Safety Data Sheet according to Regulation (EC) No 1907/2006 · Compilation date: 04.07.2007...

Safety Data Sheet according to Regulation (EC) No 1907/2006 of 7

DYLON Textilfarbe 350 g Dusty Violet

SDS No. : 554985

V001.0

Revision: 22.06.2017

printing date: 06.04.2018

Replaces version from: -

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier


1.2. Relevant identified uses of the substance or mixture and uses advised against

Intended use:

Fabric Dyes

1.3. Details of the supplier of the safety data sheet

Henkel Central Eastern Europe Gesellschaft mbH

Erdbergst. 29

A-1031 Vienna

Phone: (+43-1) 71104-0

Fax-no.: (+43-1) 71104-2523

[email protected]

1.4. Emergency telephone number

In acute cases of poisoning, the emergency number of the central poison information office (tel.: Vienna/406 43 43, around-

the-clock) is available.

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008 (CLP):

Eye Irrit. 2

H319 Causes serious eye irritation.

2.2. Label elements

Label elements (CLP):

Hazard pictogram:

Signal word: Warning

Hazard statement: H319 Causes serious eye irritation.

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Precautionary statement: P101 If medical advice is needed, have product container or label at hand.

P102 Keep out of reach of children.

P280 Wear eye protection.

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove

contact lenses, if present and easy to do. Continue rinsing.

P337+P313 If eye irritation persists: Get medical advice/attention.

2.3. Other hazards

None if used properly.

SECTION 3: Composition/information on ingredients

3.1. Substances

3.2. Mixtures

Hazardous substances according to CLP (EC) No 1272/2008:

Hazardous substances

CAS-No.

EINECS REACH-Reg No. Content Classification

Sodium carbonate 497-19-8

207-838-8 01-2119485498-19

>= 20- < 40 % Serious eye irritation 2 H319

For full text of the H - Phrases indicated by codes only see Section 16 "Other information".

SECTION 4: First aid measures

4.1. Description of first aid measures

General information:

In case of adverse health effects seek medical advice.

Inhalation:

Move to fresh air. In case of breathing difficulties seek immediate medical advise.

Skin contact:

Rinse under running water. Remove all contaminated clothing. Consult skin specialist if necessary.

Eye contact:

Rinse immediately under running water (for 10 minutes), thereafter seek immediate specialist medical advise.

Ingestion:

Do not induce vomiting, seek medical advice immediately.

Rinse mouth with water, (only if the person is conscious).

4.2. Most important symptoms and effects, both acute and delayed

After inhalation: Irritation of the respiratory tract, coughing. Inhalation of larger amounts may cause laryngospasm with

shortness of breath.

After skin contact: Moderate to strong irritation of the skin (redness, swelling, burning), severe burns also possible.

After eye contact: Moderate to strong irritation of the eyes (redness, swelling, burning, watering eyes).

After Ingestion: Ingestion may cause pain, burning, swelling and redness in the mouth and throat. Nausea and vomiting may

occur.

4.3. Indication of any immediate medical attention and special treatment needed

After inhalation: Inhalation may cause hyperacidity of the organism with following shortness of breath.

After skin contact: If irritation persists, seek medical advice.

After eye contact: No special action.

After ingestion: In case of coughing or shortness of breath immediately call the rescue services.

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SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media:

Water spray jet (if possible, avoid full jet). Adapt the fire-fighting measures to the environmental conditions.

Commercially available extinguishers are suitable for fighting incipient fires. The product itself does not burn.

Extinguishing media which must not be used for safety reasons:

None

5.2. Special hazards arising from the substance or mixture

Hazardous combustion products can be formed by pyrolysis and/or carbon monoxide.

5.3. Advice for firefighters

Use personal protective equipment and self-contained breathing apparatus.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Avoid contact with skin and eyes.

Ensure adequate ventilation.

If large amounts are released contact the fire service.

6.2. Environmental precautions Do not empty into drains / surface water / ground water.

6.3. Methods and material for containment and cleaning up

Remove mechanically. Rinse away residue with plenty of water.

6.4. Reference to other sections

See advice in section 8

SECTION 7: Handling and storage

7.1. Precautions for safe handling No special measures required if used properly.

Hygiene measures:

Avoid contact with skin and eyes. Remove soiled or soaked clothing immediately. Wash off any contamination that gets

onto the skin with plenty of water, skin care.

Protective equipment only required in case of industrial use or for large packs (not for household packs)

7.2. Conditions for safe storage, including any incompatibilities

Store dry at between +5 and +40°C.

Consider national regulations.

7.3. Specific end use(s)

Fabric Dyes

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SECTION 8: Exposure controls/personal protection

Only relevant for professional/industrial use

8.1. Control parameters

Valid for

Austria

Contains no components with occupational exposure limit values.

Attention: general dust limit value 6 mg/m3 (fine dust concentration)

8.2. Exposure controls

Respiratory protection:

If dust is produced wear P2 mask.

Hand protection:

For the contact with product protective gloves made from Spezial-Nitril (material thickness > 0.1 mm, break through time

> 480 min class 6) are recommended according to EN 374. In the case of longer and repeated contact please note that in

practice the penetration times may be considerably shorter than those determined according to EN 374. The protective

gloves must always be checked for their suitability for use at the specific workplace (e.g. mechanical and thermal stress,

antistatic effects, etc.). The gloves must be replaced immediately at the first signs of wear and tear. We recommend to

change single-use protective gloves periodical and a hand care plan in cooperation with a glove manufacturer and the

trade association in accordance with the local operating conditions.

Eye protection:

Wear tight fitting goggles.

Skin protection:

Protective clothing against chemicals. Observe manufacturer's instructions.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

The following data apply to the whole mixture.

a) Appearance powder

free-flowing

violet

b) Odor characteristic

c) Odour threshold No data available / Not applicable

d) pH

(; Conc.: 10 g/l)

11,24

e) Melting point No data available / Not applicable

f) Initial boiling point and boiling range No data available / Not applicable

g) Flash point Not applicable

h) Evaporation rate No data available / Not applicable

i) Flammability (solid , gas) No data available / Not applicable

j) Upper / lower flammability or explosive limits No data available / Not applicable

k) Vapour pressure No data available / Not applicable

l) Vapor density No data available / Not applicable

m) Relative density

Bulk density 900,000 - 1.200,000 g/l

n) Solubility (ies) soluble in water

o) Partition coefficient: n-octanol/water No data available / Not applicable

p) Auto-ignition temperature No data available / Not applicable

q) Decomposition temperature No data available / Not applicable

r) Viscosity No data available / Not applicable

s) Explosive properties No data available / Not applicable

t) Oxidising properties No data available / Not applicable

9.2. Other information

Not applicable

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SECTION 10: Stability and reactivity

10.1. Reactivity

None if used for intended purpose.

10.2. Chemical stability Stable under normal conditions of temperature and pressure.

10.3. Possibility of hazardous reactions See section reactivity

10.4. Conditions to avoid No decomposition if used according to specifications.

10.5. Incompatible materials


10.6. Hazardous decomposition products

No decomposition if used according to specifications.

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute oral toxicity:


CAS-No.

Value

type

Value

Species Method


LD50 2.800 mg/kg rat not specified

v

Acute dermal toxicity:


CAS-No.

Value

type

Value

Species Method

Sodium carbonate

497-19-8

LD50 > 2.000 mg/kg rabbit EPA 16 CFR 1500.40 (Method of

testing toxic substances)

Skin corrosion/irritation:


CAS-No.

Conclusion Exposure

time

Species Method

Sodium carbonate

497-19-8

not irritating 4 h rabbit OECD 404

Serious eye damage/irritation:


CAS-No.

Conclusion Exposure

time

Species Method

Sodium carbonate

497-19-8

irritating rabbit not specified

Germ cell mutagenicity:


CAS-No.

Result Type of study Metabolic

activation /

Exposure time

Species Method

Sodium carbonate

497-19-8

negative bacterial reverse

mutation assay (e.g

Ames test)

with Ames Test

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SECTION 12: Ecological information

12.1. Toxicity

Toxicity (Fish):


CAS-No.

Value

type

Value Exposure

time

Species Method


LC50 300 mg/l 96 h Lepomis macrochirus OECD Guideline 203 (Fish, Acute Toxicity Test)

Toxicity (Daphnia):


CAS-No.

Value

type

Value Exposure

time

Species Method

Sodium carbonate

497-19-8

EC50 200 - 227 mg/l 48 h Ceriodaphnia sp. OECD Guideline 202

(Daphnia sp. Acute

Immobilisation Test)

Toxicity (Algae):


CAS-No.

Value

type

Value Exposure

time

Species Method

Sodium carbonate

497-19-8

EC50 137 mg/l 5 d Nitzschia sp. OECD Guideline 201

(Alga, Growth Inhibition

Test)

12.2. Persistence and degradability

No data available.

12.3. Bioaccumulative potential

Does not bioaccumulate.

12.4. Mobility in soil

No data available.

12.5. Results of PBT and vPvB assessment

This mixture does not contain any substances that are assessed to be a PBT or vPvB.

12.6. Other adverse effects

Other adverse effects of this product for the environment are not known to us.

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Product disposal:

Dispose of in accordance with local and national regulations.

Disposal of uncleaned packages:

Only completely empty containers are to be disposed of as recoverable materials.

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SECTION 14: Transport information

14.1. UN number

Not hazardous according to RID, ADR, ADN, IMDG, IATA-DGR.

14.2. UN proper shipping name


14.3. Transport hazard class(es)


14.4. Packing group


14.5. Environmental hazards


14.6. Special precautions for user


14.7. Transport in bulk according to Annex II of Marpol and the IBC Code

not applicable

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

15.2. Chemical safety assessment

No Chemical Safety Assessment has been carried out.

SECTION 16: Other information


Further information:

This information is based on our current level of knowledge and relates to the product in the state in which it is delivered. It is

intended to describe our products from the point of view of safety requirements and is not intended to guarantee any

particular properties.

This Safety Data Sheet contains changes from the previous version in Section(s): 1 - 16

SAFETY DATA SHEET

DYLON FABRIC DYE FRENCH LAVENDER - LAVANDE 02

Page: 1

Compilation date: 04.07.2007

Revision date: 06.09.2016

Revision No: 8

Section 1: Identification of the substance/mixture and of the company/undertaking


Product name: DYLON FABRIC DYE FRENCH LAVENDER - LAVANDE 02

Product code: 2044027

Synonyms: TEINTURE POUR TEXTILES (F, B); TEXTIELVERF (NL, B)

TEKSTILFARVE (DK); TEXTILFÄRG (S); FARGESTOFF (N); TEKSTIILIVÄRI (FIN);


Use of substance / mixture: Domestic fabric dye. 50 g sachet.


Company name: HENKEL LIMITED

Wood Lane End

Hemel Hempstead

Hertfordshire

HP2 4RQ

UK

Tel: +44 (0)1442 278000

Fax: +44 (0)1442 278071

Email: [email protected]


Emergency tel: +44 (0)1442 278000

(office hours only)

Section 2: Hazards identification


Classification under CLP: Eye Irrit. 2: H319; -: EUH208

Most important adverse effects: Causes serious eye irritation. Contains c.i. reactive blue 225. May produce an allergic

reaction.

2.2. Label elements

Label elements:

Hazard statements: H319: Causes serious eye irritation.

EUH208: Contains c.i. reactive blue 225. May produce an allergic reaction.

Signal words: Warning

Hazard pictograms: GHS07: Exclamation mark

[cont...]

mailto:[email protected]

SAFETY DATA SHEET


Page: 2

Precautionary statements: P101: If medical advice is needed, have product container or label at hand.

P102: Keep out of reach of children.

P280: Wear protective gloves.

P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove


P337+313: If eye irritation persists: Get medical attention.

2.3. Other hazards

PBT: This product is not identified as a PBT/vPvB substance.

Section 3: Composition/information on ingredients

3.2. Mixtures

Hazardous ingredients:

SODIUM CARBONATE

EINECS CAS PBT / WEL CLP Classification Percent

207-838-8 497-19-8 - Eye Irrit. 2: H319 50-75%

Non-classified ingredients:

C.I. REACTIVE BLUE 225

EINECS CAS CHIP Classification CLP Classification Percent

401-560-2 108624-00-6 - Skin Sens. 1: H317 <1%

Section 4: First aid measures


Skin contact: Wash immediately with plenty of soap and water.

Eye contact: Bathe the eye with running water for 15 minutes. Consult a doctor.

Ingestion: Do not induce vomiting. Wash out mouth with water. If conscious, give half a litre of water

to drink immediately. Consult a doctor.

Inhalation: Remove casualty from exposure ensuring one's own safety whilst doing so.


Skin contact: There may be mild irritation at the site of contact. An itchy rash may occur at the site of

contact.

Eye contact: There may be irritation and redness. The eyes may water profusely.

Ingestion: There may be soreness and redness of the mouth and throat. Nausea and stomach

pain may occur.

Inhalation: There may be irritation of the throat with a feeling of tightness in the chest.

Delayed / immediate effects: Immediate effects can be expected after short-term exposure.

[cont...]

SAFETY DATA SHEET


Page: 3


Immediate / special treatment: Show this safety data sheet to the doctor in attendance. Eye bathing equipment should

be available on the premises.

Section 5: Fire-fighting measures


Extinguishing media: Suitable extinguishing media for the surrounding fire should be used.


Exposure hazards: In combustion emits toxic fumes of carbon dioxide.

5.3. Advice for fire-fighters

Advice for fire-fighters: Wear self-contained breathing apparatus. Wear protective clothing to prevent contact

with skin and eyes.

Section 6: Accidental release measures


Personal precautions: Refer to section 8 of SDS for personal protection details. Do not create dust.

6.2. Environmental precautions

Environmental precautions: Do not discharge into drains or rivers.


Clean-up procedures: Absorb into dry earth or sand. Transfer to a closable, labelled salvage container for

disposal by an appropriate method. Wash the spillage site with large amounts of water.


Reference to other sections: Refer to section 8 of SDS.

Section 7: Handling and storage

7.1. Precautions for safe handling

Handling requirements: Avoid direct contact with the substance. Ensure there is sufficient ventilation of the area.

Avoid the formation or spread of dust in the air.


Storage conditions: Store in a cool, well ventilated area.

Suitable packaging: Must only be kept in original packaging.


Specific end use(s): No data available.

Section 8: Exposure controls/personal protection

[cont...]

SAFETY DATA SHEET


Page: 4


Workplace exposure limits: No data available.

DNEL/PNEC Values


SODIUM CARBONATE

Type Exposure Value Population Effect

DNEL Inhalation - Long Term 10 mg/m³ Workers Local

DNEL Inhalation - Short Term 10 mg/m³ General Population Local


Engineering measures: Ensure there is sufficient ventilation of the area.

Hand protection: PVC gloves. Protective gloves. Butyl gloves. Nitrile gloves. Rubber gloves. Gloves

(alkali-resistant).

Eye protection: Safety glasses. Ensure eye bath is to hand.

Skin protection: Protective clothing.

Section 9: Physical and chemical properties


State: Powder

Colour: Lilac

Odour: Barely perceptible odour

Solubility in water: Highly soluble

pH: 11 (10g/l)


Other information: No data available.

Section 10: Stability and reactivity

10.1. Reactivity

Reactivity: Stable under recommended transport or storage conditions.

10.2. Chemical stability

Chemical stability: Stable under normal conditions.

10.3. Possibility of hazardous reactions

Hazardous reactions: Hazardous reactions will not occur under normal transport or storage conditions.

Decomposition may occur on exposure to conditions or materials listed below.

10.4. Conditions to avoid

[cont...]

SAFETY DATA SHEET


Page: 5


Materials to avoid: Strong acids.


Haz. decomp. products: Contact with acids liberates toxic gas.

Section 11: Toxicological information



SODIUM CARBONATE

ORL MUS LD50 6600 mg/kg

ORL RAT LD50 4090 mg/kg

SCU MUS LD50 2210 mg/kg

Relevant hazards for substance:

Hazard Route Basis

Serious eye damage/irritation OPT Hazardous: calculated

Symptoms / routes of exposure

Skin contact: There may be mild irritation at the site of contact. An itchy rash may occur at the site of

contact.



pain may occur.

Inhalation: There may be irritation of the throat with a feeling of tightness in the chest.


Section 12: Ecological information

12.1. Toxicity


SODIUM CARBONATE

- - - -


Persistence and degradability: No data available.


Bioaccumulative potential: No bioaccumulation potential.

[cont...]

SAFETY DATA SHEET


Page: 6



PBT identification: This product is not identified as a PBT/vPvB substance.


Other adverse effects: Negligible ecotoxicity.

Section 13: Disposal considerations


Disposal operations: Transfer to a suitable container and arrange for collection by specialised disposal

company.

Disposal of packaging: Dispose of as normal industrial waste.

NB: The user's attention is drawn to the possible existence of regional or national

regulations regarding disposal.

Section 14: Transport information

Transport class: This product does not require a classification for transport.

Section 15: Regulatory information


15.2. Chemical Safety Assessment

Chemical safety assessment: A chemical safety assessment has not been carried out for the substance or the mixture

by the supplier.

Section 16: Other information

Other information

Other information: This safety data sheet is prepared in accordance with Commission Regulation (EU) No

453/2010.

* indicates text in the SDS which has changed since the last revision.

Phrases used in s.2 and s.3: EUH208: Contains <name of sensitising substance>. May produce an allergic reaction.

H317: May cause an allergic skin reaction.

H319: Causes serious eye irritation.

Legal disclaimer: The above information is believed to be correct but does not purport to be all inclusive

and shall be used only as a guide. This company shall not be held liable for any

damage resulting from handling or from contact with the above product.

[final page]

Safety Data Sheet according to Regulation (EC) No 1907/2006 Page 1 of 7

DYLON Fabric Dye Tropical Green 03 (50g)

SDS No. : 554938

V001.0








Intended use:

Fabric Dyes


Henkel Ltd.

Betchworth House; 57-65 Station Road

RH1 1DL Redhill




Eye Irrit. 2


2.2. Label elements


Hazard pictogram:



EUH208 Contains C.I. Reactive Yellow 27. May produce an allergic reaction.







MSDS-No.: 554938

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3.1. Substances

3.2. Mixtures



CAS-No.


Sodium carbonate

497-19-8

207-838-8 01-2119485498-19

>= 70- < 90 % Serious eye irritation 2

H319

C.I. Reactive Yellow 27 75199-00-7

278-108-4 >= 0,1- < 1 % Skin sensitizer 1B H317






Inhalation:


Skin contact:


Eye contact:

Rinse immediately with plenty of running water (for 10 minutes). Seek medical attention if necessary.

Ingestion:









occur.











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None
















Hygiene measures:



onto the skin with plenty of water and soap, skin care.





Fabric Dyes




Valid for

Great Britain






MSDS-No.: 554938

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Hand protection:








Eye protection:


Skin protection:






free-flowing

green



d) pH

(; Conc.: 10 % product)

11,32









m) Relative density

Bulk density 900,000 - 1.200,000 g/l









Not applicable


10.1. Reactivity





MSDS-No.: 554938

V001.0


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CAS-No.

Value

type

Value

Species Method



C.I. Reactive Yellow 27

75199-00-7

v



CAS-No.

Value

type

Value

Species Method

Sodium carbonate

497-19-8




75199-00-7

Acute inhalative toxicity:


CAS-No.

Value

type

Value

Exposure

time

Species Method




CAS-No.

Conclusion Exposure

time

Species Method

Sodium carbonate

497-19-8




CAS-No.

Conclusion Exposure

time

Species Method

Sodium carbonate

497-19-8


Respiratory or skin sensitization:


CAS-No.

Conclusion Test type Species Method


75199-00-7

sensitising Guinea pig

maximisat

ion test

guinea pig OECD 406



CAS-No.


activation /

Exposure time

Species Method


negative bacterial reverse mutation assay (e.g

Ames test)

with Ames Test

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12.1. Toxicity

Toxicity (Fish):


CAS-No.

Value

type

Value Exposure

time

Species Method




75199-00-7

LC50 > 100 mg/l 48 h Leuciscus idus OECD Guideline 203

(Fish, Acute Toxicity Test)

Toxicity (Daphnia):


CAS-No.

Value

type

Value Exposure

time

Species Method


EC50 200 - 227 mg/l 48 h Ceriodaphnia sp. OECD Guideline 202 (Daphnia sp. Acute



EC50 > 100 mg/l 24 h Daphnia magna OECD Guideline 202 (Daphnia sp. Acute


Toxicity (Algae):


CAS-No.

Value

type

Value Exposure

time

Species Method


EC50 137 mg/l 5 d Nitzschia sp. OECD Guideline 201 (Alga, Growth Inhibition

Test)


No data available.




No data available.







Product disposal:




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14.1. UN number






14.4. Packing group







not applicable






H317 May cause an allergic skin reaction.








DYLON Fabric Dye Emerald Green 04

SDS No. : 596548

V001.0








Intended use:

Fabric Dyes


Henkel Ltd.


RH1 1DL Redhill

Phone: Tel: 01737 781 300

[email protected]




Skin Sens. 1

Eye Irrit. 2

Resp. Sens. 1

2.2. Label elements


Hazard pictogram:

Signal word: Danger

Hazard statement: H317 May cause an allergic skin reaction.


H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.

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P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

P280 Wear protective gloves/eye protection.

P302+P352 IF ON SKIN: Wash with plenty of water.

P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for

breathing.




P390 Absorb spillage to prevent material damage.

P342+P311 If experiencing respiratory symptoms: Call a POISON CENTER or doctor.

P501 Dispose of contents/container in accordance with national regulation.

P333+P313 If skin irritation or rash occurs: Get medical advice/attention.

Contains:

C.I. Reactive Blue 225,


C.I. Reactive Yellow 125,

C.I. Reactive Black 5

2.3. Other hazards

tactile warning of danger


3.1. Substances

3.2. Mixtures



CAS-No.


Sodium carbonate

497-19-8

207-838-8 01-2119485498-19


H319

C.I. Reactive Blue 225

108624-00-6

>= 1- < 5 % Skin sensitizer 1

H317

C.I. Reactive Blue 203 84229-70-9

282-468-8 >= 1- < 5 % Skin sensitizer 1B H317

Respiratory sensitizer 1B

H334


268-974-1 >= 0,1- < 1 % Skin sensitizer 1 H317


17095-24-8

241-164-5 >= 0,1- < 1 % Skin sensitizer 1

H317

Respiratory sensitizer 1 H334






Inhalation:


Skin contact:


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Eye contact:


Ingestion:









occur.












None
















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Hygiene measures:








Fabric Dyes




Valid for

Great Britain






Hand protection:








Eye protection:


Skin protection:






free-flowing

green



d) pH

(; Conc.: 10 % product; Solvent: Water)

9 - 11









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m) Relative density

Bulk density 900 - 1.200 g/l









Not applicable


10.1. Reactivity













CAS-No.

Value

type

Value

Species Method

Sodium carbonate

497-19-8



108624-00-6

LD50 > 5.000 mg/kg rat EU Method B.1 (Acute Toxicity

(Oral))


84229-70-9

LD50 > 5.000 mg/kg rat OECD 401


17095-24-8


v



CAS-No.

Value

type

Value

Species Method


LD50 > 2.000 mg/kg rabbit EPA 16 CFR 1500.40 (Method of testing toxic substances)



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CAS-No.

Conclusion Exposure

time

Species Method




108624-00-6



84229-70-9


C.I. Reactive Black 5 17095-24-8




CAS-No.

Conclusion Exposure

time

Species Method




108624-00-6

not irritating rabbit OECD 405


84229-70-9



not irritating rabbit not specified



CAS-No.



sensitising Guinea pig maximisat

ion test

guinea pig OECD 406


84229-70-9

not sensitising Buehler

test

guinea pig OECD 406


not sensitising Guinea pig maximisat

ion test

guinea pig OECD 406

ambiguous Respirator

y sensitisati

on

guinea pig not specified

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CAS-No.


activation /

Exposure time

Species Method

Sodium carbonate

497-19-8


mutation assay (e.g

Ames test)

with Ames Test


108624-00-6


mutation assay (e.g

Ames test)

with and without Ames Test

negative DNA damage and repair assay,

unscheduled DNA

synthesis in mammalian cells in

vitro

with and without OECD 482



Ames test)


negative mammalian cell gene mutation assay



84229-70-9

negative oral: gavage mouse OECD 474



Ames test)



17095-24-8


negative oral: gavage hamster,

Chinese

OECD 475

Repeated dose toxicity


CAS-No.

ResultValue Route of

application

Exposure time /

Frequency of

treatment

Species Method


84229-70-9

NOAEL=1.000

mg/kg

oral: gavage 28 ddaily rat OECD 407


17095-24-8

NOAEL=250 mg/kg oral: gavage 90 ddaily rat OECD 408

Reproductive toxicity:


CAS-No.

Result / Classification Species Exposure

time

Species Method


17095-24-8

NOAEL P = 1.000 mg/kg

NOAEL F1 = 1.000 mg/kg

One

generation study

oral: gavage

10 w rat OECD 415


12.1. Toxicity

Toxicity (Fish):


CAS-No.

Value

type

Value Exposure

time

Species Method




68155-62-4

LC50 > 100 mg/l 96 h Oncorhynchus mykiss OECD Guideline 203

(Fish, Acute Toxicity Test) C.I. Reactive Black 5

17095-24-8

LC50 > 100 mg/l 96 h Oryzias latipes OECD Guideline 203


NOEC >= 100 mg/l 14 d Oryzias latipes OECD Guideline 204 (Fish, Prolonged Toxicity

Test: 14-day Study)

MSDS-No.: 596548

V001.0


Page 8 of 9

Toxicity (Daphnia):


CAS-No.

Value

type

Value Exposure

time

Species Method

Sodium carbonate

497-19-8


(Daphnia sp. Acute

Immobilisation Test) C.I. Reactive Black 5

17095-24-8

EC50 748 mg/l 48 h Daphnia magna OECD Guideline 202

(Daphnia sp. Acute


Toxicity (Algae):


CAS-No.

Value

type

Value Exposure

time

Species Method

Sodium carbonate

497-19-8



Test) C.I. Reactive Black 5

17095-24-8

EC50 25,5 mg/l 72 h Scenedesmus subspicatus (new

name: Desmodesmus

subspicatus)

OECD Guideline 201


Test) EC10 5,1 mg/l 72 h Scenedesmus subspicatus (new

name: Desmodesmus

subspicatus)

OECD Guideline 201


Test)



CAS-No.

Result Test type Biodegradation Method


not inherently biodegradable

aerobic 10 % OECD Guideline 302 B (Inherent biodegradability: Zahn-

Wellens/EMPA Test)




Wellens/EMPA Test)





CAS-No.

LogPow Bioconcentration

factor (BCF)

Exposure

time

Species Temperature Method


17095-24-8

-4,34 20 °C OECD Guideline 107

(Partition Coefficient

(n-octanol / water), Shake Flask Method)







Product disposal:




MSDS-No.: 596548

V001.0


Page 9 of 9


14.1. UN number






14.4. Packing group







not applicable















DYLON Fabric Dye Sunflower Yellow 05

SDS No. : 555002

V001.0








Intended use:

Fabric Dyes


Henkel Ltd.


RH1 1DL Redhill

Phone: Tel: 01737 781 300

[email protected]




Eye Irrit. 2


2.2. Label elements


Hazard pictogram:



EUH208 Contains C.I. Reactive Yellow 125; Sodium benzene-sulfonate~. May produce

an allergic reaction.







MSDS-No.: 555002

V001.0


Page 2 of 9


3.1. Substances

3.2. Mixtures



CAS-No.


Sodium carbonate

497-19-8

207-838-8 01-2119485498-19


H319


68155-62-4

268-974-1 >= 0,1- < 1 % Skin sensitizer 1

H317

sodium 2-amino-4-acetamido-5-[2-(4-{[2-

(sulfonatooxy)ethane]sulfonyl}phenyl)diaz

en-1-yl]benzene-1-sulfonate 1354632-48-6

>= 0,1- < 1 % Skin sensitizer 1

H317






Inhalation:


Skin contact:

Rinse with water. Take off all clothing contaminated by the product.

Eye contact:


Ingestion:






After skin contact: Temporary irritation of the skin (redness, swelling, burning).


After ingestion: Ingestion may cause irritation of mouth, throat, digestive tract, diarrhea and vomiting. Vomit may get into

the lungs causing damage (aspiration).






MSDS-No.: 555002

V001.0


Page 3 of 9







None
















Hygiene measures:








Fabric Dyes




Valid for

Great Britain



MSDS-No.: 555002

V001.0


Page 4 of 9




Hand protection:








Eye protection:


Skin protection:






free-flowing

yellow



d) pH


10,06









m) Relative density










Not applicable


10.1. Reactivity




MSDS-No.: 555002

V001.0


Page 5 of 9











CAS-No.

Value

type

Value

Species Method

Sodium carbonate

497-19-8


sodium 2-amino-4-acetamido-5-[2-(4-{[2-(sulfonatooxy)ethane]sulfonyl}phenyl)diaz

en-1-yl]benzene-1-sulfonate

1354632-48-6


v



CAS-No.

Value

type

Value

Species Method

Sodium carbonate

497-19-8




(sulfonatooxy)ethane]sulfonyl}phenyl)diaz

en-1-yl]benzene-1-sulfonate 1354632-48-6




CAS-No.

Conclusion Exposure

time

Species Method

Sodium carbonate

497-19-8



(sulfonatooxy)ethane]sulf

onyl}phenyl)diazen-1-yl]benzene-1-sulfonate

1354632-48-6




CAS-No.

Conclusion Exposure

time

Species Method

Sodium carbonate

497-19-8


sodium 2-amino-4-

acetamido-5-[2-(4-{[2-(sulfonatooxy)ethane]sulf

onyl}phenyl)diazen-1-

yl]benzene-1-sulfonate 1354632-48-6


MSDS-No.: 555002

V001.0


Page 6 of 9



CAS-No.





1354632-48-6


ion test

guinea pig OECD 406



CAS-No.


activation /

Exposure time

Species Method

Sodium carbonate

497-19-8


mutation assay (e.g Ames test)

with Ames Test

sodium 2-amino-4-







sodium 2-amino-4-

acetamido-5-[2-(4-{[2-

(sulfonatooxy)ethane]sulfonyl}phenyl)diazen-1-

yl]benzene-1-sulfonate

1354632-48-6

negative oral: gavage rat OECD 474



CAS-No.


application

Exposure time /

Frequency of

treatment

Species Method

sodium 2-amino-4-




NOAEL=1.000

mg/kg




CAS-No.


time

Species Method




1354632-48-6

NOAEL P = 1.000 mg/kg NOAEL F1 = 1.000 mg/kg

screening oral: gavage

rat OECD 422


12.1. Toxicity

Toxicity (Fish):


CAS-No.

Value

type

Value Exposure

time

Species Method




68155-62-4


(Fish, Acute Toxicity Test) sodium 2-amino-4-acetamido-5-[2-

(4-{[2-

(sulfonatooxy)ethane]sulfonyl}phenyl)diazen-1-yl]benzene-1-sulfonate

1354632-48-6

LC50 > 500 mg/l 96 h Danio rerio OECD Guideline 203


MSDS-No.: 555002

V001.0


Page 7 of 9

Toxicity (Daphnia):


CAS-No.

Value

type

Value Exposure

time

Species Method

Sodium carbonate

497-19-8


(Daphnia sp. Acute

Immobilisation Test) sodium 2-amino-4-acetamido-5-[2-

(4-{[2-

(sulfonatooxy)ethane]sulfonyl}phenyl)diazen-1-yl]benzene-1-sulfonate

1354632-48-6

EC50 > 100 mg/l 48 h Daphnia magna OECD Guideline 202

(Daphnia sp. Acute


Toxicity (Algae):


CAS-No.

Value

type

Value Exposure

time

Species Method



Test)


(sulfonatooxy)ethane]sulfonyl}pheny

l)diazen-1-yl]benzene-1-sulfonate 1354632-48-6

EC50 > 100 mg/l 72 h Pseudokirchnerella subcapitata OECD Guideline 201 (Alga, Growth Inhibition

Test)



CAS-No.



68155-62-4

not inherently

biodegradable

aerobic 10 % OECD Guideline 302 B (Inherent

biodegradability: Zahn-

Wellens/EMPA Test) sodium 2-amino-4-acetamido-

5-[2-(4-{[2-

(sulfonatooxy)ethane]sulfonyl}phenyl)diazen-1-yl]benzene-

1-sulfonate

1354632-48-6

not inherently

biodegradable

aerobic 30 % OECD Guideline 302 B (Inherent


Wellens/EMPA Test)





CAS-No.


factor (BCF)

Exposure

time


sodium 2-amino-4-acetamido-

5-[2-(4-{[2-(sulfonatooxy)ethane]sulfonyl

}phenyl)diazen-1-yl]benzene-

1-sulfonate 1354632-48-6

-4,52 20 °C QSAR (Quantitative

Structure Activity Relationship)







MSDS-No.: 555002

V001.0


Page 8 of 9

Product disposal:





14.1. UN number






14.4. Packing group







not applicable





MSDS-No.: 555002

V001.0


Page 9 of 9










DYLON Fabric Dye China Blue

SDS No. : 555003

V001.0








Intended use:

Fabric Dyes


Henkel Ltd.


RH1 1DL Redhill

Phone: Tel: 01737 781 300

[email protected]




Eye Irrit. 2


2.2. Label elements


Hazard pictogram:



EUH208 Contains C.I. Reactive Blue 225. May produce an allergic reaction.







MSDS-No.: 555003

V001.0


Page 2 of 7

2.3. Other hazards



3.1. Substances

3.2. Mixtures



CAS-No.


Sodium carbonate

497-19-8

207-838-8 01-2119485498-19


H319


108624-00-6


H317






Inhalation:


Skin contact:


Eye contact:


Ingestion:











After inhalation: No special action.

After skin contact: No special action.


After ingestion: Do not induce vomiting. Single administration of a non-carbonated beverage (water or tea).

After ingestion: In case of ingestion of larger or unknown quantities administer a defoamer (Dimeticon or Simeticon).


MSDS-No.: 555003

V001.0


Page 3 of 7






None
















Hygiene measures:








Fabric Dyes




Valid for

Great Britain




MSDS-No.: 555003

V001.0


Page 4 of 7



Hand protection:








Eye protection:


Skin protection:






free-flowing

blue



d) pH


9 - 11









m) Relative density










Not applicable


10.1. Reactivity





MSDS-No.: 555003

V001.0


Page 5 of 7









CAS-No.

Value

type

Value

Species Method




108624-00-6


(Oral))

v



CAS-No.

Value

type

Value

Species Method

Sodium carbonate

497-19-8





CAS-No.

Conclusion Exposure

time

Species Method

Sodium carbonate

497-19-8



108624-00-6




CAS-No.

Conclusion Exposure

time

Species Method

Sodium carbonate

497-19-8






CAS-No.



108624-00-6


maximisation test

guinea pig OECD 406



CAS-No.


activation /

Exposure time

Species Method

Sodium carbonate

497-19-8



with Ames Test


108624-00-6


mutation assay (e.g

Ames test)


negative DNA damage and

repair assay,

unscheduled DNA synthesis in

mammalian cells in

vitro


MSDS-No.: 555003

V001.0


Page 6 of 7


12.1. Toxicity

Toxicity (Fish):


CAS-No.

Value

type

Value Exposure

time

Species Method



Toxicity (Daphnia):


CAS-No.

Value

type

Value Exposure

time

Species Method

Sodium carbonate

497-19-8


(Daphnia sp. Acute


Toxicity (Algae):


CAS-No.

Value

type

Value Exposure

time

Species Method

Sodium carbonate

497-19-8



Test)


No data available.




No data available.







Product disposal:




MSDS-No.: 555003

V001.0


Page 7 of 7


14.1. UN number






14.4. Packing group







not applicable














DYLON Fabric Dye Powder Pink 07 (50g)

SDS No. : 554939

V001.0








Intended use:

Fabric Dyes


Henkel Ltd.


RH1 1DL Redhill




Eye Irrit. 2


2.2. Label elements


Hazard pictogram:









MSDS-No.: 554939

V001.0


Page 2 of 7

2.3. Other hazards



3.1. Substances

3.2. Mixtures



CAS-No.


Sodium carbonate

497-19-8

207-838-8 01-2119485498-19


H319






Inhalation:


Skin contact:


Eye contact:


Ingestion:









occur.











MSDS-No.: 554939

V001.0


Page 3 of 7


None
















Hygiene measures:








Fabric Dyes




Valid for

Great Britain






MSDS-No.: 554939

V001.0


Page 4 of 7

Hand protection:








Eye protection:


Skin protection:






free-flowing

pink



d) pH


10,03









m) Relative density

Bulk density 900,000 - 1.200,000 g/l









Not applicable


10.1. Reactivity





MSDS-No.: 554939

V001.0


Page 5 of 7









CAS-No.

Value

type

Value

Species Method



v



CAS-No.

Value

type

Value

Species Method

Sodium carbonate

497-19-8





CAS-No.

Conclusion Exposure

time

Species Method

Sodium carbonate

497-19-8




CAS-No.

Conclusion Exposure

time

Species Method

Sodium carbonate

497-19-8




CAS-No.


activation /

Exposure time

Species Method



Ames test)

with Ames Test


12.1. Toxicity

Toxicity (Fish):


CAS-No.

Value

type

Value Exposure

time

Species Method

Sodium carbonate

497-19-8

LC50 300 mg/l 96 h Lepomis macrochirus OECD Guideline 203


Toxicity (Daphnia):


CAS-No.

Value

type

Value Exposure

time

Species Method




MSDS-No.: 554939

V001.0


Page 6 of 7

Toxicity (Algae):


CAS-No.

Value

type

Value Exposure

time

Species Method

Sodium carbonate

497-19-8



Test)


No data available.




No data available.







Product disposal:




MSDS-No.: 554939

V001.0


Page 7 of 7


14.1. UN number






14.4. Packing group







not applicable












SAFETY DATA SHEET

DYLON FABRIC DYE NAVY BLUE 08

Page: 1



Revision No: 5



Product name: DYLON FABRIC DYE NAVY BLUE 08






Wood Lane End

Hemel Hempstead

Hertfordshire

HP2 4RQ

UK

Tel: +44 (0)1442 278000

Fax: +44 (0)1442 278071



Emergency tel: +44 (0)1442 278000

(office hours only)



Classification under CLP: Resp. Sens. 1: H334; Skin Sens. 1: H317; Eye Irrit. 2: H319; Skin Irrit. 2: H315

Most important adverse effects: May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an

allergic skin reaction. Causes serious eye irritation. Causes skin irritation.

2.2. Label elements

Label elements:

Hazard statements: H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled.



H315: Causes skin irritation.

Signal words: Danger

Hazard pictograms: GHS08: Health hazard

[cont...]


SAFETY DATA SHEET


Page: 2



P261: Avoid breathing dust.

P280: Wear protective gloves/eye protection.

P302+352: IF ON SKIN: Wash with plenty of water/soap.

P304+340: IF INHALED: Remove person to fresh air and keep comfortable for breathing.



P342+311: If experiencing respiratory symptoms: Call a POISON CENTER/doctor/.

P501: Dispose of contents/container to in accordance with local regulations.

2.3. Other hazards



3.2. Mixtures


TRISODIUM PHOSPHATE


231-509-8 7601-54-9 - Eye Irrit. 2: H319; Skin Irrit. 2: H315;

STOT SE 3: H335

50-75%

SODIUM CARBONATE

207-838-8 497-19-8 - Eye Irrit. 2: H319 10-20%

C.I. REACTIVE BLACK 5

241-164-5 17095-24-8 - Resp. Sens. 1: H334; Skin Sens. 1:

H317

10-20%

C.I. REACTIVE RED 159

280-427-9 83400-12-8 - Skin Sens. 1: H317 <1%



Skin contact: Remove all contaminated clothes and footwear immediately unless stuck to skin. Wash

immediately with plenty of soap and water.




Inhalation: Remove casualty from exposure ensuring one's own safety whilst doing so. Consult a

doctor.

[cont...]

SAFETY DATA SHEET


Page: 3


Skin contact: There may be irritation and redness at the site of contact.



pain may occur.

Inhalation: There may be irritation of the throat with a feeling of tightness in the chest. Exposure may

cause coughing or wheezing.









Exposure hazards: In combustion emits toxic fumes.



with skin and eyes.



Personal precautions: Do not attempt to take action without suitable protective clothing - see section 8 of SDS.

Do not create dust.












[cont...]

SAFETY DATA SHEET


Page: 4


Storage conditions: Store in a cool, well ventilated area. Keep container tightly closed.







TRISODIUM PHOSPHATE

Respirable dustWorkplace exposure limits:

State 8 hour TWA 15 min. STEL 8 hour TWA 15 min. STEL

UK - - 4 mg/m3 ---

DNEL/PNEC Values


SODIUM CARBONATE






Respiratory protection: Self-contained breathing apparatus must be available in case of emergency.

Respiratory protective device with particle filter.

Hand protection: Gloves (alkali-resistant). Nitrile gloves. Rubber gloves.

Eye protection: Safety goggles. Ensure eye bath is to hand.




State: Powder

Colour: Blue



pH: 11.3 (10 g/l)

[cont...]

SAFETY DATA SHEET


Page: 5




10.1. Reactivity








Conditions to avoid: Heat.


Materials to avoid: Strong oxidising agents. Strong acids.


Haz. decomp. products: In combustion emits toxic fumes.




TRISODIUM PHOSPHATE


SODIUM CARBONATE





ORL RAT LD50 > 2000 mg/kg



[cont...]

SAFETY DATA SHEET


Page: 6


Hazard Route Basis

Skin corrosion/irritation DRM Hazardous: calculated


Respiratory/skin sensitisation INH DRM Hazardous: calculated


Skin contact: There may be irritation and redness at the site of contact.



pain may occur.





12.1. Toxicity


TRISODIUM PHOSPHATE

- - - -

SODIUM CARBONATE

- - - -


GOLDEN ORFE 96H LC50 10 - 100 mg/l


FISH (Leiciscus idus) 96H LC50 > 100 mg/l




Bioaccumulative potential: No data available.





Other adverse effects: No data available.

[cont...]

SAFETY DATA SHEET


Page: 7




company.









by the supplier.


Other information


453/2010.

Hazard Statements H319 & H315, and Precautionary Statement P305+351+338 are

omitted from the retail packs due to small size of packaging. Full warnings are provided

on this MSDS.

Phrases used in s.2 and s.3: H315: Causes skin irritation.



H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled.

H335: May cause respiratory irritation.




[final page]


DYLON Fabric Dye Dark Green

SDS No. : 555004

V001.0








Intended use:

Fabric Dyes


Henkel Ltd.


RH1 1DL Redhill

Phone: Tel: 01737 781 300

[email protected]




Skin Sens. 1


Eye Irrit. 2


2.2. Label elements


Hazard pictogram:




MSDS-No.: 555004

V001.0


Page 2 of 9











Contains:





2.3. Other hazards



3.1. Substances

3.2. Mixtures



CAS-No.



207-838-8 01-2119485498-19



75199-00-7

278-108-4 >= 1- < 5 % Skin sensitizer 1B

H317


108624-00-6


H317


84229-70-9

282-468-8 >= 0,1- < 1 % Skin sensitizer 1B

H317

Respiratory sensitizer 1B H334


17095-24-8

241-164-5 >= 0,1- < 1 % Skin sensitizer 1

H317







Inhalation:


Skin contact:


Eye contact:


MSDS-No.: 555004

V001.0


Page 3 of 9

Ingestion:









occur.












None
















MSDS-No.: 555004

V001.0


Page 4 of 9

Hygiene measures:








Fabric Dyes




Valid for

Great Britain






Hand protection:








Eye protection:


Skin protection:






free-flowing

dark green



d) pH

(; Conc.: 10,0 % product; Solvent: Water)

9 - 11









MSDS-No.: 555004

V001.0


Page 5 of 9

m) Relative density










Not applicable


10.1. Reactivity













CAS-No.

Value

type

Value

Species Method

Sodium carbonate

497-19-8



75199-00-7


108624-00-6


(Oral))


84229-70-9



17095-24-8


v



CAS-No.

Value

type

Value

Species Method




75199-00-7


84229-70-9


MSDS-No.: 555004

V001.0


Page 6 of 9



CAS-No.

Value

type

Value

Exposure

time

Species Method




CAS-No.

Conclusion Exposure

time

Species Method

Sodium carbonate

497-19-8



108624-00-6





17095-24-8




CAS-No.

Conclusion Exposure

time

Species Method

Sodium carbonate

497-19-8



108624-00-6





17095-24-8




CAS-No.



75199-00-7


maximisat

ion test

guinea pig OECD 406



ion test

guinea pig OECD 406


not sensitising Buehler test

guinea pig OECD 406


17095-24-8

not sensitising Guinea pig

maximisat

ion test

guinea pig OECD 406

ambiguous Respiratory

sensitisati

on


MSDS-No.: 555004

V001.0


Page 7 of 9



CAS-No.


activation /

Exposure time

Species Method

Sodium carbonate

497-19-8


mutation assay (e.g

Ames test)

with Ames Test


108624-00-6


mutation assay (e.g

Ames test)



unscheduled DNA


vitro




Ames test)


negative mammalian cell gene mutation assay



84229-70-9




Ames test)



17095-24-8



Chinese

OECD 475



CAS-No.


application

Exposure time /

Frequency of

treatment

Species Method


84229-70-9

NOAEL=1.000

mg/kg



17095-24-8




CAS-No.


time

Species Method


17095-24-8



One

generation study

oral: gavage

10 w rat OECD 415


12.1. Toxicity

Toxicity (Fish):


CAS-No.

Value

type

Value Exposure

time

Species Method




75199-00-7



17095-24-8




Test: 14-day Study)

MSDS-No.: 555004

V001.0


Page 8 of 9

Toxicity (Daphnia):


CAS-No.

Value

type

Value Exposure

time

Species Method

Sodium carbonate

497-19-8


(Daphnia sp. Acute

Immobilisation Test) C.I. Reactive Yellow 27

75199-00-7


(Daphnia sp. Acute


17095-24-8


(Daphnia sp. Acute


Toxicity (Algae):


CAS-No.

Value

type

Value Exposure

time

Species Method

Sodium carbonate

497-19-8




17095-24-8


name: Desmodesmus

subspicatus)

OECD Guideline 201



name: Desmodesmus

subspicatus)

OECD Guideline 201


Test)



CAS-No.





Wellens/EMPA Test)





CAS-No.


factor (BCF)

Exposure

time



17095-24-8










Product disposal:




MSDS-No.: 555004

V001.0


Page 9 of 9


14.1. UN number






14.4. Packing group







not applicable















DYLON Fabric Dye Pebble Beige 10 (50g)

SDS No. : 555005

V001.0








Intended use:

Fabric Dyes


Henkel Ltd.


RH1 1DL Redhill




Eye Irrit. 2


2.2. Label elements


Hazard pictogram:



EUH208 Contains C.I. Reactive Yellow 27. May produce an allergic reaction.







MSDS-No.: 555005

V001.0


Page 2 of 7

2.3. Other hazards



3.1. Substances

3.2. Mixtures



CAS-No.


Sodium carbonate

497-19-8

207-838-8 01-2119485498-19


H319


75199-00-7


H317






Inhalation:


Skin contact:


Eye contact:


Ingestion:









occur.







MSDS-No.: 555005

V001.0


Page 3 of 7






None
















Hygiene measures:








Fabric Dyes




Valid for

Great Britain




MSDS-No.: 555005

V001.0


Page 4 of 7



Hand protection:








Eye protection:


Skin protection:






free-flowing

brown



d) pH


10,84









m) Relative density

Bulk density 900,000 - 1.200,000 g/l









Not applicable


10.1. Reactivity





MSDS-No.: 555005

V001.0


Page 5 of 7









CAS-No.

Value

type

Value

Species Method




75199-00-7

v



CAS-No.

Value

type

Value

Species Method

Sodium carbonate

497-19-8




75199-00-7



CAS-No.

Value

type

Value

Exposure

time

Species Method




CAS-No.

Conclusion Exposure

time

Species Method

Sodium carbonate

497-19-8




CAS-No.

Conclusion Exposure

time

Species Method

Sodium carbonate

497-19-8




CAS-No.



75199-00-7


maximisat

ion test

guinea pig OECD 406



CAS-No.


activation /

Exposure time

Species Method



Ames test)

with Ames Test

MSDS-No.: 555005

V001.0


Page 6 of 7


12.1. Toxicity

Toxicity (Fish):


CAS-No.

Value

type

Value Exposure

time

Species Method




75199-00-7



Toxicity (Daphnia):


CAS-No.

Value

type

Value Exposure

time

Species Method





EC50 > 100 mg/l 24 h Daphnia magna OECD Guideline 202 (Daphnia sp. Acute


Toxicity (Algae):


CAS-No.

Value

type

Value Exposure

time

Species Method



Test)


No data available.




No data available.







Product disposal:




MSDS-No.: 555005

V001.0


Page 7 of 7


14.1. UN number






14.4. Packing group







not applicable














DYLON Fabric Dye Dark Brown 11

SDS No. : 554941

V001.0








Intended use:

Fabric Dyes


Henkel Ltd.


RH1 1DL Redhill




Eye Irrit. 2


Skin Sens. 1


2.2. Label elements


Hazard pictogram:














MSDS-No.: 554941

V001.0


Page 2 of 10

Contains:



7-[(5-chloro-2,6-difluoro-4-pyrimidinyl)amino]-4-hydroxy-3-[(4-methoxy-2-sulphophenyl)azo]naphthalene-2-sulphonic

acid, sodium salt,

C.I. Reactive Black 5,

C.I. Reactive Red 159,

Everzol orange GR

2.3. Other hazards



3.1. Substances

3.2. Mixtures



CAS-No.


Sodium carbonate

497-19-8

207-838-8 01-2119485498-19


H319




108624-00-6


H317

7-[(5-chloro-2,6-difluoro-4-

pyrimidinyl)amino]-4-hydroxy-3-[(4-methoxy-2-sulphophenyl)azo]naphthalene-

2-sulphonic acid, sodium salt

85391-83-9

286-839-5 >= 0,1- < 1 % Respiratory sensitizer 1B

H334 Skin sensitizer 1B

H317



Respiratory sensitizer 1

H334

C.I. Reactive Red 159 83400-12-8


Everzol orange GR

129009-88-7


H317






Inhalation:


Skin contact:


Eye contact:


Ingestion:



MSDS-No.: 554941

V001.0


Page 3 of 10





After eye contact: Temporary irritation of the eyes (redness, swelling, burning, watering eyes).


occur.












None
















Hygiene measures:




MSDS-No.: 554941

V001.0


Page 4 of 10





Fabric Dyes




Valid for

Great Britain





Not needed.

Hand protection:








Eye protection:


Skin protection:






free-flowing

dark brown



d) pH


11,45









m) Relative density

Bulk density 900,000 - 1.200,000 g/l

n) Solubility (ies) Not applicable




MSDS-No.: 554941

V001.0


Page 5 of 10





Not applicable


10.1. Reactivity













CAS-No.

Value

type

Value

Species Method





LD50 > 5.000 mg/kg rat EU Method B.1 (Acute Toxicity (Oral))

7-[(5-chloro-2,6-difluoro-4-pyrimidinyl)amino]-4-hydroxy-3-[(4-

methoxy-2-sulphophenyl)azo]naphthalene-

2-sulphonic acid, sodium salt 85391-83-9


17095-24-8


v



CAS-No.

Value

type

Value

Species Method

Sodium carbonate

497-19-8




75199-00-7

Naphthalenesulfonic acid, sodium salt~

85391-83-9

MSDS-No.: 554941

V001.0


Page 6 of 10



CAS-No.

Value

type

Value

Exposure

time

Species Method







CAS-No.

Conclusion Exposure

time

Species Method

Sodium carbonate

497-19-8



108624-00-6






CAS-No.

Conclusion Exposure

time

Species Method




108624-00-6



17095-24-8




CAS-No.



75199-00-7


maximisation test

guinea pig OECD 406


108624-00-6


maximisat

ion test

guinea pig OECD 406



ion test

guinea pig OECD 406


y sensitisati

on


MSDS-No.: 554941

V001.0


Page 7 of 10



CAS-No.


activation /

Exposure time

Species Method

Sodium carbonate

497-19-8


mutation assay (e.g

Ames test)

with Ames Test


108624-00-6


mutation assay (e.g

Ames test)



unscheduled DNA


vitro




Ames test)





Chinese

OECD 475



CAS-No.


application

Exposure time /

Frequency of

treatment

Species Method


17095-24-8




CAS-No.


time

Species Method


17095-24-8



One

generation

study oral: gavage

10 w rat OECD 415


12.1. Toxicity

Toxicity (Fish):


CAS-No.

Value

type

Value Exposure

time

Species Method

Sodium carbonate

497-19-8


(Fish, Acute Toxicity Test) C.I. Reactive Yellow 27

75199-00-7




LC50 > 100 mg/l 96 h Oryzias latipes OECD Guideline 203 (Fish, Acute Toxicity Test)

NOEC >= 100 mg/l 14 d Oryzias latipes OECD Guideline 204

(Fish, Prolonged Toxicity Test: 14-day Study)

C.I. Reactive Red 159

83400-12-8


(Fish, Acute Toxicity Test) Everzol orange GR

129009-88-7

LC50 > 100 mg/l 96 h Brachydanio rerio (new name:

Danio rerio)

OECD Guideline 203


MSDS-No.: 554941

V001.0


Page 8 of 10

Toxicity (Daphnia):


CAS-No.

Value

type

Value Exposure

time

Species Method

Sodium carbonate

497-19-8


(Daphnia sp. Acute


75199-00-7


(Daphnia sp. Acute


17095-24-8


(Daphnia sp. Acute

Immobilisation Test) Everzol orange GR

129009-88-7

EC50 > 117,4 mg/l 48 h Daphnia magna OECD Guideline 202

(Daphnia sp. Acute


Toxicity (Algae):


CAS-No.

Value

type

Value Exposure

time

Species Method

Sodium carbonate

497-19-8




17095-24-8


name: Desmodesmus

subspicatus)

OECD Guideline 201



name: Desmodesmus

subspicatus)

OECD Guideline 201


Test) Everzol orange GR

129009-88-7

EC50 > 100 mg/l 72 h Scenedesmus subspicatus (new

name: Desmodesmus

subspicatus)

EU Method C.3 (Algal

Inhibition test)

NOEC 13,1 mg/l 72 h Scenedesmus subspicatus (new

name: Desmodesmus

subspicatus)


Inhibition test)



CAS-No.





Wellens/EMPA Test)



aerobic < 10,000000 % OECD Guideline 302 B (Inherent biodegradability: Zahn-

Wellens/EMPA Test)

Everzol orange GR 129009-88-7

Not readily biodegradable.

aerobic 16 % OECD Guideline 301 E (Ready biodegradability: Modified OECD

Screening Test)





CAS-No.


factor (BCF)

Exposure

time


MSDS-No.: 554941

V001.0


Page 9 of 10


17095-24-8



(n-octanol / water),

Shake Flask Method) Everzol orange GR

129009-88-7

-0,5 EU Method A.8

(Partition Coefficient)







Product disposal:





14.1. UN number






14.4. Packing group







not applicable



MSDS-No.: 554941

V001.0


Page 10 of 10












SAFETY DATA SHEET

DYLON FABRIC DYE VELVET BLACK 12

Page: 1

Compilation date: 17/03/2015

Revision date: 19/09/2016

Revision No: 01



Product name: DYLON FABRIC DYE VELVET BLACK 12






Wood Lane End

Hemel Hempstead

Hertfordshire

HP2 4RQ

UK

Tel: +44 (0)1442 278000

Fax: +44 (0)1442 278071



Emergency tel: +44 (0)1442 278000

(office hours only)



Classification under CLP: Resp. Sens. 1: H334; Skin Sens. 1: H317; Eye Irrit. 2: H319; Skin Irrit. 2: H315

Most important adverse effects: May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an

allergic skin reaction. Causes serious eye irritation. Causes skin irritation.

2.2. Label elements

Label elements:

Hazard statements: H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled.



H315: Causes skin irritation.

Signal words: Danger

Hazard pictograms: GHS08: Health hazard

[cont...]


SAFETY DATA SHEET


Page: 2



P261: Avoid breathing dust.

P280: Wear protective gloves/eye protection.


P304+340: IF INHALED: Remove person to fresh air and keep comfortable for breathing.



P342+311: If experiencing respiratory symptoms: Call a POISON CENTER/doctor/.

P501: Dispose of contents/container to in accordance with local regulations.

2.3. Other hazards



3.2. Mixtures


TRISODIUM PHOSPHATE


231-509-8 7601-54-9 - Eye Irrit. 2: H319; Skin Irrit. 2: H315;

STOT SE 3: H335

50-75%

SODIUM CARBONATE

207-838-8 497-19-8 - Eye Irrit. 2: H319 10-20%



H317

10-20%


2-NAPTHALENESULFONIC ACID,

7-(4,6-DICHLORO-1,3,5-TRIAZIN-2-YL)AMINO-4-HYROXY-3-4-2-(SULFOXY)ETHYLSULPONYLPHENYLAZO,

DISODIUM SALT


- 129009-88-7 - Skin Sens. 1: H317 5-10%







to drink immediately. [cont...]

SAFETY DATA SHEET


Page: 3

Inhalation: Remove casualty from exposure ensuring one's own safety whilst doing so. If

conscious, ensure the casualty sits or lies down. Transfer to hospital as soon as

possible.


Skin contact: There may be irritation and redness at the site of contact. An itchy rash may occur at the

site of contact.



pain may occur.











Exposure hazards: In combustion emits toxic fumes.



with skin and eyes.



Personal precautions: Do not attempt to take action without suitable protective clothing - see section 8 of SDS.

Do not create dust.








[cont...]

SAFETY DATA SHEET


Page: 4



Handling requirements: Ensure there is sufficient ventilation of the area. Avoid the formation or spread of dust in

the air. Avoid direct contact with the substance.








TRISODIUM PHOSPHATE

Respirable dustWorkplace exposure limits:

State 8 hour TWA 15 min. STEL 8 hour TWA 15 min. STEL

UK - - 4 mg/m3 ---

DNEL/PNEC Values


SODIUM CARBONATE






Respiratory protection: Self-contained breathing apparatus must be available in case of emergency.

Respiratory protective device with particle filter.

Hand protection: Protective gloves. Butyl gloves. Nitrile gloves. Rubber gloves. Gloves (alkali-resistant).

Eye protection: Safety goggles. Ensure eye bath is to hand.




State: Powder

Colour: Pale grey

Odour: Characteristic odour

[cont...]

SAFETY DATA SHEET


Page: 5





10.1. Reactivity








Conditions to avoid: Humidity.


Materials to avoid: Strong acids. Strong oxidising agents.





TRISODIUM PHOSPHATE


SODIUM CARBONATE







Hazard Route Basis

[cont...]

SAFETY DATA SHEET


Page: 6

Skin corrosion/irritation DRM Hazardous: calculated


Respiratory/skin sensitisation INH DRM Hazardous: calculated



site of contact.



pain may occur.





12.1. Toxicity


TRISODIUM PHOSPHATE

- - - -

SODIUM CARBONATE

- - - -


GOLDEN ORFE 96H LC50 10 - 100 mg/l




Bioaccumulative potential: No data available.


Mobility: No data available.







company.

[cont...]

SAFETY DATA SHEET


Page: 7









Other information


453/2010.

Hazard Statements H319 & H315, and Precautionary Statement P305+351+338 are

omitted from the retail packs due to small size of packaging. Full warnings are provided

on this MSDS.

Phrases used in s.2 and s.3: H315: Causes skin irritation.








[final page]

SAFETY DATA SHEET

DYLON FABRIC DYE BAHAMA BLUE - TURQUOISE 21

Page: 1



Revision No: 6



Product name: DYLON FABRIC DYE BAHAMA BLUE - TURQUOISE 21




TEXTILFARBE (D);





Wood Lane End

Hemel Hempstead

Hertfordshire

HP2 4RQ

UK

Tel: +44 (0)1442 278000

Fax: +44 (0)1442 278071



Emergency tel: +44 (0)1442 278000

(office hours only)



Classification under CLP: Skin Sens. 1: H317; Eye Irrit. 2: H319

Most important adverse effects: May cause an allergic skin reaction. Causes serious eye irritation.

2.2. Label elements

Label elements:

Hazard statements: H317: May cause an allergic skin reaction.




[cont...]


SAFETY DATA SHEET


Page: 2







P333+313: If skin irritation or rash occurs: Get medical advice/attention.

P337+313: If eye irritation persists: Get medical advice/attention.

2.3. Other hazards



3.2. Mixtures


SODIUM CARBONATE


207-838-8 497-19-8 - Eye Irrit. 2: H319 25-50%


276-012-7 71786-55-5 - Skin Sens. 1: H317; Aquatic Chronic

3: H412

5-10%











site of contact.



pain may occur.

Inhalation: Exposure may cause coughing or wheezing.


[cont...]

SAFETY DATA SHEET


Page: 3











with skin and eyes.







Clean-up procedures: Transfer to a closable, labelled salvage container for disposal by an appropriate

method. Wash the spillage site with large amounts of water.













[cont...]

SAFETY DATA SHEET


Page: 4



DNEL/PNEC Values


SODIUM CARBONATE






Hand protection: Protective gloves. Gloves (alkali-resistant). Nitrile gloves. Rubber gloves.





State: Powder

Colour: Turquoise



pH: 10.9 (10 g/l)




10.1. Reactivity










[cont...]

SAFETY DATA SHEET


Page: 5






SODIUM CARBONATE







Hazard Route Basis


Respiratory/skin sensitisation DRM Hazardous: calculated



site of contact.



pain may occur.




12.1. Toxicity


SODIUM CARBONATE

- - - -


- IC50 > 100 mg/l

RAINBOW TROUT 96H LC50 10 - 100 mg/l

[cont...]

SAFETY DATA SHEET


Page: 6













company.









by the supplier.


Other information


453/2010.

* indicates text in the SDS which has changed since the last revision.

Phrases used in s.2 and s.3: H317: May cause an allergic skin reaction.


H412: Harmful to aquatic life with long lasting effects.




[final page]


DYLON Fabric Dye Ocean Blue 26

SDS No. : 554943

V001.0








Intended use:

Fabric Dyes


Henkel Ltd.


RH1 1DL Redhill

Phone: Tel: 01737 781 300

[email protected]




Eye Irrit. 2


2.2. Label elements


Hazard pictogram:



EUH208 Contains C.I. Reactive Red 159. May produce an allergic reaction.







MSDS-No.: 554943

V001.0


Page 2 of 7

2.3. Other hazards



3.1. Substances

3.2. Mixtures



CAS-No.


Sodium carbonate

497-19-8

207-838-8 01-2119485498-19

>= 90- <= 100 % Serious eye irritation 2

H319


83400-12-8


H317






Inhalation:


Skin contact:


Eye contact:


Ingestion:












After skin contact: No special action.


After ingestion: Do not induce vomiting. Single administration of a non-carbonated beverage (water or tea).

After ingestion: In case of ingestion of larger or unknown quantities administer a defoamer (Dimeticon or Simeticon).


MSDS-No.: 554943

V001.0


Page 3 of 7






None
















Hygiene measures:








Fabric Dyes




Valid for

Great Britain




MSDS-No.: 554943

V001.0


Page 4 of 7



Hand protection:








Eye protection:


Skin protection:






free-flowing

blue



d) pH


9 - 11









m) Relative density










Not applicable


10.1. Reactivity





MSDS-No.: 554943

V001.0


Page 5 of 7









CAS-No.

Value

type

Value

Species Method



v



CAS-No.

Value

type

Value

Species Method

Sodium carbonate

497-19-8





CAS-No.

Conclusion Exposure

time

Species Method

Sodium carbonate

497-19-8




CAS-No.

Conclusion Exposure

time

Species Method

Sodium carbonate

497-19-8




CAS-No.


activation /

Exposure time

Species Method



Ames test)

with Ames Test


12.1. Toxicity

Toxicity (Fish):


CAS-No.

Value

type

Value Exposure

time

Species Method

Sodium carbonate

497-19-8




LC50 > 100 mg/l 48 h Leuciscus idus OECD Guideline 203 (Fish, Acute Toxicity Test)

Toxicity (Daphnia):


CAS-No.

Value

type

Value Exposure

time

Species Method

Sodium carbonate

497-19-8


(Daphnia sp. Acute Immobilisation Test)

MSDS-No.: 554943

V001.0


Page 6 of 7

Toxicity (Algae):


CAS-No.

Value

type

Value Exposure

time

Species Method

Sodium carbonate

497-19-8



Test)



CAS-No.





Wellens/EMPA Test)




No data available.







Product disposal:




MSDS-No.: 554943

V001.0


Page 7 of 7


14.1. UN number






14.4. Packing group







not applicable














DYLON Fabric Dye Flamingo Pink 29

SDS No. : 554944

V001.0








Intended use:

Fabric Dyes


Henkel Ltd.


RH1 1DL Redhill

Phone: Tel: 01737 781 300

[email protected]




Eye Irrit. 2


Skin Sens. 1


2.2. Label elements


Hazard pictogram:




MSDS-No.: 554944

V001.0


Page 2 of 7











Contains:


2.3. Other hazards



3.1. Substances

3.2. Mixtures



CAS-No.



207-838-8 01-2119485498-19

>= 90- <= 100 % Serious eye irritation 2 H319


83400-12-8


H317






Inhalation:


Skin contact:


Eye contact:


Ingestion:



MSDS-No.: 554944

V001.0


Page 3 of 7







occur.












None
















Hygiene measures:




MSDS-No.: 554944

V001.0


Page 4 of 7





Fabric Dyes




Valid for

Great Britain






Hand protection:








Eye protection:


Skin protection:






free-flowing

violet



d) pH


9 - 11









m) Relative density

Bulk density 900,000 - 1.200,000 g/l





MSDS-No.: 554944

V001.0


Page 5 of 7





Not applicable


10.1. Reactivity













CAS-No.

Value

type

Value

Species Method



v



CAS-No.

Value

type

Value

Species Method

Sodium carbonate

497-19-8





CAS-No.

Conclusion Exposure

time

Species Method

Sodium carbonate

497-19-8




CAS-No.

Conclusion Exposure

time

Species Method

Sodium carbonate

497-19-8




CAS-No.


activation /

Exposure time

Species Method

Sodium carbonate

497-19-8


mutation assay (e.g

Ames test)

with Ames Test

MSDS-No.: 554944

V001.0


Page 6 of 7


12.1. Toxicity

Toxicity (Fish):


CAS-No.

Value

type

Value Exposure

time

Species Method

Sodium carbonate

497-19-8


(Fish, Acute Toxicity Test) C.I. Reactive Red 159

83400-12-8



Toxicity (Daphnia):


CAS-No.

Value

type

Value Exposure

time

Species Method

Sodium carbonate

497-19-8



Toxicity (Algae):


CAS-No.

Value

type

Value Exposure

time

Species Method

Sodium carbonate

497-19-8


(Alga, Growth Inhibition Test)



CAS-No.



83400-12-8

not inherently

biodegradable

aerobic < 10,000000 % OECD Guideline 302 B (Inherent


Wellens/EMPA Test)




No data available.







Product disposal:




MSDS-No.: 554944

V001.0


Page 7 of 7


14.1. UN number






14.4. Packing group







not applicable













SAFETY DATA SHEET

DYLON FABRIC DYE INTENSE VIOLET - VIOLET 30

Page: 1



Revision No: 7



Product name: DYLON FABRIC DYE INTENSE VIOLET - VIOLET 30


Synonyms: TEINTURE POUR TEXTILES (F, B); TEXTIELVERF (NL, B); TEXTILFARBE (D);


DYLON PERMANENT FABRIC DYE INTENSE VIOLET 30





Wood Lane End

Hemel Hempstead

Hertfordshire

HP2 4RQ

UK

Tel: +44 (0)1442 278000

Fax: +44 (0)1442 278071



Emergency tel: +44 (0)1442 278000

(office hours only)





2.2. Label elements

Label elements:





[cont...]


SAFETY DATA SHEET


Page: 2








2.3. Other hazards



3.2. Mixtures




280-427-9 83400-12-8 - Skin Sens. 1: H317 1-5%

SODIUM CARBONATE

207-838-8 497-19-8 - Eye Irrit. 2: H319 >75%




401-560-2 108624-00-6 - Skin Sens. 1: H317 <1%

DISODIUM METASILICATE

229-912-9 6834-92-0 - Skin Corr. 1B: H314; STOT SE 3:

H335

<1%


219-949-9 2580-78-1 - - <1%









[cont...]

SAFETY DATA SHEET


Page: 3



site of contact.



pain may occur.













with skin and eyes.







Clean-up procedures: Transfer to a closable, labelled salvage container for disposal by an appropriate

method. Wash the spillage site with large amounts of water.







[cont...]

SAFETY DATA SHEET


Page: 4









DNEL/PNEC Values


SODIUM CARBONATE






Hand protection: Gloves (alkali-resistant). Nitrile gloves. Rubber gloves.





State: Powder

Colour: Violet



pH: 11 (10 g/l)




10.1. Reactivity




[cont...]

SAFETY DATA SHEET


Page: 5





Conditions to avoid: Humidity.










SODIUM CARBONATE





Hazard Route Basis





site of contact.



pain may occur.




[cont...]

SAFETY DATA SHEET


Page: 6

12.1. Toxicity



FISH (Leiciscus idus) 96H LC50 > 100 mg/l

SODIUM CARBONATE

- - - -













company.









by the supplier.


Other information


453/2010.

* indicates text in the SDS which has changed since the last revision.[cont...]

SAFETY DATA SHEET


Page: 7

Phrases used in s.2 and s.3: H314: Causes severe skin burns and eye damage.







[final page]


DYLON Fabric Dye Olive Green 34

SDS No. : 555007

V001.0








Intended use:

Fabric Dyes


Henkel Ltd.


RH1 1DL Redhill

Phone: Tel: 01737 781 300

[email protected]




Skin Sens. 1


Eye Irrit. 2


2.2. Label elements


Hazard pictogram:




MSDS-No.: 555007

V001.0


Page 2 of 8











Contains:



C.I. Reactive Orange 64

2.3. Other hazards



3.1. Substances

3.2. Mixtures



CAS-No.


Sodium carbonate

497-19-8

207-838-8 01-2119485498-19


H319


75199-00-7


H317


>= 1- < 5 % Skin sensitizer 1 H317


83763-57-9


H317







Inhalation:


Skin contact:


Eye contact:


Ingestion:



MSDS-No.: 555007

V001.0


Page 3 of 8







occur.












None
















Hygiene measures:




MSDS-No.: 555007

V001.0


Page 4 of 8





Fabric Dyes




Valid for

Great Britain





Not needed.

Hand protection:








Eye protection:


Skin protection:






fine

greengreen

b) Odor no valuation


d) pH Not applicable









m) Relative density No data available / Not applicable

n) Solubility (ies) Not applicable






MSDS-No.: 555007

V001.0


Page 5 of 8



Not applicable


10.1. Reactivity













CAS-No.

Value

type

Value

Species Method

Sodium carbonate

497-19-8



75199-00-7


108624-00-6


(Oral))

v



CAS-No.

Value

type

Value

Species Method






CAS-No.

Value

type

Value

Exposure

time

Species Method


75199-00-7



CAS-No.

Conclusion Exposure

time

Species Method

Sodium carbonate

497-19-8




MSDS-No.: 555007

V001.0


Page 6 of 8



CAS-No.

Conclusion Exposure

time

Species Method




108624-00-6




CAS-No.



75199-00-7


maximisat

ion test

guinea pig OECD 406



ion test

guinea pig OECD 406



CAS-No.


activation /

Exposure time

Species Method

Sodium carbonate

497-19-8



with Ames Test


108624-00-6





repair assay,


mammalian cells in

vitro



12.1. Toxicity

Toxicity (Fish):


CAS-No.

Value

type

Value Exposure

time

Species Method

Sodium carbonate

497-19-8



75199-00-7



C.I. Reactive Orange 64 83763-57-9

LC50 > 100 mg/l 96 h Brachydanio rerio (new name: Danio rerio)

OECD Guideline 203 (Fish, Acute Toxicity Test)

Toxicity (Daphnia):


CAS-No.

Value

type

Value Exposure

time

Species Method

Sodium carbonate

497-19-8




75199-00-7



Toxicity (Algae):


CAS-No.

Value

type

Value Exposure

time

Species Method

Sodium carbonate

497-19-8



MSDS-No.: 555007

V001.0


Page 7 of 8



CAS-No.




aerobic < 10 % OECD Guideline 302 B (Inherent biodegradability: Zahn-

Wellens/EMPA Test)




No data available.







Product disposal:




MSDS-No.: 555007

V001.0


Page 8 of 8


14.1. UN number






14.4. Packing group







not applicable














SAFETY DATA SHEET

DYLON FABRIC DYE TERRACOTTA BROWN - TERRE CUITE 35

Page: 1



Revision No: 8



Product name: DYLON FABRIC DYE TERRACOTTA BROWN - TERRE CUITE 35




TEXTILFARBE (D);





Wood Lane End

Hemel Hempstead

Hertfordshire

HP2 4RQ

UK

Tel: +44 (0)1442 278000

Fax: +44 (0)1442 278071



Emergency tel: +44 (0)1442 278000

(office hours only)





2.2. Label elements

Label elements:





[cont...]


SAFETY DATA SHEET


Page: 2








P333+313: If skin irritation or rash occurs: Get medical advice/attention.

2.3. Other hazards



3.2. Mixtures


SODIUM CARBONATE


207-838-8 497-19-8 - Eye Irrit. 2: H319 >75%

C.I. REACTIVE YELLOW 27

278-108-4 75199-00-7 - Skin Sens. 1: H317 1-5%


C.I. REACTIVE ORANGE 64



H317

<1%



H317

<1%









[cont...]

SAFETY DATA SHEET


Page: 3



site of contact.



pain may occur.













with skin and eyes.













Handling requirements: Ensure there is sufficient ventilation of the area. Avoid the formation or spread of dust in

the air. Avoid direct contact with the substance.

[cont...]

SAFETY DATA SHEET


Page: 4









DNEL/PNEC Values


SODIUM CARBONATE






Hand protection: Protective gloves. PVC gloves. Butyl gloves. Nitrile gloves. Rubber gloves. Gloves

(alkali-resistant).





State: Powder

Colour: Red-brown



pH: 11 (10 g/l)




10.1. Reactivity


[cont...]

SAFETY DATA SHEET


Page: 5














SODIUM CARBONATE





ORAL RAT LD50 >5000 mg/kg


Hazard Route Basis





site of contact.



pain may occur.



[cont...]

SAFETY DATA SHEET


Page: 6


12.1. Toxicity


SODIUM CARBONATE

- - - -


BACTERIA 24H EC0 1000 mg/l

Daphnia magna 24H EC0 >100 mg/l

FISH (Leuciscus idus) 48H EC50 >100 mg/l













company.









by the supplier.

[cont...]

SAFETY DATA SHEET


Page: 7


Other information


453/2010.

Phrases used in s.2 and s.3: H317: May cause an allergic skin reaction.






[final page]


DYLON Fabric Dye Tulip Red 36

SDS No. : 554946

V001.0








Intended use:

Fabric Dyes


Henkel Ltd.


RH1 1DL Redhill

Phone: Tel: 01737 781 300

[email protected]




Skin Sens. 1


Eye Irrit. 2


2.2. Label elements


Hazard pictogram:




MSDS-No.: 554946

V001.0


Page 2 of 8











Contains:



acid, sodium salt,



3.1. Substances

3.2. Mixtures



CAS-No.


Sodium carbonate

497-19-8

207-838-8 01-2119485498-19


H319




pyrimidinyl)amino]-4-hydroxy-3-[(4-



85391-83-9

286-839-5 >= 0,1- < 1 % Respiratory sensitizer 1B

H334

Skin sensitizer 1B

H317


83763-57-9


H317 Respiratory sensitizer 1B

H334






Inhalation:


Skin contact:

If skin irritation occurs: Rinse with running water and soap.

Eye contact:


Ingestion:



MSDS-No.: 554946

V001.0


Page 3 of 8







occur.












None
















Hygiene measures:




MSDS-No.: 554946

V001.0


Page 4 of 8





Fabric Dyes




Valid for

Great Britain






Hand protection:








Eye protection:


Skin protection:






free-flowing

red



d) pH


9 - 11









m) Relative density






MSDS-No.: 554946

V001.0


Page 5 of 8





Not applicable


10.1. Reactivity













CAS-No.

Value

type

Value

Species Method






v



CAS-No.

Value

type

Value

Species Method

Sodium carbonate

497-19-8



Naphthalenesulfonic acid, sodium salt~

85391-83-9



CAS-No.

Value

type

Value

Exposure

time

Species Method




MSDS-No.: 554946

V001.0


Page 6 of 8



CAS-No.

Conclusion Exposure

time

Species Method





CAS-No.

Conclusion Exposure

time

Species Method





CAS-No.


activation /

Exposure time

Species Method

Sodium carbonate

497-19-8



with Ames Test


12.1. Toxicity

Toxicity (Fish):


CAS-No.

Value

type

Value Exposure

time

Species Method




83400-12-8


(Fish, Acute Toxicity Test) C.I. Reactive Orange 64

83763-57-9


Danio rerio)

OECD Guideline 203


Toxicity (Daphnia):


CAS-No.

Value

type

Value Exposure

time

Species Method




Toxicity (Algae):


CAS-No.

Value

type

Value Exposure

time

Species Method

Sodium carbonate

497-19-8





CAS-No.



83400-12-8

not inherently

biodegradable

aerobic < 10,000000 % OECD Guideline 302 B (Inherent


Wellens/EMPA Test) C.I. Reactive Orange 64

83763-57-9

not inherently

biodegradable

aerobic < 10 % OECD Guideline 302 B (Inherent


Wellens/EMPA Test)



MSDS-No.: 554946

V001.0


Page 7 of 8


No data available.







Product disposal:





14.1. UN number






14.4. Packing group







not applicable



MSDS-No.: 554946

V001.0


Page 8 of 8













DYLON Fabric Dye Jeans Blue 41 (50g)

SDS No. : 554947

V001.0








Intended use:

Fabric Dyes


Henkel Ltd.


RH1 1DL Redhill

Phone: Tel: 01737 781 300

[email protected]




Eye Irrit. 2


Skin Sens. 1


2.2. Label elements


Hazard pictogram:




MSDS-No.: 554947

V001.0


Page 2 of 9











Contains:



C.I. Reactive Orange 64,

Everzol orange GR

2.3. Other hazards



3.1. Substances

3.2. Mixtures



CAS-No.



207-838-8 01-2119485498-19



108624-00-6


H317


17095-24-8

241-164-5 >= 0,1- < 1 % Skin sensitizer 1

H317


H334



Respiratory sensitizer 1B

H334


>= 0,1- < 1 % Skin sensitizer 1 H317






Inhalation:


Skin contact:


Eye contact:


MSDS-No.: 554947

V001.0


Page 3 of 9

Ingestion:









occur.












None
















MSDS-No.: 554947

V001.0


Page 4 of 9

Hygiene measures:








Fabric Dyes




Valid for

Great Britain





Not needed.

Hand protection:








Eye protection:


Skin protection:






free-flowing

blue



d) pH


10,82









MSDS-No.: 554947

V001.0


Page 5 of 9

m) Relative density










Not applicable


10.1. Reactivity













CAS-No.

Value

type

Value

Species Method

Sodium carbonate

497-19-8



108624-00-6


(Oral))


17095-24-8


v



CAS-No.

Value

type

Value

Species Method





CAS-No.

Conclusion Exposure

time

Species Method

Sodium carbonate

497-19-8





17095-24-8


MSDS-No.: 554947

V001.0


Page 6 of 9



CAS-No.

Conclusion Exposure

time

Species Method




108624-00-6



17095-24-8




CAS-No.



108624-00-6


maximisation test

guinea pig OECD 406


17095-24-8

not sensitising Guinea pig

maximisat

ion test

guinea pig OECD 406

ambiguous Respiratory

sensitisati

on




CAS-No.


activation /

Exposure time

Species Method



Ames test)

with Ames Test



Ames test)



repair assay, unscheduled DNA

synthesis in

mammalian cells in vitro



17095-24-8





17095-24-8


negative oral: gavage hamster, Chinese

OECD 475



CAS-No.


application

Exposure time /

Frequency of

treatment

Species Method


17095-24-8




CAS-No.


time

Species Method


NOAEL P = 1.000 mg/kg NOAEL F1 = 1.000 mg/kg

One generation

study

oral: gavage

10 w rat OECD 415

MSDS-No.: 554947

V001.0


Page 7 of 9


12.1. Toxicity

Toxicity (Fish):


CAS-No.

Value

type

Value Exposure

time

Species Method




17095-24-8


(Fish, Acute Toxicity Test) NOEC >= 100 mg/l 14 d Oryzias latipes OECD Guideline 204

(Fish, Prolonged Toxicity

Test: 14-day Study) C.I. Reactive Orange 64

83763-57-9


Danio rerio)

OECD Guideline 203





Toxicity (Daphnia):


CAS-No.

Value

type

Value Exposure

time

Species Method

Sodium carbonate

497-19-8


(Daphnia sp. Acute


17095-24-8


(Daphnia sp. Acute

Immobilisation Test) Everzol orange GR

129009-88-7

EC50 > 117,4 mg/l 48 h Daphnia magna OECD Guideline 202

(Daphnia sp. Acute


Toxicity (Algae):


CAS-No.

Value

type

Value Exposure

time

Species Method

Sodium carbonate

497-19-8




17095-24-8


name: Desmodesmus

subspicatus)

OECD Guideline 201



name: Desmodesmus

subspicatus)

OECD Guideline 201


Test) Everzol orange GR

129009-88-7

EC50 > 100 mg/l 72 h Scenedesmus subspicatus (new

name: Desmodesmus

subspicatus)


Inhibition test)

NOEC 13,1 mg/l 72 h Scenedesmus subspicatus (new

name: Desmodesmus

subspicatus)


Inhibition test)



CAS-No.





Wellens/EMPA Test)




Wellens/EMPA Test)


Not readily biodegradable.

aerobic 16 % OECD Guideline 301 E (Ready biodegradability: Modified OECD

Screening Test)



MSDS-No.: 554947

V001.0


Page 8 of 9



CAS-No.


factor (BCF)

Exposure

time



17095-24-8




Everzol orange GR

129009-88-7

-0,5 EU Method A.8

(Partition Coefficient)







Product disposal:





14.1. UN number






14.4. Packing group







not applicable



MSDS-No.: 554947

V001.0


Page 9 of 9













DYLON Fabric Dye Burlesque Red 51

SDS No. : 555010

V001.0








Intended use:

Fabric Dyes


Henkel Ltd.


RH1 1DL Redhill

Phone: Tel: 01737 781 300

[email protected]




Skin Sens. 1


Eye Irrit. 2


2.2. Label elements


Hazard pictogram:




MSDS-No.: 555010

V001.0


Page 2 of 10











Contains:




acid, sodium salt,




2.3. Other hazards



3.1. Substances

3.2. Mixtures



CAS-No.


Sodium carbonate

497-19-8

207-838-8 01-2119485498-19


H319


83400-12-8


H317




H334




286-839-5 >= 0,1- < 1 % Respiratory sensitizer 1B H334

Skin sensitizer 1B

H317


83763-57-9



H334


108624-00-6


H317








Inhalation:


MSDS-No.: 555010

V001.0


Page 3 of 10

Skin contact:


Eye contact:


Ingestion:









occur.












None















MSDS-No.: 555010

V001.0


Page 4 of 10


No special measures required if used properly.

Hygiene measures:








Fabric Dyes




Valid for

Great Britain






Hand protection:








Eye protection:


Skin protection:






free-flowing

red



d) pH


9 - 11





MSDS-No.: 555010

V001.0


Page 5 of 10





m) Relative density










Not applicable


10.1. Reactivity













CAS-No.

Value

type

Value

Species Method

Sodium carbonate

497-19-8



17095-24-8






85391-83-9


108624-00-6


(Oral))


75199-00-7

v

MSDS-No.: 555010

V001.0


Page 6 of 10



CAS-No.

Value

type

Value

Species Method



Naphthalenesulfonic acid, sodium salt~ 85391-83-9




CAS-No.

Value

type

Value

Exposure

time

Species Method



methoxy-2-sulphophenyl)azo]naphthalene-2-sulphonic acid, sodium salt

85391-83-9


75199-00-7



CAS-No.

Conclusion Exposure

time

Species Method

Sodium carbonate

497-19-8





108624-00-6




CAS-No.

Conclusion Exposure

time

Species Method

Sodium carbonate

497-19-8



17095-24-8






CAS-No.




ion test

guinea pig OECD 406


y sensitisati

on




ion test

guinea pig OECD 406


75199-00-7


maximisation test

guinea pig OECD 406

MSDS-No.: 555010

V001.0


Page 7 of 10



CAS-No.


activation /

Exposure time

Species Method

Sodium carbonate

497-19-8


mutation assay (e.g

Ames test)

with Ames Test


17095-24-8


mutation assay (e.g

Ames test)





Chinese

OECD 475



Ames test)



repair assay,

unscheduled DNA


vitro




CAS-No.


application

Exposure time /

Frequency of

treatment

Species Method


17095-24-8




CAS-No.


time

Species Method


17095-24-8



One

generation

study oral: gavage

10 w rat OECD 415


12.1. Toxicity

Toxicity (Fish):


CAS-No.

Value

type

Value Exposure

time

Species Method

Sodium carbonate

497-19-8



83400-12-8




LC50 > 100 mg/l 96 h Oryzias latipes OECD Guideline 203 (Fish, Acute Toxicity Test)

NOEC >= 100 mg/l 14 d Oryzias latipes OECD Guideline 204

(Fish, Prolonged Toxicity Test: 14-day Study)


83763-57-9


Danio rerio)

OECD Guideline 203


75199-00-7



MSDS-No.: 555010

V001.0


Page 8 of 10

Toxicity (Daphnia):


CAS-No.

Value

type

Value Exposure

time

Species Method

Sodium carbonate

497-19-8


(Daphnia sp. Acute


17095-24-8


(Daphnia sp. Acute


75199-00-7


(Daphnia sp. Acute


Toxicity (Algae):


CAS-No.

Value

type

Value Exposure

time

Species Method

Sodium carbonate

497-19-8




17095-24-8


name: Desmodesmus

subspicatus)

OECD Guideline 201



name: Desmodesmus

subspicatus)

OECD Guideline 201


Test)



CAS-No.





Wellens/EMPA Test)




Wellens/EMPA Test)




Wellens/EMPA Test)





CAS-No.


factor (BCF)

Exposure

time



17095-24-8










MSDS-No.: 555010

V001.0


Page 9 of 10

Product disposal:





14.1. UN number






14.4. Packing group







not applicable





MSDS-No.: 555010

V001.0


Page 10 of 10











DYLON Fabric Dye Goldfish Orange 55 hand use

SDS No. : 555011

V001.0








Intended use:

Fabric Dyes


Henkel Ltd.


RH1 1DL Redhill

Phone: Tel: 01737 781 300

[email protected]




Eye Irrit. 2


Resp. Sens. 1


Skin Sens. 1


2.2. Label elements


Hazard pictogram:

Signal word: Danger




MSDS-No.: 555011

V001.0


Page 2 of 8






P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for

breathing.





P390 Absorb spillage to prevent material damage.


Contains:



acid, sodium salt,



2.3. Other hazards

tactile warning of danger


3.1. Substances

3.2. Mixtures



CAS-No.


Sodium carbonate

497-19-8

207-838-8 01-2119485498-19


H319


68155-62-4

268-974-1 >= 1- < 5 % Skin sensitizer 1

H317




286-839-5 >= 1- < 5 % Respiratory sensitizer 1B H334

Skin sensitizer 1B

H317


83400-12-8


H317


83763-57-9



H334






Inhalation:


Skin contact:


MSDS-No.: 555011

V001.0


Page 3 of 8

Eye contact:


Ingestion:









occur.












None
















MSDS-No.: 555011

V001.0


Page 4 of 8

Hygiene measures:








Fabric Dyes




Valid for

Great Britain






Hand protection:








Eye protection:


Skin protection:






free-flowing

orange



d) pH


11,32









MSDS-No.: 555011

V001.0


Page 5 of 8

m) Relative density

Bulk density 900,000 - 1.200,000 g/l









Not applicable


10.1. Reactivity













CAS-No.

Value

type

Value

Species Method

Sodium carbonate

497-19-8





85391-83-9

v



CAS-No.

Value

type

Value

Species Method



Naphthalenesulfonic acid, sodium salt~ 85391-83-9



CAS-No.

Value

type

Value

Exposure

time

Species Method




85391-83-9

MSDS-No.: 555011

V001.0


Page 6 of 8



CAS-No.

Conclusion Exposure

time

Species Method





CAS-No.

Conclusion Exposure

time

Species Method





CAS-No.


activation /

Exposure time

Species Method

Sodium carbonate

497-19-8



with Ames Test


12.1. Toxicity

Toxicity (Fish):


CAS-No.

Value

type

Value Exposure

time

Species Method




68155-62-4



83400-12-8






Toxicity (Daphnia):


CAS-No.

Value

type

Value Exposure

time

Species Method

Sodium carbonate

497-19-8



Toxicity (Algae):


CAS-No.

Value

type

Value Exposure

time

Species Method

Sodium carbonate

497-19-8



Test)



CAS-No.





Wellens/EMPA Test)




Wellens/EMPA Test) C.I. Reactive Orange 64

83763-57-9

not inherently

biodegradable

aerobic < 10 % OECD Guideline 302 B (Inherent


Wellens/EMPA Test)

MSDS-No.: 555011

V001.0


Page 7 of 8




No data available.







Product disposal:





14.1. UN number






14.4. Packing group







not applicable



MSDS-No.: 555011

V001.0


Page 8 of 8













DYLON Fabric Dye Rosewood Red 64

SDS No. : 555012

V001.0








Intended use:

Fabric Dyes


Henkel Ltd.


RH1 1DL Redhill

Phone: Tel: 01737 781 300

[email protected]




Eye Irrit. 2


Skin Sens. 1


2.2. Label elements


Hazard pictogram:




MSDS-No.: 555012

V001.0


Page 2 of 8











Contains:





2.3. Other hazards



3.1. Substances

3.2. Mixtures



CAS-No.



207-838-8 01-2119485498-19



83400-12-8


H317


75199-00-7


H317


83763-57-9


H317



108624-00-6


H317






Inhalation:


Skin contact:


Eye contact:


Ingestion:



MSDS-No.: 555012

V001.0


Page 3 of 8







occur.












None
















Hygiene measures:




MSDS-No.: 555012

V001.0


Page 4 of 8





Fabric Dyes




Valid for

Great Britain





Not needed.

Hand protection:








Eye protection:


Skin protection:






free-flowing

red



d) pH

(; Conc.: 100 g/l)

11,02









m) Relative density






MSDS-No.: 555012

V001.0


Page 5 of 8





Not applicable


10.1. Reactivity













CAS-No.

Value

type

Value

Species Method






v



CAS-No.

Value

type

Value

Species Method

Sodium carbonate

497-19-8




75199-00-7



CAS-No.

Value

type

Value

Exposure

time

Species Method




CAS-No.

Conclusion Exposure

time

Species Method

Sodium carbonate

497-19-8



108624-00-6


MSDS-No.: 555012

V001.0


Page 6 of 8



CAS-No.

Conclusion Exposure

time

Species Method




108624-00-6




CAS-No.



75199-00-7


maximisat

ion test

guinea pig OECD 406



ion test

guinea pig OECD 406



CAS-No.


activation /

Exposure time

Species Method

Sodium carbonate

497-19-8



with Ames Test


108624-00-6





repair assay,


mammalian cells in

vitro



12.1. Toxicity

Toxicity (Fish):


CAS-No.

Value

type

Value Exposure

time

Species Method

Sodium carbonate

497-19-8



83400-12-8






83763-57-9


Danio rerio)

OECD Guideline 203


Toxicity (Daphnia):


CAS-No.

Value

type

Value Exposure

time

Species Method

Sodium carbonate

497-19-8


(Daphnia sp. Acute


75199-00-7


(Daphnia sp. Acute


MSDS-No.: 555012

V001.0


Page 7 of 8

Toxicity (Algae):


CAS-No.

Value

type

Value Exposure

time

Species Method

Sodium carbonate

497-19-8



Test)



CAS-No.





Wellens/EMPA Test)




Wellens/EMPA Test)




No data available.







Product disposal:




MSDS-No.: 555012

V001.0


Page 8 of 8


14.1. UN number






14.4. Packing group







not applicable















DYLON Fabric Dye Pewter Grey

SDS No. : 555013

V001.0








Intended use:

Fabric Dyes


Henkel Ltd.


RH1 1DL Redhill

Phone: Tel: 01737 781 300

[email protected]




Eye Irrit. 2


2.2. Label elements


Hazard pictogram:



EUH208 Contains C.I. Reactive Yellow 125; C.I. Reactive Black 5; C.I. Reactive Red

159; C.I. Reactive Blue 225. May produce an allergic reaction.







MSDS-No.: 555013

V001.0


Page 2 of 9


3.1. Substances

3.2. Mixtures



CAS-No.


Sodium carbonate

497-19-8

207-838-8 01-2119485498-19


H319


68155-62-4

268-974-1 >= 0,1- < 1 % Skin sensitizer 1

H317


17095-24-8

241-164-5 >= 0,1- < 1 % Skin sensitizer 1

H317



83400-12-8


H317


>= 0,1- < 1 % Skin sensitizer 1 H317






Inhalation:


Skin contact:


Eye contact:


Ingestion:







After eye contact: Temporary irritation of the eyes (redness, swelling, burning, watering eyes).

After ingestion: Corrosivity may cause immediately pain, burning, swelling, and redness in mouth and throat. Nausea and

vomiting may occur. Risk of serious damage to the mouth, throat and esophagus.

MSDS-No.: 555013

V001.0


Page 3 of 9












None
















Hygiene measures:








Fabric Dyes

MSDS-No.: 555013

V001.0


Page 4 of 9




Valid for

Great Britain






Hand protection:








Eye protection:


Skin protection:






free-flowing

grey



d) pH


9 - 11









m) Relative density










Not applicable

MSDS-No.: 555013

V001.0


Page 5 of 9


10.1. Reactivity













CAS-No.

Value

type

Value

Species Method







v



CAS-No.

Value

type

Value

Species Method

Sodium carbonate

497-19-8





CAS-No.

Conclusion Exposure

time

Species Method

Sodium carbonate

497-19-8



17095-24-8






CAS-No.

Conclusion Exposure

time

Species Method




17095-24-8



108624-00-6


MSDS-No.: 555013

V001.0


Page 6 of 9



CAS-No.




ion test

guinea pig OECD 406


y sensitisati

on



108624-00-6


maximisation test

guinea pig OECD 406



CAS-No.


activation /

Exposure time

Species Method

Sodium carbonate

497-19-8


mutation assay (e.g

Ames test)

with Ames Test


17095-24-8


mutation assay (e.g

Ames test)





Chinese

OECD 475



Ames test)



unscheduled DNA


vitro




CAS-No.


application

Exposure time /

Frequency of

treatment

Species Method


17095-24-8




CAS-No.


time

Species Method


17095-24-8



One

generation

study oral: gavage

10 w rat OECD 415

MSDS-No.: 555013

V001.0


Page 7 of 9


12.1. Toxicity

Toxicity (Fish):


CAS-No.

Value

type

Value Exposure

time

Species Method




68155-62-4



17095-24-8




Test: 14-day Study)



Toxicity (Daphnia):


CAS-No.

Value

type

Value Exposure

time

Species Method

Sodium carbonate

497-19-8


(Daphnia sp. Acute


17095-24-8


(Daphnia sp. Acute


Toxicity (Algae):


CAS-No.

Value

type

Value Exposure

time

Species Method

Sodium carbonate

497-19-8



Test)


17095-24-8


name: Desmodesmus

subspicatus)

OECD Guideline 201



name: Desmodesmus

subspicatus)

OECD Guideline 201


Test)



CAS-No.





Wellens/EMPA Test)




Wellens/EMPA Test)




Wellens/EMPA Test)





CAS-No.


factor (BCF)

Exposure

time


MSDS-No.: 555013

V001.0


Page 8 of 9


17095-24-8



(n-octanol / water),

Shake Flask Method)







Product disposal:





14.1. UN number






14.4. Packing group







not applicable



MSDS-No.: 555013

V001.0


Page 9 of 9












Safety Data Sheet according to Regulation (EC) No 1907/2006 · Compilation date: 04.07.2007...

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Transcript of Safety Data Sheet according to Regulation (EC) No 1907/2006 · Compilation date: 04.07.2007...