RICE tables are a common tool of chemists (college professors use then a lot!) to organize the...

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USING R.I.C.E. TABLES AND STOICHIOMETRY WITH LIMITING REACTANTS

Transcript of RICE tables are a common tool of chemists (college professors use then a lot!) to organize the...

Page 1: RICE tables are a common tool of chemists (college professors use then a lot!) to organize the information for stoichiometry with a reaction and set up.

USING R.I.C.E. TABLES AND STOICHIOMETRY WITH LIMITING REACTANTS

Page 2: RICE tables are a common tool of chemists (college professors use then a lot!) to organize the information for stoichiometry with a reaction and set up.

RICE tables are a common tool of chemists (college professors use then a lot!) to organize the information for stoichiometry with a reaction and set up mathematical equations when necessary to solve for unknowns.

R = reaction (balanced)I = initial conditions (before the reaction)C = change (remove reactants, form products)E = end conditions (after the reaction)

Page 3: RICE tables are a common tool of chemists (college professors use then a lot!) to organize the information for stoichiometry with a reaction and set up.

Example 1: 10. grams of ethene is combusted. What volume of carbon dioxide will be formed?

Page 4: RICE tables are a common tool of chemists (college professors use then a lot!) to organize the information for stoichiometry with a reaction and set up.

Example 1: 10. grams of ethene is combusted. What volume of carbon dioxide will be formed?

BEWARE: Moles goes into a RICE table and moles will come out. To find volume will require a final step.

Page 5: RICE tables are a common tool of chemists (college professors use then a lot!) to organize the information for stoichiometry with a reaction and set up.

Example 1: 10. grams of ethene is combusted. What volume of carbon dioxide will be formed?

R =

Page 6: RICE tables are a common tool of chemists (college professors use then a lot!) to organize the information for stoichiometry with a reaction and set up.

Example 1: 10. grams of ethene is combusted. What volume of carbon dioxide will be formed?

R = C2H4 + 3O2 → 2CO2 + 2H2O

Page 7: RICE tables are a common tool of chemists (college professors use then a lot!) to organize the information for stoichiometry with a reaction and set up.

Example 1: 10. grams of ethene is combusted. What volume of carbon dioxide will be formed?

R = C2H4 + 3O2 → 2CO2 + 2H2O

I =

Page 8: RICE tables are a common tool of chemists (college professors use then a lot!) to organize the information for stoichiometry with a reaction and set up.

Example 1: 10. grams of ethene is combusted. What volume of carbon dioxide will be formed?

R = C2H4 + 3O2 → 2CO2 + 2H2O

I = 10. g

Page 9: RICE tables are a common tool of chemists (college professors use then a lot!) to organize the information for stoichiometry with a reaction and set up.

Example 1: 10. grams of ethene is combusted. What volume of carbon dioxide will be formed?

R = C2H4 + 3O2 → 2CO2 + 2H2O

I = 10. g0.625 mol ? 0 0

Page 10: RICE tables are a common tool of chemists (college professors use then a lot!) to organize the information for stoichiometry with a reaction and set up.

Example 1: 10. grams of ethene is combusted. What volume of carbon dioxide will be formed?

R = C2H4 + 3O2 → 2CO2 + 2H2O

I = 10. g0.625 mol ? 0 0

C =

Page 11: RICE tables are a common tool of chemists (college professors use then a lot!) to organize the information for stoichiometry with a reaction and set up.

Example 1: 10. grams of ethene is combusted. What volume of carbon dioxide will be formed?

R = C2H4 + 3O2 → 2CO2 + 2H2O

I = 10. g0.625 mol ? 0 0

C = -1x -3x +2x +2x

Page 12: RICE tables are a common tool of chemists (college professors use then a lot!) to organize the information for stoichiometry with a reaction and set up.

Example 1: 10. grams of ethene is combusted. What volume of carbon dioxide will be formed?

R = C2H4 + 3O2 → 2CO2 + 2H2O

I = 10. g0.625 mol ? 0 0

C = -1x -3x +2x +2xall the ethene will be burned, so x = 0.63 mol

Page 13: RICE tables are a common tool of chemists (college professors use then a lot!) to organize the information for stoichiometry with a reaction and set up.

Example 1: 10. grams of ethene is combusted. What volume of carbon dioxide will be formed?

R = C2H4 + 3O2 → 2CO2 + 2H2O

I = 10. g0.625 mol ? 0 0

C = -1x -3x +2x +2x-0.625 mol -1.875 mol +1.25 mol +1.25 mol

Page 14: RICE tables are a common tool of chemists (college professors use then a lot!) to organize the information for stoichiometry with a reaction and set up.

Example 1: 10. grams of ethene is combusted. What volume of carbon dioxide will be formed?

R = C2H4 + 3O2 → 2CO2 + 2H2O

I = 10. g0.625 mol ? 0 0

C = -1x -3x +2x +2x-0.625 mol -1.875 mol +1.25 mol +1.25 mol

E =

Page 15: RICE tables are a common tool of chemists (college professors use then a lot!) to organize the information for stoichiometry with a reaction and set up.

Example 1: 10. grams of ethene is combusted. What volume of carbon dioxide will be formed?

R = C2H4 + 3O2 → 2CO2 + 2H2O

I = 10. g0.625 mol ? 0 0

C = -1x -3x +2x +2x-0.625 mol -1.875 mol +1.25 mol +1.25 mol

E = 0 ?-1.875 mol 1.25 mol 1.25 mol

Page 16: RICE tables are a common tool of chemists (college professors use then a lot!) to organize the information for stoichiometry with a reaction and set up.

Example 1: 10. grams of ethene is combusted. What volume of carbon dioxide will be formed?

How many moles of CO2 was formed?

Page 17: RICE tables are a common tool of chemists (college professors use then a lot!) to organize the information for stoichiometry with a reaction and set up.

Example 1: 10. grams of ethene is combusted. What volume of carbon dioxide will be formed?

How many moles of CO2 was formed? 1.3 mol

Page 18: RICE tables are a common tool of chemists (college professors use then a lot!) to organize the information for stoichiometry with a reaction and set up.

Example 1: 10. grams of ethene is combusted. What volume of carbon dioxide will be formed?

How many moles of CO2 was formed? 1.3 molWhat volume of CO2 was formed?

Page 19: RICE tables are a common tool of chemists (college professors use then a lot!) to organize the information for stoichiometry with a reaction and set up.

Example 1: 10. grams of ethene is combusted. What volume of carbon dioxide will be formed?

How many moles of CO2 was formed? 1.3 molWhat volume of CO2 was formed?

1.25 mol x 22.4 L/mol = 28 L

Page 20: RICE tables are a common tool of chemists (college professors use then a lot!) to organize the information for stoichiometry with a reaction and set up.

Example 1: 10. grams of ethene is combusted. What volume of carbon dioxide will be formed?

How many moles of CO2 was formed? 1.3 molWhat volume of CO2 was formed?

1.25 mol x 22.4 L/mol = 28 L

What other information do we already know?

Page 21: RICE tables are a common tool of chemists (college professors use then a lot!) to organize the information for stoichiometry with a reaction and set up.

Example 1: 10. grams of ethene is combusted. What volume of carbon dioxide will be formed?

How many moles of CO2 was formed? 1.3 molWhat volume of CO2 was formed?

1.25 mol x 22.4 L/mol = 28 L

What other information do we already know?• Moles of O2 consumed• Moles of H2O produced

Page 22: RICE tables are a common tool of chemists (college professors use then a lot!) to organize the information for stoichiometry with a reaction and set up.

Example 2: 10. grams of ethene is combusted with 50. grams of O2. What volume of carbon dioxide can be formed?

Page 23: RICE tables are a common tool of chemists (college professors use then a lot!) to organize the information for stoichiometry with a reaction and set up.

Example 2: 10. grams of ethene is combusted with 50. grams of O2. What volume of carbon dioxide can be formed?

R = C2H4 + 3O2 → 2CO2 + 2H2O

Page 24: RICE tables are a common tool of chemists (college professors use then a lot!) to organize the information for stoichiometry with a reaction and set up.

Example 2: 10. grams of ethene is combusted with 50. grams of O2. What volume of carbon dioxide can be formed?

R = C2H4 + 3O2 → 2CO2 + 2H2O

I = 10. g 50. g0.625 mol 1.56 mol

Page 25: RICE tables are a common tool of chemists (college professors use then a lot!) to organize the information for stoichiometry with a reaction and set up.

Example 2: 10. grams of ethene is combusted with 50. grams of O2. What volume of carbon dioxide can be formed?

R = C2H4 + 3O2 → 2CO2 + 2H2O

I = 10. g 50. g0.625 mol 1.56 mol

C = -1x -3x +2x +2xWHICH X TO USE? SMALLEST X!

Page 26: RICE tables are a common tool of chemists (college professors use then a lot!) to organize the information for stoichiometry with a reaction and set up.

Example 2: 10. grams of ethene is combusted with 50. grams of O2. What volume of carbon dioxide can be formed?

R = C2H4 + 3O2 → 2CO2 + 2H2O

I = 10. g 50. g0.625 mol 1.56 mol

C = -1x -3x +2x +2xWHICH X TO USE? SMALLEST X!

If 0.625 = 1 x, then x = 0.625If 1.56 = 3 x, then x = 0.521 ← SMALLEST

Page 27: RICE tables are a common tool of chemists (college professors use then a lot!) to organize the information for stoichiometry with a reaction and set up.

Example 2: 10. grams of ethene is combusted with 50. grams of O2. What volume of carbon dioxide can be formed?

R = C2H4 + 3O2 → 2CO2 + 2H2O

I = 10. g 50. g0.625 mol 1.56 mol

C = -1x -3x +2x +2x-0.521 mol -1.56 mol +1.04 mol 1.04 mol

Page 28: RICE tables are a common tool of chemists (college professors use then a lot!) to organize the information for stoichiometry with a reaction and set up.

Example 2: 10. grams of ethene is combusted with 50. grams of O2. What volume of carbon dioxide can be formed?

R = C2H4 + 3O2 → 2CO2 + 2H2O

I = 10. g 50. g0.625 mol 1.56 mol

C = -1x -3x +2x +2x-0.521 mol -1.56 mol +1.04 mol 1.04 mol

E = 0.625 mol – 0.521 mol 1.56 mol – 1.56 mol 1.04 mol 1.04 mol

0.104 mol 0 1.04 mol 1.04 mol

Page 29: RICE tables are a common tool of chemists (college professors use then a lot!) to organize the information for stoichiometry with a reaction and set up.

Example 2: 10. grams of ethene is combusted with 50. grams of O2. What volume of carbon dioxide can be formed?

What volume of CO2 is actually produced?1.04 mols x 22.4 L/mol = 23 L

Page 30: RICE tables are a common tool of chemists (college professors use then a lot!) to organize the information for stoichiometry with a reaction and set up.

Example 2: 10. grams of ethene is combusted with 50. grams of O2. What volume of carbon dioxide can be formed?

What volume of CO2 is actually produced?1.04 mols x 22.4 L/mol = 23 L

What else do we know?• Moles of ethene left over• Moles of water actually produced

Page 31: RICE tables are a common tool of chemists (college professors use then a lot!) to organize the information for stoichiometry with a reaction and set up.

Why use a RICE table for limiting reactant problems?

How many RR tracks would it have taken?

Page 32: RICE tables are a common tool of chemists (college professors use then a lot!) to organize the information for stoichiometry with a reaction and set up.

Why use a RICE table for limiting reactant problems?

How many RR tracks would it have taken?2 to figure out which one is limiting

Page 33: RICE tables are a common tool of chemists (college professors use then a lot!) to organize the information for stoichiometry with a reaction and set up.

Why use a RICE table for limiting reactant problems?

How many RR tracks would it have taken?2 to figure out which one is limiting1 more to find amount of excess

Page 34: RICE tables are a common tool of chemists (college professors use then a lot!) to organize the information for stoichiometry with a reaction and set up.

Why use a RICE table for limiting reactant problems?

How many RR tracks would it have taken?2 to figure out which one is limiting1 more to find amount of excess1 more for each of the additional products

Page 35: RICE tables are a common tool of chemists (college professors use then a lot!) to organize the information for stoichiometry with a reaction and set up.

Why use a RICE table for limiting reactant problems?

How many RR tracks would it have taken?2 to figure out which one is limiting1 more to find amount of excess1 more for each of the additional products

It is your choice. We did 1 RICE table vs 4 RR Tracks.RICE tables will be necessary later. For now, it is optional.