newtowncreek.infonewtowncreek.info/docs2/2 Remedial Investigation...Alpha Analytical Deliverable...

Alpha Analytical Deliverable PackageAlpha SDG: L1219133Client: Anchor QEA, LLCSite: NEWTOWN CREEK RI

The original project report/data package is held by Alpha Analytical. This report/data package is paginated and should be reproduced only in its entirety. Alpha Analytical holds no responsibility for results and/or data that are not consistent with the original.

of 329

Sample Receipt

of 329

Sample Delivery Group Information

of 329

Sample Delivery Group Form

L1219133Laboratory Job number:

FEDEXSamples Delivered by:

799229525739TrackingnumYesBill Of Laden

PresentCoc Present

IntactContainer Status samples frozen 10/19/12 KLSample IDs

YesAll Containers Accounted For?

NoWere Extra Samples Received?

YesDo Sample Labels and COC agree?

YesAre Samples in Appropriate Containers?

YesAre Samples Received within Holding time?

N/ApH of Samples upon Receipt

Initial pH Final pHpreserved in house with

N/AChlorine Check

Other Issues

NoAre VOA/VPH Vials Present?

YesAre samples Properly Preserved?

Reagent H2O Preserved vials Frozen on

N/AFrozen by Client

N/A

N/ASoils: Is MeOHCovering the Soil?

N/AAqueous: Do Vials Contain Head Space?

A Absent No No No No

Cooler SealIce Present

Blue IcePresent Temp. (Celsius)

Frozenupon Receipt

Delivered Direct fromSite

15.4 - IR Gun

10/19/2012 09:22

Anchor QEA, LLCClient Account:

Received:

Call Tracker #

Project Manager: Review Date:Chris Anderson 10/25/2012

Project Number:

Project Name:

120782-01.01

NEWTOWN CREEK RI

Received by: KEVIN LAPLANTE

of 329

LIMS Chain of Custody

of 329

ALPHA ANALYTICAL LABORATORIES, INC. LOGIN CHAIN OF CUSTODY REPORT

Oct 31 2012, 11:32 am

Login Number: L1219133Account: ANCHOR Anchor QEA, LLCProject: 120782-01.01 Newtown Creek RI

Received: 19OCT12 Due Date: 31OCT12 Sample # Client ID Mat PR Collected Container ______________________________________________________________________________________________________

L1219133-01 SED-20121017-01 3 S0 17OCT12 15:10 1-Amber-A.25 | A2-DPKG-FULL Package Due Date: 11/01/12

A2-DPKG-FULL,A2-PEST-8081,A2-TS,QA-REVIEW

______________________________________________________________________________________________________

Page 1

Logged By: Chris Anderson

of 329

Container Tracking

of 329

ALPHA ANALYTICAL LABORATORIESContainer Tracking Report

Transaction From ToContainer ID Type Status Date Response Location Operator Response Location Operator

L1219133-01A Amber-A.25 INTACT 24-OCT-12 CUSTODY A2-ORGANIC PREP Sonja Robinson A2-CUSTODY-REFRIG-D3 A2-CUSTODY-REFRIG-D3 Sonja Robinson

L1219133-01A Amber-A.25 INTACT 24-OCT-12 CUSTODY A2-CUSTODY-REFRIG-D3 Sonja Robinson A2-ORGANIC PREP A2-ORGANIC PREP Sonja Robinson

L1219133-01A Amber-A.25 INTACT 24-OCT-12 CUSTODY A2-WET CHEMISTRY Kathy Bates A2-CUSTODY-REFRIG-D3 A2-CUSTODY-REFRIG-D3 Kathy Bates

L1219133-01A Amber-A.25 INTACT 24-OCT-12 CUSTODY A2-CUSTODY-FREEZ-W9 Kathy Bates A2-WET CHEMISTRY A2-WET CHEMISTRY Kathy Bates

L1219133-01A Amber-A.25 INTACT 24-OCT-12 CUSTODY A2-CUSTODY-REFRIDGE Dianne Janak A2-CUSTODY-FREEZ-W9 A2-CUSTODY-FREEZ-W9 Dianne Janak

L1219133-01A Amber-A.25 INTACT 23-OCT-12 A2-LOGIN A2-LOGIN Dianne Janak A2-CUSTODY-REFRIDGE A2-CUSTODY-REFRIDGE Dianne Janak

of 329

Communications

of 329

Page: 1 of

Call Tracker Report

Call # 44839

1

ANCHOR10/24/12 16:21

NEED

CANDERSON

Anchor QEA, LLC

Delaney Peterson44839

120782-01.01

L1219133

The COC indicated pesticides by 1699. I contacted Delaney and confirmed that we are to

analyze this sample for pesticides by 8081.

Call #:Call Date:

Status: Acct #:

Operator:

Contact:Company:

Project #:

Client Proj:

Login #:

Call Details

LiveType:

10/24/12 16:21Date:

of 329

Page: 1 of

Call Tracker Report

Call # 44956

1

ANCHOR10/31/12 11:40

NEED

CANDERSON

Anchor QEA, LLC

Delaney Peterson44956

120782-01.01

L1219133

From: Delaney Peterson [mailto:[email protected]]

Sent: Wednesday, October 31, 2012 11:36 AM

To: Chris Anderson

Subject: RE: 10/22/2012 eCOC

Hi Chris,

Yes, please proceed with the analysis. It was shipped without ice and is a freeze-dried

sediment.

Thanks,

Delaney

From: Chris Anderson [mailto:[email protected]]

Sent: Wednesday, October 31, 2012 8:32 AM

To: Delaney Peterson

Subject: Re: 10/22/2012 eCOC

Hi Delaney,

It seems that this sample was received at 15oC. I apologize for the oversight, we should

have contacted you the day it was received. Should we proceed with the analysis? It does

appear to be freeze dried sediment, perhaps even a SRM.

We will proceed unless I hear otherwise from you.

Thanks,

Chris

Call #:Call Date:

Status: Acct #:

Operator:

Contact:Company:

Project #:

Client Proj:

Login #:

Call Details

LiveType:

10/31/12 11:40Date:

of 329

Chain of Custody

of 329

Chain of Custody Record & laboratory Analysis RequestL/2/c;(33

\l~;~

----- .

0;-m(Q

III.•..•.. -Q) III

c:: Q)

'iii 'C- 'uc::0 ~U III.•.. CI)0 Q.

lab 10 Matrix 0 0:::Commentsz :::E:

SED 1 X

-----

CollectionOatelTime

10/17/121510

------Field Sample 10SED-20121017-1

--

laboratory Number:Date: 10/18/2012

Project Name: Newtown CreekProject Number: 120782-01Project Manager: Delaney PetersonPhone Number: 206.903.3396

Shipment Method: FedEx

Line

-I 1

2

34

56

7

8

9

10

11

1213

14

15

*Standard TAT*Level 4 data packaqe*See QAPP tables for analyte lists and QC requirements

rnhed2i-Signatunf/P~nted Name

Company: Anchor QEA, LLC

-J)Hla'-~A foJ I 'Is I \ 2- I vo 0, Date/Time

Received By:

~cA ~Signature/Printed Name

Company:

Date/Time

Relinquished By:

~~Signature/Printed Name

Company:

Date/Time

Rece~//L#rP~A_-.rOLf#,.l'.f X j, ~-

Sigrfciture/Printed Name

Company: .f\1 blAt" .•

lO(\C(/\'L' '1~22.Date/Time

Distribution: A copy will be made for the laboratory and client. The Project file will retain the original. Page _1_ of _1_ of 329

Organics

of 329

GC Extractable Analysis Pesticides

of 329

Initial Calibration

of 329

Response Factor Report HP G1530A

Method Path : O:\Organics\METHODS\ECD2-6890N\2012\Method File : PEST21029.M Title : PESTICIDES BY 8081A-ECD2Last Update : Wed Oct 31 11:02:30 2012Response Via : Initial Calibration

Calibration Files1 =F210291211.D 5 =F210291212.D 10 =F210291213.D 20 =F210291214.D 50 =F210291215.D100 =F210291216.D 150 =F210291217.D 200 =F210291218.D 0.5 =F210291210.D

Compound 1 5 10 20 50 100 150 200 0.5 Avg %RSD--------------------------------------------------------------------------------------------------

1) I BZ 192 ----------------ISTD---------------------2) S TMX - Surrogate 0.727 0.553 0.651 0.593 0.729 0.605 0.659 0.636 0.613 0.641 9.19 3) S DBOB 0.866 0.642 0.741 0.685 0.822 0.691 0.753 0.700 0.764 0.740 9.55 4) T alpha-BHC 0.913 0.749 0.862 0.854 1.081 0.968 1.049 1.040 0.787 0.922 12.94 5) T hexachloroben... 0.956 0.691 0.789 0.718 0.879 0.712 0.771 0.741 0.826 0.787 11.05 6) T beta-BHC 0.473 0.378 0.422 0.385 0.414 0.372 0.385 0.369 0.426 0.403 8.49 7) T gamma-BHC 0.921 0.738 0.851 0.812 1.021 0.894 0.967 0.951 0.884 0.893 9.57 8) T delta-BHC 0.809 0.693 0.792 0.784 0.916 0.877 0.911 0.902 0.721 0.823 10.12 9) T heptachlor 1.035 0.753 0.855 0.812 1.014 0.871 0.955 0.924 0.944 0.907 10.22 10) T aldrin 0.739 0.553 0.626 0.588 0.706 0.607 0.649 0.623 0.677 0.641 9.12 11) T chloropyrifos 0.741 0.554 0.627 0.588 0.706 0.607 0.649 0.623 0.677 0.641 9.17 12) T heptachlor ep... 0.905 0.664 0.750 0.703 0.836 0.725 0.776 0.739 0.804 0.767 9.52 13) T oxychlordane 0.903 0.665 0.750 0.703 0.836 0.726 0.776 0.739 0.807 0.767 9.49 14) T gamma-chlordane 0.909 0.700 0.792 0.750 0.881 0.799 0.862 0.825 0.840 0.818 8.00 15) T 2,4'-DDE 0.562 0.460 0.512 0.477 0.543 0.480 0.494 0.471 0.493 0.499 6.84 16) T endosulfan I 0.895 0.683 0.761 0.683 0.803 0.683 0.773 0.718 0.946 0.772 12.39 17) T alpha-chlordane 0.944 0.714 0.817 0.761 0.910 0.802 0.873 0.833 0.879 0.837 8.70 18) T trans-nonachlor 0.949 0.723 0.823 0.779 0.900 0.792 0.831 0.784 0.875 0.829 8.42 19) T 4,4'-DDE 0.727 0.612 0.690 0.678 0.735 0.749 0.758 0.734 0.674 0.706 6.59 20) T dieldrin 0.857 0.679 0.779 0.752 0.886 0.811 0.878 0.832 0.759 0.804 8.46 21) T 2,4'-DDD 0.528 0.436 0.486 0.453 0.480 0.448 0.450 0.429 0.484 0.466 6.71 22) T endrin 0.830 0.626 0.684 0.668 0.765 0.715 0.752 0.735 1.426 *L 0.999423) T endosulfan II 0.826 0.634 0.704 0.653 0.712 0.633 0.680 0.555 0.813 0.690 12.57 24) T 4,4'-DDD 0.621 0.520 0.577 0.563 0.578 0.607 0.598 0.580 0.582 0.581 4.93 25) T 2,4'-DDT 0.456 0.511 0.522 0.519 0.527 0.500 0.524 0.467 0.546 0.508 5.76 26) T cis-nonachlor 1.007 0.827 0.923 0.864 0.985 0.941 0.981 0.970 1.054 0.950 7.44 27) T endrin aldehyde 0.797 0.562 0.632 0.590 0.634 0.596 0.622 0.577 0.842 0.650 15.33 28) T endosulfan su... 0.900 0.649 0.721 0.643 0.614 0.610 0.624 0.584 0.890 0.693 17.45 29) T 4,4'-DDT 0.851 0.593 0.650 0.613 0.657 0.657 0.672 0.648 1.857 *L 0.999530) T endrin ketone 0.961 0.688 0.771 0.725 0.740 0.735 0.769 0.718 0.903 0.779 11.76 31) T methoxychlor 0.389 0.353 0.361 0.336 0.332 0.320 0.306 0.297 0.450 0.349 13.52

PEST21029.M Thu Nov 01 13:06:05 2012 Page: 1

of 329




Compound 1 5 10 20 50 100 150 200 0.5 Avg %RSD32) T mirex 0.823 0.594 0.643 0.580 0.594 0.547 0.557 0.515 0.763 0.624 16.57 33) S BZ 198 0.820 0.630 0.691 0.628 0.632 0.625 0.616 0.573 0.810 0.670 13.11 34) S DCB - Surrogate 0.775 0.624 0.696 0.622 0.597 0.587 0.557 0.526 0.732 0.635 13.02 35) T Toxaphene 0.000 -1.00 36) T Technical Chl... 0.000 -1.00

Signal #2 Calibration Files1 =F210291211.D 5 =F210291212.D 10 =F210291213.D 20 =F210291214.D 50 =F210291215.D100 =F210291216.D 150 =F210291217.D 200 =F210291218.D 0.5 =F210291210.D

Compound 1 5 10 20 50 100 150 200 0.5 Avg %RSD--------------------------------------------------------------------------------------------------

1) I BZ 192 ----------------ISTD---------------------2) S TMX - Surrogate 0.879 0.718 0.831 0.775 0.939 0.783 0.842 0.832 0.764 0.818 8.11 3) S DBOB 0.896 0.703 0.814 0.762 0.894 0.756 0.814 0.775 0.808 0.802 7.86 4) T alpha-BHC 1.118 0.926 1.065 1.040 1.314 1.180 1.284 1.302 0.994 1.136 12.51 5) T hexachloroben... 1.139 0.904 1.016 0.945 1.121 0.918 0.980 0.960 1.045 1.003 8.43 6) T beta-BHC 0.596 0.471 0.538 0.514 0.562 0.488 0.508 0.494 0.508 0.520 7.53 7) T gamma-BHC 1.100 0.890 1.020 0.984 1.200 1.075 1.151 1.168 0.950 1.060 9.99 8) T delta-BHC 1.027 0.853 0.955 0.940 1.067 1.045 1.086 1.098 0.963 1.004 8.08 9) T heptachlor 1.118 0.876 0.992 0.932 1.143 0.951 1.056 1.044 1.012 1.014 8.58 10) T aldrin 1.072 0.818 0.942 0.886 1.064 0.918 0.999 0.985 0.929 0.957 8.57 11) T chloropyrifos 0.597 0.479 0.521 0.489 0.529 0.432 0.439 0.416 0.545 0.494 12.05 12) T heptachlor ep... 1.054 0.812 0.917 0.862 0.993 0.852 0.916 0.890 0.964 0.918 8.25 13) T oxychlordane 0.960 0.736 0.830 0.771 0.875 0.720 0.754 0.725 0.895 0.807 10.70 14) T gamma-chlordane 0.976 0.778 0.847 0.797 0.871 0.812 0.866 0.856 0.994 0.866 8.61 15) T 2,4'-DDE 0.696 0.505 0.593 0.546 0.602 0.521 0.542 0.511 0.692 0.579 12.70 16) T endosulfan I 0.970 0.740 0.854 0.792 0.905 0.762 0.835 0.794 0.894 0.838 8.90 17) T alpha-chlordane 0.978 0.775 0.874 0.822 0.917 0.817 0.871 0.841 0.935 0.870 7.40 18) T trans-nonachlor 0.990 0.770 0.869 0.807 0.892 0.780 0.813 0.783 0.923 0.848 8.93 19) T 4,4'-DDE 0.801 0.651 0.731 0.700 0.739 0.741 0.763 0.757 0.749 0.737 5.70 20) T dieldrin 0.957 0.740 0.835 0.791 0.908 0.820 0.877 0.856 0.851 0.848 7.48


of 329




Compound 1 5 10 20 50 100 150 200 0.5 Avg %RSD21) T 2,4'-DDD 0.578 0.456 0.507 0.484 0.493 0.457 0.457 0.442 0.531 0.490 8.98 22) T endrin 0.933 0.679 0.725 0.689 0.765 0.711 0.749 0.750 1.656 *L 0.999423) T endosulfan II 0.868 0.699 0.771 0.729 0.795 0.697 0.744 0.617 0.804 0.747 9.78 24) T 4,4'-DDD 0.627 0.542 0.607 0.579 0.585 0.599 0.594 0.586 0.602 0.591 3.96 25) T 2,4'-DDT 0.622 0.514 0.619 0.587 0.539 0.544 0.502 0.527 0.657 0.568 9.67 26) T cis-nonachlor 0.978 0.770 0.861 0.803 0.832 0.810 0.838 0.810 0.927 0.848 7.79 27) T endrin aldehyde 0.771 0.577 0.643 0.600 0.626 0.589 0.608 0.576 0.792 0.642 12.75 28) T endosulfan su... 0.765 0.650 0.702 0.659 0.679 0.655 0.663 0.645 0.757 0.686 6.68 29) T 4,4'-DDT 0.832 0.599 0.646 0.606 0.611 0.605 0.613 0.601 1.829 *L 0.999930) T endrin ketone 0.878 0.722 0.799 0.748 0.751 0.739 0.748 0.725 0.940 0.783 9.72 31) T methoxychlor 0.380 0.342 0.371 0.349 0.334 0.316 0.299 0.293 0.409 0.344 11.18 32) T mirex 0.782 0.637 0.698 0.619 0.614 0.537 0.545 0.503 0.726 0.629 14.82 33) S BZ 198 0.745 0.656 0.704 0.646 0.613 0.603 0.587 0.555 0.720 0.648 9.97 34) S DCB - Surrogate 0.731 0.645 0.717 0.647 0.593 0.563 0.526 0.497 0.749 0.630 14.49 35) T Toxaphene 0.000 -1.00 36) T Technical Chl... 0.000 -1.00 --------------------------------------------------------------------------(#) = Out of Range ### Number of calibration levels exceeded format ###


of 329

Quantitation Report (QT Reviewed)

Data Path : O:\Organics\DATA\ECD2-6890N\2012\OCT\OCT29\Data File : F210291209.D Signal(s) : Signal #1: ECD1A.CH Signal #2: ECD2B.CHAcq On : 29 Oct 2012 6:52 pmOperator : ECD2:RRSample : PEM210291201 Misc : WG571275,PW082712BALS Vial : 10 Sample Multiplier: 1

Integration File signal 1: autoint1.eIntegration File signal 2: autoint2.eQuant Time: Oct 31 09:37:52 2012Quant Method : O:\Organics\METHODS\ECD2-6890N\2012\PEST21029.MQuant Title : PESTICIDES BY 8081A-ECD2QLast Update : Tue Oct 30 15:47:02 2012Response via : Initial CalibrationIntegrator: ChemStation 6890 Scale Mode: Large solvent peaks clipped

Volume Inj. : 1Signal #1 Phase : RTX 5 Signal #2 Phase: RTX CLP IISignal #1 Info : .25 Signal #2 Info : .25

Sub List : PEM - Degradation Check

Compound RT#1 RT#2 Resp#1 Resp#2 ug/L ug/L---------------------------------------------------------------------------Internal Standards

1) I BZ 192 0.00 0.00 0 0 N.D. d N.D. d

System Monitoring Compounds

Target Compounds19) T 4,4'-DDE 21.28 22.22 3216978 967907 N.D. M4 N.D. M4

22) T endrin 22.84 24.59 1400.5E6 411.5E6 N.D. M4 N.D. M4

24) T 4,4'-DDD 23.87 25.50 17536907 5461540 N.D. M4 N.D. M4

27) T endrin aldehyd 24.50 27.55 12266695 3591137 N.D. M4 N.D. M4

29) T 4,4'-DDT 25.97 27.10 2406.6E6 682.5E6 N.D. M4 N.D. M4

30) T endrin ketone 28.27 30.83 35782002 10307776 N.D. M4 N.D. M4

SemiQuant Compounds - Not Calibrated on this Instrument---------------------------------------------------------------------------

(f)=RT Delta > 1/2 Window (#)=Amounts differ by > 25% (m)=manual int.(I,C,F) I=Interference, C=Coelluting Calibration Peak, F=Fails CC Criteria.


of 329


Data Path : O:\Organics\DATA\ECD2-6890N\2012\OCT\OCT29\Data File : F210291209.DOperator : ECD2:RRAcquired : 29 Oct 2012 6:52 pm using AcqMethod PESTECD2.MInstrument: HP G1530ASample : PEM210291201 Misc Info : WG571275,PW082712B ??H5?ALS Vial : 10

2.00 4.00 6.00 8.00 10.00 12.00 14.00 16.00 18.00 20.00 22.00 24.00 26.00 28.00 30.00 32.00 34.00 36.00 38.00

0

1e+07

2e+07

3e+07

4e+07

5e+07

6e+07

7e+07

Time

Response_ Signal: F210291209.D\ECD1A.CH

2.00 4.00 6.00 8.00 10.00 12.00 14.00 16.00 18.00 20.00 22.00 24.00 26.00 28.00 30.00 32.00 34.00 36.00 38.00

0

5000000

1e+07

1.5e+07

2e+07

Time

Response_ Signal: F210291209.D\ECD2B.CH


of 329


Data Path : O:\Organics\DATA\ECD2-6890N\2012\OCT\OCT29\Data File : F210291210.D Signal(s) : Signal #1: ECD1A.CH Signal #2: ECD2B.CHAcq On : 29 Oct 2012 7:36 pmOperator : ECD2:RRSample : I210291201 Misc : WG571275,PW071712AALS Vial : 11 Sample Multiplier: 1



Sub List : Default - All compounds listed


1) I BZ 192 29.13 29.32 925.7E6 272.2E6 50.000M4 50.000M4

System Monitoring Compounds2) S TMX - Surrogat 7.48 7.30 5678753 2079613 0.484M4 0.464M4

Spiked Amount 100.000 Range 30 - 150 Recovery = 0.48%# 0.46%#3) S DBOB 7.88 7.92 7069880 2200411 0.522M4 0.501M4

Spiked Amount 100.000 Range 30 - 150 Recovery = 0.52%# 0.50%#33) S BZ 198 30.78 31.00 7501982 1960942 0.612M4 0.552M4

Spiked Amount 100.000 Range 30 - 150 Recovery = 0.61%# 0.55%#34) S DCB - Surrogat 37.22 37.54 6774957 2037930 0.582M4 0.590M4

Spiked Amount 100.000 Range 30 - 150 Recovery = 0.58%# 0.59%#

Target Compounds4) T alpha-BHC 8.58 9.28 7282901 2706954 0.432M4 0.436M4

5) T hexachlorobenz 8.88 8.79 7650614 2844556 0.531M4 0.518M4

6) T beta-BHC 9.36 11.09 3943514 1383123 0.535M4 0.486M4

7) T gamma-BHC 9.66 10.74 8179714 2587135 0.501M4 0.446M4

8) T delta-BHC 10.47 12.55 6669672 2621470 0.443M5 0.477M4

9) T heptachlor 12.73 12.92 8737151 2753914 0.527M4 0.496M4

10) T aldrin 14.68 14.76 12534021 2529653 1.069M4 (C) 0.483M4 D


of 329






Compound RT#1 RT#2 Resp#1 Resp#2 ug/L ug/L---------------------------------------------------------------------------

11) T chloropyrifos 14.68 16.48 12532824 1482525 1.068M4 (C) 0.547M4 D

12) T heptachlor epo 17.24 18.68 14878133 2624799 1.061M4 (C) 0.522M4 D

13) T oxychlordane 17.24 18.04 14933353 2436638 1.064M4 (C) 0.551M4 D

14) T gamma-chlordan 18.88 19.98 7777241 2704790 0.520M4 0.570M4

15) T 2,4'-DDE 19.16 20.15 4568210 1884828 0.500M4 0.595M4

16) T endosulfan I 19.77 21.23 8756909 2434058 0.620M4 0.530M4

17) T alpha-chlordan 19.94 20.95 8135533 2544513 0.531M4 0.534M4

18) T trans-nonachlo 20.25 20.62 8097100 2513193 0.534M4 0.541M4

19) T 4,4'-DDE 21.27 22.20 6234603 2039392 0.482M4 0.506M4

20) T dieldrin 21.48 22.90 7025911 2317574 0.478M4 0.499M4

21) T 2,4'-DDD 21.84 23.36 4476139 1446117 0.525M4 0.539M4

22) T endrin 22.85 24.60 13202787 4507605 1.108M4 0.841M4

23) T endosulfan II 23.39 25.77 7523231 2188556 0.596M4 0.535M4

24) T 4,4'-DDD 23.86 25.49 5389343 1638284 0.507M4 0.506M4

25) T 2,4'-DDT 24.08 25.04 5056606 1788696 0.543M4 0.575M4

26) T cis-nonachlor 24.14 25.16 9760485 2524424 0.561M4 0.544M4

27) T endrin aldehyd 24.49 27.54 7791805 2157018 0.655M4 0.613M4


of 329







28) T endosulfan sul 25.80 28.76 8238462 2059733 0.667M4 0.548M4

29) T 4,4'-DDT 25.97 27.10 17192979 4980505 1.078M4 0.296M4 D

30) T endrin ketone 28.27 30.83 8360672 2558875 0.587M4 0.597M4

31) T methoxychlor 28.80 30.07 4165510 1114346 0.651M4 0.592M4

32) T mirex 30.54 30.61 7065343 1977318 0.619M4 0.573M4

35) T Toxaphene 0.00 0.00 0 0 N.D. N.D. 36) T Technical Chlo 0.00 0.00 0 0 N.D. N.D.




of 329


Data Path : O:\Organics\DATA\ECD2-6890N\2012\OCT\OCT29\Data File : F210291210.DOperator : ECD2:RRAcquired : 29 Oct 2012 7:36 pm using AcqMethod PESTECD2.MInstrument: HP G1530ASample : I210291201 Misc Info : WG571275,PW071712A ??H5?ALS Vial : 11

2.00 4.00 6.00 8.00 10.00 12.00 14.00 16.00 18.00 20.00 22.00 24.00 26.00 28.00 30.00 32.00 34.00 36.00 38.00

0

5000000

1e+07

1.5e+07

2e+07

2.5e+07

3e+07

Time


2.00 4.00 6.00 8.00 10.00 12.00 14.00 16.00 18.00 20.00 22.00 24.00 26.00 28.00 30.00 32.00 34.00 36.00 38.00

0

2000000

4000000

6000000

8000000

1e+07

Time



of 329

#2 TMX - Surrogate

R.T.: 7.481 minDelta R.T.: 0.009 minResponse: 5678753

Conc: 0.48 ug/L M4

6.80 7.00 7.20 7.40 7.60 7.80 8.00 8.20

0

500000

1000000

1500000

Time


7.481

#2 TMX - Surrogate


Conc: 0.46 ug/L m

6.70 6.80 6.90 7.00 7.10 7.20 7.30 7.40 7.50 7.60 7.70 7.80 7.90

0

200000

400000

600000

800000

1000000

1200000

Time


7.302

F210291210.D PEST21029.M Thu Nov 01 13:01:27 2012 Page 6

of 329

#3 DBOB


Conc: 0.52 ug/L M4

7.20 7.40 7.60 7.80 8.00 8.20 8.40 8.60 8.80

0

500000

1000000

1500000

Time


7.880

#3 DBOB


Conc: 0.50 ug/L m

7.40 7.50 7.60 7.70 7.80 7.90 8.00 8.10 8.20 8.30 8.40 8.50

0

200000

400000

600000

800000

1000000

1200000

Time


7.921


of 329

#4 alpha-BHC


Conc: 0.43 ug/L M4

7.80 8.00 8.20 8.40 8.60 8.80 9.00 9.20 9.40

0

500000

1000000

1500000

Time


8.576

#4 alpha-BHC


Conc: 0.44 ug/L m

8.60 8.80 9.00 9.20 9.40 9.60 9.80 10.00

0

200000

400000

600000

800000

1000000

1200000

Time


9.276


of 329

#5 hexachlorobenzene


Conc: 0.53 ug/L M4

8.00 8.20 8.40 8.60 8.80 9.00 9.20 9.40 9.60 9.80

0

500000

1000000

1500000

Time


8.879



Conc: 0.52 ug/L m

7.80 8.00 8.20 8.40 8.60 8.80 9.00 9.20 9.40 9.60 9.80

0

200000

400000

600000

800000

1000000

1200000

Time


8.794


of 329

#6 beta-BHC


Conc: 0.54 ug/L M4

8.60 8.80 9.00 9.20 9.40 9.60 9.80 10.00 10.20

0

500000

1000000

1500000

Time


9.363

#6 beta-BHC


Conc: 0.49 ug/L m

10.60 10.80 11.00 11.20 11.40 11.60

0

200000

400000

600000

800000

1000000

1200000

Time


11.087


of 329

#7 gamma-BHC


Conc: 0.50 ug/L M4

8.80 9.00 9.20 9.40 9.60 9.80 10.00 10.20 10.40 10.60

0

500000

1000000

1500000

Time


9.658

#7 gamma-BHC


Conc: 0.45 ug/L m

10.20 10.40 10.60 10.80 11.00 11.20 11.40

0

200000

400000

600000

800000

1000000

1200000

Time


10.738


of 329

#8 delta-BHC


Conc: 0.44 ug/L M4

9.60 9.80 10.00 10.20 10.40 10.60 10.80 11.00 11.20

0

500000

1000000

1500000

Time


10.470

#8 delta-BHC


Conc: 0.48 ug/L m

11.80 12.00 12.20 12.40 12.60 12.80 13.00 13.20

0

200000

400000

600000

800000

1000000

1200000

Time


12.551


of 329

#9 heptachlor


Conc: 0.53 ug/L M4

12.00 12.20 12.40 12.60 12.80 13.00 13.20 13.40

0

500000

1000000

1500000

Time


12.730

+

#9 heptachlor


Conc: 0.50 ug/L m

12.20 12.40 12.60 12.80 13.00 13.20 13.40 13.60

0

200000

400000

600000

800000

1000000

1200000

Time


12.917


of 329

#10 aldrin


Conc: 1.07 ug/L M4

13.50 14.00 14.50 15.00 15.50

0

500000

1000000

1500000

Time


14.681

#10 aldrin


Conc: 0.48 ug/L m

14.20 14.40 14.60 14.80 15.00 15.20 15.40

0

200000

400000

600000

800000

1000000

1200000

Time


14.764


of 329

#11 chloropyrifos


Conc: 1.07 ug/L M4

13.50 14.00 14.50 15.00 15.50

0

500000

1000000

1500000

Time


14.681

#11 chloropyrifos


Conc: 0.55 ug/L m

15.80 16.00 16.20 16.40 16.60 16.80 17.00 17.20

0

200000

400000

600000

800000

1000000

1200000

Time


16.476


of 329

#12 heptachlor epoxide (B)


Conc: 1.06 ug/L M4

16.40 16.60 16.80 17.00 17.20 17.40 17.60 17.80 18.00

0

500000

1000000

1500000

Time


17.239

+



Conc: 0.52 ug/L m

18.00 18.20 18.40 18.60 18.80 19.00 19.20 19.40

0

200000

400000

600000

800000

1000000

1200000

Time


18.683


of 329

#13 oxychlordane


Conc: 1.06 ug/L M4

16.40 16.60 16.80 17.00 17.20 17.40 17.60 17.80 18.00

0

500000

1000000

1500000

Time


17.239

+

#13 oxychlordane


Conc: 0.55 ug/L m

17.20 17.40 17.60 17.80 18.00 18.20 18.40 18.60 18.80 19.00

0

200000

400000

600000

800000

1000000

1200000

Time


18.040


of 329

#14 gamma-chlordane


Conc: 0.52 ug/L M4

18.20 18.40 18.60 18.80 19.00 19.20 19.40

0

500000

1000000

1500000

Time


18.881+

#14 gamma-chlordane


Conc: 0.57 ug/L m

19.50 19.60 19.70 19.80 19.90 20.00 20.10 20.20 20.30 20.40

0

200000

400000

600000

800000

1000000

1200000

Time


19.981


of 329

#15 2,4'-DDE


Conc: 0.50 ug/L M4

18.60 18.80 19.00 19.20 19.40 19.60 19.80

0

500000

1000000

1500000

Time


19.162

#15 2,4'-DDE


Conc: 0.59 ug/L m

19.70 19.80 19.90 20.00 20.10 20.20 20.30 20.40 20.50 20.60

0

200000

400000

600000

800000

1000000

1200000

Time


20.152


of 329

#16 endosulfan I


Conc: 0.62 ug/L M4

19.00 19.20 19.40 19.60 19.80 20.00 20.20 20.40

0

500000

1000000

1500000

Time


19.765+

#16 endosulfan I


Conc: 0.53 ug/L m

20.60 20.80 21.00 21.20 21.40 21.60 21.80

0

200000

400000

600000

800000

1000000

1200000

Time


21.231


of 329

#17 alpha-chlordane


Conc: 0.53 ug/L M4

19.40 19.60 19.80 20.00 20.20 20.40 20.60

0

500000

1000000

1500000

Time


19.936

+

#17 alpha-chlordane


Conc: 0.53 ug/L m

20.40 20.60 20.80 21.00 21.20 21.40 21.60

0

200000

400000

600000

800000

1000000

1200000

Time


20.946


of 329

#18 trans-nonachlor


Conc: 0.53 ug/L M4

19.60 19.80 20.00 20.20 20.40 20.60 20.80 21.00

0

500000

1000000

1500000

Time


20.245

+

#18 trans-nonachlor


Conc: 0.54 ug/L m

20.10 20.20 20.30 20.40 20.50 20.60 20.70 20.80 20.90 21.00 21.10

0

200000

400000

600000

800000

1000000

1200000

Time


20.622


of 329

#19 4,4'-DDE


Conc: 0.48 ug/L M4

20.80 21.00 21.20 21.40 21.60 21.80

0

500000

1000000

1500000

Time


21.272

#19 4,4'-DDE


Conc: 0.51 ug/L m

21.70 21.80 21.90 22.00 22.10 22.20 22.30 22.40 22.50 22.60 22.70

0

200000

400000

600000

800000

1000000

1200000

Time


22.204


of 329

#20 dieldrin


Conc: 0.48 ug/L M4

20.90 21.00 21.10 21.20 21.30 21.40 21.50 21.60 21.70 21.80 21.90 22.00

0

500000

1000000

1500000

Time


21.484+

#20 dieldrin


Conc: 0.50 ug/L m

22.40 22.50 22.60 22.70 22.80 22.90 23.00 23.10 23.20 23.30 23.40

0

200000

400000

600000

800000

1000000

1200000

Time


22.902


of 329

#21 2,4'-DDD


Conc: 0.52 ug/L M4

21.20 21.40 21.60 21.80 22.00 22.20 22.40

0

500000

1000000

1500000

Time


21.841

#21 2,4'-DDD


Conc: 0.54 ug/L m

22.80 23.00 23.20 23.40 23.60 23.80

0

200000

400000

600000

800000

1000000

1200000

Time


23.356


of 329

#22 endrin


Conc: 1.11 ug/L M4

22.20 22.40 22.60 22.80 23.00 23.20 23.40

0

500000

1000000

1500000

2000000

Time


22.846

+

#22 endrin


Conc: 0.84 ug/L m

24.00 24.10 24.20 24.30 24.40 24.50 24.60 24.70 24.80 24.90 25.00 25.10

0

200000

400000

600000

800000

1000000

1200000

Time


24.596


of 329

#23 endosulfan II


Conc: 0.60 ug/L M4

22.60 22.80 23.00 23.20 23.40 23.60 23.80 24.00

0

500000

1000000

1500000

2000000

Time


23.386

#23 endosulfan II


Conc: 0.53 ug/L m

25.20 25.30 25.40 25.50 25.60 25.70 25.80 25.90 26.00 26.10 26.20 26.30

0

200000

400000

600000

800000

1000000

1200000

Time


25.769


of 329

#24 4,4'-DDD


Conc: 0.51 ug/L M4

23.30 23.40 23.50 23.60 23.70 23.80 23.90 24.00 24.10 24.20 24.30 24.40

0

500000

1000000

1500000

Time


23.856

#24 4,4'-DDD


Conc: 0.51 ug/L m

25.10 25.20 25.30 25.40 25.50 25.60 25.70 25.80 25.90

0

200000

400000

600000

800000

1000000

1200000

Time


25.493


of 329

#25 2,4'-DDT


Conc: 0.54 ug/L M4

23.75 23.80 23.85 23.90 23.95 24.00 24.05 24.10 24.15 24.20 24.25 24.30

0

500000

1000000

1500000

Time


24.075+

#25 2,4'-DDT


Conc: 0.57 ug/L m

24.60 24.70 24.80 24.90 25.00 25.10 25.20 25.30 25.40

0

200000

400000

600000

800000

1000000

1200000

Time


25.040


of 329

#26 cis-nonachlor


Conc: 0.56 ug/L M4

23.90 24.00 24.10 24.20 24.30 24.40

0

500000

1000000

1500000

Time


24.137

+

#26 cis-nonachlor


Conc: 0.54 ug/L m

24.80 24.90 25.00 25.10 25.20 25.30 25.40 25.50

0

200000

400000

600000

800000

1000000

1200000

Time


25.164


of 329

#27 endrin aldehyde


Conc: 0.65 ug/L M4

23.80 24.00 24.20 24.40 24.60 24.80 25.00

0

500000

1000000

1500000

Time


24.488+

#27 endrin aldehyde


Conc: 0.61 ug/L m

27.10 27.20 27.30 27.40 27.50 27.60 27.70 27.80 27.90 28.00

0

500000

1000000

Time


27.545


of 329

#28 endosulfan sulfate

R.T.: 25.804 minDelta R.T.: -0.003 minResponse: 8238462

Conc: 0.67 ug/L M4

25.50 25.60 25.70 25.80 25.90 26.00 26.10

0

500000

1000000

1500000

2000000

Time


25.804+



Conc: 0.55 ug/L m

28.50 28.60 28.70 28.80 28.90 29.00

0

500000

1000000

Time


28.757


of 329

#29 4,4'-DDT


Conc: 1.08 ug/L M4

25.40 25.60 25.80 26.00 26.20 26.40 26.60

0

500000

1000000

1500000

2000000

Time


25.968

+

#29 4,4'-DDT


Conc: 0.30 ug/L m

26.70 26.80 26.90 27.00 27.10 27.20 27.30 27.40 27.50

0

500000

1000000

Time


27.103

+


of 329

#30 endrin ketone


Conc: 0.59 ug/L M4

27.90 28.00 28.10 28.20 28.30 28.40 28.50 28.60 28.70

0

500000

1000000

1500000

2000000

Time


28.273

+

#30 endrin ketone


Conc: 0.60 ug/L m

30.50 30.60 30.70 30.80 30.90 31.00 31.10 31.20

0

500000

1000000

Time


30.831


of 329

#31 methoxychlor


Conc: 0.65 ug/L M4

28.50 28.55 28.60 28.65 28.70 28.75 28.80 28.85 28.90 28.95 29.00 29.05

0

1000000

2000000

3000000

4000000

5000000

6000000

Time


28.802

#31 methoxychlor


Conc: 0.59 ug/L m

29.70 29.80 29.90 30.00 30.10 30.20 30.30 30.40

0

500000

1000000

Time


30.065


of 329

#32 mirex


Conc: 0.62 ug/L M4

30.10 30.20 30.30 30.40 30.50 30.60 30.70 30.80 30.90

0

500000

1000000

1500000

2000000

Time


30.539+

#32 mirex


Conc: 0.57 ug/L m

30.20 30.30 30.40 30.50 30.60 30.70 30.80 30.90 31.00

0

500000

1000000

Time


30.606


of 329

#33 BZ 198


Conc: 0.61 ug/L M4

30.30 30.40 30.50 30.60 30.70 30.80 30.90 31.00 31.10 31.20

0

500000

1000000

1500000

2000000

Time


30.779

+

#33 BZ 198


Conc: 0.55 ug/L m

30.60 30.70 30.80 30.90 31.00 31.10 31.20 31.30 31.40

0

500000

1000000

Time


31.001


of 329

#34 DCB - Surrogate


Conc: 0.58 ug/L M4

36.60 36.80 37.00 37.20 37.40 37.60 37.80

0

500000

1000000

1500000

2000000

Time


37.224

#34 DCB - Surrogate


Conc: 0.59 ug/L m

36.80 37.00 37.20 37.40 37.60 37.80 38.00 38.20

0

500000

1000000

1500000

Time


37.542


of 329


Data Path : O:\Organics\DATA\ECD2-6890N\2012\OCT\OCT29\Data File : F210291211.D Signal(s) : Signal #1: ECD1A.CH Signal #2: ECD2B.CHAcq On : 29 Oct 2012 8:20 pmOperator : ECD2:RRSample : I210291202 (Sig #1); I210291201 (Sig #2)Misc : WG571275,PW071712BALS Vial : 12 Sample Multiplier: 1





1) I BZ 192 29.13 29.32 752.6E6 220.2E6 50.000M4 50.000M4








6) T beta-BHC 9.37 11.09 7126668 2623261 1.104M4 1.063M4

7) T gamma-BHC 9.66 10.74 13866472 4845539 0.998M4 1.006M4

8) T delta-BHC 10.48 12.55 12182569 4524529 1.013M4 1.000M4

9) T heptachlor 12.74 12.92 15576480 4923112 1.059M4 1.016M4

10) T aldrin 14.69 14.77 22246384 4720458 2.133M4 (C) 1.040M4 D


of 329







11) T chloropyrifos 14.69 16.48 22304135 2630640 2.136M4 (C) 1.063M4 D

12) T heptachlor epo 17.25 18.69 27243007 4642971 2.179M4 (C) 1.041M4 D

13) T oxychlordane 17.25 18.04 27194223 4227000 2.173M4 (C) 1.046M4 D


15) T 2,4'-DDE 19.16 20.16 8464322 3063853 1.077M4 1.041M4

16) T endosulfan I 19.77 21.23 13469450 4269773 1.035M4 1.042M4



19) T 4,4'-DDE 21.27 22.20 10944654 3527788 1.043M4 1.041M4

20) T dieldrin 21.49 22.90 12898009 4213154 1.049M4 1.047M4

21) T 2,4'-DDD 21.84 23.36 7950237 2547340 1.084M4 1.074M4

22) T endrin 22.85 24.60 12488321 4107784 0.837M4 0.831M4


24) T 4,4'-DDD 23.86 25.49 9340085 2760957 1.067M4 1.028M4

25) T 2,4'-DDT 24.08 25.04 6868071 2740657 0.912M4 1.019M4




of 329








29) T 4,4'-DDT 25.97 27.10 12804784 3662798 0.769M4 0.761M4



32) T mirex 30.54 30.61 12389659 3443870 1.156M4 1.096M4





of 329


Data Path : O:\Organics\DATA\ECD2-6890N\2012\OCT\OCT29\Data File : F210291211.DOperator : ECD2:RRAcquired : 29 Oct 2012 8:20 pm using AcqMethod PESTECD2.MInstrument: HP G1530ASample : I210291202 Misc Info : WG571275,PW071712B ??H5?ALS Vial : 12

2.00 4.00 6.00 8.00 10.00 12.00 14.00 16.00 18.00 20.00 22.00 24.00 26.00 28.00 30.00 32.00 34.00 36.00 38.00

0

5000000

1e+07

1.5e+07

2e+07

2.5e+07

Time


2.00 4.00 6.00 8.00 10.00 12.00 14.00 16.00 18.00 20.00 22.00 24.00 26.00 28.00 30.00 32.00 34.00 36.00 38.00

0

1000000

2000000

3000000

4000000

5000000

6000000

7000000

8000000

Time



of 329


Data Path : O:\Organics\DATA\ECD2-6890N\2012\OCT\OCT29\Data File : F210291212.D Signal(s) : Signal #1: ECD1A.CH Signal #2: ECD2B.CHAcq On : 29 Oct 2012 9:04 pmOperator : ECD2:RRSample : I210291203 (Sig #1); I210291201 (Sig #2)Misc : WG571275,PW071312FALS Vial : 13 Sample Multiplier: 1





1) I BZ 192 29.13 29.31 1059.8E6 307.4E6 50.000M4 50.000M4








6) T beta-BHC 9.35 11.07 40104891 14465825 4.537M4 4.359M4

7) T gamma-BHC 9.65 10.72 78186133 27354726 4.200M4 4.252M4

8) T delta-BHC 10.46 12.54 73489111 26225003 4.481M4 4.318M4

9) T heptachlor 12.72 12.90 79769582 26929232 4.079M4 4.179M4

10) T aldrin 14.67 14.75 117.3E6 25160763 8.395M4 (C) 4.171M4 D


of 329







11) T chloropyrifos 14.67 16.46 117.3E6 14718898 8.390M4 (C) 4.409M4 D

12) T heptachlor epo 17.22 18.67 140.7E6 24963898 8.401M4 (C) 4.204M4 D

13) T oxychlordane 17.22 18.03 140.9E6 22634463 8.402M4 (C) 4.205M4 D


15) T 2,4'-DDE 19.15 20.15 48721068 15514821 4.531M4 4.007M4

16) T endosulfan I 19.76 21.22 72381164 22761218 4.163M4 4.177M4



19) T 4,4'-DDE 21.27 22.20 64904465 20021875 4.521M4 4.385M4

20) T dieldrin 21.48 22.89 71910031 22743020 4.329M4 4.237M4

21) T 2,4'-DDD 21.84 23.35 46211087 14017510 4.588M4 4.385M4

22) T endrin 22.84 24.59 66381350 20881141 3.475M4 3.349M4


24) T 4,4'-DDD 23.85 25.49 55150383 16646811 4.587M4 4.551M4

25) T 2,4'-DDT 24.07 25.03 54200355 15797266 5.071M4 4.365M4




of 329








29) T 4,4'-DDT 25.97 27.10 62846993 18403308 3.028M4 3.081M4



32) T mirex 30.54 30.60 62975686 19570730 4.346M4 4.568M4





of 329


Data Path : O:\Organics\DATA\ECD2-6890N\2012\OCT\OCT29\Data File : F210291212.DOperator : ECD2:RRAcquired : 29 Oct 2012 9:04 pm using AcqMethod PESTECD2.MInstrument: HP G1530ASample : I210291203 Misc Info : WG571275,PW071312F ??H5?ALS Vial : 13

2.00 4.00 6.00 8.00 10.00 12.00 14.00 16.00 18.00 20.00 22.00 24.00 26.00 28.00 30.00 32.00 34.00 36.00 38.00

0

5000000

1e+07

1.5e+07

2e+07

2.5e+07

3e+07

3.5e+07

Time


2.00 4.00 6.00 8.00 10.00 12.00 14.00 16.00 18.00 20.00 22.00 24.00 26.00 28.00 30.00 32.00 34.00 36.00 38.00

0

2000000

4000000

6000000

8000000

1e+07

Time



of 329


Data Path : O:\Organics\DATA\ECD2-6890N\2012\OCT\OCT29\Data File : F210291213.D Signal(s) : Signal #1: ECD1A.CH Signal #2: ECD2B.CHAcq On : 29 Oct 2012 9:48 pmOperator : ECD2:RRSample : I210291204 (Sig #1); I210291201 (Sig #2)Misc : WG571275,PW071312EALS Vial : 14 Sample Multiplier: 1





1) I BZ 192 29.13 29.32 838.1E6 246.7E6 50.000M4 50.000M4

System Monitoring Compounds2) S TMX - Surrogat 7.48 7.30 109.2E6 40998825 10.074M4 9.890M4

Spiked Amount 100.000 Range 30 - 150 Recovery = 10.07%# 9.89%#3) S DBOB 7.88 7.92 124.2E6 40186172 9.782M4 9.736M4

Spiked Amount 100.000 Range 30 - 150 Recovery = 9.78%# 9.74%#33) S BZ 198 30.78 31.00 115.8E6 34727825 9.749M4 10.071M4

Spiked Amount 100.000 Range 30 - 150 Recovery = 9.75%# 10.07%#34) S DCB - Surrogat 37.22 37.54 116.7E6 35351406 10.287M4 10.264M4


Target Compounds4) T alpha-BHC 8.58 9.27 144.4E6 52524205 9.933M4 9.665M4

5) T hexachlorobenz 8.88 8.79 132.2E6 50140339 9.645M4 9.568M4

6) T beta-BHC 9.36 11.09 70750491 26543968 10.104M4 9.892M4

7) T gamma-BHC 9.66 10.74 142.6E6 50319892 9.755M4 9.718M4

8) T delta-BHC 10.47 12.55 132.7E6 47134114 10.195M4 9.658M4

9) T heptachlor 12.73 12.92 143.2E6 48955752 9.406M4 9.494M4

10) T aldrin 14.68 14.76 209.9E6 46467704 19.207M4 (C) 9.601M4 D


of 329










14) T gamma-chlordan 18.88 19.98 132.7E6 41777288 9.725M4 9.334M4

15) T 2,4'-DDE 19.16 20.15 85766706 29239794 10.075M4 9.449M4

16) T endosulfan I 19.77 21.23 127.6E6 42120762 9.423M4 9.627M4

17) T alpha-chlordan 19.94 20.94 136.9E6 43114728 9.697M4 9.601M4

18) T trans-nonachlo 20.25 20.62 138.0E6 42880231 9.759M4 9.621M4

19) T 4,4'-DDE 21.27 22.20 115.7E6 36046234 10.161M4 9.790M4

20) T dieldrin 21.48 22.90 130.6E6 41213909 9.962M4 9.575M4

21) T 2,4'-DDD 21.84 23.36 81513390 25007904 10.193M4 9.720M4

22) T endrin 22.85 24.59 114.7E6 35750985 7.983M4 7.531M4

23) T endosulfan II 23.38 25.77 118.0E6 38024347 9.658M4 9.632M4

24) T 4,4'-DDD 23.86 25.49 96797702 29935105 10.151M4 10.074M4

25) T 2,4'-DDT 24.07 25.04 87435100 30541355 10.281M4 10.320M4

26) T cis-nonachlor 24.14 25.16 154.6E6 42486955 9.732M4 9.698M4

27) T endrin aldehyd 24.49 27.54 105.9E6 31707393 9.226M4 9.281M4


of 329







28) T endosulfan sul 25.81 28.76 120.8E6 34638477 10.089M4 9.723M4

29) T 4,4'-DDT 25.97 27.10 109.0E6 31858880 7.123M4 7.083M4

30) T endrin ketone 28.27 30.83 129.2E6 39424691 9.600M4 9.620M4


32) T mirex 30.54 30.60 107.7E6 34425248 9.521M4 9.929M4





of 329


Data Path : O:\Organics\DATA\ECD2-6890N\2012\OCT\OCT29\Data File : F210291213.DOperator : ECD2:RRAcquired : 29 Oct 2012 9:48 pm using AcqMethod PESTECD2.MInstrument: HP G1530ASample : I210291204 Misc Info : WG571275,PW071312E ??H5?ALS Vial : 14

2.00 4.00 6.00 8.00 10.00 12.00 14.00 16.00 18.00 20.00 22.00 24.00 26.00 28.00 30.00 32.00 34.00 36.00 38.00

0

5000000

1e+07

1.5e+07

2e+07

2.5e+07

Time


2.00 4.00 6.00 8.00 10.00 12.00 14.00 16.00 18.00 20.00 22.00 24.00 26.00 28.00 30.00 32.00 34.00 36.00 38.00

0

1000000

2000000

3000000

4000000

5000000

6000000

7000000

8000000

9000000

Time



of 329


Data Path : O:\Organics\DATA\ECD2-6890N\2012\OCT\OCT29\Data File : F210291214.D Signal(s) : Signal #1: ECD1A.CH Signal #2: ECD2B.CHAcq On : 29 Oct 2012 10:32 pmOperator : ECD2:RRSample : I210291205 (Sig #1); I210291201 (Sig #2)Misc : WG571275,PW071312DALS Vial : 15 Sample Multiplier: 1





1) I BZ 192 29.13 29.31 879.4E6 255.4E6 50.000M4 50.000M4


Spiked Amount 100.000 Range 30 - 150 Recovery = 18.61%# 18.69%#3) S DBOB 7.87 7.92 240.9E6 77814237 18.377M4 18.484M4

Spiked Amount 100.000 Range 30 - 150 Recovery = 18.38%# 18.48%#33) S BZ 198 30.78 31.00 220.9E6 66015878 18.070M4 18.726M4



Target Compounds4) T alpha-BHC 8.57 9.27 300.3E6 106.3E6 19.736M4 19.063M4

5) T hexachlorobenz 8.87 8.79 252.4E6 96498566 17.914M4 18.120M4

6) T beta-BHC 9.36 11.08 135.4E6 52547095 18.668M4 19.086M4

7) T gamma-BHC 9.65 10.73 285.8E6 100.6E6 18.846M4 18.957M4

8) T delta-BHC 10.47 12.54 275.9E6 96081944 20.163M4 19.173M4

9) T heptachlor 12.72 12.91 285.6E6 95183575 18.197M4 18.158M4

10) T aldrin 14.67 14.76 413.7E6 90513404 36.670M4 (C) 18.359M4 D


of 329










14) T gamma-chlordan 18.88 19.98 263.7E6 81379342 18.657M4 17.925M4

15) T 2,4'-DDE 19.16 20.15 167.9E6 55760487 18.985M4 17.789M4

16) T endosulfan I 19.76 21.23 240.1E6 80930309 17.346M4 18.189M4

17) T alpha-chlordan 19.93 20.94 267.5E6 83976938 18.354M4 18.357M4

18) T trans-nonachlo 20.24 20.62 274.2E6 82470797 18.713M4 18.195M4

19) T 4,4'-DDE 21.27 22.20 238.5E6 71497382 19.959M4 18.952M4

20) T dieldrin 21.48 22.90 264.6E6 80862108 19.352M4 18.429M4

21) T 2,4'-DDD 21.84 23.35 159.5E6 49473695 19.167M4 18.796M4

22) T endrin 22.84 24.59 234.9E6 70415221 16.174M4 15.038M4

23) T endosulfan II 23.38 25.77 229.8E6 74531824 18.239M4 18.507M4

24) T 4,4'-DDD 23.86 25.49 198.1E6 59114965 19.833M4 19.341M4

25) T 2,4'-DDT 24.07 25.04 182.6E6 59955419 20.382M4 19.638M4

26) T cis-nonachlor 24.14 25.16 304.0E6 82009665 18.507M4 18.374M4

27) T endrin aldehyd 24.49 27.54 207.6E6 61314969 17.640M4 17.729M4


of 329







28) T endosulfan sul 25.81 28.76 226.1E6 67361164 18.298M4 18.530M4

29) T 4,4'-DDT 25.97 27.10 215.5E6 61913917 14.201M4 14.081M4

30) T endrin ketone 28.27 30.83 254.9E6 76430912 18.347M4 18.315M4

31) T methoxychlor 28.80 30.06 118.2E6 35617047 18.335M4 18.894M4

32) T mirex 30.54 30.60 204.0E6 63206483 17.591M4 17.965M4





of 329


Data Path : O:\Organics\DATA\ECD2-6890N\2012\OCT\OCT29\Data File : F210291214.DOperator : ECD2:RRAcquired : 29 Oct 2012 10:32 pm using AcqMethod PESTECD2.MInstrument: HP G1530ASample : I210291205 Misc Info : WG571275,PW071312D ??H5?ALS Vial : 15

2.00 4.00 6.00 8.00 10.00 12.00 14.00 16.00 18.00 20.00 22.00 24.00 26.00 28.00 30.00 32.00 34.00 36.00 38.00

0

5000000

1e+07

1.5e+07

2e+07

2.5e+07

3e+07

Time


2.00 4.00 6.00 8.00 10.00 12.00 14.00 16.00 18.00 20.00 22.00 24.00 26.00 28.00 30.00 32.00 34.00 36.00 38.00

0

2000000

4000000

6000000

8000000

Time



of 329


Data Path : O:\Organics\DATA\ECD2-6890N\2012\OCT\OCT29\Data File : F210291215.D Signal(s) : Signal #1: ECD1A.CH Signal #2: ECD2B.CHAcq On : 29 Oct 2012 11:15 pmOperator : ECD2:RRSample : I210291206 (Sig #1); I210291201 (Sig #2)Misc : WG571275,PW071212AALS Vial : 16 Sample Multiplier: 1





1) I BZ 192 29.13 29.31 602.4E6 177.7E6 50.000M4 50.000M4

System Monitoring Compounds2) S TMX - Surrogat 7.47 7.29 439.2E6 166.8E6 51.045M4 49.373M4

Spiked Amount 100.000 Range 30 - 150 Recovery = 51.05% 49.37% 3) S DBOB 7.87 7.91 495.3E6 158.8E6 51.045M4 49.373M4

Spiked Amount 100.000 Range 30 - 150 Recovery = 51.05% 49.37% 33) S BZ 198 30.78 31.00 380.9E6 108.9E6 51.045M4 49.373M4

Spiked Amount 100.000 Range 30 - 150 Recovery = 51.05% 49.37% 34) S DCB - Surrogat 37.22 37.54 359.8E6 105.3E6 51.045M4 49.373M4

Spiked Amount 100.000 Range 30 - 150 Recovery = 51.05% 49.37%


5) T hexachlorobenz 8.87 8.78 529.6E6 199.2E6 51.045M4 49.373M4

6) T beta-BHC 9.35 11.08 249.4E6 99855940 51.045M4 49.373M4

7) T gamma-BHC 9.65 10.73 614.9E6 213.3E6 51.045M4 49.373M4

8) T delta-BHC 10.46 12.54 551.8E6 189.6E6 51.045M4 49.373M4

9) T heptachlor 12.72 12.91 611.0E6 203.2E6 51.045M4 49.373M4

10) T aldrin 14.67 14.75 850.1E6 189.0E6 102.090M4 (C) 49.373M4 D


of 329








12) T heptachlor epo 17.24 18.68 1006.8E6 176.5E6 102.090M4 (C) 49.373M4 D

13) T oxychlordane 17.24 18.03 1007.7E6 155.5E6 102.090M4 (C) 49.373M4 D

14) T gamma-chlordan 18.87 19.98 530.6E6 154.8E6 51.045M4 49.373M4

15) T 2,4'-DDE 19.16 20.15 327.1E6 106.9E6 51.045M4 49.373M4

16) T endosulfan I 19.76 21.23 483.6E6 160.8E6 51.045M4 49.373M4

17) T alpha-chlordan 19.93 20.94 548.1E6 162.9E6 51.045M4 49.373M4

18) T trans-nonachlo 20.24 20.62 542.4E6 158.5E6 51.045M4 49.373M4

19) T 4,4'-DDE 21.27 22.20 442.6E6 131.3E6 51.045M4 49.373M4

20) T dieldrin 21.48 22.90 533.8E6 161.4E6 51.045M4 49.373M4

21) T 2,4'-DDD 21.84 23.35 289.0E6 87554158 51.045M4 49.373M4

22) T endrin 22.84 24.59 460.9E6 135.9E6 51.045M4 49.373M4

23) T endosulfan II 23.38 25.77 428.9E6 141.2E6 51.045M4 49.373M4

24) T 4,4'-DDD 23.85 25.49 347.9E6 104.0E6 51.045M4 49.373M4

25) T 2,4'-DDT 24.08 25.04 317.7E6 95803249 51.045M4 49.373M4

26) T cis-nonachlor 24.14 25.16 593.1E6 147.9E6 51.045M4 49.373M4

27) T endrin aldehyd 24.49 27.54 381.8E6 111.2E6 51.045M4 49.373M4


of 329







28) T endosulfan sul 25.81 28.76 369.6E6 120.6E6 51.045M4 49.373M4

29) T 4,4'-DDT 25.97 27.10 395.7E6 108.5E6 51.045M4 49.373M4

30) T endrin ketone 28.27 30.83 445.9E6 133.4E6 51.045M4 49.373M4


32) T mirex 30.54 30.60 357.5E6 109.1E6 51.045M4 49.373M4





of 329


Data Path : O:\Organics\DATA\ECD2-6890N\2012\OCT\OCT29\Data File : F210291215.DOperator : ECD2:RRAcquired : 29 Oct 2012 11:15 pm using AcqMethod PESTECD2.MInstrument: HP G1530ASample : I210291206 Misc Info : WG571275,PW071212A ??H5?ALS Vial : 16

2.00 4.00 6.00 8.00 10.00 12.00 14.00 16.00 18.00 20.00 22.00 24.00 26.00 28.00 30.00 32.00 34.00 36.00 38.00

0

5000000

1e+07

1.5e+07

2e+07

Time


2.00 4.00 6.00 8.00 10.00 12.00 14.00 16.00 18.00 20.00 22.00 24.00 26.00 28.00 30.00 32.00 34.00 36.00 38.00

0

1000000

2000000

3000000

4000000

5000000

6000000

7000000

Time



of 329

#2 TMX - Surrogate


Conc: 51.05 ug/L M4

6.40 6.60 6.80 7.00 7.20 7.40 7.60 7.80 8.00 8.20 8.40 8.60

0

5000000

1e+07

1.5e+07

Time


7.472

+

#2 TMX - Surrogate


Conc: 49.37 ug/L m

6.00 6.50 7.00 7.50 8.00 8.50 9.00

0

2000000

4000000

6000000

Time


7.293

+


of 329

#3 DBOB


Conc: 51.05 ug/L M4

6.80 7.00 7.20 7.40 7.60 7.80 8.00 8.20 8.40 8.60 8.80 9.00 9.20

0

5000000

1e+07

1.5e+07

Time


7.868

+

#3 DBOB


Conc: 49.37 ug/L m

7.00 7.50 8.00 8.50 9.00 9.50

0

2000000

4000000

6000000

Time


7.911

+


of 329

#4 alpha-BHC


Conc: 51.05 ug/L M4

7.80 8.00 8.20 8.40 8.60 8.80 9.00 9.20 9.40

0

5000000

1e+07

1.5e+07

Time


8.566

+

#4 alpha-BHC


Conc: 49.37 ug/L m

8.00 8.50 9.00 9.50 10.00 10.50

0

2000000

4000000

6000000

Time


9.265

+


of 329



Conc: 51.05 ug/L M4

8.00 8.50 9.00 9.50 10.00

0

5000000

1e+07

1.5e+07

Time


8.868

+



Conc: 49.37 ug/L m

8.00 8.50 9.00 9.50 10.00

0

2000000

4000000

6000000

Time


8.783

+


of 329

#6 beta-BHC


Conc: 51.05 ug/L M4

8.60 8.80 9.00 9.20 9.40 9.60 9.80 10.00 10.20

0

5000000

1e+07

1.5e+07

Time


9.352

+

#6 beta-BHC


Conc: 49.37 ug/L m

10.00 10.50 11.00 11.50 12.00 12.50

0

1000000

2000000

3000000

4000000

5000000

6000000

Time


11.076

+


of 329

#7 gamma-BHC


Conc: 51.05 ug/L M4

8.50 9.00 9.50 10.00 10.50 11.00

0

5000000

1e+07

1.5e+07

Time


9.648

+

#7 gamma-BHC


Conc: 49.37 ug/L m

9.80 10.00 10.20 10.40 10.60 10.80 11.00 11.20 11.40 11.60 11.80

0

1000000

2000000

3000000

4000000

5000000

6000000

Time


10.727

+


of 329

#8 delta-BHC


Conc: 51.05 ug/L M4

9.50 10.00 10.50 11.00 11.50 12.00

0

5000000

1e+07

1.5e+07

Time


10.460

+

#8 delta-BHC


Conc: 49.37 ug/L m

11.50 12.00 12.50 13.00 13.50

0

1000000

2000000

3000000

4000000

5000000

6000000

Time


12.540

+


of 329

#9 heptachlor


Conc: 51.05 ug/L M4

11.50 12.00 12.50 13.00 13.50 14.00

0

5000000

1e+07

1.5e+07

Time


12.722

+

#9 heptachlor


Conc: 49.37 ug/L m

11.50 12.00 12.50 13.00 13.50 14.00 14.50

0

1000000

2000000

3000000

4000000

5000000

6000000

Time


12.907

+


of 329

#10 aldrin


Conc: 102.09 ug/L M4

12.50 13.00 13.50 14.00 14.50 15.00 15.50 16.00 16.50 17.00

0

5000000

1e+07

1.5e+07

Time


14.667

+

#10 aldrin


Conc: 49.37 ug/L m

13.00 13.50 14.00 14.50 15.00 15.50 16.00 16.50 17.00

0

1000000

2000000

3000000

4000000

5000000

Time


14.754

+


of 329

#11 chloropyrifos



12.50 13.00 13.50 14.00 14.50 15.00 15.50 16.00 16.50 17.00

0

5000000

1e+07

1.5e+07

Time


14.667

+

#11 chloropyrifos


Conc: 49.37 ug/L m

15.50 16.00 16.50 17.00 17.50

0

500000

1000000

1500000

2000000

2500000

3000000

Time


16.469

+


of 329




16.00 16.50 17.00 17.50 18.00 18.50

0

5000000

1e+07

1.5e+07

Time


17.235

+



Conc: 49.37 ug/L m

16.50 17.00 17.50 18.00 18.50 19.00 19.50 20.00 20.50 21.00

0

1000000

2000000

3000000

4000000

5000000

Time


18.677

+


of 329

#13 oxychlordane



16.00 16.50 17.00 17.50 18.00 18.50

0

5000000

1e+07

1.5e+07

Time


17.235

+

#13 oxychlordane


Conc: 49.37 ug/L m

16.50 17.00 17.50 18.00 18.50 19.00 19.50

0

1000000

2000000

3000000

4000000

Time


18.032

+


of 329

#14 gamma-chlordane


Conc: 51.05 ug/L M4

18.20 18.40 18.60 18.80 19.00 19.20 19.40 19.60

0

2000000

4000000

6000000

8000000

1e+07

1.2e+07

Time


18.875

+

#14 gamma-chlordane


Conc: 49.37 ug/L m

19.40 19.60 19.80 20.00 20.20 20.40

0

1000000

2000000

3000000

4000000

Time


19.976

+


of 329

#15 2,4'-DDE


Conc: 51.05 ug/L M4

18.00 18.50 19.00 19.50 20.00 20.50

0

5000000

1e+07

Time


19.157

+

#15 2,4'-DDE


Conc: 49.37 ug/L m

19.20 19.40 19.60 19.80 20.00 20.20 20.40 20.60 20.80 21.00 21.20 21.40

0

1000000

2000000

3000000

4000000

5000000

Time


20.151

+


of 329

#16 endosulfan I


Conc: 51.05 ug/L M4

19.20 19.40 19.60 19.80 20.00 20.20 20.40

0

5000000

1e+07

Time


19.764

+

#16 endosulfan I


Conc: 49.37 ug/L m

19.50 20.00 20.50 21.00 21.50 22.00 22.50 23.00

0

1000000

2000000

3000000

4000000

5000000

Time


21.227

+


of 329

#17 alpha-chlordane


Conc: 51.05 ug/L M4

19.20 19.40 19.60 19.80 20.00 20.20 20.40 20.60

0

5000000

1e+07

Time


19.932

+

#17 alpha-chlordane


Conc: 49.37 ug/L m

20.20 20.40 20.60 20.80 21.00 21.20 21.40 21.60

0

1000000

2000000

3000000

4000000

5000000

Time


20.941

+


of 329

#18 trans-nonachlor


Conc: 51.05 ug/L M4

18.00 18.50 19.00 19.50 20.00 20.50 21.00 21.50 22.00 22.50 23.00

0

5000000

1e+07

Time


20.241

+

#18 trans-nonachlor


Conc: 49.37 ug/L m

19.80 20.00 20.20 20.40 20.60 20.80 21.00 21.20 21.40 21.60

0

1000000

2000000

3000000

4000000

5000000

Time


20.616

+


of 329

#19 4,4'-DDE


Conc: 51.05 ug/L M4

20.60 20.80 21.00 21.20 21.40 21.60 21.80

0

5000000

1e+07

Time


21.269

+

#19 4,4'-DDE


Conc: 49.37 ug/L m

21.00 21.50 22.00 22.50 23.00 23.50

0

1000000

2000000

3000000

4000000

5000000

Time


22.200

+


of 329

#20 dieldrin


Conc: 51.05 ug/L M4

20.60 20.80 21.00 21.20 21.40 21.60 21.80 22.00 22.20 22.40

0

5000000

1e+07

Time


21.481

+

#20 dieldrin


Conc: 49.37 ug/L m

22.00 22.50 23.00 23.50 24.00

0

1000000

2000000

3000000

4000000

5000000

Time


22.899

+


of 329

#21 2,4'-DDD


Conc: 51.05 ug/L M4

21.00 21.50 22.00 22.50 23.00

0

5000000

1e+07

Time


21.837

+

#21 2,4'-DDD


Conc: 49.37 ug/L m

22.60 22.80 23.00 23.20 23.40 23.60 23.80 24.00 24.20

0

1000000

2000000

3000000

4000000

5000000

Time


23.354

+


of 329

#22 endrin


Conc: 51.05 ug/L M4

22.00 22.20 22.40 22.60 22.80 23.00 23.20 23.40 23.60 23.80

0

2000000

4000000

6000000

8000000

1e+07

1.2e+07

Time


22.844

+

#22 endrin


Conc: 49.37 ug/L m

23.80 24.00 24.20 24.40 24.60 24.80 25.00 25.20 25.40

0

1000000

2000000

3000000

4000000

5000000

Time


24.591

+


of 329

#23 endosulfan II


Conc: 51.05 ug/L M4

22.50 23.00 23.50 24.00 24.50

0

5000000

1e+07

1.5e+07

Time


23.382

+

#23 endosulfan II


Conc: 49.37 ug/L m

24.50 25.00 25.50 26.00 26.50 27.00 27.50

0

1000000

2000000

3000000

4000000

5000000

Time


25.766

+


of 329

#24 4,4'-DDD


Conc: 51.05 ug/L M4

23.20 23.40 23.60 23.80 24.00 24.20 24.40

0

5000000

1e+07

1.5e+07

Time


23.854

+

#24 4,4'-DDD


Conc: 49.37 ug/L m

24.80 25.00 25.20 25.40 25.60 25.80 26.00 26.20

0

1000000

2000000

3000000

4000000

5000000

Time


25.490

+


of 329

#25 2,4'-DDT


Conc: 51.05 ug/L M4

23.75 23.80 23.85 23.90 23.95 24.00 24.05 24.10 24.15 24.20 24.25 24.30

0

5000000

1e+07

1.5e+07

Time


+

#25 2,4'-DDT


Conc: 49.37 ug/L m

24.60 24.70 24.80 24.90 25.00 25.10 25.20 25.30 25.40

0

1000000

2000000

3000000

4000000

5000000

Time


25.037

+


of 329

#26 cis-nonachlor


Conc: 51.05 ug/L M4

23.60 23.80 24.00 24.20 24.40 24.60 24.80

0

5000000

1e+07

1.5e+07

Time


24.136

+

#26 cis-nonachlor


Conc: 49.37 ug/L m

24.60 24.80 25.00 25.20 25.40 25.60 25.80

0

1000000

2000000

3000000

4000000

5000000

Time


25.161

+


of 329

#27 endrin aldehyde


Conc: 51.05 ug/L M4

22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50

0

5000000

1e+07

1.5e+07

Time


24.487

+

#27 endrin aldehyde


Conc: 49.37 ug/L m

26.60 26.80 27.00 27.20 27.40 27.60 27.80 28.00 28.20 28.40 28.60

0

1000000

2000000

3000000

4000000

5000000

Time


27.541

+


of 329



Conc: 51.05 ug/L M4

25.20 25.40 25.60 25.80 26.00 26.20 26.40

0

2000000

4000000

6000000

8000000

1e+07

1.2e+07

Time


25.807

+



Conc: 49.37 ug/L m

28.00 28.50 29.00 29.50 30.00

0

2000000

4000000

6000000

Time


28.756

+


of 329

#29 4,4'-DDT


Conc: 51.05 ug/L M4

25.00 25.50 26.00 26.50 27.00

0

2000000

4000000

6000000

8000000

1e+07

1.2e+07

Time


25.967

+

#29 4,4'-DDT


Conc: 49.37 ug/L m

26.20 26.40 26.60 26.80 27.00 27.20 27.40 27.60 27.80 28.00

0

1000000

2000000

3000000

4000000

Time


27.101

+


of 329

#30 endrin ketone


Conc: 51.05 ug/L M4

27.60 27.80 28.00 28.20 28.40 28.60 28.80

0

5000000

1e+07

1.5e+07

Time


28.271

+

#30 endrin ketone


Conc: 49.37 ug/L m

30.30 30.40 30.50 30.60 30.70 30.80 30.90 31.00 31.10 31.20 31.30

0

1000000

2000000

3000000

4000000

5000000

Time


30.828

+


of 329

#31 methoxychlor


Conc: 51.05 ug/L M4

28.20 28.40 28.60 28.80 29.00 29.20 29.40

0

5000000

1e+07

1.5e+07

2e+07

Time


28.800

+

#31 methoxychlor


Conc: 49.37 ug/L m

29.20 29.40 29.60 29.80 30.00 30.20 30.40 30.60 30.80 31.00

0

2000000

4000000

6000000

Time


30.062

+


of 329

#32 mirex


Conc: 51.05 ug/L M4

30.00 30.20 30.40 30.60 30.80 31.00 31.20

0

2000000

4000000

6000000

8000000

1e+07

1.2e+07

Time


30.538

+

#32 mirex


Conc: 49.37 ug/L m

30.00 30.20 30.40 30.60 30.80 31.00 31.20

0

1000000

2000000

3000000

4000000

5000000

Time


30.604

+


of 329

#33 BZ 198


Conc: 51.05 ug/L M4

30.00 30.50 31.00 31.50 32.00

0

2000000

4000000

6000000

8000000

1e+07

1.2e+07

Time


30.778

+

#33 BZ 198


Conc: 49.37 ug/L m

30.50 30.60 30.70 30.80 30.90 31.00 31.10 31.20 31.30 31.40 31.50

0

1000000

2000000

3000000

4000000

5000000

Time


31.001

+


of 329

#34 DCB - Surrogate


Conc: 51.05 ug/L M4

35.50 36.00 36.50 37.00 37.50 38.00 38.50 39.00 39.50

0

2000000

4000000

6000000

8000000

1e+07

Time


37.223

+

#34 DCB - Surrogate


Conc: 49.37 ug/L m

36.00 36.50 37.00 37.50 38.00 38.50 39.00

0

1000000

2000000

3000000

Time


37.537

+


of 329


Data Path : O:\Organics\DATA\ECD2-6890N\2012\OCT\OCT29\Data File : F210291216.D Signal(s) : Signal #1: ECD1A.CH Signal #2: ECD2B.CHAcq On : 29 Oct 2012 11:59 pmOperator : ECD2:RRSample : I210291207 (Sig #1); I210291201 (Sig #2)Misc : WG571275,PW071312CALS Vial : 17 Sample Multiplier: 1





1) I BZ 192 29.13 29.31 805.8E6 237.2E6 50.000M4 50.000M4


Spiked Amount 100.000 Range 30 - 150 Recovery = 95.62% 95.15% 3) S DBOB 7.87 7.91 1113.2E6 358.9E6 93.660M4 92.882M4

Spiked Amount 100.000 Range 30 - 150 Recovery = 93.66% 92.88% 33) S BZ 198 30.78 31.00 1007.5E6 286.0E6 91.275M4 88.954M4





6) T beta-BHC 9.35 11.08 598.8E6 231.4E6 91.412M4 91.757M4

7) T gamma-BHC 9.65 10.73 1441.3E6 509.9E6 103.182M4 102.973M4

8) T delta-BHC 10.46 12.54 1413.0E6 495.6E6 110.679M4 105.509M4


10) T aldrin 14.67 14.75 1956.9E6 435.4E6 190.773M4 (C) 95.771M4 D


of 329







11) T chloropyrifos 14.67 16.47 1957.4E6 204.9E6 190.672M4 (C) 83.168M4 D




15) T 2,4'-DDE 19.16 20.15 774.2E6 247.2E6 96.164M4 86.793M4




19) T 4,4'-DDE 21.27 22.20 1206.3E6 351.7E6 108.613M4 100.317M4

20) T dieldrin 21.48 22.90 1307.8E6 389.2E6 103.752M5 96.122M4

21) T 2,4'-DDD 21.84 23.35 721.8E6 216.9E6 95.386M4 90.172M4

22) T endrin 22.84 24.59 1152.5E6 337.2E6 88.291M3 80.107M4


24) T 4,4'-DDD 23.85 25.49 978.9E6 284.2E6 105.900M4 100.113M4

25) T 2,4'-DDT 24.07 25.04 805.3E6 258.1E6 98.379M4 92.196M4




of 329








29) T 4,4'-DDT 25.97 27.10 1058.8E6 287.0E6 78.833M4 73.387M4


31) T methoxychlor 28.80 30.06 515.5E6 150.0E6 88.859M4 87.474M4

32) T mirex 30.54 30.60 881.2E6 254.9E6 85.019M4 80.539M4





of 329


Data Path : O:\Organics\DATA\ECD2-6890N\2012\OCT\OCT29\Data File : F210291216.DOperator : ECD2:RRAcquired : 29 Oct 2012 11:59 pm using AcqMethod PESTECD2.MInstrument: HP G1530ASample : I210291207 Misc Info : WG571275,PW071312C ??H5?ALS Vial : 17

2.00 4.00 6.00 8.00 10.00 12.00 14.00 16.00 18.00 20.00 22.00 24.00 26.00 28.00 30.00 32.00 34.00 36.00 38.00

0

5000000

1e+07

1.5e+07

2e+07

2.5e+07

3e+07

3.5e+07

4e+07

Time


2.00 4.00 6.00 8.00 10.00 12.00 14.00 16.00 18.00 20.00 22.00 24.00 26.00 28.00 30.00 32.00 34.00 36.00 38.00

0

2000000

4000000

6000000

8000000

1e+07

1.2e+07

1.4e+07

1.6e+07

Time



of 329


Data Path : O:\Organics\DATA\ECD2-6890N\2012\OCT\OCT29\Data File : F210291217.D Signal(s) : Signal #1: ECD1A.CH Signal #2: ECD2B.CHAcq On : 30 Oct 2012 12:43 amOperator : ECD2:RRSample : I210291208 (Sig #1); I210291201 (Sig #2)Misc : WG571275,PW071912QALS Vial : 18 Sample Multiplier: 1





1) I BZ 192 29.13 29.31 684.1E6 202.8E6 50.000M4 50.000M4


Spiked Amount 100.000 Range 30 - 150 Recovery = 155.85%# 153.12%#3) S DBOB 7.87 7.91 1544.8E6 495.2E6 153.103M4 149.948M4

Spiked Amount 100.000 Range 30 - 150 Recovery = 153.10%# 149.95% 33) S BZ 198 30.78 31.00 1263.7E6 357.4E6 136.889M4 132.242M4





6) T beta-BHC 9.35 11.08 790.0E6 309.3E6 143.355M4 144.236M3

7) T gamma-BHC 9.65 10.73 1984.9E6 700.3E6 165.450M4 163.325M4

8) T delta-BHC 10.46 12.54 1868.8E6 660.8E6 169.747M4 162.587M4


10) T aldrin 14.67 14.76 2663.5E6 607.7E6 305.903M4 (C) 155.540M4 D


of 329











15) T 2,4'-DDE 19.16 20.15 1014.2E6 329.7E6 148.956M4 137.092M4




19) T 4,4'-DDE 21.27 22.20 1554.6E6 464.0E6 163.312M4 154.217M4

20) T dieldrin 21.48 22.90 1802.6E6 533.3E6 166.366M4 153.575M4

21) T 2,4'-DDD 21.84 23.35 922.7E6 278.3E6 144.748M4 137.029M4

22) T endrin 22.84 24.59 1544.2E6 455.8E6 140.929M4 129.194M4


24) T 4,4'-DDD 23.85 25.49 1226.7E6 361.2E6 155.907M4 148.958M4

25) T 2,4'-DDT 24.07 25.04 1075.3E6 305.6E6 154.522M4 130.151M4




of 329








29) T 4,4'-DDT 25.97 27.10 1379.5E6 373.1E6 124.238M4 115.320M4



32) T mirex 30.54 30.60 1143.8E6 331.2E6 132.491M4 125.320M4





of 329


Data Path : O:\Organics\DATA\ECD2-6890N\2012\OCT\OCT29\Data File : F210291217.DOperator : ECD2:RRAcquired : 30 Oct 2012 12:43 am using AcqMethod PESTECD2.MInstrument: HP G1530ASample : I210291208 Misc Info : WG571275,PW071912Q ??H5?ALS Vial : 18

2.00 4.00 6.00 8.00 10.00 12.00 14.00 16.00 18.00 20.00 22.00 24.00 26.00 28.00 30.00 32.00 34.00 36.00 38.00

0

1e+07

2e+07

3e+07

4e+07

5e+07

Time


2.00 4.00 6.00 8.00 10.00 12.00 14.00 16.00 18.00 20.00 22.00 24.00 26.00 28.00 30.00 32.00 34.00 36.00 38.00

0

5000000

1e+07

1.5e+07

2e+07

Time



of 329


Data Path : O:\Organics\DATA\ECD2-6890N\2012\OCT\OCT29\Data File : F210291218.D Signal(s) : Signal #1: ECD1A.CH Signal #2: ECD2B.CHAcq On : 30 Oct 2012 1:27 amOperator : ECD2:RRSample : I210291209 (Sig #1); I210291201 (Sig #2)Misc : WG571275,PW071912PALS Vial : 19 Sample Multiplier: 1





1) I BZ 192 29.13 29.31 713.2E6 208.9E6 50.000M4 50.000M4


Spiked Amount 100.000 Range 30 - 150 Recovery = 200.76%# 202.31%#3) S DBOB 7.87 7.91 1996.7E6 648.0E6 191.370M4 192.105M4

Spiked Amount 100.000 Range 30 - 150 Recovery = 191.37%# 192.10%#33) S BZ 198 30.78 31.00 1635.7E6 463.9E6 173.228M4 170.270M4

Spiked Amount 100.000 Range 30 - 150 Recovery = 173.23%# 170.27%#34) S DCB - Surrogat 37.22 37.54 1501.9E6 415.6E6 167.606M4 156.827M4




6) T beta-BHC 9.36 11.08 1053.6E6 412.9E6 185.543M4 188.887M4

7) T gamma-BHC 9.65 10.73 2712.5E6 976.0E6 215.460M4 219.249M4

8) T delta-BHC 10.47 12.54 2574.2E6 917.6E6 221.926M4 217.681M4


10) T aldrin 14.67 14.76 3556.1E6 822.9E6 393.644M4 (C) 204.647M4 D


of 329











15) T 2,4'-DDE 19.16 20.15 1342.7E6 426.9E6 190.771M4 175.502M4


17) T alpha-chlordan 19.94 20.95 2375.2E6 702.7E6 201.345M4 192.207


19) T 4,4'-DDE 21.27 22.20 2093.3E6 632.4E6 210.222M4 204.299M4

20) T dieldrin 21.48 22.90 2372.4E6 715.2E6 209.423M4 200.601M4

21) T 2,4'-DDD 21.84 23.35 1222.8E6 369.3E6 186.107M4 179.382M4

22) T endrin 22.85 24.59 2098.0E6 626.7E6 185.792M4 175.619M4


24) T 4,4'-DDD 23.86 25.49 1655.3E6 490.1E6 202.124M4 197.297M4

25) T 2,4'-DDT 24.07 25.04 1331.6E6 440.7E6 185.684M4 184.570M4




of 329








29) T 4,4'-DDT 25.97 27.10 1847.8E6 502.4E6 163.629M4 155.358M4


31) T methoxychlor 28.81 30.06 846.3E6 244.6E6 171.748 169.234M4

32) T mirex 30.54 30.60 1468.2E6 420.2E6 166.895M4 158.752M4





of 329


Data Path : O:\Organics\DATA\ECD2-6890N\2012\OCT\OCT29\Data File : F210291218.DOperator : ECD2:RRAcquired : 30 Oct 2012 1:27 am using AcqMethod PESTECD2.MInstrument: HP G1530ASample : I210291209 Misc Info : WG571275,PW071912P ??H5?ALS Vial : 19

2.00 4.00 6.00 8.00 10.00 12.00 14.00 16.00 18.00 20.00 22.00 24.00 26.00 28.00 30.00 32.00 34.00 36.00 38.00

0

1e+07

2e+07

3e+07

4e+07

5e+07

6e+07

7e+07

Time


2.00 4.00 6.00 8.00 10.00 12.00 14.00 16.00 18.00 20.00 22.00 24.00 26.00 28.00 30.00 32.00 34.00 36.00 38.00

0

5000000

1e+07

1.5e+07

2e+07

2.5e+07

Time



of 329

Initial Calibration Verification

of 329

Evaluate Continuing Calibration Report

Data Path : O:\Organics\DATA\ECD2-6890N\2012\OCT\OCT29\Data File : F210291220.D Signal(s) : Signal #1: ECD1A.CH Signal #2: ECD2B.CHAcq On : 30 Oct 2012 2:55 amOperator : ECD2:RRSample : C210291210 Misc : WG571275,PW102612JALS Vial : 21 Sample Multiplier: 1

Integration File signal 1: autoint1.eIntegration File signal 2: autoint2.eQuant Time: Oct 31 11:06:52 2012Quant Method : O:\Organics\METHODS\ECD2-6890N\2012\PEST21029.MQuant Title : PESTICIDES BY 8081A-ECD2QLast Update : Wed Oct 31 11:02:31 2012Response via : Initial CalibrationIntegrator: ChemStation 6890 Scale Mode: Large solvent peaks clipped


Min. RRF : 0.000 Min. Rel. Area : 50% Max. R.T. Dev 0.50minMax. RRF Dev : 15% Max. Rel. Area : 150%

Compound Amount Calc. %Dev Area% Dev(Min)-------------------------------------------------------------------------1 I BZ 192 50.000 50.000 0.0 111 0.00 4 T alpha-BHC 50.000 51.090 -2.2 97 0.00 5 T hexachlorobenzene 50.000 44.323 11.4 88 0.00 6 T beta-BHC 50.000 46.439 7.1 101 0.00 7 T gamma-BHC 50.000 49.658 0.7 97 0.00 8 T delta-BHC 50.000 51.271 -2.5 103 0.00 9 T heptachlor 50.000 48.250 3.5 96 0.00 10 T aldrin 100.000 96.355 3.6 97 0.00 11 T chloropyrifos 100.000 96.295 3.7 97 0.00 12 T heptachlor epoxide (B) 100.000 98.564 1.4 101 0.00 13 T oxychlordane 100.000 98.302 1.7 100 0.00 14 T gamma-chlordane 50.000 48.952 2.1 101 0.00 15 T 2,4'-DDE 50.000 48.491 3.0 99 0.00 16 T endosulfan I 50.000 47.615 4.8 102 0.00 17 T alpha-chlordane 50.000 50.265 -0.5 103 0.00 18 T trans-nonachlor 50.000 46.454 7.1 95 0.00 19 T 4,4'-DDE 50.000 49.845 0.3 107 0.00 20 T dieldrin 50.000 50.737 -1.5 102 0.00 21 T 2,4'-DDD 50.000 47.242 5.5 102 0.00 22 T endrin 50.000 49.165 1.7 105 0.00 23 T endosulfan II 50.000 50.164 -0.3 108 0.00 24 T 4,4'-DDD 50.000 49.722 0.6 111 0.00 25 T 2,4'-DDT 50.000 42.657 14.7 92 0.00 26 T cis-nonachlor 50.000 47.276 5.4 102 0.00 27 T endrin aldehyde 50.000 48.489 3.0 111 0.00 28 T endosulfan sulfate 50.000 43.757 12.5 110 0.00 29 T 4,4'-DDT 50.000 47.837 4.3 107 0.00 30 T endrin ketone 50.000 50.696 -1.4 119 0.00 31 T methoxychlor 50.000 45.299 9.4 106 0.00 32 T mirex 50.000 43.661 12.7 102 0.00


of 329






Compound Amount Calc. %Dev Area% Dev(Min)-------------------------------------------------------------------------Signal #2

1 I BZ 192 50.000 50.000 0.0 111 0.00 4 T alpha-BHC 50.000 50.063 -0.1 96 0.00 5 T hexachlorobenzene 50.000 45.137 9.7 90 0.00 6 T beta-BHC 50.000 48.180 3.6 99 0.00 7 T gamma-BHC 50.000 49.830 0.3 98 0.00 8 T delta-BHC 50.000 49.747 0.5 104 0.00 9 T heptachlor 50.000 48.517 3.0 96 0.00 10 T aldrin 50.000 48.360 3.3 97 0.00 11 T chloropyrifos 50.000 46.266 7.5 96 0.00 12 T heptachlor epoxide (B) 50.000 47.956 4.1 98 0.00 13 T oxychlordane 50.000 49.147 1.7 101 0.00 14 T gamma-chlordane 50.000 46.884 6.2 103 0.00 15 T 2,4'-DDE 50.000 45.780 8.4 98 0.00 16 T endosulfan I 50.000 48.479 3.0 100 0.00 17 T alpha-chlordane 50.000 49.401 1.2 104 0.00 18 T trans-nonachlor 50.000 46.280 7.4 98 0.00 19 T 4,4'-DDE 50.000 48.003 4.0 106 0.00 20 T dieldrin 50.000 48.989 2.0 102 0.00 21 T 2,4'-DDD 50.000 46.155 7.7 102 0.00 22 T endrin 50.000 48.833 2.3 105 0.00 23 T endosulfan II 50.000 51.524 -3.0 108 0.00 24 T 4,4'-DDD 50.000 49.722 0.6 111 0.00 25 T 2,4'-DDT 50.000 47.579 4.8 111 0.00 26 T cis-nonachlor 50.000 45.315 9.4 102 0.00 27 T endrin aldehyde 50.000 49.184 1.6 112 0.00 28 T endosulfan sulfate 50.000 47.733 4.5 107 0.00 29 T 4,4'-DDT 50.000 48.201 3.6 107 0.00 30 T endrin ketone 50.000 53.373 -6.7 124 0.00


of 329






Compound Amount Calc. %Dev Area% Dev(Min)-------------------------------------------------------------------------31 T methoxychlor 50.000 46.678 6.6 107 0.00 32 T mirex 50.000 45.190 9.6 103 0.00

Evaluate Continuing Calibration Report - Not Founds

2 S TMX - Surrogate 50.000 0.000 100.0# 0 -7.47#3 S DBOB 50.000 0.000 100.0# 0 -7.87#33 S BZ 198 50.000 0.000 100.0# 0 -30.78#34 S DCB - Surrogate 50.000 0.000 100.0# 0 -37.22#35 T Toxaphene -1.000 0.000 0.0 0 -0.11 36 T Technical Chlordane -1.000 0.000 0.0 0 -0.11

Signal #2

2 S TMX - Surrogate 50.000 0.000 100.0# 0 -7.29#3 S DBOB 50.000 0.000 100.0# 0 -7.91#33 S BZ 198 50.000 0.000 100.0# 0 -31.00#34 S DCB - Surrogate 50.000 0.000 100.0# 0 -37.54#35 T Toxaphene -1.000 0.000 0.0 0 -0.11 36 T Technical Chlordane -1.000 0.000 0.0 0 -37.42#--------------------------------------------------------------------------

(#) = Out of Range SPCC's out = 0 CCC's out = 0


of 329







1) I BZ 192 29.13 29.31 670.8E6 197.2E6 50.000M4 50.000M4

System Monitoring Compounds2) S TMX - Surrogat 0.00 0.00 0 0 N.D. N.D. Spiked Amount 100.000 Range 30 - 150 Recovery = 0.00%# 0.00%#3) S DBOB 0.00 0.00 0 0 N.D. N.D. Spiked Amount 100.000 Range 30 - 150 Recovery = 0.00%# 0.00%#

33) S BZ 198 0.00 0.00 0 0 N.D. N.D. Spiked Amount 100.000 Range 30 - 150 Recovery = 0.00%# 0.00%#

34) S DCB - Surrogat 0.00 0.00 0 0 N.D. N.D. Spiked Amount 100.000 Range 30 - 150 Recovery = 0.00%# 0.00%#



6) T beta-BHC 9.36 11.08 250.9E6 98812506 46.439M4 48.180M3

7) T gamma-BHC 9.65 10.73 595.1E6 208.3E6 49.658M4 49.830M4

8) T delta-BHC 10.47 12.54 566.0E6 197.0E6 51.271M4 49.747M4


10) T aldrin 14.67 14.76 828.6E6 182.6E6 96.355M4 (C) 48.360M4 D


12) T heptachlor epo 17.24 18.68 1014.0E6 173.6E6 98.564M4 (C) 47.956m D


of 329









15) T 2,4'-DDE 19.16 20.15 324.8E6 104.5E6 48.491M4 45.780M4




19) T 4,4'-DDE 21.27 22.20 472.3E6 139.5E6 49.845M4 48.003M4

20) T dieldrin 21.48 22.90 547.1E6 164.0E6 50.737M4 48.989M4

21) T 2,4'-DDD 21.84 23.35 295.3E6 89136673 47.242M4 46.155M4

22) T endrin 22.84 24.59 484.5E6 142.6E6 49.165M4 48.833M4


24) T 4,4'-DDD 23.85 25.49 387.4E6 116.0E6 49.722M4 49.722M4

25) T 2,4'-DDT 24.07 25.04 290.8E6 106.6E6 42.657M4 47.579M4




29) T 4,4'-DDT 25.97 27.10 421.7E6 116.0E6 47.837M4 48.201M4


of 329









32) T mirex 30.54 30.60 365.5E6 112.1E6 43.661M4 45.190M4





of 329


Data Path : O:\Organics\DATA\ECD2-6890N\2012\OCT\OCT29\Data File : F210291220.DOperator : ECD2:RRAcquired : 30 Oct 2012 2:55 am using AcqMethod PESTECD2.MInstrument: HP G1530ASample : C210291210 Misc Info : WG571275,PW102612J ??H5?ALS Vial : 21

2.00 4.00 6.00 8.00 10.00 12.00 14.00 16.00 18.00 20.00 22.00 24.00 26.00 28.00 30.00 32.00 34.00 36.00 38.00

0

5000000

1e+07

1.5e+07

2e+07

Time


2.00 4.00 6.00 8.00 10.00 12.00 14.00 16.00 18.00 20.00 22.00 24.00 26.00 28.00 30.00 32.00 34.00 36.00 38.00

0

1000000

2000000

3000000

4000000

5000000

6000000

7000000

Time



of 329


Data Path : O:\Organics\DATA\ECD2-6890N\2012\OCT\OCT30\Data File : F210301251.D Signal(s) : Signal #1: ECD1A.CH Signal #2: ECD2B.CHAcq On : 31 Oct 2012 8:46 pmOperator : ECD2:RRSample : I210291212 (Sig #1); I210291211 (Sig #2)Misc : WG571275,PW061312A CHLORALS Vial : 35 Sample Multiplier: 1

Integration File signal 1: autoint1.eIntegration File signal 2: autoint2.eQuant Time: Nov 01 12:52:46 2012Quant Method : O:\Organics\METHODS\ECD2-6890N\2012\PEST21029.MQuant Title : PESTICIDES BY 8081A-ECD2QLast Update : Wed Oct 31 11:02:31 2012Response via : Initial CalibrationIntegrator: ChemStation 6890 Scale Mode: Large solvent peaks clipped




1) I BZ 192 0.00 0.00 0 0 N.D. d N.D. d

System Monitoring Compounds2) S TMX - Surrogat 0.00 0.00 0 0 N.D. d N.D. d Spiked Amount 100.000 Range 30 - 150 Recovery = 0.00%# 0.00%#3) S DBOB 0.00 0.00 0 0 N.D. d N.D. d Spiked Amount 100.000 Range 30 - 150 Recovery = 0.00%# 0.00%#

33) S BZ 198 0.00 0.00 0 0 N.D. d N.D. d Spiked Amount 100.000 Range 30 - 150 Recovery = 0.00%# 0.00%#

34) S DCB - Surrogat 0.00 0.00 0 0 N.D. d N.D. d Spiked Amount 100.000 Range 30 - 150 Recovery = 0.00%# 0.00%#

Target Compounds4) T alpha-BHC 0.00 0.00 0 0 N.D. d N.D. d 5) T hexachlorobenz 0.00 0.00 0 0 N.D. d N.D. d 6) T beta-BHC 0.00 0.00 0 0 N.D. d N.D. d 7) T gamma-BHC 0.00 0.00 0 0 N.D. d N.D. d 8) T delta-BHC 0.00 0.00 0 0 N.D. d N.D. d 9) T heptachlor 0.00 0.00 0 0 N.D. d N.D. d 10) T aldrin 0.00 0.00 0 0 N.D. d(C) N.D. d 11) T chloropyrifos 0.00 0.00 0 0 N.D. d(C) N.D. d 12) T heptachlor epo 0.00 0.00 0 0 N.D. d(C) N.D. d 13) T oxychlordane 0.00 0.00 0 0 N.D. d(C) N.D. d 14) T gamma-chlordan 0.00 0.00 0 0 N.D. d N.D. d 15) T 2,4'-DDE 0.00 0.00 0 0 N.D. d N.D. d 16) T endosulfan I 0.00 0.00 0 0 N.D. d N.D. d 17) T alpha-chlordan 0.00 0.00 0 0 N.D. d N.D. d 18) T trans-nonachlo 0.00 0.00 0 0 N.D. d N.D. d 19) T 4,4'-DDE 0.00 0.00 0 0 N.D. d N.D. d 20) T dieldrin 0.00 0.00 0 0 N.D. d N.D. d 21) T 2,4'-DDD 0.00 0.00 0 0 N.D. d N.D. d 22) T endrin 0.00 0.00 0 0 N.D. d N.D. d


of 329


Data Path : O:\Organics\DATA\ECD2-6890N\2012\OCT\OCT30\Data File : F210301251.D Signal(s) : Signal #1: ECD1A.CH Signal #2: ECD2B.CHAcq On : 31 Oct 2012 8:46 pmOperator : ECD2:RRSample : I210291212 (Sig #1); I210291211 (Sig #2)Misc : WG571275,PW061312A CHLORALS Vial : 35 Sample Multiplier: 1





23) T endosulfan II 0.00 0.00 0 0 N.D. d N.D. d 24) T 4,4'-DDD 0.00 0.00 0 0 N.D. d N.D. d 25) T 2,4'-DDT 0.00 0.00 0 0 N.D. d N.D. d 26) T cis-nonachlor 0.00 0.00 0 0 N.D. d N.D. d 27) T endrin aldehyd 0.00 0.00 0 0 N.D. d N.D. d 28) T endosulfan sul 0.00 0.00 0 0 N.D. d N.D. d 29) T 4,4'-DDT 0.00 0.00 0 0 N.D. d N.D. d 30) T endrin ketone 0.00 0.00 0 0 N.D. d N.D. d 31) T methoxychlor 0.00 0.00 0 0 N.D. d N.D. d 32) T mirex 0.00 0.00 0 0 N.D. d N.D. d 35) T Toxaphene 0.00 0.00 0 0 N.D. d N.D. d 36) T Technical Chlo 0.00 0.00 0 0 N.D. d N.D. d




of 329


Data Path : O:\Organics\DATA\ECD2-6890N\2012\OCT\OCT30\Data File : F210301251.DOperator : ECD2:RRAcquired : 31 Oct 2012 8:46 pm using AcqMethod PESTECD2.MInstrument: HP G1530ASample : I210291212 Misc Info : WG571275,PW061312A CHLOR ??EO?ALS Vial : 35

2.00 4.00 6.00 8.00 10.00 12.00 14.00 16.00 18.00 20.00 22.00 24.00 26.00 28.00 30.00 32.00 34.00 36.00 38.00

1000000

1500000

2000000

2500000

3000000

3500000

4000000

Time


2.00 4.00 6.00 8.00 10.00 12.00 14.00 16.00 18.00 20.00 22.00 24.00 26.00 28.00 30.00 32.00 34.00 36.00 38.00

800000

900000

1000000

1100000

1200000

1300000

1400000

1500000

1600000

1700000

Time



of 329


Data Path : O:\Organics\DATA\ECD2-6890N\2012\OCT\OCT30\Data File : F210301252.D Signal(s) : Signal #1: ECD1A.CH Signal #2: ECD2B.CHAcq On : 31 Oct 2012 9:30 pmOperator : ECD2:RRSample : I210291211 (Sig #1); I210291212 (Sig #2)Misc : WG571275,PW071312I TOXALS Vial : 36 Sample Multiplier: 1





1) I BZ 192 0.00 0.00 0 0 N.D. d N.D. d

System Monitoring Compounds2) S TMX - Surrogat 0.00 0.00 0 0 N.D. d N.D. d Spiked Amount 100.000 Range 30 - 150 Recovery = 0.00%# 0.00%#3) S DBOB 0.00 0.00 0 0 N.D. d N.D. d Spiked Amount 100.000 Range 30 - 150 Recovery = 0.00%# 0.00%#

33) S BZ 198 0.00 0.00 0 0 N.D. d N.D. d Spiked Amount 100.000 Range 30 - 150 Recovery = 0.00%# 0.00%#

34) S DCB - Surrogat 0.00 0.00 0 0 N.D. d N.D. d Spiked Amount 100.000 Range 30 - 150 Recovery = 0.00%# 0.00%#

Target Compounds4) T alpha-BHC 0.00 0.00 0 0 N.D. d N.D. d 5) T hexachlorobenz 0.00 0.00 0 0 N.D. d N.D. d 6) T beta-BHC 0.00 0.00 0 0 N.D. d N.D. d 7) T gamma-BHC 0.00 0.00 0 0 N.D. d N.D. d 8) T delta-BHC 0.00 0.00 0 0 N.D. d N.D. d 9) T heptachlor 0.00 0.00 0 0 N.D. d N.D. d 10) T aldrin 0.00 0.00 0 0 N.D. d(C) N.D. d 11) T chloropyrifos 0.00 0.00 0 0 N.D. d(C) N.D. d 12) T heptachlor epo 0.00 0.00 0 0 N.D. d(C) N.D. d 13) T oxychlordane 0.00 0.00 0 0 N.D. d(C) N.D. d 14) T gamma-chlordan 0.00 0.00 0 0 N.D. d N.D. d 15) T 2,4'-DDE 0.00 0.00 0 0 N.D. d N.D. d 16) T endosulfan I 0.00 0.00 0 0 N.D. d N.D. d 17) T alpha-chlordan 0.00 0.00 0 0 N.D. d N.D. d 18) T trans-nonachlo 0.00 0.00 0 0 N.D. d N.D. d 19) T 4,4'-DDE 0.00 0.00 0 0 N.D. d N.D. d 20) T dieldrin 0.00 0.00 0 0 N.D. d N.D. d 21) T 2,4'-DDD 0.00 0.00 0 0 N.D. d N.D. d 22) T endrin 0.00 0.00 0 0 N.D. d N.D. d


of 329


Data Path : O:\Organics\DATA\ECD2-6890N\2012\OCT\OCT30\Data File : F210301252.D Signal(s) : Signal #1: ECD1A.CH Signal #2: ECD2B.CHAcq On : 31 Oct 2012 9:30 pmOperator : ECD2:RRSample : I210291211 (Sig #1); I210291212 (Sig #2)Misc : WG571275,PW071312I TOXALS Vial : 36 Sample Multiplier: 1





23) T endosulfan II 0.00 0.00 0 0 N.D. d N.D. d 24) T 4,4'-DDD 0.00 0.00 0 0 N.D. d N.D. d 25) T 2,4'-DDT 0.00 0.00 0 0 N.D. d N.D. d 26) T cis-nonachlor 0.00 0.00 0 0 N.D. d N.D. d 27) T endrin aldehyd 0.00 0.00 0 0 N.D. d N.D. d 28) T endosulfan sul 0.00 0.00 0 0 N.D. d N.D. d 29) T 4,4'-DDT 0.00 0.00 0 0 N.D. d N.D. d 30) T endrin ketone 0.00 0.00 0 0 N.D. d N.D. d 31) T methoxychlor 0.00 0.00 0 0 N.D. d N.D. d 32) T mirex 0.00 0.00 0 0 N.D. d N.D. d 35) T Toxaphene 0.00 0.00 0 0 N.D. d N.D. d 36) T Technical Chlo 0.00 0.00 0 0 N.D. d N.D. d




of 329


Data Path : O:\Organics\DATA\ECD2-6890N\2012\OCT\OCT30\Data File : F210301252.DOperator : ECD2:RRAcquired : 31 Oct 2012 9:30 pm using AcqMethod PESTECD2.MInstrument: HP G1530ASample : I210291211 Misc Info : WG571275,PW071312I TOX ??EO?ALS Vial : 36

2.00 4.00 6.00 8.00 10.00 12.00 14.00 16.00 18.00 20.00 22.00 24.00 26.00 28.00 30.00 32.00 34.00 36.00 38.00

1200000

1400000

1600000

1800000

2000000

2200000

2400000

2600000

2800000

3000000

Time


2.00 4.00 6.00 8.00 10.00 12.00 14.00 16.00 18.00 20.00 22.00 24.00 26.00 28.00 30.00 32.00 34.00 36.00 38.00

800000

900000

1000000

1100000

1200000

1300000

1400000

1500000

1600000

Time



of 329

Work Group

of 329

ALPHA ANALYTICAL LABORATORIES, INC.

Alpha WORK GROUP REPORT (wk02)

Nov 01 2012, 01:50 pm

Work Group: WG569308 for Department: 2 Organic Preparation

Created: 24-OCT-12 Due: Operator: sr

Sample Client ID C Product Matrix Stat UA HOLD DUE PR Location ____________________________________________________________________________________________________________________________________

L1219133-01 SED-20121017-01 S A2-PEST-8081 SOIL DONE U 1031 1031 S0 Amber-A.25 WG569308-1 Laboratory Method Bl S A2-PEST-8081 SOIL DONE U WG569308-2 Laboratory Control S S A2-PEST-8081 SOIL DONE U WG569308-3 LCS Duplicate S A2-PEST-8081 SOIL DONE U

Comments:

WG569308-3 WG569308-2

____________________________________________________________________________________________________________________________________

Page 1

of 329

Sequence Logs

of 329

of 329

Analytical Event

of 329

Degradation Check Standard

of 329


Data Path : O:\Organics\DATA\ECD2-6890N\2012\OCT\OCT30\Data File : F210301237.D Signal(s) : Signal #1: ECD1A.CH Signal #2: ECD2B.CHAcq On : 31 Oct 2012 11:58 amOperator : ECD2:RRSample : PEM210301203 (Sig #1); PEM (Sig #2)Misc : WG570776,PW082712BALS Vial : 2 Sample Multiplier: 1



Sub List : PEM - Degradation Check


1) I BZ 192 0.00 0.00 0 0 N.D. d N.D.

System Monitoring Compounds

Target Compounds19) T 4,4'-DDE 21.28 22.21 3337372 1444303 N.D. M4 N.D. M4

22) T endrin 22.84 24.58 1708.3E6 541.8E6 N.D. M4 N.D. M4

24) T 4,4'-DDD 23.86 25.49 32057510 10385289 N.D. M4 N.D. M4

27) T endrin aldehyd 24.50 27.54 8034096 2941948 N.D. M4 N.D. M4

29) T 4,4'-DDT 25.97 27.09 2950.7E6 924.9E6 N.D. M4 N.D. M4

30) T endrin ketone 28.27 30.82 51234907 15775939 N.D. M4 N.D. M4




of 329


Data Path : O:\Organics\DATA\ECD2-6890N\2012\OCT\OCT30\Data File : F210301237.DOperator : ECD2:RRAcquired : 31 Oct 2012 11:58 am using AcqMethod PESTECD2.MInstrument: HP G1530ASample : PEM210301203 Misc Info : WG570776,PW082712B ??EO?ALS Vial : 2

0.00 2.00 4.00 6.00 8.00 10.00 12.00 14.00 16.00 18.00 20.00 22.00 24.00 26.00 28.00 30.00 32.00 34.00 36.00 38.00

0

2e+07

4e+07

6e+07

8e+07

Time


0.00 2.00 4.00 6.00 8.00 10.00 12.00 14.00 16.00 18.00 20.00 22.00 24.00 26.00 28.00 30.00 32.00 34.00 36.00 38.00

0

5000000

1e+07

1.5e+07

2e+07

2.5e+07

Time



of 329

Continuing Calibration

of 329


Data Path : O:\Organics\DATA\ECD2-6890N\2012\OCT\OCT30\Data File : F210301238.D Signal(s) : Signal #1: ECD1A.CH Signal #2: ECD2B.CHAcq On : 31 Oct 2012 12:42 pmOperator : ECD2:RRSample : WG570776-1 (Sig #1); WG (Sig #2)Misc : WG570776,PW071212AALS Vial : 25 Sample Multiplier: 1




Compound Amount Calc. %Dev Area% Dev(Min)-------------------------------------------------------------------------1 I BZ 192 50.000 50.000 0.0 122 0.00 2 S TMX - Surrogate 50.000 54.254 -8.5 116 0.00 4 T alpha-BHC 50.000 58.627 -17.3# 122 0.00 5 T hexachlorobenzene 50.000 52.072 -4.1 113 0.00 6 T beta-BHC 50.000 54.045 -8.1 128 0.00 7 T gamma-BHC 50.000 56.172 -12.3 120 0.00 8 T delta-BHC 50.000 60.441 -20.9# 132 0.00 9 T heptachlor 50.000 54.655 -9.3 119 0.00 10 T aldrin 100.000 109.366 -9.4 121 0.00 12 T heptachlor epoxide (B) 100.000 109.132 -9.1 122 -0.01 13 T oxychlordane 100.000 109.054 -9.1 122 -0.01 14 T gamma-chlordane 50.000 55.743 -11.5 126 0.00 15 T 2,4'-DDE 50.000 55.351 -10.7 124 0.00 16 T endosulfan I 50.000 54.496 -9.0 127 0.00 17 T alpha-chlordane 50.000 54.465 -8.9 122 0.00 18 T trans-nonachlor 50.000 53.793 -7.6 120 0.00 19 T 4,4'-DDE 50.000 59.613 -19.2# 139 0.00 20 T dieldrin 50.000 56.929 -13.9 126 0.00 21 T 2,4'-DDD 50.000 55.749 -11.5 132 0.00 22 T endrin 50.000 55.042 -10.1 129 0.00 23 T endosulfan II 50.000 57.053 -14.1 134 0.00 24 T 4,4'-DDD 50.000 60.244 -20.5# 147 0.00 25 T 2,4'-DDT 50.000 56.977 -14.0 133 0.00 26 T cis-nonachlor 50.000 56.230 -12.5 132 0.00 27 T endrin aldehyde 50.000 53.680 -7.4 134 0.00 28 T endosulfan sulfate 50.000 52.960 -5.9 145 0.00 29 T 4,4'-DDT 50.000 55.896 -11.8 136 0.00 30 T endrin ketone 50.000 56.248 -12.5 144 0.00 31 T methoxychlor 50.000 52.366 -4.7 134 0.00 32 T mirex 50.000 51.415 -2.8 131 0.00 34 S DCB - Surrogate 50.000 55.253 -10.5 143 0.00


of 329






Compound Amount Calc. %Dev Area% Dev(Min)-------------------------------------------------------------------------

38 I BZ 192 #2 50.000 50.000 0.0 132 0.00 39 S TMX - Surrogate #2 50.000 53.269 -6.5 122 0.00 41 T alpha-BHC #2 50.000 55.352 -10.7 126 0.00 42 T hexachlorobenzene #2 50.000 51.656 -3.3 122 0.00 43 T beta-BHC #2 50.000 53.221 -6.4 130 0.00 44 T gamma-BHC #2 50.000 55.029 -10.1 128 0.00 45 T delta-BHC #2 50.000 56.715 -13.4 141 0.00 46 T heptachlor #2 50.000 52.361 -4.7 122 0.00 47 T aldrin #2 50.000 52.590 -5.2 125 0.00 49 T heptachlor epoxide (B) #2 50.000 52.195 -4.4 127 -0.01 50 T oxychlordane #2 50.000 51.398 -2.8 125 -0.01 51 T gamma-chlordane #2 50.000 52.952 -5.9 139 -0.01 52 T 2,4'-DDE #2 50.000 51.081 -2.2 129 -0.01 53 T endosulfan I #2 50.000 51.969 -3.9 127 -0.01 54 T alpha-chlordane #2 50.000 52.540 -5.1 131 -0.01 55 T trans-nonachlor #2 50.000 52.547 -5.1 132 0.00 56 T 4,4'-DDE #2 50.000 56.349 -12.7 148 -0.01 57 T dieldrin #2 50.000 53.613 -7.2 132 -0.01 58 T 2,4'-DDD #2 50.000 54.214 -8.4 142 0.00 59 T endrin #2 50.000 53.615 -7.2 137 0.00 60 T endosulfan II #2 50.000 56.075 -12.2 139 0.00 61 T 4,4'-DDD #2 50.000 58.338 -16.7# 155 0.00 62 T 2,4'-DDT #2 50.000 54.175 -8.3 150 0.00 63 T cis-nonachlor #2 50.000 54.911 -9.8 147 0.00 64 T endrin aldehyde #2 50.000 53.074 -6.1 144 0.00 65 T endosulfan sulfate #2 50.000 57.488 -15.0 153 0.00 66 T 4,4'-DDT #2 50.000 55.999 -12.0 147 0.00 67 T endrin ketone #2 50.000 56.642 -13.3 156 0.00 68 T methoxychlor #2 50.000 54.906 -9.8 149 0.00 69 T mirex #2 50.000 51.780 -3.6 140 0.00


of 329






Compound Amount Calc. %Dev Area% Dev(Min)-------------------------------------------------------------------------71 S DCB - Surrogate #2 50.000 55.163 -10.3 154 -0.01


35 T Toxaphene -1.000 0.000 0.0 0 -0.11 72 T Toxaphene #2 -1.000 0.000 0.0 0 -0.11 --------------------------------------------------------------------------



of 329





Sub List : ANCHOR-NTC_8081 - Short list ANCHOR


1) I BZ 192 29.13 29.31 732.3E6 234.2E6 50.000M4 50.000M4






6) T beta-BHC 9.36 11.07 318.8E6 129.6E6 54.045 53.221M4

7) T gamma-BHC 9.65 10.72 734.9E6 273.2E6 56.172M4 55.029M4

8) T delta-BHC 10.46 12.53 728.4E6 266.7E6 60.441M4 56.715M4


10) T aldrin 14.67 14.75 1026.7E6 235.7E6 109.366M4 (C) 52.590M4 D





of 329







15) T 2,4'-DDE 19.16 20.14 404.7E6 138.4E6 55.351M4 51.081M4




19) T 4,4'-DDE 21.27 22.19 616.6E6 194.5E6 59.613M4 56.349M4

20) T dieldrin 21.48 22.89 670.2E6 213.1E6 56.929M4 53.613M4

21) T 2,4'-DDD 21.84 23.34 380.5E6 124.3E6 55.749M4 54.214M4

22) T endrin 22.84 24.58 592.6E6 186.1E6 55.042M4 53.615M4

23) T endosulfan II 23.39 25.76 576.7E6 196.2E6 57.053 56.075M4

24) T 4,4'-DDD 23.86 25.48 512.4E6 161.5E6 60.244 58.338M4

25) T 2,4'-DDT 24.07 25.03 424.0E6 144.1E6 56.977M4 54.175M4




29) T 4,4'-DDT 25.97 27.09 537.9E6 159.7E6 55.896M4 55.999M4




of 329







32) T mirex 30.54 30.60 469.9E6 152.5E6 51.415M4 51.780M4

35) T Toxaphene 0.00 0.00 0 0 N.D. N.D.




of 329


Data Path : O:\Organics\DATA\ECD2-6890N\2012\OCT\OCT30\Data File : F210301238.DOperator : ECD2:RRAcquired : 31 Oct 2012 12:42 pm using AcqMethod PESTECD2.MInstrument: HP G1530ASample : WG570776-1 Misc Info : WG570776,PW071212A ??EO?ALS Vial : 25

2.00 4.00 6.00 8.00 10.00 12.00 14.00 16.00 18.00 20.00 22.00 24.00 26.00 28.00 30.00 32.00 34.00 36.00 38.00

0

5000000

1e+07

1.5e+07

2e+07

2.5e+07

Time


2.00 4.00 6.00 8.00 10.00 12.00 14.00 16.00 18.00 20.00 22.00 24.00 26.00 28.00 30.00 32.00 34.00 36.00 38.00

0

1000000

2000000

3000000

4000000

5000000

6000000

7000000

8000000

9000000

Time



of 329






Compound Amount Calc. %Dev Area% Dev(Min)-------------------------------------------------------------------------1 I BZ 192 50.000 50.000 0.0 116 0.00 2 S TMX - Surrogate 50.000 56.465 -12.9 115 0.00 4 T alpha-BHC 50.000 61.195 -22.4# 121 0.00 5 T hexachlorobenzene 50.000 54.526 -9.1 113 0.00 6 T beta-BHC 50.000 56.486 -13.0 128 0.00 7 T gamma-BHC 50.000 58.568 -17.1# 119 0.00 8 T delta-BHC 50.000 62.861 -25.7# 131 0.00 9 T heptachlor 50.000 56.368 -12.7 117 0.00 10 T aldrin 100.000 113.550 -13.5 120 0.00 12 T heptachlor epoxide (B) 100.000 112.963 -13.0 121 -0.01 13 T oxychlordane 100.000 112.982 -13.0 121 -0.01 14 T gamma-chlordane 50.000 57.828 -15.7# 125 0.00 15 T 2,4'-DDE 50.000 57.300 -14.6 122 0.00 16 T endosulfan I 50.000 54.447 -8.9 122 0.00 17 T alpha-chlordane 50.000 55.434 -10.9 119 0.00 18 T trans-nonachlor 50.000 54.891 -9.8 117 0.00 19 T 4,4'-DDE 50.000 61.078 -22.2# 137 0.00 20 T dieldrin 50.000 57.963 -15.9# 122 0.00 21 T 2,4'-DDD 50.000 57.432 -14.9 130 0.00 22 T endrin 50.000 56.509 -13.0 126 0.00 23 T endosulfan II 50.000 58.013 -16.0# 131 0.00 24 T 4,4'-DDD 50.000 62.484 -25.0# 146 0.00 25 T 2,4'-DDT 50.000 58.754 -17.5# 132 0.00 26 T cis-nonachlor 50.000 57.054 -14.1 128 0.00 27 T endrin aldehyde 50.000 54.768 -9.5 131 0.00 28 T endosulfan sulfate 50.000 54.058 -8.1 142 0.00 29 T 4,4'-DDT 50.000 52.421 -4.8 122 0.00 30 T endrin ketone 50.000 56.147 -12.3 137 0.00 31 T methoxychlor 50.000 48.097 3.8 118 0.00 32 T mirex 50.000 50.035 -0.1 122 0.00 34 S DCB - Surrogate 50.000 54.822 -9.6 136 0.00


of 329






Compound Amount Calc. %Dev Area% Dev(Min)-------------------------------------------------------------------------

38 I BZ 192 #2 50.000 50.000 0.0 135 0.00 39 S TMX - Surrogate #2 50.000 53.450 -6.9 125 0.00 41 T alpha-BHC #2 50.000 55.345 -10.7 129 0.00 42 T hexachlorobenzene #2 50.000 51.800 -3.6 125 0.00 43 T beta-BHC #2 50.000 53.269 -6.5 133 0.00 44 T gamma-BHC #2 50.000 55.181 -10.4 131 0.00 45 T delta-BHC #2 50.000 56.819 -13.6 144 0.00 46 T heptachlor #2 50.000 51.599 -3.2 123 0.00 47 T aldrin #2 50.000 52.537 -5.1 127 0.00 49 T heptachlor epoxide (B) #2 50.000 51.886 -3.8 129 -0.01 50 T oxychlordane #2 50.000 51.136 -2.3 127 -0.01 51 T gamma-chlordane #2 50.000 52.436 -4.9 140 -0.01 52 T 2,4'-DDE #2 50.000 50.986 -2.0 132 -0.01 53 T endosulfan I #2 50.000 51.312 -2.6 128 -0.01 54 T alpha-chlordane #2 50.000 52.271 -4.5 134 -0.01 55 T trans-nonachlor #2 50.000 52.380 -4.8 134 -0.01 56 T 4,4'-DDE #2 50.000 55.724 -11.4 150 -0.01 57 T dieldrin #2 50.000 52.446 -4.9 132 -0.01 58 T 2,4'-DDD #2 50.000 54.288 -8.6 145 -0.01 59 T endrin #2 50.000 53.546 -7.1 140 -0.01 60 T endosulfan II #2 50.000 56.339 -12.7 143 -0.01 61 T 4,4'-DDD #2 50.000 59.969 -19.9# 163 -0.01 62 T 2,4'-DDT #2 50.000 52.282 -4.6 148 -0.01 63 T cis-nonachlor #2 50.000 54.477 -9.0 149 -0.01 64 T endrin aldehyde #2 50.000 52.668 -5.3 146 -0.01 65 T endosulfan sulfate #2 50.000 63.095 -26.2# 172 0.00 66 T 4,4'-DDT #2 50.000 52.508 -5.0 141 -0.01 67 T endrin ketone #2 50.000 56.841 -13.7 160 -0.01 68 T methoxychlor #2 50.000 50.218 -0.4 139 0.00 69 T mirex #2 50.000 51.390 -2.8 142 -0.01


of 329






Compound Amount Calc. %Dev Area% Dev(Min)-------------------------------------------------------------------------71 S DCB - Surrogate #2 50.000 54.316 -8.6 155 -0.01


35 T Toxaphene -1.000 0.000 0.0 0 -0.11 72 T Toxaphene #2 -1.000 0.000 0.0 0 -0.11 --------------------------------------------------------------------------



of 329







1) I BZ 192 29.12 29.31 700.4E6 239.3E6 50.000M4 50.000M4




Target Compounds4) T alpha-BHC 8.57 9.27 790.8E6 300.8E6 61.195M4 55.345


6) T beta-BHC 9.36 11.07 318.7E6 132.5E6 56.486M4 53.269M4

7) T gamma-BHC 9.65 10.72 732.9E6 279.8E6 58.568M4 55.181M4

8) T delta-BHC 10.47 12.54 724.6E6 272.9E6 62.861M4 56.819M4


10) T aldrin 14.67 14.75 1019.6E6 240.6E6 113.550M4 (C) 52.537M4 D





of 329







15) T 2,4'-DDE 19.16 20.14 400.7E6 141.2E6 57.300M4 50.986M4




19) T 4,4'-DDE 21.27 22.19 604.3E6 196.5E6 61.078M4 55.724M4

20) T dieldrin 21.48 22.89 652.6E6 212.9E6 57.963M4 52.446M4

21) T 2,4'-DDD 21.83 23.34 374.9E6 127.2E6 57.432M4 54.288M4

22) T endrin 22.84 24.58 582.0E6 189.9E6 56.509M4 53.546M4


24) T 4,4'-DDD 23.85 25.48 508.3E6 169.6E6 62.484M4 59.969M4

25) T 2,4'-DDT 24.07 25.03 418.2E6 142.1E6 58.754M4 52.282M4




29) T 4,4'-DDT 25.96 27.09 482.5E6 153.1E6 52.421M4 52.508M4




of 329







32) T mirex 30.53 30.59 437.3E6 154.6E6 50.035M4 51.390M4

35) T Toxaphene 0.00 0.00 0 0 N.D. N.D.




of 329


Data Path : O:\Organics\DATA\ECD2-6890N\2012\OCT\OCT30\Data File : F210301255.DOperator : ECD2:RRAcquired : 31 Oct 2012 11:41 pm using AcqMethod PESTECD2.MInstrument: HP G1530ASample : WG570776-2 Misc Info : WG570776,PW071212A ??EO?ALS Vial : 25

2.00 4.00 6.00 8.00 10.00 12.00 14.00 16.00 18.00 20.00 22.00 24.00 26.00 28.00 30.00 32.00 34.00 36.00 38.00

0

5000000

1e+07

1.5e+07

2e+07

2.5e+07

Time


2.00 4.00 6.00 8.00 10.00 12.00 14.00 16.00 18.00 20.00 22.00 24.00 26.00 28.00 30.00 32.00 34.00 36.00 38.00

0

2000000

4000000

6000000

8000000

Time



of 329

Sample Raw Data

of 329


Data Path : O:\Organics\DATA\ECD2-6890N\2012\OCT\OCT30\Data File : F210301253.D Signal(s) : Signal #1: ECD1A.CH Signal #2: ECD2B.CHAcq On : 31 Oct 2012 10:13 pmOperator : ECD2:RRSample : L1219133-01D,42,5 (Sig #1); L1219133-01,42,5 (Sig #2)Misc : WG570776,WG569308ALS Vial : 29 Sample Multiplier: 1





1) I BZ 192 29.14 29.32 647.8E6 208.8E6 50.000M4 50.000M4




Target Compounds4) T alpha-BHC 0.00 0.00 0 0 N.D. d N.D. d 5) T hexachlorobenz 8.88 8.78 39412906 32637960 3.865M4 7.792M4 D6) T beta-BHC 9.30f 11.09 357.1E6 4076917 68.448M4 1.878M4 (I)D7) T gamma-BHC 0.00 0.00 0 0 N.D. d N.D. d 8) T delta-BHC 0.00 0.00 0 0 N.D. d N.D. d 9) T heptachlor 12.74 12.90 75200812 9084498 6.400M4 2.146M4 D

10) T aldrin 0.00 0.00 0 0 N.D. d(C) N.D. d 12) T heptachlor epo 0.00 0.00 0 0 N.D. (C) N.D. 13) T oxychlordane 0.00 0.00 0 0 N.D. (C) N.D. d 14) T gamma-chlordan 18.91 19.97 226.2E6 62567164 21.354M4 17.301M4

15) T 2,4'-DDE 19.16 20.10 59182038 80581531 9.150M4 (I) 33.359M4 D

16) T endosulfan I 0.00 0.00 0 0 N.D. d N.D. 17) T alpha-chlordan 19.94 20.94 146.6E6 48157401 13.520M4 13.260M4



of 329

DQuantitation Report (QT Reviewed)

Data Path : O:\Organics\DATA\ECD2-6890N\2012\OCT\OCT30\Data File : F210301253.D Signal(s) : Signal #1: ECD1A.CH Signal #2: ECD2B.CHAcq On : 31 Oct 2012 10:13 pmOperator : ECD2:RRSample : L1219133-01D,42,5 (Sig #1); L1219133-01,42,5 (Sig #2)Misc : WG570776,WG569308ALS Vial : 29 Sample Multiplier: 1





19) T 4,4'-DDE 21.28 22.18 428.5E6 372.3E6 46.836M4 (I) 121.031M4 D

20) T dieldrin 21.48 22.93 90828364 105.6E6 8.723M4 (I) 29.798M4 D

21) T 2,4'-DDD 21.83 23.35 395.4E6 49580032 65.495M4 24.257M4 D

22) T endrin 0.00 0.00 0 0 N.D. d N.D. d 23) T endosulfan II 23.39 25.80 159.1E6 12510597 17.790M4 4.011M4 D

24) T 4,4'-DDD 23.86 25.49 486.5E6 168.1E6 64.661M4 68.129M4

25) T 2,4'-DDT 0.00 0.00 0 0 N.D. d N.D. d 26) T cis-nonachlor 24.15 25.16 30675503 11824383 2.492M4 (I) 3.341M4

27) T endrin aldehyd 24.50 27.54 11295562 53274051 1.341M4 (I) 19.860M4 D

28) T endosulfan sul 0.00 0.00 0 0 N.D. d N.D. d 29) T 4,4'-DDT 25.97 27.09 691.1E6 288.8E6 81.231M4 (I) 114.105M4 D

30) T endrin ketone 0.00 0.00 0 0 N.D. d N.D. d 31) T methoxychlor 28.84 30.09 692.2E6 156.8E6 153.022M4 109.258M4 D

32) T mirex 30.58 30.60 69341719 87456316 8.578M4 33.307M4 D

35) T Toxaphene 0.00 0.00 0 0 N.D. N.D.




of 329


Data Path : O:\Organics\DATA\ECD2-6890N\2012\OCT\OCT30\Data File : F210301253.DOperator : ECD2:RRAcquired : 31 Oct 2012 10:13 pm using AcqMethod PESTECD2.MInstrument: HP G1530ASample : L1219133-01D,42,5 Misc Info : WG570776,WG569308 ??EO?ALS Vial : 29

2.00 4.00 6.00 8.00 10.00 12.00 14.00 16.00 18.00 20.00 22.00 24.00 26.00 28.00 30.00 32.00 34.00 36.00 38.00

0

1e+07

2e+07

3e+07

4e+07

Time


2.00 4.00 6.00 8.00 10.00 12.00 14.00 16.00 18.00 20.00 22.00 24.00 26.00 28.00 30.00 32.00 34.00 36.00 38.00

0

5000000

1e+07

1.5e+07

2e+07

2.5e+07

Time



of 329

#2 TMX - Surrogate


Conc: 13.86 ug/L M4

7.10 7.20 7.30 7.40 7.50 7.60 7.70 7.80 7.90

0

1000000

2000000

3000000

4000000

Time


7.489

+

#2 TMX - Surrogate


Conc: 15.37 ug/L m

6.40 6.60 6.80 7.00 7.20 7.40 7.60 7.80 8.00 8.20

0

500000

1000000

1500000

2000000

Time


7.307

+


of 329



Conc: 3.87 ug/L M4

8.40 8.50 8.60 8.70 8.80 8.90 9.00 9.10 9.20 9.30

0

2000000

4000000

6000000

8000000

1e+07

Time


8.884



Conc: 7.79 ug/L m

8.20 8.30 8.40 8.50 8.60 8.70 8.80 8.90 9.00 9.10 9.20 9.30 9.40

0

500000

1000000

1500000

2000000

Time


8.781

+


of 329

#6 beta-BHC


Conc: 68.45 ug/L M4

8.60 8.80 9.00 9.20 9.40 9.60 9.80 10.00

0

2000000

4000000

6000000

8000000

1e+07

Time


9.297

+

#6 beta-BHC


Conc: 1.88 ug/L m

10.70 10.80 10.90 11.00 11.10 11.20 11.30 11.40

0

500000

1000000

1500000

2000000

2500000

Time


11.094


of 329

#9 heptachlor


Conc: 6.40 ug/L M4

12.40 12.50 12.60 12.70 12.80 12.90 13.00

0

1000000

2000000

3000000

4000000

5000000

Time


12.738

+

#9 heptachlor


Conc: 2.15 ug/L m

12.40 12.50 12.60 12.70 12.80 12.90 13.00 13.10 13.20 13.30

0

1000000

2000000

3000000

Time


12.898


of 329

#14 gamma-chlordane


Conc: 21.35 ug/L M4

18.40 18.50 18.60 18.70 18.80 18.90 19.00 19.10 19.20 19.30

0

2000000

4000000

6000000

8000000

1e+07

Time


18.910

+

#14 gamma-chlordane


Conc: 17.30 ug/L m

19.60 19.70 19.80 19.90 20.00 20.10 20.20 20.30

0

2000000

4000000

6000000

8000000

Time


19.971

+


of 329

#15 2,4'-DDE


Conc: 9.15 ug/L M4

18.90 19.00 19.10 19.20 19.30 19.40

0

2000000

4000000

6000000

8000000

1e+07

Time


19.163

+

#15 2,4'-DDE


Conc: 33.36 ug/L m

19.80 19.90 20.00 20.10 20.20 20.30 20.40

0

2000000

4000000

6000000

8000000

Time


20.104


of 329

#17 alpha-chlordane


Conc: 13.52 ug/L M4

19.40 19.60 19.80 20.00 20.20 20.40 20.60

0

1000000

2000000

3000000

4000000

5000000

6000000

Time


19.941

+

#17 alpha-chlordane


Conc: 13.26 ug/L m

20.40 20.50 20.60 20.70 20.80 20.90 21.00 21.10 21.20 21.30 21.40

0

1000000

2000000

3000000

Time


20.940

+


of 329

#18 trans-nonachlor


Conc: 6.40 ug/L M4

20.00 20.10 20.20 20.30 20.40 20.50 20.60

0

1000000

2000000

3000000

4000000

5000000

Time


20.247

+

#18 trans-nonachlor


Conc: 13.89 ug/L m

20.30 20.40 20.50 20.60 20.70 20.80 20.90

0

1000000

2000000

3000000

4000000

Time


20.613

+


of 329

#19 4,4'-DDE


Conc: 46.84 ug/L M4

20.80 20.90 21.00 21.10 21.20 21.30 21.40 21.50 21.60 21.70

0

5000000

1e+07

Time


21.278

+

#19 4,4'-DDE


Conc: 121.03 ug/L m

21.40 21.60 21.80 22.00 22.20 22.40 22.60 22.80 23.00

0

2000000

4000000

6000000

Time


22.182

+


of 329

#20 dieldrin


Conc: 8.72 ug/L M4

20.90 21.00 21.10 21.20 21.30 21.40 21.50 21.60 21.70 21.80 21.90 22.00

0

5000000

1e+07

Time


21.475

+

#20 dieldrin


Conc: 29.80 ug/L m

22.40 22.60 22.80 23.00 23.20 23.40

0

1000000

2000000

3000000

4000000

Time


22.928

+


of 329

#21 2,4'-DDD


Conc: 65.49 ug/L M4

21.30 21.40 21.50 21.60 21.70 21.80 21.90 22.00 22.10 22.20 22.30

0

5000000

1e+07

Time


21.830

+

#21 2,4'-DDD


Conc: 24.26 ug/L m

22.90 23.00 23.10 23.20 23.30 23.40 23.50 23.60 23.70

0

1000000

2000000

3000000

4000000

Time


23.351

+


of 329

#23 endosulfan II


Conc: 17.79 ug/L M4

22.90 23.00 23.10 23.20 23.30 23.40 23.50 23.60 23.70 23.80 23.90

0

5000000

1e+07

1.5e+07

Time


23.394

+

#23 endosulfan II


Conc: 4.01 ug/L m

25.55 25.60 25.65 25.70 25.75 25.80 25.85 25.90 25.95

0

500000

1000000

1500000

2000000

2500000

Time


+


of 329

#24 4,4'-DDD


Conc: 64.66 ug/L M4

23.20 23.40 23.60 23.80 24.00 24.20 24.40 24.60

0

5000000

1e+07

1.5e+07

Time


23.861

+

#24 4,4'-DDD


Conc: 68.13 ug/L m

25.00 25.10 25.20 25.30 25.40 25.50 25.60 25.70 25.80 25.90 26.00

0

1000000

2000000

3000000

4000000

5000000

6000000

Time


25.489

+


of 329

#26 cis-nonachlor


Conc: 2.49 ug/L M4

23.85 23.90 23.95 24.00 24.05 24.10 24.15 24.20 24.25 24.30 24.35 24.40

0

5000000

1e+07

1.5e+07

Time


24.147

#26 cis-nonachlor


Conc: 3.34 ug/L m

24.85 24.90 24.95 25.00 25.05 25.10 25.15 25.20 25.25 25.30 25.35

0

1000000

2000000

3000000

Time


+


of 329

#27 endrin aldehyde


Conc: 1.34 ug/L M4

24.20 24.30 24.40 24.50 24.60 24.70 24.80

0

2000000

4000000

6000000

Time


24.501

#27 endrin aldehyde


Conc: 19.86 ug/L m

27.10 27.20 27.30 27.40 27.50 27.60 27.70 27.80 27.90 28.00

0

2000000

4000000

6000000

8000000

1e+07

Time


27.541

+


of 329

#29 4,4'-DDT


Conc: 81.23 ug/L M4

25.50 25.60 25.70 25.80 25.90 26.00 26.10 26.20 26.30 26.40

0

1e+07

2e+07

3e+07

4e+07

Time


25.972

+

#29 4,4'-DDT


Conc: 114.11 ug/L m

26.70 26.80 26.90 27.00 27.10 27.20 27.30 27.40 27.50

0

2000000

4000000

6000000

8000000

1e+07

Time


27.095

+


of 329

#31 methoxychlor



28.50 28.60 28.70 28.80 28.90 29.00 29.10 29.20

0

5000000

1e+07

1.5e+07

2e+07

2.5e+07

Time


28.845

+

#31 methoxychlor


Conc: 109.26 ug/L m

29.60 29.70 29.80 29.90 30.00 30.10 30.20 30.30 30.40 30.50 30.60

0

2000000

4000000

6000000

Time


30.090

+


of 329

#32 mirex


Conc: 8.58 ug/L M4

30.35 30.40 30.45 30.50 30.55 30.60 30.65 30.70 30.75

0

2000000

4000000

6000000

Time


30.575

+

#32 mirex


Conc: 33.31 ug/L m

30.20 30.30 30.40 30.50 30.60 30.70 30.80 30.90

0

1000000

2000000

3000000

4000000

5000000

Time


30.598

+


of 329

#34 DCB - Surrogate


Conc: 15.56 ug/L M4

36.70 36.80 36.90 37.00 37.10 37.20 37.30 37.40 37.50 37.60 37.70

0

2000000

4000000

6000000

Time


37.232

+

#34 DCB - Surrogate


Conc: 18.18 ug/L m

37.00 37.10 37.20 37.30 37.40 37.50 37.60 37.70 37.80 37.90 38.00

0

1000000

2000000

3000000

4000000

5000000

Time


37.536

+


of 329

Batch Quality Control

of 329

Method Blank Raw Data

of 329


Data Path : O:\Organics\DATA\ECD2-6890N\2012\OCT\OCT30\Data File : F210301240.D Signal(s) : Signal #1: ECD1A.CH Signal #2: ECD2B.CHAcq On : 31 Oct 2012 2:10 pmOperator : ECD2:RRSample : WG569308-1,42Misc : WG570776,WG569308ALS Vial : 26 Sample Multiplier: 1





1) I BZ 192 29.12 29.31 790.6E6 249.7E6 50.000M4 50.000M4




Target Compounds4) T alpha-BHC 0.00 0.00 0 0 N.D. N.D. 5) T hexachlorobenz 0.00 0.00 0 0 N.D. d N.D. d 6) T beta-BHC 0.00 0.00 0 0 N.D. d N.D. 7) T gamma-BHC 0.00 0.00 0 0 N.D. N.D. 8) T delta-BHC 0.00 0.00 0 0 N.D. N.D. 9) T heptachlor 0.00 0.00 0 0 N.D. N.D. 10) T aldrin 0.00 0.00 0 0 N.D. d(C) N.D. 12) T heptachlor epo 0.00 0.00 0 0 N.D. d(C) N.D. 13) T oxychlordane 0.00 0.00 0 0 N.D. d(C) N.D. d 14) T gamma-chlordan 0.00 0.00 0 0 N.D. N.D. 15) T 2,4'-DDE 0.00 0.00 0 0 N.D. d N.D. d 16) T endosulfan I 0.00 0.00 0 0 N.D. N.D. 17) T alpha-chlordan 0.00 0.00 0 0 N.D. d N.D. 18) T trans-nonachlo 0.00 0.00 0 0 N.D. d N.D. 19) T 4,4'-DDE 0.00 0.00 0 0 N.D. d N.D. 20) T dieldrin 0.00 0.00 0 0 N.D. N.D. 21) T 2,4'-DDD 0.00 0.00 0 0 N.D. d N.D. 22) T endrin 22.81 24.59 6703959 422226 0.969M4 0.530M4 D

23) T endosulfan II 0.00 0.00 0 0 N.D. d N.D.


of 329







24) T 4,4'-DDD 0.00 0.00 0 0 N.D. N.D. 25) T 2,4'-DDT 0.00 0.00 0 0 N.D. N.D. 26) T cis-nonachlor 0.00 0.00 0 0 N.D. N.D. 27) T endrin aldehyd 0.00 0.00 0 0 N.D. N.D. 28) T endosulfan sul 0.00 0.00 0 0 N.D. d N.D. 29) T 4,4'-DDT 0.00 0.00 0 0 N.D. N.D. d 30) T endrin ketone 0.00 0.00 0 0 N.D. N.D. 31) T methoxychlor 0.00 0.00 0 0 N.D. d N.D. 32) T mirex 0.00 0.00 0 0 N.D. N.D. 35) T Toxaphene 0.00 0.00 0 0 N.D. N.D.




of 329


Data Path : O:\Organics\DATA\ECD2-6890N\2012\OCT\OCT30\Data File : F210301240.DOperator : ECD2:RRAcquired : 31 Oct 2012 2:10 pm using AcqMethod PESTECD2.MInstrument: HP G1530ASample : WG569308-1,42 Misc Info : WG570776,WG569308 ??EO?ALS Vial : 26

2.00 4.00 6.00 8.00 10.00 12.00 14.00 16.00 18.00 20.00 22.00 24.00 26.00 28.00 30.00 32.00 34.00 36.00 38.00

0

5000000

1e+07

1.5e+07

2e+07

2.5e+07

3e+07

3.5e+07

Time


2.00 4.00 6.00 8.00 10.00 12.00 14.00 16.00 18.00 20.00 22.00 24.00 26.00 28.00 30.00 32.00 34.00 36.00 38.00

0

2000000

4000000

6000000

8000000

1e+07

1.2e+07

1.4e+07

Time



of 329

#2 TMX - Surrogate



6.60 6.80 7.00 7.20 7.40 7.60 7.80 8.00 8.20 8.40 8.60

0

1e+07

2e+07

3e+07

Time


7.470

#2 TMX - Surrogate


Conc: 108.18 ug/L m

6.20 6.40 6.60 6.80 7.00 7.20 7.40 7.60 7.80 8.00 8.20 8.40

0

5000000

1e+07

Time


7.288

+


of 329

#22 endrin


Conc: 0.97 ug/L M4

22.20 22.40 22.60 22.80 23.00 23.20 23.40

0

500000

1000000

1500000

2000000

Time


22.809

#22 endrin


Conc: 0.53 ug/L m

24.20 24.30 24.40 24.50 24.60 24.70 24.80 24.90

0

500000

1000000

Time


24.595


of 329

#34 DCB - Surrogate



35.50 36.00 36.50 37.00 37.50 38.00 38.50 39.00

0

5000000

1e+07

1.5e+07

2e+07

2.5e+07

Time


37.218

+

#34 DCB - Surrogate


Conc: 104.92 ug/L m

36.50 37.00 37.50 38.00 38.50 39.00

0

2000000

4000000

6000000

8000000

Time


37.523

+


of 329

LCS Raw Data

of 329







1) I BZ 192 29.12 29.31 707.9E6 227.6E6 50.000M4 50.000M4






6) T beta-BHC 9.35 11.07 554.8E6 213.0E6 97.307M4 89.972M4

7) T gamma-BHC 9.64 10.72 1398.9E6 539.1E6 110.618M4 111.728M4

8) T delta-BHC 10.46 12.53 1250.9E6 476.2E6 107.379M4 104.193M4


10) T aldrin 14.65 14.74 1326.6E6 437.1E6 146.191M4 (C) 100.323M4 D





of 329







15) T 2,4'-DDE 19.15 20.14 744.8E6 263.1E6 105.382M4 99.892M4




19) T 4,4'-DDE 21.26 22.19 1166.7E6 374.0E6 116.684M4 111.477M4

20) T dieldrin 21.47 22.88 1260.0E6 403.0E6 110.734M4 104.328M4

21) T 2,4'-DDD 21.83 23.34 682.6E6 224.2E6 103.469M4 100.574M4

22) T endrin 22.84 24.58 1106.4E6 350.6E6 105.942M4 103.532M4


24) T 4,4'-DDD 23.85 25.48 970.9E6 307.5E6 118.080M4 114.255M4

25) T 2,4'-DDT 24.06 25.02 827.4E6 259.6E6 115.022M4 100.369M4

26) T cis-nonachlor 0.00 0.00 0 0 N.D. d N.D. d 27) T endrin aldehyd 24.48 27.53 823.9E6 275.3E6 89.502M4 94.105M4


29) T 4,4'-DDT 25.96 27.09 1037.2E6 317.6E6 111.601M4 115.080M4




of 329







32) T mirex 30.53 30.59 828.4E6 264.2E6 93.772M4 92.261M4

35) T Toxaphene 0.00 0.00 0 0 N.D. N.D.




of 329



2.00 4.00 6.00 8.00 10.00 12.00 14.00 16.00 18.00 20.00 22.00 24.00 26.00 28.00 30.00 32.00 34.00 36.00 38.00

0

1e+07

2e+07

3e+07

4e+07

Time


2.00 4.00 6.00 8.00 10.00 12.00 14.00 16.00 18.00 20.00 22.00 24.00 26.00 28.00 30.00 32.00 34.00 36.00 38.00

0

5000000

1e+07

1.5e+07

Time



of 329

#2 TMX - Surrogate



6.80 7.00 7.20 7.40 7.60 7.80 8.00 8.20 8.40

0

5000000

1e+07

1.5e+07

2e+07

2.5e+07

3e+07

Time


7.469

#2 TMX - Surrogate


Conc: 99.91 ug/L m

6.20 6.40 6.60 6.80 7.00 7.20 7.40 7.60 7.80 8.00 8.20 8.40

0

2000000

4000000

6000000

8000000

1e+07

1.2e+07

Time


7.286


of 329

#4 alpha-BHC



7.80 8.00 8.20 8.40 8.60 8.80 9.00 9.20 9.40

0

1e+07

2e+07

3e+07

4e+07

Time


8.563

+

#4 alpha-BHC


Conc: 109.01 ug/L m

8.40 8.60 8.80 9.00 9.20 9.40 9.60 9.80 10.00 10.20

0

5000000

1e+07

1.5e+07

Time


9.256

+


of 329



Conc: 92.53 ug/L M4

8.00 8.50 9.00 9.50 10.00

0

1e+07

2e+07

3e+07

4e+07

Time


8.864

+



Conc: 99.36 ug/L m

8.00 8.50 9.00 9.50 10.00

0

5000000

1e+07

1.5e+07

Time


8.776

+


of 329

#6 beta-BHC


Conc: 97.31 ug/L M4

8.40 8.60 8.80 9.00 9.20 9.40 9.60 9.80 10.00 10.20

0

1e+07

2e+07

3e+07

4e+07

Time


9.348

+

#6 beta-BHC


Conc: 89.97 ug/L m

10.60 10.80 11.00 11.20 11.40 11.60

0

5000000

1e+07

1.5e+07

Time


11.066

+


of 329

#7 gamma-BHC



8.80 9.00 9.20 9.40 9.60 9.80 10.00 10.20 10.40 10.60

0

1e+07

2e+07

3e+07

4e+07

Time


9.644

+

#7 gamma-BHC


Conc: 111.73 ug/L m

9.80 10.00 10.20 10.40 10.60 10.80 11.00 11.20 11.40 11.60

0

5000000

1e+07

1.5e+07

Time


10.716

+


of 329

#8 delta-BHC



9.60 9.80 10.00 10.20 10.40 10.60 10.80 11.00 11.20 11.40

0

1e+07

2e+07

3e+07

4e+07

Time


10.456

+

#8 delta-BHC


Conc: 104.19 ug/L m

11.60 11.80 12.00 12.20 12.40 12.60 12.80 13.00 13.20 13.40 13.60

0

5000000

1e+07

1.5e+07

Time


12.529

+


of 329

#9 heptachlor



11.80 12.00 12.20 12.40 12.60 12.80 13.00 13.20 13.40 13.60 13.80

0

1e+07

2e+07

3e+07

4e+07

Time


12.715

+

#9 heptachlor


Conc: 100.45 ug/L m

12.20 12.40 12.60 12.80 13.00 13.20 13.40 13.60

0

5000000

1e+07

1.5e+07

Time


12.894

+


of 329

#10 aldrin



13.00 13.50 14.00 14.50 15.00 15.50 16.00

0

1e+07

2e+07

3e+07

Time


14.651

+

#10 aldrin


Conc: 100.32 ug/L m

14.00 14.50 15.00 15.50 16.00

0

2000000

4000000

6000000

8000000

1e+07

1.2e+07

Time


14.740

+


of 329




16.20 16.40 16.60 16.80 17.00 17.20 17.40 17.60 17.80 18.00 18.20 18.40

0

1e+07

2e+07

3e+07

4e+07

Time


17.212

+



Conc: 98.13 ug/L m

17.50 18.00 18.50 19.00 19.50 20.00

0

2000000

4000000

6000000

8000000

1e+07

Time


18.659

+


of 329

#13 oxychlordane



16.20 16.40 16.60 16.80 17.00 17.20 17.40 17.60 17.80 18.00 18.20 18.40

0

1e+07

2e+07

3e+07

4e+07

Time


17.212

+

#13 oxychlordane


Conc: 99.07 ug/L m

17.00 17.20 17.40 17.60 17.80 18.00 18.20 18.40 18.60 18.80 19.00

0

2000000

4000000

6000000

8000000

1e+07

Time


18.013

+


of 329

#14 gamma-chlordane



18.20 18.40 18.60 18.80 19.00 19.20 19.40 19.60

0

5000000

1e+07

1.5e+07

2e+07

2.5e+07

3e+07

Time


18.868

+

#14 gamma-chlordane


Conc: 101.87 ug/L m

19.40 19.60 19.80 20.00 20.20 20.40

0

2000000

4000000

6000000

8000000

1e+07

Time


19.960

+


of 329

#15 2,4'-DDE



18.00 18.50 19.00 19.50 20.00 20.50

0

5000000

1e+07

1.5e+07

2e+07

2.5e+07

3e+07

Time


19.150

+

#15 2,4'-DDE


Conc: 99.89 ug/L m

19.40 19.60 19.80 20.00 20.20 20.40 20.60 20.80 21.00

0

2000000

4000000

6000000

8000000

1e+07

Time


20.136

+


of 329

#16 endosulfan I



19.20 19.40 19.60 19.80 20.00 20.20

0

5000000

1e+07

1.5e+07

2e+07

2.5e+07

3e+07

Time


19.757

+

#16 endosulfan I


Conc: 99.68 ug/L m

20.00 20.50 21.00 21.50 22.00 22.50

0

2000000

4000000

6000000

8000000

1e+07

1.2e+07

Time


21.211

+


of 329

#17 alpha-chlordane



19.40 19.60 19.80 20.00 20.20 20.40 20.60

0

5000000

1e+07

1.5e+07

2e+07

2.5e+07

3e+07

Time


19.926

+

#17 alpha-chlordane


Conc: 100.74 ug/L m

20.20 20.40 20.60 20.80 21.00 21.20 21.40 21.60

0

2000000

4000000

6000000

8000000

1e+07

Time


20.925

+


of 329

#18 trans-nonachlor



19.00 19.50 20.00 20.50 21.00 21.50

0

1e+07

2e+07

3e+07

Time


20.235

+

#18 trans-nonachlor


Conc: 98.29 ug/L m

19.60 19.80 20.00 20.20 20.40 20.60 20.80 21.00 21.20 21.40 21.60

0

2000000

4000000

6000000

8000000

1e+07

Time


20.601

+


of 329

#19 4,4'-DDE



20.60 20.80 21.00 21.20 21.40 21.60 21.80

0

1e+07

2e+07

3e+07

Time


21.263

+

#19 4,4'-DDE


Conc: 111.48 ug/L m

21.20 21.40 21.60 21.80 22.00 22.20 22.40 22.60 22.80 23.00 23.20

0

2000000

4000000

6000000

8000000

1e+07

1.2e+07

Time


22.185

+


of 329

#20 dieldrin



20.60 20.80 21.00 21.20 21.40 21.60 21.80 22.00 22.20 22.40

0

1e+07

2e+07

3e+07

Time


21.474

+

#20 dieldrin


Conc: 104.33 ug/L m

21.80 22.00 22.20 22.40 22.60 22.80 23.00 23.20 23.40 23.60 23.80 24.00

0

2000000

4000000

6000000

8000000

1e+07

1.2e+07

Time


22.883

+


of 329

#21 2,4'-DDD



21.00 21.50 22.00 22.50 23.00

0

1e+07

2e+07

3e+07

Time


21.832

+

#21 2,4'-DDD


Conc: 100.57 ug/L m

22.60 22.80 23.00 23.20 23.40 23.60 23.80 24.00 24.20

0

2000000

4000000

6000000

8000000

1e+07

1.2e+07

Time


23.340

+


of 329

#22 endrin



22.00 22.20 22.40 22.60 22.80 23.00 23.20 23.40 23.60 23.80

0

5000000

1e+07

1.5e+07

2e+07

2.5e+07

3e+07

Time


22.838

+

#22 endrin


Conc: 103.53 ug/L m

23.80 24.00 24.20 24.40 24.60 24.80 25.00 25.20 25.40

0

2000000

4000000

6000000

8000000

1e+07

Time


24.577

+


of 329

#23 endosulfan II



22.50 23.00 23.50 24.00 24.50

0

5000000

1e+07

1.5e+07

2e+07

2.5e+07

3e+07

Time


23.375

+

#23 endosulfan II


Conc: 107.85 ug/L m

24.50 25.00 25.50 26.00 26.50 27.00

0

2000000

4000000

6000000

8000000

1e+07

1.2e+07

Time


25.752

+


of 329

#24 4,4'-DDD



23.40 23.60 23.80 24.00 24.20 24.40

0

5000000

1e+07

1.5e+07

2e+07

2.5e+07

3e+07

Time


23.849

+

#24 4,4'-DDD


Conc: 114.25 ug/L m

24.80 25.00 25.20 25.40 25.60 25.80 26.00 26.20

0

2000000

4000000

6000000

8000000

1e+07

1.2e+07

Time


25.478

+


of 329

#25 2,4'-DDT



23.40 23.60 23.80 24.00 24.20 24.40 24.60 24.80

0

5000000

1e+07

1.5e+07

2e+07

2.5e+07

3e+07

Time


24.062

+

#25 2,4'-DDT


Conc: 100.37 ug/L m

24.60 24.80 25.00 25.20 25.40 25.60

0

2000000

4000000

6000000

8000000

1e+07

Time


25.024

+


of 329

#27 endrin aldehyde


Conc: 89.50 ug/L M4

23.00 23.50 24.00 24.50 25.00 25.50 26.00

0

5000000

1e+07

1.5e+07

2e+07

2.5e+07

3e+07

Time


24.482

+

#27 endrin aldehyde


Conc: 94.11 ug/L m

26.50 27.00 27.50 28.00 28.50

0

2000000

4000000

6000000

8000000

1e+07

1.2e+07

Time


27.528

+


of 329



Conc: 98.48 ug/L M4

25.20 25.40 25.60 25.80 26.00 26.20 26.40

0

5000000

1e+07

1.5e+07

2e+07

2.5e+07

3e+07

Time


25.801

+



Conc: 104.20 ug/L m

27.50 28.00 28.50 29.00 29.50 30.00

0

2000000

4000000

6000000

8000000

1e+07

1.2e+07

Time


28.746

+


of 329

#29 4,4'-DDT



25.40 25.60 25.80 26.00 26.20 26.40

0

5000000

1e+07

1.5e+07

2e+07

2.5e+07

3e+07

Time


25.962

+

#29 4,4'-DDT


Conc: 115.08 ug/L m

26.00 26.50 27.00 27.50 28.00

0

2000000

4000000

6000000

8000000

1e+07

Time


27.089

+


of 329

#30 endrin ketone



27.80 28.00 28.20 28.40 28.60 28.80

0

1e+07

2e+07

3e+07

4e+07

Time


28.266

+

#30 endrin ketone


Conc: 114.66 ug/L m

30.00 30.20 30.40 30.60 30.80 31.00 31.20 31.40 31.60

0

5000000

1e+07

Time


30.816

+


of 329

#31 methoxychlor


Conc: 95.72 ug/L M4

28.40 28.50 28.60 28.70 28.80 28.90 29.00 29.10 29.20

0

5000000

1e+07

1.5e+07

2e+07

2.5e+07

Time


28.796

+

#31 methoxychlor


Conc: 97.34 ug/L m

29.60 29.70 29.80 29.90 30.00 30.10 30.20 30.30 30.40 30.50

0

2000000

4000000

6000000

8000000

Time


30.052

+


of 329

#32 mirex


Conc: 93.77 ug/L M4

29.80 30.00 30.20 30.40 30.60 30.80 31.00 31.20 31.40

0

5000000

1e+07

1.5e+07

2e+07

2.5e+07

Time


30.534

+

#32 mirex


Conc: 92.26 ug/L m

30.00 30.20 30.40 30.60 30.80 31.00 31.20

0

5000000

1e+07

Time


30.592

+


of 329

#34 DCB - Surrogate


Conc: 99.27 ug/L M4

35.50 36.00 36.50 37.00 37.50 38.00 38.50 39.00

0

5000000

1e+07

1.5e+07

2e+07

Time


37.218

+

#34 DCB - Surrogate


Conc: 95.43 ug/L m

36.50 37.00 37.50 38.00 38.50 39.00

0

2000000

4000000

6000000

Time


37.521

+


of 329

LCS Duplicate Raw Data

of 329







1) I BZ 192 29.12 29.30 888.2E6 274.2E6 50.000M4 50.000M4






6) T beta-BHC 9.35 11.06 723.5E6 277.4E6 101.134M4 97.285M4

7) T gamma-BHC 9.64 10.71 1795.4E6 694.3E6 113.150M4 119.444M4

8) T delta-BHC 10.45 12.53 1652.0E6 638.4E6 113.019M4 115.959M4


10) T aldrin 14.65 14.74 1685.7E6 557.9E6 148.052M4 (C) 106.316M4





of 329







15) T 2,4'-DDE 19.15 20.13 956.6E6 329.9E6 107.869M4 103.982M4




19) T 4,4'-DDE 21.26 22.18 1566.7E6 499.4E6 124.883M4 123.600M4

20) T dieldrin 21.47 22.88 1601.5E6 523.8E6 112.172M4 112.580M4

21) T 2,4'-DDD 21.83 23.34 881.2E6 293.8E6 106.465M4 109.443M4

22) T endrin 22.84 24.58 1328.7E6 425.4E6 101.416M4 104.293M4


24) T 4,4'-DDD 23.85 25.48 1309.4E6 414.9E6 126.925M4 127.983M4

25) T 2,4'-DDT 24.06 25.02 1073.7E6 340.1E6 118.968M4 109.188M4

26) T cis-nonachlor 0.00 0.00 0 0 N.D. d N.D. d 27) T endrin aldehyd 24.48 27.53 1026.2E6 342.1E6 88.849M4 97.090M4


29) T 4,4'-DDT 25.96 27.09 1394.7E6 429.5E6 119.603M4 129.266M4




of 329







32) T mirex 30.53 30.59 1072.7E6 338.0E6 96.777M4 97.993M4

35) T Toxaphene 0.00 0.00 0 0 N.D. N.D.




of 329



2.00 4.00 6.00 8.00 10.00 12.00 14.00 16.00 18.00 20.00 22.00 24.00 26.00 28.00 30.00 32.00 34.00 36.00 38.00

0

1e+07

2e+07

3e+07

4e+07

5e+07

6e+07

Time


2.00 4.00 6.00 8.00 10.00 12.00 14.00 16.00 18.00 20.00 22.00 24.00 26.00 28.00 30.00 32.00 34.00 36.00 38.00

0

5000000

1e+07

1.5e+07

2e+07

2.5e+07

Time



of 329

#2 TMX - Surrogate



6.80 7.00 7.20 7.40 7.60 7.80 8.00 8.20

0

1e+07

2e+07

3e+07

4e+07

Time


7.467

+

#2 TMX - Surrogate


Conc: 106.95 ug/L m

6.60 6.80 7.00 7.20 7.40 7.60 7.80 8.00

0

5000000

1e+07

1.5e+07

Time


7.283

+


of 329

#4 alpha-BHC



7.80 8.00 8.20 8.40 8.60 8.80 9.00 9.20 9.40

0

1e+07

2e+07

3e+07

4e+07

5e+07

6e+07

Time


8.561

+

#4 alpha-BHC


Conc: 118.85 ug/L m

8.40 8.60 8.80 9.00 9.20 9.40 9.60 9.80 10.00 10.20

0

5000000

1e+07

1.5e+07

2e+07

2.5e+07

Time


9.253

+


of 329



Conc: 93.84 ug/L M4

8.20 8.40 8.60 8.80 9.00 9.20 9.40 9.60

0

1e+07

2e+07

3e+07

4e+07

5e+07

6e+07

Time


8.862

+



Conc: 103.67 ug/L m

8.00 8.20 8.40 8.60 8.80 9.00 9.20 9.40 9.60 9.80

0

5000000

1e+07

1.5e+07

2e+07

2.5e+07

Time


8.773

+


of 329

#6 beta-BHC



8.60 8.80 9.00 9.20 9.40 9.60 9.80 10.00

0

1e+07

2e+07

3e+07

4e+07

5e+07

6e+07

Time


9.346

+

#6 beta-BHC


Conc: 97.29 ug/L m

10.40 10.60 10.80 11.00 11.20 11.40 11.60

0

5000000

1e+07

1.5e+07

2e+07

Time


11.063

+


of 329

#7 gamma-BHC



9.00 9.20 9.40 9.60 9.80 10.00 10.20 10.40

0

1e+07

2e+07

3e+07

4e+07

5e+07

6e+07

Time


9.642

+

#7 gamma-BHC


Conc: 119.44 ug/L m

10.00 10.20 10.40 10.60 10.80 11.00 11.20 11.40 11.60

0

5000000

1e+07

1.5e+07

2e+07

Time


10.713

+


of 329

#8 delta-BHC



9.60 9.80 10.00 10.20 10.40 10.60 10.80 11.00 11.20 11.40

0

1e+07

2e+07

3e+07

4e+07

5e+07

6e+07

Time


10.454

+

#8 delta-BHC


Conc: 115.96 ug/L m

11.60 11.80 12.00 12.20 12.40 12.60 12.80 13.00 13.20 13.40 13.60

0

5000000

1e+07

1.5e+07

2e+07

Time


12.526

+


of 329

#9 heptachlor



12.00 12.20 12.40 12.60 12.80 13.00 13.20 13.40 13.60

0

1e+07

2e+07

3e+07

4e+07

5e+07

Time


12.713

+

#9 heptachlor


Conc: 101.79 ug/L m

12.20 12.40 12.60 12.80 13.00 13.20 13.40 13.60

0

5000000

1e+07

1.5e+07

2e+07

Time


12.890

+


of 329

#10 aldrin



13.80 14.00 14.20 14.40 14.60 14.80 15.00 15.20 15.40

0

1e+07

2e+07

3e+07

4e+07

5e+07

Time


14.648

+

#10 aldrin


Conc: 106.32 ug/L m

14.00 14.20 14.40 14.60 14.80 15.00 15.20 15.40

0

5000000

1e+07

1.5e+07

Time


14.736

+


of 329




16.20 16.40 16.60 16.80 17.00 17.20 17.40 17.60 17.80 18.00 18.20

0

1e+07

2e+07

3e+07

4e+07

5e+07

Time


17.207

+



Conc: 103.23 ug/L m

18.00 18.20 18.40 18.60 18.80 19.00 19.20

0

5000000

1e+07

Time


18.655

+


of 329

#13 oxychlordane



16.20 16.40 16.60 16.80 17.00 17.20 17.40 17.60 17.80 18.00 18.20

0

1e+07

2e+07

3e+07

4e+07

5e+07

Time


17.207

+

#13 oxychlordane


Conc: 103.45 ug/L m

17.00 17.20 17.40 17.60 17.80 18.00 18.20 18.40 18.60 18.80 19.00

0

5000000

1e+07

Time


18.009

+


of 329

#14 gamma-chlordane



18.20 18.40 18.60 18.80 19.00 19.20 19.40 19.60

0

1e+07

2e+07

3e+07

4e+07

Time


18.866

+

#14 gamma-chlordane


Conc: 109.32 ug/L m

19.40 19.60 19.80 20.00 20.20 20.40

0

5000000

1e+07

1.5e+07

Time


19.957

+


of 329

#15 2,4'-DDE



18.40 18.60 18.80 19.00 19.20 19.40 19.60 19.80

0

1e+07

2e+07

3e+07

4e+07

Time


19.149

+

#15 2,4'-DDE


Conc: 103.98 ug/L m

19.40 19.60 19.80 20.00 20.20 20.40 20.60 20.80 21.00

0

5000000

1e+07

1.5e+07

Time


20.134

+


of 329

#16 endosulfan I



19.20 19.40 19.60 19.80 20.00 20.20

0

1e+07

2e+07

3e+07

4e+07

Time


19.755

+

#16 endosulfan I


Conc: 104.62 ug/L m

20.50 21.00 21.50 22.00

0

5000000

1e+07

1.5e+07

Time


21.209

+


of 329

#17 alpha-chlordane



19.40 19.60 19.80 20.00 20.20 20.40 20.60

0

1e+07

2e+07

3e+07

4e+07

Time


19.924

+

#17 alpha-chlordane


Conc: 107.32 ug/L m

20.20 20.40 20.60 20.80 21.00 21.20 21.40 21.60

0

5000000

1e+07

1.5e+07

Time


20.923

+


of 329

#18 trans-nonachlor



19.40 19.60 19.80 20.00 20.20 20.40 20.60 20.80 21.00

0

1e+07

2e+07

3e+07

4e+07

Time


20.234

+

#18 trans-nonachlor


Conc: 103.52 ug/L m

19.60 19.80 20.00 20.20 20.40 20.60 20.80 21.00 21.20 21.40 21.60

0

5000000

1e+07

1.5e+07

Time


20.599

+


of 329

#19 4,4'-DDE



20.60 20.80 21.00 21.20 21.40 21.60 21.80

0

1e+07

2e+07

3e+07

4e+07

Time


21.263

+

#19 4,4'-DDE


Conc: 123.60 ug/L m

21.60 21.80 22.00 22.20 22.40 22.60 22.80

0

5000000

1e+07

1.5e+07

Time


22.183

+


of 329

#20 dieldrin



20.60 20.80 21.00 21.20 21.40 21.60 21.80 22.00 22.20 22.40

0

1e+07

2e+07

3e+07

4e+07

Time


21.473

+

#20 dieldrin


Conc: 112.58 ug/L m

21.80 22.00 22.20 22.40 22.60 22.80 23.00 23.20 23.40 23.60 23.80 24.00

0

5000000

1e+07

1.5e+07

Time


22.881

+


of 329

#21 2,4'-DDD



21.20 21.40 21.60 21.80 22.00 22.20 22.40

0

1e+07

2e+07

3e+07

4e+07

Time


21.830

+

#21 2,4'-DDD


Conc: 109.44 ug/L m

22.60 22.80 23.00 23.20 23.40 23.60 23.80 24.00 24.20

0

5000000

1e+07

1.5e+07

Time


23.339

+


of 329

#22 endrin



21.80 22.00 22.20 22.40 22.60 22.80 23.00 23.20 23.40 23.60 23.80

0

1e+07

2e+07

3e+07

4e+07

Time


22.837

+

#22 endrin


Conc: 104.29 ug/L m

23.80 24.00 24.20 24.40 24.60 24.80 25.00 25.20 25.40

0

5000000

1e+07

Time


24.576

+


of 329

#23 endosulfan II



22.40 22.60 22.80 23.00 23.20 23.40 23.60 23.80 24.00 24.20 24.40

0

1e+07

2e+07

3e+07

4e+07

Time


23.375

+

#23 endosulfan II


Conc: 112.51 ug/L m

24.80 25.00 25.20 25.40 25.60 25.80 26.00 26.20 26.40 26.60 26.80

0

5000000

1e+07

1.5e+07

Time


25.751

+


of 329

#24 4,4'-DDD



23.20 23.40 23.60 23.80 24.00 24.20 24.40

0

1e+07

2e+07

3e+07

4e+07

Time


23.848

+

#24 4,4'-DDD


Conc: 127.98 ug/L m

24.80 25.00 25.20 25.40 25.60 25.80 26.00 26.20

0

5000000

1e+07

1.5e+07

Time


25.478

+


of 329

#25 2,4'-DDT



23.40 23.60 23.80 24.00 24.20 24.40 24.60

0

1e+07

2e+07

3e+07

4e+07

Time


24.061

+

#25 2,4'-DDT


Conc: 109.19 ug/L m

24.40 24.60 24.80 25.00 25.20 25.40 25.60

0

5000000

1e+07

Time


25.023

+


of 329

#27 endrin aldehyde


Conc: 88.85 ug/L M4

23.00 23.50 24.00 24.50 25.00 25.50 26.00

0

1e+07

2e+07

3e+07

4e+07

Time


24.481

+

#27 endrin aldehyde


Conc: 97.09 ug/L m

26.60 26.80 27.00 27.20 27.40 27.60 27.80 28.00 28.20 28.40 28.60

0

5000000

1e+07

Time


27.527

+


of 329




25.20 25.40 25.60 25.80 26.00 26.20 26.40

0

1e+07

2e+07

3e+07

4e+07

Time


25.801

+



Conc: 110.23 ug/L m

27.80 28.00 28.20 28.40 28.60 28.80 29.00 29.20 29.40 29.60 29.80

0

5000000

1e+07

1.5e+07

Time


28.745

+


of 329

#29 4,4'-DDT



25.40 25.60 25.80 26.00 26.20 26.40

0

1e+07

2e+07

3e+07

4e+07

Time


25.962

+

#29 4,4'-DDT


Conc: 129.27 ug/L m

26.00 26.50 27.00 27.50 28.00

0

5000000

1e+07

Time


27.088

+


of 329

#30 endrin ketone



27.80 28.00 28.20 28.40 28.60 28.80

0

1e+07

2e+07

3e+07

4e+07

5e+07

Time


28.266

+

#30 endrin ketone


Conc: 123.58 ug/L m

30.00 30.20 30.40 30.60 30.80 31.00 31.20 31.40 31.60

0

5000000

1e+07

1.5e+07

Time


30.814

+


of 329

#31 methoxychlor


Conc: 97.09 ug/L M4

28.40 28.50 28.60 28.70 28.80 28.90 29.00 29.10 29.20

0

5000000

1e+07

1.5e+07

2e+07

2.5e+07

3e+07

Time


28.796

+

#31 methoxychlor


Conc: 102.60 ug/L m

29.40 29.60 29.80 30.00 30.20 30.40 30.60

0

2000000

4000000

6000000

8000000

1e+07

Time


30.050

+


of 329

#32 mirex


Conc: 96.78 ug/L M4

29.80 30.00 30.20 30.40 30.60 30.80 31.00 31.20 31.40

0

1e+07

2e+07

3e+07

Time


30.533

+

#32 mirex


Conc: 97.99 ug/L m

30.00 30.20 30.40 30.60 30.80 31.00 31.20

0

5000000

1e+07

1.5e+07

Time


30.590

+


of 329

#34 DCB - Surrogate



35.50 36.00 36.50 37.00 37.50 38.00 38.50 39.00

0

5000000

1e+07

1.5e+07

2e+07

2.5e+07

3e+07

Time


37.217

+

#34 DCB - Surrogate


Conc: 103.43 ug/L m

36.50 37.00 37.50 38.00 38.50 39.00

0

2000000

4000000

6000000

8000000

Time


37.518

+


of 329

Sample Preparation

of 329

ORGANIC ELN REPORT

Workgroup: WG569308

Reported: 01-NOV-12 01:50 PMPage 1 of 2

WG569308-1

WG569308-2

WG569308-3

L1219133-01

10/24/12 10:21

10/24/12 10:21

10/24/12 10:21

10/24/12 10:21

Sonja Robinson

Sonja Robinson

Sonja Robinson

Sonja Robinson

10.0

10.0

10.0

10.54

.250

.250

.250

.250

.250

.250

Sarah Frazar

Sarah Frazar

Sarah Frazar

Sarah Frazar

2

2

2

2

Sample/Type

Prep Method: EPA 3570DCM/AcetoneA2-PEST

Spike Type: A2-PEST

Lot #:Lot #:Lot #:

Spike Verify by:

k42e09/l14s03psw100312cplw062512a

SFLims Spikelot: A2-PEST

Additional Reagents/Stds

Glass Wool

Na2SO4

CuSO4

197111999

k21617

owr102312a

Conc.Method: KD

Solvent Type: Hexane

Lot #: 0000018797


Cleanup Method 1:Cleanup Method 2:

Solvent Type: Hexane

- - - -

EPA 3630

Lot #: K49E21


Extract Date

Analyst

Silica Gel

SampleWeight

BCBH915OV

Surr Amtml

Spike Amt

g ml

Analyst Final Volml

Conc Date

10/25/12 09:30

10/25/12 09:30

10/25/12 09:30

10/25/12 09:30

Cleanup 1

Extraction Concentration

Solvent Type:

BLANK

LCS

LCSD

SOIL

Surrogate Type:

of 329

ORGANIC ELN REPORT

Workgroup: WG569308

Reported: 01-NOV-12 01:50 PMPage 2 of 2

Cleanup 1

Sample/Type

Cleanup Date

Analyst Cleanup Vol

Final Cleanup Vol

Final Eff

ml

Analyst Cleanup Volml

Final Cleanup Vol

Final Effml ml

Cleanup Date

WG569308-1

WG569308-2

WG569308-3

L1219133-01

10/25/12 00:00

10/25/12 00:00

10/25/12 00:00

10/25/12 00:00

Sarah Frazar

Sarah Frazar

Sarah Frazar

Sarah Frazar

1

1

1

1

1

1

1

1

2

2

2

2

Cleanup 2

BLANK

LCS

LCSD

SOIL

of 329

Wet Chemistry

of 329

Total Solids Analysis

of 329

Sample Raw Data

of 329

ALPHA ANALYTICAL LABS Last Change 04/09/09 GFF

WET CHEMISTRY DEPARTMENT File A2-TS_S.xltPERCENT TOTAL SOLIDS

Sample Number: _________________ Product: A2-TSAnalyte: Solids, Total

Client: _______________ Analysis Date: 10/24/2012 9:30Technician: KB

Analysis: %TOTAL SOLIDS Work group: WG569276in solids MDL: 0.10%

Method: STM 2540-B

105 degrees CTare Gross Net Net Net Net Net

Weight Weight Weight(1) Weight(2) Weight(3) Weight(4) Weight(5) RESULTSample Number (gm) (gm) (gm) (gm) (gm) (gm) (gm) %

DUP 1.33 1.96

1.33 7.69

1.33 7.67

1.33 1.95

Comments:

of 329

Work Group

of 329

ALPHA ANALYTICAL LABORATORIES, INC.

Alpha WORK GROUP REPORT (wk02)

Nov 01 2012, 06:07 am

Work Group: WG569276 for Department: 7 Wet Chemistry

Created: 24-OCT-12 Due: Operator: KB

Sample Client ID C Product Matrix Stat UA HOLD DUE PR Location ____________________________________________________________________________________________________________________________________

L1219046-01 SHAWNEE-1AB S A2-TS SOIL DONE U 1029 1030 2E Glass-A.1 L1219046-02 SHAWNEE-2AB S A2-TS SOIL DONE U 1029 1030 2E Glass-A.1 L1219133-01 SED-20121017-01 S A2-TS SOIL DONE U 1024 1031 S0 Amber-A.25 WG569276-1 Duplicate Sample S A2-TS SOIL DONE U

Comments:

WG569276-1 L1219133-01

____________________________________________________________________________________________________________________________________

Page 1

of 329

Supporting Documentation

of 329

of 329

Alpha Report

of 329

L1219133

Anchor QEA, LLC

120782-01.01

NEWTOWN CREEK RI

Client:

Project Name:

Project Number:

11/01/12

320 Forbes Boulevard, Mansfield, MA 02048-1806

Lab Number:

Report Date:

508-822-9300 (Fax) 508-822-3288 800-624-9220 - www.alphalab.com

720 Olive Way

Suite 1900

Delaney PetersonATTN:

ANALYTICAL REPORT

Seattle, WA 98101

Certifications & Approvals: NY (11627), CT (PH-0141), NH (2206), NJ NELAP (MA015), RI (LAO00299), PA (68-02089), LA NELAP (03090),FL (E87814), TX (T104704419), WA (C954), DOD (L2217.01), USDA (Permit #P330-11-00109), US Army Corps of Engineers.

(206) 287-9130Phone:

The original project report/data package is held by Alpha Analytical. This report/data package is paginated and should be reproduced only in itsentirety. Alpha Analytical holds no responsibility for results and/or data that are not consistent with the original.

Serial_No:11011217:05

Page 1 of 25 of 329

L1219133-01

Alpha Sample ID

SED-20121017-01

Client ID

Not Specified

Sample Location

NEWTOWN CREEK RI

120782-01.01

Project Name:Project Number:

Lab Number: Report Date:

L121913311/01/12

10/17/12 15:10

Collection Date/Time

Serial_No:11011217:05

Page 2 of 25 of 329

NEWTOWN CREEK RI

120782-01.01

Project Name:

Project Number:

Lab Number:

Report Date:L1219133

11/01/12

Case Narrative

The samples were received in accordance with the Chain of Custody and no significant deviations were encountered during the preparation

or analysis unless otherwise noted. Sample Receipt, Container Information, and the Chain of Custody are located at the back of the report.

Results contained within this report relate only to the samples submitted under this Alpha Lab Number and meet all of the requirements of

NELAC, for all NELAC accredited parameters. The data presented in this report is organized by parameter (i.e. VOC, SVOC, etc.). Sample

specific Quality Control data (i.e. Surrogate Spike Recovery) is reported at the end of the target analyte list for each individual sample,

followed by the Laboratory Batch Quality Control at the end of each parameter. If a sample was re-analyzed or re-extracted due to a

required quality control corrective action and if both sets of data are reported, the Laboratory ID of the re-analysis or re-extraction is

designated with an "R" or "RE", respectively. When multiple Batch Quality Control elements are reported (e.g. more than one LCS), the

associated samples for each element are noted in the grey shaded header line of each data table. Any Laboratory Batch, Sample Specific %

recovery or RPD value that is outside the listed Acceptance Criteria is bolded in the report. Performance criteria for CAM and RCP methods

allow for some LCS compound failures to occur and still be within method compliance. In these instances, the specific failures are not

narrated but are noted in the associated QC table. This information is also incorporated in the Data Usability format for our Data Merger tool

where it can be reviewed along with any associated usability implications. Soil/sediments, solids and tissues are reported on a dry weight

basis unless otherwise noted. Definitions of all data qualifiers and acronyms used in this report are provided in the Glossary located at the

back of the report.

In reference to questions H (CAM) or 4 (RCP) when "NO" is checked, the performance criteria for CAM and RCP methods allow for some

quality control failures to occur and still be within method compliance. In these instances the specific failure is not narrated but noted in the

associated QC table. The information is also incorporated in the Data Usability format of our Data Merger tool where it can be reviewed

along with any associated usability implications.

Please see the associated ADEx data file for a comparison of laboratory reporting limits that were achieved with the regulatory Numerical

Standards requested on the Chain of Custody.

HOLD POLICY

For samples submitted on hold, Alpha's policy is to hold samples free of charge for 30 days from the date the project is completed. After 30

days, we will dispose of all samples submitted including those put on hold unless you have contacted your Client Service Representative and

made arrangements for Alpha to continue to hold the samples.

Please contact Client Services at 800-624-9220 with any questions.

Serial_No:11011217:05

Page 3 of 25 of 329

Case Narrative (continued)

NEWTOWN CREEK RI

120782-01.01

Project Name:

Project Number:

Lab Number:

Report Date:L1219133

11/01/12

Sample Receipt & Login

L1219133-01 (Client ID: SED-20121017-01) was received at the laboratory at 15.4 degrees. The client was

notified and confirmed that this sample was a freeze-dried sediment. The lab proceeded with all requested

analyses.

Organochlorine Pesticides

L1219133-01 has elevated detection limits for all analytes due to the dilution required by the sample matrix.

L1219133-01 was re-analyzed following additional cleanup procedures due to interferences encountered in

the original analysis. The results of the re-analyses have been reported.

The WG569308-1 Method Blank, associated with L1219133-01, has a concentration above the reporting limit

for Endrin. Since the associated sample is non-detect for this target analyte, no further action was taken. The

results of the original analysis are reported.

The WG569308-2/-3 LCS/LCSD, associated with L1219133-01, were not spiked with Toxaphene or cis-

Nonachlor.

I, the undersigned, attest under the pains and penalties of perjury that, to the best of my knowledge and belief and based upon my personal inquiry of those responsible for providing the information contained in this analytical report, such information is accurate and complete. This certificate of analysis is not complete unless this page accompanies any and all pages of this report.

Authorized Signature:

Title: Technical Director/Representative Date: 11/01/12

Serial_No:11011217:05

Page 4 of 25 of 329

ORGANICS

Serial_No:11011217:05

Page 5 of 25 of 329

PESTICIDES

Serial_No:11011217:05

Page 6 of 25 of 329

FF

alpha-BHC

gamma-BHC

delta-BHC

Heptachlor

gamma-Chlordane

2,4'-DDE

Endosulfan I

alpha-Chlordane

4,4'-DDE

Dieldrin

2,4'-DDD

Endrin

Endosulfan II

2,4'-DDT

cis-Nonachlor

Endrin aldehyde

Endosulfan sulfate

4,4'-DDT

Endrin ketone

Methoxychlor

Toxaphene

Parameter Result Dilution Factor

ND

ND

ND

6.17

20.6

8.82

ND

13.0

45.2

8.41

63.1

ND

17.2

ND

2.40

1.29

ND

78.3

ND

148

ND

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

5

5

5

5

5

5

5

5

5

5

5

5

5

5

5

5

5

5

5

5

5

Qualifier Units RL

Organochlorine Pesticides by GC - Mansfield Lab

SAMPLE RESULTS

Project Name:

Project Number:

Lab Number:

Report Date:

NEWTOWN CREEK RI

120782-01.01

L1219133

0.482

0.482

0.482

0.482

0.482

0.482

0.482

0.482

0.482

0.482

0.482

0.482

0.482

0.482

0.482

0.482

0.482

0.482

0.482

0.482

24.1

TMX - Surrogate

DCB - Surrogate

TMX - Surrogate

DCB - Surrogate

55

62

61

73

30-150

30-150

30-150

30-150

Acceptance CriteriaSurrogate % Recovery Qualifier

11/01/12

SED-20121017-01Client ID:10/17/12 15:10Date Collected:10/19/12Date Received:

Not SpecifiedSample Location:

L1219133-01Lab ID:

Field Prep: Not Specified

D

Matrix: Sediment Extraction Method:

Cleanup Method1:Analytical Method:Analytical Date:Analyst:

1,8081B10/31/12 22:13RR

EPA 3570

EPA 3630Extraction Date: 10/24/12 10:21

Cleanup Date1: 10/25/12 98%Percent Solids:

MDL

0.482

0.482

0.482

0.482

0.482

0.482

0.482

0.482

0.482

0.482

0.482

0.482

0.482

0.482

0.482

0.482

0.482

0.482

0.482

0.482

24.1

Serial_No:11011217:05

Page 7 of 25 of 329

Hexachlorobenzene

beta-BHC

Aldrin

Heptachlor epoxide

Oxychlordane

trans-Nonachlor

4,4'-DDD

Mirex

Parameter Result Dilution Factor

7.51

1.81

ND

ND

ND

13.4

65.7

32.1

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

5

5

5

5

5

5

5

5

Qualifier Units RL

Organochlorine Pesticides by GC - Mansfield Lab

SAMPLE RESULTS

Project Name:

Project Number:

Lab Number:

Report Date:

NEWTOWN CREEK RI

120782-01.01

L1219133

0.482

0.482

0.482

0.482

0.482

0.482

0.482

0.482

TMX - Surrogate

DCB - Surrogate

TMX - Surrogate

DCB - Surrogate

55

62

61

73

30-150

30-150

30-150

30-150

Acceptance CriteriaSurrogate % Recovery Qualifier

11/01/12



L1219133-01Lab ID:

Field Prep: Not Specified

D

Matrix: Sediment Extraction Method:

Cleanup Method1:Analytical Method:Analytical Date:Analyst:

1,8081B10/31/12 22:13RR

EPA 3570


Cleanup Date1: 10/25/12 98%Percent Solids:

MDL

0.482

0.482

0.482

0.482

0.482

0.482

0.482

0.482

Serial_No:11011217:05

Page 8 of 25 of 329

Method Blank AnalysisBatch Quality Control

Project Name:

Project Number:

Lab Number:

Report Date:

NEWTOWN CREEK RI

120782-01.01

L1219133

10/31/12 14:101,8081BAnalytical Method:

Analytical Date:Extraction Method:

Cleanup Method1:

EPA 3570


11/01/12

Analyst: RR

alpha-BHC

Hexachlorobenzene

beta-BHC

gamma-BHC

delta-BHC

Heptachlor

gamma-Chlordane

2,4'-DDE

Endosulfan I

alpha-Chlordane

trans-Nonachlor

4,4'-DDE

Dieldrin

2,4'-DDD

Endrin

Endosulfan II

4,4'-DDD

2,4'-DDT

cis-Nonachlor

Endrin aldehyde

Endosulfan sulfate

4,4'-DDT

Endrin ketone

Methoxychlor

Mirex

Toxaphene

Parameter Result

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

0.194

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

RL

0.100

0.100

0.100

0.100

0.100

0.100

0.100

0.100

0.100

0.100

0.100

0.100

0.100

0.100

0.100

0.100

0.100

0.100

0.100

0.100

0.100

0.100

0.100

0.100

0.100

5.00

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

UnitsQualifier

Organochlorine Pesticides by GC - Mansfield Lab for sample(s): 01 Batch: WG569308-1

Cleanup Date1: 10/25/12

MDL

0.100

0.100

0.100

0.100

0.100

0.100

0.100

0.100

0.100

0.100

0.100

0.100

0.100

0.100

0.100

0.100

0.100

0.100

0.100

0.100

0.100

0.100

0.100

0.100

0.100

5.00

Serial_No:11011217:05

Page 9 of 25 of 329


Project Name:

Project Number:

Lab Number:

Report Date:

NEWTOWN CREEK RI

120782-01.01

L1219133



Cleanup Method1:

EPA 3570


11/01/12

Analyst: RR

Parameter Result RLUnitsQualifier


TMX - Surrogate

DCB - Surrogate

TMX - Surrogate

DCB - Surrogate

89

87

87

84

30-150

30-150

30-150

30-150

Surrogate %Recovery QualifierAcceptance

Criteria


MDL

Serial_No:11011217:05

Page 10 of 25 of 329


Project Name:

Project Number:

Lab Number:

Report Date:

NEWTOWN CREEK RI

120782-01.01

L1219133



Cleanup Method1:

EPA 3570


11/01/12

Analyst: RR

Aldrin

Heptachlor epoxide

Oxychlordane

Parameter Result

ND

ND

ND

RL

0.100

0.100

0.100

ug/kg

ug/kg

ug/kg

UnitsQualifier


TMX - Surrogate

DCB - Surrogate

TMX - Surrogate

DCB - Surrogate

89

87

87

84

30-150

30-150

30-150

30-150

Surrogate %Recovery QualifierAcceptance

Criteria


MDL

0.100

0.100

0.100

Serial_No:11011217:05


Alpha-BHC

Hexachlorobenzene

Beta-BHC

gamma-BHC

Delta-BHC

Heptachlor

trans-Chlordane

2,4'-DDE

Endosulfan I

cis-Chlordane

trans-Nonachlor

4,4'-DDE

Dieldrin

2,4'-DDD

Endrin

Endosulfan II

4,4'-DDD

2,4'-DDT

Endrin aldehyde

Endosulfan sulfate

4,4'-DDT

90

74

78

88

86

84

87

84

81

84

81

93

88

83

85

87

94

92

72

79

89

94

75

81

90

90

82

89

86

83

85

82

100

90

85

81

87

102

95

71

80

96

40-140

40-140

40-140

40-140

40-140

40-140

40-140

40-140

40-140

40-140

40-140

40-140

40-140

40-140

40-140

40-140

40-140

40-140

40-140

40-140

40-140

4

1

4

2

5

2

2

2

2

1

1

7

2

2

5

0

8

3

1

1

8

50

50

50

50

50

50

50

50

50

50

50

50

50

50

50

50

50

50

50

50

50

ParameterLCS

%RecoveryLCSD

%Recovery%Recovery

Limits RPD RPD Limits

Organochlorine Pesticides by GC - Mansfield Lab Associated sample(s): 01 Batch: WG569308-2 WG569308-3

Lab Control Sample AnalysisBatch Quality Control

Project Name:

Project Number:

Lab Number:

Report Date:

NEWTOWN CREEK RI

120782-01.01

L1219133

11/01/12

Qual Qual Qual

Serial_No:11011217:05


Endrin ketone

Methoxychlor

Mirex

88

76

75

92

78

78

40-140

40-140

40-140

4

3

4

50

50

50

ParameterLCS

%RecoveryLCSD

%Recovery%Recovery




Project Name:

Project Number:

Lab Number:

Report Date:

NEWTOWN CREEK RI

120782-01.01

L1219133

Tetrachloro-meta-Xylene

Decachlorobiphenyl


Decachlorobiphenyl

81

79

80

76

30-150

30-150

30-150

30-150

84

83

86

83

Surrogate Qual%Recovery Qual%RecoveryLCS LCSD

11/01/12

AcceptanceCriteria

Qual Qual Qual

Serial_No:11011217:05


Aldrin

Heptachlor epoxide

Oxychlordane

80

78

79

85

82

83

40-140

40-140

40-140

6

5

5

50

50

50

ParameterLCS

%RecoveryLCSD

%Recovery%Recovery




Project Name:

Project Number:

Lab Number:

Report Date:

NEWTOWN CREEK RI

120782-01.01

L1219133


Decachlorobiphenyl


Decachlorobiphenyl

81

79

80

76

30-150

30-150

30-150

30-150

84

83

86

83

Surrogate Qual%Recovery Qual%RecoveryLCS LCSD

11/01/12

AcceptanceCriteria

Qual Qual Qual

Serial_No:11011217:05


INORGANICS&

MISCELLANEOUS

Serial_No:11011217:05


FF


Parameter ResultDilution Factor

Matrix: Sediment


L1219133-01Lab ID:

Qualifier Units RL

SAMPLE RESULTS

Project Name:

Project Number:

Lab Number:

Report Date:

NEWTOWN CREEK RI

120782-01.01

L1219133

Field Prep:

DateAnalyzed

AnalyticalMethod Analyst

Not Specified

General Chemistry - Mansfield LabSolids, Total 98.4 % 10.100 10/24/12 09:30 30,2540G KB

Date Prepared

-

11/01/12

MDL

0.100

Serial_No:11011217:05


Solids, Total 98.4 100 % 2 10

Units RPDParameter Native Sample Duplicate Sample RPD Limits

General Chemistry - Mansfield Lab Associated sample(s): 01 QC Batch ID: WG569276-1 QC Sample: L1219133-01 Client ID: SED-20121017-01

NEWTOWN CREEK RI

120782-01.01

Project Name:

Project Number:

L1219133Lab Number:

Report Date:

Lab Duplicate AnalysisBatch Quality Control

11/01/12

Qual

Serial_No:11011217:05


*Values in parentheses indicate holding time in days

L1219133-01A Amber 250ml unpreserved A N/A 15.4 Y Absent

A AbsentCooler

Custody SealCooler Information

NEWTOWN CREEK RI

120782-01.01

A2-PEST-8081(14),A2-TS(7)

Project Name:

Project Number:

L1219133Lab Number:

Report Date:

Sample Receipt and Container Information

Container ID Container Type Cooler pHTempdeg C Pres Seal

Container Information

Analysis(*)

11/01/12

Were project specific reporting limits specified? YES

Reagent H2O Preserved Vials Frozen on: NA

Serial_No:11011217:05


Report Format: DU Report with "J" Qualifiers

GLOSSARY

Project Name:

Project Number:

Lab Number:

Report Date:

L1219133NEWTOWN CREEK RI

120782-01.01 11/01/12

Acronyms

EPA

LCS

LCSD

LFB

MDL

MS

MSD

NA

NC

NI

RL

RPD

SRM

Environmental Protection Agency.

Laboratory Control Sample: A sample matrix, free from the analytes of interest, spiked with verified known amounts of analytes or a material containing known and verified amounts of analytes.Laboratory Control Sample Duplicate: Refer to LCS.

Laboratory Fortified Blank: A sample matrix, free from the analytes of interest, spiked with verified known amounts of analytes or a material containing known and verified amounts of analytes.Method Detection Limit: This value represents the level to which target analyte concentrations are reported as estimated values, when those target analyte concentrations are quantified below the reporting limit (RL). The MDL includes any adjustments from dilutions, concentrations or moisture content, where applicable.Matrix Spike Sample: A sample prepared by adding a known mass of target analyte to a specified amount of matrix sample for which an independent estimate of target analyte concentration is available. Matrix Spike Sample Duplicate: Refer to MS.

Not Applicable.

Not Calculated: Term is utilized when one or more of the results utilized in the calculation are non-detect at the parameter's reporting unit.Not Ignitable.

Reporting Limit: The value at which an instrument can accurately measure an analyte at a specific concentration. The RL includes any adjustments from dilutions, concentrations or moisture content, where applicable.Relative Percent Difference: The results from matrix and/or matrix spike duplicates are primarily designed to assess the precisionof analytical results in a given matrix and are expressed as relative percent difference (RPD). Values which are less than five times the reporting limit for any individual parameter are evaluated by utilizing the absolute difference between the values; although the RPD value will be provided in the report.Standard Reference Material: A reference sample of a known or certified value that is of the same or similar matrix as the associated field samples.

-

-

-

-

-

-

-

-

-

-

-

-

-

Terms

Analytical Method: Both the document from which the method originates and the analytical reference method. (Example: EPA 8260B is shown as 1,8260B.) The codes for the reference method documents are provided in the References section of the Addendum.

Data Qualifiers

A

B

C

D

E

G

H

I

M

NJ

-

-

-

-

-

-

-

-

-

-

Spectra identified as "Aldol Condensation Product".

The analyte was detected above the reporting limit in the associated method blank. Flag only applies to associated field samples that have detectable concentrations of the analyte at less than five times (5x) the concentration found in the blank. For MCP-related projects, flag only applies to associated field samples that have detectable concentrations of the analyte at less than ten times (10x) the concentration found in the blank. For DOD-related projects, flag only applies to associated field samples that have detectable concentrations of the analyte at less than ten times (10x) the concentration found in the blank AND the analyte was detected above one-half the reporting limit (or above the reporting limit for common lab contaminants) in the associated method blank. For NJ-Air-related projects, flag only applies to associated field samples that have detectable concentrations of the analyte above the reporting limit.Co-elution: The target analyte co-elutes with a known lab standard (i.e. surrogate, internal standards, etc.) for co-extracted analyses.Concentration of analyte was quantified from diluted analysis. Flag only applies to field samples that have detectable concentrations of the analyte.Concentration of analyte exceeds the range of the calibration curve and/or linear range of the instrument.

The concentration may be biased high due to matrix interferences (i.e, co-elution) with non-target compound(s). The result should be considered estimated.The analysis of pH was performed beyond the regulatory-required holding time of 15 minutes from the time of sample collection.

The RPD between the results for the two columns exceeds the method-specified criteria; however, the lower value has been reporteddue to obvious interference.Reporting Limit (RL) exceeds the MCP CAM Reporting Limit for this analyte.

Presumptive evidence of compound. This represents an estimated concentration for Tentatively Identified Compounds (TICs), where the identification is based on a mass spectral library search.

1 The reference for this analyte should be considered modified since this analyte is absent from the target analyte list of the originalmethod.

-

Footnotes

Serial_No:11011217:05


Report Format: DU Report with "J" Qualifiers

Project Name:

Project Number:

Lab Number:

Report Date:


120782-01.01 11/01/12

Data Qualifiers

P

Q

R

RE

-

-

-

-

The RPD between the results for the two columns exceeds the method-specified criteria.

The quality control sample exceeds the associated acceptance criteria. For DOD-related projects, LCS and/or Continuing CalibrationStandard exceedences are also qualified on all associated sample results. Note: This flag is not applicable for matrix spike recoverieswhen the sample concentration is greater than 4x the spike added or for batch duplicate RPD when the sample concentrations are lessthan 5x the RL. (Metals only.)Analytical results are from sample re-analysis.

Analytical results are from sample re-extraction.

J

ND

-

-

Estimated value. The Target analyte concentration is below the quantitation limit (RL), but above the Method Detection Limit (MDL). This represents an estimated concentration for Tentatively Identified Compounds (TICs).Not detected at the method detection limit (MDL) for the sample.

Serial_No:11011217:05


Alpha Analytical performs services with reasonable care and diligence normal to the analytical testinglaboratory industry. In the event of an error, the sole and exclusive responsibility of Alpha Analyticalshall be to re-perform the work at it's own expense. In no event shall Alpha Analytical be held liablefor any incidental, consequential or special damages, including but not limited to, damages in any wayconnected with the use of, interpretation of, information or analysis provided by Alpha Analytical.

We strongly urge our clients to comply with EPA protocol regarding sample volume, preservation, cooling,containers, sampling procedures, holding time and splitting of samples in the field.

LIMITATION OF LIABILITIES

1

30

Test Methods for Evaluating Solid Waste: Physical/Chemical Methods. EPA SW-846. Third Edition. Updates I - IIIA, 1997.

Standard Methods for the Examination of Water and Wastewater. APHA-AWWA-WPCF. 18th Edition. 1992.

Project Name:

Project Number:

Lab Number:

Report Date:


120782-01.01

REFERENCES

11/01/12

Serial_No:11011217:05


Certificate/Approval Program SummaryLast revised August 3, 2012 – Mansfield Facility

The following list includes only those analytes/methods for which certification/approval is currently held.For a complete listing of analytes for the referenced methods, please contact your Alpha Customer Service Representative.

Connecticut Department of Public Health Certificate/Lab ID: PH-0141.

Wastewater/Non-Potable Water (Inorganic Parameters: pH, Turbidity, Conductivity, Alkalinity, Aluminum, Antimony, Arsenic, Barium, Beryllium, Boron, Cadmium, Calcium, Chromium, Cobalt, Copper, Iron, Lead, Magnesium, Manganese, Mercury, Molybdenum, Nickel, Potassium, Selenium, Silver, Sodium, Strontium, Thallium, Tin, Titanium, Vanadium, Zinc, Total Residue (Solids), Total Suspended Solids (non-filterable). Organic Parameters: PCBs, Organochlorine Pesticides, Technical Chlordane, Toxaphene, Acid Extractables, Benzidines, Phthalate Esters, Nitrosamines, Nitroaromatics & Isophorone, PAHs, Haloethers, Chlorinated Hydrocarbons, Volatile Organics.)

Solid Waste/Soil (Inorganic Parameters: pH, Aluminum, Antimony, Arsenic, Barium, Beryllium, Cadmium,Calcium, Chromium, Hexavalent Chromium, Cobalt, Copper, Iron, Lead, Magnesium, Manganese, Mercury, Molybdenum, Nickel, Potassium, Selenium, Silver, Sodium, Thallium, Titanium, Vanadium, Zinc, Total Organic Carbon, Corrosivity, TCLP 1311, SPLP 1312. Organic Parameters: PCBs, Organochlorine Pesticides, Technical Chlordane, Toxaphene, Volatile Organics, Acid Extractables, Benzidines, Phthalates, Nitrosamines,Nitroaromatics & Cyclic Ketones, PAHs, Haloethers, Chlorinated Hydrocarbons.)

Florida Department of Health Certificate/Lab ID: E87814. NELAP Accredited.

Non-Potable Water (Inorganic Parameters: SM2320B, SM2540D, SM2540G.)

Solid & Chemical Materials (Inorganic Parameters: 6020, 7470, 7471, 9045. Organic Parameters: EPA 8260,8270, 8082, 8081.)

Air & Emissions (EPA TO-15.)

Louisiana Department of Environmental Quality Certificate/Lab ID: 03090. NELAP Accredited.

Non-Potable Water (Inorganic Parameters: EPA 180.1, 245.7, 1631E, 3020A, 6020A, 7470A, 9040, 9050A, SM2320B, 2540D, 2540G, 4500H-B, Organic Parameters: EPA 3510C, 3580A, 3630C, 3640A, 3660B, 3665A,5030B, 8015D, 3570, 8081B, 8082A, 8260B, 8270C, 8270D.)

Solid & Chemical Materials (Inorganic Parameters: EPA 1311, 3050B, 3051A, 3060A, 6020A, 7196A, 7470A,7471B, 7474, 9040B, 9045C, 9060. Organic Parameters: EPA 3540C, 3570, 3580A, 3630C, 3640A, 3660,3665A, 5035, 8015D, 8081B, 8082A, 8260B, 8270C, 8270D.)

Biological Tissue (Inorganic Parameters: EPA 6020A. Organic Parameters: EPA 3570, 3510C, 3610B, 3630C, 3640A, 8270C, 8270D.)


New Hampshire Department of Environmental Services Certificate/Lab ID: 2206. NELAP Accredited.

Non-Potable Water (Inorganic Parameters: EPA 180.1, 1631E, 6020A, 7470A, 9040B, 9050A, SM2540D, 2540G, 4500H+B, 2320B, 3020A, . Organic Parameters: EPA 3510C, 3630C, 3640A, 3660B, 8081B, 8082A, 8270C, 8270D, 8015D.)

Solid & Chemical Materials (Inorganic Parameters: SW-846 1311, 3050B, 3051A, 6020A, 7471B, 9040B, 9045C. Organic Parameters: SW-846 3540C, 3580A, 3630C, 3640A, 3660B, 3665A, 8270C, 8015D, 8082A, 8081B.)

New Jersey Department of Environmental Protection Certificate/Lab ID: MA015. NELAP Accredited.

Non-Potable Water (Inorganic Parameters: SW-846 1312, 3020A, SM2320B, SM2540D, 2540G, 4500H-B, EPA 180.1, 1631E, SW-846 7470A, 9040C, 6020A, 9050A. Organic Parameters: SW-846 3510C, 3580A, 3630C, 3640A, 3660B, 3665A, 8015D, 8081B, 8082A, 8270C, 8270D)

Serial_No:11011217:05


Solid & Chemical Materials (Inorganic Parameters: SW-846 1311, 1312, 3050B, 3051A, 6020A, 7471B, 7474,9040B, 9040C, 9045C, 9045D, 9060. Organic Parameters: SW-846 3540C, 3570, 3580A, 3630C, 3640A, 3660B, 3665A, 8081B, 8082A, 8270C, 8270D, 8015D.)

Atmospheric Organic Parameters (EPA 3C, TO-15, TO-10A, TO-13A-SIM.)

Biological Tissue (Inorganic Parameters: SW-846 6020A. Organic Parameters: SW-846 8270C, 8270D, 3510C, 3570, 3610C, 3630C, 3640A)

New York Department of Health Certificate/Lab ID: 11627. NELAP Accredited.

Non-Potable Water (Inorganic Parameters: SM2320B, SM2540D, 6020A, 1631E, 7470A, 9050A, EPA 180.1, 3020A. Organic Parameters: EPA 8270C, 8270D, 8081B, 8082A, 3510C.)

Solid & Hazardous Waste (Inorganic Parameters: EPA 6020A, 7471B, 7474, 9040C, 9045D. Organic Parameters: EPA 8270C, 8270D, 8081B, 8082A, 1311, 3050B, 3580A, 3570, 3051A.)

Air & Emissions (EPA TO-15, TO-10A.)

Pennsylvania Certificate/Lab ID: 68-02089 NELAP Accredited

Non-Potable Water (Inorganic Parameters: 1312, 1631E, 180.1, 3020A, 6020A, 7470A, 9040B, 9050A, 2320B, 2540D, 2540G, SM4500H+-B. Organic Parameters: 3510C, 3580A, 3630C, 3640A, 3660B, 3665A, 8015D, 8081B, 8082A, 8270C, 8270D .)

Solid & Hazardous Waste (Inorganic Parameters: EPA 1311, 3051A, 6020A, 7471B, 7474 9040B, 9045C, 9060.Organic Parameters: EPA3050B, 3540C, 3570, 3580A, 3630C, 3640A, 3660B, 3665A, 8270C, 8270D, 8081B,8015D, 8082A.)

Rhode Island Department of Health Certificate/Lab ID: LAO00299. NELAP Accredited via NJ-DEP.

Refer to NJ-DEP Certificate for Non-Potable Water.

Texas Commission of Environmental Quality Certificate/Lab ID: T104704419-08-TX. NELAP Accredited.

Solid & Chemical Materials (Inorganic Parameters: EPA 6020, 7470, 7471, 1311, 9040, 9045, 9060. Organic Parameters: EPA 8015, 8270, 8081, 8082.)

Air (Organic Parameters: EPA TO-15)

Virginia Division of Consolidated Laboratory Services Certificate/Lab ID:460194. NELAP Accredited.

Non-Potable Water (Inorganic Parameters:EPA 3020A, 6020A, 245.7, 9040B. Organic Parameters: EPA 3510C,3640A, 3660B, 3665A, 8270C, 8270D, 8082A, 8081B, 8015D.)

Solid & Chemical Materials (Inorganic Parameters: EPA 6020A,7470A,7471B,9040B,9045C,3050B,3051, 9060.Organic Parameters: EPA 3540C, 3580A, 3630C, 3640A, 3660B, 3665A, 3570, 8270C, 8270D, 8081B, 8082A,8015D.)

Washington State Department of Ecology Certificate/Lab ID: C954. Non-Potable Water (InorganicParameters: SM2540D, 180.1, 1631E.)

Solid & Chemical Materials (Inorganic Parameters: EPA 6020, 7470, 7471, 7474, 9045C, 9050A, 9060. OrganicParameters: EPA 8081, 8082, 8015, 8270.)

U.S. Army Corps of Engineers

Department of Defense, L-A-B Certificate/Lab ID: L2217.01.

Non-Potable Water (Inorganic Parameters: EPA 6020A, SM4500H-B. Organic Parameters: 3020A, 3510C,8270C, 8270D, 8270C-ALK-PAH, 8270D-ALK-PAH, 8082A, 8081B, 8015D-SHC, 8015D.)

Solid & Hazardous Waste (Inorganic Parameters: EPA 1311, 3050B, 6020A, 7471A, 9045C, 9060, SM 2540G, ASTM D422-63. Organic Parameters: EPA 3580A, 3570, 3540C, 8270C, 8270D, 8270C-ALK-PAH, 8270D-ALK-PAH 8082A, 8081B, 8015D-SHC, 8015D.


Serial_No:11011217:05


Analytes Not Accredited by NELAP Certification is not available by NELAP for the following analytes: 8270C: Biphenyl. TO-15: Halothane, 2,4,4-Trimethyl-2-pentene, 2,4,4-Trimethyl-1-pentene, Thiophene, 2-Methylthiophene, 3-Methylthiophene, 2-Ethylthiophene, 1,2,3-Trimethylbenzene, Indan, Indene, 1,2,4,5-Tetramethylbenzene, Benzothiophene, 2-Methylnaphthalene, 1-Methylnaphthalene.

Serial_No:11011217:05


Chain of Custody Record & laboratory Analysis RequestL/2/c;(33

\l~;~

----- .

0;-m(Q

III.•..•.. -Q) III

c:: Q)

'iii 'C- 'uc::0 ~U III.•.. CI)0 Q.

lab 10 Matrix 0 0:::Commentsz :::E:

SED 1 X

-----

CollectionOatelTime

10/17/121510

------Field Sample 10SED-20121017-1

--

laboratory Number:Date: 10/18/2012

Project Name: Newtown CreekProject Number: 120782-01Project Manager: Delaney PetersonPhone Number: 206.903.3396

Shipment Method: FedEx

Line

-I 1

2

34

56

7

8

9

10

11

1213

14

15

*Standard TAT*Level 4 data packaqe*See QAPP tables for analyte lists and QC requirements

rnhed2i-Signatunf/P~nted Name

Company: Anchor QEA, LLC

-J)Hla'-~A foJ I 'Is I \ 2- I vo 0, Date/Time

Received By:

~cA ~Signature/Printed Name

Company:

Date/Time

Relinquished By:

~~Signature/Printed Name

Company:

Date/Time

Rece~//L#rP~A_-.rOLf#,.l'.f X j, ~-

Sigrfciture/Printed Name

Company: .f\1 blAt" .•

lO(\C(/\'L' '1~22.Date/Time

Distribution: A copy will be made for the laboratory and client. The Project file will retain the original. Page _1_ of _1_

Serial_No:11011217:05


Alpha Summary

Forms

of 329

Organic Summary Forms

of 329

Form 1Form 1

GC OrganicsGC Organics

Client : Anchor QEA, LLC Lab Number : L1219133 Project Name : NEWTOWN CREEK RI Project Number : 120782-01.01 Lab ID : L1219133-01D Date Collected : 10/17/12 15:10 Client ID : SED-20121017-01 Date Received : 10/19/12 Sample Location : Date Analyzed : 10/31/12 22:13 Sample Matrix : Sediment Date Extracted : 10/24/12 Analytical Method : 1,8081B Dilution Factor : 5 Lab File ID : F210301253 Analyst : RR Sample Amount : 10.54 g Instrument ID : ECD2 Extraction Method : EPA 3570 GC Column : RTX-5 Extract Volume : 2000 uL %Solids : 98 GPC Cleanup : N Injection Volume : 1 uL Sulfur Cleanup : Y

ug/Kg

CAS NO. Parameter Results RL MDL Qualifier

319-84-6 alpha-BHC ND 0.482 0.482 U

58-89-9 gamma-BHC ND 0.482 0.482 U

319-86-8 delta-BHC ND 0.482 0.482 U

76-44-8 Heptachlor 6.17 0.482 0.482

5103-74-2 gamma-Chlordane 20.6 0.482 0.482

3424-82-6 2,4'-DDE 8.82 0.482 0.482

959-98-8 Endosulfan I ND 0.482 0.482 U

5103-71-9 alpha-Chlordane 13.0 0.482 0.482

72-55-9 4,4'-DDE 45.2 0.482 0.482

60-57-1 Dieldrin 8.41 0.482 0.482

53-19-0 2,4'-DDD 63.1 0.482 0.482

72-20-8 Endrin ND 0.482 0.482 U

33213-65-9 Endosulfan II 17.2 0.482 0.482

789-02-6 2,4'-DDT ND 0.482 0.482 U

5103-73-1 cis-Nonachlor 2.40 0.482 0.482

7421-93-4 Endrin aldehyde 1.29 0.482 0.482

1031-07-8 Endosulfan sulfate ND 0.482 0.482 U

50-29-3 4,4'-DDT 78.3 0.482 0.482

53494-70-5 Endrin ketone ND 0.482 0.482 U

72-43-5 Methoxychlor 148 0.482 0.482

8001-35-2 Toxaphene ND 24.1 24.1 U

of 329

Form 1Form 1


Client : Anchor QEA, LLC Lab Number : L1219133 Project Name : NEWTOWN CREEK RI Project Number : 120782-01.01 Lab ID : L1219133-01D Date Collected : 10/17/12 15:10 Client ID : SED-20121017-01 Date Received : 10/19/12 Sample Location : Date Analyzed : 10/31/12 22:13 Sample Matrix : Sediment Date Extracted : 10/24/12 Analytical Method : 1,8081B Dilution Factor : 5 Lab File ID : F210301253 Analyst : RR Sample Amount : 10.54 g Instrument ID : ECD2 Extraction Method : EPA 3570 GC Column : RTX-CLPPesticides2 Extract Volume : 2000 uL %Solids : 98 GPC Cleanup : N Injection Volume : 1 uL Sulfur Cleanup : Y

ug/Kg


118-74-1 Hexachlorobenzene 7.51 0.482 0.482

319-85-7 beta-BHC 1.81 0.482 0.482

309-00-2 Aldrin ND 0.482 0.482 U

1024-57-3 Heptachlor epoxide ND 0.482 0.482 U

27304-13-8 Oxychlordane ND 0.482 0.482 U

39765-80-5 trans-Nonachlor 13.4 0.482 0.482

72-54-8 4,4'-DDD 65.7 0.482 0.482

2385-85-5 Mirex 32.1 0.482 0.482

of 329

Form 1Form 1


Client : Anchor QEA, LLC Lab Number : L1219133 Project Name : NEWTOWN CREEK RI Project Number : 120782-01.01 Lab ID : WG569308-1 Date Collected : NA Client ID : WG569308-1BLANK Date Received : NA Sample Location : Date Analyzed : 10/31/12 14:10 Sample Matrix : SOIL Date Extracted : 10/24/12 Analytical Method : 1,8081B Dilution Factor : 1 Lab File ID : F210301240 Analyst : RR Sample Amount : 10 g Instrument ID : ECD2 Extraction Method : EPA 3570 GC Column : RTX-5 Extract Volume : 2000 uL %Solids : NA GPC Cleanup : N Injection Volume : 1 uL Sulfur Cleanup : Y

ug/Kg


319-84-6 alpha-BHC ND 0.100 0.100 U

118-74-1 Hexachlorobenzene ND 0.100 0.100 U

319-85-7 beta-BHC ND 0.100 0.100 U

58-89-9 gamma-BHC ND 0.100 0.100 U

319-86-8 delta-BHC ND 0.100 0.100 U

76-44-8 Heptachlor ND 0.100 0.100 U

5103-74-2 gamma-Chlordane ND 0.100 0.100 U

3424-82-6 2,4'-DDE ND 0.100 0.100 U

959-98-8 Endosulfan I ND 0.100 0.100 U

5103-71-9 alpha-Chlordane ND 0.100 0.100 U

39765-80-5 trans-Nonachlor ND 0.100 0.100 U

72-55-9 4,4'-DDE ND 0.100 0.100 U

60-57-1 Dieldrin ND 0.100 0.100 U

53-19-0 2,4'-DDD ND 0.100 0.100 U

72-20-8 Endrin 0.194 0.100 0.100

33213-65-9 Endosulfan II ND 0.100 0.100 U

72-54-8 4,4'-DDD ND 0.100 0.100 U

789-02-6 2,4'-DDT ND 0.100 0.100 U

5103-73-1 cis-Nonachlor ND 0.100 0.100 U

7421-93-4 Endrin aldehyde ND 0.100 0.100 U

1031-07-8 Endosulfan sulfate ND 0.100 0.100 U

50-29-3 4,4'-DDT ND 0.100 0.100 U

53494-70-5 Endrin ketone ND 0.100 0.100 U

of 329

Form 1Form 1


Client : Anchor QEA, LLC Lab Number : L1219133 Project Name : NEWTOWN CREEK RI Project Number : 120782-01.01 Lab ID : WG569308-1 Date Collected : NA Client ID : WG569308-1BLANK Date Received : NA Sample Location : Date Analyzed : 10/31/12 14:10 Sample Matrix : SOIL Date Extracted : 10/24/12 Analytical Method : 1,8081B Dilution Factor : 1 Lab File ID : F210301240 Analyst : RR Sample Amount : 10 g Instrument ID : ECD2 Extraction Method : EPA 3570 GC Column : RTX-5 Extract Volume : 2000 uL %Solids : NA GPC Cleanup : N Injection Volume : 1 uL Sulfur Cleanup : Y

ug/Kg


72-43-5 Methoxychlor ND 0.100 0.100 U

2385-85-5 Mirex ND 0.100 0.100 U

8001-35-2 Toxaphene ND 5.00 5.00 U

of 329

Form 1Form 1


Client : Anchor QEA, LLC Lab Number : L1219133 Project Name : NEWTOWN CREEK RI Project Number : 120782-01.01 Lab ID : WG569308-1 Date Collected : NA Client ID : WG569308-1BLANK Date Received : NA Sample Location : Date Analyzed : 10/31/12 14:10 Sample Matrix : SOIL Date Extracted : 10/24/12 Analytical Method : 1,8081B Dilution Factor : 1 Lab File ID : F210301240 Analyst : RR Sample Amount : 10 g Instrument ID : ECD2 Extraction Method : EPA 3570 GC Column : RTX-CLPPesticides2 Extract Volume : 2000 uL %Solids : NA GPC Cleanup : N Injection Volume : 1 uL Sulfur Cleanup : Y

ug/Kg


309-00-2 Aldrin ND 0.100 0.100 U

1024-57-3 Heptachlor epoxide ND 0.100 0.100 U

27304-13-8 Oxychlordane ND 0.100 0.100 U

of 329

2F SOIL GC ORGANICS SURROGATE RECOVERY

Lab Name: Alpha Analytical Labs

SDG No.: L1219133 Matrix: Soil

GC Column 1: RTX-5 GC Column 2: RTX-CLPPesticides2

____________________________________________________________________ | CLIENT |TCM 1|TCM 2|DCB 1|DCB 2|OTHER |OTHER | TOT| | SAMPLE NO. |%REC |%REC |%REC |%REC | (1) | (2) | OUT| |=====================|======|======|======|======|======|======|====|

01|WG569308-3LCSD | 84 | 86 | 83 | 83 | | | 0 | 02|WG569308-2LCS | 81 | 80 | 79 | 76 | | | 0 | 03|WG569308-1BLANK | 89 | 87 | 87 | 84 | | | 0 | 04|SED-20121017-01 | 55 | 61 | 62 | 73 | | | 0 | |_____________________|______|______|______|______|______|______|____||_____________________|______|______|______|______|______|______|____||_____________________|______|______|______|______|______|______|____||_____________________|______|______|______|______|______|______|____||_____________________|______|______|______|______|______|______|____||_____________________|______|______|______|______|______|______|____||_____________________|______|______|______|______|______|______|____||_____________________|______|______|______|______|______|______|____||_____________________|______|______|______|______|______|______|____||_____________________|______|______|______|______|______|______|____||_____________________|______|______|______|______|______|______|____||_____________________|______|______|______|______|______|______|____||_____________________|______|______|______|______|______|______|____||_____________________|______|______|______|______|______|______|____||_____________________|______|______|______|______|______|______|____||_____________________|______|______|______|______|______|______|____||_____________________|______|______|______|______|______|______|____||_____________________|______|______|______|______|______|______|____||_____________________|______|______|______|______|______|______|____||_____________________|______|______|______|______|______|______|____||_____________________|______|______|______|______|______|______|____||_____________________|______|______|______|______|______|______|____||_____________________|______|______|______|______|______|______|____||_____________________|______|______|______|______|______|______|____||_____________________|______|______|______|______|______|______|____||_____________________|______|______|______|______|______|______|____||_____________________|______|______|______|______|______|______|____|

QC LIMITS TCMX = TETRACHLORO-META-XYLENE (30-150)DCBP = DECACHLOROBIPHENYL (30-150)

* Values outside of QC limits

page 1 of 1 FORM II A2-PEST-8081

of 329

3F LAB CONTROL/LAB CONTROL DUPLICATE SAMPLE RECOVERY

SOIL GC ORGANICS

Lab Name: Alpha Analytical Labs SDG No.: L1219133 Matrix: Soil Lab Control Sample: WG569308-2LCS Injected: 10/31/12 14:54 Lab File ID: F210301241 Lab Control Dup : WG569308-3LCSD Injected: 10/31/12 15:38 Lab File ID: F210301242 _______________________________________________________________________________________________

| | SPIKE | SAMPLE | LCS | LCS | LCSD | LCSD | | QC | | | ADDED | CONC | CONC | % | CONC | % | % | LIMITS | | COMPOUND | ug/kg | ug/kg | ug/kg| REC | ug/kg| REC | RPD | RPD| REC. | |========================|=======|==========|=======|=======|=======|=======|=======|====|======| |Alpha-BHC | 25 | NA | 22.5| 90 | 23.5| 94 | 4 | 50|40-140| |Hexachlorobenzene | 25 | NA | 18.5| 74 | 18.8| 75 | 1 | 50|40-140| |Beta-BHC | 25 | NA | 19.5| 78 | 20.2| 81 | 4 | 50|40-140| |gamma-BHC | 25 | NA | 22.1| 88 | 22.6| 90 | 2 | 50|40-140| |Delta-BHC | 25 | NA | 21.5| 86 | 22.6| 90 | 5 | 50|40-140| |Heptachlor | 25 | NA | 20.9| 84 | 20.4| 82 | 2 | 50|40-140| |gamma-Chlordane | 25 | NA | 21.8| 87 | 22.2| 89 | 2 | 50|40-140| |2,4'-DDE | 25 | NA | 21.1| 84 | 21.6| 86 | 2 | 50|40-140| |Endosulfan I | 25 | NA | 20.2| 81 | 20.7| 83 | 2 | 50|40-140| |alpha-Chlordane | 25 | NA | 20.9| 84 | 21.2| 85 | 1 | 50|40-140| |trans-Nonachlor | 25 | NA | 20.2| 81 | 20.6| 82 | 1 | 50|40-140| |4,4'-DDE | 25 | NA | 23.3| 93 | 25.0| 100 | 7 | 50|40-140| |Dieldrin | 25 | NA | 22.1| 88 | 22.4| 90 | 2 | 50|40-140| |2,4'-DDD | 25 | NA | 20.7| 83 | 21.3| 85 | 2 | 50|40-140| |Endrin | 25 | NA | 21.2| 85 | 20.3| 81 | 5 | 50|40-140| |Endosulfan II | 25 | NA | 21.7| 87 | 21.7| 87 | 0 | 50|40-140| |4,4'-DDD | 25 | NA | 23.6| 94 | 25.4| 102 | 8 | 50|40-140| |2,4'-DDT | 25 | NA | 23.0| 92 | 23.8| 95 | 3 | 50|40-140| |Endrin aldehyde | 25 | NA | 17.9| 72 | 17.8| 71 | 1 | 50|40-140| |Endosulfan sulfate | 25 | NA | 19.7| 79 | 20.1| 80 | 1 | 50|40-140| |4,4'-DDT | 25 | NA | 22.3| 89 | 23.9| 96 | 8 | 50|40-140| |Endrin ketone | 25 | NA | 22.0| 88 | 22.9| 92 | 4 | 50|40-140| |Methoxychlor | 25 | NA | 19.1| 76 | 19.4| 78 | 3 | 50|40-140| |Mirex | 25 | NA | 18.8| 75 | 19.4| 78 | 4 | 50|40-140| |________________________|_______|__________|_______|_______|_______|_______|_______|____|______|

* Values outside of QC limits.

COMMENTS: _________________________________________________________

_________________________________________________________

FORM III A2-PEST-8081

of 329

3F LAB CONTROL/LAB CONTROL DUPLICATE SAMPLE RECOVERY

SOIL GC ORGANICS

Lab Name: Alpha Analytical Labs SDG No.: L1219133 Matrix: Soil Lab Control Sample: WG569308-2LCS Injected: 10/31/12 14:54 Lab File ID: F210301241 Lab Control Dup : WG569308-3LCSD Injected: 10/31/12 15:38 Lab File ID: F210301242 _______________________________________________________________________________________________

| | SPIKE | SAMPLE | LCS | LCS | LCSD | LCSD | | QC | | | ADDED | CONC | CONC | % | CONC | % | % | LIMITS | | COMPOUND | ug/kg | ug/kg | ug/kg| REC | ug/kg| REC | RPD | RPD| REC. | |========================|=======|==========|=======|=======|=======|=======|=======|====|======| |Aldrin | 25 | NA | 20.1| 80 | 21.3| 85 | 6 | 50|40-140| |heptachlor epoxide | 25 | NA | 19.6| 78 | 20.6| 82 | 5 | 50|40-140| |Oxychlordane | 25 | NA | 19.8| 79 | 20.7| 83 | 5 | 50|40-140| |________________________|_______|__________|_______|_______|_______|_______|_______|____|______|

* Values outside of QC limits.

COMMENTS: _________________________________________________________

_________________________________________________________

FORM III A2-PEST-8081

of 329

4C SAMPLE NO. GC ORGANICS METHOD BLANK SUMMARY ________________

| | | WG569308-1BLANK|

Lab Name: Alpha Analytical Labs |________________|

SDG No.: L1219133

Lab Sample ID: WG569308-1 Lab File ID: F210301240

Matrix: (soil/water) SOIL Date Extracted: 10/24/12

Sulfur Cleanup: (Y/N) Y

Date Analyzed (1): 10/31/12 Date Analyzed (2): 10/31/12

Time Analyzed (1): 14:10 Time Analyzed (2): 14:10

Instrument ID (1): ECD2 Instrument ID (2): ECD2

THIS METHOD BLANK APPLIES TO THE FOLLOWING SAMPLES: _______________________________________________________________ | CLIENT | LAB | DATE | DATE | | SAMPLE NO. | SAMPLE ID |ANALYZED 1|ANALYZED 2 | |======================|==============|==========|==============|

01|WG569308-2LCS |WG569308-2 |10/31/12 |10/31/12 |02|WG569308-3LCSD |WG569308-3 |10/31/12 |10/31/12 |03|SED-20121017-01 |L1219133-01D |10/31/12 |10/31/12 ||______________________|______________|__________|______________||______________________|______________|__________|______________||______________________|______________|__________|______________||______________________|______________|__________|______________||______________________|______________|__________|______________||______________________|______________|__________|______________||______________________|______________|__________|______________||______________________|______________|__________|______________||______________________|______________|__________|______________||______________________|______________|__________|______________||______________________|______________|__________|______________||______________________|______________|__________|______________||______________________|______________|__________|______________||______________________|______________|__________|______________||______________________|______________|__________|______________||______________________|______________|__________|______________||______________________|______________|__________|______________||______________________|______________|__________|______________||______________________|______________|__________|______________||______________________|______________|__________|______________||______________________|______________|__________|______________||______________________|______________|__________|______________||______________________|______________|__________|______________||______________________|______________|__________|______________||______________________|______________|__________|______________||______________________|______________|__________|______________||______________________|______________|__________|______________||______________________|______________|__________|______________||______________________|______________|__________|______________||______________________|______________|__________|______________||______________________|______________|__________|______________|

COMMENTS: ___________________________________________________

___________________________________________________

page 1 of 1 FORM IV A2-PEST-8081

of 329

6B GC ORGANICS ORGANICS INITIAL CALIBRATION DATA


SDG No.: L1219133

Instrument ID: ECD2 Calibration Date(s): 10/29/12 10/31/12

Calibration Times: 19:36 21:30

Calibration Files

1 =F210291211.D 5 =F210291212.D 10 =F210291213.D 20 =F210291214.D 50 =F210291215.D

100 =F210291216.D 150 =F210291217.D 200 =F210291218.D 0.5 =F210291210.D

Compound 1 5 10 20 50 100 150 200 0.5 Avg %RSD

--------------------------------------------------------------------------------------------------

1) I BZ 192 ----------------ISTD---------------------

2) S TMX - Surrogate 0.727 0.553 0.651 0.593 0.729 0.605 0.659 0.636 0.613 0.641 9.19

3) S DBOB 0.866 0.642 0.741 0.685 0.822 0.691 0.753 0.700 0.764 0.740 9.55

4) T alpha-BHC 0.913 0.749 0.862 0.854 1.081 0.968 1.049 1.040 0.787 0.922 12.94

5) T hexachlorobenz 8.88 8. 0.956 0.691 0.789 0.718 0.879 0.712 0.771 0.741 0.826 0.787 11.05

6) T beta-BHC 0.473 0.378 0.422 0.385 0.414 0.372 0.385 0.369 0.426 0.403 8.49

7) T gamma-BHC 0.921 0.738 0.851 0.812 1.021 0.894 0.967 0.951 0.884 0.893 9.57

8) T delta-BHC 0.809 0.693 0.792 0.784 0.916 0.877 0.911 0.902 0.721 0.823 10.12

9) T heptachlor 1.035 0.753 0.855 0.812 1.014 0.871 0.955 0.924 0.944 0.907 10.22

10) T aldrin 0.739 0.553 0.626 0.588 0.706 0.607 0.649 0.623 0.677 0.641 9.12

11) T chloropyrifos 0.741 0.554 0.627 0.588 0.706 0.607 0.649 0.623 0.677 0.641 9.17

12) T heptachlor epo 17.25 18. 0.905 0.664 0.750 0.703 0.836 0.725 0.776 0.739 0.804 0.767 9.52

13) T oxychlordane 0.903 0.665 0.750 0.703 0.836 0.726 0.776 0.739 0.807 0.767 9.49

14) T gamma-chlordane 0.909 0.700 0.792 0.750 0.881 0.799 0.862 0.825 0.840 0.818 8.00

15) T 2,4'-DDE 0.562 0.460 0.512 0.477 0.543 0.480 0.494 0.471 0.493 0.499 6.84

16) T endosulfan I 0.895 0.683 0.761 0.683 0.803 0.683 0.773 0.718 0.946 0.772 12.39

17) T alpha-chlordane 0.944 0.714 0.817 0.761 0.910 0.802 0.873 0.833 0.879 0.837 8.70

18) T trans-nonachlor 0.949 0.723 0.823 0.779 0.900 0.792 0.831 0.784 0.875 0.829 8.42

19) T 4,4'-DDE 0.727 0.612 0.690 0.678 0.735 0.749 0.758 0.734 0.674 0.706 6.59

20) T dieldrin 0.857 0.679 0.779 0.752 0.886 0.811 0.878 0.832 0.759 0.804 8.46

21) T 2,4'-DDD 0.528 0.436 0.486 0.453 0.480 0.448 0.450 0.429 0.484 0.466 6.71

22) T endrin 0.830 0.626 0.684 0.668 0.765 0.715 0.752 0.735 1.426 *L 0.9994

23) T endosulfan II 0.826 0.634 0.704 0.653 0.712 0.633 0.680 0.555 0.813 0.690 12.57

24) T 4,4'-DDD 0.621 0.520 0.577 0.563 0.578 0.607 0.598 0.580 0.582 0.581 4.93

25) T 2,4'-DDT 0.456 0.511 0.522 0.519 0.527 0.500 0.524 0.467 0.546 0.508 5.76

26) T cis-nonachlor 1.007 0.827 0.923 0.864 0.985 0.941 0.981 0.970 1.054 0.950 7.44

27) T endrin aldehyde 0.797 0.562 0.632 0.590 0.634 0.596 0.622 0.577 0.842 0.650 15.33

28) T endosulfan sul 25.81 28. 0.900 0.649 0.721 0.643 0.614 0.610 0.624 0.584 0.890 0.693 17.45

29) T 4,4'-DDT 0.851 0.593 0.650 0.613 0.657 0.657 0.672 0.648 1.857 *L 0.9995

30) T endrin ketone 0.961 0.688 0.771 0.725 0.740 0.735 0.769 0.718 0.903 0.779 11.76

31) T methoxychlor 0.389 0.353 0.361 0.336 0.332 0.320 0.306 0.297 0.450 0.349 13.52

32) T mirex 0.823 0.594 0.643 0.580 0.594 0.547 0.557 0.515 0.763 0.624 16.57

33) S BZ 198 0.820 0.630 0.691 0.628 0.632 0.625 0.616 0.573 0.810 0.670 13.11

34) S DCB - Surrogate 0.775 0.624 0.696 0.622 0.597 0.587 0.557 0.526 0.732 0.635 13.02

35) T Toxaphene 0.000 -1.00

36) T Technical Chlo 0.00 0. 0.000 -1.00

Signal #2 Calibration Files

1 =F210291211.D 5 =F210291212.D 10 =F210291213.D 20 =F210291214.D 50 =F210291215.D

100 =F210291216.D 150 =F210291217.D 200 =F210291218.D 0.5 =F210291210.D

Compound 1 5 10 20 50 100 150 200 0.5 Avg %RSD

--------------------------------------------------------------------------------------------------

1) I BZ 192 ----------------ISTD---------------------

2) S TMX - Surrogate 0.879 0.718 0.831 0.775 0.939 0.783 0.842 0.832 0.764 0.818 8.11

3) S DBOB 0.896 0.703 0.814 0.762 0.894 0.756 0.814 0.775 0.808 0.802 7.86

4) T alpha-BHC 1.118 0.926 1.065 1.040 1.314 1.180 1.284 1.302 0.994 1.136 12.51

5) T hexachlorobenz 8.88 8. 1.139 0.904 1.016 0.945 1.121 0.918 0.980 0.960 1.045 1.003 8.43

6) T beta-BHC 0.596 0.471 0.538 0.514 0.562 0.488 0.508 0.494 0.508 0.520 7.53

7) T gamma-BHC 1.100 0.890 1.020 0.984 1.200 1.075 1.151 1.168 0.950 1.060 9.99

8) T delta-BHC 1.027 0.853 0.955 0.940 1.067 1.045 1.086 1.098 0.963 1.004 8.08

9) T heptachlor 1.118 0.876 0.992 0.932 1.143 0.951 1.056 1.044 1.012 1.014 8.58

of 329

10) T aldrin 1.072 0.818 0.942 0.886 1.064 0.918 0.999 0.985 0.929 0.957 8.57

11) T chloropyrifos 0.597 0.479 0.521 0.489 0.529 0.432 0.439 0.416 0.545 0.494 12.05

of 329

6B GC ORGANICS ORGANICS INITIAL CALIBRATION DATA


SDG No.: L1219133

Instrument ID: ECD2 Calibration Date(s): 10/29/12 10/31/12

Calibration Times: 19:36 21:30

Compound 1 5 10 20 50 100 150 200 0.5 Avg %RSD

-----------------------------------------------------------------------------------------------------------------------------

12) T heptachlor epo 17.25 18. 1.054 0.812 0.917 0.862 0.993 0.852 0.916 0.890 0.964 0.918 8.25

13) T oxychlordane 0.960 0.736 0.830 0.771 0.875 0.720 0.754 0.725 0.895 0.807 10.70

14) T gamma-chlordane 0.976 0.778 0.847 0.797 0.871 0.812 0.866 0.856 0.994 0.866 8.61

15) T 2,4'-DDE 0.696 0.505 0.593 0.546 0.602 0.521 0.542 0.511 0.692 0.579 12.70

16) T endosulfan I 0.970 0.740 0.854 0.792 0.905 0.762 0.835 0.794 0.894 0.838 8.90

17) T alpha-chlordane 0.978 0.775 0.874 0.822 0.917 0.817 0.871 0.841 0.935 0.870 7.40

18) T trans-nonachlor 0.990 0.770 0.869 0.807 0.892 0.780 0.813 0.783 0.923 0.848 8.93

19) T 4,4'-DDE 0.801 0.651 0.731 0.700 0.739 0.741 0.763 0.757 0.749 0.737 5.70

20) T dieldrin 0.957 0.740 0.835 0.791 0.908 0.820 0.877 0.856 0.851 0.848 7.48

21) T 2,4'-DDD 0.578 0.456 0.507 0.484 0.493 0.457 0.457 0.442 0.531 0.490 8.98

22) T endrin 0.933 0.679 0.725 0.689 0.765 0.711 0.749 0.750 1.656 *L 0.9994

23) T endosulfan II 0.868 0.699 0.771 0.729 0.795 0.697 0.744 0.617 0.804 0.747 9.78

24) T 4,4'-DDD 0.627 0.542 0.607 0.579 0.585 0.599 0.594 0.586 0.602 0.591 3.96

25) T 2,4'-DDT 0.622 0.514 0.619 0.587 0.539 0.544 0.502 0.527 0.657 0.568 9.67

26) T cis-nonachlor 0.978 0.770 0.861 0.803 0.832 0.810 0.838 0.810 0.927 0.848 7.79

27) T endrin aldehyde 0.771 0.577 0.643 0.600 0.626 0.589 0.608 0.576 0.792 0.642 12.75

28) T endosulfan sul 25.81 28. 0.765 0.650 0.702 0.659 0.679 0.655 0.663 0.645 0.757 0.686 6.68

29) T 4,4'-DDT 0.832 0.599 0.646 0.606 0.611 0.605 0.613 0.601 1.829 *L 0.9999

30) T endrin ketone 0.878 0.722 0.799 0.748 0.751 0.739 0.748 0.725 0.940 0.783 9.72

31) T methoxychlor 0.380 0.342 0.371 0.349 0.334 0.316 0.299 0.293 0.409 0.344 11.18

32) T mirex 0.782 0.637 0.698 0.619 0.614 0.537 0.545 0.503 0.726 0.629 14.82

33) S BZ 198 0.745 0.656 0.704 0.646 0.613 0.603 0.587 0.555 0.720 0.648 9.97

34) S DCB - Surrogate 0.731 0.645 0.717 0.647 0.593 0.563 0.526 0.497 0.749 0.630 14.49

35) T Toxaphene 0.000 -1.00

36) T Technical Chlo 0.00 0. 0.000 -1.00

-------------------------------------------------------------------------------------------------------------------------------

FORM VI-A2-PEST-8081

of 329

7 GC Organics CONTINUING CALIBRATION CHECK


SDG No.: L1219133

Instrument ID: ECD2 Calibration Date: 10/31/2012 Time: 12:42

Lab File ID: F210301238 Init. Calib. Date(s): 10/29/12 10/31/12

Sample No: WG570776-1 (Sig Init. Calib. Times : 19:36 21:30

Injection Time: 10/31/2012 12:42

Integrator: ChemStation 6890 Scale Mode: Large solvent peaks clipped

Volume Inj. : 1

Signal #1 Phase : RTX 5 Signal #2 Phase: RTX CLP II

Signal #1 Info : .25 Signal #2 Info : .25

Min. RRF : 0.000 Min. Rel. Area : 50% Max. R.T. Dev 0.50min

Max. RRF Dev : 15% Max. Rel. Area : 150%

Compound Amount Calc. %Dev Area% Dev(Min)

-------------------------------------------------------------------------

1 I BZ 192 50.000 50.000 0.0 122 0.00

2 S TMX - Surrogate 50.000 54.254 -8.5 116 0.00

4 T alpha-BHC 50.000 58.627 -17.3# 122 0.00

5 T hexachlorobenzene 50.000 52.072 -4.1 113 0.00

6 T beta-BHC 50.000 54.045 -8.1 128 0.00

7 T gamma-BHC 50.000 56.172 -12.3 120 0.00

8 T delta-BHC 50.000 60.441 -20.9# 132 0.00

9 T heptachlor 50.000 54.655 -9.3 119 0.00

10 T aldrin 100.000 109.366 -9.4 121 0.00

12 T heptachlor epoxide (B) 100.000 109.132 -9.1 122 -0.01

13 T oxychlordane 100.000 109.054 -9.1 122 -0.01

14 T gamma-chlordane 50.000 55.743 -11.5 126 0.00

15 T 2,4'-DDE 50.000 55.351 -10.7 124 0.00

16 T endosulfan I 50.000 54.496 -9.0 127 0.00

17 T alpha-chlordane 50.000 54.465 -8.9 122 0.00

18 T trans-nonachlor 50.000 53.793 -7.6 120 0.00

19 T 4,4'-DDE 50.000 59.613 -19.2# 139 0.00

20 T dieldrin 50.000 56.929 -13.9 126 0.00

21 T 2,4'-DDD 50.000 55.749 -11.5 132 0.00

22 T endrin 50.000 55.042 -10.1 129 0.00

23 T endosulfan II 50.000 57.053 -14.1 134 0.00

24 T 4,4'-DDD 50.000 60.244 -20.5# 147 0.00

25 T 2,4'-DDT 50.000 56.977 -14.0 133 0.00

26 T cis-nonachlor 50.000 56.230 -12.5 132 0.00

27 T endrin aldehyde 50.000 53.680 -7.4 134 0.00

28 T endosulfan sulfate 50.000 52.960 -5.9 145 0.00

29 T 4,4'-DDT 50.000 55.896 -11.8 136 0.00

30 T endrin ketone 50.000 56.248 -12.5 144 0.00

31 T methoxychlor 50.000 52.366 -4.7 134 0.00

32 T mirex 50.000 51.415 -2.8 131 0.00

34 S DCB - Surrogate 50.000 55.253 -10.5 143 0.00


of 329


Data Path : O:\Organics\DATA\ECD2-6890N\2012\OCT\OCT30\

Data File : F210301238.D

Signal(s) : Signal #1: ECD1A.CH Signal #2: ECD2B.CH

Acq On : 31 Oct 2012 12:42 pm

Operator : ECD2:RR

Sample : WG570776-1 (Sig #1); WG (Sig #2)

Misc : WG570776,PW071212A

ALS Vial : 25 Sample Multiplier: 1

Integration File signal 1: autoint1.e


Quant Time: Nov 01 11:03:22 2012

Quant Method : O:\Organics\METHODS\ECD2-6890N\2012\PEST21029.M

Quant Title : PESTICIDES BY 8081A-ECD2

QLast Update : Wed Oct 31 11:02:31 2012


Volume Inj. : 1






-------------------------------------------------------------------------

38 I BZ 192 #2 50.000 50.000 0.0 132 0.00

39 S TMX - Surrogate #2 50.000 53.269 -6.5 122 0.00

41 T alpha-BHC #2 50.000 55.352 -10.7 126 0.00

42 T hexachlorobenzene #2 50.000 51.656 -3.3 122 0.00

43 T beta-BHC #2 50.000 53.221 -6.4 130 0.00

44 T gamma-BHC #2 50.000 55.029 -10.1 128 0.00

45 T delta-BHC #2 50.000 56.715 -13.4 141 0.00

46 T heptachlor #2 50.000 52.361 -4.7 122 0.00

47 T aldrin #2 50.000 52.590 -5.2 125 0.00

49 T heptachlor epoxide (B) #2 50.000 52.195 -4.4 127 -0.01

50 T oxychlordane #2 50.000 51.398 -2.8 125 -0.01

51 T gamma-chlordane #2 50.000 52.952 -5.9 139 -0.01

52 T 2,4'-DDE #2 50.000 51.081 -2.2 129 -0.01

53 T endosulfan I #2 50.000 51.969 -3.9 127 -0.01

54 T alpha-chlordane #2 50.000 52.540 -5.1 131 -0.01

55 T trans-nonachlor #2 50.000 52.547 -5.1 132 0.00

56 T 4,4'-DDE #2 50.000 56.349 -12.7 148 -0.01

57 T dieldrin #2 50.000 53.613 -7.2 132 -0.01

58 T 2,4'-DDD #2 50.000 54.214 -8.4 142 0.00

59 T endrin #2 50.000 53.615 -7.2 137 0.00

60 T endosulfan II #2 50.000 56.075 -12.2 139 0.00

61 T 4,4'-DDD #2 50.000 58.338 -16.7# 155 0.00

62 T 2,4'-DDT #2 50.000 54.175 -8.3 150 0.00

63 T cis-nonachlor #2 50.000 54.911 -9.8 147 0.00

64 T endrin aldehyde #2 50.000 53.074 -6.1 144 0.00

65 T endosulfan sulfate #2 50.000 57.488 -15.0 153 0.00

66 T 4,4'-DDT #2 50.000 55.999 -12.0 147 0.00

67 T endrin ketone #2 50.000 56.642 -13.3 156 0.00

68 T methoxychlor #2 50.000 54.906 -9.8 149 0.00

69 T mirex #2 50.000 51.780 -3.6 140 0.00


of 329





Acq On : 31 Oct 2012 12:42 pm

Operator : ECD2:RR


Misc : WG570776,PW071212A




Quant Time: Nov 01 11:03:22 2012





Volume Inj. : 1






-------------------------------------------------------------------------

71 S DCB - Surrogate #2 50.000 55.163 -10.3 154 -0.01


35 T Toxaphene -1.000 0.000 0.0 0 -0.11

72 T Toxaphene #2 -1.000 0.000 0.0 0 -0.11

--------------------------------------------------------------------------

FORM VII A2-PEST-8081

of 329



SDG No.: L1219133



Sample No: WG570776-2 (Sig Init. Calib. Times : 19:36 21:30



Volume Inj. : 1






-------------------------------------------------------------------------

1 I BZ 192 50.000 50.000 0.0 116 0.00

2 S TMX - Surrogate 50.000 56.465 -12.9 115 0.00

4 T alpha-BHC 50.000 61.195 -22.4# 121 0.00

5 T hexachlorobenzene 50.000 54.526 -9.1 113 0.00

6 T beta-BHC 50.000 56.486 -13.0 128 0.00

7 T gamma-BHC 50.000 58.568 -17.1# 119 0.00

8 T delta-BHC 50.000 62.861 -25.7# 131 0.00

9 T heptachlor 50.000 56.368 -12.7 117 0.00

10 T aldrin 100.000 113.550 -13.5 120 0.00

12 T heptachlor epoxide (B) 100.000 112.963 -13.0 121 -0.01

13 T oxychlordane 100.000 112.982 -13.0 121 -0.01

14 T gamma-chlordane 50.000 57.828 -15.7# 125 0.00

15 T 2,4'-DDE 50.000 57.300 -14.6 122 0.00

16 T endosulfan I 50.000 54.447 -8.9 122 0.00


18 T trans-nonachlor 50.000 54.891 -9.8 117 0.00

19 T 4,4'-DDE 50.000 61.078 -22.2# 137 0.00

20 T dieldrin 50.000 57.963 -15.9# 122 0.00

21 T 2,4'-DDD 50.000 57.432 -14.9 130 0.00

22 T endrin 50.000 56.509 -13.0 126 0.00

23 T endosulfan II 50.000 58.013 -16.0# 131 0.00

24 T 4,4'-DDD 50.000 62.484 -25.0# 146 0.00

25 T 2,4'-DDT 50.000 58.754 -17.5# 132 0.00

26 T cis-nonachlor 50.000 57.054 -14.1 128 0.00

27 T endrin aldehyde 50.000 54.768 -9.5 131 0.00

28 T endosulfan sulfate 50.000 54.058 -8.1 142 0.00

29 T 4,4'-DDT 50.000 52.421 -4.8 122 0.00

30 T endrin ketone 50.000 56.147 -12.3 137 0.00

31 T methoxychlor 50.000 48.097 3.8 118 0.00

32 T mirex 50.000 50.035 -0.1 122 0.00

34 S DCB - Surrogate 50.000 54.822 -9.6 136 0.00


of 329





Acq On : 31 Oct 2012 11:41 pm

Operator : ECD2:RR


Misc : WG570776,PW071212A




Quant Time: Nov 01 09:19:55 2012





Volume Inj. : 1






-------------------------------------------------------------------------

38 I BZ 192 #2 50.000 50.000 0.0 135 0.00

39 S TMX - Surrogate #2 50.000 53.450 -6.9 125 0.00

41 T alpha-BHC #2 50.000 55.345 -10.7 129 0.00

42 T hexachlorobenzene #2 50.000 51.800 -3.6 125 0.00

43 T beta-BHC #2 50.000 53.269 -6.5 133 0.00

44 T gamma-BHC #2 50.000 55.181 -10.4 131 0.00

45 T delta-BHC #2 50.000 56.819 -13.6 144 0.00

46 T heptachlor #2 50.000 51.599 -3.2 123 0.00

47 T aldrin #2 50.000 52.537 -5.1 127 0.00

49 T heptachlor epoxide (B) #2 50.000 51.886 -3.8 129 -0.01

50 T oxychlordane #2 50.000 51.136 -2.3 127 -0.01

51 T gamma-chlordane #2 50.000 52.436 -4.9 140 -0.01

52 T 2,4'-DDE #2 50.000 50.986 -2.0 132 -0.01

53 T endosulfan I #2 50.000 51.312 -2.6 128 -0.01

54 T alpha-chlordane #2 50.000 52.271 -4.5 134 -0.01

55 T trans-nonachlor #2 50.000 52.380 -4.8 134 -0.01

56 T 4,4'-DDE #2 50.000 55.724 -11.4 150 -0.01

57 T dieldrin #2 50.000 52.446 -4.9 132 -0.01

58 T 2,4'-DDD #2 50.000 54.288 -8.6 145 -0.01

59 T endrin #2 50.000 53.546 -7.1 140 -0.01

60 T endosulfan II #2 50.000 56.339 -12.7 143 -0.01

61 T 4,4'-DDD #2 50.000 59.969 -19.9# 163 -0.01

62 T 2,4'-DDT #2 50.000 52.282 -4.6 148 -0.01

63 T cis-nonachlor #2 50.000 54.477 -9.0 149 -0.01

64 T endrin aldehyde #2 50.000 52.668 -5.3 146 -0.01

65 T endosulfan sulfate #2 50.000 63.095 -26.2# 172 0.00

66 T 4,4'-DDT #2 50.000 52.508 -5.0 141 -0.01

67 T endrin ketone #2 50.000 56.841 -13.7 160 -0.01

68 T methoxychlor #2 50.000 50.218 -0.4 139 0.00

69 T mirex #2 50.000 51.390 -2.8 142 -0.01


of 329





Acq On : 31 Oct 2012 11:41 pm

Operator : ECD2:RR


Misc : WG570776,PW071212A




Quant Time: Nov 01 09:19:55 2012





Volume Inj. : 1






-------------------------------------------------------------------------

71 S DCB - Surrogate #2 50.000 54.316 -8.6 155 -0.01


35 T Toxaphene -1.000 0.000 0.0 0 -0.11

72 T Toxaphene #2 -1.000 0.000 0.0 0 -0.11

--------------------------------------------------------------------------


of 329



SDG No.: L1219133



Sample No: C210291210 Init. Calib. Times : 19:36 21:30



Volume Inj. : 1






-------------------------------------------------------------------------

1 I BZ 192 50.000 50.000 0.0 111 0.00

4 T alpha-BHC 50.000 51.090 -2.2 97 0.00

5 T hexachlorobenzene 50.000 44.323 11.4 88 0.00

6 T beta-BHC 50.000 46.439 7.1 101 0.00

7 T gamma-BHC 50.000 49.658 0.7 97 0.00

8 T delta-BHC 50.000 51.271 -2.5 103 0.00

9 T heptachlor 50.000 48.250 3.5 96 0.00

10 T aldrin 100.000 96.355 3.6 97 0.00

11 T chloropyrifos 100.000 96.295 3.7 97 0.00

12 T heptachlor epoxide (B) 100.000 98.564 1.4 101 0.00

13 T oxychlordane 100.000 98.302 1.7 100 0.00

14 T gamma-chlordane 50.000 48.952 2.1 101 0.00

15 T 2,4'-DDE 50.000 48.491 3.0 99 0.00

16 T endosulfan I 50.000 47.615 4.8 102 0.00


18 T trans-nonachlor 50.000 46.454 7.1 95 0.00

19 T 4,4'-DDE 50.000 49.845 0.3 107 0.00

20 T dieldrin 50.000 50.737 -1.5 102 0.00

21 T 2,4'-DDD 50.000 47.242 5.5 102 0.00

22 T endrin 50.000 49.165 1.7 105 0.00

23 T endosulfan II 50.000 50.164 -0.3 108 0.00

24 T 4,4'-DDD 50.000 49.722 0.6 111 0.00

25 T 2,4'-DDT 50.000 42.657 14.7 92 0.00

26 T cis-nonachlor 50.000 47.276 5.4 102 0.00

27 T endrin aldehyde 50.000 48.489 3.0 111 0.00

28 T endosulfan sulfate 50.000 43.757 12.5 110 0.00

29 T 4,4'-DDT 50.000 47.837 4.3 107 0.00

30 T endrin ketone 50.000 50.696 -1.4 119 0.00

31 T methoxychlor 50.000 45.299 9.4 106 0.00

32 T mirex 50.000 43.661 12.7 102 0.00


of 329





Acq On : 30 Oct 2012 2:55 am

Operator : ECD2:RR

Sample : C210291210

Misc : WG571275,PW102612J




Quant Time: Oct 31 11:06:52 2012





Volume Inj. : 1






-------------------------------------------------------------------------

Signal #2

1 I BZ 192 50.000 50.000 0.0 111 0.00

4 T alpha-BHC 50.000 50.063 -0.1 96 0.00

5 T hexachlorobenzene 50.000 45.137 9.7 90 0.00

6 T beta-BHC 50.000 48.180 3.6 99 0.00

7 T gamma-BHC 50.000 49.830 0.3 98 0.00

8 T delta-BHC 50.000 49.747 0.5 104 0.00

9 T heptachlor 50.000 48.517 3.0 96 0.00

10 T aldrin 50.000 48.360 3.3 97 0.00

11 T chloropyrifos 50.000 46.266 7.5 96 0.00

12 T heptachlor epoxide (B) 50.000 47.956 4.1 98 0.00

13 T oxychlordane 50.000 49.147 1.7 101 0.00

14 T gamma-chlordane 50.000 46.884 6.2 103 0.00

15 T 2,4'-DDE 50.000 45.780 8.4 98 0.00

16 T endosulfan I 50.000 48.479 3.0 100 0.00

17 T alpha-chlordane 50.000 49.401 1.2 104 0.00

18 T trans-nonachlor 50.000 46.280 7.4 98 0.00

19 T 4,4'-DDE 50.000 48.003 4.0 106 0.00

20 T dieldrin 50.000 48.989 2.0 102 0.00

21 T 2,4'-DDD 50.000 46.155 7.7 102 0.00

22 T endrin 50.000 48.833 2.3 105 0.00

23 T endosulfan II 50.000 51.524 -3.0 108 0.00

24 T 4,4'-DDD 50.000 49.722 0.6 111 0.00

25 T 2,4'-DDT 50.000 47.579 4.8 111 0.00

26 T cis-nonachlor 50.000 45.315 9.4 102 0.00

27 T endrin aldehyde 50.000 49.184 1.6 112 0.00

28 T endosulfan sulfate 50.000 47.733 4.5 107 0.00

29 T 4,4'-DDT 50.000 48.201 3.6 107 0.00

30 T endrin ketone 50.000 53.373 -6.7 124 0.00


of 329





Acq On : 30 Oct 2012 2:55 am

Operator : ECD2:RR

Sample : C210291210

Misc : WG571275,PW102612J




Quant Time: Oct 31 11:06:52 2012





Volume Inj. : 1






-------------------------------------------------------------------------

31 T methoxychlor 50.000 46.678 6.6 107 0.00

32 T mirex 50.000 45.190 9.6 103 0.00


2 S TMX - Surrogate 50.000 0.000 100.0# 0 -7.47#

3 S DBOB 50.000 0.000 100.0# 0 -7.87#

33 S BZ 198 50.000 0.000 100.0# 0 -30.78#

34 S DCB - Surrogate 50.000 0.000 100.0# 0 -37.22#

35 T Toxaphene -1.000 0.000 0.0 0 -0.11

36 T Technical Chlordane -1.000 0.000 0.0 0 -0.11

Signal #2

2 S TMX - Surrogate 50.000 0.000 100.0# 0 -7.29#

3 S DBOB 50.000 0.000 100.0# 0 -7.91#

33 S BZ 198 50.000 0.000 100.0# 0 -31.00#

34 S DCB - Surrogate 50.000 0.000 100.0# 0 -37.54#

35 T Toxaphene -1.000 0.000 0.0 0 -0.11

36 T Technical Chlordane -1.000 0.000 0.0 0 -37.42#

--------------------------------------------------------------------------


of 329

8D GC ORGANICS ANALYTICAL SEQUENCE


SDG No.: L1219133

Init. Calib. Date(s): 10/29/12 10/31/12

Instrument ID : ECD2

THE ANALYTICAL SEQUENCE OF PERFORMANCE EVALUATION MIXTURES, BLANKS, SAMPLES, AND STANDARDS IS GIVEN BELOW:

___________________________________________________________ | EPA | LAB | DATE | TIME | |SAMPLE NO. | SAMPLE ID | ANALYZED | ANALYZED | |===================|================|===========|==========|

01|Degradation Check |Degradation Chec| 10/29/12 | 18:52 |02|STD0.5 |STD0.5 | 10/29/12 | 19:36 |03|STD1 |STD1 | 10/29/12 | 20:20 |04|STD5 |STD5 | 10/29/12 | 21:04 |05|STD10 |STD10 | 10/29/12 | 21:48 |06|STD20 |STD20 | 10/29/12 | 22:32 |07|STD50 |STD50 | 10/29/12 | 23:15 |08|STD100 |STD100 | 10/29/12 | 23:59 |09|STD150 |STD150 | 10/30/12 | 00:43 |10|STD200 |STD200 | 10/30/12 | 01:27 |11|ICV Quant Report ST|ICV Quant Report| 10/30/12 | 02:55 |12|Degradation Check |Degradation Chec| 10/31/12 | 11:58 |13|CCAL |WG570776-1 | 10/31/12 | 12:42 |14|WG569308-1BLANK |WG569308-1 | 10/31/12 | 14:10 |15|WG569308-2LCS |WG569308-2 | 10/31/12 | 14:54 |16|WG569308-3LCSD |WG569308-3 | 10/31/12 | 15:38 |17|Toxaphene STD25 |Toxaphene STD25 | 10/31/12 | 20:46 |18|Technical Chlordane|Technical Chlord| 10/31/12 | 21:30 |19|SED-20121017-01 |L1219133-01 D | 10/31/12 | 22:13 |20|CCAL |WG570776-2 | 10/31/12 | 23:41 |

|___________________|________________|___________|__________||___________________|________________|___________|__________||___________________|________________|___________|__________||___________________|________________|___________|__________||___________________|________________|___________|__________||___________________|________________|___________|__________||___________________|________________|___________|__________||___________________|________________|___________|__________||___________________|________________|___________|__________||___________________|________________|___________|__________||___________________|________________|___________|__________||___________________|________________|___________|__________||___________________|________________|___________|__________||___________________|________________|___________|__________|

page 1 of FORM VIII -

of 329

10A SAMPLE NO. GC ORGANICS IDENTIFICATION SUMMARY ________________ FOR SINGLE COMPONENT ANALYTES | |

| SED-20121017-01| Lab Name: Alpha Analytical Labs |________________|

SDG No.: L1219133

Lab Sample ID: L1219133-01 D Date(s) Analyzed: 10/31/12 10/31/12


GC Column (1): RTX-5 GC Column (2): RTX-CLPPesticides2 __________________________________________________________________

| | | | RT WINDOW | | | | ANALYTE |COL| RT | FROM | TO |CONCENTRATION| %RPD| |====================|===|======|======|======|=============|======| | | | | | | | | |hexachlorobenzene | 1 | 8.88 | 8.82 | 8.92 | 3.73 | | | | | | | | | | | | 2 | 8.78 | 8.73 | 8.83 | 7.51 |67.2 | | | | | | | | | | | | | | | | | |beta-BHC | 1 | 9.3 | 9.31 | 9.41 | 66. | | | | | | | | | | | | 2 |11.09 |11.02 |11.12 | 1.81 |189.3 | | | | | | | | | | | | | | | | | |heptachlor | 1 |12.74 |12.67 |12.77 | 6.17 | | | | | | | | | | | | 2 |12.9 |12.85 |12.95 | 2.07 |99.5 | | | | | | | | | | | | | | | | | |gamma-chlordane | 1 |18.91 |18.83 |18.93 | 20.6 | | | | | | | | | | | | 2 |19.97 |19.92 |20.02 | 16.7 |20.9 | | | | | | | | | | | | | | | | | |2,4'-DDE | 1 |19.16 |19.11 |19.21 | 8.82 | | | | | | | | | | | | 2 |20.1 |20.09 |20.19 | 32.2 |114 | | | | | | | | | | | | | | | | | |alpha-chlordane | 1 |19.94 |19.88 |19.98 | 13. | | | | | | | | | | | | 2 |20.94 |20.88 |20.98 | 12.8 |1.6 | | | | | | | | | | | | | | | | | |trans-nonachlor | 1 |20.25 |20.19 |20.29 | 6.17 | | | | | | | | | | | | 2 |20.61 |20.56 |20.66 | 13.4 |73.9 | | | | | | | | | | | | | | | | | |4,4'-DDE | 1 |21.28 |21.22 |21.32 | 45.2 | | | | | | | | | | | | 2 |22.18 |22.14 |22.24 | 117. |88.5 | | | | | | | | | |____________________|___|______|______|______|_____________|______|

page 1 of 3 FORM X A2-PEST-8081

of 329



SDG No.: L1219133




| | | | RT WINDOW | | | | ANALYTE |COL| RT | FROM | TO |CONCENTRATION| %RPD| |====================|===|======|======|======|=============|======| | | | | | | | | |dieldrin | 1 |21.48 |21.43 |21.53 | 8.41 | | | | | | | | | | | | 2 |22.93 |22.84 |22.94 | 28.7 |109.4 | | | | | | | | | | | | | | | | | |2,4'-DDD | 1 |21.83 |21.79 |21.89 | 63.1 | | | | | | | | | | | | 2 |23.35 |23.29 |23.39 | 23.4 |91.8 | | | | | | | | | | | | | | | | | |endosulfan II | 1 |23.39 |23.34 |23.44 | 17.2 | | | | | | | | | | | | 2 |25.8 |25.71 |25.81 | 3.87 |126.5 | | | | | | | | | | | | | | | | | |4,4'-DDD | 1 |23.86 |23.81 |23.91 | 62.3 | | | | | | | | | | | | 2 |25.49 |25.43 |25.53 | 65.7 |5.3 | | | | | | | | | | | | | | | | | |cis-nonachlor | 1 |24.15 |24.09 |24.19 | 2.4 | | | | | | | | | | | | 2 |25.16 |25.1 |25.2 | 3.22 |29.2 | | | | | | | | | | | | | | | | | |endrin aldehyde | 1 |24.5 |24.44 |24.54 | 1.29 | | | | | | | | | | | | 2 |27.54 |27.48 |27.58 | 19.1 |174.7 | | | | | | | | | | | | | | | | | |4,4'-DDT | 1 |25.97 |25.92 |26.02 | 78.3 | | | | | | | | | | | | 2 |27.09 |27.04 |27.14 | 110 |33.7 | | | | | | | | | | | | | | | | | |methoxychlor | 1 |28.84 |28.75 |28.85 | 148. | | | | | | | | | | | | 2 |30.09 |30 |30.1 | 105. |34 | | | | | | | | | |____________________|___|______|______|______|_____________|______|


of 329



SDG No.: L1219133




| | | | RT WINDOW | | | | ANALYTE |COL| RT | FROM | TO |CONCENTRATION| %RPD| |====================|===|======|======|======|=============|======| | | | | | | | | |mirex | 1 |30.58 |30.49 |30.59 | 8.27 | | | | | | | | | | | | 2 |30.6 |30.55 |30.65 | 32.1 |118 | | | | | | | | || | | | | | | | |____________________| 1 |______|______|______|_____________| | | | | | | | | | | | 2 |______|______|______|_____________|______| | | | | | | | || | | | | | | | |____________________| 1 |______|______|______|_____________| | | | | | | | | | | | 2 |______|______|______|_____________|______| | | | | | | | || | | | | | | | |____________________| 1 |______|______|______|_____________| | | | | | | | | | | | 2 |______|______|______|_____________|______| | | | | | | | || | | | | | | | |____________________| 1 |______|______|______|_____________| | | | | | | | | | | | 2 |______|______|______|_____________|______| | | | | | | | || | | | | | | | |____________________| 1 |______|______|______|_____________| | | | | | | | | | | | 2 |______|______|______|_____________|______| | | | | | | | || | | | | | | | |____________________| 1 |______|______|______|_____________| | | | | | | | | | | | 2 |______|______|______|_____________|______| | | | | | | | || | | | | | | | |____________________| 1 |______|______|______|_____________| | | | | | | | | | | | 2 |______|______|______|_____________|______| | | | | | | | | |____________________|___|______|______|______|_____________|______|


of 329

PEM PERFORMANCE EVALUATION MIXTURE REPORT


SDG No.: L1219133

PEM Standard Name: R556808-1 Analysis Date: 10/31/12 11:58

Instrument ID: ECD2

Column 1: RTX-5 Column 2: RTX-CLPPesticides2

Parameter Signal 1 Signal 2

4,4'-DDE 3337372 1444303 endrin 1708302954 541844674 4,4'-DDD 32057510 10385289 endrin aldehyde 8034096 2941948 4,4'-DDT 2147483647 924939401 endrin ketone 51234907 15775939

Parameter % Breakdown 1 %Breakdown 2

endrin 3.35 3.34 DDT 1.62 1.26

FORM XV A2-PEST-8081

of 329

newtowncreek.infonewtowncreek.info/docs2/2 Remedial Investigation...Alpha Analytical Deliverable...

Documents

Transcript of newtowncreek.infonewtowncreek.info/docs2/2 Remedial Investigation...Alpha Analytical Deliverable...