Remediation Journal Volume 4 issue 1 1993

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    Technical and Economic

    Analyses in the Development

    of Bioremediation Processes

    Paul R. Ammann Guyh

    S. Koch

    Paul Ammann i s a

    principal of m e Bra &

    Group, an economic,

    management, and

    environmental

    consulting

    im

    n Ciambridge,

    Massacbusetts. He bas

    more tban tbirty years'

    experience

    in

    tbe

    developmat, costs, and

    applications of

    environmental,

    cbemicd

    and metallurgical

    tecbtwhgies. He fcwluses

    one n dm e n t a l

    consulting

    in

    tbe areas

    of

    CERCLA

    cost recovery,

    evaluatiolS

    R&D

    planning, and tecbnical

    and market feasibility

    analysis. Gayle

    S.

    Kocb

    i s

    a principal of Tbe Bra &

    Croup. Sbe bas

    evaluated environmental

    liabilities in connection

    witb settlements,

    Utigatioff, nsurance

    recovery,

    acquisitions

    and

    sales

    and strategic

    planning.

    environmental

    uabiuty

    Ihe ve latge extent

    of

    subsugace and groundwater contamination

    with toxic otganic compounds has prompted research on a number of

    bioremedialprocesses. Ihejustification

    of

    this research has been to achieve

    lower overall remedial costs than are incurred by currently existing

    technologies. Laborato studies are often undertaken with the notion that

    a new set ofprocess conditions can reduce reagent consumption or the time

    for treatment

    by

    a signijkant actor with an attendant reduction in overall

    remediation costs. Research programs are initiated on the basis

    of

    these

    simple premises. Our work has shown that many research projects have

    been undertakenfor the wrong reasons and that eqerimental effort has

    ojen not been directed toward latge-scale implementation.

    A preliminaryprocess analysis has been shown to be a very valuable

    componentofany research and developmentprogramon bioremedial and

    other innovative technologies.As described in this article, the analysis 1 )

    identipes the critical engineering and cost parameters and (2) provides

    guidance to the research program in the design

    of

    eqeriments and the

    collection

    of

    data. 7he methodology is also useful in the

    review

    ofproposed

    new technologies and treatment equipment. 7he article includes an

    exampleof a process analysis

    for

    an actual development project directed

    toward the remediationofsolids contaminated with chlorinated hydrocar-

    bons to illustrate the benefits and the power of the technique.

    Bioremediation processes offer potential for lower-cost remediation of

    soils, sludges, and sediments and surface and subsurface water contami-

    nated with organic compounds than other physical, chemical, or thermal

    processes. Consequently, large efforts are being directed to research and

    develop bioremedial processes. Because

    of

    the large costs

    of

    R&D

    programs, of developing and proving new technologies, and the improve-

    ments in and the competition of existing remedial processes, it is prudent

    to focus studies toward realistic commercial remedial opportunities.

    This article describes an approach for the evaluation

    of

    applications

    of

    research results

    to

    full-scale remediation. The discussion addresses the

    treatment of soils, sludges, and sediments, but the methodology is also

    applicable to water treatment processes.

    REMBDIATION/WINTER993/94 115

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    AB he requirements

    of

    even higher

    etandi,wda

    of

    ckanup

    ore

    being applied

    throughout the

    country, the need for

    lower cost

    olutions is

    becoming even more

    important.

    OPPORTUNXTIWNEEDS

    Organic contamination is present in soils, sludges, and even in

    sediments

    of

    rivers and streams. The types

    of

    contaminants vary from

    volatile solvents to less volatile compounds such as polyaromatic hydro-

    carbons (PAHs) and polychlorinated biphenyls (PCBs). Contaminants

    occur as small hot

    spots,

    as well as large areas with a number

    of

    compounds

    distributed throughout the area.

    Organic contamination h s also migrated from disposal areas into

    surface waters and groundwater. Through groundwater movement, sub-

    surface plumes of organic compounds exist at many locations throughout

    the world.

    A

    wide variety

    of

    remediation processes

    exists

    for the treatmentof soils,

    including physical (e.g., vacuum extraction), chemical (e.g., solvent

    extraction), and thermal (e.g., low temperature desorption and incinera-

    tion) processes. New processes are also being developed or are evolving

    from the industrial sector, as equipment used for commercial reasons is

    modified

    to

    satisfy needs in remediation. These existing and evolving

    technologies compete with bioremediation in the environmental remediation

    market.

    Remediation costs

    for

    contaminated soils and waters are generally

    high. As the requirements of even higher standards of cleanup are being

    applied throughout the country, the need for lower-cost solutions is

    becoming even more important.

    In much of the published work in the bioremediation industry, the

    focus is on technical issues, such as (1) reaction mechanisms and

    (2)

    kinetics as a function of contaminant mix,

    soil

    types, and concentrations

    of relevant contaminants and components. Although this type of research

    is essential for the successful development of new processes, it appears

    that there has been

    less

    attention paid

    to

    design concepts and the

    economics of technologies that could result from the research. Early

    attention

    to

    the technology development and costs is vital to achieve cost-

    effective research programs.

    BIOTREATMENT

    PROCESSES

    It

    appears that biological treatment processes will play an important

    role in the future in remediation of areas of contamination. Biological

    treatment processes exhibit some intrinsic advantages compared to other

    alternatives. These include:

    Low

    reagent costs

    Typically, nutrient requirements are small and

    the costs therefore tend to

    be

    low.

    Low

    energy

    costs In the absence

    of

    a need

    to

    heat biological

    treatment systems more than, say, 10 o 2OoC energy requirements

    tend to

    be

    low. Most of the energy needs are for mechanical energy

    to

    move solids and liquids.

    Low capital costs Reaction systems in which organics in solids or

    liquids are mixed with organisms and nutrients are typically simple.

    For example, solids treatment processes use conveyors, reagent

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    F BIOREMEDIATION

    ROCESSES

    mix tanks, and large contactors. Consequently, the capital costs

    tend to

    be

    small in comparison with other treatment systems such

    as thermal desorption or incineration.

    Environmental acceptance.Biotreatment processes operate at low

    temperatures, and gas flows, such as air for oxidative treatment, are

    small. Any air emissions

    of

    concern can

    be

    controlled at very

    modest cost with existing technology. Similarly, water discharge

    streams can

    be

    treated with conventional water treatment pro-

    cesses. If necessary, any stream can

    be

    pasteurized

    to

    destroy

    microorganisms.

    There are, however, potential major disadvantages

    to

    biological

    treatment processes. Some of these are:

    The selection o f one of

    the

    available

    options

    is

    baaed

    on

    echnical

    feasibili ty, overall

    economics, and

    satisfaction o f

    regulatory matters

    and

    public concerrta.

    Relatively long treatment times. In contrast to chemical, physical,

    or thermal treatment processes in which reaction times typically

    vary from seconds or minutes

    to

    less

    than an hour, biological

    treatment processes often require days or months. Consequently,

    reactor vessels are much larger than for alternative treatment

    processes, and/or cleanup times may

    be

    extended significantly.

    Incomplete destructioddegradationof organics. Biological water

    treatment systems, such as activated sludge, are very effective for

    destruction

    of

    many organic compounds. However, biological

    treatment systems may not be as effective for the destruction

    of

    certain toxic organic compounds, particularly in soils, sludges, and

    sediments.

    Dzflcult application.For many toxic organic compounds, specific

    organisms are required to achieve degradation or destruction. In

    some instances, indigenous microorganisms either have limited

    effectiveness

    or

    are ineffective for reactions with toxic organic

    compounds. For in-situ applications, there may be additional

    complications such as preferential pathways for nutrients or

    biodegradation under anaerobic conditions.

    T icity. The presence of certain elements, such as heavy metals

    or

    compounds, may limit the effectiveness

    of

    microorganisms.

    Primarily effectiveon otganic contaminants.Bioremediation pro-

    cesses are generally iimited

    to

    soils and solids contaminated only

    with organic compounds. If heavy metals are present, for example,

    either bioremediation is only one component of remediation, or it

    may not

    be

    cost-effective compared

    to

    alternatives.

    SELECI'ION OF ALTERNATIVES

    In planning the remediation of sites contaminated with organic

    compounds, environmental managers usually have several process op-

    tions available. The selection

    of

    one

    of

    the available options is based on

    technical feasibility, overall economics, and satisfaction of regulatory

    matters and public concerns. For biotreatment processes, some of the

    decision criteria are described in the following section.

    R E M E D X A T I O N ~ ~ I N T E R

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    Whether a cleanup i s

    carried out

    by

    a

    remedial contractor

    or by the owner of a

    property, the total

    cost

    i s

    governed

    by

    the initial

    investment. .

    Technical Feasibility

    Tech nical feasibility is, of course, critical to the selection of a remedy.

    It is also a k ey focus of much of the ongoing research an d development

    work in bioremediation.

    Effective organism.

    The degradat ion

    of

    selected organic com-

    po un ds from initial conc entrations to specified cleanu p levels must

    be demonstrated in a field setting. The demonstration becomes

    complicated if there are m ultiple organic compo unds or other

    contaminants of conce rn (e.g., metals) present at a site.

    Rates and extentof degradatioddestruction.

    The rates

    of biocon-

    version are important to the econo mics, as described later, but it

    is also important that the biological reactions redu ce the levels of

    toxic organic compounds to the required cleanup levels. This

    criterion is important if cleanup levels con tinue to decrea se in the

    future. For example, Jerger et al. (1993) reported on the slurry

    reactor treatment of soils that significantly reduce d the levels

    of

    creosote but did not reach the required cleanup levels.

    Control

    of

    reaction conditions.

    The microorganisms should be

    consistently effective in degrading o r destroying haz ardou s organic

    com poun ds, and the reactions should not be subject to poisoning

    or

    loss

    of effectiveness during a large-scale site remediation.

    Typeofequipment.Biotreatment processes are often ad vantageous

    becau se they typically employ simple p rocess equipme nt, such as

    tanks and solids-liquids contactors.

    Economics

    Overall costs play a very large role in the selection of a remediation

    process. Whether a cleanup

    is

    carried out by a remed ial contractor

    or

    by

    the own er of a pro perty, the total cost is gove rned by th e initial investment

    for the process equipment, the direct operating costs for site cleanup, and

    a financial return o n the u se of the equipment.

    Studies. Significant expenses may

    be

    incurred for treatability

    studies, pilot tests, an d other studies. Study costs are generally

    higher for new, unproven technologies.

    Investment.

    The capital cost of the biotreatment process must

    be

    recovered from its operation at on e o r more sites. If a process is

    dedicated to o n e site, the soil volume must be sufficiently large so

    that the allocation

    of

    the investment

    to

    the

    soil

    treatment

    is

    acceptable. A lternatively, transportable equ ipm ent allows flexibil-

    ity for treatment

    of

    larger soil volume at multiple

    sites.

    Because

    there is a large element of uncertainty abo ut h ow many sites and

    the quantity

    of solids

    or liquids that may

    be

    treated by an

    equipm ent p ackag e, it is important that the cost of equipment be

    kept as

    low

    as possible. Investment may

    be

    reduced by using

    standard equipm ent, such as tanks a nd reactors, and establishing

    proces s conditions that allow the shortest

    possible

    treatme nt times.

    ~ ~~

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    TECHNICAL

    ND ECONOMICNAL.YSESN THE

    DEVELOPMENT

    F BIOREMEDIATIONROCESSES

    ...here may be

    concern over

    introduction of

    microbes into the

    environment,

    particularly

    for

    new,

    genetically deeigned

    organism.

    Unit treatment cas

    Technologies with the lowest overall treat-

    ment costs that meet the cleanup requirements are sought in the

    feasibility studies.

    Pmject size.

    Large projects can achieve economies of scale and

    therefore relatively smaller unit costs.

    Utilization.

    Equipment costs may

    be

    spread over a number

    of

    sites.

    To the extent that a transportable process

    is

    not used continuously,

    the owner/operator must allocate fixed costs accrued during

    downtime to each site.

    RegulatoryIssuesand Public Acceptance

    All remedial processes must have operating permits and should be

    acceptable

    to

    local communities and neighboring residents. In contrast

    to

    some technologies such as incineration,

    in

    which stack emissions are of

    concern, biotreatment processes should receive acceptance because solid

    and liquid discharges from biotreatment processes should comply with all

    applicable regulations. However, there may

    be

    concern over introduction

    of microbes into the environment, particularly for new, genetically

    designed organisms. Regulatory and public acceptance issues that must be

    addressed include:

    Permits and appmvaki. State and local permitting can be an

    expensive and time-consuming process. In addition, for many

    hazardous waste sites, bioremediation must

    be

    compared with

    alternative treatment options and approved based on cost and

    effectiveness criteria.

    Risks to humansand environment.Studies should be conducted

    to

    show that the bioremedial process will reduce risks

    to

    humans and

    the environment

    to

    the desired level.

    Public perceptions.

    Public perception

    of

    any risks introduced by

    the bioremedial process must be addressed, often by holding

    public meetings and making site documents and site experts

    available

    to

    the public.

    Many bioremediation research programs focus exclusively on techni-

    cal feasibility. However, because ultimate project success will also be

    strongly influenced by economics, regulatory issues, and public accep-

    tance, it

    is

    important that significant attention

    be

    paid

    to

    these areas as well.

    A L T A T I V E T R E A ~ P R 0 c E S S E S

    Developers of bioremediation technologies must keep in mind that

    these technologies will ultimately compete in the marketplace against

    other remedial options. The options for the remediation

    of

    contaminated

    solids and water are different.

    Remediation of

    Soils,

    Sludges,

    and

    Sediments

    The remediation of

    soils,

    sludges, and sediments can generally be

    divided into two major categories: excavation with on-site or off-site

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    PAULR AMMA GAYLE

    .

    KOCH

    treatment a n d in-situ treatment.

    Excavation with on-site

    or

    08-site treatment.

    Excavation not o nly

    adds

    cost

    to the remediation

    of

    a site, but it also

    poses

    som e risk

    of

    spreading contamination into

    the

    environment an d adds health

    risks

    to

    the remediation workers. However, postexcavation treat-

    ment

    is

    used extensively for the remediation

    of

    contaminated

    solids.

    Some

    of

    the most important processes are listed

    beIow

    (Lewis, 1993):

    Incineration

    Thermal desorption

    Thermal aeration

    Solids washing

    Solvent extraction

    Land farming

    Composting

    Slurry pha se bioreaction

    The last three alternatives emp loy microorganism s

    to

    achieve degradation

    or destruction

    of

    the organic contaminants.

    In-situ treatment.

    Degradation

    or

    destruction

    of

    organic com-

    pounds without excavation has some advantages over the pro-

    cesses described ab ove. O ne important factor

    is

    the savings

    of

    the

    excavation cost, which may

    be

    significant, but not

    as

    large

    a s

    the

    treatment

    costs. In

    addition, risks to humans and the environment

    throug h direct contact o r inhalation of contaminants are reduced.

    Some

    of

    the alternatives that ar e available include:

    Soil vapor extraction

    (SVE)

    Vapor extraction with h eating o r fracturing (hardrock)

    Solidification/containment

    Vitrification (fusion of soils)

    Infrared heating

    Soil flushing (active

    o r

    natural)

    Soil flushing with biotreatm ent

    Bioventing

    Remediation

    of

    Contaminated

    Water

    The remediation

    of

    contaminated surface and groundw ater can also

    be

    divided into two major categories: surface treatment an d in-situ treatment.

    Surface treatm ent.

    There are several options available for the

    surface treatment of contam inated wa ter. Many are derivatives of

    municipal wastewater treatment systems. Water treatment plants

    may be comprised

    of

    several modules according

    to

    the chemical

    complexity

    of

    the w ater. For exam ple, organic removal

    or

    destruc-

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    TECHNICAL

    ND ECONOMICM,YSB

    IN TH

    DEVBU~PMENT

    F BIOREMEDIATION

    ROCESSES

    The olids are

    excavated, screened to

    remove oversize Solid8

    ...

    and conveyed to

    storage bins.

    tion may be preceded by a metals removal step. Some of the

    organic treatment or removal modules may be:

    ChemicaVUV oxidation

    Adsorptiodabsorpt ion

    Biotreatment processes

    Air stripping (with o r without heat)

    When hazardous wastes have contributed to contamination of either

    surface waters or groun dwa ters that have migrated off-site, the contami-

    nated plume may be collected in wells and either treated off-site or

    pumped back to the site where the contamination

    is

    located. Physical

    barriers such as slurry walls may also

    be

    used to impede or prevent

    contaminant migration.

    In-situ treatment. In contrast to the surface treatment approaches

    described abo ve, new developm ents have be en directed toward

    the in-situ degradation of organic contaminants in groundwater.

    There are two general approaches:

    Injection of microorganisms and nutrients

    Pumping groundwater, surface addition of organisms, and

    reinjection (in this concep t, the aqu ifer bec om es th e reactor,

    saving the costs

    of

    construction of reactors at th e surface)

    At various stages in the bioremediation R&Dprocess, managers should

    evaluate and upda te their perception

    of

    the com petitive positioning of their

    technology versus alternative, competing technologies. Further

    R&D

    expenditures can then

    be

    focused o n areas that are likely

    to

    have usable,

    commercially feasible results.

    TECHNICALAND ECONOMIC ANAL.YSIS

    OF ON-SITE

    BIODEGRADATION

    PROCESSES

    As an example of the technical and economic analysis approach

    to

    evaluating conceptual remedial alternatives, a slurry-phase biodegradation

    process for treatment of soils contaminated with organic compounds is

    considered. A conceptual process is shown in

    Figure

    1.

    The solids are

    excavated, screened to remove oversize solids (which in this case, for

    simplicity are o nly a small fraction), an d conv eyed to storage bins. From the

    bins, the solids are conveyed

    to

    one

    of

    the bioreactors. The reactor

    is

    partially

    filled with liquids before the solids are added. One tank is used

    for

    the

    preparation of the chemical reagentdnutrients an d the addition of microor-

    ganisms, if needed. The bioreactors are operated in batch m ode. When the

    reaction is com plete, the slurry is discharged to settling pond s, wh ere most of

    the solids separate from the solution. The overflow solution is fdtered and

    collected in a tank for analysis prior to recycle or discharge. The treated

    sol

    can

    be

    returned to the excavation area after analysis indicates that the levels

    of

    contaminants a re

    below

    the target conce ntrations.

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    Figure 1. Conceptual Slurry-Phase Biodegradation Process.

    Preparat ion Tanks

    7

    Waste Liquid

    Storage Tanks

    Recycle to Process

    To disposal

    Treated Soil

    The process operating parameters are described in

    Table

    1.

    It

    is

    assumed that the plant ope rates 350 days a year, twenty-four hours a day.

    The

    soil

    slurries are h eated

    to

    the optimal temperature for the biodegra-

    dation process.

    As an illustration, a factored ca pital cost estimate for a project has been

    developed an d is shown in Table 2. For this process the total investmen t

    is calculated at about 2.3 million. N o t e that

    it is

    important to include all

    foreseen capital costs, including not only purchased equipm ent, but also

    installation, instrumentation, and other ancillaries, foundations and

    site

    improvements, land, engineering design, startup, taxes, and any other

    exp ected costs. In addition, contingencies in the range of 5 percent to 35

    percent should

    be

    added ; the amount

    is

    related

    to

    the level

    of

    engineering

    detail available at the time of the estimate.

    A n estimate of the operating costs is shown in Table 3. For this

    example, the cost of chemical reagen ts is estimated at about 45per cubic

    yard

    ( 33

    per ton)

    of

    soils.Although most of the reagent costs should be

    low, hydrogen peroxide, for example, could

    be

    very expensive. The

    electrical energ y costs are calculated at ab out $20

    per cub ic yard

    ( 15

    per

    ton). Intrinsically, the electrical m achinery requirem ents ar e low,However,

    because of the long treatment times, the energy of the mixers in the tanks

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    TECHNICALND ECONOMICNALYSESN THE DEVELOPMENTF B I O R E M E D I A ~ O NROCESSES

    Table

    1

    Operating Parameters for the Slurry-Phase Biodegradation

    Process.

    Annual operation

    Bioreadors

    50

    weeks per year

    7 days per week

    350 days per year

    24 hours per day

    20,000 gallons each

    3 reactors

    days per week

    1 shift per day

    25 to 30 percent

    oils

    slurry density

    Operating

    temperature

    20

    to 30

    degrees Centigrade

    Granular,

    sandy soils

    Table

    2.

    Illustrative Capital Cost Estimate for the Slurry-Phase

    Biodegradation Process.

    Item

    Purchased equipment

    Equipment installation

    Insulation

    Instrumentation and control

    Piping

    Electrical installation

    Buildings and foundations

    Yard improvements and service facilities

    PHYSICAL

    COST

    Land

    SUBTOTAL

    Engineering design and construction

    Stamp expense

    Sales taxes and shipping costs

    8

    750

    1 550

    1 550

    750

    2 300

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    Table 3. Illustrative O perating Costs for Slurry-Phase Biodegradation

    Process.

    Bases: 5,924 cubic yards per

    year

    350

    days

    per

    year

    24

    hours per day

    New Investment: $2,226,901 (with 25%contingency)

    Item

    Unit

    Cost ( /yd3)

    1.

    PROCESS MATERIALS

    Reagents and miscellaneous

    2.

    UTILITIES

    Electrical

    energy

    3. OPERATION

    Hourly

    and supervision

    4 MAINTENANCE

    Labor

    and supplies

    5. SAMPLING

    AND

    CHEMICAL ANALYSIS

    6. OTHER

    DIRECT OPERATING

    COST

    45

    2

    60

    30

    40

    20

    215

    may beco me significant. Here is on e exam ple

    of

    ho w minimizing reaction

    times can reduce operating costs. Th e third com ponen t is the cost

    of

    hourly

    labor and supervision. The staffing requirements are very im po rta nt -to

    minimize costs, the process should operate unattended as much as

    possible. For the small throughput in this example, the labor and

    supervision costs are estimated at abou t

    $60

    per cubic yard

    ( 45

    pe r ton).

    This example illustrates how th e con ceptua l design mu st consider staffing

    needs.

    Another cost item is maintenance-in this exam ple the cost is

    calculated at about $30per cubic yard ( 23 pe r ton). Maintenance is directly

    related to the plant d esign; the us e of state-of-the-art equ ipm ent an d simple

    process designs can minimize maintenance nee ds. Because operation

    is

    at

    ambient temperatures,

    maintenance should be less of a factor in

    bioremediation p rocesses than, say, high-temperature incineration equip-

    ment. Sampling an d analysis

    costs

    we re estimated at 40 per cub ic yard

    ($30

    per

    ton).

    If

    the remediation

    is

    carried out by a contractor, there are typically othe r

    indirect costs, which include project management and home office

    suppo rt. In our example, these costs are estimated at approximately $20

    per cubic yard

    ( 17

    per ton).

    124

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    IN

    TKE

    DEVELOPMENTF

    BIOREMEDIATIONROCESSES

    Figure 2. Illustrative Treatment Costs for a Slurry-Phase Biodegradation Process.

    400

    300

    9

    u

    Q

    200

    u,

    c

    v

    u

    c

    .

    C

    =

    1

    0

    Note : Cos ts are very spec i f ic

    t

    process and s i te

    cond i t i ons .

    There fore these cos ts shou ld not

    be used for s i te or techno logy eva luat i ons .

    5 10 15

    20

    Project Size (Thousand Cubic Yards)

    I

    25

    Overall, the operating costs in the illustrative example total an

    estimated

    $215

    per cubic yard

    ($165

    per ton). These costs are for a

    particular plant design and operating rate. An extension

    of

    the analysis

    to

    examine the costs as a function of a project size shows the importance of

    the cost components described above (Figure 2). Although chemical

    reagents and utilities are almost independent of the project size, unit labor

    and maintenance costs, amortization, and profit decrease with larger

    quantities

    of

    soils tested.

    In-Situ Trea tme nt

    To avoid costs and potential problems associated with excavation and

    handling

    of soils,

    significant research and development efforts are being

    devoted

    to

    in-situ treatment of contaminated soils and groundwater.

    Concepts include biodegradation, and chemical and thermal processes, as

    described earlier.

    A conceptual in-situ biodegradation process is illustrated in Figure 3.

    In contrast to the slurry phase reactor in Figure

    1

    the surface facilities are

    reduced to essentially solution storage tanks, reagent makeup tanks, and

    solution filtration equipment. A n array of injection and recovery wells

    replace the slurry-phase bioreactors and the solids handling equipment.

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    Figure

    3.

    Conceptual In-Situ Biotreatment Process.

    Reagent Preparat ion Tanks

    The net effect is a lower investment. An important difference, however,

    is

    that a slurry-phase reactor provides the most intimate contact between the

    liquid and

    soil

    phases for reaction, whereas the naturally occurring ground

    is an imperfect reactor for carrying out chemical reactions.

    Estimates

    of

    the operating costs, assuming similar solution composi-

    tions to the slurry-phase treatment process, are presented in Table 4 . The

    apparent advantage

    is

    lower utilities, operation, and maintenance costs.

    What is not captured in this cost estimate for in-situ treatment

    is

    the fact

    that the overall effectiveness

    for

    contact between reagents and the

    contaminants maybe very low and cleanup standards may not be reached

    except after extraordinarily long times. Hence, treatment costs may actually

    be more expensive than projected.

    FOCUS OF R D

    biodegradation system should be

    to:

    This simple analysis shows that the focus of research on this conceptual

    1. Demonstrate adequate degradation

    of

    the hazardous organics to

    meet cleanup standards.

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    Table

    4.

    Illustrative Operating Costs for In-Situ Biotreatm ent.

    Bases: 5,000 cubic yards per year

    350

    days per year

    24 hours per day

    New Investment:

    $600,000

    Unit

    Cost ($/yd3)

    tem

    1.

    PROCESS MATERIALS

    Reagents and miscellaneous

    2. UTILITIES

    Electrical energy

    3.

    OPERATION

    Hourly and

    supervision

    4 . MAINTTNANCE

    Labor

    and supplies

    5 SAMPLING

    AND

    CHEMICAL

    ANALYSIS

    6

    OTHER

    DIREC OPERATINGCOST

    5

    3

    40

    7

    40

    15

    150

    2.

    Ascertain cond itions that achieve the m aximum rates wh ile attaining

    the goals

    of

    sufficient

    or

    complete b iodegradation.

    3. Select reaction co nditions that use the lowest-cost reagents.

    Laboratory stud ies should be conducted so that, to the extent possible, the

    reaction cond itions simulate the larger scale reactions.

    The next

    step

    in the evaluation p rocess is to compare the bioremediation

    parameters

    to

    com peting alternative technologies. Is 215 per cubic yard

    high or low? Is the process equally competitive at high volumes as at low

    volumes? How does the process co mp are in me eting clea nu p goals? Will

    permitting and public acceptance

    be

    an advantage or disadvantage

    compared

    to

    alternative technologies? What is the likely return o n further

    investment in

    R&D?

    If

    these issues are addressed early, the success

    of

    bioremediation R D can

    be

    improved significantly by providing focus to

    the

    effort

    and building the m anagement suppo rt critical for project success.

    CONCLUSION

    Biotreatment processes provide alternatives for the remediation of

    contaminated

    solids,

    such as soils, sludges, and sediments, and for

    contaminated groundwater. Engineers and regulators faced with the

    remediation of these sources of toxic compounds have many treatment

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    alternatives from which to select. Many thermal, physical, chemical, and

    biological treatment processes have been demonstrated on a large scale

    and are

    in

    use. None

    of

    these processes

    is

    universally applicable

    to

    all

    situations because of technical limitations and/or unacceptably high costs.

    Bioremediation processes offer attractive options in situations where

    organic contamination

    is

    the primary problem; and in many situations, the

    costs are lower than competing technologies. However, before embarking

    on potentially expensive and time-consuming R&D, it is important

    to

    examine technical and economic feasibility. By identlfying early on the

    parameters that will lead

    to

    success, and by understanding alternative

    technologies and their competitive position

    in

    the remediation market

    place, companies can more effectively guide their R&D projects to

    successful commercial results.

    REFERENCES

    1.

    Jerger, D.D ., D.J. Cady, and J.H. Exner. 1993. Full-Scale Slurry-Phase Biological

    Treatment

    of

    Wood-PreservingWastes.Paper presented at In Situ and On-Site Bioreclamation,

    the S econd International Sympo sium, San Die go, April 5-8.

    2.

    Lewis, Ronald

    F.

    1993. SITE Dem onstration

    of

    Slurry-Phase Biodegradation

    of

    PAH

    Contaminated Soil .

    k

    G

    aste

    43cApril): 503.

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