S7 Going Beyond Foaming LTC2013
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Advanced Asphalt Technologies, LLC
Engineering Services for the Asphalt Industry
Warm Mix Asphalt:Going Beyond Foaming
Ramon Bonaquist, Ph.D., P.E.
Advanced Asphalt Technologies, LLC
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Advanced Asphalt Technologies, LLC
Engineering Services for the Asphalt Industry
Outline
WMA Technologies
WMA Usage
Why Use a WMA Additive?
Summary
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Engineering Services for the Asphalt Industry
WMA Technology Categories
1. Foaming Processesa. Foaming additives
b. Water injection systems
2. Organic additives3. Chemical additives
4. Hybrid Technologies
3
20 + WMA products marketed in theUnited States fit into one of thesecategories
http://www.warmmixasphalt.com/Default.aspxhttp://www.warmmixasphalt.com/Default.aspx -
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Another WMA Resource
NAPA QualityImprovementPublication 125
3rd Edition
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For Each WMA TechnologyCategory
How does it work?
Temperature reduction
Potential concerns Example products and dosage
How do you use it?
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How Do Foaming ProcessesWork?
Water expands 1600times whenconverted to steam atatmospheric pressure
Water turns to steam Steam is encapsulated by
viscous asphalt binderproducing foam
The foamed asphaltoccupies greater volume
Improves coating andcompaction at lowertemperatures
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Ways to Produce Foamed AsphaltWater Injection
Nozzles on plant
1.25 to 2.0 % water by weightof AC
30 to 50 F reduction in mixingand compaction temperature
Additive
Synthetic zeolites
20 % water
Dose at 0.1 to 0.3 % by weightof mix
50 to 70F reduction in mixingand compaction temperature
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Concerns With FoamingProcesses
Will all binders foam?
Is all foam equal?
How long is the foam effective?
Can foamed asphalt be replicated in thelaboratory for mix design?
These issues are being investigated
in NCHRP Project 9-53, Propertiesof Foamed Asphalt for Warm MixAsphalt Applications
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Example Foaming Processes
Water Injection AESCO/Madsen
Astec
Gencor Herman Grant
Maxam
Meeker
Stansteel Tarmac
Terex
Additive Advera
Aspha-min
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How are Foaming ProcessesUsed
Water Injection Nozzle
Accurate control of AC
and water Plant controls
Additives Weighing system
Conveyor system
Pneumatic
Auger
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How Do Organic AdditivesWork?
Waxes or other
hydrocarbonmodifiers Improve lubrication
Reduce viscosity
Temperatures
50 to 70 F reduction inmixing and compactiontemperature
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Concerns With OrganicAdditives
Grade Changes? Some waxes increase
high PG and decrease
low PG Other organic additives
may decrease bothhigh and low PG
Grade binder afteraddition
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Example Organic Additives &Typical Dosage
Example Products Sasobit
SonneWarmix
ECOBIT
LEADCAP
BituTech WA1
WMA Dosage 0.5 to 1.5 % by weight
of binder
Modifer Dosage 2.0 to 4.0 % by weight
of binder
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How are Organic AdditivesAdded?
Mixing chamber at plant Additive directed into binder
Pneumatic
Auger
Binder supply at plant Tanks with agitation
In-line (molten)
At binder terminal Low shear
Preferred
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How Do Chemical AdditivesWork?
Surfactants (surface active agents) Reduce surface tension between polar aggregate and
non-polar asphalt
Improves wetting and reduces internal friction
Polar Aggregate
Non-Polar AsphaltSurfactant
Molecule
Polar Head
Non-Polar Tail
Temperatures
50 to 90 F reduction in
mixing and compactiontemperature
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Concerns With ChemicalAdditives
Effect on BinderGrade Grade binder with
additive
Aggregatemineralogy andeffectiveness Perform mix design with
additive
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Example Chemical Additives &Typical Dosage
Example Products Evotherm
CECABASE RT
QualiTherm Rediset LQ
LEA Lite
WMA Dosage 0.20 to 0.75 percent by
weight of binder
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How are Chemical AdditivesAdded?
Binder supply at plant
Tanks with agitation
In-line
At binder terminal Preferred
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Hybrid WMA Technologies
Combination of two ormore WMA technologies
Marketed Product
LEA
Created by producer toaddress weaknesses in
a technology Using a chemical additive with
a water injection system toimprove coating at lower
temperatures 19
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WMA Usage
NAPA AsphaltPavement MixProduction Survey
Survey of Producers Categories
DOT
Other Agency Commercial
Technologies
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Estimated Producer WMAUsage
5.4
13.2
0.0
10.0
20.0
2009 2010
Percent of Total Tonnage
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Estimated Producer WMA Usage(by Technology)
15.5% 19.6%1.5% 0.7%
82.7% 78.8%
0.29% 0.88%
2009 2010
Organic
Additive %
Plant Foaming
%
Additive
Foaming %
Chemical
Additive %
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Why Use an Additive?
Ease of Use
Lower EffectiveTemperature Range
Alter Binder Grade
Anti-Strip Properties
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Ease of Use
Greater Use ofWMA
WMA Additives at
Terminal Chemical
Organic
Reduces AdditiveCost
No Modifications
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Lower Temperature Range
-100
-90
-80-70
-60
-50
-40
-30
-20
-100
TemperatureRedu
ction,
F
HMA
Plant Foaming
Foaming & Organic Additives
Chemical Additives
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Alter Binder Grade
Some Organic Additives
Increase High Temperature Grade One to two grade levels
Reduce polymer loading
Decrease Low Temperature Grade High RAP mixtures
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Anti-Strip Properties
Some Chemical Additives
-50.0
-40.0
-30.0
-20.0
-10.0
0.0
10.0
Process A Process B Process C
AverageDiffe
renceinTSR,%
NCHRP 9-43 MixDesign Study
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Key Points
WMA Use is Increasing
Variety of Ways to Produce WMA
Plant Foaming is Most Popular But
Additives are Gaining Market Share Terminal Addition Decreases Cost and
Requires no Plant Modifications
Allow Production at Lower Temperatures Alter Binder Grade
Anti Strip Properties
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Questions/Discussion
Ramon Bonaquist
Advanced Asphalt Technologies, LLC108 Powers Court, Suite 100Sterling, VA 20166703-444-4200