Safety Data Sheet VRLA Rechargeable Battery / Portable ...
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Safety Data Sheet VRLA Rechargeable Battery / Portable Jump Starters Utilizing Same Updated August 24, 2017 SECTION 1: PRODUCT AND COMPANY IDENTIFICATION Product Name: Valve Regulated Lead-Acid Rechargeable Battery, Maintenance Free Battery Company: Clore Automotive Address: 8735 Rosehill Rd., Suite 220, Lenexa, KS 66215 E-mail: [email protected] Phone: 913.310.1050 Emergency: CHEMTEL – 888.255.3924; +1.813.248.0573 Models: JNC300XL/JNC300XLC/JNC4000/JNC660/JNC660C/JNCAIR/JNC770/ JNC950/JNC1224/JNC065/JNC080/JNC100/JNC105/JNC110 Remark: This item (sealed VRLA rechargeable battery) is considered an article as defined by 29 CFR 1910.1200 (OSHA Hazard Communication Standard). The information contained in this SDS is supplied at the customer’s request for information only. Chemical family: This product is a non-spillable, wet lead acid storage battery. May also include gel absorbed electrolyte type lead acid battery types. SECTION 2: HAZARDS IDENTIFICATION GHS Label Elements: Signal Word: Danger
Transcript of Safety Data Sheet VRLA Rechargeable Battery / Portable ...
SafetyDataSheetVRLARechargeableBattery/
PortableJumpStartersUtilizingSameUpdatedAugust24,2017
SECTION1:PRODUCTANDCOMPANYIDENTIFICATIONProductName: ValveRegulatedLead-AcidRechargeableBattery,MaintenanceFreeBatteryCompany: CloreAutomotiveAddress: 8735RosehillRd.,Suite220,Lenexa,KS66215E-mail: [email protected]: 913.310.1050Emergency: CHEMTEL–888.255.3924;+1.813.248.0573Models: JNC300XL/JNC300XLC/JNC4000/JNC660/JNC660C/JNCAIR/JNC770/ JNC950/JNC1224/JNC065/JNC080/JNC100/JNC105/JNC110Remark: Thisitem(sealedVRLArechargeablebattery)isconsideredanarticleas definedby29CFR1910.1200(OSHAHazardCommunicationStandard). TheinformationcontainedinthisSDSissuppliedatthecustomer’srequest forinformationonly.Chemicalfamily:Thisproductisanon-spillable,wetleadacidstoragebattery.Mayalsoincludegelabsorbedelectrolytetypeleadacidbatterytypes.SECTION2:HAZARDSIDENTIFICATIONGHSLabelElements:
SignalWord:Danger
Category GHSCodes DescriptionHealth
STOTRE2AcuteTox.4Repr.1A
SkinCorr.1AFlam.Gas1
AquaticChronic1AquaticAcute1
H302H314H332H360H373H220H410P260P301/330/331P303/361/353
-Harmfulifswallowed.-Causessevereskinburnsandeyedamage.-Harmfulifinhaled.-Maydamagefertilityortheunbornchild.-Maycausedamagetoorgansthroughprolongedorrepeatedexposure.-Extremelyflammablegas(hydrogen).-Verytoxictoaquaticlifewithlonglastingeffects.-Donotbreathedust/fume/gas/mist/vapors/spray.-IFSWALLOWED:rinsemouth.DoNOTinducevomiting.-IFONSKIN(orhair):Remove/Takeoffimmediatelyallcontaminatedclothing.Rinseskinwithwater/shower.-IFINHALED:Removevictimtofreshairandkeepatrestinapositioncomfortableforbreathing.-IFINEYES:Rinsecautiouslywithwaterforseveralminutes.Removecontactlenses,ifpresentandeasytodo.Continuerinsing.ImmediatelycallaPOISONCENTERordoctor/physician.
Handling P210P260P264P280P403P405P391P273P501
-Keepawayfromheat/sparks/openflames/hotsurfaces.Nosmoking.-Donotbreathedust/fume/gas/mist/vapors/spray.-Washthoroughlyafterhandling.-Wearprotectivegloves/protectiveclothing/eyeprotection/faceprotection.-Storeinwell-ventilatedarea-Storelockedup.-Collectspillage.-Avoidreleasetotheenvironment.-Disposeofcontents/containerinaccordancewithlocal/regional/national/internationalregulation.
Note:Thebatteryhaspassedthevibrationtest,pressuredifferentialtestandleakagetestat55°CaccordingtorecommendationsontheTRANSPORTOFDANGEROUSGOODSModelRegulation
17thSPECIALPROVISION238.ItisnotrestrictedaccordingtoIATADangerousGoodsRegulation(DGR)56thperspecialprovisionA67andisnotrestrictedaccordingtoIMDGCODEperspecialprovision238.
SECTION3:INFORMATIONONINGREDIENTS
Ingredient CASNo. Concentration(%byWt.) HazardousLabelInorganicLead/LeadCompounds
7439-92-1 ~72% T
SulfuricAcid 7664-93-9 ~20% CFiberglassSeparator 65997-17-3 ~2% /
SiliconDioxide(Gelbatteriesonly) 7631-86-9 ~10%ofacidWt. /
ContainerPlastic(ABSorPP)
9003-56-9(ABS) ~5% /9003-07-0(PP) /
Note:Inorganicleadandelectrolyte(waterandsulfuricacidsolution)aretheprimarycomponentsofallCloreAutomotiveportablejumpstarterbatteries.Otheringredientsmaybepresentdependentuponbatterytype.ABSistheprimarycasematerialofourjumpstarterbatteries.SECTION4:FIRST-AIDMEASURESTakeproperprecautionstoensureyourownhealthandsafetybeforeattemptingtorescueavictimandprovidefirstaid.SkinContact:Electrolyte:Flushwithlargeamountsofwaterforatleast15minutes;removecontaminatedclothingcompletely,includingshoes,anddonotwearagainuntilcleaned.Ifacidissplashedonshoes,removeanddiscardiftheycontainleather.Leadcompounds:Washimmediatelywithsoapandwater.Leadcompoundsarenotreadilyabsorbedthroughtheskin.EyeContact:ElectrolyteandLeadcompounds:Flushimmediatelywithlargeamountsofwaterforatleast15minutes;consultphysicianimmediately.InhalationExposure:Electrolyte:Ifsulfuricacidmistorvaporisinhaled,movetoanareawithfreshairandwarmyourselfusingablanket.Seekmedicaladvice/attentionimmediately.Leadcompounds:Removefromexposure,gargle,washnoseandlips;consultphysician.
OralExposure:Electrolyte:Ifthisliquidisswallowed,washyourmouthwithplentyofwaterimmediately,thendrinkplentyofwater.Obtainmedicaladviceorattention.Donotinducevomitingwhenswallowed.Inaddition,donotperformanyaction,suchasaneutralizationprocess.Leadcompounds:Consultphysicianimmediately.
SECTION5:FIREFIGHTINGMEASURES
FlashPoint:NotApplicableFlammableLimits:LEL=4.1%(hydrogengasinair);UEL=74.1%ExtinguishingMedia:Smallfire–Foamhalogenand/ornon-flammablegasfireextinguisherLargefire:Largequantitiesofsprinkledand/oratomizedwater.(Inthiscase,topreventenvironmentaldamage,flushwatermustbetreatedappropriately.)Particularhazards:Irritant,corrosiveand/ortoxicgasesmayescapefromaburningbattery.Properfirefighting:Ifpossible,disconnectfrompowerfirstifbatteriesareonchargeorremoveignitionsourceandremovebatteriesfromthefiresource.Wherepossible,extinguishthefirefromwellventilatedareaupwindfromfire.Waterusedtoextinguishfiremustbetreatedappropriatelytopreventenvironmentaldamage.Cooldownburntbatteriesusingplentyofwater.FireFightingProcedures:Usepositivepressure,self-containedbreathingapparatus.Bewareofacidsplatterduringwaterapplicationandwearacid-resistantclothing,gloves,faceandeyeprotection.Ifbatteriesareoncharge,shutoffpowertothechargingequipment,but,notethatstringsofseriesconnectedbatteriesmaystillposeriskofelectricshockevenwhenchargingequipmentisshutdown.
SECTION6:ACCIDENTALRELEASEMEASURES
Humanbody:Donottouchthespilledelectrolyteandwalkaroundthespillagesite.Keepoutsidersfromthespillagesite.Environment:Spilledelectrolytemustbetreatedappropriatelytopreventenvironmentaldamage,suchasdirectoutflowingofthespilledelectrolyteintoriver,drain,etc..Neutralization:Neutralizespilledelectrolytewithsodiumbicarbonate,lime,etc.andflushwithlargequantitiesofwater.
SECTION7:HANDLINGANDSTORAGE
Handling:Keepawayfromignitionsources,heatandflame.Batteriesmustbepackedinsuchamannerastoeffectivelypreventshortcircuitsandtopreventmovementwhichcouldleadtoshortcircuits.Avoidmechanicalorelectricalabuseandovercharge.Morethanamomentary
shortcircuitwillgenerallyreducethebatteryservicelife.Avoidreversingbatterypolaritywithinthebatteryassembly.Storage:Storeinacool,well-ventilatedarea.Keepawayfromignitionsources,heatandflame.Batteriesmustbepackedinsuchamannerastoeffectivelypreventshortcircuitsandtopreventmovementwhichcouldleadtoshortcircuits.MaterialstoAvoid:Strongoxidant,combustiblematerialsandcorrosives.Charging:Thereisapossibleriskofelectricshockfromchargingequipmentandfromstringsofseriesconnectedbatteries,whetherornottheyarebeingcharged.Shutoffpowertochargerswhenevernotinuseandbeforedetachmentofanycircuitconnections.Batteriesbeingchargedwillgenerateandreleaseflammablehydrogengas.Charginglocationshouldbewellventilated.Keepbatteryventcapsinposition.Prohibitsmokingandavoidcreationofflamesandsparksnearby.Wearfaceandeyeprotectionwhennearbatteries.
SECTION8:EXPOSURECONTROLANDPERSONALPROTECTION NotapplicableforValveRegulatedLeadAcidbattery.
SECTION9:PHYSICAL/CHEMICALPROPERTIESNotapplicableforValveRegulatedLeadAcidbattery.
Reference(component)
Electrolyte(SulfuricAcid) LeadAppearance Clear Silverysolid
SpecificGravity 1.280–1.380(38–48%) 11.3BoilingPoint 112deg.C(38%) 1740deg.CMeltingPoint -40deg.Corbelow 327deg.C
SolidifyingPoint -56.4deg.C(34.6%) -VaporPressure 3.17kPa(30%) 0.1Paorless(25deg.C)
SECTION10:STABILITYANDREACTIVITY
Stability:Stableundernormaltemperaturesandpressures.MaterialstoAvoid:Strongoxidant,corrosives.ConditionstoAvoid:Avoidexposuretoheatandopenflame.Avoidmechanicalorelectricalabuseandovercharge.Preventshortcircuits.Preventmovementwhichcouldleadtoshortcircuits.HazardousPolymerization:Willnotoccur.HazardousDecompositionProducts:Sulfuroxides,Sulfuricacidmist,Metaloxides.
SECTION11:TOXICOLOGICALINFORMATION
RoutesofEntry:Electrolyte:Harmfulbyallroutesofentry.Undernormalconditionsofuse,sulfuricacidvaporsandmistarenotgenerated.Sulfuricacidvaporsandmistmaybegeneratedwhenproductisoverheated,oxidized,orotherwiseprocessedordamaged.Leadcompounds:Undernormalconditionsofuse,leaddust,vapors,andfumesarenotgenerated.Hazardousexposurecanoccuronlywhenproductisheatedabovethemeltingpoint,oxidizedorotherwiseprocessedordamagedtocreatedust,vapor,orfume.AcuteToxicity:InhalationLD50:Electrolyte:LC50rat:375mg/m3;LC50:guineapig:510mg/m3ElementalLead:AcuteToxicityPointEstimate=4500ppmV(basedonleadbullion)OralLD50:Electrolyte:rat:2140mg/kgElementallead:AcuteToxicityEstimate(ATE)=500mg/kgbodyweight(basedonleadbullion)Correspondtosection3
SECTION12:ECOLOGICALINFORMATION
EnvironmentalFate:Leadisverypersistentinsoilandsediments.Nodataonenvironmentaldegradation.Mobilityofmetallicleadbetweenecologicalcompartmentsisslow.Bioaccumulationofleadoccursinaquaticandterrestrialanimalsandplantsbutlittlebioaccumulationoccursthroughthefoodchain.Moststudiesincludeleadcompoundsandnotelementallead.EnvironmentalToxicity:AquaticToxicity:Sulfuricacid:24-hrLC50,freshwaterfish(Brachydaniorerio):82mg/L96hr-LOEC,freshwaterfish(Cyprinuscarpio):22mg/LLead:48hrLC50(modeledforaquaticinvertebrates):<1mg/L,basedonleadbullion
SECTION13:DISPOSALCONSIDERATIONS
AppropriateMethodofDisposalofSubstance:Lead-acidbatteriesarecompletelyrecyclable.Returnwholescrapbatteriestodistributor,manufacturerorleadsmelterforrecycling.Forneutralizedspills,placeresidueinacid-resistantcontainerswithsorbentmaterial,sandorearthanddisposeofinaccordancewithlocal,stateandfederalregulationsforacidandleadcompounds.Contactlocaland/orstateenvironmentalofficialsregardingdisposalinformation.
SECTION14:TRANSPORTINFORMATION
WeherebycertifythatalllistedCloreAutomotiveportablejumpstarterbatteriesconformtotheUN2800classificationas“Batteries,Wet,Non-Spillable”asaresultofpassingtheVibrationandPressureDifferentialTestdescribedinD.O.T.,49CFR173.159(f),andIMO/IMDG,andICAO/IATApackinginstruction872andnoteA48,A67,A164andA183.ThebatteriesarenotrestrictedaccordingtoIMO/IMDGcodeperspecialprovision238.CloreAutomotiveportablejumpstarterbatteries,havingmettherelatedconditions,areEXEMPTfromhazardousgoodsregulationsforthepurposeoftransportationbyDOTandIATA/ICAO,andthereforeareunrestrictedfortransportationbyanymeans.Forallmodesoftransportation,eachbatteryouterpackagemustbelabeled"NON-SPILLABLE."ProductsreturnedtoCloreAutomotive,orsubsequentlytransported,thatcontainabatteryorjumpstarter,mustbereturnedintheoriginalpackageorinastrongouterbox,certifiedfortheweightoftheunit,withadequatepackingmaterialtopreventtheunitfrommovementinsidethecarton.Forshipmentsofbatteries,batterypostsmustbeprotectedtopreventanypossibleshortcircuit.Forjumpstarters,thegripsmustbeproperlywrappedaroundtheunitandclampssecuredtopreventashortcircuitintransit.Ifaunitisbeingtransportedwithmetalclamps,gripsmustbeprotectedusingtheoriginallysuppliedgripguards,orthegripswrappedsoastopreventashortcircuit.Inadditionthecartonmustbemarkedwithphrase'Non-spillablebattery'soastocomplywiththerequirementsfortransportingthisasanon-dangerousshipment.
SECTION15:REGULATORYINFORMATION
EURegulation:InaccordancewithEU2006/66/ECBatteryDirective,VRLAbatteriesshouldpresentcrossed-outwheeledbinsymbolofleadtogetherwiththeISOrecyclingsymbol.Doesnotcontainanymercury,Hg,(<0.0005%)orcadmium,Cd,(<0.002%).
SECTION16:OTHERINFORMATION
ProductssuchasBatteriesarenotinthescopeofregulationwhichrequiresthepublicationofanEUSafetyDataSheet(91/155/EEC).
