PCS No. 04725A water-soluble granule containing 750 g/kgethametsulfuron methyl for control of certainbroad-leaved weeds in winter and springoilseed rape and fodder rape.

FOR PROFESSIONAL USE ONLYManufactured in the E.U.® Registered Trademark of E. I. du Pont de Nemours and Company

SAFETY PRECAUTIONSOperator protectionWhen using do not eat, drink or smokeEnvironmental ProtectionDo not contaminate ponds, waterways or ditches with chem-ical or used container.Do not contaminate water with the product or its container (Donot clean application equipment near surface water/Avoidcontamination via drains from farmyards and roads).Storage and DisposalDo not re-use container for any purpose and dispose of safelyDu Pont (UK) Limited, Crop Protection ProductsWedgwood Way, Stevenage, Herts. SG1 4QN. Tel: 00 44 1438 734450 or enquiry.agproducts@gbr.dupont.comEmergency Tel: 01 901 4670National Poisons information Service (24hrs) (IRL) 01 837 9964

Safety Information

SalsaHerbicidecontaining 750 g/kgethametsulfuron

Very toxic toaquatic life withlong lasting effects.Collect spillage.Dispose of contents / container to a licensed haz-ardous-waste disposal contractor or collectionsite except for triple rinsed empty clean contain-ers which can be disposed of as non-hazardouswaste.

To avoid risks to human health and the environ-ment, comply with the instructions for use

PCS No. 04725

Contents: 100 grams

Salsa®

OILSEED RAPE HERBICIDE

GROUP HERBICIDEB

WARNING

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PCS No. 04725A water-soluble granule containing750  g/kg ethametsulfuron methyl forcontrol of certain broad-leaved weedsin winter and spring oilseed rape andfodder rape.

Du Pont (UK) Limited, Crop Protection ProductsWedgwood Way, Stevenage, Herts. SG1 4QN. Tel: 00 44 1438 734450 or enquiry.agproducts@gbr.dupont.comEmergency Tel: 01 901 4670National Poisons information Service (24hrs)(IRL) 01 837 9964

® Registered Trademark of E. I. du Pont de Nemours and Company

Salsa®

OILSEED RAPE HERBICIDE

GROUP HERBICIDEB

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FOR PROFESSIONAL USE ONLY

SAFETY PRECAUTIONS

Operator protectionWhen using do not eat, drink or smoke

Environmental ProtectionDo not contaminate ponds, waterways or ditches with chemicalor used container.Do not contaminate water with the product or its container (Donot clean application equipment near surface water/Avoidcontamination via drains from farmyards and roads).

Storage and DisposalDo not re-use container for any purpose and dispose of safely

Manufactured in the E.U.

Safety InformationSalsaHerbicide containing 750 g/kgethametsulfuron

Very toxic to aquatic life with longlasting effects.Collect spillage.Dispose of contents / container to a licensed hazardous-waste disposal contractor or collection site except for triplerinsed empty clean containers which can be disposed ofas non-hazardous waste.

To avoid risks to human health and the environment, com-ply with the instructions for use

PCS No. 04725

WARNING

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FOR USE ONLY AS AN AGRICULTURAL HERBICIDE

Crop: Winter and Spring Oilseed rape and fodder rape

Maximum single dose: 25 g/ha

Maximum total dose: 25 g/ha

Latest time of application: 90 days pre harvest

Method of application: Tractor mounted / Trailedsprayer.Read the label before use. Using this product in amanner that is inconsistent with the label may be anoffence.

DIRECTIONS FOR USE

IMPORTANT: This information is approved as part of the Product Label. Allinstructions within this section must be read carefully in order to obtain safe andsuccessful use of this product.

Restrictions• SALSA should not be applied to any crop suffering from stress as a result of drought,

waterlogging, low temperatures, pest or disease attack, nutrient or lime deficiencyor other factors reducing crop growth.

• Due to the high level of activity of the herbicide, special care must be taken to avoid damageby drift onto broad-leaved plants outside the target area, or onto ponds, waterways orditches. Thorough cleansing of equipment is also very important - see below.

• Do not apply SALSA more than once to any oilseed rape crop.• Requirements or restrictions on other product labels must be adhered to when applied

to the same crop as SALSA. Contact your DuPont distributor for further information.

Weed controlSALSA contains ethametsulfuron methyl, a sulfonylurea (ALS inhibitor) herbicide andis most effective if applied when the weeds are small and actively growing. Goodspray cover of the weeds must be obtained for best results. Susceptible plants ceasegrowth almost immediately after application and symptoms can be seen about twoweeks after application. Weed control may be reduced when soil conditions are verydry. The susceptibility rating of the weeds in the following table refers to post-emergence application with good spray cover and growing conditions.

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S = susceptible

ResistanceThis product contains ethametsulfuron methyl, an ALS inhibitor, also classified by theHerbicide Resistance Action Committee as ‘Group B’.

When herbicides with the same mode of action are used repeatedly over several yearsin the same field, selection of resistant biotypes can take place. These can propagateand may become dominating. A weed species is considered resistant to a herbicideif it survives a correctly-applied treatment at the recommended dose. Development ofresistance within a weed species can be avoided or delayed by sequencing or tank-mixing with suitable products having a different mode of action. A strategy forpreventing and managing resistance should be adopted. The Weed Resistance Action

Committee has produced guidelines and copies are available from your distributor,crop adviser or product manufacturer.

To prevent the build-up of resistant plants, SALSA should not be used as a sole meansfor control of chickweed or mayweed. Where these are present, SALSA should beused only in tank-mixture or in sequence with herbicides with non-ALS modes ofaction. In addition, the use of cultural methods of control and non-ALS herbicideswithin the rotation will help lessen the risk of resistance development.

CropsSALSA can be used on all varieties of winter and spring oilseed rape and fodder rapebetween the growth stages given below.

DoseApply SALSA at 25 g/ha. An approved non-ionic adjuvant should be included at 100 ml per 100 litres of water (0.1% v/v).

TimingSALSA may be applied in the autumn or spring from the cotyledon up to and includingthe 8 leaf stage of crop growth.

Following cropsCereals may be sown in the same calendar year of harvest of an oilseed rape croptreated with SALSA. Cereals and maize, may be sown in the spring of the yearfollowing harvest.

NOIR

Weed species Plants at cotyledon -2 expanded true leaves

Charlock S

Chickweed, common S

Crane’s-bill, cut-leaved S

Crane’s-bill, dove’s foot S

Mayweed, scentless S

Shepherd’s purse S

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In the event of crop failure for any reason, wheat or barley can be planted. Prior tosowing, soil should be ploughed and cultivated to a depth of at least 15 cm.

Volume and applicationBEFORE USING SALSA, SPRAYING EQUIPMENT MUST BE CLEAN AND FREE FROMCONTAMINATION WITH OTHER PESTICIDES. Application should be made in 100-300 litres of water per hectare to give good spray cover of the weeds. The highervolume is recommended when crops are thick or weed growth is dense. Use aconventional field crop sprayer at a pressure of 2 - 3 bars and apply as a MEDIUMspray (as defined by BCPC). Care should be taken not to overlap spray swaths.

MixingQuarter fill the spray tank with clean water, start the agitation and add the requiredquantity of SALSA directly to the tank without prior creaming. Continue agitationwhile topping up the tank and while spraying.

CompatibilityTank-mix partners must only be used in accordance with their label warnings andrestrictions. When using SALSA in a tank-mix, always add SALSA to the spray tankfirst and ensure it is fully dispersed before adding the partner product. For furtherinformation contact your DuPont distributor.

Spray tank clean-out POOR CLEANOUT PRACTICES AND INSUFFICIENT WATER VOLUMES USED FOR THE

RINSE PROCEDURE MAY RESULT IN INADEQUATE REMOVAL OF PRODUCTDEPOSITS. SUBSEQUENT USE OF APPLICATION EQUIPMENT IN THESECIRCUMSTANCES MAY RESULT IN DAMAGE TO OTHER CROPS.

TO AVOID SUBSEQUENT DAMAGE TO OTHER CROPS, IMMEDIATELY AFTERSPRAYING SALSA THOROUGHLY CLEAN ALL SPRAY EQUIPMENT, INCLUDINGINSIDE AND OUTSIDE OF LID, USING THE FOLLOWING PROCEDURE:

1. Immediately after spraying, drain tank completely. Any contamination on theoutside of the spraying equipment should be removed by washing with clean water.

2. Rinse inside of tank with clean water and flush through boom and hoses using atleast one-tenth of the spray tank volume. Drain tank completely.

3. Half fill tank with clean water and add All Clear® Extra at the recommended rate.Agitate and then flush the boom and hoses with the cleaning solution. Top up withwater making sure the tank is completely full and allow to stand for 15 minutes withagitation. Again flush the boom and hoses and drain tank completely.

4. Nozzles and filters should be removed and cleaned separately with an All ClearExtra solution containing 50 ml of All Clear® Extra per 10 litres of water.

5. Rinse the tank with clean water and flush through the boom and hoses using atleast one-tenth of the spray tank volume. Drain tank completely.

6. Dispose of washings safely in accordance with local authority guidelines7. Do not spray onto sensitive crop or land intended for cropping with sensitive crop.

NOTE: If it is not possible to drain the tank completely, step 3 must be repeated beforegoing on to step 4.

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WarningEXTREME CARE SHOULD BE TAKEN TO AVOID DAMAGE BY DRIFT OF SPRAY ONTOBROAD-LEAVED PLANTS OUTSIDE THE TARGET AREA OR ONTO PONDS,WATERWAYS OR DITCHES. SPRAYING EQUIPMENT SHOULD NOT BE DRAINED ORFLUSHED ONTO LAND PLANTED WITH OR INTENDED FOR PLANTING WITH TREESOR CROPS OTHER THAN OILSEED RAPE

NOTICE TO BUYERAll goods supplied by us are of a high grade and we believe them to be suitable forany purpose for which we expressly supply them, but as we cannot exercise controlover their mixing or use, all conditions and warranties, statutory or otherwise, as tothe quality or fitness for any purpose of our goods are excluded and no responsibilitywill be accepted by us for any damage or injury whatsoever arising from their storage,handling, application or use.

® Registered Trademark of E. I. du Pont de Nemours and CompanyAll other trademarks are duly acknowledged

NOIR

Version 3.0 (replaces: Version 2.1)Revision Date 29.01.2015 Ref. 130000024006

SAFETY DATA SHEET according to Regulation (EC) No 1907/2006and 453/2010

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifierProduct name : SALSA® 75 WG

Synonyms : B10062112DPX-A7881 75WG

1.2. Relevant identified uses of the substance or mixture and uses advised againstUse of the Substance/Mixture : Herbicide

1.3. Details of the supplier of the safety data sheetCompany : Du Pont (UK) Limited - Wedgwood Way

Stevenage, Herts. SG1 4QN - United Kingdom

Telephone : +44 (0) 1438 734 000

E-mail address : sds-support@che.dupont.com

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1.4. Emergency telephone numberEmergency telephone number : +(353)-19014670

: Poison Centres may only possess informationrequired for products in accordance withRegulation (EC) No 1272/2008 and nationallegislation.

SECTION 2: Hazards identification

2.1. Classification of the substance or mixtureAcute aquatic toxicity, Category 1 H400: Very toxic to aquatic life.Chronic aquatic toxicity, Category 1 H410: Very toxic to aquatic life with long lasting

effects.

Dangerous for the environment R50/53: Very toxic to aquatic organisms, may causelong-term adverse effects in the aquaticenvironment.

2.2. Label elements WarningH410 Very toxic to aquatic life with long lasting effects.

Special labelling of certain substances and mixturesEUH401: To avoid risks to human health and the environment,comply with the instructions for use.,

P391 Collect spillage.P501 Dispose of contents/container to a licensed hazardous-waste disposal contractor or

collection site except for empty clean containers which can be disposed of as non-hazardous waste.

SP 1 Do not contaminate water with the product or its container (Do not clean applicationequipment near surface water/Avoid contamination via drains from farmyards androads).

2.3. Other hazardsThis mixture contains no substance considered to be persistent, bioaccumulating andtoxic (PBT). This mixture contains no substance considered to be very persistent and verybioaccumulating (vPvB).

SECTION 3: Composition/information on ingredients

3.1. SubstancesNot applicable

3.2. MixturesRegistration number Classification

according toDirective 67/548/EEC

Classification accordingto Regulation (EU)1272/2008 (CLP)

Concentration(% w/w)

Environment

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Ethametsulfuron methyl (CAS-No.97780-06-8)

Sodium dioctyl sulfosuccinate (CAS-No.577-11-7) (EC-No.209-406-4)

The above products are REACH compliant; Registration number(s) may not be providedbecause substance(s) are exempted, not yet registered under REACH or are registeredunder another regulatory process (biocide uses, plant protection products), etc.

For the full text of the R-phrases mentioned in this Section, see Section 16.For the full text of the H-Statements mentioned in this Section, see Section 16.

SECTION 4: First aid measures

4.1. Description of first aid measuresGeneral advice:

Never give anything by mouth to an unconscious person. For specialist advicecontact the National Poisons Information Service. Healthcare Professionals: (01)

809 2566 or (01) 837 9964 (24h per day – 365 days per year). Public PoisonsInformation Line: (01) 809 2166 (8am-10pm).

Inhalation:Move to fresh air. Consult a physician after significant exposure. Artificialrespiration and/or oxygen may be necessary.

Skin contact:Take off contaminated clothing and shoes immediately. Wash off immediately withsoap and plenty of water. In the case of skin irritation or allergic reactions see aphysician. Wash contaminated clothing before re-use.

Eye contact:If easy to do, remove contact lens, if worn. Hold eye open and rinse slowly andgently with water for 15-20 minutes. If eye irritation persists, consult a specialist.

Ingestion:Obtain medical attention. DO NOT induce vomiting unless directed to do so by aphysician or poison control center. If victim is conscious: Rinse mouth with water.

4.2. Most important symptoms and effects, both acute and delayed Symptoms:

No cases of human intoxication are known and the symptoms of experimentalintoxication are not known.

Xi;R36N;R50/53

Eye Irrit. 2; H319Aquatic Acute 1; H400Aquatic Chronic 1; H410

75 %

Xn;R22Xi;R37/38Xi;R41

Acute Tox. 4; H302Skin Irrit. 2; H315Eye Dam. 1; H318STOT SE 3; H335

>= 1 - < 5 %

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4.3. Indication of any immediate medical attention and special treatment neededTreatment:

Treat symptomatically.

SECTION 5: Firefighting measures

5.1. Extinguishing mediaSuitable extinguishing media:

Water spray, Foam, Dry chemical, Carbon dioxide (CO2)

Extinguishing media which shall not be used for safety reasons:High volume water jet, (contamination risk)

5.2. Special hazards arising from the substance or mixtureSpecific hazards during firefighting:

Hazardous decomposition products formed under fire conditions. Carbon dioxide(CO2) Nitrogen oxides (NOx)

5.3. Advice for firefightersSpecial protective equipment for firefighters:

Wear full protective clothing and self-contained breathing apparatus.

Further information:Prevent fire extinguishing water from contaminating surface water or the groundwater system. Collect contaminated fire extinguishing water separately. This mustnot be discharged into drains. Fire residues and contaminated fire extinguishingwater must be disposed of in accordance with local regulations.: (on small fires) If area is heavily exposed to fire and if conditions permit, let fire burnitself out since water may increase the area contaminated. Cool containers/tankswith water spray.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency proceduresPersonal precautions:

Control access to area. Keep people away from and upwind of spill/leak. Avoid dustformation. Avoid breathing dust. Use personal protective equipment. Refer toprotective measures listed in sections 7 and 8.

6.2. Environmental precautions Environmental precautions:

Prevent further leakage or spillage if safe to do so. Use appropriate container toavoid environmental contamination. Do not flush into surface water or sanitarysewer system. Do not allow material to contaminate ground water system. Localauthorities should be advised if significant spillages cannot be contained. If the spill

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area is porous, the contaminated material must be collected for subsequenttreatment or disposal. If the product contaminates rivers and lakes or drains informrespective authorities.

6.3. Methods and materials for containment and cleaning up Methods for cleaning up:

Clean-up methods - small spillage Sweep up or vacuum up spillage and collect insuitable container for disposal. Clean-up methods - large spillage Avoid dust formation. Contain spillage, pick upwith an electrically protected vacuum cleaner or by wet-brushing and transfer toa container for disposal according to local regulations (see section 13). If spill area is on ground near valuable plants or trees, remove 5 cm of top soil afterinitial clean-up.

Other information:Never return spills in original containers for re-use. Dispose of in accordance withlocal regulations.

6.4. Reference to other sectionsFor personal protection see section 8., For disposal instructions see section 13.

SECTION 7: Handling and storage

7.1. Precautions for safe handlingAdvice on safe handling:

Use only according to our recommendations. Use only clean equipment. Avoid dustformation. Do not breathe dust or spray mist. Wear personal protective equipment.For personal protection see section 8. Prepare the working solution as given on thelabel(s) and/or the user instructions. Use prepared working solution as soon aspossible - Do not store. Provide appropriate exhaust ventilation at places wheredust is formed. Avoid exceeding the given occupational exposure limits (see section8).

Advice on protection against fire and explosion:Keep away from heat and sources of ignition. Avoid dust formation in confinedareas. During processing, dust may form explosive mixture in air.

7.2. Conditions for safe storage, including any incompatibilitiesRequirements for storage areas and containers:

Store in a place accessible by authorized persons only. Store in original container.Keep in properly labelled containers. Keep containers tightly closed in a dry, cooland well-ventilated place. Keep out of the reach of children.

Advice on common storage:No special restrictions on storage with other products.

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Other data:Stable under recommended storage conditions.

7.3. Specific end use(s)Plant protection products subject to Regulation (EC) No 1107/2009.

SECTION 8: Exposure controls/personal protection

8.1. Control parametersIf sub-section is empty then no values are applicable.

Components with workplace control parameters

Talc (Mg3H2(SiO3)4) (asbestos-free) (CAS-No. 14807-96-6)

Sucrose (CAS-No. 57-50-1)

8.2. Exposure controlsEngineering measures:

Ensure adequate ventilation, especially in confined areas. Provide for appropriateexhaust ventilation and dust collection at machinery. Use sufficient ventilation tokeep employee exposure below recommended limits.

Eye protection:Safety glasses with side-shields conforming to EN166

Hand protection:Material: Nitrile rubberGlove thickness: 0.3 mmGlove length: Standard glove type.Protection index: Class 6Wearing time: > 480 minThe selected protective gloves have to satisfy the specifications of EU Directive89/686/EEC and the standard EN 374 derived from it. Please observe the instructionsregarding permeability and breakthrough time which are provided by the supplierof the gloves. Also take into consideration the specific local conditions under whichthe product is used, such as the danger of cuts, abrasion, and the contact time. Thesuitability for a specific workplace should be discussed with the producers of theprotective gloves. The break through time depends amongst other things on thematerial, the thickness and the type of glove and therefore has to be measured foreach case. The exact break through time can be obtained from the protective glove

TypeForm of exposure

Controlparameters

Update Basis Remarks

TWARespirable dust.

0.8 mg/m3 2010 ELV (IE)

TWATotal inhalable dust.

10 mg/m3 2010 ELV (IE)

TWA 10 mg/m3 2010 ELV (IE)

STEL 20 mg/m3 2010 ELV (IE)

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producer and this has to be observed. Gloves must be inspected prior to use. Glovesshould be discarded and replaced if there is any indication of degradation orchemical breakthrough. Before removing gloves clean them with soap and water.

Skin and body protection:Manufacturing and processing work: Full protective clothing Type 5 (EN 13982-2) Mixer and loaders must wear: Full protective clothing Type 5 + 6 (EN ISO 13982-2 /EN 13034) Rubber apron Nitrile rubber boots (EN 13832-3 / EN ISO 20345). Spray application - outdoor: Tractor / sprayer with hood: No personal bodyprotection normally required. Tractor / sprayer without hood: Low application: Fullprotective clothing Type 6 (EN 13034) Nitrile rubber boots (EN 13832-3 / EN ISO20345). Backpack / knapsack sprayer: Low application: Full protective clothing Type 5 + 6(EN ISO 13982-2 / EN 13034) Nitrile rubber boots (EN 13832-3 / EN ISO 20345). Mechanical automatized spray application in closed tunnel: No personal bodyprotection normally required. When exceptional circumstances require an access to the treated area before theend of re-entry periods, wear full protective clothing Type 6 (EN 13034), nitrile rubbergloves class 3 (EN 374) and nitrile rubber boots (EN 13832-3 / EN ISO 20345).The permeation resistance of the fabric must be verified independently of the «type»protection recommended, to ensure an appropriate performance level of thematerial adequate to the corresponding agent and type of exposure.To optimize the ergonomy it may be recommended to use cotton underwear whenwearing some fabrics. Take advice from supplier.

Garment materials that are resistant to both water vapour and air will maximisewearing comfort. Materials should be robust to maintain the integrity and barrier inuse.

Protective measures:The type of protective equipment must be selected according to the concentrationand amount of the dangerous substance at the specific workplace. All chemicalprotective clothing should be visually inspected prior to use. Clothing and glovesshould be replaced in case of chemical or physical damage or if contaminated.Only protected handlers may be in the area during application.

Hygiene measures:Handle in accordance with good industrial hygiene and safety practice. Regularcleaning of equipment, work area and clothing. Keep working clothes separately.Contaminated work clothing should not be allowed out of the workplace. Washhands and face before breaks and immediately after handling the product. Whenusing do not eat, drink or smoke. Keep away from food, drink and animalfeedingstuffs. For environmental protection remove and wash all contaminatedprotective equipment before re-use. Remove clothing/PPE immediately if materialgets inside. Wash thoroughly and put on clean clothing. Dispose of rinse water inaccordance with local and national regulations.

Respiratory protection:Manufacturing and processing work: Half mask with a particle filter FFP1 (EN149) Mixer and loaders must wear: Half mask with a particle filter FFP1 (EN149)

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Spray application - outdoor: Tractor / sprayer with hood: No personal respiratoryprotective equipment normally required. Tractor / sprayer without hood: Lowapplication: Half mask with a particle filter FFP1 (EN149) Backpack / knapsack sprayer: Low application: Half mask with a particle filter FFP1(EN149) Mechanical automatized spray application in closed tunnel: No personal respiratoryprotective equipment normally required.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties Form : granularColour : off-whiteOdour : mild, sulphurousOdour Threshold : not determinedpH : 7.0 at 10 g/l ( 20 °C)Flash point : Not applicableFlammability (solid, gas) : The product is not flammable.Thermal decomposition : Not available for this mixture.Auto-ignition temperature : Test Type :Auto-ignition temperature, not auto-

flammableOxidizing properties : The product is not oxidizing. Explosive properties : Not explosive

Upper explosion limit/ upper flammability limit : Not available for this mixture.Vapour pressure : Not available for this mixture.Relative density : Not available for this mixture.Bulk density : 0.84 g/cm3 , packedWater solubility : dispersiblePartition coefficient: n-octanol/water : Not applicableViscosity, kinematic : Not applicableRelative vapour density : Not available for this mixture.Evaporation rate : Not available for this mixture. Minimum ignition energy : 171 mJ

9.2. Other informationPhys.-chem./other information : No other data to be specially mentioned.

SECTION 10: Stability and reactivity

10.1. ReactivityNo hazards to be specially mentioned.

10.2. Chemical stabilityThe product is chemically stable under recommended conditions of storage, use andtemperature.

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10.3. Possibility of hazardous reactionsNo dangerous reaction known under conditions of normal use. Polymerization will notoccur. No decomposition if stored and applied as directed.

10.4. Conditions to avoidTo avoid thermal decomposition, do not overheat. Under severe dusting conditions, thismaterial may form explosive mixtures in air.

10.5. Incompatible materialsNo materials to be especially mentioned.

10.6. Hazardous decomposition productsNo materials to be especially mentioned.

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute oral toxicity LD50 / Rat : > 5,000 mg/kgMethod: US EPA Test Guideline OPP 81-1 (Data on the product itself) Information source: Internal study report

Acute inhalation toxicity• Ethametsulfuron methyl

LC50 / 4 h Rat : > 5.7 mg/l

Acute dermal toxicityLD50 / Rat : > 2,000 mg/kgMethod: US EPA Test Guideline OPP 81-2 (Data on the product itself) Information source: Internal study report

Skin irritationRabbitResult: No skin irritationMethod: OECD Test Guideline 404Information source: Internal study report (Data on the product itself)

Eye irritationRabbitResult: No eye irritationMethod: OECD Test Guideline 405Information source: Internal study report (Data on the product itself)

SensitisationGuinea pig Result: Animal test did not cause sensitization by skin contact.Method: US EPA Test Guideline OPP 81-6 (Data on the product itself) Information source: Internal study report

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Repeated dose toxicity• Ethametsulfuron methyl

Oral - feed Mouse Exposure time: 90 dNOAEL: > 5,000 mg/kgInformation source: Internal study report

Oral - feed Rat Exposure time: 90 dNOAEL: 5,000 mg/kgInformation source: Internal study report

Oral - feed Dog Exposure time: 90 dNOAEL: 10,000 mg/kgInformation source: Internal study report

Oral - feed multiple species The following effects occurred at levels of exposure that significantly exceedthose expected under labeled usage conditions., Kidney effects, altered bloodchemistry, altered hematology

Mutagenicity assessment• Ethametsulfuron methyl

Did not show mutagenic effects in animal experiments. Tests on bacterial ormammalian cell cultures did not show mutagenic effects.

Carcinogenicity assessment• Ethametsulfuron methyl

Did not show carcinogenic effects in animal experiments.

Toxicity to reproduction assessment• Ethametsulfuron methyl

No toxicity to reproduction

STOT - single exposureThe substance or mixture is not classified as specific target organ toxicant, singleexposure.

STOT - repeated exposureThe substance or mixture is not classified as specific target organ toxicant,repeated exposure.

Aspiration hazardThe mixture does not have properties associated with aspiration hazard potential. SPECIM

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SECTION 12: Ecological information

12.1. ToxicityToxicity to fish

• Ethametsulfuron methylLC50 / 96 h / Lepomis macrochirus (Bluegill sunfish): > 123 mg/l LC50 / 96 h / Oncorhynchus mykiss (rainbow trout): > 126 mg/l

Toxicity to aquatic plants Static renewal test / ErC50 / Lemna gibba (duckweed)Method: OECD Test Guideline 221(Data on the product itself) Information source: Internal study report

Toxicity to aquatic invertebrates• Ethametsulfuron methyl

EC50 / 48 h / Daphnia magna (Water flea): > 108 mg/l

Chronic toxicity to fish• Ethametsulfuron methyl

Early Life-Stage / NOEC / 87 d / Oncorhynchus mykiss (rainbow trout): 5.4 mg/l

Chronic toxicity to aquatic Invertebrates• Ethametsulfuron methyl

EC50 / 21 d / Daphnia magna (Water flea): > 9.6 mg/l

12.2. Persistence and degradabilityBiodegradability

Not readily biodegradable. Estimation based on data obtained on active ingredient.

12.3. Bioaccumulative potentialBioaccumulation

Does not bioaccumulate. Estimation based on data obtained on active ingredient.

12.4. Mobility in soilMobility in soil

The product is not expected to be mobile in soils.

12.5. Results of PBT and vPvB assessmentPBT and vPvB assessment

This mixture contains no substance considered to be persistent, bioaccumulatingand toxic (PBT). / This mixture contains no substance considered to be verypersistent and very bioaccumulating (vPvB).

12.6. Other adverse effectsAdditional ecological information

See product label for additional application instructions relating to environmentalprecautions. No other ecological effects to be specially mentioned

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SECTION 13: Disposal considerations

13.1. Waste treatment methodsProduct:

In accordance with local and national regulations. Must be incinerated in a suitableincineration plant holding a permit delivered by the competent authorities. Do notcontaminate ponds, waterways or ditches with chemical or used container.

Contaminated packaging: Do not re-use empty containers.

SECTION 14: Transport information

ADR14.1. UN number: 307714.2. UN proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE,

SOLID, N.O.S. (Ethametsulfuron methyl)14.3. Transport hazard class(es): 914.4. Packing group: III14.5. Environmental hazards: For further information see Section 12.14.6. Special precautions for user:

Tunnel restriction code: (E)

IATA_C14.1. UN number: 307714.2. UN proper shipping name: Environmentally hazardous substance, solid, n.o.s.

(Ethametsulfuron methyl)14.3. Transport hazard class(es): 914.4. Packing group: III14.5. Environmental hazards : For further information see Section 12.14.6. Special precautions for user:

DuPont internal recommendations and transport guidance:ICAO / IATA cargo aircraft only

IMDG14.1. UN number: 307714.2. UN proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE,

SOLID, N.O.S. (Ethametsulfuron methyl)14.3. Transport hazard class(es): 914.4. Packing group: III14.5. Environmental hazards : Marine pollutant14.6. Special precautions for user:

no data available

14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC CodeNot applicable

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SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance ormixtureOther regulations:

The product is classified as dangerous in accordance with Regulation (EC) No.1272/2008.Take note of Dir 94/33/EC on the protection of young people at work.Takenote of Dir 92/85/EEC on the safety and health at work of pregnant workers.Takenote of Directive 98/24/EC on the protection of the health and safety of workers fromthe risks related to chemical agents at work.Take note of Directive 96/82/EC on thecontrol of major-accident hazards involving dangerous substances.Take note ofDirective 2000/39/EC establishing a first list of indicative occupational exposure limitvalues.

15.2. Chemical Safety Assessment A Chemical Safety Assessment is not required for this/these productsThe mixture is registered as a plant protection product under Regulation (EC) No.1107/2009.Refer to the label for exposure assessment information.

SECTION 16: Other information

Text of R-phrases mentioned in Section 3R22 Harmful if swallowed. R36 Irritating to eyes. R37/38 Irritating to respiratory system and skin. R41 Risk of serious damage to eyes. R50/53 Very toxic to aquatic organisms, may cause long-term

adverse effects in the aquatic environment.

Full text of H-Statements referred to under section 3.H302 Harmful if swallowed.H315 Causes skin irritation.H318 Causes serious eye damage.H319 Causes serious eye irritation.H335 May cause respiratory irritation.H400 Very toxic to aquatic life.H410 Very toxic to aquatic life with long lasting effects.

Other information professional use

Abbreviations and acronymsADR European Agreement concerning the International

Carriage of Dangerous Goods by Road

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ATE Acute toxicity estimateCAS-No. Chemical Abstracts Service numberCLP Classification, Labelling and PackagingEbC50 Concentration at which 50% reduction of biomass is

observedEC50 Median effective concentrationEN European NormEPA Environmental Protection AgencyErC50 Concentration at which a 50% inhibition of growth rate is

observedEyC50 Concentration at which 50 % inhibition of yield is observedIATA_C International Air Transport Association (Cargo)IBC International Bulk Chemical CodeICAO International Civil Aviation OrganizationISO International Standard OrganizationIMDG International Maritime Dangerous GoodsLC50 Median Lethal ConcentrationLD50 Median Lethal DoseLOEC Lowest Observed Effect ConcentrationLOEL Lowest observed effect levelMARPOL International Convention for the Prevention of Marine

Pollution from Shipsn.o.s. Not Otherwise SpecifiedNOAEC No Observed Adverse Effect ConcentrationNOAEL No observed adverse effect level

NOEC No Observed Effect ConcentrationNOEL No Observed Effect LevelOECD Organisation for Economic Co-operation and DevelopmentOPPTS Office of Prevention, Pesticides and Toxic SubstancesPBT Persistent, Bioaccumulative and ToxicSTEL Short term exposure limitTWA Time Weighted Average (TWA):vPvB very Persistent and very Bioaccumulative

Further information

Before use read DuPont's safety information., Take notice of the directions of use on thelabel. ® Registered trademark of E.I. du Pont de Nemours and Company

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The information provided in this Safety Data Sheet is correct to the best of our knowledge,information and belief at the date of its publication. The information given is designed onlyas a guide for safe handling, use, processing, storage, transportation, disposal and releaseand is not to be considered a warranty or quality specification. The above informationrelates only to the specific material(s) designated herein and may not be valid for suchmaterial(s) used in combination with any other materials or in any process or if the materialis altered or processed, unless specified in the text.

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