REPORT OH FOR PRIORITY POLLUTANT ANALYSIS · FOR PRIORITY POLLUTANT ANALYSIS AND WASTE...
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REPORT OH JACKSONVILLE OFFSITE SAMPLE COLLECTIONS FOR PRIORITY POLLUTANT ANALYSIS AND WASTE CHARACTERIZATION Submitted to: HERCULES INCORPORATED Wilmington, Delaware Prepared by: IT CORPORATION Knoxville, Tennessee October 1988 03217654
Transcript of REPORT OH FOR PRIORITY POLLUTANT ANALYSIS · FOR PRIORITY POLLUTANT ANALYSIS AND WASTE...
REPORT OHJACKSONVILLE OFFSITE SAMPLE COLLECTIONS
FOR PRIORITY POLLUTANT ANALYSISAND WASTE CHARACTERIZATION
Submitted to:HERCULES INCORPORATEDWilmington, Delaware
Prepared by:IT CORPORATION
Knoxville, Tennessee
October 198803217654
REPORT OHJACKSONVILLE OFFSITE SAMPLE COLLECTIONS
FOR PRIORITY POLLUTANT ANALYSIS
AND WASTE CHARACTERIZATION
INTRODUCTION KOn July 21 and 22, 1988, thirteen surface sediment samples were c
0collected from the Jacksonville Wastewater Treatment Plant,Jacksonville, Arkansas, for priority pollutant and incineration <"'Cwaste characterization analyses. These samples were collectedconcurrently with the Fine Grid Sampling Program by IT Corpora-tion, a wholly owned subsidiary of International TechnologyCorporation. The Fine Grid Sampling Program was executed incompliance with the Administrative Order on Consent between theUnited States Environmental Protection Agency (USEPA), Region VI,and Hercules Incorporated, Wilmington, Delaware.
1.0 SAMPLING METHODOLOGY
The sediment samples were collected and composited according tothe USEPA approved procedures described below. All equipmentused for sampling was decontaminated prior to use and betweensample collections according to USEPA approved methodology.
1-1 Sediment Sampling procedureThe top sediment (or sludge) in each pond or basin was collectedusing an Eckman dredge. The dredge was lowered from a boat untilit settled on top of the sludge, then the closing mechanism was
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triggered and the dredge was retrieved. A stainless steel spoonor scoop was used to transfer the sample to a rectangularaluminum pan for compositing.
1.2 Sample Compositing ProcedureAll aliquots of one composite sample were approximately the samemass. Once the aliquots of one composite sample were collected 0-3
•^and placed in the aluminum pan, the sediment was mixed thorough- c\ily with a stainless steel spoon until visibly homogenous. Afterhomogenization, an imaginary grid was drawn on the pan, dividingit into four or six equal sections. An aliquot was taken fromeach section moving in a clockwise direction and placed into theappropriate glass sample jar. The contents of the pan were mixedagain, and four or six more portions were placed into the samplejar. This procedure was repeated until an adequate volume ofsample was collected in the sample jar. Then the sample jar wassealed with a teflon-lined lid. Using the same procedure,additional sample jars were filled in order to meet the analyti-cal requirements. For volatile organics analysis, the samplecontainer was filled completely to minimize head space.
1.3 Sample HandlingSample containers were selected according to EPA ContractLaboratory Program protocol. All samples were labeled andpackaged for shipment according to guidelines established by theEPA.
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For those samples submitted for tetrachlorodibenzo-p-dioxin(TCDD) analysis as well as the analyses described in this report,the sample containers for TCDD analysis were filled with samplematerial first and then from the same composited materialadditional sample jars were filled for the priority pollutant,etc. analyses. Then all the sample jars were labeled with thesame sample number. The TCDD sample and analytical informationis described in the Report on Fine Grid Sampling Plan (For TCDDand 2,3 , 7 , 8 - T C D D ) .
1.4 Sample Documentation and Chain-of-CustodyThe sample custody and documentation procedures used for thesesamples conform to the requirements established in the USEPA'sTest Methods for Evaluating Solid Wastes. (SW-846). Field sampleinformation was recorded in a field logbook and on individualcollection log forms. The information was then entered into acomputerized database for tabulation and reporting.
2 . 0 SAMPLE LOCATIONS
The thirteen sediment samples were collected from two areasinitially described in the Fine Grid Sampling Plan as Area F andAreas Gl and G2. These two areas are the aeration basin ( F ) andthe north and south oxidation ponds (G1/G2) at the JacksonvilleWastewater Treatment Plant. The specific sampling strategy isdescribed below.
2.1 Area F: Aeration Basin (Jacksonville Wastewater Treatment)The aeration basin was divided into four equal quadrants: north,north-east, south, and south-west. One top sediment (or sludge)composite sample was collected from each quadrant. Each com-posite sample was composed of six aliquots collected fromlocations spaced evenly throughout the quadrant. These locationswere determined by the on-site EPA Remedial Project Manager(RPM). In addition, one sediment sample composed of 24 ali-quots, was collected from locations throughout the entire basin.
2.2 Areas G1/G2: Oxidation Ponds (Jacksonville WastewaterTreatment)
The north pond was identified as Gl, the south as G2. Each pondwas divided into two equal sections, east and west. One topsediment composite sample, consisting of four aliquots, wascollected in each section, for a total of four composite samples.In addition, two composite samples were collected from each pondby combining eight aliquots taken from the entire oxidation pond.The aliquot locations were spaced evenly throughout the ponds andwere determined on-site by the EPA RPM.
Table 1 contains a list of the sample numbers and the correspond-ing field identification information.
3.0 ANALYTICAL PROGRAMThe sediment samples were shipped via Federal Express to ITAnalytical Services (ITAS) in Knoxville, Tennessee. The fol-
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lowing analyses were performed by EPA Contract Laboratory Program(CLP) procedures: Priority pollutant volatile organics analysis(VGA) and priority pollutant base, neutral, acid (BNA) ex-tractable organics analysis, also called semi-volatiles, by GasChromatography/Mass Spectrometry (GC/MS); priority pollutant !^"pesticides/PCBs analysis by Gas Chromatography ( G C ) ; phenoxy 0
C\iherbicides by GC; and priority pollutant metals plus Barium e -analysis by Atomic Absorption. Also, three samples were analyzedfor waste characterization parameters; a subset of these analyseswas performed by Galbraith Laboratories in Knoxville, Tennessee.
A description of the analytical procedures and a summary tablelisting the sample numbers, along with the corresponding analysesperformed on each, are presented in the Laboratory Report CaseNarrative. The analytical results may be found in the CLP datapackage report.
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TABLE 1MCXamVILLE (IFFSITi SICIMmT SAIffLiS COHECTED M
IN JKKSUVILLf. ARKAKStSMIALYZID <T IHS-KIIOXVIUi. IEIBISSEE
PIKUtCI 11B1BEB 480B78
3»MPU;LOC*TIMI DESCIiIPTlOB StMPLE/MCHIIOIl CISC [ai»T. 1
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SLOBGE. EAST EKI OF 1108IH OXIDAnOI mmi. TOP SEDIIlEm/SHIIIGE.
SLilDCE. liEST E11D OF SOUTH OXIDATMI PCNE. TOP 3BI«EMT/SLI)B;E.
aUDtE. EAST E1B OF SOITH OXIDATIOH POHD. TOP SEDIHBT/SLIBCi.
SLaDGE. IOIITH OXIDATIOII POBD. TOP sicmEin/siBDGE. EIITIIIE FOIID.SLIBGE. SOOffl OXIDATION FOIIl. IW SEI)IHE11T/SII)1)6E. BTrliE POIID.
SLUDGE. HOBIK OXIDAIION Pom. TOP SEBIIlEIH/SinillSE. EUTIRE POKI.
SlUCGE. SOBTH OHCATIOII POIIC. TOP SEDBEW/SLUDCE. E11TI8E POlll).
SSSKI. Km aimsm OF AEIATIOII BA5i». TOP SEDIIIEIIT/SLUCGE.SLIIDCE.KOBTH-EAST 3UADBA«T AE8ATKM aiSIK. TOP SECIHEHT/SIODGE.
3LIBCE. SOUTH IHIA£|BA11T AEBAIIOII BASH. TOP SEtlBIBff/SUBCE.
atlCCE.SOUTH-aEST WOUM AtlATION BASB. TOP SEDIMEHT/SUBCE.
SiaME. AE11ATB» BASH. CaiPCSIB. ENtIBE BASIH.
lias
DEPIBOrTAKE
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SAMPLE ANALYSIS DATA PACKAGE
ITAS PROJECT CODE ITFK 41695
JACKSONVILLE OFFSITE
AUGUST 31, 19SS
VOLUME I
RESPONSIVE TO THE NEEDS OF ENVIRONMENTAL MANAGEMENT
Cas. » U^ <fcSample D«Uv«ry Group f W^a^il.
ITAS Project f /r^^t^y
SAMPLE DATA SIMURT
Lab naa«i f^. IfuoxuiLLe
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Contract; ______
Lab Cod*: |-[ yiu Ca«« MO.: ^11.95 S*S Mo.; _____ SDQ Mo.; ^Hg7o(.
Matrix: (•oil/vafr)_^^_ L^ Saapr IDS uai.ai?-7t
Saapl* wt/vol: tj (g/l.) G lAto ril« IDt UHio727l
Lavl; (low/B«d) M60
t Moiitur*: not d«e.
coluan; (pack/cap) 'PACK
Oaf Xaeeivad: o'!n?2-Z3/8B
Oaf Analyxad: o-7/e-?7flB
Dilution raetor: J^S-
CONCHrrXATZON OltITSl(u»/X. or ug/Kg) u& JfcGCAS NO. COHPOUNO
74-«3-»—————Bro»o»»than«
7a-oo-3———chloro<tl»an««7-*4-l———*e«ton»7S-ia-o———c«rBon bi«ulfid«7S-3S-4————l.l-Olehlowthan« ,
S40-S9-0———1,2-Dlehlero««b*a« (total)
l07-o<-2———l.a-0iehlero<tt»<i»»7«-93-3————2-Bufnon«7i-5S-<———l, l, l-Triehloro«CJMA«a»-23-a——————carbon T«traehlorid«
7S«27-4——«—lroBodiehlaroMthur
loo<l-oi-5——cl«-l,3-OicbieTopro»w7«-Ol-«——————Trlahlon*th«n«
7«<00-S—————1.1.2<Triehlo»thur
loo<l-02-»——tCTir-l,3-Dleaioropre»tr^78-25-2- •gO——gQflo«-LO-l——«~—4'4tothvl-i-kn^*non«5»l-7»-€—————a-—XM»e«»»137 -H -4————T«tr«chlera«th«n«7»-34-5————1,1,2,2«Tfltr«eblo:FoitEan*10»-f-3————TolU«»10«-»0-7 —————chlorobmiur100-41-4—————BtBylbWIIW100-42-S—————«tyrtr1330-20-7————•XvilM ^ai«IS
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VOLATILE ORSANICS ANALYSIS DATA SHEET erA •'A;'''-- :''; •TENTATIVELY IDEHTIfIED COWOUNDS 00 0284 ————————
Lab Mama: , T p.<; - K JL)O x uu-ta_____ Contract:_______ | •^Llt I
Lab Cod«: (J STU Ca«« Ho.: Mll.qs SA3 MB.: ______ SOG Wo.: w^seai.
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SJOpI* Wt/vol: t fq/aLl 6_ Lab Fil« ID« uBt67?TI
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L«v«l: (low/Bad) M6K.
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Dilution Factor:
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L<Vl; (lOV/Btd) MtD
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n: (p«elt/cap) -PflCt OilutiCONCXMTXATXC
CAS NO. COMPOUND (ua/L or ua/
74-»7-3——————Chlere««than»
75-01-4———vinvl QU.orid«7S-oo-3—————Chlero»tto«n«7s-o»-a———M«thyl«r Chloridet7-«4-l———Acetone . .,75-15-0— —— carbon 5r«ulzide7S-3S-4————1. l-Diehloroethene
540-59-0———i.2-Oiehloroetbene (total)<7-«-3———Chlereter»
7»-93-3———2-But«none7i-55-<———l. 1.1-TrlckloroechaMSt-23-5——————carbon Tetraehlorid*. .ioi-os-4——— Vinvl Ae«taf75-27-4————»ro»odiehlero«maM7«-«7-5——————1.2-DlchloroproB«iwioo<l-oi-a———<sl—l. 3-DicshloroeroDw79-oi-<————Triehlore<th«n<
7,-oo-s————l,l,a'Trlehloro««b*ai————
loo<l-oa-«———»ata«-x, 3-51chleroprepw7S-2S-1-—————tee—fanlOB-10-l————4-lto«hvl-2-y«ni*noir
ia7-r-4———T«tr«cBlore»tl»«r7»-34-S———l,l,3.a-T<tr«chleM3tSAB»lo»-<«-3———Tola«r101 t0 T C"hlorotrnrna100-4 X-4———llhylbwirlOO-42-S—————Ityrix1330-20-7—— ——Xyiur iiatali
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Lab Na»»; )TO$- K^of.uii.Le Contract:________l-rvV.
Lab Coda: ir d^ u Ca«* Ho.: ^(.og
Matrix: (aoil/wafr) soit-
Saopi* vt/vol: ^ (q/aL) G^
L»vl: (low/a»d) M.tp
t Hoistur«: not dec.____
Coluffln: (pack/cap) TOCI-
HulBbT TIC« found: ^fS ^yOelT^
SAS Ho.: _____ SDG We.: ungZfl<.
Lab SBBplM ID: MH.-233'?P\
Lab File ID: _Hn Z3sTt> '
Daf Raccivd: 33 1^ zsiv^
Oaf Analyzed: enlz-i!a
Dilution ractor: i»»-
COMCTOTBATIOH UNITS:(U9/L or uq/Kq) ufc/A-6. (M
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1AVOLATILE ORGANICS ANALYSIS DATA SHEE-POOOSS "A sw'-'- N0 •
Lab Mamas ^ .^JOXUI^ Contract:
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Matrix; faoil/vafr) se,ii, Lab Saaplw XD: ^n - y ^ q a p )
Safflpi* vt/vol: ^ (q/t) 6 Lab rile ID; m^s^ap <
L«vl: (low/a«d) M£P
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Dat. R«e«ivd: o7<g?.g3/ft>
oaf Analyfd: ^7^7/gfiColunun; (paclt/cap) •Mcfc Diluti
COMCXMTXXTXCCAS NO. COMPOUND (Ufl/L or ua/
74-«7-3—————Chlororthan«75-01-4———vinyl chlorid*75-o»-a—————N*tl»yrn< Chierid*<7-«4-l———Ac«ten« - - - - - —7S-15-0————Carbon ofculfid*75-35-4— ————1. l-0iehloro««b«m7S-34-3———l.l-Dlehlere«than«S40-S9-o———l,2-Oichlowtbw (total")107-06-2———l. 2-Diehloro<tn*n«7«-»3-3—————2-BUtM»on«7 i-ss-<———i. i, l-TriefirSroAhaMsc-23-5————carbon Tatraehlorid*73-27-4———•ro^dichlore—aiair7B-a7-9——————l.2-OiehloroaroBurloo<l-0l-5——ci»-l, 3«DirtJoroproDir79-oi-«————Trichl«wthwX24-4«-l-————OibrnMPhloroM€6M-r7»-oo-S———~l, 1,2-TriehlonrthJJMiloo«l-02-«——t»«M-l, 3-6icoloroprep«M79-25-2-——————•MMfoalo»-lo-l———4-ltotlwl-i-»Mtanon«12 7-r -4 ————TaeraeBlara«iB*n«7»-34-s————i. i, a, 2-T««r«cblore«ibur101-<»-3——-TolU1fioa-»o-7————ciHerob»n«ih«'100-42-S————«tvrir1330-20-7———xylir ^oiall
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TENTATIVELY IDENTIFIED COMPOUNDS """"'-"i
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Lab Coda: \f s~iu Car NO.: w^ff
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Sampla wt/vol: ^ (9/aL) G
L«vl: (low/mad) Ktp
t Moistura: not dac.____
colunn: (pack/cap) •MCV.
Contract:SAS N o . : SDG Ho.; UriZZdt.
Lab S—pla ID: HH ggvopi
Lab Fila ID: ^n zsuo pi
Data Racaivad: ^ l^zs/m
Data Analyzad: o-iiz-i)^
Dilution Factor:r-
Nuabar TICa found: H (ug/L or uq/lCq) m. tki c\
CAS NUMBER
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1A E?A SA«?L£ •)Q.VOLATILE ORflANICS ANALYSIS DATA SHEOl 00054
Contract:^
C««« NO. : tiTtois SAS NO. :
Lab Naa«:,
^~~' Lab Coda: SOO Mo.: uu-gzoto
Lab Saipl* 10: ^M zsm DIMatrix: (•oil/wfrl .goii.
s«Bpr vt/vols ^ (a/«I.) S_
L«vl: (low/Bed) M^P
» Moiatur«t nat d«c. 21
Colunn; (pack/cap) •pflc.fc
Lab rn» ID; HH 23'<i n,
Oaf Xaeaivd: o7^z.Z3/fl>
Oaf Analyiad; ^•»^7;B&Dilution raetor: 1*6-
CAS NO. COMPOUNDCONCOCrXATION OMITS;(u«/L or uq/ICa) ua, /k<
74-«7-74-»3-73-01-73-00-73-0»-<7-<4-7S-1S-7S-35-7S-34-S40-59«7-<«-107-067B-M-71-35-St-23-101-057S-27-7«-»7-100«1-<7»-0l-<124-41-7»-00-S71-0-3100CX-C79-25-310«-10-5»l-7«.U7-ia.7»-34-Sio«-«a-10«-«0-100-41"100-42-1330-3C
———Vinyl Chlorid*————MathylMf Chlorid*——————Carbon biauliid*———————l.l-OiChlOWtBW
o———i,2-Diehlowth«n»7i3tal)
————I.1.1-TriGhlarocthana4————vinyl Aeataf————•rofl«dieniora—«aan*————l.a-DlcalereproDMril-g——cr-i. 3-Dienioroprop«n«i—————Trieblore««a«r.l————DibrBMChlBre««th»n«l—————l,l,a-Trlehlore»tn*ir
i2.«—~ trufl, 3«oiaaloropropw[——————•WOtOCT-l——-~—4-lto«hyl-2^Kuii«non«-<———a-B«tiio—1———1,1,2,2-f«tneai«re««hur-3-————Tolu—r•7—————chlerob«wn«.4————IthvlbM)««r ' ," 1
-s————«twn« ,„.i-7————Xvlwr ^€ocall
-LLfiff'sJtOOO110001(600fflOO
3aao?7ooS-700
S7ao5700£-looS-100
3flo«5700
A 700lloeoff70o^noe?7ct>S700s-,^6-100a-700S-700S700ItOOO11000S-700ei<»STCO
IBOOC'TOO
S-7W<-»ao
¥
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roiw z vox i/«7 irv.03217CW
IE E?A SA"?.; ;;'VOLAT:L£ ORGANICS ANALYSIS DATA SHIER 0 (\
TENTATIVELY IDENTIFIED COMPOUNDS vv-
Lab Naaa; )TPS ' ^Aionuii.f.6-/TfK
Lab Cod*: ir s~f v Ca«« MO. ; 'o<.'»g
Matrix: (aoil/wafr) son-
Saapr vt/vol: H (q/BL) G
L«v«X: (lov/acd) M.tp
» Moi«tur«; not dec. 6^
Coluan: (pack/cap) Tjftc^
Contract;SAS H o . : SDG Mo.: uriea^^
Lab Saapl* ID: HU Z3*<| D(
Lab ni« ID; HH 2»Xi &>
Oaf Racaivad; (TT l-y^s/y*Oaf Analyzed: 07^7^8*Dilution Factor: __(_
Nuaber TIC« found: j (ug/L t
CAS NUMBER
123456789
101112131415161718192021222324252627282930
i .o.SM-2
COMPOUND NAMZ
^tX«Al6
sv uq/Kq) ufc /Jf» ^•;:
RT
• .6 •»
EST. CONC.
———i&fifi————
'
Ch—2 d
—
TOKM I VOA-TIC 1/87 R»v.
XAVOLATILE ORGANICS ANALYSIS DATA SHEET,. „„,
E?A SAWPLS ;;C,
Lab Kama:,
Lab Coda:
Contract :I T F KCar NO.: iitoqs SAS No.: SOG Me.; uugzato
Matrix: (•oil/wafr) .gaii.
saapia vt/voi: _Ji__wx.)_5_Laval: (low/sad) Mtp
t Moi»tur«; not dec. 9 I
ColuBn; (pack/cap) ?^Cfc
CAS NO. COMPOUND
Lab saapr ID: HH g^gai
Lab fir 10: HM g3«<?Di
Oat« x«e«ivd: o7<gg.g3/ftft
Oaf Analysed: ft7^^gfi
Dilution raetor: >CONCXMTXATION OTIITti(uff/fc or uq/Ka) ua. /kg Q
74-»7-74-B3-7S-01-75-00-75-0»-<7-*4-75-15-75-3S-73-34-540-59<7-«-107-0»7«-»3-71-55-56-23-101-0575-27-7«-«7-100«1-(79-0l-<124-41-7»-00-.71-43-,100«1-(75«2S-IOJ-10-3»l-7«-i27-r7»-34-!loa-f-10a-»o<100-41'100-42'1330-2C
———•re«o—tnan«
——•••Carbon Dfulflda————l.l-Olehlereathwo———l,a-Dtehlere»th«n* (total)
————a-BUtanon»———1,1, l-Triehlowthan*———carbon T«traeblorld«4———vinyl Aeataf———1.2 -Olctiloroeroean* . . .»l-3——ci«-l. 3-OiehIorooroRWl—————Triehloro»ttw*f-l————DibroMchloroMUnna
)2-«———tx*n«-l, 3-Olehloropr MMt——————BroMfon-l————4-MtByl-2-»«nfeanotr-4 —————T«tracBlere«Ufn«»———l.l.a.a-T»tr»cniorB»thir „-3 ————Teluw•7————Chlarob«ns*n*•4———lthylbmian« '•9———ityrMf1-7———xylur ^o€all „ , , . .
<,<,tX>
W(,{,«•(.fcoo3300
?2ttfl^3fiS!———————?3*P5teB
1 J300 133A<>a-Sea
lLooWo33<»odivosao-Jiftff - ..3300i3*»: 3aaJaoc
Ikoo
^—iLCoo l
tefa<» . ., ...i3.oa^
^<"»'^»°0.i^ftfi-^aooZtOO
||
•^——
rom x vox 1/»7 Rav.
0321*7672
IEVOr-ATILE ORGANICS ANALYSIS DATA SHE&Ti n n '? C;
TENTATIVELY IDENTIFIED COMPOUNDS UU"U «'-'
Contract:.SAS H o . :
)TP$- K^Cif.ulLt.6Lab Naa*:,Lab Cod*: /TFX
Car HO. ; v^e
Matrix: (aoil/wafr) SOIL.
sarnpl* vt/vol: 4 (g/aL) G
L<vl: (low/Bad) M.tg
» Mortur*; not dec. 9 1
Colman: (pack/cap) Tftc^
Number TIC* found: l3
SDC Ho.; uriezat^
Lab Saaple ID: nn ?3MZC>.
Lab ?!!• ID: Hx-ijtZCn
Data Racaivd: a-,f^?^9t
Daf Analyzed: a-^z-^Bt
Dilution factor:
coMcnrniATioH OMITS:(ug/L or uq/Kq) ufc /A-g.
CMCM•
CAS miMBER
123456789
1011121314IS161718192021222324232627282930
1 1 6 . ^ - 2^•8-?-^^3-7?-'?^M-M-t<
Sill.76-WH?-??-S<.t t4-2t -13nft.?t-l«ttl.7a.«<0(. -2»-fts-Bs.g.-iS^i-27-8Hi-(.S-1
COMPOUND NAMZ
U<XXA,<(N^L«WtXH<.t . m-tHIL.CMtLflUtH^t, >-* •'!»•( t.-r-M^TBIL.Ht X * * 6 , 3.1X«TML-U«xtMfr . l.i»*«Tt'H •ritM^eW«>1»*.»1 3.<TH<<l.^Mf»»t'(l..MtL«Ht<rt*.*.(l,l. Df<«T»W,<l»tCiClpHtX^t MTHU-Z'M^HVl.1-a^rtA.et., ^i.BiMtTrt-d-w«yrA***, ?.<u*Ttvi-HtyT^'S>(,?-l*\*TM<.-ae.TflAr
RT
ra-ai»,•»??3-»°'?-?9^?•73Zr.^-&S.-S1?r.s7^&.•^•^<•».»??a.»-r
8^9f
11
BST. COWC.
Hfaot(3<»AO;3oo&/dft^ft&•/«•
varoooMaoBftaa,ttoorf
3BOOA(.200 0«««••
Q 1
•s
T
rom i VOA-TIC 1/87 R«v.
1A E?A SAMPI.2 -ioVOLATILE ORSAWICS ANALYSIS DATA SHEBTn.^tt^
Lab NM«; .-r^-XAJQXu.^
^ Lab Cod«; /T
Contract:./ TFK
C««« NO.: '<ll»qg SAS NO.: SOQ No.: uugaatoMatrix: (•oil/vafr) gon.
Safflpr vt/vol: ^ (a/at)
L»vl: (low/Bad) M£t>
t Moi»tur«t not dee. g&Coluan; (pack/cap) •Mcfc
CAS NO. COMTOUND
Lab Saapr 10: N»?3«t3D>
L^ yn< ": HN?3iji>.DBf XACBivd: O7<g?.g3^
D«f Analyfd: f t7^?^a&Dilution raetor: __J___
COHCZMTKATION OMITS I(ua/l or uq/Xg) ua. /k6 Q
75-00-3 ————Chloro»tl»«n»7S-09-2———H<thylw Chloride«7-«4-l———Ac«ton«75-lS-O——————Carbon Difulfido73-35-4— ———i. i-oiehloro«Cbm*73-34-1————i. l-oichlewthir540-59-0———l, 2-Oiehloroctbir (total)< 7 -< •- 3 ———chl orofoniI07-o«-2———l.2-0ichloro«th*n»7«-93-3——————2-»Utano»W71-55-<——————1.1.1-TriehiorocthamSt-23-5————Carbon Tatraehlorid*l.ot-os-4———Vinyl Aeacaf7«-«7-3————l,2-OiehloroBroBairioo«l-oi-5——ci«-l.3-Dieniereprop«M79-01-«——————TriehlBro«thw „ ,124-4»-l———DifcTBMcnmra«^h«n«
loo«l-02-«- ~~tran«>l,3-6ieBloropropwlo»-lo-l—————4-ltothvl-2-^ntMen«127-n -4 ———T«cr«eBloro«tli«a*7»-34-s———i ,l,a, ««f«truhle«o«il»M10ff-«« - 3 —————TBl<W«f
100-41-4—————IthylbOTiirioo-4a-s———BtvrM» , ,„. „1330-20-7———xvlur iiiEill
(.»«^200fazoe(.200•B60
32003tdoafeo3jaaa<6e>11999100
IW«1«6
«———•»»0t»Ulie————J160«<«{>
•
aiat>zoo a
^———feffio&^«ais<^«<aa
bl«00———sisrs-————ITS?"3100
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03217674
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1A EPA SA«?L£ M O .VOLATILE ORSANICS ANALYSIS DATA SHEM00168
contract:,
Car No.: '•^Ks SAS Ho.:
Lab N«aa:_
Lab Coda: SOS Mo.: tauggato
Lab Saopla ID; ^ H g3«<H Qi
Lab Fila 10; MH Z^M^&I
Matrix: (aoil/vatar) San,
Saapr wt/vols ^ (q/1.) 6_
Laval: (low/Bad) M£O
» Moiatura: not dac. 9~1
Coluan; (pacX/eap) Tflcfc
Data Raeaivad: e,7/z?.g3/fta
Oaf Analysed: ^7^7^afi
Dilution ractor:
CAS NO.COMCXMTRATXON OMITS:(uff/L er ua/Kg) ua./keCOMPOUND
74-B7-74-0-7S-01-7S-00-73-0»-•7-<4-7S-IS-75-35-75-34-S40-59<7-M-107-0671-93-71-55-5<-23-xoa-os75-27-7«-»7-100C1-<79-0l-<124-41'7«-00-71-43-100<1-75-2S-LOC-10S»l-7»127-H7»-34-10«-««10«-*0<100-41-100-42'1330-2(
——————vinyl Chlorida————Chlore»than*
—————Carbon biaulflda
————1.1-Dichloroathanao———i,2-oiebloro«th«n« (total)
2———1.2-Olcnlorotaana—————a-Butanon*—————I. I. l-Triehleroathana————Cartoon Tatraeblorld*4———vi.nvl Acataf „
H-S———er-lf3-Dlcaloropropanail———.——Triehlor—thafr
5—————x,l,«-triealoro^aaAai
>2-«———trM»-l, 3-6i,chloroprop«n«2——————•KO—fori-l—————4-Ka«hvl-i-l nianon*-4—————TacraeBlora««a«r5———i.i,2.a-TttracttlorB«tn*n«-3 —————TOlUW•7—————chlarehan««r-4 ————IthylbMUWM-a————«tyrw 1»-7————xyl—— ikakM^
WOO•i£,o.•»(,oofioov«a«
-nao4aco460IBOOy&flt,4»eo ;•IfflOO
tVooteeo^ioo-T(^>0«<100^y>«eflo4tl001&WHtoo
•3-WQ
1t9<- ,<»<»
?&<»-3tes.————4806^too
4ffOQ•S -»«?,<*
————522S-«(&).4700
Ll
'L1
U
1',1————
-3————
rom z vox. 1/87 Rav.
03217676
IEVOLATILE ORGANICS ANALYSIS DATA SHEETTENTATIVELY IDENTIFIED COMPOUNDS000169 , , ,
^ 14 2 z z •<
SDG No. : UHezo<.
Lab Saapl« ID: HH g ^ t ^ f pi
Lab Fil« ID: HH ?3^tit>i
Lab Mama: )TO$- K^Q^UILL^ Contract:1-rm
Car HO.; w^s SAS Ho.:Lab Cod*: ir •s^ u_
Matrix: (•oil/watT) SOIL.
Sampla wt/vol: f (q/aL) 6
Lavl: (low/mad) Kip
t Moistun: not dec. o<-|
Daf XBeaivd: a-rliyz.v/yt
Oaf Analyzad: o^l^^)9^
olumn: (pack/cap) •PACS. Dilution I
COMC2MTIIATIOH UKNuaibT TIC« found: 4-^"<S J rT (ug/L or ug/Kg)j
CAS NUMBER
123456789
1011121314151617181920212223242326272«2930
U&.M-3i(ie-<T-e.4<?2?-7f»-ftS-flf-SH-V5-1 1 - -»< . - • (t.3 ft-<>.<-»'1 «•-»?-?^ > 1 - Z«.-13.-»(t.iz.-li t f c - Z I - X
?o-'-S-,fcl--??6<?-6l - l' S ' i t - t - 1 - »
2<-o-7-»3-0t
COMPOUND NAMZ
Hfrxft^frCMCUDHtlrlLUt. ^(OAlJIIl.-C^1-&4(.<A^«., l-tlt+'d.-Z-^fcWIl.frfe^A.C ,3.M«-TH.VL-Hfe<d^,-?-lM.*.TH-«-f'«LLoHfclf|tAl<<- l,»-t>»MtT1*1l;CI<rtfcPTAiUa.PCJJTftJJt. , 3-feTHVt-.-I-»<fcrHVl,-£MC.l6H*»*Mt. ,(LI,l-T>l»<.^-HHt.> ~l-OC-TA^Oi- S^- Olh-.tTt+'/L
fISCLOttfeKft^fr, 1 . 1 , 3 - 1 RllM.tTttfl. •M.fr»TA*J6-,?;MCT»f«U.(+frVTAA4,?-l»».«-Tltfl.Uw iau^^ »iMfan^ eyc iHJOt c * 3C^le—KA-.C 1, 3 - HMtl-, rt»^Sr
RT
Z0.612o, 4?
.-n??,«rH.70Zt.SO?«••?^t1ZS.S32^10p.o?«.60Z.t..S3^S.T^•atr.fo
11
Factor: ( ifr
»ITS; c
LM./A-6 ^C
BST. CONC.
sr-toofoooo( ^oeoL9AO&1 Z-oooJS'f6Saoci2ZOBOt.l.cw'oSoooo^(ooo
J&^eoo(fcoooe60000fcBBeo
Q
~5:—
T
^——
roxM x VOA-TIC 1/87 R»v.
03Z1767'7
3BSOIL VOLATILE MATRIX SPIKE/MATRIX SPIKE DUPLICATE RECOVERY
000002I TAS - >:/JI>*U 11-1.«- Contract:'Lab Nan«:_
Lab Cod*:ir»<
Car Do.; mtW SDG Ho.: urtficc.SAS NO.: ______
u><< ?zi(. L«vl; (low/Bad) MCOMatrix Spile - EPA Sample HO.!
COMPOUND
I,l-0ichloro«th«n«Trictllorcrttrn*B»nz«n«Tolu«n«Chlorob«nz«n«
SPIKEADDED(ug/Kg)
3f»»",3ff«e«ssoa»3<B-03Sooa
SAMPLECONCENTWkTION
(ug/Kg)«00t>
IHOCI
MSCONCENTRATION
(ug/Kg)
a9»o3 taw1C.OO 0
•SC.t.t^flaaa
MS | QC |* 1 LIMITS 1
REC «| REC. |
10« 159-1721•n 16;-U7|1.3 166-1421103 159-1391J*-T 160-1331'••' 1 1
COMPOUND
1.l-Dichloro«th«n«Trichloro«th«n«BenzanttTolu*rrChlorob«nz»n«
SPIXEADDED(ug/Kg)
SSbooasooo3?«^«?^0."?C<00
MSDCONCENTRATION
(ug/Kg)
looaoffaoo3S«.o
•SfcBfle3eooo
-MSB- | — — — — —» 1 t
REC *| RPD »
114 1 - S
IV9 1 - 7la & 1 6>a>< 1 0
1
1OC LIMITS |
•' RPD | REC. |
22 159-172124 |62-l37|21 166-142121 159-1.39121 160-1331
1 1
^ Column to b« u««d tor flag r«covry and RfD value witft an asfrisk
* Value* oufid* of QC llaiCa
RPD! e out of ? oufid* lialfSpik* RacovrY! a out of lo oufid* liaif
COMMENTS 8
FORM III VOA-2 1/B7 Rev.
03Z17B78
02
42
27
1B EPA SAMPLE NO.SEMIVOLATILE OR6ANICS ANALYSIS DATA SHEET 000494
SBLK1r :. Name; IIA9^KNOayiLLE___________ Cont.ract: ___________ ___________
SAS No.: _______ SDG No.; WHg2&
Lab Sample ID; BL3140R____
Lab File II:'; Bl;3Jl.40R____
Date Received; 07^22/88
Pate Extracted: i22Z2SZ§S
Date ftnalysed; OS^U/SS
Dilution Factor; I.LOO____
~~7rPK.Lab Code: U::STy_ Case No.; 41695_
^atri:';:: (soi l /water) SQIL__
•-Sample wt/vc'.l; __i.^S (g/mL) G
Le'/.-l: ( low/med) MED___
''; Mciisture; not. dec. ____ dec. _
E;::tr-act.ii:i|-i; (SepF/Cc.nt/Sonc) SONC
GPC Cleanup; (Y/N) IM pH!
CrtS NO.CONCENTRATION UNITS;(ug/L or ug/Kg) Ua^KQCOMPOUND
1 OB-95-2--------Phenol111 -44-4- -------bis(2-C:hloroethyl) Ether•35-57-8---------2-Chlorophenol
106-46-7--------1, 4-Di'-hlorobenzei-»e100-51-6--------Benzy1 A 1cohol
95-48-7---------2-MethylphenoI103-60-1--------bis (2-Chloroisopropyl)Eth6;f-106-44-5--------4-Mpthylphenol
78-59-1 ---------IsophoroneSS-75-5---------2-Nitrophenol105-67-9--------2,4-Dimethyl phenol
111-9i-i--------bis<2-Chloroetho;<y)Methane120-83-2--------2,4-I>ichlorophenoI120-S2-l--------l,2.4-Trichlorobenzene91-20-3---------Naphthalene106-47-8--------4-ChloroanilineS7-68-3---------Haxachlorobutaidierie59-50-7---------4-Chloro-3-Methylphenol91-57-6---------2-Methylnaphthalane
88-06-2---------2,4,6-Trichlorophenol95-95-4---------2,4,5-Trichlorophenol91-58-7---------2-ChloronaphthalenaSS-74-4---------2-Nitroaniline131-1 l-3--------Dirnethyl Phthalate2 OS - 96-8 ------ --Acenaphthy1ene606-20-2--------2.6-Diriitrotoluene
200002000020000200002000020000200002000020000200002000020000200002000020000200009600020000200002000020000200002000020000200002000020000~f 0 11 U 1,1
2000096000200002000020000
UUUU1.14yUUUUuUuuuuuuuuuuuuuuu1.1u1-1uu
FORM I SV-1
1 C 000495 EPA SAMPLE NO.SEMIVOLATILE ORSANICS ANALYSIS DATA SHEET
/'""" b Name: IIAS^KNQ>s'ylLLE___________ Contract:——.- ~^-
Lab Code: IT;:STU_ Case No.: 4.1695_ SAS No. ;
Maitf-i;-.! ( s o i l / w a t e r ) SQIL__
Sample wt /vol ; —l^.i3 ( g / f f i L ) 6___
Level: ( low/med? MiE___
"'; Mois ture : not dec. ____ dec. ____
Extraction: (SepF/Cont/Soric) SONC
C-iPC Cleanup; ( Y / N ) N pH;
SBLK 1
———— SDC-i No. : WHS2K ?^\'A
Lab Sample ID: E'L3.14aR______
Lab F i le ID; BL31.40R____
[•ate Received: 02/22^830^
Date Extracted: 02Z2SZSS (^J
Date Analyzed: 08^11^83 C\J
• j-Dilut ion Factor: 1^00____ CM
COMPOUNDCONCENTRATION UNITS;(ug/L or ug/Kg) U@ K@
9'9-09-2---------3-Nitroanil ins33 - 32 - 9 ------- --Acenaphthene
10 0 - 0 2-7-------- 4-N i tr opheno1132-64-9--------Di benzofurari
34-66-2---------&iethyIphthalate
36-73-7---------F1uorene100-01-6--------4-Nitroaniline534 -'52-1 ------- -4, 6-Dinit.ro-2-Met.hy lphenol86-30-fc.---------N-Nit.rc.sodiprienylamine (!)
120-12-7--------Anthracene84-74-2---------Di-n-Butylphthalate206-44-0--------Flt<orai-it.hene12'9-00-0--------Pyrene85-68-7---------Butylbenzylphthalate
218-01-'9--------Chrysene117-31-7--------bis(2-Ethylhexyl»Phthalate117-84-i:i--------&i-n-0ctyl Pht.halata205-99-2--------Ber.20<b)Fli.)Orant.hene
50-32-S---------Beri2o(a)Pyreriel93-39-5--------Iriderio(l,2,3-cd)Pyrene53-7i:i-3---------Dibenz (a, h) Anthracene191-24-2--------Benso(g,h,i)Perylerie
9600020000960009600020000200002000020000
9600096 000
2000020000960002000020000200002000020000200004000020000200002000020000200002000020000200002000020000
LI
ULIU
iJU
UUU
UUUUUUUUUUUUU1 11.1U1-1UUU
( 1 ) - Cannot be separated from Diphenylamina 032V7G81
1/87 Rev.FORM I SV-2
000436 EPA SAMPLE NO.
SBLK1
IFSEMIVOLATILE ORSANICS ANALYSIS DATA SHEET
TENTATIVELY IDENTIFIED COMPOUNDS
^\ Name: IIAS;:KNgyYILLE___________ Contract;ITFK.
Case No.: 416'95 SAS No. :Lab Code: IT;:STU
Mat. r i . i ; ( s o i l / w a t e r ) SQIL__ Lab Sample ID: @L3140R__.
Lab File ID: g!=3i43R__.
Date Received; 02Z22/S8
Date Extracted: 07^:28/38
E'ate Analyzed: 08^1^/88
Dilution Factor; 1^.00____
CONCENTRATION UNITS:(ug/L or ug/Kg) US^Ka
•Sampla wt /vol ; __1^.S i 's/rnL) G___
Level; ( Ic .w/med ' MED___
"•- Mciisture; not dec. ____ dec. ____
Extract ion: (SepF/Cor-it/Sonc) SONC
SPC Clearmp; < Y / N ) N__ pH;
Number TICs found:
okSr'Q No. ; MH22*«S-
CflS NUMBER : COMPOUND NAME====^===:==:====:= f =========:====:s===^==^=:====x
1. 629-74-3 !1-HE^ADECYNE
RT ! EST. CONC.
19.57 ! 62000 1.J
FORM I SV-TIC
03Z1'7€82
1/87 Rev.
0002924B
SEMIVOLATILE METHOD BLANK SUMMARY
Contract; ___________Lab Name: IIftg^KNQ;j:VILLE___________"'s ITPK..-..o Code: IT-STI-l Case No. s 41695 SAS NO.! _______ SDQ No.: MH22S&- .
Lab Sample ID; BL;3j.40R______Lab F i l e 
0002971B
SEMI'.'TlLATILE ORGfiNICS ANALYSIS DATA SHEET•c.Pfti SAMPLE '•'<0.
WH2216ib Name; ITAS;:KNQ:^1;LLE___________ Contract:
|TP|<Case No.: 41635 SflS No.!,_-..b Ccide; H^STLI
^ fs t r - i ; ! ' ^o i l /wa te r ) SOIL__
Sample wt/ 'vol; __1^.4 (9/mL.i 8___
l-^'- e 1 : ( 1 c.w •• rned) MED___
"; Moisture: riot. dec. __S2 dec. ____
E'.'tractior,; • SepF/Cont/Sonc) SQN^:
GPC Cleanup! ( Y / N ) N__ pH; _liS._
SDG No.; WH22 W
Lab Sample ID: yH2355___
Lab Fi le ID: HH3355___
Date Received; fi7Z22^S8
Date Extracted: OT.^.S.'S^SQ
Date Arialyzed; ^SZIS^SS
Dilu t ior i Factor: 2^.00____
CAS NO.CONCENTRATION UNITS;(ug/L or ug/Kg) UG^KSCOMPOUND
I OS-95-2--------Phenol111 - 44 -4- ------ -bis(2-Cril or oethyl) Ether'?5-57-s---------2-chloropheriol
100-51-6--------Benzyl Alcohol95-50-1---------1 . 2-Dichl.:.rober-izerie•?5 - 43 - 7 - - - - - - - - - 2 -Methy 1 pherio 1
liT:-44-5--------4-Methyl phenol
-:.7-72-1-------- -Hexach 1 o r oethane
•38 -75-=;-- ------ -2-Nitropheriol
65-85 - 0 -------- -Benzo i c Ac i d11 i-91-l------- -fc.is(2-Chloroetho:»:y)Methane120-33-2--------2,4-Dichlorophenol120-32-1--------1,2,4-Trichlorobenzerie•51-20-3---------Naphthalene106-47-3--------4-Chloroaniline
5'?-50-7---------4-Chloro-3-MethyIphenc.l•?1-57-6---------2-Methylnaphthalene
83-06-2---------2,4,6-Tri chlorophenol•?5-'?5-4---------2,4, 5-Trichlorophenol•31-53-7---------2-ChI oronaphthaleneSS-74-4---------2-Nitroani1ine131-1 l-:3--------Dirnethyl Phthalate208-96-8--------Acenaphthylene606-20-2--------2,6-Dinitrotoluene
160000160000160000160000160000160000160000160000160000160000160000160000160000160000160000160000760000160000160000160000160000160000160000160000160000160000160000760000160000760000160000160000160000
IJ•
U
U
yIJ1.1U
UU1.1
U
U
U
IJ
FORM I SV-1 1/37 Rev.
03217684
Lab Ns,«— .
,.:. C .
Mal:n.
Ssrriplt-
Levc! I
•; Moi
E . r t r - a .
OPC C.
SEMIVOLATILE nRftftNICS ANALYSIS I 'ATA SHEE.
ime: ITAS-KNO;»;VILLE Contract.:ITW.
:.de: IT-STU Case Me.. : 41695 SAS N.:.. : •3I:'i3 No.:
: ' s o i l / w a t e r ) SOIL. Lab Sample I&! HH2:
a wt'-.:.!: 1,4 i g / r o L ) 6 Lab F i le It:'; HH2355
( l o w / m e d ) MED &at.e F
stur-e! r-iot dec. 82 dec. Date E
- t ion: (ScpF/Cont/Soric) 50NC Date {•
»arii..)p: ( Y / N ) N pH; "7.5 Di lu t .
CONCENTRATION UNITS;CAS NO. COMPOUND (ug/L or u.a/Kg) U6/KQ Q
100-02-7--------4-Nit.rophenol
121-14-2--------2. 4-r:lirlitrot.olue^le
86-73-7---------Fluc.rene100-i : i l -6--------4-Nitroari i l ine5.34-'=;2-l--------4.6-r)iriitro-2-Metriylprienol
120-12-7--------Anthracene34-74-2---------Di-r.-Butylphthal ate206-44-0 --------F1uoranthene
85-BS-7---------But.ylbenzylpht.hal ate
21S-01-'?--------Chrysene117-S!l-7--------bis(2-Ethylhe:»:yl)Phthalatet17-84-0--------Di-n-Octyl Phthalate
207-08-9----- - --Benzo(k > Fluoranthene5 0-32-8---------Beriz.:i< a) Pyrerie19'3-39-5--------Iridenc.(l.2,3-cd)Pyrene53-70-'3---------Dibenzia.h) Anthracene191-24-2--------Benzci(g,h, i)Perylene
1) - Carif-iot be separated from E'iphenylaroine
FORM I SV-2 1/8"
0321
Jutfao !MH221 i-. \
deceived: i:i7/22/8S
^:tracted: 07/28/88
analyzed; 08/12/88
ion Factor: 2. 00
760000160000760000760000160000160000160000160000160000760000760000160000160000160000760000160000160000160000160000160000160000310000160001:116000067000
160000160000160000160000160000160000160000
WH22I*-'\\n\
355
ULIUUUUUIJCIU1.1IJU1-1UIJUU1.1IJUIJIJIJ..TUUULIU1-11-1
;<r<C1
CC
7 Rev.
.7685
IF EFfi SAMPLE••SEMI VOLATILE ORSANICS ANALYSIS DATA SHEETQOOSSS
TENTATIVELY IDENTIFIED COMPOUNDSMI-1221 g.
^-><o Name: IIAS;KNO^IL.LE___________ Coritr-act.: ___________ ____________
•5AS No.: _______ SDG No.: »H22l^
Lab Sample ID: HH2355_____
Lab File ID: HH2255_____
Date Received: tl2Z22^8S
Date Extracted! Q^/.'SS^SS
Date Arialyzed: £8^13/38
Dilution Factor: 2^00____
>TF<Lab Code! IT;:STy_ Case No.: 4.1695_
Mat-- i .<' : (so i l /water- ) SOIL__
Sample- wl/vol; __l2-4 <'3/rnL) R__
Level: ( low/mad) ME&___
'••; Moisture; rn:it dec. __82 dec. ___
Extraction; (3epF/'Cor-it/Sc'nc) 20NC
r-jPC Clear-.Llpi (Y/N) N__ pH: _7_5_
•=}•!<~\(M• !-C\J0
urnfcier TIC'S found
CA9 NUMBER^s=s==ss=s=ss-:s:a
1 . 62016-34-62. 62?-74--33.
-N 4.5.
5 (ug/L
COMPOUND NAMEs-s=-^s^===========s===s^==ssss
OCTANE, 2,3,7-TRIMETHYL-1-HEKADECYNEUNKNOWNUNKNOWNUNKNOWN
.:')•• ug/K-3
RT========!
10 . 321 •3. 5729.0729.4629.56
UG/KG
EST. CONC.= = = 5 : S S = 3 5 ~ 3 S 5
70000310000150000170000.>9100l>'
Qs=s==
JBJJJJ
FORM I SV-TIC 1/37 Rev.
03Z17686
0003201B•5EMIVOLATILE ORGANICS ANALYSIS DATA SHEET
/^~>:- Mi
Lab C.
Watfi.
Sarnpl'
Level
'•; 11 o i •:
E-»'trar
C-jpC C
r-
r~'
MH2217irne: ITflS-KNOKVILLE Contract.;
ITFK:.de; IT-STLI Case No.: 41695 SAS No.: SDG No.:
: (soi l /water) SOIL Lab. Sample ID; HH2::
s wt /vo l : 1 . 2 <.3/rnL) G Lab File II;'; HH235SR
(low/med) MED Pate Received; 07/22/38
:ture: riot dec. 86 dec. Date Extracted; 07/2S/S8
=tion; (SepF/Cont/Soi-ic) SONC Date Analyzed: OS/17/S8
leanup: (Y/N) N pH: T'3 Dilution Factor; 1 . 1:11:11:1
CONCENTRATION UNITS:CHS NO. COMPOUND (ug/L or ug/Kg) UQ^G Q
108-95-2--------Phenol1 1 l-44-4--------bis(2-Chloroet.riyl) Ether•95-57-8---------2-Chlorophenol541-73-1 - - - - - - - -1 , 3-D ii-hl or obenzene
•?5-5Ci-l---------l,2-Dii-hloroben2ene95-48-7---------2-Methyl phenol108-6i:i-l--------bis(2-ChIoroisopropyl)Ether106-44-°;--------4-Methylphenol
58-'35-3- ------- -N i trobenzerie78-59-l---------Isophorone88-75-5---------2-Nitroph-ienol1 05-67-9------ --'2, 4-&irnethylphenol
lll-9l-l--------bis(2-Chloroet.ho:>!y)Methane120-S3-2--------2,4-Dichlorophenol120-S2-l--------l,2,4-Trichlorobenzene91-2Q-3---------Naphthalerie106-47-8--------4-Chloroaniline
5•.:.'-5l:l-7---------4-Chloro-3-M<athylphenol'?l-57-6---------2-Methylnaphfchalene
95-':»5-4---------2,4,5-Trichlorophanol91 -53-7- ------- -2-Chloronaphtrialene88-74-4---------2-Nitroaniline131-11-3- - - - - - - -D imethy l Phthalate21:18-96-8--------Acenaphthylene
FORM I SV-1 1/8-
0323
120i:i0i:i120000120000120000120000120000120000120000120000120000120000120000120000120000120000120000570000120000120000120000120000120000120000120000120000120000120000570000120000570000120000120000120000
yH22*g-
"i58R ^
UuUuuuL)1.1Uuuuuuu1-1uu1.1uuuuuLIuuuuuuuu
L
7 Rev.
vsw,
UUU^i
EPA SAMPLE NO.1CSEMIVOLATILE ORGANICS ANALYSIS DATA SHEET
MH2217
CTRt.Case No. : 416'55
/^ ' Name: ITAS^KNOK^ILLE
Ls.b C^de.; H^SJLL Case
Contract;
SAS No.: _______ Sr'Q No.; WH22+^-
Lab Sample ID! H^^2358R______»^M**1Mat r l ^- : (soi 1 /'water) SOIL__
Sample wt/ ' ' /o l ! -—l^S (•3/mL) @___
Level; (low/rned) MED___
"•• Moisture; r-icit dec. __S6 dec- ____
E;-: tract, ion: (SepF/Corit./Sonc) SONC
SPC Cleanup: (Y/N) M pH: 7,3
Lab File ID: HH2358R____
Date Received: 02Z^£'Z®8
Date Extracted; 07/2S^S8 \0
^\Date Analyzed: fiS/17^88 OJ
•=d'D i lu t ion Factor: 1.000 _ ,
CAS NO.CONCENTRATION UNITS:(ug/L or ug/K:g> Ug^KGCOMPOUND
•?'?-i:r?-2---------3-Nitroariilirie
51-28-5---------2.4-Dinitrophenol100-02-7--------4-Nit.rophenol
34-66 - 2 - - - - - - - - -D i ethy1phtha1 ate7005-72-3-------4-Chloropheriyl-phenyletrier
100-01-6--------4-Nitroani1ine
101-55-3--------4-Bromophenyl-phenylather
S7-86-5---------Peritachlorophenol85 - 0 1 -S -------- -Phenanthrerie120-12-7--------Anthracene•34-74-2---------r>i-n-Butylphthalate
12'?-00-0--------Pyrene
91 -'54-1 ------- --3, 3' -r>ichlorobenzidine56-55-3---------Benzo(a)Anthracene~ i "i ~ i ~i 1 1117-81-7--------bis(2-Ethylhexyl)Phthalate117-84-0--------Di-n-Octyl Phthalate20S-'3'?-2--------Benzo(b)Fluorant.hene207-OS-9--------Benzo<k)Fluorantherie50-32-8---------Benzol a)Pyrener?3-3-3-5--------Indeno(l,2.3-cd)Pyrene
570000120000570000570000120000120000120000120000120000570000570000120000120000120000570000120000120000120000120QQQ120000120000240000120000120000
120000120000120000120000120000120000120000
ULIUU
U1.10UU
UU
UUUUUU
U
J
UUUUUU
( 1 ) - Cannot be separated from &iphenylamine
FORM I SV-2 1/37 Rev.03217688
IFSEMIVOLATILE ORGANICS ANALYSIS DATA SHEET
TENTATIVELY IDENTIFIED COMPOUNDS
000322EPA SAMPLE NO.
WH2217a Name; ITAS^NO^yiLLE
Lab Code; IT;;STU_ Case
M a t r i > E ; ( so i l /water ) SOIL__
Sample wt/'.'ol: __1^S < g / r n L ) G___
Lavel: ( low/med) MiD___
;'; Moisture: t-iot dec. __36 dec.
Extraction; (SepF/Cont/Soric) SQNC
RPC Cleanup: ( Y / N ) N__ pH: _J_3_
[TWCase No.; 41695.
Contract: ___________ !__-_________Ob
SAS No. : _______ SDG No. ; W^^r
Lab Sample ID: HH2358R____
Lab File ID: HH2358R____
Date Received; 02 22 88
Date Extracted! Q2^2S^.QS
Date finalyzed: OS 17 SS
Dilution Factor; 1^.000___
urnber TICs found
CAS NUMBER
1. 6210S-22-92. 62016-34-6
^ 3. 54105-67-S4. 629-74-35.
5 (ug/L
COMPOUND NAME
DECANE, 2,5,9-TRIMETHYL-OCTAIME, 2,3,7-TRIMETHYL-HEPTftDECANE, 2,6-DIMETHYL-1-HEMADECYNEUNKNOWN
or ug/Kg
RT
9.3910.2512.8219.6429.56
L'S^KSEST. CONC.
560001 0 C I Q O Q75000 >
110000.'160000
Q
.J
J.-rBJJ
FORM I SV-TIC 1/87 Rev.
03217689
000345EPA SAMPLE NO.1B
SEMIVOLATILE UR6ANICS ANALYSIS t?ATA SHEET
^.b Name; ITAS^KNO^YiLLE,
Lab Code: II.;STU_ Case
Mat r i;-::: ': soiI /water) SOIL__
Sarnpl's' wt./vc'l: __l^.l (g/rnL) G___
Level: dow-'med) MED___
"•; Mors-f-ur-a: not dec. __34 dec. ____
E.-? tract ion: (SepF/Cont/Sonc) SON£
GPC Clear-tup; (Y/'N) N__ pH: .,J>__
1TFKCase No.: 41695
Cc'nt.ract.;
SAS No.; _______ SDG No.; MHgS ;
Lab Sample ID; Hy2359_____
Lab File ID: yy3359_____
Dat.e Received: 07/22/88
Date E.-it.r-acted; O^SS/SS
Date Analyzed: OS/H/88
Dilutior-i Factor: i^.J323___
CONCENTRATION UNITS:(ug/L or- U9/Kg) UG/KG QCAS NO. C OMPQUN&
WH 2-2aO-'»Hl»2+ ; KI.m IJJ» m i.a 1 !aft»/»
108-95-2--------Phenol11 l -44-4-- ------bis(2-Cri lc.roet.hyl ^ Ether95-57-8---------2-ChIorophenol541 -73-1 --------1, 3-D ich lore-benzene
li:lO-=;l-6--------Ber-izyl Alcohol
95-4S-7---------2-Met.hylphenol10S-&i:i-l--------bis(2-Criloroi50propyl)Et.her10 A-44-5--------4-Methy1pheno1
98-95-3---------Nitroberizene
38-75-5---------2-Nitrophenol105-£.7-9--------2,4-&ittiet.hylphenol
111-91-1--------bis <2-Chloroet.hoxy)Methane12 0-83-2--------2, 4-Dichloropheriol
91-20-3---------Naphthalene106-47-8--------4-Chloroaniline
59-50-7---------4-Chloro-3-Methylphenol91 - 57 - 6 ------- --2-MethyI naphtha Iene
8S-06-2---------2,4,6-Trichlorophenol•?5-'55-4---------2.4,5-Trichlorophenol91-58-7---------2-Ch1oronaphtha1ene38-74-4 ---------2-Nitroaniline131-11-3--------Dimethyl Fhthalate208-96-S------ --AcenaphthyIene
110000U O O Q O110000110000110000110000110000110000110000110000110000110000110000110000110000110000550000110000110000110000110000110000110000110000110000110000110000350000110000550000110000110000110000
UUUUUU1 (
UUUUUUU1-1UIJ
UUUUUUUUUUUUUU
FORM I SV-1 1/37 Rev.
03217690
000346EPA .SAMPLE NO.tC
SEMIVOLATILE ORSftNICS ANALYSIS DATA SHEET
<^- . Name; IIAS.:i^NgyVILLE___________ Contract;iTPK.
Lab i::"de: IT;:STJJ_ Case No.; 4i&95_ SAS No.;
M a t r i x ; ( so i l /wa te r ) SOIL__
Sample w+. /^ol : ...l l ( g / m L ) a___
Level: ( l o w / m e d ) MED___
,''; Mois tu re ; not dec. __34 dec. ____
Extraction! (SepF/Cor.t/Sonc) SONg
GPC Cleanup: ( Y / N ) N__ pH; _7_°._
———— SDQ No. ; !i)H22^- %,|i,|a»
Lab Sample ID; HH2359_______
Lab Fi le ID: HH2359_____
Date Received! 02^22^S8
Date Extracted! 07/2S/8S 0\— ___ ^
Date flnalyzed! OSZil/SS CYi'=3-
Di lut ion Factor: JL^OOi;!___ ,-.,
CAS NO.CONCENTRATION UNITS;<u.g/L or ug/Kg) UG^QCOMPOUND
9'9-09-2---------3-Nitroani l ineS3-32-9 ------- - -Acenapl-ithene51-29-5---------2,4-Dinitrophenol100-02-7--------4-Nitrophenol
121-14-2--------2, 4-Dinitrot.oli.4ene84-66-2---------Diethylphthalate
S6-73-7-- -------Fluorene10 0-01-6--------4-Nit.rc.ani l ine534-52-1--------4,6-Dinitro-2-Methylphenol
US-74-1--------Hexach1orobenzene87-86 -?,------- - -pentach 1 oropheno 1
120-12-7--------Anthracene34-74-2-- -------Di-n-Butylphtrial ate206-44-0--------Fluior»nthene
S5-6S-7---------Bi4tylbei-izylphthalate•?l-'?4-l---------3,3' -Dichlorobensidine
2IS-01-9--------Chrysene117-31-7--------bi5(2-Ethylhexyl)Phthalate117-S4-0--------Di-n-Oetyl Phthalate
50-32-8---------Benzo(a)Pyrene193-39-5--------Indeno<1.2,3-cd>Pyrerie
r31-24-2--------Benao('3,h, DPerylene
550000110000550000550000110000110000110000110000110000550000550000
110000110000550000110000110000110000110000110000110000
2 '~f ft n fi fi110000110000
110000110000110000110000110000110000110000
UUU
LIUhi'-*ULI
U
LIU
U
1-1U'
UU
UU
LI
( I ) - Cannot be separated from Diphenylarnine
FORM I SV-2 1/S7 Rev.IVWfrMCM
000347IF EPA SAMPLE NO.
M a t r i ; ; : ( so i l /wa te r ) SOIL
Sample wt/ '/ol: __l^.i ( g / m L ) S___
Level: ( l o w / m o d ) MED___
"; Moisture: not. dec. __S4 dec. ____
Extraction: (SepF/Cont/Sonc) SONC
r-iPC Cleanup: (Y/'N) N__ pH; ^,a__
Lab Sample ID; HH2'359.
Lab File ID; HH235:3_
Date Received; 22Z22/8SDate Extracted: 07/28/S8
Date Analyzed: 08 1 83
Dilution Factor; i^QQQ___
SEMI VOLATILE ORGANICS ANALYSIS DATA SHEETTENTATIVELY IDENTIFIED COMPOUNDS
':. Name!: ITAS-KNOi-SVILLE Contract.:ITff.
Lab Code: IT-STLI Case No.: 41695 SAS No.; SDS
Matri;;: (soi l /water) SOIL Lab Sample 10;
Wtt •W-MtM^
No. ; MH22A-3'^
HH2359
X-lt.a/zi
^it
Jurnber TIC'S found
CAS NUMBER= : = ; = = : = : = ; = = = : = = = = = : = : ^
1. 111-65-92. 322J.-61-2
"" 3. 1120-21-44. 17301-32-°;5. 17301-22-36. 17301-32-57. 74645-93-0S. 74645-'?S-':i9. 57-10-3
10. 629-74-311. 22104-62-712.13. 629-99-214. 6006-01-515. 30-97-716.17,13.19.20.
20 (u-3/L
COMPOUND NAME
OCTANE (DOT)OCTANE, 2-METHYL-UNDECANELINDECANE, 4,7-DIMETHYL-UNDECftNE, 2,5-DIMETHYL-UNDECANE, 4,7-&IMETHYL-DODECANE, 2 ,7.1Q-TRIMETHYL-DODECANE, 2 ,7 ,10-TRIMETHYL-HE^ADECANOIC ACID1 -HE:":ADECYNE2-BUTANONE, 4-(DIMETHYLAMINOUNKNOWN (SAT'D HYDROCARBON)PENTACOSANE3,7,11-TRIDECATRIENENITRILE,CHOLESTANOL (VAN)UNKNOWNUNKNOWNUNKNOWNUNKNOWNUNKNOWN
or ug/Kg
RT
2.337.057.639.209.42
10.6515. SO16.9518.4919.5519.9724.7725.5726.2929.0629. 4630.5130.9631.3932.67
ya/KQ
EST. CQNC.
690006100073000 .85000;'79000690007300093000
3000003700001600006000090000
1700001100000660000120000150000140000180000
Q===3SS
JJJ..TJJJJ.JBJJ..TJJJJJJJJ
FORM I SV-TIC 1/87 Rev.
nnsi'aitfiB
SOIL SEMIVOLATILE MATRI:": SPIKE/MATRI:": SPIKE DUPLICATE PECOVCTBnpQ 1
I ab Name! ITAS::KNQ><VILLE ________ Contract;- n-px._ ffFK. " o f .i^^t. C.:.de: IT;STy_ Case No.: 4.1695_ SAS NO.! _______ SDG No.; WH22i^-
^»>li»t
t. C.:.de: IT;STy_ Case No.: 4.1695_
M a t r - i ; Sp ike - EF'fl Sample N o . ; WH221_6_ Level:(low/med) MED
criMpniJNf-
Phenol2 -Ch1o r op heno1:1, 4-^. l^chloroberlZ'^neN - N i t ro-so-di -n-prop. 1.1)1,2, 4-Tr ichlor-oberi3eF-ie4 - Ch I. o r o - 3 -rnethy 1 pheno 1flcenapht.hene4 - N i b r c'p'henc* 12, 4 - D i ri i t.f ot o 1 uenePant.ach 1 oropheriolPyrer'io
SPIKE •ADDED(ug /k 'g )
925000925000463000463C100463000925000463000925000463000925000463000
SAMPLECONCENTRATION
(ug/ 'Kg)===!=S=:3 ;S :===5:=
0000000o000
MSCONCENTRATION
f u g / K g )=:==:s=:=:===:==:=:=:
57700067200034801:1033300038500Q63600031SOOQ4810002520001960002'52000
MS
REC ff
62737572S3696952542163
QCLIMITS
REC.
26- 9025-1022S 10441 1 2638 10726 10331-13711-11428- 8917-10935-142
t—^rMKJ-•(M0
~sCOMPOUND
Pheno12-Ch1oropheno11 , 4-r'ichlorober]2:er'ieN-Nit r-oso-di -n-prop. ( 1 )1 , 2, 4-Tr ichlorobenzer-ie4-Chloro-3-methyl phenolAcenap'hthene4 - N 11 r op'heno 12 , 4-r'init.rot.oluenePentach1oropheno1Pyrene
SPIKEADDED(ug/Kg)
356000856000428000428000428000856000428000856000428000856000428000
MSDCONCENTRATION
(ug/Kg)
613000707000358000346000363000700000327000455000282000205000332000
MSD7.REC »
7283848185827653662478
•/;RPD »
-15-13-11-12-2-17-10-2
-20-13-21
aq L]RpD
3550273823331950474736
IMITSREC.
26- 9025-10228 10441 12638 10726 10331-13711-11428- 8917-10935-142
'' 1 ) N-Nitroso-di-n-propyiamine
ft Column •to be used t.o flag recovery and RPD values with an asterisk* Values outside of QC limits
PPD; __0 out of _^1 outside limitsSpike Recovery: __0 out of _22 outside limits
COMMENTS; CLP,41695,,WH2216,MEDIUM,SOIL,HH2355,BNA,EPAINSTR.4500 ; J^WDB9(30M*.315MM/1UM) 45-32501OD/M: 1 LIL INJr^
FORM III SV-2 1/87 Rev.
2 r'SOIL SEMIVOLATILE SURROSATE RECOVERY
LE——_______ Contract: ___________Lab Name: IIQSr^yQ^IkLE
r^ 1TFK.;. Code: IT::STI_1_ Case No.; 41625_ SflS No.: _______ S&a No.!
Level: • ' low/med) ME&___
000290
e(>WH22f6-
^.
EPASHMF'LE NO.
SPLK1WH220-MH224WH2216WH2216MSmH2216MSt:'WH2217
Sl••MBSIt t
83•3572S29.381
S2(FBPX
6570767l:i8171
S3< T P H ) f f
657592729274
34(PHDff
737568697870
S5(2FP)»
7-3Sl70779080
S6< T B P ) #
797566°;577S6
OTHER TOTOUT
000000
CM• •(M•C\J0
51 (NB2) = Nit.roberizer.e-d552 (FBP) = 2-Fluorobiphenyl53 (TPH) = Terphenyl34 (PHL) = Phenol-d555 (2FP) = 2-Fluoropheriol56 <TBP) = 2,4,6-Tribromophenol
QC LIMITS< 23-120)( 30-115)( 18-137)( 24-113)( 25-121)( 19-122)
tt Coli-fron to be used to flag recovery values:1; Values outside of contract required QC limitsD Surrogates diluted out
^
page 1 of 1FORM II SV-2 1/87 Rev.
03217694
ID 000712 EPA SAMPLEPESTICIDE ORGAMICS ANALYSIS DATA SHEETNO.
Lab Nam«; XT^ - noxvt Lt-g____ Contract:.I^-FK
Lab Code: •n-STU Case Mo.: qito^S SAS No.:
Matrix: (soil/water) _£o3Ua. Lab Sample ID: ^3(M wsr
Lab File 10:Sample wt/vol: I. oo (q/nL) fei
Level: (low/Bed) fneo Date Received: a-il^VS» Moisture: not dec. o dec.____ Date Extracted '.^]j^99__ m
, , . , ^Date Analyzed: olinof9v ^ ,
I 's::l-—————— (M
CONCEMTRATIOM UNITS: 0(ug/L or ug/Kq) Ufa/fcfa Q
Extraction: (SepF/Cont/Sonc) SoofcGPC Cleanup: (Y/N)Jf3_ pH; 7.0 Dilution Factor:
CAS NO. COMPOUND
SOS Mo.: (<JH3»0(a
319-84-6—————alpha-BHC319-85-7—————beta-BHC_319-86-8— ————delta-BHC________58-89-9—————ganiaa-BHC (Lindane)76-44-8 ——————Heptachlor______'309-oo-z— ———Aldrin_____1024-57-3————Heptachlor epoxide959-98-8————Endosulfan I__60-57-1—————Dieldrin72-55-9——————4,4 ' -DDE"72-20-8—————Endrin33213-65-9————Endosulfan II72-54-8—————4.4'-DDD1031-07-8————Endosul fan •ul f»f;50-29-3———————4.4'-DDT72-43-5——————Methoxychlor_53494-70-S———Endrin ketone_5103-71-9—— ——alpha-Chlordane5103-74-2——-——ga—a-chlordane^B001-35-a————Toxaph«n»____12674-11-2————Aroclor-101611104-28-2———Aroclor-122111141-16-5————Aroclor-1232"53469-21-9————Aroelor-1242"12672-29-6————Aroclor-1248"11097-69-1————Aroclor-1254"11096-82-5————Aroclor-1260"
iao
(i»oJS2-»aoiao
-545"~a?o~-5%-ano
(aoo4¥Praoolaoe
(aoo19-eo-7SS5-(300
j !Ifi__l!a—!
:IU-
.ia_1
FORM X PEST 1/87 Rav
0321'7C85
4CPESTICIDE METHOD BLANK SUMMARY 000544
SDG No.: tt'ffiigf^
Lab Name; :cTft<5.ie«^e»t^t-l-E•crffc
Cas« No.: M««^SLab Code; xT-ain^
Lab Sample ID: *3V3» 81 ST
Matrix: Coil/wafr) 5og«-
Date Extracted: o7bal«y
Date Analyzed (1) ; e>S/io/79
Time Analyzed (I): n30
Instrument ID (I): vST^ofl
GC Coluinn ID (I): 9-3^ fa^ I
Contract:
SAS No.:
Lab File ID:
L»vl;( low/Bad) meP
Extraction! (S«pP/Cont/Sonc)sgoc
Daf Analyzed (2); M/ig/tfP
Tia* Analyzed (2);
Inatnurnt ID (2):
GC Coluinn ID (2):
THIS METHOD BLANK APPLIES TO THE FOLLOWINC SAMPLES, MS AND MSO:| EPA| SAMPLE HO.
Ollhauaaite021 ^H»>lp&<.
04 1 iritaaii.mSbL 1 rt«aas«.waT-»o051 iiiHaaiLiK so nil aasi iww-soei^isii.www-071 iA»aan081 iim-aaac»,a,aa,-3H riHA3m-i.a«r.&09 (1 0 11 1 11 2 11 3 11 4 11 5 11 6 11711811912012 1 12212312412 5 1261
LABSAMPLE ID
MMJMias&T-SHtaaiBtMT-soIMXMb<l«S9r--S
tttaa37<»W»3r-»ultaia y-s
DATEANALYZED 1
t>t//o/s8el o^cx/w/wo«//o/««o</h /•«ot/it/W<«/li/ «»o»/»o/«»
DATEANALYZED 2|
W^f^
Ot/rt/T
f/fftW
OB/rf/To«/^/lrt
COMMENTS:
?ag» _L of j_FORM IV PEST 1/87 R*V.
03217696J^
ID HO 054^ EPA SAMPLEPESTICIDE ORGANICS ANALYSIS DATA SHEET-""-" __________NO.
Lab Name; Jt^s-^-noxytLLg____ Contract;_I=TFK
Lab Code: Tt-sTU Case Mo.: mto^S SAS Mo.; SDG Ho.: t*JHa»0(<
Lab Sample ID: HHaa as os sr
Lab File ID:
Matrix: (soil/water) _s£EJa_
Sample wt/vol; I. \\ (q/iaL) fci
Date Received: o-ilwfVf
Date Extracted : 2^»(8P__ ln
•.- -Date Analyzed: oa/>c/gg (
Dilution Factor: _$
Level: (low/Bed) <neo
t Moisture: not dec. W. dec.___
Extraction: (SepF/Cont/Sonc) .s&nC.
GPC Cleanup: (v/N).fl_ pH;7.5
CONCENTRATION UNITS:(ug/L or ug/Kq) Ufa/tfaCAS NO. COMPOUND
•=3-(M0
319-84-6——319-8S-7———319-86-8———58-89-9———76-44-8———309-00-2——1024-57-3——959-98-8———60-57-1———72-55-9————72-20-8———33213-65-9—72-54-8———1031-07-8——SO-29-3———72-43-5————53494-70-5—5103-71-9——5103-74-2——8001-35-2——12674-11-2—11104-28-2—11141-K-5—53469-21-9—12672-29-6—11097-69-1—11096-82-5—
——alpha-BHC——beta-BHC———delta-BHC——ganuBa-BHC (Lihdane)——Heptachlor——Aldrin——Heptachlor epoxide——Endosulfan I——Dieldrin——4,4•-DDE
——Endosulfan II———4,41-DDD
-——4.4'-DOT——Methoxycailor-——Endrin keteone———alpha-Chlordane——qa—a-Chlordane——Toxaphene——Aroclor-1016———Areclor-122l——Arocior-1232———Aroclor-12 4 2——Aroclor-1248——Aroclor-1354
U>-TO1.-70toTofe'70
fr7ot.70tp-70A.-76 •130013<><»13»"13COl3ooi3oe>1SOO(•70P1300t.700(.we
ISPOft•.•too1.700l.TBO(.TOOto-roo
l-gooo1WOO
lululu10
1^"-1^-
!uIU|UIUIUILlIIIIUMluIUlululu1 1 1InIUin1
FORM X PEST 1/87 Rav.
03217637/»*'
000554 EPA SAMPLE NO.IDPESTICIDE ORGANICS ANALYSIS DATA SHEET
Lab Name; ^^fts - Knoxvfc l_i_g____ Contract:ETFK
Lab Code: •EY-STU Case Ho.: qUatS SAS Ho.:
\ U?H Sta-ile'Cf^-
SDG No.:
Matrix: (soil/water) •SOI.L-
Sample wt/vol: 1 . 1 1 (9/nL) fei
Level: (low/Bed) meo
t Moisture: not dec. ^X dec.____
Extraction: (SepF/Cont/Sone) ong.
GPC Cleanup: (Y/N).fl_ pH;7.^
CAS MO. COMPOUND
Lab Sample ID: >«Ha3sa oSST
Lab File ID:
Date Received; o-ilM^VS
Date Extracted; o-7/»/8g ^
Date Analyzed: 08 /o/gg
Dilution Factor:
CONCENTRATION UNITS;(ug/L or uq/Kq) ufa^t?
•0^
60 ^CM0
319-84-6—————alpha-BHC319-85-7—————beta-BHC_319-86-8—————delta-BHC________58-89-9——————ganuBa-BHC (Lindane)76-44-8——————Heptachlor______'309-00-2— ————Aldrin_____1024-57-3————Heptachlor epoxide959-98-8—————Endoaul fan I____'60-57-1—————Dieldrin72-55-9——————4,4"-DDE"72-20-8——————Endrin33213-65-9————Endosultan 1172 -54-8—————4,4' -DDD1031-07-8————Endoaulfan •ulfate.50-29-3——————4,4' -DOT____72-43 -5—————M«thoxychlor_S3494-70-5————tndrin ketone_5103-71-9————alpha-Chlordane_5103-74-2— ———gaiiBa-Chlordane^8001-38-2————Toxaphane12674-11-2-———Aroclor-101611104-28-2————Aroclor-1221"lll41-16-S————Aroclor-1232~53469-21-9———Aroclor-1242"12672-29-6————Aroclor-1248"11097-69-1————Aroclor-1254"11096-82-5————Aroclor-1260"
vwx>VfOO
,700
l3ooo
'3000
FORM X PEST 1/87 Revy
03217638
IDPESTICIDE ORGANICS ANALYSIS DATA SHEET
Lab Name: ITft^-^noxytLLg____ Contract:.I-TPK
Lab Code: Tt-s-nA Case No.; MitotS SAS Ho.:
Matrix: (soil/water) 30x1- Lab Sample ID: Hn aaCTST
Lab File ID; _______Sample vt/vol: 1.3to (g/nL) '"1
Date Received: oiluJVf
Date Extracted: o^l^stf/fDate Analyzed: oa/ii/vV
Dilution Factor: <?
Leval: (low/mad) fneo
» Moisture: not dec. Bp dec..
Extraction: (SepF/Cont/Sone) scu^c.
SPC Cleanup: (Y/M)Jl_ pH;7.3CONCENTRATION UNITS:(ug/L or ug/Kq) (Afa/lifaCAS NO. COMPOUND
SDG No.:
r~' i-(M•st<M0
319-84-6—————alpha-BHC319-8 5-7—————beta-BHC319-86-8—————delta-BHC58-89-9—————gainma-BHC (Lindane)76-4 4 -8——————Heptachlor309-00-2—————Aldrin1024-57-3————Heptaehlor epoxide959-98-8————Endoeulfan I60-57-1—————Oieldrin72-55-9——————4 ,4 '-DDE72-20-8——————Endrin33213-65-9————Endoaulfan II72-54-8——————4.4 • -DDD1031-07-8-———Endoeulfan •ulzate50-29-3——————4.4' -DDT
53494-70-S————Bndrin kefcone5103-71-9————alpha-Chlordane
8001-35-2————Tox«Dhene12674-11- ————Aroclor-ldlS11104-28- ————Aroclor-122111141-16- ————Aroclor-123253469-21- ————Aroclor-124212672-29- ————Aroclor-124811097-69-1————Aroclor-125411096-82-5———Aroclor-1260
Ihte«b08fa6I1*1*n^t ,0fbo2(»0 •
1700.700noe170 61-700noo1700»boonoo»b<X»4fceo17000ttoooBtoOOIbOO•boo»(W
(TOOOrteoo
u
u
^=fc=:j"
l&z:
FORM I PEST 1/87 Rev.
J^03217699
ID 000568PESTICIDE ORGANICS ANALYSIS DATA SHEET
Lab Name; XT^-<n.r\eMtVtu_e____ Contract:,ETFK
Lab Code: Xt-s-ru Case Ho.: q I to'^5 SAS No.: SDG Mo.: inJHaaoC*
Lab Sample ID: HMasst-ba ST'
Lab File ID: ____ ___
Matrix: (soil/water) 30x1-
Sample wt/vol: 5.°^ (g/aL) fci
Date Received: a-il-a^W
Date Extracted; Q-llulf/f
Level: (low/med) meo
t Moisture: not dee. ^4 dec.___• 03
Date Analyzed: &»/»o/«8 'C\!
Dilution Factor: _ s 3.
Extraction: (SepF/Cont/Sonc) Sw^C.
GPC Cleanup: (X/M)J]_ pH;-ZQ
CONCENTRATION UNITS:(ug/L or ua/Kg) gfa/kfeCAS NO. COMPOUND
EPA SAMPLE NO.
lwH«aao oiwaaaif!; '-T>
<M0
319-84-6—319-85-7—
76-44-8——309-00-2—1024-57-3-959-98-8—60-57-1——72-55-9——72-20-8——33213-65-972-54-8——1031-07-8-50-29-3——72-43-5——53494-70-S5103-71-9-5103-74-2-8001-35-2-12674-11-11104-28-11141-16-53469-21-12672-29-11097-69-311096-82-!
———alDha-BHC————beta-BHC————delta-BHC
————HeDtachlor———Aldrin
————Dieldrin.———4,4 •-DDE———Endrin————Endoaulrari II————4.4'-DDD———BndoauKan •ulfate————4.4'-DDT————MethoxYehidrS———Bndrin ketone————alpha-Chlordane———aaiMM-Chlordane————ToxaDhene———Aroclor-ldi6———Areclor-1221————Aroclor-12 3 2———Aroclor-1242———Aroclor-124 8l———Areelor-12545 ———Aroclor-12 60
1-ISO IU-»s& ^-7SO IUT?o k-rso m150 IU
ISO ,. 14•7at> ;- miseo miseo 10i?<>» luisoo IUISOto 1111500 IUIS60 IU'l«eo 14ISOC IU
ia»» 1"•TWO 1 1 1ISOOO IU-i «. m- so IU-r»««> IU
^SC»0 IUKooO IUicooo ID
1
FORM I PEST 1/87 Rev
0321WTO
3, 000542SOIL PBSTICXDB MATRIX SPIXZ/MATRIX 3PXXX DOPLIC*TB RBOOVKKX
Lab H——t iT^s-Kn&JtvT-i i g"___ contrtct:J-1PK
L*D Code: -ET-yitJi Ca— Mo.i villrtS SA« HO.!
Matrix Spile* - BP» SupX* Ho.i i. a lL.
_____ SOa llo.i i^uaaMs
L«vll(low/—d) in Eh
———————
COMPOOHD
auu-BHC (Llnd«n«)H«DtachlorAldrinDicldrinEndrin4.4'-DOT
anaADOEO(»a/m»-<aiB
=g^=
SAIIKXCONCXNTItATIOM
(ug/xff)000e00
- MOOMCBITKATIOM
(Ifl/Kt)
011.07BI.Oht30
iTBeeir/oon"t>
m i QC i* IUMITSInc «| me. i»». 14«-1271tf 1M-HOIla. 114-132 Itp 131-1341»<~t4a-1391/*a U3-1341
t Coluan to b« u—d to tl«a rwcovxy and RPO vlu— with an ••fri«k
* Value outsid* of QC liBit*
Rpp; o out of IP outxid* XiiiitaSpile R«CQV«ry: 0 out 0( la. oufid* li»it»
COMMEMTS: h\\ unVi.-isateU^
FORM III PEST-2 a/87 R«V.
" 000543SOIL PESTICIDE MATRIX SPIKE/MATRIX SPIKE DUPLICATE RECOVERS
Lab Mame: ETftS- K'lunx^J-n-f
Lab cod*:
Contract:X-r^KCase No.: tli^g" SAS Ho.: SDG 110.: ^l+A3fl(,
Matrix Spika - EPA Sample No.: (^naili, 0<- Level: (low/nod) mtc
COMPOUND
LindaneHeotachlorAldrinDialdrinEndrin4.4' DEIT
SPIKE -'ADDED(ug/Kg)
-ffle-r<iB•Tfro
l?holf&°/fr»°
SAMPLECONCENTRATION
(ug/Kg)
°00"°
0
MSCOtICEHTOATIOH
(ug/Kg)
7fl°A-70F/a»//»»./»/oo
/7to<,
MS | QC |\ | LIMITS|
REC f | REC. |
ff 146-1271/a7 135-13011-^7 134-1321»7 131-1341
^.X 142-1391•ff 123-1341
1 1
COMPOOMD
LindanaHeotachlorAldrinDieldrinEndrin4,4 ' DDT
SPIKEADDED(ug/Kg)
^fftofSIti,
-231.0.inn-iM..
MSOCONCENTRATION
(ug/Kg)
9ffwo/.S^tJW»
. ^YT»^F<^
MSDt
REC ft
RPD *QC LIMITS |RPD | REC. I
50 |46-127|31 |3S-l30|43 |34-132|38 131-134145 142-139150 |23-134|
4 Column to be used to flag recovery and RPD value* with an asterisk
* Values outside of QC lirif
RPDs o out ot <• outside liaitsSpike Recovery: g out of 13^ outside limits
COMMENTS:
FORM III PEST-2 1/87 Rev.
(fiZlVTBZ
2FSOIL PESTICIDE SURROGATE RECOVERY 000541
Lab Name: x-rf^-i.ftow^, , ca-rwc
Lab Code: iT-sm Case No.: mfaqs
Level: (low/mad) f>163&
| EPA| SAMPLE NO.1-——"————
01 ItAkaa.u.021i^Wl.bL031wtt»H.T»S04|blH»H*C"ac»-051 tonaaM. virso06|u»i»»n.ms(»L071b»(A^nosi^ssr'^'71*1 0 1m1 2 11 3 1"11511 6 11 7 11 8 11912012 1 12212 3 12 4 1251261271281 -291301 ,„
Contrac
SAS Nc
51(DBC)«
ElE«s
1 1 0
zSzq'
————
st:
o.: s
OTHER
—————
———•—
—————
ADVISORYQC LIMITS
Sl (DBC) - Oibutylchlormdaf (20-150)
t Colum to b« u«*d to flag recovry value*
* Valuec oufid* of QC lixit*
D Surroqaf dilufd out
SDG Ho.: ^Haaoc.
^s?age _L of _LFORM ZZ PEST'2 1/87 Rev.
03217TO3
y.*-
000749Herbicides Analysis Data Sheet
ITAS-KNOXVILLE
Lab Sample 10
Client 10 lAerHoa Ai
Sample Matrix
Percent Moisture (decanted)
/Vt).
JA^S
3 / 3 (
^K
(^
0
Project Code XT
Date Received
Date Extracted
Date Analyzed
Dilution Factor
^\<^\ws-
tJ/fi
7-«3-7-?^y- to-s&•3-\*-^
\'-\<3C>
Compound Name mg/Ut<p (<i9/k^ (ppm) Qualifier
2.4.-0
Z,4,S-TP (SUvex)
2,4,5-T
0,
O.OS"
0.0'S
\^
^
^
-S- " Volume of Extract Injected (»1)
• Volume of Sample Extracted (ml)
• Weight of Sample Extracted (g)
• Volunr of Total Extract (ml)
Qualifier Explanations
U . Not detected0 * Offscale peak and/or out of linear range, therefore value Is estimated0 • Identified and reported from « dilution of original sampleS » Spiked compound
Comments: -7^/y me^c/ /^/ /x- -/i//^^ ^^-r;————
iij^w<, U}^^^ w ^ss/& /«rz> aws/ '^/f^ ?^^ »*. 3/J^/Ss}.
FORM I - HERS
000750Herbicides Analysis Data Sheet
TTAS-KNOXVILLE
Lab Sample 10 _A/o--^3 fe ^)
Client ID AtCTtfOO U- *IK.
Sample Matrix S^A-^O
Percent Wsture (decanted) 0
Project Code J-TFH' V^sr
Date Recel ved iJ/f
Date Extracted •T-a^-gS-
Date Analyzed g-n-^S
Dnutlon Factor 1 : 1 0 0
Compound Name mg/Hter^^ (ppni) Qualifier
2,4,-D
2,4.5-TP (SUvex)
2.4.5-T
0. I
o.os-
0,05
^
<-!
^
-S_ » Volume of Extract Injected (ul)
• Volume of Sample Extracted (ml)
• Height of Sample Extracted (g)
" Volunc of Total Extract (ml)
Qualifier Explanations
U • Not detected0 « Offscal* peak and/or out of linear range, therefore value Is estimated0 • Identified and reported fro- a dilution of original sampleS ' Spiked compound
Comments: f M^/ /^^^^r -^ ^' ^,//4^ ^^r:
UH^S/7 U»rt^fJ« U/MJSf/ ^^^.l e»^/ ^/^^y'/._________
FORM I . HERB
03Z17705
.
000753Herbicides Analysis Data Sheet
ITAS-KNOXVILLE
Lab Sample ID _<4 rt-i?s5S'
Project Code r"rF<m(^TS
Date Received T-aa-^S-
Client l O l i l H - L A H - Date Extracted ^-a-l-gS
Sample Matr ix ^i^s_ Date Analyzed S / ^ . I S I f ^
Percent Moisture (decanted) ?A , o'~[ 011ution Factor /•'/ 60
Compound Name ing/liter Ag/k3)(ppiB) Qualifier
2,4,-0
2,<.5-TP (Sllvex)
2,4.5-T
(3.1
0,^
0.^
~s>
^
n
-£.-
• Volume of Extract Injected (uD
• Volume of Sample Extracted (ml)
• Uelght of Sample Extracted (g)
• Volume of Total Extract (ml)
Qualifier Explanations
U • Mot detected0 " Offscale p«afc Did/or out of linear range, therefore value Is estimated0 • Identified and reported fron a dilution of original sanpleS • Spiked compound
Comments:
FORM I - HERS
03217706
^
Herbicides Analysis Data Sheet 000760
ITAS-KNOXVILLE
Lab Sample ID _Hri.»j,5'8'Client 10 l ,JH^a^
Sample Matrix idc.LLeiy
Pepcent Moisture (decanted) 76,.*>3L
Ppoject Code I-T-FK m/-^
Date Receded 7-^-^
Date Extracted _/7-„>.?-9 ?'
Date Analyzed g/^ /</?&'
Dilution Factor
Compound Name mg/Hter ggkj>(pp«i) qualifier
2,4,-D
2,4,5.TP (Silvex)
2.4.5-T
I.S
/1,3(-
1.5-
&
-D
(-
_£_ • Volume of Extract Injected (11))•Volume of SaMpte Extracted (ml)• Weight of Sample Extracted (g)• Volume of Total Extract (m1)
Qualifier Explanations
U • Not detected0 • Offscal* peak and/or out of linear range, therefore value is estimated0 • Identified and reported fr<» a dilution of original sampleS * Spiked compound
ents:
FORM I - HERB
03Z1W07
/'^
Herbicides Analysis Data Sheet000766
ITAS-KMOXVILLE
Lab Sample 10 ri^J.AS'^
Client ID _ L^3.3i3.n
Project Code JT-^ ^if^TDate Recei ved l-^a-y^
Date Extracted '7-^g-^'a
Sample Matr ix .<J^<.u^y
Percent Moisture (decanted) ^ I . Q ( ^
Date Analyzed ^ / J r / / / ? ^
Dilut ion Factor___/ .•'00
Compound Name ii^/Ht«p^k^(ppm) Qualif ier
2.4.-0
2,4,5-TP (Sdvex)
2.4.5-T
O.ft«
O..l>
0.<:^^
Ul
IA
^
10.39
» Vo1uiM or Extract Injected (u1)
• Volunr of Sample Extracted (ml)
• Wight of Sample Extracted (g)
• VoluM of Total Extract (ml)
Qualif ier Explanations
U « Not detected0 • Offsc«1« peak and/or out of linear rang*, therefore value is estimated0 • Identified and reported fror a dilution of original sampleS • Spiked coMpound
Comments:
FORK I - HERB
03Z17708
^i^
Herbicides Analysis Data Sheet 000772
tTAS-KNOXVILLE
Lab Sample ID >4 i4a3<<» 0
Client 10___i<J t4 aaA
Sample Matrix
Project Code mTk^n.^
Date Received -y-.aa-g-g-
Date Extracted
Date Analyzed0
Percent Moisture (decanted) j•/, /<-/ Dilution Factor /••/O 6
Compound Name mg/Hter ^k tppin) Qualifier
2,4.-0
2,4,5-TP (Sllvex)
2,4,5-T
7, A
^
J,5
3)
6<
J)
" Volume of Extract Injected (u1)
• Volume of Sample Extracted (ml)
• Weight of Sample Extracted (9)
• Volunr of Total Extract (ml)
Qual i f i e r Explanations
U • Not detected0 • Offset}* peik lid/or out of linear rang*, therefore value is estimatedD « Identified and reported froi a dilution of original sampleS » Spiked coMpound
Comments:
FORM I - HERB03Z1W09
/^
000779Herbicides Analysis Data Sheet
ITAS-KNOXVILLE
Lab Sample ID . JJ 4.a^fo I
Client ID \iM\ ^
Sample Matrix Ji<
Percent Moisture (decanted) Rg.A"^
Project Code _Cr^K' 5"
Date Received T-JLa-g-g
Date Extracted 7-^g-g?"Date Analyzed ?//^ ///gg
On lit ion Factor / : / ! > £ >
Compound Name mg/1itep^^^;(ppin) Qualifier
2,4.-0
2,4,5-TP (Sflvex)
2,4,5-T
fA
J,^
7. 7
2s
S
J2>
• Volume of Extract Injected (u1)
• Volume of Sample Extracted (ml)
• Weight of Sanple Extracted (g)
" Volume of Total Extract (ml)
Qualifier Explanations
U • Not detected0 ' Offscal* peak and/or out of linear range, therefore value 1s estimated0 • Identified and reported fror a dilution of original sampleS ' Spiked compound
Comments:
FORM I - HERB
000785Herbicides Analysis Data Sheet
ITAS-KNOXVILLE
Lab Sample ID ^^6.^
Client 10 LJt4 a.o.'-l
Sample Matrix A&^JL^n,
Percent Hoisture (decanted) ^.'/S"
Project Code ITf^Dlt.^^
Date Received 7-J-3-?^
Date Extracted "?-°?7- g?
Date Analyzed S'/^. , / / ys
Oilution Factor _/,'/oo
Compound Name mg/Hter (i /kgJppin) QuaHfler
2,4,-D
2,4.5-TP (SUvex)
2.4.5-T
?.1
J,6
0.1^
1>
Z>
U
' Volume of Extract Injected (u1)
• Volume of Sample Extracted (nl)
• Weight of Sample Extracted (g)
• Volume of Total Extract (nil)
Qualifier Explanations
U » Not detected0 * Offscale peak and/or out of linear range, therefore value is estimated0 • Identified and reported froa a dilution of original sampleS ' Spiked compound
Comments;
FORK I - HERB
H E R B I C I D E M A T R I X S P I K E / M A T R I X S P I K E DUPLICATE B E C O V E R Y 000752
Lab Name; ITAS-Knoxvnie Contract:Lab Sample 10 Hl^c:^-
Client ID: id^ ->^\to
Project No:Jr^k-4^S' SOG No; i.c^3.^\^Matrix:
Sample Concentration units lug/liter /xig/kgYppm)
COMPOUND
2.4.Di;4.5-TP Silvcx)——
SPIKEAOOEO
^.b//.-i-5-
SAWtECONCENTRATION
^.<4>?^. ^
KSCONCENTRATION
4.So£>.l^ 1
ntREC
T-l-7-1
0'•0C\!• t-<M0
COMPOUND
2.4-D2.4.S-TP (Snyexl
SPIKEAOOEO
^/^/.^^
NSOCONCENTRATION
T.^S/ ,Aa
MSDt
REC
^/^<?
I""RPb
-ib-3.G,
U - Compound «n uriyztd for but not o«t«ct«a. Th< nu«b«r <i th« detect (on Unit for thesample.
COMMENTS:
000751HERBICIDE SPIKED BLANK RECOVERY
Lab Name: ITAS-KNOXVILLE
Lab Sample ID: J/3.J ^S)
Project No.: /TW^/i?^
Contract:SDG No.: h^rtyft/(f
Sample Concentration units: ing/liter C' /k^) (ppm) CIRCLE ONE
^(M
COMPOUND
2,4-D
2,4.5-TP (Sllvex)
2.4,5-T
SPIKEADDED
/.<>/
/l.i-ff)
BLANKCONCENTRATION
S- 1 U
O.OS U
BLANK SPIKECONCENTRATION
0. (.S'
O.I H
c\l RECOVERC
6/
-STf
U - Compound was analyzed for but not detected. The number Is the detection limit for thesample.
Comments:
U.S. E?A - CLP 000879E?A SAWU .fO.INORGANIC ANALYSIS DATA SHICT
3Scx,s<wy<u< i SSO^ o<contract: OFfsire, •/'"'' Lab Haaa:
Lab coda: :'•r'-l Caa« Ho.; /7£S^5'SA» NO. ; ____ SOQ No.; ^g/
Matrix («oil/vatar>: SOIL , Lab Saxpla XD: ^SS4<
Lavl. (lov/»«d): ____ Oaf Racaivd: ^p/aa/fg» Solida; /z=?.a
Concentration Unif (uo/L or •a/ka dry wlaht) i
1 1ICAS NO. | Analyf1 11742»-SO-S|7«40-3<-|7440-3»-|7<40-1»-17440-41-17440-41-17440-70-17440-47-|7440-4»-(7440-30-|743»-«»-|7439-»2-|7439-»S-|7439-»«-|7439-»7-17440-02-|7440-0»-|77«2-4»-(7440-22-17440-23-17440-2C-4I 7440-«-a|7440-««-«
i——— i - -,—————
I lAluainua(AntUMnylArxmie)»artu»1—xylllua1CadBiuaIcaleiuaIChro«iua1 CobaltICOppTllren
IKaon—lua1Hanaanaa*|M«reuxyii»icin(poe—15|S«l«nirllilvrHodiua
l inuilllua1 (VuMdiir• "inetcirwia<~
1Concentration
A——W—————^s
'•Ifi^
^
^fa.JfSL
Wi4^
9.&
——^———....t.Q
•7
c
?
!2
1 1Q 1 M|
-,———1-E.ltC~"~L£.
'"t'1 ? 1I PIl P I1 PIl PI1 PI1 PI
1 PI1 ?l' V '1 PI1 PI
l l1 Fl1 PI
•L—!-2!
CM\CiCM•: -CM0
coXor *«ga«-«» rfiy/B^y
Color Attar; ^<fle/a^S
Cooaanta:/^ter ^nc^
Clarity —for*: ____Clarity Attan / fiftg.
Taxtura: Mas/t^/rt
Artifeu; ___
row x - XNMv. in
7/87&d—at Qn«
U.S. C?A - CLP 000880EPA SWftt M.IHORGANXC ANALYSIS DATA SHXST
S'MJt.SSUVtUf | ^SQScontract: .gyre iL«b H»«:
Lab Cod*; :••"•-' Caa» Ho.:/IQ^^SAS Ho.; ____ SOG Me.; //.a^
Matrix (Mil/watar): _SC:L Late Saxpla ID; H^S^
L»v<l (low/rd): ____ o*f x«e*iv<t: Qlfa^ffS?
\ soll-da; g?7.0
concentration Unif (uq/& or •9/ka dry mioht) 1
1 1|C*S Mo. | Analyt*
|^43»-»0-i|7440-3<-t|7440-3»-|7440-3»-17440-41-17440-43-17440-70-17440-47-17440-4«-17440-90-| 743»-.»»-|743»-»2-17439-9S-|743»-»»-|743»-»7-|7440-02-|7440-fl»-1|77«2-4»-al744o-aa-<17440-0-1|7«40-a«-<l744o-«a-a17440-CC^
'1 1
1 IXlUBlnuB1 1 Antimony
lAnwiie1Bariua1 a«ryUlI51CadBiuaicaleiuaIChroaiw1 Cobalt. .icowrII"" „ ,ILMdllteqn—ItaIHuiqanu*|H«reuryHilelrl.
7 ifot—Iial |S«i«aiu>» Uilvrl llodiua
> |ttalliwS ivuwdiua..» <«toe———icyuud*
Concmtracion
//?/s I—^—
, . rt^
.1
^^^
W^Ll^/.^——^———1
.<S-nAQ
•tL/^iL
1C
i1
;:iM
i iQ 1 H |
1 P IA l ( . £ »i<————l"fl
1 3 11 P I1 0|1 P I1 P I1 P I
l'~?l1 011 V I1 PI1 01
1 P11 P1i e ii i
y~\sDCKi• t-(M0
color B«tor«:<4tfi /B^£&Color Affr: / f K
Co——nf: ,/^ter <^nc^
Clarity —Corwt ____clarity Affr: fLe^.
T«xtur«: MBs/u/rtArtifact*: ____
FORM I - IN 7/87Itew. in A—ad—nc On*
L*b Nf:
U.S. EPA - CU
INOXGANZC AMAX.YSZ3 DATA SHZXT
Thuf-^wvimContract: z>ff.s,re
000881EPA SAM9LZ SO.
! ^f5 '
•____ C««. NO.: /1^^5-SA* NO.; _____ SOG No.: ^
Lab supr ID: H^ss4^
L*b Code:
Matrix (soil/wfr);
L<vl (low/»«4); ____ oaf K*e«ivd: QT/ss/^
^S ^^
concentration Onif (uq/L or •9/ka dry wi«ht) * «i'3/<y
« Solids:
1 1|CAS No. | Analyf743»-*0-! '|7440-3<-|7440-1»-|7440-i»-17440-41-17440-43-17440-70-[7440-47-17440-41-17440-SO-|743»-«»-|743»-»2-|743«-«S-|743«-9«-|743»-»7-|7440-03-|7440-0»-| 77M-4»-17440-22-417440-23-SI7440-a«-<1744o-«a-a17440-««-41 1
s lAlirinua1Anttaony"|Ar««nieIBariua1 BoryllFoi1Cadaiua1CaleiuxIChroBluaI CobaltICODPTIXron(Load1Haon—iuB|Mangan«««morcuryHHclclIfoc—IuiISoloniuai unwrl llodiual |HMlli«r1 Ivan—lux"l l « l a s ;ternfCO^
Conemtration
v€l-^sI?aa aw&
'•S———22———J.6^^fl
c
E5
;B?
l l lQ 1 K |——IT!& » E . I
1 F I1 p i1 p i1 B l1 P I1 P I1 p i
1 PI1 PI1 y lI PI1 PI
i=!l!l PIl il |
^^oCVJ• 1-
(M0
color B*tof:Qiw/S^3S&
color Affr: ^ff^jf^
Co—nf: . _/^ter <Junizf
Clarity B«for«: ____
clarity Attan ^JFM^
Toxturo: MB>/if/rt
Artltacft ____
roMt I - IN 7/87Mv. tn A—ad—nc On*
000882
INORGANIC ANALYSIS DATA SHXXT "* SWLg NO.
:n»cx.sowy<u< \U)^^lS 'Contract; />ff.Syre | _ _ _ _ _ _ ,Lab Haoa:
Lab coda: Ca«« No. 8/^a^<»5"SA» No.: ____ SOQ NO. ; l^H3.tO/f
Matrix Coil/vatar): SOIL Lab Saxpla 10:
Laval (lov/aao); ____ Oaf Xacaivad:oaf x«c«ivd! o'y/as/^s'
« solids: .Q
Concentration Unif (u»/L or •o/ica dry wl«h«) i mg/K?
|CAS No. | Analyf
742»-*0-i 1
|7440-3<-17440-3C-|7440-3»-(7440-41-17440-43-17440-70-17440-47-|7440-4«-17440-50-|743»-«»-|743»-»2-|743»-»S-|743»-»<-|743«-»7-<|7440-0a-<|7«40-fl»-1| 77M-4»-3|7440-23-<|7«40-23-'|7440-a«-<17440-«2-]t7440-««>4
1 1
1 lAlualnuJ(Antlaony|Ar««nie|—ri«a1—ryXlIwicadaiua1CaleluaIChroBiuaI cobaltICoppTllronlLaadIKaan—iua|Han9«M««
1 |)toreury> IMlelclT \9MwTSl r«l«nic* riivw1 \99U,W
> ittallir1 |Va*«lua• r^*®——tewSST^
ConcMttratlon
^Ji^/*SQ
———W——————2S.———
^/.
^M
,a/\3———aQa-———
*<-,—^a
^A
/^A
c
\a
:
?
1 1Q 1 K |
l ll p i
1 911 P I1 011 P I1 P I1 P I1 P I
1 P I1 011 U I1 P I1 P I! £ !
l PI1 FI1 E I1 |
^•i^^^^^l ^'
color B«for«:(q(6U/g^£&
Color Atfr: Cti^S^SSSL
Co——nf: , ,IA^T ^^T^c
clarity —for*: ___^
Clarity Aifr» ^Le^L
Taxtura: ft£^^Q
Artitaef: ___
»
rORM I - IN 7/87te«. in A—ad—OC On*
000883EPA SAMPLE YO.INOXOANZC ANALYSIS DATA SHXXT
contract: 7^ ! ^^Lab Naa«:
Lab Coda: "•"i_ Car Me. s /r^^lffS'SAS No.: ____ SDG Ko.; l^ssO/.
Matrix («oil/vafr»: ^L La6 Saapla ID; MoiS^I
Lavl (low/aed): ____ Oaf R«c«iv«d: O'p/^a/Jpi?
t solids: tO-S
Concentration Unit* (ua/L or •9/k9 dry wight) i "'9/K;
ICAS No. | Analyf |ConcMtr«tion|C| Q ||fT55=5y-i|7440-3«-<|7440-3««3|7440-3»-317440-41-117440-43-117440-70-3[7440-47-3|7440-4«-417440-SO-I|743*-«9-4|743«-«2-1|743»-»S-<|743»-»<-S|743»-»7-<|7440-02-<17440-0»-1|77«2-4»-a17440-22-4|7440-23-1|7440-2»-<17440-42-317440-«-<
! 1
riiir»iiii»L1S11J111»I1
AlfinuaAntiaony"Arxmie "—rl™MryXXiSCadBiuBCaleiuachroBiuaCobaltcopperIronL—dHaan—iuxHangur—HircuryMlemAfocaMlwB••IcMir•llvw ''tadivftallluaVuwdiua"*i»aICyuid*
S'MS^Af).an^
^i.
^g-i^
4-.6^
^.bf-7-7
^
2
aa.
i pi
!S—! !1 o l1 3 11 PI> 011 PI1 PI1 PII P I1 ? 11 PI1 yll PII PI1 £ 1
1 ^11 PI
"—!-'!color ••gay ffiy/g{^'ff
color Atfr: ^•V^if^
Co——nf:.——/Jgr ^i^cf.
Clarity —for*: ____
Clarity Atfn /'fntt-
T«xtur«: /Heo/if/rt
Artifaef: ___
roiw i - IM 7/87Itev. in A—ad—nc On*
U.S. SPA - CLP OOOS84EPA SAMPLE .WO.INORGANIC ANALYSIS DATA SHXXT
:Rue.sw^u< i i^-H- S. IContract; /yfsirtLab N«»a:
Lab Coda: :••"•-' caao Wo.:/I£^^5'SAS No.: ____ SDG No.; l^Hs.iO/,
Matrix (Mil/vatar); SOIL l SMpr ID: M^^_)
L»vl (low/rd): ____ o«f R«c«ivd: cnla^lsf?
\ Solids: ss.nconcentration Unif (ug/L or •9/ka dry vi«ht) i '"g/<?
1 |ICAS No. | Anal/to\irsf^-i '(7440-3C-|7440-3«-|7440-1»-17440-41-17440-43-17440-70-17440-47-|7440-41-17440-SO-|743»-t»-|743»-»2-|7439-»5-|7439-»<-|743»-»7-|7440-02-|7440-0»-1|77«2-4»-a|7440-aa-<17440-23-3|7440-2»-<|7440-«2-317440-<0-<11 t
»
f»(1111
AlvinuaAntiBonyArxonieBariua8oryllI5cadBiuaCaleiuaChroaluJCobaltcopperIronLoadMaqnooiuaManqanoooHoreuryNiCltOlrot—vS•olonluB•llvr«odiirTBalliuaVUUdiUBSiaeewnIaS""
Concentration
loP "S^
^M
^l ,-Wf
A^3T/-AO/','^/S-A-7
ieu
?
?
1 1 11 Q 1 K |l ioi t'^'i^—!^!
1 311 011 91
" 1 7 11 PI1 PI1 PI
1 PI1 311 UI1 PI1 011 1
1 FI
1~"1
Color Befor«;<4(fiy/B^S(C.
Color Attar: C^^eSi.
coaurnf: ,/^jgr <^iDCf.
Clarity Baforo: ____
Clarity Attar: /*/^fe
Taxturo: /Ha>/i//n
Artitacf: ___
rORM Z - IN 7/87R«v. in AMBd—ne On*
CLP 000885EPA SAMPLE SO.INORGANIC ANALYSIS DATA 3HXXT
VwJi-wum \ l^^S^^Contract: /yfSire—— I————————Lab Naaa:
Lab Coda: :'•"•-'. Car Mo.:/I£^^5'SA» No.: ____ S06 No.; l^rtS^/p
Matrix (aoil/vatar): ^'L Lab Saapla 10: HH^S^
Laval (low/aad): ____ Oaf Raeaivad: Olts^jjpS?
.q« solid*:
Concentration Unit* (ua/L or •9/k9 dry wight) < nig/^
JCAS Ho. j AnaLyta^43'i-to-l Aluainua|7440-3<-0 |Antl»ony|7440-i«-2 lAraanio|7440-3»-3 IBartua17440-41-7 1—rylllui|7440-43-» ICadaiua17440-70-2 ICaleitU(7440-47-1 IChr—iua17440-4B-4 1 Cobalt|7440-90-» 1 copperi743»-»»-« linn17439-92-1 |Laa417439-95-4 (Haon—IuS|743»-»<-s |Hanqana««|74l9-»T-« IMarcury17440-02-0 IHleJfL|7440-<»-7 |f0t——lt5|77ta-4»-2 |s«l«niua17440-22-4 IXllVMr17440-23-» l«0«iua|7440-2«-o |lball.i«ai|7440-«2-a |vaaa41toi|7440-f-« 1«1«Ci ienniasr'
Coneantration
ffl1^33^———^———
*tf^y\
^J.<%»— — a d J
—^r———S3.———^ft^rt
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5
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1 ? 11 ?11 ul1 PI1 ?1
1 PI1 PIl £ l
CO\0<M•=1-(N0
Color B«fora! a&u/g^SJl,
color Attar: CMOtieS
clarity —for*: . ___
Clarity Attan ri£^L
Taxtura: f^^uO.
Artifacu: _
Co—anf:,l^r
rORH I - IN 7/87Mv. in AMBi—at °n*
U.S. E?A - Ctf OOOS86t?A SAMPLE SO.INORGANIC ANALYSIS DATA SKZXT
3flUt.SaWf(tA6 | //U/ -•>_•> -i A/,contract: /)ff.s/r« [ wtt^A-^Lab Kaa«:
L>b coaa; '--3-J Caa. Ke.:/IES^»5'SA. Ha.: ____ SDG Ho.; ^^
Matrix coil/vafr): ^ll Lab Saapla ID; HH£3s4
L*val (lov/»«d); ____ Oaf X«e«ivdf 07/^lffi?
» solida: H.Qf'-Qconcentration Unite (ug/fc or •9/k9 dry vi«h«) 1 mg/K; a^
\o(M1-
<M0
ICAS NO. | Analyf|742»-»0-«|7440-3<-(17440-it-17440-3*-17440-41-17440-43-17440-70-17440-47-|7440-4»-17440-SO-|743»-«»-|743»-»2-|743»-»S-|743»-»»-|743»-»7-|7440-02-017440-Ot-lI77«a-4»-a17440-22-417440-23-S|7440-2«-417440-«a-a|7440-«C^
• t
1 (AluBlnual lAntiaony"
|An«nie ~1Barlua1 B«ryl}.ni1CadBiUB1CaleiuaIChroBiua1 Cobalt~icop—rIXronILMd "1 Maon—iuaIManqanwIMwcury
» Illlefll Ifofwiwi1 |S«L*niua1 IlilVW) •oJlual ThalUu1 Vaaadiua"1 «ina,——. tesMaSST^
Conemtratlon
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color B»for»:(q(fi,u/B^£
Color ACfr: C^OUS^
COBB»nt«:——/^fer <dJ^cf
Clarity —for*: _____
Clarity Affri fLeML
Taxtur*: MB>m/ft
Artifaeta: ___
FOMI I - ZN 7/B7tey. in A—ad—nc On*
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O.S. I?A - cif 000899
L*b Ha
«nn SAru ..cow «» »>H,a HO.^oaofly/^ j .A3(%» s i '-
ms-iammi i F—————— Coatnee: aff^r-e |________; .
___ •BB Ke. 1 ^»J30^L*b Cod*: 1T-5TU CW »o.»/Cg^iW«A» Ka.:
Lwl (low/wd): ____GFAA 1 CVM ONLYMttrix (*oil/wfr)i '.nilLAB SAMPLE ID ifHSS^ 5 ————Os!
0concutraeion oniu (u»/I. or •g/Kg dry vl;ht): ma/ko
1
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03Z1W26
001147ANALYTICALSERVICES
, ...._..ATIONALTECHNOLOGY
I CORPORATION.-n-^'->''""" . ^"Si ~
5815 Middlebrook Pike • Knoxville Tennessee 37921 • 61 5-588-6401
CERTIFICATE OF ANALYSIS
Hercules, Inc., Medical Dept.ATTN: Florence K. KinoshitaHercules Plaza1313 N. Market StreetWilmlngton, DE 19894
DATE REPORTED August 31, 1988PROJECT CODE ITFK 41695
ORDER NUMBER 480078.01.08.01PAGE__1__ OF 1
Sample Description: Three (3) sludge samples received July 22, 1988
Concentration units are mg/kg (ppm)
inE "-(M•stOJ0
Total PhosphorusCalciumMagnesium
WH2218810
1,850107
WH22191,4005,140
88
WH2225
1,2003,860
.112
Approvedby ^/operations Manager
Accredited fcy ir-.e Amencan Association tor Laboratory Accreditation in the chenucal:ield oi lest:ng as luted in ihe cunwit AALA Directory ol Accredited Laboratones
KCNNCTH • WOOD*^•••tDKMT
<iA!L, » HUTCHENBCKKCUTIVC VICK-PMKCIDXNT
p.o.BoxsnoKNOXVILLE. TN »7*a0-l«'0
QUANTITATIVE MICROANALYSESORGANIC - INORGANIC
•IS/S4C-11JB
Corrected Copy ,"';,"-•; ;3 i:•l~' ' -'•• fi'' . i ";•••' 1 "'• '':1 '
3313 SYCAMORl OK.KNOXVILLE, TN 37»21-17SO
ITAS5815 Middlebrook PikeKnoxviUe, Tennessee 37921
AUG 161988August 5, ly88
Received; July 27thProject Code; ITFK^iu.
Osdr Sir;
Analysis of your compounds gave the following results:
Your #, Our #, Analyses,
Htl2368WH2218
HH2J6UWH2219
B-3073
% Carbon 3.10% Hydrogen 9.54% Nitrogen 0.42% Sulfur 0.83% Chlorine 0.019% H,0 87.74% Oxygen Iby differenc e) 86.09% Ash 62.06BTU/lb 734% Carbon 2.74% Hydrogen 10.38% Nitrogen 0.20% Chlorine 0.037% Sulfur 1.43% H,0 88.36% Oxygen {by difference) 85.21% Ash 69.36BTU/lb 392
LITTIR AND •MIPMCMT* •T U.«. •*IL - ».0. •OX •MIO. KNOXVILLt. TN ••HM-H10. OTMf CAHHIIM • ISafYUMOIIf OH. KNOXVILLI. TN »7«»1-17»0
IITACLrxID t—0
03217728
00114UITASPage 2August 5, 1988
Your #, Our >, Analyses,
tlli2370 B-3074 % Carbon 2.97UH2225 % Hydrogen 10.01
% Nitrogen 0.24% Chlorine 0.023% Sulfur 0.24% H.O 86.24% Oxygen (by difference) 86.52% Ash 65.19
BTU/lb 582(--r~-(M•^rCM
We regret that we inadvertently left the Ash results off the original letter. We apologize Qfor any inconvenience this has caused.
Sincerely yours,
GALBRATTU LABORATOB1ES, INC.
G8.ti-.sc
OAURAITH LAIORATORIO. INC.
SAMPLE DATA PACKAGE
I CASE NARRATIVE
August 31, 1988
Florence K. KinoshitaMedical DepartmentHercules PlazaHercules, Inc.1313 N. Market StreetWilmington, OE 19894
CASE NARRATIVE
ITAS Project Code:Sample Delivery Group Number (SDGif):Laboratory Name:ITAS Job Number:Case Name:
ITFK 41695WH2206ITAS-Knoxville (IT-STU)480078.01.08.01Jacksonville Off-Site
Enclosures
Enclosed are the data for ITAS Project Code ITFK 41695. Table 1 lists field andITAS sample numbers, sample matrix, sample concentration, and analysisrequested.
Sample Receipt
The samples were received in one (1) shipment on July 22, 1988. The shipmentcontained thirteen (13) sludge samples in good condition. The samples werepacked in melted ice and the temperature was 6'C when the samples were receivedat ITAS.
Note: Instructions to composite samples WH2220, WH2221, WH2222, and WH2224 werenot provided with the Request for Analysis forms. The volatiles analyses, her-bicide analyses, and semivolatile and pestldde/PCB extractions were alreadycompleted when these instructions were provided. Therefore, the four sampleextracts were composited to one prior to semivolatile and pestlcide/PCB analy-sis.
Also, please note that all results are reported on a dry weight basis except forthose in Section VIII HASTE CHARACTERIZATION.
Regional Ollice5815 Middlebrook Pike • Knoxvllle. Tennessee 37921.615-588-6401
INTERNATIONAL TECHNOLOGY CORPORATION
Page 2August 31, 1988ITFK 41695
GC/MS Analysis
The volatiles analyses were performed on 7/27/88 by purge and trap with packedSP-1000 column on a Finnlgan OWA GC/MS/DS.
The semivolatiles analyses were performed on 8/11, 8/12, and 8/17/88 by directinjection of sample extract on a JiW DB-5 capillary column on a Finnigan 4500GC/MS/DS.
The analysis followed EPA CLP SOW 10/86 protocol, with the modification of a:)
heated purge for volatiles in medium soil. Screening indicated high levels of CMorgam'cs, therefore, a11 volatiles were analyzed by the medium level method •=3-(methanol extraction followed by purge of extract aliquot), which is effectively 04a 125 fold dilution from the low level method. Samples WH2220, WH2221, WH2222 ~and WH2224 were run separately in the volatiles analyses. The analyses wentsmoothly.
The semivo1ati1es samples were also extracted using the medium level method(effective 60 fold dilution from low level). Extracts of samples WH2220,WH2221, WH2222, and WH2224 were composited 1:1:1 :1 before analysis and reportedas if the samples were composited prior to extraction. An averaged weight anddryness factor was used to calculate dry weight results overall. The semivo1a-ti1es analyses also proceeded well. No problems, QC or otherwise, were seen inthe final data.
Data were reported with qualifiers as follows:
U - Compound analyzed for but not detected.E - Compound exceeded CLP calibration range.0 - Compound analyzed at a secondary dilution factor.J - Compound detected but below the contract required detection limit. The
value given was an estimate.S - Spiked compound.8 - Compound was found in the method blank.A - Suspected aldol condensation product.Y - Indistinguishable isomer in tentatively Identified compounds.
GC Analysis (Pesticide/PCB)
The pesticide/PCB analyses were performed from 8/8/88 to 8/19/88 by gaschromatography/electron capture detection using SP-2250/SP-2401 and 3t OV-1columns on Varian 3700 instruments. The analyses followed EPA CLP SOW 10/86protocol. The samples were extracted using the medium level method; all requiredsulfur cleanup. Extracts of samples WH2220, WH2221, WH2222, and WH2224 werecomposited 1 : 1 : 1 : 1 before analysis and reported using an average weight and dry-ness factor. No major problems were encountered.
03Z1W33
INTERNATIONAL TECHNOLOGY CORPORATION
Page 3August 31, 1988ITFK 41695
Data were reported with qualif iers as follows:
U - Compound analyzed for but not detected.D - Compound analyzed at a secondary dilution factor. DL was appended to the
sample number.S - Spiked compound.X - Peak off scale and therefore out of linear range.ST - Sulfur treatment was performed.R - Used to label chromatograms for which an interfering peak response was
used to calculate a quantitation limit for the compound of interest.
The hexane Injections listed on FORM VIII PEST 2 are used only to prevent lateeluting components from interfering with sample or standard injections.Therefore, no surrogate is added and ID for d1butylchlorendate retention timeshift is not reported.
Sequence Explanations
V3740A, 2250/2401, 08/8-10/88: The INDA at 22:07 on 8/09/88 did not meet theconfirmation criteria for 4,4'-DOT. The INDB at 22:37 on 8/09/88 did not meetthe quantitation criteria for 4,4"-ODD. The sequence was resumed on the morningof 8/10/88 with INDA and INDB at 08:44 and 09:51, respectively. Both standardsmet all criteria for quantitation so the sequence was continued, and allaffected samples were reanalyzed.
SC Analysis (Herbicides)
Analyses for chlorinated phenoxyacetic acid herbicides was performed from 8/2/88through 8/18/88 by gas chromatography/electron capture detection with both mixedphase (SP-2250/SP-2401) and 31 OV-1 columns on a Tracer 565 instrument.
The analysis followed EPA SW-846 Method 8150 as modified by ITAS StandardOperating Procedure GC860523RO. In addition, boron trifluoride was used as aderivatization agent in l ieu of diazomethane. (The extraction procedure usedmore closely resembles Method 509B, Standard Methods for Examination of Waterand wastewater, 16th edition.)
The extraction blank, as analyzed on the OV-1 column, demonstrated a contaminantwhich, though not in the 2,4,-D window, obscured the 2,4-D peak. It appeared inmost samples. When run on the mixed phase column, the contaminant and 2,4-Dpeaks were resolved. Thus, In most cases, the mixed phase results were used forquantitation.
Matrix Interferences on the OV-1 column prevented the confirmation of 2,4,5-T insome samples. Matrix Interferences were also noted in some samples at the2,4,5-TP (Si'lvex) window. In these cases, the sample quantitation limits arehigher than normal.
INTERNATIONAL TECHNOLOGY CORPORATION
Page 4August 31, 1988ITFK 41695
The matrix spike, matrix spike duplicate, and blank spike all had acceptablerecoveries.
Metals Analysis
Samples were analyzed for priority pollutant metals plus barium 1n accordancewith EPA CLP SOW 7/87 protocol. The sludge samples were prepared using method3050. These digestions were performed on 8/10/88; no problems were encountered.Samples for mercury analysis were prepared just prior to analysis.
Analyses were performed using a combination of Cold Vapor Atomic AbsorptionSpectroscopy (CVAA), Graphite Furnace Atomic Absorption Spectroscopy (GFAA), andInductively Coupled Argon Plasma Spectroscopy (ICP). The CVAA analysis for mer-cury was performed on 8/10/88. The GFAA analysis for arsenic, selenium, andthallium were performed on 8/12-25/88. The remaining metals were analyzed usingICP on 8/12/88. Lead was analyzed by ICP rather than GFAA since sample con-centrations were greater than five times the ICP detection limit.
The matrix spike for ICP was inadvertently spiked at one-half the normal level.The ( recoveries were outside control limits for antimony, lead, silver, andzinc by ICP, mercury by CVAA, and arsenic by GFAA. A post digest spike was per-formed with acceptable recoveries. Silver and antimony results were most likelylow due to chloride interference. Lead, zinc, and mercury results were onlymarginally out, having insignificant impact on data validity. The arsenicresults indicate matrix effects. The duplicate precision was within controllimits for all elements. All run QC was acceptable.
Haste Characterization
Samples were analyzed for total phosphorus on 8/2/88 using EPA Method 365.3,Methods for Chemical Analyses of Hater and Wastes. EPA 600/4-79-020, March 1983.Calcium and magnesium analyses were performed by ICP on 8/10/88. The raw dataare included in Section VIII b, METALS DATA - ICP ANALYSIS.
Ultimate analyses ((C, 0, H, N, S, chlorine, moisture, and ash) and BTU/lb wereperformed by Galbraith Laboratories.
Approved by:
<y^ /^- -^
Robyn WagnerOperations Manager
RW:sm
Enclosure
INTERNATIONAL TECHNOLOGY CORPORATION
TABLE 1SAMPLE SUMMARY TABLE
ITAS Project Code:Sample Delivery Group Number (SDGj?):Laboratory Name:ITAS Job No.:Case Name:
ITFK 41695WH2206ITAS-Knoxville (IT-STU)480078.01.08.01Jacksonville Off-Site
Field NumberMH2216
MH2216 MS
WH2216 MSD
WH2217
WH2220
WH2221
WH2222
ITAS #HH2355HH2355HH2355HH2337HH2356 MSHH2356 MSHH2356 MSHH2338 MSHH2357 MSDHH2357 MSDHH2357 MSDHH2339 MSDHH2358HH2358HH2358HH2340HH2359HH2359HH2359HH2341HH2360HH2360HH2360HH2342HH2361HH2361HH2361HH2343
Matrix
S1udgeSludgeSludgeSludge
SludgeS1udgeSludgeSludge
SludgeSludgeSludgeSludge
SludgeS1udgeSludgeSludge
S1udgeSludgeSludgeSludge
SludgeSludgeSludgeS1udge
S1udgeSludgeSludgeSludge
Cone. AnalysisMed BNAMed HerbicidesMed PEST/PCBMed VOMed QC-MS-BNAMed QC-MS-HerblddesMed QC-MS-PEST/PCBMed QC-MS-VOMed QC-MSD-BNAMed QC-MSD-HerblcldesMed QC-MSD-PEST/PCBMed QC-MSD-VOMed BNAMed HerbicidesMed PEST/PCBMed VOMed BNAMed HerbicidesMed PEST/PCBMed VOMed BNAMed HerbicidesMed PEST/PCBMed VOMed BNAMed HerbicidesMed PEST/PCBMed VO
INTERNATIONAL TECHNOLOGY CORPORATION
TABLE 1SAMPLE SUMMARY TABLE(continued)
Field Number
MH2224
MH2206
WH2206 D
WH2206 S
WH2208
WH2213
WH2215
WH2220
WH2221
WH2222
WH2224
WH2218
WH2219
WH2225
ITAS <!
HH2362HH2362HH2362HH2344
HH2345
HH2346
HH2347
HH2348
HH2349
HH2350
HH2351
HH2352
HH2353
HH2354
HH2363HH2369
HH2366HH2369
HH2367HH2370
Matrix
S1udgeSludgeSludgeSludge
Sludge
Sludge
Sludge
Sludge
Sludge
Sludge
S1udge
S1udge
S1udgeS1udge
SludgeSludge
SludgeSludge
S1udgeSludge
Cone.
MedMedMedMed—
——
—
—
——
——
—
—
—
—
Analysis
BNAHerbicidesPEST/PCBVO
LTiMetals ^
QC-D-Metals c\!
^QC-S-Metals CM
0Metal s
Metals
Metals
Metals
Metals
Metals
Metals
Waste CharacterizationWaste Characterization
Waste CharacterizationWaste Characterization
Waste CharacterizationWaste Characterization
ABBREVIATIONS: BNA = Semivolat liesPEST
PCBVO
PesticidesPolycniorinated biphenylsVolatiles
MS Matrix spikeMatrix spike duplicateDuplicate
MSDDS = Spike
CHAIRMAN OP THE BOARO PRKIIDKNT CKICUTIVI VICE. ^RflOKNT «ECHETARY/TREA«UREf1
p^-- •"—- r—'"'"-"
GALBI^tITH I '—^P C i. • \/t SEP 15 ]
^(WOla.wus.i, wry^.QUANTITATIVE MICROANALYSES
P.O. BOX sisio ORGANIC - INORGANIC asaa SYCAMORE DR.KNOXVILLE. TN 37950-1C10 •IS/S46-1335 KNOXVILLE, TN 37321-1750
Ms. Robin WagnerITAS5815 Middlebrook PikeKnoxville, Tennessee 37921
September 14,1988
Dear Ms. Wagner:
Enclosed are the procedures requested.
G-45AG-26CC-20ME-4-17E16-2ME-6S-110
Sincerely yours,
Gail R. HutchensExec. Vice-President
GRHssc
LCTTCR AND SHIPMENTS •Y U.S. MAIL - P.O. •OX BflO. KMOXVILLC. TN 37»SO-1«10. OTHKR CARRICRS • 2321 SYCAMORE DM. KNOXVILLE, TN a7«31-1790
ESTABLISHED f0
BAIL R.HUTCHENSEXECUTIVE VICC.PRC81DENT
1CLMA M, RUSSELL
P. 0. BOX 41872323 SYCAMORE DR.
QUANTITATIVE MICROANALYSESORGANIC - INORGANIC
KNOXVILLE, TENNESSEE 37621PHONE 546-1335AREA CODE 6 1 5
PROCEDURE*G-45A Ash Procedure» Furnace
Preparation
Decomposition
Final Matrix
Method
/""\ Reagents
Determination
Interferences
Calculations
References
Otherprocedures
Weigh sample to nearest 0.
Begin w/ cold muffle furnamechanical loss (approx.
Finish ignition to constan
H,SO, to be added if requiCool in desiccator over de
Weigh to nearest mg.
Volatile metals
[(A-B)/c] x 100 » 7. Ash
ASIM D3174-73Clark. S.J.. Quantitative
1956, pages 37-39
i
1 mg in Pt or ceramic
ce. Gradually heat tc50 increments)
t weight at 750°C.
redsiccant
A-wt of capsule andB-wt of empty capsulC-wt of sample (g)
Methods of Organic Microanalysis
ElementRange
•> avoid
ash rese (g)
r-COM•-3-CVJ
idue
0
(g)
03217739
LETTER AND SHIPMENTS BY U.S. MAIL - P.O. BOX 4)87. OTHEB CARRIERS - 2323 SYCAMORE DR.. KNOXVILLE. TN. 37B21
____ ESTABLISHED 1»SO
H A R R Y W GALBRAITH. PM DCM*IHM»N OF THE 90ARO
KENNETH S WOODSPRESIDENT
GA1L R HUTCHENSexccuTivE VICE- riicsioeNT
VELMA M RUSSELL
P.O. BOX 5 1 6 1 0
KNOXVILLE. TN 37950-1610
GALKR^ITHJLauo'La.ioiLe.i, .One.
QUANTITATIVE MICROANALYSESORGANIC ~ INORGANIC
615/54B-13352323 SYCAMORE DPI.
KNOXVILLC, TN 37921-17SO
Element n oprocedure if6-26 Moisture by Drying
RanqePreparation
r^Instrument
CalibrationSaniple Intro.Determination
InterferencesCalculations
References
Otherprocedures
Precondition glass weighing bottle at conditions of test (105° 0for one-half hour. Record tare weight and sample weight sufficientfor a 1-10 mg weight loss.MettLer M-5 balance; Blue M StabiL-Therm Constant Temperature Cabin
Dry two hours at 105° C unless otherwise specified by client.Cool in desiccator; weigh back bottle and sample, subtract tare weiOther constituents volatile at dOS'O
Initial samole weiaht ( m q ) - dry sample weiqht (ma)x^OQ%Initial sample weight (.mg) " I'L'-L;:'l-
USPharmacopeia XXI pp. 1249 and 1280
Karl Fischer (Coulometnc) determination (S-300); Loss on drying (USP731)
•-'
et
ght
-ure
03Z1774Q
LETTER AND SHIPMENTS BY U.S. MAIL . P.O. BOX SIBO. KNOXVILLE. TN i7.»0.,«10. OTHER CARRIERS • i323 SYCAMORE DR. KNOXVILLE. TN i7.2,-,7i0
ESTABLISHED 1950
KENNETH • WOOD* SAIL H. HUTCHEN* VELMA M. RUSIELLt«C>tlTAI»Y/TNt*«UI»e«I
eALBR^IITH^La.Doiato'iis.i, Due,
QUANTITATIVE MICROANAL.YSESORGANIC - INORGANIC
eiS/548-1333
P.O. BOX 5 1 6 1 0KNOXVILLE, TN 37950-1610
2323 SYCAMORE DR.KNOXVILLE, TN 37921-17SO
PROCEDUREifCC-20 Detemiination of Volatile Matter
Element
Range
Preparation
Decomposition
^"^Final Matrix
Method
Reagents
Deternri nation
Interferences
Calculat ions
Weigh sample to nearest 0.1 nig in Pt or ceramic w/cover.
Begin w/ cold muffle furnace. Gradually heat to avoid mechanicalloss (approx. 50° increments)
Finish ignition to constant weight at 950°C.
Cool in desiccator over desi'ccant
Weigh to nearest mg.
A= wt spl (g)weight loss, % = (A-B)/A
VM, t, = C-DB = wt spl after heating (g)C = wt loss, %D = moisture, %
References
Otherprocedures
ASTM 3175
51610. KMOXVILLE. TN 37BBO-H10, OTHER CAHWIKS - 212) SYCAMORE DR. KNOXVILLE. TN J7m-<750
ESTABLISHED 1«>0
4 OP THE •OAHD
KENNETH •• WOODSPHCtlOCNT
GAIL. R. MUTCHCW:KECUTIVE VICK- PBCBIOKNT
VELMA M. RUMELL•ECRETAMY'TIIKAIUIiei
eAI.KR^lI'TH^Lavo'laioiis.i, Una.
P.O. BOX Sl«10KNOXV1LLE. TN 379SO-)610
QUANTITATIVE MICROANALYSESORGANIC - INORGANIC
BlS/a4«-l.i3S
2323 SYCAMORE DR.KNOXV1LLE, TN 37921-1780
Procedure *'
ME-4-17 Chlorine by Ion OiramatograEily
Element
Ran_qe
00-.CJ<3-
Cl (M
FFm
PreparationDeconpositionFinal Matrix
Instrument
Calibrat ion
Sample Intro.
Determination
Interferences
Calcula t ions
O^- 1 g Parr Bcnto; 200-500 mg Schoniger flask10 nil 3% v/v H202 (exact volume) as absorbing solution (30 min, swirl)
Dionex Model 10/14 Ion Chromatograph ; Dionex 2000i Ion OircnatograEAl
1-30 Fp" (bracket sanple concentration)
100 ul Auto-injector (Ilicrometrics-Model 725)
Peak area ratio, oonductimetric detection
ppm = x 10 x %"S—10 ml
References Sawicki, et.al. Ion Chramatographic Analysis, Ann ftrbor Sci, 1978 p 149-167
Otherprocedures
E 17 series
03Z1W42I. KNOXV1LLE. TN 37MI-17BOLETTER AND SHIPMENTS BY U.S. MAIL - P.O. BOX »1«10. KMOXVILLE, TN »7»»0-1«10. OT>
ESTABLISHED 1»80
HARRY W, GALBRAITH. PH DCHAIRMAN OF THE BOARD
KENNETH S WOODS GAIL R. HUTCMENS VELMA M. RUSSELLfCCttETARV/TRKAXUMCfl
^Ca.WT.ato'lis.i, Line,
P. 0 BOX 41872323 SYCAMORE DR.
QUANTITATIVE MICROANALYSESORGANIC - INORGANIC
KNOXVILLE. TENNESSEE 37B2!
PHONE 546-133SAREA CODE 6 1 5
Procedure fE16-2 Sulfur by Leco S Analyzer
Element SRange ^
Preparation
Instrument
Calibration
Sample Intro.
^-4>etermination
Interferences
Weigh only: microbalanceAdd catalyst: V^O;
Leco SC 152Phenylthiourea ( 2 1 . 0 7 % ) ; Phenylsulfone(14.69%) referenceCeramic boat; 0 atmosphere at 1400 *CSO^ to infrared detector; microprocessor formulates resultsRange 0.005 - 9 9 . 9 9 % ; sensitivity 0.001%
Calculations 103rug sample % S ( R = instrument readout)
References Leco S System 200-192 ManualASTM 04239Otherprocedures E 16 series
03Z1W43
LETTER AND SHIPMENTS BY U.S. MAIL - P.O. BOX 4187. OTHER CARRIERS - 2323 SYCAMORE DR.. KNOXVILLE. TN. 37B21
ESTABLISHED 19SO
KENNETH & WOODS^nflOCNT
SAIL R. MUTCHENS VELMA M. RUSSELL
P. 0. BOX 41872323 SYCAMORE DR.
eAL^R^IITH^avoiatoiisi, Una.
QUANTITATIVE MICROANALYSESORGANIC - INORGANIC
KNOXVILLE, TENNESSEE 379X1
PHONE 546-1335AREA CODE 6 1 5
Procedure # Carbon .Hydrogen and Nitrogen by Leco CHN - 800 Determlnator cipnient
" E - S ____________________________________Range, CHN
CMC-'CM•<rC J0
Preoaration
Instrumentr^nbration
Sample Intro.
ermlnation
Calculations
Weigh only; sample weight range: 2 to 25 mg
Leco CHN - 800
Standard: AcetanHlde (5 - 15 mg)
Sn capsule; Og atmosphere at 950°C
Infrared absorption: C»H?; Thermal conductivity: N«
Range: C - 1.00 - IOO.OX; H - 0.50 - 100.0X; N - 0.50-50.0%
Microprocessor formulates results
References
Otherprocedures
Leco manual 200-370
E-6,E-1,E-7 series
LETTER AND SHIPMENTS BY U.S. MAIL - P.O. BOX 4187. OTHER CARRIERS - 2323 SYCAMORE DR.. KNOXVILLE. TN. 37921
ESTABLISHED 1930
HARRY W GALBRAITH, PM DCHAIKMAN OF THE BOARD
KENNETH S WOODSPRESIDENT
SAIL R HLJTCHENSCUtLUTIVt VICE- MeSIOENT
\'ELMA M. RUSSELLseCKeTARY.'TIIEASURen
^'a.EfO'iakoits.i, Due..
P. 0 BOX 41872323 SYCAMORE DR.
QUANTITATIVE MICROANALYSESORGANIC - INORGANIC
KNOXVILl-E. TENNESSEE 37B21
PHONE S46-1.33SAREA CODE 6 1 5
Procedure H Gross Heat of Combustion by Bonto Calorimeter
S-110________________________________
Element BTU/Ib.
Range
(M>^(M
Preparation A. Weigh only, 0.8 - l.lgB. Foymtablet, weigh
Instrument Parr 1241 Automatic Adiabatic CalorimeterBenzoic acid control/calibration standard
Calibration
Sample Intro.
Determination
Interferences
Calculations
Oxygen Bonfa 30 fOK 0^
Tneaaiicnietric
High % halogens
H(q) =|C(T final - T •Initial) - (F corr)sanple weight (grains)
Pcorr=' f"s® correctionK= clerived calorimeter
constant
References
Otherprocedures
ASTO D-2015, D-2382, D-3176, D-3180
OC-90 .
03217745
LETTER AND SHIPMENTS BY U.S. MAIL - P.O. BOX 4187. OTHER CARRIERS . 2323 SYCAMORE DR.. KNOXVILLE. TN. 37921
ESTABLISHED 19BO
II TRAFFIC REPORTS
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GALBRAITH LABORATORIES, Inc.P.O. BOX 51610 — KNOXVILLE, TENN. 37950-1 S10
615/548-13351 REQUEST FOR ANALYSIS
SAMPLENo. r^^-70_____________REPORT TO )Tff? ______________
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PURCHASE ORDER No. _____________________ANALYZE FOR: Illi±UrY\C^L> QnOlylS________
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I HERCULES' Hercules IncorporatedHercules PlazaWilminglon. Delaware 19894(302) 594-5000Telex: 83-5479
July 22, 1.988
Mr. Bud GibsonIT Corporation5815 Middlebrook PikeKnoxville. Tennessee 37921
Dear Bud:This letter will serve as authorization Cor IT to performanalyses on samples of sewage treatment plant sludge beingshipped to you from Jacksonville. Arkansas. This work will bepart of IT Project No. 480078 (Hercules Project No. 88-25).As discussed on Thursday. July 21. three ( 3 ) samples are beingsent to you for priority pollutant (volatiles. semi-volatiles,pesticides/PCB's) and phenoxy herbicide [2.4-Dichlorophenoxy-acetic acid. 2.4.5-Trichlorophenoxyacetic acid and ,2,4,5-Trlchlorpbenoxypropionic acid (2.4.5-TP; Silvex)] .analyses.An additional eight ( 8 ) samples ace being sent to you foranalyses for the 13 priority pollutant metals and barium. Thecontent of a total of 14 metals will be determined in each ofthese eight samples.Also. as you have discussed with Dana Simecly and Al Husak.three < 3 ) additional samples are being sent to you forcharacterization of the sludge for possible incineration. Eachsample, shipped in two 250 ml bottles, is to analyzed tor thefollowing: moisture content, high heat value B . T . U . , total ashby weight, total phosphorus by weight, total chloride by weight,total nitrogen by weight, calcium, magnesium, sulfur. carbon.hydrogen and oxygen.The analyses for priority pollutants, phenoxy herbicides andmetals are to be done following CLP procedures. It is ourunderstanding that the costs for analyses for volaciles is
C\J0f~\'(M0
HERCULES
Bud GibsonIT Corporation Page 2
t450/sample, for semi-volatilea is tSOO/sample. forpesticides/PCB'B is t290/sample, for the phenoxy herbicides is(340/sample and for metal is $410/sample. It is also ourunderstanding based on conversation with Al Husak that the costfor characterization of the sludge is tsao/sample. The totalcost for these analyses is. therefore. $10,660.We also understand that the turn-around time for the analyses is4 weeks. He will. therefore, expect reports for this work byAugust 22, 1988. The reports should be sent to me at the rfollowing address: 0,
Florence K. KinoshitaMedical DepartmentHercules PlazaHercules Incorporated1313 N. Market StreetHilaington. Delaware 19894
If there is any misunderstanding or confusion about any of theabove, please contact me. My telephone number is (302) 594-7066.
Sincerely,
Florence K. Kinosbita. Ph.D.Senior Toxicologist
cc: Cynthia Q. Johnson - IT CorporationDana Siaerly - IT CorporationAl Husak - IT CorporationJohn P. Frawley - Hercules
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COMPOUND1,1-DiehloroetheneTrichloroetheneBenzeneTolueneChlorobenzene
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. flMZ• ANALYZED
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paa* ofrom v VOA l/»? B«v.
03217760
5AVOLATILE ORGANIC GC/MS TUNING AND MASSCALIBRATION - BROMOFLUOROBENZENE (BFB)
000005
Lab Nina; I'^fiS-KMOf^lu.e______ Contract:,fTFkCar Ho.: ««.«?g SAS Ho.: SDC no.: umzgoc,Lab Coda: rrST^
Lab File ID:
iMtruaant ID:
BFB Injection Data:_02l?3_[8^
BFB Injection Tima: 07 Id
Matrix: Coil/vatar) Sa\t- Laval:(low/Bad) M6& Column (pack/cap) ftkfc.
»/aSO759596173174175176177
1-Valua i« * BBU 174 2-Valu*
ION ABUNDANCE CRITERIA15.0 - 40.0* of • • • • 9530.0 - 60.0* Of ——• 95B*«« p«ak, 100* relative abundance5.0 - 9.0» of •asB 95Law than 2.0« of •aaa 174Graatar than 50.0* of •aw 955.0 - 9.0* of •aw 174Graatar than 95.0*, but lax* than 101. o* of —5.0 - 9.0* of Raaa 176
1 » RELATIVE1 ABUNDANCE1 CT.O\^If&iIc.afll64d (aad )111 • • • < • 1l«».w (iwa in
»•• 1741fl8.3 («H.fc ) l |1 tW ( ».t^ »21
f * aa** 176THIS TUNE APPLIES TO THE FOLLOWING SAMPLES, MS, MSO, BLANKS, AND STANDARDS:
| EPA| SAMPLE NO.
Oil OSt^OSD021 UBLfet031U«lt2*t.041^rt22il.M&OS luifr ??(«"•*« t»061 t^rttin071utHtto081 lultZEtl091 wri2»«101 ^»-ittU111121131141 -1511CI171n191201211221
LABSAMPLE ID
u<T<» •»?•»»Uftl.ftTT-TlUUTWOIuxissa.surtwrbWri 29116 J>1UI(?2«IDIUH HUSIUl»2?4tblUUTMKDI
LABFILE ID
tt<7 072-71UB>.*-7l-I,t<Mm7BI»»W»Suu zartroM» 23<(61>»»«tl2M»&lMH ZMIBI»M2.»t3fltMH-HWDI
DATEANALYZED
oTWM"«7/;-»/ff1i<»T/<»/<1>
6-»/(7/e6^Ir/ff»1/21/9S^ilzilenailzit»e0-H-itlB*•7 »*•»/»»
TIMEANALYZED
ff7Vfro«sa0^30<a22116b( Z Z W1 9 1 3(IffJ -.,^V^Wfft
i_0t1/«7 Rav.
03Z17761roxM v vox
^,
III VOLAIILES DATA, continued ^b. SAMPLE DATA 0
03Z1W62
XA E?A SAMPLE NO.VOLATILE ORSANICS ANALYSIS OATA SHEE»rt^r>nft
Contract:_
Ca«« Ho.: tiTl»q s SAS No.:
Lab Nan*:b cod»: SOC No.: tou«a(e
Lab Saapl* 10: H H ^33^ p>Matrix: (•oil/wfr) go^i,
Sampr vt/vol: ^ (g/»X.) 6 Lab rilt ID; HH ^33^ n i
Data Racaivds pyfzz.ga/flft
Oaf Analyzad: 07^7^6
Lavl; (low/Bed) M^P
n: (pack/cap) •PflCfc DiluticoHccmuiTic
CAS NO. COMPOUND (ug/L or UO/
74-«7-3——————Chlewthan«
73-00-3————chloro»than«73-0»-2———M«thym< Chlorida67-B4-1———Acetone75-15-0——————Carbon blaulcid*75-35-4—— ————1.1-OlehlorowfchMr7s-34-3———i.x-oicmero<thair540-59-0————l,2-0ichloro«th«n« (total)€7-«-3———Chlore(ei»107-06-2-————1.2-OichloroathaM7«-»3-3———a-Butanon«7 i-55-<———l. l. l-TrldtloroSEEin*5<-23-5—————carbon Tatraeblorlda75-27-4———•roaodiehloro—tnan*7«-«7-5—————1.2-DicBleroBroBaif100»l-0l-5———ci«-l. 3-DiehlereprepMM79-oi-»———Triehlowth«»«124«4«-l—————DlbnMeBlanM«&uM7«-00-S—————l.l.a-mehlara«fchair l.^?ao71-43-2————————••HWM 1.2SBOloo»l-02-<——tr«n«-1.3-BlehlBroeroBW 13500
1 75-as-a—-———BraMofMnB ia-?oa I10«-10-l—————4-Nth»l-a-»it^anoir 1 .laoS9l-7»-<—————2-«WM*01» « .'looia7-r-«--———T«tnchloro«tkur Lasao10»«»»-3—————Telu—— l3»oelo«-»o-7————cnlerob»n«»n«100-41-4—————Ithvlbwn* ' ' ~ 1
100-42-9—————Itvrif , ,, I3""1330-20-7———xvlir iotalk
1 1
on Factor: Jg -
>N OMITSi ftl"tt/
Ite) tf&. /k^ 0
(.qooMoo(.<»ooww3500
140&.-!SOO3SOO. 003y». , ;35<»o3SOO
(loo3SOO-ISOO(ttoo... ...... -3SOO.^soo^y^ ,„ ... „„.?S60
' a«rao
MOO-3SBO
3S»a
^
^
^»
rORM Z VOX l/«7 Rav.
03217763
VOLATILE ORGANICS ANALYSIS DATA SHEETTENTATIVELY IDENTIFIED COMPOUNDS nfl f) fl fl 7
Lab Mama; )T05- /oooxumfr Contract:_______/-re-It
Ca«a t»o.: (. SAS Ho.:Lab Coda: ir^fu
Matrix: (aoil/wafr) soi^
Sarnpl* vt/vol; ^
Lavl: (low/nrd) ^\tp
t Moistur*: not d«c.____
Column: (pack/cap) TOCie.
NuBb«r TICa found: J^S
SOC No.: Uriggof,
Lab S«Bpl« ID; t«n ^a3'7t>s
Lab File ID: HH 233TI>>
Oaf Racaivd: (TT /?.», ?.?/ga
Oaf Analyzed: o^l^-l!9^
Oilution Factor: ig-^-
MTM , .rl»>)T<
COHCINTRATIOH UNITS:(ug/L or uq/Ka) m. /A-^
CJ
123456789
101112131415161718192021222324252627282930
^S NUMBER
110-W. 3-1H (.. 8fe-l
.fSf- •»l 1CTP-3-7.1syfe-ti-i
COKPOUNO NAHE
HCxAUfei.U<Xt»)t,s;^--I>imtTrti/t—UfiVTftMfe , S.HH.-TH^t.-
H6T>rA«6 , Z-MfeTHVL-cycL«r<rr<*»i.ox/^e, ofrA/<*tim.-
BT
eo.ios^n?a.o^•M.<.&31.fc7
BST. COKC.
HoaotSaossoa,-11 oa•OBO
•
rQ 1
^
TOM I VOX-TIC 1/87 Rav.
03217764
0000
08
r ^— i<\ vt CO 0
0321
7765
QUANTITATION REPORT FILE: HHa337Dl
DATA: HH2337D1.TI 000009/-Y27/88 9: 30: 00
IPLE: CLP.41695,MH22l6,MH2216,MED,SOIL,HH2337D1,VOA,EPACONDS.: *IN8TRUMENT-OMA5* EPA CLP METHOD (VOLATILE9)FORMULA: SOIL (1:128) INSTRUMENT: OMA3 WEIGHT: 0.000SUBMITTED BY: ITFK ANALYST: WET ACCT. N O . : 4169SAMOUNT-AREA • REF.AMNT/(REF.AREA)* RESP.FACT))DET.LIM. - 0.00RESP. FAC. FROM LIBRARY ENTRYNO NAME1 CI01 BROMOCHLOROMETHANE <I.S.»l-CLP)2 CI10 1.4-DIFLUOROBENZENE <I.8.»2-CLP) in
t i^CM0
3 C120 CHLOROBEN2ENE-D5(I.S.W3-CLP)4 CS15 1.2-DICHLOROETHANE-D4 < 8 . S . t t l )3 CS03 TOLUENE-DB ( S . S . • 2 )6 CS10 4-BROMOFLUOROBENZENE <S. S. •3)7 C010 CHLOROMETHANE •»8 CO IS BROMOMETHANEf C020 VINYL CHLORIDE *10 C029 CHLOROETHANE11 C030 METHYLENE CHLORIDE12 C03S ACETONE13 C036 ACROLEIN14 C037 ACRYLONITRILE13 C040 CARBON DISULFIDE16 C04S 1.1-DICHLOROETHENE *17 COSO 1.1-DICHLOROETHANE »»1" COS3 TRAN8-1.2-DICHLOROETHENE-/ C060 CHLOROFORM •20 C06S 1,2-DICHLORQETHANE21 C110 2-BUTANONE22 C113 I,1,I-TRICHLOROETHANE23 C120 CARBON TETRACHLORIDE24 C12S VINYL ACETATE29 C130 BROMODICHLOROMETHANE26 C140 1,2-DICHLOROPROPANE «27 C143 CIS-1,3-DICHLOROPROPENE28 C1SO TRICHLOROETHENE29 C19S DIBROMOCHLOROMETHANE30 C160 1.1,2-TRICHLOROETHANE31 C169 BENZENE •32 C172 TRAN8-1.3-DICHLOROPROPENE33 C179 2-CHLOROETHYL VINYL ETHER34 C180 BROMOFORH *«39 C210 2-HEXANONE36 C209 4-METHYL-2-PENTANONE37 C220 TETRACHLOROETHENE38 C229 1,1,2,2-TETRACHLOROETHANE »«39 C230 TOLUENE *40 C239 CHLOROBENZENE41 C240 ETHYL BENZENE *42 C249 8TYRENE/A3 C290 TOTAL XYLENE8' C292 M-XYLENEtS C291 TRICHLOROFLUOROMETHANENO M/E SCAN TIME REF RRT METH AREA(HOHT) AMOUNT XTOT \^^
032V7766
1- -0 -0 -00 1^ h. Ntt-a •» -6
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22228SS822S.82S8-""'•nio^-n.e' TOO-
NO RET(L) RATIO RRT<L) RATIO10 4: 12 0. 410
/—< 6:38 1.02 0. 648 1 .017:32 1.02 0.736 1.02
13 7:48 0. 76214 8: 38 0. 84419 8:28 0.82716 9: 90 0. 96117 11 :06 1.08918 12:02 1 . 1 7 619 12:24 1 .21220 13: 18 1. 30021 13:22 1 . 0 1 0.631 1 .0122 14:30 0. 68923 14: 94 0. 70424 19:22 1.00 0.726 0.9929 19:26 0. 72926 16:96 0. 80027 17 :14 0.81428 17: 92 0. 84429 18 :16 0.86330 18:28 0.87231 18:32 1.00 0.876 1.0032 18:34 0. 87733 19:44 0. 93234 21:00 0.99239 23:24 0. 89436 21:46 1.00 0.832 1.00f 23:40 0. 904
_-< 23:24 1.00 0.894 1.0039 25:12 1.00 0.963 1.0040 26:16 1.00 1.004 1.0041 28: 14 1. 07942 32:02 1.22443 33:10 1.26844 32:20 1.00 1.236 1.0049 8: 98 0. 876
000011
AMNT AMNT<L) R.FAC R . F A C ( L ) RATIO90. 00 0. 674
0.68 90.00 0.020 1.497 0.012.02 90.00 0.098 1.426 0.04
90. 00 0. 26290. 00 0. 69790. 00 3. 04790. 00 1. 14390. 00 2. 83290.00 1.39090. 00 2. 87090. 00 I. 999
2. 73 90. 00 0. 004 0. 080 0. 0990. 00 0. 44690. 00 0. 419 |-~
0.03 90.00 0.001 1.246 0.00 _90. 00 0. 986 ^90. 00 0. 44964. 00 0. 922 ^90.00 0.449 CM90. 00 0. 984 090. 00 0. 399
0.04 90.00 0.001 1.090 0. 0036. 00 0. 44690. 00 0. 24090. 00 0. 98490. 00 0. 942
0. 32 90. 00 0. 007 1. 139 0. 0190. 00 0.449 •
0. 03 90.00 0. 001 0. 782 • 0. 000.07 90.00 0.001 0.733 0.002.01 90.00 0. 038 0.944 0. 04
90. 00 0. 49090. 00 0. 88690. 00 0. 910
0.02 90.00 0.000 0.911 0.0090. 00 1. 249
' \at
oazrriSss
000012
IT ANALYTICAL SERVICESQA/OC REPORT
' L E : HH2337D1
INTERNAL STANDARD AREA CHECK
3 OUT OF 3 ARE WITHIN SOX TO 200X OF DAILY STANDARD AREAS.»• INTERNAL STANDARD AREAS ARE WITHIN QC LIMITS »•
INTERNAL STANDARD RETENTION TIME CHECK03
3 OUT OF 3 ARE WITHIN +/- 30 SECONDS OF DAILY STANDARD RETENTION TIME r^•=a-<M0
** INTERNAL STANDARD RETENTION TIMES ARE WITHIN QC LIMITS *•
0000137/27/88 9:30:30 SCAN I OF 1020
ACQUISITION STARTED/-\' IUIRE RUN 0:HH2337D1 ACQUIRING0//27/88 9:30:00 + 0:04 FREE SECTORS:17709 SCAN: 2 OF 1020SAMPLE: CLP,41693,MH2216.MH2216,MED,SOIL.HH2337D1.VOA.EPACONDS.: »INSTRUMENT-OMA3» EPA CLP METHOD (VOLATILES)FORMULA: SOIL (1:125) INSTRUMENT: OMAS MEIOHT: 0.000SUBMITTED BY: ITFK ANALYST: MET ACCT. N O . : 41699LOW MASS:HI8H MASS:
3S300
UP:DOWN:
1.93 L»0.00 L
TOP:BOTTOM:
0. 000. OS
CENT S/P: 37 ACTUAL: 37FRAQ S/P: 20 ACTUAL: 19MIN PEAK WIDTH: 1A/0 THRESHOLD: 1MODE: CENTRQID POSITIVE ION
SAMP INT (MS): 0.200SAMP INT (MS): 0.400
PEAK WIDTH:INTEN/ION:
1000.2
MIN FRAO MIDTH X:BASELINE: 0
30 MIN AREA: S3
INTERFACE NUMBER 0SUB-INTERFACE NUMBER 0tt OF ACQU BUFFERS 16INSTRUMENT TYPE QFULL SCALE MASS 800 AMUZERO SCALE MASS 1 AMUINTENSITY/ION 2PEAK WIDTH 1000. MMUOFFSET AT LOW MASS 0 MMUOFFSET AT HIBH MASS 0 MMUVOLTAGE SETTLING TIME(MS) 4
M.S. TUNE PARAMETERS:MULTIPLIER VOLTS: -20S2.33LOW RESOLUTION: 127.00HIOH RESOLUTION: 126. 00ION ENERGY: 3. 53ION PROGRAM: 3. 96LENS VOLTAGE: -29.SOEXTRACTOR: 0. 94ELECTROMETER RANGE: 7.00ELECTROMETER ZERO: 2'. 74
ACQUISITION STARTED WITH GC FILE 1GC PARAMETERS:230 DEC30 DEC230 DEC4 MIN
8.0 D/M60 MIN230 DEC90 DEC
INJ. MODE:sec "
ZONE TEMP.INITIAL TEMP.FINAL TEMP.INITIAL TIMERAMP RATEFINAL TIMESEP. SET PT.MANIF. SET PT.PKODV OPN
7/27/S8 10:04:33ACQUISITION COMPLETEDSCANS 1 TO 1020 CENTROID
'TROIDSCANS
1020SECS OUT OF X
241.3 2040.0 1 1 . SPEAKS PER SCAN14703. 14.
PER SEC7.
IT ANALYTICAL SERVICES DIAGNOSTIC REPORT 7/37/88 10:03:10DATA FILE;HHa337DlREFERENCE: LIBRARYVE
METHOD: V08T INITIALIZATION OPTION: 2 PROCES8INO OPTION: 4 />/>/,„., „REPORT: CLPI9SB UUUU14
< -—— STANDARDS ———— X —— PLUS UNKNOWNS —— X - LIST NAMES - >PROC USED POS8 RUB PROC USED P089 RMS STANDARO/UNKNOUN
6 6 1 34 49 6 1 94 CLPISS8/CLPUNK8
49 COMPOUNDS PROCESSED. 6 FOUND
< COMPOUND X ————————— SEARCH ——————————— X SAT > < ————— CHRO ——————NO LIB ENTRY REF PRED BEL DELTA PEAKS FIT PEAKS H/Z TOP DELTA PEAKS
1 VE 1 -306 309 309 . I 999 . lad 309 , 1VE 8 -632 636 636 . 1 997 . 1 1 4 636 . 1VE 3 -7S1 789 789 . 1 980 . 1 1 7 7S9 . 1VE 4 -394 397 397 . 1 978 . 69 398 1 1V6 9 -746 790 791 1 1 984 . 98 791 . IVE 6 -911 916 919 -1 1 944 . 99 919 . 1VE 7 -48 80 . . . . . 90 . . .VE B -76 78 . . . . . 94 . . .VE 9 -97 100 . . . . . 62 . . .
10 VE 10 -12S 131 . . . . . 64 . . .1 1 VE 11 -200 503 . . . . . 84 202 . 112 VE 12 -226 229 . . . . . 43 331 . 113 VE 13 -233 239 . . . . . M . . .14 VE 14 -299 298 . . . . . 33 . . .19 VE 19 -293 296 . . . . . 76 . . .
V6 16 -293 396 . . . . . 96 . . ., VE t7 -332 339 . . . . . 63 . • .
18 VE 18 -398 361 . . . . . 96 . . .19 VE 19 -371 374 . . . . . 83 . . .20 VE 20 -396 399 . . . . . 63 . . .21 VE 21 -398 401 . . . . . 73 404 . 123 VE 32 -433 436 . . . . . 97 . . .23 VE 23 -449 448 . . . . . 1 1 7 .24 VE 24 -498 461 . . . . . 43 499 . 139 VE 39 -461 464 . . . . . S3 . . .36 VE 36 -906 910 . . . . . 63 . . .37 VE 37 -914 918 . . . . . 79 ' .28 VE 28 -933 937 . . . . . 13039 VE 39 -946 990 . . . . . 12930 VE 30 -9M 936 . . . . . 97 . . .31 VE 31 -393 B96 . . . . . 78 997 . 132 VE 33 -934 998 . . . . . 79 . . .33 VE 33 -989 993 . . . . . 63 . . .34 VE 34 -638 633 . . . . . 173 . . .39 VE 39 -699 703 . . . . . 43 . . .36 VE 36 -690 694 . . . . . 43 699 . 137 VE 37 -708 713 . . . . . 164 . . .38 VE 38 -701 709 . . . . . 83 703 . 239 VE 39 -793 796 . . . . . 93 797 . 340 VE 40 -789 789 . . . . . 112 789 . 1•I VE 41 -843 847 . . . . . 106 . . .
VE 43 -999 960 . . . . . 104 . . .^J VE 43 -989 994 . . . . . 106 . . .44 VE 44 -969 970 . . . . . 106 967 . 149 VE 46 -269 272 . . . . . 103 . . ^ .
03Z1W71
I. T. ANALYTICAL SERVICESLIBRARY SEARCH REPORT
VOLATILE ORGANIC ANALYSIS./""^TA FILE: HH2337DI
<LIBRAT20N FILE: CAL040788SEARCH OF LIBRARYVE
000015
SCAN COMPOUND DELTA
309 CI01 BROMOCKLOROMETHANE <I.B.#1-CLP) 0636 CI10 I,4-OIFLUOROBENZENE (1.8.W2-CLP»78S CI20 CHLOROBENZENE-D3(I.S.#3-CLP)398 C81S 1.2-DICMLOROETHANE-D4 (S.S.ttD731 CS09 TOLUENE-OS (S. S.tt2>91S CS10 4-BROHOFLUOROBENZENE (8.8.»3)231 C039 ACETONE404 CI10 2-BUTANONE789 C239 CHLOROBENZENE
PUR-FIT <AHT FLA08NO > SAT LIB
982-998 SO0 917-998943-98S SO943-983 42927-989 49833-910 49907-907 27B3-781 3496-623 2
0SO000000 -2'''o -a"^
(M0
03217772
DATA: HMS337D1 0231C033 ACETONE/-'WANCED SPECTRUM MATCH
RELATIVE INTENSITY <X)MASS LIBRARY SAMPLE43 100 10038 16 16
000016
0321W73
£2 £17 20I.T. ANALYTICAL SERVICES TRIPLE MASS SPECTRUM DATAi HH233701 »23107/27/88 3:30:06 + 7:42 CALIi CAL940788 •13SAMPLE! CLP,4169S,MH2216,tW2216.MED,SOIL,HH2337Dl-UOA,EPACONDS.i XINSTRUMENT-OUASt EPiA CLP METHOO (UOLATILES)ENHANCED SPECTRUM (S 15G IN OT)
RAM SPECTRUM
C835 ACETONE
BASE M/Ei 43/- 44RIC: 191./ 1131.
35 48 45 59 35 c
DATA: HH2337D1 •404C110 2-BUTANONEENHANCED SPECTRUM MATCH
RELATIVE INTENSITY (X)MASS LIBRARY SAMPLE33 26 0 PEAK NOT IN SAMPLE37 14 0 PEAK NOT IN SAMPLE43 100 10072 16 IS
RAM SPECTRUM MATCHRELATIVE INTENSITY ( X )
MASS LIBRARY SAMPLE35 26 1637 14 743 100 10073 16 14
S Z £ 17 Z O
I.T. ANALYTICAL SERVICES TRIPLE MASS SPECTRUM DATA: HH233701 •40407/27/88 9138(00 + 13l28 CALIf 00.040788 113SAMPLE] CLP,41695-MH2216,MH22ie/MED-SOIL,HH2337Dl,UOA,EPACONDS.i tIHSTRUMEHT-ONASX EPA CLP METHOD <UOLATILES>ENHANCED SPECTRUM <S 15B IN 0T)
BASEM/Es 43 /63RICi 938./ 4311.
_L_i
RAM SPECTRUM
41Cllfl 2-BUTftHOHE
i ' | ' 1 ' 1 ' 1 ' 1 ' |48 58 68 f 78 88 98 188 f
DATA: MM2337D1 »7STC233 CHLOROBENZENE/"""(ilHANCED SPECTRUM MATCH
RELATIVE INTENSITY (X)MASS LIBRARY SAMPLE38 15 71 OUT OF 20X RANGE30 24 37 OUT OF 20X RANGE31 24 2977 63 0 PEAK NOT IN SAMPLE112 100 100114 34 38
000020
RAM SPECTRUM MATCHRELATIVE INTENSITY (X)
MASS LIBRARY SAMPLE38 IS 70 OUT OF 20X RANGE30 24 39 OUT OF 20X RANGE31 24 2977 63 49112 100 100114 34 26
03217777
0 I.T. ANALYTIC0 87/27/88 9i;0 SAMPLES CLP^0 CONDS.s UHS1
6.1-
3.9-
ie9.9-
59.9-
C6.H5.
•
ENHANCED SPEC
J 11 i i y i i i i ' i i i i i i i iRAM SPECTRUM
,1.1f ' "( ' 1 ' 1 ' 1 ' 1 ' I ' 1
0. C235 CHLOROeBCENE
^
J Ltl Lt- ^.. . ..
L^ i
•M. SERUICES TRIPLE MASS SPECTRUH OATAi HH2337D1 «789 BASE H/Ei 112/ 117 1s
30:08 + 26:18 CALI; CfiSWTBQ «13 RICs 13e9. / 23235. 5tl695,MH2216,MH2216<MED,SOIL-ttl2337Dl,UOA-EPA NrRUMENT-OMASt EPA CLP METHOO (UOLATILES) §
:TRUM (S 15B
1 i ' | ' l
IN9T)
i 1 i 1 i 1 i | i 1 i 1 i 1 i 1 i | i 1 i 1 i 1 i 1 i | i 1 i 1 i 1
i ' i ' l ' l ' i ' l ' l ' l ' | ' l ' l ' l ' l ' | ' l ' l ' i
1 i 1 i 1 i | i 1 i I i I i I i | i 1 i 1 i 1 i I i | i I i I i I
1
r 354.
r 5816.
M/E 58 199 209 256
000022FILE HH2337D1 PEAK HEIGHTS AND COMPUTED AMOUNTS BY SCAN NUMBER:
' N LIMIT SET AT 9.0 UNITSUaE ALL PEAKS FOR LIBRARY SEARCH
^309636789603819845898
29309.049733. 092160.09220.26768.97907.9
10678.9
90. 090. 090.0
9. 76. 97. 2
10. 2
> •-
1^ ---'=^•^
^ ^ '
^10 -- 4000<lo » </<i>o<?ao » gooo1?00 = '710°
LIBRARY SEARCH DATA: HH2337D1 « 603 BASE M/Es 43 ft(97/27/88 3:3e:ee + 20106 CftLIl CAL840788 » 13 RICf 5231. F-SMPLEi CLP-41695-W2216,MH2216/MED,SOIL,HH233701-UO|i>-EPA nCOOS.! »INSTRUMEHT-OMft5» EPA CLP METHOO <UOLATILES> itENHANCED <S 158 IN BT) ... §
VEWHE CAS • 119-B4-3
CAS t 5618-62-2
CAS » 4161-24-4
60 c iee 129 140
c
0 £ £ 1 7 3 0
LIBRARY SBKCH DATA) HH233701 » 815 BASE H/Ei 4307/27/08 9:38:08 + 27(10 CALIi CALWe788 • 13 RICi 3359.SWLEi CLP,41695.W2216,m2216,MED,SOIL-HH233701,iX»,EPACONOS.i tINSTRUENT-OUASt EPA CLP METHOD (VOLATILES)ENHftNCED <S 13B IN 8T)
CftS « 7116-86-1
-M——r^1-HEXBC, 2, S,S-TRI»OTffL- CAS« 62185-56-2
CftS « 3874-77-9
"i •100
-,—|—.
159c 208 258
C
LIBRARY SEARCH DATA) HH233701 • 842 BASE H/El 4307/27/88 9f38l88 + 28104 CflLIs ?.948788 • 13 RICl 5719.SlWl-E; CLP,41695/tW22ie,MH2216,MED,SOIUHH233701,UOA,EPACOBS.: XIHSTRUMEHT-OUMtt EPA CLP METHOD (UOLATILES)ENHANCED <S 15B IN 8T)
ISo
HEPTANE,3-HETHYL- CAS » 589-81-1
CAS» 583-48-2
BUTANE, 2.2,3-TRIMETWL- CAS » 464-86-2
58 188'—i—'158 288 258c
Z £ £ 1 7 3 0
LIBRARY SEARCH DATA! HH2337D1 • 858 BASE M/Ei 4397/27/88 9:38190 + 28:36 CALI: CAL948788 t 13 RIC: 9935.SAMPLE: a-P,4l695,MH2216,MH2216,MED-SOIL,HH233701,Wt,EPACOWS.; «NSTRUHEHT-OMA5t EPA CLP METHOD <UOLATILES)ENHANCED (S 15B IN OT)
sCAS • 392-27-8
CAS t 392-13-2
HEXANE, 3-ETHYL-4-METHYL- CAS • 3074-77-9
190 139• l •299 239c c
^ £ £ £ fr 2 0 'l SCM00 LIBRARY SEARCH0 07/27/88 9:30:60 + 32:40
- ° SAMPLE; CLP-41695,HH2216-MH221S-MED,SOIL,HH2337D1/UOA-EPA "•'CONOS.; itINSTRUflENT-OWWX EPA CLP METHOD <WLATILE5)
1053 i ' ' , -SWLE
1.1, 1
C8.H24.04.SI4 CYCLOTETRASILOXANE-OCTAMETHYL- CAS # 55€M MT1!^ '3 PK 281RANK 1IN 21804PUR 774 •
C19.H38.05.SI4 BENZOICACID/3,4-5-TRIS<TRIMETHYLSILOXY)-,TRIMETHYLSILYLESTER CAS # 2078-17-31053 i
M WT 459B PK 281RANK 2IN 28995PUR 594 •
C17.H14.04 ISOFLAVONE-5/7-DI11ETHOW- CAS # 24195-17-3,'• NT1^ 13 PK 282RANK 3IN 206S7PUR 482 •
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iDATA; HH2337D1 « 988 EASE M/E; 281 aCALI: CAL040788 » 13 RIC; 9615. S
, . ; - , , . 1 , . , , , , , . t . . , t l . , , IL , , , , , , , , , , , , . , , , , , . , , , , . , , , , , , ,
1
li 1. ki t.
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203 259 383 358 493
C C
c^o^y^)^0
.-•'• i • 1 1 . . , . , . • , . , ' . , . , . J . . . i . , . , . , . . . , . , . , . , . , . i . . . , . , . ,1 . 1 i .
i . i i . , ' . • 1 . 1 ' , i , , i . . , , , . , . , . , , . , . . . , — , . , , , , , . ,
i
S-67-2
^
453
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'
VOIATILE ORGANS ANALYSIS DATA SHg^00028 E?A SAMPL£ N0 •
Lab Naa«:,
Lab Code:
Contract:
Car NO.: 'i^s SAS No.: SDC No.: uuggato
Matrix: («oil/vfr)_^fiJ_
Saapr vt/vol: ^ (g/»L) 6_
L»vl: (low/rd) M^P
» Moi«tur«: not d«c. 8(yColuBn: (pack/cap) 'pflcin
Lab SaBpX* ID:
Lab ril« 10:
Oaf Rec«iv«d: o7lz?.g3/fl>
Oaf Analyxad: a^l^i^afi
Dilution raetor: l-^s-
CAS NO. COMPOUNDCONCXMTXATION UNITS:(u»/L or uq/Kq) u&. /ks
74-B7-374-«3-S75-01-75-00-75-09-<7-<4-7S-IS-75-35-75-34-S40-59<7-<»-io7-oe7B-93-71-55-5<-23-XOI-0575-37-7«-t7-100C1-C79-0l-<124-41"79-00-i71-43-S100«1-<75-25-310«-l0-591-7B-ia7-r-7»-34-iloa-r'10«-90<100-41-100-42-1330-aC
———vinyl Chloride——————M«thyl«n« Qilorida—————*e«ten«———Carbon bilulzida———I. l-Diehlore««am*—————l,1-Dichloroethana0————l,a-Dichlowth«B<i (tofl)————Chlerotor»
—————l.l.l-Trlehlewthan*————carbon Tatraehlorid*4————vinyl Ac*ff
—————l.a-DichloreDrepMrn-5———er-l. 3-DicaloroproDir
•l-————oi6ra—eBlora—taur1——.——l,1.2*Triahloro^h*n«
»3-«———trifl, 3-Dlehloropropm*t——————•NMfoa-l—————4-Mthyl-2->ttn^aAoa«••———3-RmaneiM•4————T«eraeuero«tE«Mi————— i.i.a. 2'TacraebloNtlMM
•7————a»loreb«»»«».5————»tvr«>«1-7————xvl«ir ^oiali
8<100OTOO8^ad*<»06' 00OTOOys-ooUSdB43304SBOt<500ysoo
Z3C,0veaoH5t>6fAooISaoveeotnaoaSss—————ISao«?-»HScoWoo•<5topqoopwo'/SooV5»fsao
SSAO^2S———————uSoawa» u
TOM Z VOX 1/»7 R«v.
0321W8S
IEVOLATILE ORGANICS ANALYSIS DATA SHEEBlnnnQQ
TENTATIVELY IDENTIFIED COMPOUNDS VUUU&a,
Lab uana; )TO$- K^c>/.uii.L6/TFI<
/--\Lab Coda: ir£~i\) Car No.: ««(. '
Matrix: (aoil/watar) salt-
Sampla vt/vol: 1 (g/aL) G
Lavl: (low/nad) M.tp
t Moi»tur«; not dec.____
Column: (pack/cap) TV^X.
SDG Mo.: Linear
Contract;.SXS H o . :
Lab Saapl* ID:Lab Fila ID:
HH 334001
^ri gg'<a&.
Data Racaivd: silty^xlv^
Data Analyzad: _o-7fz7^8t
Dilution Factor:
COWCHtTRATIOM UHlTS:(ug/L or ug/Ka) ue. lk&Nuohrr TIC« found:
CAS NUMBER
1234S6789
101112131415!«1718192021222324252627282930
1 1 0 - ^ - 3ITHZ--11--7,fM-@.'-»-sqa- z-7-tf
COMPOUND NAME
H<XAM6^rxLc.ftAit, .e.r.M^rn^L-wyro^ -?-rt^T^t--W£W^A, l--^Ttf4L-
1
RT
?o.o-iZ7.13?«.o3?9.S7
BST. COMC.
5y<'x>vtao
-. --, fiJo^7oao
,
Q
-3
FORM X VOA-TIC 1/87 Rav.
0000
30
\o y^ tr\
•^ (M 0
3UANTITATION REPORT FILE: HH2340D1 000031
DATA: HH2340D1.TIP-y27/88 12:24:00
' iPLE: CLP.41693.MH2216.MH2217.MED.SOIL,HH2340D1, VOA.EPACONDS.: •IN8TRUMENT-OWA3* EPA CLP METHOD (VOLATILE8)FORMULA: SOIL (1:129) INSTRUMENT: OWAS HEIGHT: 0.000SUBMITTED BY: ITFH ANALYST: WET ACCT. NO. : 41699AMOUNT-AREA • REF.AMNT/<REF.AREA)* RESP.FACT))DET.LIM.- 0.00RESP. FAC. FROM LIBRARY ENTRYNO NAME1 CI01 BROMOCHLOROMETHANE (I.S.«1-CLP)2 C 110 1,4-DIFLUOROBENZENE (I.S.»2-CLP)3 CI20 CHLOROBENZENE-DSd.S.•3-CLP)4 CS19 1.2-DICHLOROETHANE-D4 (S.S.ttD5 CSOS TOLUENE-D8 (S. S. tt2)6 CS10 4-BROMOFLUOROBENZENE (S. S. tt3)7 CO 10 CHLOROMETHANE »•8 CO 15 BROMOMETHANE9 C020 VINYL CHLORIDE •10 C023 CHLOROETHANEIt C030 METHYLENE CHLORIDE12 COOS ACETONE13 C036 ACROLEIN14 C037 ACRYLONITRILE15 C040 CARBON DISULFIDE16 C049 1.l-DICHLOROETHENE •17 C090 1.1-DICHLOROETHANE »«
^>, C093 TRAN8-1,2-DICHLOROETHENE/ C060 CHLOROFORM »
20 C065 1,2-DICHLOROETHANE21 C110 2-BUTANONE22 C119 1,1.1-TRICHLOROETHANE23 C120 CARBON TETRACHLORIDE24 C129 VINYL ACETATE25 C130 BROMODICHLOROMETHANE26 C140 1,2-DICHLOROPROPANE •27 C143 CIS-1,3-DICHLOROPROPENE28 C130 TRICHLOROETHENE29 C199 DIBROMOCHLOROMETHANE30 CI&0 1.I,2-TRICHLOROETHANE31 C163 BENZENE32 C172 TRANS-1,3-DICHLOROPROPENE33 C179 2-CHLOROETHYL VINYL ETHER34 C1SO BROMOFORM •*39 C210 Z-HEXANONE36 C203 4-METHYL-2-PENTANONE37 CaaO TETRACHLOROeTHENE38 C229 1 . 1 , 2 < 2-TETRACHLOROETHANE —39 C230 TOLUENE *40 C235 CHLOROBENZENE41 C240 ETHYL BENZENE *42 C24S STYRENEJ^ C2SO TOTAL XYLENES
f C252 M-XYLENE^S CaSI TRICHLOROFLUOROMETHANENO M/E SCAN TIME REF RRT METH AREA(HCHT) AMOUNT XTOT U<1^
03S177SS
000032NO H/E SCAN
1S34367a9
10111213141316171819203122 97 2S3Z42326a?
1.^
30313233343S363738394041424344 10643
N0123436
a9
128114117639B9330946264B443S<337*96 163 196 183 162 172
117 2438363 273 2
130 a129 297 •»7B79 263 2
173 a43 3 ^—-43
164 38392
112106 3104 3 „ . A A106 3 <?^VW'
103 1
RET(L> RATIO R R T < L )10212613S330
1a3
6
141010120028343010
307633783396730914
199231
237
403
461
337
636
736788
969
1.00 1.0001.00 1.0001.00 1.0001.00 1.2901.00 0. 9331. 00 1. 164
TIME RE10:14 1 1.00021:10 3 1.00026: 10 313:12 1 1. 29023:00 3 0. 93330:28 3 1. 164
6:387:42 0.732
8:34
13:26 2 0.639
13: 22 2 0. 7262
18:34 2 0.877
Z1: 32 3 0. 836
323:12 3 0.96326:16 3 1.004
32:18 3 1.234
0. 1330. 2440.309
y RRT
3 1.000
0. 648
0.837
RATIO1. 001.001.001.001.001.00
HETHA BBA BVA BBA BBA BBA BB
A BBA W
A BB
A BB
A*BB
A BB
A BB
A BBA BB
A BB
AHNTSO. 0030.0030.004B.9948. 4fl47.89
AKEAtHOHT) AMOUNT23442.
113837.108310.33281.67934.73982.
666.1300.
28.
473.
177.
333.
363.
242.7933.
90.
AflNT(L)30.0090.0030.0090.0030.0030.0090.0030.0090.00
90. 000 UC/L30. 000 UO/L90. 000 UO/L43. 946 UO/L48.480 UO/L47.887 UB/L
- .»''
0.973 UO/L1.944 UO/L
0.030 UO/L
2.627 UO/L
0.063 UO/L
0.223 UO/L
0.228 UO/L
0.132 UO/L3.881 UO/L
0. 081 UO/L
R.FAC R.FAC(L)1.000 1.0001.000 1.0001.000 1.0001.420 1.3490. 624 0. 6430. 683 0. 713
1.0400.8640. 940
XTOT16.9316. 3316. 3313. 1916. 0319.83
(y^)A-wr-P- -
^-vr
"Z.3*0
1 8. 87 s 330.
^a
/WOT'
-<rb8
••"oS' asa"1 1. 28 '- •4<0-
,pf0
RATIO1.001.001.000.92^0.97i^0.96>^'
^
03Z17789
000033NO RET<L) RATIO RRT(L) RATIO10 4: 12 0. 410•4 6:38 1.00 0.648 1.00
' 7:32 1.02 0. 736 1. 0213 7:48 0. 76214 8: 38 0. 84415 8:28 1 . 0 1 0.827 1 .0116 9: 90 0. 96117 11:06 1.08318 12:02 1.17619 12:24 1.21220 13:18 1.30021 13:22 1.00 0.631 1.0022 14:30 0.68S23 14:S4 0. 70424 15:22 1.00 0.726 1.0025 19:26 0.72926 16: 96 0. 80027 17:14 0. 81428 17: 92 0. 84429 18:16 0. 86330 18:28 0.87231 18:32 1. 00 0.876 1. 0032 18:34 0. 87733 19:44 0. 93234 21:00 0.99239 23: 24 0. 89436 21:46 1.00 0.832 1.00
<^ 23: 40 0. 904-, 23:24 0. 894
39 29:12 1.00 0.963 1.0040 26:16 1.00 1.004 1.0041 28:14 1.07942 32:02 1.22443 33:10 1. 26844 32:20 1.00 1.236 1.0049 8: 98 0. 876
AMNT AMNT(L) R.FAC R.FAC(L) RATIO90. 00 0. 674
0.97 90.00 0.028 1.497 0.021.94 90.00 0.099 1.426 0.04
90. 00 0. 26290. 00 0. 697
0.02 90.00 0.001 3.047 0. 0090.00 1. 14390. 00 2. 83290.00 1.39090. 00 2. 87090.00 1.999
2.63 90.00 0.004 0. 080 0. 0990. 00 0. 446 0^90.00 0.419 ^
0.06 90.00 0.002 1.246 0.0090. 00 0. 98690. 00 0. 44964.00 0. 922 (^1
90.00 0.449 090. 00 0. 98490. 00 0. 399
0. 22 90.00 0. 009 1. 090 0. 0036. 00 0. 44690. 00 0. 24090. 00 0. 98490. 00 0. 942
0. 23 30.00 0. 009 1. 139 0. 0090. 00 0. 449 .90. 00 0. 782 •
0. 19 90. 00 0.002 0.733 0. 003.88 90.00 0. 073 0.944 0. 08
90. 00 0. 49090. 00 0. 88690. 00 0. 910
0.08 90.00 0.001 0.911 0.0090.00 1.249
'-03217790
000034
IT ANALYTICAL SERVICES^ QA/QC REPORT
' ;LE: HH2340DI
INTERNAL STANDARD AREA CHECK
3 OUT OF 3 ARE WITHIN 907. TO 200X OF DAILY STANDARD AREAS.
»* INTERNAL STANDARD AREAS ARE WITHIN QC LIMITS **
0• 1-y~\
3 OUT OF 3 ARE WITHIN +/- 30 SECONDS OF DAILY STANDARD RETENTION TIME •= -
INTERNAL STANDARD RETENTION TIME CHECK
•* INTERNAL STANDARD RETENTION TIMES ARE WITHIN QC LIMITS »» CM0
03Z1W91
0000357/27/88 12:29:09 SCAN I OF 1020
ACQUISITION STARTED
UIRE RUN 0:HH2340D1 ACQUIRING0//27/88 12:24:00 + 0:04 FREE SECTORS:17109 SCAN: 2 OF 1020SAMPLE: CLP.41699,UH2216.WH2217,MED,SOIL,HH2340D1< VOA,EPACONDS.: •IN8TRUMENT-OWA9* EPA CLP METHOD (VOLATILES)FORMULA: SOIL (1:129) INSTRUMENT: OUA9 UEIOHT: 0.000SUBMITTED BY: ITFK ANALYST: MET ACCT. NO.: 41699
LOW MASS: 39 UP: 1.99 L» TOP: 0.00HIGH MASS: 300 DOWN: 0.00 L BOTTOM: 0.09
CENT S/P: 37 ACTUAL: 37 SAMP INT <MS>: 0.200 PEAK WIDTH: 1000. '~FRAO S/P: 20 ACTUAL: 19 SAMP INT (MS): 0.400 INTEN/ION: 2 '?t
mMIN PEAK WIDTH: 1 MIN FRAO WIDTH X: 90 MIN AREA: 29 ^A/D THRESHOLD: 1 BASELINE: 0MODE: CENTROID POSITIVE ION
M . S . TUNE PARAMETERS:INTERFACE NUMBER 0 MULTIPLIER VOLTS: -2082. 39SUB-INTERFACE NUMBER 0 LOW RESOLUTION: 127.00• OF ACQU BUFFERS 16 HIGH RESOLUTION: 126. 00INSTRUMENT TYPE Q ION ENEROY: 3.93FULL SCALE MASS 800 AMU ION PROGRAM: 5.96ZERO SCALE MASS 1 AMU LENS VOLTAGE: -29. BOINTENSITY/ION 2 EXTRACTOR: 0.94
^"\ PEAK WIDTH 1000. MMU ELECTROMETER RANGE: 7.00OFFSET AT LOW MASS 0 MMU ELECTROMETER ZERO: 2-. 74OFFSET AT HIGH MASS 0 MMUVOLTAGE SETTLING TIME(MS) 4
ACQUISITION STARTED WITH GC FILE 1GC PARAMETERS:
CM0
290 DEC90 DEC230 DEC4 MIN
8.0 D/M60 MIN290 DEC90 DEO
ZONE TEMP.INITIAL TEMP.FINAL TEMP.INITIAL TIMERAMP RATEFINAL TIMESEP. SET PT.MANIF. SET PT.
INJ. MODE: PKD1 SEC - 0V OPN
7/27/88 12:98:51ACQUISITION COMPLETEDSCANS 1 TO 1020 CENTROIO
MODE SCANS SEC8 OUT OF X PEAKS PER SCAN PER SECf I T R O I D 1020 292.0 2040.0 12.4 20703. 20. 10.
03217792
000036 .,IT ANALYTICAL SERVICES 01AON08TIC REPORT 7/27/88 13:39:84DATA FILE:HH2340D1 ^REFERENCE: LIMARYVE , \
METHOD: VOST INITIALIZATION OPTION: 5 PROCESSING OPTION: 4REPORT: CLPISSa •sd-
< ——- STANDARDS -——— >< —— PLUS UNKNOWNS —— >< - LIST NAMES - > c\!
PROC USED poss RUB PROC USED poss ana STANDARD/UNKNOWN 06 6 2 76 43 6 t 76 CLPI888/CLPUNKB
43 COMPOUNDS PROCESSED. 6 FOUND
< COMPOUND X ——————————- SEARCH ——————————— >< SAT > < ———— CHRO —————— ;NO LIB ENTRY REF PRED SEL DELTA PEAKS FIT PEAKS M/Z TOP DELTA PEAKS
1 VE 1 -306 308 30a . 2 T»6 . 12S 307 -1 12 VE 2 -632 633 636 1 993 . 114 633 -1 13 VE 3 -7S1 783 7S3 . 984 . 117 7SS . 14 VE 4 -394 396 396 . 985 . 63 396 . 13 VE 3 -746 730 730 . 999 . 9B 730 . 16 VE 6 - 9 1 1 913 914 -1 933 . 93 9*4 . 17 VE 7 -48 49 . . . . . 30 . . . '8 VE 8 -76 78 . . . . . 94 . . .9 V6 9 -97 99 . . . . . 62 . . .
10 VE 10 -128 130 . . . . . 64 . . .11 VE 11 -300 202 . . . . . 84 199 . 112 VE 12 -226 228 . . . . . 43 231 . 113 VE 13 -232 234 . . . . . 36 . . .14 VE 14 -233 237 . . . . . 33 . . .13 VE 13 -233 233 . . . . . 76 237 . 1
-' VE 16 -293 293 . . . . . 96 . . .VE 17 -332 334 . . . . . 63 . . .
18 VE 18 -338 360 . . . . . 96 . . .19 VE 19 -371 373 . . . . . 83 . . .20 VE 20 -396 398 . . . . . 62 . . .21 V6 21 -398 400 . . . . . 72 403 . I22 VE 22 -433 436 . . . . . 97 . . .23 VE 23 -443 448 . . . . . 11724 VE 24 -438 461 . . . . . 43 461 . 223 VE 23 -461 464 . . . . . 83 . . .26 VE 26 -306 309 . . . . . 63 . . .27 VE 27 -914 917 . . . . . 79 . . .28 VE 28 -333 936 . . . . . 13029 VE 29 -946 949 . . . . . 129 . . .30 VE 30 -992 333 . . . . . 97 . . .31 VE 31 -392 933 . . . . . 78 337 . 132 VE 32 -394 997 . . . . . 79 . . .33 VE 33 -989 992 . . . . . 63 . . .34 VE 34 -628 631 . . . . . 17339 VE 39 -699 702 . . . . . 43 . . . '36 VE 36 -690 693 . . . . . 43 696 . 137 VE 37 -708 711 . . . . . 16438 VE 38 -701 704 . . . . . 83 . . .39 VE 39 -792 736 . . . . . 92 796 . 140 VE 40 -789 789 . . . . . 1 1 2 788 . 141 VE 41 -843 847 . . . . . 106
' VE 42 -993 939 . . . . . 104.J VE 43 -989 993 . . . . . 106 . . .44 VE 44 -963 969 . . . . . 106 969 . 143 VE 46 -269 271 . . . . . 103
I . T . ANALYTICAL SERVICESLIBRARY SEARCH REPORT
VOLATILE ORGANIC ANALYSIS-^ATA FILE: HHZ340DI
iLIBRATION FILE: CAL0407BBSEARCH OF LIBRARYVE
000037
SCAN COMPOUND307 CI01 BROMOCHLOROMETHANE (I.S.»l-CLP»635 CX10 1.4-DIFLUOROBENZENE (I.S.#2-CLP)78S CI20 CHLOROBENZENE-DSd.S.•3-CLP)396 CS15 1,2-DICHLOROETHANE-D4 < S . S . # 1 )730 CSOS TOLUENE-DB (S. S . « 2 )914 CS10 4-BROHOFLUOROBENZENE (S.S. tt3)231 C033 ACETONE403 C110 a-BUTANONE788 C239 CHLOROBENZENE
DELTA
-10 912-998
000
-133
-1
PUR-FIT
971-993
932-981949-986929-989770-839638-743678-709633-804
/<
wrN0 >
30
90464848-a—34
FL<SAT
0900000000
\Q8LIB
00000
-3m-1^
%040
DATA: HH2340D1 •231C035 ACETONE.ENHANCED SPECTRUM MATCH
RELATIVE INTENSITY (X)MASS LIBRARY SAMPLE43 100 100SB 16 0 PEAK NOT IN SAMPLE
RAW SPECTRUM MATCHRELATIVE INTENSITY < X >
MASS LIBRARY SAMPLE43 100 10038 16 0 PEAK NOT IN SAMPLE
000038
S 17 £ 17 30
I.T. ANALYTICAL SERVICES TRIPLE MASS SPECTRUM OATAt HH234fl01 »23107/27/88 12:24:90 + 7i42 CALI; CAL048788 »13SAMPLE! CLP,41635,MH2216,MH2217,MED,SOIL,HH234801,WA-EPACOOS.: XINSTRUMENT-OMAS* EPA CLP METHOO (UOLATILES)ENHANCED SPECTRUM <S 15B IN 9T)
BASEH^l 43/RICl 136./
21.4-1
19.7-
RAM SPECTRUM
50.8
C3.H6.0 €935 ACETONE
35 49 45 59 55
DATA: HH2340D1 »403C110 2-BUTANONE/ lHANCED SPECTRUM MATCH
RELATIVE INTENSITY <X)MASS LIBRARY SAMPLE39 26 0 PEAK NOT IN SAMPLE37 14 0 PEAK NOT IN SAMPLE43 100 10072 16 12
RAW SPECTRUM MATCHRELATIVE INTENSITY (%)^
MASS LIBRARY SAMPLE39 26 1637 14 743 100 10072 16 16
L 17 £ 17 20I.T. ANALYTICAL SERVICES TRIPLE MASS SPECTRUM DATAi HH234901 •40387/27/88 12(24:99 + 13l26 CALIl CflLe48788 •13SAMPLE! CLP,41695,MH2216,MH2217,MED,SOIL,W234e01,UO<!|,EPACONDS.s »INSTRmiENT-OMA5» EPA CLP METHOD (WLATILES)
ENHANCED SPECTRUM <S 15B IN OT>
BASE M/Ei 43/65 E'RICi 761./ 4987.
§
RAM SPECTRUM
die 2-SUTANONE
i ' | ' 1 > 1 ' 1 > 1 i |49 59 6 9 / 7 9 89 90 199 /
DATA: HH2340D1 •7B8C235 CHLOROBENZENE^WANCED SPECTRUM MATCH
RELATIVE INTENSITY ( X )MASS LIBRARY SAMPLE38 15 94 OUT OF 20% RANGE90 24 0 PEAK NOT IN SAMPLE91 24 3077 69 70112 100 100114 34 34
RAM SPECTRUM MATCHRELATIVE INTENSITY ( X )
MASS LIBRARY SAMPLE3S 19 31 OUT OF 20X RANGE90 24 48 OUT OF 20X RANGE51 24 3177 69 9S112 100 100114 34 29
000042
I.T. ANALYTICAL SERVICES TRIPLE MASS SPECTRUM DATAl HH234801 »78807/27/88 12:24:08 + 26<16 CALIi CALB48788 »13SAMPLEi a-P,41695-HH2216<MH2217,MED,SOIL-HH234a)l,VOA,EPACOWS.; XINSTRUMEHT-OUA9X EPA CLP METHOD (UOLATILES)ENHANCED SPECTRUM (S 1SB 1M 8T)
BASE H/Es 112/ 117RICl 3859./ 31775.
RAM SPECTRUMm.u
58.8-
C6.H5.
M/E /
CL
40 5
1 1
C235 CHLOR061
I l l l .
MZENE
0 68 7 8 / 8 8 98 188 118 128 /
1 > 1 > | > 1 "r—r
000044FILE HH2340D1 PEAK HEIGHTS AND COMPUTED AMOUNTS BY SCAN NUMBER:
N LIMIT SET AT 3.0 UNITSUSE ALL PEAKS FOR LIBRARY SEARCH
30S636785
S337617090
602S14841897
227 IS. 643487.994923.23312. 62672.02767.42288. 02282.S3220.06028.06999.78361.4
90. 0 v ^ .90. 0 / ' ' ) (•^\.'>5/ -^90. 0 '7. 3"1
6. 4t--= gco -- &-»6D7. 8 ^-. <\^o » 700C?
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. 9 =- l^o -- i<r60
LIBRARY SEARCH DATAi HH234801 • S 3 BASE H/E: 4487/27/88 12i24i89 + li46 CALIl CT1L840788 « 13 RICl 1006.SAMPLE; CLP,41695-MH2216,(#C217,MED,SOIL,HH234801,VOA,EPACONDS.; »IMSTRUMENT-OMA5» Em CLP METHOD <UOLATILES>EHHANCED (S 156 IN OT)
HYOROPETOXIDE, 1,4-OI(»MN-2-YL CAS » 4722-59-2
CAS • 754-48-7
CAS « 127-19-5
58' i •68 78 88 90 108 118 128
LIBRARY SEARCH OATAi HH234801 • 5 7 BASE N/E; 5987/27/88 12:24898 + 1:54 CALI; CALe487re • 13 RICs 92.SAMPLE; CLP-41695,MH22t6-HH22l7,ffiD-SOIL,HH234a)l,UOli>-EPACOWS.; »IHSTRUMENT-OMfl5» EPA CLP METHOD (VOLATILES)ENHANCED (5 15B IN 9T)
CAS • 36749-13-9
PROPANE, 2-CTH(»fl'-2-»C7HYL- CAS • 637-92-3
2-BUTANOL, 2,3-OIMETHYL- CAS t 594-69-5
58 69 79 89 98 lee 119
C C
£ 5 £ 17 S O
•M LIBRARY SEARCH0 97/27/W 12i24iee + 2l920 SAMPLE: CLP,41695,MH2216,MH2217,MED,SOIL-Hh0 CONDS.! tINSTRUHEHT-OHAM! EPA CLP HETHOC0 ENHANCED <S 15B 1H 9T)1468^
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8^1SrtEK^458
M/E
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, , 1 14e 45
FORt1AMIDE,M,N-DIMETHYL-
2-BUTAWHINE CAS « 13952-84-6
—i—\—,—.i—i—i—i—i—i—i—i—i—i—,—.—,—.—,—,—.—,50 55 68
G
DATA: HH234801CALIl CAL94078
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1 . 168-12-2
79-05-8
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LIBRARY SEARCH DATAi HH234001 t 70 BASE H/E: 4497/27/88 12:24:00 + 2:20 CALI: CAL040788 • 13 RIC: 246.SAMPLEi CLP,41695.MH2216,MH2217/MED,SOIL-HH234801,UOA,EPftCONDS.: tINSTRUMENT-OMASH EPA CLP METHOD <UOLATILES>ENHANCED <S 15B IN 0T)
CAS « 189-89-7
2-BUTANAHINE CAS • 13952-84-6
PROPANAMIDE CAS • 79-66-9
40 45-i—se 55 60
i65 79
1
LIBRARY SEARCH DATA! HH234801 • 88 BASE M/E; 4587/27/88 12:24:88 + 2f48 CALIl CAL04e788 « 13 RICl 1543.SAMPLEi CLP-41695/MH2216,MH2217,MED-SOIL-HH234a»l,UW/EPACONOS.: tINSTRUMEMT-OHA'tt EPA CLP fCTHOO (UOLATILES)ENHANCED <S 13B IN 0T)
2-PROPANOL-1-HETHOW- CAS » 187-98-2
SILAME. <FLUOROICTHYL>TCI11ETHYL- CAS * 28871-61-6
-i—•—• ' • i—• ' ' ' i2-BUTANOL,3-METH(»ff- CftS » 53778-72-6
48 58 68 78 88 98
9<^ £ 1 7 2 0
LIBRARY SEARCH DATAl HH234801 • 602 BASE M/Ei 4397/27/99 12)24:09 + 29104 CALIl C0.940788 • 13 RICt 5295.SWPLE; CLP,41695-W2216-MH2217,MED,SOIL,HH234«)1.W1,EPACONDS.t »INS7TaJfCNT-OMA5» EPft CLP METHOD (UOLATILES)ENHANCED (S 15B IN BT)
HEXANE CAS • 119-54-3
CAS * 5618-62-2
CAS • 96-14-0
40. . . . . . , . . . . 1
45 SB 55 68 65 78 75 80 85
C
^ LIBRARY SEARCH0 87/27/880 SAMPLE: CLP/41695,UH2216,UH2217,MED,SOIUHH234801,VWbEPA n0 CONDS.; (INSTRUMENT
ENHANCED1000
SAMPLE
C13.H28 UNOECANE,4,5-OIMETHYL- CAS • 17312-79-71090 i
HHT 184MNM 11S?^
3.H29 HE}<ANE,3-ETHYL-4-METHYL- CftS « 3074-77-9MKT^ln 111 i&o
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UNDECANE>2,5-DIMETHYL- CAS • 17381-22-3
DATAl HH234e01 • 814 BASE M/Ei 43 ^27:88 CALIl CAL840788 • 13 RIC) 5159. ^
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UWffff SEARCH DATA! HH2340)l • 841 BASE M/Ei 4397/27/88 12:24(08 + 28s82 CALIs CAL94e788 t 13 RICl 4935.SAMPLES CLP/41695,MH2216,MH2217->CD.SOIL/HH234a)l,WA,EPACONOS.: XINSTRUMENT-OMAS* EPA CLP METHOD (UOUffILES)ENHANCED <S 15B IN 0T>
HEPTANE,3-nETHYL- CAS » 589-81-1
CAS « 583-48-2
HEXANE- 2,3,3-TRIHETHYL- CAS » 16747-28-7
188 158
C200 250
6 5 £ 1 7 2 0
LIBRARY SEARCH DATA: HH2349D1 « 857 BASE M/ts 4307^7/88 12:24:08 + 28:34 CALI; CAL04e788 • 13 RIC: 7967.SAMPLE! a-P,41695,MH2216,MH2217,MED,SOIL,HH234801,UOA-EPACONDS.8 «INSTRU11ENT-OHA5« EPA CLP METHOD (UOLATILES)ENHAHCED <S 15B IN OT)
HEPTANE, 2-11ETHYL- CftS » 592-27-8
CAS » 592-13-2
HEXANE, 3-ETHYL-4-METHyL- CAS t 3874-77-9
iee 150 299 259 c
1A EPA SAMPLE NO.VOLATILE ORCAMICS ANALYSIS DATA SHEEffl()0054
Lab Nana; ITA^ - K^W \)\LLe____ Contract:.
Car NO.: '^^S SAS No.:Lab Coda: /TSTU Car No.: vi^S SOS NO.; tougz6fa
Lab saBpr ID: HH?.^4i P(
Lab rir ID; HH z-^^i n.
Matrix: (aoil/watar) .Saii,
Saapla wt/vol: ^ (q/»L) 6
Oaf Raeaivad: o7/z?.g3/8»Data Analyfd: f>7l-z7^fi
Laval: (low/Bad) M£P
t Moistura: not dac. g^
Coluan: (pack/cap) 7flc,t: Dilution ractor: lg6-CONCIMTIIATION OMITS » ^ *'»'•»(ug/L or uq/Kq) ua. /ks 0CAS NO. COMPOUND
I U^rt S2ZO
74-«7-3———Chloro«rthan«75-01-4—————vinvl Chlerida .-,--
7S-o»-2———M«thylan« Chlorida•7-«-l——————Acaten» „ ..75-lS-O———Carbon Olauliida7s-3S-4————l,l-Dlchloro«tlrn«
540-59-0————l,2-Diehloro«tfa«n» (totaill"67-<6-3———chlerofor«l07-o<-2———l. 2-Olehloroathana7«-93-3————2-But«non«7 i-55-<————l, l, 1-TrlehIoroctaiuM56-23-5—————Carbon Tatraeblorlda10I-05-4————Vinyl Aeatat*7S-a7-4———»re»edlchlerB—than;78-«7-5———l.a-DlehleroBroDW s~ioaioo«l-oi-5——or-1.3-DlcnlerBBroBW79-oi-«———Trlehlowth«r s^ac,124-4«-l————DitreMchloreMthan« \&-,^79-00-5—————1.1.a-TrichAoro«th<J» le-7oo
1 71-o-a-—————Mnna* r - - -100«l-02-«————tru)«-l,3-61enloroprop«Jf75-2S-2-——~»ro^ter»I0«-l0-l————4-ltothyl-i=»»nkanon<591-7<-<—————2-Bwanen*i27-n-4———T»tr«cnlore»tE«r79-34-s——————l. l, a. 2-T«tracaloro«taan«10t-««-3—————Tolu«B«lo«-«o-7———chlorobm««iM100-41-4 ————Ithylbwifn*100-42-5—————StyriM1330-20-7———xvlw <€55Il~'
1100&11000llooo11000
G^?yo
&700S-700
57005700S-loo5-70"
2^5700
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IE EPA. SA.-*?L£ SC.VOLATILE ORGANICS ANALYSIS DATA SHEHinn1'!1'!
TENTATIVELY IDENTIFIED COMPOUNDS——-
Lab Kama: t T f t g ' . K^O^U\I.L& Contract:;TC-)<
Ca«a No.: ^(."g SAS NO.:/-sLab Cod«: J r ^ T u
Matrix: taoil/wafr) soi^
Saapr wt/vol: t< (g/aL) 6
Lavl: (low/Bad) Ktp
» Moiatura; not dac. 6^
Coluan: (pack/cap) •PACH
CONCENTRATION UNITS:(ug/L or uq/Kq) ue. lk6.N<uBbar TICa found: i
SDC Wo.: uriezof.
Lab saapla ID: HU Z3MI D|
Lab rila ID: HH g3«i ^i
Data Raeaivad: ^^^z.^gs
Data Analyzad: 0-7 7 8t
Dilution Factor:
CJI
1234S6789
1011121314151617181920212223242526272S2930
^S NUMBER
no.?t-3
COMPOUND NAME
HttAAit
RT
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QT
rORM I VOA-TIC 1/87 Rav.
0321781,2
0000
56
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21*7
613
QUANTITATION REPORT FILE: HH2341D1 000057DATA: HH234101.TI^27/QQ 13:13;00
.PLE: CLP. 41693,MH2216.MH2220.MED,SOIL-HH2341D1,VOA,EPACONDS.: »IN9TRUMENT-OWA9» EPA CLP METHOD (VOLATILES)FORMULA: SOIL (1:123) INSTRUMENT: OUA9 WEIOHT:SUBMITTED BY: ITFK ANALYST: WET ACCT.NO. :AMOUNT-AREA « REF.AMNT/CREF.AREA)* RE8P.FACT),DET. LIM. - 0.00RESP. FAC. FROM LIBRARY ENTRYNO NAME1 CIOI BROMOCHLOROMETHANE (I.8.»1-CLP)2 CI10 1,4-DIFLUOROBENZENE (I.9.»2-CLP)3 C120 CHLOROBENZENE-DS(1.8.W3-CLP)4 CSIS 1.2-DICHLOROETHANE-D4 (S.S.ttD5 CS09 TOLUENE-D8 (S.S.*2)6 CS10 4-BROMOFLUOROBENZENE (8.8.#3)7 C010 CHLOROMETHANE »»8 CO IS BROMOMETHANE9 C020 VINYL CHLORIDE *10 C025 CHLOROETHANE11 C030 METHYLENE CHLORIDE12 C039 ACETONE13 C036 ACROLEIN14 C037 ACRYLONITRILE13 C040 CARBON DISULFIDE16 C043 1.1-DICHLOROETHENE *17 COBO 1.1-DICHLOROETHANE •»C COS3 TRAN8-1.2-DICHLOROETHENE-/ COAO CHLOROFORM »20 C069 1,2-DICHLDROETHANE21 CI10 2-BUTANONE22 C11S 1,1,1-TRICHLOROETHANE23 C120 CARBON TETRACHLORIDE24 C123 VINYL ACETATE29 C130 BROHOOICHLOROMETHANE26 C140 1.2-DICHLOROPROPANE «27 C143 CIS-1, 3-D ICHLOROPROPENE28 C190 TRICHLOROETHENE29 C1SS DIBROMOCHLQROnETHANE39 C160 1,1,2-TRICHLOROETHANE31 C1&3 BENZENE32 C172 TRANS-1.3-DICHLOROPROPENE33 C17S 2-CHLOROETHYL VINYL ETHER34 C180 BROMOFORM »»33 C210 2-HEXANONE36 C20S 4-METHYL-a-PENTANONE37 C220 TETRACHLOROETHENE '38 C229 1>1.2.2-TETRACHLOROETHANE *«39 C230 TOLUENE *40 C235 CHLOROBENZENE41 C240 ETHYL BENZENE *42 C249 STYRENE,A3 C2TO TOTAL XYLENE8
' C292 M-XYLENE~,-S C291 TRICHLOROFLUOROMETHANENO M/E SCAN TIME REF RRT METH AREAiHQHT) AMOUNT
0.00041&9B
000058
NO1
^456789
101112131415161718192021223324292627r^30313233343836373839404142434449
N012349
^<S9
M/E S128114117659893SO946264844356S37696639683627297
11743836373
13012997787363
1734343
1648392
112106104106106103
RET(L)10: 1421: 1026: 1013: 1223:0030:28
1:342:303: 10
•CAN308 1636 :783 :396 1730 :913 :
203229
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1 Rf1.1.1.1.1.1.
30.0030.00
RR11.00<l.OOt1. 00<1.28^0. 93;1. 161
0. 63'i0. 74<
0.634
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' A BBt A BB
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AMNT30.0030.0030. 0041.6348. 0248.22
AREACHQ24376.
114023.110621.31629.68321.76089.
748.2038.
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38.
237.141.
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IHT) AMCK.30. C30. C30. C41. t48. C48. S
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000059NO RET(L) RATIO RRT(L) RATIO10 4: 12 0. 410
/t4 6:38 l.Oa 0.648 1.02' ! 7:32 1 . 0 1 0.736 1 . 0 1
13 7: 48 0. 76214 8: 38 0. 84415 8:28 0.82716 9: SO 0. 96117 1 1 : 0 6 1.08918 12:02 1 . 17619 12:24 1 . 2 1 220 1 3 : 1 8 1. 30021 13:22 1 .00 0.631 1.0022 14:30 0. 68323 14: 34 0. 70424 13:22 1.00 0.726 1.0029 19:26 0.72926 16: 96 0. 80027 17: 14 0. 81428 17:92 0.84429 18: 16 0. 86330 18: 28 0. 87231 18:32 1.00 0.876 1.0032 18:34 0.87733 19:44 0.93234 21:00 0.99239 23:24 0.89436 21: 46 0. 832
/—" 23: 40 0. 904J 23:24 1.01 0.894 1.01
39 29: 12 1. 00 0. 963 1. 0040 26:16 1.00 1.004 1.0041 28:14 1.07942 32:02 1.22443 33: 10 1. 26844 32:20 1.23649 8:98 0. 876
AMNT AMNT(L) R. FAC R.FAC<L) RATIO90. 00 0. 674
1.04 90.00 0.030 1.497 0.022. 91 90. 00 0. 083 1. 426 0.06
90. 00 0. 26290. 00 0. 69790. 00 3. 04790. 00 1. 14390. 00 2. 83290.00 1.39090. 00 2. 87090. 00 I. 999
3. 39 90. 00 0. 009 0. 080 0. 0790. 00 0. 446 LH90.00 0.419
0.04 90.00 0.001 1.246 0.0090. 00 0. 98690. 00 0. 44964. 00 0. 922 <M90. 00 0. 449 090. 00 0. 98490. 00 0. 399
0.02 90.00 0.001 1.090 0.0036. 00 0. 44690. 00 0. 24090. 00 0. 98490. 00 0. 94290.00 1 .13990. 00 0. 449 ,
0 .19 90.00 0.002 0.782 •0.000. 09 90.00 0.001 0.733 0.001.99 90.00 0.030 0.944 0.03
90. 00 0. 49090. 00 0. 88690. 00 0. 91090. 00 0. 91190. 00 1. 249
000060IT ANALYTICAL SERVICES
QA/QC REPORT• L E : HH2341DI
INTERNAL STANDARD AREA CHECK
3 OUT OF 3 ARE WITHIN SOX TO 200X OP DAILY STANDARD AREAS.»» INTERNAL STANDARD AREAS ARE WITHIN QC LIMITS *»
INTERNAL STANDARD RETENTION TIME CHECK
3 OUT OF 3 ARE WITHIN +/- 30 SECONDS OF DAILY STANDARD RETENTION TIME
^0^0t<~\vf
•» INTERNAL STANDARD RETENTION TIMES ARE WITHIN QC LIMITS •« C\J0
r
7/27/88 13:13:30ACQUISITION STARTED
SCAN 1 OF 1020 000061
RUN 0:HH2341D1 ACQUIRING0:04 FREE SECTORS:16897 SCAN: 2 OF 1020
SAMPLE: CLP,41693.WH2216,WH2220,MED,SOIL.HH2341D1,VOA,EPACONDS.: »INSTRUMENT-OWA3» EPA CLP METHOD (VOLATILES)
WIRE07/27/8B t3:13:00 +
FORMULA: SOIL <1:123) INSTRUMENT: OWA3 WEIOHT: 0.000SUBMITTED BY: ITFK ANALYST: WET ACCT. NO.: 41699
LOW MASS:HIGH MASS:
35300
UP:DOWN:
1. 9S L*0.00 L
TOP:BOTTOM:
0. 000. 09
CENT S/P: 37 ACTUAL:FRAO S/P: 20 ACTUAL:MIN PEAK WIDTH: 1A/D THRESHOLD: 1
3719
SAMP INT (MS): 0. 200SAMP INT (MS): 0.400
PEAK WIDTH:INTEN/ION:
1000.2
MIN FRAO WIDTH X:BASELINE: 0
SO MIN AREA: 23
MODE: CENTROIO POSITIVE IONINTERFACE NUMBER 0SUB-INTERFACE NUMBER 0» OF ACQU BUFFERS 16INSTRUMENT TYPE QFULL SCALE MASS 800 AMUZERO SCALE MASS 1 AMUINTENSITY/ION 2
^ PEAK WIDTH 1000. MMUOFFSET AT LOW MASS 0 MMUOFFSET AT HIGH MASS 0 MMUVOLTAGE SETTLING TIME(MS) 4
ACQUISITION STARTED WITH GC FILE 1GC PARAMETERS:
M. S. TUNE PARAMETERS:MULTIPLIER VOLTS: -20S2.33LOW RESOLUTION: 127.-00HIGH RESOLUTION: 126.00ION ENERGY: 3. 33ION PROGRAM: 3. 96LENS VOLTAGE: -29.SOEXTRACTOR: 0. 94ELECTROMETER RANGE: 7, 00ELECTROMETER ZERO: 2-. 74
230 DEO30 DEC
230 DEC4 MIN
8.0 0/M60 MIN
230 DEO90 DEC
INJ. MODE:1 SEC •
ZONE TEMP.INITIAL TEMP.FINAL TEMP.INITIAL TIMERAMP RATEFINAL TIMESEP. SET PT.MANIF. SET PT.
PKD• DV OPN
7/27/88 13:47:37ACQUISITION COMPLETEDSCANS 1 TO 1020 CENTROIO
ITROIDSCANS
1020SECS OUT OF X
238. 0 2040. 0 12.6PEAKS PER SCAN22490. 22.
PER SEC11.
03217S18
IT ANALYTICAL BCTVrCCS OlAaNOBTIC HEPO-T 7/27/'BB 13:40:10DATA FILE:HH2341D1 t0REFERENCE: LIBRARYVE
METHOD: V08T INITIALIZATION OPTION: 2 PROCESSINe OPTION: 4 000062 -REPORT: CLPISS8 """*... ^
< ——— STANDARDS ———— >< -— PLUS UNKNOWNS —— >< - LIST NAMES - > -PROC USED POSS RMS PROC USED POSS RMS STANDARD/UNKNOWN pJ
6 6 1 46 43 6 1 46 CLPISB8/CLPUNKS0
43 COMPOUNDS PROCESSED, 6 FOUND
< COMPOUND >< -———————— SEARCH ————————— •>< SAT > < ————— CHRO —————— :NO LIB ENTRY REF PRED SEL DELTA PEAKS FIT PEAKS M/Z TOP DELTA PEAKS
1 VE 1 -306 308 30B . 1 909 . 128 3082 VE 3 -633 633 636 1 1 993 . 1 1 4 6363 VE 3 -7BI 783 78S . 1 983 . 1 1 7 789
VE 4 -394 396 396 . 1 980 . 63 396VE 3 -746 730 730 . 1 991 . 98 730VE 6 -911 913 913 . 1 934 . 99 913VE 7 -48 49 . . . . . 90 .VE 8 -76 77 . . . . . 94 .VE 9 -97 98 . . . . . 62 .
10 VE 10 -138 189 . . . . . 64 . . .1 1 VE 1 1 -200 202 . . . . . 84 203 . 112 VE 12 -226 228 . . . . . 43 229 . 113 VE 13 -332 234 . . . . . 36 . . .14 VE 14 -233 297 . . . . . 33 . . .13 VE 19 -293 299 . . . . . 76 . . .
VE 16 -293 299 . . . . . 96 . . .VE 17 -332 334 . . . . . 63 . • .
18 VE 18 -398 360 . . . . . 96 . . .19 VE 19 -371 373 . . , . . 83 . . .20 VE 30 -396 398 . . . . . 63 . . .21 VE 21 -398 400 . . . . . 73 403 . 123 VE 33 -433 436 . . . . . 97 . . .23 VE 23 -443 448 . . . . . 1 1 7 .24 VE 24 -498 461 . . . . . 43 460 . 329 VE 29 -461 464 . . . . . 83 . . .36 VE 36 -906 909 . . . . . 63 . . .27 VE 27 -914 317 . . . . . 79 . . .28 VE 38 -933 336 . . . . . 130 .29 VE 39 -346 349 . . . . . 129 . . .30 VE 30 -992 999 . . . . . W . . .31 VE 31 -333 333 . . . . . 7 8 338 . 132 VE 33 -994 397 . . . . . 73 . . .33 VC 33 -389 393 . . . . . 63 . . .34 VE 34 -638 631 . . . . . 173 .39 VE 39 -699 703 . . . . . 43 . . .36 VE 36 -690 693 . . . . . 43 . . .37 VE 37 -708 713 . . . . . 16438 VE 38 -701 709 . . . . . 83 707 . 339 VE 39 -733 736 . . . . . 93 738 . 240 VE 40 -789 789 . . . . . 113 788 . 141 VE 41 -843 S47 . . . . . 106
VE 42 -999 960 . . . . . 104 . . .^J VE 43 -989 994 . . . . . 106 . . .44 VE 44 -969 970 . . . . . 10643 VE 46 -269 271 . . . . . 103 . . — .
^03217819
I . T . ANALYTICAL. SERVICESLIBRARY SEARCH REPORT
VOLATILE ORGANIC ANALYSIS000063
JttATA FILE: HH2341D1' 1.IBRATION FILE: CAL040788
aEARCH OF LIBRARYVE
SCAN COMPOUND
308 CIOI BROMOCHLOROMETHANE (I.8.»1-CLP)636 CI10 1,4-DIFLUOROBENZENE (I.S.ttZ-CLP)78S Cia0 CHLOROBENZENE-D9(I.S.#3-CLP)396 CS1S 1,2-DICHLOROETHANE-D4 (S.S.ttI)7SO CSOS TOLUENE-D8 <S.S.»5)919 C810 4-BROMOFLUOROBENZENE (8.S.tt3)203 C030 METHYLENE CHLORIDE229 C039 ACETONE403 C110 2-BUTANONE788 C23S CHLOROBENZENE
DELT^
01 914-999
0000113
-1
A^ PUR-FIT <
972-99B
930-986990-986934-99S796-864740-833670-744688-7S1947-829
MT FLNO > 8AT
50 030
90 042 048 048 0-t- 03-^ 03«^- 02«^- 0
AOSLI;
00000
-3-2-1-a-2
B
0^\0I<• r<M0
03217820
DATA: HH2341D1 tt203C030 METHYLENE CHLORIDE
-«=WANCED SPECTRUM MATCH
RELATIVE INTENSITY (X>MASS LIBRARY SAMPLE36 12 0 PEAK NOT IN SAMPLE47 25 0 PEAK NOT IN SAMPLE49 100 10051 32 32S4 68 6386 42 36
000064
RAW SPECTRUM MATCH
RELATIVE INTENSITY (X»MASS LIBRARY SAMPLE36 12 0 PEAK NOT IN SAMPLE47 22 0 PEAK NOT IN SAMPLE49 100 10091 32 41S4 68 6386 42 36
03217821
^ LS. 17 30
I.T. ANALYTICAL SERVICES TRIPLE MASS SPECTRUM DATAl HH2341DI »29307/27/88 13:13(90 + 6i46 CALIl CAL949788 »13SAMPLE! CLP-41695,MH2216-W2220-MED,SOIL,HK2341DLWA,EPACONDS.; »INSTRUMEMT-OHAS« EPA CLP METHOD <UOLATILES>ENHANCED SPECTRUM <S 15B IN BT)
BASE M^t 49/ 44RIC; 454.-' 1641.
' I ' IRAM SPECTRUM
T t 1 | 1 I l I l I l ' I ' • » r
' I ' II 1 I T 10930 HETHYLEHE CHLORIDE
-r-r-r
59 ieel ' I ' l/ t5e 299 259C
DATA: HH2341DI •Z29C03S ACETONE/o HANCED SPECTRUM MATCH
RELATIVE INTENSITY (X)MASS LIBRARY SAMPLE43 100 10058 16 0 PEAK NOT IN SAMPLE
000066
RAW SPECTRUM MATCHRELATIVE INTENSITY <X)
MASS LIBRARY SAMPLE43 100 100SB 16 16
03Z17823
£ L £. t7 2 0
I.T. ANALYTICAL SERVICES TRIPLE MASS SPECTRUM DATA; HH2341D1 »22907/27/88 13:13:00 + 7l38 CALI: CftL84e788 tl3SAMPLE: CLP,4l695,MH2216,HH222e,MED,SOIL,HH2341Dl,WA,EPACONOS.i »INSTRUMENT-OMA5» EPA CLP HETHOO (WLATILES)
ENHANCED SPECTRUM <S 15B IN BT)
RAM SPECTRUM
BASE H^E: 43/ 44RICl 219./ 1227.
C3.H6.0 C835 ftCETONE
35 49 c 45 58 55
DATA: MH2341DI tt403C 1 1 0 2-BUTANONE
.^lHANCED SPECTRUM MATCH
RELATIVE INTENSITY <%)MASS LIBRARY SAMPLE
33 26 0 PEAK NOT IN SAMPLE37 14 0 PEAK NOT IN SAMPLE43 100 10072 16 16
000068
RAU SPECTRUM MATCH
RELATIVE INTENSITY (X)MASS LIBRARY SAMPLE35 26 B37 14 643 100 10072 16 19
03Z1782S
I.T. (m-YTICAL SERUICES TRIPLE MASS SPECTRUM OATAt HH234101 •40307/27/88 i3il3:ee + 13(26 CALI; €N.940788 »13SAMPLE) CLP,41695,MH2216,MH2220,MED.SOIL,HH23410l,UOA,EPftCONDS.! «INSTR(JMENT-OMft5« EPA CLP HETHOO <UOLATILES>
ENHftMCED SPECTRUM (S 15B IN eT>
BASE M/E: 43/65RIC; 825. / 4875.
MM SPECTRUM
C118 2-BUTANONE
i ' | i 1 ' 1 i 1 ' 1 ' |48 58 6 8 / 7 0 88 90 108 /
DATA: HH2341D1 •788C233 CHLOROBENZENE/-'NHANCED SPECTRUM MATCH
RELATIVE INTENSITY ( X )MASS LIBRARY SAMPLE38 13 76 OUT OF 20X RANGE50 24 62 OUT OP 20X RANGE31 24 3077 63 64112 100 100114 34 27
RAM SPECTRUM MATCHRELATIVE INTENSITY <X>
MASS LIBRARY SAMPLE38 13 97 OUT OF 20X RANGE30 24 74 OUT OF 20X RANGE31 24 3177 63 68112 100 100114 34 26
000070
L L £ 17 3 0 ^
I.T. (WALYTICAL SERVICES TRIPLE MASS SPECTRUM DATA: HH2341D1 »78807/27/88 13;13:08 + 26:16 CALI; CAL0497% •13SftMPLE: a-P.41695,MH2216-W222e,MED,SOIL,HH2341Dl,UOft/EPftCOWS.! tINSTRUMEHT-OMflSt EPA CLP METHOD (UOLATILES)
ENHANCED SPECTRUM <S 1SB IN OT)
• ' l • ' 'RAU SPECTRUM
BASE M^l 112/' 117RICt 2823./ 38111.
-r-rC235 CHLOROBENZENE
TT-
108 irc 200 250 C
FILE HH2341D1 PEAK HEIGHTS AND COMPUTED AMOUNTS BY SCAN NUMBER:
/—^•N LIMIT SET AT B.0 UNITS
UdE ALL PEAKS FOR LIBRARY SEARCH
308 23310. 3 90.0\. , . J.636 44126. 9 90. O Y 5 (^ I H)783 51907.2 30. 0 /602 3134.3 3. B(^~s. •73 . - |M
b««0
000072
S8 88 fi29Z fi9 89S 0S Sfr W
Z-C8-SZ • SW
EllN-0'IIH'K Z-Z9-819S » StO
e-tfi-aii « sro3NW3H
3-ldM9S8ZTT
(19 NT 851 S) 033NWH3<S31Iiy-10ft) OOH13M <r0 Ud3 «SU«)-iN3UnaLSNIt "50N03
tU3'tlOri'TOIWZHHniOS'03M'eZZZHM'9IZZHM'£69H''d"13 <J1dMbS•ins soia ei • saiawiw) snya wez + easer-ei o^a/iA et- 1241 3SV8 289 • TQIZHH '»i«l H3W3S AWaan
024379
XA EPA SAMPLE NO.VOLATILE ORGAMICS ANALYSIS DATA SKEEI^M,
Lab N«M; I-TA«;-j<A;OXui^g Contract:,
Car No.: 'i^i^s SAS No.:Lab coda: ir&ru
Matrix: (•oil/wafr) ^an,
Sample vt/vol: H (q/»L) 6
Level: (low/Bed) K£&
» Moisture: not dee. 9 1
Column: (pack/cap) ?flCb
CAS NO. COMPOUND
UH2ZZI
SDG No.; fem?go(e
Lab Saapl* ID: HH g?4g.Bi
Lab rir ID: HH Z3HZf>l
Oaf Kacaivad: opfzg.ga/fift
Oaf Analyrd: ^71^7^6
Dilution ractor: I___
COMCINTHATION OMITS:(ug/l. or uq/Ka) uft. /ks 0
74-B7-74-«3-7S-01-75-00-75-09-<7-<4-75-IS-75-35-75-34-540-59»7-«-107-067«-93-71-55-56-23-10B-0575-27-7«-«7-10061-79-01-124-4C79-00-71-43-10061-<75-25--10«-l0-59l-7«-H7-ll<79-34-Sloi-r-101-90-100-41.100-42-1330-2C
———Vinyl Chloride
——————M«thyl»n« Chloride
o———l,2-Dichloro»tto«n« (total)
2———1.2-Diehlorothan*—————2-Bufnon*————l,l,l-Trichloro«than<———carbon Tatrachlorid*4———vinyl *e«taf—————»ro»odichlore—than«—————1,2-oicnieroBreBwr1-5———«1«-1.3-Dicnloroproyn*———TricBlewtliiw
)2-«- ——tfn«-1.3-Oieliloroprop«M-l——«——4-)taChyl-2-r«itanon«
-4———T»tr»rtlowtl»—5— ————l ,1,9,2-T««raohloro«Uiw
-7———caiereb«»»<M»«.4 •————Ithylbmcur-5————Styr»n«t-7————-xvlur (iotali
6.<,oofefcoe(.(.<>•(>fa063300
??oa33flo23oo320033t<33fte3 Sco
^90»»«>o33oo(.(•OO«so«3^0330.*5 3«»
1 ?3»ftJSoo
lt.00
3?»PJ3«»o(.L60
...2^A -2 woe
JIftBOaaao
33002.100
u
|=
|
fc
roxM z VOA l/»7 Rev.
Q3ZV3fS31,
IE EPA SA."?..; ;;C.VOLATILE ORGANICS ANALYSIS DATA SHEBTinn^i-
TENTATIVELY IDENTIFIED COMPOUNDS OUUU/0
Lab Naur:/Tt-)<
^Lab Coda; ir Jfru Car No.: vt-if
Matrix: (aoil/wafr) sou-
Sampl« wt/vol; t/ (a/aL) G
L«v«l: (low/Bad) i^tp
t Moisture: not dec. 8 1
Colmnn: (pack/cap) TOO-
NuobT TICa found: I 3
Contract:5AS N O . : SDG No.; unzgof.
Lab Saapl« ID: H H ? 31 Z 01
Lab Fil« ID: HH-Z^ZPI
Dat« Rccaivd: a-T /g^ z^/g8
Oaf Analyzed: {niz-il^*
Dilution ractor: I
COMCIHTOATIOH OMITS:{ug/L or uq/Kq) ufc /k6
Ct
1234S67a9
101112131415161718192021222324252627282930
&S NUMBER
1 1 & . ^ . 3f6&.8->--&W3-79.%^M-»V.«<S-ll-Tt.f^2-<i?-St.al-tt.-l3na-Zt.lK'»il-?<»-B)<!>(.. Z / . ftS-BS.ai-1S 1 ? - 2 7 - 8lt.-(.S--t
COMPOUND NAME
Mex«A<«CttLtMtXMo*, M,ttH1>--Ct(Ll-aHt»4Mfr. *.»•»»>((.-t-M.tTM«lL.Ht I tA^t , ?.M,«Tt*YL-M«XftMfr , l.»A*T»»-H •ueprA^c»t*>1**.*| ». (THIl-l-MfUtll..0»tl.<>(KH*.».0,J- Dt»»«T»W«Tl»csei&HtxnAit i.«TMU-z-M«-rH«.l.<»t7HA10t., ^•».&1M*TM<1-K€TT»*tfe ?.M*-rrtVl-Ht?TA^*;?.IX.«THW«..OILtflAlt
RT
^•a.o^Pfr,"??3ra e
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ZST. CONC.
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^ c- g (SJIIUflOft) OOH13H dT> ?0 «SW10-J.N3MfftllSNI» ''SONOO 0
^ •s^i g1 yda'wft'loewzHHnios'aaH'izzzm'sizaiM'aso'dD 'TidMys
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^ i. 024382
8UANTITATION REPORT FILE: HH2342D1 000077DATA: HH2342D1.TIO.Z/27/88 13:37:00
' 1PLE: CLP.4169B.HH2216.MH2221,MED.SOIL,MH2342DI,VOA,EPALUNDS.: •INSTRUMENT-OUA3* EPA CLP METHOD (VOLATILES)FORMULA: SOIL (1:129) INSTRUMENT: OWA3 WEICHT:SUBMITTED BY: ITPK ANALYST: MET ACCT.NO.AMOUNT-AREA » REF. AMNT/<REF.AREA)* RESP.FACT)fDET.LIM.- 0.00RESP. FAC. FROM LIBRARY ENTRYNO NAME1 CI01 BROMOCHLOROMETHANE (I.S.ttl-CLP)2 CI10 1.4-DIFLUOROBENZENE (I.S.»2-CLP)3 CI20 CHLOROBENZENE-D3(I.8.»3-CLP)4 CS13 1,2-DICHLOROETHANE-D4 ( S . S . t t I )9 CS03 TOLUENE-D8 <S. S. tt2>6 CS10 4-BROMOFLUOROBENZENE (S. S.tt3>7 CO 10 CHLOROMETHANE «•8 CO IS BROMOMETHANE9 C020 VINYL CHLORIDE »10 C02S CHLOROETHANE11 C030 METHYLENE CHLORIDE12 C033 ACETONE13 C036 ACROLEIN14 C037 ACRYLONITRILE13 C040 CARBON DISULFIDE16 C04S 1>1-DICHLOROETHENE *17 C030 1.1-DICHLOROETHANE **r^ C033 TRANS-1.2-DICHLOROETHENE
C060 CHLOROFORM *20 C06S 1,2-01CHLOROETHANE21 •CI10 2-BUTANONE22 CUB 1, 1. 1-TRICHLOROETHANE23 CI20 CARBON TETRACHLORIDE24 C123 VINYL ACETATE23 C130 BROMODICHLOROMETHANE26 C140 1,2-DICHLOROPROPANE *27 C143 CIS-1,3-DICHLOROPROPENE28 C130 TRICHLOROETHENE29 C133 DIBROMOCHLOROMETHANE30 C160 1-1,2-TRICHLOROETHANE31 C163 BENZENE32 C172 TRAN8-1.3-DICHLOROPROPENE33 C173 2-CHLOROETHYL VINYL ETHER34 C180 BROMOFORM «*33 C210 2-HEXANONE36 C203 4-METHYL-2-PENTANONE37 C220 TETRACHLOROETHENE38 C223 1.1,2,2-TETRACHLOROETHANE ••39 C230 TOLUENE *40 C233 CHLOROBENZENE41 C240 ETHYL BENZENE «42 C243 STYRENE43 C230 TOTAL XYLENES
f - - C232 M-XYLENEJ C231 TRICHLOROFLUOROMETHANE
NO M/E SCAN TIME REF RRT METH AREA(HOHT) AMOUNT
0.00041693
000078
M/E SCAN TIME REF RRT METH128 308 10:16 1 1.000 A BB114 633 21:10 2 1.000 A B B117 784 26:08 3 1.000 A BB63 396 13:12 1 1. 286 A BB98 730 23:00 3 0. 937 A BB93 913 30:30 3 1.167 A B B30 194 162 164 184 202 6:44 1 0.636 A BB43 231 7:42 1 0.730 A BB36337696639683 162 172 403 13:26 2 0.633 A BB97 . 2
117 243 460 13:20 2 0.724 A*BB83 263 273 2
130 2129 297 278 336 18:32 2 0.876 A BB73 263 2
173 243 343 637 21:34 3 0.838 A BV
164 383 703 23:30 3 0.89992 736 23:12 3 0. 964
112 789 26:18 3 1.006106 847 2S: 14 3 1 . 080104 3106 996 33: 12 3 '1. 270106 969 33:18 3 1.236103 1
RET(L> RATIO RRT(L)10: 14 1. 00 1. 00021:10 1.00 1.00026: 10 1. 00 1. 00013: 12 1. 00 1. 29023: 00 1, 00 0. 93330:28 1.00 1.164
1:34 0. 1332: 30 0. 2443: 10 0. 309
RATIO1.00 30.001.00 30.001.00 30.001.00 42.331. 00 48. 011.00 47.07
BBBBVBBB
BBBB
AMNT
AREA(HOHT)23940.
120343.. 113683.
31324.70190.76323.
433.2239.
486.
104.
6392.
3667.
1388.6162.
61699.4910.
2089.3102.
W^AMNT<L) R.
30.00 1.30. 00 1.30.00 1.30.00 1.30.00 0.30. 00 0.30. 0030. 0030. 00
AMOUNT XTOT30.000 UO/L 14.6630.000 UO/L 14.6630.000 UO/L 14.6642. 343 UO/L 12. 4148.006 UO/L 14. 0747. 069 UC/L 13. 80
^ (
0. 621 UO/L /Ot-T8" •^003. 279 UB/L i O. 96 -• }AW
00v\<d-(M0
IWOa. 317 UC/L i/0. 74 - -3+w
o. 033 UO/L Or-or
/<»002. 432 UO/L >^"0. 71 =- -W
2. 189 UO/L ^ef
0.893 UC/L A-2S' , , .3. 696 UC/L 1. 08' UlW »•—•
28. 738 UC/L ^Q. 43- Wrs^flW4. 797 UC/L \. 41 s ^«T>3tot
1. 802 UC/L 0. 334 2. 670 UO/L v^'0. 78 5fc» i^
4.t7-2
FAC R.FAC(L) RATIO000 1.000 1.00000 1.000 1.00000 1.000 1.00308 1.343 0.83i/617 0. 643 0. 96 671 0.713 0.94^
1. 0400. 864 ^<-0. 940 ^" L,,-7(»1P»
03217835
000079NO R E T < L > RATIO RRT(L) RATIO10 4: 12 0. 410
/->< 6:38 1.02 0.648 1.017:32 1.02 0.736 1.02
13 7:48 0. 76214 8:38 0.84415 8:28 0.82716 9: 90 0. 96117 11:06 1.08918 12:02 1.17619 12:24 1.21220 13: 18 1. 30021 13:22 1.00 0.631 1.0022 14:30 0.68323 14: S4 0. 70424 19:22 1.00 0.726 1.0029 19:26 0.72926 16: 96 0. 80027 17:14 0. 81428 17:92 0.84429 18: 16 0. 86330 18:28 0. 87231 18:32 1.00 0.876 1.0032 18:34 0.87733 19:44 0. 93234 21: 00 0. 99239 23:24 0.89436 21:46 1.01 0.832 1.01
<~^ 23: 40 0. 904-. 23:24 1.00 0.894 1.01
39 29:12 1. 00 0.963 1. 0040 26:16 1.00 1.004 1.0041 28: 14 1. 00 I. 079 1. 0042 32:02 1.22443 33:10 1.00 1.268 1.0044 32:20 1.00 1.236 1.0049 8: 98 0. 876
03y\
AMNT AMNT(l-) R. FAC R.FAC(L) RATIO90. 00 0. 674
0.62 90.00 0.018 I.497 0. 013. 28 90. 00 0. 094 1. 426 0.07
90. 00 0. 26290. 00 0. 69790. 00 3. 04790. 00 1. 14390. 00 2. 83290.00 1.39090. 00 2. 87090. 00 1. 999
2.92 90.00 0.004 0.080 0. 09 m90. 00 0. 44690. 00 0. 419
0.03 90.00 0.001 1.246 0.0090. 00 0. 986 ^90. 00 0. 449 (M64. 00 0.922 090. 00 0. 44990. 00 0. 98490. 00 0. 399
2.43 90.00 0.093 1.090 0.0936. 00 0. 44690. 00 0. 24090. 00 0; 98490. 00 0. 942
2.19 90.00 0.090 1.139 0.0490. 00 0. 449 .
0.89 90.00 0.014 0.782 • 0.023.70 90.00 0.094 0.733 0. 07
28. 76 90. 00 0. 943 0.944 0. 984.80 90.00 0.043 0.490 0.10
90. 00 0. 8861.80 90.00 0.018 0.910 0. 042.67 90.00 0.027 0.911 0.09
90.00 1.249
000080IT ANALYTICAL SERVICES
OA/QC REPORT' L E : HH2342D1
INTERNAL STANDARD AREA CHECK
3 OUT OF 3 ARE MITHIN BOX TO 200% OF DAILY STANDARD AREAS.
»» INTERNAL STANDARD AREAS ARE MITHIN QC LIMITS •*vo
INTERNAL STANDARD RETENTION TICS CHECK TO
3 OUT OF 3 ARE MITHIN */- 30 SECONDS OF DAILY STANDARD RETENTION TIME ^r
»•» INTERNAL STANDARD RETENTION TIMES ARE MITHIN QC LIMITS •» 0
03217837
7/27/88 13:38:24ACQUISITION STARTED
SCAN 1 OF 1020 000081
JUIRE RUN 0:HH2342D1 ACQUIRING0//27/88 13:97:00 + 0:04 FREE SECTORS:16674 SCAN: 2 OF 1020SAMPLE: CLP,41693,WH2216.MH2221.MED,SOIL.HH234201,VOA.EPACONDS.: •INSTRUMENT-OWA9* EPA CLP METHOD (VOLATILES)FORMULA: SOIL < 1 : 1 2 3 ) INSTRUMENT: OWA9 WEIOHT: 0.000SUBMITTED BY: ITFK ANALYST: WET ACCT. NO. : 41699
LOW MASS:HI OH MASS:
CENT S/P: 37FRA8 S/P: 20
33300
UP:DOWN:
1. 93 L»0.00 L
TOP:BOTTOM:
0. 000. 03
ACTUAL:ACTUAL:
3719
SAMP INT (MS): 0.200SAMP INT (MS): 0.400
PEAK WIDTH:INTEN/ION:
1000.2
MIN PEAK WIDTH: 1A/D THRESHOLD: I
MODE: CENTROID POSITIVE ION
INTERFACE NUMBERSUB-INTERFACE NUMBERtt OF ACQU BUFFERSINSTRUMENT TYPEFULL SCALE MASSZERO SCALE MASSINTENSITY/ION
f^ PEAK WIDTHOFFSET AT LOW MASSOFFSET AT HI OH MASSVOLTAGE SETTLING TIME(MS)
MIN FRAG WIDTH X:BASELINE: 0
0016Q800 AMU
1 AMU2
1000. MHU0 MMU0 MMU
50 MIN AREA: 29
M.S. TUNE PARAMETERS:MULTIPLIER VOLTS: -2082.39LOW RESOLUTION: 127.00HIGH RESOLUTION: 126. 00ION ENERGY: 3. 33ION PROGRAM: 9.96LENS VOLTAGE: -29. 80EXTRACTOR: 0. 94ELECTROMETER RANGE: 7. 00ELECTROMETER ZERO: 2-. 74
ACQUISITION STARTED WITH OC FILE I
OC PARAMETERS:230 DEC
50 DEC230 OEO
4 MIN8. 0 D/M60 MIN
290 DEG90 DEC
INJ. MODE1 SEC '
ZONE TEMP.INITIAL TEMP.FINAL TEMP.INITIAL TIMERAMP RATEFINAL TIMESEP. SET PT.MANIF. SET PT.
PKD• W OPN
7/27/88 14:32:10ACQUISITION COMPLETEDSCANS 1 TO 1020 CENTROID
OIDSCANS
1020SECS
243. 3OUT OF2040.0
X11. 9
PEAKS PER SCAN26361. 26.
PER SEC13.
COIT ANALYTICAL SERVICES DIAON08TIC REPORT 7/27/88 14: 33: 37 -^DATA FILE:HH2342D1REFERENCE: LIBRARYVE nnnflfiO ^METHOD: voar INITIALIZATION OPTION- a PBOCESSTNO OPTION: « UUuUOri .METHOD: V08T INITIALIZATION OPTION: 2 PROCESSING OPTION: 4
REPORT: CLPI588 •=3-CV!0< -—— STANDARDS ———— X -— PLUS UNKNOWNS —— >< - LIST MARES - ?
PROC USED P09S RM8 PROC USED POSS RHS STANDARD/UNKNOWN6 6 1 71 43 a 1 93 CLPISSS/CLPUNK8
43 COMPOUNDS PROCESSED. 8 FOUND
< COMPOUND X -—————————— SEARCH -————————— ?< SAT > < ————— CMRO ——————NO LIB ENTRY REF PRED SEL DELTA PEAKS FIT PEAKS H/Z TOP DELTA PEAKS
1 VB I -306 309 30B -I 994 . 128 300 . 12 VE 2 -638 639 636 1 994 . 114 633 -1 13 VE 3 -781 783 783 . 967 . 117 784 -1 14 VE 4 -394 397 397 . 980 . 63 396 -I 13 VE 3 -746 730 730 . 941 . 98 730 . 16 VE 6 -911 913 914 -1 932 . 93 913 1 17 VE 7 -48 31 . . . . . 30 . . .8 VE B -76 79 . . . . . 94 . . .9 VE 9 -97 100 . . . . . 62 . . .
10 VE 10 -128 131 . . . . . 64 . . .11 VE 11 -200 203 . . . . . 84 202 . 112 VE 12 -226 229 . . . . . 43 231 . 113 VE 13 -232 233 . . . . . 36 . . .14 VE 14 -233 238 . . . . . 33 . . .13 VE 13 -233 236 . . . . . 76 . . .
VE 16 -293 296 . . . . . 96 . . .VE 17 -332 333 . . . . . 63 .' .
18 VE 18 -338 361 . . . . . 96 . . .19 VE 19 -371 374 . . . . . 83 . . .20 VE 20 -396 399 . . . . . 62 . . .21 VE 21 -39S 401 . . . . . 72 403 . 122 VE 23 -433 436 . . . . . 97 .23 VE 23 -443 448 . . . . . 117 . . .24 VE 24 -43S 461 . . . . . 43 460 . 223 VE 23 -461 464 . . . . . 83 . . .26 VE 26 -306 309 . . . . . 63 . . .27 VE 27 -314 317 . . . . . 73 . . .28 VE 28 -333 336 . . . . . 13029 VE 29 -346 349 . . . . . 129 . . .30 VE 30 -9M 9S9 . . . . . 97 . . .31 VE 31 -332 333 337 2 1 940 . 78 336 -1 132 VE 32 -334 337 . . . . . 73 . . .33 VE 33 -389 998 . . . . . 63 . . .34 VE 34 -628 631 . . . . . 17333 VE 39 -699 703 . . . . . 43 . . .36 VE 36 -630 634 . . . . . 43 697 . 137 VE 37 -708 712 . . . . . 164 . . .38 VE 38 -701 703 . . . . . 83 709 . 139 VE 39 -792 796 . . . . . 92 796 . 140 VE 40 -789 789 788 -1 1 942 . 112 789 1 141 VE 41 -843 847 . . . . . 106 847 . 1
VE 42 -999 999 . . . . . 104,J VE 43 -989 993 . . . . . 106 996 . I44 VE 44 -969 969 . . . . . 106 969 . 149 VE 46 -269 272 . . . . . 103
03217839 l^rfjl
I . T . ANALYTICAL SERVICESLIBRARY SEARCH REPORT
VOLATILE OROANIC ANALYSIS000083
. EiATA FILE: HH2342D1' tLIBRATION FILE: CAL040788
dEARCH OF LIBRARYVE
SCAN COMPOUND
308 CI01 BROMOCHLOROMETHANE (I.S.ttl-CLP)635 CI10 1,4-DIFLUOROBENZENE (I.8.02-CLP)784 C120 CHLOROBENZENE-DS(I. S. »3-CLP)396 CS13 1,2-DICHLOROETHANE-D4 <8.8.ttl)750 CS03 TOLUENE-OS (S.S.ttZ)913 CS10 4-BROMOFLUOROBENZENE (S.S.tt3>231 C033 ACETONE403 CI10 2-BUTANONE336 C163 BENZENE637 Ca03 4-METHYL-2-PENTANONE736 C230 TOLUENE *789 C233 CKLOROBENZENE847 C240 ETHYL BENZENE •996 C2BO TOTAL XYLENE8969 C2S2 M-XYLENE
DELT;
-I0 921-983
-I-100221300030
Ai> PUR-FIT <
980-993
924-971947-983923-981779-861903-903702-740863-872472-343883-916914-941839-946
0- 0374-709
MTNC >
30
304248473 -3 --2 " 0^4 ^
29'3 '•2-3 '
F18A'
030000000
000000
.A08r LI;
0000
-10.-40
-2-2-4-10
-1-99-2
B
00y\'^s(M0
03217840
DATA: HH234Z01 tt231C03S ACETONE
•syMHANCED SPECTRUM MATCH
RELATIVE INTENSITY (X)MASS LIBRARY SAMPLE
43 100 100SB 16 26
000084
0C---t^• t
040
I- 6 £ 17 3 0 '
I.T. ANALYTICAL SERVICES TRIPLE MASS SPECTRUM DATA: HH2342D1 »23187/27/88 13:57:99 * 7:42 CALI; CAL949788 »13SAMPLE: a-P/41693,MH2216,MH2221,MED,SOIL-HH2342Dl-UW-EPflCONDS.: «INSTRUMEHT-04A5» EPA CLP METHOO <UOLATILES)
ENHANCED SPECTRUM <S 156 IN OT)
RAM SPECTRUM
C935 ACETONE
BASEM/El 43/RIC: 274./
33 40 45 50-I—55
DATA: HMa34ZDl »403C110 2-BUTANONE^NHANCED SPECTRUM HATCH
RELATIVE INTENSITY (X)MASS LIBRARY SAMPLE33 26 0 PEAK NOT IN SAMPLE37 14 0 PEAK NOT IN SAMPLE43 100 10072 16 10
000086
RAW SPECTRUM MATCHRELATIVE INTENSITY (X)
MASS LIBRARY SAMPLE33 26 937 14 743 100 10072 16 12
03217843
£ 6 £ 1 7 Z O
I.T. ANALYTICAL SERVICES TRIPLE MASS SPECTRUM DATAt HH2342D1 «48307/27/88 13;57;BB + 13i26 CALIi CAL948788 #13SAMPLE! aP/41695,MH2216,W2221,MED-SOIL,W23420LWA,EPftCONDS.i «INSTRUMENT-OMA5» EPA CLP METHOD <VOLATILES)ENHANCED SPECTRUM <S 15B IN V\)
BASE M/Ei 43/RICi 769./
-1————rRAM SPECTRUM
-LLC4.H8.0 Clie 2-BUTflNONE
i ' 1 1 I ' 1 ' l ' I ' 148 59 6 8 / 7 9 88 90 188 /
DATA: HH2342D1 tt336C16S BENZENE
/CHANCED SPECTRUM MATCH
RELATIVE INTENSITY <X)MASS LIBRARY SAMPLE
39 10 0 PEAK NOT IN SAMPLE30 17 0 PEAK NOT IN SAMPLE51 19 2032 SO 2477 19 2378 100 100
RAW SPECTRUM MATCH
RELATIVE INTENSITY <X)MASS LIBRARY SAMPLE
oooosb
39505152777S
1017182019100
16IS172322100
03217845
S 6 : 17 3 0
I.T. (WLYTICAL SERVICES TRIPUE MASS SPECTRUM WTAi HH2342D1 »55687/27/88 l3l37i99 + 18)32 CftLIt CflL04e788 »l3SAMPLEl CLP,41695,MH2216,MH2221,MED,SOIL,HH2342Dl,UOA.EPftCONDS.; »INSTRUMENT-OW>5» EPA CLP METHOD (UOLATILES)
ENHAHCED SPECTRUM (S 1SB IN 0T)
RfU SPECTRUM
C165 BENZENE
BftSE K/Et 78/ 78 ^RICi 1733./ 3251. y
48 59 60 70 80
DATA: HH2342D1 #637C205 4-METHYL-2-PENTANONE/ HANCED SPECTRUM MATCH
RELATIVE INTENSITY ( X )MASS LIBRARY SAMPLE39 12 1441 22 33 OUT OF 20X RANGE43 100 10057 17 32 OUT OF 20X RANGESB 32 3 OUT OF 20X RANGES3 10 0 PEAK NOT IN SAMPLE
000090
RAW SPECTRUM MATCHRELATIVE INTENSITY <X)
MASS LIBRARY SAMPLE39 12 2341 22 Sl OUT OF 20X RANGE43 100 10057 17 4S OUT OF 20X RANGE58 32 0 PEAK NOT IN SAMPLE83 10 0 PEAK NOT IN SAMPLE
03217847
L6£ f r g O
I.T. ANALYTICAL SERVICES TRIPLE MASS SPECTRUM OATAt HH2342D1 K5707/27/88 13;57»90 + 21:54 CALIl CAL948788 •13SAMPLE: CLP-41695,HH2216,MH2221,MED,SOIL,HH234201,UOA-EPACONDS.; «INSTRUMENT-OMftS» EPft CLP METHOD (UOUffILES)ENHANCED SPECTRUM (S 13B IN 9T)
BASE H/E« 43''RICi 2851./
RAM SPECTRUM
-I———»-C295 4-METHYL-2-PEMTANONE
49 58i
ee 7 9 / 8 8 9e iee lie 129 /
DATA: HH2342DX »73AC330 TOLUENE */-ENHANCED SPECTRUM MATCH
RELATIVE INTENSITY (X)MASS LIBRARY SAMPLE39 16 0 PEAK NOT IN SAMPLE69 13 1191 100 10092 98 97
RAM SPECTRUM MATCHRELATIVE INTENSITY (%)
MASS LIBRARY SAMPLE39 16 139 OUT OF 20X RANGE63 13 1991 100 10092 98 97
000092
6 6 £ 17 Z 0
I.T. ANALYTICAL SERVICES TRIPLE MASS SPECTRUM DATAi HH2342D1 »756Q7/27/9S 13857:ee + 25s12 CALIt CAL048788 •l3SAMPLE: CLP,41695,MH2216,MH2221,MED,SOIL,HH2342D1.VW>,EPAKINDS.; »INSTRUMEHT-OHA5» EPft CLP METHOO (VOLATILES)
ENHflNCED SPECTRUM (S 15B IN ST)
RAM SPECTRUM
1——!•'C238 TOLUENE »
BASE M^s 91/ 43RICi 3583./ 55231.
58 198 c
DATA: HHS342D1 tt7B?C235 CHLOROBEN2ENE
^-^•HANCED SPECTRUM MATCH
RELATIVE INTENSITY (X)MASS LIBRARY SAMPLE39 15 1650 24 2651 24 2477 63 66
1 1 2 100 1001 1 4 34 36
000094
00<=?<3-CM0
03217851
1 . 0 1 7 t 7 S O
I.T. ANALYTICAL SERVICES TRIPLE MASS SPECTRUM DATAl HH2342DI »78987/27/88 13857:08 + 26il8 CALI: CftLBWSB »13SAMPLEl CLP,41695,MH2216,MH2221,1®,SOIUHH2342D1,WA-EPACONDS.i tINSTRUfCNT-OMAS* EPA CLP METHOD (UOLATILES)
ENHANCED SPECTRUM (S 15B IN eT)
BASE M/Es 112/ 112 ^RIC: 17535./ 58879.^
S
i •i"' i •ri iRAH SPECTRUM
T-r-
' • I IC6.H5.CL C235 CHLOROBENZENE
,,1, ,. J" i ' l ' i ' i ? i i i i i i i i i i i i ' i ' i ' 1 1 1 1 1 i i i i ' i • i i i ' i ' i '58 108 / '58 288 258 /
DATA: HHZ34ZD1 •847C240 ETHYL BENZENE «^-MHANCED SPECTRUM MATCH
RELATIVE INTENSITY (%)MASS LIBRARY SAMPLE39 13 0 PEAK NOT IN SAMPLESl 12 1191 100 100106 32 32
000096
RAH SPECTRUM MATCHRELATIVE INTENSITY (X)
MASS LIBRARY SAMPLE39 19 48 OUT OF 20X RANQE31 12 1891 100 100106 33 32
03217653
£ 0 17 1 7 3 0
r-CT000046.2-)
23.1-
I.T. ANALYTICAL <07/27/88 13;S7i«SAMPLE: CLP,4169;CONDS.i tINSTRIMENHANCED SPECTRUt
,L , 1 . IL1 1 1 |" l 1 ' 1 l ' 1 ! " ) " 1 '1 i 1 i I i I i I i I i | i I i I i I i I r i i | i | i | i | i i i | i | i |
SERVICES TRIPLE MASS SPECTRUM DATA: HH234201 «847 WSE M/E» 91/B + 28il4 CALIi CAL048788 •13 RIC; 4903./5,MH2216,MH2221-MED,SOIL,HH2342D1-UOA-EPAENT-OMASt EPA CLP tCTHOO (UOLATILES)M (S 15B IN 0T>
<3 §38527. §§
- 2269.
RAM SPECTRUM
C240 ETHYL BENZENE «
. ll , , i . ,li . .—u58 188 'c 288 258
DATA: MM2342D1 »W6C290 TOTAL XYLENES
^JHANCED SPECTRUM MATCH
RELATIVE INTENSITY < X >MASS LIBRARY SAMPLELIBRARY BASE PEAK NOT IN SAMPLE
RAW SPECTRUM MATCHRELATIVE INTENSITY ( X )
MASS LIBRARY SAMPLE39 25 12S OUT OF 20X RANGE91 13 2177 12 2S91 100 100103 18 32106 46 43
C; 0 t7 1 7 3 001
0 I.T. ANALYTICAL SERVICES TRIPLE N0 97/27/88 13i57i90 + 33«120 SAMPLES CLP,41695.MH2216,MH2221<M'=> CONDS.s *INSTRUMENT-OMA» EPA
29.9-
14.5-
199.9-
59.9-
C8.H18
M/E /
ENHANCED SPECTRUM (S.15B IN 9T)
1 1 '| ' 1 ' ' 1 ' 1 i i | i 1 i 1 i 1 i 1 i | > 1 < 1 > 1 > 1 > ) > 1 i 1 i 1 i 1 ' ' 1 ' 1 ' 1RAM SPECTRUM
J—l i '—| i I i I i | i |—i | i | i | i | i ) i | i | i | i—|1 i | i | i | i | i | i | i—| i | i—| i i—
» C259 TOTAL }<YLENES
, l . | i , I ' l i59
1 , , i \ 1
hi i 1
JiLL
•w. i .199
.H. i tl . .,
!„ ,
i i i i i i i i 1 i i i i i i i i i 1 i i i i i i i i i i i i15T 299 259
IASS SPECTRUM DATA: HH234201 •996 WCALI: CAL949788 »13 R1C
ETLSOIL,HH234201-UOA,EPACLP METHOD (UOLATILES)
. 1 . - . . 1 . .1.
WtrtESf»SE M/E; 282/ 43 ;-,
C: 1571./ 22655. txC'3c
1
,
1 1 1
C
556.
r 1929.
-
i-
•
DATA: HH23420I (»969C232 M-XYLENE^-SHANCED SPECTRUM MATCH
RELATIVE INTENSITY (X)MASS LIBRARY SAMPLE39 12 0 PEAK NOT IN SAMPLE91 100 100103 20 0 PEAK NOT IN SAMPLE106 92 36
000100
RAM SPECTRUM MATCHRELATIVE INTENSITY (X »
MASS LIBRARY SAMPLE39 12 113 OUT OF 20X RANGE91 100 100105 20 19106 32 34
^00• f•st(M0
03217857
L 0 fr ^ 3 0
I.T. ANALYTICAL SERVICES TRIPLE MASS SPECTRUM DATA: HH2342D1 «96907/27/88 13;57-.ee + 32(18 CALIi CAL04e788 »l3SAMPLE! a-P-41G95,MH2216,MH2221,MED,SOIL-HH2342Dl,UOA-EPftCONDS.! XINSTRUMENT-OUA5* EPA CLP METHOD <UOLATILES)
ENHANCED SPECTRUM <S 1SB IN 9T)
BASE M : 91/ 43CH3C. WC.. 3lf IJ MRIC; 1421./ 22943. 8
0
•l | l -TTRAM SPECTRUM
1| ^jit, ,l.|l^,ll(,l,L|J.,^L,pf,
C252 M-XYLENEC252 M-XYLENEl | i—i—i—i—i"
• ^ l |"» 1^1 1 .^ . ' I 1 . | •50 188 17" 299 250 /
FILE HH2342D1 PEAK HEIOHTS AND COMPUTED AMOUNTS BY SCAN NUMBER:
M LIMIT SET AT 3.0 UNITSUSE ALL PEAKS FOR LIBRARY SEARCH
000102
30863378460262S69069671279376176779481484389B909
23032. 447416. 379339. 96006.7
61932.01930S. 622933. 119343.6
103331.020032.021216. 031840.047334. 991233. 6
149999. 0107007.0
30. 030. 030.06. 3^ ^ T(0 v
63.320. 324. 2 >/•' •=• ?tt>t s
9. 7-' E
63.2-^ =12.613. 432. 729.937. 394. 367.4
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03217859
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0 ^ 17 172 0'3'0 LIBRARY SEARCH^ 07/27/88 13:57:88 + 20:560 SAMPLEi CLP,41695,MH2216,MH2221-MED,SOIL,HH2342Dl,UOft,EPA NS CONDS.; tINSTRUMEMT-OHftSl! EPA CLP METHOD (UOLATILES) "~ ENHANCED <S 15B IN BT) - e
1879 iSAMPLE
1
«•(DATAt HH2342D1 • 628 BASE M/Ei 55 2CALIt CALe40788 • 13 RIC: 52863. ^
1 . . . , , , , , , . , 1CAS • 198-87-2
2-PENTEHE,3.4-DIMETHYL--(Z)- CAS • 4914-91-4
2-PENTENE, 3» 4-DHCTHYL-, <E)- CAS « 4914-92-5
M/E 48 58 68 78 98 18
^ L t7 1 7 3 0
LIBRARY SEARCH DATA: HH2342DI » 690 BASE M/El S597/27/88 13:57:00 + 23(08 CALIi CAL040768 » 13 RIC; 19543.SAMPLEl CLP,41695,HH2216,MH2221,MED,SOIL,HH234201,WA-EPACOWS.: tINSTRUMENT-OMASt EPA CLP METHOD (UOLATILES)ENHANCED <5 15B 1H 07)
CYCLOHEXANE,1-ETHYL-2-METHYL-,TRANS- CAS » 4923-78-8
CYCLOHEXANE, 1-ETHYL-2-»CTHYL-,CIS- CAS « 4923-77-7
CYCLOHEXANE,1,4-OIMETHYL-,CIS- CAS • 624-29-3
-T--58 70 80 90 108 110
S i . t7 1/30
LIBRARY SEARCH DATA) HH2342D1 » 696 BASE ll/Ci 4397^7/88 13i57l0e + 23:12 CALI: CAL049788 » 13 RIC: 15695.SAMPLEl a-P,41695,MH2216,»<H2221,MED,SOIL-W234201-UOA,EPACONDS.i tINSTRUCNT-OUAS* EPA CLP METHOD (UOLATILES)ENHWCEO (S 15B IN OT)
CAS • 589-34-4
HEPTANE CAS « 142-82-5
PENTANE,2,3,4-TRIMETHYL- CAS * 565-75-3
58 79 99 199 119
LIBRARY SEARCH DATAl HH2342D1 • 712 BASE M/E: 4307/27/88 13:57:00 + 23:44 CALIt CAL84e788 » 13 RIC: 13023.SAMPLE: CLP/41695,1»12216/UH2221.1CLSOIL,W2342D1.WI-EPACONDS.: «INSTRUHEHT-OMA5« EPA CLP HETHOO <UOLATILES>ENHANCED <S 15B IN 8T)
CAS » 591-76-4
CAS» IB&-08-7
HEPTANE, 3-METHYL- CAS » 589-81-1
68 80 198 129 146 169
t? I- t7 1 7 2 0
LIBRARY SEARCH DATAl HH2342D1 • 752 BASE M/E; 4397/27/88 l3:57»88 + 25:04 CALIl CftLMe788 • 13 RIC; 85375.SAMPLE; CLP-4169S,MH2216,MH2221,MED,SOIL,ttC342DLUOA,EPACONDS.; XINSTRUMENT-OHflSt EM CLP METHOD (UOLATILES)EHHAHCED (S 1SB 1H OT)
HEPTANE CftS » 142-82-5
3-HEXAMOME CAS » 589-38-8
C6.H12.0 3-PENTftNONE,2-»CTHYL- CAS » 565-C9-5H M T31B
H/E 50 1(
Ili •I
J-i8 158 288 258
C I
Oi0 LIBRARY SEARCH DATAl HH2342DI • 761 BASE H^Ei 79T-' 97--27/88 13:57:99 + 25:22 CftLI; CAL949788 • 13 RIC: 9439.0 SAMPLE: CLP/4:l695-MH22l6<m222LMED/SOIL,HH23420HW,EPA0 COUDS.: »INSTRUMEHT-OHft5» EPA CLP METHOO (UOLrtTILES)-' ENHANCED <S 15B 1H 8?)
18061SlWtE
C8.H18
fl^R2??!
X.H16
SS^IMNR ^^^
C8.H16
11/-E
C
-i—*-
^CyCLOPENT»C,l,2,4-TRIMETWL-,
CYCLOPENTflNE,1/2,4-TRIMETHYL-,
49 68 88
PENTflNE.3-ETHYl
^ I L — — — ^ ^ -
L-2-METHYL-
l
CflS • 699-26-7
<l.ALPHft.,2.ALPHA.,4.BETA.)- CftS • 4858-28-6
<l.ftl-PHA.,2.BETft.,4.ftUW.)- CAS » 16883-48-9
199 128 149
G C
9 H7 f r 2 0
0 LIBRARY SEARCH DATA: HH2342D1 * 757 BASE M/E: 57 ?.T- 87/27/88 13i57iee + 25:34 CALIl CAL94B788 « 13 RIC: 14447. ^.T^ S«PL£! a-P,41695,MH2216-MH2221,MED,SOIL,HH2342Dl-UOA,EPA ^0 CONDS.i «INSTRUMEHT-OMA5» EPft CLP METHOD (UOLATILES) 0CT EHHANCED <S 158 IN 8T)
ieeeiSAMPLE
Cie.H20 CYCLOHEXANE,<1,1-OIMETHYLETHYL)- CAS • 3178-22-1M MT1?®B JJf 1
PUR S§7
;7.H14
^'1]IN 944PUR 684
C8.H16MMT1?^
If1!M^
(- L C
LI . . 1
LJ
1-HD<ENE,3.4-OIMETWL- CAS » 16745-94-1
50 180 150 2ee 259
. „ 1
———————————————————————————————l-PEHTENE<4,4-DIfCTWL- CAS » 762-62-S
-ii 1.
}
L t- 17 17 S O
000
LIBRARY SEARCH DATAi HH2342D1 « 794 BASE M/Cs 9787/27/88 13:57;80 + 26:28 CALIi CAL848788 • 13 RIC: 38399.SAMPLE; CLP-41695-UH2216,MH2221-MED,SOIL,HH2342DLIX)A,EPACOWS.t XINSTRlMENT-OUASt EPA CLP METHOD (UOLATILES)ENHANCED (S 1SB IN 9T)
10001SAMPLE
C9.H18 CYCLOHEXANE,l-ETHYL-2-»CTHyL-,TRAN5- CAS » 4923-78-8
DuJK 1T M - W WAn •VQ£.fPUR 915
3.H18
C9.H18
M/E
L
L
50 108 158 298 258
1 ,.1, .. .CYCLOHEXAI
, ,nl| . , 1 . , .1CTCLOHEXAI
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HE,l-ETH]n--2• CTlffL-.CIS- CAS • 4923-77-7
lNE/1-EWL-1-11ETHYL- CAS • 4926-98-3
l i
0001
12
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LIBRARY SEARCH DATAi HH234201 « 842 BASE H/E; 4397/27/88 13f57s88 + 28:04 CftLIi CflLe48788 • 13 RICs 71679.SAMPLE: CLP,41695,MH2216,MH2221-MED,SOIL,HH2342Dl.UOft,EPACONDS.; <INSTRUMENT-OMft5» EPA CLP nETHOO (WLATILES)ENHANCED <S 156 IN 0T)
CAS • S89-81-1
CAS» 583-48-2
BUTANE, 2,2,3-TRIHETNYL- CAS» 464-86-2
168 158•—i—'288 258
C
02 t7 1 7 3 0
LIBRARY SEARCH DATA: HH2342D1 t 858 BASE M/-E: 4307/27-^8 13i57:W + 28:36 CALI; CALe48788 « 13 RICt 141567.SAMPLE: CLP, 41695. W2216-HH222L11ED, SOIL-HH2342D1,UOA,EPACONDS.: «INSTRUMENT-OMA5» EPA CLP METHOD <WLATILES>ENHANCED <S 15B IN BT)
HEPTANE.2-ME7HYL- CAS • 592-27-8
CftS • 592-13-2
HEXANE, 4-ETHYL-2-HETHYL- CAS » 3874-75-7
180 158 288 258
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t-1
000
12S9iSWLE
C8.H18
•3.VBS
C8.H18H HT'm^ T[H 2989
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1
50 100 158 200 250c c
LIBRARY SEARCH DATfli HH2342D1 • 908 BASE M/E; 43 iE>07/27/88 13:57:08 + 30:16 CALI: CAL040788 « 13 RIC: 87167. ^SAWLE; CLP,41695-MH2216,KC221,MED,SOIL,HH2342Dl-UOA,EPfl SCONDS. f tINSTRUMENT-OMS* EPA CLP METHOD (VOLATILES) 0ENHANCED <S 15B IN OT)
-. . I'l . • ll • . •1———r———-————- - . • • • . - . — — — — — — — — — — . — — — — — . . . . . . .OCTANE CAS » 111-65-9
.. . i. . il,. ..1—, . . , . , . , . . . . . . . , . , . . . . . . . . . . . . . ,HEPTANE,2,4-OI»CTHYL- CAS • 2213-23-2
^-r-4lL——4l——J-.——,——,——,——,——,——,——,——,——,——,——,——,——,——,——,——,——,——HEXANE-3-ETH'rt-- CAS • 619-99-8
1.1 il ll
1AVOLATILE ORGAMICS ANALYSIS DATA SHE EPA SArtPLS NO.
Contract:Lab Naa«:_
Lab Codtt: Ca«« No.: iibqg SAS Ho.: SOG Ho.: tougzatoLab Sa«pr ID; ri*Z-»3Dl
l-to "!• ID: HH 23M^ft»oaf R«c«ivd: o7!g?.g3/a»
Oaf xnalyxad: ^7^7^a&Dilution ractor: 1___
Matrix: (•oil/vatT) .goii,
Safflpr wt/vol: ^ (a/»L) 6
L«v«l: (low/Md) M^P
» Moi«tur»: not d«e._$0__
Caluan: (pack/cap) ?flCfc
COMCDtTKATIOM UNITSt(ug/L or uq/Xa) ua, /ksCAS NO. COMPOUND
74-«3-9—————Bro»o—tha»r7B-01-4————vinyl Chloride7S-o»-2—————M*thyl«n« Chiorid*7S-13-0————Carbon Oiaulfid*7S-34-l————l.l-Oichloro«than»540-S9-0———1,2-Diehloro«ta«n« (^otal)67-«-3——————ChlorotOCTl07-os-2———l.2-0iehlero«taan»7«-93-3———2-Butanon«71-SS-6———1, l, l-Trichloro«tnan«B6-23-S——— carbon Tatraeolorid*101-05-4—————vinyl Aeataf7S-27-4————Bro»odichlero—tBan<7«-»7-s———i. 2-DicbloroeroDaJMlOO<l-Ol-5————ci«-1.3-DichiorBBrocw79-ol-<—————TricBloro»tb<n»l24-4«-l—»—«»Dihro«ocaioroMtaan«7»-oo-5-—•~—i.L.2«Tridiloro«taan«I00«l-02-«-~—tr«n«-l,3'6ickloroprofwn«73-2S-2-——————•MMfonl0«-lo-l———«-lltlwl-2-*»nfei»n<5»l-7»-<-————2-Ruunon*l27-n-4———T»tr«enloro»thw7»-34-5———i. l, a, 2«T*tr*ehler5SiEiMi10<-C-3—————Tolu«n«I0«-»0-7———a>lerobwi«i» ~ '100-41-4—————Cthvlb«n««n« ~100-42-5—————•tvrur1330-20-7— ———xylur Tioiali
(.ZOOfcZOOiizoo(??«»•SO&
32003t003(00ilftfi3/00?tM3(«9. ....
IStt*3»ofr
•?^——————flioo4iee————IJAA
»!<&
3l«tf?ioyZoeo
^6iite-.-,-feffi0 ....^———?'M . , , „ „.„^
3*o*oB300
aw ,zaoa
u——
^=
iMCM<=fc3-(M0
roxM z VOA 1/B7 R»v.
03217873
IEVOLATILE ORGANICS ANALYSIS DATA SHEET
TENTATIVELY IDENTIFIED COMPOUNDS n n I 1 ^
Lab Naur; )TO$- ^•Aio^mi.tfe- Contract;/TFX
,Lab Cod*: ;r^Tu Car Mo.: v^s SAS Ho.:-^Lab Cod*: IT S~l SOS Ko.: urigzat.
Lab Saapl* ID: t4H PSfPDI
Lab Fir 10s HH 23M3PI
Matrix: (aoil/wafr) soi^-
saapr vt/vol: ^ (a/aL) 6
L«v«l: (lov/B«d) |s\tp
» Moisture: not dec. 80
Column: (pack/cap) TOCC.
Daf Reeaivd: s-i^^lyf.
Oaf Analyrd: o^l^^ht
Dilution Factor: >____
EPA SA.'«?_£ •;•:
MuabT TIC» found: •go' ^1COHCtNTRATIOH UNITS:(U9/L or uq/Kg) m. /A-6
01
123456789
1011121314151617181920212223242S2627282930
^S NUMBER
iKir-lt-3W^-9/oa.8-».2
)&«6.M-7&.S- CT. 3^•».78.1t t w - w - s^fiSflQ-^sni ' - i i . -^f c t ' / . f t . S^l-»2-Sn^-EZ-lf6?6- 71.-C.i<Tr3-t9-»
;(>(.• ?(•»
?STH- fS -42 .?7 .SS(.u^.?l.7/tl-tS'-T«?lt--<•<?. Z
COMPOUND NAME
C-^lOPtinkUt, 1,?.1>IM(T»»V1-^,mm^ - -.C«^L6»fcXAA»t^t TittleC1ClflPtA»T»>*kii, » -Tt4>IL.VtutA^ , t.3-T>l»*»T»><L.T>(*JTk^t •S-tt t^L-<-«CL6HtxiAtA, iU.l>lM»T»>H,, C•D^fcAr , ^H-.TRlMt-TlUt.M«XAA16, t-Mt-THIt.(N£Lt«6Klt*)t., i,>t.T>mt*T»»'(«,- iU*-PTA^»» •
<SJ,LloK«aUt £l,l-niM*TH1l<TI»»t)kUtyit^t. l.-ri<TH^L-CM6LfcM^*Al* l-<Tl«l.£.1*r»WL-1-OCTAAtOt- <t.-I.-»IK*TM'«.-MtB-rAAi* •3 .M.*TMyL.M*»TAM*', t-M.tlfr<(l..Z-M&X6AIUK ,»,».T>llKtT»Hl. -a&TfcAltM<:l.oT»t*lTftAi6 )|l.3-"rlll*frtm^
\}H\^H»*iM C4LCCKC11.??
BTi<i.?r~to.OS?<>.<» ZI.&621.87»».73t-t.fttt»inZ3.-»324.S2Zff.to2&63tS.47?(;.4-»«-».«3^fl,<•?^t».<.ft??-873&.n3 1 , e e3?.l.o
EST. CONC.
9l*owoo
ZBOOOO«»•«fio&o&«66
74MO7200ttl6t^at^a
WtAAda7ttoao
ZlaooaX10066
(-76006J^O^ft« CO 600
,ifAa- ,1(20<>«>«rzao«b9ooo
Q
T
FORM I VOA-TIC 1/87 R»v.
03217874
1°
0001
18
292 §"
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w "8 (
l-S
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0321
7875
QUANTITATION REPORT PILE: HH2343D1 000119
DATA: HH2343D1.TIP=<27/88 14:48:00' PLE: CLP,41699,WH2216,MH2222,MED,SOIL,HH2343D1,VGA,EPACUND9. : *INSTRUMENT-OUA9* EPA CLP METHOD (VOLATILES)FORMULA: SOIL (1:123) INSTRUMENT: OWAB WEIOHT: 0.000SUBMITTED BY: ITFH ANALYST: WET ACCT.NO.: 41699AMOUNT-AREA » REP. AMNT/(REF.AREA)« RESP.FACT))DET. LIM.« 0.00RESP. FAC. FROM LIBRARY ENTRY
NO NAME1 CI01 BROMOCHLOROMETHANE (I.S.»1-CLP)2 CI10 1,4-DIPLUOROBENZENE (I.S.»2-CLP) m
(M«^r• l-(M0
3 CI20 CHLOROBENZENE-D9(I.S.W3-CLP)4 CS19 l.a-DICHLOROETHANE-D4 (S.S.ttI)9 CSOS TOLUENE-D8 (S.S.tt2)6 CS10 4-BROMOFLUOROBENZENE <S. S. »3)7 C010 CHLOROMETHANE •*8 CO IS BROMOMETHANEf C020 VINYL CHLORIDE »
10 C029 CHLORQETHANE11 C030 METHYLENE CHLORIDE12 C039 ACETONE13 C036 ACROLEIN14 C037 ACRYLONITRILE13 C040 CARBON DISULFIDE16 C04S 1,1-DICHLOROETHENE *17 C030 1,1-DICHLOROETHANE *•^ COB3 TRAN8-1.2-DICHLOROETHENE
/ C060 CHLOROFORM •20 C069 1.2-DICHLOROETHANE21 CI10 2-BUTANONE22 CH3 I, 1, 1-TRICHLOROETHANE23 C120 CARBON TETRACHLORIDE24 C12S VINYL ACETATE29 C130 BROMODICHLOROMETHANE26 C140 1,2-DICHLOROPROPANE »27 C143 CI8-1.3-DICHLOROPROPENE28 C1SO TRICHLOROETHENE29 C1SS DIBROMOCHLOROMETHANE30 C160 1,1,2-TRICHLOROETHANE31 C169 BENZENE32 C172 TRAN8-1.3-DICHLOROPROPENE33 C179 2-CHLOROETHYL VINYL ETHER34 C180 BROMOFORM **33 CS10 2-HEXANQNE36 C20B 4-MeTHYL-2-PENTANONE37 C220 TETRACHLOROETHENE38 C229 1,1,2.2-TETRACHLOROETHANE »«39 C230 TOLUENE «40 C239 CHLOROBENZENE41 C240 ETHYL BENZENE *42 C243 STYRENE^3 C2BO TOTAL XYLENES
f C292 M-XYLENE-,J C2S1 TRICHLOROFLUOROMETHANE
NO M/E SCAN TIME REF RRT METH AREA(HQHT) AMOUNT XTOT W^ 1,4^")B
rtT»-l i^cmc
000120NO
1~2
)496789
10It12131413161718192021222324232627
•"/
30313233343336373839404142434443
N012343
-6''~sd
-7/^
M/E12811411763989330946264844336337696639683627297
11743836373
13012997787363
1734343
1648392
112106104106106103
RET(L>10:21:26:13:23:30:
1:2:3:
SCAN TIME REF RRT METH308 10: 16 1 1 . 000633 21: 10 2 1. 000784 26:08 3 1.000
730 23:00 3 0. 9B7913 30:30 3 1. 167
402 13:24 2 0.633 A BB 464.222222
2333 18:30 2 0.874 A BB337 18:34 2 0. 877 A BB
2223
636 21:32 3 0.837 A W3
703 23:26 3 0.897 A BB733 23:10 3 0.963 A BB788 26:16 3 1.003 A VB847 28:14 3 1.080 A B B960 32:00 3 1.224 A BB
3970 32:20 3 1.237 A BB
141010120028343010
396 13:12 1 1.286
11
200 6: 40231 7: 42
2
1 '^t\l<»|8tRATIO RRT(L) RATIO1. 00 1. 0001. 00 1. 0001.00 1.0001. 00 1.2901.00 0.9331. 00 1. 164
0. 1330.2440. 309
0.649 A BB0.730 A BB
.00 30.00
.00 30. 00
. 00 30. 00
. 00 43. 08
. 00 48. 96
. 00 46. 23
BBBBBBBBBBBB
AMNT
AREA(HGHT)23829.
122094.114847.33192.72316.73763.
813.3477.
26.8703.
12734.
3017.164447.133396.13666.
33.
3367.
AMNT(L) R.30.00 1.30.00 1.30. 00 1.30. 00 1.30. 00 0.30. 00 0.30. 0030. 0030.00
AMOUNT30.30.30.43.48.46.
1.3.
2.
0.3.
4.
2.97.61.13.0.
4.
FAC000000000393630660
000000000079938230
1
« *
174116
372
030270
868
793649346216016
372
R . F A C < L >1.1.1.1.0.0.1.0.0.
UO/LUe/LUC/LUO/Lue/Lue/L
f
UO/LUO/L
UO/L
UO/Lue/L
UO/L
ue/LUO/Lue/LUO/LUO/L
ue/L
000000000349643713040864940
XTOT10. 2710. 2710. 279.26
10. 039. 30
(^(r)
si^ssi/-4 03 =-
>^0. 49 --
',orGi
- 0. 67 --
^-VG'JB-rr
1^20.03-^T2.64>>^^a. 71 ?-
,A-00
•"if 94=-
RATIO1. 001. 001.000. 90^0. 98 •"0.92
^6T
3 tOO-C\tr
• i-C\J0
iso aSew
ZJOOO- W-
(»|060t^wM-13AJ».
3*^"-*SP<^»MC
-ynrtv
03217877
000121NO RET(L) RATIO RRT<L) RATIO10 4: IS 0. 410
.^ 6:38 1.01 0.648 1.00. 7:32 1.02 0.736 1.02
13 7: 48 0. 76214 8: 38 0. 84413 8:28 0.82716 f: SO O. 96117 11:06 1.08918 12:02 1. 17619 12:24 1.21220 13:18 1.30021 13:22 1.00 0.631 1.0022 14:30 0.68923 14:94 0. 70424 19:22 0.72629 19:26 0.72926 16:96 0.80027 17: 14 0. 81428 17:92 0.84429 18: 16 0.86330 18:28 1.00 0.872 1.0031 18:32 1.00 0.876 1.0032 18:34 0. 87733 19: 44 0. 93234 21:00 0.99239 23:24 0. 89436 21:46 1.00 0.832 1.01f, 23:40 0. 904
_J 23:24 1.00 0.894 1.0039 29: 12 1. 00 0. 963 1. 0040 26:16 1.00 1.004 1.0041 28:14 1.00 1.079 1.0042 32:02 1.00 1.224 1.0043 33: 10 1. 26844 32:20 1.00 1.236 1.0049 8: 98 0. 876
AMNT AMNT(L) R.FAC R.FAC(L) RATIO90. 00 0. 674
1.17 90.00 0.034 1.497 0.029. 12 90. 00 0. 146 1. 426 0. 10
90. 00 0. 26290. 00 0. 69790. 00 3. 04790.00 1.14390. 00 2. 83290.00 1.39090. 00 2. 87090. 00 1.999
2.37 90.00 0.004 0.080 0.0990. 00 0. 44690.00 0.41990. 00 1. 246
r~-(M
90. 00 0. 986 ^90. 00 0. 449 ^1-64. 00 0. 922 0490. 00 0. 449 090. 00 0. 984
0.03 90.00 0.000 0.399 0. 003.27 90.00 0.071 1.090 0.07
36. 00 0. 44690. 00 0. 24090. 00 0. 98490. 00 0. 942
4.87 90.00 0.111 1.139 0.1090. 00 0. 449 >
2.79 90.00 0.044 0. 782 • 0. 0697.69 90.00 1.432 0.733 1.9961.99 90.00 1.162 0.944 1.2313.22 90.00 0.119 0.490 0.260. 02 90. 00 0. 000 0. 886 0. 00
90. 00 0. 9104.97 90.00 0.047 0.911 0.09
90. 00 1. 249
000122IT ANALYTICAL SERVICES
QA/QC REPORT' L E : HH2343D1
INTERNAL STANDARD AREA CHECK
3 OUT OF 3 ARE WITHIN BOX TO 200X OF DAILY STANDARD AREAS.
•» INTERNAL STANDARD AREAS ARE WITHIN QC LIMITS •*
INTERNAL STANDARD RETENTION TIME CHECK
'"""""""""'""""'""'"'"''""""""""""""""""'" C\J3 OUT OP 3 ARE WITHIN +/- 30 SECONDS OF DAILY STANDARD RETENTION TIME -^
•' a-** INTERNAL STANDARD RETENTION TIMES ARE WITHIN QC LIMITS •* (^J
0
7/27/88 14:49:14ACQUISITION STARTED
SCAN 1 OF 1020000123
RUN 0:HH2343D1 ACQUIRINGFREE SECTORS:16416 SCAN: 2 OF 1020
'UIREt<//27/88 14:48:00 + 0:04SAMPLE: CLP,41693.UH2216> MH2222< MED,SOU-,HH2343D1,VOA,EPACONDS.: »INSTRUMENT-OMAS» EPA CLP METHOD (VOLATILES)FORMULA: SOIL ( 1 : 1 2 9 ) INSTRUMENT: OWA9 WEIGHT: 0.000SUBMITTED BY: ITFK ANALYST: MET ACCT. NO.: 41693
LOM MASS:HIGH MASS:CENT S/P:FRA® S/P:
39300
UP:DOUN:
1. 9S L»0. 00 L
TOP:BOTTOM:
0. 000. OS
3720
ACTUAL:ACTUAL:
3719
SAMP INT (MS): 0.200SAMP INT (MS): 0. 400
MIN PEAK WIDTH: 1A/D THRESHOLD: 1MODE: CENTROID POSITIVE ION
MIN FRAG WIDTH X:BASELINE: 0
SO
PEAK WIDTH: 1000.INTEN/ION: 2MIN AREA: 25
INTERFACE NUMBER 0SUB-INTERFACE NUMBER 0tt OF ACQU BUFFERS 16INSTRUMENT TYPE QFULL SCALE MASS 800 AMUZERO SCALE MASS 1 AMUINTENSITY/ION 2PEAK WIDTH 1000. MMUOFFSET AT LOW MASS 0 MMUOFFSET AT HIGH MASS 0 MMUVOLTAGE SETTLING TIME(MS) 4
M.S. TUNE PARAMETERS:MULTIPLIER VOLTS: -2082.35LOW RESOLUTION: 127.00HIGH RESOLUTION: 126.00ION ENERGY: 3. 53ION PROGRAM: 5.96LENS VOLTAGE: -29. SOEXTRACTOR: 0. 94ELECTROMETER RANGE: 7. 00ELECTROMETER ZERO: 2-. 74
ACQUISITION STARTED WITH GC FILEGC PARAMETERS:230 DEC
50 DEC230 DEC
4 MIN8.0 D/M60 MIN
250 DEC90 DEC
INJ. MODE:1 SEC •
ZONE TEMP.INITIAL TEMP.FINAL TEMP.INITIAL TIMERAMP RATEFINAL TIMESEP. SET PT.MANIF. SET PT.
PKD• DV OPN
7/27/88 15:22:59ACQUISITION COMPLETEDSCANS 1 TO 1020 CENTROID
MODE SCANS^"^TROID 1020
SECS OUT OF X268.3 2040.0 13.2
PEAKS PER SCAN32568. 32.
PER SEC16.
IT Awn-vTrcrtL SCTVICES DIAOMOSTIC KCPOHT 7 fir/as 13:42:20DATA FILE:HH2343Dl 0REFERENCE: LIBRARYVE t\f\r\ln/l K-',
METHOD: V08T INITIALIZATION OPTION: 2 PROCESSING OPTION: 4 IIUU1^4REPORT; cLpissa •^r< ——— STANDARDS ———— X —— PLUS UNKNOWNS —— X - LIST NAMES - > ^
PROC USED POSS RMS PROC USED POSS RM8 STANDARD/UNKNOWN CM6 6 Z 37 43 B 1 64 CLPI088/CLPUNK8 Q
43 COMPOUNDS PROCESSED. S FOUND
< COMPOUND X ——-——————— SEARCH —————————— X SAT > < -———— CHRO —-——— ;NO LIB ENTRY REP PRED SEL DELTA PEAKS FIT PEAKS M/Z TOP DELTA PEAKS
1 VE 1 -306 308 300 . 2 791 . 128 30B . 12 VE 2 -633 635 639 . 1 994 . 114 639 . 13 VE 3 -7S1 7S4 7S4 . 1 908 . 117 784 . 14 V6 4 -394 397 397 . 1 979 . 63 396 -1 19 VE 9 -746 749 790 1 I 841 . 9 8 790 . I6 VE 6 -911 914 914 . 1 940 . 99 919 1 17 VE 7 -48 90 . . . . . 90 . . .S VE 8 -76 78 . . . . . 94 . . . -'9 VE 9 -97 99 . . . . . 62 . . .
10 VE 10 -128 131 . . . . . 64 .11 VE 11 -200 203 . . . . . 84 500 . 112 VE 12 -226 229 . . . . . 43 231 . 113 VE 13 -232 239 . . . . . 96 . . .14 VE 14 -299 298 . . . . . 93 . . .19 VE 19 -293 296 . . . . . 76 . . .
• VE 16 -293 296 . . . . . 96 . . .VE 17 -332 339 . . . . . 63 . . . . •
18 VE 18 -398 361 . . . . . 96 . . .19 VE 19 -371 374 . . . . . 83 . . .20 VE 20 -396 399 . . . . . 62 . . .21 VE 21 -398 401 . . . . . 7 2 402 . 122 VE 32 -433 436 . . . . . 97 . . .23 VE 23 -449 448 . . . . . 11724 VE 24 -498 461 . . . . . 43 . . .29 VE 89 -461 464 . . . . . 33 . . .26 VE 26 -906 909 . . . . . 63 . . .27 VE 27 -914 917 . . . . . 79 .28 VE 28 -933 936 . . . . . 130 . . .29 VE 29 -946 949 . . . . . 129 . . .30 VE 30 -992 999 . . . . . 97 999 . 131 VE 31 -995 339 336 1 1 936 . 78 337 1 132 VE 33 -894 937 . . . . . 79 . . .33 VE 33 -989 992 . . . . . 63 . . .34 VE 34 -628 631 . . . . . 173 . . .39 V6 39 -699 702 . . . . . 43 . . .36 VE 36 -690 693 . . . . . 43 696 . 137 VE 37 -708 711 . . . . . 164 .38 VE 38 -701 704 . . . . . 83 703 . 139 VE 39 -792 799 . . . . . 92 799 . 140 VE 40 -789 788 788 . 1 920 . 112 788 . 141 VE 41 -843 846 . . . . . 106 847 . 1
VE 42 -999 998 . . . . . 104 960 . 1-> VE 43 -989 993 . . . . . 106 . . . •
44 VE 44 -969 969 . . . . . 1 0 6 970 . 149 VE 46 -269 272 . . . . . 103
l.T. ANALYTICAL SERVICES finn-tOt; _LIBRARY SEARCH REPORT UUU1<;3
VOLATILE ORGANIC ANALYSIS ^-•»TA FILE; HH2343D1 <-i-
.LIBRATION FILE: CAL040788SEARCH OF LIBRARYVE ^
AMT FLAOSSCAN COMPOUND DELTA PUR-FIT < NO > SAT LIB CM
0308 CI01 BROnOCHLOROHETHANE (I.S.Hl-CLP) 0 980-998 30 0 0639 CI10 1,4-DIFLUOROBENZENE (I.S.»2-CLP) 0 909-967 SO 0 0784 CI20 CHLOROBENZENE-DSd. S. •3-CU°> O 8SS-933 30 0 0396 CS19 1.2-DICHLOROETHANE-04 < S . S . * 1 ) -I 944-98S 49 0 0790 C809 TOLUENE-OS (S. S. •;) 1 782-869 49 0 -3919 CS10 4-BROMOFLUOROBENZENE (B. S. *3) 1 814-903 46 0 -S200 C030 METHYLENE CHLORIDE -3 704-884 1 0 - 1231 C039 ACETONE 2 913-913 9 0 0402 C110 2-BUTANONE 1 632-709 2 0 - 2997 C169 BENZENE 2 078-897 3 0 - 1696 C209 4-METHYl--2-PENTANONe 3 462-993 -»-- 0 -3
/-^ 703 C229 !< 1.2, a-TETRACHLOROETHANE »• -1 S09-362 ^3-' 0 -9 -i799 CS30 TOLUENE » 0 698-949 98 0 078S C339 CHLOROBENZENE 0 938-972 62 0 - 1847 C240 ETHYL BENZENE * 1 902-969 13 0 -1970 CS98 M-XYL6NE 1 497-912 9 0 - 1
0321788Z
DATA: HH2343D1 •200C030 METHYLENE CHLORIDE^(HANGED SPECTRUM MATCH
RELATIVE INTENSITY (X)MASS LIBRARY SAMPLE36 12 0 PEAK NOT IN SAMPLE47 23 2349 100 10031 32 3684 68 3786 42 36
000126
RAM SPECTRUM MATCHRELATIVE INTENSITY <X)
MASS LIBRARY SAMPLE36 12 0 PEAK NOT IN SAMPLE47 22 2049 100 10031 32 1384 6B 6186 42 38
0321*7883
£ £ fr 17 2 0 . -i
I.T. ANALYTICAL SERVICES TRIPLE MftSS SPECTRUM MTfti HH234301 #28007/27/88 14:48l08 + 6 ( 4 0 CALI; CAL048788 »l3SAMPLE: CLP,41695,MH22l6,MH2222-MED,SOIL,HH234301,lW-EPACONDS.i »INS'raUHEMT-OW15» . EPft CLP METHOO (UOLATILES)
ENHANCED SPECTRUM <S 15B IN 0T)
RAM SPECTRUM
C930 (CTHYLENE CHLORIDE
48 50 70
BASE M/Ei 49/ 44RICi 794./ 1937.
DATA: HH2343D1 «231C035 ACETONE.ENHANCED SPECTRUM MATCH
RELATIVE INTENSITY <X»MASS LIBRARY SAMPLE43 100 100SB 16 19
000128
5 £ t7 f r Z O
I.T. ANALYTICAL SERVICES TRIPLE MASS SPECTRUM DATA: HH234301 »23i87/27/88 14:48:00 + 7(42 CALI; CALe48788 «13SAMPLE: CLP-4l695,MH2216,MH2222.MED,SOIL,HH23430LVOA-EPACOWS.: »INSTRUMENT-OHA3» EPA CLP METHOD (UOLATILES)ENHANCED SPECTRUM <S 1SB IN 8T)
RAM SPECTRUM
C035 ACETONE
BASE M/E: 43/ 44RICl 369. / 1395.
35 40 c 45 se 55 C
DATA: HH3343D1 «402C110 2-BUTANONEFINANCED SPECTRUM MATCH
RELATIVE INTENSITY <X>MASS LIBRARY SAMPLE35 26 0 PEAK NOT IN SAMPLE37 14 0 PEAK NOT IN SAMPLE43 100 10072 16 18
RAW SPECTRUM MATCHRELATIVE INTENSITY (X)
MASS LIBRARY SAMPLE3S 26 1137 14 1243 100 10072 16 14
000130
L £ V 17 3 0 ' • '
I.T. ANtt-'iTICflL SERVICES TRIPLE MASS SPECTRUM MTAl HH234301 1148297/27/88 14:48:96 + 13)24 CALI; CAL948788 «13SAMPLE! 0-P>41695,l«Z216-HH2222,MED.SOIL-HH234301,UOA,EPftCONDS.i «NSTRUMENT-OHflS» EPA CLP METHOD <IOLATILES)
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BASE M/E! 4»/ SS nRICi 74S./- 5151. ^
0
43.6-1
RAM SPECTRUM
58.9-
C4.H8.0 C118 2-fiUTAHOtE
M/E 58T"60 78
-I—98 198 c
DATA: HH2343D1 »997Cl&S BENZENE 000132
iNCED SPECTRUM MATCH
RELATIVE INTENSITY (X)MASS LIBRARY SAMPLE39 10 0 PEAK NOT IN SAMPLE50 17 2051 18 2252 20 2277 19 2278 100 100
RAM SPECTRUM MATCHRELATIVE INTENSITY <X)
MASS LIBRARY SAMPLE39 10 23BO 17 2091 IS 2192 20 2077 19 1978 100 100
6S: 1 7 1 7 2 0
I.T. WALYTICflL SERVICES TRIPLE MASS SPECTRUM DftTAl HH234301 »557 BASE H/El87/27/88 14t48:ee + 18l34 CALIl CAL&WSS «13 RICs 2815./SAMPLE: CLP,41695,HH22l6,MH2222.MED,SOIL,HH234301,UOft,EPflCONDS.i »INSTRUMENT-OHft5» EPft Ct-P HETHOO <UOLATtLES>
OVfWCED SPECTRUM <S 13B IN BT)
RAM SPECTRUM
C16S BENZENE
0
I78/78 N/ 4983. g
49 58 60 C 80 99 190
DATA: HH2343D1 tt636C209 4-METHYL-2-PENTANONE 000134
ENHANCED SPECTRUM HATCHRELATIVE INTENSITY <X)
MASS LIBRARY SAMPLE39 12 1241 22 S3 OUT OF 20X RANGE43 100 10097 17 56 OUT OF 20% RANGESB 32 0 PEAK NOT IN SAMPLE89 10 4
RAM SPECTRUM MATCHRELATIVE INTENSITY <X)
MASS LIBRARY SAMPLE39 12 2441 22 91 OUT OF 20X RANGE43 100 10097 17 99 OUT OF 20X RANGE98 32 2 OUT OF 20X RANGE89 10 3
03217891
[. 17 17 1 7 2 0
I.T. ANALYTICAL SERVICES TRIPLE MASS SPECTRUM DATA: HH234301 •65687/27/88 14:48:08 + 21:52 CALIi 01.940788 «13SAMPLEl CLP-41695,MH2216-HH2222>MEO-SOIL>W234301.UOft.EPflCONDS.: «INSTRUMENT-OMA5> EPA CLP METHOD (UOLATILES)
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|BASE M/Ei 43/ 43 f
RICi 7815./ 14879. ^P
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C2B5 4-METWL-2-PEHTAMONE
58 188 c
DATA: HH2343D1 #703C22S 1.1.2.2-TETRACHLOROETHANE
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RELATIVE INTENSITY <X)MASS LIBRARY SAMPLE
000136
6061S3859793
1011100641012
00
100000
PEAKPEAK
PEAKPEAKPEAK
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NOTNOTNOT
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RAW SPECTRUM MATCHRELATIVE INTENSITY <X)
MASS LIBRARY SAMPLE60 10 0 PEAK NOT IN SAMPLE61 11 0 PEAK NOT IN SAMPLES3 100 10085 64 2 OUT OF 20X RANGE87 10 0 PEAK NOT IN SAMPLE99 12 11
1^-COT-<
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I.T. WW-YTICTL SERVICES TRIPLE MASS SPECTRUM DftTA; HH234301 »79307/27/88 14(48:09 + 23:26 CALIt CftL84e788 •13SAMPLE! CLP,41695-MH2216,MH2222-MED,SOIL,HH234301,UOft,EPACONDS.l »INSTRUMEhn--OMft5« EM CLP METHOD (UOLftTILES)
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DATA: HH2343D1 #733C230 TOLUENE *
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RELATIVE INTENSITY (%)MASS LIBRARY SAMPLE39 16 2S63 13 1391 100 10092 38 61
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RAM SPECTRUM MATCHRELATIVE INTENSITY (X)
MASS LIBRARY SAMPLE38 19 1990 24 24S1 24 2277 69 99112 100 100114 34 29
000140
I.T. ANALYTICAL SERVICES TRIPLE MASS SPECTRUM DATAi HH234301 «78887/27/88 14!48l00 + 26tl6 CTLI: CALB40788 113SAHPLEi a-P,41695,MH2216-1^2222,MED,SOIL-»C34301,UOA,EPACONDS,; »INSTRUMENT-OHA5» EPA CLP HETHOO (UOLATILES)ENHANCED SPECTRUM <S 158 IN BT)
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RELATIVE INTENSITY <X)MASS LIBRARY SAMPLE39 13 0 PEAK NOT IN SAMPLE51 13 1091 100 100106 32 32
RAM SPECTRUM MATCHRELATIVE INTENSITY (X)
MASS LIBRARY SAMPLE39 13 41 OUT OF 20X RANOE31 12 1391 100 100106 32 32
000142
6 17 t7 1 7 ^ 0
I.T. ANALYTICAL SERVICES TRIPLE MASS SPECTRUM DATAl HH234301 «84787/27/88 14:48:00 + 28(14 CALI: CftLB48788 »13SMPLEl CLP>41695,MH2216,MH2222,MHLSOIL/W234301<UOA,EPACONDS.l (INSTRUMENT-GUAM; EPfl CLP METHOD (UOLATILES)
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DATA: HH2343D1 •970C252 M-XYLENE/••CHANGED SPECTRUM MATCH
RELATIVE INTENSITY <X)MASS LIBRARY SAMPLE39 1B 0 PEAK NOT IN SAMPLEft 100 100105 20 51106 32 51
RAM SPECTRUM MATCHRELATIVE INTENSITY <X)
MASS LIBRARY SAMPLE39 12 97 OUT OF 20X RANGE91 100 100105 20 27106 52 49
000144
^ I.T. ANALYTICAL SERVICES TRIPLE MASS SPECTRUM OATAi HH234301 •978 BASE M/El 91/ 43 f*0 07/27/88 14:48!0B + 32:20 CALIi CALe40788 •13 RIC; 2619./ 48783. »30 SAMPLE: a-P,41695,MH2216,MH2222,MED,SOIL,HH234301-UW,EPA ^0 CONDS.i »INSTRUMENT-OMA5« EPft CLP METHOD (UOLATILES) <5
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CAS » 617-78-7
PENTANE- 2.3,4-TRIMETHYL- CAS • 565-75-3
CAS • 584-94-1
c lee 120 148c
LIBRARY SEARCH DATftt HH234301 • 690 BASE M/Et 5507/27/88 14s48:ee + 23100 CALIi CflLWeTSS • 13 RIC: 33727.SlWLEi aP,41695,MH2216,W2222-HED/SOIL/HH234a)l,VOA,EMCOND5.8 «INSTRUMEMT-OMftS» EPft CLP METHOD <UOLATILES>ENHANCED <S 15B IN OT)
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DECAME,3,3,4-TRIMETHYL- CAS » 49622-18-6
PEMTANE, 2,3.4-TRI11ETHYL- CAS « 565-75-3
CAS • 589-53-7
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1-OOOECENE CAS * 112-41-4
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, , 1 , , , > , 1 , , „ , , , , , , , , , , , , , , , , , , , , , , , , ,1-OCTANOU2-BUTYL- CAS # 3913-02-8
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HEPTANE.2-6-DI METHYL- CA5 # 1072-05-5
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£ L 17 17 3 0 "•
DATA; HH2343D1 #1608 BASE M/-E: 4306 + 33:36 CALIs CAL040788 # 13 RIC; 65887.95- MH2216, MH2222< MED- SOIL, HH2343C1, UOA, EPA
JWNT-OMA5» EPA CLP METHOD (UOLATILES)
c- so^VJSS')-; ^7000* ' / ' • tf'
..1- -J 1 ^. - . . . - .
(.133 158 288 258 c
XA ePA SAMPLE NO.VOLATILE ORCANICS ANALYSIS DATA SHEfl»()0168
Lab Haa«:.Lab Coda:
contracts,
Ca«« NO.! ^Ke SAS Ho.: SDG No.: touggoto
Matrix: Coil/wfr) .Son,
Saapr wt/vol: ^ (g/»L) _
L«V«1: (1OW/Dttd) M£t>
t Moi«tur«; not d«e. g"1
Colunn: (pack/cap) 'pack
CAS NO. COMPOUND
Lab Saapl* ID:Lab ril« ID:Data Racaivad:Data Analysed:Dilution ractor:
CONCINTRATION UNITSt(u»/L or uq/Kq) of, /ka
74-B7-1 74-«3-
1 75-01-| 73-00-
1 7S-0»-| <7-<4-
73-15-7S-3S-7S-34-540-59<7-«-107-067B-93-71-55-5<-23-lOt-0575-27-7«-a7-100«1-7»-0l-124-4C79-00-71-41-100«1-<75-2S-310C-10-591-7B-w-u-7»-34-!101-««<10<-»0-100-41-100-42-1330-2(
———M<thyl«n» Chloride
———l.l-Dlchloreethtr————1,1-Dicnloroethan*o———i,3-Diebloro«fth«n« Kio€«l)
———2-Butanen» ,—————1.1.1-Triehloroecnan*4———vinyl Acataf—————1.2-Diehloroeropanal-5———er-l. 3-DicnioroproD«rl—————DihrimphlQrQMthaM-—————I, l,2-Triealoro«tb*JMl2-«'~~-~tnwl,3-6iehloropropwt-..-.....teo tena 1-l—————4->tethvl-i-»Mtanon«•A « » B^B » »« 4 ttAW ——J——k^
———————————————^^^^^^^~———————-^———————————————————————————————^^^
-4———TttracBlore»th»n»
-3 —————TolUtf-7—————caierBb*na«ir-4—————ltBylB«»««ii«-5———Btyr«»t-7————Xylir (total i
Woo(,0.
^00<»too«S»o
-»-?aa-i&se........ .ItO<<f»00Hfcfle«f»00ifaoo
, . ,—SSffa..Ifceo^«00
Tt^»<»4<,oo4800^eao4to00«BOAft^
3ZOOO4800
..!LS2S——————W<»w4^^too
^?oo^•leo-a
50100-75———^———
1700
Ll
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032V79SS
IEVOLATILE ORGANICS ANALYSIS DATA SHEET
TENTATIVELY IDENTIFIED COMPOUNDS n r» n < n nContract;_______
EPA SA.'<?_S ;;C.
I ~1 ^ 14 Z 2 2 f
SAS Ho.: _____ SDC Ho.: uHeax.Lab sanpl* ID: H H 2?^ p i
Lab File ID: H H Z?'-iMbi
Lab Wanr: )TPS- K^Q^M.L^/TF)<
Caxa NO. ; w^e^Lab Code: J - T ^ T UMatrix: faoil/wafr) soi^-
sanpla wt/vol: f (o/nL) 6
L«vl: (low/mad) i^tp Data Racaivd: a-7/g;»,z?^g8
Dat« Analyzad: enlt-ilf^Dilution Factor; |___
\ Moistura: not dac._°^JL-Column: (pack/cap) •phcv.
CONCZNTRATION UNITS:(ug/L or uq/Kq) ufc /A-fr
ir>,
^r<=3-|CM
NuabT TXC* found: _^S[_IS ^f^rf
CAS mnazBi23456789
101112131415161718192021222324252627282930
ll& .C»-3(»fi-»7:e-V-?2?-7B-»s-eq-31-f^ 1 - • ? & - • <f ca f r -oM-o111-^7-a(.01- Zt-l3t-7ft.12.-lI t t . -ZI - g3&Ti-l.t.-3SSO-f i l - lsi i -z-y-al«.o-7-<»3-0(.
COMPOUND NAME
H^^frCM<iunKl,»**-fr ,«<<.<•-r«fl.-C^l-OttfrXAAJ*-, l-ft+YL-Z.lHfrTHtl,H-t^e ,S-M;«'TII-VL-HfcXa^.-Z-lK.frTI+Wt-C.fCLOHfclfltAl^ >i»-t»ft<fr»ll;a<HK,PT»*J6.P6JJTft*;<- . 3.feTHV.-.1-it«,TMVL.£MCiai+*x*wt., (LI, i- Dim <>-»»«.» ~1-OCtAAJOi. 'S,7. DiX-.H-t^'/t.
csciAtt&M*Jfr, 1 .1 .3 .1 (n.<fri+»i-l+t-T>TftAJfr,?.'|UtTlHU(+frVTA-U&,->-n*«--nf«l-V«t>^»om< ( PiMfenw c»ey»t*J(»Ait-'
C^ctow»*t-<.6^ l,3-P<Mt-tllfl-,rAl^-
RT
20.6 . ^o,*??^7.<n
Z3.1(.Zt.-l B
Z«<.fio2<.»2^•?-'2f?221. (oZ7.C3ZO.OOZ-t.6315.^•at. ie
BST. COKC.?lti-
?0000/ 1000(qOOC.(2.000
7?^^?ff?0 ,Zzoob«.-Z.ouoS&ooo2.1000
^tto oo o<fcOOOB
60000feoooo
Q
"^—73
^
TOWl I VOA-TIC 1/87 Rav.
03217926
ee'ez ees^ .W'9eez
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£I» Q6WVKO TWO 9e*Zfi!fiT 88/2Z//0
8£Z
9Z8T 01 88 SNU3S3ia024476
QUANTITATION REPORT FILE: HH2344DI 000171
DATA: HH2344DI.TI0.^27/88 13:92:00' IPLE: CLP,41693,MH221&.WH2224.MED.SOIL,HH2344DI,VOA.EPAC.UNDS.: •IN8TRUMENT-OMA&* EPA CLP METHOD (VOLATILES)FORMULA: SOIL (1:128> INSTRUMENT: OMA9 WEIOHT: 0.000SUBMITTED BY: ITFK ANALYST: WET A C C T . N O . : 41693AMOUNT-AREA * REF.AMNT/(REF.AREA)* RESP.FACT)lDET. LIM. - 0. 00RESP. FAC. FROM LIBRARY ENTRYNO NAME1 CI01 BROMOCHLOROMETHANE <I.S.#1-CLP>2 CI10 1,4-DIFLUOROBENZENE (I.S.»2-CLP)3 CI20 CHLOROBENZENE-DSd.S.»3-CLP) r~-
r-«^'<OJ0
4 C819 1.2-DICHLOROETHANE-D4 ( S . 8 . « 1 )9 CSOS TOLUENE-OS (8 . S . • 2 )6 CS10 4-BROMOFLUOROBENZENE ( S . S . »3)7 C010 CHLOROMETHANE «*S COIS BROMOMETHANE9 C020 VINYL CHLORIDE •10 C02S CHLOROETHANE11 C030 METHYLENE CHLORIDE12 0033 ACETONE13 C036 ACROLEIN14 C037 ACRYLONITRILE19 C040 CARBON DISULFIDE16 C049 1,1-DICHLOROETHENE •17 C030 1.1-DICHLOROETHANE »*y^ COS3 TRAN8-1.2-DICHLOROETH6NE
C060 CHLOROFORM •20 C06S 1,2-DICHLOROETHANE21 CI10 2-BUTANONE22 C119 1.I,I-TRICHLOROETHANE23 C120 CARBON TETRACHLORIOE24 C12S VINYL ACETATE23 C130 BROMODICHLOROMETHANE26 C140 1,2-DICHLOROPROPANE •27 C143 CIS-1,3-DICHLOROPROPENE28 C130 TRICHLOROETHENE29 C199 DIBROMOCHLOROMETHANE30 C160 1,1,2-TRICHLOROETHANE31 C169 BENZENE32 C172 TRAN8-1.3-DICHLOROPROPENE33 C17S 2-CHLOROETHYL VINYL ETHER34 C180 BROHOFORM —39 C210 2-HEXANONE36 C20S 4-METHYL-2-PENTANONE37 C220 TETRACHLOROETHENE38 C225 1,1.2.2-TETRACHLOROETHANE **39 C230 TOLUENE •40 C239 CHLOROBENZENE41 C240 ETHYL BENZENE *42 C249 8TYRENE43 C2BO TOTAL XYLENE8
r ' - C2S2 M-XYLENE.-> C2S1 TRICHLOROFLUOROMETHANENO M/E 8CAN TIME REF RRT METH AREA(HOHT) AMOUNT XTOT \^el|5L<
03217928
8 L t? t7 2 0
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3^ 3888888888
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RET(L)4: 126:387:327:488:388:289: SO
11:0612:0212:2413: 1813:2214:3014:3413:2213:2616:3617: 1417: 3218: 1618:2818:3218:3419:4421:0023:2421:4623:4023:2423: 1226: 1628: 1432:0233: 1032:20
8: 38
RATIO R R T ( L >0.410
1.00 0.6481.01 0.736
0. 7620. 844
1.00 0.8270. 9611.0891. 1761. 2121. 300
1.00 0.6310. 6830. 704
1.00 0.7260. 7290. 8000.8140. 8440.8630.872
1.00 0.8761.00 0.877
0. 9320. 9920.894
1.00 0.8320.904
1. 00 0. 8941. 00 0. 9631. 001. 001. 001. 001. 00
0. 876
. 004
. 079
.224
. 268
. 236
RATIO
1. 001. 01
1.01
1. 00
1.00
1.001. 00
1. 00
1. 001.001.001.001.001.001.00
AMNT
1. 328. 00
0. 04
2. 93
0. 03
33.871. 27
2. 43
0. 964. 72
38. 893. 180. 172. 172. 74
AMNT(L)30.0030. 0030. 0030. 0030.0030.0030.0030. 0030. 0030.0030.0030. 0050. 0030.0030. 0030. 0030.0064. 0030. 0030.0030.0090.0036.0030.0030.0030. 0090. 0090.0030.0030.0090.0090.0090.0090. 0030. 0030. 00
R.FAC f
0. 0440. 228
0.003
0.003
0. 001
0.7380. 016
0. 096
0. 0130. 0691. 1110. 0470. 0030. 0220. 028
C» . F A C ( L )
0. 6741.4371. 4260. 2620. 6373.0471. 1432. 8321. 3302. 8701. 9390. 0800. 4460.4191.2460. 3860.4430. 3220. 4490. 3840.3391.0900. 4460. 2400. 3840. 9421. 1390.4490. 7820. 7330. 9440.4300. 8860. 3100. 9111.249
)00173RATIO
0.030. 16
0.00
0. 06
0, 00
0.680.04
0.09
• 0. 020. 091. 180. 100. 000. 040.03
000174IT ANALYTICAL SERVICES
QA/QC REPORT^•—^ wn/m. Kerun i' LE: HH2344D1INTERNAL STANDARD AREA CHECK
3 OUT OF 3 ARE WITHIN 90X TO 200X OF DAILY STANDARD AREAS.** INTERNAL STANDARD AREAS ARE WITHIN QC LIMITS ««
INTERNAL STANDARD RETB4TION TIME CHECK 0
3 OUT OF 3 ARE WITHIN +/- 30 SECONDS OF DAILY STANDARD RETENTION TIME "^' 1-
•» INTERNAL STANDARD RETENTION TIMES ARE WITHIN SC LIMITS *» CM0
7/27/88 13:33:00 SCAN I OF 1020 000175ACQUISITION STARTED
f^' 1UIRE RUN 0:HH2344D1 ACQUIRINGU//27/88 19:32:00 + 0:04 FREE SECTORS:16108 SCAN: 2 OF 1020SAMPLE: CLP,41693.UH2216,MH2224,MED,SOIL.HH2344D1.VQA,EPACONDS.: »INSTRUMENT-OMAS» EPA CLP METHOD (VOLATILES)FORMULA: SOIL ( 1 : 1 2 3 ) INSTRUMENT: OUA3 WEIGHT: 0.000SUBMITTED BY: ITFK ANALYST: MET ACCT. NO. : 41693
LOW MASS: 33 UP: 1. 93 L» TOP: 0. 00HIGH MASS: 300 DOWN: 0.00 L BOTTOM: 0.03
CENT S/P: 37 ACTUAL: 37 SAMP INT (MS): 0.200 PEAK WIDTH: 1000.FRAG S/P: 20 ACTUAL: 19 SAMP INT (MS): 0.400 INTEN/ION: 2 -r-
03MIN PEAK WIDTH: 1 MIN FRAG WIDTH X: 30 MIN AREA: 23 , .A/D THRESHOLD: 1 BASELINE: 0 ^
MODE: CENTROID POSITIVE ION (NM . S . TUNE PARAMETERS: 0
INTERFACE NUMBER 0 MULTIPLIER VOLTS: -2082.33SUB-INTERFACE NUMBER 0 LOW RESOLUTION: 127.00• OF ACOU BUFFERS 16 HIGH RESOLUTION: 126.00INSTRUMENT TYPE Q ION ENERGY: 3.33FULL SCALE MASS 800 AMU ION PROGRAM: 3.96ZERO SCALE MASS 1 AMU LENS VOLTAGE: -29.80INTENSITY/ION 2 EXTRACTOR: 0.94
^ PEAK WIDTH 1000. MMU ELECTROMETER RANGE: 7, 00OFFSET AT LOW MASS 0 MMU ELECTROMETER ZERO: 2-. 74OFFSET AT HIGH MASS 0 MMUVOLTAGE SETTLING TIME(MS) 4
7/27/S8 16:26:4SACQUISITION COMPLETEDSCANS 1 TO 1020 CENTROID
MODE SCANS SECS OUT OF X PEAKS PER SCAN PER SECCENTROID 1020 281.7 2040.0 13.8 32123. 31. 16.
03217932
IT ANALYTICAL SERVICES DIAON08TIC REPORT 7/27/88 16:30:03 CMDATA FILE:HH234401REFERENCE: LIBRARYVE '--'
METHOD: VOST INITIALIZATION OPTION: 2 PROCESSINO OPTION: 4 00017R <^REPORT: CLPI888 UUU±«"
C ——— STANDARDS ———- X —— PLUS UNKNOWNS —— X - LIST NAMES - > (MPROC USED POSS RHS PROC USED POS8 RMS STANDARD/UNKNOWN
6 6 3 123 0 » 1 13; CLPI8S8/CLPUNKB 0
49 COMPOUNDS PROCESSED. 9 FOUND
< COMPOUND •>< ———————— SEARCH -—————————— >< SAT > < ————— CMRO -———— :NO LIB ENTRY REF PRED SB- DELTA PEAKS FIT PEAKS H/Z TOP DELTA PEAKS
1 VE 1 -306 307 306 -1 3 999 . 130 306 . 12 VE 2 -632 634 633 1 1 997 . 1 1 4 633 . 13 VE 3 -781 7S3 784 1 1 996 . 117 784 . 14 VE 4 -394 393 393 . 1 982 . 63 396 1 19 VE 3 -746 748 749 1 1 932 . 98 749 . 16 VE 6 -911 914 918 -2 1 942 . 93 912 . 17 V6 7 -48 30 . . . . . SO . . . ;8 VE 8 -76 78 . . . . . 94 . . .9 VE 9 -97 99 . . . . . 62 . . .
10 VE 10 -128 130 . . . . . 64 . . .1 1 VE 1 1 -200 202 . . . . . 84 199 . I12 VE 12 -226 228 230 2 1 839 . 43 228 -2 113 VE 13 -232 234 . . . . . 36 . . .14 VE 14 -239 237 . . . . . 33 . . .19 VE 19 -233 233 . . . . . 76 299 . 2
•• VE 16 -293 299 . . . . . 96 .. .VE 17 -332 334 . . . . . 63 . • .
18 VE 18 -398 360 . . . . . 96 . . .19 VE 19 -371 373 . . . . . 83 . . .20 VE 20 -396 398 . . . . . 62 . . .21 VE 21 -398 400 . . . . . 72 402 . 122 VE 22 -433 439 . . . . . 97 . . .23 VE 23 -449 447 . . . . . 1 1 7 .24 VE 24 -438 460 . . . . . 43 461 . 129 VE 23 -461 463 . . . . . 83 . . .36 VE 26 -906 908 . . . . . 63 . . .27 VE 27 -914 916 . . . . . 79 .28 VE 28 -933 939 . . . . . 13029 VE 29 -346 948 . . . . . 12930 VE 30 -992 994 . . . . . 97 . . .31 VE 31 -S9S SB4 936 2 1 993 . 78 336 . 132 VE 32 -394 996 . . . . . 79 999 . 133 VE 33 -989 991 . . . . . 63 . . .34 VE 34 -628 630 . . . . . 17339 VE 39 -699 701 . . . . . 43 . . .36 VE 36 -690 692 . . . . . 43 699 . 137 VE 37 -708 710 . . . . . 164 . . .38 VE 38 -701 703 . . . . . 83 704 . I39 VE 39 -792 799 . . . . . 92 793 . 140 VE 40 -783 788 788 . 1 979 . 112 788 . 141 VE 41 -843 846 . . . . . 106 843 . 1
VE 42 -933 998 . . . . . 104 961 . 2•J VE 43 -989 992 . . . . . 106 993 . 144 VE 44 -969 968 . . . . . 106 966 . 149 VE 46 -269 271 . . . . . 103
I . T . ANALYTICAL SERVICESLIBRARY SEARCH REPORT
VOLATILE ORGANIC ANALYSISJQATA FILE: HH2344DI
f A.IBRATION FILE: CAL0407BB^dARCH OF LIBRARYVE
SCAN COMPOUND306 CIOI BROMOCHLOROM6THANE (I.S.tl-CLP)639 CI10 1,4-DIFLUOROBENZENE (I.S.ttS-CLP)784 C120 CHLOROBENZENE-D9 < 1 . 8 . tt3-CLP >396 CS19 1.2-DICHLOROETHANE-D4 < S . S . » 1 )749 CS09 TOLUENE-OB ( S . S . • 2 >912 CS10 4-BROMOFLUOROBENZENE (S.S.#3)199 C030 METHYLENE CHLORIDE228 C03S ACETONE402 C110 2-BUTANONE996 Cl&S BENZENE999 C172 TRANS-1.3-DICHLOROPROPENE653 C20S 4-METHYL-2-PENTANONE759 C230 TOLUENE *788 C239 CHLOROBENZENE84S C240 ETHYL BENZENE «993 C2SO TOTAL XYLENE8966 C2S2 M-XYLENE
000177
DELTA
-11 922-987
111
-2-3022
-1300
-11
-2
/PUR-FIT <
979-999
909-9SS924-9768S8-984712-776742-8A7890-906706-743972-990
0- 0408-837860-924944-9727S9-889280-693342-697
WNQ >
30
90494846•f83
34»-
.a-9
999a3
FL;8AT
090000000000 -99^000000
\G3LIB
0000
-3--1CO
O^t-a^CM
-3-10
-1-4-2
03217934
DATA: HH234401 »1WC030 METHYLENE CHLORIDE
.^HANGED SPECTRUM MATCH
RELATIVE INTENSITY < X )MASS LIBRARY SAMPLE
36 12 0 PEAR NOT IN SAMPLE47 23 1849 100 10031 32 2SS4 68 6286 42 34
000178
RAM SPECTRUM MATCHRELATIVE INTENSITY (X)
MASS LIBRARY SAMPLE36 12 0 PEAK NOT IN SAMPLE47 22 1349 100 100S1 32 3184 68 3786 42 28
03217935
5 9 17 17 2 0
I.T. ANALYTICAL SERVICES TRIPLE MASS SPECTRUM DATAi HH2344D1 •199 BASE N/E;87/ 7/88 15s52;ee + 6l38 CALIi CAL94e788 *13 RIC: 733./SflMPLEi CLP,41695,MH2216/MH2224-MED,SOIL,HH234401,UOA-EPACONDS.i XINSTRUMENT-OUA5* EPA CLP METHOD (UOLATILES)
ENHAMCED SPECTRUM <S 15B 1M 0T)
RAM SPECTRUM
C038 METHYLENE CHLORIDE
48 58 C 68 80
DATA: HH2344D1 »2Z8C03S ACETONE,-<NHANCEO SPECTRUM MATCH
RELATIVE INTENSITY (X)MASS LIBRARY SAMPLE43 100 10059 16 21
L 9 1717 Z 0 • • ! ' ' ' r\
I . T . ANALYTICAL SERVICES TRIPLE MASS SPECTRUM DATA: HH234401 »22807/27/88 15:52:90 4 7i36 CALIl CAL048788 •13SAMPLE! CLP.41695-HH2216,MH2224,MED,SOIL,HH23440LUOA,EPACONDS.; «INSTR(JMENT-OM«» EPA CLP METHOO <UOLATILES>ENHANCED SPECTRUM <S 15B IN OT)
RAM SPECTRUM
0835 ACETONE
BASE 11/E« 43/ 44RICf 696./ 1961.
35 49 45 59 55
DATA: HH2344D1 tt402C110 2-BUTANONE
/ HANCED SPECTRUM MATCH
RELATIVE INTENSITY (X)MASS LIBRARY SAMPLE
3S 26 0 PEAK NOT IN SAMPLE37 14 0 PEAK NOT IN SAMPLE43 100 10072 16 13
RAM SPECTRUM MATCH
RELATIVE INTENSITY (X)MASS LIBRARY SAMPLE3S 26 737 14 S43 100 10073 16 13
CO00i-4000
6 8 1 7 1 7 3 0 ' • • ''
I.T. ANALYTICAL SERVICES TRIPLE MASS SPECTRUM DATA; HH234401 «49297/27/88 15:52:00 + 13(24 CALI: CflL84C788 «l3SAMPLE: CLP,4169S,MH2216,MH2224,MED,SOIL,HH234401,WA,EPACOWS.: »INSTRUMENT-OMft5» EPA CLP METHOD (UOLATILES)
ENHANCED SPECTRUM (S 158 IN 9T)
BASE M/Ei 43/ £5RIC: 928./ 4135. S?
' . l
RAH SPECTRUM
C4.H8.0 C119 2-BUTAHOHE
M/E 40 50 69 78 89 99 199 C
DATA: HH234401 »336C16S BENZENE
^NHANCED SPECTRUM MATCH
RELATIVE INTENSITY (X)MASS LIBRARY SAMPLE39 10 IS30 17 2291 IS 2232 20 2477 19 227S 100 100
000184
I.T. ANALYTICAL SERVICES TRIPLE MASS SPECTRUM OATAi HH234401 «55607/27/88 l5;52:ee + 18(32 CALI: CALM0788 *13SAMPLE: CLP,41695,HH2216,MH2224,HED,SOIL<HH234401,UOA,EPflCOMBS, i »INSTRUMENT-OHAS» EPft CLP fCTHOO (UOATILES)
ENHANCED SPECTRUM <S 15B IN eT>
BASE ?€8 78/ 78 1^RICt 3S327./ 37823. ^
roo
RAM SPECTRUM
C165 BENZENE
48 59 <L 69 78
DATA: HH2344D1 tt999C172 TRANS-1.3-DICHLOROPROPENE
/•"^HANGED SPECTRUM MATCH
RELATIVE INTENSITY (X)MASS LIBRARY SAMPLELIBRARY BASE PEAK NOT IN SAMPLE
000186
RAW SPECTRUM MATCHRELATIVE INTENSITY (X)
MASS LIBRARY SAMPLELIBRARY BASE PEAK NOT IN SAMPLE CM
CT-.' r' r(M0
£ 6 17 17 3 0
I.T. ANALYTICAL SERVICES TRIPLE MASS SPECTRUM DATAt HH2344D1 «55597/27/88 15:52:08 + 18:36 CALIi CAL048788 *13SAMPLE: CLP,41695,MH2216-MH2224,MED,SOIL,HH234401>UOA,EPACONDS.; »mSTRUMEMT-OHA5» EPA CLP METHOD (UOATILES)
ENHANCED SPECTRUM <S 15B IN en
RAM SPECTRUM
C172 TRANS-l-3-OICHLOROPROPENE
59 100
BASE H/Es 78/ 78RIC; 34847./ 37247.
DATA: HH2344D1 tt633C203 4-METHYL-2-PENTANONE
,- NHANCED SPECTRUM MATCH
RELATIVE INTENSITY (X)MASS LIBRARY SAMPLE39 12 1741 22 32 OUT OF 20X RANGE43 100 10097 17 62 OUT OF 20X RANOESB 32 0 PEAK NOT IN SAMPLE89 10 3
RAM SPECTRUM MATCH
RELATIVE INTENSITY <X)MASS LIBRARY SAMPLE39 12 3041 22 87 OUT OF 20X RANOE43 100 10037 17 73 OUT OF 20X RANGE90 32 4 OUT OF 20X RANOE8S 10 9
CTCOT-<
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00
5 6 17 fr Z 0 ' g
I.T. WftLYTKX. SERVICES TRIPLE HASS SPECTRUfI OATAl HH2344D1 K55 W6E M/Es 43/- 43 ?307/27/88 15l52iee + 21t9B CALIi CAL94W88 tl3 RICi 2239./ 88B7. gSAMPLE: CLP,41695,MH2216,HH2224,HEtLSOIL,HH234401,Wl/EPft -CONDS.; «INSTRUMENT-OHAS» EPft CLP METHOD <UOLATILES>
ENHWCEO SPECTRUM (S 15B IN 0T)
'—rT ' 1 ' I 1 1 i 1 i 1 i | i 1 i 1 i 1 i 1 i | i 1 i 1 i 1 i 1 i | i 1 i 1 i 1 i 1 i i iRAM SPECTRUM
•l"f'.'-,'''J , ' 1 - ' | l-,^;•I 1 T ' IC6.H12.0 C205 4-METHYL-2-PENTftNONE
H^/ 58 188 / 158 288 25T
DATA: HHZ344D1 tt733C230 TOLUENE •
ENHANCED SPECTRUM MATCH
RELATIVE INTENSITY (X)MASS LIBRARY SAMPLE39 16 0 PEAK NOT IN SAMPLE65 13 1391 100 10092 5S 62
000190
RAM SPECTRUM MATCH
RELATIVE INTENSITY < X >MASS LIBRARY SAMPLE39 16 111 OUT OF 20% RANOE69 13 1691 100 10092 SS 62
03217947
L 6 17 1 7 3 0
I.T. ANALYTICAL SERUICES TRIPLE MASS SPECTRUM DATA: HH234401 »75507/27/88 15:52808 + 25:10 CALI; CAL94078B •13SAMPLE: (^41695,MH2216,MH2224,WILSOIL.HH2344D1,UOA,EPACOWS.: tINSTRUMENT-OHMt EPft CLP METHOC (UOLATILES)
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BASE M/Ei 9l/ 43 00RICi 4775./ 51647. 2
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50 iee / • e 2ee 258 /
DATA: HM2344D1 •780C23S CHLOROBENZENE
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RELATIVE INTENSITY (X)MASS LIBRARY SAMPLE38 IS 1930 24 2651 24 2577 65 63
1 1 3 100 1001 1 4 34 33
000192
03217949
6 6 1 7 t ? 2 0
I.T. AMflLniCAL SERVICES TRIPLE MASS SPECTRUM DATfti HH234401 •78887/27/88 15s52i0e + 26:16 CALIl CfLWWW •13SfWLE; CLP,41695-MH2216,MH2224,MED-SOIL-HH234401,UOA,EPACONDS.t tINSTRUMENT-OMASt EPft CLP METHOD (WLATILES)
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RELATIVE INTENSITY (X)MASS LIBRARY SAMPLE39 19 0 PEAK NOT IN SAMPLE91 12 1091 100 100106 32 33
RAW SPECTRUM MATCHRELATIVE INTENSITY (X)
MASS LIBRARY SAMPLE39 19 76 OUT OF BOX RANOE91 12 1991 100 100106 32 36
1. 0 S 17 2 0
I.T. ANALYTICAL SERVICES TRIPLE MASS SPECTRUM DATAt HH234401 «84S97/27/88 15!52:0e + 28(18 CflLI; CAL948788 •13SAMPLE; CLP,41695-UH2216,MH2224-MED,SOIL,HH234401-UW1,EPACONDS.r »IHSTRUMENT-OHft5» EPft CLP NETHOO (UOIATILES)
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DATA: HHZ34401 •993C3SO TOTAL XYLENE8ENHANCED SPECTRUM MATCH
RELATIVE INTENSITY (X)MASS LIBRARY SAMPLE39 29 0 PEAK NOT IN SAMPLESl 13 0 PEAK NOT IN SAMPLE77 12 0 PEAK NOT IN SAMPLE91 100 100105 18 0 PEAK NOT IN SAMPLE106 46 41
000196
RAM SPECTRUM MATCHRELATIVE INTENSITY ( X )
MASS LIBRARY SAMPLE39 23 147 OUT OF 20X RANGE91 13 2077 12 2991 100 100105 IS 47 OUT OF 20X RANGE106 46 3S
03217953
I.T. ANALYTICAL SERVICES TRIPLE MASS SPECTRUM DATA: HH234401 499307/27/88 15152100 + 33:06 CALIl CPLWTW •13SAMPLE; CLP,41695,MH2216,HH2224,MED-SOIL,HH234401,WA,EPACONDS.l XINSTRUMENT-OMA5» EPA CLP METHOD (UOLATILES>ENHANCED SPECTRUM <S 15B IN W)
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-T-T-TC259 TOTAL XYLENES
' I '100 280 250
DATA: HH234401 »966C292 M-XYLENE.CHANGED SPECTRUM MATCH
RELATIVE INTENSITY (X)MASS LIBRARY SAMPLE39 12 36 OUT OF 20X RANGE91 100 100105 20 0 PEAK NOT IN SAMPLE106 52 31
000198
RAW SPECTRUM MATCHRELATIVE INTENSITY (X)
MASS LIBRARY SAMPLE39 12 1S1 OUT OF 20X RANGE91 100 100109 20 129 OUT OF 20X RANGE106 92 99
03217955
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CAS » 27881-10-3
BENZENE;ME7HYL- CAS « 108-88-3
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CYCLOHEXANE, l-ETWL-2-fCTNYL-, TRANS- CAS * 4923-78-8
CYCLOHEXANE, 1-ETHYL-2-METWL-, CIS- CAS • 4923-77-7
CAS » 624-29-3
58 68 78 98 188 118
LIBRWY SEARCH DATA; HH2344D1 t 695 BASE M/Et 43V7/27/W 15:52100 + 23s 18 CALIl CAUM0788 « 13 RICs 12447.SAIPLEi CLP-41635,MH2216-MH2224/»BLSOIL,HH23440l-UOft,EPftCOWS.: »INSTRUHENT-OMfl"» EPA CLP METHOD <UOLATILES>EHHANCED <S 1SB IN ST)
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HEPTftHE CAS • 142-82-5
CftS » 49622-18-6
68 88 108 128 148 168 188C
LIBRARY SEARCH DATA; HH2344D1 • 711 BASE M/Es 4307/27/88 15:52:09 + 23:42 CALIi CAL949788 « 13 RICl 12127.SlWLE: C1-P.41695,MH2216,HH2224,MED,SOIL,W234401,UOA,EPACONDS.; «INSTRUfClff-ONft» EM CLP METHOD <UOU»TILES)ENHANCED <S 13B IN OT)
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OATA. V3T07122.TI °00^2/12/38 ? : 1 9 : 0 0YiPLE: CLP, , ,VSTD020,LOW,SOIL,VST07122,VOA,IC-020
-JNDS : *INSTRUMENT-OMA5* EPA CLP METHOD (VOLATILES)FORMULA. INSTRUMENT: OMA5 WEIGHT: 0.000SUBMITTED BY: ANALYST: MET ACCT.NO. :4MOUNT=AREA » REF AMNT/(REF. AREA)» RESP FACT);DET. L I M . = 0.00RESP. FAC. FROM LIBRARY ENTRY
NO NAME1 CIOI QRaMOCHLOROMETHANE ( I S.B1-CLP)2 CI10 1.4-DIFLUOROBENZENE ( I . S . » 2 - C L P )3 CI20 CHLOROBENZENE-D5(I.S.#3-CLP)d CS15 1,2-DICHLOROETHANE-D4 < S . S . » 1 )
cr-C\im• rCM0
5 CS05 TOLUENE-D8 ( S . S . # 2 )6 CSIO 4-BROMOFLUOROBENZENE ( S . S . # 3 )7 C010 CHLOROMETHANE **3 CO 15 DROMOMETHANE9 C020 VINYL CHLORIDE »10 C025 CHLOROETHANE11 C030 METHYLENE CHLORIDE12 C035 ACETONE13 C036 ACROLEIN14 C037 ACRYLONITRILE15 C040 CARBON DISULFIDE16 C045 1,1-DICHLOROETHENE »17 C050 1,I-DICHLOROETHANE »»
——^8 C053 TRANS-1,2-DICHLOROETHENE1 ? C060 CHLOROFORM » ;
=!0 C065 1,2-DICHLOROETHANE21 CI10 2-3UTANONE22 C115 I,1,1-TRICHLOROETHANE23 CI20 CARBON TETRACHLORIDE24 C125 VINYL ACETATE25 C130 BROMODICHLOROMETHANE26 C140 1,2-DICHLOROPROPANE *27 C143 CIS-1,3-DICHLOROPROPENE2S C150 TRICHLOROETHENE29 C155 DIBROMOCHLOROMETHANE30 C160 1,1,2-TRICHLOROETHANE31 C165 BENZENE32 C172 TRANS-I-3-DICHLOROPROPENE33 C175 2-CHLOROETHYL VINYL ETHER34 C180 BROMOFORM *»35 C210 2-HEXANONE36 C205 4-METHYL-2-PENTANONE37 C220 TETRACHLOROETHENE38 C223 1 , 1 , 2 , 2-TETRACHLOROETHANE **39 C330 TOLUENE »40 C235 CHLOROBENZENE41 C240 ETHYL BENZENE »42 C245 STYRENE43 C250 TOTAL XYLENES
/—S4 C252 M-XYLENE5 C251 TRICHLOROFLUOROMETHANE
NO M/E SCAN TIME REF RRT METH AREA(HGHT) AMOUNT 7.TOT
03217S80
000223NO
12
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101 11 213141 5161718192031222324252627
^^0313233343536373839404142434445
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1 1 743S36375
130129977S7563
1734343
1648392
1 1 2106104106106103
RET(L>10 032 1 : 0426: 0213: 0624: 5230- 20
1 : 302: 223: 04
SCAN304632781393746910
457192
1231962252332552522923303583703963994324444584615055 1 5533546552553555589627699650707700732785842954987963367
RATIO RRT(L)1 . 001 . 001. 001. 001 . 001. 001 001. 001. 00
TIME R10: 082 1 . 0426: 0213: 0624: 5230; 20
1 : 302 223: 044: 066: 327' 307. 468: 30B; 249: 44
1 1 : 001 1 : 5612: 2013: 1213 1814: 2414 481 5 : 161 5 : 2216. 5017: 1017. 4618: 1218: 2418: 2618: 3019: 3820: 5423: 1821: 4023: 3423: 2025: 0436: 1058: 0431: 4832: 5432: 068: 54
1 0001 . 0001 0001 . 2930. 9551. 1650. 1480. 2340. 303
IEF123133111111111111112222222222222233333333331
RATIO1 .1 .1 .1 .1 .1.1 .1 .1 .
1 .1 .1 .1 .0.1 .0.0.0.0.0.0.0.0.0.0.1 .1 .1 .1 .0.0.0.0.0.0.0.0.0.0.0.0.0.0.0.0.0.0.0.1.1.1.1 .1 .0.
000000000000000000
RRT000000000293955165148234303405645740766839829961086178217303631684703725729799815843864873875878932992895832905896963003078222264233878
METHA BEA BEA BEA BQA BEA BQA BBA BEA BBA BBA BBA BEA BVA BEA BBA BBA BBA BBA BEA BBA BBA BBA VBA BBA BBA BBA VBA BBA BGA BBA BBA BBA BVA BBA BBA BVA BBA BBA BBA BBA BBA BBA BBA BBA BB
AMNT50. 0050. 0050. 0020. 0020. 0020. 0020. 0020. 0020. 00
AREA(HSh39630.
1 8 8 5 1 1 .148201.276624802447360.25038.10203.1 5 1 4 5 .9700.
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5802.1376569264.21735.50209.23919.48604.31843.
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116156.41S33.36807.5118733836.39989.27289.91521.26288.20473.35515.86026.98E96.32784.63012.54814.64291.31639.62464.36739.361 S3.23754.
AMNT(L)50. 0050. 0050. 0020. 0020 0020. 0020. 0020. 0020. 00
IT) AMC50.50.50.20.20.20.20.20.20.20.20.20.20.20.20.20.20.20.20.20.20.20.20.20.20.20.26.20.20.20.20.14.20.20.20.20.20.20.20.20.20.20.20.20.20.
R. FAC1. 0001. 0001. 0001. 74S0. 3100. 7991. 5790. 6440. 955
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RUN 0.VST07122FREE SECTORS:16125
SOIL, VST07122,VOA,IC-020EPA CLP METHOD (VOLATILES)INSTRUMENT. OMA5ANALYST: MET
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ACQUISITION STARTED WITH 8C FILE
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4 CS15 I,2-DICHLOROETHANE-D4 ( S . S . f t I )5 CS05 TOLUENE-DB <S S .#2)6 CS10 4-BROMOFLUOROBENZENE < S . S . # 3 )7 C010 CHLOROMETHANE •»•»8 C 0 1 5 SROMOMETHANE9 C020 VINYL CHLORIDE »
10 C025 CHLOROETHANE1 1 C030 METHYLENE CHLORIDE12 C035 ACETONE13 C036 ACROLEIN14 C037 ACRYLONITRILE15 C040 CARBON DISULFIDE16 C045 1,1-DICHLOROETHENE *1 7 C050 1, 1-DICHLOROETHANE •»»
/-<8 C053 TRANS-1,2-DICHLOROETHENE9 C060 CHLOROFORM » ;
20 C065 I,2-DICHLORDETHANE21 C I10 2-BUTANONE22 C 1 1 5 I,1,1-TRICHLOROETHANE23 C130 CARBON TETRACHLORIDE34 C 1 2 5 VINYL ACETATE35 C130 BROMODICHLOROMETHANE26 C 1 4 0 1.2-DICHLOROPROPANE *27 C143 CIS-1,3-DICHLOROPROPENE28 C 1 5 0 TRICHLOROETHENE2'? C 1 5 5 DIBROMOCHLOROMETMANE30 C160 1,1,2-TRICHLOROETHANE31 C165 BENZENE33 C172 TRANS-1,3-DICHLOROPROPENE33 C175 2-CHLOROETHYL VINYL ETHER34 C180 BROMOFORM •»35 C210 2-HEXANONE36 C205 4-METHYL-2-PENTANONE37 C220 TETRACHLOROETHENE38 C225 1 , 1 , 2. 2-TETRACHLOROETHANE •»*39 C330 TOLUENE *40 C235 CHLOROBENZENE41 C240 ETHYL BENZENE »42 C245 STYRENE43 C250 TOTAL XYLENES
^~<k4 C252 M-XYLENE5 C251 TRICHLOROFLUOROMETHANE
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veVEUEVEveVEveVEVEVEVEVEVEVEVEVEveVEVEVEVEVEVEveUEveVEVEVEVEVEUEVEVEVEVEVEVEUEVEVEVEUEVEVE
ANDARED P
a
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ND -NTRY
I234567
a9
101 1ia1314IS16171919ao212233242526272B2930313233343536373839404142434446
DS ——OSS
S
S PROCt
REF-30a-632-781-394-746-911-48-76-97
-128-200-226-232-255-253-293-332-3S8-371-396-398-433-445-458-461-306-314-533-546-SS2-Bsa-534-589-62S-699-650-708-701-752-785-343-953-989-965-269
— ><Rns141
ESSED.
PREO30362'?77839174390S
457394
125197223Z2925225029032935536839339943044B4334585035 1 1330343S4934933158662569664770S69B749782840952986962566
—— PLUPROC U
43
42 FOU
SEL D303630779390744706
457293
12419622622923S24929132-?33536839339 S431442436458303511S31343549
386623
6487056977307B2840931984960S66
8 UNKNCSED PC
42
ND
CH -——ELTA PE
11
-11
-a-1-i-i-i3
-11
1
1
1
1
-11
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DUNS3SS
1
:AHSI1112111111111111111111111111t
11
1I11111111
R11S S96 CL
———— ?<FIT P9949B79119739939229939749839659B39769699789B79799839969879909299919969689879839B7993983937
988997
1000940992991992994982993932987
-LIST NAMETANDARD/UNKFIS3S/CLFUN
SAT > < -EAKS M/Z
1281 1 41 1 765989330946264844336337696639683627297
1 1 743836373
13012997787363
1734343
1648392
1 1 2106104106106103
S - :-•NOUNKS
TOP303630778390744906437293
12419622622923324929132933536839339643044243643850331153134334933053158762469664B7036977497S2840951984960266
CHRO ———DELTA PEAKS
11
-1
.
.
11
1 1-1 1
11111X1111
1 1-t 1
1111
-1 1111111
03218008
7AVOLATILE CONTINUING CALIBRATION CHECK
000251Lab Name; ,TA<-K*xn^u.Lg Contract:
/^^ nrf-I Lab Cod*: [-f.<i-ru Car No.; HIL^S SAS Mo.: _____ SDG Mo.; i^nzz^j.
ln»trua»nt ID: rtii^ft S Calibration Oaf; o-»lz->Jfl^ TJM: o-7W(,
Lab ril* ID: US-Total! Init. Calib. DafC); cnlizlao ______
Matrix: (•oil/watT) SOIL Lavl: (lov/»«d) utt> Coluxn:(pack/cap) pnc.t
Min RJIT50 for SPCC(t) • 0.300 (0.2SO for Broxofoni) Max «D for ccc<«) • 25.o»
USf imrso i *oCOMPOUND
« 1 . 1 3* I I-OUQ I q.q »Chloroa«than«_Bro»oB»than»__I Vinyl ChloridT| Chloro«than«I o.fcao I fl.om I -3t.3 I* a.aa« I rt.«><<o I -ig.> •I «.sm lo.nw I -zs-3 II O-'^V I I.HV-I I -gZ.t I|M«tbyl«n« chlorid«_IAc*ton«_ I i.z«i I mzt. I .10.9 lI iLtti I a^fi I «fl II Carbon Diaulfia*IL,l-0ichloro«tb«n«________* l.f«3 I 1 .1M3 I 10. q »
1 1 , l.-0iehloro«than«____» g.ftfc3 I z.aaz I i.\ »11.2-Dichloro«th«r (total) I i.nw li.aso I ^.s II Chlorofom * r.TJft | ^.ft^p | -ta *ll.a-Dichlorothana | 1.92.1 | I.'WJ I--y.i- I|2-But»non«____________I Aafto I a.n»o I -0.1 I11.1.1-Trichloroathan* \ a.ii.z I a.wm. I 3.5 II Carbon T«traehlorid«_____ | aMta \ o.Hi9 I i.3 |I Vinyl Acataf_______I l.sc.v, I i.em. I -z .M IIBro»odichloro—than« IA.S^I I o.sft* 1-o.z. I11,3-Oichloropropana_____* s.»in I o.wws I &.o *Iei«-l.3«Dichloroprop«M I«.«sa I c.ggg. I yITrichlowthw^_______I a.fgs I . t I -sI Dibroaochlore—taan* I o.siit I o^au I -•;11,1,2-Tricalorothair___l^.a«3 I o-ssi 1-1.1 1| BOTXOT* ________I i.m-r I 1.^0 I f.9 Iltran»-1.3»DioM,ereDroB«r I a.«fl7 I O.M««|. I a.3 I| Broaefora________<a.nat I d.sfl< 1-eo.t t14-llthyl-2-Mntano»r I >.3» I l.i3^ I ITS I13-—x«noM • I i.iie I rt-ttt. I n.w I|Ttfcbloro«fcb«r ' "" I 0.1 •>o I o.w'rt I u.s Il.l,a,a-Ttr»chlor53EhM»»ft^a_lS^S£_l_aA_<ToltMir_____________•A122-1 0^3^ I is^ •Chlorob«nx«r_________• i-oif o.^w I iia tgthylb«nw ——— '*c>.«<l7 • - '
IXylan* (total). O.S'<I. rt.Cl&
I Toluw-d»______ I {\.19-1 I fl.t.H3 I'I •. •ia> I o.ii3 Il ^ f c o o l i.gug I
IBroaofluoroe«nx«n«11,2-0ichloro«taan«=dr
rORN VIZ VOX 1/87 R<v.
03218009
0321
8010
QUANT I TAT I ON REPORT FILE: VST07271
DATA: VST07271.TIW27/8S 7: 46: 00
1PLE: CLP,4169S,WH2216,VSTD030,MED.SOIL,VST07271.VGA,CC-090CLINDS.: •INSTRUMENT-OMA9» EPA CLP METHOD (VOLATILES)FORMULA: SOIL INSTRUMENT: OUAS WEIOHT:SUBMITTED BY: ITFK ANALYST: WET ACCT.NO.AMOUNT-AREA • REF.AMNT/<REF.AREA)* RESP.FACT)!DET.HM.- 0. 00RESP. FAC. FROM LIBRARY ENTRY
NAMECI01 BROMOCHLOROMETHANE (I.S.ttl-CLP)CI10 1.4-DIFLUOROBENZENE (I.S.ttZ-CLP)CI20 CHLDROBENZENE-DBd.S. »3-CLP)CS15 1,2-DICHLOROETHANE-D4 < S . S . * 1 )C809 TOLUENE-DB (S.S.«2)C810 4-BROMOFLUOROBENZENE ( S . S . W 3 )C010 CHLOROMETHANE **C019 BROMOMETHANEC020 VINYL CHLORIDE •COBS CHLOROETHANEC030 METHYLENE CHLORIDEC039 ACETONEC036 ACROLEINC037 ACRYLONITRILEC040 CARBON DI8ULFIDEC049 1,1-DICHLOROETHENE *COSO 1,1-DICHLOROETHANE *«C083 TRANS-1,2-DICHLOROETHENEC060 CHLOROFORM *C069 1.2-OICHLOROETHANECI10 a-BUTANONEC119 1, 1, 1-TRICHLOROETHANECI20 CARBON TETRACHLORIDEC12S VINYL ACETATEC130 BROMODICHLOROMETHANEC140 l.S-DICHLOROPROPANE *C143 CIS-1,3-DICHLOROPROPENEC130 TRICHLOROETHENEC199 DIBROMOCHLOROMETHANECl&O 1<1.2-TRICHLOROETHANEC163 BENZENEC172 TRAN8-1,3-DICHLOROPROPENEC17S 2-CHLOROETHYL VINYL ETHERC180 BROMOFORM «*C210 2-HEXANONECSOS 4-METHYL-a-PENTANONECS20 TETRACHLOROETHENECZSB 1,l,2,a-TETRACHLOROETHANE •»CS30 TOLUENE •C239 CHLOROBENZENEC240 ETHYL BENZENE *C24S STYRENEC230 TOTAL XYLENESC292 M-XYLENEC2S1 TRICHLOROFLUOROMETHANE
000253
0. 00041693
NO M/E SCAN TIME REF RRT METH AREA(HOHT) AMOUNT XTOT 1 1' ,^
000254NO
1^
4S&789
101112131419161718192021222324252627r^3031323334333637383940414243444S
N012349
^rJ9
032180^
M/E SCAN12811411763989990946364844396S37696639683637297
11743836379
13012997787963
1734343
1648392
112106104106106103
RET<U10: 1421: 1026: 1013: 1229:0030:28
1:342:303: 10
307639789396790914477999
126199226234299294299333361372399401439447461463908917936948994996997992630702693710702796788847961999970269
RATIO RRT<U1.00 1.0001.00 1.0001.00 1.0001.00 1.2901.001.00 1.1641. 001.001.00
TIME REF RRT METH10: 14 1 1.000 A BB21: 10 2 1. 000 A BB26: 10 3 1. 000 A BB13: 12 1 1. 290 A BB29:00 330:28 3
1:342:303: 104: 126:387:327:488:38 1 0. 844 BB8:28 19: 90 1
11:06 112:02 112:34 113: 18 113:22 214:30 214: 94 2 0. 704 VB19:22 2 0. 726 BV19:26 2 0.729 BB16: 96 217: 14 217: 92 218: 16 218: 28 218:32 2 0. 876 BB18:34 219: 44 221:00 223: 24 321:46 323:40 3 0. 904 BB23:24 325: 12 326: 16 328: 14 332:02 333: 10 333:20 38:98 1
0.999
0. 1930.2440. 309
0.762 BB
RATIO AMNT1.00 90.001.00 90.00111. 00 90. 001. 00 90. 0011. 00 90. 001
0. 9991. 1640. 1930. 2440. 3090. 4100. 6480. 736
0. 827 BB0. 9611. 0891, 1761. 2121. 3000.6310. 689
0. 8000. 8140. 8440. 8630.872
0. 8770. 9320.9920. 8940.832
0. 8940.9631.0041.0791. 2241. 3681.2360.876
.00 90. 00
.00 90. 00
00 90.00
00 90. 00
BBBBBBBVBBBBBBBB
BBBBBBBBBBBVBB
BBBBBBBBBB
BBBBBBBBBB
BBBBBBBBBBBBBBBB
AREA(HOHT)28196.
129811.121649.43962.78226.86797.29334.24364.26499.18998.41084.40212.7389.
18919.89918.32219.79849.38069.80913.99127.10397.97908.93894.
161730.76129.97799.86719.98249.79784.46694.
141933.41713.31141.79819.
114999.138924.94639.99121.89188.
114786.94763.
107766.62039.62170.39229.
AMNT(L) R.SO. 00 1.90.00 1.90.00 1.90.00 1.SO. 00 0.90.00 0.90. 00 1.90. 00 0.90. 00 0.
AMOUNT90.90.90.90.90.90.90.90.90.90.90.90.90.90.90.90.90.90.90.90.90.90.90.90.90.90.64.90.90.90.90.36.90.90.90.90.90.90.90.90.90.90.90. 00090.90.
FAC000000000949643713040864940
000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000
000000
R . F A C < L »1.1.1.1.0.0.1.0.0.
Ue/LW/Lue/LUC/LUO/Lue/LUC/LUC/Lue/LUO/LUO/LUO/LUO/LUO/LUQ/LUQ/Lue/Lue/Lue/Lue/Lue/Lue/Lue/Lue/Lue/Lue/Lue/Lue/Lue/Lue/Lue/Lue/Lue/Lue/Lue/Lue/Lue/Lue/Lue/Lue/Lue/Lue/Lue/Lue/Lue/L
000000000949643713040864940
XTOT2. 222.222.222.222.222. 222.222. 222. 222. 222. 222. 22 ^2. 22 •-.2. 22 u2. 222.222.22 -2.22 (
2. 222. 222.222.222. 22
• 2.222. 222. 222.84
, 2.22• 2. 22
2.222.221.602. 222.222.222.222.222. 222.222. 222. 222.222. 222. 232.22
RATIO1.001.001.001.001.001.001. 001. 001. 00
000255
RET(L)4: 126:387:327:488:388:289:90
11:0612:0212:2413: 1813:2214:3014:5419:2219:2616: 9617: 1417: 9218: 1618:2818:3218:3419:4421:0023:2421:4623:4023:2429: 1226: 1628:1432:0233: 1032:208:98
01
111
tATIO1.00
. 00
. 00
.00
. 00
.00
.00
.00
. 00
.00
. 00
.00. 00. 00. 00. 00. 00. 00. 00. 00. 00. 00. 00. 00. 00. 00. 00. 00. 00. 00. 00. 00
1. 001. 001. 001. 00
RRT(L)0. 4100. 6480. 7360.7620.8440.8270. 9611. 0891. 1761. 2121. 3000. 6310.6890.7040. 7260.7290.8000.8140. 8440. 8630.8720. 8760. 8770. 9320. 9920. 8940. 8320. 9040.8940. 9631. 0041. 0791. 2241. 2681. 2360. 876
RATIO1. 001.001. 001.001. 001. 001. 001. 001. 001. 001. 001. 001. 001. 001.001. 001. 001. 001. 001. 001. 001. 001.001.001.001.001. 001. 001.001. 001.001. 001.001.001. 001.00
AMNT90. 0090. 0090. 0090. 0090. 0090.0090.0090. 0090. 0090. 0090. 0090. 0090. 0090.0090.0090. 0090. 0064.0090. 0090. 0090. 0090. 0036.0090. 0090. 0090. 0090. 0090.0090.0090. 0090. 0090.0090. 0090. 0090. 0090.00
AMNT(L)90.0090. 0090.0090. 0090. 0090.0090.0090.0090.0090.0090. 0090.0090. 0090.0090. 0090. 0090.0064.0090. 0090. 0090. 0090. 0036. 0090.0090. 0090.0090.0090.0090.0090.0090. 0090.0090.0090. 0090.0090.00
R. FAC0. 6741. 4971. 4260.2620.6973. 0471. 1432. 8321. 3902.8701. 9990.0800. 4460.4191.2460. 9860. 4490. 9220. 4490. 9840.3991. 0900.4460.2400.9840. 9421. 1390.4490.7820. 7330. 9440.4900.8860. 9100. 9111.249
R.PAC<L)0. 6741.4971. 4260.2620. 6973. 0471. 1432. 8321.3902.8701.9990.0800. 4460.4191.2460. 9860. 4490. 9220. 4490. 9840.3991.0900. 4460. 2400. 9840. 9421. 1390. 4490.7820. 7330. 9440.4900. 8860. 9100. 9111.249
RATIO1. 001.001.001.001.001.001. 001.001. 001. 001.001. 001. 001.001. 001. 001. 001.001.001.001.001.001. 001.001.001.001.00
> 1 . 00' 1.00
1.001. 001. 001.001.001.001.00
y03218013
7/27/88 7:47:26ACQUISITION STARTED
' W I R E07/27/88 7: 46: 00 + 0:04
SCAN 1 OF 1020
RUN 0:VST07271FREE SECTORS:1S113
000256
ACQUIRINGSCAN: 2 OF 1020
SAMPLE: CLP,41693,WH2216.V8TD090. MED,SOIL.V8T07271.VOA.CC-OSOCONDS.: »INSTRUMENT-OHA9» EPA CLP METHOD (VOLATILES)FORMULA: SOIL INSTRUMENT: OWAS WEIGHT: 0.000SUBMITTED BY: ITFK ANALYST: WET ACCT. N O . : 41699LOU MASS:HIGH MASS:
33300
UP:DOWN:
1. 99 L*0. 00 L
TOP:BOTTOM:
0. 00O.OS
CENT S/P: 37 ACTUAL:FRAO S/P: 20 ACTUAL:
MIN PEAK WIDTH: 1A/D THRESHOLD: 1
3719
SAMP INT <MS): 0.200SAMP INT (MS): 0.400
MIN FRAG WIDTH X:BASELINE: 0
SO
PEAK WIDTH: 1000.INTEN/ION: 2
MIN AREA: 23
MODE: CENTROID POSITIVE IONINTERFACE NUMBER 0SUB-INTERFACE NUMBER 0tt OF ACQU BUFFERS 16INSTRUMENT TYPE aFULL SCALE MASS BOO AMUZERO SCALE MASS 1 AMUINTENSITY/ION 2
^ PEAR WIDTH 1000. MMUOFFSET AT LOW MASS 0 MMUOFFSET AT HI OH MASS 0 MMUVOLTAGE SETTLING TIME(MS) 4
ACQUISITION STARTED WITH GC FILE 1OC PARAMETERS:
M . S . TUNE PARAMETERS:MULTIPLIER VOLTS: -2082.33LOW RESOLUTION: 127.00HIGH RESOLUTION: 126.00ION ENERGY: 3. 33ION PROGRAM: 3. 96LENS VOLTAGE: -29.80EXTRACTOR: 0.94ELECTROMETER RANGE: 7k 00ELECTROMETER ZERO: S. 74
2SO DEOSO DEC230 OEQ4 MIN
S.0 D/M60 MIN250 DEC90 DEO
ZONE TEMP.INITIAL TEMP.FINAL TEMP.INITIAL TIMERAMP RATEFINAL TIMESEP. SET PT.MANIF. SET PT.
INJ. MODE: PKD1 SEC • DV OPN
7/27/88 8:21:12ACQUISITION COMPLETEDSCANS 1 TO 1020 CENTROID
DIDSCANS
1020SECS OUT OF X
263.0 2040.0 12.9PEAKS PER SCAN26814. 26.
PER SEC13.
IT fDATitREFE
MR
PRO
,
< CNO
123496789
101 1IS131413
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IfTICALLE:V8TO;E; LIB30: V09»T: CLP
3TANDARJSEO P
6
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3UND >ENTRY
133496789
101 1121314IS161718192021222324292627282930313233343336373839404142434446
sex v ic7271RARYVET INIS88
0881
8 PROC
< ———REF
-306-632-781-394-746-911-48-76-97
-128-200-226-232-299-293-293-332-398-371-396-398-433-449-498-461-906-914-933-946-992-993-994-989-658-699-690-708-701-792-789-843-999-989-969-269
E8
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PRED308639789396790919477697
128200226233296294294333399372398400439447460463908916939949999999937992631703693712709796789847960994970270
DIAO*
ZATIO*
—— PIPROC
49
42 ft
— SC^8EL308639789396790919477999
129199226234298299299333360372399401439447461463908917936948994
992630
693711703796789847961999970269
X08TIC
H OPTIC
.US UNKuses
42
3UND
DELTA
-t-2-3-I
1211
1
11
1
11
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-1
-1-2
11
-1
REPORT
M: 2
I.NOUN8P088
3
PEAK8111111111111211111111111111111
11
1111111111
PROCESSINO C
—- X - LI81RM8 5TANDAF99 CLPISBBy
FIT PEAK8992994981972984949991969991860991979939971984981990993984987931993991969988976980992979970
978 '.992
992 '.939997989991998997990966980
3PTION
T NAHEfM/WWW/CLP UK
n/i12811411769989990946264844396937696639683627297
1 1 743836379
13012997787963
1734343
1648398
112106104106106103
7/27/
4
B - >MOWNW
TOP307639789396790914477999
12619922623429929429»333'361372399401439447461463908917936948994996997992630702693710702796788847961999970269
f
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CHRO —————— :DELTA PEAKS
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8AVOLATILE INTERNAL STANDARD AREA SUMMARY
Lab Naur: iffl< - KJl)01(..\)llLe•7^/at
Contract:• fTFt
000258
Ab Coda: >TSTO Can Mo.: MK.TS SAS Ho.: _____ SDG Ho.; \A^ ZZat.
Lab File ID (Standard): u^-rd^ > Oaf Analyzed; o-rlg-Jea
Instnufnt ID: Ol^fl 5" Tia« Analyzed: o-7tj(,
Matrix: (•oil/wafr) Sol'- L«vl: (low/Bed) ftxefi Coluan: (pack/cap) •p.AC^
0304
13 HOUR STD————-——"
UPPER LIMIT
LOWER LIMIT
ZPA SAMPLENO.
yBLtV^tt-?^l.3H221(.l»&Uiri •;'2H.MAC>lArtZzn^H 2Z70U rt Z Z Z Iv»rt 2 Z Z ZUrt Z Z Z W
ISX(BCM)AREA »
<^\q(."————————
S(>3fl?
;4oqft
?nsaqSS274S^f^''233T<•SS'^22.US7&Zsq^O73eeqrusyo
RT
10. g 3
10. Z710. 361B.Z7(0. 27IB.?3
lo.Z->10. ^^fO.20
IS2(DrB)AREA «
1 V\ 9 He^q<.5Z
(tttOfc
iz&e&zin3ff3(nqara,,e?371 1 ^ 8 = 71.40Z.S1?OS'/5,?zo^IZ25Z4.
RT
ei.n
Zl.nZl, ZO2 1 , 1 - 7zi.n21.nZl. Z&Z1 .17
2,1. n
IS3(CBZ)AREA «
1 2 1 L V 5
Zt -SOTo
(,o,8e2
use^(»71'<<f(ot«W31^110510^310nofczi
ii3fca3ny w?nfl^e
RTZ&.l-^—-.
—————••X
^•1?e&.i-rz&.n
ZA.nZfc.neti.is2<,.i5
321
ISl (BCM) • Brcmochloro—than*IS3 (DFB) • 1,4-Difluorobmsan*ZS3 (CBZ) - chl.orobiuw
UPPXR &XMXT - + 100»of infmal •candard ana.LOWER LIMIT • • 90«of int«rnal •tandard ana.
« Coliout u«*d to flag infrnal •tandard ar«a valu— with an a»fri«)i
•g* J. of _L.»OR»l VIII VOA 1/87 R»v.
03218016
Ill VOLATILES DATA, continuedd. RAW QC DATA
03218017
u?
LU --
1/1 0.g
:i-im
a:
fefeU
. <EO
J 0
<r —it- _i
••.<r -ac
1/1o
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f-TASS LIST DATA: BFB07121 » 225 BASE M/E:07/12/88 5:05:00 + 7:30 C A L I : CAL070688 tt 1 R I C .SAMPLE. CLP, , ,BFB07121 ,LOW.SOIL ,BFB07121 .VGA,CALCCNDS.: •» INSTRUMENT-OMA5* EPA CLP METHOD (VOLATILES)r^
36 0. 00 0. 00 0. M I N I M A M I N INTEN: 0.232 # O M A X I M A
MASS ;'. RA 7. R I C INTEN.
35.94?37.06?33.10?39.08"40 04?41 087'42. 08?43. 08?44.06?45.08?49.02?50. 06?5 1 . 10?54.10?5 5 . 1 0 ?56. 06? M57 OS?53.08?59.10?60.02?
,^61. 08? Mr ,2. OS? M
63.04? M68.00?6'?. 0671. 1473. 0474. 0675. 0476. 06 M79. 9081 . 0086. 0086. 9885. 0383. 9092 0094 0295. 0096. 02
147.041 4 8 . 1 2174.00175.02176.00177.00
/^-2p7. 06' >7. 20?
e'81. 66?
1 .86.4.
18.55.
17.55.36.
a.2 1 .
8.1 .2.2.
10.10.4.1 .3.a.3.5.8.2.
81.16.42.2.1 .1.2.7.
13.1 .1.6.
100.5.7.1 .
69.3.
68.3.1 .2.1 .
85620368439'?46988300220600036791345547191671089121633683200940854659301 17769005868156253886127431 1
0. 271. 240. 870. 672. 650. 860. 782. 588. 025 170. 323. 021. 150. 150. 380. 421. 491 . 520. 640. 170. 450. 390. 440. 851. 180. 38
1 1 . 692. 426. 060. 300. 200. 270. 351. 081. 910. 160. 250. 96
14. 360. 801. 100. 17
10. 000. 519. 890. 520. 180. 350. 16
45.210.147.1 1 4 .449,146.133.438.
1360.877.
54.513.195.25.65.71.
252.257.109.29.77.66.75.
144.200.
64.1982,410.
1028.51 .34.45.60.
184.334.27.43.
163.2436.
136.187.28.
1696.86.
1678.88.31.59.27.
6 9 S t7 Z 0 • • '•
MASS SPECTRUM WTAi BFB97271 »238 BASE M i 9587/27/88 7ll6l0e + 7:48 CALIi CAL848788 tl3 RICl 15888.SflMPLEl CLP,41695,MH2216,BFB87271,LOH-SOIL,BFB87271,UW,CTLCONDS.i »INSTRUMENT-ONA» EM CLP METHOD (UOLATILES)
96.1
174.1
3.1
281.3
158 200 250
MASS07/27SAMPLCQNDE
281 * 0MASS
37.38.39.40.41.42.43.44.49.46.47.49.SO.91.S9.96.97.98.99.61.
^3.-•W.
68.69.73.74.79.76.77.81.82.87.88.93.94.99.96.
174.179.176.177.267.268.269.281.
LISTV88 7•E: CLPf . : »IN
37
06?10?14?06?26?12?12?10?14?18?10? M14?12?12?10?16?14?16?14?12?18?18?14?10141412141204080814081414160808081014?20?22?26?
: 16: C.4165STRUH
0.
X
6.7.9.
19.2.4.
1 1 .63.21.
1.2.3.
24.6.1 .1 .8.7.2.3.2.1.9.
10.96.19.38.3.1 .1.1.4.
10.371.9.
100.9.
88.4.
88.4.
16.2.1,3.
»0 +>9,MIENT
00
RA
9306684932823617042932230133420800499318072912898028819212291296
814700086499309948987293
7:H221-OM
0.
X RIC
1.1 .0.2.0.0.1.9.3.0.0.0.3.0.0.0.1.1.0.0.0.0.1.1.8.2.9.0.0.0.0.0.1.0.1.
14.0.
12.0.
12.0.2.0.0.0.
406>BFk9«
00
010383273470662408183447919321161710434730183399312368971619166792263863749772927341382992
DATA:CALI:
^07271,1EPA CI
0.
INTEN.
161.164.132.360.
94.112 .264.
1468.489.29.94.79.
998.147.33.29.
186.174.68.74.48.29.
212.293.
1320.399.902.
91.26.30.26.
106.241.42.
220.2324.
118.2060.
119.2092.
116.383.60.40.82.
BFB07S71CAL04078(
LOU.SOIL,ILP METHOD
MINIMAMAXIMA
» 230 BASE1 » 13 RIC:)FB07271,VOA,CAL(VOLATILE8)
MIN INTEN:
'
: M/E: f919888.
(
0.
000262
03218021
1A EPA SArtPLS NO.VOLATILE ORGAHICS ANALYSIS DATA SHBll,,,^^^
Lab NM«; ^ps. KAJOXUILL£ Contract :
/^"^Lab Code: ^ '=>-TQ Ca«« No.: 4tl.qg SAS Ho.;
Matrix: (•oil/wafr).
SDG No.: ^HggcK.
Lab S.Bpr ID; \JHL^-n
tl fg/«L) CSainpl* wt/vcl:Lavl: (low/Md) M6P
» Moisture; not d«c.
caluBn; (p«c)t/eap) '?Ac>>
CAS HO. COMPOUND
Lab rile ID:
D«f K«e«ived: <^ lZ2.Z3/a»
0«f Analysed: o^/e^/flgDilution raetort J e-
CONCINTRATZON OMITS:(uff/L or ua/Xg> ua /fc6
74-«7-74-»3-75-01-7S-00-73-0»-<7-<4-73-13-73-33-73-34-340-39»7-<e-l07-0<7«-»3-71-33-3<-a3-101-0373-27-7»-»7-100C1-7»-01-L24-4C7»-00-71-43-100«1-(73-25--10C-10-3»1-7»-127-H-7»-34-i10«-««-10C-90-100-41-100-42-1330-2C
————Chlero»tl»«n«———Acetone———— carbon bfulzid*————l. l-0ichloro«th*n«
o———i,2-Dleblowthw (total)———cnleretoB»
———1.1. l-Trichloro««h*M———Carbon T«fcr«eblorid«4———Vinyl Ac*ff , -
————•roiMdiehloro—tauf———l.a-DlcBloroBropirl-3———-cr-l.3-Dlcnioreprep«f—————Triahlewth«r-——~—i, l, ««triehloro««han«l2-«——tri»-l,3-Dlcnloropropm«[-—————•nMfoa-l————4-Ntnyl-2-XntanoM-4————T*tr«ehloro« airl———l.l,a.2-T«tracBlBWtBlf-3 ————Teltttf•4————-»tBymm««ir-»————»tyw>»l-7————x»lir iotaLl
isao'?<?» .IS9«..17-00
<.?0izoo<fZ6(.20fcSo(.Zo(,?o<-2o
I 200(,2 a(.20
1200&,?o(,Zo(.go(ato(.za<,20to?o(.M<.20(2001200(.ZO(.^0(.^afcCfi.bZff£>20/.?0
-^———
rom z VOA 1/«7 R«V.
03218022
1E E?A SWP'.S, SO.VOLATILE ORGANICS ANALYSIS DATA SHEET
TENTATIVELY IDENTIFIED COMPOUNDS r\f\{\nCA—————00026^Lab Naur; iras- KJL)O»UU.L£ r-Bti^r—^. i "o*.^Contracts.
ITF-r-Ca«« HO.: m(,q5 SAS NO.:Lab Coda: SDG Ho.: \A)HggoC.
Lab saapr ID: \)Bl.^?lt
Lab fil» ID: UBK>7?71
Matrix: faoil/vafr) 5o<L
sampi* wt/vel: ^ (q/aL) 6_
L«vl: (low/nrd) M6b
» Moisture: not dec.____
Coluan: (pack/cap) Tftcic.
Oat* Racaivd: e7/ea.gg/ga
Data Analyzed: oT/^aa
Dilution Factor:c
COHCBITRATIOM OWITS: i' ,>,, ,NufflbT TIC« found: o (ug/L or uq/Kq) u&/fcs »'3>l»v
CAS NUMBER
123456789
101112131415161718192021222324352627282930
COMPOUND HAMZ.„.—-——.-.-,—...-.-..——
RT BST. COWC.
>
Q
.
'M,
-Ti' r13
roRM z VOX-TIC 1/87 Rav.
03218023
£ L 5 t7 3 0 •
RIC DATAi
87^27/88 8:33:88
CALIlSAMPLEl CU'-41695,HH2216-UBU<1-M
ED,SOIL,UBCONDS.i »INSTRl)HENT-OHA5»
EPA CLP (CTHOO (VOLATILES) -
\"
RANGE: G 1-1828
LABELi N 8, 4.9
QUWl
1«»- >;
S '
0i- ^
? ^
3I
^
te UJ
-? §
^ ^
<^ y
388 ?
1
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^Jl8
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/ 290
4aeL
6:48
13:28
^*•-Tn
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UBL87271 •45 SCANS
38 TO 1928 ^
?3
CftL848788 •l3
{- ip
COILB7271,UO
ft,BUW
^ •
. ®
A 6. l.fl.J
8
BftSEl U 28, 3
7
63;LU%5pS5y
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600 888
1W
SCANV
28:88
26:48 33?^
TIME
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^^.^ k
QUANTITATION REPORT FILE: VBL07271
DATA: VBL07271. TI(W27/8B 8:33:00
• PLE: CLP.41693,WH22l6,VBLKl,MED,SOIL,VBL07271,VOA,BLANKCuNDS.: •INSTRUMENT-OWA9* EPA CLP METHOD (VOLATILES)FORMULA: SOIL INSTRUMENT: OWAS MEIOMT:SUBMITTED BY: ITFR ANALYST: MET ACCT.NO.AMOUNT-AREA * REF.AMNT/<REF.AREA)* RESP.FACT))DET.LIM.- 0.00RE8P. FAC. FROM LIBRARY ENTRYNO NAME1 CI01 BROMOCHLOROMETHANE (I.S.ttl-CLP)2 CIIO 1,4-OIFLUOROBENZENE (I.S.»2-CLP)3 CI20 CHLOROBENZENE-D5(I.8.#3-CLP)4 C81S 1.2-DICHLOROETHANE-D4 ( 8 . S . » 1 )9 C805 TOLUENE-D8 (8.S.»2>6 CS10 4-BROMOFLUOROBENZENE ( 8 . S . t t 3 )7 C010 CHLOROMETHANE **8 C013 BROMOMETHANE9 C020 VINYL CHLORIDE *10 C02S CHLQROETHANE11 C030 METHYLENE CHLORIDE12 C035 ACETONE13 C036 ACROLEIN14 C037 ACRYLONITRILE15 C040 CARBON DISULFIDE16 C04S 1,1-DICHLORQETHENE *17 COBO 1.1-DICHLOROETHANE —
^~^ COS3 TRAMS-1.2-DICHLOROETHENEC060 CHLOROFORM *
20 C065 1,2-DICHLOROETHANE21 C110 2-BUTANONE22 C11S 1,1,1-TRICHLOROETHANE23 CI20 CARBON TETRACHLORIDE24 C13S VINYL ACETATE29 C130 BROMODICHLOROMETHANE26 C140 1,2-DICHLOROPROPANE •27 C143 CIS-1,3-DICHLOROPROPENE28 C150 TRICHLOROETHENE29 C1S3 DIBROMOCHLOROMETHANE30 C160 1,1,2-TRICHLOROETHANE31 C169 BENZENE32 C172 TRANS-1.3-DICHLOROPROPENE33 C179 2-CHLOROETHYL VINYL ETHER34 C180 BROMOFORM **35 C210 2-HEXANONE36 C20S 4-11ETHYL-2-PENTANONE37 C220 TETRACHLOROETHENE38 C22S 1,1.2,2-TETRACHLOROETHANE ««39 C230 TOLUENE *40 C23S CHLOROBENZENE41 C240 ETHYL BENZENE »42 C249 STYRENE43 C2SO TOTAL XYLENESC- C2S2 M-XYLENE
•J C231 TRICHLOROFLUOROMETHANENO M/E SCAN TIME REF RRT METH AREA<HOHT) AMOUNT
000266
0. 00041695
^tr-m•q-(M0
^€r'Iri/XTOT ^'^
03218025
000267
NOI
^436789
101112131419161718192021222324252627r^30313233343936373839404142434443
N0123496-,J9
M/E12811411769989930946264844336337696639683627297
11743836379
13012997787963
1734343
1648392
112106104106 3106 3103
RET(L) RATIO RRT(L»10:21:26:13:29:30:
1:2:3:
SCAN TIME REF RRT METM
1111
12222222'2222222
1
141010120028343010
308639784396790913
201227
702633710704799788846960
1.00 1.0001.00 1.0001.00 1.0001.00 1.2901. 00 0. 9331.00 1. 164
10:16 1 1.00021:10 2 1.00026:08 3 1.00013: 12 1 1 . 28629: 00 3 0. 99730:26 3 1. 169
6:42 1 0.693 A SB7:34
23:24 3 0. 899 A BV21:46 3 0.833 A BB23:40 3 0. 906 A BB23:28 3 0. 898 A BB29: 10 3 0.963 A BB26: 16 3 1.003 A*BB28: 12 3 1.079 A BB32:00 3 1.224 A*BB
0. 1930.2440. 309
0.737 A BV
RATIO1. 00 90. 001.00 30.001. 00 30. 001.00 41.811. 00 49. 481. 00 '
BBBBBBBBBBBB
AMNT
46. 34
AREA(MCHT)27989.
126862.119229.39646.73330.76492.
94.911.
884.491.28.86.27.76.43.
192.
AMNT(L) R.90.00 1.90.00 1.90. 00 1.90. 00 1.90. 00 0.30. 00 0.90. 0090. 0090.00
AMOUNT90.30.90.41.49.46.
0.0.
0.0.0.0.0.0.0.0.
FAC000000000292636664
000000000814480939
117690
407187027048016033043074
R . F A C < L >1.1.1.1.0.0.1.0.0.
UC/LUO/LUQ/LU8/LUO/LUO/L
UO/LUC/L
UO/LUO/LUO/LUO/LUO/Lue/LUO/Lue/L
000000000949643713040864940
XTOT17.2717. 2717. 2714. 4317. 1016. 08
(^)
J^-W^aa-'
.
^a,JOrW^W-^8fr-
J><-or^w/ororS^^sS'
RATIO1.001.001.000. 84 •0.99(^0.93(^
^€i ef^
03218026
5SSi
^oS^
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76
000269IT ANALYTICAL SERVICES
QA/QC REPORT' i . E : VBL07271
INTERNAL STANDARD AREA CHECK
3 OUT OF 3 ARE MITHIN SOX TO 200X OF DAILY STANDARD AREAS.
«» INTERNAL STANDARD AREAS ARE WITHIN OC LIMITS **
INTERNAL STANDARD RETENTION TIME CHECK r-
3 OUT OF 3 ARE WITHIN +/- 30 SECONDS OF DAILY STANDARD RETENTION TIME ln•^
** INTERNAL STANDARD RETENTION TIMES ARE WITHIN QC LIMITS ** CM0
03218028
7/27/88 8:33:28ACQUISITION STARTED
SCAN 1 OF 1020 000270
RUN 0:VBL07271 ACQUIRINGFREE SECTORS:17B99 SCAN: 2 OF 1020
AURE07/27/88 8:33:00 + 0:04SAMPLE: CLP,41699,WH2216,VBLK1,MED> SOIL.VBL07271,VOA,BLANKCONDS.: »INSTRUMENT-OWAS» EPA CLP METHOD (VOLATILE8)FORMULA: SOIL INSTRUMENT: OMAS MEIOHT: 0.000SUBMITTED BY: ITFK ANALYST; WET ACCT. NO. : 4169SLOW MASS:HIGH MASS:
33300
CENT S/P: 37 ACTUAL: 37FRAG S/P: 20 ACTUAL: 19MIN PEAK WIDTH: 1A/0 THRESHOLD: 1
UP: 1. 99 L»DOWN: 0. 00 L
SAMP INT (MS): 0.200SAMP INT (MS): 0.400
TOP:BOTTOM:
0. 000.03
MIN FRAG WIDTH X:BASELINE: 0
SO
PEAK WIDTH:INTEN/ION:MIN AREA:
1000.2
29
MODE: CENTROID POSITIVE IONINTERFACE NUMBER 0SUB-INTERFACE NUMBER 0« OF ACQU BUFFERS 16INSTRUMENT TYPE QFULL SCALE MASS 800 AMUZERO SCALE MASS 1 AMUINTENSITY/ION 2
F^ PEAK WIDTH 1000. MMUOFFSET AT LOW MASS 0 MMUOFFSET AT HIGH MASS 0 MMUVOLTAGE SETTLING TIME(MS) 4
ACQUISITION STARTED WITH GC FILE IGC PARAMETERS:
M.S. TUNE PARAMETERS:MULTIPLIER VOLTS: -2082. 33LOW RESOLUTION: 127.00HIGH RESOLUTION: 126.00ION ENERGY: 3. 53ION PROGRAM: 3.96LENS VOLTAGE: -29.80EXTRACTOR: 0.94ELECTROMETER RANGE: 7, 00ELECTROMETER ZERO: 2-. 74
250 DECSO DEC
230 DEG4 MIN
8.0 D/M60 MIN
290 DEG90 DEG
INJ. MODE1 SEC •
ZONE TEMP.INITIAL TEMP.FINAL TEMP.INITIAL TIMERAMP RATEFINAL TIMESEP. SET PT.MANIF. SET PT.
PKD• DV OPN
7/27/88 9:07:14ACQUISITION COMPLETEDSCANS 1 TO 1020 CENTROID
TROIDSCANS
1020SECS OUT OF X
241.8 2040.0 11.9PEAKS PER SCAN12480. 12.
PER SEC6.
03218029
0'.IT ANALYTICAL BBRVrcca DIrtONOSTIC REPORT 7/27/8B 9:07:47DATA FILE:VBL07271 i"-REFERENCE: LIBRARYVE ,^
METHOD: V08T INITIALIZATION OPTION: 2 PROCESSINO OPTION: 4REPORT: cu'1888 000271 5
< ——— STANDARDS ———— X —— PLUS UNKNOWNS —— X - LIST NAMES - >PROC USED POSS RH8 PROC USED POS8 RHS STANDARD/UNKNOWN 0
A 6 1 34 43 6 1 34 CLPIS88/CLPUNHS
43 COMPOUNDS PROCESSED. 6 FOUND
< COMPOUND >< ———-———— SEARCH ——————————— >< SAT ? < -———— CHRO —————— :NO LIB ENTRY REF PRED SB- DELTA PEAKS FIT PEAKS H/Z TOP DELTA PEAKS
1 VE 1 -306 308 308 . 996 . 138 300 . 12 VE 2 -632 633 633 . 997 . 1 1 4 633 . 13 VE 3 -TSl 784 784 . 988 . 1 1 7 784 . 14 VE 4 -394 396 396 . 978 . 63 396 . 13 VE 3 -746 749 730 1 987 . 98 730 . 16 VE 6 -911 913 914 -1 939 . 93 913 -1 17 VE 7 -48 49 . . . . . 30 . . .8 VE 8 -76 77 . . . . . 94 . . .9 VE 9 -97 99 . . . . . 68 . . .
10 VE 10 -138 130 . . . . . 64 . . .1 1 VE 1 1 -200 202 . . . . . 84 201 . 112 VE 12 -236 238 . . . . . 43 287 . 113 VE 13 -233 234 . . . . . 36 . . .14 VE 14 -333 237 . . . . . 33 . . .13 VE 13 -233 233 . . . . . 76 . . .
«| VE 16 -293 299 . . . . . 96 . . ./ VE 17 -332 334 . . . . , 63 . • .
18 VE 18 -338 360 . . . . . 96 . . .19 VE 19 -371 373 . . . . . 83 . . .20 VE 20 -396 398 . . . . . 62 . . .21 VE 21 -398 400 . . . . . 73 . . .33 VE 33 -433 433 . . . . . 97 . . .33 VE 33 -449 447 . . . . . 1 1 724 VE 24 -498 460 . . . . . 43 . . .29 VE 23 -461 463 . . . . . 83 . . .26 VE 26 -306 909 . . . . . 63 . . .27 VE 27 -914 917 . . . . . 79 . . .28 VE 28 -933 936 . . . . . 130 . . .39 VE 39 -946 949 . . . . . 129 . . .30 VE 30 -998 999 . . . . . 97 . . .31 VE 31 -998 999 . . . . . 78 . . .33 VE 33 -334 997 . . . . . 79 . . .33 VE 33 -989 998 . . . . . 63 . . .34 VE 34 -628 631 . . . . . 173 . . .39 VE 39 -699 703 . . . . . 43 708 . I36 VE 36 -630 633 . . . . . 43 693 . 137 VE 37 -708 711 . . . . . 164 710 . I38 VE 38 -701 704 . . . . . 83 704 . I39 VE 39 -792 733 . . . . . 92 799 . 140 VE 40 -783 788 . . . . . 1 1 3 78B . 341 VE 41 -843 846 . . . . . 106 846 . 1' VE 42 -999 939 . . . . . 104 960 . 8
.J VE 43 -989 993 . . . . . 106 . . .44 VE 44 -969 969 . . . . . 10643 VE 46 -369 271 . . . . . 103
03218030 ^CC
I . T . ANALYTICAL SERVICESLIBRARY SEARCH REPORT
VOLATILE ORGANIC ANALYSISiTA FILE: VBL07271LIBRATION FILE: CAL040788
aEARCH OF LIBRARYVE
000272
SCAN COMPOUND
308 CI01 BROMOCHLOROMETHANE <I.S.«1-CLP)63S CI10 1.4-DIFLUOROBENZENE <I.S. W2-CLP)7S4 CI20 CHLOROBENZENE-DSd. 8. #3-CLP)396 CS13 1 > 2-DICHLOROETHANE-D4 (S.S.«1)790 CS09 TOLUENE-D8 (8. S.tt2)913 CS10 4-BROHOFLUOROBENZENE <S.S.»3)
DELTA PUR-FIT <AMT
NOFLAOS
> SAT LIB
0 985-W8 SO 0 00 908-999 SO 0
0 926-981 30 0 00 949-984 42 0 01 949-996 49 0 00
-2 699-7S4 47 0 -3 ,^1
03216031
FILE VBL07271 PEAK HEIOHTS AND COMPUTED AMOUNTS BY SCAN NUMBER:
(^•N LIMIT SET AT 9.0 UNITS^c£ ALL PEAKS FOR LIBRARY SEARCH
000273
308 27304.S 50.0635 49648. 3 50.0785 36298.8 50.0
03216032
1AVOLATILE ORGANICS ANALYSIS DATA SHE EPA SAMPLE N O .
Lab Maaa; ^ -XAJOXtii^g contract: I 10 H Z Z / < o «tS ,
I T F KLab C0d«: /T5TU Car NO.! OlbqS SAS MO. :
Matrix: (aoil/vafr)_^.i_
Saapla vt/vol: L> (?/»!.) 6_
L«vl: (low/aed) M£P
t Moistur*: not d«e. S -
coluinn: (pack/cap) 7flc.fc
SD6 Mo.; touggaCp
Lab Saapl* 10:
Lab ril« 10:
Oaf Racaivd:
Oaf Analyrd:g7f??|g3/gft
n7^7^^Dilution Factor» >
CAS NO. COMPOUNDCONCXMTXATZON OHITS;(ufl/I. or uq/Ka) ua. /ks
74-B7-74-»3-7S-01-7S-00-7S-0»-•7-<4-7S-15-75-3S-75-34-540-39«7-«6-l07-0<7«-93-71.-53-5»-23-l0«-0575-27-7B-B7-100(1-79-01-124-4«79-00-71-43-l00<l-<75-as-aloa-xo-59l-7«.ia7-r-7»-34-SI0a-«a.ioa-90'100-4X-100-43-1330-2C
•——...vinyl Chloride
-———Carbon Ofulfid*—————I.1-Oichloroathana
—————l.1,1-Trichloroathan*————carbon Tafcraealorid*4.————Vinyl Aeataf • - •
——.—l.a-OicbloreBroBtf1-5———ci«-l. 3-Diehloropropw—————Triehloroathan* '33TT—————X,1.2-Triehloro«tb«n«
l2.«——txwfl,3«0iehloreprop«ri——————Broaofon-l~»~—4-)tothyl-i-fmianon«
-4 ————T«tr«chi,or5it55»»———-i ,1,2, a-T»traoBiere»tnan»
•3———Telu«f.4 ————Kthylbwm
i-7————XvioJM ^oiall
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£ 8 S 17 3 0a '»RIC DATAl HH2338S •45 SOWS 38 TO 1029 § v ^ =
07/27/88 10:22:09 CALIi CALB40788 «13 00 ^-^SAMPLE; CLP,41695,MH2216,MH2216S,»CD,SOIL,HH2338S,IWI,MS ^ 3
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QUANTITATION REPORT FILE: HM2338S nnnnnoOUU<;7bDATA: HH2338S.TI&.V27/88 10:22:00
' 1PLE: CLP,41699.WH22l6,MH2216S,MED,SOIL-HH23388,VOA.MSCUNDS.: *IN8TRUMENT-OUA9* EPA CLP METHOD <VOLATILES)FORMULA: SOIL (1:129) INSTRUMENT: OMA3 HEieHT: 0.000SUBMITTED BY: ITFK ANALYST: MET A C C T . N O . : 4169SAMOUNT-AREA * REF.AMNT/(REF.AREA)* RE8P.FACT))DET.LIM." 0.00RESP. FAC. FROM LIBRARY ENTRYNO NAME1 CI01 BROMOCHLOROMETHANE (I.S.ttl-CLP)2 CI10 l>4-DIFLUOROBENZENE (I.S.ttS-CLP)3 CI SO CHLOROBENZENE-DS(I.S. «3-CLP)4 CS15 1.2-DICHLOR06THANE-D4 (S.S.ttU9 C809 TOLUENE-D8 ( S . S . • 2 )6 CS10 4-BROMOFLUOROBENZENE (S.S.*3)7 CO 10 CHLOROMETHANE •«8 CO IS BROMOMETHANE9 COaO VINYL CHLORIDE «10 C02S CHLOROETHANEIt C030 METHYLENE CHLORIDE12 C03S ACETONE13 C036 ACROLEIN14 C037 ACRYLONITRILE19 C040 CARBON OISULFIDE16 C045 1,1-DICHLOROETMENE •17 C090 I,I-DICHLOROETHANE •*
^~^ COS3 TRANS-1.2-DICHLOROETHENE/ C060 CHLOROFORM «
20 C069 1,2-DICHLOROETHANE21 CI10 2-BUTANONE22 C119 1,1,1-TRICHLOROETHANE23 C120 CARBON TETRACHLORIDE24 C125 VINYL ACETATE29 C130 BROMODICHLOROMETHANE26 C140 1<2-DICHLOROPROPANE *27 C143 CIS-1.3-DICHLOROPROPENE28 C190 TRICHLOROETHENE29 C199 DIBROMOCHLOROMETHANE30 C160 1.1,2-TRICHLOROETHANE31 C169 BENZENE32 C172 TRAN8-1,3-DICHLOROPROPENE33 C179 2-CHLOROETHYL VINYL ETHER34 C180 BROMOFORM •*39 C210 2-HEXANONE36 C20S 4-METHYL-2-PENTANONE37 C220 TETRACHLOROETHENE38 C229 1,1,2.2-TETRACHLOROETHANE »*39 C230 TOLUENE »40 C239 CHLOROBENZENE41 C240 ETHYL BENZENE »42 C249 STYRENE43 C290 TOTAL XYLENESf C292 M-XYLENE 03218035
.J C291 TRICHLOROFLUOROMETHANE
• t-00in<a-<M0
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000278NO RET<L) RATIO R R T ( L ) RATIO10 4: 12 0. 410
/J-4 6:38 1.02 0.648 1.027:32 1.02 0.736 1.02
*J 7:48 0.76214 8: 38 0. 84419 8:28 0.82716 9:50 1.00 0.961 1.0017 11:06 1.08318 12:02 1.17619 12:24 1.21220 13:18 1.30021 13:22 1.00 0.631 1.0022 14:30 0. 68923 14:94 0.70424 19:22 1.00 0.726 1.0029 19:26 0. 72926 16:96 0. 80027 17:14 0.81428 17:92 1.00 0.844 1.0029 18:16 0. 86330 18:28 0. 87231 18:32 1.00 0.876 1.0032 18:34 1.00 0.877 1.0033 19:44 0. 93234 21:00 0.99239 23:24 0. 89436 21:46 0.832
i-- 23: 40 0. 90423:24 1.00 0.894 1.01
39 29: 12 1. 00 0. 963 1. 0040 26:16 1.00 1.004 1.0041 28:14 1.07942 32:02 1.22443 33:10 1.26844 32:20 1.23649 8: 98 0. 876
AUNT AMNT<L) R.FAC R.FAC<U RATIOSO. 00 0. 674
0.73 90. 00 0.021 1.497 0.013. 36 90. 00 0. 067 1. 426 0.09
90. 00 0. 26290. 00 0. 69790. 00 3. 047
99.14 90.00 1.260 1.143 1.1090. 00 2. 83290.00 1.39090. 00 2. 87090. 00 1 . 999
3. 06 90. 00 0. 009 0. 080 0. 0690. 00 0. 446 \0
90. 00 0. 419 000.03 90.00 0.001 1.246 0. 00 m
90. 00 0. 98690. 00 0. 44964. 00 0. 922
46.24 90.00 0.419 0.449 0.9290. 00 0. 98490. 00 0. 399
91.16 90.00 1.116 1.090 1.021.89 36.00 0.023 0.446 0.09
90. 00 0. 24090. 00 0. 98490. 00 0. 94290. 00 1. 13990. 00 0.449 .
0. 09 90. 00 0. 001 0. 782 • 0. 0092.61 90.00 0.771 0.733 1.0999.31 90.00 1.044 0.944 1 .11
90. 00 0. 49090. 00 0. 88690. 00 0. 91090. 00 0. 91190.00 1.249
<a-(M0
000279IT ANALYTICAL SERVICES
^, QA/QC REPORT' LE: HH2338S
INTERNAL STANDARD AREA CHECK
3 OUT OF 3 ARE WITHIN 50X TO SOOX OF DAILY STANDARD AREAS.
*« INTERNAL STANDARD AREAS ARE WITHIN QC LIMITS «*
INTERNAL STANDARD RETENTION TIME CHECK (~-
3 OUT OF 3 ARE WITHIN +/- 30 SECONDS OF DAILY STANDARD RETENTION TIME Lr\c '
»•• INTERNAL STANDARD RETENTION TIMES ARE WITHIN 3C LIMITS ** 040
03218038
7/27/OB 10:23:27ACQUISITION STARTED
r^UIRE
07/27/88 10:22:00 + 0:04
SCAN I OF 1020
RUN O:HH2338SFREE SECTORS:17942
000280
ACQUIRINGSCAN: 2 OF 1020
SAMPLE: CLP,41695,WH2216,MH2216S,MED,SOIL,HH2338S,VGA,MSCONDS.: *INSTRUMENT-OWA9» EPA CLP METHOD (VOLATILES)FORMULA: SOIL (1:129) INSTRUMENT: OWA9 UEI8HT: 0.000SUBMITTED BY: ITFK ANALYST: MET ACCT. NO.: 41699
TOP:BOTTOM:
0. 000. 05
PEAK WIDTH:INTEN/ION:
1000.2
UP: 1. 99 L*DOWN: 0. 00 L
LOM MASS:HIGH MASS:
33300
37 SAMP INT (MS): 0.20019 SAMP INT (MS): 0.400
CENT S/P: 37 ACTUAL:FRAC S/P: 20 ACTUAL:MIN PEAK WIDTH: 1A/D THRESHOLD: 1
MIN FRAG WIDTH X:BASELINE: 0
SO MIN AREA: 29
MODE: CENTROID POSITIVE IONM.S. TUNE PARAMETERS:MULTIPLIER VOLTS: -2082.39LOW RESOLUTION: 127. 00HIGH RESOLUTION: 126. 00ION ENERGY: 3. 93ION PROGRAM: 9. 96LENS VOLTAGE: -29.SOEXTRACTOR: 0. 94ELECTROMETER RANGE: 7. 00ELECTROMETER ZERO: 2'. 74
INTERFACE NUMBER 0SUB-INTERFACE NUMBER 0tt OF ACQU BUFFERS 16INSTRUMENT TYPE QFULL SCALE MASS SOO AMUZERO SCALE MASS 1 AMUINTENSITY/ION 2
( " PEAK WIDTH 1000. MMUOFFSET AT LOU MASS 0 MMUOFFSET AT HIOH MASS 0 MMUVOLTAGE SETTLING TIME<MS) 4
ACQUISITION STARTED WITH GC FILE 1OC PARAMETERS:290 DEC
90 OEO230 DEO
4 MINS. 0 D/M60 MIN
290 DEC90 DEG
INJ. MODE1 SEC •
ZONE TEMP.INITIAL TEMP.FINAL TEMP.INITIAL TIMERAMP RATEFINAL TIMESEP. SET PT.MAN IF. SET PT.
PKD" DV OPN
7/27/SS 10:97:13ACQUISITION COMPLETEDSCANS 1 TO 1020 CENTROID
CO03ini-
CM0
MODE SCANS' TROID 1020
SECS OUT OF X23S. 0 2040.0 1 1 . 7
PEAKS PER SCAN20204. 20.
PER SEC10.
03218039
o-\IT ANALYTICAL SCTVICCa OlAeNOBTtC HCPOUT T/27/BB 10: 37: 46DATA FILE:HHa3388 03REFERENCE: LIBRARYVE ,,-,
METHOD: V08T INITIALIZATION OPTION: a FBOCE9SINO OPTION: 4 nnnOQ1REPORT: CLPI8SB UUU<;01 . -
< ——— STANDARDS ———— X —— PLUS UNKNOUNS —— >< - LIST NAMES - > c\1
PROC USED POSS RMS PROC USED POS8 RHS STANDARD/UNKNOWN 06 6 2 0 3 43 11 1 6 3 CLPIBBa/CLPUNKS
43 COMPOUNDS PROCESSED, 11 FOUND
< COMPOUND >< -—-—————— SEARCH —————————— >< SAT > < ————— CHRO ————— ;NO LIB ENTRY REP PRED BEL DELTA PEAKS FIT PEAKS M/Z TOP DELTA PEAKS
1 VE 1 -306 30T 309 . 3 999 . 12S 30S -1 1a VE 3 -633 639 636 1 997 . 114 633 -1 13 VE 3 -7S1 7S4 7S4 . 983 . 117 7S4 . 14 VE 4 -394 397 397 . 9B3 . 69 397 . 13 VE 9 -746 749 790 1 986 . 98 790 . 16 VE 6 -911 914 913 -1 934 . 99 913 . 17 VE 7 -48 91 . . . . . 90 . . .8 VE 8 -76 79 . . . . . 94 . . .9 VE 9 -97 100 . . . . . 63 . . .
10 VE 10 -128 131 . . . . . 64 . . .11 VE 11 -200 203 . . . . . 84 203 . 118 VE 13 -226 229 . . . . . 43 331 . 113 VE 13 -232 239 . . . . . 96 . . .14 VE 14 -399 298 . . . . . 93 . . .19 VE 19 -293 296 . . . . . 76 . . .
. VE 16 -293 396 296 . 1 983 . 96 396> . 1./ VE 17 -332 339 . . . . . 63 . • .18 VE 18 -398 361 . . . . . 96 . . .19 VE 19 -371 374 . . . . . S3 . . .30 VE 30 -396 399 . . . . . 63 . . .21 VE 21 -390 401 . . . . . 7 2 402 . 122 VE 22 -433 436 . . . . . 97 . . .S3 VE S3 -449 448 . . . . . 117 .24 VE 34 -498 461 . . . . . 43 462 . 229 VE 29 -461 464 . . . . . 83 . . .26 VE 36 -906 909 . . . . . 63 . . .27 VE 27 -914 917 . . . . . 79 . . .38 VE 38 -933 936 936 . 1 990 . 130 936 . 139 VE 29 -946 949 . . . . . 129 . . .30 VE 30 -992 999 . . . . . 97 . . .31 VE 31 -992 999 996 1 1 906 . 78 996 . 132 VE 35 -B94 W . . . . . 73 SS7 . 133 VE 33 -989 993 . . . . . 63 . . .34 VE 34 -628 631 . . . . . 173 .39 VE 39 -699 703 . . . . . 43 . . .36 VE 36 -690 693 . . . . . 43 . . .37 VE 37 -708 711 . . . . . 16438 VE 38 -701 704 . . . . . 83 709 . 339 VE 39 -792 799 799 . 1 991 . 92 799 . 140 VE 40 -789 788 788 . 1 990 . 118 788 . 1"1 VE 41 -843 846 . . . . . 106
VE 42 -999 998 . . . . . 104 . . .-.3 VE 43 -989 998 . . . . . 106 . . .44 VE 44 -969 968 . . . . . 106 . . .49 VE 46 -269 372 . . . . . 103 -_,....,..,-_ rf" .
032l8040iP ,|tf
1A E?A SAMPLE NO.VOLATILE ORSANICS ANALYSIS DATA SHEEI,,^nQO
ITA^ -f<Uox\)iLif____ contract;_______ J ^rt 2Z |b c<$pLa6 NaB«;_
<^Lal» Coda: Ca«« NO.: ^KS SAS NO.: SOS No. s to»gg6to
Lab saapr ID; Hti^^pMatrix: (•oil/wafr) sail.
Sanpitt wt/vol: H Lato fir ID; rtrt zsy? ss^
Dat. Racaivd: o7fz?.gJ/ft»
Oaf Analyzed: ft^lg-^aa
Dilution factor:
L«Vl: (loW/Bttd) Mfcp
t Moi«tur«: not d<c. 82.
ColuBn; (pack/cap) 'Mc.fc
CAS NO. COMPOUNDconcmrnATioM OMITS:(ug/l. or uq/Xal of, /k^ o
74-B7-74-«3-75-01-75-00-75-0»-•7-M-7S-15-75-35-7S-34-540-59<7-<6-107-0678-93-71-55-5<-23-101-0575-27-7»-a7-100C1-C79-01-<124-4C-79-00-i71-43-3100«1-(7S-25-3loa-io-591-7B-127-H-7»-34-iloa-«a-ioa-90-100-41-100-42'1330-2C
-—————Vinyl Chlorid*
———Ae»ton»————— carbon Dfulfid*——————1. l-Dichloro««t>m*————l,l-Dichloro«than«o———l,a-Dichlero»tto«n« ^total)2————1.2-0ichloro«than«———2-But»non«———l,l,l-Trichlorowtnan*4———Vinyl Aetttaf— ———•reMdiehloroMuan*
Bl-5——ei«-l. 3-Oieblorooropw ,i-—————Trichlowth«r.l————-Dibro^chloraMthan«l———l,l,a-Trichlereth*»ii2-«*«~—tzm«-l, 3-0iehloroprop«r[—————•reaofora-X————4-Mthyl-2-P«ntailon«-4 ————T«tr«cttloro<tl»«n«i———l.l.a.2-T«traehloroatlaJf "-3 —————TOlUMf-7—————anero6<tti«»n»•4————KChvlb«l«UM•s—————stvrir . , , ,i-7————xvlir detail
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QUANTITATION REPORT FILE: HH2339SD 000284DATA: HH2339SD.TIQ.Z/27/88 11:06:00
' SPLE: CLP,41693,MH2216.UH22168D,MED.SOIL.HH2339SD,VOA,USDCLINDS.: »INSTRUMENT-OWA9» EPA CLP METHOD (VOLATILE8)FORMULA: BOIL (1:123) INSTRUMENT: OMAS MEIOHT:SUBMITTED BY: ITFK ANALYST: WET ACCT.NO.AMOUNT-AREA • REF.AMNT/<REF.AREA)* RE8P.FACT)lDET.LIM.- 0.00RESP. FAC. FROM LIBRARY ENTRYNO NAME1 CI01 BROMOCHLOROMETHANE (I.S.ttl-CLP)S CI10 1.4-DIFLUOROBENZENE <I.S.tt2-CLP)3 C120 CHLOROBENZENE-DS(I.S.«3-CLP >4 CS15 1>2-DICHLOROETHANE-D4 O . S . t t I )9 CSOS TOLUENE-DB (S. S. tt2>6 CS10 4-BROMOFLUOROBENZENE (S.S.#3)7 CO 10 CHLOROMETHANE **8 C01S BROHOMETHANE9 C020 VINYL CHLORIDE «10 C023 CHLOROETHANE11 C030 METHYLENE CHLORIDE12 C039 ACETONE13 C036 ACROLEIN14 C037 ACRYLONITRILE15 C040 CARBON DISULFIDE16 C049 1,1-DICHLOROETHENE »17 COBO 1>1-DICHLOROETHANE »*
/-•^ COS3 TRAN8-1.2-DICHLOROETHENEC060 CHLOROFORM »
20 C063 1,2-DICHLOROETHANE21 CI10 2-BUTANONE22 C11S I,1-1-TRICHLOROETHANE23 C120 CARBON TETRACHLORIDE24 C129 VINYL ACETATE23 C130 BROMODICHLOROMETHANE26 C140 1,2-DICHLOROPROPANE »27 C143 CI8-1,3-DICHLOROPROPENE28 C1SO TRICHLOROETHENE29 C199 DIBROMOCHLOROMETHANE30 C160 I,1,2-TRICHLOROETHANE31 C163 BENZENE32 C172 TRAN8-1.3-DICHLOROPROPENE33 C17S 2-CHLOROETHYL VINYL ETHER34 C180 BROMOFORM *•39 C210 2-HEXANONE36 C20S 4-METMYL-2-PENTANONE37 C220 TETRACHLOROETHENE38 C22S 1,1.2.2-TETRACHLOROETHANE »»39 C230 TOLUENE *40 C239 CHLOROBENZENE41 C240 ETHYL BENZENE •42 C24S STYRENE43 C290 TOTAL XYLENES^ C292 M-XYLENE
-. C291 TRICHLOROFLUOROMETHANENO M/E 8CAN TIME REF AREA<HOHT» AMOUNT RRT METH
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000287
n IT ANALYTICAL SERVICESQA/QC REPORT
h.E: HH2339SD
INTERNAL STANDARD AREA CHECK
3 OUT OF 3 ARE WITHIN 90X TO 200X OF DAILY STANDARD AREAS.
»• INTERNAL STANDARD AREAS ARE WITHIN QC LIMITS *«
INTERNAL STANDARD RETENTION TIME CHECK incr'.m
3 OUT OF 3 ARE WITHIN */- 30 SECONDS OF DAILY STANDARD RETENTION TIME - -i-CM
*• INTERNAL STANDARD RETENTION TIMES ARE WITHIN QC LIMITS — Q
03218046
7/27/88 11:06:32ACQUISITION STARTED
SCAN 1 OF 1020000288
HIRE RUN 0:HH2339SD ACQUIRING07/27/88 11:06:00 + 0:04 FREE SECTORS:17337 SCAN: 2 OF 1020SAMPLE: CLP,41695.WH2216« UH2216SD,MED,SOIL.HH2339SD,VGA,MSDCONDS.: »INSTRUMENT-OWA9» EPA CLP METHOD (VOLATILES)FORMULA: SOIL (1:129) INSTRUMENT: OWA9 HEIGHT: 0.000SUBMITTED BY: ITPK ANALYST: WET ACCT. NO. : 41699
TOP:BOTTOM:
0.000. 05
LOW MASS: 35HIGH MASS: 300
UP: 1. 93 L»DOWN: 0.00 L
SAMP INT (MS): 0.200SAMP INT (MS): 0.400
CENT S/P: 37 ACTUAL: 37FRAG S/P: 20 ACTUAL: 19MIN PEAK WIDTH: 1A/0 THRESHOLD: 1
MIN FRAG WIDTH X: 90BASELINE: 0
MODE: CENTROID POSITIVE IONINTERFACE NUMBER 0SUB-INTERFACE NUMBER 0ft OF ACQU BUFFERS 16INSTRUMENT TYPE QFULL SCALE MASS 800 AMUZERO SCALE MASS 1 AMUINTENSITY/ION 2PEAK WIDTH 1000. MMUOFFSET AT LOW MASS 0 MMUOFFSET AT HIGH MASS 0 MMUVOLTAGE SETTLING TIME(MS) 4
ACQUISITION STARTED WITH CC FILE 1GC PARAMETERS:
ZONE TEMP.INITIAL TEMP.FINAL TEMP.INITIAL TIMERAMP RATEFINAL TIMESEP. SET PT.MANIF. SET PT.
29090
2304
8.060
29090
NJ.1
DEC -DEG •DEG -MIN «D/M -MIN "DEG •DEG •
MODE:SEC •
PKDDV OPN
7/27/88 11:40:37ACQUISITION COMPLETEDSCANS 1 TO 1020 CENTROID
PEAK WIDTH: 1000.INTEN/ION: 2MIN AREA: 29
M . S . TUNE PARAMETERS:MULTIPLIER VOLTS: -2082. 39LOW RESOLUTION: 127.00HIGH RESOLUTION: 126.00ION ENERGY: 3.93ION PROGRAM: 9. 96LENS VOLTAGE: -29.80EXTRACTOR: 0. 94ELECTROMETER RANGE: 7» 00ELECTROMETER ZERO: V. 74
t*nDEiTROID
SCANS1020
8EC8237.7
OUT OP2040.0
X PEAKS PER SCAN1 1 . 7 23133. 23.
PER SEC1 1 .03218047
r-... 0\
IT ANALYTICAL SERVICES DIAGNOSTIC HBPOBT - 7/87/88'il: 40; 34, lDATA FILE:HH8339SO , - -.-REFERENCE: LIBRARYVE nhrt^Ra"
METHOD: VOST INITIALIZATION OPTION: a PROCES8INO OPTION: 4 UlHJ't09 CMREPORT: CLPI8S8 Q
< —— STANDARDS ———— X —— PLUB UNKNOWNS ——-X - LIST NAHES -,?PROC WSeS P088 RHS PROC USED POSB IMS STANDARD/UNKNOWN
6 6 2 33 49 1 1 1 64 CLPISS8/CLPUNHB
43 COnPOUNDS PROCESSED, 11 FOUND
< COMPOUND X —————————— SEARCH ————————— X SAT, > < —————• CHRP r n"K'l.«. :NO LIB ENTRY REF PRED SB. DELTA PEAKS FIT PEAKS M/» " TOP DELTA PEAKS :
1 VE 1 -306 301 308 . 3 993 . 199 308 . li -2 VE 2 -638 633 633 . 997 . 11-4 635 . 1 ,3 VE 3 -781 784 784 . 974 . 11.7- 7B* . 1; •4 VE 4 -394 396 396 . 900 . 63 396 . t ' -3 VE 3 -746 749 749 . 994 . 9» 749 . I6 VE 6 -911 914 913 -1 933 . 93 913 . 17 VE 7 -4B 30 . . . . . BO . .B VE B -76 78 . . . . . 94 ;9 VE 9 -97, 99 . . . . . 63 . . . .
10 VE 10 -129 130 . . . . . 64 ,. .1 1 VE 11 -300 202 . . . . . 84 201 . !•12 VE 12 -326 288 . . . . . 43 231 . 113 VE 13 -832 234 . . . . . 36 . . .14 VE 14 -839 297 . . . . . 93 . . .19 VE 19 -233 899 . . . . . 7fc
•> VE 16 --293 299 299 . 1 988 . 96 293, . 1VE 17 -338 334 . . . . . 63 . • .
18 VE 18 -338 360 . . . . . 96- . . .19 VE 19 -371 373 . . . . . 83 , .20 VE 20 -396 398 . . . . . 68-•••• if21 VE 81 -398 401 . . . . . 72- 408 . 122 VE 22 -433 436 . . . . . 97- > .83 VE 33 -449 448 . . . . . 117-.24 VE 34 -438 461 . . . . . 4 3 438 . 329 VE 89 -461 464 . . . . . 83 . . .86 VE 86 -306 309 . . . . . A3. .27 VE 27 -914 917 . . . ... . 7s- »• • •28 VE 28 -933 936 936 . 1 999 . 130' 936 . 129 VE 89 -946 349 . . . . . 18930 VE 30 -998 999 . . . :, , . 97 , ,31 VE 31 -998 999 396 1 1 991 . 78 396'. . I32 VE 38 -394 937 . . . . . 79 • 396 . 133 VE 33 -989 398 . . . . . 6 8 .34 VE 34 -688 631 . . . . . 173-.39 VE 33 -699 703 . . . . . 43-136 VE 36 -630 . 633 . . . . . 43. 693 . 837 VE 37 -70B 711 . . . . . 1 6 4 .,»< . -. .38 VE 38 -701 "704 . . . . . 83 7B4l . 839 VE 39 -798 799 799 . 1 990 . 92 73j»-7 . 140 VE 40 -789 788 788 . 1 993 . 113 787 -1 14t VE 41 -843 846 . . . . . 106
VE 42 -999 998 . . . . . 104 ..1 VE 43 -989 993 . . . . . 106, . .,.•..-
44 VE 44 -963 968 . . . . . 106- 968 . 149 VE 46 -269 371 . . . . . 103 . • ./• •
0^048 ^1»^
