 Article 18 Section 14 of the Code The Chief will approve the plan as of the effective date^of this Order

AR100327

H W - 0 1 1 - 9 9 Page Number 3

REQUIREMENTS OF ORDER

Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows

1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^

2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore

remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling

GENERAL PROVaiONS

1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order

2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order

3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order

Effective Date

Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief

Wt T 1 V Oflice of Waste Management

AR100328

^ ^ S I S

^wmmmmamn

AR100329

Page 51: SDMS DocID 2121999 · International Enterprises Corp. building (Coyne Building), which is located at 1111 Vernon Street, Westmoreland District, Wayne County, West Virginia. The following

H W - 0 1 1 - 9 9 Page Number 3

REQUIREMENTS OF ORDER

Now therefore in accordance wfth Chapter 22 Article 18 Secfions 14 and 15 of the Code it is hereby agreed between the parties and ORDERED tiy the Chief as follows

1) Upon the effective date ofthis Order and for the vk)lations dted in t i ^ Order CTS agrees to an administrative isatllement of $500000 (five thousand dollare) CTS shall pay the administrative setUemmt of $S0(X) (fiva thousand dollais) to ttie West VIrginta Hazardous Waste Management Fund within fifteen days of the effective date of this Order ^

2) CTS shall enatt the approived ptan for the sampling of the |xt area wtthin forty-five days of the eiledive date of this Order and shall provide the environmental inspector with at least 48 hours advance notification prior to sampling andAor remedial activities pursuant to the plen Futore

remedial acSom to alddress contamtnaSon tram the pit if any shall be dependent on the resulte of this sampling

GENERAL PROVaiONS

1) The Chief resenres all lights and defenses which he may have pursuant to any legal authority as well as a right to raise as a basis for supporting such legal authority or defenses tacts other than those enumerated in ttte Basis for Order

2) CTS hereby wahes its rights to appeal this Order under the provisions of Chapter 22 Article 18 Section 20 of the Code Under this Order CTS agrees to undertake all actions required iiy the terms and condifions of this Order and consente to and will not contest ttte Chiefs jurisdiction regarding this Order However CTS does not admit to any tactual end legal determinetion made by the Chief in this Order and reseives ail rights and defenses available regarding Dabiilty and responsitjility in any proceedings regarcflng the tadlity other than proceedings either administrative or dvil to enforce this Order

3) This Order becomes effective on the dote Indicated and shall terminate upon notification from the Chtof that CTS has fulfilled the requirements as set forth In the Requirementa of Order

Effective Date

Authorized Representative f B Fwhith PE Coyne Textile Senrices Inc Chief

Wt T 1 V Oflice of Waste Management

AR100328

^ ^ S I S

^wmmmmamn

AR100329

Page 52: SDMS DocID 2121999 · International Enterprises Corp. building (Coyne Building), which is located at 1111 Vernon Street, Westmoreland District, Wayne County, West Virginia. The following

^ ^ S I S

^wmmmmamn

AR100329