Revision : Thermodynamics
Transcript of Revision : Thermodynamics
Thermodynamics key facts (1/9)
โข Heat is an energy [measured in ๐ฝ๐ฝ] which flows from high to low temperature
โข When two bodies are in thermal equilibrium they have the same temperature
โข The S.I. unit of temperature is Kelvin (๐พ๐พ). This is related to degrees Celsius โ by
โข Temperature difference ฮ๐๐ is the same in both units
๐๐ ๐พ๐พ = ๐๐ โ + 273
Thermodynamics key facts (2/9)
โข Heat energy needed to raise a temperature
โข The specific heat capacity ๐๐ determines the energy ๐๐ needed to raise the temperature of mass ๐๐ of a substance by โ๐๐
โข Units of ๐๐ will be ๐ฝ๐ฝ ๐๐๐๐โ1 ๐พ๐พโ1
๐๐ = ๐๐ ๐๐ โ๐๐
Thermodynamics key facts (3/9)
โข Heat energy needed to change phase
โข The latent heat ๐ฟ๐ฟ determines the energy ๐๐needed to change the phase of a mass ๐๐
โข Units of ๐ฟ๐ฟ will be ๐ฝ๐ฝ ๐๐๐๐โ1 - can be fusion or vaporization
โข This energy is either absorbed (solid โ liquid โ gas) or released (gas โ liquid โ solid)
โข A phase change takes place at constant temperature
๐๐ = ๐๐ ๐ฟ๐ฟ
Thermodynamics key facts (4/9)
โข Conduction is heat energy transfer by direct molecular contact
Thickness โ๐ฅ๐ฅ
๐๐ + โ๐๐ ๐๐
Heat transfer
Area ๐ด๐ด
Power = โ๐๐โ๐ก๐ก
= ๐ ๐ ๐ด๐ด ฮ๐๐ฮ๐ฅ๐ฅ
๐ ๐ = thermal conductivity
Thermodynamics key facts (6/9)
โข Radiation is heat energy transfer by emission of electromagnetic radiation
Power = โ๐๐โ๐ก๐ก
= ๐๐ ๐ด๐ด ๐๐4
๐๐ = Stefan-Boltzmann constant, ๐ด๐ด = surface area of emitter, ๐๐ = temperature of emitter (assumes emissivity=1)
Thermodynamics key facts (7/9)
โข Ideal gas law
โข 1st form : ๐๐ ๐๐ = ๐๐ ๐๐๐ต๐ต ๐๐
โข ๐๐ = Pressure, ๐๐ = Volume, ๐๐ = number of molecules, ๐๐๐ต๐ต = Boltzmannโs constant, ๐๐ = temperature [in K]
โข 2nd form : ๐๐ ๐๐ = ๐๐ ๐ ๐ ๐๐
โข ๐๐ = number of moles, ๐ ๐ =gas constant
Thermodynamics key facts (8/9)
โข Kinetic theory of ideal gas
โข Pressure is due to molecular collisions
โข Average kinetic energy of molecules depends on temperature
12๐๐๐ฃ๐ฃ2 = 3
2๐๐๐ต๐ต๐๐๐๐ = mass of molecule, ๐ฃ๐ฃ2 = average square speed, ๐๐ = temperature
Thermodynamics key facts (9/9)
โข Thermal expansion
โข Materials expand due to temperature rise โ๐๐
โข Length ๐ฟ๐ฟ increases by โ๐ฟ๐ฟ = ฮฑ ๐ฟ๐ฟ โ๐๐ where ๐ผ๐ผ =coefficient of linear expansion
โข Volume V increases by โ๐๐ = ๐ฝ๐ฝ ๐๐ โ๐๐ where๐ฝ๐ฝ = coefficient of volume expansion
Practice exam questions: Section A
๐๐ = ๐๐ ๐๐ โ๐๐๐๐ = ๐๐๐ค๐ค๐ค๐ค๐ก๐ก๐ค๐ค๐ค๐ค๐๐๐ค๐ค๐ค๐ค๐ก๐ก๐ค๐ค๐ค๐คโ๐๐๐ค๐ค๐ค๐ค๐ก๐ก๐ค๐ค๐ค๐ค= 1 ร 4186 ร 5 = 20930 ๐ฝ๐ฝ
โ๐๐๐ด๐ด๐ด๐ด=๐๐
๐๐๐ด๐ด๐ด๐ด๐๐๐ด๐ด๐ด๐ด=
209302 ร 900 = 12 ๐พ๐พ
Option B
๐พ๐พ๐พ๐พ = 12๐๐๐ฃ๐ฃ
2 = 32๐๐๐ต๐ต๐๐ Option C
Practice exam questions: Section A
Reflects radiation โ option A
Fractional expansion is the same โ option A
ฮ๐ฟ๐ฟ๐ฟ๐ฟ
= ๐ผ๐ผ ฮ๐๐
Practice exam questions: Section B
๐๐ = ๐๐ ๐๐ โ๐๐ = 2.2 ร 900 ร 18 = 3.6 ร 104 ๐ฝ๐ฝ
Practice exam questions: Section B
Stefan-Boltzmann law: ๐๐ = ๐๐ ๐ด๐ด ๐๐4
Re-arranging: ๐ด๐ด = ๐๐๐๐ ๐๐4
= 705.67ร10โ8ร 2800 4 = 2.0 ร 10โ5 ๐๐2
Practice exam questions: Section B
Ideal gas law (using moles): ๐๐๐๐ = ๐๐๐ ๐ ๐๐
๐๐ = 2.2 ๐๐๐๐๐๐๐๐๐๐๐๐ = 2.2 ร 10โ3 ๐๐3
๐๐ = โ130 + 273 = 143 ๐พ๐พ
๐๐ =๐๐๐ ๐ ๐๐๐๐
=2.9 ร 8.31 ร 143
2.2 ร 10โ3= 1.6 ร 106 ๐๐๐๐
Practice exam questions: Section C
๐๐ = ๐๐๐ค๐ค๐ค๐ค๐ก๐ก๐ค๐ค๐ค๐ค๐๐๐ค๐ค๐ค๐ค๐ก๐ก๐ค๐ค๐ค๐คโ๐๐ +๐๐๐๐๐๐๐๐๐๐๐ค๐ค๐ค๐ค๐๐๐๐๐๐๐๐๐๐๐ค๐ค๐ค๐คโ๐๐
๐๐ = 0.35 ร 4186 ร 3.3 + 0.25 ร 387 ร 3.3 = 5150 ๐ฝ๐ฝ
๐๐ = ๐๐๐๐๐๐๐ค๐ค๐ฟ๐ฟ๐๐ +๐๐๐๐๐๐๐ค๐ค๐๐๐ค๐ค๐ค๐ค๐ก๐ก๐ค๐ค๐ค๐คโ๐๐ = 5150 ๐ฝ๐ฝ
๐ฟ๐ฟ๐๐ =5150โ (0.012 ร 4186 ร 21.7)
0.012= 3.39 ร 105 ๐ฝ๐ฝ/๐๐๐๐
Practice exam questions: Section C
Heat loss rate = ๐ ๐ ๐ด๐ด ฮ๐๐โ๐ฅ๐ฅ
= 0.80 ร 5.0 ร 132.4ร10โ3
= 2.2 ร 104 ๐๐
Practice exam questions: Section C
Atomic mass = 4.0 ร 1.66 ร 10โ27 = 6.64 ร 10โ27 ๐๐๐๐
12๐๐๐ฃ๐ฃ๐ค๐ค๐๐๐๐
2 = 32๐๐๐ต๐ต๐๐
๐ฃ๐ฃ๐ค๐ค๐๐๐๐ =3๐๐๐ต๐ต๐๐๐๐ =
3 ร 1.38 ร 10โ23 ร 4006.64 ร 10โ27 = 1.58 ร 103 ๐๐ ๐๐โ1
๐๐ = 127 + 273 = 400 ๐พ๐พ
Practice exam questions: Section C
๐๐ = ๐๐๐๐๐๐๐๐๐๐ ร ๐๐๐๐๐๐๐๐ = 2.2 ร 103 ร 5.9 ร 60 = 7.8 ร 105 ๐ฝ๐ฝ
๐๐ = ๐๐ ๐๐ โ๐๐
๐๐ =๐๐๐๐ โ๐๐
=7.8 ร 105
4186 ร 79= 2.4 ๐๐๐๐
Next steps
โข Make sure you are comfortable with unit conversions
โข Review the thermodynamics key facts
โข Familiarize yourself with the thermodynamics section of the formula sheet
โข Try questions from the sample exam papers on Blackboard and/or the textbook
Electricity key facts (1/9)
โข Electric charge ๐๐ is an intrinsic property of the particles that make up matter, and can be positive (e.g. proton) or negative (e.g. electron)
โข The S.I. unit of charge is Coulombs (๐ถ๐ถ)
โข The elementary charge (on a proton or electron) is ยฑ 1.6 ร 10โ19 ๐ถ๐ถ
โข Electric current ๐ผ๐ผ is the rate of flow of charge
๐ผ๐ผ =โ๐๐โ๐๐
๐ผ๐ผ is measured in Amperes (๐ด๐ด)
Electricity key facts (2/9)
โข Coulombโs Law gives the force felt by two charges ๐๐1 and ๐๐2 separated by distance ๐๐
โข Like charges repel, opposite charges attract
๐๐1 ๐๐2๐น๐น ๐น๐น
๐๐
๐น๐น =๐๐ ๐๐1 ๐๐2๐๐2
๐๐ = 9 ร 109 ๐๐ ๐๐2 ๐ถ๐ถโ2
Electricity key facts (2/9)
โข Superposition principle for Coulombโs Law :if there are multiple charges, the forces from individual charges sum like vectors
+ve
+ve
+ve ๐น๐น๐ก๐ก๐๐๐ก๐ก๐ค๐ค๐ด๐ด = ๐น๐น1 + ๐น๐น2
๐น๐น1
๐น๐น2
Electricity key facts (3/9)
โข The electric field at a point is the force a unit charge (๐๐ = 1 ๐ถ๐ถ) would experience there
โข Can be represented by electric field lines
๐พ๐พ =๏ฟฝโ๏ฟฝ๐น๐๐
๏ฟฝโ๏ฟฝ๐น = ๐๐ ๐พ๐พ
Positive charge feels force along electric field line
Negative charge feels force the other way
Electricity key facts (4/9)
โข The electric potential difference ฮ๐๐ [in volts] is the work needed to move unit charge (๐๐ = 1 ๐ถ๐ถ)between 2 points
โข Electric field is the potential gradient : ๐พ๐พ = โโ๐๐โ๐ฅ๐ฅ
Work done = Potential Energy difference = ๐๐ ฮ๐๐
If capacitor with plate separation ๐ท๐ท is connected to battery with potential ๐๐, then ๐พ๐พ = ๐๐/๐ท๐ท
Electricity key facts (5/9)
โข Basic circuit principles : current ๐ผ๐ผ is driven by a potential difference ๐๐
Same current flows through all components of a series circuit
Same voltage is dropped over all components of a parallel circuit
Electricity key facts (6/9)
โข Ohmโs Law determines the current flowing through a resistance ๐ ๐
โข Resistance is measured in Ohms (ฮฉ)
๐ผ๐ผ =๐๐๐ ๐
๐๐ = ๐ผ๐ผ ๐ ๐
Electricity key facts (6/9)
โข Resistances may be combined in series or parallel
๐ ๐ 1 ๐ ๐ 2๐ ๐ ๐ก๐ก๐๐๐ก๐ก๐ค๐ค๐ด๐ด = ๐ ๐ 1 + ๐ ๐ 2
๐ ๐ 1
๐ ๐ 21
๐ ๐ ๐ก๐ก๐๐๐ก๐ก๐ค๐ค๐ด๐ด=
1๐ ๐ 1
+1๐ ๐ 2
[R increases]
[R decreases]
Electricity key facts (7/9)
โข Electrical energy is dissipated as heat by a resistor
โข Electrical Power ๐๐ = ๐ผ๐ผ ๐๐ = ๐ผ๐ผ2๐ ๐ = ๐๐2
๐ ๐ [unit is W]
Electricity key facts (8/9)
โข A capacitor is a device to store charge. Its capacitance ๐ถ๐ถ measures the amount of charge ๐๐that can be stored for given potential difference ๐๐
๐ถ๐ถ =๐๐๐๐
๐๐ = ๐ถ๐ถ ๐๐+๐๐ โ๐๐
๐๐
โข Capacitance is measured in Farads (๐น๐น)
โข Capacitors may be combined in series or parallel [see lectures]
Electricity key facts (9/9)
โข General circuits may be analysed using Kirchoffโs rules
โข Signs are different for inward/outward current
โข This rule arises from conservation of charge
Kirchoffโs junction rule : the sum of currents at any junction is zero ๐ผ๐ผ2
๐ผ๐ผ1
๐ผ๐ผ3
๐ผ๐ผ1 + ๐ผ๐ผ2 โ ๐ผ๐ผ3 = 0
Electricity key facts (9/9)
โข General circuits may be analysed using Kirchoffโs rules
โข Battery adds potential ๐๐, resistors subtract potential ๐ผ๐ผ๐ ๐
โข This rule arises from conservation of energy
Kirchoffโs loop rule : the sum of voltage changes around a closed loop is zero 2 ฮฉ
9 ๐๐๐ผ๐ผ2
4 ฮฉ ๐ผ๐ผ1
9 โ 4 ๐ผ๐ผ1 โ 2 ๐ผ๐ผ2 = 0
Practice exam questions: Section A
Coulombโs Law: ๐น๐น = ๐๐ ๐๐1 ๐๐2๐ค๐ค2
Double ๐๐ โ ๐น๐น decreases by 14
โ option A
Current is the same โ ๐๐ = ๐ผ๐ผ ๐ ๐ โ smaller voltage across smaller ๐ ๐ โ option B
Practice exam questions: Section B
๐๐ = ๐๐ โ๐๐๐ด๐ด๐ต๐ต
โ๐๐๐ด๐ด๐ต๐ต=๐๐๐๐
=45
15 ร 10โ3= 3000 ๐๐
Practice exam questions: Section B
Ohmโs Law: ๐ผ๐ผ = ๐๐๐ ๐
= 11047ร103
= 2.3 ร 10โ3 ๐ด๐ด
Practice exam questions: Section B
1๐ ๐ ๐ก๐ก๐๐๐ก๐ก๐ค๐ค๐ด๐ด
=1๐ ๐ 1
+1๐ ๐ 2
145
=1
56+
1๐ ๐ 2
๐ ๐ 2 = 230 ๐๐ฮฉ
Practice exam questions: Section C
๐ผ๐ผ1 + ๐ผ๐ผ2 โ ๐ผ๐ผ3 = 0
10 โ 6๐ผ๐ผ1 โ 2๐ผ๐ผ3 = 0 5 โ 3๐ผ๐ผ1 โ ๐ผ๐ผ3 = 0
โ4๐ผ๐ผ2 โ 14 + 6๐ผ๐ผ1 โ 10 = 0
โ2๐ผ๐ผ2 โ 12 + 3๐ผ๐ผ1 = 0
Practice exam questions: Section C
๐๐๐๐๐๐ = โ10 + ๐๐6ฮฉ = 2 ๐๐ โ ๐๐6ฮฉ = 12 ๐๐
๐ผ๐ผ1 =๐๐๐ ๐
=126
= 2 ๐ด๐ด
From before: 5 โ 3๐ผ๐ผ1 โ ๐ผ๐ผ3 = 0
๐ผ๐ผ3 = 5 โ 3๐ผ๐ผ1 = 5โ 3 ร 2 = โ1 ๐ด๐ด
Practice exam questions: Section C
From before:โ2๐ผ๐ผ2 โ 12 + 3๐ผ๐ผ1 = 0
๐ผ๐ผ2 =3๐ผ๐ผ1 โ 12
2=โ62
= โ3 ๐ด๐ด
๐๐ = ๐ผ๐ผ32๐ ๐ = โ1 2 ร 2 = 2 ๐๐
Practice exam questions: Section C
Combine the 2ฮฉ, 4ฮฉ, 6ฮฉ resistors in parallel1
๐ ๐ ๐๐๐ค๐ค๐ค๐ค๐ค๐ค๐ด๐ด๐ด๐ด๐ค๐ค๐ด๐ด=
12
+14
+16โ ๐ ๐ ๐๐๐ค๐ค๐ค๐ค๐ค๐ค๐ด๐ด๐ด๐ด๐ค๐ค๐ด๐ด = 1.1 ฮฉ
Combine the 1ฮฉ, 1.1ฮฉ resistors in series ๐ ๐ ๐ก๐ก๐๐๐ก๐ก๐ค๐ค๐ด๐ด = 2.1 ฮฉ
Ohmโs Law: ๐ผ๐ผ = ๐๐๐ ๐ ๐ก๐ก๐ก๐ก๐ก๐ก๐ก๐ก๐ก๐ก
= 62.1
= 2.9 ๐ด๐ด
Practice exam questions: Section C
Voltage across parallel combination = 1.12.1
ร 6 ๐๐ = 3.1 ๐๐
๐ผ๐ผ =๐๐๐ ๐
=3.16
= 0.52 ๐ด๐ด